Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
1.

Identification

Product Name

: UV ink LF-200 Yellow

Order No.

: SPC-0591Y-2

General Use: Ink jet printing ink

Product Description: UV curable ink

SDS Number: 037-U051135

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2ASensitization – Skin

: Category 1B

Carcinogenicity: Category 1A

Toxic to Reproduction: Category 2

Specific Target Organ Toxicity: Category 1 (respiratory system)(Repeated Exposure)The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]

Page 1 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
SymbolSignal Word
DangerHazard Statements
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure (respiratorysystem)
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's Operation Manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).
Page 2 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
Hazards not otherwise classified
None.

14% of the mixture consists of ingredients of unknown acute oral toxicity.
NFPA Rating (scale 0 – 4)
Health = 2
1

Flammability = 1
2Reactivity= 11

Special = None

3.

Composition / Information on IngredientsNo

Chemical Name

Wt%CAS No.

1ISOBORNYL ACRYLATE

15-405888-33-5

2PHENOXY ETHYL ACRYLATE

10-3048145-04-6

3TETRAHYDROFURFURYL ACRYLATE

7-132399-48-6

4VINYL MONOMER

7-13

Trade Secret5-1075980-60-8

52,4,6-TRIMETHYLBENZOYLDIPHENYLPHOSPHINE OXIDE

6ALIPHATIC URETHANEACRYLATE

5-10

Trade Secret

7

ACRYLATE MONOMER

3-7

Trade Secret

89H-THIOXANTHEN-9-ONE, 2,4-DIETHYL-

1-582799-44-8

1-568511-62-6

9NICKEL, 5,5'-AZOBIS-2,4,6(1H,3H,5H)PYRIMIDINETRIONE COMPLEXES

10SUBSTITUTED AMINE OLIGOMER

1-5

Trade Secret

11

DISPERSANT

0.1-3

Trade Secret12STABILIZER

0.5-1.5

Trade Secret4.

First Aid Measures

Description of first aid measuresInhalation: Remove person to fresh air. If you are concerned, get medical advice.

Skin Contact: Immediately wash with soap and water. Remove contaminatedclothing and wash before reuse. If signs/symptoms develop,get medical
Page 3 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
attention.
Eye Contact: Immediately flush with large amounts of water. Remove contact lenses
if easy to do. Continue rinsing. Get medicalattention.

If Swallowed: Rinse mouth. If you are concerned, get medical advice.

Most important: See Section 11 Information on toxicological effects.

symptoms and effects,
both acute and delayed
Indication of any: Not applicable.

immediate medical
attention and special
treatment required
5.

Fire Fighting Measures

Suitable extinguishing: In case of fire: Use a fire fighting agent suitable for ordinary

media

combustible material such as water or foam to extinguish.

Special hazards arising: Closed containers exposed to heat from fire may build pressure andfrom the substance orexplode.

mixtureHazardous: Carbon monoxide / During Combustion

Decomposition or

Carbon dioxide / During Combustion

By-Products
Special protective actions: No special protective actions for fire-fighters are anticipated.

for fire-fighters
6.

Accidental Release Measures

Personal precautions,: Evacuate area. Ventilate the area with fresh air. For large spill, or

protective equipment andspills in confined spaces, provide mechanical ventilation to disperse

emergency proceduresor exhaust vapors, in accordance with good industrial hygiene
practice. Refer to other sections of this SDS for information regarding
physical and health hazards, respiratory protection, ventilation, andpersonal protective equipment.

Environmental: Avoid release to the environment. For larger spills, cover drains andprecautions

build dikes to prevent entry into sewer systems or bodies of water.

Methods and material for: Contain spill. Working from around the edges of the spill inward,
Page 4 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05Safety Data Sheetscontainment and cleaning

cover with bentonite, vermiculite, or commercially availableup

inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does notremove a physical, health, or environmental hazard. Collect as muchof the spilled material as possible.
Place in a closed container approved for transportation byappropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate thearea with fresh air. Read and follow safety precautions on the solvent
label and SDS. Seal the container. Dispose of collected material assoon as possible.

7.

Handling and Storage

Precautions for safe

: For industrial or professional use only. Do not handle until all safety

handling

precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or onclothing. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling. Contaminated work clothing should not beallowed out of the workplace.
Avoid release to the environment. Wash contaminated clothing before
reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acidetc.) Use personal protective equipment (gloves, respirators, etc.) asrequired.

