‒

ᜒ๫˟‒

1D and 3D Photonic Crystals

₇㢟㸸㸦୍ḟඖ࠾ࡼࡧ୕ḟඖࣇ࢛ࢺࢽࢵࢡ⤖ᬗ㸧ㅮ ᖌ㸸Jae-Suk Lee ᩍᤵGwangju Institute of Science andTechnology (GIST), South Korea᪥ ᫬㸸2019 ᖺ 4 ᭶ 9 ᪥㸦ⅆ㸧15: 30~17:00
ሙ ᡤ㸸ᕤᏛ㒊ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷࢭ࣑ࢼ࣮ᐊ 2
Brush block copolymers (BBCPs) can be prepared by the polymerizationof macromonomers. However, this method intensively requires high-quality
macromonomers. Here, we report the combination of living anionic
polymerization and ring-opening metathesis polymerization to synthesize
the precisely controlled macromonomers and BBCPs.
Norbornene-end-functionalized macromonomers were prepared by living
anionic polymerizaion and ω-end functionalization with a norborenene
derivative. BBCPs were synthezied by sequential ROMP of two
macromonomers using a Grubbs catalyst. The ROMP was also utilized in
the combination of a monomer containing polyhedral oligomericsilsesquioxane (POSS) and a macromonomer to prepare POSS-bottlebrushblock copolymers (POSSBBCPs). The self-assembly allow the BBCPs and
POSSBBCPs to be converted to 1D PCs with well-defined lamellar
nanostructures and distinct light-reflection properties.
In the last section of our presentation, we introduce the self-emulsion
polymerization (SEP) technique which was develoved in our lab and report
one of their application for the 3D photonic application.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 బ⸨ ᩄᩥ㸦ෆ⥺㸸㸴㸴㸮㸰㸧ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇㢟㸸Synthesis of Helical Poly(phenylacetylene)s

Bearing L-Amino Acid Derivatives and Their
Applications in Chiral Separation by HPLCㅮ ᖌ㸸Chunhong Zhang ᩍᤵࣁࣝࣅࣥᕤ⛬኱Ꮫ୰ᅜ
᪥ ᫬㸸2019 ᖺ 5 ᭶ 16 ᪥㸦ᮌ㸧15: 30~17:00
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ኱఍㆟ᐊ MC526
To develop effective chiral stationary phases (CSPs) with high chiralrecognition abilities is one key point of chiral separation in high-performanceliquid chromatography (HPLC). Many polysaccharide-based CSPs have beendeveloped and even commercialized. Recent years, some synthetic helicalpolymers have also attracted researchers’ great interest. Herein, optically active
helical poly(phenylacetylene)s bearing L-amino acid derivatives were designed
and synthesized as CSPs for HPLC, which exhibited high chiral recognition
abilities for some racemates.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧 㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃ
ࡉࢀ࡚࠸ࡲࡍࠋ
㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 బ⸨ ᩄᩥ㸦ෆ⥺㸸㸴㸴㸮㸰㸧ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇ 㢟㸸Quantum mechanical and molecular dynamics

studies of vibrational spectraof hydrogen-bonded systemsㅮ ᖌ㸸Prof. Marek J. Wójcik

Faculty of Chemistry,
Jagiellonian University, Poland᪥ ᫬㸸2019 ᖺ 5 ᭶ 21 ᪥㸦ⅆ㸧13:15~14:15
ሙ ᡤ㸸⌮Ꮫ㒊 7 ྕ㤋 2 㝵 219࣭220 ᐊ

せ᪨㸸Theoretical modeling of vibrational spectra of ices and aqueous
ionic solutions will be presented. I will also present results of ourrecent molecular dynamics studies of hydrogen-bonded crystals andpolymers, and near infrared (NIR) experimental and theoreticalstudies of alcohols, imidazole and nucleic acid bases.

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸⌮Ꮫ◊✲㝔໬Ꮫ㒊㛛 Ṋḟᚭஓ㸦ෆ⥺㸸3535㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇ 㢟㸸ᛂ⏝໬Ꮫ⣔ 105 ㅮ⩦఍105 ᇶ♏ㅮ⩦ ㅮᖌ㸸ᮌᮧ ᝅ   ໭ᾏ㐨኱ᏛᕤᏛ◊✲㝔 ᕤᏛ⣔ᢏ⾡ࢭࣥࢱ࣮
᪥⛬㸸2019 ᖺ 5 ᭶ 29 ᪥(Ỉ) 16:00 - 18:00
఍ሙ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ

1 㝵ࢭ࣑ࢼ࣮ᐊ

ཷㅮᑐ㇟⪅㸸ᛂ⏝໬Ꮫ⣔ NMR ࣮ࣘࢨ࣮ㅮ⩦఍ෆᐜ㸸
1) 1D,2DNMR ࡢ
2)ᐃࣃ࣓࣮ࣛࢱ࡟ࡘ࠸࡚

NMR ࢹ࣮ࢱฎ⌮ࡢᡭ㡰3) Delta Ver.5 ࡢ᧯సἲࡢ⤂௓

༠㈶㸸   ᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ኱⇃ Ẏ ෆ⥺ ᕤᏛ⣔ᢏ⾡ࢭࣥࢱ࣮   ᮌᮧ ᝅ ෆ⥺ ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ࠥㅮ₇఍ࡢࡈ᱌ෆࠥ
₇㻌 㢟䠖㻌
ㅮ㻌 ᖌ䠖The Engineering of Surfaces: fromparticles to solar cells
Prof. David A. Lewis
Flinders Institute for Nanoscale
Science and Technology, Flinders
University᪥㻌 ᫬䠖 㻞㻜㻝㻥 ᖺ 㻢 ᭶ 㻡 ᪥䠄Ỉ䠅㻝㻢㻦㻟㻜ࠥ㻝㻤㻦㻜㻜ሙ㻌 ᡤ䠖 ໭ᾏ㐨኱Ꮫ㻌 ⌮Ꮫ㒊ᮏ㤋 㻺㻙㻟㻜㻤 ᐊඹ㻌 ദ䠖㻌 ໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔䠈䝣䝻䞁䝔䜱䜰໬Ꮫᩍ⫱◊✲䝉䞁䝍䞊䠈㻌໭ᾏ㐨኱Ꮫ≀㉁⛉Ꮫ䝣䝻䞁䝔䜱䜰䜢㛤ᣅ䛩䜛 㻭㼙㼎㼕㼠㼕㼛㼡㼟 䝸䞊䝎䞊䝥䝻䜾䝷䝮㻌せ ᪨䠖In this presentation, I will focus on recent research in two quite different areas:(i) The manipulation of the surface chemistry of particles to control theirinteraction and the rheological behavior in nanofluids. In this part of thepresentation, I will discuss the modification of particles through very highattachment density, uniform layers and the surprising rheological behavior ofthis particles in high solids fluids.
(ii) The workfunction of interfaces in OPV’s are critical to maximize electron
and hole transport across the layers, yet depending on how the subsequent
layers are deposited, the structure and the properties may not be what is
expected. In this part, I will discuss recent results on the chemistry andelectronic properties of metal oxides, such as molybdenum oxide deposited asthin films on polymer substrates and how the workfunction changes upon
exposure to moisture.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ๼քಕ୉ָ୉ָӅཀྵָ‫ڂݜ‬ӅԿָ෨໵  ଞӿ ‫ܡ‬   ʤ7HO0DLONHL#VFLKRNXGDLDFMSʥ㻌ᜒ๫˟‒ ‒

ԍ ୌʁ Pushing the Limits of N-heterocyclic Carbenesߪ ࢥʁ Prof. Eunsung Lee

POSTECH,Pohang, Republic of Koreaೖ ࣎ʁ ೧  ݆  ೖʤۜʥʛ ৖ ॶʁ޽ָ෨ ࡒྋʀԿָ‫ܧ‬౫ 0& ‫࣪گ‬㻌གྷࢭʁN-Heterocyclic Carbenes (NHCs) have been intensively explored forstabilizing unstable species such as radicals and zerovalent nonmetal species,
and for activating small molecules such as CO, H2, NH3, N2O, NO, etc.
Such a capability of NHCs can be attributed to their strong donor charactersan d s t eri c tu n ab il it y th at l ead t o th e r emar kab l e r eact ivi t y.
Recently, we reported N-heterocyclic carbene nitric oxide ʤNHCNO)
radicals, which can be also considered as iminoxyl radicals. We also foundthat triazenyl cations stabilized by NHC form the corresponding triazenyl
radicals upon the treatment of elemental potassium as a reductant.
With the novel reactivity of NHCs, we have also been exploring porous
metal–organic frameworks (MOFs) and cages (MOCs) with various
N-heterocyclic carbene precusors, imidazolium salts, and metal ions due totheir potential applications such as catalysis, gas storage, molecularseparations, etc.

༠㈶㻌 䠖㻌

㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ޽ָ‫ڂݜ‬ӅԢ༽Կָ෨໵  ґ౽ ഻ʤ಼તʁʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒
₇ 㢟㸸Asymmetric Synthesis of N-Arylamines andDiamines by Copper-CatalyzedHydroamination of Alkenesㅮ ᖌ㸸Dr. Saki Ichikawa

Department of Chemistry
Massachusetts Institute of Technology᪥ ᫬㸸2019 ᖺ 6 ᭶ 13 ᪥㸦ᮌ㸧16:30~18:00
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ኱఍㆟ᐊ㸦MC526㸧

Copper-catalyzed asymmetric hydroamination is an establishedmethod to access various chiral amines with high enantioselectivity.
However, the synthesis of several important classes of enantioenrichedamines has been hindered by competitive side reactions.
Herein, we developed broadly applicable hydroamination protocols
for the asymmetric synthesis of N-arylamines and 1,2-diamines.
ᕷᕝ༤ኈࡣᮾி኱Ꮫ࡛Ꮫኈㄢ⛬ࢆಟ஢ᚋࠊ⡿ᅜ࣭0,7 ࡟࡚༤ኈྕࢆྲྀᚓ
ࡉࢀ࡚࠸ࡲࡍࠋᮏㅮ₇࡛ࡣ⡿ᅜ࡛ࡢᏛ఩◊✲ࡢෆᐜ࡞ࡽࡧ࡟ࡈ⮬㌟ࡢ␃
Ꮫ⤒㦂ࡸ༞ᴗᚋࡢ◊✲⪅ࡢ࢟ࣕࣜ࢔ࣃࢫ࡟ࡘ࠸࡚ࡶࡈㅮ₇࠸ࡓࡔࡁࡲࡍࠋ
ᮏㅮ₇䛿䚸኱Ꮫ㝔⥲ྜ໬Ꮫ㝔䛄໬Ꮫ◊✲ඛ➃ㅮ⩏䠄ಟኈㄢ⛬㑅ᢥ⛉┠䠅䠋㻌⥲ྜ໬Ꮫ≉ู◊✲➨஧䠄༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠䠅䛅䛾୍㒊䛸䛧䛶ㄆᐃ㻌䛥䜜䛶䛔䜎䛩䚹㻌
㻌
༠㈶㻌 䠖㻌

㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㻌㻌㐃⤡ඛ䠖ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛㻌 㻌 ஂಖ⏣㻌 ᾈྖ䠄ෆ⥺䠖㻤㻝㻞㻣䠅㻌

‒

ᜒ๫˟‒
₇ 㢟㸸Mystery of gel working on Contact Lenses~Chance & Necessity~ㅮ ᖌ㸸Dr. Eri Ito
Menicon Co., Ltd. / Nagoya Institute of Technology᪥ ᫬㸸2019 ᖺ 6 ᭶ 19 ᪥㸦Ỉ㸧16:30~17:30

