2020
UNISOKU
NEWSLETTER

Foggy Aoi-Ike (Blue-Pond) in Biei-cho, Hokkaido where UNISOKU members visited in the 45th anniversary company trip.
The clearer photo is well known as a wallpaper in Mac OS X.

Business Policy 経営方針
UNISOKU continues to contribute to the development of science and technology by providing customers
with scientiﬁc instruments that satisfy their exploring demands.

UNISOKU was founded by Dr. Toshihiko Nagamura, and since then the company’s spirit has been based on his frontier mentality,“Provide unique measurement systems to the society”. We first grew up with time-resolved optical instruments such as Stopped-Flow
spectroscopy system and Flash Photolysis system. In 1986, UNISOKU started productizing STM systems for the first time in Japan,
and afterward, we further developed those STM systems into advanced versions working under extreme experimental environments
including ultra-low temperature, ultra-high vacuum conditions. Today, we expand our sales worldwide, and UNISOKU low-temperature
STM systems become a de facto standard in the academic communities. We continue to support customers to help them use our systems
comfortably and challenge for developing valuable instruments. Our challenge for providing unique instruments to satisfy customers’
inquisitive mind, “desire to observe, know and solve” will never change. We realize such instruments with our knowledge and experienceand hope to contribute to the development of science and technology, eventually leading to a convenient and prosperous society.

ユニソクはお客様の探究心に応える計測を提供し、お客様の成果を通じて、科学技術の発展に貢献しつづけることを目指します。
株式会社ユニソクは、創業者である長村俊彦の「ユニークな測定器を世の中に提供していく」というチャレンジ精神によって誕生しました。創業当時はストップトフロー分光システムや
閃光分解分光システムといった、高速分光システムで事業を拡大しました。
1986 年には当時まだ国内では製造されていなかった走査型トンネル顕微鏡の製品化に成功しました。その後、極低温、超高真空という極限環境の STM を追究することに46th Management Plan Meetingより、現在では世界に販売を展開し、多くの研究者にご愛用いただくようになりました。
ユニソクはユーザーの皆様へのサポートを持続し、皆様に安心して装置をお使いいただけるよう、経営の安定を図りながら、新しい価値の創造に挑戦しつづけ、社員と会社の成長を目指します。
お客様の「観たい」、「知りたい」、「突き止めたい」という探究心に応えるユニークな測定器を提供したいというユニソクのチャレンジ精神は変わることなく、お客様が求める計測を社員の知識と経験で実現し、お客様の成果を通じて科学技術の発展と便利で豊かな社会の実現に貢献することをこれからも志して参ります。

The Code of Conduct 行動指針
Challenge courageously

Even in difficult situations, we try something new with ourstrong will.
Think positively and look from others standpoints
We express our gratitude not criticize. We achieve goals throughmutual cooperation. We think from the standpoints of customers,
partners and colleagues, and provide values for them.
Create values
To meet ever-changing social needs, we aim to create values thatprovide happiness and impressive experience to customers by ourknowledge and skills.
Pursue happinessWe work to share happiness with our customers and colleagues.

COMPANY PROFILE

困難なことでも強い意志を持って果敢に挑戦することを目指します。

物事を前向きに、相手の立場で考える

感謝の気持ちを示し、人を非難せず、互いに協力しながら目標を達成することを目指します。
顧客・取引先・同僚の視点で考え、相手にとって価値あることの提供を目指します。
常に変化する世の中のニーズに応え、知恵と工夫で、幸福と感動を与える価値を創造することを目指します。

幸福の追求

仕事を通じて、顧客や同僚とともに歩み、分かち合える
幸福を見つけることを目指します。

会社概要

商号

株式会社ユニソク

FOUNDATION NOV. 1974

設立

昭和 49 年 11 月

CEOYutaka Miyatake

LOCATION

2-4-3 Kasugano, Hirakata, Osaka, Japan

BUSINESSManufacturing and sales of our own UHV LT SPMs and

EMPLOYEES

50,000,000 JPY

Optical spectroscopy systems, research and development
47

UNISOKU has joined Tokyo Instruments (TII) Group as a subsidiary company in 2010. TII was founded by Shoji Suruga (the former
president of UNISOKU) in 1981 with the mission, “Provide the most advanced scientific instruments to domestic researchers andengineers, and do our best to support them to use the instruments with satisfaction”. Starting from the imported sales of optical
instruments such as lasers and photodetectors, TII has expanded self-developed products business and developed from an importcompany into a R&D type technology trading company that owns advanced techniques. In 2017, TII group has established a holding
company, SPECS-TII GmbH in Switzerland co-founded by SPECS GmbH. In parallel, we have established the local corporations in
the U.S., Russia and China to increase sales and improve our customer support from SPECS, TII and UNISOKU. We also plan toestablish sales offices in other countries in the near future. UNISOKU aims to provide satisfactory products and service to our customers
by strengthening locally based sales and technical support using the global network of SPECS-TII.

東京インスツルメンツグループの一員としてユニソクは2010年に株式会社東京インスツルメンツの子会社として東京インスツルメンツ（TII）グループに加わりました。東京
インスツルメンツは駿河正次（前ユニソク社長）によって「世界最先端の理化学製品をいち早く国内の研究者、開発エンジニアに提供すること、加えて購入製品を満足して使用していただくためのサポート・サービスに全力を尽くす」ことを理念に1981年に創立されました。レーザー、光検出器など分光装置関連の輸入販売に加え、自社開発製品の事業を拡大して輸入商社から高い技術力を持つ研究開発型の技術
商社へと発展しました。
TII グループは、2017 年にドイツ SPECS GmbH 社とホールディングス会社
SPECS-TII GmbHをスイスに設立すると同時に、SPECS, TII, UNISOKUの製品の販売とカスタマー
サポートを強化するため、
米国、ロシア、中国に現地法人を立ち上げました。
今後、これら以外の国にも営業拠点設立を計画しています。
ユニソクは、こうした
SPECS-TII グローバル連携のネットワークを使い、各地域に根差した販売
ならびに技術的サポートを強化し、お客様へのさらなる安心とサービスの提供を目指して参ります。

価値の創造

TRADE NAME UNISOKU CO., LTD.

CAPITAL01

果敢に挑戦

As a Member of Tokyo Instruments Group代表取締役社長
所在地
資本金
事業

社員数

宮武

優

大阪府枚方市春日野 2 丁目 4 番 3 号
5000 万円

走査型プローブ顕微鏡、高速分光装置
製造販売「研究開発分野」にて事業
47 名

SPECS-TII Beijing
SPECS-TII Beijing 主催

User Meeting in China＜ 中国ユーザーミーティング ＞

The meeting was hosted by SPECS-TII Beijing, and users of
UNISOKU and SPECS were invited to Kunming, China.
90 people including their families attended and 10 professors
introduced their research. On the 2nd day, we enjoyed an excursion
to Yunnan Stone Forest. By sharing time together, we could collectdirect comments and the newest information from the users.
We believe that the meeting was also a good opportunity for both
UNISOKU and SPECS users to mingle.
SPECS-TII Beijingが主催し、ユニソクとSPECSの顧客を中国・昆明に招待しました。
招待者のご家族を含む合計90名の参加者にお集まり頂き、およそ10名の先生方に研究内容の紹介をして頂きました。
また2日目には、石林への観光を実施し、参加者の多くに楽しんでもらえ、また移動中や観光地での歓談を通して、ユーザーからの直接的な意見や最新の情報を頂くことができました。
この会議を通じてUNISOKUとSPECS
ユーザーの交流を図ることができました。
02

Events in 2019-2020
1月
JAN

2019年の製品開発ニュース

全代理店集結第一回セールスミーティング開催

President Miyatake gave a talk at Cryogenics and Superconductivity Society of Japan.
宮武社長

低温工学・超電導学会にて講演

UNISOKU has signed a domestic exclusive distributor agreement with SPECS GmbH for
Nanonis Controller sales.
SPECS社のナノニスコントローラの国内総代理店契約を締結

The total number of CoolSpeK sales reached 400 (including the former model).

