Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
1.

Identification

Product Name

: MUH-100 Silver

Order No.

: MUH10-Si-B2

General Use: Ink for ink jet printer

Product Description: UV curable ink

SDS Number: 037- U161891

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPANTelephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS classification of the substance/mixture]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2ASensitization – Skin

: Category 1

Environmental Hazards
Hazardous to the Aquatic: Category 3

Environment - Acute Hazard
Hazardous to the Aquatic: Category 3Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS label elements, including precautionary statements]
Page 1 of 13

Safety Data Sheets

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

SymbolSignal Word
Warning
Hazard Statements
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H412 Harmful to aquatic life with long lasting effects.
Precautionary Statements[Prevention]
P261 Avoid breathing gas/mist/vapours/spray.
P264 Wash hands and eyes thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
[Storage]
None.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
3.

Composition / Information on Ingredients
Chemical / mixture classification: mixtureNo

Chemical Name

Wt%

CAS No.

1

Acrylic ester A

30-40

Trade secret2

Acrylic ester B

20-30

Trade secret3

Acrylic ester C

10-20

Trade secret4

Acrylic ester D5-10

Trade secret5

Acrylic ester E

0.1-0.5

Trade secret

6

Polymerization initiator

1-10

Trade secret
Page 2 of 13

Safety Data Sheets

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

7

Polymerization inhibitor A<0.1

Trade secret

8

Polymerization inhibitor B<0.1

Trade secret9

Antioxidant A

0.1-1

Trade secret

10

Antioxidant B

0.1-1

Trade secret

11

Organic components

1-5

Trade secret12

Pigment

0.1-0.8

Trade secret

4.

First Aid Measures

Inhalation: Remove to fresh air and keep at rest in a position comfortable forbreathing. Call a POISON CENTER or doctor/physician if you feelunwell.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before reuse. If skin irritation or rash occurs: Get medical
advice/attention.

Eye Contact: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. If eye irritation
persists, get medical advice/attention.

Ingestion: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.

Most Important Symptoms/Effects
Acute: skin irritation, eye irritation, allergic skin reactions

Delayed: allergic skin reactions

Indication of any: Treat symptomatically and supportively.

immediate medical
attention and special
treatment needed
5.

Fire Fighting Measures

Extinguishing Media: Carbon dioxide, foam, powder.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

Media
Protective Equipment: Wear full protective fire fighting gear including self containedand Precautions forbreathing apparatus (SCBA) for protection against possible exposure.

Firefighters
Page 3 of 13

Safety Data Sheets
Fire Fighting Measures

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03: Move material from fire area if it can be done without risk. Useextinguishing agents appropriate for surrounding fire. Do not scatterspilled material with high-pressure water streams. Cool containers
with water spray until well after the fire is out. Avoid inhalation ofmaterial or combustion by-products. Stay upwind and keep out of lowareas.

Fire/Explosion Hazard

Non combustible.
Not considered a significant fire risk, however containers may burn.
May emit poisonous fumes.
May emit corrosive fumes.

6.

Accidental Release Measures

Personal precautions,: Wear personal protective clothing and equipment, see Section 8.

protective equipment andemergency procedures
Environmental: Avoid release to the environment.

precautions
Methods and Materials: Avoid heat, flames, sparks and other sources of ignition. Stop leak if

for Containment andpossible without personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal. Large
spills: Dike for later disposal. Keep unnecessary people away, isolate
hazard area and deny entry. Stay upwind and keep out of low areas.

7.

Handling and Storage

Precautions for Safe

: Avoid breathing gas/mist/vapours/spray. Wash hands and eyes

Handling

thoroughly after handling. Contaminated work clothing should not beallowed out of the workplace. Avoid release to the environment. Wearprotective gloves/protective clothing/eye protection/face protection.

Conditions for safe

: Avoid direct sunlight. Keep in a well-ventilated area. Keep out ofstorage

reach of children. Keep away from fire and heat source. Store lockedup.

8.

Exposure Controls / Personal Protection
Page 4 of 13

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Ingredient

SourcePigment

TWA

STEL

Peak

Notes

US NIOSH

10 (total),

Not

Not

Not Available

Recommended Exposure5(resp)mg/m3

Available

Available

1 mg/m3

Not

Not

TLV® Basis:

Available

Available

Pneumoconio

Limits (RELs)
US ACGIH Threshold
Limit Values (TLV)

sis; LRT irr;
neurotoxicity
US OSHA Permissible

15 mg/m3

Exposure Levels (PELs)

Not

Not

Not Available

Available

Available

Not

Not

Available

Available

Not

Not

Available

Available

Not

Not

Available

Available

Not

Not

Available

Available

Not

Not

TLV® Basis:

Available

Available

Eye irr; skin

- Table Z1
US OSHA Permissible

5 mg/m3

Exposure Levels (PELs)

Not Available- Table Z1
Polymerization

US NIOSH

inhibitor

Recommended

2 mg/m3

Not Available

Exposure Limits (RELs)
US NIOSH

5 mg/m3

Recommended

Not Available

Exposure Limits (RELs)
Polymerization

US NIOSH

inhibitor

Recommended

5 mg/m3

Not Available

Exposure Limits (RELs)
US ACGIH Threshold

5 mg/m3

Limit Values (TLV)

dam
EMERGENCY LIMITS
Ingredient

TEEL-1

TEEL-2

TEEL-3

Acrylic ester E

3 mg/m3

170 mg/m3

990 mg/m3

Polymerization inhibitor A

15 mg/m3

49 mg/m3

320 mg/m3

Exposure Controls
Occupational Exposure Controls
Appropriate: Provide local exhaust or process enclosure ventilation system.
Page 5 of 13

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
Engineering Controls

Ensure compliance with applicable exposure limits.

Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: Consult with a health and safety professional for specific respirators
appropriate for your use.

Glove

: Wear appropriate chemical resistant gloves.

Recommendations

Eye /Face: Wear splash resistant safety goggles with a faceshield.

Protection

Skin Protection

9.

: Wear appropriate chemical resistant clothing.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: SilverOdor: SlightpH: Not available

Melting point / freezing point: Not available

Boiling Point / Boiling Range: 102 – 200 degree C

Flash Point: 131 degree C

Autoignition temperature (ignition point): 380 degree C

Flammability (Solid, Gas)

: Not available

Upper / Lower Flammability or: 11.5[vol %] ／ 2.2[vol %]Explosive Limits
Vapor Pressure: 1.33 Pa (20 degree C)

Vapor Density: Not available
Page 6 of 13

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
Evaporation Rate

: Not available

Relative density (Water = 1)

: 1.092

Water Solubility: Not available

Solubility in solvent: Not available

Partition Coefficient (n-octanol / Water): Not available

Decomposition Temperature: Not available

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Conditions to Avoid: Avoid high temperature.

Hazardous: See section 5.

Decomposition Products
11. Toxicological Information
Acute Toxicity
Ingredient name

OralDermal

As a ProductNot classified

Not classified

Information on Likely Routes of Exposure
Inhalation: No information available for the product.

Ingestion: No information available for the product.

Skin Contact: irritation, allergic skin reaction

Eye Contact: Causes serious eye irritation

Immediate Effects: skin irritation, serious eye irritation, allergic skin reaction

Delayed Effects: allergic skin reaction

Irritation/Corrosivity: skin irritation, eye irritation

Data
Respiratory: No information available for the product.

Sensitization
Dermal Sensitization: Available data characterizes components of this product as dermal
sensitization hazards.

Germ Cell: No information available for the product.

Mutagenicity
Page 7 of 13Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
Carcinogenicity: No information available for the product.

Reproductive Toxicity: No information available for the product.

Specific Target Organ: No information available for the product.

Toxicity - Single
Exposure
Specific Target Organ: No information available for the product.

Toxicity - Repeated
Exposure
Aspiration Hazard: Not expected to be an aspiration hazard.

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Ecotoxicity: Harmful to aquatic life with long lasting effects.
Hazardous to the Aquatic Environment - Acute Hazard, Category 3
Hazardous to the Aquatic Environment - Long Term Hazard,
Category 3

Ingredient

VALUE

SOURCEFish

0.078-0.108mg/L

2

48

Crustacea

0.7364mg/L

2

EC50

96

Algae or other aquatic plants

0.0054mg/L

2

BCF

360

Algae or other aquatic plants

9mg/L

4NOEC

72

Algae or other aquatic plants>=0.004mg/L

2PolymerizationEC5048

Crustacea

3.53mg/L

2initiator

EC5072

Algae or other aquatic plants>2.01mg/L

2Polymerization

LC5096

Fish

28.5mg/L

2inhibitors

EC5048Crustacea

3mg/L

2EC5072

Algae or other aquatic plants

19mg/L

2NOEC

504

Crustacea

0.68mg/L

2Pigment

ENDPOINTTEST DURATION (HR)LC5096

EC50SPECIESLegend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances –Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - AquaticToxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data
Persistence and: No information available for the product.

Degradability
Page 8 of 13

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

Other Toxicity: No information available for the product.

13. Disposal Considerations
Disposal Methods: Dispose in accordance with all applicable regulations.
Remove the contents completely from the container from thecontainer.
Do not dump this product into sewers, on the ground or into any bodyof water.

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS
GOODS

Air transport (ICAO-IATA / DGR)

: NOT REGULATED FOR TRANSPORT OF DANGEROUS
GOODS

Sea transport (IMDG-Code /: NOT REGULATED FOR TRANSPORT OF DANGEROUS

GGVSee)GOODSTransport in bulk according to: Not Applicable

Annex II of MARPOL and the
IBC code
15. . Regulatory Information
Safety, health and environmental regulations / legislation specific for the substance or mixture
PIGMENT IS FOUND ON THE FOLLOWING REGULATORY LISTS
US - Alaska Limits for Air Contaminants
US - California Permissible Exposure Limits for Chemical Contaminants
US - Hawaii Air Contaminant Limits
US - Massachusetts - Right To Know Listed Chemicals
US - Michigan Exposure Limits for Air Contaminants
US - Minnesota Permissible Exposure Limits (PELs)
US - Oregon Permissible Exposure Limits (Z-1)
Page 9 of 13

