ࢩ࢔ࣀᯫᶫᆺ஧ḟඖ㓄఩㧗ศᏊࡢࢩ࣮ࢺᵓ㐀ಟ㣭࡟ࡼࡿ⇕⭾ᙇᣲືไᚚ(ᇳ➹⪅ྡ) ኱㇂ு(ᡤᒓྡ) ஑ᕞ኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲㝔

1. ࡣࡌࡵ࡟࡟ࡼࡿ࣮ࣜࢺ࣋ࣝࢺゎᯒ࡟ࡼࡾヲ⣽࡟᳨ウࡋ࡚ࡁࡓࠋ↓ᶵ̿᭷ᶵࢼࣀᵓ㐀య㸦㓄఩㧗ศᏊ㸧ࡣ✀ࠎࡢ㑄⛣㔠ᒓ࢖࢜ࣥࢆ᭷ᶵ㓄఩Ꮚࡀᯫᶫࡋࡓࢿࢵࢺ࣮࣡ࢡᵓ௒ᅇࠊࡇࢀࡲ࡛࡟ぢฟࡉࢀࡓ஧ḟඖࢿࢵࢺ࣮࣡ࢡᵓ㐀≉᭷ࡢᵓ㐀≉ᛶ࡟ࡘ࠸࡚⤂௓ࡍࡿࠋ㐀ࢆ᭷ࡍࡿ≀㉁࡛࠶ࡾࠊḟୡ௦ࡢᶵ⬟ᛶ㘒యᮦᩱ࡜ࡋ࡚ᵓ㐀ࠊ㟁Ꮚⓗࠊ☢Ẽⓗ≉ᛶ࡟ࡘ࠸࡚άⓎ࡟◊✲ࡉࢀ

2. ᐇ㦂࡚࠸ࡿࠋ㑄⛣㔠ᒓ࢖࢜ࣥࡢ㓄఩ᙧែ࡜᭷ᶵ㓄఩Ꮚࢆ㐺

2-1 ヨᩱ

ษ࡟㑅ᢥࡍࡿࡇ࡜࡟ࡼࡿ㦵᱁ࡢᵓ㐀࣭ᶵ⬟タィࢆᚓព(1) ヨᩱㄪ〇࡜ࡋࠊࡇࢀࡲ୍࡛ḟඖ㙐ࠊ஧ḟඖࢩ࣮ࢺࠊ୕ḟඖ㦵᱁[Mn(salen)]Cl 㘒 య ࡜[PPh4]2[MnN(CN)4] ࠊ

࡞࡝ᵝࠎ࡞໬ྜ≀ࡀሗ࿌ࡉࢀ࡚ࡁࡓࠋ≉࡟ࠊ㓄఩㧗ศ

K2Pt(CN)4ࠊK2PtI2(CN)4 㘒య㓄఩Ꮚࢆ 2:1 ࡢ๭ྜ࡛Ꮚࡢ୰࡛ࡶࢩ࢔ࣀᇶ(CŋN)ࢆ௓ࡋࡓつ๎ᵓ㐀ࢆ᭷

H2O ୰࠶ࡿ࠸ࡣࠊH2O+MeOHࠊH2O+MeCN ⁐፹ࡍࡿ໬ྜ≀⩌ࡣࠊ࣋ࣥࢮࣥ⎔ࢆ᭷ࡍࡿ୍⯡ⓗ࡞ᯫᶫ㓄୰࡛ΰྜࠊ᧠ᢾࡍࡿࡇ࡜࡛ࠊ㸳✀㢮ࡢ஧ḟඖ㓄఩㧗ศ఩Ꮚ࡜ẚ㍑ࡋ࡚㔠ᒓ࢖࢜ࣥ㛫ࡢ㊥㞳ࡶ㏆ࡃ↓ᶵ≀࡟Ꮚ㏆࠸⯆࿡῝࠸≉ᛶࢆ♧ࡍࡇ࡜࡛╔┠ࡉࢀ࡚ࡁࡓࠋ౛࠼

