CONTENTS
P03 • 1. Welcome Message
P04 • 2. Organization
P05 • 3. Acknowledgements
P07 • 4. General Information
P11. Floor Plan
P13. Floor Plan of Exhibition Area
P14 • 5. Scientific Program
P14 Program at a Glance
P15 Detailed ProgramP35 • 6. Abstracts
P55 • Poster Session

1

2

Welcome Message
On behalf of the organization community, we would like to extend our warmest welcome to invite
all delegates from all over the world to attend the 8th Asian Conference on Coordination
Chemistry (ACCC8), which is held on August 7-11, 2022 in National Taiwan University, Taipei,
Taiwan, and organized by National Tsing Hua University, National Taiwan University, Chemical
Society Located in Taipei, Taiwan Bioinorganic Chemistry Society and co-organized by Academia
Sinica.
The Asian Conference on Coordination Chemistry (ACCC) is the largest and most reputableregional conference in Asia focusing on the area of coordination chemistry. The aims of theconference are to provide a forum for coordination chemists from all over the world to gather
together and present their most recent research findings and to offer a stimulating atmosphereto discuss and exchange ideas on the most frontier research topics in coordination chemistry.
The conference also serves to showcase the fast development of coordination chemistry in Asia.
The conference is devoted to the recent advances and new trends in coordination chemistry
including electronic structures and bonding of metal complexes, supramolecular chemistry,organometallic chemistry, bioinorganic chemistry, metal catalysis, small molecule activation,functional coordination compounds for materials science, biomedical science and environmental
science and energy, as well as other emerging topics in coordination chemistry.
ACCC has long been an important information-sharing platform in the chemistry field. This year,
we bring you not only renowned speakers and experts; we also present you with an in-depth andenriched scientific program. We sincerely hope you can join us in learning the latest research andperspectives, share knowledge and actively participate in advancing the field of coordination
chemistry in Asia.
Although we have been facing the challenge of the Covid-19 pandemic since 2019, the adversity
can bring us together against such difficulties. ACCC8 is held as a hybrid conference, it allows theparticipants around the world to join the meeting online, thus shortening the distance ofcommunication between all of us.
This symposium consists of plenary lectures, keynote lectures, invited lectures, oral presentations
and online poster presentations (including short talk presentations, optional). Moreover, an oralpresentation session is planned especially for young researchers (graduate students,
postdoctoral researchers, and young researchers from industry) to encourage their activity.
We appreciated your participation. Enjoy ACCC8 in Taipei during August 7-11.
Hope you could find some new perspectives and inspirations on coordination chemistry.

Yi-Chou Tsai

Ching-Wen Chiu

Chen-Hsiung Hung

Way-Zen Lee

Chair, ACCC8

Co-chair, ACCC8

Co-chair, ACCC8

Co-chair, ACCC8National Tsing Hua University

National Taiwan University

Academia Sinica

National Taiwan Normal University

3Organization
Conference Chair
Yi-Chou TsaiNational Tsing Hua University

Conference Co-chairs
Ching-Wen Chiu

National Taiwan University

Chen-Hsiung Hung

Academia Sinica

Way-Zen Lee

National Taiwan Normal University

Organizing Committee
Chun-Hung Kuo

National Yang Ming Chiao Tung University

Lan-Chang Liang

National Sun Yat-sen University

Chia-Her Lin

National Taiwan University

Po-Heng Lin

National Chung Hsing University

Hsueh-Ju Liu

National Yang Ming Chiao Tung University

Shie-Ming Peng

National Taiwan University

Biing-Chiau Tzeng

National Chung Cheng University

Masahiro Yamashita

Tohoku University

4

Acknowledgements
The Organizing Committee of 8th Asian Conference on Coordination Chemistry (ACCC8 2022) would liketo acknowledge and express our sincere gratitude to the following organizations and companies for theirgreat support:

Organizers

National Tsing Hua
University

National Taiwan
University

Taiwan Bioinorganic
Chemistry Society

Chemical Society
Located in Taipei

Co-organizer

Institute of Chemistry, Academia Sinica

Government & Academic Organizations

Ministry of Science andTechnology

Taiwan Bioinorganic
Chemistry Society

National Tsing Hua University

Institute of Chemistry,
Academia Sinica

Ministry of Education
5

Department ofInformation and Tourism,
Taipei City Government

National Taiwan
University

Exhibitions & Sponsors

MICROTRAC BEL Corp.

DKSH TAIWAN Ltd.

ACS Publications-The Journal of
Organometallics

Nova Materials Co., Ltd.

ZIMMERMAN SCIENTIFIC CO., LTD

ADVANCED EDUCATIONTECHNOLOGY CORPORATIONACS Publications

TechMax Technical Co., Ltd.

Royal Society of Chemistry

Agilent Technologies, Inc.

Chang Chun Petrochemical
Co.,Ltd.

Note: The sponsors and exhibition logos are listed in the amount of the payment.

6General Information
Conference
Date: Sunday, August 7 - Thursday, August 11, 2022
Venue: Boya Lecture Building, National Taiwan University
Address: No. 1, Sec. 4, Roosevelt Road, Taipei, 10617 Taiwan R.O.C.

Registration
Date

Operating Hours

Sunday, August 7, 2022

16:00 – 18:00

Monday, August 8, 2022

08:10 – 17:00

Tuesday, August 9, 2022

08:10 – 17:00

Wednesday, August 10, 2022

08:10 – 17:00

Thursday, August 11, 2022

08:10 – 12:00

Venue: Main Entrance, 1F, Boya Lecture Building

Name Badge
All delegates are required to wear their official name badges at all times in the meeting venues.
Individuals will be identified as follows:
Yellow badge

Chair / Co-chair / Organizing Committee

Red badge

Speaker / Session ChairBlue badge

Delegate

Green badge

Exhibitor

Grey badge

Staff

Official Language
The official language of ACCC8 2022 is English

7

LunchLunch boxes will be provided by showing the badge.
Date

Time

Monday, August 8, 2022

12:30 – 14:00

Tuesday, August 9, 2022

12:30 – 14:00

Wednesday, August 10, 2022

12:30 – 14:00

Venue: Hallway, 1F, Boya Lecture Building

Refreshments
Date

Time

Monday, August 8, 2022

10:40 – 11:00
15:30 – 15:50

Tuesday, August 9, 2022

10:40 – 11:00
15:30 – 15:50

Wednesday, August 10, 2022

10:40 – 11:00
15:30 – 15:50

Thursday, August 11, 2022

10:00 – 10:30

Venue: Hallway, 1F, Boya Lecture Building

Secretariat Office & Speaker’s Ready Room
Date

Operating Hours

Sunday, August 7, 2022

16:00 – 18:00

Monday, August 8, 2022

08:10 – 17:00

Tuesday, August 9, 2022

08:10 – 17:00

Wednesday, August 10, 2022

08:10 – 17:00

Thursday, August 11, 2022

08:10 – 12:00

Venue: 2F, Room 203&204, Boya Lecture Building

8

Social Programs
Event

Date

Time

Venue

Opening Ceremony

Sunday, August 7, 2022

17:00-17:15

Room 101, Boya Lecture Building

Welcome Reception

Sunday, August 7, 2022

18:00-20:00

Hallway, 1F, Boya Lecture Building

Conference Banquet

Wednesday, August 10, 2022

18:30-20:30

Ballroom 1, 3F, Caesar Metro Taipei

Closing Ceremony

Thursday, August 11, 2022

12:00-12:15

Room 101, Boya Lecture Building

Excursion

Thursday, August 11, 2022

12:15-14:00

DalongDong Baoan Temple,
Taipei Confucius Temple

Welcome Reception
Date: Sunday, August 7, 2022
Time: 18:00-20:00
Venue: Hallway, 1F, Boya Lecture Building
Dress Code: Smart casual※ All attendees who registered for the ACCC8 2022 are cordially invited to the Welcome
Reception.

Conference Banquet
Date: Wednesday, August 10, 2022
Time: 18:30-20:30
Venue: Ballroom 1, 3F, Caesar Metro Taipei
Dress Code: Smart casual
Transportation: Shuttle bus service is provided as follows:

Time

From

To

18:00

National Taiwan University

Caesar Metro Taipei

20:30

Caesar Metro Taipei

National Taiwan University※ Departure: Meet up in front of the entrance of New Moon Pavilion, National Taiwan
University.

9

Excursion
Date: Thursday, August 11, 2022
Time: 12:15-14:00
Destination: DalongDong Baoan Temple & Taipei Confucius Temple
Lunch: Lunch boxes will be provided on the bus.
Reservation Only: Admission is only for those who confirmed with the Secretariat before theConference.
Transportation: Shuttle bus service is provided as follows:

Time

From

To

12:20

National Taiwan University

DalongDong Baoan Temple

13:40

Taipei Confucius Temple

National Taiwan University※ Departure: Meet up in front of the entrance of New Moon Pavilion, National Taiwan
University at 12:20.

DalongDong Baoan Temple & Taipei Confucius Temple
Taipei Confucius Temple was built in the early 1880s, damaged several decades later, andreconstructed in 1925 by the crème de la crème of carpenters from Quanzhou, China. The
absence of words in the temple venerates the Confucian disdain of pompous drivel. This class2 national historic site reflects a rare level of artistic achievement. The two-month Baosheng
Cultural Festival (April-May) held here features an array of traditional art performances. Baoan
Temple is a UNESCO Asia-Pacific Heritage Award recipient.

Taipei Confucius Temple

DalongDong Baoan Temple

10Floor Plan

11

12

Floor Plan of Exhibition Area
Venue: Hallway, 1F, Boya Lecture Building
Date

Operating Hours

Monday, August 8, 2022

10:40 – 17:00

Tuesday, August 9, 2022

08:40 – 17:00

Wednesday, August 10, 2022

08:40 – 17:00

Thursday, August 11, 2022

08:40 – 11:30

Layout of Exhibition Area

Exhibitors List
Booth No.

Exhibitor

1

Nova Materials Co., Ltd.

2

MICROTRAC BEL Corp. / DKSH TAIWAN Ltd.

3

ZIMMERMAN SCIENTIFIC CO., LTD

4

ACS Publications

5

ADVANCED EDUCATION TECHNOLOGY CORPORATION

13

Memo

Detailed Program
Sunday, August 7, 2022
17:00-17:15

Opening Ceremony (1F, Room 101)

Plenary Session 1 & ACCC Award 1(Functional Materials)
17:15-18:00
Chair
17:15-18:00

18:00-20:00

1F, Room 101
Shie-Ming Peng
From simple discrete metal-ligand motifs to
PL-01
supramolecular assembly, nanostructures and functions

Vivian Wing-Wah Yam

Welcome Reception (Hallway, 1F)

Monday, August 8, 2022
Plenary Session 2(Magnetic Materials)
08:40-09:25
Chair
08:40-09:25

1F, Room 101
Masahiro Yamashita
Switchable molecular materials based on valence tautomerism
PL-02
and spin crossover

Colette Boskovic

Organometallic Chemistry
09:30-12:30
Chair

1F, Room 102
Ching-Wen Chiu
A Tetrahedral and High-Spin TiII Ion

09:30-10:00

KL-01

10:00-10:20

IL-01

10:20-10:40

IL-02

10:40-11:00

Coffee Break, 1F Hallway

11:00-11:20

IL-03

11:20-11:40

IL-04

11:40-12:00

IL-05

12:00-12:30

KL-02

Heterometallic Clusters with U-M Bonds Supported by
Double-Layer N-P Ligands
Si–Cl Bond Cleavage Induced by an Iron Complex Bearing a
Phenanthroline-Based PNNP Ligand
Reversible CO2 /CO conversion by a homogeneous copperbased molecular catalyst
Highly Stereoselective Palladium-Catalyzed C-F Bond
Functionalization of gem-Difluoroalkenes
Pd-Catalyzed Stereospecific Cross Coupling of
Organoboron Compounds to Access Chiral 𝜶-Aryl
Carbonyl Compounds
Recent Advance in the Chemistry of Low-Coordinate LowValent Transition-Metal Complexes
15

Daniel J. Mindiola
Congqing Zhu
Yumiko Nakajima

Arnab Dutta
Gavin Chit Tsui

Hong Geun Lee
Liang DengSupramolecular Chemistry
09:30-10:40
Chair

1F, Room 103
Norman Lu

09:30-10:00

KL-04

Water-Soluble Molecular Architectures

Partha Sarathi
Mukherjee

10:00-10:20

IL-11

Managing inequality: helical fluxionality of metallohelicate

Dongwhan Lee

10:20-10:40

IL-12

Confinement of unfolding and refolding proteins in an M12L24
coordination cage

10:40-11:00

Coffee Break, 1F Hallway
1F, Room 103

11:00-12:30
Chair

Takahiro
NakamaShih-Sheng Sun

11:00-11:20

IL-13

11:20-11:40

IL-14

11:40-12:00

IL-15

12:00-12:30

KL-05

Dynamics of Gold Rings and Boxes
Metallo-molecular containers with open/close functions basedon [CoIII(saloph)] scaffolds
Highly phosphorescent Pd(II) complexes with metal-metal-toligand charge-transfer excited states in fluid solutions
Non-coulombic ionic crystals created via metalloligand
approachJohn Yip
Shigehisa Akine
Wei LuTakumi Konno

Metal Organic Frameworks
2F, Room 201

09:30-12:30
Chair

Biing-Chiau Tzeng

09:30-10:00

KL-07

Metal-Organic Frameworks (MOFs)-Driven Carbon Neutral
Society: Heterogeneous Catalysis, Membrane Separation, andPower Generation

Chia-Wen (Kevin)Wu

10:00-10:20

IL-21

Metal-organic cage assemblies for gel engineering

Shuhei Furukawa

10:20-10:40

IL-22

Ionic Metal–Organic Frameworks (iMOFs) Based Sequestrationof Environmental Pollutants for Water Remediation

