SDS No.65S

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Implementation: Sep.20,2011
Issue date: Jun.1,2024

SAFETY DATA SHEET
1. Product and company(manufacturer) identification
Product:
Manufacturer:
Address:
Responsible section:
Telephone:
Urgent telephone:
Fax:
Urgent contact:
Application & restriction
Document number:
2. Hazards identification
GHS Classification
Physicochemical hazards:

Health hazards:

Environmental hazards:

ESLON Adhesive No.65S
Sekisui Chemical Co., Ltd.
Toranomon 2-10-4, Minato-ku, Tokyo 105-8566
Urban Infrastructure & Environmental Products Company
Pipe Systems Division+81-3-6748-6492+81-3-6748-6492+81-3-6748-6564
same as above
Adhesive for polyvinyl chloride piping system
Other applications are prohibited.
#65S

Explosives
Not classified
Flammable gases
Not classified
Aerosols and chemicals under
Not classified
pressure
Oxidizing gases
Not classified
Gases under pressure
Not classified
Flammable liquids
Category 2
Flammable solids
Not classified
Self-reactive substances andNot classified
mixtures
Pyrophoric liquids
Not classified
Pyrophoric solids
Not classified
Self-heating substances and mixtures Classification Not Possible
Substances and mixtures which, in
Not classified
contact with water, emit flammablegases
Oxidizing liquids
Not classified
Oxidizing solids
Not classified
Organic peroxides
Not classified
Corrosive to metals
Not classified
Desensitized explosives
Classification Not Possible
Acute toxicity (oral)
Category 4
Acute toxicity (dermal)
Category 4
Acute toxicity (inhalation: gas)
Not classified
Acute toxicity (inhalation: vapor)
Category 4
Acute toxicity (inhalation: dust andClassification Not Possible
mist)
Skin corrosion/irritation
Category 2
Eye damage/irritation
Category 2A
Respiratory sensitization
Classification Not Possible
Skin sensitization
Category 1
Germ cell mutagenicity
Category 2
Carcinogenicity
Classification Not Possible
Reproductive toxicity
Category 2
Specific target organ toxicity (single Category 1 (respiratory)
exposure)
Category 2(kidneys, central nervous
Category 3 (narcotic effect, respiratory
tract irritancy)
Specific target organ toxicity
Category 1 (respiratory, bones, digestive(repeated exposure)tract, nervous system,central nervous
system)Aspiration hazard
Not classified
Hazard to the aquaticNot classified
environment(Acute hazard)
Hazard to the aquaticNot classified
environment(Long-term hazard)
Hazard to the ozone layer
Classification Not Possible

SDS No.65S

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Pictogram or symbol:
Signal word:
Hazard statement:

Danger(H302+H312+H332)Harmful if swallowed, in contact with skin or if inhaled.
(H225)Highly flammable liquid and vapor.
(H315)Causes skin irritation.
(H317)May cause an allergic skin reaction.
(H319)Causes serious eye irritation.
(H335)May cause respiratory irritation.
(H336)May cause drowsiness or dizziness.
(H341)Suspected of causing genetic defects.
(H361)Suspected of damaging fertility or the unborn child.
(H370)Causes damage to organs(respiratory).
(H371)May cause damage to organs(kidneys, central nervous system).
(H372)Causes damage to organs(respiratory, bones, digestive tract, nervous
systems, central nervous systems) through prolonged or repeated exposure.

