Product Name: Dye Sublimation Ink Sb300 Black D
SDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Safety Data Sheets* * *Section 1 - IDENTIFICATION* * *Product Identifier: Dye Sublimation Ink Sb300 Black D
Order No.
SB300-KD-BB / SB300-KD-2L
Recommended Use
Pigment ink for ink jet printerRestrictions on Use
None known.
SDS Number037-W243775
Manufacturer Information
Mimaki Engineering Co., Ltd
2182-3 Shigeno-otsu, Tomi-shi, Nagano
389-0512 Japan

Telephone number: +81-268-64-2413

Importer / Distributor Established in USA
MIMAKI USA, INC.
150 Satellite Boulevard NE, suite A, Suwanee, Georgia 30024,
U.S.A.

Téléphone: +1-678-730-0170

Emergency Telephone No.
: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

* * *Section 2 - HAZARD(S) IDENTIFICATION* * *Classification in accordance with 29 CFR 1910.1200.
Skin Corrosion / Irritation, Category 2
Serious Eye Damage/Eye Irritation, Category 2A
Skin sensitizer, Category 1GHS LABEL ELEMENTS
Symbol(s)Signal WordWARNING
Hazard Statement(s)H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
Precautionary Statement(s)____________________________________________________________
Page 1 of 7

Product Name: Dye Sublimation Ink Sb300 Black D
SDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Safety Data Sheets

Prevention
P261 Avoid breathing gas/mist/vapors.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P305+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P308 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
Storage
None needed according to classification criteria.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulation (to bespecified).
Hazard(s) Not Otherwise Classified
None known.

* * *Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS* * *CAS
57-55-6
56-81-5Trade Seclet
7732-18-5
Trade Seclet

Component
1,2-Propylene glycol
Glycerin
Disperse dye
Water
Additives

Percent
10-30
5-15
Trade Seclet
Balance0.1-1* * *Section 4 - FIRST-AID MEASURES* * *Description of Necessary Measures
Inhalation
Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician.
Skin Contact
Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off
contaminated clothing and wash before re-use.
Eye Contact
Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get immediate medical attention.
Ingestion
If swallowed, get medical attention.
Most Important Symptoms/Effects
Acuteallergic skin reaction, skin irritation, eye irritation
Delayedallergic skin reaction____________________________________________________________
Page 2 of 7

Safety Data Sheets

Product Name: Dye Sublimation Ink Sb300 Black D
SDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Indication of Immediate Medical Attention and Special Treatment Needed, If Needed
Treat symptomatically and supportively.

* * *Section 5 - FIRE-FIGHTING MEASURES* * *Suitable Extinguishing Media
carbon dioxide, regular dry chemical, water spray, alcohol resistant foam
Unsuitable Extinguishing MediaDo not scatter spilled material with high-pressure water streams.
Special Hazards Arising from the Chemical
Negligible fire hazard.
Hazardous Combustion Products
Combustion: oxides of carbon, acrolein, aliphatics
Fire Fighting Measures
Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure
water streams. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks.
Avoid inhalation of material or combustion by-products.
Special Protective Equipment and Precautions for Firefighters
Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against
possible exposure.

* * *Section 6 - ACCIDENTAL RELEASE MEASURES* * *Personal Precautions, Protective Equipment and Emergency Procedures
Wear personal protective clothing and equipment, see Section 8. Avoid release to the environment.
Methods and Materials for Containment and Cleaning Up
Eliminate all ignition sources if safe to do so. Stop leak if possible without personal risk. Reduce vapors with water
spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriatecontainer for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard areaand deny entry. Stay upwind and keep out of low areas.

* * *Section 7 - HANDLING AND STORAGE* * *Precautions for Safe Handling
Avoid breathing dust, mist, fumes or vapors. Avoid contact with eyes, skin and clothing. Do not eat, drink, orsmoke when using this product. Wear protective gloves and eye/face protection. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for Safe Storage, including any Incompatibilities
Store and handle in accordance with all current regulations and standards. Store in a well-ventilated place. Keepcontainer tightly closed. Keep cool. Keep separated from incompatible substances.

