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48

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ῒ

ῌ 
ῌ High pCO, Spring Water in the Primorye, Far East Russia
Kenji SUGIMORI
Department of Biology, Toho University, School of Medicine+ῌ ῏ ῍ ῐ ῎   !" #$% &'()*'+), -./0123 4 5 67' 89:;<=>? @VladivostokA 6BCD=? @KhabarovskA 6EF, 89:;<=>?6GH#$ 3/* km IJ'+K6E #LMNO
EFP , -2Q #$ RST>UVWXY6EZ [\ "]^_`) #P )Q!a"F, -89:;<=>?6#$bc"d 0** km ` ef'ghi @AmurA jklEmn BCD=?6"F, 89:;<=>?6#$-BCD=?6#o'p  qrstuvhuT @PrimoryeA w @Fig. +, Photo +A xy` ,/ $ km,  _, -tuvhuTw' +** zX{|}%~&|}"') @Fig. +A, -`$()' 89:;<=>?6"'%~&|}'~"F 4'~ f'}", _$'-w'{*") ) 
{} b 4 {} +,7', .'EF, +,{}#$QtuvhuTwb"&|}~EF, _$'-w|}4b"./0 |}1'2 34. ".'`)~EF-'56"F, -¡E E ¢£9i8¤hqh 7¥¦#$§¨'2 ῌ " + gῌL zX`)} ῍ Br, I, As 85© ª"¦9«¬E)
~ ῎ CO,, H, S, Rn 8s=­("9«¬E)~ ῏ :ῌ{}:'®¯° @®
;"FA ~EF7_`),¥¦#$-w' '~ '±!a +3 ²³´µ 8=uh=? @UssuriyskA 6" B¶·¸ @Lake KhankaA '()¹º»D· @SchmakovkaA /0

/-  ,**- 5!ῌ}~4VW@V#XY  

Fig. +

Location of the Primorye, Far East Part of Russia, and sampling points of high pCO, water.

Photo +




49



Typical landscape of the Primorye.



Sicheva, A.F. !"# Bogatkov, N.M.

Avdeeva, A.B. $%&'()*+ Far East

Geological Survey, Central Institute of Health and Physiotherapy, Primorye Territorial
Geological Survey ,-./0)123 45678)19:;<9=2 <%>?* "@ABCDEFGH<2& IJ)KL"@A& Far East Geological Survey )Primorye Territorial Geological Survey M-./ NOH<PQH<2 R2  0* STU94VW@V#XYZ-.[\]^ Ushakin, E.P. $&'()*_9:;<9=2& `<%PaXbc)19defg*hij )k)&lm n+ opqrst[uV@u7E&vH<2)kwx&y R2 u8z{|#

m}W

50
Chistovodnoe  Lastochika  Gornovod-noe   Dmitrievsky  !"#

( )*+,-. /0" 12 3)/, 456"$% &!'

78$9:-; <= >?@A<=B/,=&$ Ushakin, +303 ; Chudaeva et al., +333.
")C- !"D?@"E +** F)G0%"HI=&$G JKL

E/KMHM "!N""#<=*M%&I-O#<E$I=&H&. <%< J%& '"7&=(-HP)GH/, )*+<=&$ &!,Q)R$D %0 +S%TER$GD"78$ -.)/0/,1U=&$.
V-2W "X$  D"78$Y3#4E5(6"Z7/,-G8NTR$. 2
WDE9:[;<%0\;<= >:;<%0(;<=?]"@8$D G
$ Khanchuk et al., +330. !^9:-AT _` abM5cde "
Bf$ghi Medveji6h Avdeevsky E9:\&=" J,FjAE>:(<&="Bf$.
DkT CTE456l>mῌ"]&=K

LB/,=&H&GnDTR$. D?@E%]=CEF GH"bIHoJpq"RI-K%0) 2WῌLWMNHoJOU$ rs0,$. !^ ti uPQ"vG$v+Hwxy?@"Rf$?SzTU@{|&"pf$456}W6 l>2
W~V W~" 9 +333 X 2 "`?`*&HG0J,0DO=V+$ Y-. TED,0Bf$)" J,0zWZ@[\"]&=)]f$.

