Time Table
9:00

June 4 (Sun.)

June 5 (Mon.)

June 6 (Tue.)

Invited Lecture 1
David Nicewicz

Invited Lecture 9
Michael Haley

Invited Lecture 2
Daniele Leonori

Invited Lecture 10
Manabu Abe

Invited Lecture S-1
Takashi Koike

Invited Lecture S-5
Ryohei Kishi

Coffee BreakCoffee BreakInvited Lecture 3
Burkhard König

Invited Lecture 11
Chunyan Chi

Invited Lecture 4
Xinyuan Liu

Invited Lecture 12
Takashi Kubo

Invited Lecture S-2
Corinna Schindler

Invited Lecture S-6
Shingo Ito

12:00

Invited Lecture S-3
Hongli Bao

Invited Lecture S-7
James Blinco

13:00

Lunch

Lunch

Invited Lecture 5
Steven Bottle

Plenary Lecture 2
Michelle Coote

10:00

11:00

14:00

Registration

15:00

Invited Lecture S-4
Yang Yang

Invited Lecture S-8
Tetsuro Kusamoto

Invited Lecture 7
Sungwoo Hong

Invited Lecture S-9
Nobuhiro Yanai

Invited Lecture 8
Ching-Wen Chiu
Opening

16:00

Invited Lecture 6
Derek A. Pratt

Plenary Lecture 1
Ilhyong Ryu

Coffee BreakCoffee BreakInvited Lecture 13
Aiko Fukazawa

PosterInvited Lecture 14
John Murphy
Invited Lecture S-10
Chen Zhu
Invited Lecture S-11
Hideki Yorimitsu

17:00

Welcome Party

Invited Lecture S-12
Louis Fensterbank

June 7 (Wed.)
Invited Lecture 15
Armido Studer

June 8 (Thu.)
Plenary Lecture 3
Corey Stephenson

Invited Lecture 16
Samir Zard

June 9 (Fri.)
Invited Lecture 25
Song Lin

9:00

Invited Lecture 26
Troels Skrydstrup

Invited Lecture S-13
Takuji Kawamoto

Invited Lecture S-16
Lei Jiao

Invited Lecture S-5
Jie WuCoffee BreakCoffee BreakCoffee BreakInvited Lecture 17
Philippe Renaud

Invited Lecture 19
Hirohisa Ohmiya

Invited Lecture 27
Shunsuke Chiba

Invited Lecture 18
Emmanuel Lacôte

Invited Lecture 20
Guosheng Liu

Invited Lecture 28
Qian Zhang

Invited Lecture S-14
Yi-Feng Wang

Invited Lecture S-17
Michael James

Closing

Invited Lecture S-15
Ullrich Jahn

Invited Lecture S-18
Takashi Nishikata

12:00

Lunch

Lunch

13:00

10:00

11:00

Invited Lecture 21
Brett Fors
Invited Lecture 22
Atsushi Goto

14:00

Invited Lecture S-19
Antoine Debuigne
Invited Lecture S-20
Tomoko Yajima
Coffee Break

15:00

Invited Lecture 23
Cyrille Boyer
Invited Lecture 24
Hideyuki Otsuka

16:00

Invited Lecture S-21
Chi-How Peng
Invited Lecture S-22
Takeo Suga
Invited Lecture S-23
Didier Gigmes

Banquet17:00

Oral Presentations

June 4 (Sun.)
16:00-16:45 Plenary Lecture 1

Radical Ways for Selective Functionalization of C-H and C=C Bonds

Ilhyong Ryu (Osaka Metropolitan University/ National Yang Ming Chiao Tung University)

June 5 (Mon.)
9:00-9:25 Invited Lecture 1

New Avenues in Synthesis via Organic Photoredox Catalysis
David Nicewicz (University of North Carolina at Chapel Hill)
9:25-9:50 Invited Lecture 2

Novel Synthetic Methods Using Halogen-Atom Transfer and Photoexcited Nitroarenes
Daniele Leonori (RWTH Aachen University)

9:50-10:10 Invited Lecture S-1

Radical Fluoroalkylation Reactions by Highly Reducing Organic Photocatalysts
Takashi Koike (Nippon Institute of Technology)
10:10-10:40 Coffee Break
10:40-11:05 Invited Lecture 3

Light-induced Radical Polar Cross Over Reactions
Burkhard König (University of Regensburg)
11:05-11:30 Invited Lecture 4

Chiral Anion/Cu-Catalyzed Enantioconvergent Radical Cross-Couplings
Xinyuan Liu (Southern University of Science and Technology)

11:30-11:50 Invited Lecture S-2

New Cycloadditions of Carbonyls and Imines
Corinna Schindler (University of Michigan)

11:50-12:10 Invited Lecture S-3

Asymmetric Outer-Sphere Radical Reactions

Hongli Bao (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science)
12:10 – 13:30 Lunch
13:30-13:55 Invited Lecture 5

What’s Solvent Got to Do with It?

