Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets
1.

Identification

Product Name

: IJ Primer PR-200

Order No.

: PR200-Z-22 / PR200-Z-60 / PR200-Z-BA / PR200-Z-B2

General Use: Primer for ink jet printer

Product Description: The undercoating liquid

SDS Number: 037-O060306

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0700

Emergency Telephone No.

: +81-268-64-2281

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Not classified

Substances and Mixtures, which in: Not classified

Contact with Water, Emit Flammable
Gases
Health Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2

Sensitization – Skin

: Category 1

Carcinogenicity: Category 2

Toxic to Reproduction: Category 2

Page 1 of 13Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets
Environmental Hazards
Hazardous to the Aquatic: Category 2

Environment - Acute Hazard
Hazardous to the Aquatic: Category 2

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
Warning
Hazard Statements
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer’s operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing gas/mist/vapours.
P264 Wash hands and eyes thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P321 Specific treatment (see 4-Response on our website/SDS URL:
www.mimaki.co.jp/sds).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
[Storage]
P405 Store locked up.
[Disposal]
Page 2 of 13

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets

P501 Dispose of contents and container in accordance with local, regional, national andinternational regulation (to be specified).

HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 1

1

Flammability= 00 Flammability

Flammability = 0

Reactivity = 00

Instability = 0

Protective Equipment =3.

HealthReactivity
Protective Equipment

Health = 1010

Special =Composition / Information on Ingredients

NoChemical Name

Wt%CAS No.

1

Aliphatic monomer

40-50

Trade Secret

2Acrylic oligomer

25-35

Trade Secret3

Aromatic monomer

15-25

Trade Secret

4

Photo-initiator<10

Trade Secret5

Additives<10

Trade Secret*Acrylic oligomer contains acrylic acid and toluene. And aromatic monomer contains phenyl
glycidyl ether
4.

First Aid Measures

Inhalation: Remove victim to fresh air and keep at rest in a position comfortablefor breathing. Get medical advice/ attention if you feel unwell.
Get medical advice/ attention if experiencing respiratory symptom.
Cover body with blanket to warm and keep at rest. Perform CPR if
not breathing.

Eye Contact: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. Rinse with cleanwater for at least 15 minutes and then seek medical attention ifnecessary. When rinsing, open your eyelids with fingers to insure
saturation of water. Seek medical attention if the problem persists.

Page 3 of 13

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets
Skin Contact: Remove/ Take off all contaminated clothing immediately. Wash withplenty of soap and water. Get immediate medical advice/ attention, ifskin irritation or rash occurs.

Ingestion: Rinse mouth. Do not give an unconscious person anything to drink.
Get immediate medical advice/ attention. If vomiting occurs, leanpatient forward or place on left side (head-down position, if possible)
to maintain open airway and prevent aspiration. Do not induce
vomiting.

Protection To First-Aiders
5.

: Wear appropriate protective equipment if necessary.

Fire Fighting Measures

Flammable Properties: Flash point: Approx 106 ℃

Ignition point: Not available

Flammable point : Not available
Extinguishing Media: Suitable extinguishing media
Fire-extinguishing powder, fire-fighting foam, carbon dioxide, sand,water spray
Unsuitable extinguishing media
High pressure water jet.

Specific hazards arising: When exposed to high temperatures, this product may generatefrom productdangerous decompositions such as nitrogen oxides carbon monoxide,
carbon dioxide, and sulfur dioxide.

Specific extinguish: Cut off the combustion source to the origin of fire and extinguish bymeasuresusing the appropriate fire extinguishing media. Firefighting
measures should be done from windward as much as possible.
Take appropriate measures to disallow substances that may affectthe environment from being dispersed by the drainage. Remove allcontainers possible to a safe place promptly. If not possible toremove, cool down the area. Work from windward and avoid
inhaling any harmful gases. Use respiratory equipment if necessary.

Page 4 of 13

Safety Data Sheets

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Special protective: Cut off the combustion source to the origin of fire and extinguish byequipment andusing extinguishing media. Combustion / Flue gases generateprecautions

carbon monoxide and etc. To avoid the fire from spreading, coolsurrounding area with water spray. Extinguish from windward andavoid inhaling any harmful gases. Use respiratory equipment if
necessary. Extinguish from the windward where the gases do notaccumulate and prevent the leakage from spreading. Wearappropriate protective wear (heat-proof) including air respirators.
Wear respiratory equipment for harmful gases are produced fromcombustion or high temperature.

6.

Accidental Release Measures

Personal Precautions: Avoid breathing gas / mist/vapours. Wear protective equipment(boots, gloves, and glasses) to prevent contact with skin. Remove
ignition sources in the area and work from windward. Clean up
immediately when it spills on the floor or any surface. (The floor
surface becomes slippery). Prohibit entry other than related
personnel. Ventilate released area. Do not touch and/or walk in thespills. The worker wears an appropriate protective equipment, andavoids eyes, the skin contacts, and inhalations. (refer to Section 8)
Provide adequate ventilation if indoors. Cordon off the area andprevent entry of non-related personnel. Work from windward andremove personnel downwind of the area. Wear appropriate
protective equipment to prevent contact with skin and inhaling
fumes. Remove ignition sources in the area promptly. Prepare fire
extinguishing equipment in case of ignition.