, 



ti u^%0_ 3/ km Ptu^#9 /0"_4u`&"%I=_ ,** km *I- Dka&" b)cGdc<=&$eVGRI-. J,,c%09$fEg"g"'h Ei$TRk!+Hw`u&-  j i9T&M0%7k&' m lmR$eV &T&-. Jmn"E H<-¡x?GR9 J . ¢V%0opqG =&-.  jI-

fEJD%0£LT1¤r"j¥$J!TR$ Photo ,. J"f$  sEt῍¦-u§avw& <-. 456ti u¨Ex©EH&) ©
m"p<=EC RV9+yoMGH"z&T A-M/0"TSGªV,=&$D
EGH"7&<%I-D w& f. -«< Jopq«I-E " I=7M {¬­®

)"yG¯8 |&}~G <=-. D}~E Fe,° GSz/,= Fe-° "z<--U rs0,$.
±G²t³w"´U=&$oJ%0_4u`&"_ , km c0µ *`:"¶G9JD%0 + km *I-Dk")·¸G?]RI-. DeVEghi &!eVT +,+,E¹`·¸%0 <- Photo -. DD"Ee
V WºM0&fG&-G »HI=&$RE·¸G;]«8TR$K oTR$K
G/,=&H&D TR$. ·¸G;]«8HT $"{¬G%%I=&-G±ῌH¼µS"@ J&=I=&-. ["+,+,E-Uf3 /- ¼ R,**-S 7kῌ·LMLn|0¯¸©1¹2º» pq 




51   !"#$% !&'() 
*+,-./0123456780
239:;

< "+ km #$567802

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4

@

km #$D=> (*AB C

+,EF4GHI 0* cm JK2LM1NOPQ RPhoto .S "

TU4 V4!" JK2LM#$) W

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[&'(*]^)_ῌ \

`&'(  !a; b#$ ;cd44ef(g*#$hac:i1jM,MD^;Z  !k.lmn80oM4
Vpq;Z? rs,t+uMvMwq4xyz{P|!5K}~Z
 Fig. +  + , 4" 
*pq!
J8} RShmakovkaS

Photo , a : Whole view of main spring situated at theroad side in the Schmakovka Group.
b : Visiters are stu$ng their own bottols withspring waters in the semicircular roof.

 pq! Z5K} RKhankaS !4"L
MLn|" kLK RSikhote-AlinS 


J8}pqZMt

*kA ,/ km #$% `4;oK& ";]`PY '( Fig. + W - . |KLKA  ; V4* AAkL

Kh!4)

Photo -

Sampling place of Medveji Spring.

kLKh!*h%   ¡L¢M1tZ 4 V T£ ¤!¥`))¦JK
2LM1>§*¨4©  "!+ª«¬+­!",§`-¬q`* ^ `Z  ®¯)  " b°;(*±. m ²³D 4´

µ()/pqZ  RPhoto /S !s7¶K0oM RNerobinskyS 4 Vpq;Z

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52

   

  
 

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)*+'

#  !#!$,-.
/ #!+'01234'# ## 56)*+
7#!

+89

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>?@ABC)*DE' =F!
>GHIJ4K'LM$NO"! ,: 'P km QR$ TL=34 J4SUVW:TXYZU![:\ ]^ _`>I3abcd e*fgh[=P

Photo .

Sampling place of Avdeevsky Spring.

Photo /

Sampling place of Nerobinsky Spring.

i m jkQ#!$ T%
&\J>lmῌno _Bolchoi Kluchc:pq +,12,e*
rs e*t.* cm u!v "#w xy$z{( !! |% !$&}  _Photo 0c !'(~)
*+ ,-#! e*hq.'/!$-0\2:!   ZU

1M.

vTT2U!34 J4S   3T>GHIJ
4K'LM$4QM$

#! ῌM$+Q ῌM$
:k:

='LM$56'M$T:

7'#!=  UUE 89 ;== +Q!=T%&'LM$T:#_Photo 1c  T,: , <M$T:  UUE =E#!T::H4'>!T: ?2
T:E¢ 

'"#!$E@¡'A#£¤V¥'¦TM-T:






§9z=:¨!UU©'Xh#Uª TT'«:#!'ª$%&¬:E' =F b­4_Nazanc¬ 1 km :-B®
W'C!°E PDEEz$2± 2$:TX'¯  hFG²&e* G²&:,³H´µ ¶!"4 |%!$  .²&·:¸+ "!=V+! ,-.²& $IJ+ K! ¹

C /- ¼ (,**-) J.1ῌ¶@Y2·l2¸ BA¹ºB²»£ij

53



 
   !" 

