Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets
1.

Identification

Product Name

: SS2 ink White

Order No.

: SPC-0411W-A

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037-S030524

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Eye Damage / Irritation: Category 2

Carcinogenicity: Category 2

Specific Target Organ Toxicity: Category 2 (central nervous system)(Single Exposure)Environmental Hazards
Hazardous to the Aquatic: Category 3

Environment - Acute Hazard
The above list does not include category being non-classifiable or not-applicable.

Page 1 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H227 Combustible liquid
H319 Cause serious eye irritation
H351 Suspected of causing cancer
H371 May cause damage to central nervous system
H402 Harmful to aquatic life
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P260 Do not breathe vapor or mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/clothing and eye/face protection.
[Response]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P337+P313 If eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use appropriate media for extinction.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents and container in accordance with local, regional, national andinternational regulation.
NFPA Rating (scale 0 – 4)
Health = 22

Flammability = 2
Instability = 020

Special = NonePage 2 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets
CANADIAN WHMIS SYMBOLS

3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1Glycol ether solvents

70-80

Trade Secret2Lactone solvent series

10-20

Trade Secret3

Titanium dioxide

1-813463-67-7

4Vinyl resin

1-5

Trade Secret

4.

First Aid Measures

Inhalation: Remove person to fresh air and keep comfortable for breathing. Calla POISON CENTER or doctor/physician.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes. Removecontact lenses, if present and easy to do. Continue rinsing. Get
immediate medical attention.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before re-use. Get medical attention if irritation develops.

Ingestion: If swallowed, get medical attention.

Most Important Symptoms/Effects
Acute: eye irritation, central nervous system damage

Delayed: cancer

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed

Page 3 of 12

Safety Data Sheets
5.

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Fire Fighting Measures

Flammable Properties: Flash point 70.5℃ (TCC)
Auto Ignition Temperature: 169℃
Flammable point : 2.2% to 33.0%

Extinguishing Media: carbon dioxide, regular dry chemical, water spray, alcohol resistantfoam

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

MediaSpecial Hazards Arising: Combustible liquid and vapor.

from the Chemical
Hazardous Combustion: oxides of carbon, oxides of titanium, acid halides

ProductsFire Fighting: Move container from fire area if it can be done without risk. Do notMeasures

scatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stay
away from the ends of tanks. Avoid inhalation of material or
combustion by-products. For fires in cargo or storage area: Coolcontainers with water from unmanned hose holder or monitor
nozzles until well after fire is out. If this is impossible then take thefollowing precautions: Keep unnecessary people away, isolate
hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or
any discoloration of tanks due to fire.

Special Protective: Wear full protective fire fighting gear including self containedEquipment andbreathing apparatus (SCBA) for protection against possible

Precautions forexposure.

Firefighters
6.

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment

Avoid release to the environment.

and Emergency
Procedures
Page 4 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data SheetsMethods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of lowareas.

7.

Handling and Storage

Precautions for Safe

: Obtain special instructions before use. Do not handle until all safety

Handling

precautions have been read and understood. Keep away from heat,sparks, open flame, and hot surfaces - No smoking. Do not breathe
vapor or mist. Avoid contact with eyes, skin and clothing. Do not eat,drink, or smoke when using this product. Wear protective gloves andeye/face protection. Wash thoroughly after handling. Avoid release tothe environment.

Conditions for Safe

: Store and handle in accordance with all current regulations andStorage, including any

standards. Store in a well-ventilated place. Keep container tightly

Incompatibilitiesclosed. Keep cool. Grounding and bonding required. Store locked up.
Keep separated from incompatible substances.

8.

Exposure Controls / Personal Protection

Exposure Limit Values
No1

Chemical Name
Titanium dioxide(13463-67-7)

TWA
ACGIH:

10 mg/m3 TWA

OSHA:

15 mg/m3 TWA (total dust)

Mexico10 mg/m3 TWA LMPE-PPT (as Ti)
20 mg/m3 STEL [LMPE-CT] (as Ti)

Component Biological: There are no biological limit values for the component(s) of thisLimit Values

product.

