Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 1 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

1. PRODUCT AND COMPANY IDENTIFICATION
Product Name

: Reactive Dye Ink Rc210 Blue

Product Code: SPC-0702BL-1

General Use: Ink Jet Ink

Product Description: Ink Jet Ink

MSDS Number: 031-36W19BP

Manufacture
Company Name

: Mimaki Engineering Co., Ltd

Address: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 JapanTelephone No.

: +81-268-64-2413

Importer/Distributor Established in USA
Company Name

: MIMAKI USA. INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.ATelephone No.

: +1-678-730-0170

Emergency Telephone No.

: +81-268-64-2281

2. HAZARDS IDENTIFICATIONWARNING!

Emergency Overview
Irritating to eyes
May be harmful if swallowed, inhaled, or absorbed through skin
Mist or aerosol may be irritating to eyes, nose, throat, and lungs
May cause central nervous system depression

Appearance Blue

Physical State

Liquid.

Potential Health Effects
Principle Routes of Exposure

Inhalation. Skin contact. Eye contact.

Acute Toxicity
Eyes

Irritating to eyes.

Odor SpecificProduct Name: Reactive Dye Ink Rc210 Blue

Material Safety Data Sheets

MSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 2 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
Skin

May cause irritation. May be harmful if absorbed through skin.

Inhalation

May be harmful if inhaled. Inhalation of aerosols: May cause irritation of respiratory
tract. May cause central nervous system depression with nausea, headache,dizziness, vomiting, and incoordination.

Ingestion

May be harmful if swallowed. May cause adverse liver effects. May cause adverse
kidney effects. May cause additional affects as listed under "Inhalation".

Chronic Effects

May cause adverse liver and kidney effects. May cause central nervous systemdepression. Contains materials which based on animal tests may cause adverse
reproductive and birth effects at maternally toxic levels.

Main Symptoms

Symptoms of overexposure may be headache, dizziness, tiredness, nausea andvomiting.

Aggravated Medical

Central nervous system. Pre-existing eye disorders. Respiratory disorders.

Conditions

Interactions with Other Chemicals

Use of alcoholic beverages may enhance toxic effects.

Environmental Hazard

See Section 12 for additional Ecological Information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name

CAS-NoWeight %Water

7732-18-5

40-50

Diglycerin

59113-36-915-25Ethylene glycol

107-21-1

15-25

Reactive Dye

Trade Secret

10-20

Additives

Trade Secret<5Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 3 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

4. FIRST AID MEASURES

General Advice

If symptoms persist, call a physician.

Eye Contact

Immediately flush with plenty of water.

After initial flushing, remove any contactlenses and continue flushing for at least 15 minutes. Keep eye wide open while
rinsing. If symptoms persist, call a physician.

Skin Contact

Wash off immediately with soap and plenty of water. If symptoms persist, call aphysician.

Inhalation

IF INHALED: Remove to fresh air and keep at rest in a position comfortable forbreathing. If breathing has stopped, contact emergency medical services
immediately.

Ingestion

Call a physician or Poison Control Center immediately. Clean mouth with waterand afterwards drink plenty of water. Do not induce vomiting without medicaladvice.

Notes to Physician

Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flammable Properties

Combustible material: may burn but does not ignite readily.

Flash Point

Not determined.

Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and thesurrounding environment.

Explosion Data
Sensitivity to Mechanical Impact

None

Sensitivity to Static Discharge

NoneProduct Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 4 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
Protective Equipment andAs in any fire, wear self-contained breathing apparatus pressure-demand,

Precautions for Firefighters

MSHA/NIOSH (approved or equivalent) and full protective gear.

NFPA

Health Hazard 2Flammability 1Instability 0

Physical and ChemicalHazards -HMIS

Health Hazard 2*

Flammability 1

Physical Hazard 0

Personal Protection -*Indicates a chronic health hazard.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions

Wear protective gloves/clothing and eye/face protection. Ensure adequate
ventilation. Avoid contact with the skin and the eyes.

Environmental Precautions

Prevent entry into waterways, sewers, basements or confined areas. Do not flush
into surface water or sanitary sewer system.

Methods for Containment

Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up

For spills: Absorb with inert absorbent materials such as: Dry sand. Vermiculite.
Activated charcoal. Place in appropriate chemical waste container.

7. HANDLING AND STORAGE

Handling

Handle in accordance with good industrial hygiene and safety practice. Wear
personal protective equipment. Avoid breathing vapors or mists. Avoid contact withskin, eyes and clothing.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 5 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines

Chemical NameACGIH TLVOSHA PELNIOSH IDLH

Ethylene glycol

Ceiling: 100 mg/m3 aerosol only(vacated) Ceiling: 50 ppm-(vacated) Ceiling: 125 mg/m3

107-21-1

OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. ACGIH TLV:AmericanConference of Governmental Industrial Hygienists - Threshold Limit Value.

Other Exposure Guidelines

Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965
F.2d 962 (11th Cir., 1992).

Engineering Measures

Showers
Eyewash stations
Ventilation systems

Personal Protective Equipment
Eye/Face Protection

Safety glasses with side-shields.

Skin and Body Protection

Wear protective gloves/clothing.

Respiratory Protection

If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA
approved respiratory protection should be worn.

Positive-pressure supplied air

respirators may be required for high airborne contaminant concentrations.
Respiratory protection must be provided in accordance with current localregulations.

Hygiene Measures

Handle in accordance with good industrial hygiene and safety practice.

Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 6 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Blue.

Odor

Specific.

Odor ThresholdNo information available.

Physical State

LiquidpH

No information available.

Flash Point

No information available.

Autoignition Temperature

No information available.

Decomposition Temperature

No information available.

Boiling Point/Range

No information available

Melting Point/Range

No information available

Flammability Limits in Air

No information available.

