SAFETY DATA SHEET
500722 ETHYL VANILLIN P.G. ACETAL
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1. IDENTIFICATION
Product Description:ETHYL VANILLIN P.G. ACETAL

CAS #68527-76-4

FEMA Number3838

Other means of identification
Vigon Item #500722

Recommended use

Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.

Recommended restrictions

For Manufacturing Use OnlyCompany

24 Hour Emergency Response Information

Vigon International, Inc.

INFOTRAC (ACCT# 78928);
1-800-535-5053 WITHIN THE U.S.A.
1-352-323-3500 OUTSIDE THE U.S.A.

127 Airport Road
E. Stroudsburg, PA 18301
For information call: 570-476-6300
Web Site: www.vigon.com
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name
Address

Vigon International, Inc.
127 Airport Road
E. Stroudsburg, PA 18301
United StatesTelephone

For information call:

WebsiteE-mail

www.vigon.com
regulatory@vigon.com

Emergency phone number

INFOTRAC
1-800-535-5053
1-352-323-3500

570-476-6300(ACCT# 78928);
WITHIN THE U.S.A.
OUTSIDE THE U.S.A.

2. HAZARD(S) IDENTIFICATION
Physical hazards

Not classified.

Health hazards

Acute toxicity, oral

Environmental hazards

Not classified.

Category 4

Label elements

Signal word

Warning

Hazard statement

Harmful if swallowed.

Precautionary statement
Prevention

Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

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Response

IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

Storage

Store away from incompatible materials.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwiseclassified (HNOC)

None known.

Supplemental information

100% of the substance consists of component(s) of unknown acute dermal toxicity. 100% of thesubstance consists of component(s) of unknown acute inhalation toxicity. 100% of the substanceconsists of component(s) of unknown acute hazards to the aquatic environment. 100% of thesubstance consists of component(s) of unknown long-term hazards to the aquatic environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Chemical nameCommon name and synonyms

CAS number%

ETHYL VANILLIN PROPYLENE
GLYCOL ACETAL

Phenol,2-ethoxy-4-(4-methyl-1,3-dioxolan-2-yl)2-Ethoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol

68527-76-4100

4. FIRST-AID MEASURES
Inhalation

If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.

Skin contact

Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.

Eye contact

Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.

Ingestion

Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only if
the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.

Most important
symptoms/effects, acute anddelayed

Direct contact with eyes may cause temporary irritation.

Indication of immediate medical
attention and special treatment
neededNot available.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media

Water spray, fog, CO2, dry chemical, or alcohol resistant foam.

Unsuitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.

Specific hazards arising fromthe chemical

Fire may produce irritating, corrosive and/or toxic gases.

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Special protective equipment
and precautions for firefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection. Wear self-contained breathing apparatus with a full
facepiece operated in the positive pressure demand mode when fighting fires.

Fire fighting
equipment/instructions

In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Water runoff can cause environmental damage. Ventilate closed spaces before
entering them. Keep run-off water out of sewers and water sources. Dike for water control.

Specific methods

Use water spray to cool unopened containers.

General fire hazards

Static charges generated by emptying package in or near flammable vapor may cause flash fire.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective
equipment and emergency
procedures

Eliminate all sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
Keep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.

Methods and materials forcontainment and cleaning up

Collect and dispose of spillage as indicated in section 13 of the SDS.

Environmental precautions

Retain and dispose of contaminated wash water. Avoid release to the environment. Contact local
authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if
safe to do so. Do not contaminate water.

Never return spills in original containers for re-use. Do not allow material to contaminate groundwater system. Clean surface thoroughly to remove residual contamination.

7. HANDLING AND STORAGE
Precautions for safe handlingDo not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged
exposure. Wash thoroughly after handling.

Conditions for safe storage,including any incompatibilities

Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational exposure limits

This substance has no PEL, TLV, or other recommended exposure limit.

Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Use explosion-proof ventilation equipment to stay below exposure limits.

Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).
Eye/face protection
Skin protection
Hand protection
Other

Chemical resistant gloves.
Not available.

Respiratory protection

Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection must
be provided.

Thermal hazards

Wear appropriate thermal protective clothing, when necessary.

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General hygiene considerations

Keep away from food and drink. Always observe good personal hygiene measures, such as
washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance

Refer to Spec Sheet

Physical state

Liquid.

FormLiquid.

Color

Refer to Spec Sheet

Odor

Characteristic.

