Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Safety Data Sheets
1.

Identification

Product Name

: Latex ink LX101 Magenta

Order No.

: LX101-M-60

Ink Ver.

:1

General Use: Ink for ink jet printer

Product Description: Aqueous ink

SDS Number: 037-W350535

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2ASpecific Target Organ Toxicity: Category 3 (Respiratory tract irritation)(Single Exposure)
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolPage 1 of 13

Safety Data Sheets

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Signal Word
Warning
Hazard Statements
H315 Cause skin irritation
H319 Cause serious eye irritation
H335 May cause respiratory irritation.
Precautionary Statements[Prevention]
P261 Avoid breathing gas/mist.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
[Storage]
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
NFPA Rating (scale 0 – 4)
Health = 2
1

Flammability = 1
Instability = 3

23Special = None
3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1

Glucol ether solvents

10-20

Trade Secret2

Alcohol solvent series

28-32

Trade Secret3

Pigment

1-5

Trade Secret4

Organic ingredient1-5

Trade SecretPage 2 of 13

Safety Data Sheets
54.

Methyldiethanolamine

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

0.1-1.5

105-59-9First Aid Measures

Description of first aid measures
Eye Contact: If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart andaway from eye and moving the eyelids by occasionally lifting theupper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek
medical attention.
Removal of contact lenses after an eye injury should only beundertaken by skilled personnel.

Skin Contact: If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.

Inhalation: If fumes or combustion products are inhaled remove fromcontaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should beremoved, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with ademand valve resuscitator, bag-valve mask device, or pocket mask
as trained. Perform CPR if necessary.
Transport to hospital, or doctor, without delay.

Ingestion: If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side
(head-down position, if possible) to maintain open airway andprevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with
reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and asmuch as casualty can comfortably drink.
Seek medical advice.
Page 3 of 13

Safety Data Sheets

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Most important symptoms and effects, both acute and delayed
See Section 11.
5.

Fire Fighting Measures

Extinguishing Media: Alcohol stable foam. Dry chemical powder. BCF (where regulationspermit). Carbon dioxide. Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture
Fire Incompatibility: Avoid contamination with oxidising agents i.e. nitrates, oxidisingacids, chlorine bleaches, pool chlorine etc. as ignition may result

Special protective equipment and precautions for fire-fighters
Fire Fighting: Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains orwater course.
Use water delivered as a fine spray to control fire and cool adjacentarea.
Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protectedlocation.
If safe to do so, remove containers from path of fire.

Fire/Explosion Hazard: Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent
rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Mists containing combustible materials may be explosive.
Combustion products include:
carbon dioxide (CO2)other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.

Page 4 of 13

Safety Data Sheets
6.

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
See section 8.
Environmental precautions
See section 12.
Methods and material for containment and cleaning up
Minor Spills: Slippery when spilt.
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective
equipment.
Contain and absorb spill with sand, earth, inert material orvermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.

Major Spills: Slippery when spilt.
Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains orwater course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency
services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

Page 5 of 13

Safety Data Sheets
7.

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Handling and Storage

Precautions for Safe

: Avoid all personal contact, including inhalation.

Handling

Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
DO NOT allow material to contact humans, exposed food or foodutensils.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately. Launder contaminatedclothing before re-use.
Use good occupational work practice.
Observe manufacturer's storage and handling recommendations
contained within this SDS.
Atmosphere should be regularly checked against establishedexposure standards to ensure safe working conditions aremaintained.
DO NOT allow clothing wet with material to stay in contact with skin

Conditions for Safe

: Store in original containers.

Storage, including any

Keep containers securely sealed.

Incompatibilities

No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly forleaks.
Observe manufacturer's storage and handling recommendations
contained within this SDS.
Are incompatible with strong acids, acid chlorides, acid anhydrides,oxidising and reducing agents.

Page 6 of 13

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Safety Data Sheets8.

Exposure Controls / Personal Protection

Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
IngredientMaterial name

TEEL-1

TEEL-2

TEEL-3As a productNot Available

Not Available

Not Available

Not Available

Ingredient

Original IDLH

Revised IDLH

Glucol ether solvents

Not Available

Not Available

Alcohol solvent series

Not Available

Not Available

Pigment

Not Available

Not Available

Organic ingredient

Not Available

Not Available

methyldiethanolamine

Not Available

Not Available

Exposure Controls
Occupational Exposure Controls
Appropriate: General exhaust is adequate under normal operating conditions.

Engineering Controls

Local exhaust ventilation may be required in special circumstances.
If risk of overexposure exists, wear approved respirator. Supplied-air
type respirator may be required in special circumstances. Correct fit
is essential to ensure adequate protection.
Provide adequate ventilation in warehouses and enclosed storage
areas.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear chemical protective gloves, e.g. PVC.

Eye Protection: Safety glasses with side shields.
Page 7 of 13

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Safety Data Sheets
Chemical goggles.

