Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Safety Data Sheets
1.

Identification

Product Name

: PHT50 Cyan

Order No.

: PHT50-C-60

General Use: Inkjet printing ink

Product Description: Water based pigment ink

SDS Number: 037-W557288

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone: +1 866 928 0789 (within United States only, Toll free)No.

+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Not classified
Environmental Hazards
Not classified
The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolNone
Signal Word
None
Hazard Statements
Page 1 of 8

Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Safety Data Sheets
None

Precautionary Statements[Prevention]
None[Response]
None[Storage]
None[Disposal]
None

3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1Water

65-75

7732-18-5

2Diethylene Glycol

10-20

111-46-6

3Glycerol

1-10

56-81-5

4

Polyurethane resin

1-10

Trade Secret5Copper phthalocyanine

1-10

147-14-8

4.

First Aid Measures

Inhalation: Move victim into fresh air. If breathing is difficult, give oxygen andconsult a physician immediately.

Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes andconsult a physician if feel uncomfortable.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before re-use. If skin irritation or rash occurs: Get medical
advice/attention.

Ingestion: Never give anything by mouth to an unconscious person. Call aphysician or Poison Control Center immediately.

Most Important Symptoms/Effects
Acute: Based on available data, the classification criteria are not met.

Delayed: Based on available data, the classification criteria are not met.

Indication of Immediate: Treat symptomatically. Symptoms may be delayed.

Medical Attention andPage 2 of 8

Safety Data Sheets

Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Special Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash point Not flammable

Extinguishing Media: Use extinguishing media suitable for surrounding area.

Unsuitable Extinguishing: There is no restriction on the type of extinguisher which may beMediaused.

Special Hazards Arising: Development of hazardous combustion gases or vapor possible in thefrom the Chemical

event of fire.

Special Protective: As in any fire, wear self-contained breathing apparatus

Equipment and（MSHA/NIOSH approved or equivalent) and full protective gear.

Precautions forFight fire from a safe distance, with adequate cover.

Firefighters

Prevent fire extinguishing water from contaminating surface wateror the ground water system.

6.

Accidental Release Measures

Personal Precautions,: Use personal protective equipment, do not breathe

Protective Equipment

gas/mist/vapour/spray.

and Emergency

Ensure adequate ventilation. Remove all sources of ignition. Take

Proceduresprecautionary measures against static discharges.
Evacuate personnel to safe areas. Keep people away from and upwindof spill/leak.

Methods and Materials: Cut off the source of the leak as much as possible.

for Containment and

Keep leaks in a ventilated place.

Cleaning Up

Absorb spilled material in dry sand or inert absorbent. In case oflarge amount of spillage, contain a spill by bunding.
Remove all sources of ignition. Use spark-proof tools andexplosion-proof equipment.
Contain spillage, and then collect with an electrically protectedvacuum cleaner or by wet-brushing and place in container.

Environmental: Prevent further leakage or spillage if safe to do so.

precautions

Discharge into the environment must be avoided.

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Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Safety Data Sheets
7.

Handling and Storage

Precautions for Safe

: Handling is performed in a well ventilated place.

Handling

Avoid contact with eyes.
Keep away from heat/sparks/open flames/ hot surfaces.

Conditions for Safe

: Keep containers tightly closed.

Storage, including any

Keep containers in a dry, cool and well-ventilated place.

Incompatibilities

Keep away from heat/sparks/open flames/hot surfaces.
Store away from incompatible materials and foodstuff containers.

8.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical NameACGIH (TLV)

OSHA (PEL)
15 mg/m3 TWA (mist, total particulate)1

Glycerol(56-81-5)

Not established

5 mg/m3 TWA (mist, respirable fraction)(Vacated) 10 mg/m3 TWA (mist, total particulate)(Vacated) 5 mg/m3 TWA (mist, respirable fraction)

Component Biological: No relevant regulations

Limit Values
Exposure Controls
Occupational Exposure Controls
Appropriate: Ensure adequate ventilation, especially in confined areas.

Engineering Controls

Ensure that eyewash stations and safety showers are close to theworkstation location.
Set up emergency exit and necessary risk-elimination area.
Handle in accordance with good industrial hygiene and safety
practice.

Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: Consult with a health and safety professional for specific respirators
appropriate for your use.