Steven Bottle (Queensland University of Technology)
13:55-14:20 Invited Lecture 6

No HAT Required! Radical-Trapping Antioxidants Can Inhibit Lipid Peroxidation andAssociated Cell Death by Multiple Radical Mechanisms
Derek A. Pratt (University of Ottawa)
14:20-14:40 Invited Lecture S-4

New Strategies for Stereoselective Radical Biocatalysis
Yang Yang (University of California, Santa Barbara)
14:40-15:05 Invited Lecture 7

Site-Selective Pyridine C–H Functionalization under Visible Light Irradiation
Sungwoo Hong (KAIST)

15:05-15:30 Invited Lecture 8

Synthesis and Reactivity of a Di-Substituted Boron Radical Cation
Ching-Wen Chiu (Department of Chemistry, National Taiwan University)
15:30-16:00 Coffee Break
16:00-18:00 Poster Session

June 6 (Tue.)
9:00-9:25 Invited Lecture 9

Tuning Diradical Properties in Diindenoarenes
Michael Haley (University of Oregon)
9:25-9:50 Invited Lecture 10

Is π-Single Bonding (C–π–C) Possible? A Challenge in Organic Chemistry
Manabu Abe (Hiroshima University)
9:50-10:10 Invited Lecture S-5

Theoretical Study on Structures of Unpaired Electrons in Open-Shell Systems
Ryohei Kishi (Osaka University)
10:10-10:40 Coffee Break
10:40-11:05 Invited Lecture 11

Novel Pi-Structures with Open-Shell Singlet Diradical Character
Chunyan Chi (National University of Singapore)
11:05-11:30 Invited Lecture 12

Nature of Electron-Electron Coupling in Carbon-Carbon Contacts Beyond 2 ÅTakashi Kubo (Osaka University)

11:30-11:50 Invited Lecture S-6

Azahomocorannulene and Azadihomocorannulene Radical(oid)s
Shingo Ito (Nanyang Technological University)
11:50-12:10 Invited Lecture S-7

Bipolar Isoindoline Nitroxide Materials for Nonaqueous Redox Flow Batteries
James Blinco (Queensland University of Technology)
12:10 – 13:30 Lunch
13:30-14:20 Plenary Lecture 2

Non-Radicals as Radicals, Radicals as Non-Radicals, and Protons as Initiators
Michelle Coote (College of Science and Engineering, Flinders University)

14:20-14:40 Invited Lecture S-8

Spin-correlated Photoluminescence of Assembled Open-Shell Molecules
Tetsuro Kusamoto (Osaka University)
14:40-15:00 Invited Lecture S-9

Generation and Spin Polarization of Radicals By Photoexcitation
Nobuhiro Yanai (Kyushu University)
15:00-15:30 Coffee Break
15:30-15:55 Invited Lecture 13

Exploring the Cross-Conjugated π-Electron Systems with Robustness toward MultiElectron Reduction
Aiko Fukazawa (Kyoto University)

15:55-16:20 Invited Lecture 14

Assaying Radical Pathways

John Murphy (University of Strathclyde)
16:20-16:40 Invited Lecture S-10

Late-Stage Modification of Complex Alkenes by Radical Rearrangements
Chen Zhu (Chemical Engineering and Materials Science, Soochow University)
16:40-17:00 Invited Lecture S-11

Reductive Metalation of Unsaturated Bonds by Taming Radical Anions
Hideki Yorimitsu (Kyoto University)
17:00-17:20 Invited Lecture S-12

Organometallic Catalysis under Visible LightLouis Fensterbank (Sorbonne University)

June 7 (Wed.) (Dennis Curran Sympo.)
9:00-9:25 Invited Lecture 15

Boron an Emergent Element in Radical Chemistry
Armido Studer (Westfälische Wilhelms-University Münster)
9:25-9:50 Invited Lecture 16

Radical Stability in Aid of Efficiency. Convergent Routes to Organoboron Compounds
Samir Zard (Ecole Polytechnique)9:50-10:10 Invited Lecture S-13

Radical Reactions for Introducing 1,1,2,2,3,3-Hexafluoropropylenamide Groups
Takuji Kawamoto (Yamaguchi University)

10:10-10:40 Coffee Break
10:40-11:05 Invited Lecture 17

Radical Chain and Photocatalyzed Reactions
Philippe Renaud (University of Bern)

11:05-11:30 Invited Lecture 18

Visible-Light Radical Photopolymerizations Initiated by NHC–Boryl Radicals
Emmanuel Lacôte (CNRS - Université Claude Bernard Lyon 1)

11:30-11:50 Invited Lecture S-14

Boryl Radicals Enabled Selective Activation of Carbon-Heteroatom Bonds
Yi-Feng Wang (University of Science and Technology of China)
11:50-12:10 Invited Lecture S-15

From Phenolics to Alkaloids – Bioinspired Radical Total Syntheses

Ullrich Jahn (Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences)
12:10 – 13:30 Lunch

June 8 (Thu)
9:00-9:50 Plenary Lecture 3

Redox Catalysis Strategies for Complex Molecules
Corey Stephenson (University of Michigan)
9:50-10:10 Invited Lecture S-16

