Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:

Safety Data Sheets
1.

Identification

Product Name

: Flushing Liquid 04

Item No.

: MP-M019269 / MP-M019271

General Use: Washing liquid of ink

Product Description: Aqueous liquid

SDS Number: 037-C201535

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0100

Emergency Telephone No.

: +81-268-64-2281

2.

Hazards Identification〔GHS Classification〕
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Acute Toxicity – Oral

: Not classified

Skin Corrosion / Irritation: Not classified

Eye Damage / Irritation: Not classified

Sensitization – Skin

: Category 1

Toxic to Reproduction: Category 2

Specific Target Organ Toxicity: Category 1 (kidney, liver)(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.
〔GHS Label Elements〕

Page 1 of 9Safety Data Sheets

Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:SymbolSignal Word
DangerHazard Statements
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure (kidney, liver).
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's Operation Manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe gas/mist/vapors.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).

Page 2 of 9

Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:

Safety Data Sheets3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1

Alcohol derivative

40-50%

Trade Secret2

Glycerols

10-20%

Trade Secret3

Waterbalance7732-18-5

4.

First Aid Measures

Inhalation: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor/physician.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing. Get immediate medical attention.

Skin Contact: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical advice/attention. Take off contaminated clothing andwash before re-use.

Ingestion: If swallowed, get medical attention.

Most Important Symptoms/Effects
Acute: allergic skin reaction.

Delayed: allergic skin reaction, kidney damage, liver damage

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Not flammable under normal condition.

Extinguishing Media: Dry chemical or carbon dioxide.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

Media
Hazardous Combustion: Combustion: Irritant gas, carbon monoxide

Products
Fire Fighting Measures: Move container from fire area if it can be done without risk.
Page 3 of 9Safety Data Sheets

Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:Do not scatter spilled material with high-pressure water streams.
Cool containers with water spray until well after the fire is out.
Stay away from the ends of tanks. Avoid inhalation of material or
combustion by-products.
Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible exposure.

Precautions forFirefighters
6.

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment

Avoid release to the environment.

and Emergency
Procedures
Methods and Materials: Eliminate all ignition sources if safe to do so.

for Containment andStop leak if possible without personal risk. Reduce vapors withCleaning Up

water spray.
Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of lowareas.

7.

Handling and Storage

Precautions for Safe

: Avoid breathing dust, mist, fumes or vapors.

Handling

Avoid contact with eyes, skin and clothing. Do not eat, drink, orsmoke when using this product.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of theworkplace.

Conditions for Safe

: Store and handle in accordance with all current regulations andStorage, including anystandards.

Incompatibilities

Store in a well-ventilated place. Keep container tightly closed.
Page 4 of 9Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:

Safety Data Sheets

Keep cool. Keep separated from incompatible substances.
8.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical Name

1

Glycerols

TWA

STEL

Ceiling

Skin

SEN

OSHA PEL

15mg/㎥

N.E.

N.E.

N.E.

N.E.

ACGIH TLV

10mg/㎥

N.E.

N.E.

N.E.

N.E.

Exposure Controls
Occupational Exposure Controls
Engineering Controls: Not special measures required.

Personal Protection
Respiratory: Not required under suitable use as setting the cartridge on theProtection

printer; however, self-contained breathing apparatus or organic
canister mask is sufficient when used for work.

Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear appropriate chemical resistant gloves.

Eye Protection: Wear splash resistant safety goggles with a faceshield. Provide an
emergency eye wash fountain and quick drench shower in theimmediate work area.

Skin Protection: Wear appropriate chemical resistant clothing.

Environmental Exposure Controls: Not established.

Page 5 of 9Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:

Safety Data Sheets
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: ClearOdor: Slight odorpH

: 7-10 (25 degree C)

Boiling Point / Boiling Range: No data available

Melting Point / Melting Range: No data available

Flash Point: Not detected until 100 degree C(closed cup, ASTM D3278)

Relative Density: about 1.10(25 degree C)

Solubility: No data available

Water Solubility: Complete

Viscosity: 9-10 mPa・s (25 degree C)

VOC: 496.1 g/l

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Will not polymerize.

