B.B. TECH(CHANGSHA) CO., LTD.
MATERIAL SAFETY DATA SHEET
Valve Regulated Lead-Acid Rechargeable battery
Date:23.Apr.2020
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product name: Valve Regulated Lead-Acid Rechargeable battery
Company: B.B. TECH(CHANGSHA) CO., LTD.
Address: No.57 DongsiRoad, Changsha National Economic & Technical Development Zone,Changsha, Hunan PRC
E-mail: maggy@bb-battery.com
Tel: +86-731-82955888
Fax: +86-731-82955111
US Office: B&B Battery USA, Inc.
Address: 6415 Randolph Street, Commerce, CA 90040
Tel: 323-278-1900
Fax: 323-278-1268

SECTION 2: INFORMATION ON INGREDIENTS
Product name: Valve Regulated Lead-Acid Rechargeable battery
Ingredient

CAS No.

Concentration

Hazardous Label

Inorganic Lead/Lead Compounds

7439-92-1

~ 72%

T

Sulfuric Acid7664-93-9

~ 20%

C

Fiberglass Separator

65997-17-3~ 2%/9003-56-9 (ABS)
Container Plastic (ABS or PP)/~ 5%9003-07-0 (PP)/Composition comments: All concentrations are in percent by weight unless ingredient is a gas.
Gas concentrations are in percent by volume.

SECTION 3: HAZARDS IDENTIFICATION
Hazards Identification: The battery has passed the vibration test, pressure differential test andleakage test at 55℃ according to Recommendations on the TRANSPORT OF DANGEROUS
GOODS Model Regulation 20th SPECIAL PROVISION 238. It is not restricted to IATA Dangerous
Goods Regulation (DGR) 61th according to special provision A67 and is not restricted to IMDG
CODE according to special provision 238.
Emergency Overview: The internal battery materials may cause severe irritation to eyes and skin.
Causes burns.

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SECTION 4: FIRST-AID MEASURESSkin Exposure: If the internal battery materials of an opened battery cell come into contact with the skin,
immediately flush with plenty of water for at least 15 minutes. Seek immediate medical attention.
Eye Exposure: In case of contact the electrolyte contained inside the battery with eyes, flush withcopious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids
with fingers. Seek immediate medical attention.
Inhalation Exposure: If potential for exposure to mist or dusts occurs, remove immediately to fresh airand seek medical attention.
Oral Exposure: If swallowed, do not induce vomiting. Seek immediate medical attention.
Most important symptoms/effects, acute and delayed: Under normal conditions of processing anduse, exposure to the chemical constituents in this product is unlikely. The battery should not beopened or burned. Exposure to the ingredients contained within or their combustion products could beharmful.
Indication of immediate medical attention and special treatment needed: Treat symptomatically.
General information: Ensure that medical personnel are aware of the material(s) involved, and takeprecautions to protect themselves.

SECTION 5: FIRE FIGHTING MEASURESExtinguishing Media: Suitable: Dry chemical, Sandy soil, Carbon dioxide or appropriate foam.
Unsuitable extinguishing media: In the event that a battery is ruptured and the internal components are
exposed, DO NOT USE WATER. Do not use carbon dioxide directly on cells.
Specific hazards arising from the chemical: Batteries evolve flammable hydrogen gas during
charging and may increase fire risk. Containers may explode when heated.
Firefighting:Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent
contact with skin and eyes.
Specific hazards: Emit toxic fumes under fire conditions.
General fire hazards: Like any sealed container, battery cells may rupture when exposed to excessive
heat; this could result in the release of corrosive and flammable materials.

SECTION 6: ACCIDENTAL RELEASE MEASURES
If batteries show signs of leaking, avoid skin or eyes contact with the material leaking form the battery.
Use chemical resistant rubber gloves and non-flammable absorbent materials for clean up. Mix with inert
material (e.g. dry sand, vermiculite) and transfer to sealed container for disposal.

SECTION 7: HANDLING AND STORAGE
Handling:
Keep away from ignition sources, heat and flame. Such batteries must be packed in inner packages insuch a manner as to effectively prevent short circuits and to prevent movement which could lead toshort circuits. Avoid mechanical or electrical abuse and overcharge. More than a momentary shortcircuit will generally reduce the battery service life. Avoid reversing battery polarity within the battery
assembly.
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In case of a battery unintentionally be crushed, acid resistant gloves must be used to handle all battery
components. Avoid contact with eyes, skin. Avoid inhalation. No smoking at working site. Materials toAvoid: Strong oxidant, Combustible materials and Corrosives
Storage:
Store in a cool; well-ventilated area. Keep away form ignition sources, heat and flame. Such batteries
must be packed in inner packages in such a manner as to effectively prevent short circuits and toprevent movement which could lead to short circuits. Materials to Avoid: Strong oxidant, Combustible
materials and Corrosives.

