SAFETY DATA SHEETSDS No.5020-0043

Revised date

September 24, 2019 1/4 page

1. PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME
： Inertsil WP300 SIL
NAME OF SUPPLIER： GL Sciences Inc.
ADDRESS： 22-1 Nishishinjuku 6-chome Shinjuku-ku Tokyo 163-1130, JapanCHARGE SECTION： International Sales Section
TELEPHONE No.
： +81-3-5323-6620
FACSIMILE No.
： +81-3-5323-6621
PRODUCT No.
： 5020-03282~5020-04882, 5020-05990~5020-06046, 5020-11532~5020-11782,5020-11832~5020-11882, 5020-15032~5020-15582, 5020-15732~5020-15982,5020-19032~5020-20232, 5020-79091~5020-79095, 5020-86011~5020-86067,
5020-87047, 5020SDS No.
： 5020-0043
Research use only.
2. HAZARDS IDENTIFICATION
Inertsil WP300 SIL is the article using for such as chromatography analysis, research and development. Packing
material will not leak from column under usual using conditions. We show the information about packing materials
below.
GHS CLASSIFICATIONHAZARDS SYMBOL： Serious eye damage/eye irritation： Category 2BSpecific target organ toxicity (single exposure)： Category 3(Respiratory tract irritancy)：

SIGNAL WORD
： Warning
HAZARD STATEMENTS：
H320
Cause eye irritation
H335
May cause respiratory irritation
PRECAUTIONARY STATEMENTS ：[Prevention]
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P264
Wash hands thoroughly after handling.
P271
Use only outdoors or in a well-ventilated area.
[Response]
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing.
P337+P313
If eye irritation persists: Get medical attention.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312
Call a POISON CENTER or doctor if you feel unwell.
[Storage]
P403+P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
[Disposal]
P501
Dispose of contents/container in accordance with all applicable regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTSSUBSTANCE / MIXTURE： Substance
CHEMICAL IDENTITY： Silica gel
SYNONYMS： --CHEMICAL FORMULA： SiO 2CONTENT： 100%CAS RN： 112926-00-8
TSCA INVENTORY： Not ListedEINECS No.
： Not Listed

PRODUCT NAME ： Inertsil WP300 SIL
SDS No.5020-0043

Revised date

September 24, 2019 2/4 page

4. FIRST AID MEASURES
GENERAL ADVICE： Wash off with soap and plenty of water. In the case of respirable dust and/orfumes, use self-contained breathing apparatus and dust impervious protective
suit. Use personal protective equipment.
INHALATION： Move victim to fresh air and gargle. If breathing is difficult, give oxygen.
If irritation persists, consult a physician.
SKIN CONTACT： Remove contaminated clothes and shoes, rinse skin with plenty of water orshower, or wipe off cleansing cream with coating, tender cloth. Use soap tohelp assure removal. If irritation persists, consult a physician.
EYE CONTACT： Remove any contact lenses at once. Flush eyes well with flooding large
amounts of running water for at least 15 minutes. Assure adequate flushing byseparating the eyelids with sterile fingers. If irritation persists, consult aphysician.
INGESTION： Rinse mouth, give plenty of water to vomit. Never give anything by mouth to an
unconscious person. If feel unwell, consult a physician.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED： May cause irritation of mucous membranes, respiratory tract, skin and eyes.