Glove: Wear appropriate chemical resistant gloves.
Page 4 of 8Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Safety Data Sheets
Recommendations

Eye /Face: Wear coverall, chemical goggles and face shield when handling.

Protection

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, as appropriate.

9.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: BlueOdor: No information available

pH: 8-10

Boiling Point / Boiling Range: No information available

Melting Point / Melting Range: No information available

Decomposition Temperature: No information available

Flash Point: Not flammable

Auto ignition temperature: No information available

Flammability (Solid, Gas)

: Not flammable

Explosive Properties: No information available

Oxidizing Properties: No information available

Upper / Lower Flammability or: No information available

Explosive Limits
Vapor Pressure
Relative Density: No information available

Solubility: No information available

Water Solubility: No information available

Partition Coefficient (n-octanol / Water): No information available

Viscosity: 3-5mPa・s
Page 5 of 8

Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Safety Data Sheets
Vapor Density: No information available

Evaporation Rate

: No information available

VOC: No information available

10. Stability and Reactivity
Conditions to Avoid: Incompatible materials, heat, flame and spark.

Stability: Stable under proper operation and storage conditions.

Materials to Avoid: Alkali, sodium, calcium, and other active metal, halogen, metal oxide,
nonmetal oxide, acyl halide and metal phosphide. Oxidants, alkali
metals, alkaline earth metals and aluminum.

Hazardous Reactions /: Contact with incompatible substances can cause decomposition orDecomposition Products

other chemical reactions.
In contact with active metals (alkali metals, Na, Ca etc.) causes areaction and release hydrogen. In contact with oxidants causes severereactions, and may cause a fire or explosion.
Under normal conditions of storage and use, hazardous decomposition
products should not be produced.

11. Toxicological Information
Acute Toxicity: Glycerol (56-81-5)
Oral LD50 Rat 12,600 mg/kg
Dermal LD50 Rabbit >10,000 mg/kg

Skin corrosion/irritation: Based on available data, the classification criteria are not met

Serious eye: Based on available data, the classification criteria are not met

damage/irritation
Respiratory: Based on available data, the classification criteria are not met

sensitization
Skin sensitization: Based on available data, the classification criteria are not met

Germ Cell Mutagenicity: Based on available data, the classification criteria are not met

Carcinogenicity: Based on available data, the classification criteria are not met

Reproductive toxicity: Based on available data, the classification criteria are not met

Specific Target Organ: Based on available data, the classification criteria are not met

Toxicity - Single
Exposure
Page 6 of 8

Safety Data Sheets
Specific Target Organ

Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12: Based on available data, the classification criteria are not met

Toxicity - Repeated
Exposure
Aspiration hazard: Based on available data, the classification criteria are not met

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity (Acute: Glycerol (56-81-5)

aquatic toxicity)

LC50 Fish 885mg/L(96h)Copper phthalocyanine (147-14-8)
EC50 Crustaceans >500mg/L(48h)Ecotoxicity (Chronic: No information available.

aquatic toxicity)
Mobility: No information available for the product.

Persistence and: No information available for the product.

Degradability
Bioaccumulative: No information available for the product.

Potential
Other Adverse Effects: No information available for the product.

13. Disposal Considerations: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Waste chemicals: Recommend the use of incineration disposal.

Contaminated: Containers may still present chemical hazard when empty. Keeppackaging

away from hot and ignition source of fire.

14. Transport Information
Check a thing without a leak in a container.
Page 7 of 8

Safety Data Sheets

Product Name: PHT50 CyanSDS No.: 037-W557288
First issue: 2022/12/05
Revised: 2023/05/12

Perform prevention of collapse of cargo surely.
IMDG-CODE: Not regulated as dangerous goods for transport.

IATA-DGR: Not regulated as dangerous goods for transport.

UN-ADR: Not regulated as dangerous goods for transport.

15. Regulatory Information
OSHA Status: This product is not considered to be hazardous under 29 CFR 1910.1200.

TSCA Status: Polyurethane resin (Trade Secret) Yes
Glycerol (56-81-5) Yes
Copper phthalocyanine (147-14-8) Yes

Other regulatory
California Proposition 65: Not regulated under California Proposition 65

16. Other Information
References

1) SDS of raw material
2) IPCS: The International Chemical Safety Cards (ICSC)This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

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