3月
MAR

UNISOKU achieved 44th Invention Award sponsored by the Japan Society for
Advancement of Inventions.
“An innovative time-resolved spectroscopic technique to observe so far unobservablechemical reaction in ‘gap time region’ ”

8月
AUG

Cryogen-free STM under development achieved the base temperature of 3.5 K (the lowest
temperature among commercial systems) and successfully obtained atomic resolution images.

3月
MAR

5月
MAY

STM image of HOPG

USM1300 Based 400mK-High Magnetic Field-Optical
Interference AFM Developed

sMIM

米国プライムナノ社との共同開発

・Very low temperature TAFM = 0.4 K

UNISOKU entrance garden was renovated.
ユニソク玄関前整備
8月
AUG

・High magnetic field (11 T)

・Cantilever AFM (fiber interferometer)
・Microwave compatible (~ 3 GHz)

・Wide scan range (15 μ m × 15 μ m@T = 4 K)

市村清新技術財団により高感度TDSの開発助成金授与

MHz Ampliﬁer Available Soon in Collaboration
with Prof. Milan Allan Group (Leiden University)
MHzアンプ：ライデン大とのライセンス契約
製品名：RydeenAmp (雷電アンプ)

昆明にてSPECS TIIグループ合同

・High resolution tunnelingspectroscopy measurements
・Atomic-scale shot noise
measurements
K. M. Bastiaans et al.,Rev. Sci. Instrum. 89, 093709 (2018).
Atomic-scale shot noise measurements

SPMユーザーミーティング参加

Topo

UNISOKU opened the official YouTube channel.
ユニソク公式YouTubeチャンネル開設

9月
SEP

12月
DEC

The total number of SPM USM1300 sales reached 100.

1月
JAN

45周年記念北海道社員旅行

10月
OCT

K. M. Bastiaans et al., Nat. Phys. 14, 1183 (2018).

外部資金▶市村清新技術財団 新技術開発助成 FY2019-2020「薄膜材料用超高感度水素検出装置の開発」
東工大細野研との共同開発

UNISOKU STM product was introduced in “Doraemon Science World @ Future Life”.
弊社取扱い製品のSTM装置が、小学館発行「ドラえもん科学ワールド 未来のくらし」
に掲載
2020
1月
JAN

新入社員紹介Three new members have joined UNISOKU in
2019. Each of them is expected to play an activerole in the optics, production and sales department,
respectively.
2019年は3名の新入社員が入社しました。
架け橋と世界一の分光製品をつくって 製造業にいた経験を活かし 中国エリア担当です。
それぞれ分光、製造、営業事務のスペシャリスト いきたいと思います。
職人魂で尽力出来るようなれるよう日々精進しています。
頑張ります！
として即戦力となり、日々仕事に邁進しています。
03

The AFM platform was jointly developed with PrimeNano to commercialize
the UHV ULT-sMIM (Scanning Microwave lmpedance Microscopy).
＜PrimeNano Inc. Web site＞ https://www.primenanoinc.com/

SPM USM1300 販売台数が累計100台を突破

New Face 2019

Noise

このAFMプラットフォームはPrimeNano社とのUHV ULT-sMIM(Scanning Microwave lmpedanceMicroscopy)製品化の為に開発されました。

ロシア代理店としてCoolSpeK初受注(RAS)

10月
OCT

2020

10月
OCT

SPECS TII Russia received the 1st order of CoolSpeK as an exclusive distributor in Russia.

The 45th anniversary company trip to Hokkaido was held.

High resolution dI/dV

Advantages

UNISOKU joined SPECS TII group user meeting in Kunming, China.
中国Superconducting gap of Pb「第18回低温工学・超電導若手合同講演会」にて若手奨励賞 受賞「パルス管冷凍機を用いた低温走査トンネル顕微鏡の開発」

・Ultra-high vacuum condition

開発中の無冷媒STMシステムで3.5 K(業界最低到達温度)、原子分解能STM観察に成功

R&D grant for a highly sensitive thermal desorption spectroscopy (TDS) system was given
by Kiyoshi Ichimura Foundation for New Technology.

UNISOKU Cryogen-Free STM System Coming Soon

無冷媒STM・Base temperature of TSTM = 3.5 K achieved
・Low vibration noise level realizedby our original design

CoolSpeK販売台数が累計400台を突破（旧モデルを含む）

日本発明振興協会 第44回発明大賞「発明功労賞」受賞『見えなかったすき間時間の化学反応が見える高速分光技術』

5月
MAY

1月
JAN

国内販売開始

2月
FEB

4月
APR

Product Development News in 2019

The 1st UNISOKU sales meeting was held, inviting all the distributors around the world.

▶JST研究成果最適展開支援プログラム(A-STEP)企業主導フェーズ
NexTEP-Bタイプ FY2019-2023(予定)「時間・スピン分解走査マルチプローブ顕微鏡」
筑波大重川研との共同開発

Publication Stats in 2019
Total number of publications using UNISOKU systems* = 240 (247 in 2018)
Total impact factors ~ 1720 (~ 1266 in 2018)
Corresponding to 40 Nature papers (~ 30 in 2018)
Impact factor per employee ~ 36 (~ 26 in 2018)
Approaching to the impact factor of Nature (~ 43)
The detailed information about the publication list is available on our website.
*including preprints

Popular SPM Research Fields in 2019

Graphene
Molecules
Monatomic Films excluding TMDs
Transi�on Metal Dichalcogenides(TMDs)
Topological Superconductors (Majorana)
Fe-based Superconductors
Topological Materials (Weyl)

Num. of
Publications

Average
Impact Factor

20

6.19

13

10.97

9

11.82

20

18
11
8

8.44

8.08

12.11

14.07
04

製品・ユーザー・論文の紹介

Introduction of
Products / Users / Publications

Ultra High Vacuum Low Temperature SPM System

USM1200

超高真空低温走査型プローブ顕微鏡システム

USM1300

Ultra High Vacuum Very Low Temperature High Magnetic Field STM System
超高真空極低温強磁場中走査型トンネル顕微鏡システム

Bestselling very low temperature SPM system▶ Base temperature: 350 mK (holding time: 30 h with 14 L 3He)
▶ Magnetic ﬁelds: 11 T, 15 T, 2-2-9 T (standard)▶ 3He refrigerator improved since 2017

・Longer 3He holding time and lower base temperature
・Noise levels during 1 K pot pumping reduced▶ AFM option available

Long term SPM measurements realized with low cost cryogen
Cooling performance greatly improved since 2017
▶ LHe consumption rate: 0.7 L/day▶ Total number of shipments reached 100“Atomic-scale Fragmentation and Collapse of Antiferromagnetic Order in a Doped Mott Insulator”
H. Zhao et al., Nat. Phys. 15, 1267 (2019). 《Cover Article》▶ LHe holding time (10 L): 12 days
▶ LN2 holding time (14 L): 1 week

The antiferromagnetic Mott insulator is generally known to exhibit a phase transition from an insulating to a metallic state by carrier doping
along with spatially inhomogeneous electronic states varying on nanometer length scales. However, the evolution of the antiferromagnetic orderacross the phase transition on the same length scales has remained unknown. Zhao et al. (Zeljkovic group, Boston College) performed spin-polarized
STM to reveal the relation among the antiferromagnetic order, the inhomogeneous electronic state and chemical disorder near the phase transition
in a doped Mott insulator (Sr1-xLa)2IrO4. They found that the long-range antiferromagnetic order melts into a short-range fragmented state thatis uncorrelated with the energy gap magnitude and the chemical disorder at the surface. Their findings provide a significant insight into how
the antiferromagnetic order in a Mott insulator evolves with charge carrier doping and establish spin-polarized STM as a powerful tool for
probing atomic-scale magnetism in complex oxides.