* * *Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION* * *Component Exposure Limits
Glycerin (56-81-5)
OSHA:Mexico

15 mg/m3 TWA (mist, total particulate); 5 mg/m3 TWA (mist, respirable fraction)
10 mg/m3 TWA LMPE-PPT (mist)

Component Biological Limit Values
There are no biological limit values for the component(s) of this product.
Appropriate Engineering Controls
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
Individual Protection Measures, such as Personal Protective Equipment____________________________________________________________
Page 3 of 7

Safety Data Sheets

Product Name: Dye Sublimation Ink Sb300 Black D
SDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Eyes/Face Protection
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick
drench shower in the immediate work area.
Skin Protection
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Consult with a health and safety professional for specific respirators appropriate for your use.

* * *Section 9 - PHYSICAL AND CHEMICAL PROPERTIES* * *Physical State:
Color:
Odor:
pH:
Boiling Point:
Decomposition
Temperature:
LEL:
Vapor Pressure:
Density:
Water Solubility:
Coeff. Water/Oil Dist:
Viscosity:
Oxidizing Properties:
Flammability (solid, gas):

Liquidblackcharacteristic odor
7-10 (20°C)
Not available
Not available
Not available
Not available
Not available
SolubleNot available
5-10 mPas
Not available
Not applicableAppearance:
Physical Form:
Odor Threshold:
Melting Point:
Flash Point:
Evaporation Rate:black liquid
liquidNot available
Not available
Not flammableNot available

UEL:
Vapor Density (air = 1):
Specific Gravity (water = 1):
Log KOW:
Auto Ignition Temperature:
Volatility:
Explosive Properties:

Not available
Not available~1
Not available
Not available
Not available
Not available

Other Property Information
No additional information is available.

* * *Section 10 - STABILITY AND REACTIVITY* * *Reactivity
No reactivity hazard is expected.
Chemical Stability
Stable under normal conditions of use.
Possibility of Hazardous Reactions
Will not polymerize.
Conditions to Avoid
Avoid flames, sparks, and other sources of ignition. Avoid contact with incompatible materials.
Incompatible Materials
acids, bases, oxidizing materials, metal oxides, reducing agents, combustible materials, halocarbons, metals,
metal salts
Hazardous Decomposition
Combustion: oxides of carbon, acrolein, aliphatics* * *Section 11 - TOXICOLOGICAL INFORMATION* * *Acute Toxicity____________________________________________________________
Page 4 of 7

Safety Data Sheets

Product Name: Dye Sublimation Ink Sb300 Black D
SDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Component Analysis - LD50/LC50
The component(s) of this material have been reviewed in various sources and the following selected endpoints
are published:
1,2-Propylene glycol (57-55-6)
Oral LD50 Rat 20 g/kg; Dermal LD50 Rabbit 20800 mg/kg
Glycerin (56-81-5)
Oral LD50 Rat 12600 mg/kg; Dermal LD50 Rabbit >10 g/kg; Inhalation LC50 Rat >570 mg/m3 1 hInformation on Likely Routes of Exposure
Inhalation
irritation, difficulty breathing, headache, nausea
Ingestion
fever, nausea, vomiting, diarrhea, headache, dizziness, sleep disturbances, blood disorders, kidney damage,paralysis, reproductive effects, convulsions, skin disorders, stomach pain, drowsiness, loss of coordination,
unconsciousness
Skin Contact
allergic reactions, irritation, nausea, headache, drowsiness, dizziness, loss of coordination
Eye Contactirritation
Immediate Effects
allergic skin reaction, skin irritation, eye irritation
Delayed Effects
allergic skin reaction
Medical Conditions Aggravated by Exposure
No information available for the product.
Irritation/Corrosivity Dataskin irritation, eye irritation
Respiratory Sensitization
No information available for the product.
Dermal Sensitization
May cause an allergic skin reaction.
Germ Cell Mutagenicity
No information available for the product.
Carcinogenicity
Component Carcinogenicity
No data listed by ACGIH, IARC, NTP, DFG or OSHA is available for the component(s) of this product.
Reproductive Toxicity
No information available for the product.
Specific Target Organ Toxicity - Single Exposure
No target organs identified.
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
Aspiration Hazard
Not expected to be an aspiration hazard.

