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1 Identification. Product identifier. Trade name POLYESTER TGIC-FREE. Article number: 29,58,59,68,138,149. Restrictions Industrial Powder coating Application. Recommended Use:
Powder coating material. Manufacturer/Supplier:
USA:TIGER Drylac U.S.A., Inc.
3945 Swenson Ave
St. Charles, IL 60174
Phone: +1- 630-587-2918
Fax: +1-630-587-2923
Canada:TIGER Drylac Canada Inc.
110 Southgate Drive
Guelph, Ontario, N1G 4P5
Phone: +1-519-766-4781
Fax: +1-519-766-4787
MexicoTIGER Drylac Mexico S.A. de C.V.
Circuito Exportación 212, Parque Industrial Tres Naciones
San Luis Potosí, SLP, C.P. 78395
Phone +52-444-799-7243
Fax +52-444-799-7244. Informing department: Product Safety Department. Emergency telephone number:
24/7:1-800-255-3924; International:+01 or +001-813-248-0585

2 Hazard(s) identification. Classification of the substance or mixture
Combustible Dust
May form combustible dust concentrations in air.
. Label elements. GHS label elements
The product is classified and labeled according to the Globally Harmonized System(GHS).
. Hazard pictograms Void. Signal word Warning. Hazard statements
May form combustible dust concentrations in air.
. Classification system. NFPA ratings (scale 0-4)

11

Health = 1
Fire = 1
Reactivity = 11. HMIS-RATINGS (SCALEHEALTH

1FIRE

1

REACTIVITY 10 - 4)

Health = 1
Fire = 1
Reactivity = 1. Other hazards. Results of PBT and vPvB assessment. PBT: Not applicable.
. vPvB: Not applicable.

(Contd. on page 2)
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Trade name POLYESTER TGIC-FREE(Contd. of page 1)

3 Composition/information on ingredients. Chemical characterization: Mixtures. Description: Mixture consisting of the following components with harmless additives.
. Hazardous ingredients:
7727-43-7 barium sulphate, natural; barium sulfate
10-25%
13463-67-7 titanium dioxide; titanium (IV) oxide
10-25%
21645-51-2 aluminium hydroxide; aluminum (III) hydroxide
2.5-10%
Acute Tox. 4, H332
. Additional information
For the wording of the listed hazard phrases refer to section 16.

4 First-aid measures. Description of first aid measures. After inhalation Supply fresh air; consult doctor in case of symptoms.
. After skin contact Instantly wash with water and soap and rinse thoroughly.
. After eye contact Rinse opened eye for several minutes under running water.
. After swallowing Seek immediate medical advice.
. Information for doctor. Most important symptoms and effects, both acute and delayed None
. Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures. Extinguishing media. Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcoholresistant foam.
. For safety reasons unsuitable extinguishing media
Gaseous extinguishing agents (e.g. Carbon dioxide) under high pressure. Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
CO, CO2, NOx. Advice for firefighters. Protective equipment:
Put on breathing apparatus.
Wear full protective suit.

6 Accidental release measures. Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Avoid causing dust.
Keep away from ignition sources
Wear protective clothing.
Use breathing protection against the effects of dust.
. Environmental precautions:
Do not allow product to reach sewage system or water bodies.
. Methods and material for containment and cleaning up: Collect mechanically.
. Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
. Protective Action Criteria for Chemicals. PAC-1:
7727-43-7 barium sulphate, natural
15 mg/m³
13463-67-7 titanium dioxide
30 mg/m³
21645-51-2 aluminium hydroxide
8.7 mg/m³(Contd. on page 3)
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Trade name POLYESTER TGIC-FREE(Contd. of page 2)

7631-86-9
1344-28-1
112926-00-8
471-34-1
1314-23-4
14808-60-7
111-42-2

silicon dioxide, chemically preparedaluminium oxide
Silicon dioxide
calcium carbonate
zirconium oxide
quartz (SiO2)
2,2'-iminodiethanol

18 mg/m³
15 mg/m³
18 mg/m³
45 mg/m³
14 mg/m³
0.075 mg/m³
3 mg/m³. PAC-2:
7727-43-7
13463-67-7
21645-51-2
7631-86-9
1344-28-1
112926-00-8
471-34-1
1314-23-4
14808-60-7
111-42-2

barium sulphate, natural
titanium dioxide
aluminium hydroxide
silicon dioxide, chemically preparedaluminium oxide
Silicon dioxide
calcium carbonate
zirconium oxide
quartz (SiO2)
2,2'-iminodiethanol