USM1200 Publication List in 2019 (Selected) 論文リスト“Living Annulative π-Extension Polymerization for Graphene Nanoribbon Synthesis”
Y. Yano et al., Nature 571, 387 (2019).

(a)

(b)

(c)

“Long-Range Ordered Structures of Corannulene Governed by Electrostatic Repulsion and Surface-State Mediation”
X. Wen et al., J. Phys. Chem. Lett. 10, 6800 (2019).

(a) STM image of (Sr1-xLax)2IrO4 (x=0.05).
(b) Spin-resolved magnetic contrast map.
(c) Spectral gap map. All images are
obtained over an identical region of
the sample.

“Unveiling Oxygen Adsorption States on One-Dimensional Pt-Induced Nanowires on Ge(001)”
H. C. Sun et al., J. Phys. Chem. C 123, 13263 (2019).
“Dechlorinated Ullmann Coupling Reaction of Aryl Chlorides on Ag(111): A Combined STM and XPS Study”
J. Dai et al., Chem. Phys. Chem. 20, 2367 (2019).
“Reversible Oxidation of Blue Phosphorus Monolayer on Au(111)”
J. L. Zhang et al. Nano Lett. 19, 5340 (2019).

“Stepwise On-Surface Dissymmetric Reaction to Construct Binodal Organometallic Network”
J. Liu et al., Nat. Commun. 10, 2545 (2019).
Realizing dissymmetric reactions, which allows differentiated functionalization of equivalent sites within one molecule, is crucial for synthetic
chemistry and materials science but remains challenging. Liu et al. (Wu Kai group, Peking University) demonstrated the dissymmetric reactionof 1,4-dibromo-2,5-diethynylbenzene (2Br-DEB) on Ag(111) in a stepwise manner and revealed the stepwise conversion using STM combinedwith density functional theory calculations. They found that 2Br-DEB molecules underwent chemical reactions to form 1D alkynyl-silver-alkynyl
chains at 300 K and a 2D binodal organometallic network at 320-450 K. Their detailed investigation sheds light on potential application forcontrolled fabrication of complicated yet ordered nanostructures on a surface.
(b)

(a)

1 nm

1 nm

(c)

Twisted bilayer graphene has recently attracted considerable interest because the electronic correlation can be tuned by the rotational angle between
two stacking graphene sheets. Especially, at the magic angle (θ ~ 1.1˚), the electronic correlation is greatly enhanced and even superconductivity
is discovered by carrier doping. Choi et al. (Nadj-Perge group, California Institute of Technology) performed low temperature STM measurements(T = 1.5 K) to investigate electronic correlations in this system near the magic angle. A pair of flat electronic bands responsible for the strong
correlation are observed to deform when aligned with the Fermi level, indicating greatly enhanced electronic correlations. They also found near
the charge neutral point, an enhanced splitting of the flat bands along with symmetry broken density of state maps in the most symmetric moiré
regions. This feature could be attributed to the formation of a nematic ground state due to strong electronic interactions. The superconducting
state emerging from such symmetry-broken correlated states are expected to be investigated in the near future.
(a)

(b)

(c)

5 nm

(a) STM image of 2Br-DEB molecules on Ag(111) spontaneously assembled at 150 K.
(b) STM image of the 1D alkynyl-silver-alkynyl chains formed at 300 K.
(c) STM image of the 2D binodal organometallic network formed at 330 K.
05“Electronic Correlations in Twisted Bilayer Graphene Near the Magic Angle”
Y. Choi et al., Nat. Phys. 15, 1174 (2019).

(a) Experimental set-up.
(b) STM image of the twisted bilayer graphene showing a moiré pattern (θ = 1.01˚).
(c) Spatially resolved local density of state maps near the charge neutral point showing
a symmetry-broken feature in the symmetric moiré region.
06

Haim Beidenkopf (USM1300 User)

Goutam Sheet (USM1300 User)

The Weizmann Institute, Israel

SpIN Lab, Indian Institute of Science Education andResearch (IISER) Mohali, India

Research Interests

Research Interests• Scanning tunneling microscopy and spectroscopy• Molecular beam synthesis of topologicalnanocrystals and nanowires• Inducing topology in semiconducting nanowires• Electronic and magnetic properties of topologicalstates of matter: Weyl semimetals, topologicalinsulators, topological superconductors andcorrelated materials• Point contact spectroscopy, atomic force microscopy• Scanning tunneling microscopy and spectroscopy• Conventional/ unconventional/ topologicalsuperconductivity, magnetism, multiferroicity andcharge density wave

STM topograph of the cleaved surface of Re- MoTe2 obtained in(a) high-strain region and (d) low-strain region, (e) atomicallyresolved STM- topograph within the same region. On the right,
temperature evolution of the STS data. “Generation of strain-induced
pseudo-magnetic field in a doped type-II Weyl semimetal”,
Kamboj et al., Phys. Rev. B 100, 115105 (2019).

Spectroscopic mapping of a screw dislocation andthe associated helical edge state in bismuth allowed
us to resolve its electronic topological classification
Nayak et al., Science Advances 5, eaax6996 (2019).
(a) Atomic resolution image of the cleaved surface of PdTe2 where two types of defects (indicated by the white and yellow arrows) and quasiparticle interference
around them are visible. (b) Zoomed image of a defect-free area. (c) A differential conductance spectrum measured by STS at 22 K and (d) recorded at 385 mK
showing clear coherence peak and a low-bias conductance dip.

“Conventional superconductivity in the type-II Dirac semimetal PdTe2”, Das et al., Phys. Rev. B 97, 014523 (2018).

Quasiparticle interference of trivial states and topological Fermi arcs states on:
Left: “The non centrosymmetric Weyl semimetal TaAs.”
Batabyal et al., Science Advances 2, e1600709 (2016).
Right: “The magnetic Weyl semimetal Co3Sn2S2.”
Morali et al., Science 365, 1286 (2019).

dI/dV map showing a vortex lattice on the surfaceof the transition metal dichalcogenide 4HbTaS2

USM1300 Publication List in 2019 （Selected）論文リスト“Magnetic Hysteresis of Single-Molecule Magnets Adsorbed on Ferromagnetic Substrate”
Z. K. Qi et al., ACS Nano DOI: 10.1021/acsnano.9b04428“Charge-stripe crystal phase in an insulating cuprate”
H. Zhao et al., Nat. Mater. 18, 103 (2019).

“Strongly Compressed Few-Layered SnSe₂ Films Grown on a SrTiO₃ Substrate: The Coexistence of Charge Ordering and Enhanced Interfacial Superconductivity”
Z. Shao et al., Nano Lett. 19, 5304 (2019).

“Fermi-Arc Diversity on Surface Terminations of the Magnetic Weyl Semimetal Co₃Sn₂S₂”
N. Morali et al., Science 365, 1286 (2019).