N-Boryl Pyridyl Anion and Its Application in Radical Chemistry
Lei Jiao (Tsinghua University)
10:10-10:40 Coffee Break
10:40-11:05 Invited Lecture 19

Radical N-Heterocyclic Carbene Catalysis
Hirohisa Ohmiya (Kyoto University)
11:05-11:30 Invited Lecture 20

Site- and Enantioselective sp3 C-H Functionalizations via Copper-Catalyzed Radical
Relay
Guosheng Liu (Shanghai Institute of Organic Chemistry, CAS)

11:30-11:50 Invited Lecture S-17

Electron-catalysed Nucleophilic Hydroxylation Through Reagent Design
Michael James (The University of Manchester)

11:50-12:10 Invited Lecture S-18

Chemoselective Borylation at Sterically Congested Position by a Photoredox Catalyst
Takashi Nishikata (Yamaguchi University)

12:10 – 13:30 Lunch
13:30-13:55 Invited Lecture 21

On Demand Switching of Polymerization Mechanism
Brett Fors (Cornell University)

13:55-14:20 Invited Lecture 22

Control in Radical Polymerization via Halogen Bonding
Atsushi Goto (Nanyang Technological University)
14:20-14:40 Invited Lecture S-19

Radical Polymerization of Methylene Heterocyclic Compounds Towards Novel
Functional and Responsive Polymers
Antoine Debuigne (Liege University)

14:40-15:00 Invited Lecture S-20

Photoinduced Synthesis of Fluorine-Containing Organic Compounds
Tomoko Yajima (Ochanomizu University)
15:00-15:30 Coffee Break
15:30-15:55 Invited Lecture 23

Nanostructure Control in 3D Printing through Polymerization Self-Assembly Process
Cyrille Boyer (UNSW Sydney)

15:55-16:20 Invited Lecture 24

Radical-type Mechanofunctional Dynamic Covalent Polymers
Hideyuki Otsuka (Tokyo Institute of Technology)
16:20-16:40 Invited Lecture S-21

Reversible-deactivation Radical Polymerization of Vinyl Acetate Mediated By Schiff Base
Derivatives
Chi-How Peng (National Taiwan University)

16:40-17:00 Invited Lecture S-22

Photo-active Polymeric Dormant: Design and Application to Precise UV-Curing
Takeo Suga (WASEDA University)

17:00-17:20 Invited Lecture S-23

Development of Peroxide Alternatives

Didier Gigmes (Aix-Marseille University/CNRS)

June 9 (Fri.)
9:00-9:25 Invited Lecture 25

Electrochemistry as an Enabling Tool for Organic Reaction Discovery
Song Lin (Cornell University)

9:25-9:50 Invited Lecture 26

Recent Developments in Carbonylation Reactions Involving Radical Intermediates
Troels Skrydstrup (Aarhus University)

9:50-10:10 Invited Lecture S-24

Toward On Demand Synthesis of Organic Small Molecules
Jie Wu (Department of Chemistry, National Singapore University)
10:10-10:40 Coffee Break

10:40-11:05 Invited Lecture 27

Polysulfide Anion Photocatalysis for Chemical Synthesis
Shunsuke Chiba (Nanyang Technological University)

11:05-11:30 Invited Lecture 28

New Methods for C–N Bonds Formation Based on Radical Intermediate
Qian Zhang (Northeast Normal University)

Poster Presentations

June 5 (Mon.) 16:00-18:00
Synthesis_01

1

Defluoroarylation of Trifluoromethylarenes Using Photoredox Catalyst andOrganostannanes

Naoki Sugihara1, Masayuki Abe1, Yoshihiro Nishimoto1, 2, Makoto Yasuda1,2 (1. Graduate School ofEngineering, Osaka University, 2. Innovative Catalysis Science Division, Institute for Open andTransdisciplinary Research Initiatives (ICS-OTRI), Osaka University)

2

3
4
5

Visible-Light-Enabled Intramolecular Aminopyridylation of Alkenes

Yejin Koo1,2, Sungwoo Hong2,1* (1. Department of Chemistry, Korea Advanced Institute of Science andTechnology (KAIST), 2. Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic
Science (IBS))

Catalytic Formal Carbyne Transformation of Phosphorus Ylides

Taiga Ando, Ryuhei Suzuki, Kosuke Ohmatsu, Takashi Ooi (Nagoya University)

Photoredox Catalyzed Radical Alkene Group Transfer

Floriane Baussiere, Marius Myreng Haugland (UiT the Arctic University of Norway)

Synthesis of Cyclic and Linear Fluoroalkyl Aromatics by Photoinduced Reaction of
Aromatics and 1,4-Diiodoperfluorobutane

Airi Yamaguchi, Tadashi Kanbara and Tomoko Yajima (Ochanomizu University)

6

Generation of Functionalized Alkyl Radicals via the Direct Photoexcitation of 2,2’(Pyridine-2,6-diyl)diphenol-Based Borates

Yusuke Miyamoto1, Yuto Sumida*2, Hirohisa Ohmiya*1 (1. Institute for Chemical Research, Kyoto
University, 2. Division of Pharmaceutical Sciences, 2. Graduate School of Medical Sciences, Kanazawa
University)

