M Sodeoka

Publication List
Original Papers
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Total Synthesis of (+)- and (-)-Tryptoquivaline G by Biomimetic Double Cyclization. Masako
Nakagawa, Mikio Taniguchi, Mikiko Sodeoka, Manabu Ito, Keiichi Yamaguchi, and Tohru Hino. J.
Am. Chem. Soc., 105, 3709-3710 (1983).
Oxidation of 2,3-Disubstituted Indoles with m-Chloroperbenzoic Acid. Formation of o-Aminophenol
Derivatives and a Dimeric Product. Tohru Hino, Hitoshi Yamaguchi, Kenji Matsuki, Kumiko
Nakano, Mikiko Sodeoka, and Masako Nakagawa. J. Chem. Soc. Perkin Trans. I, 141-146 (1983).
Synthesis of the Imidazo[1,2-a]indole-spirolactone Ring System by Oxidative Double Cyclization. A
Synthetic Approach to Tryptoquivalines. Masako Nakagawa, Mikiko Sodeoka, Keiichi Yamaguchi,
and Tohru Hino. Chem. Pharm. Bull., 32, 1373-1384 (1984).
Total Synthesis of (+)- and (-)-Tryptoquivalin G and L by Biomimetic Double Cyclization. Masako
Nakagawa, Mikiko Taniguchi, Mikiko Sodeoka, Manabu Ito, Keiichi Yamaguchi, and Tohru Hino.
Heterocycles, 21, 406-406 (1984).
Practical Synthesis of (+)-9(O)-methano-D6(9a)-PGI1. The Highly Potent Carbon Analog of
Prostacyclin. Mikiko Sodeoka, and Masakatsu Shibasaki. Chem. Lett., 579-582 (1984).
An Efficient Synthesis of Isocarbacyclin Starting from Furfural. Toshiaki Mase, Mikiko Sodeoka,
and Masakatsu Shibasaki. Tetrahedron Lett., 25, 5087-5090 (1984).
Stereospecific Synthesis of Exo-trisubstituted Olefins. The Highly Efficient Synthesis of
Carbacyclins. Masakatsu Shibasaki, Mikiko Sodeoka, and Yuji Ogawa. J. Org. Chem., 49,
4096-4098 (1984).
New Function of (Arene)tricarbonylchromium(0) Complexes as Hydrogenation Catalysts:
Stereospecific Semihydrogenation of Alkynes and Highly Chemoselective Hydrogenation ofa,b-unsaturated Carbonyl Compounds. Mikiko Sodeoka, and Masakatsu Shibasaki. J. Org. Chem.,
50, 1147-1149 (1985).
Stereospecific Construction of Exo-tetrasubstituted Olefins. The Efficient Synthesis of
Cyano-carbacyclins. Masakatsu Shibasaki, and Mikiko Sodeoka. Tetrahedron Lett., 26, 3491-3494(1985).
Stereospecific Synthesis of Exo-allylic Alcohol. An Efficient Asymmetric Synthesis of (R)-(-)-2acetyl-5,8-dimethoxy-1,2,3,4-tetrahydro-2-naphthol. Mikiko Sodeoka, Takamasa Iimori, andMasakatsu Shibasaki. Tetrahedron Lett., 26, 6497-6500 (1985).
Asymmetric Synthesis of (2R)-2-Hydroxy-2-(2-(Z)-octenyl)-1-cyclopentanone. Genji Iwasaki, Mami
Sano, Mikiko Sodeoka, Kiyoshi Yoshida, and Masakatsu Shibasaki. J. Org. Chem., 53, 4864-4867(1988).
Highly Efficient Synthesis of Carbacyclin Analogue. Stereospecific Synthesis of Aryl-Substituted
Exocyclic Olefin. Mikiko Sodeoka, Shoji Satoh, and Masakatsu Shibasaki. J. Am. Chem. Soc., 110,4823-4824 (1988).
Highly Stereoselective Synthesis of Exocyclic Tetrasubstituted Enol Ethers and Olefins. A Synthesisof Nileprost. Atsuo Takahashi, Yoshie Kirio, Mikiko Sodeoka, Hiroaki Sasai, and Masakatsu
Shibasaki. J. Am. Chem. Soc., 111, 643-647 (1989).
Efficient Synthesis of Isocarbacyclins. Mikiko Sodeoka, Yuji Ogawa, Toshiaki Mase, and Masakatsu
Shibasaki. Chem. Pharm. Bull., 37, 586-598 (1989).
Synthetic Studies of Azadirachtin. Synthesis of the Cyclic Acetal Intermediate in Naturally OccuringForm. Yuji Nishikimi, Takamasa Iimori, Mikiko Sodeoka, and Masakatsu Shibasaki. J. Org. Chem.,
54, 3354-3359 (1989).
Catalytic Asymmetric C-C Bond Formation: Asymmetric Synthesis of cis-Decalin Derivatives byPalladium-Catalyzed Cyclization of Prochiral Alkenyl Iodides. Yoshihiro Sato, Mikiko Sodeoka, andMasakatsu Shibasaki. J. Org. Chem., 54, 4738-4739 (1989).

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A New Method for the Stereocontrolled Synthesis of Silyl Dienol Ethers Using(Naphthalene)chromium Tricarbonyl Catalyzed Isomerization. Mikiko Sodeoka, Hiroyoshi Yamada,and Masakatsu Shibasaki. J. Am. Chem. Soc., 112, 4906-4911 (1990).
On the Role of Silver Salts in Asymmetric Heck-type Reaction. A Greatly Improved Catalytic
Asymmetric Synthesis of cis-Decalin Derivatives. Yoshihiro Sato, Mikiko Sodeoka, and Masakatsu
Shibasaki. Chem. Lett., 1953-1954 (1990).
Stereocontrolled Synthesis of Exocyclic Olefins Using Arene Tricarbonyl Chromium Complex
Catalyzed Hydrogenation: 1. Efficient Synthesis of Carbacyclin and Its Analogs. Mikiko Sodeoka,
Yuji Ogawa, Yoshie Kirio, and Masakatsu Shibasaki. Chem. Pharm. Bull., 309-322 (1991).
Stereocontrolled Synthesis of Exocyclic Olefins Using Arene Tricarbonyl Chromium Complex
Catalyzed Hydrogenation: 2. A Catalytic Asymmetric Synthesis of the Anthracycline Intermediate.
Mikiko Sodeoka, Takamasa Iimori, and Masakatsu Shibasaki. Chem. Pharm. Bull., 323-327 (1991).
Control of Ring Junction Stereochemistry via Radical Cyclization. A New Construction oftrans-Hydrindan System. Shoji Satoh, Mikiko Sodeoka, Hiroaki Sasai, and Masakatsu Shibasaki. J.
Org. Chem., 56, 2278-2280 (1991).
A New Method for the Stereocontrolled Synthesis of Dienamine Derivatives Using(Naphthalene)chromium Tricarbonyl Catalyzed Isomerization. Hiroyoshi Yamada, Mikiko Sodeoka,
and Masakatsu Shibasaki. J. Org. Chem., 56, 4569-4574 (1991).
An Effective System for Epoxide-Initiated Cation-Olefin Cyclization. E. J. Corey and Mikiko
Sodeoka. Tetrahedron Lett., 32, 7005-7008 (1991).

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Synthesis of cis-Decalin Derivative via p-Allylpalladium Intermediate and Its Transformation to
Usefully Functionalized trans-Decalin Derivative. Toshiyasu Takemoto, Yuji Nishikimi, Mikiko
Sodeoka, and Masakatsu Shibasaki. Tetrahedron Lett., 33, 3527-3530 (1992).

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A Catalytic Asymmetric Synthesis of cis-Decalin Derivatives via p-Allylpalladium Intermediates.
Toshiyasu Takemoto, Yuji Nishikimi, Mikiko Sodeoka, and Masakatsu Shibasaki. Tetrahedron Lett.,
33, 3531-3532 (1992).
A Multifunctional Plasmid for Protein Expression by ECPCR: Overproduction of the p50 Subunit of
NF-kB. Mikiko Sodeoka, Christopher J. Larson, Lin Chen, Kenneth P. LeClair, and Gregory L.
Verdine. Bioorg. Med. Chem. Lett., 3, 1089-1094 (1993).

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Limited Proteolysis and Site-Directed Mutagenesis of the NF-kB p50 DNA-Binding Subunit.
Mikiko Sodeoka, Christopher J. Larson, Lin Chen, William S. Lane, and Gregory L. Verdine.
Bioorg. Med. Chem. Lett., 3, 1095-1100 (1993).
Asymmetric Heck Reaction. A Catalytic Asymmetric Synthesis of the Key Intermediate for
Vernolepin. Kazuhiro Kondo, Mikiko Sodeoka, Miwako Mori, and Masakatsu Shibasaki.
Tetrahedron Lett., 34, 4219-4222 (1993).
Catalytic Asymmetric Synthesis of a Functionalized Indolizidine Derivative. A Useful Intermediate
Suitable for the Synthesis of Various Glycosidase Inhibitors. Seiji Nukui, Mikiko Sodeoka, andMasakatsu Shibasaki. Tetrahedron Lett., 34, 4965-4968 (1993).
Catalytic Asymmetric Synthesis of Benzylic Quaternary Carbon Centers. An Efficient Synthesis of(-)-Eptazocine. Toshiyasu Takemoto, Mikiko Sodeoka, Hiroaki Sasai, and Masakatsu Shibasaki. J.
Am. Chem. Soc., 115, 8477-8478 (1993).
Asymmetric Heck Reaction. Catalytic Asymmetric Syntheses of Bicyclic Enones, Dienones and the
Key Intermediate for Vernolepin. Kazuhiro Kondo, Mikiko Sodeoka, Miwako Mori, and Masakatsu
Shibasaki. Synthesis, 920-930 (1993).
Manganese(III)-Based Oxidative Free-Radical Reaction of a-Allyl-b-Keto Ester with Molecular
Oxygen. Takashi Ohshima, Mikiko Sodeoka, and Masakatsu Shibasaki. Tetrahedron Lett., 34,
8509-8512 (1993).
Palladium-Catalyzed Asymmetric Arylation of 4,7-Dihydro-1,3-dioxepin. Catalytic Asymmetric
Synthesis of g-Butyrolactone Derivatives. Yuichi Koga, Mikiko Sodeoka, and Masakatsu Shibasaki.
Tetrahedron Lett., 35, 1227-1231 (1994).
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Asymmetric Heck Reaction of Alkenyl Iodides in the Presence of Silver Salts. Catalytic Asymmetric
Synthesis of Decalin and Functionalized Indolizidine Derivatives. Yoshihiro Sato, Seiji Nukui,
Mikiko Sodeoka, and Masakatsu Shibasaki. Tetrahedron, 50, 371-382 (1994).

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Carbon-Carbon Bond-Forming Reaction Through a h5-Pentadienylchromium Complex. Mikiko
Sodeoka, Hiroyoshi Yamada, Toshiyuki Shimizu, Susumu Watanuki, and Masakatsu Shibasaki. J.
Org. Chem., 59, 712-714 (1994).

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Evidence for a Non-a-helical DNA-binding Motif in the Rel Homology Region. Jia Liu, Mikiko
Sodeoka, William S. Lane, Gregory L. Verdine. Proc. Natl. Acad. Sci. USA, 91, 908-912 (1994).
DNA Binding by an Amino Acid Residure in the C-terminal Half of the Rel Homology Region. Jia
Liu, Qing R. Fan, Mikiko Sodeoka, William S. Lane, Gregory L. Verdine. Chem. & Biol., 1, 47-55(1994).