“Negative Flat Band Magnetism in a Spin–Orbit-Coupled Correlated Kagome Magnet”
J. X. Yin et al., Nat. Phys. 15, 443 (2019).
“Evidence of anisotropic Majorana bound states in 2M-WS₂”
Y. Yuan et al., Nat. Phys. 15, 1046 (2019).
“Half-Integer level Shift of Vortex Bound States in an Iron-Based Superconductor”
L. Kong et al., Nat. Phys. 15, 1181 (2019).
“Atomic-Scale Fragmentation and Collapse of Antiferromagnetic Order in a Doped Mott Insulator”
H. Zhao et al., Nat. Phys. 15, 1267 (2019).
“Interface Engineering of Au(111) for the Growth of 1T′-MoSe₂”
F. Cheng et al., ACS Nano 13, 2316 (2019).
“Unusual Electronic States and Superconducting Proximity Effect of Bi Films Modulated by a NbSe₂ Substrate”
L. Peng et al., ACS Nano 13, 1885 (2019).
“Steering the Achiral into Chiral with a Self-Assembly Strategy”
H. Song et al., ACS Nano 13, 7202 (2019).
“The Effects of Atomic-Scale Strain Relaxation on the Electronic Properties of Monolayer MoS₂”
D. J. Trainer et al., ACS Nano 13, 8284 (2019).
“Dimensional Crossover and Topological Phase Transition in Dirac Semimetal Na₃Bi Films”
H. Xia et al., ACS Nano 13, 9647 (2019).
07(a) Tunneling spectra (dI/dV vs V plots) with theoretical fits using Dynes equation showing two gaps measured at 1.9 K on surface of polycrystalline Mo8Ga41.
“Multiband superconductivity in Mo8Ga41 driven by a site-selective mechanism”, Sirohi et al., Phys. Rev. B 99, 054503 (2019).

“Tuning Single-Atom Electron Spin Resonance in a Vector Magnetic Field”
P. Willke et al., Nano Lett. 19, 8201 (2019).

“Evidence for d-Wave Superconductivity in Single Layer FeSe/SrTiO₃ Probed by Quasiparticle Scattering Off Step Edges”
Z. Ge et al., Nano Lett. 19, 2497 (2019).
“Directly visualizing the sign change of d-wave superconducting gap in Bi₂Sr₂CaCu₂O₈+δ by phase-referenced quasiparticle interference”
Q. Gu et al., Nat. Commun. 10, 1603 (2019).
“Resolving the Topological Classification of Bismuth with Topological Defects”
A. K. Nayak et al., Sci. Adv. 5, eaax6996 (2019).
“Selective Trapping of Hexagonally Warped Topological Surface States in a Triangular Quantum Corral”
M. Chen et al., Sci. Adv. 5, eaaw3988 (2019).
“Atomic-Scale Interface Engineering of Majorana Edge Modes in a 2D Magnet-Superconductor Hybrid System”
A. Palacio-Morales et al., Sci. Adv. 5, eaav6600 (2019).
“Quantum Vortex Core and Missing Pseudogap in the Multiband BCS-BEC Crossover Superconductor FeSe”
T. Hanaguri et al., Phys. Rev. Lett. 122, 077001 (2019).
“High-Magnetic-Field Tunneling Spectra of ABC-Stacked Trilayer Graphene on Graphite”
L. J. Yin et al., Phys. Rev. Lett. 122, 146802 (2019).
“Quantum Phase Transition of Correlated Iron-Based Superconductivity in LiFe₁−xCoxAs”
J. X. Yin et al., Phys. Rev. Lett. 123, 217004 (2019).
“Vanadyl Phthalocyanines on Graphene/SiC(0001): Toward a Hybrid Architecture for Molecular Spin Qubits”
I. Cimatti et al., Nanoscale Horiz. 4, 1202 (2019).
08Ultra High Vacuum Low Temperature SPM System

USM1400“Resolving the Correlation between Tip-Enhanced Resonance Raman Scattering and Local Electronic
States with 1 nm Resolution” S. Liu et al.,. Nano Lett. 19, 5725 (2019).

超高真空低温走査型プローブ顕微鏡システム

Tip-enhanced Raman spectroscopy, combining the chemical sensitivity of surface-enhanced Raman scattering with the high-spatial
resolution of STM, is an emerging powerful tool for nanoscale science and technology. However, understanding the interaction between a
confined electromagnetic field and local electronic states of the sample surface has remained elusive because of experimental challenges. Liuet al. (Takashi Kumagai group, Fritz-Haber Institute of the Max-Planck Society) performed tip-enhanced resonance Raman scattering(TERRS) and STS measurements for ultrathin ZnO films on Ag(111) which possess modified electronic band structures depending on thelayer thickness. By using Au or Ag tips sharpened by field ion beam (FIB) milling reported by this group before [Nano Lett. 19, 3597
(2019)], they realized the TERRS spatial resolution of ~1 nm at T = 78 K, allowing to discuss the correlation between TERRS signals andthe local DOS with near-atomic resolution. Their results show adirect evidence of the (sub)nanometer-scale interaction between a
confined electromagnetic field and local electronic structures of
ZnO films.

Ideal system for combining SPM with optical spectroscopies
such as tip-enhanced Raman spectroscopy (TERS)▶ Base temperature: 3.5 K▶ Focusing lenses with NA ~ 0.35 with 3D piezo positioners▶ Single molecule resolution in TERS mode
▶ Compatible with SPECS sample holder▶ Lens stage motion at low temperatures improved(a, b) SEM micrographs of an Au tip fabricated by FIB.
(c) STM image of a two-monolayer-thick ZnO film on Ag(111).
(d) STS map at VS = +1.8 V taken at the same field of view as (c).
(e, f) TERRS and dI/dV spectra taken at locations shown as the same colors in (c, d),respectively.
(g) Profiles of the topographic height, STS map and TERRS intensity along theline in (c, d).

Probing Conﬁguration on Diﬀerent Substrates

Nan Jiang

University of Illinois at Chicago, U.S.A.

Cu(100)Research Interests

・Tip-enhanced
Raman spectroscopy (TERS)
・Surface-supported nanostructures
・Photon-induced chemical reactions
・Functionalization of
new 2D materials

Intensity (a.u.)

Phenyl Flat

“Programmable Graphene Nanobubbles with Three-Fold Symmetric Pseudo-Magnetic Fields”
P. Jia et al., Nat. Commun. 10, 3127 (2019).

Phenyl Up

Ag(100)

Phenyl Up
Au(100)

1600

1400

1200

1000

800

Raman Shift (cm-1)

600

The corresponding TERS spectra for trans isomers directly describe the adsorbed
configuration i.e. “Phenyl Up” configurations on Ag(100) and Au(100) while the“Phenyl Flat” configuration appears on Cu(100). Nanoscale 11, 19877 (2019).

Graphene nanobubbles (GNBs) are known to generate large pseudo-magnetic fields by local strain which are unavailable by ordinary laboratory
magnets. However, the size and location of GNBs are generally difficult to control so that their potential applications are limited. Jia et al.
(Xi Wang group, Chinese Academy of Sciences and Lin He group, Beijing Normal Univ.) demonstrated the ability to manipulate the location,
size and shape of GNBs on hydrogen-terminated Ge(110) by tuning the tip voltage. They observed clear peaks in dI/dV spectra on a GNB thatare attributed to Landau levels caused by strain-induced pseudo-magnetic fields. Interestingly, they also found such peak structures are unevenly
observed in the GNB at specific rotational angles, indicating the existence of three-fold symmetric pseudo-magnetic fields ranging from 0 to
125.7 T. The programmable GNBs with enormous pseudo-magnetic fields would represent a unique platform for various low dimensional
phenomena under extremely high magnetic fields.
(a)

(b)

(c)

(d)

Reaction Stereoselectivity via Surface Functionalization(a) STM image of a graphene nanobubble (GNB) on Ge(110).
(b) 2D projection of the GNB shown in (a).

Self-Assembly and Binding Conﬁgurations

On Au(100), the leaving bromine atoms in the Ullmann-like coupling reaction of 3,
6-dibromo-9,10-phenanthrenequinone (DBPQ) were found to remain adsorbed on
the surface. This creates a stereoselective surface resulting in trans dimers comparedto the bare substrate which results in cis dimers and bowl trimers.
Nanoscale 12, 2726 (2020).

