ISSUED DATE：Sep.18.2018
PAGE： 1/8

SAFETY DATA SHEET
1．IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
GHS product identifier：ZEOFILL
Recommended use of the chemical and restrictions on use：Dehydration, purification, separation of gas and liquid, catalyst, ion exchange,porous carrier, soil improvement, water treatment, gas adsorption
Supplier’s detail
Name of manufacturer：Shin Tohoku Chemical Industry Co., Ltd.
Address：1-4-10, Kamisugi, Aoba-ku, Sendai-shi, Miyagi, 980-0011 Japan
Name of section：Production Headquarters
Phone number：+<81> 22-225-2724
Emergency phone number ：Shin Tohoku Chemical Industry Co., Ltd.
+<81> 22-225-2724

2．HAZARDS IDENTIFICATION【GHS CLASSIFICATION】
Physical hazards
Health Hazards

Environmental Hazards

Flammable solids
Acute toxicity (Oraｌ)
Acute toxicity (Dermal)
Acute toxicity (Inhalation: Dust)
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity(Single exposure)Specific target organ toxicity(Repeated exposure)
Aspiration hazard
Hazardous to the aquatic environment(Acute hazard)
Hazardous to the aquatic environment(Long-term hazard)
Hazardous to the ozone Layer［GHS LABEL ELEMENTS］
Symbols[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.

：Classification not possible：Category 5：Category 5：Classification not possible：Classification not possible：Category 2：Classification not possible：Classification not possible：Category 2：Category 1A：Classification not possible：Classification not possible：Category 1 (Respiratorysystem, Kidneys, Immunesystem)：Classification not possible：Not classified：Classification not possible：Classification not possible

ISSUED DATE：Sep.15.2018
PAGE： 2/8

Signal word
Hazard statements：Danger・May be harmful if swallowed
・May be harmful in contact with skin・Causes serious eye irritation
・Suspected of causing genetic defects
・May cause cancer
・Causes damage to organs (Respiratory system, Kidneys, Immune system)
through prolonged or repeated exposure
Precautionary statements[Prevention]
・Wash hands and eyes thoroughly after handling.
・Wear protective gloves/protective clothing/eye protection/face protection.
・Obtain special instructions before use.
・Do not handle until all safety precautions have been read and understood.
・Do not breathe dust/fume/gas/mist/vapours/spray.
・Do not eat, drink or smoke when using this product.
[Response]・Call a POISON CENTER or doctor/physician if you feel unwell.
・IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses if present and easy to do. Continue rinsing.
・If eye irritation persists: Get medical advice/attention.
・IF exposed or concerned: Get medical advice/attention.
・Get Medical advice/attention if you feel unwell.
[Storage]
・Store locked up.
[Disposal]
・Dispose of contents/containers in accordance with the rules of thecountry/province/municipality.

3．COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Mixture：Substance (Natural mineral)
Chemical name or common name：Mordenite type zeolite (Natural mineral)
Composition：This material contains minerals such as quartz as a main component ofmordenite type zeolite.
Ingredients
Composition(%)
Chemical formulaCAS No.
1318-02-1
Mordenite type zeolite
80-90(Na2,Ca,K2)4[Al8Si40O96]･28H2O
14808-60-7
Quartz (crystalline silica)
10-20SiO2

4．FIRST-AID MEASURES
Inhalation

Skin contact[ZEOFILL]

・Get medical advice/attention if necessary.
・When inhaled dust which is generated at processing the product, remove victim
to fresh air and keep at rest, cover body with a blanket etc. to keep him/herwarm.
・Wash away affected portion with running water, then wash adequately withsoap.
・If you feel skin abnormality such as itching or pain, etc., get medical attention.

Shin Tohoku Chemical Industry Co., Ltd.

ISSUED DATE：Sep.15.2018
PAGE： 3/8Eye contact

・If dust in eyes, never rub your eyes and rinse away cautiously with water for atleast 15 minutes.
・When washing eyes, open eyelids well with fingers and move the eyes around toreach water to every corner of the eyes.
・If you feel your eyes abnormality, consult an ophthalmologist.
Ingestion
・Rinse out mouth with water, ｇet medical advice/attention.
Most important symptoms and effects, both acute and delayed
・May be harmful if swallowed
・May be harmful in contact with skin・Causes serious eye irritation
・Suspected of causing genetic defects
・May cause cancer
・Causes damage to organs (Respiratory system, Kidneys, Immune system)
through prolonged or repeated exposure
Protection for first aider
・No data available
Indication of any immediate medical attention and special treatment needed・No data available

5．FIRE-FIGHTING MEASURESThis product is not combustible. If the containers/packing etc. catch fire, extinguish the fire in the usualmeasures.
Suitable extinguishing media ・Dry chemical powder ,Carbon dioxide, Dry sand, Foam, Water spray
Unsuitable extinguishing media・Nothing special
Specific hazards arising from the chemical
・Toxic gases (Metal fumes, etc.) may be generated upon combustion.
Specific extinguishing methods
・Use normal extinguishing media (Chemical powder, carbon dioxide, or water) foran early stage of fire.
・For large fire, in order to extinguish a fire at once, cut off the air using foam.
・In case of fire in the surrounding areas, cool equipment by water spraying.
・If possible, move containers to safe areas.
・Be careful not to cause environmental pollution by the outflow of fire
extinguishing and/or dilution water.
Special protective equipment for firefighters
・Firefighters should wear proper protective equipment such as self-contained
breathing apparatus. Extinguish fire from windward.