* * *Section 12 - ECOLOGICAL INFORMATION* * *____________________________________________________________
Page 5 of 7

Safety Data Sheets

Product Name: Dye Sublimation Ink Sb300 Black D
SDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Component Analysis - Aquatic Toxicity
1,2-Propylene glycol (57-55-6)
Fish:

Algae:
Invertebrate:

96 Hr LC50 Oncorhynchus mykiss: 51600 mg/L [static]; 96 Hr LC50 Oncorhynchus
mykiss: 41 - 47 mL/L [static]; 96 Hr LC50 Pimephales promelas: 51400 mg/L [static]; 96Hr LC50 Pimephales promelas: 710 mg/L
96 Hr EC50 Pseudokirchneriella subcapitata: 19000 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L [Static]

Glycerin (56-81-5)
Fish:

96 Hr LC50 Oncorhynchus mykiss: 51 - 57 mL/L [static]

Persistence and Degradability
No information available for the product.
Bioaccumulation
No information available for the product.
Mobility
No information available for the product.
Other Toxicity
No additional information is available.

* * *Section 13 - DISPOSAL CONSIDERATIONS* * *Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
Disposal of Contaminated Packaging
Empty containers may contain product residue. Dispose in accordance with all applicable regulations.

* * *Section 14 - TRANSPORT INFORMATION* * *US DOT Information
Not regulated as a hazardous material for transport.
TDG Information
Not regulated as dangerous goods for transport.
Marine Pollutant
1,2-Propylene glycol (57-55-6)
IBC Code:

Category Z* * *Section 15 - REGULATORY INFORMATION* * *U.S. Federal Regulations
None of this products components are listed under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA
Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b),or require an OSHA process safety plan.
SARA 311/312
Acute Health: Yes Chronic Health: No Fire: No Pressure: No Reactive: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component
1,2-Propylene glycol
GlycerinCAS
57-55-6
56-81-5

CANo
No

MA
No
Yes

MN
Yes
Yes

____________________________________________________________
Page 6 of 7

NJ
Yes
Yes

PAYes
Yes

Product Name: Dye Sublimation Ink Sb300 Black DSDS No. 037-W243775
First issue: 2018/03/07
Revised: 2019/12/16

Safety Data Sheets
Not regulated under California Proposition 65
Canada

WHMIS CLASSIFICATION: D2B.
Canadian WHMIS Ingredient Disclosure List (IDL)
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The
List is composed of chemicals which must be identified on MSDSs if they are included in products which fall under
WHMIS criteria specified in the Controlled Products Regulations and present above the threshold limits listed onthe IDL.
1,2-Propylene glycol (57-55-6)
1%
Chemical Inventory Listings
Component Analysis - Inventory
Component
1,2-Propylene glycol
Glycerin
Disperse dye
Additives

CAS
57-55-6
56-81-5Trade Seclet
Trade Seclet

USYes
Yes
Yes
Yes

CADSL
DSLDSL
DSL

EUEIN
EIN
EIN
NoAU
Yes
Yes
Yes
Yes

PHIL
Yes
Yes
Yes
Yes

JPYes
Yes
Yes
Yes

KR
Yes
Yes
Yes
Yes

CN
Yes
Yes
Yes
Yes

NZ
Yes
Yes
Yes
Yes

* * *Section 16 - OTHER INFORMATION* * *NFPA Ratings: Health: 2 Fire: 1 Reactivity: 0Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; CAS Chemical Abstracts Service; CLP - Classification, Labelling and Packaging; EEC - European EconomicCommunity; EIN (EINECS) - European Inventory of Existing Commercial Chemical Substances; ELN (ELINCS) European List of Notified Chemical Substances; IARC - International Agency for Research on Cancer; IATA International Air Transport Association; IMDG - International Maritime Dangerous Goods; IBC Code - International
Bulk Chemical Code; Kow - Octanol/water partition coefficient; LC50 - Lethal Concentration, 50%; LD50 - Lethal
Dose, 50%; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NTP = National Toxicology
Program; REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - European RailTransport; STEL - Short-term Exposure Limit; TWA - Time Weighted Average; UEL - Upper Explosive Limit
Other Information
The information set forth in this Safety Data Sheet does not purport to be all-inclusive and should be used only asa guide. While the information and recommendations set forth herein are believed to be accurate, the company
makes no warranty regarding such information and recommendations and disclaims all liability from reliance
thereon.

End of Sheet 037-W243775____________________________________________________________
Page 7 of 7