#$%&' (Sodovy) *+,-  -+, ./0123456* 7 

89:;<=>?@*- ./01234ABC DBEF;G -HD 5I J.1KLM H
NOPQAB>R; S
STU V  WX
3Y23Z [\] (Lenino) *^? _!`"@"+,D;@ abcd _! - km

ebfI !?g +  +- km "4
hBij-" e!"

 " X'$kl#Imlno'p" , $q3rls%;@t" [ \ ] (Lenino- - & ' u v w \ l(Narzany)) *xcy!z{|("@-" (Photo 2) }
^? H~  !
H )

Photo 0 a : Whole view of Bulchoi Keuch Spring
situated in the forest.
b : Sampling place of Bulchoi Keuch Spring.

 *+; @      

Primorye-Central Sikhote-Aline <,<}D;@  =y!J&  !94
9!>-"@*-! , km _./"
e -  e`."@f0 1@ 
2*01; ? 
ij -" d¡3#$%&'¢@ - .£4¤- B

Photo 1 The scene of collapsed bridge on the road of
the Sikhote-Alin crossing road.

 ¥I  Qῌ @!"  [\]ῌ, (Lenino-,) ¦§@ij- (Photo 3)
./01234AB56¨©ª +,« ij@N¬­!¬789 @®¯-55d  (Photo +*) : °±v ;<-dy=%>? P²³´µ

®0¯°

54

    
ῌ !" #Nizine Luzky$%& '()*+ !" #Luzky$ ,- ./0 1 23456789:;<= >? , @A:;B.*+ 234C56789DEF G
:;1H &IJKLM
NOPQ *IR STUV:;&SWXY+ #Photo ++$SZ<= >?:;5S[\]W
XY S *+B ^_`ab #c
d -* cm$ :;ef 1ghijkl
Bmn+S op5q+>LrsRjklt1 uvwH1HY xy*+ #Photo ++$zῌ1&R

wH?+ /01{|}~
#Chuguevka$ r   +LB +p*+S5.


Fig. +  3

/01~ #Gornovodnoe$ ,.R N P¡¢3T£V¤¥¦1§¨©

#Photo +,$ 1ª«¬& ­«¬ #
Photo 2 a : Whole view of Narzany Spring (An arrowshows the origin of spring).
b : Sampling place of Narzany original spring
shown by an arrow in the photo number 2 a.

Photo 3Sampling place of Lenino-, Spring.

Photo +* Butterﬂies take minerals from the spring waterand soil (Arrows show the group of butterﬂies).

8 /- ¼ ],**- ¹­ºῌ»7RSTHSUVLWXYZ[\ !
 55  
 !" #$%& ' ()*+ ,- .)
 / 0123#456# # !

7 89:;<="5=>? @*AB<)CDEF<=GHIJE<K*
L

M'

,#N&OB"- 




PQ RSTHSUVLWXY
Z[\ !4 ]High pCO, Water^5_`B< !ab5cd
K ##&e !Yfgh ijW" #XYZ[\ !4&klmnoRSTHSUVp<qr) 

"stuUC]Chudaev, O.V.vnN
Wm  !&!w /.2x+,.1y !
z!w{WNM' #4&<+,*** m |!}"~

Photo ++ a : Borehole with hand pump of Luzky
Spring.
b : Another sampling place beside the boreholewith hand pumping of Luzky Spring.

4N<= ]Chudaev et al., ,**+" /#=< !N6 Ca-HCO4 B< Na-HCO-

 /&#$X5a !4L "!