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Asymmetric Heck-Type Reaction Utilizing Hypervalent Alkenyliodonium Salt. Yuji Kurihara,
Mikiko Sodeoka, and Masakatsu Shibasaki. Chem. Pharm. Bull., 42, 2357-2359 (1994).
Effects of Solvent and Additives in the Asymmetric Heck Reaction of Alkenyl Triflates: Catalytic
Asymmetric Synthesis of Decalin Derivatives and Determination of the Absolute Stereochemistry of(+)-Vernolepin. Kazuhiko Ohrai, Kazuhiro Kondo, Mikiko Sodeoka, and Masakatsu Shibasaki. J.
Am. Chem. Soc., 116, 11737-11748 (1994).
Regio- and Stereoselective Functionalization of the Optically Active Tetrahydroindolizine Derivative.
Catalytic Asymmetric Synthesis of Lentiginosine, 1,2-Diepilentiginosine, and Geraphyrotoxin 209D.
Seiji Nukui, Mikiko Sodeoka, Hiroaki Sasai, and Masakatsu Shibasaki. J. Org. Chem., 60, 398-404(1995).
Structure of the NF-kB p50 Homodimer Bound to DNA. Christoph W. Müller, Félix A. Rey, Mikiko
Sodeoka, Gregory L. Verdine, and Stephen C. Harrison. Nature, 373, 311-317 (1995).
Stereocontrolled Syntheses of Phorbol Analogs and Evaluation of Their Binding Affinity to PKC.
Kazuyuki Sugita, Charles F. Neville, Mikiko Sodeoka, Hiroaki Sasai, and Masakatsu Shibasaki.
Tetrahedron Lett., 36, 1067-1070 (1995).
Catalytic Asymmetric Aldol Reaction via Chiral Pd(II) Enolate in Wet DMF. Mikiko Sodeoka,
Kazuhiko Ohrai, and Masakatsu Shibasaki. J. Org. Chem., 60, 2648-2649 (1995).
Regioselective Olefin Insertion in Asymmetric Heck Reaction. Catalytic Asymmetric Synthesis of a
Versatile Intermediate for Diterpene Syntheses. Kazuhiro Kondo, Mikiko Sodeoka, and Masakatsu
Shibasaki. J. Org. Chem., 60, 4322-4323 (1995).
Catalytic Asymmetric Synthesis of a Versatile Intermediate for Diterpene Syntheses. Regioselective
Olefin Insertion in Asymmetric Heck Reaction. Kazuhiro Kondo, Mikiko Sodeoka, and Masakatsu
Shibasaki. Tetrahedron: Asymmetry 6, 2453-2464 (1995).
Synthesis and Crystal Structure of a New C2-Symmetric Chiral Bis-sulfoxide Ligand and Its
Palladium(II) Complex. Ryosuke Tokunoh, Mikiko Sodeoka, Kei-ichi Aoe, and Masakatsu
Shibasaki. Tetrahedron Lett. 36, 8035-8038 (1995).
Photoaffinity Labeling of PKC with a Phorbol Derivative: Importance of the 13-Acyl Group in
Phorbol Ester-PKC Interaction. Mikiko Sodeoka, Koichiro Uotsu, and Masakatsu Shibasaki.
Tetrahedron Lett. 36, 8795-8798 (1995).
Determination of the C-7,9,12,13,17 and 18 Stereochemistry of Tautomycetin. Synthesis of the
Tautomycetin Degradation Product. Jian-Ping Dai, Mikiko Sodeoka, and Masakatsu Shibasaki.
Tetrahedron Lett., 37, 491-494 (1996).
Novel Phorbol Analogs Which Bind to Protein Kinase C (PKC) without Activation. Kazuyuki Sugita,
Daisuke Sawada, Mikiko Sodeoka, Hiroaki Sasai, and Masakatsu Shibasaki. Chem. Pharm. Bull., 44,463-465 (1996).
Catalytic Asymmetric Intramolecular Cyclopropanation of Enol Silyl Ether. Synthesis of the Phorbol
CD-Ring Skeleton. Ryosuke Tokunoh, Hiroshi Tomiyama, Mikiko Sodeoka, and Masakatsu
Shibasaki. Tetrahedron Lett., 37, 2449-2452 (1996).
Catalytic Asymmetric Synthesis of Halenaquinone and Halenaquinol. Akihiko Kojima, Toshiyasu
Takemoto, Mikiko Sodeoka, and Masakatsu Shibasaki. J. Org. Chem., 61, 4876-4877 (1996).
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Asymmetric Heck Reaction-Carbanion Capture Process. Catalytic Asymmetric Total Synthesis of(-)-D9(12)-Capnellene. Takashi Ohshima, Katsuji Kagechika, Midori Adachi, Mikiko Sodeoka, andMasakatsu Shibasaki. J. Am. Chem. Soc., 118, 7108-7116 (1996).
Asymmetric Synthesis of RK-682 and Its Analogs, and Evaluation of Their Protein Phosphatase
Inhibitory Activities. Mikiko Sodeoka, Rumiko Sampe, Terumi Kagamizono, and Hiroyuki Osada.
Tetrahedron Lett., 37, 8775-8778 (1996).
Stable Diaqua Palladium(II) Complexes of BINAP and Tol-BINAP as Highly Efficient Catalysts for
Asymmetric Aldol Reactions. Mikiko Sodeoka, Ryosuke Tokunoh, Futoshi Miyazaki, Emiko
Hagiwara, and Masakatsu Shibasaki. SYNLETT, 463-466 (1997).
Structure-Activity Relationship of Cantharidin Derivatives to Protein Phosphatases 1, 2A1, and 2B.
Mikiko Sodeoka, Yoshiyasu Baba, Satoko Kobayashi, and Nozomu Hirukawa. Bioorg. Med. Chem.
Lett., 7, 1833-1836 (1997).
Rational Design, Synthesis and Evaluation of a New Type of PKC Inhibitor. Mikiko Sodeoka,
Midori A. Arai, Koji Adachi, Koichiro Uotsu, and Masakatsu Shibasaki. J. Am. Chem. Soc., 120,457-458 (1998).
Enantioselective Addition of Enol Silyl Ethers to Imines Catalyzed by Palladium Complexes: A
Novel Way to Optically Active Acylalanine Derivatives. Emiko Hagiwara, Akio Fujii, and Mikiko
Sodeoka. J. Am. Chem. Soc., 120, 2474-2475 (1998).
Catalytic Asymmetric Synthesis of Halenaquinone and Halenaquinol. Akihiko Kojima, Toshiyasu
Takemoto, Mikiko Sodeoka, and Masakatsu Shibasaki. Synthesis, 581-589 (1998).
Photoaffinity Labeling of PKC Isozymes by Phorbol Ester Derivatives. Koichiro Uotsu, Mikiko
Sodeoka, and Masakatsu Shibasaki. Bioorg. Med. Chem., 6, 1117-1126 (1998).
Polymer-Bound N-hydroxysuccinimide Esters: A Column-Free Fluorescent-Labeling Method. Miho
Katoh and Mikiko Sodeoka. Bioorg. Med. Chem. Lett., 9, 881-884 (1999).
(2E,6R)-8-Hydroxy-2,6-dimethyl-2-octenoic Acid, a Novel Anti-osteoporotic Monoterpene, Isolated
from Cistanche salsa. Koji Yamaguchi, Chikara Shinohara, Sachiko Kojima, Mikiko Sodeoka,
Tomoko Tsuji. Biosci. Biotech. Biochem. 63, 731-735 (1999).
Mechanism of Palladium Complex-Catalyzed Enantioselective Mannich-Type Reaction:
Characterization of A Novel Binuclear Palladium Enolate Complex. Akio Fujii, Emiko Hagiwara,
and Mikiko Sodeoka. J. Am. Chem. Soc., 121, 5450-5458 (1999).
Palladium Diaqua and Hydroxo Complexes with Polymer-supported BINAP Ligands and Their Use
for Catalytic Enantioselective Reactions. Akio Fujii and Mikiko Sodeoka. Tetrahedron Lett., 40,
8011-8014 (1999).
Novel a-Glucosidase Inhibitors with a Tetrachlorophthalimide Skeleton. Sonei Sou, Satoshi Mayumi,
Hiroyasu Takahashi, Ryu Yamasaki, Shizuo Kadoya, Mikiko Sodeoka, and Yuichi Hashimoto.
Bioorg. Med. Chem. Lett., 10, 1081-1084 (2000).
Identification of Protein Disulfide Isomerase as a Phorbol Ester-Binding Protein. Satoshi Mayumi,
Akihiko Azuma, Hisayoshi Kobayashi, Mikiko Sodeoka, Keiichi Yano, Seiji Sugimoto, Yasuyuki
Endo, and Yuichi Hashimoto. Biol. Pharm. Bull., 23, 1111-1113 (2000).
a-Glucosidase Inhibitors with a Tetrachlorophthalimide Skeleton; Structure-Activity RelationshipStudy. Hiroyasu Takahashi, Sonei Sou, Ryu Yamasaki, Mikiko Sodeoka, and Yuichi Hashimoto.
Chem. Pharm. Bull., 48, 1494-1499 (2000).
Anti-Androgenic Activity of Substituted Azo- and Azoxy-Benzene Derivatives. Hiroyasu Takahashi,
Toshiyasu Ishioka, Yoshiko Koiso, Mikiko Sodeoka, and Yuichi Hashimoto. Biol. Pharm. Bull., 23,1387-1390 (2000).
Asymmetric Synthesis of a 3-Acyltetronic Acid Derivative, RK-682, and Formation of Its Calcium
Salt during Silica Gel Column Chromatography. Mikiko Sodeoka, Ruriko Sampe, Sachiko Kojima,
Yoshiyasu Baba, Naoko Morisaki, and Yuichi Hashimoto. Chem. Pharm. Bull., 49, 206-212 (2001).
Synthesis of a Tetronic Acid Library Focused on Inhibitors of Tyrosine and Dual-Specificity Protein
Phosphatases and Its Evaluation Regarding VHR and Cdc25B Inhibition. Mikiko Sodeoka, Ruriko
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Sampe, Sachiko Kojima, Yoshiyasu Baba, Takeo Usui, Kazunori Ueda, and Hiroyuki Osada. J. Med.
Chem., 44, 3216-3222 (2001).
Design and Synthesis of a Dimeric Derivative of RK-682 with Increased Inhibitory Activity against
VHR, a Dual-Specificity ERK Phosphatase: Implications for Molecular Mechanism of the Inhibition.
Takeo Usui, Sachiko Kojima, Shun-ichi Kidokoro, Kazunori Ueda, Hiroyuki Osada, and Mikiko
Sodeoka. Chem. & Biol., 8, 1209-1220 (2001).
Direct Generation of Nucleophilic Chiral Palladium Enolate from 1,3-Dicarbonyl Compounds:
Catalytic Enantioselective Michael Reaction with Enones. Yoshitaka Hamashima, Daido Hotta, andMikiko Sodeoka. J. Am. Chem. Soc., 124, 11240-11241 (2002).
Solution-Phase Parallel Synthesis of Carbamates Using Polymer-bound N-Hydroxysuccinimide.
Hirokazu Sumiyoshi, Takafumi Shimizu, Miho Katoh, Yoshiyasu Baba, and Mikiko Sodeoka. Org.
Lett., 4, 3923-3926 (2002).
An Efficient Enantioselective Fluorination of Various b-Ketoesters Catalyzed by Chiral PalladiumComplexes. Yoshitaka Hamashima, Kenji Yagi, Hisashi Takano, László Tamás, and Mikiko
Sodeoka. J. Am. Chem. Soc., 124, 14530-14531 (2002).
Structure-Based Design of Highly Selective Catalytic Site-Directed Inhibitor of Ser/Thr Protein
Phosphatase 2B (Calcineurin). Yoshiyasu Baba, Nozomu Hirukawa, Naoto Tanohira, and Mikiko
Sodeoka. J. Am. Chem. Soc., 125, 9740-9749 (2003).
Immobilization and Reuse of Pd Complexes in Ionic Liquid: Efficient Catalytic Asymmetric
Fluorination and Michael Reactions with b-Ketoesters. Yoshitaka Hamashima, Hisashi Takano,
Daido Hotta, and Mikiko Sodeoka. Org. Lett. 5, 3225-3228 (2003).
Conversion of Ca2+ Salt of an Organic Compound to Its Li+ Salt to Simplify the Fast Atom
Bombardment Mass Spectrum. Naoko Morisaki, Hisayoshi Kobayashi, Kazuo Nagasawa, Yoshiyasu
Baba, Mikiko Sodeoka, and Yuichi Hashimoto. Chem. Pharm. Bull. 51, 1341-1344 (2003).
Design, Synthesis, and Structure-Activity Relationship of New Isobenzofuranone Ligands of Protein
Kinase C. Yoshiyasu Baba, Yosuke Ogoshi, Go Hirai, Takeshi Yanagisawa, Kumiko Nagamatsu,
Satoshi Mayumi, Yuichi Hashimoto, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 14, 2963-2967(2004).
Evaluation of Series of Isobenzofuranone Dimers as PKCa Ligands: Implication for the Distance
between the Two Ligand Binding Sites. Yoshiyasu Baba, Satoshi Mayumi, Go Hirai, Hidekazu
Kawasaki, Yosuke Ogoshi, Takeshi Yanagisawa, Yuichi Hashimoto, and Mikiko Sodeoka. Bioorg.
Med. Chem. Lett. 14, 2969-2972 (2004).
Amine-salt-controlled, Catalytic Asymmetric Conjugate Addition of Various Amines andAsymmetric Protonation. Yoshitaka Hamashima, Hidenori Somei, Yuta Shimura, Toshihiro Tamura,and Mikiko Sodeoka. Org. Lett. 6, 1861-1864. (2004).
Structure-based Design of a Selective Heparanase Inhibitor as an Antimetastatic Agent. Keisuke
Ishida, Go Hirai, Koji Murakami, Takayuki Teruya, Siro Simizu, Mikiko Sodeoka, and Hiroyuki
Osada. Mol. Cancer Therapeutics, 3, 1069-1077 (2004).