789Photoinduced Decarbonylative 1,3-Migration of Bicyclo[2.2.2]octenones

Gary Jing Chuang (Chung Yuan Christian University, Department of Chemistry)

Diastereoselective Direct Functionalization of Pyrrolidine Derivatives

Shoma Chiba1, Kokoro Nowaki, Bumpei Maeda, Kei Murakami (Kwansei Gakuin University)

Radical Cascades Involving Sequential C–H Bond Activations

Lise Benoist ,Éléonore Barbier, Mariam Sangare, Philippe Renaud*, Fabrice Dénès* (University ofBern, Department of Chemistry, Biochemistry and Pharmaceutical Sciences, Switzerland)

10 Reductive C–C Bond Cleavage of 1,2-Diaryl-1,2-diborylethanes by Means of Sodium
Mizuki Fukazawa, Fumiya Takahashi, Hideki Yorimitsu (Department of Chemistry, Graduate School of
Science, Kyoto University)

11 Enantioselective Copper-Catalyzed FUKUYAMA Indole Synthesis from 2Vinylphenyl Isocyanides

Till Drennhaus1, Dirk Leifert1, Jessika Lammert1, Jan P. Drennhaus2, Klaus Bergander1, Constantin G.
Daniliuc1, Armido Studer1 (1. Organisch-Chemisches Institut, Westfälische Wilhelms-Universität
Münster, Germany, 2. Department of Physics and Astronomy, KU Leuven, Belgium)

12 Triple Photoredox/Cobalt/Brønsted Acid
Hydroalkoxylation of Unactivated Alkenes

Catalysis

Enabling

Markovnikov

Masanari Nakagawa1, Yuki Matsuki2, Kazunori Nagao*1, and Hirohisa Ohmiya*1 f(1. Institute for
Chemical Research, Kyoto University, 2. Division of Pharmaceutical Sciences, Graduate School of
Medical Sciences, Kanazawa University)

13 Copper-Catalyzed Three-Component Coupling Reaction of Terminal Alkenes with
Trimethylsilyl Azide and Cyclic Ethers via the Radical Pathway
Yuichi Ikemoto1, Sho Chiba1, Zhenyao Li1, Hiroki Mori2, Yasushi Nishihara2 (1. Graduate School of
Natural Science and Technology, Okayama University, 2. Reserch Institute for Interdisciplinary Science,
Okayama University)

14 Denitrogenative Annulation Reactions of 1,2,3,4-Benzothiatriazin-1,1(2H)-dioxides
with Arynes via Formation of Diradical Species
Jen-Chieh Hsieh (Tamkang University)

15 Switchable Synthesis of ammonium Salts via α-ammonio Radical

Takumi Kinoshita, Yota Sakakibara, Kei Murakami (Kwansei Gakuin University)

16 Retro-1,2-Brook Rearrangement Induced by the Reduction of Silyl Enol Ethers

Ban Kinoshita, Fumiya Takahashi, Hideki Yorimitsu (Department of Chemistry, Graduate School of
Science, Kyoto University)

17 Decarboxylative Pyridylation of Carboxylic Acid with External Oxidant Free
Photocatalytic System
Changha Kim1,2, Sungwoo Hong*2,1 (1. Korea Advanced Institute of Science and Technology (KAIST),
2. Institute of Basic Science (IBS))

18 α -Amino Acid and Peptide Synthesis Using Catalytic Cross-Dehydrogenative
Coupling
Ryo Yazaki1, Taro Tsuji1, Kayoko Hashiguchi1, Mana Yoshida1, Tetsu Ikeda1, Yunosuke Koga1, Yusaku
Honda1, Tsukushi Tanaka1, Suyong Re2, Kenji Mizuguchi2,3, Daisuke Takahashi1, Takashi Ohshima1 (1.
Kyushu University, 2. NIBIOHN, 3. Osaka University)

19 Mechanochemistry Enabling Air-Tolerant and Highly Efficient Birch Reduction With
Sodium Lump

Keisuke Kondo1, Koji Kubota1,2, Hajime Ito1,2 (1. Division of Applied Chemistry, Graduate School ofEngineering, Hokkaido University, 2. Institute for Chemical Reaction Design and Discovery, Hokkaido
University)

20 Photocatalytic, Automated Synthesis of Tetrahydronaphthyridines
Qiao Cao , Alexander J Cresswell (University of Bath)

21 Ester Hydrogenolysis via β-C-O Bond Cleavage Catalyzed by a Phenanthroline-Based
PNNP-Cobalt(I) Complex

Yumiko Nakajima*1,2, Heng Zhang2, Yoshihiro Shimoyama2 (1. School of Materials and Chemical
Technology, Tokyo Institute of Technology, 2. Interdisciplinary Research Center for Catalytic Chemistry,
National Institute o Advanced Industrial Science and Technology (AIST))

22 Visible-Light-Induced Defluorofunctionalization of Trifluoromethylarenes

Mingshuo Chen, Xiaoping Chen, Xiaheng Zhang* (University of Chinese Academy of Sciences)