Precautionary statement:

Obtain special instructions before use.(P201)
Do not handle until all safety precautions have been read and understood.(P202)
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.(P210)
Keep container tightly closed.(P233)
Ground/bond container and receiving equipment.(P240)
Use explosion-proof electrical/ventilating/lighting/ equipment.(P241)
Use only non-sparking tools.(P242)
Take precautionary measures against static discharge.(P243)
Do not breathe dust/fume/gas/mist/vapors/spray. (P260)
Avoid breathing dust/fume/gas/mist/vapors/spray. (P261)
Wash hands and eyes thoroughly after handling. (P264)
Do not eat, drink or smoke when using this product.(P270)
Use only outdoors or in a well-ventilated area.(P271)
Contaminated work clothing should not be allowed out of the workplace.(P272)
Wear protective gloves/protective clothing/eye protection/faceprotection.(P280)
IF ON SKIN: Wash with plenty of soap and water.(P302+P352)
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.(P303+P361+P353)
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. (P304+P340)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing.(P305+P351+P338)
IF exposed or concerned: Get medical advice/attention.(P308+P313)
Call a POISON CENTER or doctor/physician if you feel unwell.(P312)
Get medical advice/attention if you feel unwell.(P314)
Specific treatment (see label).(P321)
Rinse mouth.(P330)
If skin irritation occurs: Get medical advice/attention.(P332+P313)
If skin irritation or rash occurs: Get medical advice/attention.(P333+P313)
If eye irritation persists: Get medical advice/attention.(P337+P313)
Take off contaminated clothing and wash it before reuse.(P362+P364)
In case of fire: Use for extinction:(P370+P378)
Store in a well-ventilated place. Keep container tightly closed.(P403+P233)
Store in a well-ventilated place. Keep cool.(P403+P235)
Store locked up.(P405)
Dispose of contents/container in accordance withlocal/regional/national/international regulations.(P501)

3. Composition/information on ingredients
Nature of composition:
MixtureChemical or common name:
Adhesive, containing vinyl chloride-vinyl acetate copolymer
Component
Cyclohexanone
Methyl ethyl ketone
AcetoneResin (VC-VAc copolymer, etc.)
Tin compoundContent

CAS Number

54%
17%
13%
17%
Less than 0.3%

108-94-1
78-93-3
67-64-1
9003-22-9
15571-58-1

Reference Number inGazetted List in Japan(3)-2376(2)-542(2)-542(6)-76(2)-2307

OthersSDS No.65S

4. First-aid measures
If vapor is inhaled:
If touched to skin:
If gets in eye:If swallowed:
Anticipated acute & chronic symptoms:

Protection of first-aid provider:
Special note to physician:
5. Fire-fighting measures
Extinguishing agents:
Prohibited extinguishing agent:Specific hazards:

Proper extinguishing method:

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Take the affected person to a clean-air space and give him rest in a easybreathing pose.
Seek physician's counsel as may be needed.
Wash the skin immediately with a lot of water and soap.
Take off the contaminated clothing's for cleaning.
Seek physicians counsel if he suffers from irritation or drowsiness.
Thoroughly wash the eye with clean water for a several minutes. Remove
contact lens if easily removable. Continue washing after removal.
Seek physician's counsel.
Immediately wash the mouth with water.
Immediately seek physician's counsel.
Rinse the mouth well and drink a lot of water to vomit.
Irritation to respiratory organs, cough and gasp, when inhaled.
Irritation to digestive organs, nausea, vomit and diarrhea, when swallowed.
Skin irritation, defatting, eye irritation, reddening and ache, when contacted.
Anesthesia, headache, drowsiness, restricted vision, vomit, diarrhea and loss of
consciousness, when over-exposed to vapor.
First-aid provider should use protective wears such as organic solvent mask,
when the circumstances require.
No information
Carbon dioxide, powder agent, foam agent
Water flux
Fire may cause to generate irritant, toxic or erosive gas.
Easily flammable. It will readily be ignited by heat, spark or flame.
Heating of container may cause explosion.
Easily inflammable liquid and vapor.
Remove surrounding combustibles and use extinguishing agents.
Use foam agent to choke a large scale fire.
Spray water over the neighborhood to cool and prevent fire spread.
Fight against fire standing to its windward as much as possible and wear
Respirator if necessary.