ㅮᖌࡢ෗┿ࢆ
ධࢀ࡚ୗࡉ࠸ሙ ᡤ㸸⌮Ꮫ㒊 7 ྕ㤋 219 ྕᐊ
せ᪨㸸Contact lenses are the most frequent examples of industrial useof hydrogels. It has already been 60 years since their first use in Contact
Lenses starting with 2-Hydroxy ethyl methacrylate (HEMA). Is it acompleted area? The answer is “No”.
The material is still evolving through fusion of heterogeneoustechnologies and utilization of classical to advanced polymer science.
Currently the mainstream research uses the so-called “silicone
hydrogel” as a material for Lenses which is a copolymer ofsilicone-based monomer suitable for hard lenses and hydrophiliccomponents. Low biocompatibility of the hydrophobic silicone
component is a deficiency although silicone possess high permeability ofgases. Therefore, control of the interfacial properties between the lenses
and tear film and the nanoscale structure have become particularly
important.
Therefore, it is necessary to advance towards the next level oftechnology by elucidating the detail mechanism for developing
innovative products in future.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸⌮Ꮫ◊✲㝔໬Ꮫ㒊㛛 ゅ஬ ᙲ㸦ෆ⥺㸸3474㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ᜒ๫˟‒ ‒

ԍ ୌʁ Revisiting the paradigm of transition states

and reaction mechanismsߪ ࢥʁ Prof. Srihari Keshavamurthy(Indian Institute of Technology
Kanpur, India) ೖ ࣎ʁ ೧  ݆  ೖʤ݆ʥʛ ৖ ॶʁཀྵָ෨ຌ‫ ؙ‬1 ࣪㻌གྷࢭʁThe concepts of transition states and reaction mechanisms havebeen around for more than a century. Indeed, these concepts have shaped
modern chemistry as we know it and it is hard to think of understanding
chemical reactivity without them. In fact, we have gotten so comfortablewith these models that we believe every reaction must conform to `theparadigm’. However, over the last two decades, thanks to developments
in experiments and theory, uncomfortable questions are being asked
about the usual assumptions that one makes to deduce the reaction
mechanisms. Are these examples just exceptions? Can we still fit these
new observations by making small extensions to the old paradigm? Or,
do we have to shift paradigms altogether?
In this talk I will briefly introduce and discuss some of these recent
developments and the challenges that they pose to theoretical chemists.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁཀྵָ‫ڂݜ‬ӅԿָ෨໵  ෤࣏ బ໷ʤ಼તʁʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒
₇ 㢟㸸How Chemistry Brings in New Physics Problems:

Stabilizing OBDD Structure of Block Copolymers by
Configurational Regularityㅮ ᖌ㸸Hsin-Lung Chen ᩍᤵ
Department of Chemical Engineering,
National Tsing Hua University, Taiwan᪥ ᫬㸸2019 ᖺ 7 ᭶ 1 ᪥㸦᭶㸧15: 30~17:00
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ୰఍㆟ᐊ MC102
Block copolymers constitute a fascinating class of soft materials, whose remarkablefeatures lie in their capability of self-assembling into a broad spectrum of nanostructures. It isbelieved that the physics of block copolymer is well understood. In the theoretical frameworkof block copolymers, the constituent blocks are normally coarse-grained into Gaussian chainswith the segmental interactions lumped into an interaction parameter; in this case, thechemical details of the polymers are lost. In recent years, new complex structures have been
disclosed in block copolymers possessing specific chemical characteristics, including chirality,
tacticity and conformational asymmetry. These findings point out a direction that chemistry
can play an active role to bring in new intriguing problems in the physics of block
copolymers.
Here I would like to demonstrate that the introduction of configurational regularity into
one of the constituent blocks in a diblock copolymer can stabilize the ordered bicontinuous
double diamond (OBDD) morphology, which was commonly considered to be unstable
relative to ordered bicontinuous double gyroid (OBDG) structure. We discovered that OBDD
existed as the thermodynamically equilibrium bicontinuous structure temperature in a block
copolymer composed of a stereoregular block, syndiotactic polypropylene-block-polystyrene(sPP-b-PS). A thermally-induced transition from OBDD to OBDG occurred upon heating,signifying that OBDD and OBDG represent the stable structure at lower and higher
temperature, respectively. The role of configurational regularity was further consolidated via
isotactic polypropylene-block-polystyrene (iPP-b-PS) system, where the diblock was also
found to exhibit OBDD morphology and OBDG-OBDD transition. I will address thesignificance of the release of enthalpy via the helical segment formation and its resultant
inter-helix association by the stereoregular block for stabilizing the OBDD structure.

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧 㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃ
ࡉࢀ࡚࠸ࡲࡍࠋ
㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 బ⸨ ᩄᩥ㸦ෆ⥺㸸㸴㸴㸮㸰㸧ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ᜒ๫˟‒ ‒

ԍ ୌʁ Diverse applications using a two dimensionaltransition metal dichalcogenide alloy layerߪ ࢥʁ Dr. Byungjin Cho

Assistant Professor
Department of Advanced Material
Engineering, Chungbuk National
University, Republic of Koreaೖ ࣎ʁ ೧  ݆  ೖʤ໨ʥʛ ৖ ॶʁ޽ָ෨ ࡒྋʀԿָ‫ܧ‬౫ 0& ‫࣪گ‬㻌

གྷࢭʁCompositionally variant 2D atomic layers have attracted much interest,
offering the possibility of creating a large number of electronic and sensing
applications. In this seminar, two applications based on 2D TMDs will be addressed:transistor and sensor.
Firstly, we will introduce high performance transistor applications via approach ofutilizing unique 2D TMD alloy synthesis methods. The two-dimensional WSe2–
based transistor with mixed transition layer containing van der Waals (M-vdW,
NbSe2/WxNb1−xSe2/WSe2) junction realizes atomically sharp interface, exhibiting
the superior transistor performance. Secondly, we will show that two-dimensional(2D) metal (NbSe2)−semiconductor (WSe2)-based flexible, wearable, andlaunderable gas sensors can be prepared through simple one-step chemical vapor
deposition of prepatterned WO3 and Nb2O5. Compared to a control device with a
Au/ WSe2 junction, gas-sensing performance of the 2D NbSe2/WSe2 device wassignificantly enhanced, which might be attributed to the formation of a NbxW1−xSe2
transition alloy junction lowering the Schottky barrier height.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ޽ָ‫ڂݜ‬ӅԢ༽Կָ෨໵  ෱࡜ ߔधʤ಼તʁʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮



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₇ 㢟㸸Sodium-ion Batteries– Post Li-ion Energy Storage System for Futureㅮ ᖌ㸸Prof. Li Lu

National University of Singapore,
Singapore᪥ ᫬㸸 2019 ᖺ 7 ᭶ 12 ᪥㸦㔠㸧 14:45 ~ 15:45
ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ ࢭ࣑ࢼ࣮ᐊ 2
せ ᪨: /X ‫گ‬दͺɼ஦ࠅʀੜ՜୉ָͲर࢞՟ఖΝर྅‫ޛ‬ɼϗϩάʖʀϩʖϲΟϱΩφϨρέ୉ָͲദ࢞ߺΝखಚ͢ͱ͏Ζࠅࡏ੓Ν༙ͤΖ‫͍Ͳंڂݜ‬Εɼ
೧Ͷ 186 ͹‫گ‬दͶ஥೜ͪ͢ɽ‫Ͳࡑݳ‬ͺɼ༹ʓ͵ు‫ـ‬Կָυώ΢ηΏ‫ک‬༢ుରമຜ͵ʹ͹ψόࡒྋ߻੔෾໼Ν‫ݙ‬ӀͤΖ੊ֆ਼༙͹‫͍Ͳंڂݜ‬Ζɽ͞ΗΉͲ͹༹ʓ͵ࡒྋ߻੔Ͷ‫ͤؖ‬Ζ઎ۨద͵‫ڂݜ‬Νߨͮͱ͘ͱ͕Εɼྭ͓ͻɼϟΩωΩϩΠϫ΢΢ϱήͶ‫ͤؖ‬Ζ॑གྷ͵ॽ੸͹ஸं͹Ҳਕͳ͢ͱ΍எΔΗ
ͱ͏ΖɽͤͲͶ  ๅۛ͏࿨ชΝ൅න͢ͱ͕Εɼଡ͚͹ࠅࡏճ٠Ͳডଶߪ
ԍंΏक࠷ंΝແΌɼ͠ΔͶɼଡ͚͹ࠅࡏࢿ͹ΦυΡνʖ΍ແΌͱ͏Ζɽ͞ΗΉͲͶɼ༹ʓ͵ࠅ͹‫ڠͳंڂݜ‬ಋ‫ڂݜ‬Ν਒Όͱ͕Εɼ‫Ͳࡑݳ‬ͺɼుஓࡒྋ෾໼Ν‫ݙ‬ӀͤΖ‫ंڂݜ‬͹ҲਕͲ͍ΖɽຌߪԍͲͺ࣏੊େుஓͳ͢ͱ‫غ‬ଶ͠Ηͱ͏ΖψφϨΤϞ΢ΨϱుஓΝ஦ৼͳ͢ͱɼ࠹઎୼͹‫ڂݜ‬Ν়ղ͢ͱ͏͚ͪͫɽ
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ୕ᾆ ❶㸦ෆ⥺㸸7116㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ᜒ๫˟‒ ‒

ԍ ୌʁ Novel Triphenylamine-based Polymers Towards

Emergent Optoelectronic Applicationsߪ ࢥʁ Prof. Guey-Sheng LIOU
Institute of Polymer Science and Engineering,
National Taiwan Universityೖ ࣎ʁ ೧  ݆  ೖʤۜʥʛ ৖ ॶʁϓϫϱτΡΠԢ༽Ռָ‫ڂݜ‬౫  ֌ ιϝψʖ࣪̏㻌གྷࢭʁThis article describes the recent development of triphenylamine (TPA)-based
advanced materials for various optoelectronic applications, such as electrochromic(EC), electrofluorochromic (EFC), and polymeric memory devices. We herein
systemically discuss the structural design, optical and electrical properties ofdifferent TPA-containing high-performance polymers (HPPs) that will bebeneficial for polymer chemists and scientific community to have deeper andbroader understanding of the recent developments and further prompt theengineering and conceptual design of materials for a number of emerging
applications (data storage, displays, and flexible electronics). Thus, a majority of
the recent works in our laboratory involving the synthesis and property evaluationof functional HPPs as well as their structural design by using the respective novel
TPA-based monomers will be included in this talk as the application of AIE-active
PL luminescent and EC materials with interesting color transitions, good EC
reversibility in the visible region or NIR range, and EFC (so called
electrochemically photo-switching) devices. The relation between structures andproperties of the resulted functional high-performance polymers will be presented
in terms of their functionality.
References:
1) H. J. Yen, G. S. Liou*, Design and Preparation of Triphenylamine-based Polymeric Materials Towards
Emergent Optoelectronic Applications. Prog. in Polym. Sci., 2019, 89, 250-287 (reviewer article).
2) H. T. Lin, C. L. Huang, G. S. Liou*, Design, Synthesis and Electrofluorochromism of New Triphenylamine
Derivatives with AIE-Active Pendent Groups. ACS Appl. Mater. Interfaces, 2019, 11, 11684-11690.


ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ
࿊ཙ઎ʁ޽ָ‫ڂݜ‬ӅԢ༽Կָ෨໵  ࠦ౽ ෆชʤ಼તʁʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇ 㢟㸸ᛂ⏝໬Ꮫ⣔ 105 ㅮ⩦఍12(6< ㅮ⩦ㅮᖌ㸸ᮌᮧ ᝅ   ໭ᾏ㐨኱ᏛᕤᏛ◊✲㝔 ᕤᏛ⣔ᢏ⾡ࢭࣥࢱ࣮
᪥⛬㸸2019 ᖺ 7 ᭶ 17 ᪥(Ỉ) 16:00 - 18:00
఍ሙ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ

1 㝵ࢭ࣑ࢼ࣮ᐊ

ཷㅮᑐ㇟⪅㸸ᛂ⏝໬Ꮫ⣔ NMR ࣮ࣘࢨ࣮ㅮ⩦఍ෆᐜ㸸
1) NOESY ࡢᴫせ2) 1D NOESYࠊ2D NOESY ࡢ
3)

༠㈶㸸

ᐃ᧯స

NOE ࡛▱ࡗ࡚࠾ࡁࡓ࠸ࡇ࡜   ᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ኱⇃ Ẏ ෆ⥺ ᕤᏛ⣔ᢏ⾡ࢭࣥࢱ࣮   ᮌᮧ ᝅ ෆ⥺ ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ᜒ๫˟‒ ‒ԍ ୌʁ

Quantum Transport and Chemistry
for Smart Nanosensors

ߪ ࢥʁ Dr. Nicolas Clément

LIMMS/CNRS-IIS andInstitute of Industrial Science,
The University of Tokyo, Japanೖ ࣎ʁ ೧  ݆  ೖʤۜʥʛ ৖ ॶʁ޽ָ෨ ࡒྋʀԿָ‫ܧ‬౫ 0& ‫࣪گ‬གྷ ࢭʁ
Our work focuses on the development of a new class of versatile,
mass-fabrication-compatible and energy-efficient devices and sensors by indirectly
assessing to complex molecular interactions from current measurements. To reachthis goal, we use concepts inspired by the mesoscopic physics community and apply
them to electrochemical or (bio-) molecular systems. Sensors are in the 10 nm range,
an ideal length scale for statistical analysis and single entity measurement. Moreprecisely, we have demonstrated the measurement of ʌ-ʌ electronics couplings fromcurrent measurements, which shows the reliability of Landauer-type formalism formolecular electronics, at a quantitative level. We now extend such formalism tobio-electrochemistry, with target applications in cancer research. Finally, we also
exploited non-Coulombic ion-specific interactions for ion sensing with target
applications of rare earth elements sensors in deep-sea and and the monitoringhyponatremia in cirrhotic patients.

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ޽ָ‫ڂݜ‬ӅԢ༽Կָ෨໵  ౣీ ෆ޼ʤ಼તʁʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇ 㢟㸸Synthesis and Characterization ofSpectroscopically Intriguing Phthalocyanines
and Cyclic Pyrrole Compoundsㅮ ᖌ㸸Prof. Nagao Kobayashiᑠᯘ㛗ኵඛ⏕Faculty of Textile Science andTechnology, Shinshu University.
᪥ ᫬㸸2019 ᖺ 7 ᭶ 23 ᪥㸦ⅆ㸧16:00~18:00
ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ㸯㝵ࢭ࣑ࢼ࣮ᐊせ ᪨㸸ࣇࢱࣟࢩ࢔ࢽࣥ(Pc)ࢆྵࡴࢸࢺࣛ࢔ࢨ࣏ࣝࣇ࢕ࣜࣥ(TAP)㢮ࡢࢫ࣌ࢡࢺࣝࡣࠊ᭱㛗Ἴ㛗྾཰ᖏࡢ⚗ไࡢᗘྜ࠸ࡀ㏻ᖖࡢ࣏ࣝࣇ࢕ࣜࣥ
㢮ࡼࡾᙅࡃࠊᐇ㦂ࢹ࣮ࢱࡢ⌮ㄽⓗ⪃ᐹࡀࡋࡸࡍ࠸ࠋ௒ᅇࡣ୺࡟ㅮ
₇⪅ࡢ◊✲࠿ࡽࠊศගᏛⓗ࣭㟁Ẽ໬Ꮫⓗ࡟㠃ⓑ࠸⤖ᯝࢆࡶࡓࡽࡋ
ࡓ⣔ࢆࠊ᫬㛫ࡢチࡍ⠊ᅖ࡛⤂௓ࡍࡿࠋලయⓗ࡟ࡣ౛࠼ࡤࠊ1) 1000
nm ௨ୖ࡟୺྾཰ࢆ᭷ࡍࡿ Pc, 2)␗ᖖ࡟ᙉᗘࡢᙉ࠸㟁Ⲵ⛣ື྾཰ᖏࢆ᭷ࡍࡿ TAP, 3) ศᏊࡢᑐ⛠ᛶ(ᗄఱᵓ㐀)࡜㓟໬㑏ඖ㟁఩ࡢ⥡㯇࡞ᑐᛂࠊ4) ㌶㐨ࡢᑐ⛠ᛶ࣭࢚ࢿࣝࢠ࣮‽఩ࡢࢳࣗ࢘ࢽࣥࢢ࡟ࡼ
ࡿ㸰ศᏊ㛫┦஫స⏝ࡢ on-off, 5) 10 ಶࡢࣆ࣮ࣟࣝ࠿ࡽ࡞ࡿ⎔≧໬ྜ≀࡞࡝࡛࠶ࡿࠋ

༠㻌 ㈶㻌 䠖㻌㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ⊦⇃Ὀⱥ㸦ෆ⥺:6557㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ᜒ๫˟‒ ‒ԍ ୌʁOrganic/Inorganic Solid Electrolytes for

Solid-State Lithium Batteriesߪ ࢥʁ Prof. Fei Chen

State Key Laboratory of Advanced Technology
for Materials Synthesis and Processing,Wuhan University of Technology, China
ೖ ࣎ʁ2019 ೧ 7 ݆ 25 ೖʤ໨ʥ10:30ʛ12:00
৖ ॶʁϓϫϱτΡΠԢ༽Ռָ‫ڂݜ‬౫ ιϝψʖ࣪ 1
གྷ ࢭʁ
Recently, all solid-state lithium batteries (ASSLBs) have been paid worldwide attention due to their safety andhigh energy density features. In order to enable ASSLBs to operate at low temperature and high rate andexhibit high capacity, the solid electrolyte should have high ionic conductivity, electrochemical stability,
mechanical properties and good interfacial contact with electrode materials. However, none of the solid
electrolyte materials currently studied can meet the above requirements at the meantime: The advantages ofinorganic solid electrolytes usually lie in ionic conductivity, electrochemical stability, and mechanicalproperties rather than interfacial contact, while organic solid electrolytes are the opposite. In this work, wehave prepared PEO/LLZO solid electrolyte with complementary advantages and applied it to ASSLBs. Firstly,
molecular dynamic simulations were performed to study the phase transition of LLZO from low ionic
conductive tetragonal phase to highly ionic conductive cubic phase. Results showed that, by introducing a few
lithium vacancies into LLZO lattice, the cubic phase can be efficiently stabilized at room temperature.
Secondly, field assisted sintering technology and conventional solid-state method were used to prepare LLZO.
By regulating lithium concentration and framework structure, Ta-doped LLZO with ionic conductivity as highas 1.1×10-3 Scm-1 was obtained. Thirdly, the crystallization behavior, micromorphology, ion mobility,
electrochemical stability and contact stability to lithium metal of PEO-LLZO solid electrolyte with different
LLZO content were studied. With the change of LLZO content, the ionic conductivity of PEO-LLZO
composite solid electrolyte has two peaks at 7.5% and 60%. Finally, two composite solid electrolytes wereapplied to ASSLBs (LiFePO4/Li). All the ASSLBs can be safely operated over a wide range of current density(0.2~2C) and temperature (30~60oC) without incurring damage. ASSLBs with PEO-7.5%LLZO-SN solid
electrolyte exhibit excellent cycling stability and prolonged life. At 1C and 60oC, the specific capacity of the500th cycle is 108.8 mAh·g-1. Capacity retention rate is >80.0%.

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ޽ָ‫ڂݜ‬ӅԢ༽Կָ෨໵  ౣీ ෆ޼ʤ಼તʁ6576ʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇ 㢟㸸 Chirality in Dynamic Combinatorial Chemistryㅮ ᖌ㸸 Dr. G. Dan Pantos

Department of Chemistry, University of Bath, UK᪥ ᫬㸸 2019 ᖺ 7 ᭶ 26 ᪥㸦㔠㸧16:00 ~ 17:30
ሙ ᡤ㸸 ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ㸯㝵ࢭ࣑ࢼ࣮ᐊせ ᪨㸸
Chirality is at the core of all biological processes as it influences protein(mis)folding, substrate recognition etc. Unsurprisingly, point chirality impacts
the outcome of dynamic combinatorial libraries (DCLs). In some cases,
enantiomeric or diastereomeric products are formed when chiral building blocks
are combined, while in other cases structural divergence is observed.
Structurally Divergent Reactions on Racemic Mixtures (SDRRM) lead to two
distinct chemical entities starting from two enantiomers.1 We will discuss theoutcomes of chiral DCLs including the first Dynamic Combinatorial approach togenerate structural divergence from racemic building blocks. The divergence isdue to a stereospecific electron-donor (D) – electron-acceptor (A) interaction,
leading to structurally distinct pseudorotaxanes. These factors, combined with adifference in the stability of the final products, lead to the spontaneous assemblyof two structurally different, non-isomeric [2]catenanes: one with a DAAD
aromatic stack, while the other has a DADD stack. This work provides a new
approach towards understanding and developing SDRRMs and raises thepossibility of supramolecular interactions in aqueous media, playing a crucialrole in the biological world’s homochirality.2,3
References
1. Miller, L. C. & Sarpong, R. Chem. Soc. Rev. 2011, 40, 4550
2. Guijarro, A. & Yus, M. The Origin of Chirality in the Molecules of Life: a Revision from Awareness to
the Current Theories and Perspectives of this Unsolved Problem. (RSC, Cambridge, UK, 2008).
3. Amplification of Chirality (Ed. K. Soai). Topics in Current Chemistry 2008, 284, 1.

ᮏㅮ₇䛿䚸኱Ꮫ㝔⥲ྜ໬Ꮫ㝔䛄໬Ꮫ◊✲ඛ➃ㅮ⩏䠄ಟኈㄢ⛬㑅ᢥ⛉┠䠅䠋㻌⥲ྜ໬Ꮫ≉ู◊✲➨஧䠄༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠䠅䛅䛾୍㒊䛸䛧䛶ㄆᐃ㻌䛥䜜䛶䛔䜎䛩䚹㻌
㻌
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㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ⊦⇃Ὀⱥ㸦ෆ⥺㸸㸴㸳㸳㸴㸧  ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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ԍ ୌʁFrom Machine-Learning Interatomic