10:40-11:00

Coffee Break, 1F Hallway

11:00-11:20

IL-23

11:20-11:40

IL-24

11:40-12:00

IL-25

12:00-12:30

KL-08

Sujit Kumar
Ghosh

Rapid Structural Transformation and Functional Application of
Chia-Her Lin
Defect Al-MOFs
Stimuli-responsive Metal-organic Frameworks Showing Unique
Ryotaro Matsuda
Molecular Adsorption and Conversion
Coordination Polymers for Naked-Eye Multi-responsive
Jaursup Boonmak
Chromism and Luminescent Applications
Microenvironment Modulation in Metal-Organic FrameworkHai-Long Jiang
Based Catalysis

16

Functional Materials
2F, Room 202

09:30-12:30
Chair

Jiann-Tsuen Lin
Molecular functionalization as a powerful approach to Cu2O
photocatalytic activity enhancement
Helical Metal-Metal Interactions Boost Circularly Polarized
Luminescence
Development of coordination compounds for electrochemicalenergy-storage devices

09:30-10:00

KL-10

10:00-10:20

IL-31

10:20-10:40

IL-32

10:40-11:00

Coffee Break, 1F Hallway

11:00-11:20

IL-33

11:20-11:40

IL-34

11:40-12:00

IL-35

12:00-12:30

KL-11Lanthanide-Sensitized Optoelectronic Functions of Lead Halide
Perovskites
Functional Coordination Polymers Based on Redox-Active
Tetrathiafulvalene and its Derivatives
Porous Ionic Crystals Based On Polyoxometalates
As A Tunable Platform For Functional Materials
Progress in Phosphor Materials and Future Perspectives

MichaelHuang
Youngmin You
MasashiOkubo

Ayumi Ishii
Jing-Lin Zuo
Sayaka Uchida
Ru-Shi Liu

Organometallic Chemistry
1F, Room 102

14:00-16:30
Chair

Lan-Chang Liang
Rare-earth metal phosphinidene complexes: from dinuclear ones
to mononuclear and terminal ones
Cp*Rh(III)/chiral Lewis base hybrid catalysis for enantioselective
C–H functionalization

14:00-14:30

KL-03

14:30-14:50

IL-06

14:50-15:10

IL-07

Catalytic enantioselective construction of Si-stereogenic silanes

15:10-15:30

IL-08

Dinuclear Cobalt Complexes for Electrochemical Water Oxidation:
Tuning Rate and Overpotential Through the Redox Non-Innocent Yu-Heng Wang
Ligand

15:30-15:50

Coffee Break, 1F Hallway

15:50-16:10

IL-09

16:10-16:30

IL-10

Base-Promoted Perfluoroalkylation of Rhodium Porphyrin
Complexes with Perfluoroalkyl Iodides
Radical delocalization enables the stabilization of a high-spin
threecoordinate Fe(III) imidyl complex

17

Yaofeng Chen
Tatsuhiko
YoshinoChuan He

Ching Tat To
Chun-Yi Lin

Other Topics in Coordination Chemistry
1F, Room 103

14:00-15:30
Chair

Minghuey Shieh

14:00-14:30

KL-06

Coordination Chemistry at the Crossroads

Andy Hor

14:30-14:50

IL-16

Spin State Switching in Dynamic Molecular Materials

Sanjit Konar

14:50-15:10

IL-17

Rational Design of Electrocatalyst for CO2 Reduction

Abhishek Dey

15:10-15:30

IL-18

Zinc-Salophen Complexes as New Building Blocks for Photovoltaic
Applications

Hsien-Hsin
Chou

15:30-15:50

Coffee Break, 1F Hallway

Supramolecular Chemistry
1F, Room 103

15:50-16:30
Chair

Yi-Tsu Chan

15:50-16:10

IL-19

Kinetic Effects of Catenane Ligands in Transition Metal
Catalysis

Ho Yu Au-Yeung

16:10-16:30

IL-20

Application of porphyrins in new generation solar cells

Chen-Yu Yeh

Metal Organic Frameworks
2F, Room 201

14:00-16:30
Chair

Jing-Yun Wu
Postsynthetic modifications of metal–organic frameworks andtheir applications
Metal-organic frameworks incorporating high-density acidic
sites for effective ammonia capture
Electrically Conductive Metal-Organic Framework Nanosheets
Created at Air/Liquid Interfaces
Metal–Organic Frameworks for Polymer Adsorption and
Separation

14:00-14:30

KL-09

14:30-14:50

IL-26

14:50-15:10

IL-27

15:10-15:30

IL-28

15:30-15:50

Coffee Break, 1F Hallway

15:50-16:10

IL-29

New organic-inorganic hybrid metal phosphates for foodsafety and environmental applications

16:10-16:30

IL-30

Stimuli-responsive porous metal–organic crystals

18

Myoung Soo Lah
Chang Seop Hong
Rie Makiura
Nobuhiko
HosonoChih-Min Wang
Hiroshi Sato

Catalysis, Energy and Small Molecule Activation
2F, Room 202

14:00-15:30
Chair

Mizuki Tada

14:00-14:30

KL-12

Alkane hydroxylation catalyzed by late transition-metal
complexes

14:30-14:50

IL-36

Water Oxidation with Metal Porphyrins

14:50-15:10

IL-37

15:10-15:30

IL-38

15:30-15:50

Coffee Break, 1F Hallway

Rui Cao

Potent Methane Oxidation Catalyst Achieved by Close Stackingof Double-Decker-Type Iron Phthalocyanine Complex on
Graphite Surface
Inorganic Nanocatalysts to Enhance Hydrogenation Reactions
toward Sustainable Materials Transformations

Yasuyuki Yamada
Miho Yamauchi

2F, Room 202

15:50-16:30
Chair

Shinobu ItohYu-Heng Wang

15:50-16:10

IL-39

Orange-red fluorescent polycyclic cinnolino[2,3-f]
phenanthridin-9- ium salts by palladium(II)-catalyzed C－Hbond activation

Shih-Ching
Chuang

16:10-16:30

IL-40

Photocatalytic Water Splitting and CO2 Reduction

Ken Sakai

Rising Star Award(Magnetic Materials)
1F, Room 101

16:35-17:05
Chair
16:35-17:05

Masahiro Yamashita
Spin Manipulation in Magnetic Molecules

Shang-Da Jiang

Plenary Session 3(Electronic Structures and Bonding of Metal Complexes)
1F, Room 101

17:05-17:50
Chair

Andy Hor

17:05-17:50

PL-03

Non-innocence of coordinated ligands. Electronic structure
and Reactivity

Goutam Kumar Lahiri

Poster Session 1 (online)
online18:00-20:00

19

Tuesday, August 9, 2022
Plenary Session 4(Bioinorganic Chemistry and Biomedical Diagnostics)
1F, Room 101

08:40-09:25
Chair
08:40-09:25

Ching-Wen Chiu
PL-04

Carbenium Ions as Z-type Ligands

François Gabbaï

Organometallic Chemistry
1F, Room 102

09:30-10:40
Chair

Munetaka Akita
Group 6 metal complexes featuring metal─germanium triple
bonds: synthesis, reactivity, and catalysis
Linear correlation between the equilibrium constant andhalf-wave potential of cobalt complexes in cobalt-mediatedradical polymerization
Vanadyl Complex-mediated Self-assembly and Radical Type
Cross Coupling Reactions

09:30-10:00

KL-13

10:00-10:20

IL-41

10:20-10:40

IL-42

10:40-11:00

Coffee Break, 1F Hallway

Chi-How Peng
Chien-Tien Chen

1F, Room 102

11:00-12:30
Chair

Hisako Hashimoto

Hsueh-Ju Liu

11:00-11:20

IL-43

11:20-11:40

IL-44

11:40-12:00

IL-45

12:00-12:30

KL-14

Luminescent gold complexes that change structure uponmechanical stimulation
Mismatched donor-acceptor pairs: serendipitous structuraland reaction chemistryCompetence of Diborene Compounds in Small Molecules
Activation and Catalytic Hydroboration

Lan-Chang Liang

Organometallic molecular switch driven by redox stimuli

Munetaka Akita

20

Hajime Ito

Cheuk-Wai So

Catalysis, Energy and Small Molecule Activation
1F, Room 103

09:30-10:40
Chair

Takahiko Kojima
Synthesis and Operando Characterization of Pt-Bimetallic Oxygen
Reduction Catalysts for Polymer Electrolyte Fuel Cell
Development of metal halide perovskites and vanadium
complexes for artificial photosynthesis and plastics upcycling
Tailoring the Photoluminescence of Atomically Precise Ligand
Protected Metal Nanoclusters

09:30-10:00

KL-16

10:00-10:20

IL-51

10:20-10:40

IL-52

10:40-11:00

Coffee Break, 1F Hallway

Mizuki Tada
Han Sen Soo
Manzhou Zhu

1F, Room 103

11:00-12:30
Chair

Yunho Lee

11:00-11:20

IL-53

11:20-11:40

IL-54

11:40-12:00

IL-55

Molecular catalysts for photochemical and electrochemical
conversions of ubiquitous small molecules
Uncoordinated Groups as Functional Units of Metal-Organic
Frameworks
Molecular assembly at photocatalyst-mediator interface towardZ-scheme water splitting reaction

Shigeyuki
Masaoka
Wei ShiAtsushi
Kobayashi

Functional Materials
12:00-12:30

KL-17

Photo-catalysis with Earth Abundant Metal Complexes. Excited
State Dynamics and Application Studies

Chi-Ming Che

Electronic Structures and Bonding of Metal Complexes
2F, Room 201

09:30-10:40
Chair

Yi-Chou Tsai

09:30-10:00

KL-19

From Metal-Metal Multiple Bonds to Helical Metal Strings

Shie-Ming Peng

Other Topics in Coordination Chemistry
10:00-10:20

IL-61

Dynamically Functional Palladium Chains Supported by Linear
Tetraphosphines

Tomoaki Tanase

Transition Metal
10:20-10:40
10:40-11:00

T-type photochromism through generating copper(I)metallacyclopentadiene biradical
Coffee Break, 1F Hallway
IL-62

21

Zhong-Ning Chen
(canceled)Other Topic in Coordination Chemistry
2F, Room 201

11:00-12:30
Chair

Yi-Chou Tsai

11:00-11:20

IL-63

11:20-11:40

IL-64

11:40-12:00

IL-65

12:00-12:30

KL-20

Geometric and electronic structures characterization on Fe(II)complexes with the tridentate pyridine-tetrazolate ligand
Bond analysis in "novel molecules" and their applications inchemistry
Characteristic Features of Transition Metal Complexes Having
Lewis Acidic Group 13 Element Ligand

MakotoYamashita

Hydride-Containing Copper- And Silver-Rich Nanoclusters

Chen-Wei Liu

I-Jui Hsu
Lili Zhao

Functional Materials
2F, Room 202

09:30-10:00
Chair
09:30-10:00

Ming-Hsi Chiang
KL-22

Exploring quantum functions using triplets in MOFs

Nobuhiro Yanai

Bioinorganic Chemistry and Biomedical Diagnostics
2F, Room 202

10:00-10:40
Chair

Ming-Hsi Chiang
Using Decoy Molecules to Manipulate P450BM3
Biotransformations
Exploitation of Photofunctional Transition Metal Complexes inBioorthogonal Labeling, Cellular Imaging, and Photocytotoxic
Applications

10:00-10:20

IL-71

10:20-10:40

IL-72

10:40-11:00

Coffee Break, 1F Hallway

Kenneth KamWing Lo

2F, Room 202

11:00-12:30
Chair

Osami Shoji

Hua-Fen Hsu

11:00-11:20

IL-73

Molecular Mechanisms Controlling Formation and Reactivity ofOxoiron(IV) Porphyrin π-Cation Radical Complex

11:20-11:40

IL-74

Lanthanide Porphyrin Phototheranostics

Jun-Long Zhang

11:40-12:00

IL-75

Conversion of Myoglobin into Artificial Metalloenzymes

Takashi Hayashi

12:00-12:30

KL-23

New Insights into the Platinum(IV) Prodrug Activation

Wee Han Ang

22

Hiroshi Fujii

Metal Organic Frameworks
1F, Room 102

14:00-15:30
Chair

Fa-Kuen Shieh
MOF@MOF Architectures: Synthesis, Characterization &Application
3D mixed-valence metal‒organic frameworks and theirstructure-performance relationships for high-powerelectrochemical energy storage
Open Coordination Chemistry in a Paddlewheel Metal-Organic
Framework
Metal-organic framework nanospace as platform for selective
photochemical reactions

14:00-14:30

KL-15

14:30-14:50

IL-46

14:50-15:10

IL-47

15:10-15:30

IL-48

15:30-15:50

Coffee Break, 1F Hallway

Teng-Hao Chen
Nak Cheon
Jeong
Shinpei
Kusaka

1F, Room 102

15:50-17:00
Chair

Hoi Ri Moon

Teng-Hao Chen

15:50-16:10

IL-49

16:10-16:30

IL-50

Application of Porous Coordination Polymer Containing Aromatic
Azo Linkers as Cathode Active Materials in Sodium-Ion Batteries
Influence of Framework Metal Ion of Analogous Coordination
Polymers on the Adsorptive Removal and Photocatalytic
Oxidative Degradation of Dyes

Hirofumi
YoshikawaJing-Yun Wu

Oral Presentation (Metal Organic Frameworks and Organometallic Chemistry)
16:30-16:45

Oral-01

16:45-17:00

Oral-02

Precise Synthesis of Graphene Nanoribbons in Metal–Organic
Frameworks
Reactions of NO and β-Diketiminate Ligands Supported Ru(I)
Complexes

23

Takashi Kitao
Chuan-Sheng
Huang

Supramolecular Chemistry
1F, Room 103

14:00-15:30
Chair

Chen-Wei Liu
2D Metallo-Supramolecular Arrays Assembled from Giant Cages

14:00-14:30

KL-18

14:30-14:50

IL-56

14:50-15:10

IL-57

15:10-15:30

IL-58

15:30-15:50

Coffee Break, 1F Hallway

Fabrication of tunable hydrogel networks through metal-ligand
coordination crosslinking
Structure-property correlations of semiconducting
Te/SeFe3(CO)9─dipyridyl Cu polymers
Electrically conductive metallocycle: densely packed molecularhexagons assembled by π-radicals