5Nz=<&%& L '(n' !4/= CO,  C &J
E0)#N:" /  ,.0 atm. No\*+ pCO, n' pH & ..*1x
0.+2 N"XK PQ, ! pH &N6 /x0 -" PQ^_`e !4w+ pH .XZ ]DO HCO- /01+ ]electric conductivity : EC
5 Table + {" / h stuUCv<n (= +33.
daev et al., ,**+ :+333

H2 ]Chu-Table + 3"HnN  H¡¢£¤$%!w& +0./y N¥!m \ ¥&/.0x++.2y ' +33.

HN¦&B" / pH 2 ...,x0.11  HCO- *+"\" DO & *x+.. mgῌL N4§52' EC & ,,1x,,.**
mSῌcm " #&{ B RSTHSUVXYZ[\ !4.¨©6& ,-x,,+** mgῌL N !n KB¦;<=" / PQ=e !
Yfgª & +33.

HHN

Table ,ῌ+ ,ῌ, ,ῌ- ,ῌ. {" #=<2N

PQ^H5!}WN KB«&;<=B: " Cu, Ga, Ge 2ª
 & +333

^\25{" / ¬S­®¯ῌ3HsN°±²³I±U^M &´µ¶·¸Z2\" ¬S­®¯ῌ3Hs^&¥N!} Be, Al,

¸¼

56
Zn, As, Sb 

 LaEu   GdLu !"#$$%&'()*(+ ,( -./012/345 6$7Mn, Mo, Bi 

89:;<ῌ=.>?4$ @A 
 !"# $$%&'()*(+,(B20CD45

Sc, V, Cu, Sr,

U E5F>G$HI"JKL

M" N0FC3OPQ>45

Co,

Rb 7RJKLMST+ 89:;<ῌ=.>?45 6UVWXYZJ[F>G$7 
Se, Y, Ba J\ST+ .]Q>4

5

Li, Ba, V, Cr, Cu, Ga, Ge, Br, Sr JT Mo $ Cs 

7R#KLMST+ ^._`>45
Rb, Se,Sr, Cs aJ\ST Shandet al., +33/ ; Chudaeva et al., +333 ; Chudaev et al., ,**++.ῌ ῎ ῍ ῏b:Ncde9f>93ghijk
UVWXYZJlmnRIPhoto +, a and b : Sampling place of Gornovodnoe
Spring.

opqrstuvwx yz{|z}~ $5 T  P4 
gWRῌR $5T+(4

(lr T I(M"#~(Ir5M E\e9f>93ghijkUVWXYZJopqk$$ [|EF>G* ( M(¡ T+ $¢£$ UVWXYZJm#¤¥¦§Y¨© ªRJKLk y y5«¬Wk ¡\S+ E¡¡Tm ­j I\ST pH  / ®¯°

Li, Sr, U ¥¦§Y ±I ² Pb | LaEu  #KLM $,
T+ T pH  /./ ®³5EC  +,*** mSῌcm ´

T Li, Sr, Ba ¥¦§

Y a# ,T+ µR UVWXYZJ
¶g·­jk6¸|¹$7k$Co, Ni, Rb |  GdLu  # $,T+ T §Y% £$­¶º ±I5$  RI» I ­¶º #5!"#³ /- ´ ,**- ©ª«ῌ¬­UqrTqs®1Kj7¯°±PD²h3

57

Table + Water temperature, pH, DO, HCO- and electric conductivity (EC) of the high pCO,
waters in the South Primorye, Far East Russia (+333 samples)
Locality
SHMAKOVKA Group+. Medveji
Medveji (’3. sample),. Abdeevsky
Abdeevsky (’3. sample)
SHETUKHINSKAYA Group-. Nerobinsky
Nerobinsky (’3. sample).. Bolshoi Kluch
Bolshoi Kluch (’3. sample)
SAMARKA Group/. Sodovy
Sodovy (’3. sample)
LENINSKOE Group
0. Narzany
Narzany (’3. sample)
1. Lenino-,
Lenino-, (’3. sample)
CHUGUEVKA Group
2. Luzky
Luzky (borehole)
Luzky (borehole5 ’3. sample)
GORNOVODNOE Group3. Gornovodnoe
Gornovodnoe (’3. sample)