Environmental: Avoid releasing to the environment. Collect spillage. Do not empty

precautions

into drain. If it is mixed with wastewater, drain it after the activatedsludge process. Be careful not to influence living organisms andwater quality in the environment by products released into rivers
and any type of body of water. Contact local authorities if it isflowing into rivers or any type of body of water as necessary. Be
careful not to influence the environment by products released intorivers or any type of body of water. If the pollution of water pipes orPage 5 of 13

Safety Data Sheets

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

waterways occur, contact relevant organizations. Clean the area andavoid entry into plumbing system. Be careful not to drain or release
untreated waste water into the environment.
Methods and materials: Contain the flow path with blankets or sand bags and collect into anfor recovery andappropriate container for large spills. Gather and collect into aneutralization

container for small spills. Prevent the inflow into drains, sewer,basement, or enclosed areas. Clean spills frequently as there isdanger of slipping on remnants. Remove all ignition sources.
Smoking, open flame or ignition sources are not allowed in the area.
Contain with consideration to safety. Collect into open container by
absorbing with cloths, rags, sand or etc. and then rinse with plentyof water. Collect what has scattered into a container that can besealed. Clean the spilled area with a cloth or a rag. Wearappropriate protective equipment throughout the process.

7.

Handling and Storage
Relevant regulation shall be subject to where this product will behandled and stored.

Handling: Work in accordance with the Occupational Safety and Health Act andrelated laws and regulations. Keep the concentration below theallowed limit. Avoid inhalation and contact. Wear protection if risk ofexposure occurs. Use only in a well-ventilated area. Avoid smoking,open flames, heat and sources of ignition. Always cleanse with soapand water after handling. Determine proper procedures forcompliance. Seal container after use. Avoid leakage, overflow,
dispersal and generating steam without any good reason. Avoid
improper handling like tipping over, dropping, strong impact to or
dragging the container. Wash hands thoroughly and rinse mouth
after handling. Do not eat, drink or smoke when using this product.
Do not carry contaminated gloves and protective equipment into rest
/ break areas. Prohibit entry to work areas other than related
personnel. Collect used containers in a defined / fixed area. Usecontainers that are not damaged, corroded or cracked. Use local
exhaust ventilation systems indoors work areas. Wear proper
protective equipment to avoid inhalation and contact with eyes andPage 6 of 13

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheetsskin.
Storage: Store in a well-ventilated area. Protect from sunlight (UltraViolet-light). Keep container tightly closed. Keep cool. Store in a darklight-safe area. Do not freeze. Store locked up.

8.

Exposure Controls / Personal Protection

Exposure Limit Values: Not specified

No

Chemical Name

TWA

1

Acrylic compound2

Aromatic compound3

Additives

ACGIH

2ppm

OSHA

10ppm

ACGIH

0.1ppm

ACGIH

2mg/m3(IFV)TWA : Time Weighted Average, IFV : As inhalable fraction and vapor.
Exposure Controls
Occupational Exposure Controls
Engineering Controls: In the case of indoor use, contain at the source or install a local
exhaust system. Provide safety shower and eye / hand wash stations
and identify the area clearly. Contain at the source and install a local
exhaust system if dust is generated.

Personal Protection: Wear following protective equipment as necessary and accordingly.
Inspect equipment on a regular basis by using a protective equipment
maintenance chart.

Respiratory: Supplied air respirator, air/ oxygen breathing apparatus, organic

Protection

vapor gas mask

Hand Protection: Wearing gloves that organic solvents or chemicals do not penetrate ispreferred.

Page 7 of 13

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets
Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: Wearing protective clothing (long sleeve uniform) that organicsolventor the chemical do not infiltrate easily preferred.

Environmental Exposure Controls: Not available
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: YellowOdor: FaintpH: Not Applicable

Boiling Point / Boiling Range: Approx 181℃

Melting Point / Melting Range: Not available

Flash Point: Approx 106℃

Relative Density: Approx 1.1mg/cm3Solubility: Not available

Water Solubility: Not available

Partition Coefficient (n-octanol / Water): Not available

Viscosity: Not available

10. Stability and Reactivity
Reactivity: Decomposes upon heating and produces carbon dioxide and carbon
monoxide.

Conditions to Avoid: Sunlight, heat, open flame, high temperature, sparks, staticelectricity, other sources of ignition.

Stability: Stable under normal conditions.

Materials to Avoid: Incompatible with acid, alkali, amines and is prohibited to mix with.

Page 8 of 13

Safety Data Sheets

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Hazardous Reactions /: Carbon monoxide (CO), carbon dioxide (CO2) gas might be generated

Decomposition Products

by combustion. Vapor from organic solvents.

