Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Safety Data Sheets
1.

Identification

Product Name

: ES3 ink Light Magenta

Order No.

: SPC-0440LM

General Use: Ink for ink jet plotter

Product Description: Solvent pigment ink

SDS Number: 037-S040320

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Acute Toxicity – Inhalation: Not classified

Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2

Sensitization – Respiratory: Not classified

Sensitization – Skin: Not classified

Germ Cell Mutagenicity: Not classified

Carcinogenicity: Not classified

Toxic to Reproduction: Category 1

Page 1 of 11

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Safety Data Sheets
Specific Target Organ Toxicity: Category 2 (central nerve)(Single Exposure)Specific Target Organ Toxicity: Not classified(Repeated Exposure)
Aspiration Hazard
Environmental Hazards
Hazardous to the Aquatic: Not classified: Not classified

Environment - Acute Hazard
Hazardous to the Aquatic: Not classified

Environment - Long Term Hazard
Hazardous to the Ozone Layer: Not classified

The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H227 Combustible liquid
H315 Causes skin irritation
H319 Causes serious eye irritation
H360 May damage fertility or the unborn child
H371 May cause damage to organs (central nerve)
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from open flames and other ignition sources.-No smoking.
P260 Do not breathe gas/mist.
P264 Wash hands and eyes thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ eye protection/ face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Page 2 of 11

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Safety Data Sheets

Continue rinsing.
P308+P311 If exposed or concerned: Call a POISON CENTER/ doctor.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use alcohol-resistant-related fire foam, dry chemical, carbon
dioxide, water spray, dry sand for extinguish.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international regulation (to be specified).
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 22Flammability= 2

2 Flammability

Flammability = 2

Reactivity = 1

1

Instability = 1

Protective Equipment = C

C Protective Equipment

HealthReactivity

Health = 2221

Special = 0

CANADIAN WHMIS SYMBOLS : Not applicable
3.

Composition / Information on Ingredients
ChemicalNo

Chemical Name

Wt%CAS No.

1Diethylene Glycol Diethyl ether

55-65

112-36-7

C8H18O3

2

Tetraethylene Glycol Dimethyl Ether

10-20

143-24-8

C10H22O5

3γ-Butyrolactone<2096-48-0

C4H6O2

4

Proprietary organic materials

1-5

Trade Secret-

5

Tetraethylene Glycol Monobuthyl Ether

1-5

1559-34-8

C12H26O5

6Colorants<1Trade Secret-

FormulaPage 3 of 11

Safety Data Sheets
4.

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

First Aid Measures

Inhalation: IF exposed or concerned: Get medical advice/attention. Remove
subject to ventilated fresh air. If not breathing, give artificial
respiration right away. If breathing is difficult, give oxygen.

Eye Contact: Immediately flush with room temperature, low pressure and cleanwater for at least 15 minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. Seek medical attention if eye irritation
continues. If eye irritation persists, Get medical advice/ attention.

Skin Contact: IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash before reuse. If skin irritationoccurs: Get medical advice/attention.

Ingestion: IF exposed or concerned: Call a POISON CENTER/ doctor.
IF SWALLOWED: Do not induce vomiting.

Most important symptoms and effects, both acute and delayed: Skin: Ink contact with skin may cause irritation, swelling orredness.
Note To Physician
5.

: Not necessary

Fire Fighting Measures

Flammable Properties: Combustible liquid under Hazard Communication Standard (HCS,U.S.A).
Flash point : about 71℃ (Closed cup)
Autoflammability: None
Explosive properties: 1.4~6.9v/v% as dipropylene glycol
mono-methyl ether

Extinguishing Media: Water spray, dry chemical, carbon dioxide or, alcohol foam

Unsuitable Extinguishing: NoneMedia
Fire Fighting: Extinguish to use fire fighting media or plentiful fog water.

Instructions

Put protection wear without fail in case of firefighting work.
Wear full fire-fighting turn-out gear (full bunker gear) andrespiratory protection (self-contained breathing apparatus).
Do not work in the leeward.
Page 4 of 11

Safety Data Sheets
6.

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
For non-emergency: Eye or Skin protection required during clean-up. Use proper

personnelventilation.

For emergency: Noneresponders
Environmental: Do not release to sewer, surface- or ground-water.

precautions:
Methods and material for containment and cleaning up
Advice on how to contain: Use sponges to wipe-up ink.

a spill
Advice how to clean-up: Rinse area with damp cloth. Place waste in closed container fora spilldisposal.
Wash hands with soap and water.

Any other information:: Do not dispose of waste to the sewer.

Reference to other: Please refer SECTION 13 for disposal.

sections
7.

Handling and Storage

Handling: Obtain SDS (Safety Data Sheet) and printer's manual instructions
before use. Do not handle until all safety precautions have been readand understood. Wear protective equipment (see 8-section). Use
proper ventilation and no fire in work place. Keep out of reach ofchildren and do not drink ink. Do not dismantle cartridge. Make sure
cartridge is dry before insertion into printer housing. Avoid contact
with skin, eyes or clothing. In the case of skin contact, wash with soapand water.

Storage: Store locked up. Do not store the cartridge in high or freezing
temperatures. Keep cartridge out of direct sunlight. Do not store thecartridge with oxidizing agents or explosives.

SPECIFIC USES

: Not specified

Page 5 of 11

Safety Data Sheets
8.

