Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:

Safety Data Sheets
1.

Identification

Product Name

: Maintenance Liquid 09

Order No.

: ML009-Z-K1

General Use: Cleaning solution for ink jet printer

Product Description: Aqueous liquid

SDS Number: 037-C040335

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0100

Emergency Telephone No.

: +81-268-64-2281

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Acute Toxicity – Inhalation: Not classified

Skin Corrosion / Irritation: Not classified

Eye Damage / Irritation: Category 2

Sensitization – Skin

: Not classified

Germ Cell Mutagenicity: Not classified

Toxic to Reproduction: Not classified

Specific Target Organ Toxicity: Category 2 (central nervous system)(Single Exposure)

Page 1 of 10

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:

Safety Data Sheets
Environmental Hazards
Hazardous to the Aquatic: Not classified

Environment - Acute Hazard
Hazardous to the Aquatic: Not classified

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
WarningHazard Statements
H227 Combustible liquid
H319 Causes serious eye irritationH371 May cause damage to organs (central nervous system)
Precautionary Statements[Prevention]
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor.
P337+P313 If eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use water spray, sands, foam, dry chemical powder or carbon
dioxide for extinguish.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international regulation(to be specified).

Page 2 of 10

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:Safety Data Sheets
NFPA Rating (scale 0 – 4)
Health = 1
2

Flammability = 2
1

Instability = 1

1

Special =3.

Composition / Information on Ingredients

Substance or Mixture: SubstanceNo

Chemical Name

Wt%

CAS No.

1Diethyleneglycol monobutyl ether

100

112-34-5

OSHA Hazardous:Component 1 is not hazardous component.

Components(29 CFR 1910. 1200)
4.

First Aid Measures

Inhalation: If breathing is difficult, remove victim to fresh air and keep at restin a position comfortable for breathing. Call a POISON CENTER ordoctor/ physician. Get medical advice/attention if you feel unwell.

Eye Contact: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. Get medicaladvice/attention.

Skin Contact: Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower. Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.

Ingestion: Immediately call a POISON CENTER or doctor/physician.

Page 3 of 10

Safety Data Sheets
5.

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:Fire Fighting Measures

Flammable Properties: Combustible liquid.
Flash point : 78℃ (Method : Closed cup)
Upper/lower flammability or explosive limits : 0.4 - 24.6 vol%Auto-ignition : 224℃
During combustion: Harmful or toxic vapors (e.g. Carbon monoxide)
are released.

Extinguishing Media: Use water spray, sand, foam, dry chemical powder or carbon dioxide.
(Unsuitable media ; Straight spray)

Fire Fighting: Wear full fire-fighting turn-out gear (full bunker gear) andInstructions

respiratory protection (self-contained breathing apparatus).
Keep personal removed from and up wind of fire.

6.

Accidental Release Measures

Personal precautions,: Wear proper protective equipment, keep personal removed from.

protective equipment and- Avoid contact with skin and eyes

emergency- Appropriate gloves

Procedures- Safety glasses- Shuts off all sources of ignition

Environmental: Large Spill: Dike far ahead of liquid spill for later recovery andprecautions

disposal. Prevent entry into waterways, sewers, basements orconfined areas.

Methods and materials: Do not wash away into public drainage way or river. Shut off allfor containment andsources of ignition; No smoking or flames in area. Absorb spill withcleaning up

inert material (e.g., dry sand or earth), then place in closed
containers using non-sparking tools. Flush residual spill (area) withcopious amounts of water.

Page 4 of 10

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:

Safety Data Sheets
7.

Handling and Storage

Handling: Wear proper protective equipment.
Avoid contact with eyes and other membranes.
In case of handle indoor, required local exhaust.
Keep away from heat, sparks and open flame.-No smoking
Do not breath gases, vapor and spray using in warming, especially.
Make available in the work area emergency shower and eyes wash.

Storage: Close up tight and store it in Fireproof construction warehouse.
Please, use early if opened the vessel.
Exercise routine care in accordance with good industrial hygiene
practice.
Keep away from combustible materials and sources of ignition.
Store in a well-ventilated place. Keep cool. Store locked up.

8.

Exposure Controls / Personal Protection

Exposure Limit Values
No1

Chemical Name
Diethyleneglycol
monobutyl ether

Occupational exposure limit values
ACGIH TLVTWA : 10ppm(inhalable fraction and vapor)

JSOH

Not applicable

OSHA PEL

Not applicable

Exposure Controls
Occupational Exposure Controls
Engineering Controls: Use exhaust ventilation to keep airborne concentration below
exposure limits.

Personal Protection
Respiratory: An air purifying respirator with organic vapor cartridge or canister

Protection

may be permissible under certain circumstances where air-borne
concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited.
Use a positive-pressure, air-supplied respirator if there is any
potential for uncontrolled release, exposure levels are unknown, or in
any other circumstances where air-purifying respirators may not
Page 5 of 10

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:

Safety Data Sheets
provide adequate protection.
Hand Protection: Impervious gloves recommended.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, safety shoes, or whole body suits made from neoprene, asappropriate.