MnN(MeOH) (22), MnN(MeCN) (33), Pt (44), PtI2 (55))ࡤࠊࢩ࢔ࣀᇶᯫᶫ୕ḟඖᵓ㐀ࢆ᭷ࡍࡿ௦⾲ⓗ࡞ࣉࣝࢩࡢ༢⤖ᬗ࠾ࡼࡧ⢊ᮎヨᩱࢆྜᡂࡋࡓࠋࡲࡓࠊ5 ࡢྜᡂ࢔ࣥࣈ࣮ࣝ໬ྜ≀ࡣࠊࢩ࢔ࣀᇶࡢᅇ㌿㐠ື࡟⏤᮶ࡍࡿ᫬࡟ຍ࠼ࡿࣚ࢘⣲ࡢ๭ྜࢆㄪ⠇ࡍࡿࡇ࡜࡛ࠊࣚ࢘⣲ྵ㈇ࡢ⇕⭾ᙇᣲືࢆ♧ࡋࠊࡇࢀࡣࠊZrW2O8 ࡞࡝ࡢ㈇ࡢ

᭷⋡ࡢ␗࡞ࡿ஧ḟඖ㓄఩㧗ศᏊ⢊ᮎヨᩱ 6, 7, 8 ࢆྜ⇕⭾ᙇࢆ♧ࡍ↓ᶵ໬ྜ≀࡜㢮ఝࡋࡓ≉ᛶ࡛࠶ࡿࠋ୍᪉ᡂࡋࡓࠋ

࡛ࠊ᭷ᶵ㓄఩Ꮚࢆᵓ⠏せ⣲࡜ࡋ࡚ྵࡴ㓄఩㧗ศᏊࡣ༢2-2 ᐇ㦂᪉ἲ[Mn(salen)]2[M(CN)4](M=MnN(11),⤖ᬗヨᩱࢆᐜ᫆࡟ᚓࡽࢀࡿ࡟ࡶ㛵ࢃࡽࡎࠊ⇕⭾ᙇࡸᅽ

1–5 ࡢ༢⤖ᬗ࡟ᑐࡋ ᗘྍኚ༢⤖ᬗ㹖⥺ᅇᢡ ᐃ⦰࡜࠸ࡗࡓຊᏛ≉ᛶ࡟㛵ࡍࡿ◊✲ࡣࠊᴟࡵ࡚㝈ࡽࢀࡿࢆ⾜࠸ࠊࡑࢀࡒࢀࡢ⇕⭾ᙇᣲື࡜ࡑࢀ࡟క࠺ᵓ㐀ኚ໬ࡢࡀ⌧≧࡛࠶ࡿࠋࡇࢀࡣࠊ㓄఩㧗ศᏊࡢᶵ⬟࡜ࡋ࡚㔠࡟ ࡘ ࠸࡚ ᳨ウ ࡋࡓ ࠋ4 ࡢ ⬺ Ỉヨ ᩱ࡟ ࡘ࠸ ࡚ࡣᒓ࢖࢜ࣥ⏤᮶ࡢ☢Ẽ࣭㟁Ẽ໬Ꮫⓗᛶ㉁ࠊከᏍయ࡜ࡋ࡚