6．ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures・Rope off the spilled area to prohibit the entrance of unauthorized personnel.
・Wear proper protective equipment during recovery operation.
・Do not collect spillage at the leeward.
・Avoid breathing dust, avoid attach to eyes and skin.

[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.

ISSUED DATE：Sep.15.2018
PAGE： 4/8
Environmental precautions ・Prevent dust from scattering into the atmosphere, and do not dispose of it intosoil, sewers, rivers or drains etc.
Methods and material for containment and cleaning up
・In case of small amount of spilｌs, sweep up spilｌs together carefully with abroom not to scatter.
・In case of large amount of spills, cover the surface of spills with a sheet toprevent dust from scattering, then use a dust collector to collect it, or sprinkle
water and collect sludge by shovels, etc.
・The waste shall be disposed of in accordance with “13.DISPOSALCONSIDERATIONS”.

7．HANDLING AND STORAGE
Precautions for safe handling・Keep formation of air bone dust to a minimum.
・Avoid inhalation of dust and contact with skin as much as possible.
・If dust is generated when processing the product, work in the room where local
exhaust equipment was installed.
・If there is a risk of exposure, wear appropriate protective equipment.
・Enforce gargle, hand washing and face washing after handling.
・Avoid prolonged handling and repeated exposure as much as possible.
・If you feel abnormality or abnormality has occurred in the body, take measuresaccording to section 4 “FIRST-AID MEASURES”, and then be sure to consult
a physician.
Conditions for safe storage, including any incompatibilities
Safe storage conditions
・Avoid wetting and high humidity, store in a dry and well-ventilated location.
・Keep away from incompatible materials. (Refer to section 10)
Safe packaging materials
・There is no limitation on the material, but use materials that have as little
moisture permeability as possible.

8．EXPOSURE CONTROLS/PERSONAL PROTECTION
Appropriate engineering controls・Install eye washer and shower near work area.
・Keep good ventilation in the work area, install a dust collector or local exhaustsystem as necessary.
Occupational Exposure Limits
ACGIH-TLV 1)・(TWA) 1 mg/m3 (Aluminum metal and insoluble compound, Respirable fraction)・(TWA) 0.025 mg/m3 (Silica, crystalline-α-quartz, Respirable fraction)・(TWA) 10 mg/m3 (Particles, Insoluble or poorly soluble, not otherwise specified,Inhalable particles)・(TWA) 3 mg/m3 (Particles, Insoluble or poorly soluble, not otherwise specified,
Respirable particles)
Note) (TWA): Time-Weighted Average (8 hours)[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.

ISSUED DATE：Sep.15.2018
PAGE： 5/8
Individual protection measures, such as personal protective equipment
Respiratory protection ：Dust mask, air-supplied respirator
Hands protection：Protective gloves (Made of rubber)
Eye protection：Protective glasses with the side shield or face protection.
Skin and body protection：Protective clothing, protective boots and apron

9．PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Appearance
ColourOdour
Odour threshold
pH
Melting/Freezing point
Initial boiling point andboiling range
Flash point
Evaporation rate(n-BuAc = 1)
Flammability (solid, gas)
Upper/lower flammability
or explosive limits
Vapour pressure
Vapour density
Relative density：Crushed particles to powder：White to light yellow：Odourless：No data available：Purified water ± 0.6 (Mixing with purified water)：>1250℃：Not applicable (Due to high melting inorganic inert substances)：Not Flammable：No data available：Not flammable：No data available：No data available：No data available：0.6±0.1 (Apparent density)
2.1 (True density)：Insoluble：No data available

SolubilityPartition coefficient:
n-octanol/water (log value)
Auto-ignition temperature ：Not Flammable
Decomposition temperature ：No data available
Viscosity：No data available

10．STABILITY AND REACTIVITY
Reactivity
・Stable under normal handling condition.
Chemical stability
・Stable under normal handling condition.
Possibility of hazardous reactions
・No hazardous reactions happen under normal handling condition.
Conditions to avoid
・Humidity, water
Incompatible materials
・No data available
Hazardous decomposition products
・Toxic gases (Metal fumes, etc.) may be generated on combustion.

[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.