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Catalytic Asymmetric Addition of b-Ketoesters to Various Imines Using Chiral Pd Complexes.
Yoshitaka Hamashima, Naoki Sasamoto, Daido Hotta, Hidenori Somei, Natsuko Umebayashi, andMikiko Sodeoka. Angew. Chem. Int. Ed. 44, 1525-1529 (2005).

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An Efficient Catalytic Enantioselective Fluorination of b-Ketophosphonates Using Chiral PalladiumComplexes. Yoshitaka Hamashima, Toshiaki Suzuki, Yuta Shimura, Tadashi Shimizu, Natsuko
Umebayashi, Toshihiro Tamura, Naoki Sasamoto, and Mikiko Sodeoka. Tetrahedron Lett. 46,
1447-1450 (2005).
Structure-Activity Relationship of N-Methyl-Bisindolylmaleimide Derivatives as Cell Death
Inhibitors. Miho Katoh, Kosuke Dodo, Mikako Fujita, and Mikiko Sodeoka. Bioorg. Med. Chem.
Lett. 15, 3109-3113 (2005).
Inhibition of Hydrogen Peroxide-Induced Necrotic Cell Death with 3-Amino-2-Indolylmaleimide
Derivatives. Kosuke Dodo, Miho Katoh, Tadashi Shimizu, Masahiro Takahashi, and Mikiko
Sodeoka. Bioorg. Med. Chem. Lett. 15, 3114-3118 (2005).

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Asymmetric Total Synthesis of (-)-Spirofungin A and (+)-Spirofungin B. Takeshi Shimizu,
Tomoharu Sato, Katsunori Murakoshi, and Mikiko Sodeoka. Org. Lett. 7, 5573-5576 (2005).
Optically Active Cantharidin Analogues Possessing Selective Inhibitory Activity on Ser/Thr Protein
Phosphatase 2B (Calcineurin): Implications for the Binding Mode. Yoshiyasu Baba, Nozomu
Hirukawa, and Mikiko Sodeoka. Bioorg. Med. Chem. 13, 5164-5170 (2005).
Catalytic Enantioselective Fluorination of Oxindoles. Yoshitaka Hamashima, Toshiaki Suzuki,
Hisashi Takano, Yuta Shimura, and Mikiko Sodeoka. J. Am. Chem. Soc. 127, 10164-10165 (2005).
Catalytic Enantioselective Michael Reaction of 1,3-Dicarbonyl Compounds via Formation of Chiral
Palladium Enolate. Yoshitaka Hamashima, Daido Hotta, Natsuko Umebayashi, Yasunori Tsuchiya,
Takeyuki Suzuki, and Mikiko Sodeoka. Adv. Synth. Cat. 347, 1576-1586 (2005).
Highly enantioselective fluorination reactions of b-ketoesters and b-ketophosphonates catalyzed bychiral palladium complexes. Yoshitaka Hamashima, Toshiaki Suzuki, Hisashi Takano, Yuta Shimura,
Yasunori Tsuchiya, Ken-ichi Moriya, Tomomi Goto, and Mikiko Sodeoka. Tetrahedron, 62,
7168-7179 (2006).
A New Entry to Pd-H Chemistry: Catalytic Asymmetric Conjugate Reduction of Enones with EtOH,
and a Highly Enantioselective Synthesis of Warfarin. Yasunori Tsuchiya, Yoshitaka Hamashima,
and Mikiko Sodeoka. Org. Lett. 8, 4851-4854 (2006).
Pd(II)-Catalyzed Asymmetric Addition of Malonates to Dihydroisoquinolines. Naoki Sasamoto,Christian Dubs, Yoshitaka Hamashima, and Mikiko Sodeoka. J. Am. Chem. Soc. 128, 14010-14011(2006).
Enantioselective Fluorination of tert-Butoxycarbonyl Lactones and Lactams Catalyzed by ChiralPd(II)-Bisphosphine Complexes. Toshiaki Suzuki, Tomomi Goto, Yoshitaka Hamashima, andMikiko Sodeoka. J. Org. Chem. 72, 246-250 (2007).
Catalytic Asymmetric Aldol Reactions of Enolizable Carbon Pronucleophiles with Formaldehyde
and Ethyl Glyoxylate. Isao Fukuchi, Yoshitaka Hamashima, and Mikiko Sodeoka. Adv. Synth. Cat.
349, 509-512 (2007).

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Pd(II)-Catalyzed Asymmetric Fluorination of a-Aryl-a-Cyanophosphonates with the Aid of
2,6-Lutidine. Ken-ichi Moriya, Yoshitaka Hamashima, and Mikiko Sodeoka. SYNLETT 1139-1142(2007).

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Importance of interaction between C1 domain and lipids in protein kinase Ca activation:
Hydrophobic side chain direction in isobenzofuranone ligands controls enzyme activation level. Go
Hirai, Tadashi Shimizu, Toru Watanabe, Yosuke Ogoshi, Megumi Ohkubo and Mikiko Sodeoka.
ChemMedChem 2, 1006-1009 (2007).

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Asymmetric Fluorination of a-Aryl Acetic Acid Derivatives with the Novel Catalytic System
Consisting of NiCl2-Binap/R3SiOTf/2,6-Lutidine. Toshiaki Suzuki, Yoshitaka Hamashima, andMikiko Sodeoka. Angew. Chem. Int. Ed. 46, 5435-5439 (2007).
A Novel Bisindolylmaleimide Derivative Enhances Functional Recovery of Heart After Long-Term
Hypothermic Heart Preservation. Rajesh Gopalrao Katare, Zou Zhitian, Mikiko Sodeoka, and Shiro
Sasaguri. Transplantation, 83, 1588-1594 (2007).
Stereo-controlled and Convergent Entry to CF2-Sialosides: Synthesis of CF2-linked GangliosideGM4. Go Hirai, Toru Watanabe, Kazunori Yamaguchi, Taeko Miyagi, and Mikiko Sodeoka. J. Am.
Chem. Soc. 129, 15420-15421 (2007).
A Novel Bisindolylmaleimide Derivative Inhibit Mitochondrial Permeability Transition Pore andProtect the Heartfrom Reperfusion Injury. Rajesh Gopalrao Katare, Zou Zhitian, Mikiko Sodeoka,
and Shiro Sasaguri. Canadian Journal of Physiology and Pharmacology, 85, 979-985 (2007).

97)
98)
99)

100) Convenient Method for the Preparation of Carbamates, Carbonates, and Thiocarbonates. Mamoru
Shimizu and Mikiko Sodeoka. Organic Letters, 9, 5231-5234 (2007).
101) Catalytic Asymmetric Conjugate Reduction with Ethanol: A More Reactive System
Pd(II)-iPr-DUPHOS Complex with Molecular Sieves 4A. Daiki Monguchi, Christine Beemelmanns,

6

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Daisuke Hashizume, Yoshitaka Hamashima, and Mikiko Sodeoka. J. Organomet. Chem. 693,
867-873 (2008).
102) Catalytic Enantioselective Aldol-type Reaction of b-Ketoesters with Acetals. Natsuko Umebayashi,
Yoshitaka Hamashima, Daisuke Hashizume, and Mikiko Sodeoka. Angew. Chem. Int. Ed. 47,
4196-4199 (2008).
103) Mechanistic Studies on the Catalytic Asymmetric Mannich-type Reaction with Dihydroisoquinolines
and Development of Oxidative Mannich-type Reaction Starting from Tetrahydroisoquinolines.
Christian Dubs, Yoshitaka Hamashima, Naoki Sasamoto, Thomas M. Seidel, Shoko Suzuki, Daisuke
Hashizume, and Mikiko Sodeoka. J. Org. Chem. 73, 5859-5871 (2008).
104) Development of Column-free Alkoxycarbonyl, Aryloxycarbonyl, and Acyl Transfer Reagents.
Mamoru Shimizu and Mikiko Sodeoka. Heterocycles, 76, 1301-1312 (2008).
105) PdII-catalyzed Asymmetric Addition Reactions of 1,3-Dicarbonyl Compounds: Mannich-type
Reactions with N-Boc Imines and Three-component Aminomethylation. Yoshitaka Hamashima,
Naoki Sasamoto, Natsuko Umebayashi, and Mikiko Sodeoka. Chem. Asian J. 3, 1443-1455 (2008).
106) Synthesis and Biological Activities of Reveromycin A and Spirofungin A Derivatives. Takeshi
Shimizu, Takeo Usui, Makoto Fujikura, Makoto Kawatani, Tomoharu Satoh, Kiyotaka Machida,
Naoki Kanoh, Je-Tae Woo, Hiroyuki Osada, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 18,
3756-3760 (2008).
107) A New Route for the Preparation of the Succinates. Takeshi Shimizu, Katsunori Murakoshi, Koji
Yasui, Mikiko Sodeoka. Synthesis, 3209-3218 (2008).
108) Synthesis of CH2-linked a(2,3)sialylgalactose analogue: On the stereoselectivity of the key
Ireland-Claisen rearrangement. Toru Watanabe, Go Hirai, Marie Kato, Daisuke Hashizume, Taeko
Miyagi, and Mikiko Sodeoka. Organic Letters, 10, 4167-4170 (2008).
109) Limited Inhibitory Effects of Oseltamivir and Zanamivir on Human Sialidases. Keiko Hata, Koichi
Koseki, Kazunori Yamaguchi, Setsuko Moriya, Yasuo Suzuki, Sangchai Yingsakmongkon, Go Hirai,
Mikiko Sodeoka, Mark von Itzstein, and Taeko Miyagi. Antimicrobial Agents and Chemotherapy 52,
3484-3491 (2008).
110) Ginkgolic acid inhibits protein SUMOylation by blocking formation of the E1-SUMO intermediate.
Isao Fukuda, Akihiro Ito, Go Hirai, Shinichi Nishimura, Hisashi Kawasaki, Hisato Saitoh, Ken-ichi
Kimura, Mikiko Sodeoka, and Minoru Yoshida. Chemistry & Biology, 16, 133-140 (2009).
111) Asymmetric synthesis of isobenzofuranone derivatives and their unique character as protein kinase
Ca (PKCa) activators. Go Hirai, Yosuke Ogoshi, Megumi Ohkubo, Yuki Tamura, Toru Watanabe,
Tadashi Shimizu, and Mikiko Sodeoka. Tetrahedron Letters, 50, 3609-3612 (2009).
112) Enantioselective Protonation in Aza-Michael Reaction Using the Combination of Chiral
Pd-µ-hydroxo Complex with Amine Salts. Yoshitaka Hamashima, Toshihiro Tamura, Shoko Suzuki,
and Mikiko Sodeoka. SYNLETT, 1631-1634 (2009).
113) Synthesis of DFGH-ring System of Type B Physalins: A Characteristic Highly
Oxygen-functionalized and Cage-shaped Molecule. Megumi Ohkubo, Go Hirai, and Mikiko Sodeoka.
Angew. Chem. Int. Ed. 48, 3862-3866 (2009).
114) Diastereo- and Enantioselective Conjugate Addition of a-Ketoesters to Nitroalkenes Catalyzed by
Chiral Ni(OAc)2 Complex under Mild Conditions. Ayako Nakamura, Sylvain Lectard, Daisuke
Hashizume, Yoshitaka Hamashima, and Mikiko Sodeoka. J. Am. Chem. Soc. 132, 4036-4037 (2010).
115) Total Synthesis of (+)-Chaetocin and its Analogs: Their Histone Methyltransferase G9a Inhibitory
Activity. Eriko Iwasa, Yoshitaka Hamashima, Shinya Fujishiro, Eisuke Higuchi, Akihiro Ito, Minoru
Yoshida, and Mikiko Sodeoka. J. Am. Chem. Soc. 132, 4078-4079 (2010).
116) Asymmetric conjugate addition of a-keto esters to nitroolefins catalyzed by chiral CuII hydroxo
complexes. Ayako Nakamura, Sylvain Lectard, Ryo Shimizu, Yoshitaka Hamashima, and Mikiko
Sodeoka. Tetrahedron Asymmetry, 21, 1682-1687 (2010).