SAGA-LS (BL15) ࡛ࡢ ᗘྍኚ⢊ᮎ㹖⥺ᅇᢡ ᐃࢆࡢ◊✲ࡀ୺ὶ࡛࠶ࡿࡇ࡜ࠊࡲࡓࠊ」㞧࡞ᵓ㐀ࢆ࡜ࡿࡓ⾜ࡗࡓࠋࡲࡓࠊ6–8 ࡟ᑐࡋࠊ100 K ࡛ࡢ⢊ᮎ X ⥺ᅇࡵ࡟ຊᏛ≉ᛶ࡟ᐤ୚ࡍࡿᅉᏊࢆぢฟࡍࡢࡀ㠀ᖖ࡟㞴ᢡ ᐃࢆ⾜ࡗࡓࠋᚓࡽࢀࡓᅇᢡࣃࢱ࣮ࣥࢆ⏝࠸࡚࣮ࣜࡋ࠸࠿ࡽ࡛࠶ࡿࠋࢺ࣋ࣝࢺゎᯒࢆ⾜ࡗࡓࠋᡃࠎࡣࠊ᭷ᶵ㓄఩Ꮚࢆྵࡴࢩ࢔ࣀᯫᶫ஧ḟඖࢩ࣮ࢺᆺ㓄఩㧗ศᏊࡢ♧ࡍ⇕ᛂ⟅ᛶ࡟╔┠ࡋࠊ␗᪉ⓗ࡞⇕⭾3㸬⤖ᯝཬࡧ⪃ᐹᙇᣲື࡟㛵ࡍࡿ◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋ஧ḟඖࢿࢵࢺ࣮࣡ ༢⤖ᬗᵓ㐀ゎᯒ࡟ࡼࡾࠊᚓࡽࢀࡓ஧ḟඖ㓄఩㧗ศᏊࢡᵓ㐀ࡣࠊ㠃ෆ࡜㠃㛫᪉ྥࡢ␗᪉ᛶࢆ᭷ࡋ࡚࠸ࡿࡓࡵ

ࡣ ࠊ [Mn(salen)]+ ࣘ ࢽ ࢵ ࢺ ࡢ ࢔ ࢟ ࢩ ࢔ ࣝ ఩ ࡟ࡑࢀࡒࢀࢆタィྍ⬟࡛࠶ࡾࠊ㓄఩㧗ศᏊ࡜ࡋ࡚୺ὶࡢ

[M(CN)4]2 ࡢࢩ࢔ࣀᇶࡀ㓄఩ࠊᯫᶫࡍࡿࡇ࡜࡛ᵓ⠏୕ḟඖᵓ㐀య࡛ࡣ♧ࡋᚓ࡞࠸≉ᚩⓗ࡞ᵓ㐀≉ᛶࢆⓎࡉࢀࡿࢪࢢࢨࢢࢩ࣮ࢺࡀ✚ᒙࡋࡓᵓ㐀ࢆ᭷ࡋ࡚࠸ࡓ⌧ࡍࡿ฼Ⅼࡀ࠶ࡿࠋᡃࠎࡣࠊ ᗘኚ໬࡟కࡗࡓᵓ㐀ኚ㸦ᅗ㸯㸧ࠋ100 K ࠿ࡽ 400 K ࡲ࡛ࡢᵓ㐀ゎᯒ࡟ࡼࡾ໬ࡢᥥീࡸ஧ḟඖࢩ࣮ࢺࡢ໬Ꮫಟ㣭࡟ࡼࡿᵓ㐀ኚ໬ࡑࢀࡒࢀࡢ⇕⭾ᙇᣲື࡟ࡘ࠸࡚ㄪ࡭ࡓ࡜ࡇࢁࠊ࡟ࡘ࠸࡚ࠊ༢⤖ᬗᵓ㐀ゎᯒ࠶ࡿ࠸ࡣ⢊ᮎ X ⥺ᅇᢡ ᐃ[M(CN)4]2 ࣘࢽࢵࢺࡢᵓ㐀࡟౫Ꮡࡋ࡚ࠊ␗࡞ࡿ␗᪉ⓗ⇕⭾ᙇᣲືࢆ♧ࡋࡓࠋࡑࢀࡒࢀࡢ⇕⭾ᙇಀᩘ࡟ࡘ࠸