Potentials to Materials Chemistryߪ ࢥʁ Dr. Volker L. Deringer

University of Cambridge, the U.K.
ೖ ࣎ʁ2019 ೧ 8 ݆ 2 ೖʤۜʥ14:45ʛ15:45
৖ ॶʁ޽ָ෨ࡒྋʀԿָ౫ঘճ٠࣪ʤMC527ʥགྷ ࢭʁ
Understanding the links between structure and properties in materials is one of the mostcentral challenges for chemistry. Atomic-scale simulations based on density-functional theory(DFT) have played important roles in this – but they are computationally expensive and can
describe structurally complex materials only in small model systems. Novel simulation
methods based on machine learning (ML) have recently attracted a lot of attention incomputational physics, chemistry, and materials science: by “learning” from reference DFT
data, they achieve similar accuracy but require only a small fraction of the cost.
In the first part of this talk, I will argue that ML-based interatomic potentials are
particularly useful for studying structurally complex materials, such as amorphous(non-crystalline) solids. I will describe an ML potential for amorphous carbon [1] that was
built using the Gaussian Approximation Potential (GAP) framework [2], with a special viewon what is needed to create and validate ML potentials for the amorphous state. I will present
recent applications of GAP-ML models to porous and partly "graphitised" carbons that are
relevant for batteries and supercapacitors [3], and to amorphous silicon, where ML-driven
simulations allowed us to unlock long simulation times and accurate atomistic structures [4].
In the second part, I will point out possible directions for the automated exploration and“learning” of solid-state potential-energy landscapes. We recently introduced an ML-driven
approach to inorganic crystal structure prediction, dubbed GAP-driven random structure
searching (GAP-RSS) [5]. This technique, iteratively exploring and fitting structural space,allowed us to create to a flexible and accurate interatomic potential for elemental boron [5],and more recently to develop a more general computational framework that can explore andfit potential-energy surfaces for different materials [6]. These early results are hoped to enable
a more widespread use of ML-driven materials simulations in the years to come.
References: [1] Phys. Rev. B 2017, 95, 094203, [2] Phys. Rev. Lett. 2010, 104, 136403, [3]Chem. Commun. 2018, 54, 5988, [4] VJ. Phys. Chem. Lett. 2018, 9, 2879, [5] Phys. Rev. Lett.
2018, 120, 15600, [6] arXiv:1905.10407.
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ԍ ୌʁToward a universal understanding of thin-film

and nanostructure growth on weakly-interacting
substrates
ߪ ࢥʁ Prof. Kostas Sarakinos

Nanoscale Engineering Division,
IFM-Material Physics,
Linköping University, Swedenೖ ࣎ʁ2019 ೧ 8 ݆ 30 ೖʤۜʥ14:45ʛ16:15
৖ ॶʁཀྵָ෨ຌ‫ ؙ‬N-308 ࣪གྷ ࢭʁήϧϓΥϱΏ MoS2 ͵ʹ͹್࣏‫ݫ‬੓ࡒྋΏ SiO2ɼTiO2ɼZnO ͵ʹ͹࢐Կ෼͹‫خ‬൚৏Ͳ͹ۜ଒മຜ͹੔ௗգఖ͹ཀྵմͳͨ͹ψόߑଆର͹‫ܙ‬য়੏‫ޜ‬ͺ߶͏੓೵Ν༙ͤΖޭుࢢࡒྋΏιϱεϱήυώ΢η͹ߑ஛Ͷ޴͜ͱ‫ۅ‬Όͱ॑གྷͲ͍Ζɽ͞ΗΔͺ‫خ‬൚৏Ͳۜ଒‫͗ࢢݬ‬ౣয়͹݃ধ֫΃ͳ੔ௗ͢ɼ
͠ΔͶ್࣏‫ݫ‬ద͵࿊କରͲ͍ΖϓΡϩϞ΃ͳ੔ௗͤΖϕϫιηͲ͍Ζ͗ɼͨΗΔͺΉͫॉ෾ཀྵմ͠Ηͱ͏͵͏ɽຌߪԍͲͺɼಝͶ૮‫༽ࡠޕ‬͹ओ͏‫خ‬൚ͳۜ଒‫ࢢݬ‬͹‫ܧ‬Ͷͯ͏ͱɼ‫خ‬൚৏Ͳ͹ۜ଒മຜ͹੔ௗ͹ͨ͹৖؏ࡱͳࣰ
‫ؔۯ‬΢ϟʖζϱήΝߨ͏ɼଐౕ࿨ద͵ϠϱτΩϩϫεϝϣϪʖεϥϱͳ߻Κͦͱɼۜ଒മຜ͹੔ௗգఖͶ͕͜Ζ஦ؔয়ସ͹‫ܙ‬ସรԿͳͨ͹ξ΢ψϝ
έηͶͯ͏ͱ়ղͤΖɽࢂߡช‫ݛ‬
1) B. Lü, G.A. Almyras, V. Gervilla, J.E. Greene, and K. Sarakinos, Phys. Rev. Mat. 2, 063401 (2018).
2) V. Gervilla, G.A. Almyras, F. Thunström, J.E. Greene, and K. Sarakinos, Appl. Surf. Sci. 488, 383 (2019).
3) A. Jamnig, D.G. Sangiovanni, G. Abadias, and K. Sarakinos, Sci. Rep. 9, 6640 (2019).
4) B. Lü, V. Elofsson, E.P. Münger, and K. Sarakinos, Appl. Phys. Lett. 105, 233113 (2014).

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₇ 㢟㸸࣐࢖ࢡࣟἼ≉␗ຠᯝ࡜ྜᡂ᭷ᶵ໬Ꮫ཯ᛂㅮ ᖌ㸸ᒣ⏣ᚭ ඛ⏕៞᠕⩏ሿ኱Ꮫ⌮ᕤᏛ㒊໬Ꮫ⛉࣭ᩍᤵ᪥ ᫬㸸2019 ᖺ 9 ᭶ 20 ᪥㸦㔠㸧15:00㹼16:30
ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ 2F ࢭ࣑ࢼ࣮ᐊ 2
せ ᪨㸸Ỉࡸ࢔ࣝࢥ࣮ࣝ࡞࡝኱ࡁ࡞ศᴟࢆᣢࡘ໬ྜ≀ࡣ࣐࢖ࢡࣟἼ࢚ࢿࣝ
ࢠ࣮ࢆࡼࡃ྾཰ࡋ㸪⤖ᯝ࡜ࡋ࡚ ᗘୖ᪼ࢆࡶࡓࡽࡍࠋ1986 ᖺ࡟ጞࡲࡗࡓ
᭷ᶵྜᡂ཯ᛂ࡟ᑐࡍࡿ࣐࢖ࢡࣟἼࡢ฼⏝ࡣࡇࡢཎ⌮࡟ᇶ࡙ࡃࡶࡢ࡛㸪࣐࢖ࢡࣟἼ↷ᑕࡣຠᯝⓗ࡞ຍ⇕ᡭẁ࡛࠶ࡗࡓࠋࡍ࡞ࢃࡕ㸪໬Ꮫ཯ᛂࡣ㎿㏿࡞཯ᛂ⣔ࡢᗘୖ᪼࡟ࡼࡾຍ㏿ࡉࢀ㸪࣐࢖ࢡࣟἼࡢࠕ⇕ⓗຠᯝࠖ࡜ࡉࢀࡿࠋ ୍᪉㸪༢⣧࡞ຍ⇕ຠᯝࡔࡅ࡛ࡣㄝ࡛᫂ࡁ࡞࠸⌧㇟ࡶሗ࿌ࡉࢀ࡚࠾ࡾ㸪ࠕ㠀⇕ⓗຠᯝࠖࡲࡓࡣࠕ࣐࢖ࢡࣟἼ≉␗ຠᯝࠖ࡜࠸ࢃࢀ㸪Ọࡽࡃ㆟ㄽࡢᑐ㇟࡜࡞ࡗ࡚࠸ࡿࠋ࣐࢖ࢡࣟἼࡢ⇕ⓗຠᯝࢆ฼⏝ࡍࡿ࡟ࡣศᴟࡢ኱ࡁ࡞
཯ᛂ⁐፹ࢆ⏝࠸ࡿࡀ㸪ศᴟࡢᑠࡉ࠸⁐፹ࢆ⏝࠸ࡿ࡜࣐࢖ࢡࣟἼ࢚ࢿࣝࢠ
࣮ࡣ཯ᛂᇶ㉁࡟┤᥋ᒆࡅࡽࢀࠕ࣐࢖ࢡࣟἼ≉␗ຠᯝࠖࡀほࡉࢀࡿࡇ࡜ࡀᮇᚅࡉࢀࡿࠋᮏㅮ₇࡛ࡣ୙ᩧྜᡂ཯ᛂ࡟࠾ࡅࡿࠕ࣐࢖ࢡࣟἼ≉␗ຠᯝࠖࡢᐇ㦂ⓗ࡞᳨ド࡟ࡘ࠸࡚⤂௓ࡍࡿࠋඹ ദ㸸໬Ꮫ཯ᛂ๰ᡂ◊✲ᣐⅬ㸦WPI-ICReDD㸧༠㻌 ㈶㻌 䠖㻌㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ఀ⸨ ⫕    ໬Ꮫ཯ᛂ๰ᡂ◊✲ᣐⅬ  ⨾ከ ๛㸦ෆ⥺㸸9653㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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₇ 㢟㸸 Mechanochemical Polymer Synthesisㅮ ᖌ㸸 Prof. Dr. Jeung Gon Kim

Department of Chemistry
Chonbuk National University, Korea᪥ ᫬㸸2019 ᖺ 9 ᭶ 25 ᪥㸦Ỉ㸧15:00~16:00
ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ ࢭ࣑ࢼ࣮ᐊ㸯せ᪨㸸Mechanochemical reactions are promising methods to break andform chemical bonds. While many areas of chemistry have enjoyed
the merits of mechanochemistry, it has been unexplored in polymer
synthesis. Applying mechanical stress on polymeric materials has
been regarded to cause degradation. Recently, we stared to pursue theuse of mechanical force for the construction of macromolecules and amechanochemical polymerization of lactide is developed using ball
milling. Mechanical energy from the collisions between the balls andthe vessel efficiently promoted an organic-base-mediated metal- andsolvent-free solid-state polymerization. Also solid-state post-polymeri
zation modification was achieved by means of mechanochemistry as
well. The current status of mechanochemical polymer synthesis by our
research team will be presented.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

༠㈶㻌 䠖㻌

㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ఀ⸨ ⫕㸦ෆ⥺㸸6561㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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₇ 㢟㸸 Visible Light Photoredox-Catalyzed

Deoxygenation of N-Heterocyclic N-Oxidesㅮ ᖌ㸸 Prof. Dr. Jun Hee Lee
Department of Advanced
Materials Chemistry,
Dongguk University, Korea᪥ ᫬㸸 2019 ᖺ 9 ᭶ 25 ᪥㸦Ỉ㸧16:15~17:15
ሙ ᡤ㸸 ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ ࢭ࣑ࢼ࣮ᐊ㸯せ᪨㸸

Deoxygenation reactions that furnish N-heterocycles represent a
fundamental transformation in organic synthesis. Despite the recent
invention of several successful implementations of these reactions,such approaches commonly require harsh reaction conditions.
In our continuous efforts to develop new transformations via
visible-light-induced photoredox catalysis, we recently developed ascalable and operationally simple protocol that allows for thechemoselective deoxygenation of a wide range of N-heterocyclic
N-oxides at ambient temperature using only commercially available
reagents. Further details of this protocol will be discussed in thepresentation.
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༠㈶㻌 䠖㻌

㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ఀ⸨ ⫕㸦ෆ⥺㸸6561㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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₇ 㢟㸸A Three-Pronged Approach to the Development of