Odor threshold

Not available.

pH

Not available.

Melting point/freezing point

Not available.

Initial boiling point and boilingrange> 320 °F (> 160 °C) at 1.0 mmHg

Flash point> 200.0 °F (> 93.3 °C) Closed Cup

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits
Not available.
Flammability limit - lower(%)
Flammability limit - upper(%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

0.00002 mm Hg at 25 °C

Vapor density

7.8

Relative density

Not available.

Solubility(ies)
Solubility (water)

Insoluble

Partition coefficient(n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information
Explosive properties

Not explosive.

Flammability class

Combustible IIIB estimatedMolecular formulaC12H16O4

Molecular weight224.26 g/mol
224.26 g/mol

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500722 ETHYL VANILLIN P.G. ACETAL
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Oxidizing properties

Not oxidizing.

Specific gravity

1.16 at 25 °C

10. STABILITY AND REACTIVITY
Reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability

Material is stable under normal conditions.

Possibility of hazardous
reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials

Strong oxidizing agents.

Hazardous decomposition
products

No hazardous decomposition products if stored and handled as indicated.

11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Knowledge about health hazard is incomplete.
Inhalation
Skin contact

Knowledge about health hazard is incomplete.

Eye contact

Knowledge about health hazard is incomplete.

Ingestion

Harmful if swallowed.

Symptoms related to thephysical, chemical andtoxicological characteristics

Direct contact with eyes may cause temporary irritation.

Information on toxicological effects
Acute toxicity
ProductHarmful if swallowed.
Species

Test Results

ETHYL VANILLIN PROPYLENE GLYCOL ACETAL (CAS 68527-76-4)
Acute

OralLD50

Rat

1590 mg/kg

Skin corrosion/irritation

Due to partial or complete lack of data the classification is not possible.

Serious eye damage/eye
irritation

Due to partial or complete lack of data the classification is not possible.

Respiratory or skin sensitization
Respiratory sensitization

Due to partial or complete lack of data the classification is not possible.

Skin sensitization

Due to partial or complete lack of data the classification is not possible.

Germ cell mutagenicity

Due to partial or complete lack of data the classification is not possible.

Carcinogenicity

Due to partial or complete lack of data the classification is not possible.

IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

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US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity

Due to partial or complete lack of data the classification is not possible.

Specific target organ toxicity single exposure

Due to partial or complete lack of data the classification is not possible.

Specific target organ toxicity repeated exposure

Due to partial or complete lack of data the classification is not possible.

Aspiration hazard

Due to partial or complete lack of data the classification is not possible.

12. ECOLOGICAL INFORMATION
Ecotoxicity

The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.

Persistence and degradability

No data is available on the degradability of this substance.

Bioaccumulative potential

No data available.

Mobility in soil

No data available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. DISPOSAL CONSIDERATIONS
Disposal instructions

Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.

Local disposal regulations

Dispose in accordance with all applicable regulations.

Hazardous waste code

Not established.

Waste from residues / unused
products

Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging

Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.

14. TRANSPORT INFORMATION
ADN
Not regulated as dangerous goods.
ADR
Not regulated as dangerous goods.
RID
Not regulated as dangerous goods.
DOT
BULK
Not regulated as dangerous goods.

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DOT
NON-BULK
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.

15. REGULATORY INFORMATION
US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.

Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Classified hazard
categories

Yes
Acute toxicity (any route of exposure)

SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act(SDWA)

Not regulated.

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Issue date

11-29-2015

Revision date

06-05-2020

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HMIS® ratings

Health: 1
Flammability: 1
Physical hazard: 0

Disclaimer

Vigon International, Inc. cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safe
handling, use, processing, storage, transportation, and disposal and should not be considered as aguarantee or quality specification. This product has not been evaluated for safe use in e-cigarettes
or any vaping application where the product(s) is/are intentionally vaporized and inhaled. VigonInternational, Inc. has performed no testing on these products in e-cig/vaping applications. It is thesole responsibility of the individual(s) purchasing this product to assess its’ safety in the finalapplication. The above information relates only to this product and not to its use in combination
with any other material or any particular process and is designed only as guidance for the safe
handling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It is
the responsibility of the user to review all safety information about this product and determine its
safety and suitability in their own processes and operations. Appropriate warnings and safe
handling procedures should be provided to all handlers and users, taking into account the intended
use and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.

Revision information

This document has undergone significant changes and should be reviewed in its entirety.