ࢆ཯ᫎࡋ࡚ṇ࡜㈇ࡢ┿㏫ࡢ␗᪉ⓗ⇕⭾ᙇᣲືࡀⓎ⌧1 ࡜ 2 ࡣ㠃ෆ᪉ྥࡢ a (b) ㍈ࡢಀ
࡚ ⾲ 1 ࡟♧ࡍࠋ1ࡋ࡚࠸ࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓ㸦ᅗ㸰ྑ㸧ࠋࡍ࡞ࢃࡕࠊ

ᩘࡀ㈇ (NTE) ࡛࠶ࡾࠊ3 ࡜ 5 ࡣṇࡢ⇕⭾ᙇ⋡஧ḟඖࢩ࣮ࢺෆ࡟Ꮡᅾࡍࡿ “㓄఩ᵓ㐀ࡦࡎࡳࡢ⦆࿴”(PTE) ࢆ♧ࡋࡓࠋ୍᪉࡛ࠊ4 ࡣ⇕⭾ᙇ⋡ࡀ㠀ᖖ࡟ᑠࡉࡀ⇕ᛂ⟅ᛶࡢ㉳※࡛࠶ࡾࠊ“ࡦࡎࡳࡢ኱ࡁࡉ” ࡀ⇕⭾ᙇ࠸ࢮࣟ⇕⭾ᙇᣲື (ZTE) ࢆ♧ࡋࡓࠋ㠃እ᪉ྥࡢ c ㍈ᣲືࡢ኱ࡁࡉ࡟ᐤ୚ࡋࠊ“ࡦࡎࡳࡢ᪉ྥ” ࡀ⭾ᙇ࡜཰⦰࡟㛵ࡋ࡚ࡣࠊ3 ࡢࡳ㈇ࡢ್ࢆ♧ࡋࠊ௚ࡢ໬ྜ≀ࡣṇࡢࡢ㐪࠸ࢆ⏕ࡳฟࡋ࡚࠸ࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋࡇࢀ

⇕⭾ᙇᣲື࡛࠶ࡗࡓࠋࡣࠊ㓄఩㧗ศᏊࡢ㘒యࢿࢵࢺ࣮࣡ࢡࡢ⇕ᛂ⟅ᛶࢆศᏊᵓ㐀࡛ࣞ࣋ࣝ᫂ࡽ࠿࡟ࡋࡓึࡵ࡚ࡢ౛࡛࠶ࡾࠊ≀㉁ࡢ
⇕⭾ᙇᣲືࡢ⌮ゎ࡜ไᚚࡢࡓࡵࡢ㔜せ࡞▱ぢ࡛࠶ࡿ࡜⪃࠼࡚࠸ࡿࠋ[1,2]ᅗ㸯㸬15 ࡢ⤖ᬗᵓ㐀ࠋ
⾲㸯. 15 ࡢ⇕⭾ᙇಀᩘ (M = 1u106)
Da,b MK1Dc MK11 (150 K-400 K)

15.9+103

2 (360 K-460 K)

7.75+94.03 (340 K-400 K)

+52.2

28.0

4 (200 K-380 K)

1.49+55.7

ᅗ㸰㸬[Mn(salen)]+ ࣘࢽࢵࢺࡢ“㓄఩ᵓ㐀ࡦࡎࡳ”࡜⇕⭾5 (150 K-370 K)+46.4+38.9

ᙇ࡟ࡼࡿᵓ㐀ኚ໬ࠋࢪࢢࢨࢢࢩ࣮ࢺࡢゅᗘࡢ ᗘ౫Ꮡᛶࡢ᳨ウ࡟ࡼࡾࠊࢮࣟ⇕⭾ᙇ⋡࡛࠶ࡗࡓ 4 ࡣࠊྠᵝࡢศᏊෆ㓄఩ᵓᚓࡽࢀࡓ␗᪉ⓗ⇕⭾ᙇᣲືࡣࠊࢪࢢࢨࢢࢩ࣮ࢺࡀ⭾ᙇ㐀ࡦࡎࡳࡀ࠶ࡿ࡟ࡶ㛵ࢃࡽࡎࠊࡑࡢ⦆࿴⌧㇟ࡀ㉳ࡇࡽ࠶ࡿ࠸ࡣ཰⦰ࡍࡿ࡜࠸࠺ᵓ㐀ኚ໬࡟㉳ᅉࡋ࡚࠸ࡿࡇ

