Safety Data Sheet
1.Products and company identification
Product name

ROVAL ALPHA Zinc Rich Spray

Supplier NameSHANGHAI ROVAL ZINC RICH PAINT CORPORATION

Supplier Address

NO.393 Fenggong RD, Jiading Malu Shanghai, China

Telephone number+86-21-69156584

FAX+86-21-69156593

Emergency Telephone number+86-532-8388-9090

E-mailsh-info@roval.cn

Recommended use

Galvanizing Repair and Anti-corrosion of steel

Date of revision

Aug 1st, 2023

2. Hazards identification
2.1 Classification of the substance or mixture
PHYSICAL AND CHEMICAL HAZARDS
Flammable aerosol: Category 2
HEALTH HAZARDS
Acute toxicity inhalation (vapors): Category 4
Skin corrosion/irritation: Category 2
Serious eye damage/Eye irritation: Category 2
Reproductive toxicity: Category 1
STOT: Single exposure: Category 1 (central nerve system)
Category 3 (May cause respiratory irritation, May cause drowsiness or dizziness)
Repeated exposure: Category 1 (central nerve system, kidney)
ENVIRONMENTAL HAZARDS:
Acute aquatic toxicity: Category 1
Chronic aquatic toxicity: Category 2(Note) GHS classification without description: Not classified/Classification not possible
2.2 Label elements

Signal word: DANGER< ROVAL ALPHA Zinc Rich Spray >Page 1 of 8

HAZARD STATEMENT
H223 Flammable aerosol
H229: Pressurized container: may burst if heatedH315: Causes skin irritation
H319: Causes serious eye irritation
H332: Harmful if inhaled
H360: May damage fertility or the unborn child
H362: May cause harm to breast-fed children
H370: Causes damage to organs
H372: Causes damage to organs through prolonged or repeated exposure
H410: Very toxic to aquatic life with long-lasting effects.
PRECAUTIONARY STATEMENT
Prevention
P201: Obtain special instruction before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P211: Do not spray on an open flame or other ignition source.
P240: Ground/bond container and receiving equipment.
P251: Do not pierce or burn, even after use.
P260: Do not breathe dust/fumes/gas/mist/vapors/spray.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower.
P304+312: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses
if present and easy to do – continue rinsing.
P308+313: If exposed: Call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use carbon dioxide/dry powder/foam/dry sand to extinguish.
Storage
P410+411: Protect from sunlight. Store at temperatures not exceeding 40°C/104°F.
P405: Store locked up.
Disposal
P501: Dispose of contents/container in accordance with local/national regulation.

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3. Composition /information on ingredients
Mixture / Substance selection: Mixture
Chemical identity% WeighCAS numberToluene

25.3

108-88-3

Xylene0.22

1330-20-7

Ethyl benzene

0.21

100-41-4Acetone

5~1067-64-1

Dimethyl ether

35~40

115-10-6

Zinc

20~257440-66-6

Zinc oxide<5.01314-13-2

4. First-aid measures
IF INHALED
Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor / physician if you feel unwell.
IF ON SKIN (or hair)
Take off immediately all contaminated clothing. Rinse skin with water / shower.
Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice / attention.
IF IN EYES
Rinse cautiously with water for several minutes. Remove contact lenses. If present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice / attention.
IF SWALLOWEDDo NOT induce vomiting.
Immediately call a POISON CENTER or doctor / physician.
5. Fire-fighting measures
5.1 Extinguishing media
In case of fire, use carbon dioxide/dry powder/foam/dry sand to extinguish.
Do not use direct water jet.
5.2 Advice for firefighters
Evacuate non-essential personnel to safe area.
Eliminate all ignition sources if safe to do so.
Cool container with water spray.
Wear fire/flame resistant/retardant clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
6. Accidental release measures
6.1 Personnel precautions, protective equipment and emergency procedures
Evacuate area.
Keep unauthorized personnel away.
Wear an air-supplied respirator for handling a spill at a poor ventilated workplace.
Wear proper protective equipment.
Eliminate all sources of ignition and ventilate the area.
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6.2 Environmental precautions
Prevent spills from entering sewers, watercourses or low areas.
6.3 Methods and materials for containment and cleaning up
Absorb spill with inert material (dry sand, earth, et al), then place in a chemical waste container.
Fill the disposal into labelled, closable containers.
6.4 Preventive measures for secondary accident
Collect spillage.
Prepare extinguishers before catching fire.
Stop leak if safe to do so.
7. Handling and storage
7.1 Precautions for safe handling
Avoid breathing gas/mist/vapors/spray.
Keep away from heat/sparks/open flames/hot surfaces. -No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Exhaust/ventilator should be available.
Avoid contact with skin/eyes.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/eye protection/face protection.
Use personal protective equipment as required.
7.2 Storage
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
8. Exposure controls / personal protection
8.1 Control parameters
Chemical identity

ACGIH_TLV (2016)

Toluene20ppm (TWA)

Xylene100ppm (TWA)

Ethyl benzene

20ppm (TWA)
500ppm(TWA)

AcetoneZinc oxide

750ppm (STEL)
2mg/m³（TWA）

8.2 Exposure controls
Appropriate engineering controls
Exhaust/ventilator should be available.
Eye wash station should be available.
Washing facilities should be available.
Individual protection measures
Respiratory protection< ROVAL ALPHA Zinc Rich Spray >Page 4 of 8Wear respiratory protection
Hand protection
Wear protective gloves. Recommended material: impermeable or chemical resistant rubber
Eye protection
Wear safety glasses with side -shields or chemical safety goggle.
Skin and body protection
Wear protective clothing.
Wear impervious clothing and boots in case of repeated or prolonged treatment.
9. Physical and chemical properties
Physical state: Liquid