6. Accidental release measures
Health hazard precaution, protective wear and first- Workers should use protective wears ( See Chapter 8) to prevent contact withaid
the spilt adhesive and inhalation of its vapor.
Rope off the crowd from the leak spot.
Work from the windward and evacuate the leeward crowd.
In case of indoor leakage, ventilate as much as possible until the cleaning iscompleted.
Environmental hazard precaution:
Prevent flow out to river, etc. so as not to badly affect the environment.
Recovery and neutralization:
For small scale leakage, use absorbent (sawdust, dirt, sand, waste rug) toremove most of the spill and wipe off the rest using waste rug.
For large scale leakage, build bank around the spill and lead the liquid to a safer
place for recovery.
Prevention of secondary casualty:
Quickly remove all the combustibles from around the leak spot and provide
extinguishers ready for use.

SDS No.65S

7. Handling and storage precautions
Handling
Technical measures:
Local & total ventilation:
Safe handling:

4/7pageUse protective wears if inhalation or skin contact is foreseen.
Fire ban.
Handling work must be practiced in a room where local or total ventilation
facility is functioning.
Ban of high temperature substance, sparking and fire at nearby points.
Prohibition of eating, drinking and smoking while the product is used.
Wash hands well after handling.
Avoid contact of the product with eye, skin and clothing.
Do not inhale vapor, mist and spray of the product.
Handle it only after reading and understanding all the precautions.
Use the product only in a well ventilated room or outdoors.

Storage
Storing conditions:

8. Exposure controls and personal protection
Facility measures:Store in a remote room from heat, sparks and naked flame. No smoking in thestorage room.
Store in a cool, ventilated room.
Lock the storage room.
Local ventilation of closed work room or total proper ventilation to prevent
vapor inhalation.
Cyclohexanone

Methyl ethyl ketone

Acetone20 ppm200 ppm

500 ppm

Japan society for occupational health.

25 ppm200 ppm

200 ppm

ACGIH

20 ppm200 ppm

500 ppm

Control concentration:
Permissible concentration (Exposure limit, Biological
exposure guide line)

TLV-TWA

Protective wears:
Respiratory protection:
Hand protection:
Eye protection:
Skin and body protection:
Hygienic measures:

Use aspirator with appropriate filter
Impermeable gloves
Solvent-resistant goggles
long-sleeve fatigue uniform
Wash hands well after handling.

9. Physical and chemical properties
Physical state, form:
Color:
Odor:
Melting point/freezing point:
Bp, initial bp & boiling range:
Flammability:
Evaporation rate:
Flash point:
Auto ignition point:
Decomposition temperature:pH:
Dynamic viscosity:
Solubilities:
n-Octanol/water partition coefficient:(log Pow)
Vapor pressure:Specific gravity (density):
Vapor density:
Particle characteristics:
nonvolatile content:
Viscosity:
10. Stability and reactivity
Stability:
Possibility of hazardous reaction:
Prohibitive conditions:
Prohibitive contact:
Hazardous decomposed substances:

LiquidColorless transparent
Characteristic stimulative odor
-20℃ or lower
56.5℃ (bp)Highly flammable liquid and vapor
no data available-17℃ (Closed Method)
420℃
no data available
Not applicableca.540（mm2/s）/20℃
insoluble in water
no data available
no data available
ca.0.93(20℃)
no data available
no data availableca. 16%ca. 500 mPa・s

Stable under normal conditions and handling.
Vigorously reacts with strong oxidizing agents and ignites.
Heat
With oxidizing agent
Generates Aldehyde, Acid and Organic matter by thermal decomposition.