࡞࠸᪉ྥ࡟ࡦࡎࢇ࡛࠾ࡾࠊࡍ࡞ࢃࡕ⇕ᛂ⟅ᛶࡀไ㝈ࡉ࡜ࡀศ࠿ࡗࡓࠋࡇࡇ࡛ࠊ඲࡚ࡢ໬ྜ≀ࡢᵓ㐀ኚ໬࡟ࡘࢀ࡚࠸ࡿࡇ࡜ࡀศ࠿ࡗࡓࠋ4 ࡛ほ ࡉࢀࡓᑠࡉ࡞㈇ࡢ

࠸࡚ヲ⣽࡟᳨ウࡍࡿࡇ࡜࡛ࠊ⇕⭾ᙇ⌧㇟ࡢ㉳※ࡀࠊ㦵⇕⭾ᙇᣲືࡣࠊࣉࣝࢩ࢔ࣥࣈ࣮ࣝ࡞࡝࡛ࡶほ ࡉࢀ࡚᱁ࡢ⠇࡟࠶ࡿ [Mn(salen)]+ ࣘࢽࢵࢺࡢ“㓄఩ᵓ㐀ࡦ࠸ࡿࢩ࢔ࣀᇶࡢ transverse vibration mode ࡟ࡼࡿࡎࡳ”࡛࠶ࡿࡇ࡜ࢆぢฟࡋࡓ㸦ᅗ㸰㸧ࠋ[Mn(salen)]+ ࣘ࡜⪃࠼ࡽࢀࡿࠋ4 ࡣ⤖ᬗỈࢆྵࢇ࡛࠸ࡓࡇ࡜࠿ࡽࠊ⤖ࢽࢵࢺ୰࡟ࡣ㔠ᒓ୰ᚰࡢ㓄఩ཎᏊ࠿ࡽ࡞ࡿ㸶㠃య㸦ᅗᬗỈࡢ⇕⭾ᙇᣲື࡟ᑐࡍࡿᙳ㡪ࢆ᳨ウࡍࡿࡓࡵ࡟ࠊ⬺㸰㉥㸧࡜ salen 㓄఩Ꮚࡢ㡬Ⅼࢆྵࡴ㸶㠃య㸦ᅗ㸰㯮㸧Ỉฎ⌮࡟ࡼࡾᚓࡽࢀࡓ 4_dehydrated ࡢ⢊ᮎヨᩱ࡟ࡀᏑᅾࡋࠊࡑࢀࡽࡀࡦࡎࢇ࡛࠸ࡿࡇ࡜ࡀศ࠿ࡿࠋ⇕࡟ࡘ࠸࡚ࠊ ᗘྍኚ⢊ᮎ㹖⥺ᅇᢡ ᐃ࠿ࡽ⇕⭾ᙇᣲືࡢࡼࡾࠊࡇࡢศᏊෆ㓄఩ᵓ㐀ࡦࡎࡳࢆῶᑡࡉࡏࡿࡼ࠺࡟ẚ㍑ࢆ⾜ࡗࡓࠋࡍࡿ࡜ࠊ4_dehydrated ࡣࠊ4 ࡼࡾࡶ஧✀㢮ࡢ㸶㠃యࡀᅇ㌿ࡍࡿࡇ࡜࡛ࢪࢢࢨࢢࢩ࣮ࢺࡢ

