Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets
1. IDENTIFICATION
Product Name
Order No.
Ink Ver.
Recommended use of the chemicaland restrictions on use
Restrictions on use

SDS Number
Manufacturer

Importer / Distributor Established inUSA

Emergency telephone No.

MH-110 Ink Pure Clear
MH110-PCL-BD
1
UV curable 3D model ink
This product is a bottle containing ink. Under normal conditions of use,
the substance is released from a bottle only inside an appropriate printing
system, and therefore, exposure is limited. But the liquid within the bottle
is considered hazardous, and the SDS has been prepared in case ofexposure to the liquid.
037-U145342
MIMAKI ENGINEERING CO., LTD.
2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 Japan+81-268-64-2413
MIMAKI USA, INC.
150 Satellite Boulevard NE, suite A, Suwanee, Georgia 30024, U.S.A.
+1-678-730-0170+1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2. HAZARDS IDENTIFICATIONClassification of the chemical inaccordance with paragraph (d) of 29
CFR § 1910.1200
Acute toxicity - oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Sensitization - skin Category 1
Reproductive toxicity Category 2
Specific target organ toxicity (repeated exposure) Category 2
Hazardous to the Aquatic Environment - Acute Hazard Category 2
Hazardous to the Aquatic Environment - Long Term Hazard Category 2
GHS Label Elements
Symbols

Signal Word
Hazard Statements

Danger
H302 Harmful if swallowed
H315 Causes skin irritation____________________________________________________________
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Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets

H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeatedexposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
Prevention

ResponseStorage
DisposalStatement(s) of Unknown AcuteToxicity

Obtain SDS (Safety Data Sheet) and printer's Operation Manual beforeuse. (P201)
Do not handle until all safety precautions have been read andunderstood(P202)
Do not breathe gas/mist.(P260)
Wash hands and eyes thoroughly after handling. (P264)
Do not eat, drink or smoke when using this product(P270)
Contaminated work clothing should not be allowed out of theworkplace.(P272)
Avoid release to the environment.(P273)
Wear protective gloves/protective clothing/eye protection/faceprotection.(P280)
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwell(P301+P312)(IF SWALLOWED):Rinse mouth. ((P301)+P330)
IF ON SKIN: Wash with plenty of soap and water(P302+P352)
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue
rinsing(P305+P351+P338)(IF IN EYES): Immediately call a POISON CENTER or
doctor/physician.((P305)+P310)
IF exposed or concerned: Get medical advice/attention(P308+P313)
Get medical advice/attention if you feel unwell(P314)
If skin irritation or rash occurs: Get medical advice/attention(P333+P313)
Take off contaminated clothing and wash it before reuse.(P362+P364)
Collect spillage.(P391)
Store locked up(P405)
Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).(P501)(Oral) 89.90% of the mixture consists of ingredient(s) of unknown acutetoxicity.

3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical nameAcryl ester

Contents
45-55%CAS number
Confidential____________________________________________________________
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Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets
Isobornyl acrylate
Oligomer4-(1-oxo-2-propenyl)-morpholine
Diphenyl-2,4,6-trimethylbenzoyl phosphine oxide
4-Hydroxy-2,2,6,6-tetramethylpiperidinoxyl
Additive
4. FIRST-AID MEASURESIn case of inhalation
In case of skin contact

In case of eye contact
In case of ingestion

5. FIRE-FIGHTING MEASURESSuitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from thechemicalSpecial protective equipment andprecautions for fire-fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective
equipment and emergency
procedures

Environmental precautions
Methods and materials forcontainment and cleaning up

7. HANDLING AND STORAGE
Precautions for safe handlingTechnical measures

10-20%
10-20%
5-15%
1-10%
<1%
<0.1%

5888-33-5
Confidential
5117-12-4
75980-60-8
2226-96-2
Confidential

Call a doctor if you feel unwell.
IF ON SKIN: Wash with plenty of soap and water.
Specific treatment.
Take off immediately all contaminated clothing and wash it before reuse.
Call a doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Rinse mouth.
IF SWALLOWED: Call a doctor if you feel unwell.