Page 5 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets
Exposure Controls
Occupational Exposure Controls
Appropriate: Ventilation equipment should be explosion-resistant if explosive

Engineering Controls

concentrations of material are present. Provide local exhaust or
process enclosure ventilation system. Ensure compliance withapplicable exposure limits.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear appropriate chemical resistant gloves.

Eye Protection: Wear splash resistant safety goggles with a faceshield. Provide anemergency eye wash fountain and quick drench shower in theimmediate work area.

Skin Protection

9.

: Wear appropriate chemical resistant clothing.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: WhiteOdor: slight solvent odorpH

: Not available

Boiling Point / Boiling Range: >=176 ℃

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: 70.5℃ (closed cup)
Page 6 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets
Auto ignition temperature: 169℃

Flammability (Solid, Gas)

: Not applicable

Explosive Properties: Not available

Oxidizing Properties: Not available

Upper / Lower Flammability or: 2.2% to 33.0%

Explosive Limits
Vapor Pressure: Less than 133Pa(20℃)

Specific Gravity: 1.01±0.01 (20 ℃)

Solubility: Not available

Water Solubility: Not available

Partition Coefficient (n-octanol / Water): Not available

Viscosity: 4.8±0.3(20°C)

Vapor Density: Not available

Evaporation Rate

: Not available

VOC: 923.1 g/L

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Will not polymerize.

Reactions
Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Containers may
rupture or explode if exposed to heat. Avoid contact with incompatiblematerials.

Incompatible Materials: acids, bases, oxidizing materials, metals, halogens

Hazardous: Combustion: oxides of carbon, oxides of titanium, acid halides

Decomposition
11. Toxicological Information
Acute Toxicity: The component(s) of this material have been reviewed in various

Component Analysis -sources and the following selected endpoints are published:

LD50/LC50
Glycol ether solvents (Proprietary)
Oral LD50 Rat 6500 µL/kg
Page 7 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets
Lactone solvent series (Proprietary)

Oral LD50 Rat 1540 mg/kg; Inhalation LC50 Rat >5100 mg/m3 4 h
Titanium dioxide (13463-67-7)
Oral LD50 Rat >10000 mg/kg
Information on Likely Routes of Exposure
Inhalation: irritation, nausea, headache, drowsiness, dizziness, loss ofcoordination, unconsciousness, coma, cough, cancer

Ingestion: irritation, nausea, headache, drowsiness, dizziness, loss ofcoordination, unconsciousness, coma

Skin Contact: irritation, nausea, headache, drowsiness, dizziness, unconsciousness,
coma

Eye Contact: irritation, eye damage

Immediate Effects: eye irritation, central nervous system damage

Delayed Effects: cancer

Medical Conditions: respiratory disorders

Aggravated by Exposure
Irritation/Corrosivity: eye irritation

DataRespiratory: No information available for the product.

Sensitization
Dermal Sensitization: No information available for the product.

Germ Cell Mutagenicity: No information available for the product.

Carcinogenicity: Component Carcinogenicity
Lactone solvent series (Proprietary)
IARC:

Monograph 71 [1999]; Supplement 7 [1987];
Monograph 11 [1976] (Group 3 (not classifiable))

Titanium dioxide (13463-67-7)
ACGIH:IARC:

A4 - Not Classifiable as a Human Carcinogen
Monograph 93 [2010]; Monograph 47 [1989] (Group2B (possibly carcinogenic to humans))
Category 3A (could be carcinogenic for man,

DFG:inhalable fraction with the exception of ultra smallparticles)

OSHA:

PresentVinyl resin (Proprietary)
IARC:

Supplement 7 [1987]; Monograph 19 [1979] (Group 3Page 8 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data Sheets(not classifiable))
Reproductive Toxicity: No information available for the product.

Specific Target Organ: central nervous system

Toxicity - Single
Exposure
Specific Target Organ: No target organs identified.