Water Temperature
§

pH

DO
mg/L

HCOmg/L

EC
mS/cm

++4.
2
+*4+
240

040.
/41.
04/*
/4+3

*
*
*
*

+5,-*
+5,+3
+*.42
+0-42

,5***
+5..1
,,1
,1,

14.
14,
24*
141

/41,
/4+/
04//422

*4,
*
*
*

+*.43
-,*41
+5.-+
+52*1

,/0
./1
+53-,5*/0

24,
14/

/40.
/4,/

*4*

-034,
.*/4/

0.1
0*2

/40
/42
242
+*4+

042/42.4.,
.43

+4.
+4+
*
*4,

+5-+1
+5.3+
+,24+//4++512.
+52/,-1
,31

++42
+04/
+-43

040,
040,
/41,

*4+4*
*4-

-3/
+512*
2/-4.

0+*
,5.**
+5+/0

341

0411
¨

*41
¨

32-4/
+5+-.

+5/0+5-0+¨ ; no data   YbῌLa  3 !"#$%& Shand et al., +33/' (& Fe, Mn, F )*+#,-. SO. /0123
456 378!9:;<=>$7' ?@1ABCD1E F7 GH-1IJK#.L@M7# N+OPQR1E S TUV $73V"#$78#6W?M&' 8XGH-1YZ[3#\]

^878#_`%

37# V<aN+OP45, F7 b1+-;<=#$c (&$7N+O
P+#defg h3i56j3%&Xkl b1)(M7N+OPmn#o;73pX`@ UqrTqstsuvB;wZxlx1y% zC?M 378#{_
M7' ?@18st19|};~#_M 37  Dalnegorsk  5

&N+OP5.j7 #$7# (;ῌ#.j7@M7' aj781y7 CD`@$7Rῌ5zC 37x
lZxw#>:  #¡¢?M7st$78V[3;3Xk £¤5¥&M 37¦D!$7'

῍ῐ῎῏

58

Table ,ῌ+ Chemical composition of the high pCO, water samples in the South Primorye, Far East Part ofRussia (Shand et al., +33/ ; Chudaeva et al., +333 and unpublished data, continued)
Locality
SHMAKOVKA Group+. Medveji,. Abdeevsky
SHETUKHINSKAYA Group-. Nerobinsky.. Bolshoi Kluch
SAMARKA Group/. Sodovy
LENINSKOE Group
0. Narzany
1. Lenino-,
CHUGUEVKA Group
2. Luzky
GORNOVODNOE Group3. Gornovodnoe

V
Zr
B
Li
mgῌL mgῌL mgῌL mgῌL

Be
mgῌL

Al
mgῌL

ND -2
2* +/0ῌ0 ῌ0 ῌ+* ,041-

/4*/
+41,

134*0 +41+ -43- +/4-3 *4,+*3,42 142/4.. *4.-

ῌ0 ῌ0
ῌ0
2

24-1 ,,*3*+41/ ,4-2 .4,0 *40+ 1.0+4-.
342 +4., +431 +-4+2 *412 34,,

0* 1-4*,+* ,/2

Cr
Co
Ni
Cu
Zn
mgῌL mgῌL mgῌL mgῌL mgῌL

Ga
mgῌL

Ge
As
mgῌL mgῌL+41+ ῌ*4*1 ῌ*4+0 ῌ*4/0-/4*+ ῌ*4*1 ῌ*4+0 ῌ*4/0*4,*4, +/241+*4*1 ῌ*4+0 +4,,

ND ῌ0 ῌ+* ,241. ῌ*4++*4+1 +4+2 /41

34/0 +4+1

04,0 ῌ*4+. ῌ*4+/*40

ῌ0 ῌ0 ῌ+* +32
ῌ0 ῌ0 ῌ+* -,4.

,423
*4-/

-,4., *42/ *41/ 2412 +4*++,0+40, 043/ +.4-1 *401

.4., ῌ*4+. ῌ*4+/,24+, ῌ*4+. ῌ*4+/

*4.1
.4*,

ῌ0 ῌ0

/* 1./*400+24,2 +420 +4+/

+04,3 ῌ*4+.

*4-, +*4+,

2+* ,0024/,.34*1 +4.

+341.

*4,.

.-

/4*/ /4/1+4., 14/- *43

*4,-

-4,.