Dry chemical, alcohol-resistant foam, CO2, sand.
Cylindric water.
Risk of producing harmful gases such as carbon monoxide. Avoid
inhalation of smoke or gases.
Use goggles in combination with dust mask, and another protections as
appropriate to situation.

Use goggles in combination with dust mask, and another protections as
appropriate to situation.
Large spills :Evacuate area.
Ensure adequate ventilation.
Do not discharge into the drains, surface waters or ground water directly.
small spill : absorb with material such as non-combustible materialwash
thoroughly after handling
Large spills: Dike spills and dispose of in safe area.

Use local exhaust ventilation in case of production of fume or mist.
Facilities storing or utilizing this material should be equipped with aneyewash facility and a safety shower.

____________________________________________________________
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Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets
Safe handling advice
Conditions for safe storage, including
any incompatibilities
Suitable storage conditions

Wash hands thoroughly after handling.
Wear protective gloves/protective clothing.

Store locked up.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
This product is a bottle containing ink. Under normal conditions of use, the substance is released from a bottle
only inside an appropriate printing system, and therefore, exposure is limited. But the liquid within the bottle isconsidered hazardous.
Please prepare the following protective equipment in case of handling damaged bottle, setting an ink bottle to theprinter, handling a waste bottle and being exposed to liquid.
Appropriate engineering controls
Use local exhaust ventilation in case of production of fume or mist.
Facilities storing or utilizing this material should be equipped with aneyewash facility and a safety shower.
Use explosion-proof electrical equipment and prevent from staticelectricity.
Individual protection measures
Respiratory protection
Wear the respirator against toxic gas.
Follow the OSHA respirator regulations found in 29 CFR 1910.134.
Respiratory protection approved by NIOSH- Category 19C Type C
supplied-air respirator operated in pressure demand- Category 21C
air-purifying respirator equipped- Category 23C
air-purifying respirator equipped
Hand protection
Gloves and other dermal protection may not be used for a time period
longer than they are actually tested and must be replaced at the end ofeach work shift.
- Safety 4/4H EVOH/PE laminate- Ansell Edmont Neoprene number 865- Solvex Nitrile Rubber number 275
Eye protection
Chemical goggles or equivalent eye protection.
Tightly fitting safety goggles.
It is recommended to install an eyewash station near the printer, foremergency use.
Skin and body protection
Full body chemical protective clothing. Clothing which covers any otherexposed areas of the arms, legs, and torso.
Wear appropriate protective gloves and clothing to prevent skin exposure.
Protective Materials
Provide an emergency eye wash fountain and quick drench shower in theimmediate work area.
____________________________________________________________
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Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets
Environmental Exposure Controls

This product contains the substance which is regulated to release towater under SNUR.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State
LiquidColor
Clear to light yellow
Odor
Unique odorOdor threshold
No data available
pHNo data available
Melting point
No data available
Boiling point
No data available
Flash point
93℃ or more
Evaporation rate
No data available
Flammability(Solid,Gas)
No data available
Flammability or explosive limits
No data available
Vapor pressure
No data available
Vapor density
No data available
Specific Gravity (Density)
1.08（25℃）
Solubility
No data available
Partition coefficient: n-octanol/water No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
57.1±3mPa・s（25℃）
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Acute toxicity (Oral)

No information available
Stable under normal conditions of use.
Polymerization and curing may occur when exposed to light, particularly
ultraviolet rays.
No information available
Strong oxidizing agents, radical initiator, inert gas, oxygen scavenger
Combustion may produce toxic gas, carbon monoxide and carbon dioxide.

