Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
1.

Identification

Product Name

: Cleaning solution RS

Order No.

: SPC-0336

General Use: Cleaning solution for ink jet printer

Product Description: Solvent liquid

SDS Number: 037-C014621

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE, suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[Classification of the substance or mixture]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Dermal: Category 4

Eye Damage / Irritation: Category 1

Specific Target Organ Toxicity: Category 1(Single Exposure)Specific Target Organ Toxicity: Category 2(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.
[Label Elements]

Page 1 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
SymbolSignal Word
DangerHazard Statements
H227 Combustible liquid.
H312 Harmful in contact with skin.
H318 Causes serious eye damage.
H370 Causes damage to organs.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements[Prevention]
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands and eyes thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor.
(P305+) P310 (IF IN EYES ) Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use water spray/fog for extinction.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
NFPA Rating (scale 0 – 4)
Health = 32Flammability = 2
Instability = 0

30Special =3.

Composition / Information on Ingredients[Substances]
See section below for composition of Mixtures
Page 2 of 14

Safety Data Sheets

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Mixtures
No

Chemical Name

Wt%

CAS No.

1Ethylene glycol monobutyl ether acetate

90-100112-07-2

2

Cyclohexanone

1-10

108-94-1

The specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
4.

First Aid Measures[Description of first aid measures]
Eye Contact: If this product comes in contact with the eyes:
Wash out immediately with water.
If irritation continues, seek medical attention.
Removal of contact lenses after an eye injury should only beundertaken by skilled personnel.

Skin Contact

If skin or hair contact occurs:
Immediately flush body and clothes with large amounts of water,using safety shower if available.
Quickly remove all contaminated clothing, including footwear.
Wash skin and hair with running water. Continue flushing withwater until advised to stop by the Poisons Information Centre.
Transport to hospital, or doctor.

Inhalation: If fumes or combustion products are inhaled remove fromcontaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be
removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with ademand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
Transport to hospital, or doctor, without delay.

Ingestion: Immediately give a glass of water.
First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.

Indication of Immediate: Treat symptomatically.

Medical Attention andSpecial Treatment
NeededPage 3 of 14

Safety Data Sheets
5.

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Fire Fighting Measures[Extinguishing Media]
Extinguishing Media: Foam. Dry chemical powder. BCF (where regulations permit).
Carbon dioxide. Water spray or fog - Large fires only.

[Special hazards arising from the substrate or mixture]
Fire Incompatibility: None known.

[Advice for firefighters]
Fire Fighting: Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or
water course.
Use water delivered as a fine spray to control fire and cool adjacentarea.
Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected
location.
If safe to do so, remove containers from path of fire.

Fire/Explosion Hazard: Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent
rupture of containers.
On combustion, may emit irritating/ toxic fumes.
May emit acrid smoke.
Mists containing combustible materials may be explosive.
May emit poisonous fumes.

6.

Accidental Release Measures

Personal precautions,: See section 8.

protective equipment andemergency procedures
Environmental: See section 12.

precautions[Methods and material for containment and cleaning up]
Page 4 of 14

Safety Data Sheets
Minor Spills

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29: Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective
equipment.
Contain and absorb spill with sand, earth, inert material orvermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.

Major Spills: Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or
water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency
services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.
7.

Handling and Storage[Precautions for safe handling]
Safe handling: Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Page 5 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets

Work clothes should be laundered separately. Launder contaminatedclothing before re-use.
[Conditions for safe storage, including any incompatibilities]
Safe Storage: Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly forleaks.
Observe manufacturer's storage and handling recommendations
contained within this SDS.

Storage: None known

incompatibility
8.

Exposure Controls / Personal Protection[Control parameters]
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Ingredient

SourceEthylene glycol

US ACGIH Thresholdmonobutyl ether

Limit Values (TLV)

acetateUS NIOSH

TWA

STEL

Peak

Notes

20 ppmNot Available

Not Available

TLV® Basis:
Hemolysis

33 mg/m3 / 5 ppm

Not Available

Not Available

Not Available

200 mg/m3 / 50

Not Available

Not Available

Not Available

50 ppmNot Available

TLV® Basis: Eye

Recommended Exposure
Limits (RELs)
Cyclohexanone

US OSHA Permissible
Exposure Levels (PELs) –ppm

Table Z1
US ACGIH Threshold

20 ppmLimit Values (TLV)US NIOSH
Recommended Exposure& URT irr
100 mg/m3 / 25

Not Available

Not Available[skin]

ppm

Limits (RELs)

EMERGENCY LIMITS
Ingredient

TEEL-1

TEEL-2

TEEL-3
Page 6 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
Ethylene glycol monobutyl ether acetate

15 ppm35 ppm210 ppm

Cyclohexanone

60 ppm830 ppm

5,000 ppm

Ingredient

Original IDLH

Revised IDLH

Not Available

Not Available

5,000 ppm

700 ppm

Ethylene glycol monobutyl
ether acetate
Cyclohexanone
Exposure Controls
Appropriate: General exhaust is adequate under normal operating conditions.