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117) Unnatural enantiomer of chaetocin shows strong apoptosis-inducing activity throughcaspase-8/caspase-3 activation. Yuou Teng, Katsuya Iuchi, Eriko Iwasa, Shinya Fujishiro, Yoshitaka
Hamashima, Kosuke Dodo, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 20, 5085-5088 (2010).
118) Direct C2-trifluoromethylation of indole derivatives catalyzed by copper acetate. Ryo Shimizu,
Hiromichi Egami, Tatsuya Nagi, Jungha Chae, Yoshitaka Hamashima, and Mikiko Sodeoka.
Tetrahedron Lett. 51, 5947-5949 (2010).
119) Scope and Mechanism of Tandem Aza-Michael Reaction–Enantioselective Protonation Using a
Pd-µ-hydroxo Complex under Mild Conditions Buffered with Amine Salts. Yoshitaka Hamashima,
Shoko Suzuki, Toshihiro Tamura, Hidenori Somei, and Mikiko Sodeoka. Chem. Asian J. 6, 658-668(2011).
120) Imaging of EdU, an Alkyne-tagged Cell Proliferation Probe, by Raman Microscopy. Hiroyuki
Yamakoshi, Kosuke Dodo, Masaya Okada, Jun Ando, Almar Palonpon, Katsumasa Fujita, Satoshi
Kawata, and Mikiko Sodeoka. J. Am. Chem. Soc. 133, 6102-6105 (2011).
121) Development of a Selective Vaccinia H1-Related (VHR) Phosphatase Inhibitor with Nonacidic
Phosphate Mimicking Core Structure. Go Hirai, Ayako Tsuchiya, Yusuke Koyama, Yuko Otani,
Kana Oonuma, Kosuke Dodo, Siro Simizu, Hiroyuki Osada, and Mikiko Sodeoka. ChemMedChem 6,
617-622 (2011).
122) Design and Synthesis of Protein Kinase Ca Activators Based on “Out of Pocket” Interactions. Go
Hirai, Megumi Ohkubo, Yuki Tamura, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 21,
3587-3590 (2011).
123) Catalytic Asymmetric a-Chlorination of 3-Acyl-oxazolidin-2-one under Trinary Catalytic System.
Yoshitaka Hamashima, Tatsuya Nagi, Ryo Shimizu, Teruhisa Tsuchimoto, and Mikiko Sodeoka. Eur.
J. Org. Chem. 3675-3678 (2011).
124) Total syntheses of chaetocin and ent-chaetocin. Eriko Iwasa, Yoshitaka Hamashima, Shinya
Fujishiro, Daisuke Hashizume, and Mikiko Sodeoka. Tetrahedron 67, 6585-6599 (2011).
125) Studies on the Selectivity between Glycosylation and Intermolecular Aglycone Transfer ofThioglucoside in Synthesis of Lactose Derivatives. Marie Kato, Go Hirai, and Mikiko Sodeoka.
Chem. Lett. 40, 877-879 (2011).
126) Catch & release of alkyne-tagged molecules in water by polymer-supported cobalt complex.
Hiromichi Egami, Shinji Kamisuki, Kosuke Dodo, Miwako Asanuma, Yoshitaka Hamashima and
Mikiko Sodeoka. Organic & Biomolecular Chemistry 9, 7667-7670 (2011).
127) Label-free Raman Observation of Cytochrome C Dynamics During Apoptosis. Masaya Okada,
Nicholas Isaac Smith, Almar Flotildes Palonpon, Hiromi Endo, Satoshi Kawata, Mikiko Sodeoka,
and Katsumasa Fujita. Proc. Nat. Acad. Sci. 109, 28-32 (2012).
128) Synthesis and Biological Activities of Chaetocin and its Derivatives. Mikiko Sodeoka, Kosuke Dodo,
Yuou Teng, Katsuya Iuchi, Yoshitaka Hamashima, Eriko Iwasa, and Shinya Fujishiro. Pure & Appl.
Chem. 84, 1369-1378 (2012).
129) Dual-specificity Protein Phosphatase CDC25A/B Inhibitor Identified from a Focused Library with
Non-electrophilic Enamine Core Structure. Ayako Tsuchiya, Go Hirai, Yusuke Koyama, Kana
Oonuma, Yuko Otani, Hiroyuki Osada, and Mikiko Sodeoka. ACS Med. Chem. Lett. 3, 294-298(2012).
130) Synthesis of Optically Pure Norcantharidin Analog NCA-01, a Highly Selective Protein Phosphatase
2B Inhibitor, and Its Derivatives. Tadashi Shimizu, Masato Iizuka, Hiroko Matsukura, Daisuke
Hashizume, and Mikiko Sodeoka. Chem. Asian. J. 7, 1221-1230 (2012).
131) Copper-Catalyzed Trifluoromethylation of Allylsilanes. Ryo Shimizu, Hiromichi Egami, Yoshitaka
Hamashima, and Mikiko Sodeoka. Angew. Chem. Int. Ed. 51, 4577-4580 (2012).
132) Catalytic Asymmetric Mono-Fluorination of α-Keto Esters: Synthesis of Optically Active
β-Fluoro-α-Hydroxy and β-Fluoro-α-Amino Acid Derivatives. Shoko Suzuki, Yuki Kitamura,
Sylvain Lectard, Yoshitaka Hamashima, and Mikiko Sodeoka. Angew. Chem. Int. Ed. 51, 4581-4585(2012).

8

M Sodeoka133) Kinetically Controlled One-pot Formation of DEFGH-rings of Type B Physalins throughDomino-type Transformations. Masaki Morita, Go Hirai, Megumi Ohkubo, Hiroyuki Koshino,
Daisuke Hashizume, Keiji Maruoka, and Mikiko Sodeoka. Org. Lett. 14, 3432-3437 (2012).
134) Oxytrifluoromethylation of Styrene Derivatives Using Copper Catalyst. Hiromichi Egami, Ryo
Shimizu, and Mikiko Sodeoka. Tetrahedron Lett. 53, 5503-5506 (2012).
135) Small-molecular inhibitors of Ca2+-induced mitochondrial permeability transition (MPT) derived
from muscle relaxant dantrolene. Shinpei Murasawa, Katsuya Iuchi, Shinichi Sato, Tomomi
Noguchi-Yachide, Mikiko Sodeoka, Tsutomu Yokomatsu, Kosuke Dodo, Yuichi Hashimoto, andHiroshi Aoyama. Bioorg. Med. Chem. 20, 6384-6393 (2012).
136) Rapid Trifluoromethylation of Indole Derivatives. Ayako Miyazaki, Ryo Shimizu, Hiromichi Egami,
and Mikiko Sodeoka. Heterocycles, 86, 979-983 (2012).
137) Alkyne-tag Raman imaging for visualization of mobile small molecules in live cells. Hiroyuki
Yamakoshi, Kosuke Dodo, Almar Palonpon, Jun Ando, Katsumasa Fujita, Satoshi Kawata, andMikiko Sodeoka. J. Am. Chem. Soc. 134, 20681-20689 (2012).
138) Epidithiodiketopiperazine as a pharmacophore for protein lysine methyltransferase G9a inhibitors:
Reducing cytotoxicity by structural simplification. Shinya Fujishiro, Kosuke Dodo, Eriko Iwasa,
Yuou Teng, Yoshihiro Sohtome, Yoshitaka Hamashima, Akihiro Ito, Minoru Yoshida, and Mikiko
Sodeoka. Bioorg. Med. Chem. Lett. 23, 733-736 (2013).
139) Synthesis and evaluation of 2, 3-dinorprostaglandins: dinor-PGD1 and 13-epi-dinor-PGD1 areselective agonists of peroxisome proliferator-activated receptor alpha. Ayato Sato, Kosuke Dodo,
Makoto Makishima, Yuichi Hashimoto, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 23,
3013-3017 (2013).
140) Raman and SERS microscopy for molecular imaging of live cells. Almar Palonpon, Jun Ando,
Hiroyuki Yamakoshi, Kosuke Dodo, Mikiko Sodeoka, Satoshi Kawata, and Katsumasa Fujita.
Nature Protocol, 8, 677-692 (2013).
141) CDC25A-inhibitory RE Derivatives Bind to Pocket Adjacent to the Catalytic Site. Ayako Tsuchiya,
Miwako Asanuma, Go Hirai, Kana Oonuma, Muhammad Muddassar, Eri Nishizawa, Yusuke
Koyama, Yuko Otani, Kam Y. J. Zhang, and Mikiko Sodeoka. Molecular BioSystems, 9, 1026-1034(2013).
142) Alkene Trifluoromethylation Coupled with C-C Bond Formation: Construction of
Trifluoromethylated Carbocycles and Heterocycles. Hiromichi Egami, Ryo Shimizu, Shintaro
Kawamura, and Mikiko Sodeoka. Angew. Chem. Int. Ed. 52, 4000-4003 (2013).
143) Concise synthesis of oxindole derivatives bearing a trifluoromethyl group: Copper-catalyzed
trifluoromethylation of acryloanilides. Hiromichi Egami, Ryo Shimizu, and Mikiko Sodeoka. J.
Fluorine Chemistry, 152, 51-55 (2013).
144) Trifluoromethylation Reactions for the Synthesis of b-Trifluoromethylamines. Hiromichi Egami,
Shintaro Kawamura, Ayako Miyazaki, and Mikiko Sodeoka. Angew. Chem. Int. Ed., 52, 7841-7844(2013).
145) Contribution of Cage-shaped Structure of Physalins to their Mode of Action in Inhibition of NF-κB
Activation. Masaaki Ozawa, Masaki Morita, Go Hirai, Satoru Tamura, Masao Kawai, Ayako
Tsuchiya, Kana Oonuma, Keiji Maruoka, and Mikiko Sodeoka. ACS Med. Chem. Lett. 4, 730-735(2013).
146) Unexpected Diels-Alder/Carbonyl-ene Cascade toward the Biomimetic Synthesis of
Chloropupukeananin. Takahiro Suzuki, Yuria Miyajima, Kaname Suzuki, Kanako Iwakiri, Masaki
Koshimizu, Go Hirai, Mikiko Sodeoka, and Susumu Kobayashi. Organic Letters 15, 1748-1751(2013).
147) Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of anaryl group. Hiromichi Egami, Ryo Shimizu, Yoshihiko Usui, and Mikiko Sodeoka. Chem. Commun.,49, 7346 – 7348 (2013).
148) Development of bis-unsaturated ester aldehydes as amino-glue probes: sequential double
azaelectrocyclization as a promising strategy for bioconjugation. Katsunori Tanaka, Yuka Nakamoto,9M Sodeoka