Category 4:2226-96-2 (converted value = 500mg/kg, source: Registeredsubstances (ECHA)), 5117-12-4 (converted value = 500mg/kg, source:1272/2008/EC)
Not classified:5888-33-5 (toxicity value = 5000mg/kg, source: Registeredsubstances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC)
No data:Confidential (source: None)____________________________________________________________
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Safety Data Sheets

Acute toxicity (Dermal)
Acute toxicity (Inhalation : Gases)
Acute toxicity (Inhalation : Vapours)
Acute toxicity (Inhalation : dust/mist)
Skin corrosion/ Irritation

Serious eye damage/ irritation

Respiratory Sensitization
Skin Sensitization

Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity

Reproductive toxicity, effects on orvia lactation

Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Calculation result = 1148.3050847mg/kg. Classification result = Category
4.
Unable to classify due to insufficient data.
Does not fall under gas based on GHS definitions.
Unable to classify due to insufficient data.
Unable to classify due to insufficient data.
Category 2:5888-33-5 (source: Registered substances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC), 222696-2 (source: Registered substances (ECHA)), 5117-12-4 (source:1272/2008/EC)
No data:Confidential (source: None)
Sum of Category 2 Concentration limit = 10%. Classification result =Category 2.
Category 1:2226-96-2 (source: Registered substances (ECHA)), 5117-124 (source: 1272/2008/EC)
Category 2:5888-33-5 (source: Registered substances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC)
No data:Confidential (source: None)
Sum of Eye category 1 Concentration limit = 3%. Classification result =Category 1.
Unable to classify due to insufficient data.
Category 1:5117-12-4 (source: 1272/2008/EC), 5888-33-5 (source:Registered substances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC), 222696-2 (source: Registered substances (ECHA))No data:Confidential (source: None)
5888-33-5 >= 0.1% Classification result = Category 1
Unable to classify due to insufficient data.
Unable to classify due to insufficient data.
Category 2:75980-60-8 (source: 1272/2008/EC)
Classification not possible:2226-96-2 (source: Registered substances(ECHA)), 5117-12-4 (source: 1272/2008/EC), 5888-33-5 (source:Registered substances (ECHA))No data:Confidential (source: None)
75980-60-8 >= 0.1% Classification result = Category 2
Unable to classify due to insufficient data.

____________________________________________________________
Page 6 of 9

Safety Data Sheets

Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Specific target organ toxicity - Single Category 3:5888-33-5 (organ = respiratory tract irritation, source:exposure
Registered substances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC), 222696-2 (source: Registered substances (ECHA)), 5117-12-4 (source:1272/2008/EC)
No data:Confidential (source: None)

Specific target organ toxicity Repeated exposure

Substances classified as hazardous are below the concentration limit.
Contains substance of unknown toxicity. Changed from Not classified toClassification not possible.
Category 2:2226-96-2 (organ = spleen、liver, source: Registeredsubstances (ECHA)), 5117-12-4 (organ = ---, source: 1272/2008/EC)
Classification not possible:75980-60-8 (source: 1272/2008/EC), 588833-5 (source: Registered substances (ECHA))No data:Confidential (source: None)
5117-12-4 >= 1% Classification result = Category 2
Unable to classify due to insufficient data.

Aspiration hazard
12. ECOLOGICAL INFORMATION
Hazardous to the Aquatic
Environment - Acute Toxicity

Hazardous to the Aquatic
Environment - Chronic Toxicity

Hazardous to the Ozone layer
13. DISPOSAL CONSIDERATIONS
Disposal Methods

Category 1:5888-33-5 (source: Registered substances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC), 222696-2 (source: Registered substances (ECHA)), 5117-12-4 (source:1272/2008/EC)
No data:Confidential (source: None)(M factor x 10 x Category 1) + Category 2 >= Concentration limit(25%).
Classification result = Category 2. does not apply to the target country.
Category 1:5888-33-5 (source: Registered substances (ECHA))Classification not possible:75980-60-8 (source: 1272/2008/EC), 222696-2 (source: Registered substances (ECHA)), 5117-12-4 (source:1272/2008/EC)
No data:Confidential (source: None)(M factor x 10 x Category 1) + Category 2 >= Concentration limit(25%).
Classification result = Category 2. does not apply to the target country.
Unable to classify due to insufficient data.

Comply with all USA, national and local regulations.
Wear the appropriate protective equipment during disposal.
Fully cured printed matter can be disposed of as ordinary office trash.

