Material Safety Data Sheets
Sheets1.

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 1 of 11

Product and Company
Company Identification

Product Name

: Pigment Ink For Textile Cyan

Product Code: SPC-0350C

General Use: Ink jet printing ink

Product Description: Pigment ink

MSDS Number: 031-33W03CC

Manufacture
Company Name

: Mimaki Engineering Co., Ltd

Address: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 Japan

Telephone No.

: +81-268-64-2413

Importer/Distributor Established in USA
Company Name

: MIMAKI USA. INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.ATelephone No.

: 1-678-730-0100

Emergency Telephone No.

: +81-268-64-2413

2.

Hazards Identification

Emergency Overview: Inhalation of vapor or mist can cause headache, nausea andirritation of the nose, throat and lungs.
Causes severe eye irritation.
Prolonged or repeated overexposure to the solvent(s) in this material
can cause the following:
liver damage, kidney damage, embryofetotoxic effects
Prolonged or repeated overexposure to carbon black can cause lungeffects.

Potential Health Effects
Inhalation: Inhalation of solvent vapor or mist can cause the following:
irritation of nose, throat, and lungs
headache, nausea

Eye Contact: Direct contact with material can cause the following:
Severe irritation, tearing, reddening

Skin Contact: Material can cause the following:slight irritation

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 2 of 11

Material Safety Data Sheets
SheetsIngestion: Material is possibly harmful if swallowed.
Material can cause the following:
Abdominal pain, Vomiting, nausea, depression,diarrhea, gastrointestinal irritation, dizziness

Carcinogens: Prolonged or repeated overexposure to carbon black can cause lungeffects.
C.I. Pigment Blue 15
IRIS: Not classified.

Potential Environmental: Prolonged or repeated overexposure to the solvent(s) in this material

Effects

can cause the following:kidney damage, liver damage

Medical conditions: No medical conditions are known to be aggravated by exposure toSPC-0350C INK.

HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 2*

Health =Flammability= 0

Flammability =Reactivity = 0

Instability =Special =Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 3 of 11

Material Safety Data Sheets
Sheets3.

Composition / Information On Ingredients
ChemicalNo

Chemical Name

Wt%

CAS No.

1

Acrylic polymer(s)5.0-7.0%

Not Hazardous

Trade Secret

2C.I. Pigment Blue 15

2.0-4.0%

147-14-8

Trade Secret3

Residual monomers<100.0 PPM

Not Required

C32H16CuN84Glycols

11.0-13.0%

Trade SecretTrade Secret

5Pyrrolidone

7.0-9.0%616-45-5

C4H7NO

6

Anionic / nonionic surfactant(s)2.0-4.0%

Trade SecretTrade Secret

7Water

64.0-67.0%

7732-18-5

H2O

Formula

OSHA Hazardous:This product is considered hazardous under the OSHA Hazard

Components

Communication Standard (29 CFR 1910.1200).

(29 CFR 1910. 1200)

4.

First Aid Measures
Measures
Inhalation: Move to fresh air. Give artificial respiration if breathing has
stopped. Consult a physician.

Eye Contact: Immediately flush eye(s) with plenty of water. Get prompt medicalattention.

Skin Contact: Wash with water and soap as a precaution. If skin irritation
persists, call a physician. Wash contaminated clothing before reuse.

Ingestion: Drink 1 or 2 glasses of water. Consult a physician. Never give
anything by mouth to an unconscious person. If vomiting occurs
spontaneously, keep airway clear.

Note To Physician: Treatment may vary with condition of victim and specifics ofincident.

5.

Fire Fighting Measures
Measures
Flammable Properties

Flash point: Noncombustible
Lower explosion limit: Not applicableMaterial Safety Data Sheets
Sheets

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 4 of 11Upper explosion limit: Not applicable
ThermalCombustion generates toxic fumes of the following:, nitrogen oxides

decomposition(NOx), Carbon oxides, sulfur oxides.

Extinguishing Media: Use the following extinguishing media when fighting fires involving
this material:polar solvent (alcohol) foam
Water spray
Dry chemical
Carbon dioxide (CO2)Fire Fighting: Wear full fire-fighting turn-out gear (full bunker gear) andInstructions

respiratory protection (self-contained breathing apparatus).
Evacuate area and fight fire from a safe distance. Containers canrupture and release highly toxic vapors or decomposition products if
exposed to heat. Dried product can burn. Material can splatter above
100C/212F.

Further information:Remain upwind.
Avoid breathing smoke.
Use water spray to cool unopened containers.

6.

Accidental Release Measures
Measures

METHODS: Contain spilled liquid with sand or earth. DO NOT use combustible

FOR CLEANING UP

materials, such as sawdust.
Eliminate all ignition sources, use explosion-proof equipment.
Vacuum or sweep material and place in a disposal container.
The material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems
and bodies of water.

