Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
1.

Identification

Product Name

: UV ink Black

Order No.

: SPC-0371K-2

General Use: For ink jet

Product Description: UV curable ink

SDS Number: 037-U010377

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2

Carcinogenicity: Category 2

Specific Target Organ Toxicity: Category 3 (respiratory tract irritation)(Single Exposure)Specific Target Organ Toxicity: Category 1(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.

Page 1 of 13

Safety Data Sheets

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H315 Cause skin irritation
H319 Cause serious eye irritation
H335 May cause respiratory irritation
H351 Suspected of causing cancer
H372 Causes damage to organs through prolonged or repeated exposure
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe /gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
[Storage]
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).

Other Information[Hazards not otherwise classified (HNOC)]
Not Applicable
Page 2 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets[Other hazards]• Toxic to aquatic life with long lasting effects• Toxic to aquatic life
[Unknown Acute Toxicity]
82% of the mixture consists of ingredient(s) of unknown toxicity
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 22Flammability= 1

1 Flammability

Flammability = 1

Reactivity = 00Instability = 0

Protective Equipment = X

X Protective Equipment

HealthReactivity

Health = 2
120

Special = -CANADIAN WHMIS SYMBOLS : D2A - Very toxic materials

3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1Monomers

65-75

Trade Secret2

Isooctyl acrylate (structure unspecified)

5-15

29590-42-9

3Photoinitiator

5-10

Trade Secret

1-5119313-12-1

1-Butanone,42-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]2-(phenylmethyl)-

5

Carbon black

1-5

1333-86-4

6

Oligomer

1-5

Trade Secret

7Additives

1-5

Trade Secret8

Copper compounds

0.1-1

Trade Secret

Page 3 of 13

Safety Data Sheets
4.

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

First Aid Measures

General advice: If symptoms persist, call a physician.

Inhalation: Move to fresh air in case of accidental inhalation of vapors. Ifsymptoms persist, call a physician.

Eye Contact: Rinse immediately with plenty of water and seek medical advice.
Remove contact lenses, if present and easy to do. Continue rinsing.
Keep eye wide open while rinsing.

Skin Contact: If skin irritation persists, call a physician. Wash off immediately
with soap and plenty of water. Wash contaminated clothing before
reuse.

Ingestion: If swallowed, call a poison control center or physician immediately.
Do not induce vomiting without medical advice. Never give anythingby mouth to an unconscious person.

Protection To First-Aiders: Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayedSymptoms: Not Available

Indication of any immediate medical attention and special treatment needed
Note to physicians5.

: Treat symptomatically.

Fire Fighting Measures

Flammable Properties: Flash point ; 131 ℃ / 268 °F
Explosion data ; No data available

Extinguishing Media: Dry chemical, CO2, water spray or alcohol-resistant foam.

Unsuitable Extinguishing: Straight streams.

Media
Specific hazards arising: In the event of fire and/or explosion do not breathe fumes. Mayfrom the chemicalcause sensitization by inhalation and skin contact. Thermal
decomposition can lead to release of irritating and toxic gases andvapors.

Page 4 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
Fire Fighting: As in any fire, wear self-contained breathing apparatus

Instructions

pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6.

Accidental Release Measures

Personal Precautions: Use personal protection recommended in Section 8. Avoid contact
with eyes and skin. Keep people away from and upwind of spill/leak.

Environmental: Collect spillage. Prevent entry into waterways, sewers, basements

precautions

or confined areas. Do not flush into surface water or sanitary sewer
system.

Methods for containment: Absorb or cover with dry earth, sand or other non-combustible
material and transfer to containers.

Methods for cleaning up: Use personal protective equipment as required. Soak up with inert
absorbent material. Pick up and transfer to properly labeledcontainers. Clean contaminated surface thoroughly.

7.

Handling and Storage

Handling: Use personal protection recommended in Section 8. Avoid contact
with skin and eyes. Do not breathe gas/mist.

Storage: Keep out of the reach of children. Keep in properly labeled containers.
Keep containers tightly closed in a cool, well-ventilated place. Avoid
direct sunlight or high temperature. Store locked up.