5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
FIRE & EXPLOSION HAZARDS： Carbon dioxide, dry chemical powder, foam, water spray： CO 2 , CO are included in a flue gas. Use cylinder-type air respiratory apparatus
at the fire extinguishing in the room.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS： Fireman should wear normal protective equipment (full bunker gear) andpositive-pressure self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTIONS： Remove ignition sources and ventilate the area. In case of insufficientventilation, wear suitable respiratory equipment. Avoid raising dust and avoid
contact with skin and eyes.
ENVIRONMENTAL PRECAUTIONS： Prevent spills from entering sewers, watercourses or low areas.
Comply with local disposal regulations.
METHODS FOR CLEANING UP： Do not touch spilled material without suitable protection. After material iscompletely picked up, wash the spill site with soap and water and ventilate thearea. Pick all wastes up in a plastic bag for disposal and seal it tightly.
Remove, clean, or dispose contaminated clothing.
7. HANDLING AND STORAGE
HANDLINGSTORAGE
INCOMPATIBLE PRODUCTS： Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeatedexposure. Handle this product with appropriate protective equipment.
： Store away from sunlight in a cool well-ventilated dry place.
Keep container tightly closed.
： Oxidizers, strong acids, bases

8. EXPOSURE CONTROL/PERSONAL PROTECTION
ENGINEERING MEASURES： Use exhaust ventilation to keep airborne concentrations below exposure limits.
Use adequate ventilation.
VENTILATION： Local Exhaust ; Necessary, Mechanical(General) ; Recommended
CONTROL PARAMETERS
ACGIH TLV
： Inhalable particles ; TWA 10mg/m3, Respirable particles ; TWA 3mg/m3(as PNOS)
OSHA PEL： TWA 20mppcf (80mg/m3/%SiO 2 ) (as amorphous silica)
NIOSH REL： TWA 6mg/m3 (as amorphous silica)
PERSONAL PROTECTIONRESPIRATORY PROTECTION ： Safety mask, Half or full face piece respirator, self-contained breathingapparatus, supplied air respirator, etc. Use respirators approved underappropriate government standards and follow all regulations.
HAND PROTECTION： Safety gloves
EYE PROTECTION： Safety glasses(goggles)
SKIN PROTECTION： Protective clothing

PRODUCT NAME ： Inertsil WP300 SIL
SDS No.5020-0043

Revised date

September 24, 2019 3/4 page

9. PHYSICAL AND CHEMICAL PROPERTIESPHYSICAL STATE： Solid (powder)
COLOUR： WhiteODOUR： Odourless
MELTING POINT / FREEZING POINT： No data available
BOILING POINT OR INITIAL BOILING POINT AND BOILING RANGE： No data available
FLAMMABILITY： Non Flammable
LOWER AND UPPER EXPLOSION LIMIT / FLAMMABILITY LIMIT： Not applicable
FLASH POINT： No data available
AUTO-IGNITION TEMPERATURE ： No data available
DECOMPOSITION TEMPERATURE： No data available
pH： No data available
KINEMATIC VISCOSITY： Not applicable
SOLUBILITY： No data available
PARTITION COEFFICIENT
n-octanol/water (log value)： No data available
VAPOUR PRESSURE： No data available
DENSITY AND/OR RELATIVE DENSITY： No data available
RELATIVE VAPOUR DENSITY： Not applicable
PARTICLE CHARACTERISTICS ： Spherical, <10µm10. STABILITY AND REACTIVITY
REACTIVITY： Stable under recommended using and storage conditions.
CHEMICAL STABILITY： Stable under recommended using and storage conditions.
CONDITION TO AVOID： Sunlight, heat, moisture, CO 2 , oxidizers, acids, alkalis
INCOMPATIBLE MATERIALS： Oxidizers, strong acids, bases
HAZARDOUS DECOMPOSITION PRODUCTS： CO, CO 2
11. TOXICOLOGICAL INFORMATIONACUTE TOXICITY -oral： Rat; LD50 >5,000mg/kg (Precipitated silica(Tixosil53)), >5,110mg/kg(Precipitated silica(Sident9)) (SIDS(2006), ECETOC JACC(2006))
ACUTE TOXICITY -dermal： Rabbit; LD50 >2,000mg/kg (Silica gel(Syloid244)), >5,000mg/kg (Silica gel(ZEO49, ZEOSYL113, ZEOSYL200, ZEOFREE153)) (SIDS(2006), ECETOC
JACC(2006))
ACUTE TOXICITY -inhalation： No data available
SKIN CORROSION/IRRITATION ： No irritation in skin irritation tests (OECD TG 404, Precipitated silica(Sident9))
using rabbits (SIDS(2006), ECETOC JACC(2006)).
No irritation in skin irritation tests (24 hour exposure, Precipitated silica(SIPERNAT)) using rabbits (SIDS(2006), ECETOC JACC(2006)).
No irritation in skin irritation tests (24 hour exposure, Silica gel(Syloid244))
using rabbits (SIDS (2006)).
EYE DAMAGE/EYE IRRITATION ： Mild conjunctival redness in eye irritation tests (OECD TG 405, Precipitatedsilica(Sident9)) using rabbits (SIDS(2006), ECETOC JACC(2006)).
Slight or no irritation in eye irritation tests (Precipitated silica) using rabbits(SIDS(2006)).
SENSITIZATION： No data available
GERM CELL MUTAGENICITY： No data available
CARCINOGENICITY： There is no information on carcinogenicity to humans. The evidence ofcarcinogenicity is inadequate in humans and experimental animals. Therefore,
the substance is classified as Group 3 by IARC (IARC 68,1997).
REPRODUCTIVE TOXICITY： There is no information on reproductive toxicity to humans.
SPECIFIC TARGET ORGAN TOXICITY - single exposure ： Irritating to respiratory tract (SIDS(2006), ECETOC JACC(2006))