Toxicity - RepeatedExposure
Aspiration Hazard: No information available for the product.

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Harmful to aquatic life.

Component Analysis -: Lactone solvent series (Proprietary)

Aquatic Toxicity

Algae:
Invertebrate:

Persistence and72 Hr EC50 Desmodesmus subspicatus: 360 mg/L;
96 Hr EC50 Desmodesmus subspicatus: 79 mg/L
48 Hr EC50 Daphnia magna Straus: >500 mg/L

: Not available

Degradability
Bioaccumulation: Not availableMobility: Not available

Other Toxicity: Not available

13. Disposal Considerations: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Disposal Methods: Dispose in accordance with all applicable regulations.

Component Waste: The U.S. EPA has not published waste numbers for this product'sNumbers

components.

Page 9 of 12

Safety Data Sheets

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
US DOT Information
Shipping: Combustible liquid, n.o.s.

Name(Contains: Glycol ether solvents, Lactone solvent series)

UN Number: NA1993

Hazardous Class: Combustible liquid

Packing Group (PG): III

TDG Information: Not regulated as dangerous goods for transport.

Marine Pollutant: Lactone solvent series (Proprietary)
IBC Code: Category Y
Titanium dioxide (13463-67-7)
IBC Code: Category Z (slurry)

15. Regulatory Information
U.S. Federal: None of this products components are listed under SARA Sections

Regulations

302/304 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4),
TSCA 12(b), or require an OSHA process safety plan.

SARA TitleⅢ: Acute Health: Yes

Section 311/312

Chronic Health: Yes
Fire: Yes
Pressure: No
Reactive: No

Page 10 of 12

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Safety Data SheetsU.S. State Regulations: The following components appear on one or more of the following statehazardous substances lists:

Component

CAS No.

CAMAMN

NJPA

Titanium dioxide

13463-67-7

No

Yes

Yes

Yes

Yes

California Proposition: WARNING:

65

This product can expose you to chemicals including Cadmium
and cadmium compounds, Lead and lead compounds, Mercury
and mercury compounds, Nickel compounds, Titanium dioxide,
Vinyl Chloride, which is known to the State of California tocause cancer/ birth defects or other reproductive harm. For
more information go to www.P65Warnings.ca.gov.

Canada: WHMIS CLASSIFICATION: B3, D2A, D2B.

Canadian WHMIS: None of the product component(s) are listed on the Ingredients

Ingredient Disclosure

Disclosure List (IDL).

List (IDL)
Chemical Inventory: Component Analysis - Inventory

Listings
Component
Glycol ether solvents(Proprietary)
Lactone solvent series(Proprietary)
Titanium dioxide(13463-67-7)
Vinyl resin(Proprietary)

USCA

EU

AU

PHIL

JP

KR

CN

NZ

Yes

NSL

EIN

No

No

Yes

No

Yes

No

Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

Yes

Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

YesYesDSLNo

Yes

Yes

Yes

Yes

Yes

Yes

16. Other Information
Key/Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European RoadTransport; CAS - Chemical Abstracts Service; CLP - Classification, Labelling and Packaging;
EEC - European Economic Community; EIN (EINECS) - European Inventory of Existing
Commercial Chemical Substances; ELN (ELINCS) - European List of Notified Chemical
Page 11 of 12

Safety Data Sheets

Product Name: SS2 ink WhiteSDS No. 037-S030524
First issue: 2009/12/08
Revised: 2019/10/10

Substances; IARC - International Agency for Research on Cancer; IATA - International AirTransport Association; IMDG - International Maritime Dangerous Goods; IBC Code International Bulk Chemical Code; Kow - Octanol/water partition coefficient; LEL - Lower
Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NTP =National Toxicology Program; REACH - Registration, Evaluation, Authorisation and Restrictionof Chemicals; RID - European Rail Transport; STEL - Short-term Exposure Limit; TWA - Time
Weighted Average; UEL - Upper Explosive Limit
Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 12 of 12