Color: SilverOdor: Smells like solvent

Boiling point: -24.8°C ~230°C

Flash point: Paint liquid -15.0°C, propellant -41.1°C

Auto-ignition temperature: 190°C

Lower and upper explosion limit/flammability limit:
Lower explosion limit: 0.6vol%Upper explosion limit: 27vol%

Vapor pressure: 506.6kPa (20.8°C)

Specific Gravity: 0.96

10. Stability and Reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
Stable under normal storage/handling conditions.
10.3 Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
10.5 Incompatible materials
Reactive or incompatible with the following materials: oxidizing materials
10.6 Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

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11. Toxicological Information
Acute Toxicity
Material

Oral

Category

DermalCategory

Toluene5.0g/kgNot classified

12.0g/kg

Not classified

Xylene3.5g/kgNot classified

Ethyl benzene

3.5g/kgNot classified

15.4g/kg

Not classified

Acetone>5.0g/kg

Not classified>5.0g/kg

Not classified

Dimethyl ether

Not possible

Not possible

Zinc>2.0g/kg

Not classified

Zinc oxide>5.0g/kg

Not classified

Material

Not possible

GasCategory

Not possible>5.0g/kg

Vapor

Category

Not classified

Dust / Mist

Category

TolueneNot applicable

4000ppm4

Not possible

XyleneNot applicable

6700ppm4

Not possible

Ethyl benzene

Not applicable

4000ppm4

Not possible

AcetoneNot applicable

32000ppm

Not classified

Not possible

Dimethyl ether

164000ppm

Not classified

Not applicableNot classified

Zinc

Not applicableNot possible>5.41mg/L

Not classified

Zinc oxide

Not applicableNot applicable>5.7mg/L

Not classified

SkinEyeRespiratory

corrosion/Irritation

damage/Irritation

sensitization

Toluene

22B

Not possible

Not classified

Xylene22A

Not possible

Not possible

Ethyl benzene

32B

Not possible

Not possible

AcetoneNot classified

2B

Not possible

Not classified

Dimethyl ether

Not possible

Not possible

Not possible

Not possible

Zinc

Not classified

2B

Not possible

Not classified

Zinc oxide

Not classified

Not classified

Not possible

Not classified

Material

Material

Skin sensitization

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

TolueneNot classified

Not possible

1AXyleneNot classified

Not classified

1B

Ethyl benzene

Not classified

2

1BAcetone

Not classified

Not classified

2

Dimethyl ether

Not possible

Not possible

Not possible

Zinc

Not possible

Not possible

Not possible

Zinc oxide

Not possible

Not possible

2< ROVAL ALPHA Zinc Rich Spray >Page 6 of 8

Material

STOT (single)

STOT (Chronic)

Aspiration Hazard

1 (central nerve system, liver)

11 (central nerve system)
Toluene3 (respiratory tract irritation,anesthetic action)
1 (respiratory system, liver, central

Xylenenerve system, kidney)

1 (respiratory system, nervesystem)

3 (anesthetic action)
Ethyl Benzene
Acetone2 (central nerve system)

Not possible

12 (blood)

23 (anesthetic action)

Not possible

Not possible

Not possible

Not possible

Not possible

Not possible

Not possible

3 (respiratory tract irritation)
3 (respiratory tract irritation,anesthetic action)

Dimethyl ether
Zinc
Zinc Oxide2

1 (respiratory system, systemictoxicity)

12. Ecological Information
12.1 Ecotoxicity
Material

Acute aquatic toxicity

Chronic aquatic toxicity

Hazard to Ozone

Toluene23Not possible

Xylene22

Not possible

Ethyl benzene

1

Not classified

Not possible

AcetoneNot classified

Not classified

Not possible

Dimethyl ether

Not classified

Not classified

Not possible

Zinc

11

Not possible

Zinc oxide11Not possible

12.2 Persistence and degradative
Xylene does not have rapid degradative (BOD: 39%)
Ethyl benzene has rapid derivative, stripping from water (BOD: 81-126%)
12.3 Bioaccumulation potential
Xylene may be low potential (log Kow=3.16)
Ethyl Benzene may be low potential (log Kow=3.15)
13. Disposal considerations
Waste treatment methods
Avoid release to the environment.
Dispose of contents/container in accordance with local/national regulation.
Dispose to an authorized waste collection point.
14. Transport information
UN No.

: 1950UN Class: 2.1 (Flammable gas)

PG

: ---

< ROVAL ALPHA Zinc Rich Spray >Page 7 of 815. Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture.
Other information is not available.
Other regulatory information
We are not able to check up the regulatory information with regard to the substances in your country orregion, therefore, we request this matter would be filled by your responsibility.
16. Other information
International Chemical Safety Cards (ICSCs)/ Hazardous Substances Data Bank (HSDB)MSDS from The Japan Paint Manufacturers Association (JPMA)MSDS from manufacturers of raw materials
This data sheet is created based on the information we currently have and may be revised according to newinformation. In addition, the precautions apply only to normal handling, and in the case of special handling,please make adequate countermeasure to maintain your safety.

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