Incompatible materials
8.

: Strong oxidizing agents.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical NameACGIH

OSHA PELNIOSH IDLH
IDLH: 1750 mg/m3

1Carbon black

TWA: 3 mg/m3

TWA: 3.5 mg/m3

TWA: 3.5 mg/m3

inhalable(vacated)

TWA: 0.1 mg/m3 Carbon black infraction

TWA: 3.5 mg/m3presence of Polycyclic aromatichydrocarbons PAH
Page 5 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
2Coppercompounds

TWA: 1 mg/m3
Cu dust and

IDLH: 100 mg/m3 Cu dust andN.E.

mist

mist
TWA: 1 mg/m3 Cu dust and mist

NIOSH IDLH Immediately Dangerous to Life or Health
Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO
v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Exposure Controls
Occupational Exposure Controls
Engineering Controls: Showers
Eyewash stations
Ventilation systems.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Gloves made of plastic or rubber.

Eye Protection: Tight sealing safety goggles. Face protection shield.

Skin Protection: Suitable protective clothing. Apron. Gloves made of plastic or rubber.

General Hygiene Considerations: When using do not eat, drink or smoke. Wash contaminated clothing
before reuse. Regular cleaning of equipment, work area and clothingis recommended. Wash face, hands and any exposed skin thoroughly
after handling.

Page 6 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
Environmental Exposure Controls: Not available
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: BlackOdor: Characteristic odor

Boiling Point / Boiling Range: Not Available

Melting Point / Melting Range: Not Available

Decomposition Temperature: Not Available

Flash Point: 131℃ / 268゜F (Cleveland Open Cup)Auto ignition temperature: Not Available

Upper / Lower Flammability or: Not Available

Explosive Limits
Vapor Pressure: Not Available

Specific Gravity: 1.0-1.1g/cm3 (25 ℃)

Solubility: Not Available

Water Solubility: Immiscible in water

Viscosity: <30 mPa∙s (25 ℃)

VOC: Not Available

10. Stability and Reactivity
Conditions to Avoid: Extremes of temperature and direct sunlight.

Reactivity: No reactivity under the normal usage

Stability: Stable under recommended storage conditions.

Materials to Avoid: Strong oxidizing agents.

Possibility of Hazardous: None under normal processing.

ReactionsDecomposition Products: Thermal decomposition can lead to release of irritating and toxic
gases and vapors.

Page 7 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
11. Toxicological Information
Acute Toxicity: 82% of the mixture consists of ingredient(s) of unknown toxicity
Chemical Name

LD50

LD50

LC50--(structure unspecified)(Rat)

Skin Irritation: Category 2 as a product.

Sensitization: Not Available
Organ

Inhalation> 5 g/kg: Category 2 as a product.

TargetDermalIsooctyl acrylate
Eye Irritation

SpecificOral: Category 3 (respiratory tract irritation) as a product.

Toxicity(Single Exposure)SpecificTarget

Organ: Category 1 as a product.

Toxicity(RepeatedExposure)
Chronic Toxicity: Avoid repeated exposure.

Carcinogenicity: Category 2 as a product. The table below indicates whether eachagency has listed any ingredient as a carcinogen.
Chemical Name

ACGIH

IARC

NTP

OSHA

Carbon black

A3Group 2B-X

ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)Group 2B - Possibly Carcinogenic to Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.

Page 8 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
Ecotoxicity: Toxic to aquatic life with long lasting effects. Toxic to aquatic life.
83% of the mixture consists of component(s) of unknown hazards tothe aquatic environment
Chemical Name
Isooctyl acrylate(structure unspecified)

Persistence andFishCrustaces

0.67: 96 h Pimephales

0.4: 48 h Daphnia

promelas mg/L

magna mg/L

LC50

EC50

: Not Available

Degradability
Bioaccumulative: Not Available

Potential
Other Adverse Effects: Not Available

13. Disposal Considerations: Disposal should be in accordance with applicable regional, national and local laws andregulations.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Us Department of Transportation (DOT)
UN Number: UN3082

Proper Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-))Hazardous Class:9

Packing Group (PG)