Eric R. O. Siwu, Ambara R. Pradipta, Koji Morimoto, Takeshi Fujiwara, Suguru Yoshida, Takamitsu
Hosoya, Yuki Tamura, Go Hirai, Mikiko Sodeoka, and Koichi Fukase. Org. Biomol. Chem. 11,
7326-7333 (2013).
149) Turn-ON Fluorescent Affinity Labeling Using a Small Bifunctional O-Nitrobenzoxadiazole Unit:
Selective Labeling and Imaging of Target Protein. Takao Yamaguchi, Miwako Asanuma, Shuichi
Nakanishi, Yohei Saito, Masateru Okazaki, Kosuke Dodo, and Mikiko Sodeoka. Chem. Sci. 5,1021-1029 (2014).
150) Simultaneous imaging of protonated and deprotonated carbonylcyanide p-trifluoromethoxyphenylhydrazone in live cells by Raman microscopy. Hiroyuki Yamakoshi, Almar F. Palonpon,
Kosuke Dodo, Jun Ando, Satoshi Kawata, Katsumasa Fujita, and Mikiko Sodeoka. Chem. Commun.
50, 1341-1343 (2014).
151) A Catch and Release Protocol of Alkyne-Tagged Molecules Based on a Resin-Bound Cobalt
Complex for Peptide Enrichment in Aqueous Media. Ayako Miyazaki, Miwako Asanuma, Kosuke
Dodo, Hiromichi Egami, and Mikiko Sodeoka. Chem. Eur. J. 20, 8116-8128 (2014).
152) RE12 derivatives displaying Vaccinia H1-related phosphatase (VHR) inhibition in the presence ofdetergent and their anti-proliferative activity against HeLa cells. Frédéric Thuauda, Shuntaro Kojima,
Go Hirai, Kana Oonuma, Ayako Tsuchiya, Takako Uchida, Teruhisa Tsuchimoto, and Mikiko
Sodeoka. Bioorg. Med. Chem. 22, 2771-2782 (2014).
153) Oxy-trifluoromethylation of alkenes and its application to the synthesis of b-trifluoromethylstyrene
derivatives. Hiromichi Egami, Ryo Shimizu, Yoshihiko Usui , and Mikiko Sodeoka. J. Fluor. Chem.
167, 172-178 (2014).
154) Dual Catalysis with Copper and Rhenium for Trifluoromethylation of Propargylic Alcohols:
Efficient Synthesis of a-Trifluoromethylated Enones. Hiromichi Egami, Takafumi Ide, Masashi
Fujita, Toshifumi Tojo, Yoshitaka Hamashima, and Mikiko Sodeoka. Chem. Eur. J. 20, 12061-12065(2014).
155) A Selenium-Based S-adenosylmethionine Analogue Reveals the Mammalian Seven-Beta-Strand
Methyltransferase METTL10 to Be an EF1A1 Lysine Methyltransferase. Tadahiro Shimazu, Joaquin
Barjau, Yoshihiro Sohtome, Mikiko Sodeoka, and Yoichi Shinkai. PLoS One 9, e105394 (2014).
156) Dual-Polarization Raman Spectral Imaging to Extract Overlapping Molecular Fingerprints of Living
Cells. Liang-da Chiu, Almar F. Palonpon, Nicholas I. Smith, Satoshi Kawata, Mikiko Sodeoka, andKatsumasa Fujita. J. Biophotonics, 8, 546-554 (2015).
157) Sphingomyelin distribution in lipid rafts of artificial monolayer membranes visualized by Raman
microscopy. Jun Ando, Masanao Kinoshita, Jin Cui, Hiroyuki Yamakoshi, Kosuke Dodo, Katsumasa
Fujita, Michio Murata, and Mikiko Sodeoka. Proc. Nat. Acad. Sci. 112, 4558-4563 (2015).
158) A sensitive and specific Raman probe based on bisarylbutadiyne for live cell imaging of
mitochondria. Hiroyuki Yamakoshi, Almar Palonpon, Kosuke Dodo, Jun Ando, Satoshi Kawata,
Katsumasa Fujita, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 25, 664-667 (2015).
159) Aminotrifluoromethylation of Olefins via Cyclic Amine Formation: Its Mechanistic Study andApplication to Synthesis of Trifluoromethylated Pyrrolidines. Shintaro Kawamura, Hiromichi Egami,
and Mikiko Sodeoka. J. Am. Chem. Soc. 137, 4865-4873 (2015).
160) Saccharothriolides A-C, Novel Phenyl-substituted 10-Membered Macrolides from a Rare
Actinomycete Saccharothrix sp. Shan Lu, Shinichi Nishimura, Go Hirai, Masashi Ito, Teppei
Kawahara, Miho Izumikawa, Mikiko Sodeoka, Kazuo Shin-ya, Toshio Tsuchida, and Hideaki
Kakeya. Chem. Commun. 51, 8074-8077 (2015).
161) Product Control in Alkene Trifluoromethylation: Hydro-trifluoromethylation, Vinylic
Trifluoromethylation, and Iodo-trifluoromethylation Using Togni Reagent. Hiromichi Egami,
Yoshihiko Usui, Shintaro Kawamura, Sayoko Nagashima, and Mikiko Sodeoka. Chem. Asian J. 10,2190-2199 (2015).
162) Novel Raman-tagged sphingomyelin that closely mimics original raft-forming behavior. Jin Cui,
Shigeru Matsuoka, Masanao Kinoshita, Nobuaki Matsumori, Fuminori Sato, Michio Murata, JunAndo, Hiroyuki Yamakoshi, Kosuke Dodo, and Mikiko Sodeoka. Bioorg. Med. Chem. Lett. 23,
2989-2994 (2015).
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163) Unique features of chiral palladium enolates derived from b-ketoamide: Structure and catalytic
asymmetric Michael and fluorination reactions. Kenji Hayamizu, Naoki Terayama, Daisuke
Hashizume, Kosuke Dodo, and Mikiko Sodeoka. Tetrahedron, 71, 6594-6601 (2015), Tsuji special
issue.
164) VDAC3 gating is activated by suppression of disulfide-bond formation between the N-terminal
region and the bottom of the pore. Masateru Okazaki , Katsue Kurabayashi, Miwako Asanuma,
Yohei Saito, Kosuke Dodo, and Mikiko Sodeoka. Biochim. Biophys. Acta (Biomembranes), 1848,3188-3196 (2015).
165) A unique SN2’-type reaction of allylic alcohols with organolithium reagent accelerated by a proximal
trifluoromethyl group. Hiromichi Egami, Yoshihiko Usui, Shintaro Kawamura, Ryo Shimizu,
Sayoko Nagashima, and Mikiko Sodeoka. J. Fluor. Chem. 179, 121-128 (2015). Governer special
issue.
166) Reactions of Carbonyl Compounds with Phosphorus Ylide Generated from Tribromofluoromethane
and Tris(dimethylamino)phosphine. Go Hirai, Eri Nishizawa, Daiki Kakumoto, Masaki Morita,
Mitsuaki Okada, Daisuke Hashizume, Sayoko Nagashima, and Mikiko Sodeoka. Chem. Lett., 44,1389-1391 (2015).
167) Photo-induced formation of cyclopropanols from α-ketoamides via g-C-H bond activation. Eisuke
Ota, Yu Mikame, Go Hirai, Hiroyuki Koshino, Shigeru Nishiyama, and Mikiko Sodeoka.
Tetrahedron Lett. 56, 5991-5994 (2015).
168) Dual function of coronatine as a bacterial virulence factor against plants: possible COI1–JAZindependent role. Syusuke Egoshi, Yousuke Takaoka, Hiroaki Saito, Yuuki Nukadzuka, Kengo
Hayashi, Yasuhiro Ishimaru, Hiroyuki Yamakoshi, Kosuke Dodo, Mikiko Sodeoka, and Minoru
Ueda. RSC Adv., 6, 19404–19412 (2016).
169) Photochemical and Additive-free Coupling Reaction of α-Cumyl α-Ketoesters via Intermolecular
C-H Bond Activation. Eisuke Ota, Yu Mikame, Go Hirai, Shigeru Nishiyama, and Mikiko Sodeoka.
Synlett 27, 1128-1132 (2016).
170) Identification of Nitrogen Signaling Factors that regulate adaptive nitrogen metabolism in fission
yeast. Xiaoying Sun, Go Hirai, Masashi Ueki, Hiroshi Hirota, Qianqian Wang, Yayoi Hongo,
Takemichi Nakamura, Yuki Hitora, Hidekazu Takahashi, Mikiko Sodeoka, Hiroyuki Osada, Makiko
Hamamoto, Minoru Yoshida, and Yoko Yashiroda. Scientific Report 6, 20856 (2016).
171) Platinum-Catalyzed Friedel-Crafts-Type C-H Coupling-Allylic Amination Cascade to Synthesize
3,4-Fused Tricyclic Indoles. Yuta Suzuki, Yuito Tanaka, Shun-ichi Nakano, Kasuke Dodo, Natsumi
Yada, Ken-ichi Shinohara, Kazuko Kita, Atsushi Kaneda, Mikiko Sodeoka, Yasumasa Hamada, andTetsuhiro Nemoto. Chem. Eur. J. 22, 4418-4421 (2016).
172) Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source.
Shintaro Kawamura, and Mikiko Sodeoka. Angew. Chem. Int. Ed. 55, 8740-8743 (2016).
173) Structure-activity relationship study of 3-amino-2-indolyllactam derivatives: Development ofinhibitors of oxidative stress-induced necrosis. Kosuke Dodo, Kenji Hayamizu, Tadashi Shimizu, andMikiko Sodeoka. Chem. Pharm. Bull. 64, 886-898 (2016).
174) Alkyne-tag SERS screening and identification of small-molecule-binding sites in protein. Jun Ando,
Miwako Asanuma, Kosuke Dodo Hiroyuki Yamakoshi, Satoshi Kawata, Katsumasa Fujita, andMikiko Sodeoka . J. Am. Chem. Soc. 138, 13901-13910 (2016).
175) Solvent-Dependent Copper-Catalyzed Synthesis of Pyrazoles Under Aerobic Conditions. Florian
Pünner, Yoshihiro Sohtome and Mikiko Sodeoka. Chem. Commun. 52, 14093-14096 (2016).
176) A new carbamidemethyl-linked lanthanoid chelating tag for PCS NMR spectroscopy of proteins inliving HeLa cells. Yuya Hikone, Go Hirai, Masaki Mishima, Kosuke Inomata, Tappei Ikeya,
Souichiro Arai, Masahiro Shirakawa, and Mikiko Sodeoka, Yutaka Ito. J. Biomol. NMR, 66, 99-110(2016).
177) Total synthesis of natural derivatives and artificial analogs of 13-oxyingenol and their biologicalevaluation. Takayuki Ohyoshi, Yuki Tamura, Ichiro Hayakawa, Go Hirai, Yamato Miyazawa, Shota
Funakubo, Mikiko Sodeoka, and Hideo Kigoshi. Org. Biomol. Chem. 14, 11426-11437 (2016).
11

