NEDO-NSTDA 3rd Webinar

Introduction to Chiyoda’s
Carbon Recycling Activities

Chiyoda Corporation© Chiyoda Corporation 2023, All Rights Reserved.

Contents
1. Introduction of Chiyoda
2. Chiyoda’s Carbon Recycling Activities
A) Classification of Carbon Recycling Technologies
B) Chiyoda’s Carbon Recycling Activities (Summary)C) Post Combustion CO2 Capture for Gas Turbine (R&D)
D) Mineralization (R&D)
E) Para-xylene Synthesis (R&D)
F) Ethylene Electrochemistry Synthesis (R&D)
G) Reformer [CT-CO2AR™] using CO2 as Feedstock(Commercialized）
3. Chiyoda’s Activities in Thailand© Chiyoda Corporation 2023, All Rights Reserved.

11. Introduction of Chiyoda© Chiyoda Corporation 2023, All Rights Reserved.

2

Chiyoda’s Project Foot Prints
40%of world’s
LNG EPCProjects(by capacity)

OverRussia

Mongolia••

Yamal LNG Project

1,800

New Ulaanbaatar
International Airport

Projects
in Global
Environment
FieldsJapan•
•
•
•
•••

Xylene Isomerization UnitsCIS Photovoltaic Power Plant
CIS Photovoltaic Production Plant
Advanced injectable drugs Plant
GMP Vector Manufacturing Plant
Production Facilities of Drug
Substances for Bio-Pharmaceuticals
Facilities for Solid Preparation

USA••••

Cameron LNG Liquefaction Project(Train 1,2,3)Freeport LNG Export LNG Project(Train 1,2,3)Golden Pass LNG Project (Train 1,2,3)
GCGV OlefinsVietnam•Qatar••OverSaudi Arabia

800

•
•

Refinery Units
ConstructedCoker Unit for Jubail Refinery Project
Titanium Sponge Plant

Laffan Refinery Phase 2
North Field East LNG(Ongoing)

Indonesia••

Nghi Son Refinery andPetrochemical Complex

Philippines•New Bohol AirportOver

Tangguh LNG Expansion Project(Train 3) (Ongoing)
Copper Smelting Project (Ongoing)

Australia•

Ichthys Onshore LNG Facilites Project(Train 1, 2)© Chiyoda Corporation 2023, All Rights Reserved.

600
Petrochemicals
Chemicals
PlantsConstructed3

Current Business Portfolio
Gas Value Chain

Petroleum Refineries

Petrochemicals & Chemicals• Gas Processing (Onshore/Offshore)• LNG (Onshore/Offshore)− Liquefaction− Regasification− FLNG/Platform & Nearshore LNG− FLNG Power Generation• Clean Fuel
• Chemical Refinery Integration• Heavy Oil Upgrading•••••

CO2 Capture

Olefins
Aromatics
Synthesis Gas/Fertilizer
MethanolSpecialty Chemicals- Cryogenic Liquefaction- LNG Receiving & Cold
Energy Utilization- CO2 Capture

Green Energy

Cryogenic
Liquefaction• Solar Energy•• Wind Power•• Biomass Power•
Generation• Energy Storage/Energy Management
Systems (EMS)• Green Hydrogen• Hydrogen Value Chain

Environment
Flue Gas Desulfurization •Energy Conservation•
CO2 Capture, Storage andUtilization•- CO2 Capture- CO2 Liquefaction/Tank- CO2 Storage- CO2 Utilization

Pharmaceuticals
Pharmaceuticals
Tissue Engineering(iPS cell)
Laboratories

Metals & Mining

General Industry• Metallurgical
Refining andSmelting• Electronic Materials• Food Processing• Vegetable Factory

Chemical Synthesis Tech. (For CCU)
Catalyst (For SPERATM)© Chiyoda Corporation 2023, All Rights Reserved.

4

2. Chiyoda’s Carbon Recycling Activities© Chiyoda Corporation 2023, All Rights Reserved.

5

Classification of Carbon Recycling Technologies
2. Chemical products

EOR

1.Capture

Utilization

Direct utilizationof CO2（dry ice, welding, drinks etc）

StorageCarbonRecycling Oxygenated compounds（Polycarbonate, urethane etc）
 Biomass-derived chemicals
 Commodity chemicals（olefins, BTX etc.）

3. Fuels• Microalgae biofuels (jet fuel/diesel)• CO2 derived fuels or biofuels(Methanol, ethanol, diesel, etc.)• Gas fuels（methane）

4. Minerals

AGR for natural gas
pre/post combustion CO2 capture
DAC for space station

Syngas (H2+CO),
H2,Renewable Energy

 carbonate
 Concrete products・concrete structures etc.