Polymer

23 Microphase-separation Using Multifunctional Polymeric Dormants
Shuhei Abe, Kenichi Oyaizu, Takeo Suga (Waseda University)

24 Synthesis of Topological Block Polymers by Organotellurium-Mediated Emulsion
Polymerization in Water
Yuhan Jiang, Masatoshi Tosaka, and Shigeru Yamago (Institute for Chemical Research, Kyoto
University)

25 Radical (Co)Polymerization of Vinylboronic Acid Derivatives and Subsequent
Deprotection for Synthesis of Vinyl Polymers Bearing Boronic Acid on Backbone

Takuma Kawada, Tsuyoshi Nishikawa, Makoto Ouchi (Graduate School of Engineering, Kyoto
University)

26 Enhancing Triethylborane Initiation through Mechanistic Understanding Using a
Novel Radical Trapping TechniqueIvan Ocana, Andrew Rickard, Victor Chechik (University of York)

27 Selection of Halogen Endgroups of Photo-active Polymeric Dormants to Control
Nanodomains in UV-Cured Coatings
A. Mochizuki, M. Iwakiri, K. Oyaizu, T. Suga (Department of Applied Chemistry, Waseda University)

28 Synthesis of Structurally Controlled Dendritic Hyperbranched Polyacrylates by
TERP and Their Rheological Properties

Tianxiang Tong, Masato Kibune, Masatoshi Tosaka, Yumi Matsumiya, Hiroshi Watanabe, Shigeru
Yamago(Institute for Chemical Research, Kyoto University)

29 Polymerization Chemistry of Vinylboronic Acid Derivatives: Boron-Based Monomer
Design Leading to Post-Polymerization Transformation of Side-Chain Element
Tsuyoshi Nishikawa, Makoto Ouchi (Kyoto University)

30 Microphase Separation of Polymer RAFT agents via controlled UV-curing

Nana Suzuki, Kenichi Oyaizu, Takeo Suga (Department of Applied Chemistry, Waseda University)

Bio

31 The Fate of Lipid-Derived Alkoxyl Radicals and Their Role in Oxidative Cell Death
Dmitry D. Saraev (University of Ottawa)

32 Development of GBM-targeted Prodrug Responsive to Free Radicals Inducing ROS

Yoon Kyung Park, Dokyoung Kim* (Department of Biomedical Science, Graduate School, Kyung Hee
University)

33 Design and Synthesis of Mechanistic Probes for Deoxypodophyllotoxin Synthase
Catalyzed Carbon-carbon Bond Formation
Tun-Cheng Chien (National Taiwan Normal University)

34 Aminic and Phenolic Organoseleniums as Lipid Peroxyl Radical-Trapping Agents

Vijay P. Singh (Department of Chemistry & Centre for Advanced Studies in Chemistry, Panjab
University)

35 Iron-silicate-coated Porous Silicon Nanoparticles for Cancer Therapy via Hydroxyl

Radical Generation

Hyeji Um, Dokyoung Kim* (Department of Biomedical Science, Graduate School, Kyung Hee
University)
Synthesis_02

36 Reductive Borylmetallation of Styrenes Using Flow Microreactors

Kazuki Nishihara, Yiyuan Jiang, Takashi Kurogi, Hideki Yorimitsu (Kyoto University)

37 Deaminative Borylation and Hydrodeamination
Radical/Radical Ion Intermediatesof Aromatic Amines

via

Kohei Sekine1,2, Akira Shiozuka2, Takumi Toki2, Kyohei Kawashima1, Toshifumi Mori1,2, Yoichiro
Kuninobu1,2 (1. Institute for Materials Chemistry and Engineering, Kyushu University, 2.
Interdisciplinary Graduate School of Engineering Sciences, Kyushu University)

38 Facilitating [2+2] Photocycloadditionsby Promoting Oxygen Tolerance and Substrate
Activation in Water

Julian C. G. Kürschner, Linda Brüss, Line Næsborg (University of Münster WWU, OrganischChemisches Institut)

39 Electrochemical Synthesis of Diarylsultone via Dehydrogenative C – O Bond
Formation

Yasuyuki Okumura, Koichi Mitsudo, Seiji Suga (Division of Applied Chemistry, Graduate School of
Natural Science and Technology, Okayama University)

40 Photo-induced C–H Bond Thiocyanation and One-Pot Isothiocyanation
Bunpei Maeda1, Yusuke Aihara2, Ayato, Sato2, Toshinori Kinoshita2, Kei Murakami1 (1. Graduate
School of Science and Engineering, Kwansei Gakuin University, 2. Institute of Transformative BioMolecules (WPI-ITbM), Nagoya University)

41 Photocatalytic Generation and Downstream Reactivity of alpha-Amino Radical
SpeciesAndrew Maitland, Darren Dixon (University of Oxford)

42 Light-Driven Radical-Polar
Organosilanes

CrossoverCatalysisfor

Cross-Couplingwith

Tomotoki Matsuo, Kazunori Nagao*, Hirohisa Ohmiya* (Institute for Chemical Research, Kyoto
University)