M Sodeoka178) Comparative Characterization of the Leaf Tissue of Physalis alkekengi and Physalis peruviana Using
RNA-seq and Metabolite Profiling. Atsushi Fukushima, Michimi Nakamura, Hideyuki Suzuki,
Mami Yamazaki, Eva Knoch, Tetsuya Mori, Naoyuki Umemoto, Masaki Morita, Go Hirai, Mikiko
Sodeoka, and Kazuki Saito. Frontiers in Plant Science, 7, article 1883 (2016).
179) Reversibility of 3-Phenyl-2-oxindole Dimer Formation: Application to Construct Compounds with
Two Distinct Vicinal All-carbon Quaternary Centers. Yoshihiro Sohtome, Masumi Sugawara,
Daisuke Hashizume, Daiki Hojo, Miki Sawamura, Atsuya Muranaka, Masanobu Uchiyama, andMikiko Sodeoka. Heterocycles. 95, 1030-1040 (2017).
180) Synthesis of the Right-Side Structure of Type B Physalins. Masaki Morita, Shuntaro Kojima,
Megumi Ohkubo, Hiroyuki Koshino, Daisuke Hashizume, Go Hirai, Keiji Maruoka, and Mikiko
Sodeoka. Israel J. Chem. 57, 309-318 (2017).
181) Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition.
Yoshihiro Sohtome, Genta Nakamura, Atsuya Muranaka, Daisuke Hashizume, Sylvain Lectard,
Teruhisa Tsuchimoto, Masanobu Uchiyama, and Mikiko Sodeoka. Nature Comm. 8, 14875 (2017).
182) Noncanonical Function of a Small-Molecular Virulence Factor Coronatine against Plant Immunity:
An In Vivo Raman Imaging Approach. Minoru Ueda, Syusuke Egoshi, Kosuke Dodo, Yasuhiro
Ishimaru, Hiroyuki Yamakoshi, Takeshi Nakano, Yousuke Takaoka, Shinya Tsukiji, and Mikiko
Sodeoka. ACS Central Science, 3, 462-472 (2017).
183) Catalytic Enantioselective [3+2] Cycloaddition of α-Keto Ester Enolates and Nitrile Oxides. SamuelL. Bartlett, Yoshihiro Sohtome, Daisuke Hashizume, Peter S. White, Miki Sawamura, Jeffrey S.
Johnson, and Mikiko Sodeoka. J. Am. Chem. Soc. 139, 8661-8666 (2017).
184) Crystal structural characterization reveals novel oligomeric interactions of human voltage-dependentanion channel 1. Toshiaki Hosaka, Masateru Okazaki, Tomomi Kimura-Someya, Yoshiko
Ishizuka-Katsura, Kaori Ito, Shigeyuki Yokoyama, Kosuke Dodo, Mikiko Sodeoka, and Mikako
Shirouzu. Protein Science, 26, 1749-1758 (2017).
185) Convergent synthesis of the ent-ZA’B’C’D’-ring system of maitotoxin. Tatsuo Saito, Masayuki
Morita, Hiroyuki Koshino, Mikiko Sodeoka, and Tadashi Nakata. Org. Lett. 19, 3203-3206 (2017).
186) Synthesis of Polyunsaturated Fatty Acid-Containing Glucuronosyl-diacylglycerol through Direct
Glycosylation. Qianqian Wang, Yuta Kuramoto, Yozo Okazaki, Eisuke Ota, Masaki Morita, Go
Hirai, Kazuki Saito, and Mikiko Sodeoka. Tetrahedron. Lett. 58, 2915-2918 (2017).
187) Hyperoxidation of ether-linked phospholipids accelerates neutrophil extracellular trap formation.
Satoshi Yotsumoto, Yuito Muroi, Tatsuya Chiba, Rio Ohmura, Maki Yoneyama, Megumi
Magarisawa, Kosuke Dodo, Naoki Terayama, Mikiko Sodeoka, Ryohei Aoyagi, Makoto Arita,
Satoko Arakawa, Shigeomi Shimizu and Masato Tanaka. Scientific Report, 7, 16026 (2017).
188) Specific fluorescence labeling of target proteins by using a ligand–4-azidophthalimide conjugate.
Kosuke Chiba, Miwako Asanuma, Minoru Ishikawa, Yuichi Hashimoto, Kosuke Dodo, Mikiko
Sodeoka, and Takao Yamaguchi. Chem. Comm. 53, 8751-8754 (2017).
189) N-Heterocycle-forming amino/carboperfluoroalkylations of aminoalkene by using perfluoro acidanhydrides: mechanistic studies and applications directed toward perfluoroalkylated compound
libraries. Shintaro Kawamura, Kento Dosei, Elena Valverde, Kiminori Ushida, and Mikiko Sodeoka.
J. Org. Chem. 82, 12539-12553 (2017).
190) Synthesis of CF3-Containing Oxazolines via Trifluoromethylation of Allylamides with Togni
Reagent in the Presence of Alkali Metal Iodides. Shintaro Kawamura, Daisuke Sekine, and Mikiko
Sodeoka. J. Fluor. Chem. 203, 115-121 (2017).
191) Indolylmaleimide Derivative IM-17 Shows Cardioprotective Effects in Ischemia-Reperfusion Injury.
Kosuke Dodo, Tadashi Shimizu, Jun Sasamori, Kazuyuki Aihara, Naoki Terayama, Shuhei Nakao,
Katsuya Iuchi, Masahiro Takahashi, and Mikiko Sodeoka. ACS Med. Chem. Lett. 9, 182-187 (2018).
192) Thienyl-substituted α-Ketoamide: A Less Hydrophobic Reactive Group for Photo-Affinity Labeling.
Eisuke Ota, Kazuteru Usui, Kana Oonuma, Hiroyuki Koshino, Shigeru Nishiyama, Go Hirai, andMikiko Sodeoka. ACS Chem. Biol. 13, 876-880 (2018).