Conditions for safe

: Store in a well-ventilated place. Keep container tightly closed tostorage including any

prevent loss of stabilizing materials. Keep cool. Protect from sunlight.

incompatibilities

Store away from heat. Store away from acids. Store away fromoxidizing agents.

Page 5 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
8.

Exposure Controls / Personal Protection

Control parameters
Occupational exposure limits: If a component is disclosed in section 3 but does not appear
in the table below, an occupational exposure limit is notavailable for the component.

Ingredient
VINYL MONOMERTETRAHYDROFUR
FURYL ACRYLATECAS No.

AgencyTrade

Manufacturer

Secretdetermined

2399-48-6

Limit type

Additional
Comments

TWA:0.1 ppm(0.57 mg/m3)

Manufacturer

TWA:0.1 ppm(0.64mg/m3)

determined

STEL:0.3 ppm(1.91mg/m3)

OSHA

TWA(as Ni):1 mg/m3

NICKEL,INSOLUBLE

68511-62-6

COMPOUNDSACGIH: American Conference of Governmental Industrial Hygienists
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure LimitExposure Controls
Occupational Exposure Controls
Engineering Controls: Use general dilution ventilation and/or local exhaust ventilation tocontrol airborne exposures to below relevant Exposure Limits and/or
control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate,
use respiratory protection equipment.

Personal protective equipment (PPE)
Eye/face protection: Select and use eye/face protection to prevent contact based on theresults of an exposure assessment. The following eye/face protection(s)are recommended: Indirect Vented Goggles

Skin/hand: Select and use gloves and/or protective clothing approved to relevant

protection

local standards to prevent skin contact based on the results of anexposure assessment. Selection should be based on use factors such asexposure levels, concentration of the substance or mixture, frequency
and duration, physical challenges such as temperature extremes, andPage 6 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
other use conditions.

Consult with your glove and/or protective clothing manufacturer for
selection of appropriate compatible gloves/protective clothing. Note:
Nitrile gloves may be worn over polymer laminate gloves to improvedexterity. Gloves made from the following material(s) arerecommended: Polymer laminate
If this product is used in a manner that presents a higher potential
for exposure (eg. spraying, high splash potential etc.), then use ofprotective coveralls may be necessary. Select and use body protection
to prevent contact based on the results of an exposure assessment. The
following protective clothing material(s) are recommended: Apron polymer laminate
Respiratory: An exposure assessment may be needed to decide if a respirator isprotection

required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure
assessment, select from the following respirator type(s) to reduce
inhalation exposure: Half facepiece or full facepiece air-purifying
respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult withyour respirator manufacturer.

9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: Yellow color

Odor: Acrylate odor

Odor threshold;: No Data Available

pH: No Data Available

Melting Point: Not Applicable

Boiling Point: > 95 ºC

Flash Point: 95 ºC [Test Method: Closed Cup]

Evaporation Rate

: No Data Available

Flammability (Solid, Gas)

: Not Applicable

Flammable Limits(LEL): No Data Available

Flammable Limits(UEL): No Data Available

Vapor Pressure: No Data Available
Page 7 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
Vapor Density: No Data Available

Density: No Data Available

Specific Gravity: 1.08 [Ref Std: WATER=1]

Solubility In Water: No Data Available

Solubility- non-water: No Data Available

Partition Coefficient (n-octanol / Water): No Data Available

Auto ignition temperature: No Data AvailableDecomposition Temperature: No Data Available

Viscosity: 20 centipoise [@ 25 ºC]

Percent volatile: No Data Available

10. Stability and Reactivity
Reactivity: This material may be reactive with certain agents under certain
conditions - see the remaining headings in this section.

Chemical stability: Stable.

Possibility of hazardous: Hazardous polymerization may occur.

reactions
Conditions to avoid: HeatIncompatible materials: Strong oxidizing agents

Hazardous: None known.

decomposition products
11. Toxicological Information
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following
health effects:Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough,sneezing, nasal discharge, headache, hoarseness, and nose and throat
pain.

Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness,swelling, itching, and dryness. Allergic Skin Reaction (non-photoinduced): Signs/symptoms may include redness, swelling, blistering,and itching.

