Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30

Safety Data Sheets
1.

Identification

Product Name

: BS4 ink Blue Shade Magenta

Order No.

: BS4-BM-2L / BS4-BM-60

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037- S184541

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Acute Toxicity – Oral

: Category 4

Eye Damage / Irritation: Category 2ASpecific Target Organ Toxicity: Category 2 (central nervous system)(Single Exposure)
The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolPage 1 of 8

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30

Safety Data Sheets
Signal WordWarning

Hazard Statements
H302 Harmful if swallowed.
H319 Cause serious eye irritation.
H371 May cause damage to organs (central nervous system)
Precautionary Statements[Prevention]
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwell.
(P301)+P330 (IF SWALLOWED): Rinse mouth.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P337+P313 If eye irritation persists: Get medical advice/attention.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
[Statement(s) of Unknown Acute Toxicity(Oral) 80% of the mixture consists of ingredient(s) of unknown acute toxicity.
NFPA Rating (scale 0 – 4)
Health = 20

Flammability = 0

20Instability = 0
Special =3.

Composition / Information on IngredientsNo

Chemical Name

Wt%CAS No.

1Glycol Ethers

60-70

Trade secret

2.gamma.-Butyrolactone

10-20

96-48-03Diethylene glycol diethyl ether

10-20

112-36-7
Page 2 of 8

Safety Data Sheets

4.

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30

42,5,8,11,14-Pentaoxapentadecane<10143-24-8

5Resin<5Trade secret

6Quinacridone<5Trade secret

7Additives<5Trade secretFirst Aid Measures

Inhalation: Call a POISON CENTER/doctor/physician if you feel unwell.
IF exposed or concerned: Call a POISON CENTER ordoctor/physician.

Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention. IF exposed orconcerned: Call a POISON CENTER or doctor/physician.

Skin Contact: IF ON SKIN: Wash with plenty of soap and water. If skin irritation
occurs: Get medical advice and attention. IF exposed or concerned:
Call a POISON CENTER or doctor/physician.

Ingestion: IF SWALLOWED: Immediately call a POISONCENTER or doctor/physician. Rinse mouth. IF exposed or concerned:
Call a POISON CENTER or doctor/physician.

Most Important Symptoms/Effects
Acute: eye irritation, central nervous system damage

Delayed: No data available.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash Point: No data available

Extinguishing Media: Dry chemical, alcohol-resistant foam, CO2, sand.
When dust occurs, use dry sand.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

Media
Special Hazards Arising: Risk of producing harmful gases such as carbon monoxide andPage 3 of 8

Safety Data Sheets

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30

from the Chemicalsulfur oxides. Avoid inhalation of smoke or gases.

Special Protective: Use goggles in combination with dust mask, and another protections

Equipment andas appropriate to situation.

Precautions forFirefighters
6.

Accidental Release Measures

Personal Precautions,: Use goggles in combination with dust mask, and another protections

Protective Equipment

as appropriate to situation. Large spills : Evacuate area. Ensureand Emergency

adequate ventilation.

Procedures
Methods and Materials: small spill : absorb with material such as noncombustible

for Containment andmaterialwash thoroughly after handling

Cleaning Up

Large spills: Dike spills and dispose of in safe area.

Environmental: Do not discharge into the drains, surface waters or ground water

Precautions

directly.

7.

Handling and Storage

Precautions for Safe

: Technical measures

Handling

Use local exhaust ventilation in case of production of fume or mist.
Facilities storing or utilizing this material should be equipped withan eyewash facility and a safety shower.
Safe handling advice
Do not eat, drink or smoke when using this product. Wash hands
thoroughly after handling. Wear eye protection/face protection. Do notbreathe dust/fume/gas/mist/vapours/spray.

Conditions for Safe

: Suitable storage conditions

Storage, including any

Store locked up.

Incompatibilities
8.

Exposure Controls / Personal Protection

Exposure Controls
Occupational Exposure Controls
Page 4 of 8

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30

Safety Data Sheets
Appropriate: Use local exhaust ventilation in case of production of fume or mist.

