ProgramNovember 12 (Mon)
Room A

16:00-16:30 Opening Ceremony
Chair: Michinori Suginome						Opening Remarks/Addresses
16:30-16:45 IKCOC Prize Ceremony			Prize Winner: Klaus Müllen
Presenter: Zen-ichi Yoshida			
16:45-17:45 OL									Opening Lecture (IKCOC Prize Lecture)
Klaus Müllen
Carbon Nanostructures by Design – the Future is not Black
Chair: Koichi Komatsu

18:00-20:00		
Reception (Rooms B and C)

November 13 (Tue)Room A

9:00-10:00		 PL-1 David Milstein			
Design and Applications of Environmentally Benign Catalytic Reactions
Chair: Michinori Suginome						–Coffee Break–

10:30-11:10 IL-01 Tomislav Rovis			
Controlling Catalysis with Visible Light
Chair: Joost NH Reek			
11:10-11:50 IL-02 Benjamin List
Very Strong and Confined Acids Enable a General Approach to Asymmetric			
Lewis Acid Catalysis
Chair: Satoshi Minakata			
11:50-12:30 IL-03 Helma Wennemers			
Asymmetric Catalysis with Peptides and More
Chair: Yasuhiro Uozumi						–Lunch–6

14:00-14:40 IL-04 Michael M. Haley			Synthesis and Optoelectronic Properties of Quinoidal Electron-Accepting			Organic Semiconductors
Chair: Takashi Kubo			
14:40-15:20 IL-05 Ben Zhong Tang			Polymer Synthesis for AIE-Active Materials
Chair: Shigehiro Yamaguchi			
15:20-16:00 IL-06 Michal Hocek
Enzymatic Synthesis of Base-Modified Nucleic Acids for Diagnostics and			Chemical Biology
Chair: Hiroshi Sugiyama			
16:00-16:40 IL-07 Geert-Jan Boons
Complex Glycans in Health and Disease
Chair: Yukari Fujimoto			

Room B

Chair: Kenji Matsuda			
10:30-10:45 OP-01 Sachie Arae, Shota Beppu, Takahiro Kawatsu, Kazunobu Igawa,			Katsuhiko Tomooka, Ryo Irie
Catalytic Enantioselective Hydroarylation of Alkynes for Asymmetric			Synthesis of Axially Chiral Benzo[a]carbazoles
10:45-11:00 OP-02 Qiang Chen, Klaus Müllen, Akimitsu Narita			Synthesis of Dibenzo[hi,st]ovalene as Highly Luminescent Nanographene			with Zigzag Edges
11:00-11:15 OP-03 Koichi Mitsudo, Keisuke Shigemori, Seiji Suga			Synthesis and Properties of Dithieno-fused 1,4-Azaborines
11:15-11:30 OP-04 Aiko Fukazawa, Yusuke Toda, Masahiro Hayakawa, Anna Sekioka,			
Hiroyuki Ishii, Toshihiro Okamoto, Jun Takeya, Yuh Hijikata,			Shigehiro Yamaguchi
End-Capping π-Conjugated Systems with Medium-Sized Sulfur-Containing			Rings towards Solution-Processable Air-Stable Semiconductors
Chair: Akihiro Orita			11:30-11:45 OP-05 Yosuke Tani, Takuji Ogawa
A Rigid π-system That Shows Enhanced Emission in the Solid-state;			
Versatile Synthesis and Photoluminescence of Ester-bridged Stilbenes
11:45-12:00 OP-06 Yasunori Minami, Yuta Noguchi, Tamejiro Hiyama
Facile Synthesis of Benzosiloles: Palladium-catalyzed C–H bond Activation			and Intramolecular anti-Hydroarylation