Reactions
Conditions to Avoid: Avoid contact with incompatible materials.

Incompatible Materials: Acid, oxidizing agents

Hazardous Reactions /: Combustion: Irritant gas, carbon monoxide.

Decomposition Products
11. Toxicological Information
Acute Toxicity
Component Analysis LD50/LC50: Alcohol derivative
Oral (rat) LD50 ; 12,565mg/kg
Dermal (rabbit) LD50 ; 11,890mg/kg
Glycerols
Oral (rat) LD50 ; 12,600mg/kg
Dermal (rabbit) LD50 ; 10,000mg/kg
Page 6 of 9

Safety Data Sheets

Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:Inhalation LC50 Rat >570 mg/m3 1 h
Immediate Effects: allergic skin reaction.

Delayed Effects: allergic skin reaction, kidney damage, liver damage

Irritation/Corrosivity: No information available for the product.

Data
Respiratory: No information available for the product.

Sensitization
Dermal Sensitization: May cause an allergic skin reaction.

Germ Cell: No information available for the product.

Mutagenicity
Carcinogenicity
Component Carcinogenicity: No data listed by ACGIH, IARC, NTP, DFG or OSHA is available forthe component(s) of this product.
Reproductive Toxicity: Suspected of damaging fertility or the unborn child.

Specific Target Organ: No target organs identified.

Toxicity - Single
Exposure
Specific Target Organ: kidney, liver

Toxicity - Repeated
Exposure
Aspiration Hazard: Not expected to be an aspiration hazard.

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Component Analysis -: Alcohol derivative

Aquatic Toxicity

Fish: 96 Hr LC50 Pimephales promelas: 75200 mg/L [flow-through];
Invertebrate: 48 Hr EC50 Daphnia magna: 84000 mg/L
Glycerols
Fish: 96 Hr LC50 Oncorhynchus mykiss: 51 - 57 mL/L [static]

Persistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.
Page 7 of 9Safety Data Sheets
Other Toxicity

Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:: No additional information is available.

13. Disposal Considerations
Disposal Methods: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Us Department of Transportation (DOT)
Hazardous Materials: Not Applicable

Sea Transport (IMDG)Class: Not Applicable

Packing Group (PG)

: Not Applicable

UN Number: Not Applicable

Proper Shipping Name

: Not Applicable

Marine Pollutant: Not Applicable

Air Transport (ICAO/IATA)Class: Not Applicable

Packing Group(PG): Not Applicable

UN Number: Not Applicable

Proper Shipping Name

: Not Applicable

Page 8 of 9

Product Name: Flushing Liquid 04
SDS No. 037-C201535
First issue: 2016/11/17
Revised:

Safety Data Sheets
15. Regulatory Information
OSHA Hazardous: This material is considered hazardous.

Components(29 CFR 1910. 1200)
TSCA Section 4(a) Final: Not regulated.

Test Rules Regulated
TSCA Section 8(a): Not regulated.

Preliminary Assessment
Information Rule(PAIR)
TSCA Section12(b): Not regulated.

One-Time Export
Notification Regulated
California Proposition 65: Not regulated.

U.S. State Regulations
The following components appear on one or more of the following state hazardous substances
lists:
ComponentCASCAMA

MN

NJPA

Alcohol derivative

Trade SecretNo

No

Yes

NoYes

Glycerols

Trade SecretNo

Yes

Yes

Yes

Yes

Chemical Inventory Listings
Component Analysis – Inventory
Component

USCAEUAUPHILJPKR

CNNZ

Alcohol derivative

Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

Yes

Glycerols

Yes

DSL

EINYes

Yes

Yes

Yes

Yes

Yes

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.
Page 9 of 9