New Trifluoromethylation Reactionsㅮ ᖌ㸸Prof. Gavin Chit Tsui

Chinese University of Hong Kong᪥ ᫬㸸2019 ᖺ 9 ᭶ 30 ᪥㸦᭶㸧16:30~18:00
ሙ ᡤ㸸⌮Ꮫ㒊ᮏ㤋 N-308 ㅮ⩏ᐊせ ᪨㸸
Fluorinated molecules continue to be of major interest for the applications in pharmaceuticals,
agrochemicals and functional materials. To address the synthetic challenges in the area of trifluoromethylation
reactions, a three-pronged approach is needed to solve the problems of efficiency, selectivity and CF3-source. We
have recently developed a series of novel trifluoromethylation methods using the fluoroform-derived CuCF3
reagent. By employing common feedstocks such as terminal alkynes and simple alkenes, a variety of valuable
CF3-containing building blocks including the trifluoromethylated alkynes, alkenes and β-trifluoromethyl alcohols
can be synthesized in one step. These processes, namely trifluoromethylation, hydrotrifluoromethylation andhydroxytrifluoromethylation, allow the distinctive construction of C(sp)-CF3, C(sp2)-CF3 and C(sp3)-CF3 bonds,
respectively. Furthermore, a three-component vicinal trifluoromethylation-allylation of arynes was realized where
two carbon-carbon bonds (C-CF3 and C-allyl) are formed in one pot to provide the trifluoromethylated allylarenes.
Even 1,2-bis(trifluoromethylation) of arynes was made possible for the first time. This reagent also enables the
preparation of α-trifluoromethyl esters and ketones directly from α-diazo carbonyl compounds under mild
conditions. Overall, the ultimate CF3 source in these versatile fluorinated molecules is the inexpensive industrial
by-product fluoroform from Teflon manufacturing.
We have also investigated the synthesis of diverse trifluoromethylated heterocycles via domino strategies
with copper. An interrupted click reaction, using CuI/phen as the catalyst and (trifluoromethyl)trimethylsilane(TMSCF3) as the nucleophilic CF3 source, has been developed to synthesize 5-trifluoromethyl-1,2,3-triazoles in
one step from readily available terminal alkynes and azides. The reaction shows complete regioselectivity, broad
substrate scope and good functional group tolerability. Moreover, domino 5-endo-dig cyclization/trifluoromethylation of α,β-alkynic tosylhydrazones and propargylic N-hydroxylamines allows convenient access to4-(trifluoromethyl)pyrazoles and 4-trifluoromethyl-4-isoxazolines, respectively. These reactions are facilitated by
the Cu(OTf)2/TMSCF3/KF combination. By employing easily accessible 2-alkynylanilines and the low-cost
fluoroform-derived CuCF3 reagent, both 2- and 3-(trifluoromethyl)indoles can be prepared in good yields with noambiguity of the CF3 position. Analogous cyclization/trifluoromethylation of 2-alkynylphenols can afford
3-(trifluoromethyl)benzofurans and one of the compounds was identified as a promising antibacterial andantifungal agent. Applications of the above methods in the expedient synthesis of trifluoromethylated drug
analogues including rufinamide, celecoxib, bazedoxifene, melatonin, papaverine and estrone have also beensuccessfully demonstrated.

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ
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₇ 㢟㸸㧗ศᏊ⛥ⷧ⁐ᾮ≀ᛶ୍̿యఱࡀ㠃ⓑ࠸ࡢ㸽ㅮ ᖌ㸸஭⏣኱ᆅ ඛ⏕   ி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉   㧗ศᏊ໬Ꮫᑓᨷ࣭෸ᩍᤵ
᪥ ᫬㸸2019 ᖺ 10 ᭶ 18 ᪥㸦㔠㸧10:30~12:00
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ 527 ᐊせ ᪨㸸
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₇ 㢟㸸㎷-ࢺࣟࢫࢺ཯ᛂࡢ᪂ᒎ㛤ㅮ ᖌ㸸໭ᮧ㞞ே ᩍᤵ        ྡྂᒇ኱Ꮫ኱Ꮫ㝔࣭๰⸆⛉Ꮫ◊✲⛉ᩍᤵ ᪥ ᫬㸸2019 ᖺ 10 ᭶ 25 ᪥㸦㔠㸧16:30~18:00
ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ 1 㝵ࢭ࣑ࢼ࣮ᐊ 1
せ᪨㸸1860 ᖺ௦࡟ Geuther-Wislicenus ࡟ࡼࡗ࡚☜❧ࡉࢀࡓࠕ࢔ࢭࢺ㓑㓟࢚ࢫࢸ࣭࣐ࣝࣟࣥ㓟࢚ࢫࢸࣝྜᡂࠖࡣྜ┠ⓗⓗ࡞᭷ᶵྜᡂࡢཎⅬ࡜ࡋ࡚ࡼ࠸ࠋ≉࡟ᐁ⬟ᇶኚ᥮≉ᛶࡢ㧗࠸ࠕ࢔ࣜࣝ໬ࠖࡣ᭷⏝≀㉁ྜ
ᡂ࡟ᙉຊ࡞ᡭẁࢆᥦ౪ࡋࡓࠋࡇࡢ࢔ࣜࣝ໬ࡣ 1965 ᖺ࡟ᮾࣞ◊✲ᡤࡢ㎷࡟ࡼࡗ࡚㠉᪂ⓗ࡟ᒎ㛤ࡉࢀࡓࠋȧ࢔ࣜࣝࣃࣛࢪ࣒࢘㘒యࡀồ㟁Ꮚ๣࡜ࡋ࡚ᶵ⬟ࡍࡿྠẶࡢⓎぢࡣࠊᮾࣞ◊✲ࢢ࣮ࣝࣉ࣭ࣘࢽ࢜
࣮ࣥ࢝ࣂ࢖ࢻ♫ࡢゐ፹໬ࠊࢺࣟࢫࢺࡢኳ↛≀ྜᡂ࡬ࡢᛂ⏝࡜ࡣࡌࡵ࡚ࡢ୙ᩧゐ፹໬ࠊ࣎ࢫࢽࢵࢳࠊ࢝࢞ࣥࠊᯘ-⇃⏣ࡽࡢᶵᵓゎ᫂◊✲ࢆ௓ࡋ࡚ࠊᡤㅝࠕ㎷-ࢺࣟࢫࢺ཯ᛂࠖ࡜ࡋ࡚☜❧ࡉࢀࡓࠋ௒࡛ࡣ
㛵㐃ㄽᩥᩘࡣᩘ༓࡟ࡶཬࡪࠋ୙ᩧ᭷ᶵྜᡂࡢ☜ࡓࡿ୍ゅࢆ༨ࡵࡿࡔࡅ࡟ࠊ⬺ሷᆺࣉࣟࢭࢫ࠿ࡽ⬺Ỉᆺࣉࣟࢭࢫ࡬ࡢᒎ㛤ࡣࠊཎᏊ࣭
ẁ㝵ຠ⋡ࠊ⎔ቃ㈇ⲴపῶࡢほⅬ࠿ࡽࡔࡅ࡛࡞ࡃࠊ」㞧࡞ኳ↛᭷ᶵ໬ྜ≀ࡢ඲ྜᡂࡢほⅬ࠿ࡽࡶ㨩ຊⓗ࡛࠶ࡿࠋሷᇶᛶ᮲௳࠿ࡽ㓟ᛶ᮲௳࡬ࡢኚ᥮ࡣࠊྜᡂᡓ␎࡟ᰂ㌾ᛶࢆ୚࠼ࡿ࠿ࡽ࡛࠶ࡿࠋᮏㅮ₇࡛ࡣࠊᙜ◊✲ᐊ࡛㛤Ⓨࡉࢀࡓ⬺Ỉᆺ୙ᩧ㎷-ࢺࣟࢫࢺ཯ᛂࡢゐ፹㛤Ⓨ࣭ᛂ⏝࣭ᶵᵓゎ᫂࡟㛵ࡋ࡚ᴫㄝࡋࡓ࠸ࠋ

༠㈶㻌 䠖㻌

㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ኱⇃ Ẏ㸦ෆ⥺㸸6599㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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ᜒ๫˟‒

₇ 㢟㸸Advanced Design of Zeolite As A Selective Catalyst

and Adsorbentㅮ ᖌ㸸Dr. Alex Yip

Department of Chemical and Process
Engineering, University of Canterbury᪥ ᫬㸸2019 ᖺ 11 ᭶ 21 ᪥㸦ᮌ㸧15:00~16:00
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ 208 ྕᐊ

せ᪨㸸Ionothermal synthesis method, in which ionic liquids (ILs) act as both solvent andtemplate/structure-directing agent (SDA), has received great attention due to its almost
zero vapor pressure at typical zeolite synthesis temperatures (ca. 170-180 °C).
However, the existing reports in literature show that a wide range of random zeolite
types tend to form when ionic liquids were used for zeolite synthesis. We
systematically studied the effect of various ILs, such as 1-ethyl-3-methylimidazolium
bromide ([EMIM]Br), 1-ethyl-3-methylimidazolium chloride ([EMIM]Cl),
1-buthyl-3-methylimidazolium chloride ([BMIM]Cl), etc., on the resulted zeolite
products using tetraethyl orthosilicate (TEOS), fumed silica and colloidal silica as the
Si sources. The results showed that the morphology of the product zeolite can be
tailored using appropriate ILs as a soft template and that anisotropic behavior can beobtained in zeolite catalysis. This talk will also present a core-shell zeolite that issuitable for use as an ethylene scavenger, which finds a great potential in the foodstorage and transporting industry.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 Ⲷ㔝 ໏㸦ෆ⥺㸸6591㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

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₇ 㢟㸸From Functional Polymer to IntrinsicallyStretchable and Healable Transistorㅮ ᖌ㸸Prof. Yu-Cheng Chiu
Department of Chemical Engineering,
National Taiwan University of Scienceand Technology, Taipei, Taiwan᪥ ᫬㸸 2019 ᖺ 12 ᭶ 3 ᪥㸦ⅆ㸧14:45~15:45
ሙ ᡤ㸸 ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ୰఍㆟ᐊ㸦MC102㸧ඹ ദ㸸 㧗ศᏊᏛ఍໭ᾏ㐨ᨭ㒊せ ᪨㸸
Polymer materials with electronic or semi-conducting function haveattracted broad academic and industrial interest for electronics applications.
Here we would like to present design concepts to address the challenges ofdeveloping high-performance charge-storage polymer and intrinsicallystretchable semiconducting polymer. Incorporating insulating polymers withcharge-affinity moieties into the dielectrics of transistor devices will be
introduced first and demonstrate it brings transistors a memory function, whichis comparable to that of the state-of-the-art metallic nano-floating gate hybrid
memory devices. On the other hand, current molecular design rules for highcharge carrier mobility semiconducting polymers are unable to render the
fabricated devices simultaneously stretchable and mechanically robust. To solve
this problem, introducing chemical moieties to promote dynamic non-covalentcrosslinking of the conjugated polymers are demonstrated that it is able toundergo an energy dissipation through breakage of bonds when strain is applied,
while retaining its high charge mobility. Furthermore, we observed that thepolymer can be efficiently repaired and healed. These improved mechanicalproperties of our fabricated stretchable semiconductor enabled us to fabricate
highly stretchable and high performance wearable organic transistors. This
material design concept advances the pathways for future development ofskin-like wearable electronics.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛బ⸨ ᩄᩥ㸦ෆ⥺㸸6602㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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₇ 㢟㸸Two-Dimensional Colloidal Quantum Wells

for Future Photonic Sourcesㅮ ᖌ㸸Prof. Chih-Jen Shih
Department of Chemistry and Applied
Biosciences, ETH Zürich, Switzerland᪥ ᫬㸸2019 ᖺ 12 ᭶ 3 ᪥㸦ⅆ㸧15:45~16:45
ሙ ᡤ㸸 ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ୰఍㆟ᐊ㸦MC102㸧ඹ ദ㸸 㧗ศᏊᏛ఍໭ᾏ㐨ᨭ㒊せ ᪨㸸
Miniaturized
photonic
sourcesbasedonsemiconducting
two-dimensional (2D) materials offer new technological opportunities beyond
the modern III-V platforms. For example, the quantum-confined 2D electronic
structure aligns the exciton transition dipole moment, directing emission
perpendicular to the surface which gives rise to high-efficiency quantum optics
and electroluminescent devices. It requires scalable materials and processes tocreate the decoupled multi-quantum-well (MQW) superlattices, in which
individual 2D material layers are isolated by atomically thin quantum barriers(QBs). My research group developed synthetic routes to obtain monodispersed,
quantum-confined colloidal quantum wells (CQWs) of lead halide perovskites
with precise thickness control, yielding different emission colors without
altering the chemical composition. We successfully developed the protocols
fabricating the thin-film MQW superlattices out of these materials.
Unexpectedly, an enhancement of PLQY with respect to colloidal dispersions
was observed, and individual QWs can be decoupled with unprecedentedly
ultrathin QBs that screen interlayer interactions within the range of 6.5 Å. These
unique phenomena were investigated in order to uncover the underlying physicalmechanisms. The photonic sources demonstrated here have narrowband
emission together with high quantum yield, directionality, and wavelength
tunability, which are highly desirable for many near-field and far-field
applications such as nanoantennas and light-emitting diodes.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛బ⸨ ᩄᩥ㸦ෆ⥺㸸6602㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