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193) The alkyne-tag Raman imaging of coronatine, a plant pathogen virulence factor, in Commelina
communis and the possible mode of action. Minoru Ueda, Kengo Hayashi, Syusuke Egoshi,
Yasuhiro Ishimaru, Yousuke Takaoka, Hiroyuki Yamakoshi, Kosuke Dodo and Mikiko Sodeoka.
Org. Biomol. Chem. 16, 3305-3496 (2018).
194) Unveiling Epidithiodiketopiperazine as a Non-Histone Arginine Methyltransferase Inhibitor by
Chemical Protein Methylome Analyses. Yoshihiro Sohtome, Tadahiro Shimazu, Joaquin Barjau,
Shinya Fujishiro, Mai Akakabe, Naoki Terayama, Kosuke Dodo, Akihiro Ito, Minoru Yoshida,
Yoichi Shinkai, and Mikiko Sodeoka. Chem. Commun. 54, 9202-9205 (2018).
195) Metal-free alkene oxy- and amino-perfluoroalkylations via carbocation formation by using perfluoroacid anhydrides: unique reactivity between styrenes and perfluoro diacyl peroxides. Elena Valverde,
Shintaro Kawamura, Daisuke Sekine, and Mikiko Sodeoka. Chem. Sci. 8, 7115-7121 (2018).
196) Reactivity and property of bis(chlorodifluoroacetyl) peroxide generated in-situ fromchlorodifluoroacetic anhydride for chlorodifluoromethylation reactions. Shintaro Kawamura,
Cassandra J. Henderson, Yuma Aoki, Daisuke Sekine, Shū Kobayashi, and Mikiko Sodeoka. Chem.
Commun. 54, 11276-11279 (2018).
197) Tri-methylation of ATF7IP by G9a/GLP recruits a chromodomain protein MPP8. Takeshi Tsusaka,
Masaki Kikuchi, Tadahiro Shimazu, Takehiro Suzuki, Yoshihiro Sohtome, Mai Akakabe, Mikiko
Sodeoka, Naoshi Dohmae, Takashi Umehara and Yoichi Shinkai. Epigenetics & Chromatin, 11, 56(2018).
198) A translation inhibitor targets a bimolecular cavity between eIF4A and polypurine RNA. Shintaro
Iwasaki, Wakana Iwasaki, Mari Takahashi, Ayako Sakamoto, Chiduru Watanabe, Yuichi Shichino,
Stephen N. Floor, Koichi Fujiwara, Mari Mito, Kosuke Dodo, Mikiko Sodeoka, Hiroaki Imataka,
Teruki Honma, Kaori Fukuzawa, Takuhiro Ito, and Nicholas T. Ingolia. Mol. Cell, 73, 738-748(2019).
199) Control of site selectivity in trifluoromethylation of alkenes bearing a pendant indolyl group:
synthesis of CF3-containing tetrahydrocarbazoles. Ryo Murakami, Daisuke Sekine, Yuma Aoki,
Shintaro Kawamura, and Mikiko Sodeoka. Tetrahedron, 75, 1327-1335 (2019).
200) Synthesis of All Stereoisomers of RK460 and Evaluation of Activity and Selectivity as Abscisic
Acid Receptor Antagonists. Yu Mikame, Kazuko Yoshida, Daisuke Hashizume, Go Hirai, Kazuo
Nagasawa, Hiroyuki Osada and Mikiko Sodeoka. Chem. Eur. J. 25, 3496-3500 (2019).
201) Detection of esterase activity by chromogenic and fluorogenic probe based on an O-nitrobenzoxazole(O-NBD) unit. Kana Okada, Takao Yamaguchi, Kosuke dodo, Mikiko Sodeoka, and Satoshi Obika.
Bioorg. Med. Chem. 27, 1444-1448 (2019).
202) Synthesis of All Stereoisomers of Monomeric Spectomycin A1 and A2, and Evaluation of Their
Protein SUMOylation-Inhibitory Activity. Yusaku Nomura, Frédéric Thuaud, Daisuke Sekine,
Akihiro Ito, Satoko Maeda, Hiroyuki Koshino, Daisuke Hashizume, Atsuya Muranaka, Thomas
Cruchter, Masanobu Uchiyama, Satoshi Ichikawa, Akira Matsuda, Minoru Yoshida, Go Hirai, andMikiko Sodeoka. Chem. Eur. J. 25, 8387-8392 (2019).
203) Molecular Field Analysis Using Intermediates in Enantio-Determining Steps Can Extract
Information for Data-Driven Molecular Design in Asymmetric Catalysis. Shigeru Yamaguchi, andMikiko Sodeoka. Bull. Chem. Soc. Jpn. 92, 1701-1706 (2019).
204) Development of a water-soluble indolylmaleimide derivative IM-93 showing dual inhibition offerroptosis and NETosis. Kosuke Dodo, Erika Kuboki, Tadashi Shimizu, Ryu Imamura, Megumi
Magarisawa, Masahiro Takahashi, Takuto Tokuhiro, Satoshi Yotsumoto, Kenichi Asano, Takashi
Suda, Masato Tanaka, and Mikiko Sodeoka. ACS Med. Chem. Lett. 10, 1272-1278 (2019).
205) Cross-Coupling Reaction of Dimer-derived Persistent Tertiary Carbon-Centered Radicals with Azo
Compounds. Rikako Ohnishi, Masumi Sugawara, Mai Akakabe, Hiroyuki Koshino, Yoshihiro
Sohtome, and Mikiko Sodeoka. Asian J. Org. Chem. 8, 1017-1023 (2019).
206) Highly Chemoselective gem-Difluoropropargylation of Aliphatic Alcohols. Toshitaka Okamura,
Syusuke Egoshi, Kosuke Dodo, Mikiko Sodeoka, Yoshiharu Iwabuchi, and Naoki Kanoh. Chem.
Eur. J. 25, 16002-16006 (2019).
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207) Formal aerobic oxidative cross-coupling of benzofuranones with azo compounds using
Pd-µ-hydroxo complex. Rikako Ohnishi, Masumi Sugawara, Tetsuya Ezawa, Yoshihiro Sohtome,
and Mikiko Sodeoka. Chem. Pharm. Bull. 68, 895-898 (2020).
208) Regiodivergent Oxidative Cross-Coupling of Catechols with Persistent tert-Carbon Radicals.
Masumi Sugawara, Rikako Ohnishi, Tetsuya Ezawa, Mai Akakabe, Miki Sawamura, Daiki Hojo,
Daisuke Hashizume, Yoshihiro Sohtome, and Mikiko Sodeoka. ACS Catalysis, 10, 12770-12782(2020).
209) Quantitative drug dynamics visualized by alkyne-tagged plasmonic-enhanced Raman microscopy.
Kota Koike, Kazuki Bando, Jun Ando, Hiroyuki Yamakoshi, Naoki Tereayama, Kosuke Dodo,
Nicholas Isaac Smith, Mikiko Sodeoka, and Katsumasa Fujita. ACS Nano, 14, 15032-15041 (2020).
210) Synthesis of DFGH-Ring Derivatives of Physalins vis One-Pot Construction of GH-Ring and
Evaluation of Their NF-kB-Inhibitory Activity. Makoto Yoritate, Yuki Morita, Manuel Gemander,
Masaki Morita, Tomohiro Yamashita, and Mikiko Sodeoka, Go Hirai. Org. Lett. 22, 8877-8881(2020).
211) Image-based Screen Capturing Misfolding Status of Niemann-Pick type C1 Identifies Potential
Candidates for Chaperone Drugs. Ryuta Shioi, Fumika Karaki, Hiromasa Yoshioka, Tomomi
Noguchi-Yachide, Minoru Ishikawa, Kosuke Dodo, Yuichi Hshimoto, Mikiko Sodeoka, and Kenji
Ohgane. PLoS ONE, 15(12): e0243746 (2020).
212) Dual targeting of DDX3 and eIF4A by the translation inhibitor Rocaglamide A. Mingming Chen,
Miwako Asanuma, Mari Takahashi, Yuichi Shichino, Mari Mito, Koichi Fujiwara, Hironori Saito,
Stephen N. Floor, Nicholas T. Ingolia, Mikiko Sodeoka, Kosuke Dodo, Takuhiro Ito, and Shintaro
Iwasaki. Cell Chem. Biol. 28, 475-486 (2021).
213) Ganglioside GM3 Analogues Containing Monofluoromethylene-linked Sialoside: Synthesis,
Stereochemical Effects, Conformational Behavior, and Biological Activities. Go Hirai, Marie Kato,
Hiroyuki Koshino, Eri Nishizawa, Kana Oonuma, Eisuke Ota, Toru Watanabe, Daisuke Hashizume,
Yuki Tamura, Mitsuaki Okada, Taeko Miyagi, and Mikiko Sodeoka. JACS Au, 1, 137-146 (2021).
214) Development of deuterated derivatives of γ-linolenic acid and their application for biological studies:
metabolic tuning and Raman imaging. Ayato Sato, Yuki Tamura, Syusuke Egoshi, Koichi Fujiwara,
Kana Oonuma, Shuhei Nakao, Kosuke Dodo, and Mikiko Sodeoka. Chem. Comm. 57, 2180-2181(2021).
215) The orphan methyltransferase METTL9 mediates pervasive 1-methylhistidine modification of
mammalian proteomes. Erna Davydova, Tadahiro Shimazu, Maren Schuhmacher, Magnus E.
Jakobsson, Tongri Liu, Hanneke L.D.M. Willemen, Anders Moen , Angela Y.Y. Ho, Jędrzej Małecki,
Lisa Schroer, Rita Pinto, Takehiro Suzuki, Ida A. Grønsberg, Yoshihiro Sohtome, Mai Akakabe,Sara Weirich, Masaki Kikuchi, Jesper V. Olsen, Naoshi Dohmae, Takashi Umehara, Mikiko
Sodeoka, Michael McDonough, Niels Eijkelkamp, Christopher J. Schofield, Albert Jeltsch, Yoichi
Shinkai, and Pål Ø. Falnes. Nature Comm. 12, 891 (2021).
216) Cu-catalyzed Allylic Perfluoroalkylation of Alkenes by Using Perfluoro Acid Anhydrides:
Preparation of N-(5,5,5-Trifluoro-2-penten-1-yl)phthalimide. Yuma Aoki, Shintaro Kawamura, andMikiko Sodeoka. Org. Synth. 98, 84-96 (2021).
217) Detecting Nitrile-containing Small Molecules by Infrared Photothermal Microscopy. Fangfang Tai,
Kota Koike, Hiroyuki Kawagoe, Jun Ando, Yasuaki Kumamoto, Nicholas I. Smith, Mikiko Sodeoka,
and Katsumasa Fujita. Analyst, 146, 2307-2312 (2021).
218) Dynamics in Catalytic Asymmetric Diastereoconvergent (3 + 2) Cycloadditions with Isomerizable
Nitrones and a-Keto Ester Enolates. Tetsuya Ezawa, Yoshihiro Sohtome, Daisuke Hashizume,
Masaya Adachi, Mai Akakabe, Hiroyuki Koshino, and Mikiko Sodeoka. J. Am. Chem. Soc. 143,9094-9104 (2021).
219) Multi-focus Raman Plate Reader for High-throughput Chemical Screening. Hiroyuki Kawagoe, JunAndo, Miwako Asanuma, Kosuke Dodo, Tetsuya Miyano, Hiroshi Ueda, Mikiko Sodeoka, andKatsumasa Fujita. Sci. Rep. 11, 15742 (2021).
220) Deuteration of terminal alkynes realizes simultaneous live cell Raman imaging of similar
alkyne-tagged biomolecules. Syusuke Egoshi, Kosuke Dodo, Kenji Ohgane, and Mikiko Sodeoka.
Org. Biomol. Chem. 19, 8232-8236 (2021).
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221) 1,2-Bis-perfluoroalkylations of alkenes and alkynes with perfluorocarboxylic anhydrides via theformation of perfluoroalkylcopper intermediates. Takuma Tagami, Yuma Aoki, Shintaro Kawamura,and Mikiko Sodeoka. Org. Biomol. Chem. 19, 9148-9153 (2021).
222) Design, Synthesis and Biological Activity of 16,17-Dihydroheronamide C and ent-Heronamide C.
Naoki Kanoh, Ryusei Terashima, Hiromichi Nishiyama, Yuta Terajima, Shota Nagasawa, Yusuke
Sasano, Yoshiharu Iwabuchi, Hiroaki Saito, Syusuke Egoshi, Kosuke Dodo, Mikiko Sodeoka,
Chengqian Pan, Yoshinobu Ikeuchi, Shinichi Nishimura, and Hideaki Kakeya. J. Org. Chem. 86,
16249-16258 (2021).
223) Effect of Alkynyl Group on the Reactivity of 2-Thieny-substituted α-Ketoamide: Development of
Photo-reactive Minimalist Probe. Takahiro Moriyama, Daiki Mizukami, Makoto Yoritate, Kazuteru
Usui, Daisuke Takahashi, Eisuke Ota, Mikiko Sodeoka, Tadashi Ueda, Satoru Karasawa, and Go
Hirai. Chem. Eur. J. 28, e202103925 (2022).
224) METTL18-mediated histidine methylation on RPL3 modulates translation elongation for proteostasis
maintenance. Eriko Matsuura-Suzuki, Tadahiro Shimazu, Mari Takahashi, Kaoru Kotoshiba,
Takehiro Suzuki, Kazuhiro Kashiwagi, Yoshihiro Sohtome, Mai Akakabe, Mikiko Sodeoka, Naoshi
Dohmae, Takuhiro Ito*, Yoichi Shinkai, and Shintaro Iwasaki. eLife 11, e72780 (2022).

Selected Review and Accounts (in English)225) Arene Chromium Tricarbonyl Catalyzed Reactions in Organic Synthesis. Mikiko Sodeoka and
Masakatsu Shibasaki. Synthesis, 643-658 (1993).
226) Asymmetric Heck Reaction: Catalytic Asymmetric Syntheses of Bioactive Molecules. Masakatsu
Shibasaki, Mikiko Sodeoka. J. Synth. Org. Chem. Jpn. 52, 956-967 (1994).
227) Asymmetric Synthesis Using Palladium Catalysts. Mikiko Sodeoka and Masakatsu Shibasaki. Pure
& Appl. Chem., 70, 411-414 (1998).
228) Development of Protein Phosphatases Inhibitors: A Focused Library Approach. Mikiko Sodeoka,
Yoshiyasu Baba. J. Synth. Org. Chem. Jpn. 59, 1095-1102 (2001).
229) Development of Catalytic Asymmetric Reactions via Chiral Palladium Enolate. Yoshitaka
Hamashima and Mikiko Sodeoka. Chemical Record, 4, 231-242 (2004).
230) Development of Catalytic Enantioselelctive Reactions via Palladium Enolates as Key Intermediates.
Mikiko Sodeoka, Yoshitaka Hamashima. Bull. Chem. Soc. Jpn., 78, 941-956 (2005).
231) Acid-Base Catalysis Using Chiral Palladium Complexes. Mikiko Sodeoka and Yoshitaka
Hamashima. Pure & Applied Chem. 78, 477-494 (2006).
232) Enantioselective Fluorination Reactions Catalyzed by Chiral Palladium Complexes. Yoshitaka
Hamashima and Mikiko Sodeoka. SYNLETT 1467-1478 (2006).
233) Catalytic Enantioselective a-Fluorination of Carbonyl Compounds Using Chiral Transition Metal
Complexes. Yoshitaka Hamashima, Mikiko Sodeoka. J. Synth. Org. Chem. Jpn. 65, 1099-1107(2007).
234) Synthesis of Optically Active Heterocyclic Compounds Using Pd-catalyzed Asymmetric Reactions
As A Key Step. Mikiko Sodeoka and Yoshitaka Hamashima. Pure & Applied Chemistry, 80,
763-776 (2008).
235) A strategy for constructing C-sialosides based on Ireland-Claisen rearrangement and its application
for synthesis of CF2-linked ganglioside GM4 analogue. Mikiko Sodeoka, Go Hirai, Toru Watanabe,
and Taeko Miyagi. Pure & Appl. Chem. 81, 205-215 (2009).
236) Chiral Pd aqua complex-catalyzed asymmetric C-C bond-forming reactions: a Brønsted acid-basecooperative system. Mikiko Sodeoka and Yoshitaka Hamashima. Chem. Commun. 5787-5798(2009).
237) Development of Selective Inhibitors of Necrosis. Mikiko Sodeoka and Kosuke Dodo. Chemical
Record, 10, 308-314 (2010).