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant
Page 8 of 12OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets

redness, swelling, pain, tearing, cloudy appearance of the cornea, andimpaired vision.
Ingestion: May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, stomach upset, nausea, vomiting and diarrhea.

Prolonged or repeated: Respiratory Effects: Signs/symptoms may include cough, shortness ofexposure may cause

breath, chest tightness, wheezing, increased heart rate, bluish coloredtarget organ effects

skin (cyanosis), sputum production, changes in lung function tests,
and/or respiratory failure.

Reproductive/Developme: Contains a chemical or chemicals which can cause birth defects or

ntal Toxicity

other reproductive harm.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient

CAS No.

Class Description

NI CMPDS NOT ALLOYS

68511-62-6

Known human carcinogen

NICKEL COMPOUNDS

68511-62-6

Grp. 1: Carcinogenic to humans

Regulation
National Toxicology Program Carcinogens
International Agency for Research onCancer

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Ecotoxicity: Please contact the address or phone number listed on the first page of
the SDS for additional chemical fate information on this materialand/or its components.

Persistence and: Not available

Degradability
Bioaccumulation: Not available

Mobility: Not available

Other Toxicity: Not available

13. Disposal Considerations
Disposal Method: Dispose of contents/ container in accordance with thelocal/regional/national/international regulations.
Page 9 of 12
OSHA 1910.1200 App D Rev. No.2.0

Safety Data Sheets

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Dispose of waste product in a permitted industrial waste facility. As adisposal alternative, incinerate in a permitted waste incineration
facility. Proper destruction may require the use of additional fuelduring incineration processes. Empty drums/barrels/containers usedfor transporting and handling hazardous chemicals (chemicalsubstances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposedof as hazardous wastes unless otherwise defined by applicable waste
regulations. Consult with the respective regulating authorities todetermine the available treatment and disposal facilities.
EPA Hazardous Waste: Not regulated

Number (RCRA)
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Sea Transport (IMDG)Class:9

Packing Group (PG)

: ⅢUN Number: UN 3082

Proper Shipping Name

: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S., (Contains: ISOBORNYL ACRYLATE AND NICKEL,5,5'-AZOBIS-2,4,6(1H,3H,5H)-PYRIMIDINETRIONE COMPLEXES)

Marine Pollutant: YesRemarks: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is
excepted from Dangerous Goods regulations.
Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.

Page 10 of 12
OSHA 1910.1200 App D Rev. No.2.0

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Safety Data Sheets
15. Regulatory Information
TSCA Status: This material contains a chemical which requires export
notification under TSCA Section 12[b]:Ingredient (Category ifapplicable)
9H-THIOXANTHEN-9-ONE,2,4-DIETHYL-CAS No.

Regulation

StatusToxic Substances Control Act
82799-44-8(TSCA) 5 SNUR or Consent OrderApplicableChemicals: This material contains a chemical regulated by an EPA
Significant New Use Rule (TSCA Section 5)

Ingredient (Category if applicable)
9H-THIOXANTHEN-9-ONE, 2,4-DIETHYL-CAS No.
82799-44-8

Reference
40CFR721.9664

SARA Title Ⅲ
Section 311/312 (40 CFR 370)

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 (40 CFR 372)

Ingredient

CAS No.

% by Wt

NICKEL,68511-62-6

1-5

5,5'-AZOBIS-2,4,6(1H,3H,5H)-PY
RIMIDINETRIONECOMPLEXES(NICKELCOMPOUNDS)
California Proposition 65: WARNING
This product can expose you to chemicals including Nickel
compounds and Toluene, which are known to the State ofCalifornia to cause cancer/ birth defects or other reproductive
harm. For more information go to www.P65Warnings.ca.gov.

CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements ofTSCA.
The components of this material are in compliance with the provisions of Japan Industrial
Safety and Health Law. Certain restrictions may apply. Contact the selling division for additional
information.
The components of this material are in compliance with the provisions of Japan Chemical
Page 11 of 12
OSHA 1910.1200 App D Rev. No.2.0

Safety Data Sheets

Product Name: LF-200 Yellow
SDS No. 037-U051135
First issue: 2016/01/06
Revised: 2019/09/05

Substance Control Law. Certain restrictions may apply. Contact the selling division for additional
information.
16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 12 of 12OSHA 1910.1200 App D Rev. No.2.0