㠃ෆࡢ㈇ࡢ⇕⭾ᙇ⋡ࡀ኱ࡁ࠸ࡇ࡜ࡀศ࠿ࡗࡓ㸦ᅗ㸱㸧ࠋᵓ㐀ኚ໬ࡀ⏕ࡌ࡚࠸ࡓࠋࡲࡓࠊ“ࡦࡎࡳࡢ᪉ྥ”ࡢ㐪࠸ࡍ࡞ࢃࡕࠊ4 ࡟࠾࠸࡚ࡣ஧ḟඖࢩ࣮ࢺࡢ཰⦰ࡀ⤖ᬗỈ࡟ࡼࡗ࡚ጉࡆࡽࢀ࡚࠸ࡿࡇ࡜ࡀศ࠿ࡗࡓࠋ[2]ࢪࢢࢨࢢࢩ࣮ࢺࡢゅᗘ࡟ᙳ㡪ࡍࡿࣚ࢘⣲࡜ salen 㓄఩Ꮚ㛫ࡢ❧య཯Ⓨࡢ͆ᩘ͇ࡀ 0.5 ࡛᭱኱࡜࡞ࡾࠊࡑࢀ௨ୖ࡛ࡣኚࢃࡽ࡞࠸ࡇ࡜ࢆព࿡ࡋ࡚࠸ࡿ㸦ᅗ㸲㸧ࠋ
[4]4. ࡲ࡜ࡵᡃࠎࡣࡇࢀࡲ࡛ࠊࢪࢢࢨࢢࢩ࣮ࢺᵓ㐀ࢆ᭷ࡍࡿ஧ḟඖ㓄఩㧗ศᏊࢆ⏝࠸࡚ࠊ஧ḟඖ໬ྜ≀≉᭷ࡢ㠃ෆ࡜㠃ᅗ㸱㸬(a) 4_dehydrated ࡢ ᗘྍኚ⢊ᮎ㹖⥺ᅇᢡࣃࢱ࣮እࡢ␗᪉ᛶ࡟ᇶ࡙࠸ࡓᵓ㐀≉ᛶ࡟ࡘ࠸࡚᫂ࡽ࠿࡟ࡋ

ࣥࠋ(b) 4 (open circle) ࡜ 4_dehydrated (close circle) ࡟࡚ࡁࡓࠋ஧ḟඖࢩ࣮ࢺࡢ✚ᒙయࡣࠊࡑࡢᵓ㐀≉ᛶࡀ࠾ࡅࡿ᱁Ꮚᐃᩘࡢ ᗘኚ໬ࠋࢩ࣮ࢺࢧ࢖ࢬ࡟ࡶᙳ㡪ࢆཷࡅࡿ࡜⪃࠼ࡽࢀࡿࠋ⌧ᅾࡣࠊࢼࣀ⢏Ꮚ໬࡟ࡼࡾࢩ࣮ࢺࢧ࢖ࢬࢆᑠࡉࡃࡍࡿࡇ࡜࡛⇕⭾ᙇ⋡ࡀ࡝ࡢࡼ࠺࡟ኚ໬ࡍࡿ࠿࡟ࡘ࠸᳨࡚ウࡋ࡚࠸ࡿࠋཧ⪃ᩥ⊩[1] R. Ohtani, A. Grosjean, R. Ishikawa, R.
Yamamoto, M. Nakamura, J. K. Clegg, S. Hayami“Zero in-plane thermal expansion in guest-tunable
2D coordination polymers” Inorg. Chem. 2017, 56,
6225-6233

ᅗ㸲㸬ࣚ࢘⣲ࡢ๭ྜ࡟ࡼࡿࣚ࢘⣲㸫salen 㓄఩Ꮚ㛫ࡢ┦[2] R. Ohtani, R. Yamamoto, T. Aoyama, A.

஫స⏝ࡢᩘ࡟㛵ࡍࡿᶍᘧᅗࠋ

Grosjean, M. Nakamura, J. K. Clegg, S. Hayami“Positive and negative two-dimensional thermal 5 ࡣ஧ḟඖࢩ࣮ࢺෆࡢ඲࡚ࡢⓑ㔠ࢧ࢖ࢺ࡟ࣚ࢘⣲expansions via relaxation of node distortions” Inorg.