Chemically Identifying Regioisomeric Adsorbates on Ag(100)638 cm-¹

Three types of self-assemblies of rubrene on Ag(100)were characterized with STM-TERS to yield vibrational
fingerprints of two possible adsorption configurations.
With 5 Ångström resolution, adjacent configurations
were identified.
J. Phys. Chem. C 124, 2420 (2020).[Cover]09

Intensity (a.u.)trans-H2F20TPPDL

cis-H2F20TPPDLStructure 1

699 cm-¹

Structure 2

633_Ag(100)_trans

1400

1200
1000
Raman Shift(cm-1)

USM1400 Publication List in 2019 （Selected）論文リスト“Tuning Thermal Transport Through Atomically Thin Ti3C2Tz MXene by Current Annealing in Vacuum”
Z. Hemmat et al., Adv. Func. Mater. 29, 1805693 (2019).

“Thinnest Nonvolatile Memory Based on Monolayer h-BN”
X. Wu et al., Adv. Mater. 31, 1806790 (2019).
“Chemical Vapor Deposition Grown Large-Scale Atomically Thin Platinum Diselenide with Semimetal–Semiconductor Transition”
J. Shi et al., ACS Nano 13, 8442 (2019).
“Near-Field Manipulation in a Scanning Tunneling Microscope Junction with Plasmonic Fabry-Pérot Tips”
H. Bockmann et al., Nano. Lett. 19, 3597 (2019).
“Realization of Strained Stanene by Interface Engineering”
Y. Liu et al., J. Phys. Chem. Lett. 10, 1558 (2019).

633_Ag(100)_cis

1600(c) dI/dV spectra taken on the colored markers in (b).
(d) Pseudo-magnetic fields as a function of rotational angles.

800

600

STM ImageTERS Image

The corresponding TERS spectra for trans/cis isomers and TERS imaging confirm that
it is possible to precisely distinguish these two co-existing regioisomers.
Nano Lett. 19, 3267 (2019).

“Anisotropic Growth and Scanning Tunneling Microscopy Identification of Ultrathin Even-Layered PdSe₂ Ribbons”
S. Jiang et al., Small 15, 1902789 (2019).
“Graphene Acoustic Phonon-Mediated Pseudo-Landau Levels Tailoring Probed by Scanning Tunneling Spectroscopy”
C. Chi et al., Small DOI: 10.1002/smll.201905202“Bismuth Mediated Defect Engineering of Epitaxial Graphene on SiC(0001)”
T. Hu et al., Carbon 146, 313 (2019).
“Probing Surface Mediated Configurations of Nonplanar Regioisomeric Adsorbates Using Ultrahigh Vacuum Tip-Enhanced Raman Spectroscopy”
S. Mahapatra et al., Nanoscale 11, 19877 (2019).
“New Delay-Time Modulation Scheme for Optical Pump–Probe Scanning Tunneling Microscopy (OPP-STM) With Minimized Light-Intensity Modulation”
O. Takeuchi et al., Jpn. J. Appl. Phys. 58, SIIA12 (2019).
10Ultra High Vacuum / Low Temperature / High Magnetic Field SPM System

USM1500

超高真空低温強磁場中走査型プローブ顕微鏡システム

The superfluid density governed by the phase coherence of Cooper pairs is a central property for understanding superconductivity. However,spatial variation of the superfluid density in unconventional superconductors has remained largely unknown because of technical challenges.
Cho, Bastiaans, Chatzopoulos et al. (Milan Allan group, Leiden University) used atomic-resolution Josephson STM to image a superfluid in
the iron-based superconductor FeTe0.55Se0.45 and simultaneously measured topographic and superconducting gap structures. They found thatthe superfluid is strongly inhomogeneous and the inhomogeneity is correlated with the coherence of quasiparticle (the height of the coherencepeak) rather than structural disorder, quasiparticle scattering and the energy to break Cooper pairs. This unique experimental technique is
expected to be applied to other superconductors and also temperature-dependent superfluid density and superconducting gap measurements
will further help to reveal the mechanism limiting the superconducting transition temperature in unconventional superconductors.

Compact cryogenic high magnetic ﬁeld SPM system▶ Base temperature: 2.0 K▶ LHe holding time: 4 days/40 L ~ 7 days/70 L▶ Magnetic ﬁelds: 8 T(standard), 14 T, 2-2-9 T(a)Department of Surface Science,
Russian Academy of Sciences, Russia“Coordination-Controlled C–C Coupling Products via ortho-Site C–H Activation”
X. Zhang et al., ACS Nano 13, 1385 (2019).

“Role of Charge Density Wave in Monatomic Assembly in Transition Metal Dichalcogenides”
H. Feng et al., Adv. Func. Mater. 29, 1900367 (2019).

• Advanced 2D systems• Atomic and band structure• Electron transport• Quantum and collective transport phenomena• ARPES, STM/STS“Polar and Phase Domain Walls with Conducting Interfacial States in a Weyl Semimetal MoTe₂”
F. T. Huang et al., Nat. Commun. 10, 4211 (2019).
“Quasiparticle interference evidence of the topological Fermi arc states in chiral fermionic semimetal CoSi”
Q. Yuan et al., Sci. Adv. 5, eaaw9485 (2019).
“Real-Space Imaging of Orbital Selectivity on SrTiO₃(001) Surface”
C. Song et al., ACS Appl. Mater. Interfaces 11, 37279 (2019).

1 ML C60/(Tl, Au)/Si(111)

Sheet Resistance (kΩ. )40

T0 ≈ 1.5 K
x ≈ 1.030“Super Large Sn₁–xSe Single Crystals with Excellent Thermoelectric Performance”
M. Jin et al., ACS Appl. Mater. Interfaces 11, 8051 (2019).

``defective’’ ﬁt``defective’’“Nitrogen-Doped Graphene on Copper: Edge-Guided Doping Process and Doping-Induced Variation of Local Work Function”
J. Neilson et al., J. Phys. Chem. C 123, 8802 (2019).

``perfect’’“A Two-Dimensional Crystal Formed by Pentamers on Au(111)”
C. Yuan et al., Chem. Commun. 55, 5427 (2019).

T0 ≈ 36 K
x ≈ 0.26

20“Nanofabricated Tips for Device-Based Scanning Tunneling Microscopy”
M. Leeuenhoek et al., Nanotechnology 30, 335702 (2019).

10
2.2“Flat AgTe Honeycomb Monolayer with Topologically Nontrivial States”
B. Liu et al., J. Phys. Chem. Lett. 10, 1866 (2019).

2.0
1.8

“Weak Antilocalization at the Atomic-Scale Limit of Metal Film Thickness”
A. V. Matetskiy et al., Nano Lett. 19, 570 (2019).

‒450 meV‒250 meV

0

5

10
15
20
Temperature (K)25“Imaging Doubled Shot Noise in a Josephson Scanning Tunneling Microscope”
K. M. Bastiaans et al., Phys. Rev. B 100, 104506 (2019).

30“Superconductor-Insulator Transition in an Anisotropic Two-Dimensional
Electron Gas Assisted by One-Dimensional Friedel Oscillations:(Tl , Au)/Si(100)-c(2×2)”
N. V. Denisov et al., Phys. Rev. B 100, 155412 (2019).

‒50 meV+150 meV

Γ- Μ

Γ- Κ

“Observation of the Nesting and Defect- Driven 1D Incommensurate Charge Density Waves Phase in the 2D System”
A. V. Matetskiy et al., J. Phys. Condens. Matter. 31, 115402 (2019).

11

(c)

USM1500 Publication List in 2019 （Selected）論文リスト

Research Interests“C60 Capping of Metallic 2D Tl-Au Compound with Preservationof Its Basic Properties at the Buried Interface”
D. A. Olyanich et al., Appl. Surf. Sci. 501, 144253 (2020).

(b)(a) STM image of FeTe0.55Se0.45.
(b) Spatially resolved superfluid density map.
(c) Coherence peak height map.
All images were taken in the same field of view.