SECTION 8: EXPOSURE CONTROL/PPE
Occupational exposure limits:
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053).
Components
TypeValue
Lead and lead compounds
TWA
0.05 mg/m(CAS 7439-92-1)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Sulphuric acid (CAS 7664-93-9)
US. ACGIH Threshold Limit Values
Components

PEL

1 mg/m

TypeValue

33FormLead and lead compounds
TWA(CAS 7439-92-1)
Sulphuric acid
TWA
(CAS7664-93-9)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type0.05 mg/m

Lead and lead compounds(CAS 7439-92-1)
Sulphuric acid(CAS 7664-93-9)

TWA

0.05 mg/m

TWA

1 mg/m

0.2 mg/m

33

Thoracic fraction.

Value
33

Biological limit values: No biological exposure limits noted for the ingredient(s).
ACGIH Biological Exposure IndicesComponents
Value
DeterminantSpecimen
Sampling Time
Lead and lead compounds 200 µg/I
LeadBlood(CAS 7439-92-1)* - For sampling details, please see the source document.

*Engineering Controls: Use ventilation equipment if available. Safety shower and eye bath.
Personal Protective Equipment:
Respiratory: Wear government approved air-purifying respirator if needed.
Eye: Wear safety glasses with side shields (or goggles).
Clothing: Wear appropriate protective clothing.
Hand: Wear chemical resistant gloves
Thermal hazards: When material is heated, wear gloves to protect against thermal burns.
Other Protect: No smoking, drinking and eating at working site. Wash thoroughly after handing. Wearsuitable protective clothing. Use of an impervious apron is recommended.

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SECTION 9: PHYSICAL/CHEMICAL PROPERTIES
Appearance
Physical stateFormColor
OdorOdor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas):
Upper/lower flammability or explosive limits
Flammability limit – lower(%)
Flammability limit - upper(%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity Not available.
Other information:
Explosive properties
Oxidizing properties

Solid.
Sulfuric acid, gelatinous. Lead, solid.
Not available.
Odorless.
Not available.
<1Not available.
235 - 240 °F (112.78 - 115.56 °C) (Sulfuric acid)
Below room temperature (as hydrogen gas).
< 1 (n-BuAc=1)

4 % (Hydrogen)
74 % (Hydrogen)
10 mm Hg
> 1 ( Air=1)
1.27 - 1.33
100 % (Sulfuric acid)Not available.
Not available.
Not available.

Not explosive.
Not oxidizing

SECTION 10: STABILITY AND REACTIVITY
Stability: Stable under normal temperatures and pressures.
Incompatible materials: Strong bases. Combustible organic materials. Reducing agents. Finely dividedmetals. Strong oxidizers. Water.
Conditions to Avoid: Avoid exposure to heat and open flame, Avoid mechanical or electrical abuse andovercharge. Prevent short circuits. Prevent movement which could lead to short circuits.
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: Sulfur dioxide. Sulfur trioxide. Carbon monoxide. Sulfuric acid.
Hydrogen

SECTION 11: Toxicological information
Information on likely routes of exposure:
Inhalation
Exposure to contents of an open or damaged battery: Harmful if inhaled.
Skin contact Exposure to contents of an open or damaged battery: Causes severe skin burns.
Eye contact
Exposure to contents of an open or damaged battery: Causes serious eye damage.
Ingestion
Exposure to contents of an open or damaged battery: Harmful if swallowed.

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Symptoms Related to the physical,
chemical and toxicological characteristics

Exposure to contents of an open or damaged battery:
Dust may irritate the eyes and the respiratory system.