Table ,ῌ, Chemical composition of the high pCO, water samples in the South Primorye, Far East Part ofRussia (Shand et al., +33/ ; Chudaeva et al., +333 and unpublished data, continued)
Locality

Se
Rb
Sr
Ag Mo
Cd
Sb
Cs
Ba
Ti
Pb
U
Bi
Sc
Y
mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL

SHMAKOVKA Group+. Medveji+4*0 .43/,. Abdeevskyῌ*42, ,.432
SHETUKHINSKAYA Group-. Nerobinskyῌ*42, 04,3.. Bolshoi Kluchῌ*42, .4..
SAMARKA Group/. Sodovy
ῌ+*43
LENINSKOE Group
0. Narzanyῌ+,.4*+
1. Lenino-,ῌ+/4-2
CHUGUEVKA Group
2. Luzkyῌ+1423
GORNOVODNOE Group3. Gornovodnoe
ῌ*42, 142,1/, ῌ*4+. ῌ*4., ῌ*4*/+*. ῌ*4+. ῌ*4., ῌ*4*/*4+, *4//*4*2 *4+0,-- ῌ*4+. *413 +4,.,,3* ῌ*4+. ῌ*4., ῌ*4*/*4+3 ,41++,4, ῌ*4*/ 24*3 *4+/ ῌ*4*2 ῌ*42 +*40*4+, *4-+ -,-,, ῌ*4*/ ῌ*4+ *4, ῌ*4*2 ῌ*42 ,4.-

3*, ῌ*4+, ῌ*4-/ ῌ*4*2 ῌ*4+. *4-/12431 ND ῌ*4++-,
*4*2 *4++*0*4/, ῌ*4*2 *4/, ῌ*4*2 ῌ*42

ND ῌ*4+/ ῌ*4*3 ῌ*4+/

,4,2
*4,-

*42

*4,

,,,/* ῌ*4+, ῌ*4-/ *4*2 ῌ*4+. 14++ +,-., ῌ*4++,+0 ῌ*4+, ῌ*4-/ ῌ*4*/ ῌ*4+. -4+/,*42 ῌ*4++*4./ *4++ ῌ*4+/ ῌ*42
*4, ῌ*4*3 ῌ*4+/ ῌ*42

+422
*43

,,,,* ῌ*4+,+4*1*4*3 ῌ*4+. +4*+

.--

ῌ*4++

*4-/

*4,- ῌ*4+/

+40

,431

+,3/* ῌ*4+.

.4/.

*4*/ ῌ*4*2 ++4+1

+,1

ῌ*4*/

*4+.

.42 ῌ*4*2+4/ ,+4/.

 /-!,**-" ῌ



59

Table ,ῌ- Chemical composition of the high pCO, water samples in the South Primorye, Far East Part ofRussia (Shand et al., +33/ ; Chudaeva et al., +333 and unpublished data)
Locality
SHMAKOVKA Group+. Medveji,. Abdeevsky
SHETUKHINSKAYA Group-. Nerobinsky.. Bolshoi Kluch
SAMARKA Group/. Sodovy
LENINSKOE Group
0. Narzany
1. Lenino-,
CHUGUEVKA Group
2. Luzky
GORNOVODNOE Group3. Gornovodnoe

Na
K
Ca
Mg
SO.
Cl
F
Br
I
Si
Fe
Mn
mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL

,3
,+4/

+40. ,+2
1041.41- ++4/ 1400

*430
-4*.

+4.
*40

*433
*4.3

*4*+1 *4**. -+4/
*4**0 *4**,. ,/43

+0*4.2243/ *4,1/

+24,
0-4.

+4., //42 /4,0,431 .+.,41

14+
34,2

*4/
+4.

.
*4*2

*4*++ *4**+3 ,04+
*4*++ *4**,/ ,,4.

,/
+.40

,+

*43/

14-+ +4+2

1/4/

,,42

34+,

*43

*4+

*4*++

-+4-4*3 --/341 *4,
,,4+

0.4,
+*42

+1
.42.

,4,
*43

*4.3
*4,/

*4*+. *4**, ,.4*4*+- *4**,2 ,,4-

,*4/
+/4,

*430/
*4..2

2.4/

-43 +0+++43 *4,

-4-

*4*3

*4*+- *4**,.