As Above

FGD
gas/liquid contactor,slurry/material handling

Others Negative emission technologies【Records & Base Technology】• CO2 Capture• Syngas, Hydrogen• Renewable Energy• FGD (Chiyoda Technology)【Synergy with Carbon Recycling】• Chemical products & fuels havesynergy with syngas, H2 andrenewable energy• Minerals has synergy with FGD

Made by Chiyoda based on “Roadmap for Carbon Recycling Technology” by Ministry of Economy, Trade and Industry
AGR：Acid Gas Removal, DAC：Direct Air Capture,
FGD : Flue Gas Desulphurization, EOR : Enhanced Oil Recovery

Chiyoda Corporation 2023, All Rights Reserved.

6

Chiyoda’s Carbon Recycling Activities (Summary)

Chiyoda’s Carbon Capture and Utilization (CCU) business from CO2 capture to utilization.
Chiyoda is aiming to establish a Carbon Recycle Supply Chain in the near future.

CO2 Capture Large-scale CO2 separation and recovery from gas-fired power
generation exhaust gas••

R&D stage in NEDO’s Green Innovation Fund project (FY2022ー2030)
Partnership with JERA Co. Inc., RITE (The Research Institute of
Innovative Technology for the Earth)
R&DExhaustGas

Natural Gas Turbine

Para-xylene（Polyester clothes/plastic bottles）
 Para-xylene production from CO2 and H2•••Solid sorbent
CO2CO2 Separation andRecovery process

Chemicals,
Fuel, etc.

Para-xylene is essential to manufacture polyester clothes anddrink bottles
R&D stage in NEDO project (July 2020 – March 2024)
Partnership with University ofToyama, Nippon SteelEngineering Co., Ltd., Nippon
Steel Corporation, HighChem
Company Ltd. and Mitsubishi
Corporation

CO2 Utilization process(Under Consideration

https://www.chiyodacorp.com/media/200714_e.pdf

https://www.chiyodacorp.com/media/220513_e.pdf

Carbonate（Concrete）

NEDO project scope

Ethylene Ethylene production from CO2 + H2O by Integrated
Electrochemical Systems.

Waste
concrete

Capture/Fix
CO2by Calcium•••

Recycledaggregate

Aggregate

Reaction under ambient pressure/temperature
Ethylene can be made into chemical products such as e-fuel.
R&D stage in NEDO Moonshot Research & Development
Program (July 2020 – March 2030)

 Technology by Blue Planet (a start-up company in the USA).
 Chiyoda has entered into an MOU with Blue Planet and Mitsubishi
Corporation.
 Chiyoda participates in a demonstration project in the USA,providing technical support and accelerating commercialization.
https://www.chiyodacorp.com/media/210205_e.pdf
NEDO: the New Energy and Industrial Technology Development Organization
Blue Planet: Blue Planet Systems Corporation
MOU: Memorandum Of Understanding

https://www.chiyodacorp.com/media/200909_e.pdf

7
Chiyoda Corporation 2023, All Rights Reserved.

Post Combustion CO2 Capture for Gas Turbine (R&D)
 Solid sorbent material for low cost CO2 separation and recovery from gas turbines.
 Bench tests and demonstrations to establish low cost processes and lead to early socialimplementation.
 Funded by NEDO (Green Innovation Fund project).
Organization

Project Scale

Chiyoda Corporation, JERA Co. Inc.,The Research Institute of Innovative Technology for theEarth (RITE)□ Project scale ：Approximately 10.1 billion yen□ Support scale*：Approximately 8.7 billion yen* Including incentives. This is subject to change

Project Perioddepending on the project progress.

Fiscal year 2022～2030 (Nine years)

Scope
Solid sorbent2022

2024□ Subsidy rate ：Consignment → 2／3 grant(Incentive 10%)ProcessPilot test

2030

2026
Stage gate 1

Stage gate 2

Solid Sorbent
Development- Solid sorbent
development- Laboratory test

Bench Test
- Performance confirmation- Engineering dataacquisition
Demonstration
Overall system study and longterm operation demonstration

Press Release: https://www.chiyodacorp.com/media/220513_e.pdf© Chiyoda Corporation 2023, All Rights Reserved.

8

Mineralization (R&D)


CO2 is sequestrated as the mineral, CaCO3.
MOU signed with Blue Planet Systems Corporation (a start up company that owns technologyin the USA) and Mitsubishi Corporation
Joint demonstration is ongoing in the USA

Press Release: https://www.chiyodacorp.com/media/210205_e.pdf
SiO2: Silicon Dioxide, CaCO3: Calcium Carbonate, CaO: Calcium Oxide© Chiyoda Corporation 2023, All Rights Reserved.

