Manganese Dioxide Primary Lithium Battery 1/4
Document Number: SDS-24-01E-01

Issued date: January 1, 2024

SAFETY DATA SHEET (SDS)
1. Product and Company identification
Product Category: Manganese Dioxide Primary Lithium Battery
Nominal Voltage:3V
Product name
Type
Lithium (g)Type
Lithium (g)CR14250SE
0.29
CR2/3 8LHT
0.57
CR14250SE-R
0.29
CR8･L
0.87
CR14250SEK
0.29
CR8･LHC
0.90
0.31
CR8LHT
0.90
CR1/2 6･L
0.41
CR12600SE
0.52
CR2/3 6･L
CR6･L
0.71
CR17335SE
0.52
CR2/3 6L
0.43
CR17335SE-R
0.52
CR1/2 6LHT
0.31CR17450SE
0.75
CR2/3 6LHT
0.43
CR17450SE-R
0.75
0.57
CR2/3 8･L
Supplier’s Name
: FDK CORPORATION
Supplier’s Address: 1-6-41, Konan, Minato-ku, Tokyo 108-8212 Japan
Telephone +81-3-5715-7420
Emergency Contact: CHEMTREC at (800)424-9300
Note : SDS is not applicable to the product hermetically sealed as dry battery. The battery has no risk to life andhealth under normal use or transportation because ingredients of battery are not leaked out by virtue ofhermetical sealing with metal case.
This SDS notify possible risk of our battery under abnormal use but mainly aim to provide information about
ingredients, notification of handling and transportation regulations as a useful reference.

2. Hazards identification
The important hazards andadverse effects of the chemical
product
Chemical product - specifichazards

No information available
No information available

Chemical contents are sealed in metal can. Therefore, risk of exposure neveroccurs unless battery is mechanically or electrically abused.
Outline of an anticipatedRisk of explosion by fire is anticipated if batteries are disposed of in fire oremergency
heated above 100 degree Celsius. If the batteries are extremal short circuitedor charged, the batteries may generate heat and explosion or fire.
Note) Our battery is not classified in accordance with the GHS classification.
3. Principal Composition/ information on Ingredients
PartMaterial

CAS No.

Contents

Positive electrode

Manganese Dioxide

1313-13-930 ～ 50 wt%

Negative electrode

Lithium metal

7439-93-2

2 ～ 4 wt%

Lithium perchlorate

7791-03-9

0.5 ～ 1.5 wt%

1,2-Dimethoxyethane

110-71-4

3 ～ 4.5 wt%

N/A

5 ～ 15 wt%

Electrolyte

Mixture of organic solvent

FDK CORPORATION

Manganese Dioxide Primary Lithium Battery 2/4
Document Number: SDS-24-01E-01

4. First-aid measures
Inhalation
Skin contact
Eyes contact
Swallowing

If ingredient leaked out from inside of a battery and if inhaled it, move to a place
where fresh air is provided. Refer for medical attention.
If ingredient leaked out from inside of a battery and stuck on skin, wash the contact areas
off immediately with plenty of water and soap. If appropriate procedures are not taken, thismay cause sores on the skin. Refer for medical attention.
If ingredient leaked out from inside of a battery and came into eyes, flush the eyes withplenty of water for at least 15 minutes immediately without rubbing. Take a medicaltreatment. If appropriate procedures are not taken, this may cause an eye irritation.
In case of swallowing of battery, immediately refer for medical attention.

5. Fire-fighting measures
Fire extinguishing agent:
Dry chemical, alcohol-resistant foam, powder, atomized water, carbon dioxide and dry sand are effective.
Extinguishing method:
Escape batteries to safe place prevent from ignition by spreading fire.
Because packaging material of battery is paper, use water extinguisher, CO2 extinguisher or powder
extinguisher as normal extinguisher.
Since vapor, generated from burning batteries may make eyes, nose and throat irritate, be sure to extinguish
the fire on the windward side. Wear the respiratory protection equipment in some cases.
6. Accidental release measures
Chemical contents are sealed in metal can. But if the battery is mechanically or electrically abused, contents
may leak out. In such case, take action as showing below.
Personal precautions: Temporary inhalation of odor and attaching of electrolyte to skin does not cause serious
health hazard. Be sure the ventilation and washing out of electrolyte quickly.
Environmental precautions: Clean up it quickly. Specific environmental precaution is not necessary.
Method and materials for containment and methods and materials for cleaning up:
Contain and collect spillage and place in container for disposal according to local regulations.
7. Handling and storing
Do not short-circuit, disassemble, deform, heat or incinerate.
Do not place battery on metal case, metal plate or antistatic material.
In case of multi cell application, replace all batteries to new at once when replacing used
Handlingbatteries.
Do not mix the different type of batteries, the new and old batteries of the same type, or thedifferent manufacture of the same type batteries.
Do not use batteries for unspecified purposes.