Alexander Saranin(Tl, Au)/Si(111)“A Strongly Inhomogeneous Superfluid in an Iron-based Superconductor”
D. Cho, K. M. Bastiaans, D. Chatzopoulos et al., Nature 571, 541 (2019).

“C60 Capping of Metallic 2D Tl-Au Compound with Preservation of Its Basic Properties at The Buried Interface”
D. A. Olyanich et al., Appl. Surf. Sci. 501, 144253 (2020).
“Superconductor-Insulator Transition in an Anisotropic Two-Dimensional Electron Gas Assistedby One-Dimensional Friedel Oscillations: (Tl,Au)/Si(100)−c(2×2)”
N. V. Denisov et al., Phys. Rev. B 100, 155412 (2019).
“Multifarious Interfaces, Band Alignments, and Formation Asymmetry of WSe₂–MoSe₂ Heterojunction Grown by Molecular-Beam Epitaxy”
Y. Dai et al., ACS Appl. Mater. Interfaces 11, 43766 (2019).

+350 meV“A Shallow Acceptor of Phosphorous Doped in MoSe₂ Monolayer”
Y. Xia et al., Adv. Electron. Mater. DOI: 10.1002/aelm.201900830
HIGH
LOW

“Local Superconductivity in Vanadium Iron Arsenide”
S. Sefat et al., Phys. Rev. B 100, 104525 (2019).
“Atomic, Electronic and Transport Properties of In-Au 2D Compound on Si(100)”
D. V. Gruznev et al., J. Phys. Condens. Matter DOI: 10.1088/1361-648X/ab5f28“Tunable Magnetism of a Single-Carbon Vacancy in Graphene”
Y. Zhang et al., Sci. Bull. DOI: 10.1016/j.scib.2019.11.023
12

USM1600

Dilution-Refrigerator Based UHV/Ultra Low Temperature/High Magnetic Field STM System
希釈冷凍方式超高真空超低温強磁場中走査型トンネル顕微鏡システム

Micro-Tensile Testing System

微小応力印加装置

Positioning a sample with
sub-micro meter accuracy andmaterial testing under optical
microscope are possible

Dilution-refrigerator based STM system▶ Base temperature: 40 mK▶ Magnetic ﬁelds: 11 T(standard), 15 T, 2-2-9 T▶ Tension, compression, cyclic fatigue
micro clip操作軸
微小応力印加装置 本体 (例)tests and four terminal contact
resistance measurements can be conducted with this system.
▶ Those measurements can be performed using your own optical microscope and SEM▶ Feel free to ask us about additional optimization such as customized micro-chip and original design▶ Measurements while applying extension force of mN order▶ Operation from ambient to UHV conditions

USM1600 Publication List in 2019 論文リスト“Directional Massless Dirac Fermions in a Layered van der Waals material with
one-Dimensional Long-Range Order”
T. Y. Yang et al., Nat. Mater. DOI: 10.1038/s41563-019-0494-1

Takashi SUMIGAWA"Superconductivity of Topological Surface States and Strong Proximity Effectin Sn1−xPbxTe–Pb Heterostructures"
H. Yang et al., Adv. Mater. 31, 1905582 (2019).

Kyoto University, Japan"Standing Waves Induced by Valley-Mismatched Domains in Ferroelectric SnTe Monolayers"
K. Chang et al., Phys. Rev. Lett. 122, 206402 (2019).

Materials in nanometer or micrometer have unique characteristic mechanical behavior, whichis conspicuously different from the counterpart of bulk. Our group possesses special experimental
technique for nano-/micro-sized materials and investigates the mechanical behavior, strengthand fracture by loading experiments with in situ SEM/TEM observations.

"Realization of metallic state in 1T-TaS2 with persisting long-range order of charge density wave"
X. Y. Zhu et al., Phys. Rev. Lett. 123, 206405 (2019).
"From atomic layer to the bulk: low-temperature atomistic structure, ferroelectric and electronic properties of SnTe films"
T. P. Kaloni et al., Phys. Rev. B 99, 134108 (2019).

Recent Results"The Unusual Suppression of Superconducting Transition Temperature in Double-Doping 2H-NbSe2"
D. Yang et al., Supercond. Sci. Technol. 32, 085008 (2019).

・Fracture mechanics in nanoscale
Specimen・Fatigue of nano-/micro-sized metals
・Mechanical behavior of thin films comprising of nanoelements
・Ferroelectricity of nano-sized materials"Quantized Conductance of Majorana Zero Mode in the Vortex of the Topological Superconductor (Li0.84Fe0.16)OHFeSe"
C. Chen et al., Chin. Phys. Lett. 36, 057403 (2019).

Si edges
Brass wire“Disorder-Induced Multifractal Superconductivity in Monolayer Niobium Dichalcogenides”
K. Zhao et al., Nat. Phys. 15, 904 (2019).
Specimen

The interplay between disorder and superconductivity as represented by disorder-enhanced superconductivity is an intriguing phenomenonin quantum many-body physics but experimental observation has remained elusive. Zhao et al. (Shuai-Hua Ji, Xi Chen, Qi-kun Xue group,
Tsinghua Univ.) reported a well-controlled disorder effect on superconductivity in monolayer NbSe2 (Tc ~ 0.9 K) using the dilution-refrigeratorbased STM (the electron temperature of 228 mK). They introduced disorder in situ by depositing silicon atoms on the surface and also by
substituting Se by isovalent S atoms during the sample growth. They found that with increasing disorder by Si adatoms, the superconducting
gap reaches a maximum (more than three times larger than that for a pristine sample) and subsequently decreases. By the isovalent substitution,
the superconducting gap is similarly enhanced and shows the maximum at x = 0.49 in NbSe2-xSx. At this optimal substitution, Tc is found to beas high as 2.9 K. They claim that these results are attributed to multifractal superconducting states.
(a)

(b)

(c)

Tension–compression loading device
originally developed by our group.

(d)

2 um

(a,b) STM image of NbSe2 monolayer on graphene/SiC before and after silicon deposition, respectively.
(c) dI/dV spectrum near the Fermi level as a function of the Si adatom density.
(d) The superconducting gap as a function of the Si adatom density.
13*T. Sumigawa et al., ACS Nano 11, 6271 (2017).

*T. Sumigawa et al., Acta Materialia 153, 270 (2018).
*T. Sumigawa et al., Mater. Sci. Eng. A 764, 138218 (2019).

14

picoTAS

Picosecond Transient Absorption Spectroscopy System
ピコ秒過渡吸収分光システム

Cryostat for Spectrophotometer USP-203 Series

CoolSpeK UV/CD/IR

分光用クライオスタット

Compact cryostat that requires no vacuum pump

▶ Temperature range: -80 ℃ ~ +100 ℃▶ Total number of shipments since released > 420▶ Newly compatible with J-1500 (JASCO) and IRSprit (SHIMADZU)▶ Appeared in 14 J. Am. Chem. Soc. papers in 2019
▶ Innovative system based on the patented RIPT method▶ New option, ﬂuorescence-lifetime measurement now available▶The world’s ﬁrst-ever spectrophotometer covering transient-absorption andﬂuorescence-lifetime measurements in one instrument▶ Variable excitation and detection wavelengths for the ﬂuorescence▶ Low temperature measurements available by combining with a thin-proﬁle CoolSpeK▶ YouTube channel launched to introduce the RIPT method“Reaction of Oxygen with the Singlet Excited State of [n]Cycloparaphenylenes (n = 9, 12, and 15): A Time-Resolved
Transient Absorption Study Seamlessly Covering Time Ranges from Sub-Nanoseconds to Microseconds
by the Randomly-Interleaved-Pulse-Train Method”
T. Suenobu et al., J. Phys. Chem. A 124, 46 (2020).
After light absorption, many photofunctional organic molecules
transfer from singlet excited state to triplet excited state by intersystemcrossing (ISC) in nanoseconds then return to the ground state in
microseconds. It has been difficult so far to observe this series ofprocesses with a single instrument, therefore, integrated analysis has
almost not been performed. Suenobu (Osaka Univ.), Katoh (Nihon Univ.)and UNISOKU collaboratively found unanticipated enhancement of
ISC by oxygen in cycloparaphenylenes (known as 'Nanohoop') byusing our picoTAS based on the RIPT method and succeeded indetailed analysis. This result has proved that picoTAS provides
important information hidden in unexplored observation areas.