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₇ 㢟㸸Current Status and Issues of Accelerated

Corrosion Tests for Evaluating Corrosion
Resistance of Coated Steel Sheets in Automobilesㅮ ᖌ㸸⸨⏣ᰤ ඛ⏕    

JFE ࢸࢡࣀࣜࢧ࣮ࢳओ࣭ࣇ࢙࣮ࣟ
໭ᾏ㐨኱Ꮫ࣭ᐈဨᩍᤵ
᪥ ᫬㸸2019 ᖺ 12 ᭶㸲᪥㸦Ỉ㸧10:30~12:00
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ୰఍㆟ᐊ㸦MC102㸧ඹ ദ㸸 ⭉㣗㜵㣗Ꮫ఍໭ᾏ㐨ᨭ㒊せ᪨㸸The author introduces an outline of the development and history ofstandardization of the accelerated corrosion tests that are used fordevelopments of automobiles in the world, and summarize, to the bestof his abilities, the ideal form of accelerated corrosion tests in the
future.
㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ᖜᓮᾈᶞ㸦ෆ⥺㸸6575㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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₇ 㢟㸸Introducing the Deep Sea. For the Rest of Usㅮ ᖌ㸸ฟཱྀⱱ ඛ⏕   ᾏὒ◊✲㛤Ⓨᶵᵓ ⏕࿨⌮ᕤᏛࢭࣥࢱ࣮   ࢭࣥࢱ࣮㛗࣭᪂ᶵ⬟㛤ᣅ◊✲ࢢ࣮ࣝࣉ࣮ࣜࢲ࣮
᪥ ᫬㸸2019 ᖺ 12 ᭶ 4 ᪥㸦Ỉ㸧16:00~17:30
ሙ ᡤ㸸ᕤᏛ㒊 ᮦᩱ࣭໬ᏛᲷ 526 ኱఍㆟ᐊせ ᪨㸸 ᆅ⌫⾲㠃ࡢ⣙㸵๭ࢆそ࠺ᾏࡢᖹᆒࡢ῝ࡉࡣ ࣓࣮ࢺࣝ࠶ࡾࠊࡑࡢෆ ࣓࣮ࢺࣝ௨῝ࢆ῝ᾏ࡜࿧ࡧࡲࡍᆅ⌫ࢆ㝮ࠎࡲ࡛ㄪ࡭ᑾࡃࡍࡇ࡜ࡀ࡛ࡁ
ࡿࡼ࠺࡟࡞ࡗࡓ௒᪥࡛ࡣࡶࡣࡸࠕⓎぢࠖࡢ᫬௦ࡣ⤊ࢃࡗࡓ࡜ࡶゝࢃࢀࡲࡍࡀࠊࡑࡢ၏୍ࡢ౛እࡀ῝ᾏ࡛ࡍ ῝ᾏࡣ㧗ᅽຊࠊᬯ㯮ࠊప ࡟ᨭ㓄ࡉࢀࡓୡ⏺࡛ࡍࡀࠊࡈࡃ⛥࡟ࡣ Υࢆ㉸࠼ࡿ㉸㧗 ࡢỈࢆ྿ࡁฟࡍ ἨࡶᏑᅾࡋࡲࡍ኱ኚ㦫ࡃ࡭ࡁࡇ࡜࡟ࠊᆅ
ୖ࡜ࡣ࠿ࡅ㞳ࢀࡓ῝ᾏࡢᴟ㝈ୡ⏺࡟ࡶከ✀ከᵝ࡞⏕ࡁ≀ࡀࣘࢽ࣮ࢡ࡞⏕Ꮡᡓ␎ࢆ㥑౑ࡋ࡚ᬽࡽࡋ࡚࠸ࡲࡍㅮ₇࡛ࡣࠊ῝ᾏࡢᴟ㝈ୡ⏺ࡢ≉ᚩࡸࡑࡇ࡟ᬽࡽࡍ⏕ࡁ≀ࡢ⏕Ꮡᡓ␎ࠊࡉࡽ࡟ࡣࡑࢀࡽ࡟ࣄࣥࢺࢆᚓࡓ࢖ࣀ࣮࣋ࢩࣙ
ࣥࡢྍ⬟ᛶ࡟ࡘ࠸࡚࠾ヰࡋࡋࡲࡍඹദ㸸㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ᒣᮏ ᣅ▮㸦ෆ⥺㸸6606㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

ᜒ๫˟‒

₇ 㢟㸸Unraveling Organic and Coordination

Chemistry using Mechanochemistryㅮ ᖌ㸸Prof. Dr. Xavier Bantreil

Institut des Biomolécules Max Mousseron(IBMM), Université de Montpellier, France᪥ ᫬㸸2019 ᖺ 12 ᭶ 11 ᪥㸦Ỉ㸧16:30~18:00
ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉ᏛᲷ㸯㝵ࢭ࣑ࢼ࣮ᐊ㸯せ᪨㸸Mechanochemistry has been highlighted in 2019 by IUPAC as an
emerging technology that will change the world. In this context, wedemonstrated the benefits of mechanochemistry in the synthesis of
imidazolium salts, precursors of NHC (NHC = N-Heterocyclic
Carbene), as well as of corresponding NHC-metal complexes.
Additionally, mechanochemistry was recently applied to the synthesisof sydnone, high value mesoionic heterocycles, and of
sydnone-containing complexes.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

༠㈶㻌 䠖㻌

㻌᭷ᶵྜᡂ໬Ꮫ༠఍໭ᾏ㐨ᨭ㒊㻌㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 ఀ⸨ ⫕㸦ෆ⥺㸸6561㸧

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ࠥㅮ₇఍ࡢࡈ᱌ෆࠥ
‒₇ 㢟㸸ാࡃ࡜ࡣ㸫ᑵ⫋㠃᥋࡟⮫ࡴ࡟࠶ࡓࡾ㸫㻌ㅮ ᖌ㸸ᇼ㑔ⱥኵᩍᤵ኱㜰ᕷ❧኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉໬Ꮫ⏕≀⣔ᑓᨷ㧗ศᏊ⛉Ꮫ◊✲ᐊ᪥ ᫬㸸2020 ᖺ 1 ᭶ 10 ᪥㸦㔠㸧15㸸00 ~ 16㸸30ሙ ᡤ㸸ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ 2 㝵 ࢭ࣑ࢼ࣮ᐊ 2せ ᪨㸸
ㅮ₇⪅ࡣ௨๓୕⳻㟁ᶵ ᰴ ඛ➃ᢏ⾡⥲ྜ◊✲ᡤ࡟ᖺ㛫໅ົࡋ࡚࠾ࡾࠊ
኱Ꮫ⏕ࡢᑵ⫋㠃᥋࡟ࡶྠᖍࡋࡓࠋࡲࡓࠊ኱㜰ᕷ❧኱Ꮫ࣭⏘Ꮫᐁ㐃ᦠࢭࣥࢱ࣮ᡤ㛗࡜ࡋ࡚ࡶࢥ࣮ࢹ࢕ࢿ࣮ࢱࡢ᥇⏝࡟ࡶ㛵ಀࡋ࡚࠸ࡓࠋࡇࢀࡽࡢ⤒㦂ࡶ㋃ࡲ࠼ࠊ♫఍࡛ാࡃࡇ࡜ࡢᚰᵓ࠼ࡸᑵ⫋㠃᥋࡛ࡢ࢔ࢻࣂ࢖ࢫࢆ኱Ꮫ
ᩍဨࡢ❧ሙ࠿ࡽᏛ⏕ࡢⓙࡉࢇ࡟ࡈㅮ₇ࡋࡓ࠸ࠋඹദ㸸໭ᾏ㐨኱Ꮫࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮㸪≀㉁⛉Ꮫࣇࣟࣥࢸ࢕࢔ࢆ㛤ᣅࡍࡿ$PELWLRXV࣮ࣜࢲ࣮ࣉࣟࢢ࣒ࣛ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛 㛗㇂ᕝ㟹ဢ㸦ෆ⥺㸸㸵㸯㸯㸲㸧

‒

ᜒ๫˟‒

₇ 㢟㸸
㸦࢖ࢯ㸧࢟ࣀࣜࣥྵ᭷㓄఩Ꮚࢆά⏝ࡋࡓ㔠ᒓ㘒యࡢᶵ⬟Ⓨ⌧ㅮ ᖌ㸸୕᪉⿱ྖ ᩍᤵ

㸦ዉⰋዪᏊ኱Ꮫ◊✲㝔 ⮬↛⛉Ꮫ⣔㸧᪥ ᫬㸸2020 ᖺ 1 ᭶ 28 ᪥㸦ⅆ㸧16:00~17:30
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ 5 㝵 MC508

せ ᪨㸸 ࢟ࣀࣜࣥࡣࠊࣆࣜࢪࣥ࡜ẚ㍑ࡋ࡚ࠊሷᇶᛶࡀప࠸ࡓࡵ㔠ᒓ࡟ᑐࡍࡿ㓄఩ຊࡀᙅࡃࠊ㔠ᒓѸ❅⣲㛫㊥㞳ࡀ㛗ࡃ࡞ࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࠋࡇࡢ≉ᛶࢆ฼⏝ࡋࠊᡃࠎࡣྠ᪘㔠ᒓ࡛࠶ࡿ࢝ࢻ࣑࣒࢘࡜ள㖄ࡢࢃࡎ࠿࡞࢖༙࢜ࣥ
ᚄࡢᕪࢆཝᐦ࡟㆑ูࡍࡿ⺯ගࢭࣥࢧ࣮ศᏊࢆሗ࿌ࡋ࡚ࡁࡓࠋࡇࢀ࡜ࡣ㏫࡟ࠊ
࢖ࢯ࢟ࣀࣜࣥࡣࣆࣜࢪࣥࡼࡾࡶሷᇶᛶࡀ㧗࠸ࡓࡵ㔠ᒓ࡟ᑐࡍࡿ㓄఩ຊࡀᙉࡃࠊࡲࡓࡑࡢࡓࡵள㖄㘒య࡟࠾࠸࡚ศᏊෆ࢚࢟ࢩ࣐࣮ᙧᡂ࡟ᇶ࡙ࡃ㧗࠸⺯ගᙉᗘࢆ♧ࡍࡇ࡜ࡶぢ࠸ࡔࡋ࡚࠸ࡿࠋࡉࡽ࡟ᡃࠎࡣ᭱㏆ࠊ࢖ࢯ࢟ࣀࣜࣥࡢ
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ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

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₇㢟㸸Molecular Functional Materials –From Fundamentals to Energy,
Materials and Biomedical ApplicationsㅮᖌProf. Vivian Wing-Wah YAM
Department of Chemistry,
The University of Hong Kong,
Hong Kong

Yam ඛ⏕ࡣࠊගᶵ⬟ᛶ㔠ᒓ㘒య࣭㉸ศᏊ໬Ꮫࡢ➨୍ே⪅࡛ࡍࠋࢧ࣐࣮࢖ࣥࢫࢸ࢕ࢸ
࣮ࣗࢺࡢㅮᖌ࡜ࡋ࡚᮶Ꮫࡉࢀࡿᶵ఍࡟බ㛤ㅮ₇఍ࢆ⾜࠸ࡲࡍࠋ
ⓙᵝࡢ⫈ㅮࢆḼ㏄ࡋࡲࡍࠋ᪥᫬㸸 ᖺ  ᭶  ᪥ 㔠 㹼
ሙᡤ㸸⌮Ꮫ㒊  ྕ㤋  ᩍᐊඹദ㸸 ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮   ᪂Ꮫ⾡㡿ᇦ◊✲ࠕࢯࣇࢺࢡࣜࢫࢱࣝࠖ