43 Highly Selective Hydrogenation of C=C Bonds Catalyzed by a Rhodium Hydride

Yiting Gu,1,3 Jack R. Norton,1 Farbod Salahi,2 Vladislav G. Lisnyak,2 Zhiyao Zhou,2 Scott A. Snyder2(1. Department of Chemistry, Columbia University, 2. Department of Chemistry, University of Chicago,
3. Current Address: Frontier Institute of Science and Technology (FIST), Xi’an Jiaotong University)

44 Visible-Light-Induced Radical Carboamination of Styrenes with Carboxylic Acids
and (Diarylmethylene)aminobenziodoxolones
Daichi Okumatsu, Kensuke Kiyokawa, Satoshi Minakata (Department of Applied Chemistry, Graduate
School of Engineering, Osaka University)

45 Site-Selective Pyridylic C–H Functionalization by Photocatalytic Radical Cascades

J. Kim1,2, S. Hong*2,1 (1. Departmentof Chemistry, Korea Advanced Institute of Science and Technology(KAIST), 2. Centerfor Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS))

46 Electrochemical [3+2] Cycloaddition Reactions in Laminar Flow Microreactor

Kazuhiro Okamoto, Naoki Shida, Mahito Atobe (Department of Engineering, Yokohama National
University)

47 Copper-catalyzed Radical Cascade Reaction of Cyclobutanes: Synthesis of Highly
Functionalized Cyclobutene Derivatives
Chunyang Liu, Yan Li, Qian Zhang (Department of Chemistry, Northeast Normal University)

48 Synthesis of tert-Alkylphosphonate Oligonucleotides through Light-Driven RadicalPolar Crossover

Kenji Ota1, Kazunori Nagao1, Dai Hata2, Naoya Miyamoto2, Ryosuke Tokunoh2, Yusuke Sasaki2,
Hirohisa Ohmiya1 (Institute for Chemical Research, Kyoto University, 2. Research, Takeda
Pharmaceutical Company Limited)

49 Convergent Radical Decarboxylative and Deboronative Phosphorylation Enabled by
Novel Phosphite Radical Trap

Santosh K. Pagire, Chao Shu, Dominik Reich, Adam Noble, Varinder K. Aggarwal* (School ofChemistry, University of Bristol)

50 Iron-catalyzed Synthesis of Alpha-Azido Amino Acids: An Easy Access to Versatile
Building Blocks

Pierre Palamini, Jerome Waser (École Polytechnique Fédérale de Lausanne, Laboratory of Catalysis andOrganic Synthesis)

51 Radical Caging Strategy for Cholinergic Optopharmacology

Rikako Nakamura1, Takeru Yamazaki2, Yui Kondo3, Miho Tsukada3, Yusuke Miyamoto1, Nozomi
Arakawa3, Yuto Sumida3*, Taketoshi Kiya4, Satoshi Arai2*, Hirohisa Ohmiya1* (1. Institute for
Chemical Research, Kyoto University, 2. WPI Nano Life Science Institute (NanoLSI), Kanazawa
University, 3. Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa
University, 4. Division of Life Sciences, Graduate School of Natural Science and Technology, Kanazawa
University)

52 Cross-Coupling of Chiral Amino Acid Chlorides and Hydrocarbons Enabled by
Mechanistically Controlled Nickel/Photoredox Dual Catalysis
Beomsoon Park, Soon Hyeok Hong* (Korea Advanced Institute of Science and Technology)

53 Diastereoselective Synthesis of Congested b-Amino Ketone via N-Heterocyclic
Carbene-Catalyzed Radical–Radical Coupling
Yukiya Sato1, Yuto Sumida2, Hirohisa Ohmiya1 (1. Institute for Chemical Research, Kyoto University,
2. Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University)

54 Novel Synthetic Methods using Photoexcited Nitroarenes

Raquel Sanchez1‡, Rory Mykura2‡, Vincent Duong1, Lucrezia Angelini1, Rodrigo Carbajo3, Josep
Llaveria4, Alessandro Ruffoni*2 and Daniele Leonori*2 (1. Department of Chemistry, University ofManchester, 2. Institute of Organic Chemistry, RWTH Aachen University, 3. In Silico Discovery &External Innovation, Therapeutics Discovery, Janssen Research & Development, 4. Global Discovery
Chemistry, Therapeutics Discovery, Janssen Research & Development)

55 Visible-Light-Induced Bromoperfluoroalkylation of Olefins Catalyzed by 10Phenylphenothiazine
Koto Tagami, Tomoko Yajima (Ochanomizu University)

PhysicalOrganic

56 Modelling Radical Ions: New Stability Scale and Machine Learning Representation
Stiv Llenga, Ganna Gryn'ova (Heidelberg Institute for Theoretical Studies (HITS gGmbH))

57 Synthesis and Electronic Properties of Pyrene-Containing Tetraazacyclophane

Yuna Funato1, Hiroyuki Fueno2, Akira Koshio1, and Akihiro Ito1 (1. Department of Applied Chemistry,Mie University, 2. Department of Molecular Engineering, Kyoto University)