picoTAS Publication List in 2019 (Selected) 論文リスト“Suppressed Triplet Exciton Diffusion Due to Small Orbital Overlap as a Key Design Factor for Ultralong-Lived Room-Temperature
Phosphorescence in Molecular Crystals”
K. Narushima et al., Adv. Mater. 31, 1807268 (2019).
“Carrier-Selective Blocking Layer Synergistically Improves the Plasmonic Enhancement Effect”
T. Kawawaki et al., J. Am. Chem. Soc. 141, 8402 (2019).
“Photocatalytic Oxygenation Reactions with a Cobalt Porphyrin Complex Using Water as an Oxygen Source and Dioxygen as an Oxidant”
Y. H. Hong et al., J. Am. Chem. Soc. 141, 9155 (2019).
“Pyrrole-Based π-System–PtII Complexes: Chiroptical Properties and Excited-State Dynamics with Microsecond Triplet Lifetimes”
G. Hirata et al., Chem. Eur. J. 25, 8797 (2019).
“Size-Dependent Relaxation Processes of Photoexcited [n]Cycloparaphenylenes (n = 5–12): Significant Contribution of Internal Conversion
in Smaller Rings”
M. Fujitsuka et al., J. Phys. Chem. A 123, 4737 (2019).
“Effect of Reabsorption of Fluorescence on Transient Absorption Measurements”
Y. Shibasaki et al., Spectrochimica Acta Part A: Mol and Biom Spect. 220, 117127 (2019).
“Exergonic Intramolecular Singlet Fission of an Adamantane-Linked Tetracene Dyad via Twin Quintet Multiexcitons”
Y. Matsui et al., J. Phys. Chem. C 123, 18813 (2019).
15▶ Strengthening international sales and marketing partnership▶ New version with CE mark to be released soon

Stopped-Flow Rapid Scan Spectrometer

RSP-2000

ストップトフローラピッドスキャン分光測定装置

Latest stopped ﬂow platform▶ Fully USB supported version now available▶ Data memory doubled, transfer speed tripled▶ Near-infrared measurement both for single-channel and multichannel▶ Customized ﬂow control system for lab-based SAX-HPLC reported in Sci. Rep.

"Newly developed Laboratory-based Size exclusion chromatography Small-angle x-ray scattering System (La-SSS)"
R. Inoue et al., Sci. Rep. 9, 12610 (2019).

Nanosecond Transient Absorption Spectroscopy System

TSP-1000/2000

ナノ秒時間分解分光測定装置(レーザーフラッシュフォトリシス装置)▶ Conventional laser ﬂash photolysis▶ Time resolution: 10 ns▶ Single click measurements from UV to NIR▶ Ultra-sensitive TA measurement (ΔOD ~ 10-5) under development

・Ampliﬁer and optics optimized for high-sensitivity measurements
・Adopted a high resolution oscilloscope▶ Option for emission lifetime measurements of singlet oxygen available

TSP-1000/2000 Publication List in 2019 (Selected) 論文リスト“Solid-State, Near-Infrared to Visible Photon Upconversion via Triplet–Triplet Annihilation of a Binary System Fabricated by Solution Casting”
A. Abulikemu et al., ACS Appl. Mater. Inrefaces 11, 20812 (2019).

”Liquid Crystallinity as a Self-Assembly Motif for High-Efficiency, Solution-Processed, Solid-State Singlet Fission Materials”
S. Masoomi-Godarzi et al., Adv. Energy Mater. 9, 1901069 (2019).
“Photochromic Reaction by Red Light via Triplet Fusion Upconversion”
A. Tokunaga et al., J. Am. Chem. Soc. 141, 17744 (2019).
16

14

ひらかた

枚方周辺の歴史・観光や地域の紹介

4 7

Introduction of history, sightseeing area around Hirakata
1st-C

弥生

1 田口山遺跡 Taguchiyama ruins (田口山2-2010-3)弥生時代中期後半に成立した高地性集落。竪穴住居跡や土器、石器が出土している。
The ancient village established in the late Yayoi period.

19

禁野車塚古墳 Kinya-kurumazuka mound tomb (宮之阪5-381-3)
古墳時代前期前半(4世紀前半)に築造されたと考えられる前方後円墳で大阪府内でも最古クラス。
全長120メートル。 One of the oldest imperial tombs in Osaka.
2

3

古墳

～

710

5

794

奈良

6

～

1185

平安
～

1336

1573

室町

樟葉宮跡の社 (継体天皇 樟葉宮跡伝承地)
Kuzuha no miya ruins (楠葉丘2-19-1)
第26代 継体天皇が即位し、5年にわたり宮を営んだとされる。
The 26th emperor Keitai was enthronedat this place in 507.

阿弖流為・母禮の塚 (牧野阪2丁目)
Monument of Aterui and More
征夷大将軍 坂上田村麻呂によって東北地方の平定がなされ、蝦夷の首長 阿弖流為(アテルイ)と副将 母禮(モレ)を伴って帰京した。
The chiefs of Emishi (living in the north east area of Japan)
were executed after loss in the war against Yamato dynasty.

17

5
2

16

津田城 Tsuda castle (津田山手2-11-1)
1490年 津田正信が国見山に築城し、1575年 織田信長によって落城された。
Built by the lord, Masanobu Tsuda in 1490 and destroyed by Nobunaga Oda in 1575.

The Tokyo 2020 Olympic
Torch Relay Route東京2020オリンピック
聖火リレーのコース

片埜神社 Katano shrine (牧野阪2-21-15)
創建は約2000年前 (第11代 垂仁天皇 BC29-70）
豊臣秀頼によって再建、
交野郡一宮・大坂城の鬼門鎮護の社とされる。
Believed to be built ~2000 years ago,and rebuilt by Hideyori Toyotomi in 1602.

三之宮神社 Sannomiya shrine (穂谷2-7-1)
創建は341年 (第16代 仁徳天皇）1600年頃に豊臣秀頼によって再建、交野郡三宮・大坂城の鬼門鎮護の社とされる。
Built in 341 and called Sannomiya since rebuilt
by Hideyori Toyotomi around 1600
together with Katano and Ninomiya shrines toguard Osaka Castle from demons.

11

ゴール

岡東中央公園枚方公園駅

スタート 西口広場

14 APR. 2020

Where is Hirakata?

1868
1912

18

Osaka

There are various theories about the historical backgroundand credibility.

1926
1989

昭和

KUZUHA MALL (楠葉花園町15-1)
駅前ショッピングモール
The big shopping mall opened in 2005 and reopened after renovating in 2014.
20

歴史的経緯や信憑性については諸説ある。

明治19

HIRAKATA
Kansai
Airport16

禁野火薬庫 Kinya gunpowder factory site (禁野本町) 17
国内屈指の軍需施設だったが1939年に大規模な爆発事故が起きた。
The area where the imperial families exclusively enjoyed hunting
in ancient times was used for the gunpowder factory in the late 19th century.
Exploded twice (1909, 1939). The second explosion was disastrous.