ISSUED DATE：Sep.15.2018
PAGE： 6/8

11．TOXICOLOGICAL INFORMATION
There are no data available on the mixture itself. Data of ingredients are as follows.
Acute toxicity［Oral］
Mordenite type zeolite
Rat
LD50>2000mg/kg 2)［Dermal］>2000mg/kg 2)Mordenite type zeolite
Rabbit LD50
[Inhalation]>14ml/L 2)
Mordenite type zeolite
Rat
LC50Note) LD50: Lethal Dose, 50% kill
LC50: Lethal Concentration, 50% kill
Skin corrosion/irritation
Mordenite type zeolite
Showed no irritation in skin irritation tests of rabbits. 2)
Serious eye damage/eye irritation
Mordenite type zeolite
Showed moderate irritation in eye irritation tests of rabbits.2)
Respiratory sensitization
No ingredients data available
Skin sensitization
No ingredients data available
Germ cell mutagenicity
Quartz (crystalline silica)
Showed positive in in vivo somatic cell mutagenicity studies of rat.2)
Carcinogenicity
Mordenite type zeolite
IARC: Group 3 (Unclassifiable as to Carcinogenicity in Humans) 1)
Quartz (crystalline silica)
IARC: Group 1 (The agent is carcinogenic to humans) 1)
JSOH: Group 1 (Carcinogenic to humans) 3)
ACGIH: A2 (Suspected human carcinogen) 1)
NTP: K (Known to be carcinogens) 1)
Reproductive toxicity
No ingredients data available
Specific target organ toxicity (Single exposure)
No ingredients data available
Specific target organ toxicity (Repeated exposure)
Mordenite type zeolite
Causes damage to organs （Respiratory organ） through prolonged orrepeated exposure. 2)
Quartz (crystalline silica)
Causes damage to organs （Respiratory system, Kidneys, Immunesystem） through prolonged or repeated exposure. 2)
Aspiration hazard
No ingredients data available

12．ECOLOGICAL INFORMATION
Eco-toxicity
Mordenite type zeolite Pimephales promelas
NOEC (21d)
175 mg/l 2)
Daphnia magna
EC50 (72h)
377 mg/l 2)
Daphnia magna
NOEC (21d)200 mg/l 2)
2)
Hazard is lower than GHS hazard category.
Hazardous to the aquatic environment (Long-term hazard) is lower than GHS
hazard category. 2)[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.

ISSUED DATE：Sep.15.2018
PAGE： 7/8
Quartz (crystalline silica)
Hazard is lower than GHS hazard category. 2)Note) EC50: Median Effect Concentration
NOEC: No Observed Effect Concentration
Persistency and Biodegradability
No data available
Bioaccumulation potential
No data available
Mobility in soil
No data available
Other adverse effects
Hazardous to the ozone Layer
No data available

13．DISPOSAL CONSIDERATIONS
Residual waste

・Entrust residual wastes as industrial wastes to a certificated special authority.
・Take care not to scatter dust in the air.
・Follow all relevant laws, regulations and municipality instructions.
Contaminated containers and packaging
・In case of disposing of empty containers, remove the contents completely.
・Perform a proper disposal of in accordance with the relevant laws, regulations
and standards.

14．TRANSPORT INFORMATION
UN Number：Not applicable
UN proper shipping name：Not applicable
Transport hazard class：Not applicable
Packing group：Not applicable
Marine pollutants：No
Transport in bulk (according to AnnexⅡof MARPOL 73/78 and the IBC Code)：Not applicableSpecial safety measures applicable to transport or conveyance・Load containers carefully to avoid damaging containers, leaking product.
・Prevent load collapse surely.
・Do not stack heavy load high.
・Avoid wetting.
・When loading and unloading cargoes, put the parking brake on, shut down theengine, and put car stops under tires.
・Handle in accordance with the description of “7 HANDLING AND STORAGE.”
・Observe strictly transportation related laws and regulations.

15．REGULATORY INFORMATIONGHS classification and labeling ：In accordance with UN GHS fourth revised edition.
The product and its ingredients are not regulated by international agreements such as Montreal Protocol,
Stockholm Convention, Rotterdam Convention and Basel Convention.
Regulatory information with regard to this product in your country or region should be examined by your own
responsibility.
[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.

ISSUED DATE：Sep.15.2018
PAGE： 8/8

16. OTHER INFORMATION INCLUDING INFORMATION ON PREPARATION AND REVISION OFTHE SDS
Update history:
Issued date; Sep.18.2018 (1st edition)
References:
1) 2017 Threshold Limit Values for Chemical Substances in the Work Environment (ACGIH)
2) GHS Classification Data Base (National Institute of Technology and Evaluation, Japan)
3) Recommendation of Occupational Exposure Limits; Journal of Japan Society for Occupational
Health 2017 vol.58
Abbreviations and acronyms:
ACGIH
American Conference of Government Industrial Hygienists
TLV
Threshold Limit Values
IARCInternational Agency for Research Cancer
JSOH
Japan Society for Occupational Health
NTP
United States National Toxicology Program
IBC
International Bulk Chemical
Disclaimer:
The information contained herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is given in good faith in accordance with the data in a variety of technicalpublications. It is the user’s responsibility to determine the suitability of this information for the adoptionof necessary safety precautions.
In addition, the information listed here is made based on the latest information by our investigation at thetime of creation, but please understand that revision is possible by amendment of laws, regulations or theannouncement of new toxicity test results.

[ZEOFILL]

Shin Tohoku Chemical Industry Co., Ltd.