Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
1.

Identification

Product Name

: HS ink Cyan

Order No.

: SPC-0473C-5, SPC-0589C-5

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037-S060577

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2

Sensitization – Skin

: Category 1

Germ Cell Mutagenicity: Category 2

Toxic to Reproduction: Category 2

Specific Target Organ Toxicity: Category 2 (respiratory system)(Single Exposure)Specific Target Organ Toxicity(Repeated Exposure): Category 1 (bone marrow, spleen, kidneys, adrenalgland, respiratory system and liver)
Category 2 (central nervous system, bone)
Page 1 of 10

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Environmental Hazards
Hazardous to the Aquatic: Category 3

Environment - Acute Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal WordDanger
Hazard Statements
H227 Combustible liquid
H315 Cause skin irritation
H317 May cause an allergic skin reaction
H319 Cause serious eye irritation
H341 Suspected of causing genetic defects
H361 Suspected of damaging fertility or the unborn child
H371 May cause damage to respiratory system
H372 Causes damage to bone marrow, spleen, kidneys, adrenal gland, respiratory system
and liver through prolonged or repeated exposure
H373 May cause damage to central nervous system, bone through prolonged or repeatedexposure
H402 Harmful to aquatic life
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see 4-Response on our website/SDS URL:
www.mimaki.co.jp/sds).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
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Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets

P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire: Use appropriate media for extinction.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents and container in accordance with local, regional, national andinternational regulation.
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 22Flammability= 2

2 Flammability

Flammability = 2

Reactivity = 1

1

Reactivity

Instability = 1

Protective Equipment = G

G Protective Equipment

Special = None

3.

Health = 2221Composition / Information on IngredientsNo

4.

HealthChemical Name

Wt%CAS No.

1Phthalocyanine blue

0.1-5

Registered2

Vinyl chloride / Vinyl acetate copolymer resin

0.1-5

Registered

3

Polyester resin

0.1-5

Registered4

Dipropylene glycol methyl ether acetate

10-3088917-22-05Dipropylene glycol dimethyl ether

10-30

111109-77-4

63-Methoxybutyl acetate

10-30

4435-53-4

7N-Methyl-2-pyrrolidone

10-30

872-50-4

8Cyclohexanone

1-5

108-94-1

9Additives

0.1-5

RegisteredFirst Aid Measures

Inhalation: If inhaled, immediately remove to fresh air and keep warm andcalm. If breathing irregularly or not breathing, give artificial
respiration and consult a doctor immediately.

Eye Contact: Flush eyes thoroughly with water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Consult an ophthalmologist
immediately.
Page 3 of 10

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Skin Contact: Wash skin thoroughly with plenty of water. If on clothing, remove
immediately contaminated clothing.

Ingestion: Do not induce vomiting. If swallowed, keep calm and consult adoctor immediately. Keep from swallowing vomit.

Protection To First-Aiders: Wear tools for appropriate protection. Ventilate. See section 7 and 8.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Avoid breathing combustion products.
Flash point: 68℃

Ignition point : Not available
Explosion point : 0.85～15.00vol%
Extinguishing Media: Foam, carbon dioxide, dry chemical, water spray

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams

Media
Fire Fighting Measures: Move container from fire area if it can be done without risk. Do notscatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stayaway from the ends of tanks. Avoid inhalation of material or
combustion by-products. For fires in cargo or storage area: Coolcontainers with water from unmanned hose holder or monitor
nozzles until well after fire is out. If this is impossible then take thefollowing precautions: Keep unnecessary people away, isolate
hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or
any discoloration of tanks due to fire.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible

Precautions forexposure.

Firefighters

Page 4 of 10

Safety Data Sheets
6.

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment

Avoid release to the environment.

and Emergency
Procedures
Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas.

7.

Handling and Storage

Handling: Obtain SDS (Safety Data Sheet) and printer's operation manual
before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot
surfaces.-No smoking. Do not breathe gas/mist. Wash hands
thoroughly after handling. Do not eat, drink or smoke when using
this product. Contaminated work clothing should not be allowed outof the workplace. Avoid release to the environment. Wear protective
gloves/protective clothing/eye protection/face protection.

Storage: Store and handle in accordance with all current regulations andstandards. Keep container tightly closed. Keep cool. Grounding andbonding required. Store locked up. Keep separated from incompatible
substances.

Page 5 of 10

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
8.

