Material Safety Data Sheets
Sheets1.

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 1 of 10

Product and Company
Company Identification

Product Name

: Pigment Ink For Textile Yellow

Product Code: SPC-0435Y

General Use: Ink jet printing ink

Product Description: Pigment ink

MSDS Number: 031-33W03YC

Manufacture
Company Name

: Mimaki Engineering Co., LtdAddress: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 Japan

Telephone No.

: +81-268-64-2413

Importer/Distributor Established in USA
Company Name

: MIMAKI USA. INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.ATelephone No.

: 1-678-730-0100

Emergency Telephone No.

: +81-268-64-2413

2.

Hazards Identification

Not classified as hazardous according to regulatory criteria.

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 2 of 10

Material Safety Data Sheets
Sheets3.

Composition / Information On Ingredients
ChemicalNo

Chemical Name

Wt%

CAS No.

12,2’-oxybisethanol diethylene glycol

7.0～10.0%

111-46-6

1.0～2.5%9004-83-5-

0.5～0.6%

1336-21-6

NH4OH

234.

Poly(oxy-1,2-ethanediyl), .alpha.-(2-(tert-dodecylthio)ethyl
Ammonia, aqueous solution

FormulaC4H10O3/(CH2CH2OH)2O

First Aid Measures
Measures
Inhalation: Move to fresh air. Give artificial respiration if breathing has
stopped. Consult a physician.

Eye Contact: Immediately flush eye(s) with plenty of water. Get prompt medicalattention.

Skin Contact: Wash with water and soap as a precaution. If skin irritation
persists, call a physician. Wash contaminated clothing before reuse.

Ingestion: Drink 1 or 2 glasses of water. Consult a physician. Never give
anything by mouth to an unconscious person. If vomiting occurs
spontaneously, keep airway clear.

Note To Physician: Treatment may vary with condition of victim and specifics ofincident.

5.

Fire Fighting Measures
Measures
Flammable Properties

Flash point: Noncombustible
Lower explosion limit: Not applicable
Upper explosion limit: Not applicable

ThermalCombustion generates toxic fumes of the following:, nitrogen oxides

decomposition(NOx), Carbon oxides, sulfur oxides.

Extinguishing Media: Use the following extinguishing media when fighting fires involving
this material:polar solvent (alcohol) foam

Material Safety Data Sheets
Sheets

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 3 of 10

Water spray
Dry chemical
Carbon dioxide (CO2)Fire Fighting: Wear full fire-fighting turn-out gear (full bunker gear) andInstructions

respiratory protection (self-contained breathing apparatus).
Evacuate area and fight fire from a safe distance. Containers canrupture and release highly toxic vapors or decomposition products if
exposed to heat. Dried product can burn. Material can splatter above
100C/212F.

Further information:Remain upwind.
Avoid breathing smoke.
Use water spray to cool unopened containers.

6.

Accidental Release Measures
Measures

METHODS: Contain spilled liquid with sand or earth. DO NOT use combustible

FOR CLEANING UP

materials, such as sawdust.
Eliminate all ignition sources, use explosion-proof equipment.
Vacuum or sweep material and place in a disposal container.
The material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems
and bodies of water.

HANDLING: Avoid contact with skin, eyes and clothing.
Do not breathe (dust, vapor, mist, gas).
Wash thoroughly after handling.
Use only clean, dry utensils in handling.
Keep container tightly closed. Store in a cool, dry, well ventilatedplace.
Destroy contaminated shoes in proper manner.

STORAGE: Solidifies at about 5 - 25 °C (41 - 77 °F) and may break container.
Keep from freezing - product stability may be affected.

SPECIFIC USES

: Formaldehyde will be generated under acidic conditions. Maintainadequate ventilation under these conditions to prevent exposure toformaldehyde above ceiling of 0.3 ppm.

FURTHER: Monomer vapors can be evolved when material is heated during

Material Safety Data Sheets
SheetsINFORMATION

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 4 of 10

processing operations. See SECTION 8, for types of ventilation
required.
Improper disposal or re-use of this container may be dangerous andillegal. Refer to applicable local, state and federal regulations.
Dispose empty container in a sanitary landfill or by incineration asallowed by state and local authorities.

7.

Handling And
And Storage

HANDLING: Avoid contact with skin, eyes and clothing.
Do not breathe (dust, vapor, mist, gas).
Wash thoroughly after handling.
Use only clean, dry utensils in handling.
Keep container tightly closed. Store in a cool, dry, well ventilated
place.
Destroy contaminated shoes in proper manner.

STORAGE: Solidifies at about 5 - 25 °C (41 - 77 °F) and may break container.
Keep from freezing - product stability may be affected.

SPECIFIC USES

: Formaldehyde will be generated under acidic conditions. Maintainadequate ventilation under these conditions to prevent exposure toformaldehyde above ceiling of 0.3 ppm.

FURTHER: Monomer vapors can be evolved when material is heated during

INFORMATION

processing operations. See SECTION 8, for types of ventilation
required.
Improper disposal or re-use of this container may be dangerous andillegal. Refer to applicable local, state and federal regulations.
Dispose empty container in a sanitary landfill or by incineration asallowed by state and local authorities.

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 5 of 10

Material Safety Data Sheets
Sheets8.