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧ 㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ
㐃⤡ඛ㸸⌮Ꮫ◊✲㝔໬Ꮫ㒊㛛㘒య໬Ꮫ  ຍ⸨ᫀᏊ㸦ෆ⥺㸸㸧


‒

ᜒ๫˟‒
₇㢟㸸Challenges and Opportunities for

Natural Products and Drug Discovery
in the Genomic Eraㅮ ᖌ㸸Prof. Ben Shen

Co-Chair and Professor, Department of Chemistry,
Professor, Department of Molecular Medicine,
Director, The Natural Products Library Initiativeat The Scripps Research Institute (TSRI),
the U.S.A.
᪥ ᫬㸸௧࿴ඖᖺ 6 ᭶ 27 ᪥㸦ᮌ㸧15㸸00㹼16㸸30ሙ ᡤ㸸໭ᾏ㐨኱ᏛᕤᏛ㒊ࣇࣟࣥࢸ࢕࢔ᛂ⏝⛉Ꮫ◊✲Ჷ ࢭ࣑ࢼ࣮ᐊ 2ඹ ദ㸸 ᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊㸪᪥ᮏ㎰ⱁ໬Ꮫ఍໭ᾏ㐨ᨭ㒊㸪ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮
6KHQ ‫گ‬दͺɼళષ෼ਫ਼߻੔͹୊ҲਕंͲɼ͞ΗΉͲ߇ञ ෼࣯Ͳ͍ΖΦϱζ΢ϱ‫ܧ‬Կ߻෼Ώ߇ۗ੓ζτϩϘϱͲ͍ΖϕϧτϱεϱʀϕϧτϱεϜ΢εϱͶ‫ͤؖ‬Ζ‫ݨͲڂݜ‬ஸ͵‫੹ۂ‬Ν‫͕ͱ͝ڏ‬ΔΗΉͤɽࠕյɼళષ
෼ਫ਼߻੔ͳ৿༂୵ࡩͶ‫ͤؖ‬Ζ࠹৿͹‫಼ڂݜ‬༲͖͓͗͑͗Ζ΍͹ͳଚͣΉͤɽຌߪԍͺ୉ָӅ૱߻ԿָӅʲԿָ‫ڂݜ‬઎୼ߪٝʤर࢞՟ఖમ୔Ռ໪ʥʙ
૱߻Ռָಝพ‫ڂݜ‬୊ωʤദ࢞‫غޛ‬՟ఖમ୔Ռ໪ʥ
ʳ͹Ҳ෨ͳ͢ͱ೟ఈ͠Ηͱ͏Ήͤɽ   ࿊ཙ઎ʁ ๼քಕ୉ָ୉ָӅཀྵָ‫ڂݜ‬Ӆ ‫ٶ‬ઔӵव ಼  

๼քಕ୉ָ୉ָӅ޽ָ‫ڂݜ‬Ӆ ୉ཤ బʤ಼ ʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

‒

₇ 㢟㸸Navigating stability and metastability

in the synthesis of novel functional materialsㅮ ᖌ㸸Dr. Wenhao Sun
Lawrence Berkeley National Laboratory,
the U.S.A.
᪥ ᫬㸸2019 ᖺ 6 ᭶ 28 ᪥㸦㔠㸧13:30~14:30
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ኱఍㆟ᐊ㸦MC526㸧
୺ദ㸸᪂Ꮫ⾡㡿ᇦ◊✲ࠕ」ྜ࢔ࢽ࢜ࣥ໬ྜ≀ࡢ๰〇࡜᪂ᶵ⬟ࠖ 
Dr. Wenhao Sun ࡣࠊMIT ࡛Ꮫ఩ࢆྲྀᚓࡋࡓࡢࡕࠊ࣮ࣟࣞࣥࢫ࣭ࣂ࣮ࢡ࣮ࣞᅜ❧◊✲ᡤ࡟ᡤᒓࡋ࡚࠸ࡲࡍࠋ⌧ᅾ Material Project ࡟ᡤᒓࡋ࡚࠸ࡿඛ㐍Ẽ㗦ࡢ◊✲⪅࡛ࠊィ⟬࣭ྜᡂ୧㠃࠿ࡽࡢ᪂つᮦᩱ๰ฟ࡟㛵ࢃࡗ࡚࠸ࡲࡍࠋ
Abstract: Despite rapid progress in the computational design of novel functional materials, the materials
discovery pipeline remains bottlenecked by the difficulty of reliably synthesizing predicted compounds inthe lab. Developing a theoretical foundation for predictive materials synthesis requires a more quantitative
understanding of metastable phases, which often appear as kinetic byproducts during materials formation.
By mapping the thermodynamic landscape of crystalline metastability, and calculating relative nucleation
rates between competing polymorphs, we can construct synthesis maps to navigate through thethermodynamic and kinetic energy landscape towards desired material phases. I will showcase several
applications of this ab initio framework to predict non-equilibrium crystallization pathways of carbonate
minerals and functional manganese oxides in hydrothermal synthesis, and conclude with thermodynamic
strategies for the discovery and synthesis of metastable thin-film nitride semiconductors. Mastering
metastability will deepen our fundamental understanding of nucleation and crystal growth, and can expand
the search space for functional technological materials beyond equilibrium phases and compositions.

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛୕ᾆ❶㸦ෆ⥺㸸㸵㸯㸯㸴㸧ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ಝพߪԍճ͹͕எΔͦ
‒

ԍ ୌʁ

ߪ ࢥʁ

Total Synthesis ofMacrocyclic Natural Products
Prof. Tao Yeʤ‫ א‬ᔸ ‫گ‬दʥ
Professor & Senior Principal Investigator,
Peking University Shenzhen Graduate School,
Chinaೖ ࣎ʁ 2019 ೧ 7 ݆ 25 ೖʤ໨ʥ16:00ʛ17:30
৖ ॶʁ ๼քಕ୉ָ ཀྵָ෨ 2 ߺ‫ؙ‬2-409 ߪٝ࣪གྷ ࢭʁ

Tao Ye ‫گ‬दͺ஦ࠅͶ͕͜Ζళષ෼ਫ਼߻੔͹ஸ໌͵‫ंڂݜ‬͹ҲਕͲɼք༺ళષ෼Ν஦ৼͶɼmandelalides, Psymberin, Zincophorin, kopsanes͵ʹ෵ࡸ͵ࠐ֪Ν࣍ͬɼ߇ञ ੓͵ʹଡ࠾͵ਫ਼෼‫׈‬੓ΝࣖͤϛϨίν΢χɼϘϕν΢χɼΠϩΩϫ΢χ͹સ߻੔Νๅࠄ͢ͱ͏
Ήͤɽࠕյɼళષ෼સ߻੔Ͷ‫ͤؖ‬Ζ࠹৿͹‫಼ڂݜ‬༲͖͓͗͑͗Ζ΍͹ͳଚͣΉͤɽ

ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ๼քಕ୉ָ୉ָӅཀྵָ‫ڂݜ‬Ӆ ‫ٶ‬ઔӵवʤ಼ 2622ʥ

ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮

ࠥㅮ₇఍ࡢࡈ᱌ෆࠥ
₇㻌 㢟䠖㻌



Mobile Electronics as Quantitative
Point-of-care Diagnostic Tools:
from Disc Player to Smartphoneㅮ㻌 ᖌ䠖㻌

Professor Hua-Zhong Yu
Department of Chemistry,
Simon Fraser University,Canada᪥㻌 ᫬䠖 㻞㻜㻝㻥 ᖺ 㻣 ᭶ 㻟㻝 ᪥䠄Ỉ䠅㻝㻢㻦㻟㻜ࠥ㻝㻤㻦㻜㻜ሙ㻌 ᡤ䠖 ໭ᾏ㐨኱Ꮫ㻌 ⌮Ꮫ㒊ᮏ㤋 㻺㻙㻟㻜㻤 ᐊඹ㻌 ദ䠖㻌 ໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔䠈䝣䝻䞁䝔䜱䜰໬Ꮫᩍ⫱◊✲䝉䞁䝍䞊䠈㻌໭ᾏ㐨኱Ꮫ≀㉁⛉Ꮫ䝣䝻䞁䝔䜱䜰䜢㛤ᣅ䛩䜛 㻭㼙㼎㼕㼠㼕㼛㼡㼟 䝸䞊䝎䞊䝥䝻䜾䝷䝮㻌せ ᪨䠖Current guidelines for healthcare emphasize rapid testing and reporting,which can be better satisfied by point-of-care (POC) diagnostic tools
rather than centralized medical laboratories using automatedmulti-analyte analyzers by trained professionals. With POC testing, theturn-around time is significantly reduced, leading to earlier decision
making and more efficient medical treatment. At present, POC protocols
are predominantly based on rapid-test immunoassay strips/cassettes thatcombine gold nanoparticles for colorimetric (mostly qualitative)
detection and flow-through systems for sample delivery. Mobile
electronics provides a promising alternative to today’s POC testing
protocol; we have established both the chemistry and signal readout
methodology for running assays with disc players, and recently exploredthe feasibility of using smartphones as the detection platform forquantitative colorimetric analysis.
ᮏㅮ₇ࡣࠊ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ࠗ໬Ꮫ◊✲ඛ➃ㅮ⩏㸦ಟኈㄢ⛬㑅ᢥ⛉┠㸧㸭⥲ྜ໬Ꮫ≉ู◊✲➨஧㸦༤ኈᚋᮇㄢ⛬㑅ᢥ⛉┠㸧࠘ࡢ୍㒊࡜ࡋ࡚ㄆᐃࡉࢀ࡚࠸ࡲࡍࠋ

࿊ཙ઎ʁ๼քಕ୉ָ୉ָӅཀྵָ‫ڂݜ‬ӅԿָ෨໵  ଞӿ ‫ܡ‬   ʤ7HO0DLONHL#VFLKRNXGDLDFMSʥ㻌ᮐᖠⓎືศᏊ⛉Ꮫ償元儮兠

100 ᖺ僑୍ᗘ僔኱ኚ㠉僑ྥ傷僅儬兌儣僔ᡓ␎僎ᮦᩱᢏ⾡僞僔ᮇᚅㅮᖌ凬䢢 㬼㣫䢢 㡰୕儬兌儣⮬ື㌴ᰴᘧ఍♫ඛ㐍ᢏ⾡儏兗儵儯兠 ➨ 1 ᮦᩱᢏ⾡㒊 ୺ᰝ
9 ᭶ 19 ᪥凚ᮌ凛10:30到11凬30䢢 ໭ᾏ㐨኱Ꮫ⌮Ꮫ㒊 7 ྕ㤋 3 㝵䢢 310 ᐊ