Engineering Controls

Provide adequate ventilation in warehouse or closed storage areas.

Personal protection
Eye and face

: Safety glasses with side shields.

protection

Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may
absorb and concentrate irritants.

Hands/feet protection: Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber

Body protection: P.V.C. apron.

Respiratory Protection: Consult with a health and safety professional for specific respirators
appropriate for your use.

Thermal hazards

9.

: Not Available.

Physical and Chemical Properties[Information on basic physical and chemical properties]
Appearance- Physical State: liquid- Color: Clear liquid

Odor: Solvent odour

Odour threshold: Not Available

pH (as supplied): Not Available

Melting point / freezing point (°C)

: Not Available

Initial boiling point and boiling range (°C)

: 191
Page 7 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
Flash point (°C)

: 74.3

Evaporation rate

: Not Available

Flammability: Combustible

Upper Explosive Limit (%): 10.7Lower Explosive Limit (%): 0.8

Vapour pressure (kPa): Not Available

Solubility in water (g/L): Immiscible

Vapour density (Air = 1)

: Not Available

Relative density (Water = 1)

: 0.938

Partition coefficient n-octanol / water: Not Available

Auto-ignition temperature (°C)

: 340

Decomposition temperature: Not Available

Viscosity (cSt): Not Available

Molecular weight (g/mol): Not Available

Taste: Not Available

Explosive properties: Not Available

Oxidising properties: Not Available

Surface Tension (dyn/cm or mN/m): Not Available

Volatile Component (%vol): Not Available

Gas group: Not Available

pH as a solution (1%): Not Available

VOC g/L: Not Available

10. Stability and Reactivity
Reactivity: Stable under normal conditions of use.

Chemical Stability: Unstable in the presence of incompatible materials.
Product is considered stable.

Possibility of Hazardous: Hazardous polymerisation will not occur.

Reactions
Conditions to Avoid: See section 7

Incompatible Materials: See section 7

Hazardous: See section 5

Decomposition
11. Toxicological Information
Page 8 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
Acute Toxicity: Category 4, as a product- Dermal
TOXICITYIRRITATIONAs a productNot Available

Not Available

Ethylene glycol

Not Available

Not Available

Not Available

Not Available

monobutyl ether acetate
Cyclohexanone[Information on toxicological effects]
Inhaled: There is strong evidence to suggest that this material can cause, if
inhaled once, very serious, irreversible damage of organs.
The material is not thought to produce adverse health effects orirritation of the respiratory tract (as classified by EC Directives using
animal models). Nevertheless, good hygiene practice requires that
exposure be kept to a minimum and that suitable control measures beused in an occupational setting.

Ingestion: There is strong evidence to suggest that this material can cause, if
swallowed once, very serious, irreversible damage of organs.
The material has NOT been classified by EC Directives or otherclassification systems as 'harmful by ingestion'. This is because of thelack of corroborating animal or human evidence.

Skin Contact: There is strong evidence to suggest that this material, on a single
contact with skin, can cause very serious, irreversible damage oforgans.
The liquid may be able to be mixed with fats or oils and may degrease
the skin, producing a skin reaction described as non-allergic contact
dermatitis. The material is unlikely to produce an irritant dermatitis as
described in EC Directives.
Open cuts, abraded or irritated skin should not be exposed to thismaterial.
Entry into the blood-stream, through, for example, cuts, abrasions or
lesions, may produce systemic injury with harmful effects. Examine theskin prior to the use of the material and ensure that any external
damage is suitably protected.

Eye: Although the liquid is not thought to be an irritant (as classified by EC
Directives), direct contact with the eye may produce transient
discomfort characterised by tearing or conjunctival redness (as with
Page 9 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
windburn).
Chronic: Substance accumulation, in the human body, is likely and may causesome concern following repeated or long-term occupational exposure.