+/

-*4-

*42/2

/24/

,4+2 -*-

+2

-4/

+4+

*4**3 *4**+2 ,,4.

+,4+

.4,,

,14,

*4**,

+14+

+4,+4+2

Table ,ῌ. Chemical composition of the high pCO, water samples in the South Primorye, Far East Part ofRussia (Shand et al., +33/ ; Chudaeva et al., +333 and unpublished data, continued)
Locality
SHMAKOVKA Group+. Medveji,. Abdeevsky
SHETUKHINSKAYA Group-. Nerobinsky.. Bolshoi Kluch
SAMARKA Group/. Sodovy
LENINSKOE Group
0. Narzany
1. Lenino-,
CHUGUEVKA Group
2. Luzky
GORNOVODNOE Group3. Gornovodnoe

La
Ce
Pr
Nd Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL mgῌL*4+/ *4-- *4*- *4+1 *4*0 *4*, *4*0 *4*, *4+, *4*- *4+/ *4*. *4,+ *4*.
*4*. *4*0 *4*, *4*. *4*2 *4*. *4*+ *4*, *4*- *4*, *4*, *4*, *4*, *4*,+4-. ,40/*4.. *4/1*4-+ +4/, *4.2
*4*1 *4-, *4,0

*4*3 *4+3 *4*, 2*4*, *42/ *4+0*4+. *4+2 *4*-*4*/ *4*,*4*- *4*+

+4+1
*4,+

*4,1
*4*.

*42,
*4+.

*4+
*4*+

*40
*4*2
*4+- *4*,*4*- *4*,*4*, *4*+*4*+ *4*,*4, *4,2*4,1 *4/3*4*- *4,/ *4+*4*3 *4.3 *4+.

*4*. *4*3*4*- *4+2*4**4*,

*4+/
*4+.

*4*.
*4*-

*4+,
*4*3

*4*+
*4*+

*4+, *4*,*4*2 *4*,*4/. +4,1*4+, *4/+ *4-+

*4+, *4-

*4*-

*4-,

*4*1

*4,-

*4*-

*4,.

*4*.

*4,2 *4//*4*3 *4/3 *4.-

*4,

*4,2

,4,/

*4/2

,4*1

*4-

,4,/

*4-1

+4+/

FGHI

60

῎

῍



   Russian Academyof Science, Far East Geological Institute, Oleg Chudaev  Russian Academy of
Science, Paciﬁc Institute of Geography, Valentina Chudaeva  ! "#$῏ῌ%&'()*( (Chudaeva), +.,., %&'()*, -.+., %)./010*, ,.2., 3'4&/'5,
6.7. and 8(/', 9. (+333) : 7:/);(.</=) +0'= 9;:40;<> (Mineral
Waters of Prymorye). +1, p, ?(.</(&1( · +.(':*05@01
Chudaev, O.V., Chudaeva, V.A., Sugimori, K., Nagao, K., Takano, B., Matsuo, M., Kuno, A. andKusakabe, M. (,**+) : New geochemical data of the high pCO, waters of Primorye (Far
East Russia). Proceedings of Water Rock Interaction +*th (by Cidu, R. ed.) Vol. +, .1-ῌ.10,
Balkema, Lissa
Khanchuk, A.I., Ratkin, V.V., Ryazantseva, M.D., Golozubov, V.V. and Gonokhova, N.G. (+330) :Geology and Mineral Deposits of Primorsky Kray. 0+ p, Dalnauka, Vladivostok
Shand, P., Edmunds, W.M., Chudaeva, V.A., Lutsenko, T.N., Chudaev, O.V. and Chelnokov, A.
N. (+33/) : High pCO, cold springs of the Primorye region, Eastern Russia. Proceedings ofWater Rock Interaction 2th (by Kharaka, Y. and Chudaev O.V. ed.), -3-ῌ-30, Balkema,
Rotterdam
Ushakin E.P. ed. (+303) 9;:40;51:A 1;(A (Primorye Teritory) B:';0C)0.
0C:> DDDE (Hydrogeology of USSR, vol. XXV), /,* p, 7. 2)';(, 7051*((Moscow)