Engineering Controls

Facilities storing or utilizing this material should be equipped withan eyewash facility and a safety shower.

Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: If necessary, wear respiratory protection.

Glove: If necessary,wear protective gloves.

Recommendations

Eye /Face: Wear eye protection/face protection.

Protection

Skin Protection

9.

: If necessary,wear protective clothing.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: redOdor: Slight solvent odor

pH:5-7

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Flash Point: Not available

Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not available

Upper / Lower Flammability or: Not available

Explosive Limits
Page 5 of 8

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30

Safety Data Sheets
Vapor Pressure: Not available

Density: 0.97g/cm

Water Solubility: Not available

Viscosity: 3.7 - 3.9 mPa/s @25 °C

Vapor Density: Not available

Evaporation Rate

: Not available

10. Stability and Reactivity
Reactivity: No information available.

Chemical Stability: Stable in general.

Possibility of Hazardous: This product may produce toxic gas when heatedabove

Reactionsdecomposition.

Conditions to Avoid: No information available

Incompatible Materials: No information available

Hazardous: No information available

Decomposition
11. Toxicological Information
Acute Toxicity: Oral.gamma.-Butyrolactone (96-48-0) toxicity value = 800mg/kg(source: NITE)
Calculation result = 1378.4118952mg/kg.
Classification result = Category 4.
DermalContains substance of unknown toxicity. Changedfrom Not classified
to Classification not possible.
Inhalation : Vapours, Dusts
Contains substance of unknown toxicity. Changedfrom Not classified
to Classification not possible.
Inhalation : Mists
No data available.

Skin corrosion/: Contains substance of unknown toxicity. Changedfrom Not classified

Irritation

to Classification not possible.

Serious eye damage/: Diethylene glycol diethyl ether (112-36-7), Category 2A
Page 6 of 8

Safety Data Sheets
irritation

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541
First issue: 2019/01/07
Revised: 2024/01/30.gamma.-Butyrolactone (96-48-0), Category 2A (source: NITE)
Sum of Eye category 2A Concentration limit = 10%.
Classification result = Category 2A.

Respiratory: Unable to classify due to insufficient data.

sensitization
Skin sensitization: Unable to classify due to insufficient data.

Germ cell mutagenicity: Contains substance of unknown toxicity. Changedfrom Not classifiedto Classification not possible.

Carcinogenicity: Unable to classify due to insufficient data.

Reproductive toxicity: Unable to classify due to insufficient data.

Specific target organ: .gamma.-Butyrolactone (96-48-0), Category 2 (central nervous

toxicity -system), Category 3 (narcotic effect) (source: NITE)

Singleexposure

96-48-0 >= 1% Classification result = Category2 (central nervoussystem)

Specific target organ: Unable to classify due to insufficient data.

toxicity Repeatedexposure
Aspiration hazard: Unable to classify due to insufficient data.

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Ecotoxicity: No information available.

Persistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

Other Toxicity: No information available for the product.

13. Disposal Considerations
Disposal Methods: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

Residual Waste: Before disposal, make the wastes harmless, stabilized, andPage 7 of 8

Safety Data Sheets

Product Name: BS4 ink Blue Shade Magenta
SDS No. 037-S184541First issue: 2019/01/07
Revised: 2024/01/30

neutralized, and minimize danger andtoxicity of the wastes. Dispose ofwaste in accordance with local, state and federal regulations.
Contaminated: Passed to a licensed waste contractor.

Container andIn case of disposal of empty containers, remove thecontent

Packagingthoroughly.

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
US DOT Information: Not dangerous goods

IATA Information: Not dangerous goods

IMDG Information: Not dangerous goods

15. Regulatory Information
New Jersey - RTK: New Jersey - RTK (Right to Know) – Hazardous Substance List(Right to Know)
California: California - Safer Consumer Products – Informational List ofCandidate Chemicals and Chemical Groups.

16. Other Information
References: NITE GHS
EU CLP Regulation, AnnexVI

This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 8 of 8