____________________________________________________________
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Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets

Contaminated Container andPackaging

However, disposal of liquid and uncured waste, cleaning cloths, gloves,and empty material containers must be done in accordance with local
laws and regulations. They are classified as hazardous industrial waste.
When this product is subjected to incineration, it must be done inaccordance with the standard for disposing Industrial Waste.
Use industrial waste disposal companies who is authorized by local
municipal government for the disposal. Do not dump this product intosewers, on the ground or into any body of water.
Passed to a licensed waste contractor.
In case of disposal of empty containers, remove the content thoroughly.

14. TRANSPORT INFORMATIONIMDG
UN numberUN proper shipping name
Transport hazard class(es)Packing group
IATA
UN numberUN proper shipping name
Transport hazard class(es)Packing group
DOT
UN numberUN proper shipping name

3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Contains: Isobornyl acrylate)
9Ⅲ
3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Contains: Isobornyl acrylate)
9Ⅲ3082ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Contains: Isobornyl acrylate)
Transport hazard class(es)9Packing group
Ⅲ
Renarks: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is excepted from Dangerous Goods
regulations. Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.
15. REGULATORY INFORMATION
No main regulation
Component Analysis - Inventory
Isobornyl acrylate (5888-33-5)
TSCA UnitedStatesYes

ENCS JapanKECI Annex
1, 2 - Korea

IECSC China

DSL/NDSL- Canada

PICCS Philippines

AICS Australia

Yes

Yes

Yes

Yes

YesYes

EINECS/ELINCS- European
Union
Yes

____________________________________________________________
Page 8 of 9

TCSI Taiwan
Yes

NZIoC NewZealand
Yes

Product Name: MH-110 Ink Pure ClearSDS No. 037-U145342
First issue: 2020/07/02
Revised: 2022/02/25

Safety Data Sheets
4-(1-oxo-2-propenyl)-morpholine (5117-12-4)
TSCA UnitedStates
Yes

ENCS JapanKECI Annex
1, 2 - Korea

IECSC China

DSL/NDSL- CanadaPICCS Philippines

AICS Australia

Yes

Yes

Yes

Yes

Yes

Yes

EINECS/ELINCS- European
Union
Yes

TCSI Taiwan
Yes

NZIoC New
Zealand
Yes

Diphenyl-2,4,6-trimethylbenzoyl phosphine oxide (75980-60-8)
TSCA UnitedStatesYes

ENCS JapanKECI Annex
1, 2 - Korea

IECSC China

DSL/NDSL- Canada

PICCS Philippines

AICS Australia

Yes

Yes

Yes

Yes

Yes

Yes

EINECS/ELINCS- European
Union
Yes

TCSI Taiwan
Yes

NZIoC New
ZealandYes

4-Hydroxy-2,2,6,6-tetramethylpiperidinoxyl (2226-96-2)
TSCA UnitedStatesYes

ENCS JapanKECI Annex
1, 2 - Korea

IECSC China

DSL/NDSL- Canada

PICCS Philippines

AICS Australia

Yes

Yes

Yes

Yes

Yes

Yes

EINECS/ELINCS- EuropeanUnion
Yes

TCSI TaiwanYes

NZIoC NewZealandYes

California Proposition 65
WARNING:
This product can expose you to chemicals including Ethyl acrylate and Propylene oxide which
are known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
16. OTHER INFORMATION
Literature References
Other data

National Fire Protection
Association(U.S.A)
HealthFlammability
Reactivity
Specific hazard
HMIS(U.S.A)
Health Hazard
Fire HazardReactivity
Personal Protection

NITE GHS
EU CLP Regulation, AnnexVI
The information suggested in this Safety Data Sheet does notcomprehend everything and should be adopted only as a guide.
The accuracy of the information and recommendations suggested herein
are credible. However the company makes no warranty regarding suchinformation and recommendations and disclaims all liability for reliance
thereon.

310
Not applicable*310
The customer is responsible for determining the PPE code for thismaterial____________________________________________________________
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