100 ᖺ僑୍ᗘ僔኱ኚ㠉僔୰傎儓兏兂僑僕᪂傽傪ྲྀ僰⤌僥傲ᚲせ僑僐僉僌傳僤傽僅傏໬▼⇞ᩱ働ື債傎ಶே傲ᡤ᭷傿僱儓兏兂傱僯僔⬺༷傎᪂僅僐౯್僔ᥦ౪働傿傏儑兠兓兠儭僕傎傘㟁ື໬備傎傘㍍㔞໬備傎傘▱⬟໬備傏◊✲㛤Ⓨ働僕傎ศᯒ兟ゎᯒ傎ィ⟬⛉Ꮫ僸㥑౑傽傎ศᏊ傱僯タィ兟ྜᡂ傎〇ရ働僔ᶵ⬟Ⓨ⌧僑儥兇児兗儜傽僌傪僤傿傏⌧ᅾ僔ᮦᩱ僔ㄢ㢟僎儬兌儣僔ྲྀ僰⤌僥僑僊傪僌ᴫㄝ傪僅傽僤傿傏ඹദ凬儹兑兗優儇儆໬Ꮫᩍ⫱◊✲償兗儣兠≀㉁⛉Ꮫ儹兑兗優儇儆僸㛤ᣅ傿僱 䣃䣯䣤䣫䣶䣫䣱䣷䣵 兎兠儤兠⫱ᡂ儻兑儔免兄䢢䢢儻兑儜儋儓儬僎僕㛵ಀ傽僐傪Ꮫ⏕凚Ꮫ㒊⏕兟኱Ꮫ㝔⏕凛僔⫈ㅮ僨Ḽ㏄傽僤傿傏ၥྜඛ凬ᬒᒣ⩏அ凚⌮Ꮫ◊✲㝔兟໬Ꮫ㒊㛛䢢 ᾮయ໬Ꮫ◊✲ᐊ凛y.kageyama@sci.hokudai.ac.jp➨19ᅇ⏕≀ィ
₇㢟
ㅮᖌ
᪥᫬
ሙᡤ
୺ദ
ඹദ

໬Ꮫ᠓ㄯ఍

㻌 䝘䝜䝫䜰䜢⏝䛔䛯1⢏Ꮚゎᯒᢏ⾡䛾㛤Ⓨ㻌 㱟ᓮ㻌 ዌ㻌 ஑ᕞ኱Ꮫඛᑟ≀㉁໬Ꮫ◊✲ᡤ㻌 ຓᩍ
㻌 2019ᖺ9᭶20᪥䠄㔠䠅㻌 㻌 16䠖00䡚17䠖00㻌 ᕤᏛ㒊ᮦᩱ䞉໬ᏛᲷ䠄MC102䠅㻌 ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛⏕≀ィ ໬Ꮫ◊✲ᐊ㻌 䝣䝻䞁䝔䜱䜰໬Ꮫᩍ⫱◊✲䝉䞁䝍䞊㱟ᓮඛ⏕䛿䚸䝘䝜䝯䞊䝖䝹䝇䜿䞊䝹䛾䝫䜰䠄✰䠅䜢฼⏝䛧䛯⢏Ꮚゎᯒᢏ⾡䛾
㛤Ⓨ䛷ὀ┠䜢㞟䜑䛶䛔䜛ⱝᡭ◊✲⪅䛷䛩䚹JST䛥䛝䛜䛡䛂⏕య䛻䛚䛡䜛ᚤ⢏Ꮚ䛾ᶵ⬟䛸ไᚚ䛃䛷䛿䚸䜶䜽䝋䝋䞊䝮䛾ᙧ≧᝟ሗ䛸⤌ᡂ᝟ሗ䜢ྠ᫬䛻ィ 䛩䜛㠉᪂ⓗ䛺1⢏Ꮚゎᯒᢏ⾡䛾㛤Ⓨ䛻ྲྀ䜚⤌䜣䛷䛔䜎䛩䚹᠓ㄯ఍䛷䛿䚸䝘䝜䝫䜰䜢⏝䛔䛯1⢏Ꮚィ ᢏ⾡䛾᭱᪂䛾ᡂᯝ䛻䛴䛔䛶ㅮ₇䛧䛶䛔䛯䛰䛝䜎䛩䚹㐃⤡ඛ㻌 ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛㻌 Ώ៞ḟᏛ䠄ෆ⥺6744䠅ࠥㅮ₇఍ࡢࡈ᱌ෆࠥ
₇㢟㸸Ⓨගࡋ࡞࠸ศᏊࢆᇶ┙࡜ࡋࡓᶵ⬟ᛶⓎගᮦᩱ㛤Ⓨㅮᖌ㸸⏣୰ ୍⏕ ᩍᤵி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉㧗ศᏊ໬Ꮫᑓᨷ

᪥᫬㸸 2019 ᖺ 10 ᭶ 3 ᪥㸦ᮌ㸧15:00 ~ 16:15
ሙᡤ㸸 ᕤᏛ㒊ᮦᩱ࣭໬Ꮫ⣔Ჷ኱఍㆟ᐊ㸦MC030㸧ඹദ㸸㻌໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔㸪ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮㸪≀㉁⛉Ꮫࣇࣟࣥࢸ࢕࢔ࢆ㛤ᣅࡍࡿ $PELWLRXV ࣮ࣜࢲ࣮ࣉࣟࢢ࣒ࣛ㻌せ᪨㸸࣍࢘⣲㘒యࡣ㧗࠸๛┤ᛶ࡟⏤᮶ࡋ࡚㧗㍤ᗘⓎගࢆ♧ࡍࡶࡢࡀከ࠸ࠋ
ࡋ࠿ࡋࠊᙜ↛࡞ࡀࡽ◊✲ࢆ⾜ࡗ࡚࠸ࡃ࡜Ⓨගࡋ࡞࠸ศᏊࡶᚓࡽࢀ࡚
ࡃࡿࠋࡑࡋ࡚ࠊࡇࢀࡽࡢගࡽ࡞࠸ศᏊࡣⓎගᮦᩱ㛤Ⓨ࡟࠾ࡅࡿ◊✲ᑐ㇟࡜ࡣࡳ࡞ࡉࢀ࡟ࡃ࠸ࠋࡇࡇ࡛ࡇࢀࡽࡢศᏊ࡟࠾ࡅࡿᾘගᶵᵓࢆ
ㄪ࡭࡚ࡳࡿ࡜ࠊບ㉳≧ែ࡛ศᏊࡀ኱ࡁࡃኚᙧࡋ࡚࠸ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓࠋࡑࡋ࡚ࡇࢀࡽࡢศᏊࢆ฼⏝ࡍࡿ࡜ࠊࡇࢀࡲ࡛࡟࡞࠸ࣘࢽ࣮ࢡ
࡞่⃭ᛂ⟅ᛶⓎගᮦᩱࡀᚓࡽࢀ࡚ࡁࡓࠋ
ᮏㅮ₇࡛ࡣࠊࡇࢀࡽࡢࠕᰂ㌾࡞ࠖ࣍࢘⣲㘒యࡀぢ௜࠿ࡗࡓ⤒⦋࡜ࡑࡢ᭷⏝ᛶ࡟ࡘ࠸࡚ㄝ᫂ࡍࡿࠋ
㐃⤡ඛ㸸ᕤᏛ◊✲㝔ᛂ⏝໬Ꮫ㒊㛛㛗㇂ᕝ㟹ဢ㸦ෆ⥺㸸7114㸧㻌੊ֆద͵Ϊϧη‫ڂݜ‬͹‫ݘ‬Ҙཔೖߪԍ 

C DD
           
#$%&!%$!%'()‫ؙ‬%*$$+%,#$   -  ./0  

4!56!

12        
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14:00-15:00 “  78  ”   9 :           ;           :  
  9:       :    :   <  = >:?    
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     <   ?
           !

  4!       
電子科学研究所 光電子ナノ材料研究分野
准教授 小野 円佳 !! !" 
 

北海道大学 人材育成本部女性研究者支援室  !! !"

‒

₇ 㢟㸸 Enabling Prescriptive Synthesis of Metastable Ternary

Oxides with Mixed Anionsㅮ ᖌ㸸Prof. James Neilson
Department of Chemistry, Colorado State University,
CO,USA᪥ ᫬㸸2019 ᖺ 10 ᭶ 23 ᪥㸦Ỉ㸧14:45~15:45
ሙ ᡤ㸸ᕤᏛ㒊ᮦᩱ࣭໬ᏛᲷ఍㆟ᐊ㸦MC526㸧ඹ ദ㸸᪂Ꮫ⾡㡿ᇦ◊✲ࠕ」ྜ࢔ࢽ࢜ࣥ໬ྜ≀ࡢ๰〇࡜᪂ᶵ⬟ࠖ Complex oxides enable a diverse set of electronic properties. However, we do
not yet know how to prescriptively synthesize desired compositions or
polymorphs of materials, particularly if they are metastable. Metathesis (ordouble-exchange) reactions are well suited to address synthesis questions
pertaining to atomic transport and permit the identification of incipient stages ofphase differentiation in solid-state reactions. As an example, the reaction, A2CO3+ Mn2O3 + YCl3, where A = Li, Na, or K, yields different Y-Mn-O products (andpolymorphs) depending on which spectating alkali is present. From a
combination of in situ and ex situ analysis of myriad synthesis reactions
combined with first-principles calculation of thermodynamic parameters, we
identify competent intermediates that enable kinetic control of the reaction, suchas the phases LiMnO2 and YOCl. These results allow us to establish the criticalprocesses in solid-state reaction pathways that enable, or hinder, prescriptivesynthesis.
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426th Institute for Catalysis (ICAT) Colloquium

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ੵ৾৖ইটথॸॕ॔ૢ৷ఐ৾ଢ଼஢༠  మ७঑ॼ‫ش‬஼‫ڮ‬

Recent advances in synthetic polymer chemistry have allowed the generation of simple,
protein-like structures with biological activity from synthetic designer polymers. To mimic the
biological functions of the natural proteins, many synthetic approaches have incorporated vinyl
monomers bearing the constitutional amino acid residues found in nature. However, since vinyl
monomers have an all-carbon backbone, they are structurally rigid and have an intrinsic
limitation in aqueous solubility. These factors often pose a challenge for creating systems withfull potential to mimic natural polypeptides. Unlike many other existing approaches in theliteratures, we present to employ functional polyethers bearing amino acid side chains. Toward
this end, we develop a library of a novel class of well-defined, functional epoxide monomers,
which are polymerized into functional peptidomimetic polyethers via anionic ring-opening
polymerization. The integration of a flexible polyether backbone coupled with amino acidmoieties offers several advantages for materials and biomedical fields: (a) functional groupavailability resulting in improved hydrophilicity in biomimetics, and (b) capability ofself-assembly to form hierarchical superstructures. Two specific examples toward mimicking themarine mussel foot proteins and the antimicrobial peptides secreted from frog will be presented
with their future biomedical applications.
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This seminar is approved of the "Topical Lectures in Chemical Sciences and Engineering" (for MC students)
and the "Research in Chemical Sciences and Engineering II" (for DC students) under the Graduate School ofChemical Sciences and Engineering.

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ੵ৾৖ইটথॸॕ॔ૢ৷ఐ৾ଢ଼஢༠  మ७঑ॼ‫ش‬஼‫ڮ‬
Building up of complexly architectured macromolecules by deliberately linking polymer
chains has been one of the central themes in synthetic polymer chemistry. Combining different
chains and expanding the range of accessible architectures has enabled to create new materials
with unprecedented properties stemmed from the unique chemical nature. We are particularlyinterested in developing ways to control composition and spatial arrangements of the polymer
segments in the target architecture. In this talk, I would like to discuss how sequence,
segregation, and chemical structure of the segments can be controlled in a programmed fashion.
By highlighting our recent efforts on single unit monomer insertion (SUMI) in the synthesis ofasymmetric bottlebrush polymers, intramolecular segregation in the synthesis of heteroarm corecross-linked star polymers, and post-polymerization modification for synthesis of polyolefin, I
hope to demonstrate that previously inaccessible polymers with novel self-assembly behavior canbe realized.
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This seminar is approved of the "Topical Lectures in Chemical Sciences and Engineering" (for MC students)
and the "Research in Chemical Sciences and Engineering II" (for DC students) under the Graduate School ofChemical Sciences and Engineering.

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