Explosion Limits

No information available.

Solubility

No information available

Evaporation Rate

No information available

Vapor Pressure

No data available

Vapor Density

No data available

VOC Content (%)

15-25

10. STABILITY AND REACTIVITY

StabilityStable under recommended storage conditions.

Incompatible Products

Strong oxidizing agents. Chlorosulfonic acid, oleum, sulfuric acid, perchloric acid,
chromium trioxide, potassium permanganate and sodium peroxide.

Conditions to Avoid

Heat, flames and sparks.

Hazardous Decomposition Products Sulfur oxides. Nitrogen oxides (NOx). Carbon dioxide (CO2) Carbon monoxide(CO).

Hazardous Polymerization

Hazardous polymerization does not occur.

Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 7 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Product Information

May be harmful by inhalation, ingestion, or skin absorption. Irritating to eyes: Mistor aerosol may be irritating to eyes, nose, throat, and lungs.

Component Information

Chemical Name

LD50 Oral

LD50 Dermal

LC50 Inhalation

Ethylene glycol

4000 mg/kg ( Rat )9530 µL/kg ( Rabbit )-Chronic Toxicity

Chronic Toxicity

May cause adverse liver and kidney effects. May cause central nervous systemdepression. Contains materials which based on animal tests may cause adverse
reproductive and birth effects at maternally toxic levels.

Carcinogenicity

Contains no ingredients above reportable quantities listed as a carcinogen.

Target Organ Effects

Central nervous system (CNS). Liver, kidney, and respiratory system. Reproductivesystem. Contains material that may adversely affect the developing fetus.

Product Name: Reactive Dye Ink Rc210 Blue

Material Safety Data Sheets

MSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 8 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

12. ECOLOGICAL INFORMATION

Ecotoxicity
The environmental impact of this product has not been fully investigated.

Chemical Name

Ethylene glycol

Toxicity to Algae

Toxicity to Fish

Toxicity toDaphnia Magna (Water

Microorganisms

Flea)

EC50: 6500 - 13000 mg/L

LC50: 41000 mg/L

EC50 = 10000 mg/L 16 h

EC50: 46300 mg/L

Pseudokirchneriella

Oncorhynchus mykiss 96 h

EC50 = 620 mg/L 30 min

Daphnia magna 48 h

subcapitata 96 h

LC50: 14-18 ml/L

EC50 = 620.0 mg/L 30 min

Oncorhynchus mykiss 96 h
static
LC50: 27540 mg/L Lepomis
macrochirus 96 h static
LC50: 40761 mg/L
Oncorhynchus mykiss 96 h
static
LC50: 40000-60000 mg/L
Pimephales promelas 96 h
static
LC50: 16000 mg/L Poecilia
reticulata 96 h static

Chemical NameLog Pow

Ethylene glycol-1.93Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 9 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods

This material, as supplied, is not a hazardous waste according to Federal
regulations (40 CFR 261).

This material could become a hazardous waste if it ismixed with or otherwise comes in contact with a hazardous waste, if chemicaladditions are made to this material, or if the material is processed or otherwisealtered.

Consult 40 CFR 261 to determine whether the altered material is ahazardous waste.

Consult the appropriate state, regional, or local regulations for

additional requirements.

Contaminated Packaging

Do not re-use empty containers.

14. TRANSPORT INFORMATION

DOT

Not regulated

TDG

Not regulated

MEX

Not regulated

ICAO

Not regulated

IATA

Not regulated

IMDG/IMO

Not regulated

RID

Not regulated

ADR

Not regulated

ADN

Not regulated

Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 10 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

15. REGULATORY INFORMATIONInternational Inventories
TSCA

All components are listed on the TSCA Inventory.

DSL

All components are listed either on the DSL or NDSL.

LegendTSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains achemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of FederalRegulations, Part 372:

Chemical Name

CAS-NoWeight %SARA 313 - Threshold Values %Ethylene glycol

107-21-1

15-25

1.0

SARA 311/312 Hazard Categories
Acute Health Hazard

Yes

Chronic Health Hazard

Yes

Fire Hazard

NoSudden Release of Pressure Hazard

No

Reactive Hazard

NoClean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and
40 CFR 122.42).

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Product Name: Reactive Dye Ink Rc210 BlueMSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 11 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
Chemical Name

Hazardous Substances RQs

Extremely Hazardous

RQ

Substances RQs
Ethylene glycol

5000 lb

RQ 5000 lb final RQ
RQ 2270 kg final RQU.S. State Regulations

California Proposition 65: WARNING:
This product can expose you to chemicals including Ethylene glycol, which is known
to the State of California to cause birth defects or other reproductive harm.
For more information go to www.P65Warnings.ca.gov.

U.S. State Right-to-Know Regulations

Chemical NameNew Jersey

Massachusetts

Pennsylvania

Illinois

Rhode Island

Ethylene glycol

XX

X

X

X

International Regulations

Chemical Name

Carcinogen Status

Ethylene glycol

Exposure Limits
Mexico: Ceiling= 100 mg/m3

CanadaThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations(CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class
D2B

Toxic materials

Product Name: Reactive Dye Ink Rc210 Blue

Material Safety Data Sheets

MSDS No. 031-36W19BPFirst issue: 2011/01/26
Revised: 2018/08/31
Page 12 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

Chemical Name

NPRI

Ethylene glycol

X

LegendNPRI - National Pollutant Release Inventory

16. OTHER INFORMATION
General Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication.

The information given is designed only as a guide for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered as a warranty or quality specification.

The information relates only to thespecific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text.

Revision history
VersionDate

Content

1.0

2011/01/26

First Issue

2.0

2018/08/31

Sectiom15: Proposition65 Information Described