ࡀ㓟໬ⓗ௜ຍࡋࡓᵓ㐀ࢆ᭷ࡋ࡚࠸ࡓࠋࡇࢀࡲ࡛࡟ࠊྠ

Chem. 2018, 57, 11588-11596ᵝࡢⓑ㔠ࣘࢽࢵࢺࢆ᭷ࡍࡿ୕ḟඖ㓄఩㧗ศᏊ࡟ẁ㝵

[3] R. Ohtani, K. Yoneda, S. Furukawa, N. Horike,ⓗ࡟ࣚ࢘⣲ࢆ௜ຍࡍࡿࡇ࡜࡛≀ᛶไᚚ࡟ᡂຌࡋࡓሗ

S. Kitagawa, A. B. Gaspar, M. C. Muñoz, J. A. Real,࿌౛ࡀ࠶ࡿࠋ[3] ࡑࡇ࡛ࠊྜᡂ᫬࡟⏝࠸ࡿࣚ࢘⣲ࡢ㔞

M. Ohba “Precise Control and Consecutiveࢆㄪ⠇ࡍࡿࡇ࡜࡛ࠊ஧ḟඖࢩ࣮ࢺෆ࡟ Pt(CN)4 ࣘ

Modulation of Spin Transition Temperature Usingࢽࢵࢺ࡜ PtI2(CN)4 ࣘࢽࢵࢺࢆ␗࡞ࡿ๭ྜ࡛ᣢࡘ㓄Chemical఩㧗ศᏊ 6ࠊ7ࠊ8 ࢆྜᡂࡋᵓ㐀ゎᯒࡍࡿࡇ࡜࡛ࠊࣚPolymers” J. Am. Chem. Soc. 2011, 133, 8600-8605

࢘⣲ྵ᭷⋡ࡀ஧ḟඖࢩ࣮ࢺᵓ㐀࡟ࡶࡓࡽࡍᙳ㡪࡟ࡘ

[4] R. Ohtani, R. Yamamoto, H. Ohtsu, M. Kawano,࠸᳨࡚ウࡋࡓࠋ6–8 ࡟ᑐࡋ 100 K ࡛ᚓࡽࢀࡓ⢊ᮎ㹖

J. Pirillo, Y. Hijikata, M. Sadakiyo, L. F. Lindoy, S.

⥺ᅇᢡࣃࢱ࣮ࣥ࠿ࡽ࣮ࣜࢺ࣋ࣝࢺゎᯒࢆ⾜ࡗࡓ࡜ࡇHayami “Consecutive oxidative additions of iodineࢁࠊࣚ࢘⣲ྵ᭷⋡ࡀ 0.5 ࢆ㜈್࡜ࡋ࡚ࢪࢢࢨࢢࢩ࣮

onࢺࡢᵓ㐀ኚ໬ࡢᵝᏊࡀኚ໬ࡍࡿࡇ࡜ࡀศ࠿ࡗࡓࠋࡍ࡞

Formation of I-Pt-I chains and inhomogeneousࢃࡕࠊ0.5 ௨ୗ࡛ࡣẁ㝵ⓗ࡟ࢪࢢࢨࢢࢩ࣮ࢺࡢゅᗘࡀ

layers” Dalton Trans. 2019, 48, 7198-7202

ᑠࡉࡃ࡞ࡗࡓ୍᪉࡛ࠊ0.5 ௨ୖ࡛ࡣࠊ5 ࡜࡯࡜ࢇ࡝ኚࢃࡽ࡞࠸ࢩ࣮ࢺᵓ㐀ࢆ᭷ࡍࡿࡇ࡜ࡀศ࠿ࡗࡓࠋࡇࢀࡣࠊ

Migration

undulating

2DinPorous

Coordination

coordination

polymers: