EHS-SDS-1002

Product: Carefree® Valve Regulated Sealed
Lead Acid Battery
Date: 2/05/2018
Revision: Orig

Applicable Product CF, CFR, HE
Numbers: series
Document Number: EHS-SDS-1002

SAFETY DATA SHEET
Carefree and HE Valve Regulated Sealed Lead Acid Batteries®

SECTION 1- IDENTIFICATION
Product Identifier/Name:
Other Means of Identification:
Manufacturer Name:
Emergency Telephone:
Recommended use:
Recommend Restrictions:
Telephone for information:
Product Identifier/Name:

Carefree® valve regulated sealed lead acid battery
None
EaglePicher Technologies, PO Box 49, Joplin, MO 64802
CHEMTREC: 1-800-424-9300
All proper and legal purposes
None known
1-417-623-8000
Valve Regulated Sealed Lead Acid Battery (VRB, VRLA, SLAB).

SECTION 2- HAZARD IDENTIFICATIONGHS Classification of the substance or mixture:
Metal Corrosion Category 1, Acute Toxicity (oral) Category 4, Acute Toxicity (inhalation) Category 3, Skin
Corrosion/Irritation Category 1A, Serious Eye Damage Category 1, Carcinogenicity Category 1A, Reproductive
Toxicity Category 1A, Specific Target Organ Toxicity – SE (resp. irr.) Category 3, Specific Target Organ Toxicity– RE Category 2, Acute Aquatic Hazard Category 1, Chronic Aquatic Hazard Category 1
GHS Label Elements

Signal Word: DANGERIn the Event of the Internal Battery Components Being Exposed:
Hazard Statements:
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage.
H302 Harmful if swallowed
H318 Causes serious eye damage.
H331 Toxic if inhaled
H351 Suspected of causing cancer.
H360 May damage fertility or the unborn child. H400 Very toxic to aquatic life
H372 Causes damage to organs - nervous system. H420 Very toxic to aquatic life with long lasting effects

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EHS-SDS-1002

In the Event of Exposure to Internal Components:
Precautionary Statements:
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe mist/vapors/spray
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response:
P301+P312
P301+P330+P331
P302+P352
P303+P361+P353
P304+P340
P305+P351+P338
P308+P313
P310
P333+P313
P342+P311
P363
P390
P391

IF SWALLOWED: Call a POISON CENTER/ doctor/physician/ first aider/if you feelunwell.
IF SWALLOWED: Rinse mouth. Do NOT induce
IF ON SKIN: Wash with plenty of water and soap
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/ shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/attention
Immediately call a POISON CENTER/ doctor/physician/ first aider
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a POISON CENTER/ doctor/ physician/ firstaider
Wash contaminated clothing before reuse.
Absorb spillage to prevent material damage.
Collect spillage.

Other Hazards:
OSHA HCS 2012: Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product isconsidered hazardous.

SECTION 3 - COMPOSITION, INFORMATION ON INGREDIENTSThe following list of chemicals may be found in EaglePicher Technologies Lead Acid batteries. The specific battery
number will determine the exact ingredients and percentages.
Chemical Name
Lead/Lead Oxide/Lead
SulfateSulfuric acid
Calcium (lead calcium
alloy)
Arsenic (inorganic)
Tin
Inert ingredients

CAS Number
7439-92-1

Composition(%) by Weight
60-70

Classification

7664-93-9
7440-70-2

10-15
<0.15

Repr. 1A; STOT RE 1 (Liver, Kidney, Blood,
Nervous system); Carc. 2
Eye Dam. 1; Skin Corr. 1A
N/A

7440-38-2
7440-31-5
NA

<1
<1
<6

N/A
N/A
N/A

CA Prop 65 Warning: Battery posts, terminals, and related accessories can contain lead and lead compounds,chemicals known to the State of California to cause cancer and reproductive harm, and during charging, strong2.

EHS-SDS-1002

inorganic acid mists containing sulfuric acid are evolved, a chemical know to the State of California to cause
cancer. Wash hands after handling.

SECTION 4- FIRST AID MEASURES

Inhalation - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable forbreathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing.
Do not use mouth-to-mouth method if victim inhaled the substance; give artificial respiration with the aid ofa pocket mask equipped with a one-way valve or other proper respiratory medical device.