ほしだ園地 Hoshida Garden (交野市大字星田5019-1)
大阪府が府政100年を記念して整備。
1997年なみはや国体の競技会場としてクライミングウォールが整備され、同時期に 吊り橋(星のブランコ）が作られた。
人道吊り橋としては国内最大規模。
One of the largest pedestrian suspension bridges in Japan.
Beautiful autumn leaves. The climbing wall is too high to climb.

2020年4月14日

江戸

15※菊人形 Chrysanthemum dolls
東京両国国技館で開催されていた菊人形に着目し、成功を収めた。
Chrysanthemum version of Madame Tussauds.
The exhibition was held to attract people to
Hirakata Park during 1910-2005.

8

1868

18
国土地理院｜地理院地図

枚方T-SITE Hirakata T-SITE (岡東町12-2)
書店を中心とした複合商業施設
The modern shopping complex based on a fancy bookstore.

1989
～

安土
桃山

1

12

20

ひらかたパーク(公園町1-1)
Hirakata Park (commonly called Hira-Par)
京阪電鉄の開業に合わせて作られ、集客策として「ひらかた大菊人形展」を96年(1910～2005)にわたって開催した。現存する遊園地では日本最古。
The oldest amusement park in Japan since 1910
(open together with Keihan Railway).
The annual number of visitors is ~1.2 million.

1603

～

～

1603

15

13

8

11

枚方市駅 Hirakata-shi station (岡東町19-14)
1910年に開業。現在の利用者は1日約10万人。
Built in 1910 and currently run by Keihan Electric Railway Co., Ltd.
The number of people using the station is ~100,000 per day.

17

交野天神社本殿 Katano-ten shrine (楠葉丘2-19-1)
室町時代中期に遡る枚方市内の古建築としては最古のもの。
One of the oldest buildings in Hirakata.

10 二宮神社 Ninomiya shrine (船橋本町1-707)
創建は313～399年(第16代仁徳天皇)の説と738年(第45代聖武天皇)の説がある。
1584年に豊臣秀頼によって再建、交野郡二宮・大坂城の鬼門鎮護の社とされる。
Built in 313-399 or 738 and called Ninomiya since rebuilt by Hideyori Toyotomi in 1584.

1573

3

7

9

樟葉台場跡 Kuzuha fort ruins (中之柴2丁目) 14
江戸幕府により京都防衛のために築造された河川台場。
三箇所の砲座と番所、火薬庫を備える大規模の施設(38,000㎡)
Built along Yodo River by Edo Shogunate at the end of Edo Period todefend Kyoto from the group aiming to overthrow the Shogunate.

6

9

13

～

794

10

牧野車塚古墳 (車塚1-369)
Makino-kurumazuka mound tomb
古墳時代前期中頃(4世紀後半)に築造されたと考えられる前方後円墳。全長107.5メートル。
The ancient tomb built in the late 4th century.

百済寺跡 (中宮西之町4340)
Baekje temple ruin
百済滅亡後、日本に在留した百済王族の子孫
百済王 敬福が建立。
Built in ~750 by descendants of Baekje royal family
who originally lived in the Korean Peninsula.

伝王仁墓 Tomb of Wani (藤阪東町2-2220-2)
4世紀後半頃に百済より渡来し、千字文と論語を伝えたとされる伝承上の人物の墓。
1616年に著された「王仁墳廟来朝記」をもとに、1731年京都の儒者
並川誠所が当地の領主に王仁墓として崇敬するよう進言した
Legend has it that Wani came to Japan from Baekje (Korea) and conveyed
Chinese characters and Confucianism to Japan in the late 4th century.

12～

Mid 3rd ～ 7th Century4

枚方宿(鍵屋) Hirakata Inn (Kagiya) (堤町10-27)
枚方は伏見と大坂の中間に位置する交通の要衝であり、水上交通の中継港として繁栄した。鍵屋は江戸時代の町家建築の構造を残している。
Hirakata prospered as a key junction of trade between Kyoto andOsaka in Edo Period and was the 56th posting station in the 57 stationsof the Tokaido Road. Kagiya was a typical inn.

2019

平成
18

Where to Contact in Your Area 代理店紹介
For customers outside those areas, contact UNISOKU directly.

EUROPE / ISRAEL / NORTH AFRICA
nanoscore GmbH ●Mail：info@unisoku.co.jp

CHINA

SPECS-TII Technology (Beijing) Co., Ltd. ●Maisebachstraße 3, 61479 Glashütten, Germany
TEL +49 (0) 6174-619-950 FAX +49 (0) 6174-619-949
t.berghaus@nanoscore.denanoscore.deRoom 418A, Building 39, 4 Workers Stadium North Rd,
Chaoyang District, Beijing 100027, P.R.China
TEL +86-10-65010355
New Oﬃce
sales@specs-tii.com.cn
The oﬃce has been relocated in Jan. 2020www.specs-tii.com.cn

TAIWANRUSSIASHUMOTEK CORP. ●No. 111, Jiabei 1st St. Zhunan, Miaoli County 35058, Taiwan
TEL +886-37-612810 (Oﬃce),+886-919-706759, +886-918-706759
febchangs@gmail.com, info@shumotek.com
www.shumotek.com

SOUTH KOREA

SPECS-TII RUS ●5, Bolshaya Sadovaya Str., Moscow, 123 001
TEL +7 (495) 920-90-05
info@specs-tii.ru, www.specs-tii.ru

CANADA / USA / MEXICOSPECS-TII Inc. ●20 Cabot Blvd. Suite 300
MA 02048 Mansﬁeld / United Statesusa@specs.com

INA Korea Co., Ltd. ●4F. 115. Mallijae-ro, Mapo-gu,
Seoul 04208. Korea
TEL +82-2-714-5456, FAX +82-2-714-5457
shpark@inakr.com, www.inakr.com

Lambda Ray Co., Ltd. ●55-16, #247 beon-gil, Mabuk-ro, Giheung-gu,
Yongin-si, Gyeonggi-do, 16891, Korea
TEL +82-31-693-5776, FAX +82-31-284-6089
jayjeong@lambdaray.co.kr
www.lambdaray.co.kr● SPM● Optics● BothWorldwide Exchange LLC ●P. O. Box 1559
Princeton, NJ 08542
info@wwe-us.com
www.wwe-us.com

UNISOKU Sawada’s Business Journey to Russia

In Aug, 2019, at Sheremetyevo airport, the President of the distributor in Russia welcomedme with a word, “Here is a place to enjoy a life.” What came into my sight was Cyrillic
letters that looked like left-and-right-reversed alphabets. I tried to read aloud in English
pronunciation but it soon failed because the letters got left and right reversed. (I wondered
if Russian people did not mix up when they spoke English…) After I got out of the nearest
station to the distributor oﬃce, there were some huge swings (shown in the photo) andthose enjoying the swings were grown-ups!? I did a double take. In Russia, it seems thatswings are not only for kids but also for grown-ups. It is still humorous when I rememberthat scene. I felt that there are many places where people can enjoy sunshine and relax
in Moscow and the town itself is designed to enjoy their lives.

ユニソク澤田のロシア紀行

2019年8月、シェレメチェボ空港にて「ここは生活を楽しむところだから」と現地代理店社長が出迎えてくれた。目に入るものはアルファベットを左右ひっくり返したようなキリル文字、英語の発音で読もうとするがすぐに文字がひっくり返り断念。(英語も話せるロシア人は発音が混同しないのだろうか。) 空港から鉄道に乗って代理店オフィス最寄り駅から出てすぐ広場に大きなブランコがあり、乗っているのは子どもではなく立派な大人…!? 思わず二度見してしまう。
ここではブランコは子どもだけの乗り物ではないようだ。大人がブランコを漕ぐ姿が今思い出してみても何とも珍しい光景だった。このように街の至る所に何をするでもなく日光に当たりながら座ってゆっくりできる場所が沢山あり、町全体が暮らしを楽しむようにデザインされていると感じた。

20200323