11. Toxicological Information
Acute Toxicity: ORAL
Aliphatic compound

LD50(rat)： 4890 mg/kg

Acrylic compound

LD50(rat)：>2000 mg/kg

Photo-initiator

LD50(rat)：>2000 mg/kg: DERMAL
Aliphatic compound

LD50(rat)： >5000 mg/kg

Acrylic compound

LD50(rat)：>2000 mg/kg

Photo-initiator

LD50(rat)：>2000 mg/kg

Eye Irritation: Causes severe eye irritation. Category 2 as a product.
This ingredient was reported of mild
ocular irritating property in the eye
Aliphatic compound
irritation tests in the rabbits.
This ingredient was reported of severe
ocular irritating property in the eye
Aromatic compound
irritation tests.

Skin Irritation: Causes moderate skin irritation. Category 2 as a product.
This ingredient was reported ofmoderate ocular irritating property
Aliphatic compoundin the skin irritation tests in therabbits.
This ingredient was reported ofmoderate ocular irritating property
Acrylic compoundin the skin irritation tests in therabbits. (P.I.I:2.0)
This ingredient was reported ofmoderate ocular irritating property
Aromatic compoundin the skin irritation tests.

Skin Sensitization: May cause an allergic skin reaction. Category 1 as a product.

Mutagenicity

Aromatic compound

This ingredient have skin sensitization.

Photo-initiator

This ingredient showed positive by skinsensitization test in guinea pig.

: No information available.

Page 9 of 13

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets
Carcinogenicity: Suspected of causing cancer. Category 2 as a product.
IARC : 2B(Possibly carcinogenic to Humans)
ACGIH : A3
(Confirmed Animal Carcinogen withUnknown Relevance to Humans)
Aromatic compound
EU : 3(Possibly carcinogenic to Humans)
Proposition 65 :Chemical known to cause cancer.

Reproductive and Developmental Toxicity: Suspected of damaging fertility or the unborn child. Category 2 as aproduct.
Aromatic compound

This ingredient suspected of damaging
fertility or the unborn child.
Proposition 65：
Reproductive toxicity substanceSpecific Target Organ Toxicity (Single Exposure): No information available.
Specific Target Organ Toxicity (Repeated Exposure): No information available.
Aspiration hazard: No information available.

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Toxic to aquatic life.
Aliphatic compound

Bioaccumulative
Potential

Eco-toxicity data
Crustacea species : Ceriodaphnia dubia :EC50(48h) 1-10mg/l: No information as a product.
Photo-initiator

No rapidly biodegradable substance.

Additives

No rapidly biodegradable substance.

Page 10 of 13

Safety Data Sheets

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

13. Disposal Considerations: Comply with all USA, national and local regulations. A contaminated container and packing aredisposed of after removing extraneous matter thoroughly. Follow all regulations in your countryor regions.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Use a container provided for in the UN Recommendations on the TDG Model Regulations. Avoid
direct sunlight during transportation. Confirm the container has no damage, corrosion, leakage
before transportation. Take measures to prevent the load from tipping, falling and damages.
Follow all regulations on the transport in your countries regions. Verify the container as no leaks
when transporting and take preventative measure when loading so that the cargo does not tip,
fall or get damaged during transit.
UN Number: 3082

Proper Shipping Name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID
N.O.S(Aliphatic monomer)

Transport hazard: 9 (Miscellaneous dangerous substances & articles)class(es)Packing Group(PG): III

Marine Pollutant: Yes (Product)

Remarks: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is
excepted from Dangerous Goods regulations.
Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.

Page 11 of 13

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

Safety Data Sheets
15. Regulatory Information

Classified and labeling in accordance with OSHA HCS (29CFR 1910,1200), revised in 2012:
See section
TSCA Status:
Chemical name

TSCA INVENTORY

Aliphatic monomer

ListedAcrylic oligomer

No Listed

Aromatic monomer

ListedPhoto-initiator

ListedAdditives

ListedSNUR Components: Not Applicable

Cancerogenity: EPA (Environmental Protection Agency)

categories

II : Toluene
TLV (Threshold Limit Value established by ACGIH)
A3 : Phenyl glycidyl ether
A4 : Acrylic acid, Toluene
NIOSH-Ca (National Institute for Occupational Safety and Health)
Phenyl glycidyl ether

CERCLA Hazardous: Acrylic acid, Toluene

Substances(40 CFR 117, 302)
Section 311/312: None of the ingredient is listed.

(40 CFR 370)
Section 313: Acrylic acid, Toluene(40 CFR 372)
※Acrylic acid and Toluene are not applicable for less than regulation level.
California Proposition 65: WARNING
This product can expose you to chemicals including Phenyl
glycidyl ether and Toluene, which are known to the State ofCalifornia to cause cancer/ birth defects or other reproductive
harm. For more information go to www.P65Warnings.ca.gov.

OthersPlease refer to any other federal, state and local regulations.

Page 12 of 13

Safety Data Sheets

Product Name: IJ Primer PR-200
SDS No. 037-O060306
First issue: 2015/07/23
Revised: 2021/11/17

16. Other Information
References

1) Guide to Occupational Exposure Values (ACGIH 2014)
2) Registry of Toxic Effects of Chemical Substances (CCOHS)
3) SDS published by manufacturer of the productThis information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13