Storage

Be sure to store batteries in well-ventilated, dry and cool conditions.
Keep away from water, rain, snow, frost or dew condensation.
Do not store batteries near source of heat or nozzle of hot air.
Do not store batteries in direct sunshine.
Take care not to get wet packing by dew condensation when packing is removed from cold towarm and humid condition.
Enough number of fire fighting apparatuses should be installed in warehouse.
Keep batteries out of reach of children.

8. Exposure controls and personal protection
There is no need of personal protective equipment on regular handling and storage. In the event, however, alarge amount of electrolyte should be released by mechanical or electrical abuse, use the protections asshown below.
Respiratory protection: Mask (with a filter preferably)
Hand protection: Synthetic rubber gloves
Eye protection: Goggles or glasses
FDK CORPORATION

Manganese Dioxide Primary Lithium Battery 3/4
Document Number: SDS-24-01E-01

9. Physical and chemical properties
State: SolidShape: Cylindrical
10. Stability and reactivity
Stability: Stable on regular handling
Conditions to avoid: External short circuit of battery, deformation by crush, exposure at high temperature ofmore than 100 degree C (may cause heat generation and ignition), direct sunlight, highhumidity
Materials to avoid: Substances that cause short circuit.
11. Toxicological information
Since chemicals are contained in a sealed can, there are no hazards.
12. Ecological information
Persistence and degradability
Mobility in soil

No information available
No information available

13. Disposal considerations
Dispose of batteries in accordance with applicable federal, state and local regulations.
For safety precaution, battery should be insulated in proper manner; covering both terminals by tape,wrapping of battery in insulation bag or packing battery in original package is recommended in order toprevent ignition or explosion due to short-circuit.
14. Transportation Information
Lithium metal cells and batteries are classified as Class 9 Dangerous Goods in the United Nations
Recommendation, and given UN numbers as shown in the below table. In case of transport of lithium metal cells
and batteries, compliance with all the relevant UN regulations in addition to the requirements of United Nations
Recommendation is required.
Our battery (listed on section 1) and its shipping package complies with the requirement of UN Manual of Test
and Criteria, Part III, subsection 38.3 as well as the requirements described below, so it is permitted to transport.
＜Air Transport＞
Our battery is applicable to IATA Dangerous Goods Regulations (IATA-DGR) Packing Instruction 968 section IB
because it corresponds to either case that the cell – lithium content is not more than 1g or the battery – lithiumcontent is not more than 2g, so it is permitted to transport without using the Packing Group II package when it
complies with all requirements of the transport conditions for Section IB.
Our products can be transported by cargo aircraft only since our products are classified into lithium metal
batteries.
＜Maritime Transport＞
Our battery is applicable to the International Maritime Dangerous Goods Code (IMDG-Code) Special provision188 because it corresponds to either case that the cell – lithium content is not more than 1g or the battery –lithium content is not more than 2g, so it is permitted to transport as Exempted Dangerous Goods when it
complies with all requirements of the transport conditions.
Sipping names / Packing requirements
Proper Shipping NameUN ID No.

Lithium metal batteries

3090

Lithium metal batteries packed with equipment

3091

Lithium metal batteries contained in equipment3091

Air transport
Packing Instruction
968
Packing Instruction
969
Packing Instruction
970

Maritime transport
Special Provision
188
Special Provision188Special Provision188

FDK CORPORATION

Manganese Dioxide Primary Lithium Battery 4/4
Document Number: SDS-24-01E-01

Related regulations: Following regulations shall be cited and considered.
UNAir transport
Maritime transport
Land transport(Intra-European)
USAOrganization / Issue documents
UN / Recommendations on the Transport of Dangerous Goods
・Model Regulations ; 22nd revised edition
・Manual of Tests and Criteria: Subsection 38.3; 7th revised edition Amendment 1
IATA（International Air Transport Association）/
IATA Dangerous Goods Regulations ; 65th Edition *1
IMO（International Maritime Organization）/
IMDG Code ; 2022 Edition *2
RID（International Carriage of Dangerous Goods by Rail）, ADR（International Carriage ofDangerous Goods by Road）
USDOT（US Department of Transportation）/ DOT 49 CFR（US law）

Each country, region, or shipping company may have its own regulations, so please check with the shipping
company in advance.
15. Applicable legislation
EU Directive 2006/66/EC
EU Regulation 2023/1542
CA Lithium Perchlorate Regulation
16. Other information
Reference● IATA Dangerous Goods Regulations, latest edition *1
Notes on this sheet*1 Dangerous Goods Regulations – 65th Edition: International Air Transport Association (IATA)*2 IMDG Code – 2022 Edition: International Maritime Organization (IMO)
This sheet refers to normal use of the product in question. FDK Corp. makes no warranty expressed or implied.

FDK CORPORATION