HANDLING: Avoid contact with skin, eyes and clothing.
Do not breathe (dust, vapor, mist, gas).
Wash thoroughly after handling.
Use only clean, dry utensils in handling.
Keep container tightly closed. Store in a cool, dry, well ventilated
place.
Destroy contaminated shoes in proper manner.

Material Safety Data Sheets
Sheets
STORAGE

Product Name：Pigment Ink
For Textile CyanMSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 5 of 11: Solidifies at about 5 - 25 °C (41 - 77 °F) and may break container.
Keep from freezing - product stability may be affected.

SPECIFIC USES

: Formaldehyde will be generated under acidic conditions. Maintainadequate ventilation under these conditions to prevent exposure toformaldehyde above ceiling of 0.3 ppm.

FURTHER: Monomer vapors can be evolved when material is heated during

INFORMATION

processing operations. See SECTION 8, for types of ventilation
required.
Improper disposal or re-use of this container may be dangerous andillegal. Refer to applicable local, state and federal regulations.
Dispose empty container in a sanitary landfill or by incineration asallowed by state and local authorities.

7.

Handling And
And Storage

HANDLING: Avoid contact with skin, eyes and clothing.
Do not breathe (dust, vapor, mist, gas).
Wash thoroughly after handling.
Use only clean, dry utensils in handling.
Keep container tightly closed. Store in a cool, dry, well ventilatedplace.
Destroy contaminated shoes in proper manner.

STORAGE: Solidifies at about 5 - 25 °C (41 - 77 °F) and may break container.
Keep from freezing - product stability may be affected.

SPECIFIC USES

: Formaldehyde will be generated under acidic conditions. Maintainadequate ventilation under these conditions to prevent exposure toformaldehyde above ceiling of 0.3 ppm.

FURTHER: Monomer vapors can be evolved when material is heated during

INFORMATION

processing operations. See SECTION 8, for types of ventilation
required.
Improper disposal or re-use of this container may be dangerous andillegal. Refer to applicable local, state and federal regulations.
Dispose empty container in a sanitary landfill or by incineration asallowed by state and local authorities.

8.

Exposure Controls / Personal Protection

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 6 of 11

Material Safety Data Sheets
SheetsExposure Limit Values
No

Chemical Name
OSHA PEL

1

Modified Carbon
black

ACGIH
TLV
NIOSH/GUIDEOSHA PEL

2Glycols

ACGIH
TLV
OSHA PEL

Pyrrolidone

ACGIH
TLV

TWA

STEL

Ceiling

Skin

REL3.5 mg/m3

N.E

N.E

N.E

N.E

3.5 mg/m3

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

1mg/m3

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

Exposure Controls
Occupational Exposure Controls
Engineering: Use local exhaust ventilation with a minimum capture velocity of 100

Controls

ft/min. (0.5 m/sec.) at the point of vapor evolution. Refer to the current
edition of Industrial Ventilation: A Manual of Recommended Practice
published by the American Conference of Governmental Industrial
Hygienists for information on the design, installation, use, andmaintenance of exhaust systems.

Personal Protection
Respiratory: A respiratory protection program meeting OSHA 1910.134 and ANSI

Protection

Z88.2 requirements or equivalent must be followed wheneverworkplace conditions warrant a respirator's use. None required if
airborne concentrations are maintained below the exposure limit
listed in Exposure Limit Information. Up to 10 times the exposure
limit: Wear a properly fitted NIOSH approved (or equivalent)
half-mask, air-purifying respirator. Up to 1000 ppm organic vapor:
Wear a properly fitted NIOSH approved (or equivalent) full-facepiece,
air-purifying respirator, OR full-facepiece, airline respirator in thepressure demand mode. Above 1000 ppm organic vapor or Unknown:
Wear a properly fitted NIOSH approved (or equivalent) self-containedMaterial Safety Data Sheets
Sheets

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 7 of 11

breathing appartus in the pressure demand mode, OR full-facepiece,
airline respirator in the pressure demand mode with emergency
escape provision. Air-purifying respirators should be equipped with
NIOSH approved (or equivalent) organic vapor cartridges and R95 orP95 filters.

Hand Protection

Chemical-resistant gloves should be worn whenever this material ishandled. The glove(s) listed below may provide protection against
permeation. (Gloves of other chemically resistant materials may notprovide adequate protection): Neoprene gloves Gloves should beremoved and replaced immediately if there is any indication ofdegradation or chemical breakthrough. Rinse and remove gloves
immediately after use. Wash hands with soap and water.
Eye Protection

Wear coverall, chemical goggles and face shield when handling.
Skin Protection

To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, as appropriate.
Environmental Exposure Controls: Not available

Material Safety Data Sheets
Sheets9.