170 mg/m³
330 mg/m³
73 mg/m³
740 mg/m³
170 mg/m³200 mg/m³
210 mg/m³
110 mg/m³
33 mg/m³
28 mg/m³. PAC-3:7727-43-7
13463-67-7
21645-51-2
7631-86-9
1344-28-1
112926-00-8
471-34-1
1314-23-4
14808-60-7
111-42-2

barium sulphate, natural
titanium dioxide
aluminium hydroxide
silicon dioxide, chemically preparedaluminium oxide
Silicon dioxide
calcium carbonate
zirconium oxide
quartz (SiO2)
2,2'-iminodiethanol

990 mg/m³
2,000 mg/m³
440 mg/m³
4,500 mg/m³
990 mg/m³
1,200 mg/m³
1,300 mg/m³
680 mg/m³
200 mg/m³
130 mg/m³

7 Handling and storage. Handling. Precautions for safe handling No special measures required.
. Information about protection against explosions and fires:




Keep ignition sources away - Do not smoke.

Dust can combine with air to form an explosive mixture.
. Conditions for safe storage, including any incompatibilities. Storage. Requirements to be met by storerooms and containers:
Store only in the original container.
Static charges may build up in the powder. Information about storage in one common storage facility: Not required.
. Further information about storage conditions: None.
. Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection. Additional information about design of technical systems: No further data; see item 7.

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Trade name POLYESTER TGIC-FREE(Contd. of page 3). Control parameters. Components with critical values that require monitoring at the workplace:
7727-43-7 barium sulphate, naturalPEL (U.S.A)
Long-term value: 15* 5** mg/m³*total dust **respirable fraction
REL (U.S.A)
Long-term value: 10* 5** mg/m³*total dust **respirable fraction
TLV (U.S.A)
Long-term value: 5* mg/m³*inhalable fraction; E
EL (Canada)
Long-term value: 5 mg/m³
inhalable
VLE (Mexico) Long-term value: 10 mg/m³
13463-67-7 titanium dioxide
PEL (U.S.A)
Long-term value: 15* mg/m³*total dust
REL (U.S.A)
See Pocket Guide App. A
TLV (U.S.A)
Long-term value: 10 mg/m³
EL (Canada)
Long-term value: 10* 3** mg/m³*total dust;**respirable fraction; IARC 2B
VLE (Mexico) Long-term value: 10 mg/m³
A421645-51-2 aluminium hydroxide
REL (U.S.A)
Long-term value: 2 mg/m³
as Al
TLV (U.S.A)
Long-term value: 1* mg/m³
as Al;*as respirable fraction
EL (Canada)
Long-term value: 10 mg/m³. Regulatory information
PEL (U.S.A): Guide to Occupational Exposure Values (OSHA PELs)
REL (U.S.A): Guide to Occupational Exposure Values (NIOSH RELs)
TLV (U.S.A): Guide to Occupational Exposure Values (ACGIH)
EL (Canada): SOR / 86-304, Control of Hazards 10.19(1)(a)VLE (Mexico): NOM-010-STPS-2014. Additional information:
The lists that were valid during the compilation were used as basis.
. Exposure controls A dust collection system is recommended.
. Personal protective equipment. General protective and hygienic measures
Wash hands during breaks and at the end of the work.
. Breathing equipment:

In case of brief exposure or low pollution use breathing filter apparatus. In
case of intensive or longer exposure use breathing apparatus that is
independent of circulating air.

. Protection of hands:

Protective gloves.

Antistatic gloves. Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the productis a preparation of several substances, the resistance of the glove material can not
be calculated in advance and has therefore to be checked prior to the application.
. Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective
gloves and has to be observed.

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Trade name POLYESTER TGIC-FREE(Contd. of page 4). Eye protection:Safety Glasses. Body protection: Protective work clothing.

9 Physical and chemical properties. Information on basic physical and chemical properties. General Information. Appearance:
Form:
SolidColour:
According to Trade Name
. Odor:
Nearly odourless. Odor threshold:Not applicable.
. pH-value:

Not applicable.

. Change in condition
Melting point/Melting range:
Freezing point :> 50 C / 120F
Not applicable. Flash point:

Not applicable. Flammability (solid, gaseous)

Not applicable.

. Auto-ignition temperature:

Not Available.

. Decomposition temperature:

Not applicable.

. Self-inflammability:

Product is not selfigniting.

. Danger of explosion:

Product is not explosive. However,formation of explosive air/dust mixtures ispossible. Critical values for explosion:
Lower:
Upper:

71 g/m³
Not applicable. Steam pressure:

Not applicable.

. Density (Specific gravity) at 20 °C (68°F). Relative density. Vapor pressure:. Evaporation rate

1.63 g/cm³ (13.6 lbs/gal)
Not applicableNot applicable.
Not applicable.

. Solubility in / Miscibility with
Water:

Insoluble. Partition coefficient (n-octanol/water): Not available.
. Viscosity:
dynamic:
kinematic:

Not applicable.
Not applicable.