Contact lenses may pose a special hazard; soft contact lenses may
absorb and concentrate irritants.
Skin Protection: Wear appropriate chemical resistant clothing.
Wear safety footwear or safety gumboots, e.g. Rubber

9.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: MagentaOdor: slight

pH: 9.3-10.3Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: Not flammable

Flammability (Solid, Gas)

: Not applicable

Explosive Properties: Not available

Oxidizing Properties: Not available

Specific Gravity: 1.02-1.04

Solubility: Not available

Water Solubility: Not available

Partition Coefficient (n-octanol / Water): Not available

Viscosity: Not available

Vapor Density: Not available

Evaporation Rate

: Not available

VOC: Not available

10. Stability and ReactivityReactivity: No reactivity hazard is expected.

Chemical Stability: Unstable in the presence of incompatible materials.
Product is considered stable.

Possibility of Hazardous: Hazardous polymerisation will not occur.
Page 8 of 13

Safety Data Sheets

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Reactions
Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Avoid contact
with incompatible materials.

Incompatible Materials: Strong acids, acid chlorides, acid anhydrides, oxidising and reducingagents.

Hazardous: See section 5

Decomposition
11. Toxicological Information
Acute Toxicity: methyldiethanolamine

Component Analysis -Dermal (rabbit) LD50: 10244 mg/kg

LD50/LC50

Oral (rat) LD50: 1945 mg/kg

Information on Likely Routes of Exposure
Inhalation: Respiratory tract irritation

Ingestion: no information on significant adverse effects

Skin Contact: irritation

Eye Contact: irritation

Immediate Effects: Skin irritation, eye irritation

Delayed Effects: Respiratory tract irritation

Medical Conditions: No information available for the product.

Aggravated by Exposure
Irritation/Corrosivity: Skin irritation, eye irritation

DataRespiratory: No information available for the product.

Sensitization
Dermal Sensitization: No information available for the product.

Germ Cell Mutagenicity: No information available for the product.

Carcinogenicity: No data listed by ACGIH, IARC, NTP, DFG or OSHA is available forthe component(s) of this product.

Reproductive Toxicity: No information available for the product.

Specific Target Organ: Respiratory tract irritation.

Toxicity - SingleExposure
Specific Target Organ: No target organs identified.

Toxicity - RepeatedPage 9 of 13Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Safety Data Sheets
Exposure
Aspiration Hazard: Not expected to be an aspiration hazard.

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Ecotoxicity
Product: Not classified
Component Analysis - Aquatic Toxicity
Methyldiethanolamine
ENDPOINTTESTSPECIESVALUE

SOURCEDURATION (HR)LC5096

Fish

320mg/L

1EC5048Crustacea=230mg/L

1EC5096

Algae or other aquatic plants=20mg/L

1NOEC96

Fish=460mg/L

1SOURCE: Extracted from 1. IUCLID Toxicity DataPersistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

Other Toxicity: No information available for the product.

13. Disposal Considerations: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Disposal Methods: Dispose in accordance with all applicable regulations.

Component Waste: The U.S. EPA has not published waste numbers for this product's

Numberscomponents.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
Page 10 of 13

Safety Data Sheets

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODSAir transport: NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS(ICAO-IATA / DGR)
Sea transport: NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS(IMDG-Code / GGVSee)Transport in bulk

: Not Applicableaccording to Annex II of
MARPOL and the IBC
code
Marine Pollutant: NO

15. Regulatory Information
Safety, health and environmental regulations / legislation specific for the substance or mixture
METHYLDIETHANOLAMINE (105-59-9) IS FOUND ON THE FOLLOWING REGULATORYLISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
Federal Regulations
Superfund Amendments and Reauthorization Act of 1986 (SARA)SECTION 311/312 HAZARD CATEGORIES
Flammable (Gases, Aerosols, Liquids, or Solids)

NoGas under pressure

No

ExplosiveNo

Self-heating

No

Pyrophoric (Liquid or Solid)No

Pyrophoric Gas

No

Corrosive to metal

No

Oxidizer (Liquid, Solid or Gas)

No

Organic Peroxide

No

Self-reactive

No

In contact with water emits flammable gas

NoPage 11 of 13

Product Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

Safety Data Sheets
Combustible Dust

NoCarcinogenicity

No

Acute toxicity (any route of exposure)No

Reproductive toxicity

NoSkin Corrosion or Irritation

Yes

Respiratory or Skin Sensitization

NoSerious eye damage or eye irritation

Yes

Specific target organ toxicity (single or repeated exposure)

Yes

Aspiration Hazard

No

Germ cell mutagenicity

No

Simple Asphyxiant

No

US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR302.4)
None Reported
State Regulations
California Proposition 65: WARNING:
This product can expose you to chemicals including Acetaldehyde, Formaldehyde, which
is known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
National Inventory Status
National Inventory

StatusAustralia - AICSY

Canada - DSL

NCanada - NDSLY

China - IECSC

NEurope - EINEC / ELINCS / NLPYJapan - ENCS

Y

Korea - KECIYNew Zealand - NZIoC

N

Philippines - PICCS

N

USA - TSCAYY = All ingredients are on the inventory
N = Not determined or one or more ingredients are not on the inventory and are not exempt fromlisting
Page 12 of 13

Safety Data SheetsProduct Name: Latex ink LX101 Magenta
SDS No. 037-W350535
First issue: 2013/06/25
Revised: 2019/10/29

16. Other Information
Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13