Environmental Exposure Controls: Not available
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: clearness

Odor: Slightly specific odor.

pH: Not available

Melting Point / Melting Range: -76℃

Boiling point: 230℃

Flash Point: 78℃ (Method : Closed cup)

Auto ignition temperature: 224℃

Upper / Lower Flammability or: 0.4～24.6vol%

Explosive Limits
Vapor Pressure: Below 0.1kPa (20℃)

Relative Density: 0.952g/cm3 (20℃)

Solubility: Soluble to water

Viscosity: 6.6mPa･s(20℃)

Surface tension: 29.1mN/m(25℃)

Refractive index: 1.4309(20℃)

Specific heat: 2.29J/g (25℃)
Page 6 of 10

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:

Safety Data Sheets
Vapor latent heat: 311J/g(1013hPa)

10. Stability and Reactivity
Conditions to Avoid: High temperature. Left with opened cap. Store of outdoor.

Stability: Stable usually.

Materials to Avoid: Strong oxidizing agent.

Hazardous Reactions /: Reacts intensely with the strong oxidizing agent.

Decomposition Products
11. Toxicological Information
Acute Toxicity

Eye Irritation:Oral (rat)Dermal (rat)LD50>5000mg/kg

LD50>2000mg: It admitted to produce moderate irritating and damage to ocular
tissue in rabbit eye irritation test and it recovered in 14 days
（ECETOC TR. 64(1995)、PATTY(5th, 2001), and other test is
produced highly irritating（IUCLID(2000)）.

Skin Irritation: Mild irritating and not irritating is obtained in rabbit skin irritation
test(IUCLID(2000) 、BUA(1997) 、HSDB(2997)) and it caused
erythema a part of subject in human patch test （DFGOT VII(1992)、ECETOC TR. 64(1995)、HSDB(2007)).

Skin Sensitization: Non sensitizer in guinea pig maximization test.
(ECETOC TR. 64 1995)

Respiratory: Not Available

Sensitization
Germ cell mutagenicity: The result of the micronucleus test using mouse bone-marrow cells,
which is an in vivo mutagenicity test using somatic cells, is negative(DFGOT VII 1992).

Mutagenicity: Not Available

Carcinogenicity: Not Available

Reproductive and Developmental Toxicity: The bat effect to exposure test materials were not admitted by
one-generation reproductive test using rat by oral route(OECD TG415), one-generation reproductive test by dermal route and 13 weeks
Page 7 of 10

Safety Data Sheets

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:dosage reproductive test
（DFGOT VII(1992), EU-RAR(1997), HSDB (2007)).
Specific target organ: The central nervous system symptom and kidneys disorders istoxicity

reported as acute symptoms (DFGOT VII(1992)).

(single exposure)Specific target organ: The serious effect to 6 weeks(only male rat) and 13 weeks repeatedtoxicity

oral administration test using rats (NOAEL ; 891mg/kg/day (cutoff(repeated exposure)value ; 217mg/kg/day) and 250mg/kg/day)（DFGOT VII(1992)、HSDB(2007)）

Aspiration hazard: Not Available

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: LC50(96h) =1300mg/L of fishes (Lepomis macrochirus)
EC50(48h) >100mg/L of crustacea (Daphnia magna)
EC50(96h) >100 mg/L of algae (Scenedesmus)（EU-RAR, 1999）

Persistence and: BOD5=880mg/L(1g/L soln.), CODMn=880mg/L (1g/L soln.)

Degradability
Bioaccumulative: Water solubility=1,000,000mg/L（PHYSPROP Database、2008)

Potential
Other Adverse Effects: Not Available

13. Disposal Considerations
Steps to be taken in case

: Absorb spills with suitable absorbent like a piece of waste clothes.

material is released orspilled
Waste disposal method: Scrap materials may be disposed by licensed contractor or burn in anapproved incinerator.
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Page 8 of 10

Safety Data Sheets
Neutralizing Chemicals

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:: Generally not required.

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Number: Not applicable.

Proper Shipping Name

: Not applicable.

Class: Not applicable.

Packing Group (PG)

: Not applicable.

Environmental hazard: Not applicable.

Export HS-code: 2909.19-000(Reference information)(Refer to "About the Export HS code" of Sec. 16)

Transport in bulk (according to AnnexⅡ of MARPOL 73/78 and the IBC code.): Poly(2-8)alkylene glycol monoalkyl(C1-C6) ether
Others: Follow all regulations in your country.

15. Regulatory Information
OSHA Status: This product is not hazardous under 29 CFR 1910. 1200.

TSCA Status: TSCA INVENTORY：Listed.
HSP (40 CFR 721.72)(SNURs) : Not Applicable

CERCLA: No RQ is assigned to this generic or broad class, although the class is

Reportable Quantity

a CERCLA hazardous substance. (related to Glycol ethers)(40 CFR 302)
SARA TitleⅢ
Section 302: Not Applicable(40 CFR 355)
Section 313: Listed.

(40 CFR 372)
US CAA Section 111: Listed.

Volatile Organic
Compounds
California Proposition: Not Applicable

65
Canada WHMIS: Classifications of Substances B3, D2BPage 9 of 10

Safety Data Sheets

Product Name: Maintenance Liquid 09
SDS No. 037-C040335
First issue: 2014/12/02
Revised:: Ingredient Disclosure List: 1% (Minimum Concentration)
Others: Please refer to any other federal, state and local regulations.

16. Other Information
References

1) Chemical Risk Information Platform (CHRIP) ;(National Institute of Technology and Evaluation (Japan))2) Possession data
3) Result of the GHS classification in Japan(National Institute of Technology and Evaluation)

About the Export HS: Though the Export HS code has been described as reference

code

information, another code might be applicable because of theinterpretation and the usage, etc. After selecting the Export HS codein the responsibility of the exporter to export, please correspond
appropriately according to the instruction of the customs.

This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

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