. Solvent content:
Organic solvents:

0.0 %Solids content:. Other information

100.0 %
Chemical stability:

Not applicable

10 Stability and reactivity. Reactivity No further relevant information available.
. Chemical stability Not applicable. Conditions to be avoided: No decomposition if used according to specifications.
. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available.
. Incompatible materials: No further relevant information available.

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Trade name POLYESTER TGIC-FREE. Hazardous decomposition products: In case of fire: CO, CO2, NOx(Contd. of page 5)

11 Toxicological information. Information on toxicological effects. Acute toxicity:. LD/LC50 values that are relevant for classification:
Oral LD50 >2,000 mg/kg (rat). Primary irritant effect:. on the skin: No irritant effect.
. on the eye: Possible irritant effects. Sensitization: No sensitizing effect known.
. Additional toxicological information:. Carcinogenic categories. IARC (International Agency for Research on Cancer)
13463-67-7 titanium dioxide
7631-86-9 silicon dioxide, chemically prepared112926-00-8 Silicon dioxide
14808-60-7 quartz (SiO2)
111-42-2 2,2'-iminodiethanol2B
3312B. NTP (National Toxicology Program)
14808-60-7 quartz (SiO2)K. OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

12 Ecological information. Toxicity. Aquatic toxicity: No further relevant information available.
. Persistence and degradability No further relevant information available.
. Behaviour in environmental systems:. Bioaccumulative potential No further relevant information available.
. Mobility in soil No further relevant information available.
. Additional ecological information:. General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water
bodies or sewage system.
. Results of PBT and vPvB assessment. PBT: Not applicable.
. vPvB: Not applicable.
. Other adverse effects No further relevant information available.

13 Disposal considerations. Waste treatment methods. Recommendation









Must not be disposed of together with household garbage. Do not allow
product to reach sewage system.

. Uncleaned packagings:. Recommendation: Disposal must be made according to official regulations.

14 Transport information. UN-Number. DOT, ADR, IMDG, IATA
. UN proper shipping name
. DOT, IMDG, IATANotVoid
Not Applicable
Void(Contd. on page 7)
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Trade name POLYESTER TGIC-FREE. ADR. Transport hazard class(es). DOT, IMDG, IATA
. Class. ADR, ADN. Class. Packing group. DOT, IMDG, IATA
. ADR(Contd. of page 6)

N/A
Void

Void
Not regulated.
Void
N/A
Void
Void
N/A
Not applicable.

. Environmental hazards:. Transport in bulk according to Annex II ofMARPOL73/78 and the IBC CodeNot applicable.
. UN "Model Regulation":Void

15 Regulatory information. Safety, health and environmental regulations/legislation specific for the substance ormixture. SARA (Superfund Amendments and Reauthorization Act):. Section 355 (Extremly hazardous substances):
None of the ingredients is listed.
. Section 313 (Specific toxic chemical listings):
7727-43-7 barium sulphate, natural
1344-28-1 aluminium oxide. TSCA (Toxic Substances Control Act):7727-43-7 barium sulphate, natural
13463-67-7 titanium dioxide
21645-51-2 aluminium hydroxide
7631-86-9 silicon dioxide, chemically prepared1332-58-7 kaolin1344-28-1 aluminium oxide
119-53-9 Benzoin471-34-1 calcium carbonate
1860-26-0 2-ethyl-N,N-bis(2-ethylhexyl)hexylamine

ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE. Hazardous Air Pollutants
111-42-2 2,2'-iminodiethanol. Proposition 65:. Chemicals known to cause cancer:
13463-67-7 titanium dioxide. Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
. Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
. Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
. Cancerogenity categories. EPA (Environmental Protection Agency)
7727-43-7 barium sulphate, naturalD, CBD(inh), NL(oral). TLV (Threshold Limit Value established by ACGIH)
13463-67-7 titanium dioxide1332-58-7 kaolin1344-28-1 aluminium oxide

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Trade name POLYESTER TGIC-FREE
1314-23-4
14808-60-7
111-42-2

zirconium oxidequartz (SiO2)
2,2'-iminodiethanol(Contd. of page 7)

A4
A2
A3

. NIOSH-Ca (National Institute for Occupational Safety and Health)13463-67-7 titanium dioxide
14808-60-7 quartz (SiO2). GHS label elements
The product is classified and labeled according to the Globally Harmonized System(GHS).
. Hazard pictograms Void
. Signal word Warning. Hazard statements
May form combustible dust concentrations in air.
. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
These data are based on our present knowledge. However, they shall not constitute aguarantee for any specific product features and shall not establish a legally valid
contractual relationship.
. Relevant phrases
H332 Harmful if inhaled.
. Date of preparation / last revision 08/28/2020 / . Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity – Category 4US