58 Hole-catalyzed Transformations of a Silicon-Silicon Triply Bonded Compounds
Shintaro Ishida, Daichi Yanagisawa, Takeaki Iwamoto (Tohoku University)

59 Design and Synthesis of Nitroxide Radicals having SOMO-HOMO Energy
Conversion
Ayaka Itasaka, Manabu Abe* (Department of Chemistry, Graduate School of Advanced Science andEngineering, Hiroshima University)

60 Conformational Tuning Improves the Stability of Spirocyclic Nitroxides with Long
Paramagnetic Relaxation Times
Mateusz Piotr Sowinski1, Sahil Gahlawat1, Bjarte Aarmo Lund1, Anna Luisa Warnke1, Kathrin Helen
Hopmann1, Janet Eleanor Lovett2, Marius Myreng Haugland1 (1. UiT The Arctic University of Norway,
2. University of St Andrews, UK)

61 Synthesis, Structures, Electrochemical and Optical Properties of Vinyl-Extended
Tetrathiafulvalene Functionalized Two 2,6-dicyano-l5-Phosphinine Units

Tomoya Misaki1, Aya Yoshimura,1 Takashi Shirahata,1,2 Minoru Hayashi,1 Yohji Misaki*1,2 (1. Grad.
Sch. Sci. Eng., Ehime University, 2. RU:E-USE, Ehime University)

62 Phosphorus-centered Radicals for the Synthesis of P-Chirogenic Organophosphorus
Compounds
Toshiaki Murai, Ryota Wada, Koji Iwata, Yuuki Maekawa (Gifu University)

63 Electronic Structures of Doubly Bridged Bis(triarylamine) Radical Cations

Ryota Yabuuchi1, Fumiya Takasaki2, Masashi Uebe2, Akira Koshio1, Akihiro Ito1 (1. Department ofApplied Chemistry, Mie University, 2. Department of Molecular Engineering, Kyoto University)

64 Reversible Radical Generation System Operated by Visible Light
Anna Vasilevska1,2, Tomas Slanina1 (1. IOCB Prague, 2. Charles University)

65 Open-Shell Germylene Stabilized by a Phenalenyl-Based Ligand

Takuya Kodama, Kenta Uchida, Chihiro Nakasuji, Ryohei Kishi, Yasutaka Kitagawa, Mamoru Tobisu(Osaka University)

66 Structure-Property Relationships of Fluorescent Radical Precursors for Detecting
Polymeric Mechanoradicals
Takumi Yamamoto, Hideyuki Otsuka (Tokyo Institute of Technology)

67 Synthesis of Diarylamines with Nitrosonium ion

Pin-Hsien Chen, Duen-Ren Hou (National Central University)

68 Synthetic Study on Thiophosphoryl Radical by Sulfidation of an Isolable Phosphinyl
Radical
Yusuke Yoshida, Shintaro Ishida, Takeaki Iwamoto (Graduate School of Science, Tohoku University)

Material

69 Imidazole-annelated Benzoquinone-Type Organic Anolytes for Aqueous Redox Flow
Battery
Tsuyoshi Murata, Marina Hamasaki, Yasushi Morita (Aichi Institute of Technology)

Synthesis_03

70 Late-stage
α-C(sp3)–H
Pharmaceuticals

Functionalizationof

Trialkylamine-containing

Yangyang Shen1,3, Ignacio Funez-Ardoiz2, Franziska Schoenebeck,*2 Tomislav Rovis*1 (1. Departmentof Chemistry, Columbia University, 2. Institute of Organic Chemistry, RWTH Aachen University, 3.
Current Address: Frontier Institute of Science and Technology (FIST), Xi’an Jiaotong University)

71 Visible Light-Mediated Radical Difunctionalization with N-Aminopyridinium Salts

Sanghoon Shin1,2, Sungwoo Hong*2,1 (1. Department of Chemistry, Korea Advanced Institute of Scienceand Technology (KAIST), 2. Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic
Science (IBS))

72 Substituent Effects of Methoxy Group on Reactivity and Solid-State Magnetic
Property of 2,2-Diphenylquinoline-N-oxyl Derivatives
Msaomi Takii, Youhei Miura, Naoki Yoshioka (Faculty of Science and Technology, Keio University)

73 Photoredox/Cobalt-Catalyzed Markovnikov Selective Hydrohalogenation of Alkene

Shotaro Shibutani, Kazunori Nagao, Hirohisa Ohmiya (Institute for Chemical Research, Kyoto
University)

74 2-Silylated Dihydroquinazolinone as Photocatalytic Energy Transfer Enabled
Radical Hydrosilylation Reagent
Tatsuhiro Uchikura, Haruka Nakamura, Takahiko Akiyama (Gakushuin University)

75 Hydroperfluoroalkylation of Unactivated Alkenes

Gulsana Sissengaliyeva, Elena Pruteanu, Fabrice Dénès, Philippe Renaud (Department of Chemistry,
Biochemistry and Pharmaceutical Sciences, University of Bern)

76 Low-Valent Titanium-Mediated Alcohol C–O Bond Homolysis

Takuya Suga, Yuuki Takahashi, Chinatsu Miki, Yutaka Ukaji (Kanazawa University)