Skin: Data Not Available to make classification

Irritation/Corrosion
Serious Eye: Category 1, as a productDamage/Irritation
Respiratory or Skin

: Data Not Available to make classification

sensitisation
Mutagenicity: Data Not Available to make classification

Carcinogenicity: Data Not Available to make classification

Reproductivity: Data Not Available to make classification

STOT – Single: Category 1, as a productExposure
STOT – Repeated: Category 2, as a productExposure
Aspiration Hazard: Data Not Available to make classification

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Toxicity
IngredientAs a product
Ethyleneglycolmonobutyl
ether acetate

Cyclohexanone

Endpoint

Test Duration

SpeciesValue

Not Applicable

Not Applicable

Not Applicable

LC50

96

Fish

41.186mg/L

3

EC50

48

Crustacea=37mg/L

1

EC50

96

3.228mg/L

3

EC0

48

Crustacea=10mg/L

1

LC50

96

Fish

71.940mg/L

3

EC50

72

32.9mg/L

5

EC10

72

3.56mg/L

4

Not
Applicable(hr)

Algae or otheraquatic plants

Algae or otheraquatic plants
Algae or other

SOURCE
Not
Applicable

Page 10 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets

aquatic plants
NOEC
Legend:24

Fish

ca.5mg/L

1

1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances – Ecotoxicological Information -Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data

Mobility: No information available for the product.

Persistence and: No information available for the product.

Degradability
Bioaccumulative: No information available for the product.

Potential
Other Adverse Effects: No information available for the product.

13. Disposal Considerations
Disposal Methods: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Marine Pollutant: No

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport: NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS(ICAO-IATA / DGR)
Sea transport: NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS(IMDG-Code / GGVSee)Transport in bulk

: Not Applicableaccording to Annex II of
MARPOL and the IBC
code

Page 11 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets
15. Regulatory Information[Safety, health and environmental regulations / legislation specific for the substance or mixture]
Chemical Name

Regulatory

ETHYLENE GLYCOL MONOBUTYL

US - California OEHHA/ARB - Acute Reference

ETHER ACETATE(112-07-2)

Exposure Levels and Target Organs (RELs)
US - California OEHHA/ARB - Chronic Reference
Exposure Levels and Target Organs (CRELs)
US - Pennsylvania - Hazardous Substance List
US ACGIH Threshold Limit Values (TLV)US ACGIH Threshold Limit Values (TLV) – arcinogens
US Clean Air Act - Hazardous Air Pollutants
US EPCRA Section 313 Chemical List
US NIOSH Recommended Exposure Limits (RELs)
US Toxic Substances Control Act (TSCA) - Chemical
Substance Inventory

CYCLOHEXANONE(108-94-1)

International Agency for Research on Cancer (IARC) –Agents Classified by the IARC Monographs
US - Alaska Limits for Air Contaminants
US - California Permissible Exposure Limits for
Chemical Contaminants
US - Hawaii Air Contaminant Limits
US - Idaho - Limits for Air Contaminants
US - Massachusetts - Right To Know Listed Chemicals
US - Michigan Exposure Limits for Air Contaminants
US - Minnesota Permissible Exposure Limits (PELs)
US - Oregon Permissible Exposure Limits (Z-1)
US - Pennsylvania - Hazardous Substance List
US - Rhode Island Hazardous Substance List
US - Tennessee Occupational Exposure Limits - Limits
For Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A
Final Rule Limits for Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A
Transitional Limits for Air Contaminants
US - Washington Permissible exposure limits of air
contaminants
Page 12 of 14

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

Safety Data Sheets

US - Wyoming Toxic and Hazardous Substances Table
Z1 Limits for Air Contaminants
US ACGIH Threshold Limit Values (TLV)US ACGIH Threshold Limit Values (TLV) - arcinogens
US NIOSH Recommended Exposure Limits (RELs)
US OSHA Permissible Exposure Levels (PELs) - Table
Z1
US Toxic Substances Control Act (TSCA) - Chemical
Substance Inventory[Federal Regulations]Superfund Amendments and Reauthorization Act of 1986 (SARA)SECTION 311/312 HAZARD CATEGORIES
Immediate (acute) health hazard: Yes

Delayed (chronic) health hazard: Yes

Fire hazard: Yes

Pressure hazard: No

Reactivity hazard: No

US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR
302.4)
Name

Reportable Quantity in Pounds (lb)Reportable Quantity in kg

Cyclohexanone

5000

2270

[State Regulations]
US. CALIFORNIA PROPOSITION 65
None Reported[National Inventory]
Australia - AICS:Y

Canada - DSL:YCanada - NDSL:Y

China - IECSC:Y

Europe - EINEC / ELINCS / NLP:YJapan - ENCS

:Y

Korea - KECI:YNew Zealand - NZIoC:YPhilippines - PICCS:Y

USA - TSCA:YY = All ingredients are on the inventory
Page 13 of 14

Safety Data Sheets

Product Name: Cleaning solution RS
SDS No. 037-C014621
First issue: 2019/01/31
Revised: 2019/10/29

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 14 of 14