PRODUCT NAME ： Inertsil WP300 SIL
SDS No.5020-0043

Revised date

September 24, 2019 4/4 page

SPECIFIC TARGET ORGAN TOXICITY - repeated exposure ： No adverse effects were seen in lung function and chest radiography of workers
exposed to dust of this substance for an average of 8.5 years (ACGIH(7th,2001),
ECETOC JACC(2006), SIDS(2006), DFGOT vol.2(1991)).
ASPIRATION HAZARD： No data available
12. ECOLOGICAL INFORMATION
Hazardous to the aquatic environment - Acute hazard –： Crustacea(Daphnia magna); 24-hour EC50>1000 mg/L (SIDS(2006))
Zebrafish(Danio rerio); 96-hour LC50=1000 mg/L (SIDS(2006))
Hazardous to the aquatic environment - Chronic hazard –： No data available
BIODEGRADABILITY： May not occur microbial degradation
BIOACCUMULATIVE POTENTIAL ： No data available
MOBILITY IN SOIL
： No data available
HAZARDOUS TO THE OZONE LAYER： Not listed in Montreal Protocol list.
13. DISPOSAL INFORMATION
Dispose in a hazardous-waste site in accordance with all applicable regulations. Any disposal practice must be incompliance with country, local, state, and federal laws and regulations (contact country, local or state environment
agency for specific rules).
14. TRANSPORT INFORMATION
IATA： Not dangerous goods
ADR/RID： Not dangerous goods
DOT(Department of Transportation)： Not dangerous goods
MARINE POLLUTANT： Not classified
15. REGULATORY INFORMATIONFor classification and labeling of chemicals in accordance with the applicable rules and regulations in the EU or eachcountry, refer to GHS classification of this product (See Section 2).
US REGULATION ：OSHA HCS 2012/29 CFR 1910.1200
EU REGULATION ：CLP Regulation ((EC) No. 1272/2008)
16. OTHER INFORMATIONNOTICE:The information contained in the SDS description is applicable exclusively to the chemical substance identified
herein and for its intended use as an analytical reference standard or reagent and to the unit quantity intended forthat purpose. The information does not relate to, and may not be appropriate for, any application or larger quantityof the substance described. Our products are intended for the use by individuals possessing sufficient technicalskill and qualification on use the material potential hazardous chemical. Accordingly, no representation or warranty,
express or implied, with respect to merchantability and fitness for a particular purpose is made with respect to theinformation contained herein.
Attention:
This product in terms of chemical identity and the unit amount provide is intended for use in chemical analysis andnot for human consumption, nor any other purpose.