Information on toxicological effects:
Acute toxicity Exposure to contents of an open or damaged battery: Harmful if inhaled or swallowed.
Components
Species
Test Results
Sulphuric acid (CAS 7664-93-9):
AcuteOral
LD50
Rat
2140 mg/kg
Skin corrosion/irritationExposure to contents of an open or damaged battery:Causes severe skin burns
Serious eye damage/eye
Exposure to contents of an open or damaged battery:
irritation
Causes serious eye damage.
Respiratory or skin sensitization:
Respiratory sensitization
No data available.
Skin sensitization
No data available.
Germ cell mutagenicity
No data available.
Carcinogenicity

The International Agency for Research on Cancer (IARC) has
classified "strong inorganic acid mists containing sulfuric acid"as a known human carcinogen, (IARC category 1). This
classification applies only to mists containing sulfuric acid andnot to sulfuric acid or sulfuric acid solutions.
IARC Monographs. Overall Evaluation of Carcinogenicity
Lead and lead compounds (CAS 7439-92-1)
2B Possibly carcinogenic to humans.
Sulphuric acid (CAS 7664-93-9)
1 Carcinogenic to humans.
NTP Report on Carcinogens
Lead and lead compounds (CAS 7439-92-1)
Reasonably Anticipated to be a Human
Carcinogen. Sulphuric acid (CAS 7664-93-9)
Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not regulated.

Reproductive toxicity:

Specific target organ
toxicity – repeatedexposure:None under normal conditions. Exposure to contents of an open
or damaged battery: May damage fertility or the unborn child.
None under normal conditions. Exposure to contents of toxicity-single
an open or damaged battery: Causes damage to organs exposure(respiratory system).
None under normal conditions. Exposure to contents of an open ordamaged battery: Causes damage to organs through prolonged
or repeated exposure: Respiratory system.

Aspiration hazard

Due to the physical form of the product it is not an aspiration hazard.

chronic effects:

Exposure to contents of an open or damaged battery: Heavy lead
exposure may result in central nervous system damage,encephalopathy and damage to the blood-forming (hematopoietic)
tissues. Chronic inhalation of sulfuric acid mist may increase the risk oflung cancer.

Specific target organ
toxicity-single exposure:5

SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity:

Components

The product is not classified as environmentally hazardous. However, thisdoes not exclude the possibility that large or frequent spills can have a harmful
or damaging effect on the environment. Exposure to contents of an open ordamaged battery: Very toxic to aquatic life with long lasting effects.
Species

Test Results

Lead and lead compounds (CAS 7439-92-1)
LC50
Rainbow trout, donaldson trout
1.17 mg/l, 96 Hours(Oncorhynhus mykiss)
Persistence and degradability: The degradation half-life of the product is not known. Lead andits compounds are highly persistent in water.
Bioaccumulative potential:
Bioaccumulation of lead occurs in aquatic and terrestrial animals
and plants, but very little bioaccumulation occurs through the foodchain.
Mobility in soil:
If the product enters soil, one or more constituents will or may
be mobile and may contaminate groundwater.
Mobility in general:
The product is insoluble in water and will spread on water surfaces
Other adverse effects:
None known.

SECTION 13: DISPOSAL CONSIDERATIONSAppropriate Method of Disposal of substance:
Lead-acid batteries are completely recyclable. Return whole scrap batteries to distributor, manufacturer
or lead smelter for recycling. For neutralized spills, place residue in acid-resistant containers withsorbent material, sand or earth and dispose of in accordance with local, state and federal regulations
for acid and lead compounds. Contact local and/or state environmental officials regarding disposal
information.

SECTION 14: TRANSPORT INFORMATION

We hereby certify that all B.B. Valve Regulated Lead-acid Rechargeable batteries conform to theUN2800 classification as “ Batteries, wet, Non-Spillable, and electric storage” as a result of passing theVibration and Pressure Differential Test described in D.O.T., 49 CFR 173.159(f), and IMO/IMDG, andICAO/IATA packing instruction 872 and note A48, A67, A164 and A183. The batteries are not restricted
to IMO/IMDG code according to special provision 238.
B.B. Batteries having met the related conditions are EXEMPT from hazardous goods regulations for thepurpose of transportation by DOT, and IATA/ICAO, and therefore are unrestricted for transportation by
any means, including air transport. For all modes of transportation, each battery outer package is labeled"NON-SPILLABLE". All our Batteries are marked non-spillable.

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SECTION 15: REGULATORY INFORMATION
EU Regulation:
In accordance with EU2013/56/EU Battery Directive, VRLA batteries should present crossed-out
wheeled bin symbol of lead together with the ISO recycling symbol. Does not contain any mercury(Hg<0.0005%) or cadmium (Cd<0.002%).

SECTION 16: OTHER INFORMATION
Products such as Batteries are not in the scope of regulation which requires the publication of an EU
Safety Data Sheet (91/155/EEC).

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