Safety Data Sheets

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

US - Pennsylvania - Hazardous Substance ListUS - Rhode Island Hazardous Substance List
US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A
Transitional Limits for Air Contaminants
US - Washington Permissible exposure limits of air contaminants
US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants
US ACGIH Threshold Limit Values (TLV)US ACGIH Threshold Limit Values (TLV) - Carcinogens
US ATSDR Minimal Risk Levels for Hazardous Substances (MRLs)
US EPCRA Section 313 Chemical List
US NIOSH Recommended Exposure Limits (RELs)
US OSHA Permissible Exposure Levels (PELs) - Table Z1
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
POLYMERIZATION INHIBITOR B IS FOUND ON THE FOLLOWING REGULATORY LISTS
US - California Permissible Exposure Limits for Chemical Contaminants
US List of Active Substances Exempt from the TSCA Inventory Notifications (Active-Inactive)
Rule
US NIOSH Recommended Exposure Limits (RELs)
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
ACRYLIC ESTER C IS FOUND ON THE FOLLOWING REGULATORY LISTSInternational Agency for Research on Cancer (IARC) – Agents Classified by the IARCMonographs
US AIHA Workplace Environmental Exposure Levels (WEELs)
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
ACRYLIC ESTER B IS FOUND ON THE FOLLOWING REGULATORY LISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
ACRYLIC ESTER E IS FOUND ON THE FOLLOWING REGULATORY LISTSUS AIHA Workplace Environmental Exposure Levels (WEELs)
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
ACRYLIC ESTER A IS FOUND ON THE FOLLOWING REGULATORY LISTSUS AIHA Workplace Environmental Exposure Levels (WEELs)
Page 10 of 13

Safety Data Sheets

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

US List of Active Substances Exempt from the TSCA Inventory Notifications (Active-Inactive)
Rule
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
POLYMERIZATION INITIATOR IS FOUND ON THE FOLLOWING REGULATORY LISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
POLYMERIZATION INHIBITOR A IS FOUND ON THE FOLLOWING REGULATORY LISTS
US - California Permissible Exposure Limits for Chemical Contaminants
US - Hawaii Air Contaminant Limits
US - Massachusetts - Right To Know Listed Chemicals
US - Michigan Exposure Limits for Air Contaminants
US - Minnesota Permissible Exposure Limits (PELs)US - Pennsylvania - Hazardous Substance List
US - Rhode Island Hazardous Substance List
US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air Contaminants
US - Washington Permissible exposure limits of air contaminants
US ACGIH Threshold Limit Values (TLV)US NIOSH Recommended Exposure Limits (RELs)
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
US TSCA Section 4/12 (b) - Sunset Dates/Status
ANTIOXIDANT A IS FOUND ON THE FOLLOWING REGULATORY LISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
ANTIOXIDANT B IS FOUND ON THE FOLLOWING REGULATORY LISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
Federal Regulations
Superfund Amendments and Reauthorization Act of 1986 (SARA)SECTION 311/312 HAZARD CATEGORIESFlammable (Gases, Aerosols, Liquids, or Solids)No

Gas under pressure

NoExplosive

No
Page 11 of 13

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
Self-heating

No

Pyrophoric (Liquid or Solid)No

Pyrophoric Gas

No

Corrosive to metal

No

Oxidizer (Liquid, Solid or Gas)

No

Organic Peroxide

No

Self-reactive

No

In contact with water emits flammable gas

No

Combustible Dust

No

Carcinogenicity

No

Acute toxicity (any route of exposure)No

Reproductive toxicity

No

Skin Corrosion or Irritation

YesRespiratory or Skin Sensitization

Yes

Serious eye damage or eye irritation

Yes

Specific target organ toxicity (single or repeated exposure)No

Aspiration Hazard

NoGerm cell mutagenicity

NoSimple Asphyxiant

NoUS. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR302.4) : None Reported
State Regulations
California: WARNING

Proposition 65

This product can expose you to chemicals including
Trimethylolpropane triacrylate and Toluene which are known to
the State of California to cause cancer/ birth defects or otherreproductive harm. For more information go towww.P65Warnings.ca.gov.

National Inventory Status
National Inventory

StatusAustralia - AICSY

Canada - DSL

N (Acrylic ester C、Organic component)

Canada - NDSLY

China - IECSC

Y
Page 12 of 13

Product Name: MUH-100 Silver
SDS No. 037-U161891
First issue: 2018/08/08
Revised: 2022/06/03

Safety Data Sheets
Europe - EINEC / ELINCS / NLPYJapan - ENCS

Y

Korea - KECIYNew Zealand - NZIoC

N (Organic component)

Philippines - PICCS

N (Antioxidant B)

USA - TSCAY

Legend: Y = All ingredients are on the inventory
N = Not determined or one or more ingredients are not on the inventory and are notexempt from listing (see specific ingredients in brackets)
16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13