9

Para-xylene Synthesis (R&D)


Para-xylene synthesis from CO2 and H2 (e-PX) to substitute existing fossil fuel-derived chemicals.
This R&D project is fully funded by NEDO. (Duration: July 2020 to March 2024).
Partnershipwith University of Toyama, Nippon Steel Engineering Co., Ltd., Nippon Steel Corporation,HighChem Company Ltd. and Mitsubishi Corporation
Started pilot plant operation from March 2022.

ConventionalMethodOngoing
R&D
NEDO project scope

Press Release: https://www.chiyodacorp.com/media/200714_e.pdf
e-PX: Para-Xylene from CO2 and H2

PTA: Pure Terephthalic Acid
PET: Poly Ethylene Terephthalate© Chiyoda Corporation 2023, All Rights Reserved.

10Ethylene Electrochemistry Synthesis (R&D)


Ethylene production from CO2 + H2O by Integrated Electrochemical Systems.
Funded by NEDO Moonshot Research & Development Program
Duration: Maximum 10 years from August 2020

UBE Corporation

Press Release: https://www.chiyodacorp.com/media/200909_e.pdf
URL (Project) : https://www.innovation-riken.jp/moonshotPJ00_en/© Chiyoda Corporation 2023, All Rights Reserved.

11

Reformer [CT-CO2AR™] using CO2 as Feedstock (Commercialized）


Chiyoda has commercialized a reforming catalyst using less H2O and CO2 as feedstock
Synthesis gas with wide range of H2/CO ratio can be produced.
This Chiyoda technology is currently being used by a chemical company in Japan.

CO+H2

Total Energy Input

87

CAPEX

89

OPEX

92
76

CO2 Emission(*)(*) Calculate CO2 emission
per final product (oxo-alcohol)

By adjusting CH4/H2O and CH4/CO2 ratios in the reformer feed,
synthesis gas with a wide range of H2/CO ratios canbe produced.
Example: H2/CO=1.0 for chemicals (ex. oxo-alcohol)
H2/CO<1.0 for carbon monoxide(ex. as a feedstock of acetic acid)

0

20
40
Relative Value [-]

60

80100

(Conventional : 100)

When the H2/CO ratio =1.0
(for oxo-alcohol production),
CO2 emissions are reduced by 24%.

https://www.chiyodacorp.com/en/service/gtl/co2-reforming/
https://www.youtube.com/watch?v=f6TtfF_vm-E© Chiyoda Corporation 2023, All Rights Reserved.

12

3. Chiyoda’s Activities in Thailand© Chiyoda Corporation 2023, All Rights Reserved.

13

Chiyoda’s activities in Thailand
MOU for development of CCUS technologies at Coal-Fired Power Plant
 Location: Rayong, Thailand Collaboration among BLCP
Power Limited, Mitsubishi
Corporation and Chiyoda
 Plan to conduct Feasibility
Study for lowering carbon
emissions at BLPC’s coal-fired
power plant, particularly indeveloping technologies that
produce carbon-dioxide-derived
chemical and fuels.

MOU signing ceremony at the 5th JTEPD

Press Release: https://www.chiyodacorp.com/media/230120_e.pdf© Chiyoda Corporation 2023, All Rights Reserved.

14

Chiyoda’s activities in Thailand
MOU for the development of Clean Hydrogen/ Ammonia Value Chain
 Location: Southern provincesof Thailand Collaboration among EGAT,
Mitsui O.S.K Lines, Mitsubishi
Thailand Limited and Chiyoda
 Plan to conduct Feasibility
Study for the value chain ofclean hydrogen/ ammonia
including the production,
storage, transportation andutilization.

Photo at AZEC Ministerial Meeting

Press Release: https://www.chiyodacorp.com/media/230306_e.pdf© Chiyoda Corporation 2023, All Rights Reserved.

15

Chiyoda’s activities in Thailand
Links (Videos) for more detail about CCUS and Hydrogen
Chiyoda's solution
https://www.chiyodacorp.com/en/service/
CO2 Utilization Catalyst for the Sustainable Future: CT-CO2AR
https://www.youtube.com/watch?v=f6TtfF_vm-E
Chiyoda’s Way for Future LNG
https://www.youtube.com/watch?v=GzgGRIHmtfA
SPERA Hydrogen PV_202006
https://www.youtube.com/watch?v=4umkve6kAAk

For more information, please contact us through CHIYODA CORPORATION (our website)
 gx-asia-bd@chiyodacorp.com (E-mail address)© Chiyoda Corporation 2023, All Rights Reserved.

16

Thank you© Chiyoda Corporation 2023, All Rights Reserved.

17