Yi-Cheun Yeh
Minghuey Shieh
Hiroaki Iguchi

1F, Room 103

15:50-17:00
Chair

Yi-Tsu Chan

Yi-Tsu Chan

15:50-16:10

IL-59

Capturing of fullerene with macrocyclic metal complexes

Kentaro Tanaka

16:10-16:30

IL-60

Confined Electron Transfer within Metal-Organic
Supramolecular Architectures for Sustainable Photocatalysis

Chunying Duan

Oral Presentation (Supramolecular Chemistry)
16:30-16:45

Oral-03

16:45-17:00

Oral-04

Following and Controlling the Assembly of Paddlewheel-Based
Cages
Structures and functions of hydrogen-bonded organic
frameworks based on metal chlorido complexes bearing abis(benzimidzol-2-yl)methane

24

David Turner
Shun Ohta

Magnetic Materials
14:00-15:30
Chair

2F, Room 201
Hui-Lien-Tsai
Molecular Spin Qubits for Quantum Computer and Highly
Density Memory Devices Based on Molecular Magnets
Rigid Pyrimidyl Ligands to Construct of Low-Dimensional
Magnetic Coordination Polymers

Masahiro
Yamashita

14:00-14:30

KL-21

14:30-14:50

IL-66

14:50-15:10

IL-67

Development of stimuli-responsive metal complex

Yoshihiro
Sekine15:10-15:30

IL-68

Control of the Long-Range Magnetic Ordering via Gas
Adsorption in a π-stacked Pillared Layer Framework

Wataru Kosaka

15:30-15:50

Coffee Break, 1F Hallway

15:50-17:00
Chair

Chen-I Yang

2F, Room 201
Chen-I Yang

15:50-16:10

IL-69

16:10-16:30

IL-70

Heterometallic interaction emerges from resonant inelastic Xray scattering in magnetic Gd−Pt molecules
Peculiar Magnetic Response and Negative Thermal Expansion ofa Nickel Dithiolate Crystal

Takefumi
YoshidaKiyonori
Takahashi

Oral Presentation (Magnetic Materials and Lanthanides and Actinides)
16:30-16:45
16:45-17:00

Oral-05

TBC

Oral-06

Selective Crystallization of Dy3+ Complex from Nd3+/Dy3+
Mixture Enabled by Cooperation of Coordination and
Crystallization

Tetsu Sato25

Atsuko MasuyaSuzuki

Bioinorganic Chemistry and Biomedical Diagnostics
2F, Room 202

14:00-16:30
Chair

Way-Zen Lee
Electronic Structures and Reactivity of Iron(V)- Nitrido and -Oxo
Complexes
Design and Directed Evolution of Noncanonical β-Stereoselective
Metalloglycosidases
Design, synthesis, and biological evaluation of cyclometalated
iridium(III) complex-peptide hybrids that induce paraptotic
programmed cell death in cancer cells
Bioinspired Approaches to Selective Catalytic Oxidations byNonheme Iron Complexes

14:00-14:30

KL-24

14:30-14:50

IL-76

14:50-15:10

IL-77

15:10-15:30

IL-78

15:30-15:50

Coffee Break, 1F Hallway

15:50-16:10

IL-79

16:10-16:30

IL-80

Nitrogen Activation and Conversion by the Fe Sites of Biomimetic
Mo-Fe-S Cubes
Anticancer screening of N(3) ring substituted 3-acetylcoumarinthiosemicarbazones and their copper(II) complexes

Shengfa Ye
Woon Ju SongShin Aoki
Tapan K. Paine

Yasuhiro Ohki
Paras Nath
Yadav

Oral Presentation (Bioinorganic Chemistry and Biomedical Diagnostics)
16:30-16:45

Oral-07

16:45-17:00

Oral-08

Metal-Mediated Stabilization and Structure Induction of
DNA Three-Way Junction Motifs Modified with Bpy andPhen Ligands
Bioinspired Co(NO)x Complexes: Correlating Structure andNO-Transfer Reactivity towards Cysteine

Yusuke Takezawa
Chien-Wei Chiang

Plenary Session 5(Metal Organic Frameworks)
1F, Room 101

17:05-17:50
Chair

Yi-Tsu Chan

17:05-17:50

PL-05

Metal-Organic Frameworks for Photo-/Electro-Catalytic CO2
Reduction

Xiao-Ming Chen

Poster Session 2 (online)
online18:00-20:00

26

Wednesday, August 10, 2022
Plenary Session 6(Electronic Structures and Bonding of Metal Complexes)
08:40-09:25
Chair
08:40-09:25

1F, Room 101
David Harding
PL-06

Low-dimensional electrons system in coordination networks

Hiroshi Kitagawa

Magnetic Materials
1F, Room 102

09:30-10:40
Chair

Phan Van Hoa
Tuneable ligand field leads to correlations with spin crossoverT1/2 and redox potential Epa in Fe(II) helicates
Solvent and periphery ligand effects on structural and magnetic
properties of Fe(III) spin crossover complexes

09:30-10:00

KL-25

10:00-10:20

IL-81

10:20-10:40

IL-82

10:40-11:00

Coffee Break, 1F Hallway

Phase Switchable Porous Magnets

Phimphaka
Harding
HitoshiMiyasaka

1F, Room 102

11:00-12:30
Chair

Sally Brooker

Po-Heng Lin

11:00-11:20

IL-83

Ultrasmall Nano Particle Encapsulated within an Organic Cage

Masayuki Nihei

11:20-11:40

IL-84

Ferroelectricity in spin crossover compounds

Shinya Hayami

11:40-12:00

IL-85

12:00-12:30

KL-26

Quantum Information Processing with the Zero-Field Splitting
Effects in High-spin Centers
Bidirectional photoswitching and solvent effects in iron(III) spincrossover complexes

27

Shen Zhou
David Harding

Catalysis, Energy and Small Molecule Activation
1F, Room 103

09:30-12:30
Chair

Michael Huang

09:30-10:00

KL-28

Ruthenium-Oxygen Species in Oxidation Reactions:Characteristics and Mechanistic Insights

Takahiko Kojima

10:00-10:20

IL-91

Fueling the Future

Kuo-Wei Huang

10:20-10:40
10:40-11:00
11:00-11:20

Electrochemical Polymerization Provides Function-Integrated
Systems for Water Oxidation
Coffee Break, 1F Hallway
Ligand engineering toward the structural and functional
IL-93
control of metal nanoclusters
IL-92

Mio Kondo

Quan-Ming Wang

11:20-11:40

IL-94

Potential-driven dynamic structures of electrocatalysts

Hao Ming Chen

11:40-12:00

IL-95

Bioinspired Molecular Water Oxidation Catalysts

Ming-Tian Zhang

12:00-12:30

KL-29

Bioinspired Small Molecule Conversion Catalysis Mediated by
1st-row Transition Metals

Yunho Lee

Lanthanides and Actinides
2F, Room 201

09:30-12:30
Chair

Chun-Yi Lin

09:30-10:00

KL-31

Cerium Carboxylate Clusters: Synthesis and Photocatalysis

10:00-10:20

IL-101Fine-tuned core structures of lanthanide complexes byapplying nitrophenolate-type ligands

10:20-10:40

IL-102

Rare-earth Metallacyclic Chemistry

10:40-11:00

Coffee Break, 1F Hallway
Lanthanide ELEMENTS: a Helicate structure for the
IL-103luminescence

11:00-11:20
11:20-11:40

Kazushi Mashima
Po-Heng Lin
Wen-Xiong Zhang

Miki Hasegawa

IL-104Lanthanide macrocycles: Magnetism and beyond

Jinkui Tang

11:40-12:00

IL-105Syntheses and reactivity of heterobimetallic rareearth/latetransition metal complexes with LM→Ln dative
bonds

Peng Cui

12:00-12:30

KL-32

Rare-earth-catalyzed hydrosilylation

28

Chunming Cui

Main Group Element Chemistry
2F, Room 202

09:30-10:40
Chair

Tiow-Gan Ong

09:30-10:00

KL-34

Small molecules activation by N,S-chelated metal complexes

Sundargopal
Ghosh10:00-10:20

IL-111

Stable Organic Radicals (feat. N-Heterocyclic Carbenes)

Eunsung Lee

10:20-10:40

IL-112

Reactivity of a Cyclic (Alkyl)(amino)silylene and Its Derivatives

10:40-11:00

Coffee Break, 1F Hallway
2F, Room 202

11:00-12:30
Chair

TakeakiIwamotoHsueh-Ju Liu

11:00-11:20

IL-113

11:20-11:40

IL-114

11:40-12:00

IL-11512:00-12:30

KL-35

Tridentate Nacnac: Pendant Picolyl Powers Peculiar Chemistry
Coordination chemistry staring from dilithiostannoles and plumboles
The Low-Valent Gold Complexes Coordinated by
Dialkyltetrylene
Controlled Functionalization of Carboranes via Transition
Metal- Catalyzed B-H Activation

Sakya Singha
Sen
Masaichi Saito
Zhifang Li
Zuowei Xie

Magnetic Materials
14:00-14:30
Chair
14:00-14:30

1F, Room 102
Yun-Ming Wang
KL-27

Multifunctional spin-crossover materials and organic radicals
magnetism

Phan Van Hoa

Bioinorganic Chemistry and Biomedical Diagnostics
1F, Room 102

14:30-17:00
Chair
14:30-14:50
14:50-15:10
15:10-15:30
15:30-15:50
15:50-16:10
16:10-16:30

Yun-Ming Wang
IL-86

Multi-action Platinum Anticancer Compounds

Iron(III)-based CORM with dynamic variation in responsive
wavelengths depending on H+
Peroxy Intermediates in Aldehyde Deformylation and Nitrile
IL-88
Activation
Coffee Break, 1F Hallway
Molecular mechanism of NO reduction catalyzed by FeIL-89
containing nitric oxide reductases
Metal-Ligand Cooperation in Dinuclear Dinitrosyl Iron
IL-90
Complexes for Small Molecule Activation
IL-87

29

Janice AldrichWright
Hiroshi Nakajima
Jaeheung Cho

Yoshitsugu Shiro
Tsai-Te Lu

Oral Presentation (Electronic Structures and Bonding of Metal Complexes)
16:30-16:45

Oral-09

Structure of the Copper (II)-Cefotaxime Complex

16:45-17:00

Oral-10Synthesis, properties and structural analysis of a new seriesof oligonuclear copper (II) complexes with pyrazolato-bridges

KhulanByambasuren
Marilena
Ferbinteanu

Metal Organic Frameworks
1F, Room 103

14:00-17:00
Chair

Chia-Her Lin

14:00-14:30

KL-30

MOFs to Create Advanced Polymers

Takashi Uemura

14:30-14:50

IL-96

Rare Earth Functional Complexes

Weisheng Liu

14:50-15:10

IL-97

Machine-Learning-Assisted Synthesis of Semiconductive
Coordination Polymers

Daisuke Tanaka

15:10-15:30

IL-98

Insights into MOF Chemical Biology

Fa-Kuen Shieh

15:30-15:50

Coffee Break, 1F Hallway
Dynamic Structural Transformation of Metal-Organic
IL-99
Framework

15:50-16:10
16:10-16:30

IL-100

Metal-organic network-forming glasses for energy applications

Minyoung Yoon
Satoshi Horike

Oral Presentation (Catalysis, Energy and Small Molecule Activation)
16:30-16:45

Oral-11

16:45-17:00

Oral-12

Electrochemical conversion of methane to useful oxygenates
using an oxygen transfer cascade provided by a bi-layer
coating electrode
Electrochemical and photochemical hydrogen evolution fromwater catalyzed by first row transition metal complexes

Yeshayahu BenEliyahu
Kosei Yamauchi

Functional Materials
2F, Room 201

14:00-15:30
Chair
14:00-14:30
14:30-14:50
14:50-15:10
15:10-15:30
15:30-15:50

Chen-Yu Yeh
KL-33

Molecular spin state manipulation and spin chemistry

Song Gao

An open-shell, magnetoluminescent, two-dimensional
coordination polymer with a triangular organic radical ligand
Chromatographic separation of hydrogen isotopes at ambient
IL-107
temperature using dihydrogen complexes
Synthesis and properties of atomically precise silver nanoclusters
IL-108with polyoxometalates
Coffee Break, 1F Hallway

TetsuroKusamoto
ShinyaTakaishi

IL-10630

Kosuke Suzuki

Functional Materials
2F, Room 201

15:50-17:00
Chair
15:50-16:10
16:10-16:30

Tien-Lin Wu
IL-109Phase transitions in multi-component dense crystals

Wei-XiongZhang

IL-110

Thermo- and mechano-triggered luminescence ON/OFF
switching by supercooled liquid/crystal transition of Pt(II)complex thin films

Masaki
YoshidaOral Presentation (Functional Materials)
16:30-16:45

Oral-13

16:45-17:00

Oral-14

Macro- and atomic-scale observations of a one-dimensional
heterojunction in a nickel and palladium nanowire complex
Bis-pyrazole-bis-acetate based coordination complexes asbuilding blocks for the design of hybrid materials

Masanori
Wakizaka
Afaf Oulmidi

Main Group Element Chemistry
2F, Room 202

14:00-17:00
Chair

Kuo-Wei Huang
Five-fold Symmetric Complexes for Spherical SupramolecularAggregations
Formation of stable intra- and inter-molecular radical ion pairs
by Lewis acid coordination

ManfredScheer

14:00-14:30

KL-36

14:30-14:50

IL-116

14:50-15:10

IL-117

Synthesis Towards Chiral π-Conjugated Iridium Metallacycles

Rong Shang

15:10-15:30

IL-118From methane functionalization to polystyrene hydrogenolysis:
borenium in C-H and C-C bond activations

HuadongWang

15:30-15:50

Coffee Break, 1F Hallway

15:50-16:10

IL-119

Coordination Chemistry of the Cationic Donor Ligands

16:10-16:30

IL-120Synthesis of Disilane-Bridged Aromatic Compounds for the
Luminescent Materials

Xinping Wang

Moumita
Majumdar
Yoshinori
Yamanoi

Oral Presentation (Electronic Structures and Bonding of Metal Complexes)
16:30-16:45

