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1mol/L Acetic acid,JUNSEI CHEMICAL CO., LTD.,95333jis_E1-1,27/01/2014
date of issue : 27/01/2014

Safety Data Sheets

1. Identification
Product name :1mol/L Acetic acid
Name of supplier :JUNSEI CHEMICAL CO., LTD.
Address :1-6, Ohmano-Cho, Koshigaya, Saitama 343-0844, Japan
Division :Quality Assurance Department
Phone :+81-48-986-6161
FAX :+81-48-989-2787
E-mail :shiyaku-t@junsei.co.jp
Product code(SDS NO) :95333jis_E1-1

2. Hazards identification
GHS classification and label elements of the product
GHS classification(Note) GHS classification without description : Not applicable/Out of classification/Notclassifiable

3. Composition/information on ingredients
Substance/Preparation :Preparation
Ingredient name:Acetic acidcontent(%):ca. 6
Chemical formula:C2H4O2
Chemicals No, Japan:2-688
CAS No.:64-19-7
MW:60.05
HAZCODE_EU:3_H226; 1A_H314 (conc.≧90)
ECNO:200-580-7
Ingredient name:Watercontent(%):Residual quantity of the ingredient mentioned above
Chemical formula:H2O
CAS No.:7732-18-5
MW:18.02
ECNO:231-791-2

4. First-aid measures
IF INHALED
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN（or hair）
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower.
If skin irritation or rash occurs: Get medical advice/attention.
IF IN EYES :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.

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IF SWALLOWEDRinse mouth.
Call a POISON CENTER or doctor/physician if you feel unwell.

5. Fire-fighting measures
Suitable extinguishing media
Use appropriate extinguishing media suitable for surrounding facilities.
Specific hazards arising from the chemical
Containers may explode when heated.
Fire may produce irritating, corrosive and/or toxic gases.
Runoff from fire control or dilution water may cause pollution.
Special protective equipment and precautions for fire-fighters
Wear fire/flame resistant/retardant clothing.
Wear cold insulating gloves/face shield/eye protection.
Firefighters should wear self-contained breathing apparatus with full face peace operated
positive pressure mode.

6. Accidental release measures
Personnel precautions, protective equipment and emergency procedures
Ventilate area after material pick up is complete.
Wear proper protective equipment.
Environmental precautions
Avoid release to the rivers, lakes, ocean, groundwater.
Methods and materials for neutralization, containment and cleaning up
Absorb spill with inert material (dry sand, earth, et al), then place in a chemical waste
container.
Preventive measures for secondary accident
Collect spillage.

7. Handling and storagePrecautions for safe handling
Preventive measures(Exposure Control for handling personnel)
Use personal protective equipment as required.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Exhaust/ventilator
Exhaust/ventilator should be available.
Safety treatments
Avoid contact with skin.
Avoid contact with eyes.
Avoid breathing dust, vapor, mist, or gas.
Safety Measures/Incompatibility
Wear protective gloves/protective clothing/eye protection/face protection.
When using do not eat, drink or smoke.
Conditions for safe storage, including any incompatibilitiesRecommendation for storage
Keep container tightly closed.
Keep cool . Protect from sunlight.
Store in well-ventilated place.

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8. Exposure controls/personal protection
Control parameters e.g. occupational exposure limit values or biological limit values
Adopted value(Acetic acid)
ACGIH(2003) TWA: 10ppm
STEL: 15ppm (URT & eye irr; pulm func)
OSHA-PEL(Acetic acid)
TWA 10ppm, 25mg/m3
NIOSH-REL(Acetic acid)
TWA 10ppm, 25mg/m3; STEL 15ppm, 37mg/m3
Appropriate engineering controls
Do not use in areas without adequate ventilation.
Eye wash station should be available.
Washing facilities should be available.
Protective equipment
Respiratory protection
Wear positive pressure self-contained breathing apparatus (SCBA).
Hand protection
Wear protective gloves.
Eye protection
Wear eye/face protection.

