Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

Safety Data Sheets
1.

Identification

Product Name

: Antifreeze Mixed water 35%

Order No.

: SPC-0783

General Use: General cold and heat medium(Food factory), ice storage refrigerant

Product Description: Antifreeze Mixed water

SDS Number: 037-O040575

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classified

Pyrophoric Liquids: Not classifiedHealth Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Skin Corrosion / Irritation: Not classified

Eye Damage / Irritation: Not classified

Sensitization – Respiratory: Not classified

Sensitization – Skin

: Not classified

Germ Cell Mutagenicity: Not classified

Specific Target Organ Toxicity: Not classified(Single Exposure)
Page 1 of 10

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

Safety Data Sheets
Specific Target Organ Toxicity: Not classified(Repeated Exposure)Environmental Hazards
Hazardous to the Aquatic: Not classified

Environment - Acute Hazard
Hazardous to the Aquatic: Not classified

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolNone
Signal Word
None
Hazard Statements
None
Precautionary Statements
None
3.

Composition / Information on Ingredients

No4.

Chemical Name

Wt%

CAS No.

1

Propylene glycol

15-25

57-55-62

Additive

1-5

Trade Secret3

Water

75-80

7732-18-5

First Aid Measures

Inhalation: Immediately remove victim to fresh air. Keep Victim warm bycovering with a blanket and rest. If breathing is weak or stopped,
loosen clothing and maintain an open airway and then, give
artificial respiration. If unconscious but breathing or if conscious but
breathing is difficult, it is effective to give oxygen. It isrecommended to conduct under doctor’s instructions.

Eye Contact: Remove contact lenses, if present and easy to do. Continue rinsing.
Rinse eyes with clean water for at least 15 minutes and get medical
attention from an ophthalmologist immediately. Hold eyelids open
and away from eyeballs with fingers to ensure that all surfaces are
Page 2 of 10

Safety Data Sheets

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

flushed thoroughly.
Skin Contact: Remove contaminated clothing, shoes, etc. promptly. Cut it off ifnecessary. Flush affected area with water or lukewarm water andwash off with soap. If visual change occurs or pain persists, getmedical attention.

Ingestion: If conscious, induce vomiting by giving more than two cups of milkor water and get medical attention immediately. Never give water,etc to an unconscious person. Keep victim warm and get medical
attention immediately.

Expected acute and: If swallowed, it can cause diarrhea, vomit.

delayed symptoms, mostIf in eyes, it can cause inflammation.

important sign and

If on skin, it can cause inflammation.

symptoms

If inhaled mist, it can cause nausea.

5.

Fire Fighting Measures

Flammable Properties: Flash point : None

Extinguishing Media: Use water (water fog), dry powder, alcohol-resistant foam.

Unsuitable extinguishing: Don’t use fire hose.

MediaFire Fighting: Eliminate all sources of ignition form fire area. For initial fire, use

Instructions

water (water fog), dry powder, etc. for fighting fire. For large fire, itis effective to use foam (alcohol-resistant foam), etc to shut off air
supply. Pouring water can be dangerous by expanding fire. Coolsurrounding facilities, etc. with water spray. Prohibit unnecessary
personnel from entering fire area. Immediately remove movable
container to a safe area.

Protection for: Wear safety glasses, protective clothing, and respiratory protection

fire-fightersfor the situation during fire fighting. Extinguish fire form upwind.

6.

Accidental Release Measures

Personal Precautions: Prohibit unnecessary personnel from entering spilled areaseparated by rope, etc. Wear suitable protective equipment during
clean-up to prevent contact with water drop or inhalation of gas.
Work from upwind and evacuate from downwind.
Page 3 of 10

Safety Data Sheets

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

Precautions for the: Since it is related to soil and water contamination, recover spills asenvironment

much as possible.

Recovery/neutralization: For large spills, dike with earth and sand, etc. to prevent spreading
and sweep into an empty container and dispose of in a safe place. Be
tender of discharging into sewers, drains, etc. Be sure to wear
protective equipment during clean-up. For small spills, absorb withdry sand, earth, sawdust, wastes, etc and collect into an empty
container that can be closed.

Method for containment: Stop leakage, if it can be done without risk. In case of running off,and clean-up

prevent spread of the liquid and scoop or absorb with a proper
absorbent. If inevitable, use a chemical. When using a chemical, it
should meet the technical standards set by the Ordinance of theMinistry of Transport.

Preventive measure of: Immediately eliminate all source of ignition nearby. Request

secondary disastercooperation by giving notice to relevant agencies.

7.