Oral-15

A radical approach to novel reactivity

Nicolaas P.van
Leest

16:45-17:00

Oral-16

Electronic tuning of FeII and RuII complexes through choice of
coordinated azine

Matthew Robb

31

Plenary Session 7(Bioinorganic Chemistry and Biomedical Diagnostics)
1F, Room 101

17:05-17:50
Chair
17:05-17:50

Chen-Hsiung Hung
Bioinorganic Strategies to Study Multiple Facets in Alzheimer’s
DiseasePL-07

Mi Hee Lim

Thursday, August 11, 2022
Plenary Session 8(Functional Materials)
1F, Room 101

08:40-09:25
Chair

Ru-Shi Liu

08:30-09:15

PL-08

Luminescence Materials: A Wonderful Toolbox for Applied Imaging
and Assistive Technologies

Xiaogang Liu

Main Group Element Chemistry
1F, Room 102

09:20-10:30
Chair

Ching-Wen Chiu

09:20-09:40

IL-121Synthesis of Novel Aluminum Catalysts for Ring-Opening
Polymerization of ε-Caprolactone and Their Polymerization
Mechanism Study

Hsuan-YingChen

09:40-10:00

IL-122

N-Heterocyclic Silylene Stabilized Disilicon(0) Complexes

Zhenbo Mo

Oral Presentation (Supramolecular Chemistry and Electronic Structures and Bonding of Metal Complexes)
10:00-10:15

Oral-17

Tow-dimensional MOFs Composed of Single-Molecule Magnets

Yoji Horii

10:15-10:30

Oral-18

Multimetallic Set up of 2,1,3-Benzothiadiazole: Revelation ofElectronic Structure and Application Potential

Sanchaita Dey

Functional Materials
1F, Room 103

09:20-10:30
Chair

Jeffrey M. Farrell

09:20-09:40

IL-123

09:40-10:00

IL-124

Substituent Engineering of Organoboron Compounds for Ultrathin
and Nondoped OLEDs
Construction of Amorphous Coordination Polymers From Liquid
Metal Complexes
32

Tien-Lin Wu
Tomoyuki
MochidaOral Presentation (Functional Materials and Transition Metal)
10:00-10:15

Oral-19

10:15-10:30

Oral-20

Unusual Substituent effects of Paddle-Wheel Organometallic
Molecular Wires on Single-Molecule Conductance
Circularly polarized luminescence of (O^N^C^C)-cyclometalated
carbene platinum(II) complexes having distorted structure

Yuya Tanaka
Soichiro
Kawamorita

Catalysis, Energy and Small Molecule Activation
2F, Room 201

09:20-10:30
Chair

Hao Ming Chen

09:20-09:40

IL-125

Nanoarchitectonic Engineering for Small Molecule Conversion

Chun-Hung Kuo

09:40-10:00

IL-126

Preparation of New Polymers via Coordination Polymerization
using Rare-earth Metal Catalysts

Dongmei Cui

Oral Presentation (Catalysis, Energy and Small Molecule Activation)
10:00-10:15

Oral-21

Steering Redox Pathways via Hybrid Bilayer Membranes

Edmund Tse

10:15-10:30

Oral-22

Precise synthesis and catalytic evaluation of Mo-based
subnanoclusters on low-temperature CO2 hydrogenation

Augie Atqa

Metal Organic Frameworks
2F, Room 202

09:20-10:30
Chair

Chia-Her Lin

09:20-09:40

IL-127

09:40-10:00

IL-128Distorted coordination geometries of metal nodes for structuralproperties of coordination polymers
Iridium-functionalized stable metal–organic framework-basedmaterials for electrocatalysis

Ryo Ohtani
Chung-Wei
Kung

Oral Presentation (Metal Organic Frameworks)
10:00-10:15

Oral-23

MOF@PVA beads for VOC capture

Pamela Berilyn So

10:15-10:30

Oral-24

Core-Shell Microspheres of SiO2@MOF for Cycloaddition of
CO2 with Epoxides

Chen-Yen Tsai

33

ACCC Award 2(Bioinorganic Chemistry and Biomedical Diagnostics)
1F, Room 101

10:30-11:15
Chair
10:30-11:15

Masahiro Yamashita
Biomimetic Metal-Oxygen Intermediates in Dioxygen Activation andFormation Chemistry

Wonwoo Nam

Plenary Session 9(Organometallic Chemistry)
1F, Room 101

11:15-12:00
Chair

Deng Liang
Domesticating the Reactivity of Non-Octet Carbon toward Plethoraof Chemistry

11:15-12:00

PL-09

12:00-12:15

Closing Ceremony (1F, Room 101)

34

Tiow-Gan Ong

Abstracts
Sunday, August 7
Plenary Session 1 & ACCC Award 1

Time: 17:15-18:00

Vivian Wing-Wah Yam
Professor
Institute of Molecular Functional Materials andDepartment of Chemistry
The University of Hong Kong
Hong Kong
1. Curriculum Vitae:
Professor Vivian W.-W. Yam is the Chair Professor of Chemistry and Philip Wong Wilson Wong Professor
in Chemistry and Energy at The University of Hong Kong. She received both her BSc(Hons) and PhD fromThe University of Hong Kong. She was elected to Member of Chinese Academy of Sciences, International
Member (Foreign Associate) of US National Academy of Sciences, Foreign Member of Academia
Europaea, Fellow of TWAS and Founding Member of Hong Kong Academy of Sciences. She was Laureateof 2011 L'Oréal-UNESCO For Women in Science Award. Her research interests include
inorganic/organometallic chemistry, supramolecular chemistry, photophysics and photochemistry, andmetal-based molecular functional materials for sensing, organic optoelectronics and energy research.
Also see: https://chemistry.hku.hk/wwyam
2. Abstract:
Speech Topic: From simple discrete metal-ligand motifs to supramolecularassembly, nanostructures and functions
Various strategies for the design and synthesis of new classes of chromophoric and luminescent metal
complexes will be described. These simple discrete metal complexes can undergo supramolecularassembly to give a variety of nanostructures and morphologies with different colors and emission
properties. Explorations into the underlying factors that govern their structures, properties andmorphologies and their assembly mechanisms have provided new insights into the interplay of thevarious intermolecular forces for the directed assembly of metal-containing soft materials and hybrids.
Manipulation of the electronic effects, molecular conformation, orientation and assembly has led to thecontrol of the excited states in novel molecular materials and supramolecular assemblies. The
exploration into the potential applications and functions of these luminescent discrete metal complexes,
supramolecular assemblies and polymers will also be described.

35

Monday, August 8
Plenary Session 2

Time: 08:40-09:25

Colette Boskovic
Professor
School of Chemistry
The University of Melbourne
Australia
1. Curriculum Vitae:
Boskovic graduated from the University of Melbourne with a PhD in 1998. After postdoctoral stints at
Indiana University, USA, and the University of Berne, Switzerland, she returned to the University of
Melbourne in 2004 as a Lecturer and was promoted to full Professor in 2022.

Colette was awarded the 2004 Selby Research Award from the University of Melbourne, the 2013 Alan
Sargeson Lectureship from the Royal Australian Chemical Institute (RACI) Inorganic Chemistry Divisionand the 2014 Dean’s Award for Excellence in Research (Teaching and Research) from the Faculty of
Science, University of Melbourne. She received an Australian Research Council Future Fellowship in
2019. Colette was elected a Fellow of the RACI in 2020. She is presently the Chair-Elect of the RACI
Inorganic Chemistry Division Committee. She is a member of the International Advisory Boards for theInternational Conference on Molecule-based Magnets (ICMM), Asian Conference on Molecular
Magnetism (ACMM) and Asian Conference on Coordination Chemistry (ACCC).
Colette leads the Inorganic Molecular Materials research group in the School of Chemistry at the
University of Melbourne. Her research interests focus on the chemistry of paramagnetic transition
and rare earth metals, including valence tautomeric and spin crossover molecular switches, redoxactive ligands and single-molecule magnets.

36

2. Abstract:
Speech Topic: Switchable molecular materials based on valence tautomerism and spin crossover
Molecules that can be reversibly switched between distinguishable forms are of interest for a range of
future applications, including in sensors, data storage and molecular spintronics. Transition metal
complexes are ideal switchable molecules because facile modulation of their electronic structure
affords readily detectable changes in electronic properties, including colour and magnetic moment.
Spin crossover involves stimulated interconversion between different spin states and is a well-known
mechanism for switchability in metal complexes. Valence tautomerism is another possibility, whereintramolecular electron transfer between a metal and a redox-active ligand can be induced, allowing
switching between species with different charge distributions. In some cases, a spin transition
accompanies electron transfer. Our work with switchable metal complexes has focused mainly onvalence tautomerism, but also spin crossover. Our recent efforts with computational collaborators
have explored the use of density functional theory to predict both the likelihood of an interconversion
for metal complexes, as well as the switching characteristics, including transition temperature. [1,2] We
have also focused on understanding the origin of stepwise interconversions in dinuclear metal
complexes. [3] Our aim is to be able to use density functional theory to design new metal complexes
with properties suitable for applications prior to synthesis and experimental validation.
References[1] Janetzki, J. T.; Zahir, F. Z. M.; Gable, R. W.; Phonsri, W.; Murray, K. S.; Goerigk, L.; Boskovic, C. A
Convenient DFT-Based Strategy for Predicting Transition Temperatures of Valence Tautomeric
Molecular Switches. Inorg. Chem. 2021, 60, 14475.
[2] Gransbury, G. K.; Boulon, M. E.; Petrie, S.; Gable, R. W.; Mulder, R. J.; Sorace, L.; Stranger, R.; Boskovic,
C. DFT Prediction and Experimental Investigation of Valence Tautomerism in Cobalt-Dioxolene
Complexes. Inorg. Chem. 2019, 58, 4230.
[3] Gransbury, G. K.; Livesay, B. N.; Janetzki, J. T.; Hay, M. A.; Gable, R. W.; Shores, M. P.; Starikova, A.;
Boskovic, C. Understanding the Origin of One- or Two-Step Valence Tautomeric Transitions inBis(Dioxolene)-Bridged Dinuclear Cobalt Complexes. J. Am. Chem. Soc. 2020, 142, 10692.

37

Monday, August 8
Rising Star Award

Time: 16:35-17:05

Shang-Da Jiang
Professor
Spin-X InsituteSouth China University of Technology
China
1. Curriculum Vitae:
Prof. Shang-Da Jiang works in the field of molecular magnetism and obtained the Ph. D degree at
Peking University, China (2011). His Ph. D thesis was awarded National Excellent Doctorial Dissertationof China. He has been a Humboldtian in the University of Stuttgart (2001-2014) and a postdoctor inLaboratoire National des Champs Magnétiques Intenses in France (2015). He worked in the Peking
University as a research scientist (2015-2020), and presently is a full professor of chemistry in Spin-X
Institute at South China University of Technology. His research interests are the quantum coherence
manipulation of magnetic molecules by microwave, electric field and laser stimulations. Prof. Jiang has
published more than 60 publications with over 5000 citations. He has obtained the National Science
Fund of China for Excellent Young Scholars in 2018.
2. Abstract:
Speech Topic: Spin Manipulation in Magnetic Molecules
Quantum information technology can realize a new information processing based on quantum mechanics principles.
Magnetic molecules can be applied as the quantum information processing units due to their tunable quantum
coherence properties and larger Hilbert space. This talk will firstly introduce the research ideas of the "Magnetic
Molecular Coherence Manipulation", and the "cage protection" proposal to enhance the magnetic molecularcoherence. The talk will also introduce our experiments on coherent manipulation of magnetic molecules by transient
electric fields and lasers. The quantum phase interference phenomenon of multi-level molecules of fullerene
molecules shows that magnetic molecules could be more interesting compared with traditional quantum systems.

[1] Jiang, S.-D.* et al., Endohedral Metallofullerene as Molecular High Spin Qubit: Diverse Rabi Cycles in
Gd2@C79N. J. Am. Chem. Soc. 2018, 140, 1123-1130.
[2] Jiang, S.-D.* et al., Electric field manipulation enhanced by strong spin-orbit coupling: promoting rare-earth
ions as qubits. Natl. Sci. Rev. 2020, 7, 1557-1563.
[3] Jiang, S.-D.* et al., Coherent manipulation and quantum phase interference in a fullerene-based electron
triplet molecular qutrit. npj Quan. Infor. 2021, 7, 32.
[4] Jiang, S.-D.* et al., Implementation of Quantum Level Addressability and Geometric Phase Manipulation in
Aligned Endohedral Fullerene Qudits. Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202115263[5] Jiang, S.-D.* et al., Spin-Electric Coupling with Anisotropy-Induced Vanishment and Enhancement in
Molecular Ferroelectrics. J. Am. Chem. Soc. 2022, DOI: 10.1021/jacs.2c00484

38

Monday, August 8
Plenary Session 3

Time: 17:05-17:50

Goutam Kumar Lahiri
Professor
School of Chemistry
Indian Institute of Technology Bombay
India
Email: lahiri@chem.iitb.ac.in
1. Curriculum Vitae:
Educational Qualification:
Ph.D: Jadavpur University, India
Postdoctoral Fellow: West Virginia University, USA
Professional Career:
Professor: I.I.T.-Bombay
Research Interest
Manifestations of electronic structural aspects of metal complexes involving redox active ligands including
molecular functionalization and catalysis
Publications: ~300 (h-index: 51); Ph.D students Supervised:36

Awards and Recognitions
Associate Editor: Indian J. Chem.-New Delhi and J.Chem.Sci.-Bangalore
J C Bose Fellowship
CRSI Silver Medal
B. M. Birla awards in chemistry
Fellow, Indian National Science Academy, The National Academy of Sciences, India, Indian Academy of
Sciences, Maharashtra Academy of Sciences
Institute (IIT Bombay) Chair Professor
Ramanna Fellowship (DST, New Delhi)
Excellence in Teaching (IIT Bombay)
Mercator Chair Professorship (DFG-Germany)
Royal Society Award for International Authors