7

12:00-12:15 OP-07 Takumi Nakazato, Yasutaka Nakamura, Takuto Kamatsuka,			
Junichi Inoue, Tsuneaki Sakurai, Shu Seki, Hiroshi Shinokubo,			Yoshihiro Miyake			
Reductive Aromatization of Arylene Diimides to 2,7-Diazapyrenes and			2,9-Diazaperopyrenes
12:15-12:30 OP-08 Daniel T. Payne, Whitney A. Webre, Wipakorn Jevasuwan,			Yoshitaka Matsushita, Niangyon Zhu, Zdenek Futera, Naoki Fukata,			Jan Labuta, John S. Fossey, Francis D’Souza, Katsuhiko Ariga,			Wolfgang Schmitt, Jonathan P. Hill
Oxidation-Induced Isomerisation and Hemiquinhydrone Complex			
Formation of Anti-Oxidant-Substituted Resorcinarenes			–Lunch–

Chair: Tetsuro Shinada			
14:00-14:15 OP-09 Marcus Baumann, Ian R. Baxendale			Large Scale Continuous Flow Synthesis of Drug-Like Building Blocks
14:15-14:30 OP-10 Jun Shimokawa, Kazuya Douki, Masato Kitamura			
Short Synthesis of Phalarine Core Structure
14:30-14:45 OP-11 Masaru Enomoto, Kazuki Kurasawa, Eunsang Kwon,			Shigefumi Kuwahara
Bioinspired Total Synthesis of Delitschiapyrone A
14:45-15:00 OP-12 Chihiro Tsukano, Takayoshi Heike, Kazuya Nishibayashi			Tagwa A. Mohammed, Yoshiji Takemoto
Total Synthesis of (±)-Shagene B
15:00-15:15 OP-13 Masahiro Uwamori, Ryunosuke Osada, Ryoji Sugiyama,			Masahisa Nakada
First Enantioselective Total Synthesis of Cotylenin A
Chair: Artur M. S. Silva			
15:15-15:30 OP-14 Kyalo Stephen Kanyiva, Daisuke Hamada, Sohei Makino,			Hideaki Takano, Takanori Shibata			Silver-Catalyzed Decarboxylative Synthesis of Oxindoles, Pyrroloindolines
and Coumarins From α-Amino Acid Precursors
15:30-15:45 OP-15 Tetsuaki Fujihara, Ayumi Sawada, Tatsuya Yamaguchi, Yasushi Tsuji
Copper-Catalyzed Borylative and Silylative Transformation of Allenes
15:45-16:00 OP-16 Yu Shibata, Ken Tanaka
Effects of Functionalized Cp Ligands for Rhodium-Catalyzed C–H Bond			
Functionalizations
16:00-16:15 OP-17 Itaru Nakamura, Yasuhiro Ishida, Masahiro Terada
Copper-Catalyzed Domino [1,3]/[1,2] Rearrangement for the Efficient			Synthesis of Multisubstituted ortho-Anisidines
16:15-16:30 OP-18 Joost NH Reek			
Supramolecular substrate orientation to control selectivity in transition			
metal catalysis
816:40-18:40
Poster Session 1 (Room C and Room D)				
PA(C)-01–PA(C)-85 (Room C)				
PA(D)-01–PA(D)-46 (Room D)
November 14 (Wed)Room A