77 Selective Defluoroaminoxylation of Perfluoroalkylarenes Mediated by Organic
Photocatalyst

Naoki Sugihara1, Yoshihiro Nishimoto*1,2, Makoto Yasuda*1,2 (1. Department of Applied Chemistry,
Graduate School of Engineering, Osaka University, 2. Innovative Catalysis Science Division, Institutefor Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University)

78 Discovery of Molecule-Induced Radical Formation (MIRF) Reactions of Benzynes

Alexander J. Stewart1, Jia Hao Pang2, Shunsuke Chiba2, John A. Murphy*1 (1. University of Strathclyde,
2. Nanyang Technological University)

79 Photocatalytic Deuterium Atom Transfer Deuteration of Electron-Deficient Alkenes
with High Functional Group Tolerance

Akihiko Suzuki1, Yuji Kamei1, Masaaki Yamashita1, Yusuke Seino1, Yuto Yamaguchi1, Tatsuhiko
Yoshino1, Masahiro Kojima1, Shigeki Matsunaga1, 2 (1. Faculty of Pharmaceutical Sciences, Hokkaido
University, Japan, 2. Department of Chemistry, Graduate School of Science, Kyoto University, Japan)

80 Visible-Light-Mediated Reduction and Borylation of Aryl Chlorides Catalyzed byOrganic Aluminum Complex

Yoshihiro Nishimoto1,2, Ryota Takahashi1, Takuma Miyamura3, Yasuko Osakada3,4, Mamoru Fujitsuka4,
Manabu Abe2, Makoto Yasuda1,2 (1. Graduate School of Engineering, Osaka University 2. Innovative
Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI),
Osaka University 3. Graduate School of Advanced Science and Engineering, Hiroshima University 4.
Institute for Advanced Co-Creation Studies, Osaka University 5. SANKEN (The Institute of Scientificand Industrial Research), Osaka University)

81 Persulfate-Mediated Oxidative Glycosylation of p-Methoxyphenyl Glycosides as
Novel Glycosyl Donors
Eunbin Jang, Hoe In Kim, Jaehoon Sim (College of Pharmacy, Kyung Hee University)

82 Total Synthesis of Batrachotoxin

Yuuki Watanabe, Hisahiro Morozumi, Hiroyuki Mutoh, Koichi Hagiwara, Masayuki Inoue (Graduate
School of Pharmaceutical Sciences, The University of Tokyo)

83 Bifunctional 1-Hydroxypyrene-Photocatalyst for Hydrodesulfurization via Reductive
C(aryl)–S Bond Cleavage

Di Wu1, Akira Shiozuka1, Kohei Sekine1,2, Yoichiro Kuninobu1,2 (1. Interdisciplinary Graduate Schoolof Engineering Science, Kyushu University, 2. Institute for Materials Chemistry and Engineering,
Kyushu University)

84 Azido-Alkynylation of Alkenes Through Radical-Polar Crossover

Julien Borrel, Jerome Waser (Laboratory of Catalysis and Organic Synthesis (LCSO), Institute ofChemical Sciences and Engineering (ISIC), EPFL)

85 Reductive anti-Dizincation of Alkynes

Haruka Yamaguchi, Fumiya Takahashi, Takashi Kurogi, Hideki Yorimitsu* (Department of Chemistry,
Graduate School of Science, Kyoto University)

86 Aminoacylation of Alkenes by Cooperative NHC and Photoredox Catalysis

Lena Lezius, Jannik Reimler, Dr. Nadine Döben, Prof. Dr. Armido Studer (University of Münster)

87 Intramolecular Hydrogen Atom Transfer Hydroarylation of Alkenes Using CobaltPhotoredox Catalysis
Yuto Yamaguchi1, Yusuke Seino1, Akihiko Suzuki1, Yuji Kamei1, Tatsuhiko Yoshino1, Masahiro
Kojima*1, Shigeki Matsunaga*1,2 (1. Hokkaido University, 2. Kyoto University)

88 Functionalization of Alkenylammonium Salts Enabled by Photo Redox Catalyst
Aoi Yoshita, Yota Sakakibara, Kei Murakami (Kwansei Gakuin University)

89 Cobalt-Catalyzed
Nucleophiles

Enantioselective

Hydrofunctionalizationof

Alkenesand

Ge Zhang (Northeast Normal University)

90 Generation of Vinylic Lithium Species from Silyl Enol Ethers

Ziwei Zhang, Fumiya Takahashi, Takashi Kurogi, Hideki Yorimitsu (Department of Chemistry,
Graduate School of Science, Kyoto University)

91 Synthesis of Block Copolymer Grafted Silica Nanoparticles by SI NMP for The Design
and The Characterization of Tyre Nanocomposite Models

Maxime Blanchard*1 ,2, Marine Bonnevide2, Nicolas Malicki2, Marc Couty2, Trang N.T. Phan1, Didier
Gigmes1 (1. Aix-Marseille University, Institut de Chimie Radicalaire (UMR7273), 2. Manufacture
Française des Pneumatiques Michelin)