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Product Name : Glutamate dehydrogenase (GTD-209/309/409)

First issue : May. 1, 2014
Revised: May. 31. 2022
SDS No.871F

Safety Data Sheet
1

Chemical product and company identification
Identification of the productProduct CodeSupplier
NameAddress
Department
Phone
Fax

Recommended use and restrictions on use

Gultamate dehydrogenase
GTD-209 / 309 / 409
TOYOBO CO.,LTD.
Osaka Umeda Twin Towers South,
1-13-1 Umeda Kita-ku, Osaka 530-0001, Japan
Biotechnology Overseas Sales and Marketing Department+81-6-6348-3846+81-6-6348-3833
diagnostic product2 Hazard Identification3

Most Important Hazards and Effects

Harmful if Sodium azide is swallowed.
Insufficient data are available on the effect of thissubstance on human health, therefore care must be taken.

GHS classification

Classification not possible

Composition/Information on Ingredients
Substance/Mixture
Chemical Nature
Chemical specificity
Concentration or concentration range
CAS#
Stabilizer, etc
Ingredients Contributing to the Hazard
Common Chemical nameConcentration or concentration range
Chemical formulaCAS#4

MixtureGultamate dehydrogenase
Freeze and drying powder including enzyme
ca. 2-4%(W/V)
9029-11-2
ca. 96-98% (W/V)
Sodium azide
ca. 0.05% (W/V)
NaN326628-22-8

First Aid Measures
Inhalation
Skin Contact
Eye Contact

Ingestion

Remove to fresh air. Consult a physician whenunpleasantness occurs.
Wash off with plenty of water. Consult a physician when
inflammation on the skin occurs.
Rinse cautiously with water for several minutes. Remove
contact lenses,if present and easy to do. Continue
rinsing. If eye irritation persists, get medical
advise/attention.
Rinse mouth. Swill plentiful amount of water or milk for
immediate vomiting. Consult a physician.

5 Fire
火災時の措置Fighting Measures
Extinguishing Media
Precautions for fire-fighters

Water spray,dry chemical powder,or carbon dioxide etc.
Avoid working at leeward.

6 Accidental
漏出時の措置
Release Measures
Personal Precautions, protective equipment andemergency procedure.
Environmental Precautions
Methods and materials for containment andcleaning up.

Wear proper protective gear to avoid eye/skin contact andinhalation. Work from the windward side.
High concentrated waste fluid should not be directly
discharged into rivers.
Use cloth, paper or anything similar to soak up thesolution leaking out of the container.
(Waste water should be treated with activated sludge oradsorbed with activated carbon etc.)

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Product Name : Glutamate dehydrogenase (GTD-209/309/409)

First issue : May. 1, 2014
Revised: May. 31. 2022
SDS No.871F

Safety Data Sheet
7 Handling
取扱い及び保管上の注意and Storage
Handling
Technical Measures
Precautions

Wear protective gear to avoid eye/skin contact andinhalation.
Do not drop the container to prevent the content poppingout.

StorageTechnical Measures
Incompatible substances and mixtures
Storage Conditions
Packaging Materials

Keep sealed container in refrigerator.
None specified.
Store at 4℃ to avoid deactivating.
Use the initial container of the product.

8 Exposure
暴露防止及び保護措置
Controls/Personal Protection
Engineering controls
Occupational exposure limit,biological limit
Personal Protective Equipment
Respiratory Protection
Hand Protection
Eye Protection
Skin and Body Protection

Provide shower and eye washing equipment nearby.
(ACGIH) Sodium azide
TLV: 0.29mg/m3
Protecting mask
Protecting gloves
Safety goggles
Long sleeve working wear

9 Physical
物理的及び化学的性質
and Chemical Properties
Physical State, form and colorOdour
pH
Flash Point
Explosiveness
DensitySolubility

LiquidColorless/No odour
ca. pH7.8 (1% W/V)
No information available.
No information available.
ca 1.0g/cm3(4℃)
Freely soluble in water.

10 Stability
安定性及び反応性and Reactivity
Stability
Possible hazard reactions at specific condition

Stable at 2-8℃. When left for long at room
temperature,proteins might be degraded, which does notcause any hazardous reaction.

Conditions to avoid

Prolonged storage under higher temperature than roomtemperature.
Compound which decompose strong acid or strong alkali
protein.
Nitric monoxide, metal azide, hydrazoic acid.

Materials to avoidHazardous Decomposition Products

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Product Name : Glutamate dehydrogenase (GTD-209/309/409)

First issue : May. 1, 2014
Revised: May. 31. 2022
SDS No.871F

Safety Data Sheet
11 Toxicological Information
Acute Toxicity (Oral)
Skin corrosion/irritation(Sodium azide) LD50 27mg/Kg
May cause serious corrosion on skin with sodium azide.
No information as products.

Serious eye damage/irritation

May cause serious eye damage with sodium azide.
No information as products.

Sensitization
Germ cell mutagenicity
Carcinogenicity
Toxic to reproduction
Specific target organ toxicity(Single exposure)Specific target organ toxicity(Repeated exposure)
Aspiration hazards

No information available.
No information available.
No information available.
No information available.
No information available.
No information available.
No information available.

12 Ecological
環境影響情報Information
Persistence/Degradability

This product is biodegradable and does not remain on theenvironment for long.

13 Disposal
廃棄上の注意Considerations
Residues

Dispose in accordance with all applicable local andnational laws and regulations. May cause explossion by
any shock under dried condition, because sodium azide iseasy to combine with heavy metal. Wash off drainpipe withplenty of water not to keep residues in after draining.

A pollution container and packing

Wash with copious amounts of water and waste conforming tolocal regulations depending on the type of the material.

14 Transport
輸送上の注意Information
International regulations
IMO information
IATA information
Domestic regulations
Rail and road transportation information
Marine transportation information
Aviation transportation information
Specific precautions transport measures andconditions

Not applicableNot applicableNot applicableNot applicableNot applicable
Avoid direct sunshine and check the container and loading
to prevent leakage or turnover,fall and damage.Transport
in accordance with regulations.Do not load with foods andfeed. Keep at temperatures 2-8℃.

15 Regulatory
適用法令 Information
Regulations

Follow all of laws and regulations in your country.

16 Other
その他の情報Information
Notice

The information shall not be taken as being all inclusive
and is to be used only a guide.All materials and mixtures
may be present unknown hazards and should be used withcaution.The SDS is subject to revision as new information
becomes available.The information in this SDS,to the bestof our knowledge, is accurate and correct. However,TOYOBO
makes no warranty and assumes no liability whatsoever inconnection with any use of this information.