9:00-9:40		 IL-08 Martin D. Burke			
Democratizing Synthesis
Chair: Tohru Oishi			
9:40-10:20		 IL-09 Nobuyoshi Yasuda
The Art of Process Chemistry
Chair: Katsuhiko Tomooka			
10:20-11:00 IL-10 Chihaya Adachi			Exciton management in OLEDs and future organic laser diodes
Chair: Peter Bäuerle						–Coffee Break–Room B
Chair: Hiroshi Shinokubo			
9:00-9:15		 OP-19 Hayato Tsuji, Ouyang Chun, Kohei Hashimoto, Eiichi Nakamura,			Yutaka Majima
Long-range Coherent Resonant Tunneling through Rigid Planar Carbonbridged Oligo(phenylenevinylene)
9:15-9:30		 OP-20 Kazukuni Tahara, Toru Ishikawa, Yuki Kubo, Brandon E. Hirsch,			Steven De Feyter, Yoshito Tobe
Self-Assembled Monolayers as Templates for Nanopatterned Chemical
Functionalization of Graphitic Surfaces
9:30-9:45		 OP-21 Sara Kusumoto, Sadegh Mahvidi, Sakiko Takeuchi,			Tetsuya Nakagawa, Yasushi Yokoyama			
All-Optical Switching in the Photochromic Behavior of Diarylethenes
9:45-10:00		 OP-22 Takashi Hirose, Yusuke Nakakuki, Kenji Matsuda
Development of the Basic Structures of Helically Twisted Polycyclic
Aromatic Hydrocarbons
10:00-10:15 OP-23 Koji Miki, Kenzo Saiki, Tomokazu Umeyama, Jinseok Baek,			Takeru Noda, Hiroshi Imahori, Yuta Sato, Kazu Suenaga,			Kouichi Ohe
Tube-Ring Interaction: Complexation of Single-Walled Carbon Nanotubes			with [n]Cycloparaphenyleneacetylenes

9Chair: Ming-Chang Yeh
10:15-10:30 OP-24 Anastasios Polyzos
Light Driven Palladium Catalysis: Enabling Directed
C(sp3)-H Functionalisation
10:30-10:45 OP-25 Mamoru Tobisu
Nickel-Mediated Decarbonylation and Decarboxylation of Simple
Carbonyl Compounds
10:45-11:00 OP-26 Yusuke Makida, Yuki Nakayama, Masahiro Saita, Ryoichi Kuwano
Switchable Chemoselectivity in Asymmetric Hydrogenation of Azaindoles–Coffee Break–
11:30-13:30

Poster Session 2 (Room C and Room D)
PB(C)-01–PB(C)-84 (Room C)
PB(D)-01–PB(D)-46 (Room D)–Lunch–14:00-			–Excursion–

November 15 (Thu)
Room A

9:00-10:00		 PL-2 Michael Grätzel
Molecular Photovoltaics and Perovskite Solar Cells
Chair: Yoshito Tobe
–Coffee Break–
10:30-11:10 IL-11 Qi-Lin Zhou
Privileged Chiral Spiro Catalysts
Chair: Sensuke Ogoshi
11:10-11:50 IL-12 Michael J. Krische
Hydrogen-Mediated C-C Bond Formation
Chair: Kouichi Ohe
11:50-12:30 IL-13 Cathleen M. Crudden
Advances in the Suzuki-Miyaura Cross-Coupling
Chair: Seijiro Matsubara–Lunch–1013:40-14:20 IL-14 Peter R. Schreiner
Understanding London Dispersion Effects in Molecular Materials
Chair: Masahiro Murakami
14:20-15:00 IL-15 Craig Hawker
The Power of Organic Chemistry in Functional Polymer Synthesis
Chair: Kohtaro Osakada–Coffee Break–
Chair: Shigeru Yamago
15:30-15:45 OP-40 Norbert Krause
Water as Reaction Medium for Sustainable Gold Catalysis
15:45-16:00 OP-41 Masahiro Terada, Yusuke Ota, Azusa Kondoh
Enantioselective Intramolecular Nicholas Reaction Catalyzed by Chiral
Phosphoric Acid: Enantio-convergent Synthesis of Seven-membered Cyclic
Ethers from Racemic Diols
16:00-16:15 OP-42 Kazuaki Ishihara
Rational Design of High-Performance Catalysts Based on Acid–BaseCombination Chemistry
16:15-16:30 OP-43 E. Mena-Osteritz, P. Bäuerle
Synthetic approaches towards 2D- and 3D-thiophene-based nanomaterials
16:30-16:45 OP-44 Toshio Nishikawa, Misaki Niki, Yushi Hirata, Atsuo Nakazaki,Hirokazu Kawagishi
Collective Synthesis of Chaxines, Novel Steroidal Natural Products Isolated
from Chinese Edible MushroomRoom B