392. Abstract:
Speech Topic: Non-innocence of coordinated ligands. Electronic structure andReactivity
Metal complexes of redox non-innocent (RNI) ligands, capable of participating in multi-electron transfer
processes due to closeness in energy of their frontier orbitals have considered to be important from thebroader perspectives of fundamental electron transfer aspects,[1] as well as their application potency insmall-molecule activation,[2] catalysis,[3] bio-mimicking[4] and designing molecular electronic devices.
[5] The present deliberation would primarily be centered on addressing (i) inner sphere electron transfer
at the metal-ligand interface (MnL p Mn+1L p–1 ) of such redox-active molecular frameworks including
dynamic resonating[6] or valence tautomeric[7] issue and (ii) assessing redox mediated chemical noninnocence of the coordinated ligand moiety.
References[1] (a) Kaim, W.; Lahiri, G. K. Angew. Chem., Int. Ed., 2007, 46, 1778-1796. (b) Kumari, M.; Bera, S. K.;
Blickle, S.; Kaim, W.; Lahiri, G. K. Chem. Eur. J. 2021, 27, 5461-5469.
[2] (a) Lyaskovskyy, V.; de Bruin, B. ACS Catal., 2012, 2, 270-279. (b) Panda, S.; Bera, S. K.; Goel, P.; Dutta,
A. K.; Lahiri, G. K. Inorg. Chem., 2019, 58, 11458- 11469.
[3] (a) Kundu, S.; Stieber, S. C. E.; Ferrier, M. G.; Kozimor, S. A.; Bertke, J. A.; Warren, T. H. Angew. Chem.,
Int. Ed., 2016, 55, 10321-10325. (b) Ray, R.; Chandra, S.; Yadav, V.; Mondal, P.; Maiti, D.; Lahiri, G. K. Chem.
Commun. 2017, 53, 4006- 4009.
[4] Dhara, S.; Panda, S.; Lahiri, G. K. Dalton Trans., 2021, 50, 12408-12412.
[5] Goswami, S.; Matula, A. J.; Rath, S. P.; Hedström, S.; Saha, S.; Annamalai, M.; Sengupta, D.; Patra, A.;
Ghosh, S.; Jani, H.; Sarkar, S.; Motapothula, M. R.; Nijhuis, C. A.; Martin, J.; Goswami, S.; Batista, V. S.;
Venkatesan, T. Nat. Mater., 2017, 16, 1216-1224.
[6] Singh, A.; Dey, S.; Panda, S.; Lahiri, G. K. Inorg. Chem., 2021, 60, 18260-18269. [7] Singh, A.; Panda, S.;
Dey, S.; Lahiri, G. K. Angew. Chem., Int. Ed., 2021, 60, 11206-11210.

40

Tuesday, August 9
Plenary Session 4

Time: 08:40-09:25

François Gabbaï
Professor
Department of Chemistry
Texas A&M University
USA
1. Curriculum Vitae:
François Gabbaï was born in Montpellier (France) in the late 60’s. Upon completion of his undergraduate
studies at the University of Bordeaux in 1990, he joined the graduate program at the University of Texas
at Austin to work with Alan Cowley. After obtaining his Ph.D. in 1994, he was awarded an Alexandervon Humboldt Fellowship and subsequently a Marie Curie Fellowship which allowed him to work with
Hubert Schmidbaur at the Technical University of Munich first as a postdoctoral fellow and later as an“Habilitand”. In 1998, he joined Texas A&M University where he now holds the Arthur E. Martell Chairof Chemistry. François, who is a member of the advisory board of several international journals, hasserved as an associate editor for Organometallics between 2011 and 2019, and for Chemical Sciencesince April 2019. He is a Fellow of the American Chemical Society (ACS), a Fellow of the Royal Society ofChemistry, and the recipient of several awards including the 2009 North American Dalton Lectureshipand the 2016 F. Albert Cotton Award in Synthetic Inorganic Chemistry from the ACS. His most recent
recognitions include a 2019 Distinguished Achievement Research Award from the Texas A&M
Association of Former Students and his promotion to the title of Distinguished Professor. His researchinterests revolve around the chemistry of p-block elements and late transition metals with applicationsin the domain of molecular recognition, anion transport, and catalysis.

41

2. Abstract:
Speech Topic: Carbenium Ions as Z-type Ligands
As part of our contribution to the chemistry of ambiphilic ligands, we have started tosystematically develop examples of such ligands in which the Lewis acidic functionality is a carbenium
ion. In this presentation, we will describe the synthesis of phosphine-carbenium[1,2] and carbenecarbenium ligands and show that these new systems can be readily coordinated to electron-rich group
10 and 11 metals (M), leading to a family of complexes featuring weak Au ⋯ Ccarbenium[1] or genuine
Ni/Pd/Pt→Ccarbenium dative interactions. In addition to describing the atypical bonding situations thatarise in the chemistry of these complexes,[3,4] we will also show that the electron deficiency of thecarbenium unit can be used to adjust the catalytic reactivity of gold(I) centers in reactions thatnecessitate the carbophilic activation of unsaturated hydrocarbons.[1,5]Finally, we will show that even in the absence of an Au→Ccarbenium dative bond, the electron-accepting
properties of the carbenium ion provides access to low energy excited states, the formation of which
can be exploited to induce the clean and highly efficient photoreduction of gold(III) centers.
References[1] Wilkins, L. C.; Kim, Y.; Litle, E. D.; Gabbaï, F. P., Stabilized Carbenium Ions as
Latent, Z-type Ligands. Angew. Chem. Int. Ed. 2019, 58, 18266-18270.
[2] Zhou, J.; Litle, E. D.; Gabbaï, F. P., Isolation and reactivity of a gold(I)hydroxytrifluoroborate complex stabilized by anion-π+ interactions. Chem. Commun.
2021, 57, 10154-10157.
[3] Park, G.; Gabbaï, F. P., The Elusive Au(I)···H–O Hydrogen Bond: Experimental
Verification. J. Am. Chem. Soc. 2021, 143, 12494-12498.
[5] Liu, W.-C.; Kim, Y.; Gabbaï, F. P., Conformational Switching through the OneElectron Reduction of an
Acridinium-based, γ-Cationic Phosphine Gold Complex.
Chem. Eur. J. 2021, 27, 6701-6705.
[5] Litle, E. D.; Wilkins, L. C.; Gabbaï, F. P., Ligand-enforced intimacy between a gold cation and acarbenium ion: Impact on stability and reactivity. Chem. Sci. 2021, 12, 3929-3936.

42

Tuesday, August 9
Plenary Session 5

Time: 17:05-17:50

Xiao-Ming Chen
Professor
School of Chemistry
Sun Yat-Sen University
China
1. Curriculum Vitae:
Xiao-Ming Chen obtained his BSc (1983) and MSc (1986) degrees from Sun Yat-Sen University (SYSU),
Guangzhou, China, and PhD degree (1992) from The Chinese University of Hong Kong. He joined
chemistry faculty at SYSU since 1992, and became a professor since 1995. He is Member of Chinese
Academy of Sciences (since 2009), Fellow of The World Academy of Sciences for Advancement of
Science in Developing Countries (TWAS, since 2013). His research interests include synthesis, structuresand properties of functional coordination polymers (including MOFs) and metal complexes. He has
published 510 papers in academic journals including Science, JACS, Angew. Chem., Adv. Mater., andChem. Rev. etc. He has currently more than 45,000 citations (H-index >115) in Web of Science. He won
several science awards, such as China National Natural Science Prize, TWAS Prize in Chemistry,
Khwarizmi International Award, International Award of Japan Society of Coordination Chemistry, as well
as Highly Cited Researcher in Chemistry (2014-2021).

43

2. Abstract:
Speech Topic: Metal-Organic Frameworks for Photo-/Electro-Catalytic CO2 Reduction
In recent years, catalytic CO2 reduction reaction (CO2RR) driven by solar or renewable energy has
attracted extensive attention due to its potential role in mitigating green-house effect and energy crisis.
However, due to the extremely stable chemical bond in CO2, the competing hydrogen evolution reactionin the presence of water, as well as the reduction of CO2 involving a multi-electron stepwise processwith several intermediates generated from different chemisorbed species, the design of highly efficientand selective catalysts for CO2RR, especially to produce hydrocarbons, is challenging.
With many useful characteristics, such as well-defined structures, high porosity, structural diversity,
designable and modifiable frameworks/pore surface, metalorganic frameworks (MOFs) can serve as aplatform to provide precise structureproperty relationship, and regulate the catalytic sites and chemical
micro-environment for better performance.
In this talk, our investigations on the design and modification of MOFs for photoand electro-catalytic
CO2RR to give products of CO,[1] CH4,[2] and C2+ hydrocarbons[3] will be presented, focusing on theimportance of the active site binding ability and supramolecular interaction with CO 2 and the specificintermediate species, rational integration of photosensitizers with CO2 reduction centers for thecatalytic activities and selectivities, as well as rational integration of dual metal active sites for the
production of ethylene and other high value-added C2+ compounds.
References[1] Wang, Y.; Huang, N.-Y.; Shen, J.-Q.; Liao, P.-Q.; Chen, X.-M.; Zhang, J.-P.; J. Am. Chem. Soc. 2018, 140,
38.
[2] Zhu, H.-L.; Huang, J.-R.; Zhang, X.-W.; Wang, C.; Huang, N.-Y.; Liao, P.-Q.; X.-M. Chen, ACS Catal. 2021,
11, 11786.
[3] Qiu, X.-F.; Zhu, H.-L.; Huang, J.-R.; Liao, P.-Q.; Chen, X.-M., J. Am. Chem. Soc. 2021, 143, 7242.

44

Wednesday, August 10
Plenary Session 6

Time: 08:40-09:25

Hiroshi Kitagawa
Professor
Department of Chemistry
Kyoto University
Japan
1. Curriculum Vitae:
Hiroshi Kitagawa was born at Osaka in 1961 and finished his PhD at Kyoto University in 1991 and, afterworking as Assistant Professor at the Institute for Molecular Science (IMS) and Japan Advanced
Institute of Science and Technology (JAIST), he was appointed as an Associate Professor at the
Department of Chemistry, University of Tsukuba in 2000. He became a Professor at the Departmentof Chemistry, Faculty of Science at Kyushu University in 2003 and moved to Kyoto University as a
Professor in 2009. He was engaged at Japan Science and Technology Agency (JST) as Director of the
network-type research institution “Science and Creation of Innovative Catalysts”, PRESTO, and is also
engaged at JST as Director of the network-type research institution “Exploring Innovative Materials in
Unknown Search Space”, CREST, and as Program Officer, Materials Science Panel, Fusion Oriented
Research for Disruptive Science and Technology (FOREST). He is also Chief Program Officer, ChemistryGroup, Research Center for Science Systems, Japan Society for the Promotion of Science (JSPS). He
has been President, Japan Society of Coordination Chemistry from 2020. He has published more than
470 original research papers dealing with solid-state chemistry, coordination chemistry, nanoscience,
low-dimensional electron systems, and molecule-based conductors.

45

2. Abstract:
Speech Topic:

Low-dimensional electrons system in coordination networks

More than 35 years, we have investigated MX or MMX chains system as a model of pure 1-D electron
system, because this system has wide variety of possible electronic phases[1-2]. The MMX chain iscomposed of M-M dimer and bridging iodine. In this system, there are four dominant interactions,transfer integral t, on-site Coulombic repulsion U, nearest neighbor Coulombic repulsion V, andelectron-lattice interaction S, those are competing to each other in energy. The charge-ordering stateswith lattice distortions of a halogen-bridged binuclear-metal mixed-valence complex (MMX chain),
Pt2(L)4I (L = CH3CS2- and C2H5CS2-), have been investigated by transport, magnetic, and opticalmeasurements. This complexes are binuclear unit-assembled conductor containing metal−metalbonds. It exhibits metallic conduction, representing the first example of a metallic halogenbridged onedimensional transition-metal complex. Conductive MOF nanotube and other electrically conductive
MOFs are also presented[3-6].
References[1] H. Kitagawa, et al., J. Am. Chem. Soc., 121, 10068 (1999), J. Am. Chem. Soc., 121, 2321 (1999),
Coord. Chem. Rev.,190, 1169 (1999), J. Am. Chem. Soc., 123, 11179 (2001), Angew. Chem. Int. Ed., 41,2767, (2002), J. Am. Chem. Soc., 126, 1614 (2004), J. Am. Chem. Soc., 128, 6676 (2006), J. Am. Chem.
Soc., 128, 8140 (2006), J. Am. Chem. Soc., 128, 12066 (2006), Chem. Asian J., 4, 1673 (2009),
CrystEngComm, 16 6277-6286 (2014), Inorg. Chem., 53, 1229 (2014), Eur. J. Inorg. Chem., 4402-4407(2016), Inorg. Chem., 55, 2620 (2016), Nature Commun., 7, 11950 (2016), Angew. Chem. Int. Ed., 56,
3838 (2017), Nature Commun. 11, 843 (2020), K. Otake, H. Kitagawa, Small, 17, 2006189 (2021), K.
Otake, K. Otsubo, H. Kitagawa, Journal of Physics: Condensed Matter, 33, 034002 (2021).
[2] T. Yamada, K. Otsubo, R. Makiura, H. Kitagawa, Chem. Soc. Rev., 42, 6655 (2017).
[3] K. Otsubo, Y. Wakabayashi, J. Ohara, S. Yamamoto, H. Matsuzaki, H. Okamoto, K. Nitta, T.Uruga, H.
Kitagawa, Nature Materials, 10, 291 (2011).
[4] S. Sakaida, K. Otsubo, O. Sakata, C. Song, A. Fujiwara, M. Takata, H. Kitagawa, Nature Chemistry, 8,377 (2016).
[5] K. Otake, K. Otsubo, K. Sugimoto, H. Kitagawa, Angew. Chem. Int. Ed., 55, 6448 (2016).
[6] D. Lim, M. Sadakiyo, H. Kitagawa, Chemical Science, 10, 16-33 (2019), Y. Yoshida, K. Fujie, D. Lim, R.
Ikeda, H. Kitagawa, Angew. Chem. Int. Ed., 58, 10909-10913 (2019), K. Otsubo, S. Nagayama, S.
Kawaguchi, K. Sugimoto,H. Kitagawa, JACS Au, 2, 109-115 (2022). D. Lim, H. Kitagawa, Chem. Soc. Rev.,50, 6349-6368 (2021).