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 8 of 11

Physical And
And Chemical Properties

Appearance- Physical state: liquid- Colour: Blue-greenOdour: mildpH: 7.5 - 9.5

Boiling Point / Boiling Range: 100 °C ( 212.00 °F) Water

Melting Point / Merting Range: Not available

Decomposition Temperature: Not available

Flash Point: Noncombustible

Auto-Ignition Temperature: Not available

Flammability(solid, gas)

: Not available

Vapour Pressure: 17.0 mmHg at 20 °C (68 °F) Water

Specific Gravity: 0.95 - 1.05

Solubility: Not available

Water solubility: Dilutable

Viscosity: 2.500 - 4.000 mPa.s

Vapour density: <1.0Water

Evaporation Rate

: <1.00 Water

VOC: 14.0g/l

10. Stability
tability And Reactivity
Reactivity
Conditions To Avoid: Thermal decomposition may yield acrylic monomers.

Stability: Product will not undergo polymerization.

Materials To Avoid: Avoid contact with acids, alkalies and strong oxidizing agents.

Hazardous Reactions/: This material is considered stable.

Decomposition Products

However, avoid temperatures above 177C/350F, the onset of polymer
decomposition. Thermal decomposition is dependent on time andtemperature.

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007Revised：Jun 13, 2008
Page 9 of 11

Material Safety Data Sheets
Sheets
11. Toxicologocal Information
Acute Toxicity

Component: Glycols
Oral LD50

Dermal LD50

>10,000 mg/kg(rat)>10,000 mg/kg(rabbit)

Inhalant LC50

Component: C.I. Pigment Blue 15
Oral LD50

Dermal LD50

Inhalant LC50

> 5,000 mg/kg(rat)
Eye Irritation: Not available

Skin Irritation: rabbit slight irritation

Sensitization: Patch test on human volunteers did not demonstrate sensitization
properties.

Mutagenicity: Not available

Carcinogenicity: Not available

12. Ecological InformationInformation
Handling is noted because it might influence the environment
when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground,
the river, and the drain ditch.
Ecotoxicity: Toxicity to fish
LC50 100 mg/l
Toxicity to aquatic invertebrates
EC50 Daphnia magna 100 mg/l

Persistence And: Not available

Degradability
Bioaccumulative Potential: Not available

Other Adverse Effects: Not available

13. Disposal Considerations
Considerations: When a decision is made to discard this material as supplied, it doesMaterial Safety Data Sheets
Sheets

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 10 of 11

not meet RCRA's characteristic definition of ignitability, corrosivity, orreactivity, and is not listed in 40 CFR 261.33. The toxicity
characteristic (TC), however, has not been evaluated by the Toxicity
Characteristic Leaching Procedure (TCLP).
Incinerate liquid and contaminated solids in accordance with local,state, and federal regulations.
Comply with all EU, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Class/UN Number: Not applicable
DOT, IMO/IMDG : Not applicable

15. Regulatory Information
OSHA Status: This product is considered hazardous under the OSHA Hazard
Communication Standard (29 CFR 1910.1200).

TSCA Status: All components of this product are in compliance with the inventory
listing requirements of the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

Cercle Reportable: Not Applicable

Quantity(40 CFR 117, 302)
SARA TitleⅢSection 302: Releases of this material to air, land, or water are not reportable to(40 CFR 355)

the National Response Center under the Comprehensive
Environmental Response, Compensation, and Liability Act (CERCLA)or to state and local emergency planning committees under theSuperfund Amendments and Reauthorization Act (SARA) Title III
Section 304.

Product Name：Pigment Ink
For Textile Cyan
MSDS No. 031-33W03CC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 11 of 11

Material Safety Data Sheets
SheetsSection 311/312: Acute Health Hazard(40 CFR 370)
Section 313: This product does not contain a chemical which is listed in Section(40 CFR 372)

313 at or above de minimis concentrations.

Pennsylvania: The following chemicals are listed because of the additional
requirements of Pennsylvania law:
Components:
Formaldehyde
Any material listed as "Not Hazardous" in the CAS REG NO. columnof SECTION 3, Composition/Information On Ingredients, of thisMSDS is a trade secret under the provisions of the Pennsylvania
Worker and Community Right-to-Know Act.

California: This product contains trace levels of a component or components(Proposition 65)

known to the state of California to cause cancer:
Components:

OthersEthyl acrylate

140-88-5

Formaldehyde

50-00-0: This product is a 'controlled product' under the Canadian Workplace
Hazardous Materials Information System (WHMIS).
Please refer to any other federal, state and local regulations.

16. Other Information
Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and dose not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.
Revision history
VersionDate

Content

1.00

Oct 18, 2007

First issue

2.00

Jun 13, 2008

No.9 VOC