Chair: Kiyosei Takasu
10:30-10:45 OP-27 Yen-Cheng Lin, Yi-Ting Lai, Wen-Wei Chang, Li-Ching Lin,
Chih-Chien Chu
Targeted photoresponsive carbazole-coumarin nanoconjugates for efficient
combination therapy in Leukemia cancer cells
10:45-11:00 OP-28 Ambara R. Pradipta, Katsunori Tanaka
Synthetic Chemistry for Clinical Trials: Azide-Acrolein Click Reaction for
Intraoperative Diagnosis of Breast Cancer Patients
11:00-11:15 OP-29 Kenzo Yamatsugu, Shigehiro A. Kawashima, Motomu Kanai
Synthetic Histone Acylation with Chemical Catalysts
11:15-11:30 OP-30 Ralf Schwörer, Darshita Budhadev, Martin A. Fascione,
Peter C. Tyler
Automated Synthesis of Heparan Sulfates: Potential Alzheimer’sTherapeutics

11Chair: Hidetoshi Tokuyama
11:30-11:45 OP-31 Yoshiyuki Manabe, Masahiro Nagasaki, Hiroki Shomura,Naoya Minamoto, Soichiro Okamura, Shuto Miyake, Kanae Hatano,Kazuya Kabayama, Koichi Fukase
Syntheses of complex type N-glycans and live cell imaging of their protein
conjugates
11:45-12:00 OP-32 Lennart Brewitz, Anthony Tumber, Christopher J. Schofield
Synthesis of Novel 2-Oxoglutarate Analogues as Potent Inhibitors of AspH
12:00-12:15 OP-33 Yuta Maki, Ryo Okamoto, Masayuki Izumi, Yasuhiro Kajihara
Semisynthesis of Complex-Type Triantennary Oligosaccharide and Its
Application to Glycoprotein Synthesis
12:15-12:30 OP-34 Tohru Oishi
Structure-Activity Relationship Studies of Maitotoxin Based on theChemical Synthesis of Partial Structures–Lunch–
Chair: Yujiro Hayashi
13:40-13:55 OP-35 Toshimichi Ohmura, Takeru Torigoe, Satoshi Kusaka, Kaito Yagi,
Michinori Suginome
Synthesis of O- and N-Heterocycles through Iridium-Catalyzed
Intramolecular C(sp3)–H Addition
13:55-14:10 OP-36 Kazuhiko Semba, Ryohei Kameyama, Hong Zheng,
Shigeyoshi Sakaki, Yoshiaki Nakao
Reductive Cross-Coupling of Carbon–Carbon Unsaturated Compounds andAryl Halides by Cooperative Palladium/Copper Catalysis
14:10-14:25 OP-37 Yoshiya Fukumoto
Rhenium-Catalyzed Reaction of Terminal Alkynes with Imines
Leading to N-Alkylideneallylamines
14:25-14:40 OP-38 Hayato Tsurugi, Mariko Inoue, Abhinanda Kundu, Haruki Nagae,
Kazushi Mashima
Ortho-C-H Bond Aminoalkylation of Pyridine Derivatives Catalyzed byYttrium Complexes with N,N’-Diarylethylenediamido Ligands

14:40-14:55 OP-39 Ken-ichi Fujita, Masato Kuwahara, Masaaki Nishioka, Masato Yoshida
Iridium Complex-Catalyzed Synthesis of Acetic Acid Based on
Dehydrogenation of an Ethanol-Water Solution–Coffee Break–
Chair: Ryoichi Kuwano
15:30-15:45 OP-45 Kotohiro Nomura, Sapanna Chaimongkolkunasin, Xiaohua Hou(Imido)vanadium(V)-Alkylidene Complexes as New Thermally Robust,
Efficient Catalysts for Ring-Opening Metathesis Polymerization of Cyclic
Olefins12