46

Wednesday, August 10
Plenary Session 7

Time: 17:05-17:50

Mi Hee Lim
KAIST Endowed Chair Professor
Department of Chemistry
Korea Advanced Institute of Science and Technology(KAIST)
Republic of Korea
1. Curriculum Vitae:
Education
1995 – 1999 B.S. Ewha Womans University
1999 – 2001 M.S. Ewha Womans University
2002 – 2006 Ph.D. Massachusetts Institute of Technology
Professional Career
2006. 10. – 2008. 06.
2008. 08. – 2013. 08.
2013. 09. – 2018. 01.
2018. 02. – present

Postdoctoral Scholar, California Institute of Technology
Assistant Professor, Univ. of Michigan, Ann Arbor, USA
Associate Professor, Ulsan National Institute of Science and Technology (UNIST)
Associate Professor, Professor, and KAIST Endowed Chair Professor, Korea
Advanced Institute of Science and Technology (KAIST)

Selected Awards and Honors
2021 The Year Award for Women in Science and Technology (The Ministry of Science and ICT & WISET)
2020 S-Oil Next-Generation Scientist Award (S-Oil Science Prodigy & Culture Foundation & the Korean
Academy of Science and Technology)
2020 Asian Biological Inorganic Chemistry (AsBIC) James Hoeschele Award
2019 Member of the Young Korean Academy of Science and Technology
2018 Society of Bioinorganic Chemistry (SBIC) Early Career Award
2016 Award for “30 Young Scientists of Korea” to Lead Basic Science Research for the Next 30 Years(POSTECH & Dong-A Ilbo)
2015 KCS-Wiley Young Chemist Award, Korea
2012 Alfred P. Sloan Research Fellow, USA

47

3. Abstract:
Speech Topic:

Bioinorganic Strategies to Study Multiple Facets in Alzheimer’s Disease

Alzheimer’s disease (AD), associated with degeneration of neurons and synapses in the brain, leads tomotor impairment and eventual fatality. Neurodegeneration could be related to various interconnectedfeatures, including (i) plaque formation from amyloid-β (Aβ) peptide fragments, (ii) metal ion
dyshomeostasis and miscompartmentalization, as well as (iii) inflammation and increased oxidative
stress due to overproduction of reactive oxygen species (ROS). The inter-relations between some ofthese pathological factors have been investigated. Metals are found entangled in the A β plaque andlikely contribute to Aβ neurotoxicity and oxidative stress. ROS have been shown to increase the rate ofAβ plaque formation. Our understanding of the correlation between these elements and AD
neuropathogenesis has been very limited, however. There is currently no cure for AD; therapies arefocused on symptomatic relief targeting the decrease in the levels of acetylcholine, only one of themultiple factors causing the disease.[1-3] To find a cure for AD, we require a better understanding of therelationship between the various causative factors of this devastating disease. Towards this goal, we
need suitable chemical tools capable of targeting and regulating its multiple underlying factors
simultaneously.[2,3] Herein, our rational design and preparation of our chemical tools will be discussedwith our investigations of their interactions and reactivities with targets in vitro as well as their efficacy
in vivo. [4-11]
References[1] Chem. Soc. Rev. 2017, 46, 310.
[2] Chem. Rev. 2019, 119, 1221.
[3] Acc. Chem. Res. 2021, 54, 3930.
[4] Proc. Natl. Acad. Sci. USA 2010, 107, 21990.
[5] Chem. Sci. 2015, 6, 1879.
[6] J. Am. Chem. Soc. 2014, 136, 299.
[7] J. Am. Chem. Soc. 2015, 137, 14785.
[8] Nat. Commun. 2016, 7, 13115.
[9] J. Am. Chem. Soc. 2017, 139, 2234.
[10] Proc. Natl. Acad. Sci. USA 2020, 117, 5160.
[11] J. Am. Chem. Soc. 2020, 142, 8183.

48

Thursday, August 11
Plenary Session 8

Time: 08:30-09:15

Xiaogang Liu
Professor
Department of Chemistry
National University of Singapore
Singapore
Employment History
2004-2006 Postdoctoral Fellow, Department of Materials Science and Engineering, Massachusetts
Institute of Technology, USA
2006-2011 Assistant Professor, Department of Chemistry, National University of Singapore, Singapore
2011-2016 Associate Professor, Department of Chemistry, National University of Singapore,
Singapore
2017-present Professor, Department of Chemistry, National University of Singapore, Singapore
Academic qualifications
1996 B.S., Beijing Technology and Business University, Beijing, China
1999 M.S., East Carolina University, Greenville, North Carolina, USA
2004 Ph.D., Northwestern University, Evanston, Illinois, USA
Scientific awards
Outstanding Research Award (NUS 2017)
President’s Science Award (Singapore 2016)
Recent Publications
1) “Rare-Earth Doping in Nanostructured Inorganic Materials”, Chemical Reviews 2022, 122, 55195603.
2) “Organic phosphors with bright triplet excitons for efficient X-ray-excited luminescence”, Nature
Photonics 2021, 15, 187-192.
3) “Mapping Drug-Induced Neuropathy through In-Situ Motor Protein Tracking and Machine
Learning,” Journal of the American Chemical Society 2021, 143, 14907–14915
4) “Continuous-wave Near-IR STED Microscopy using Downshifting Lanthanide Nanoparticles”,
Nature Nanotechnology 2021, 16, 975-980.
5) “Anomalous upconversion amplification induced by surface reconstruction in lanthanide
sublattices”, Nature Photonics 2021, 15, 732-737.
6) “High-resolution X-ray luminescence extension imaging”, Nature 2021, 590, 410–415.
7) “Lanthanide-doped inorganic nanoparticles turn molecular triplet excitons bright,” Nature 2020,
587, 594.

49

Abstract:
Speech Topic: Luminescence Materials: A Wonderful Toolbox for Applied Imaging and Assistive
Technologies
Lanthanide-doped nanoparticles exhibit unique luminescence properties, including massive Stokes shift,
sharp emission bandwidth, high resistance to optical blinking, and photobleaching. They are also unique inconverting long-wavelength stimulation into short-wavelength emission. These attributes offer the
possibility of developing alternative luminescent labels for organic fluorophores and quantum dots. In
recent years, researchers have demonstrated spectral-conversion nanocrystals for many biologicalapplications, such as highly sensitive molecular detection and autofluorescence-free cell imaging. Withsignificant progress over the past decade, we can now design and fabricate nanoparticles that display
tailorable optical properties. In particular, by controlling different combinations of dopants and dopant
concentrations, we can generate a plethora of colors under excitation with a single wavelength. By
incorporating a set of lanthanide ions in defined concentrations into different layers of a core-shellstructure, we have expanded the emission spectra of the particles to cover almost the entire visible region,
which is not possible with conventional bulk phosphors. In this talk, I will highlight recent advances in the
broad utility of lanthanide-based nanocrystals for multimodal imaging, bio-detection, therapy, X-ray
scintillation, and assistive technology.

50

Thursday, August 11
ACCC Award 2

Time: 10:30-11:15

Wonwoo Nam
Professor
Department of Chemistry and Nano Science
Ewha Womans University
Korea
1. Curriculum Vitae:
Wonwoo Nam was born in Seoul, Korea. He received his B.S. (Honors) degree in Chemistry from
California State University, Los Angeles and his Ph.D. degree in Inorganic Chemistry from UCLA under
the direction of Professor Joan S. Valentine in 1990. After one year postdoctoral experience at UCLA, hebecame an Assistant Professor at Hong Ik University in 1991. He moved to Ewha Womans University in
1994, where he is presently a Distinguished Professor of Ewha Womans University. His current research
focuses on the mechanistic studies of dioxygen activation and formation by biomimetic models of heme
and nonheme iron monooxygenases.
Awards & Honors• The 4th Young Scientist Award (Award given by the President of Korea), 2000
• Korean Chemical Society Award, 2006
• The 5th DuPont Science and Technology Award, 2006
• The 3rd Kyeong-Am Academic Award, 2007
• Korea Science Award (Award given by the President of Korea), 2015
• Korea Toray Science and Technology Prize, 2020
Activities as Editor or Editorial Board Member• Editor-in-Chief; Bulletin of the Korean Chemical Society (KCS), 2020 – Present• Associate Editor; Chemical Science (RSC), 2011 – 2019
• Editorial Advisory Board; Chemical Science (RSC), 2019 – Present• Editorial Advisory Board; Chem Catalysis (Cell), 2021 – Present• Editorial Advisory Board; Accounts of Chemical Research (ACS), 2006 – 2015
• Editorial Advisory Board; Chemical Communications (RSC), 2012 – Present51

2. Abstract:
Speech Topic: Biomimetic Metal-Oxygen Intermediates in Dioxygen Activation and Formation
Chemistry
Dioxygen is essential in life processes, and enzymes activate dioxygen to carry out a variety of biologicalreactions. One primary goal in biomimetic research is to elucidate structures of reactive intermediates
and mechanistic details of dioxygen activation and oxygenation reactions occurring at the active sites of
enzymes, by utilizing synthetic metal-oxygen complexes. A growing class of metal-oxygen complexes,
such as metal– superoxo, –peroxo, –hydroperoxo, and –oxo species, have been isolated, characterized
spectroscopically, and investigated in various oxygenation reactions. During the past decade, we havebeen studying the chemical and physical properties of various reactive intermediates in oxygenation
reactions, such as high-valent iron(IV)- and manganes(V)-oxo complexes of heme and non-heme ligandsin oxotransfer and C-H activation reactions, non-heme metal-peroxo complexes in nucleophilic
reactions, and non-heme metal-superoxo complexes in electrophilic reactions. The effects of supporting
and axial ligands on structural and spectroscopic properties and reactivities of metal-oxygen adducts
have been extensively investigated as well. In this presentation, I will present our recent results on thesynthesis and structural and spectroscopic characterization of mononuclear nonheme metaldioxygen
intermediates as well as their reactivities in electrophilic and nucleophilic oxidation reactions.
References
1. “Iron and Manganese Oxo Complexes, Oxo Wall and Beyond” Nature Reviews Chemistry 2020, 4, 404–
419.
2. “Hydrogen Atom Transfer Reactions by Metal-Oxygen Intermediates” Acc. Chem. Res. 2018, 51, 2014–
2022.
3. “Synthetic Mononuclear Nonheme Iron-Oxygen Intermediates” Acc. Chem. Res. 2015, 48, 2415–2423.
4. “Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo
Complexes” Acc. Chem. Res. 2014, 47, 1146–1154.
5. Jaeheung Cho, Ritimukta Sarangi, and Wonwoo Nam* “Mononuclear Metal-O2 Complexes Bearing
Macrocyclic TMC Ligands Acc. Chem. Res. 2012, 45, 1321– 1330.
6. “High-Valent Iron(IV)-Oxo Complexes of Heme and Nonheme Ligands in Oxygenation Reactions” Acc.
Chem. Res. 2007, 40, 522–531.
7. “Guest Editorial: Dioxygen Activation by Metalloenzymes and Models” Acc. Chem. Res. 2007, 40,
465.

52

Thursday, August 11
Plenary Session 9

Time: 11:15-12:00

Tiow-Gan Ong
Professor
Institute of Chemistry
Academia Sinica
Taiwan2. Curriculum Vitae:
Dr. Tiow-Gan Ong has distinguished himself as an organometallic chemist exploring non-octet chemicalbonding using “ligand-design strategy.” Presently, Dr. Ong is the Research Fellow at Institute of Chemistryat Academia Sinica, acting as Academic Deputy Director. He is also the Professor at National Taiwan
University and Koashiung Medical University. Dr. Ong has obtained his Ph.D in 2000 at University of
Kentucky under the supervison of Professor Robert Toreki. Subsequently, he did his postdoctoral training
at UC Santa Barbara (Professor Guillermo Bazan) and then Univeristy of Ottawa (Professor Darrin
Richeson) before beginning his independent career as the Asssitant Research Fellow at Academia Sinica,
Taiwan in 2006.
Ong group have consistently contributed his work in Organometallic and Catalysis that leads to several
key breakthroughs;•
C–H/C-O bond activation in selective manner relied on synergistic interaction between Nickel-Lewis
Acid medaited catalysis.
•
Curiosity-driven science on new class of C0 science so called Carbone and Carbodicarbene, leading
to new paradigm in FLP, metal-free catalysis, tandem 1 & 2 electron reaction and radical-orientatedreaction.
•
Epitome of these basic studying on C0 class also leads to isolation of unstable Dicarbon (C2), which
has been published recently in Nature Chemistry.
His scientific contributions with impacts on broad field of chemistry have been well recognized in national
and international level with recent representative awards; University of Ottawa Visiting Research Award(2020), Outstanding Research Award from Taiwan Ministry of Science and Technology (2019) and theAcademia Sinica Presidential Scholar Program Award (2021).