SDS No.65S

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11. Hazard information
Acute toxicity:(Appended Table)
Content

Acute toxicity(oral)

Acute toxicity(dermal)Acute toxicity(inhalation: gas)

Acute toxicity(inhalation: vapor)

Acute toxicity(inhalation: dust
and mist)

Cyclohexanone

54%

Category 4(1544mg/kg)

Category 3(947mg/kg)

Not classified

Category 3(2450ppm)

Not Classified(8000ppm)

Methyl ethyl
ketone17%

Not Classified(>2000mg/kg)

Not Classified(>5000mg/kg)

Not classified

Category 4(11700ppm)

Classification Not
Possibleacetone13%

Not Classified(>5000mg/kg)

Not Classified(>7400mg/kg)

Not classified

Not Classified(32000ppm)

Classification Not
Possible

Resin (VC-VAc
copolymer, etc.)

17%Classification Not
PossibleClassification Not
PossibleClassification Not Classification Not Classification Not
Possible
Possible
Possible

Acute toxicity(oral):Acute toxicity(dermal):Acute toxicity(inhalation: vapor):Skin corrosion/irritation:
Eye damage/irritation:

Respiratory sensitization:
Skin sensitization:

Germ cell mutagenicity:
Carcinogenicity:
Reproductive toxicity:
Specific target organ toxicity(single exposure):

Specific target organ toxicity(repeated exposure):

Aspiration hazard:

The product contains substances of acute toxicity (oral) of Categories
indicated in Appended Table. The dose is calculated for the mixture (theproduct) to be ATE mix=1500 mg/kg.
The product, as a mixture, falls in Category 4.
The product contains substances of acute toxicity (transdermal) of Categories
indicated in Appended Table. The dose is calculated for the mixture (theproduct) to be ATE mix=1723 mg/kg.
The product, as a mixture, falls in Category 4.
The product contains substances of acute toxicity (vapor inhalation) of
Categories indicated in Appended Table. The dose is calculated for the mixture(the product) to be ATE mix=17mg/l
The product, as a mixture, falls in Category 4.
The product contains skin-irritating substances of the following Categories:
Category 2: Cyclohexanone (54 %), methyl ethyl ketone (17 %).
The product, as a mixture, falls in Category 2.
The product contains caustically injuring and irritating substances of thefollowing Categories:
Category 2A: Cyclohexanone (54 %), methyl ethyl ketone (17 %)Category 2B: Acetone(13%)
The product, as a mixture, falls in Category 2A.
Respiratory organ sensitization: No available data.
The product contains caustically injuring and irritating substances of thefollowing Categories:
Category 1: Cyclohexanone (54 %).
The product, as a mixture, falls in Category 1.
The product contains mutagenicity substances of the following Category:Category 2: Cyclohexanone (54 %).
The product, as a mixture, falls in Category 2.
Respiratory organ sensitization: No available data.
The product contains reproductive toxicity of the following Category:Category 2: Cyclohexanone (54 %)、Acetone(13%)
The product, as a mixture, falls in Category 2.
The product contains single-exposure toxic substances of the following
Categories:
Cyclohexanone （54%）＞1%, Category 1 (respiratory), Category 2 (central
nervous system) and Category 3 (narcotic effect),Methyl ethyl ketone （17%）＞1%, Category 2 (Kidneys) and Category 3(respiratory tract irritancy).
Acetone （13%）＞1%, Category 3 (narcotic effect, respiratory tract irritancy).
The product, as a mixture, falls in Category 1 (respiratory), Category 2 (kidneys,
central nervous system) and Category 3 (narcotic effect, respiratory tract
irritancy).
The product contains multiple-exposure toxic substances of the following
Categories:
Cyclohexanone （54%）＞1%, Category 1 (bones, central nervous system),
Methyl ethyl ketone （17%）＞1%, Category 1 (nervous system),Acetone （13%）＞1%, Category 1 (central nervous system, respiratory, digestive
tract).
The product, as a mixture, falls in Category 1 (respiratory, bones, digestive
tract, nervous systems, central nervous systems).
The product contains more than 10% in total of respiratory-harmful substancesof the following Category, however, the kinematic viscosity at 40℃ is more than
20.5mm2/s:
The product, as a mixture, falls Not Classified.

SDS No.65S

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12. Ecological information
Hazard to the aquatic environment(Acute hazard):
Hazard to the aquatic environment(Long-term
hazard):Hazard to the ozone layer：
13. Notes on disposal
Residual & waste:

Contaminated containers & packages:

14. Transport information
International rule
UN number:
UN classification:
Packing Group:Sea Pollution Prevention Act

Not classified
Not classified
Does not contain any ingredient listed in the Annexes to the Montreal Protocol.
Classification Not Possible.
In the disposal of residual and other wastes, observe the relevant laws
/regulations and local government rules.
Users of the product should contract with the local government or licensed'Industrial Waste Processors' for disposal of waste.
It is important to let the contractor know well of fire and health hazards of the
product, prior to disposal.
Clean the containers for reuse or dispose them properly in accordance with
relevant regulations and local government rules.
Completely empty containers prior to disposal.

1133 (Adhesive, containing inflammable liquid)Class 3 (inflammable liquid)Ⅱ
Harmful liquid material
The enforcement order separate table first；Z Group(Cyclohexanone, methyl ethyl ketone, Acetone)
However, it is non-corresponded when net weights of one container are less than 5L

Domestic control:
Guidance Number
Onshore control info.
Offshore control info.
Air cargo control info.
Special safety measure:

15. Regulatory information
Labor Safety and Hygiene Law:

Fire Defense Law:
PRTR Law:
Poisonous & Deleterious Substance Control Law:
Sea Pollution Prevention Act

128
Observe the Fire Defense Law.
Observe the Marine Vessel Safety Law.
Observe the Aviation Law.
Observe the Fire Defense Law.
On-board containers of hazardous material must be piled firmly and orderly to
avoid falling, tumbling and breaking.
Cargo of hazardous material must be transported in a way the containers or thematerial itself do not suffer severe friction and vibration.
If possible cause of casualty, such as heavy leakage, is found duringtransportation, try to remedy the situation and notify the fact to the nearby fire
department or the relevant bureau.
The driver carrying hazardous material must hold Yellow Card.
Do not load hazardous materials together with food and feedstuff.
Hazardous materials to be notified to the authority (Chapter 57, Section 2)(Cyclohexanone, methyl ethyl ketone, Acetone, Tin compound)
Hazardous materials to be posted (Chapter 18 of Ordinance)(Cyclohexanone, methyl ethyl ketone, Acetone)
2nd class organic solvents (Solvent Addiction Prevention Rule, Clause 1.1.4)(Cyclohexanone, methyl ethyl ketone, Acetone)
Carcinogenicity of chemical substances(Ordinance on Industrial Safety and Health Chapter 34,Section 2-4)
Not applicableChemical substances that cause skin and other skin disorders(related to Article 22 of the Law).
(Cyclohexanone, methyl ethyl ketone)
No. 4 Haz-Mat, No.1 Petroleum, Non-water soluble liquid (Hazard Degree II)
Not applicableNot applicable
Harmful liquid material
The enforcement order separate table first；Z Group(Cyclohexanone, methyl ethyl ketone, Acetone)
However, it is non-corresponded when net weights of one container are less than 5L

SDS No.65S

16. Other information
Literature:

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1) Chemicals Safety Data Sheet (MSDS) Part 1: Content and Order of Items
2) Guideline for MSDS Edition (Revised Edition) by Japan Chem. Ind. Assoc.
3) GHS Classification Database, Site of National Institute of Technology and Evaluation
4) Hazard Handbook of Chemicals by Japan Industrial Safety and Health Association
5) Hazard communication of chemicals based on GHS-Labelling and Safety Data Sheet(SDS) JIS
Z 7253:2019

This data sheet is edited by referring to currently available information, however, it is not intended to guarantee the data values or the
precision of contained information. The precautions mentioned above are for ordinary handling and use only therefore please handle withcare by implementing appropriate safety measures for new application and usage.