Skin - IF ON SKIN: Wash with plenty of water for at least 15 minutes. Remove contaminated clothing andwash before reuse. If signs/symptoms develop, seek medical attention.

Eyes - IF IN EYES: Rinse with water for at least 15 minutes while holding eyelids open. Remove contactlenses, if present and easy to do. Continue rinsing. If signs/symptoms develop, get medical attention.

Ingestion - Do NOT induce vomiting. If conscious, drink large quantities of milk or water. Get medical
attention immediately. Never give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed:
Acute: Electrolyte is corrosive and contact may cause skin irritation and chemical burns. Electrolyte causes severe
irritation and burns of eyes, nose and throat. Ingestion can cause severe burns and vomiting.
Subchronic and Chronic Health Effects: Repeated contact with electrolyte causes irritation and skin burns.
Repeated exposure to mist may cause erosion of teeth, chronic eye irritation and/or chronic inflammation of thenose, throat and lungs.
Prolonged exposure to lead may cause central nervous system damage, gastrointestinal disturbances, anemia,
irritability, metallic taste, insomnia, wrist-drop, kidney dysfunction, and reproductive system disturbances.
Pregnant women should be protected from excessive exposure to prevent lead from crossing the placental barrier
and causing infant neurological disorders.
Medical Conditions Generally Aggravated by Exposure: Contact with internal components if battery is broken
or opened, then persons with the following conditions must take precautions: pulmonary edema, bronchitis,
emphysema, dental erosion and tracheobronchitis.
Routes of Entry:
Inhalation, ingestion

SECTION 5- FIRE FIGHTING MEASURES
Flash Point:
Not
Applicable

Flammable Limits in Air% by Volume:
NA

Extinguishing Media:
Class ABC Dry
Chemical, CO2, Halon.

Special FireFighting
Procedures

Lead acid batteries do not burn, or burn with difficulty. Do not use water on fires wheremolten metal is present. Extinguish fire with agent suitable for surrounding combustible
materials. Cool exterior of battery if exposed to fire to prevent rupture. The acid mist
and vapors generated by heat or fire are corrosive. Use NIOSH approved self-contained

3.

Auto-Ignition:
Not ApplicableEHS-SDS-1002

breathing apparatus (SCBA) and full protective equipment operated in positive-pressure
mode.

Unusual Fire
and
Explosion
Hazards

Unsuitable Extinguishing Media: Water should not be used unless from a safe
distance due to vigorous and exothermic reaction which will result.
Sulfuric acid vapors are generated upon overcharge and polypropylene case failure.
Use adequate ventilation. Avoid open flame/spark/other sources of ignition nearbattery.

SECTION 6- ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures:
Use acid resistant aprons, boots, and protective clothing. ANSI approved safety glasses with side shields and faceshield recommended.
Methods and Materials for Containment and Cleanup:
As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions.
Keep unauthorized personnel away. Do not get water inside container.
Avoid contact with any spilled material. Stop leak if you can do it without risk. If battery is leaking, place battery ina heavy duty plastic bag. Contain spill by diking with soda ash, etc. Neutralize spill area with soda ash or lime,
dilute with acetic acid. Make certain mixture is neutral then collect residue and place in a drum or other suitablecontainer.
Environmental Precautions:
Lead and its compounds and sulfuric acid can pose a severe threat to the environment. Contamination of water,soil, and air should be prevented. Avoid runoff to waterways and sewers.

SECTION 7- HANDLING AND STORAGE
Precautions to be Taken in Handling and Storage: Store away from reactive materials, open flames and sourcesof ignition as defined in Section 10 – Stability and Reactivity Data. Store batteries in cool, dry, well ventilatedareas. Batteries should be stored under roof for protection against adverse weather conditions. Avoid damage tocontainers.
Other Precautions: Good personal hygiene and work practices are mandatory. Refrain from eating, drinking or
smoking in work areas. Thoroughly wash hands, face, neck and arms before eating, drinking and smoking. Work
clothes and equipment should remain in designated lead contaminated areas, and never taken home or launderedwith personal clothing. Wash soiled clothing, work clothes and equipment before reuse.

4.

EHS-SDS-1002

SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION
Exposure Limits / Guidelines
Chemical Name
OSHA PEL/TWA Exposure
ACGIH TLV
LimitsLead/Lead Oxide/Lead Sulfate
0.05 mg/m3
0.05 mg/m3
3
Sulfuric acid
1.0 mg/m
1.0 mg/m3
Calcium (lead calcium alloy)
Not establishedNot establishedArsenic (inorganic)
0.01 mg/m3
0.01 mg/m3
3
Tin
2 mg/m2 mg/m3
Inert ingredients
N/A
N/A
Note: PELs for individual states may differ from OSHA PELs. Check with local authorities for the applicable state
PELs.
Engineering Controls:
No specific engineering controls are required to prevent exposure to internal components of the sealed battery. Use
local exhaust when PEL is exceeded.
Exposure Controls:
Personal Protective Equipment:
Respiratory Protection: None required under normal conditions. Acid gas NIOSH approved respirator when the
PEL is exceeded or employee experiences respiratory irritation.
Protective Gloves: Wear acid resistant gloves.
Eye Protection: ANSI approved safety glasses with side shields. Face shield recommended.
Other Protective Clothing or Equipment: Safety shower and eyewash.
Administrative Controls:
Follow proper handling guidelines in this SDS.

SECTION 9- PHYSICAL AND CHEMICAL PROPERTIESBOILING POINT (760 mm Hg)
SPECIFIC GRAVITY
VAPOR PRESSURE (mm Hg, 25ºC)
VAPOR DENSITY (air=1)
VOLATILE BY VOLUME (%)
EVAPORATION RATE (butyl acetate=1)
PHYSICAL STATE
SOLUBILITY IN WATER (% by weight)
PH
APPEARANCEODORODOR THRESHOLDMELTING POINT/FREEZING POINT

N/A
1.250 – 1.320
N/A
Hydrogen: 0.069 Electrolyte: 3.4 @ STP
N/A
N/A
Solid plastic rectangular shape. .
100% soluble (electrolyte)<2Battery: Plastic solid. Case has metal terminals.
Lead: gray, metallic, solid; gray/brown oxide
Electrolyte: clear liquid
Odorless, liquid absorbed in glass mat material. No
apparent odor
N/A
> 320˚F

5.

EHS-SDS-1002

FLAMMABILITYUPPER/LOWER FLAMMABILITYEXPLOSIVE LIMITSRELATIVE DENSITYPARTITION COEFFICIENT: NOCTANOL/WATER
AUTO IGNITION TEMPERATUREDECOMPOSITION TEMPERATURE
VISCOSITY

N/A
N/A
N/A
N/A
N/A
Cases decompose at >320˚ F
N/A

SECTION 10- STABILITY AND REACTIVITY
1. REACTIVITY: Electrolyte – water reactive (1)2. STABLE OR NOT STABLE: Stable
3. INCOMPATIBILITY (MATERIAL TO AVOID): Sparks, open flames, keep battery away from strongoxidizers.
4. HAZARDOUS DECOMPOSITION PRODUCTS: Combustion can produce carbon dioxide and carbon
monoxide. Will release an explosive hydrogen/oxygen gas mixture. Oxides of lead, lead, and/or leadcompounds may be released. Sulfuric acid may release sulfur dioxide and/or sulfur trioxide.
5. HAZARDOUS POLYMERIZATION: Has not been reported.
6. CONDITIONS TO AVOID: Avoid short-circuiting, overcharging and smoking or sparks near battery surface.
Cases decompose at >320˚ F.

SECTION 11- TOXICOLOGICAL INFORMATIONGHS Properties
Acute toxicity
Aspiration Hazard
Carcinogenicity
Germ Cell Mutagenicity
Skin corrosion/Irritation
Skin sensitization
STOT-RESTOT-SE
Toxicity for Reproduction
Respiratory sensitization

Classification
EU/CLP • Acute Toxicity - Oral 4 - ATEmix = 703.47 mg/kg
OSHA HCS 2012 • Classification criteria not met
EU/CLP • Classification criteria not met
OSHA HCS 2012 • Classification criteria not met
EU/CLP • Classification criteria not met
OSHA HCS 2012 • Carcinogenicity 2
EU/CLP • Classification criteria not met
OSHA HCS 2012 • Classification criteria not met
EU/CLP • Skin Corrosion 1A
OSHA HCS 2012 • Skin Corrosion 1A
EU/CLP • Classification criteria not met
OSHA HCS 2012 • Classification criteria not met
EU/CLP • Specific Target Organ Toxicity Repeated Exposure 2
OSHA HCS 2012 • Specific Target Organ Toxicity Repeated Exposure 1
EU/CLP • Classification criteria not met
OSHA HCS 2012 • Classification criteria not met
EU/CLP • Toxic to Reproduction 1A
OSHA HCS 2012 • Toxic to Reproduction 1A
EU/CLP • Classification criteria not met

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EHS-SDS-1002

Serious eye damage/Irritation

OSHA HCS 2012 • Classification criteria not met
EU/CLP • Classification criteria not met
OSHA HCS 2012 • Serious Eye Damage 1

Potential Health Effects
Inhalation
Acute (Immediate)

Chronic (Delayed)

Lead - For industry, inhalation is much more important than is ingestion. Systemic effects
include loss of appetite, anemia, malaise, insomnia, headache, irritability, muscle and joint
pains, tremors, flaccid paralysis without anesthesia, hallucinations and distorted
perceptions, muscle weakness, gastritis and liver changes. Major organ systems affected
are the nervous system, blood system and kidneys. Experimental evidence suggests thatblood levels of lead below 10 μg/dL can lower the IQ scores of children. Low levels oflead impair neurotransmission and immune system function and may increase systolicblood pressure. Reversible kidney damage can occur from acute exposure.
Sulfuric Acid - Experimental poison by inhalation.
Lead - Chronic exposure can lead to irreversible vascular sclerosis, tubular cell atrophy,
interstitial fibrosis, and glomerular sclerosis. Very heavy intoxication can sometimes be
detected by formation of a dark line on the gum margins.
Sulfuric acid - Repeated or prolonged inhalation of sulfuric acid mist can cause
inflammation of the upper respiratory tract, leading to chronic bronchitis. Severe exposure
may cause chemical pneumonitis. Erosion of tooth enamel due to strong acid fume
exposure has been observed in industry. Workers exposed to low concentrations of thevapors gradually lose their sensitivity to its irritating action. Occupational exposures tostrong-acid mists containing sulfuric acid have been associated with several respiratory
tract cancers. However, there is no animal data supporting the carcinogenicity of sulfuric
acid. Sulfuric acid has been found to be non-mutagenic, and in two studies of workers
employed in lead acid battery manufacture, no association between sulfuric acid mist
exposure and respiratory tract cancers was observed.

Skin
Acute (Immediate)

Chronic (Delayed)

Sulfuric Acid - Extremely irritating, corrosive, and toxic to tissue, resulting in rapid
destruction of tissue, causing severe burns. If much skin is involved, exposure isaccompanied by shock, collapse and symptoms similar to those seen in severe burns.
Repeated contact with dilute solutions can cause dermatitis.
No Data Available

Eyes
Acute (Immediate)
Chronic (Delayed)

Causes serious eye damage.
No Data Available

Ingestion
Acute (Immediate)

Chronic (Delayed)
Reproductive Effects

Lead - Poison by ingestion in large dosages and with prolonged exposure leading to thesame effects as seen in exposure by inhalation. Adults absorb 5-15% of ingested lead andretain less than 5%. Children absorb about 50% and retain about 30%. Sulfuric Acid Moderately toxic by ingestion.
No Data Available
Lead - Severe toxicity can cause sterility, abortion, and neonatal mortality and morbidity.
Experimental teratogen. Experimental reproductive effects. Pathological lesions have beenfound on male gonads.
Sulfuric Acid - Experimental teratogen.

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EHS-SDS-1002

Carcinogenic Effects

Repeated and prolonged exposure may cause cancer.

Carcinogenic Effects
Chemical
Sulfuric acidLead
Lead as Lead
Compounds
Lead as Lead, inorganic
compounds

CAS
7664-93-9
7439-92-1
NO DATA AVAILABLENO DATA AVAILABLE

IARC
Group 1-Carcinogenic
Group 2A-Probable
Carcinogen
Not Listed
Group 2A-Probable
Carcinogen

NTP
Not Listed
Reasonably Anticipated tobe Human Carcinogen
Reasonably Anticipated tobe Human Carcinogen
Not Listed

SECTION 12- ECOLOGICAL INFORMATION
In most surface water and groundwater, lead forms compounds with anions such as hydroxides, carbonates, sulfates,and phosphates, and precipitates out of the water column. Lead may occur as sorbed ions or surface coatings on
sediment mineral particles or may be carried in colloidal particles in surface water. Most lead is strongly retained insoil, resulting in little mobility. Lead may be immobilized by ion exchange with hydrous oxides or clays or bychelation with humic or fulvic acids in the soil. Lead (dissolved phases) is bioacuumulated by plants and animals,
both aquatic and terrestrial.
1. When properly used or disposed of the battery does not present an environmental hazard.
2. Do not let internal components enter marine environment. Avoid release to waterways, wastewater orground water.
3. Toxicity - Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects
4. Persistence and degradability - Material data lacking.
5. Results of PBT and vPvB assessment PBT and vPvB assessment has not been conducted for this material.
SECTION 13- DISPOSAL CONSIDERATIONS
Lead acid batteries are completely recyclable. Return whole scrap batteries to a permitted recycler. For neutralized
spills, place residue in acid-resistant containers with sorbent material and dispose of in accordance with theapplicable regulations in country and state.
SECTION 14- TRANSPORT INFORMATION
EaglePicher Technologies Carefree® batteries are valve regulated lead acid (VRLA) batteries that have passed
vibration, pressure differential and free-flowing acid tests under CFR 49 173.159(d) and meet IATA Special
Provisions A48, A67, A164, 183, PI872 (IATA 59th Edition).
IMDG: Excepted from regulations, meets the requirements in Special Provision 238.
The batteries are securely packaged, protected from short circuits and labeled “Non-Spillable” or “Non-Spillable
Battery.”
Carefree® batteries are exempt from DOT Hazardous Material Regulations and IATA Dangerous Goods
Regulations.
NOTE: Shipper has the option of shipping the batteries Hazmat regulated under UN2800. Additional labeling andpaperwork would be required. See CFR 49 and IATA Dangerous Goods Regulations for more information.

8.

EHS-SDS-1002

If the battery is not shipped in the original packaging or no longer meets any of the referenced requirements
above, then the package must be shipped as follows:
UN number UN proper
Transport
Packing group Environmental
shipping name hazard
hazards
class(es)UN2800Batteries, Wet, Hazard Class 8 Packing Group
DOT
Non-spillable
II
UN2800Batteries,
Wet,
HazardClass
8
Packing GroupTDG
Non-spillable
II
Batteries, Wet, Hazard Class 8 Packing GroupIMO/IMDG UN2800
Non-spillable
II
Batteries, Wet, Hazard Class 8 Packing Group
IATA/ICAO UN2800
Non-spillableII

SECTION 15- REGULATORY INFORMATION
U.S. Hazardous under OSHA Hazard Communication Standard:

Lead – Yes
Arsenic – Yes
Sulfuric Acid – Yes

Ingredients Listed on TSCA Inventory:
CERCLA Section 304 Hazardous SubstanceYes
Lead – Yes
RQ: N/A
Arsenic – Yes
RQ: 1 pound
Sulfuric Acid – Yes
RQ: 1000 pounds
EPCRA Section 302 Extrrememly Hazardous Substance:
Sulfuric Acid – Yes
EPCRA Section 313 Toxic Release Inventory:
Lead – CAS NO: 7439-92-1
Arsenic – CAS NO: 7440-38-2
Sulfuric Acid – CAS NO 7664-93-9

SECTION 16- OTHER INFORMATIONThis SDS is intended to provide a summary of our knowledge and guidance regarding the use of thischemical. The information contained here has been compiled from sources considered byEaglePicher Technologies, LLC to be dependable and is accurate to the best of the Company’s
knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication
regulations. This information is offered in good faith. Each user of this material needs to evaluate
the conditions of use and design the appropriate protective mechanisms to prevent employee
exposures, property damage or release to the environment. EaglePicher Technologies, LLC
assumes no responsibility for injury to the recipient or third persons or for any damage to any
property resulting from misuse of the chemical.
Created 2/5/20189.