53

3. Abstract:
Speech Topic: Domesticating the Reactivity of Non-Octet Carbon toward Plethora of ChemistryTiow-Gan Onga,b*aInstitute of Chemistry, Academia Sinica, Taipei, Taiwan
bDepartment of Chemistry, National Taiwan University, Taipei, Taiwan

tgong@gate.sinica.edu.tw
ABSTRACT
Carbodicarbenes (CDCs) are carbones (CL2) repertoire that feature a dicoordinated central carbon(0) atom bearing two lone pairs of electrons, with N-heterocyclic carbenes (NHCs) as ligands (L). Becauseof the two lone pairs on the central carbon atom, CDCs have been regarded as strong σ-donating
surrogates complementary to the well-established NHCs. This presentation will describe the synthetic
preparation[1] and chemical properties of the CDC[2] as well as its application toward supporting metallic
complexes for catalysis in tandem photoredox,[3] cross-coupling reaction via tandem C-H and C-O bondactivation[4] and a new spin in diversifying FLP reactivity with co-modulator benzyl alcohol. Finally, we
also described phosphine-stabilized dicarbon as effective ligand for metal complexes and catalysis.[5]Dicarbon is a reactive carbon allotrope that naturally exists only in the high temperature medium ofstellar space.
REFERENCES[1] W.-C. Chen, J.-S. Shen, T. Jurca, C.-J. Peng, Y.-H. Lin, Y.-P. Wang, W.-C. Shih, G. P. A. Yap, T.-G. Ong,
Angew. Chem. Int. Ed. 2015, 54, 15422–15427.
[2] W.-C. Chen, W.-C. Shih, T. Jurca, L. Zhao, D. M. Andrada, C.-J. Peng, C.-C. Chang, S.-K. Liu, Y.-P. Wang,
Y.-S. Wen, et al., J. Am. Chem. Soc. 2017, 139, 12830–12836.
[3] Y.-C. Hsu, V. C. C. Wang, K.-C. Au-Yeung, C.-Y. Tsai, C.-C. Chang, B.-C. Lin, Y.-T. Chan, C.-P. Hsu, G. P. A.
Yap, T. Jurca, et al., Angew. Chem. Int. Ed. 2018, 57, 4622–4626.
[4] T.-H. Wang, R. Ambre, Q. Wang, W.-C. Lee, P.-C. Wang, Y. Liu, L. Zhao, T.-G. Ong, ACS Catal. 2018, 8,11368–11376.
[5] Leung, T.-F.; Jiang, D.; Wu, M.-C.; Xiao, D.; Ching, W.-M.; Yap, G. P. A.; Yang, T.; Zhao, L.; Ong, T.-G.;
Frenking, G. Nat. Chem. 2021, 13, 89-93.

54

Poster Session
Monday, August 8, 2022
Poster Session 1
online18:00-20:00

P01-01

Some New Evaluations for a Cyanide Ag-Cu Complex and Laccase

P01-02

Ordered self-assembly of lanthanide complexes

P01-03
P01-04

Synthesis and characterization of naphthalenediimide based semiconductive
coordination polymers with potassium centers
Reactivity of a tetrahedral CuI 4 cluster covered by S-donating octahedral
metalloligands

Takashiro Akitsu
Lijuan Liang
Tappei Tanabe
Nobuto Yoshinari

P01-05

Cation-ordered pentavalent fullerides

P01-06

Characterization of Two-electron Oxidized CuII -salen Complexes with Paramethoxy and methylthio Groups; Geometric Structure, Magnetic Property,
and Benzyl Alcohol Oxidation Mechanisms

P01-07

Syntheses and magnetic properties of di-nuclear cobalt complexes
containing asymmetry tetraoxalene ligand

Naohiro Takahashi

P01-08

Electrical conduction of quasi-one dimensional halogen-bridged metal
complex heterojunction

Keisuke Ishiguro

P02-01

Design, Synthesis and Photophysical Properites of Optically Pure
Triscyclometalated Iridium(III) Complexes Synthesized via DiastereomericIntermediates

Azusa Kanbe

P02-02

Organorhodates and -iridates—structure and reactivity—

Takanori Iwasaki

P02-03

Cyclotrimerization of benzonitriles by the catalytic systems composed oftitanium chlorido complexes and magnesium

Keiichiro Saitoh

P02-04

A Bis-(carbone) Pincer Ligand and its Coordinative Behavior Toward MultiMetallic Configurations

Bamlaku Semagne
Aweke

P02-05Base-Promoted Perfluoroalkylation of Rhodium Porphyrin Complexes with
Perfluoroalkyl Iodides

Li-Jie Fu

P02-06

Synthesis and properties of a neutral chromium complex with a Cr≡Si triplebondMasahiro
Matsuoka

P02-07

Crystal structure and molecular recognition of dinuclear and 2D sheet-like
Zn(II) complexes using fluorinated carboxylic acid

Tomoki Jitsukata

P02-08Cyclotrimerization of alkynes catalyzed by a bis(indolyl)-coordinatedtitanium diamido complex

Yuki Kawahara

P02-09Synthesis and structure of an isolable hydroalumylene complex of tungsten

Keisuke Matsui

55

Tomoyuki
Takeyama

Keita SatoP02-10
P02-11
P02-12Cyclic (Alkenyl)(amino)carbene as a Strong π-Accepting Carbene: Synthesis
and Coordination Chemistry
Ag13H8 Silver Hydride Core in Tetrahedral Cage Formed by Four Triangular[CuAg3(CCAr)3(PPh3)3] + Panels
Discovery and Mechanistic Analysis of Zn2+- Promoted Decomposition
Reactions of Cyclometalated Iridium(III) Complexes

Shota Kamiyama
Tsutomu Mizuta
Surajit Haldar

P02-13

Crystal structures and reversible vapor adsorption of aromatic derivatives
using nickel(II) complexes with perfluorinated ligand

Hirotomo UsuiP02-14Heterometallic d8 -d 10 Coupling of Rh(I) and M(0) (M = Pd, Pt) in a Sandwich
Framework of pπ-Conjugated Ligands

Iori Inoue

P02-15

Theoretical Mechanistic Study of 1,10-Phenanthroline Palladium Catalyzed
Chain-Walking Processes

Kazuma Muto

P02-16

Characterization of a Ti(IV)-Schiff-base-benzyl Complex Reaction with aHydroxyketone Using ELF Topological Characterization

Bernard G. Ramos

P03-01

Theoretical study of effect on ionization potential by hydrogen bonds
around [4Fe-4S] active site in HiPIP

Taigo Kamimura

P03-02

Platinum(IV)-Chlorambucil Complexes: A New Series Of Multifunctional
Prodrugs

Angelico Aputen

P03-03

Cyclooxygenase Inhibiting Platinum(IV) Prodrugs with Potent Anticancer
Activity

Aleen Khoury

P03-04

Platinum(II) Cyclometallated Cytotoxic Complexes with G- Quadraplex
Stabilization and Luminescent Properties

Brondwyn S.
McGhieP03-05

X-ray Structure and Electrophilic Reactivity of Nonporphyrinic Terminal
Manganese(IV)–Hydroxide Complexes

Younwoo Park
(canceled)

P03-06

Spectroscopic Characterization of a Peroxyhemiacetal-Like Intermediate in
Aldehyde Deformylation

Yeongjin Son(canceled)

P03-07

Synthesis of π-Expanded Vitamin B12 and Application to the Photocatalytic
Reaction

Keita Shichijo

P03-08Synthesis and Characterization of Roussin’s Red Esters with Derivatives of
Pyrenyl Group for the Detection of ROS

Show-Jen Chiou

P03-09Modeling Heme Peroxidase: Heme Saddling Facilitates Reactions with
Hyperperoxides to Form High-Valent Fe(IV)–Oxo Species

Chang-Quan Wu

P04-01

Solvent-induced polarity switching of molecular crystals constructed byasymmetric five-coordinate complexes

Junichi Yanagisawa

P04-02

Heterometallation of silver(I) sulfide nanoclusters protected by thiolato
iridium(III) octahedra

Zi Lang Goo

P04-03Evidence for Stereoselective Substitution of Pyridine Derivatives (PY) in mer{RuIII(PY)3}3+ Units
56

Chihiro Iwasaki

P04-04

Structures and Applications of Paddlewheel-Type Dirhodium Complexes
with N,N’-Donating Ligands

Natsumi Yano

P04-05Syntheses and crystal structures of tri- and octa-nuclear silver(I) clusters
having ethynide and diamine ligands

Daiki Hashimoto

P04-06

Optical resolution of a tetrahedral chiral-at-nickel(II) complex with only
achiral ligands

Yuanfei Liu

P04-07The characteristic of phosphorescence for a ruthenium-terpyridine
chromophore complex: DFT modeling postulated low-energy triplet excitedstate and spin orbit coupling perturbation

Chi Wei Yin

P05-01Highly disordering nanoporous frameworks of lanthanide- dicarboxylates forcatalysis of CO2 cycloaddition with epoxides

Supaphorn
Thammakan

P06-01

Photochromic Dithienylethene-Containing Four-Coordinate Boron(III)Compounds with Spirocyclic Scaffold

Tony Ho-Ching
Fung

P06-02

Coordination and Hydroboration of Ru(II)-Borate Complexes:
Dihydridoborate vs. Bis(dihydridoborate)

Sourav Gayen

P06-03

Coordination Behavior of Iminophosphonamido Silylene toward Group 10
Transition Metals

Norio Nakata

P09-01Synthesis and Allosteric Molecular Recognition of Cavitand-based
HemicarcerandKentaro Harada

P09-02

Self-assembly of platinum(Ⅱ) complexes possessing chiral triethylene glycol
chains

Masaya Yoshida

P09-03

Hexapap: A Uniquely-Shaped Macrocycle Possessing Inwardly Assembled
Metal Coordination Sites

Takashi Nakamura

P09-04

Isocyanide-Templated Assembly of Pillar[5]arene-based Pseudorotaxanes

Korawit
Khamphaijun

P09-05

Stimuli-responsive and structure-adaptive three-dimensional gold(I) cluster
cages constructed via “de-aurophilic” interaction strategy

Liang-Liang Yan

P09-06

Catalytic Hydrolysis of Phosphate Monoester by Supramolecular
Phosphatases Functionalized with Lewis Acidic Moieties

Hirokazu Okamoto

P09-07Heterometallic coordination compounds with thiolate amino acid as water
splitting electrocatalysts

Naoto Kuwamura

P09-08

Selective Construction of Metallonanobelts by Template-Directed SelfAssembly Using Various Kinds of Molecules with Oligoether Chains

Ryosuke Nakamura

P09-09Color changes of a bis(benzimidazole)-coordinated nickel dichlorido complex
induced by the vapor of methanol or pyridine

Tatsunari
Murakami

P09-10Size-selective Guest Recognition and the Open/Close Control of Macrocyclic
Cobalt(III) Dinuclear Metallohosts Having Aromatic Bridging Ligands

Ryo SudoP09-11

Cooperative motion of supramolecular cation composed of branched-chain
alkylammonium and dibenzo[18]crown-6 in [Ni(dmit)2] salts

Kazuya Kanamaru

57

P09-12

Solvent-Mediated Photo-Reactivity of Diolefins in One-Dimensional MetalOrganic Frameworks

Dong Hee Lee

P09-13

Regioselective Syntheses of Calix[6]-crown-6 Isomers and Their Heavy Alkali
Metal Complexes

In-Hyeok Park

P09-14

Crystal Structure and Thermal Expansion of a Monovalent [Ni(dmit)2] Salt
with Supramolecular Cation Composed of 2,2'- oxybis(ethylaminium+ ) and[18]crown-6

Masato Haneda

P09-15

Direct X-ray Observation of Stepwise Metal Exchange Reaction from CdII to
CoII in a 116-Nuclear Cage-of-Cage Complex

Benny
WahyudiantoP09-16

Regioselective Photoreaction of Supramolecular Isomers Triggered by Guest
Exchange

Jihye Oh

P10-01

Theoretical Study on Electronic States and Magnetic Anisotropy of
Dysprosium Complexes by Using Density Functional Theory

Keigo Cho

P10-02

Redox-Active Bridged Dinuclear Fe(III) Complexes to Target Multi-Step Spin
Crossover

Jett T. Janetzki

P10-03Modulation of Magnetic Properties in Organic−Inorganic Perovskite−Type
Materials with Ferroelasticity by Metal Substitution

Naoto Tsuchiya

P10-04

Theoretical Study on Electronic Structure and Magnetic Anisotropy of
Bathocuproine Cobalt(II) Complexes

Masahiro Tsuda

P10-05

Crystal structures and magnetic properties of two cyano-bridged Ni-W
bimetal assembles

Shintaro Akagi

P10-06

Observation of the phonon-frequency shifts at magnetic phase transition on
a MnW octacyanide molecule-based magnet

Shuntaro
NAGASHIMA

P10-07

Syntheses, Crystal Structures, and Properties of Paramagnetic Multinuclear
Assembles with Trans Pt–M–Pt Trinuclear Complexes

Atsushi Takamori

P10-08

Identifying Valence Tautomeric Cobalt-Dioxolene Complexes: A DFTBenchmarkF. Zahra M. Zahir

P10-09

Guest-Induced Multistep-to-One-Step Reversible Spin Transition with
Enhanced Hysteresis in a 2D Hofmann Framework

Dibya Jyoti Mondal

P10-10

Structural control of Prussian blue analogues by alkali metal substitution

Marina NISHIURA

P10-11

Structures and magnetic properties of trinuclear cobalt complexes

Ryuya Tokunaga

P10-12Fabrication of novel cyanide-bridged CoFe dinuclear complex

Riku Fukushima

P10-13Synthesis and physical property of Cyano-bridged [Co2Fe4]complexes

Yutaka Hirai

P10-14

Electronic pyroelectricity in valence tautomeric complexes

Shu-Qi Wu

58

P10-15

Construction of chiral spin crossover complexes by design of counter anion

P10-16

Observation of slow magnetic relaxation in π-radicals isolated in crystal
structures by chemical modification

Shohei Koyama

P10-17Structural and Statistical Investigation of Salen-type 3d-4f Single Molecule
Magnets

Yuji Takiguchi

P10-18Realizing Bifunctional Fluorescence Valence Tautomerism in a Series ofMononuclear Cobalt Compounds

P10-19Multi-step spin-crossover in polymorphic Fe(III) compounds

Yingying Wu

P10-20

Crystal structures and magnetic properties of octacyano-bridged Cu-W
bimetal assembles

Masashi Okawa

P10-21

Photochromic dithienylethenes for the construction of photoswitchable
quantum nanomagnets

Katarzyna Rogacz

P10-22Spin-lattice relaxations of a S=1/2 copper(II) ion incorporated into Keggintype silicotungstateToshiharu Ishizaki

P10-23

Cation shrinking effect for a charge transfer in an iron mixed-valencecomplex with dithiooxalato bridging ligand

Ryosuke Taniai

P10-24Significant Control on Quantum Tunneling of Magnetization (QTM) in
Dysprosium(III) Single-Molecule Magnet via Symmetry Approach

Pradip Kumar Sahu

P13-01Synthesis and Oxidation Catalysis of Difluoride-Containing Polyoxovanadates