Handling and Storage

Handling: Keep good working environment. Prevent spills, overflow, scattering

Technical measures:and generation of vapors. Prohibit the use of sources of fire, sparks
and arcs around the handling place. Prohibit the use near sources ofignition of high temperature. Repair machinery containing residues
after completely removing them in a safe place. Take precautionary
measures against static discharge and wear conductive working
clothes, shoes, etc. Since vapors are heavier than air, it is likely tostay in low areas. So, pay attention to ventilation and sources of fire,etc. Handle at room temperature and pay attention to mixing withwater or impurities. If it is possible to contact with skin or eyes, wear
protective equipment. If mist is generated, do not breathe mist bywearing respirators, etc. Use a pump, etc. to take out the productfrom a container. Use a thin tube and do not suck it with mouth. Do
not weld, heat, puncture or cut containers. It can cause ignition ofresidues following explosion.

Local exhaust or general: See‘Section 8.Exposure Controls and Personal Protective

ventilation

Equipment’.

Avoid to contact: See ‘Section 10. Stability and Reactivity’.
Page 4 of 10

Safety Data Sheets

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

Precaution for safe

: Obtain special instruction before use. Do not handle until all safety

handling

precautions have been read and understood. Pay attention to sourcesof fire. Wash hands and eyes thoroughly after handling. If onclothing, change clothing. Use only outdoors or in a well-ventilatedarea. Do not eat or smoke when using this product. Do not put
pressure to an empty container. It can cause rupture of a container.
Do not drink. Keep out of the reach of children.

StorageTechnical measure: Avoid heat, sparks, open flames and static built -up. Be sure to keep
container tightly closed.

Incompatible materials: See ‘Section 10. Stability and Reactivity’.

Storage condition: Keep container in a well-ventilated area. Protect from direct sunlight.
Keep away from oxidizing agents.

Safe container and: Use container without damage, corrosion, cracks, etc. Do not handle apackaging material

container in a violent manner such as turning over, impacting or
dragging it. Keep used container at a certain designated place.

8.

Exposure Controls / Personal Protection

Exposure Controls: Not established.

Exposure Controls
Permissible exposure level(Threshold limits, biological exposure indices, etc):
Not established.
The Japanese Occupational Hygiene Society (2009): Not established.
ACGIH (2009): Not established.
Occupational Exposure Controls
Engineering Controls:

If mist and vapor is generated, use enclosure of sources or local
exhaust ventilation. Provide safety shower, basin and eye wash
facilities near the place where the product is handled and indicate
the location clearly.

Personal Protection
Respiratory: Wear gas mask for toxic gas, if necessary.

Protection

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Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

Safety Data Sheets

Hand Protection: Wear impermeable rubber gloves.

Eye Protection: Wear ordinary glass with side shields or safety goggles.

Skin Protection: Wear long-sleeved working clothes. Take off wet clothing and wash
before reuse.

general hygiene consideration: Check protective equipment on a regular based on a checklist. Do noteat or smoke during work. Wash hands with soap before eating orsmoking.
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: Red clear

Odor: Almost odorless

pH: 8.0 - 9.0

Boiling Point / Boiling Range: Not Available

Melting Point / Melting Range: Not Available

Flash Point: NoneIgnition temperature: None.

Explosive limits: Lower: None.

Explosive limits: Upper: None.

Vapor pressure: Not Available

Vapor density(Air=1): No data.

Specific gravity(Density): 1.020 - 1.030

Solubility: Soluble in water, low alcohols, acetone
Page 6 of 10

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

Safety Data Sheets
Partition coefficient(n-octanol/water): Not Available

Auto-ignition temperature: Not AvailableDecomposition temperature: Not Available

10. Stability and Reactivity
Conditions to Avoid: No data. (No hazardous reactions under normal handling condition.)

Stability: Stable

Materials to Avoid: Strong acids, strong oxidizing agents.

Hazardous Reactions /: Explosion/ignition at room temperature hardly occurs, but if moisture

Decomposition Products

is evaporated at high temperature, it is easy to ignite/burn. It canreact with strong acids, strong oxidizing agents violently.

11. Toxicological Information
Acute Toxicity: (Annex) Acute toxicity(Oral, dermal, inhalation)
Content

Oral

Dermal(%)①Propylene

15~25%

glycol②Additive③WaterTotal
Oral:

1~5%

75~80%

Inhalation

Inhalation

Inhalation(Gas)(Vapor)(Dust, mist)

Not

Not

Not

Classification

Classification

classifiedclassified

applicable

not possible

not possible

Classificat

Classifica

Not

Classification

Classification

ion nottion notapplicable

not possible

not possible

possiblepossible

Not

Not

Not

Not classified

Not classifiedclassifiedclassified

applicable100%: It contains acute toxicant (oral) on Annex. The product as a
mixture is classified as ‘Acute toxicity (Oral): Not classified’.