15:45-16:00 OP-46 Masahito Murai, Kazuhiko Takai			Rhenium-Catalyzed anti-Markovnikov Addition Reaction of Carbon
Nucleophiles to Unactivated Terminal Acetylenes
16:00-16:15 OP-47 Takashi Nishikata
Cu-catalyzed Radicals-Organometallics Combined Reaction System To
Load A Fourth Substituent On The Carbon
16:15-16:30 OP-48 Kazumasa Kitahara, Ryouta Kawanishi, Mei Kee Kam, Seiji Iwasa,			Kazutaka Shibatomi
Enantioselective Decarboxylative Halogenation of β-Keto Acids
16:30-16:45 OP-49 Yi Ning Ji Chen, Hongming Li, Alan M. Hyde, Qinghao Chen,			Kevin M. Belyk, Katrina W. Lexa, Jingjun Yin, Edward C. Sherer,			R. Thomas Williamson, Andrew Brunskill, Sumei Ren,			Louis-Charles Campeau, Ian W. Davies, Rebecca T. Ruck			
Rational Pre-catalyst Design for Bis-phosphine Mono-oxide Pd-catalyzed			
Asymmetric C-N Coupling
16:45-18:45
Poster Session 3 (Room C and Room D)				
PC(C)-01–PC(C)-84 (Room C)				
PC(D)-01–PC(D)-46 (Room D)
19:00-21:00		

Banquet (Room A)

November 16 (Fri)Room A

9:00-9:40		 IL-16 Harry L. Anderson
The biggest aromatic rings? Exploring the synthesis and properties of large
π-conjugated macrocycles
Chair: Takashi Hayashi			
9:40-10:20		 IL-17 Tom W. Muir
Houdini Proteins: Discovery and Applications of Ultrafast Inteins
Chair: Kazuya Kikuchi			
10:20-11:00 IL-18 Young-Tae Chang			Fluorescent imaging probe development for live cells in the body
Chair: Itaru Hamachi						–Coffee Break–

11:30-12:30 PL-3 K.C. Nicolaou
The Art and Science of Total Synthesis and Its Impact on Biology andMedicine: From the Fundamentals to the Translational13			
12:30-13:00		

Chair: Masakatsu Shibasaki
Closing Remarks

Room B

Chair: Masaki Shimizu			
9:00-9:15		 OP-50 Manuel Alcarazo			Electrophilic Cyanation and Alkynylation Reagents Based on Sulfur			
Platforms
9:15-9:30		 OP-51 Keisuke Asano, Shunsuke Einaru, Kenta Shitamichi, Tagui Nagano,			Akira Matsumoto, Seijiro Matsubaratrans-Cyclooctenes as Halolactonization Catalysts			
9:30-9:45		 OP-52 Yuuki Fujita, Gen Onodera, Tsutomu Fukuda, Masanari Kimura
Cu-Catalyzed Stereoselective Formation of α,β-Unsaturated Carbonyls via			Alkynylborates
9:45-10:00		 OP-53 Tomohiko Shirai, Yasunori Yamamoto			
Cationic Iridium/S-Me-BIPAM-Catalyzed Direct AsymmetricIntermolecular Hydroarylation of Bicycloalkenes
Chair: Mikiko Sodeoka			
10:00-10:15 OP-54 Gavin Chit Tsui
Turning Waste Into Value: New Trifluoromethylation Reactions with			Fluoroform-Derived CuCF3
10:15-10:30 OP-55 Kazuhiro Okamoto, Takuya Shimbayashi, Daiki Nakamoto,			Gaku Matsushita, Kouichi Ohe			
Radical Reactions initiated by Iron Catalyst and Oxime Esters
10:30-10:45 OP-56 Koji Hirano, Akihiro Matsude, Atifah Najib, Sho Tabuchi,			Masahiro Miura			
Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary			
Benzyl Carbonates
10:45-11:00 OP-57 Kazuishi Fukuda, Ryosuke Yamada, Nobuharu Iwasawa, Jun Takaya
Ru-Catalyzed C–H Borylation of Arylphosphines: A Powerful Tool for
Modification of Phosphine Ligands

14