Yuji Kikukawa

P13-02

Interaction of a Hydrophobic Cation and a Bowl-type Dodecavanadate
Complexes

Hiroya Iwai

P13-03Hydride-containing eight-electron superatoms determined by neutron
diffraction

Tzu-Hao Chiu

P13-04Paper No. Unsymmetric multidentate azine-based ligands coordinating to anickel(II) ion

Kennedy Mawunya
Hayibor

P13-05Ab initio structural investigation of C60/PAH co-adducts – new structuresfrom powder diffraction data

Akane Matsumoto

P13-06

Luminescence switch based on the chemically induced reversibility ofcovalent bonds in Tb(III) complexes: An acid/base-driven system

Chihiro KachiTerajima

P13-07Fabrication and phase-transition of WO3 thin films via molecular precursor
method involving the tungsten complex of citric acid

Taichi Murayama

P13-08Palladium is Alloyed with Hydride-Encapsulated Silver-Rich Nanoclusters
Stabilized by Dithiolates

Yu-Rong Ni

59

Ayumu Suzuhigashi

Yuqin Li

Tuesday, August 9, 2022
Poster Session 2
online18:00-20:00

P07-01Highly Active Constrained Aluminum Catalysts for the Synthesis of Cyclic
Carbonates from Epoxide/CO2 Coupling Reactions

Nattiya
LaiwattanapaisarnP07-02

Indium Chloride Complexes Supported by Constrained Schiff-Base Ligands
for Cyclic Carbonate Synthesis

Thitirat
Piyawongsiri

P07-03

Theoretical Study on Effect of Dispersion Correction in Interaction between
p-Styrenesulfonate and 3,5-Bis(2-pyridyl)pyrazole-Bridged Binuclear IridiumCopper Complex

Yuta Hayashi

P07-04

Ru(III)-Ru(IV) complexes with the doubly oxido-bridged core

Tomoyo MisawaSuzuki

P07-05Photocatalytic CO2 Reduction Using Heteroleptic Cu(I) bipyridine Complexes
as a Photosensitizer

Hiroyuki Takeda

P07-06

Catalytic Water Oxidation by a Doubly N-Confused Hexaphyrin Dinuclear
Cobalt Complex

Takashi Nakazono

P07-07

Photocatalytic CO2 Reduction on Rhenium Complexes Connected to a Zinc
Porphyrin: Significant Effect of the Connected Positions

Yuto Suzuki

P07-08Chromatography separation of hydrogen isotopes at ambient temperatureusing dihydrogen complexes

Tamon Yamauchi

P07-09Photoelectrochemical water oxidation by TiO2 photoanode modified withmolecular ruthenium photosensitizer and catalyst

Xin Yan

P07-10Electrochemical Hydrogen Evolution from Water Catalyzed by a Co-NHC
Complex

Masanori Kan

P07-11Comparing the water oxidation characteristics of cobalt polymolybdates andRu-bda catalysts

Natsuki TairaP07-12

Photocatalysis of CO2 reduction by diazapyridinophane complexes of Fe, Co,
and NiYuto Sakaguchi

P07-13

Photocatalytic water oxidation by carbon nitride modified with Rubda-typewater oxidation catalyst

Yuki Tomita

P07-14

Light-Induced Electron Transfer/Phase Migration of a RedoxMediator for the Photocatalytic C–C Coupling in a Biphasic Solution

Ren Itagaki

P07-15Controlling the photofunctionality of polyanionic heteroleptic copper(I)photosensitizer using the ionic interactions with polycationicalkylammonium ions in aqueous media

P07-16

Acceptorless Dehydrogenation by the Combinational Use of Semiconductor
Photocatalyst and Metal Complex
60

Fumika Sueyoshi

Kana Aitsuki

P07-17Syntheses and Structures of Vanadium Dinitrogen Complexes Supportedwith Triamidoamine Ligands with a Series of Sterically Hindered Substituents

Yoshiaki Kokubo

P07-18

Cu modified TiO2 catalyst for electrochemical reduction of carbon dioxide tomethaneAkihiko Anzai

P07-19Observation of N2 and H2 adsorbed on Ru catalysts by in-situ modulation
excitation infrared spectroscopy

Tomohiro Noguchi

P07-20Hydrogen peroxide production over Zr-based metal-organic
framework photocatalyst with missing-linker defects

Yoshifumi Kondo

P07-21

Reactions of an anionic diniobium complex bearing a bridging dinitrogen
ligand in a side–on end–on fashion

Naofumi Suzuki

P08-01

Removal of toxic metals from polymetallic concentrate and sulfation
roasting

Narangarav
Tumun-Ulzii

P11-01

A Tip-to-Middle Anisotropic MOF-on-MOF Growth with a Structural
Adjustment

Gihyun Lee

P11-02Synthesis of Aromatic Ladder Polymer Utilizing Coordination Nanospaces

P11-03Structural Characterization and Water Adsorption of Two Cu(II)Supramolecular Isomers Constructed by 4,4’-dipyridyl disulfide (dpds) and
4,5-dihydroxycyclopent-4-ene-1,2,3-trione (Na2C5O5) Ligands

Chih-Chieh Wang

P11-04Structural Characterization of A Series of Cd(II) Coordination
Polymers Constructed by tpsmb and Multi-carboxylated Ligands

Hsaio-Hsun Wang

P11-05Synthesis and Structural Characterization of A Series of Coordination
Polymers Constructed by 1,2,4,5-tetrakis(4-pyridylsulfanylmethylbenzene)(TET) and Anionic Ligands

Tzu-Ao Wang

P11-06

Synthesis, Structural Characterization and Properties of Co(II) Coordination
Polymers with 1,3,5-tris(4-pyridylsulfanylmethyl)2,4,6-trimethyl-Benzene(tpsmb) and Oxygen-based Ligands

Han-Fei Lin

P11-07Ferric metal-organic framework as a nanoreactor for synergistic ferroptosis,
starvation, and drug anticancer therapy

Ping-Hsuan Wu

P11-08Quinone-based metal–organic framework for CO2 capture

Yao-Ting Wang

P11-09P11-10
P11-11
P11-12

Hydroxy- and fluorine-functionalized metal−organic frameworks for gas
separations
Copper-doped ZIF-8: Antioxidant nanozyme with coordination sites similar
to the active site of Cu,Zn-SOD
Electrode Performances of Metal-Organic Frameworks with Azo Containing
Ligands
A Thiadiazole-Functionalized Zn(II)-Based Luminescent Coordination
Polymer with Seven-Fold Interweaved Herringbone Nets Showing SolventResponsive Fluorescence Properties and Discriminative Detection of
Ethylenediamine
61

Takumi Miura

Kuan Hao-Ping
Hiroki Nakahara
Ryo Matushima

Po-Min ChuangP11-13

Reversible Ion-Exchange Ability of a Novel MOF Consisting of Zirconium
Mellitate toward Selective Ammonium Recovery

Genki Hatakeyama

P11-14

Synthesis, Structure, and Proton Conductivity of Isostructural Oxalatebridged Coordination Polymers for Fuel Cells

Marlon T. Conato

P11-15

Coexistence between negative thermal expansion and spin-crossover fromnew 2-D Hofmann like coordination polymer Fe(L)2[M(CN)4]

Ryota KOSUGE

P11-16

Synthesis, crystal structure, and photochromic behavior of a Cu(II)coordination polymer with diindolylmethane derivative

ChaowatKaenpracha

P11-17

Bromine Vapor Induced Continuous p- to n-Type Conversion of
Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]

P11-18

Hydrogen Isotope Separation in Hofmann-type Metal-Organic Frameworks
with High-Density Open Metal Sites

Junsu HaP11-19Diamine-Appended MOF-Based Adsorbents with Long-Term Stability under
Humid Conditions

Jong Hyeak Choe

P11-20Understanding the structural transformation of 2-dimensional Cu(II)- toCu(I)-based metal-organic framework

Jonghoon Park

P11-21Synthesis of a Porous Coordination Polymer with Dithiocarbamate
Derivative as a Ligand, and Application to a Lithium ion Secondary Battery

Tomoki Nishiyama

P11-22Fabrication of 3D Hofmann-type thin film by casting method

Qiyuan Zhang

P11-23

Sequential Perturbation for Systematic Tuning of Metal–Organic Framework
Supercooled Liquid and Glasses

Ming-Hua Zeng

P11-24Single-Molecule Diode-Typed Metal-Organic Framework for Confined
Photocatalysis and Electrocatalysis with Added Value

Tiexin Zhang

P12-01

Crystal Lattice Design of H2O-Tolerant n-type Semiconducting Anionic
Naphthalenediimide Salts

Tomoyuki
AkutagawaP12-02

Response Of Complex Dielectric Constant On Linkage Isomerization Of
Co(III) Nitrite Complex

Shinkiro Chinen

P12-03

Preparation and Structure of Halide Solid Solution of
Hexamethylenetetramine-based Metal-free Perovskite

Hiroki Honda

P12-04

Theoretical Study of Substituent Effect on Frontier Orbital Energies ofTris(2,2’-bipyridine) Ruthenium(II) Complex Using Multivariate Analysis

Kazuaki Tokuyama

P12-05Controlled construction of multinuclear copper cores within ring-shaped
polyoxometalate by ligand-protecting strategy

Yoshihiro Koizumi

P12-06Introduction of Materials Informatics Technique to In Silico Design of
Functional Molecular Materials: Case Study in Frontier Energies of[Ru(bpy)3]2+

Yasutaka Kitagawa

P12-07

Theoretical Study on Electron Conductivity of Paddle-Wheel Type Binuclear
Complexes for Design Guideline of Single-Molecule Transistors

Naoka Amamizu

62

Shraddha Gupta

P12-08

Theoretical Study on Frontier Orbitals of Paddle-Wheel Type Dinuclear
Ruthenium(II,II) Complexes Bearing Polycyclic Aromatic Hydrocarbons in
Bridging Ligands

P12-09Mixed Matrix Membranes based on SBS Triblock Copolymer with Ni-MOF-74 Jeesica Hermayanti
Pratama
Filler for a Highly Selective H2/CH4 and CO2/CH4 Separation

P12-10

Molecular design of efficient yellow- to red-emissive alkynylgold(III)complexes for the realization of thermally activated delayed fluorescence(TADF) and their applications in solution-processed organic light-emitting
devicesP12-11
P12-12
P12-13Aggregation induced emission enhancement on a specific surface of transbis(iminomethylpyrrolato)platinum(II) complex bearing vaulted structure
Comparison of the thermal behaviour of salen type complexes with one or
two substituent(s) at the ethylene diamine moiety
Tailoring CeO2-based heterostructure through pyrolysis coordinationtunable bimetallic NiCe-MOF toward enhancing oxygen evolution reaction

Keisuke Sasaki

Cathay Chai AuYeung

Shufang Huang
Kazuo Miyamura
Haiyan An

P12-14

Electron Storage Performances of Hybrid Materials Consisting of
Polyoxometalates and Carbon Nanohorns

P12-15Synthesis of amino-functionalized mesoporous SBA-15 nanoparticles withexcellent adsorption performance

Tzong-Horng Liou

P12-16

Solvent Vapor-Induced Reversible Polarity Switching

Fumiya Kobayashi

P12-17

Charge storage of redox-active self-assembled monolayers toward organic
transistor applications

Keishiro Tahara

P12-18Mixed valency in (Sm1-xCax)2.75C60

Naoya Yoshikane

P12-19Development of Poly(2,2’-bipyridyl) Ligands for Cancer Therapy Whose Anticancer Activity is Controlled by Complexation with Metal Cations.

Tomohiro Tanaka

P12-20Vapoluminescence of platinum complexes with bis- triethylsilylethynylphenanthroline and several arylethynyl ligands

Michito Shiotsuka

P12-21Synthesis and luminescence properties of silver(I) halogenido coordination
polymers bridged by pyrazine-related ligands

Kiyoshi Tsuge

P12-22

Photo-Controlled Gelation of Ionic Liquids Using Gelator-Coordinated
Ruthenium Complexes

Ryo Sumitani

P12-23

Switching of the Emitting States of Pt(II) Complexes by Time- resolved EPR
and Optical Spectroscopy

P12-24

Porous Organic Polymer-based Composites for Photocatalytic Sulfur
Mustard Simulant Degradation under Ambient Conditions

P12-25Synthesis of Aluminosilicate from a Single-Source Spiro-7 type MolecularPrecursor

63

Katsuhiro
Wakamatsu

Motoko S. Asano
Hyojin Kim
Akira Imaizumi

P12-26
P12-27
P12-28Structure and phase transition behavior of solid solutions composed ofmetal-free perovskite-type compounds
One-dimensional Coordination Polymer with Supramolecular Interactions as
Cathode Material for High Performance Sodium-Ion Batteries
Terahertz Wave Absorption Material Showing Charge-Transfer Phase
Transition

Jumpei Moriguchi
Yi-An Lo
Yuuki Mineo

P12-29Bistability at room temperature in Cyanido-bridged Co-W assembly

Kazuki Nakamura

P12-30Kinematic Study of Molecular Motions in Crystal; Force Conversion from
Thermal Linear Expansion of Metal Ions to Circular Rotation of Ligands

Ryo Tsunashima(canceled)P12-31

Ambient-temperature formation of antiviral Cu films on a glass plate by
reduction of Cu(II) complex in aqueous solution

Hsiang-Jung Wu

P12-32

Antibacterial Cu2O thin films of transparent and well-adhered on apolycarbonate plate; formation by UV-irradiation onto Cu(II) complex film

Kyoko Kumagai

P12-33

Electrical and Magnetic Properties of Paramagnetic TTF-metal complexes

Daiki Tauchi

P12-34

Synthesis of gallium/platinum alloy sub-nanoparticles using dendrimers

Mariko Uchiyama

P12-35

N-Heterocyclic Carbene Metal Complexes for Designing Molecular Rotationin Crystals with Photofunctions

Mingoo Jin

P12-36Functional molecule-based materials consisting of cyanido-bridged metal
complexes

Shin-ichi OhkoshiP12-37

Tuning of the Magnetoresistance Effect by Modulating the Spin State of
Axially Ligated Manganese Phthalocyanine Complex

Kosuke Mine64