Dermal:: It contains acute toxicant (dermal) on Annex. The product as amixture is classified as ‘Acute toxicity (Dermal): Not classified’.

Inhalation:: It contains acute toxicant (inhalation) on Annex. The product as a
mixture is not possible to classify for acute toxicity(inhalation).

Eye Irritation:

・It contains eye irritants classified below.-Not classified: Water,propylene glycol5)
The product as a mixture is classified as ‘Serious eye damage/eye・Page 7 of 10

Safety Data Sheets

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

irritation: Not classified’.
・Serious eye damage/eye irritation of 1~5% of this mixture isunknown.
Skin Irritation:

・It contains skin irritants classified below.-Not classified: Water
・The product as a mixture is classified as ‘Skin corrosion/irritation:
Not classified’.
・Skin corrosion/irritation of 1~5% of this mixture is unknown.

Sensitization:

・It contains respiratory sensitizers classified below.-Not classified:
Water, propylene glycol5)
・The product as a mixture is classified as ’Respiratory sensitization:
Not Classified’.
・Respiratory sensitization of 1~5% of this mixture is unknown.
・It contains skin sensitizers classified below.-Not classified: Water,propylene glycol5)
・The product as a mixture is classified as ’Skin sensitization: Notclassified’.
・Skin sensitization of 1~5% of this mixture is unknown.

Germ cell mutagenicity:

・It contains germ cell mutagens classified below.-Not classified:Water, propylene glycol5)
・The product as a mixture is classified as ‘Germ cell mutagenicity:
Not classified’.
・Germ cell mutagenicity of 1~5% of this mixture is unknown.

Carcinogenicity:・Classification is not possible due to lack of data.

Reproductive toxicity:

・Classification is not possible due to lack of data.

Specific target organ toxicity (single exposure):・It contains specific target organ toxicants(single exposure)classified below.-Not classified: Water, propylene glycol5)
・The product as a mixture is classified as ‘Specific target organ
toxicity (single exposure): Not classified’.
Specific target organ toxicity (repeated exposure):・It contains specific target organ toxicants(repeated exposure)classified below.-Not classified: Water
・The product as a mixture is classified as ‘Specific target organ
toxicity(repeated exposure): Not classified’.
Aspiration hazard:

・Classification is not possible due to lack of data.

Page 8 of 10

Safety Data Sheets

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
・It contains hazardous substances(acute)to aquatic environment

Ecotoxicity

classified below.-Not classified: Water, propylene glycol5)
・The product as a mixture is classified as ‘Hazards to aquatic
environment (Acute): Not classified’.
・Hazards to aquatic environment (Acute) of 1~5% of this mixture is
unknown.
・It contains hazardous substances (chronic) to aquatic environment
classified below.-Not classified: Water, propylene glycol5)
・The product as a mixture is classified as ‘Hazards to aquatic
environment (Chronic): Not classified’.
・Hazards to aquatic environment (Chronic) of 1~5% of this mixture is
unknown.
Persistence/degradability:: Not AvailableBio-accumulation:: Not Available

Mobility in soil:: Not Available

Other adverse effects:: Not Available

Environment criteria:: Not Available

13. Disposal Considerations
Residual wastes: Comply with all USA, national and local regulations. Do not dump
this product into sewers, on the ground or into any body of water.

Contaminated container and packages:: Contaminated or empty container packaging are to be disposed
according to national and local regulation.
14. Transport Information
US DOT Information: Not regulated as a hazardous material for transport.

TDG Information: Not regulated as dangerous goods for transport.
Page 9 of 10

Safety Data Sheets

Product Name: Antifreeze Mixed water 35%
SDS No. 037-O040575
First issue: 2015/07/09
Revised: 2023/11/29

IATA Information: Not regulated as dangerous goods for transport.

ICAO Information: Not regulated as dangerous goods for transport.

IMDG Information: Not regulated as dangerous goods for transport.

Special precautions: Load the containers in a manner that they are certain not to resultin direct sunlight exposure, damage, corrosion, leak, while beingtransport.
Load the containers in manner that they are not to fall apart while
being transport.
Do not place heavy load on top of the container.
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.

15. Regulatory Information
US federal regulations: All components are active on the TSCA Inventory List.

16. Other Information
References

1) The Japanese Occupational Hygiene Society recommendation onpermissible exposure level, etc (OELs)
2) Thresholds limit values for chemical substances and physical agentsand biological exposure indices. ACGIH
3) National Institute of Technology and Evaluation (NITE)
4) European Chemical Substances Information System5) Material Safety Data Sheet (Propylene glycol), Japan PetrochemicalIndustry Association (1998)

This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 10 of 10