Exposure Controls / Personal Protection

Exposure Limit Values
No1

Chemical Name
Cyclohexanone(CAS No. 108-94-1)

TWASTEL

OSHA PEL

50 ppm-ACGIH TLV

20ppm

50ppm

NIOSH

25ppm

-Exposure Controls
Occupational Exposure Controls
Engineering Controls: Ventilation equipment should be explosion-resistant if explosive
concentrations of material are present. Provide local exhaust or
process enclosure ventilation system. Ensure compliance withapplicable exposure limits.

Personal Protection
Respiratory: Wear protective masks for hazardous materials.

Protection

Hand Protection: Wear gloves resistant to organic solvents and chemicals.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, asappropriate.

Environmental Exposure Controls: Not available

Page 6 of 10

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
9.

Physical and Chemical Properties

Appearance- Physical State: liquid (25℃)- Color: CyanOdor: Solvent odorpH

: Not available

Boiling Point / Boiling Range: 156～209 ℃

Melting Point / Melting Range: < －30℃

Flash Point: 68℃

Flammability (Solid, Gas)

: Not Applicable

Upper / Lower Flammability or: 0.85～15.00 vol%Explosive Limits
Vapor Pressure: 450Pa (20℃)

Relative Density: 0.97 (25℃)

Solubility (Ies): Very small amountPartition Coefficient (n-octanol / Water): Not available

Viscosity: 3.5mPa・s (25℃)

10. Stability and Reactivity
Conditions to Avoid: Excessive heat and cold, sparks, ignition sources, direct sunlight andhigh humidity.

Stability: Stable

Materials to Avoid: Oxidant, reducing agent, strong acid, strong base, inert gas,deoxidant

Hazardous Reactions /: Combustion: toxic gases, oxides of carbon, oxides of nitrogen

Decomposition Products
Other: Plastic and rubbers might be melted.

11. Toxicological Information
Acute Toxicity:

ProductOral（rat）
LD50>2,000mg/kg
Not classified

Dermal（rabbit）
LD50>2,000mg/kg
Not classified
Page 7 of 10

Safety Data Sheets

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Eye Contact: eye irritation

Skin Irritation: irritation, sensitization

Sensitization: Skin sensitization may occur.

Mutagenicity: Available data characterizes components of this product as germ cellmutagenicity

Carcinogenicity

Specific Target Organ: Cyclohexanone (CAS No. 108-94-1)
Monograph 71 [1999]; Monograph 47 [1989]
IARC(Group 3 (not classifiable)): respiratory system

Toxicity - Single
Exposure
Specific Target Organ: bone marrow, spleen, kidneys, adrenal gland, respiratory system andToxicity - Repeatedliver, central nervous system, bone

Exposure
Reproductive and: Available data characterizes components of this product as

Developmental Toxicity

reproductive hazards.

Others: Not Available

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Hazardous to the Aquatic Environment - Acute Hazard
Calculated value : L(E)C50 >10.0mg/L Category 3

Persistence and: Not available

Degradability
Bioaccumulative: Not available

Potential
Other Adverse Effects: Not available

Page 8 of 10

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
13. Disposal Considerations

Have waste inks, containers and other materials disposed by licensed industrial waste disposer.
Adsorb to diatom earth and others to dispose waste inks, and use open incinerator.
Dispose of wastes by licensed industrial waste disposer to comply with the local laws andregulations. Empty inks and other materials out of containers if disposed.
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Number: Not Applicable

US DOT Information: Not regulated as dangerous goods for transport. *1*1 Class combustible liquid (NA1993), Packing group III for quantities of 450 liters (119 gallons) ormore; not regulated for smaller quantities
15. Regulatory Information
TSCA Status: All components on TSCA INVENTORY.

SARA TitleⅢ
Section 311/312: Fire Hazard: Yes(40 CFR 370)

Pressure Hazard: No
Reactivity Hazard: No
Immediate Hazard: Yes
Delayed Hazard: Yes

California Proposition: WARNING:

65

This product can expose you to chemicals including
Acetaldehyde, Methanol, N-Methylpyrrolidone, Vinyl chloride,
which are known to the State of California to cause cancer/
birth defects or other reproductive harm. For more information
go to www.P65Warnings.ca.gov.

Others: Please refer to any other federal, state and local regulations.

Page 9 of 10Safety Data Sheets

Product Name: HS ink CyanSDS No. 037-S060577
First issue: 2011/09/30
Revised: 2019/10/30

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 10 of 10