9. Physical and Chemical Properties
Physical properties
Appearance :liquid
Color :colorlessodour data N.A.
pH :2.4
Phase change temperature
Initial Boiling Point/Boiling point data N.A.
Melting point/Freezing point data N.A
Decomposition temperature data N.A.
Flash point data N.A
Auto-ignition temperature data N.A
Vapor pressure data N.A
Vapor density data N.A
Relative Vapor Density (Air=1) data N.A
Specific gravity/Density data N.A
Solubility
Solubility in water :miscible
n-Octanol /water partition coefficient data N.A

10. Stability and Reactivity
Stability
Stable under normal storage/handling conditions.
Conditions to avoid
Contact with incompatible materials.
Heat.
Incompatible materials
Bases, Oxidizing agents

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Hazardous decomposition products
Carbon oxides

11. Toxicological Information
Symptoms related to the physical, chemical and toxicological characteristics
Acute toxicity
Oral toxicity component(s) data(Acetic acid)rat LD50=3310 mg/kg (PATTY 5th, 2001)
Dermal toxicity component(s) data(Acetic acid)rabbit LD50=1060 mg/kg (PATTY 5th, 2001)
Irritant properties
Skin corrosion/irritation
Skin corrosion/Irritation component(s) data
(Acetic acid)rabbit 525 mg open ; SEVERE rabbit 50 mg/24H ; MILD
Serious eye damage /irritation
Eye damage/irritation component(s) data
(Acetic acid)rabbit 50μg ; SEVERE rabbit 100 mg rinse ; MILDNo Allergenic and sensitizing effects data available
No Mutagenic effects data available
No Teratogenic effects data available
No Carcinogenic effects data available
No Toxicity for reproduction data available
No Delayed/chronic effects from short/long-term exposure data available
No Aspiration hazard data available
Additional data
There are no data available on the preparation itself.

12. Ecological Information
Ecotoxicity
Aquatic toxicity
Aquatic toxicity component(s) data(Acetic acid)
Crustacea（Daphnia magna） EC50=65 mg/L/48hr （AQUIRE, 2010）
Water solubility(Acetic acid)miscible (ICSC, 1997)
Persistence and degradability(Acetic acid)
BOD_Degradation : 74% (Registered chemicals data check & review, Japan)
Bioaccumulative potential(Acetic acid)log Pow=-0.17（PHYSPROP Database, 2005）
Additional data
There are no data available on the preparation itself.

13. Disposal Considerations
Disposal methods

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1mol/L Acetic acid,JUNSEI CHEMICAL CO., LTD.,95333jis_E1-1,27/01/2014
Dispose of contents/container in accordance with local/national regulation

14. Transport Information
UN No, UN CLASS
Not applicable to UN NO.

15. Regulatory Information
Sea pollutants control law
Noxious Liquid ; Cat. Z :Acetic acid
Non Noxious Liquid ; Cat. OSWater
The product is not applicable to GHS classifications.
US major regulations
TSCA
Acetic acid; Water
Other regulatory information
Ensure this material in compliance with federal requirements and ensure conformity to local
regulations.

16. Other information
Reference Book
Globally Harmonized System of classification and labelling of chemicals, (4th ed., 2011), UN
Recommendations on the TRANSPORT OF DANGEROUS GOODS 17th edit. UN
Classification, labelling and packaging of substances and mixtures (reg.(EC) No 1272/2008)2012 EMERGENCY RESPONSE GUIDEBOOK(US DOT)2013 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php
Supplier's data/information
Chemical Risk Information Platform (CHRIP)(NITE) http://www.safe.nite.go.jp/japan/db.html
GHS Classification Guidance for Enterprises 2013 Revised Edition （August, 2013,METI)
Other information
This information contained in this data sheet represents the best information currently
available to us. However, no warranty is made with respect to its completeness and weassume no liability resulting from its use. It are advised to make their own test
The data given here is based on current knowledge and experience. The purpose of thisSafety Data Sheet is to describe the products in terms of their safety requirements. The
data does not signify any warranty with regard to the products' properties.
The GHS classification data given here is based on currentEU official data