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238) Recent Advances in Catalytic Enantioselective Fluorination Reactions. Sylvain Lectard, Yoshitaka
Hamashima, and Mikiko Sodeoka. Adv. Synth. Cat. 352, 2708-2732 (2010).
239) Epipolythiodiketopiperazine Alkaloids: Total Syntheses and Biological Activities. Eriko Iwasa,
Yoshitaka Hamashima, and Mikiko Sodeoka. Israel J. Chem. 51, 420-433 (2011).
240) Efficient Fluorination of Organic Molecules with Chiral Anions. Mikiko Sodeoka. Science, 334,
1651-1152 (2011). (Perspective)241) Molecular imaging of live cells by Raman microscopy. Almar F. Palonpon, Mikiko Sodeoka, andKatsumasa Fujita. Curr. Opin. Chem. Biol. 17, 708-715 (2013).
242) Metal-catalyzed synthesis of heterocycles bearing a trifluoromethyl group. Mikiko Sodeoka andHiromichi Egami. Pure & Appl. Chem. 86, 1247-1256 (2014).
243) Recent Progress on Trifluoromethylation of Alkenes with Concomitant Introduction of Additional
Functional Groups. Hiromichi Egami and Mikiko Sodeoka. Angew. Chem. Int. Ed., 53, 8294-8308(2014).
244) Focused Library with Core Structure Extracted from Natural Products and Modified: Application to
Phosphatase Inhibitors and Several Biochemical Findings. Go Hirai and Mikiko Sodeoka. Acc. Chem.
Res. 48, 1464-1473 (2015).
245) High-speed Raman imaging of cellular processes. Jun Ando, Almar F. Palonpon, Mikiko Sodeoka,
and Katsumasa Fujita. Curr. Opin. Chem. Biol. 33, 16-24 (2016).
246) Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic
Centers; Synthetic Challenges and Pharmaceutical Needs. Yi Zhu, Jianlin Han, Jiandong Wang,
Norio Shibata, Mikiko Sodeoka, Vadim A. Soloshonok, Jaime A. S. Coelho, F. Dean Toste. Chem.
Rev. 118, 3887-3964 (2018).
247) Development of chaetocin and S-adenosylmethionine analogues as tools for studying protein
methylation. Yoshihiro Sohtome and Mikiko Sodeoka. Chemical Record, 18, 1660-1671 (2018).
248) Fluoroalkylation Methods for Synthesizing Versatile Building Blocks. Shintaro Kawamura, andMikiko Sodeoka. Bull. Chem. Soc. Jpn. 92, 1245-1262 (2019).
249) Multi-Selective Catalytic Asymmetric Reactions Using a-Keto Esters as Pronucleophiles. Yoshihiro
Sohtome, and Mikiko Sodeoka. Synlett 31, 523-534 (2020).
250) Diacyl Peroxides as Convenient Multifunctional Synthetic Reagents. Shintaro Kawamura, Subrata
Mukherjee, and Mikiko Sodeoka. Org. Biomol. Chem. 19, 2096-2109 (2021).
251) Cross-Coupling Reactions of Persistent Tertiary Carbon Radicals. Yoshihiro Sohtome, Kyohei
Kanomata, and Mikiko Sodeoka. Bull. Chem. Soc. Jpn. 94, 1066-1079 (2021).
252) A Decade of Alkyne-Tag Raman Imaging (ATRI): Applications in Biological Systems. Subha
Bakthavatsalam, Kosuke Dodo, and Mikiko Sodeoka. RSC Chem. Biol. 2, 1415-1429 (2021).
253) Propargylic Se-adenosyl-l-selenomethionine: A chemical tool for methylome analysis. Yoshihiro
Sohtome, Tadahiro Shimazu, Yoichi Shinkai, and Mikiko Sodeoka. Acc. Chem. Res. 54, 3818-3827(2021).
254) Recent Advances on the Halo- and Cyano-Trifluoromethylation of Alkenes and Alkynes. Bo Fu,
Jorge Escorihuela, Jianlin Han, Santos Fustero, Pablo Barrio, Mikiko Sodeoka, Shintaro Kawamura,
Alexander Sorochinsky and Vadim A. Soloshonok. Molecules 26, 7221 (2021).
255) Deuterium Raman imaging for lipid analysis. Syusuke Egoshi, Kosuke Dodo, Mikiko Sodeoka. Curr.
Opin. Chem. Biol. 70, 102181 (2022).
日本語総説等256) (アレーン)トリカルボニルクロム(０) 錯体を触媒とする還元反応 -カルバサイクリン類合成への応用を中心として-.柴崎正勝, 袖岡幹子. 有機合成化学協会誌, 43, 877-890 (1985).

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257) (アレーン)トリカルボニルクロム(０) 錯体を触媒とする還元反応. 柴崎正勝, 袖岡幹子. ファルマシア, 22, 463-469 (1986).
258) (アレーン)トリカルボニルクロム(０) 錯体を用いる有機合成. 柴崎正勝, 袖岡幹子.
Organometallic News, No 2, 2-5 (1989).
259) クロムカルボニル錯体触媒の配位機能を利用した立体制御法. 袖岡幹子. 化学と工業,
216-220 (1990).
260) 遷移金属を活用した新反応の開発研究 -生物活性物質合成への応用-. 袖岡幹子. 薬学研究の進歩. 研究成果報告集 9, 1-14 (1993).
261) アレーントリカルボニルクロム 錯体を用いる高選択的合成法の開発とその医薬合成への応用. 袖岡幹子. 薬学雑誌, 114, 219-232 (1994).
262) 細胞中での遺伝子のスイッチon-offを可能にした化学. 袖岡幹子. 化学, 49, 61 (1994).
263) NF-κB p50-DNA 複合体の結晶構造. 袖岡幹子. 実験医学, 13, 1168-1171 (1995).
264) 医薬のターゲットとしてのプロテインホスファターゼ -日陰から日向へ-. 袖岡幹子. バイ
オサイエンスとインダストリー, 56, 47-48 (1998).
265) パラジウム. 袖岡幹子. ファルマシア, 36, 630-631 (2000).
266) パラジウム触媒を用いる不斉マンニッヒ型反応. 藤井章雄, 萩原恵美子, 袖岡幹子. 有機合成化学協会誌, 58, 728-735 (2000).
267) 有機合成化学から生命科学へのアプローチ. 袖岡幹子. 有機合成化学協会誌, 59, 480-481(2001).
268) 不斉アルドール反応の新たなステージ. 馬場良泰, 袖岡幹子. 化学,

56, 61-63 (2001).

269) 副作用の少ない新しい免疫抑制剤の開発をめざす研究− プロテインホスファターゼ2B選択
的な単独阻害剤の設計・合成・評価− . 袖岡幹子. 医科学応用研究財団研究報告 (Research
paper of the Suzuken Memorial Foundation) 20, 151-154 (2001).
270) Fluorine in the Life Sciences. 袖岡幹子. ファルマシア, 39, 1205 (2003).
271) エナンチオ選択的フッ素化反応の新展開. 濱島義隆, 袖岡幹子. ファルマシア, 40, 507-511(2004).
272) Development of intracellular signal transduction modulators. Mikiko Sodeoka. 日本農芸化学会誌,78, 1156-1157 (2004).
273) 低分子阻害剤によるタンパク質リン酸化の制御：構造変化と選択性. 平井剛, 闐闐孝介, 袖
岡幹子. 実験医学増刊, 23, No.4, 199-204 (651-656) (2005).
274) プロテインキナーゼC (PKC)の構造と活性化機構の解明を目指した新規C1ドメインリガン
ドの創製. 平井剛, 清水忠, 袖岡幹子. 有機合成化学協会誌, 64, 515-527 (2006).
275) パラジウム触媒による不斉フッ素化反応. 袖岡幹子, 濱島義隆. 触媒, 49, 20-24 (2007).
276) ネクローシス阻害剤の開発 − 細胞死メカニズムの解明をめざして− . 闐闐孝介, 袖岡幹子.
化学と生物 46, 478-482 (2008).
277) カチオン性10族金属錯体を用いた不斉触媒反応の新展開：パラジウムエノラートを鍵とする反応を中心にして. 濱島義隆, 袖岡幹子. TCIメール, No. 140, 2-21 (2008).
278) ヒストンメチル化酵素阻害剤(+)-Chaetocinおよび類縁体の合成と構造活性相関. 岩佐江梨子,
濱島義隆, 藤城信哉, 樋口瑛介, 伊藤昭博, 吉田稔, 袖岡幹子. Chemical Biology, vol. 3, No. 2,
8-9 (2010).
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279) 急進する芳香族トリフルオロメチル化反応開発. 袖岡幹子, 江上寛道. 化学, Vol.66, No.8,
68-69 (2011).
280) 遷移金属錯体の酸•塩基作用を利用する触媒的不斉反応の開発. 濱島義隆, 袖岡幹子. 有機合成化学協会誌, 69, 972-983 (2011).
281) ラマン顕微鏡を用いたDNA合成プローブEdUの生細胞イメージング. 山越博幸, 闐闐孝介,
Palonpon Almar, 岡田昌也, 安藤潤, 藤田克昌, 河田聡, 袖岡幹子. Chemical Biology, 4, No. 2,
2-5 (2011).
282) アルキン標識を用いた低分子化合物のラマンイメージング. 山越博幸, 闐闐孝介, 安藤潤,藤田克昌, 袖岡幹子. 実験医学 30, No. 7, 202-208 (1220-1226) (増刊) (2012).
283) 微小タグとラマン顕微鏡による小分子イメージング. 藤田克昌, 袖岡幹子. 生物物理 52,
No. 1, 34-35 (2012).
284) 有機合成・遷移金属触媒・ケミカルバイオロジー 垣根を越えて人と出会い. 袖岡幹子. 化学と工業 Vol. 66-10, 808-810 (2013).
285) 炭素-炭素二重結合のトリフルオロメチル化反応の新展開. 江上寛通, 袖岡幹子. ファルマシ
ア Vol. 50, No.1, 24-28 (2014).
286) ラマン散乱顕微鏡による生体分子イメージング. 岡田昌也, 袖岡幹子, 藤田克昌. 生化学, 86,
No. 2, 137-144 (2014).
287) C-シアロシド結合を有する糖鎖アナログ：その合成と利用価値. Go Hirai, Eisuke Ota,
Motonari Sakai, Shigeru Nishiyama, and Mikiko Sodeoka. Trends in Glycoscience and
Glycotechnology, 127, No. 154, 47-60 (2015).
288) 超原子価ヨウ素試薬を用いるアルケンの 求電子的トリフルオロメチル化反応. 河村伸太郎,
袖岡幹子. Organometallic News, No 2, 54-59 (2015).
289) アルキン標識ラマンイメージング 生体内の低分子化合物を見る, 安藤潤, どど孝介, 藤田克昌, 袖岡幹子. バイオサイエンスとインダストリー Vol. 73, No. 5, 369-373 (2015).
290) ラマン散乱を利用した細胞分子イメージング. 安藤潤, 袖岡幹子, 藤田克昌. 日本分子イメージング学会誌 9, 3-11 (2016).
291) 目的志向型ライブラリー戦略による両特異性プロテインホスファターゼ阻害剤の開発：コア
構造の改変とユニークな阻害メカニズム. 平井剛, 淺沼三和子, 土屋綾子, 袖岡幹子. 有機
合成化学協会誌, 74, 532-540 (2016).
292) 酸化ストレスによるネクローシス選択的阻害剤：細胞死研究への阻害剤の活用．闐闐孝介,
袖岡幹子．実験医学, 34, No. 7, 47-54 (1055-1062). 増刊 (2016).
293) さきがけとなる研究を. 袖岡幹子. 有機合成化学協会誌, 77, 1 (2019).
294) 虚血最灌流障害の細胞障害機序とその対策. 中尾周平, 闐闐孝介, 袖岡幹子. Coronary
Intervention, 14(6), 27-33 (2019).
295) 遷移金属エノラート種の幾何学制御 多点認識反応場の理解と制御を目指して. 五月女宜裕、袖岡幹子. ファルマシア, 55(10), (2019) “最前線”
296) 酸化ストレス誘導性ネクローシスの抑制剤開発. 闐闐孝介, 袖岡幹子. 細胞 53, 671-674(2021).

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