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Exposure Controls / Personal Protection

Exposure Limit Values
No1

The 8-Hour TWA Exposure

Chemical Name

Value

Diethylene glycol diethyl etherCalifornia

5 ppm(CAS No. 112-36-7)

OELs

33mg/m3

California OELs : California Code of Regulations, Title 8, Section 5155. Airborne Contaminants
Exposure Controls
Occupational Exposure Controls
Engineering Controls: Use exhaust ventilation to avoid from exposure.

Personal Protection
Respiratory: An air purifying respirator with organic vapor cartridge or canister

Protection

may be permissible under certain circumstances where air-borne
concentrations are expected to exceed exposure limits. Protection
provided by air purifying respirators is limited. Use apositive-pressure, air-supplied respirator if there is any potential for
uncontrolled release, exposure levels are unknown, or in any othercircumstances where air-purifying respirators may not provide
adequate protection.

Hand Protection: Wear gloves that resist organic solvents and chemicals.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, asappropriate.

Environmental Exposure Controls: Not available
Page 6 of 11Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Safety Data Sheets
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: Magenta

Odor: Slightly

pH: Not Applicable

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: about 71℃ (Closed cup)

Auto ignition temperature: Not available

Explosive Properties: Explosive limits: 1.4~6.9v/v% as γ-Butyrolactone

Relative Density: Not availableSolubility (ies): Soluble

Viscosity: Not available

Vapor Density: Greater than 1 (air = 1)

Evaporation Rate

: Not available

VOC: 756.5 g/L

10. Stability and Reactivity
Conditions to Avoid: High and freezing temperatures

Stability: Stable under normal temperature

Materials to Avoid: Oxidizers and explosives

Hazardous Reactions /: To burn this product may be produce toxic gases.

Decomposition Products.

11. Toxicological Information
Acute Toxicity: Oral LD50
>2500mg/kg(rats)

Eye Irritation

Dermal LD50>2000mg/kg(rats): Moderate irritant. (rabbit, OECD 405)
Diethylene Glycol Diethyl ether : Category 2A (GHS Classification)
γ-Butyrolactone : Category 2A (GHS Classification)

Page 7 of 11

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

Safety Data Sheets
Skin Irritation: Mild irritant. (rabbit, OECD 404)
Diethylene Glycol Diethyl ether : Category 2 (GHS Classification)

Skin Sensitization: Non-sensitizer(LLNA, OECD 429)

Mutagenicity: Negative (by Ames Test)

Carcinogenicity: Not meet the criteria for classification according to EU Directive1999/45/EC
Not contain any substances listed in IARC Monographs (1,2A and 2B)

Reproductive Toxicity: Tetraethylene Glycol Dimethyl Ether : Category 1B(GHS Classification)

Specific Target Organ Toxicity (Single Exposure): γ-Butyrolactone : Category 2 (central nerve) (GHS Classification)
Category 3 (drowsiness or dizziness)(GHS Classification)
12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Not available

Persistence and: Not available

Degradability
Bioaccumulative: Not available

Potential
Results of PBT and: Has not carried out PBT and vPvB assessment

vPvB assessment
Other Adverse Effects: Not available

Page 8 of 11

Safety Data Sheets

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

13. Disposal Considerations: Dispose of contents/container to an appropriate treatment anddisposal facility in accordance with applicable laws and regulations,and product characteristics at time of disposal.
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Us Department of Transportation (DOT)
Hazardous Materials: Not Applicable

Sea Transport (IMDG)
Class: Not Applicable

Packing Group (PG)

: Not Applicable

UN Number: Not Applicable

Proper Shipping Name

: Not Applicable

Marine Pollutant: Not Applicable

Air Transport (ICAO/IATA)Class: Not Applicable

Packing Group(PG): Not Applicable

UN Number: Not Applicable

Proper Shipping Name

: Not Applicable

Page 9 of 11

Safety Data Sheets

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

15. Regulatory Information
TSCA Section 4(a): Not regulated

Final Test Rules
Regulated
TSCA Section 5: Ingredient : Diethylene glycol diethyl ether (CAS No. 112-36-7)

Significant New Use

Reference: 76FR40850

Rule Regulation

Ingredient : Tetraethylene glycol dimethyl ether (CAS No. 143-24-8)

proposed

Reference: 76FR40850

TSCA Section 8(a): Not regulated

Preliminary Assessment
Information Rule (PAIR)
TSCA Section 12(b)Ingredient : Diethylene glycol diethyl ether (CAS No. 112-36-7)

One-Time Export

Reference: TSCA 5 Proposed SNUR

Notification RegulatedIngredient : Tetraethylene glycol dimethyl ether (CAS No. 143-24-8)
Reference: TSCA 5 Proposed SNUR

Clean Air Act Section: Diethylene glycol diethyl ether (CAS No. 112-36-7)

112, Hazardous Air
Pollutants
EPCRA: Diethylene glycol diethyl ether (CAS No. 112-36-7)(SARA Title III)
Section 313
California Proposition: Not regulated65
Canada Information: WHMIS Controlled Product:
Not applicable (Manufactured article)

Australia Information: Statement of Hazardous Nature:
Classified as Toxic and Irritant according to criteria of NOHSCNew Zealand: Hazardous Substances and New Organisms Act 1996:

Information

Not regulated

Others: Please refer to any other federal, state and local regulations.

Page 10 of 11

Safety Data Sheets

Product Name: ES3 ink Light Magenta
SDS No. 037-S040320
First issue: 2008/06/12
Revised: 2019/10/30

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 11 of 11