Exposure Controls / Personal ProtectionNo
1

Chemical Name

STEL

Ceili
ng

Skin

REL

2,2’-oxybisethanol

OSHA PEL

N.E

N.E.

N.E.

N.E.

N.E.

diethylene glycol

ACGIH TLV

N.E

N.E.

N.E.

N.E.

N.E.

OSHA PEL

N.E.

N.E.

N.E.

N.E.

N.E.

35ppm

35ppm

N.E.

N.E.

N.E.

(As Ammonia)(As Ammonia)

Ammonia, aqueous

20ppm

50ppm

solution

N.E.

N.E.

N.E.

(As Ammonia)(As Ammonia)

14mg/m3

36mg/m3

N.E.

N.E.

N.E.

(As Ammonia)(As Ammonia)

17mg/m3

N.E.

N.E.

N.E.

N.E.

ACGIH TLV
2TWA

ECTLV

JPJSOH OEL
Exposure Controls
Occupational Exposure Controls
Engineering

Use only in area provided with appropriate exhaust ventilation.

Controls
Personal Protection
Respiratory

Use

certified

respiratory

Protection

requirements(89/656/EEC,protection
89/686/EEC

equipment),or

meetingequivalent,EU
when

respiratory risks cannot be avoided or sufficiently limited by technicalmeans of collective protection or by measures, methods or proceduresof work organization.

Hand Protection

Chemical-resistant gloves should be worn whenever this material ishandled. The glove(s) listed below may provide protection againstpermeation. (Gloves of other chemically resistant materials may notMaterial Safety Data Sheets
Sheets

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 6 of 10

provide adequate protection): Neoprene gloves Gloves should beremoved and replaced immediately if there is any indication ofdegradation or chemical breakthrough. Rinse and remove gloves
immediately after use. Wash hands with soap and water.
Eye Protection

Wear coverall, chemical goggles and face shield when handling.
Skin Protection

To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, as appropriate.
Environmental Exposure Controls: Not available

Material Safety Data Sheets
Sheets9.

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 7 of 10

Physical And
And Chemical Properties

Appearance- Physical state: liquid- Colour: YellowOdour: ammonia

pH: 7.5 - 9.5

Boiling Point / Boiling Range: 100 °C ( 212.00 °F) Water

Melting Point / Merting Range: Not available

Decomposition Temperature: Not available

Flash Point: Noncombustible

Auto-Ignition Temperature: Not available

Flammability(solid, gas)

: Not available

Vapour Pressure: 17.0 mmHg at 20 °C (68 °F) Water

Specific Gravity: 0.95 - 1.05

Solubility: Not available

Water solubility: Dilutable

Viscosity: 2.500 - 4.000 mPa.s

Vapour density: <1.0Water

Evaporation Rate

: <1.00 Water

VOC: 10.0g/l

10. Stability
tability And Reactivity
Reactivity
Conditions To Avoid: Thermal decomposition may yield acrylic monomers.

Stability: Product will not undergo polymerization.

Materials To Avoid: Avoid contact with acids, alkalies and strong oxidizing agents.

Hazardous Reactions/: This material is considered stable.

Decomposition Products

However, avoid temperatures above 177C/350F, the onset of polymer
decomposition. Thermal decomposition is dependent on time andtemperature.

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 8 of 10

Material Safety Data Sheets
Sheets
11. Toxicologocal Information
Acute Toxicity

Component: 2’-oxybisethanol diethylene glycol
Oral LD50

Dermal LD50

>10,000 mg/kg(rat)>10,000 mg/kg(rabbit)

Inhalant LC50

Component: Ammonia, aqueous solution
Oral LD50

Dermal LD50

Inhalant LC50

>350 mg/kg(rat)
Eye Irritation: Not available

Skin Irritation: rabbit slight irritation

Sensitization: Patch test on human volunteers did not demonstrate sensitization
properties.

Mutagenicity: Not available

Carcinogenicity: Not available

12. Ecological Information
Information
Handling is noted because it might influence the environment
when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground,
the river, and the drain ditch.
Ecotoxicity

There is no data available for this product.
2’-oxybisethanol diethylene glycol:
Acute and prolonged toxicity to fish
Toxicity to fish

LC50 >100 mg/l

Toxicity to aquatic invertebrates
EC50 Daphnia magna 100 mg/l
Ammonia, aqueous solution
Acute and prolonged toxicity to fish
Toxicity to fish
LC50 Oncorhynchus mykiss (rainbow trout) 24 h 0.097 mg/l
TLm Fathead minnow (Pimephales promelas) 96 h 8.2 mg/l

Material Safety Data Sheets
SheetsPersistence And

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 9 of 10: Not available

Degradability
Bioaccumulative Potential: Not available

Other Adverse Effects: Not available

13. Disposal Considerations
Considerations: Comply with all EU, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Class/UN Number: Not applicable
DOT, IMO/IMDG,IATA/ICAO : Not applicable

15. Regulatory Information
TSCA Status: All components of this product are in compliance with the inventory
listing requirements of the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

Material Safety Data Sheets
Sheets

Product Name：Pigment Ink
For Textile Yellow
MSDS No. 031-33W03YC
First issue：Oct 18, 2007
Revised: Jun 13, 2008
Page 10 of 1016. Other Information
Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and dose not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.
Revision history
VersionDate

Content

1.00

Oct 18, 2007

First issue

2.00

Jun 13, 2008

No.9 VOC