: III

Special Provisions: 8, 146, 173, 335, IB3, T4, TP1, TP29

Marine pollutant: Not Applicable

Emergency Response: 171

Guide Number

Page 9 of 13

Safety Data Sheets
DescriptionProduct Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12: UN3082, Environmentally hazardous substance, liquid, n.o.s.
(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-)),
9, IIITDG
UN Number: UN3082

Proper Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-))Hazardous Class:9Packing Group (PG)

: IIISpecial Provisions: noneMarine pollutant: Not regulated

Description: UN3082, Environmentally hazardous substance, liquid, n.o.s.
(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-)),
9, IIIMEX
UN Number: UN3082

Proper Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-))Hazardous Class:9

Special Provisions: nonePacking Group (PG)

: III

Description: UN3082, Environmentally hazardous substance, liquid, n.o.s.
(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-)),
9, IIIIATA
UN Number: UN3082

Proper Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-))Hazardous Class:9

Packing Group (PG)

: III
Page 10 of 13

Safety Data Sheets

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

ERG Code: 9L

Special Provisions: A97, A158

Description: UN3082, Environmentally hazardous substance, liquid, n.o.s.
(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-)),
9, IIISea Transport (IMDG)
UN Number: UN3082

Proper Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-))Hazardous Class:9Packing Group (PG)

: III

EmS-No.

: F-A, S-F

Special Provisions: 274, 335

Marine Pollutant: This material meets the definition of a marine pollutant

Description: UN3082, Environmentally hazardous substance, liquid, n.o.s.
(Isooctyl acrylate, 1-Butanone,2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-)),
9, III

Environmental hazard
Remarks: Yes: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is
excepted from Dangerous Goods regulations.
Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.

15. Regulatory Information
U.S. Federal Regulations
CERCLA: This material, as supplied, does not contain any substances regulated

Reportable Quantity

as hazardous substances under the Comprehensive Environmental(40 CFR 302)

Response Compensation and Liability Act (CERCLA) (40 CFR 302) or
the Superfund Amendments and Reauthorization Act (SARA) (40CFR 355). There may be specific reporting requirements at the local,regional, or state level pertaining to releases of this material

Page 11 of 13

Product Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12

Safety Data Sheets
SARA TitleⅢ
Section 311/312: Acute health hazard

Yes(40 CFR 370)

Chronic Health Hazard

NoFire hazard

NoSudden release of pressure hazard No
Reactive Hazard

NoSection 313: Section 313 of Title III of the Superfund Amendments and(40 CFR 372)

Reauthorization Act of 1986 (SARA). This product does not containany chemicals which are subject to the reporting requirements of theAct and Title 40 of the Code of Federal Regulations, Part 372

CWA (Clean Water Act): This product does not contain any substances regulated as pollutants
pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

U.S. State Regulations
California Proposition: WARNING65

This product can expose you to chemicals including
Benz[a]anthracene, Benzo[a]pyrene, Benzo[j]fluoranthene,
Benzo[k]fluoranthene, Carbon black, Dibenz[a,h]anthracene,
Naphthalene, Toluene, which are known to the State ofCalifornia to cause cancer/birth defects or other reproductive
harm. For more information go to www.P65Warnings.ca.gov.
Chemical Name

California Proposition 65

Carbon black

Carcinogen(1333-86-4)
U.S.State: This product contains substances regulated by state right-to-know

Right-to-Know

regulations.

Regulations
Chemical NameNew Jersey

Massachusetts

Pennsylvania

XXXCarbon black(1333-86-4)
U.S.EPA Label Information
EPA Pesticide: Not ApplicableRegistration Number

Page 12 of 13

Safety Data Sheets
CanadaProduct Name: UV ink BlackSDS No. 037-U010377
First issue: 2008/06/20
Revised: 2019/11/12: This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the SDS
contains all the information required by the CPR

WHMIS Hazard Class: D2A - Very toxic materials

Others: Please refer to any other federal, state and local regulations.

16. Other Information
References1) LOLI Database (ChemADVISOR, Inc.)
2) Japan National Institute of Technology and Evaluation
3) EU CLP(1272/2008)Annex VI Table 3.1

This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13