EvoluChem™ PhotoChemistry Kit
PhotoRedOx Duo(HCK1006-01-022, 光源・バイアルフォルダー別売り）

従来品（PhotoRedOx Box, HCK1006-01-016）との比較テスト

PhotoRedOx Box

96 % yield, 360 min

反応効率を向上→時間節約に！

95% yield, 45 min

光源 ： blue Kessil 34W LED , バイアルサイズ： 4 ml

EvoluChem™ LED のご紹介
光反応に最適なLEDライト
数種類の波長から選択可能
従来のLEDライトより高効率

EvoluChem™ LED 18W
Light Spectrum
Power Consumption

18W Max

Input Voltage

100-240 VAC

Beam Angle

25°

Wavelength Options

365 nm, 405 nm, 455 nm,475 nm, 525 nm, 6200K
white

LED

Cree XPE, Cree XTE and LG(9X)

EvoluChem vs Kessil
Experimental Details:
In duplicate in a 4-ml vial equipped with a teﬂon septa and-bromoacetophenone (4.95mg, 25 µmol) and potassium benzyltriﬂuoroborate (4.50 mg,DMA containing NiCl2 -dme (1.1 mg, 5 µmol, 0.1 mol %),EvoluChem Royal Blue VS Kessil Royal Blue100%

dtbbpy (1.3 mg, 5 µmol, 0.1 mol %) and Ir(dF-CF3-ppy)2
2,6sparged with nitrogen via submerged needle for 5 minutes

Conve r sion (%)

80%

60%

40%

and vial was placed in EvoluChem photoreactor with blue

20%

Kessil 34W LED or with a EvoluChem Royal Blue LED 18W.

0%
050

100

150200250300350

400

Reaction Time (min)Kessiland 360 minutes.

EvoluChem

P205-18-1

P206-18-1

P201-18-2

P202-18-1

P203-18-1

P204-18-1
6200K

365 nm405 nm450-455 nm

475-480 nm

525-530 nm

LEDLG

LG

CREE XPECREE XPECREE XPECREE XTE

Wavelength

365 nm405 nm450-455 nm

475-480 nm

525-530 nm

Cold White
6200K

PartNumber

HCK1012-01-011

HCK1012-01-010

HCK1012-01-002

HCK1012-01-003

HCK1012-01-004

HCK1012-01-005

HepatoChem, Inc. 100 Cummings Center, Suite 451C, Beverly, MA 01915 Phone: (617) 500-5285, Fax: (617) 274-0827
info@hepatochem.com - www.hepatochem.com＜お問い合わせ＞ 重松貿易株式会社 化学品部
TEL：(06)6231-6146 Mail：info@shigematsu-bio.com
Copyright © 2008-2018 HepatoChem Inc. All Rights reserved.

EvoluChem™ PhotoRedOx Duo
The EvoluChem™ PhotoRedOx Duo is using the same unique design as the PhotoRedOx Box. PhotoRedOx Duo increases
the reaction vials capacity to 16 vials (2, 4 or 8 ml) using 2 of the same vial holders as the PhotoRedOx box. Using the 2blue LED setup allows to increase reaction rate of difficult reaction conditions.

PhotoRedOx Duo

2X Vials

2X Light power
PhotoRedOx Duo 2 Holders

Test Reaction
Experimental Details:

In duplicate in a 4-ml vial equipped with a teflon septa and 2x7mm stir bar, were weighed 4-bromoacetophenone (4.95 mg, 25

PhotoRedOx Box

PhotoRedOx Duoµmol) and potassium benzyltrifluoroborate (4.50 mg, 25 µmol, 196 % yield, 360 min

95% yield, 45 minequiv.). To this vial was added a 1.0 ml solution in DMA containing NiCl2 -dme (1.1 mg, 5 µmol, 0.1 mol %), dtbbpy (1.3 mg, 5µmol, 0.1 mol %) and Ir(dF-CF3-ppy)2(dtbpy) (1.12 mg, 1 µmol,0.02 mol %) followed by addition of 2,6-lutidine (17.5 µl, 150µmol, 6 equiv.) . The solution was sparged with nitrogen via

submerged needle for 5 minutes and vial was placed in EvoluChem photoreactor with blue Kessil 34W LED or reactor withtwo blue kessil 34W. Reaction time course was monitored at 0,5, 15, 45, 120, 240, 360 and 1440 minutes.

HepatoChem, Inc. 100 Cummings Center, Suite 451C, Beverly, MA 01915 Phone: (617) 500-5285, Fax: (617) 274-0827
info@hepatochem.com - www.hepatochem.com＜お問い合わせ＞ 重松貿易株式会社 化学品部
TEL： (06)6231-6146 Mail： info@shigematsu-bio.com

Copyright © 2008-2017 HepatoChem Inc. All Rights reserved.