Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Safety Data Sheets
1.

Identification

Product Name

: PRE FILL UP SOLUTION

Order No.

: FU010-Z-22

Ink Ver.

:1General Use: Pre fill up solution for ink jet printer

Product Description: Solvent clear liquid

SDS Number: 037-C170266

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Acute Toxicity – Inhalation: Not classified

Eye Damage / Irritation: Category 2

Specific Target Organ Toxicity: Category 3(Single Exposure)(Respiratory irritation, drowsiness or dizziness)

Environmental Hazards
Hazardous to the Aquatic: Not classified

Environment - Acute Hazard

Page 1 of 9

Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Safety Data Sheets
Hazardous to the Aquatic: Not classified

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
Warning
Hazard Statements
H227 Combustible liquid
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
Precautionary Statements[Prevention]
P210 Keep away from open flames and other ignition sources. No smoking.
P261 Avoid breathing gas/mist/vapours.
P264 Wash hands and eyes thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use Alcohol-resistant-related fire foam for extinguish.
[Storage]
P403+P233+P235 Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).

Page 2 of 9Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Safety Data Sheets
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 1

1

Flammability= 2

2 Flammability

Flammability = 2

Reactivity = 1

1Instability = 1

Protective Equipment =B

B Protective Equipment

HealthReactivity

Health =121

1Special = 0

CANADIAN WHMIS SYMBOLS
Not applicable (Manufactured article)
3.

Composition / Information on Ingredients
ChemicalNo

Chemical Name

wt%

CAS No.

1Dipropylene glycol monomethyl ether

35-45

34590-94-8

C7H16O3

2Diethylene glycol diethyl ether

35-45

112-36-7

C8H18O3

3

Triethylene glycol monomethyl ether

15-25

112-35-6

C7H16O4

OSHA Hazardous

FormulaComponents 1 is hazardous components.

Components(29 CFR 1910. 1200)
4.

First Aid Measures

Inhalation: Remove subject to ventilated fresh air. If not breathing, give
artificial respiration right away. If breathing is difficult, giveoxygen. Seek immediate medical attention.

Eye Contact: Immediately flush with room temperature, low pressure, cleanwater for at least 15 minutes. Seek medical attention if eyeirritation continues.

Skin Contact: Wash surface areas with soap and water. Wash soiled clothing
before rewearing. Consult a physician if irritation continues.

Ingestion: Seek medical advice; and attention if stomach continues to be upset.
If swallowed, do not induce vomiting.

Protection To First-Aiders: Wear a tool for appropriate protection. Ventilate.
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Safety Data Sheets
5.

Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Fire Fighting Measures

Flammable Properties: Combustible liquid under Hazard Communication Standard (HCS,U.S.A).
Flash point: about 76°C (Cleveland open cup)
Autoflammability: None
Explosive limits: 1.3~10.4v/v% as dipropylene glycol mono-methylether

Extinguishing Media: Water spray, dry chemical, carbon dioxide or, alcohol foam

Fire Fighting: Extinguish to use fire fighting media or plentiful fog water. Put

Instructions

protection wear without fail in case of fire fighting work; do not workin the leeward.
Wear full fire-fighting turn-out gear (full bunker gear) andrespiratory protection (self-contained breathing apparatus).

6.

Accidental Release MeasuresPersonal Precautions: Remove the person of the leeward. Keep away the person fromperiphery of the place of the leakage. Ventilate sufficiently during
clean-up in case of inside of a house.

Eye or Skin protection required during clean-up. Use proper ventilation.
Environmental: Do not release to sewer, surface- or ground-water.

Precautions
Methods for cleaning up: If a spill occurs, use sponges to wipe-up ink, then rinse area withdamp cloth. Place waste in closed container for disposal. Do notdispose of waste to the sewer. Wash hands with soap and water.

Reference to other: Please refer SECTION 13 for disposal.

sections
7.

Handling and Storage

Handling: Use proper ventilation and no fire in work place. Use spark-proof
tools. Keep out of reach of children and do not drink ink. Make sure
cartridge or bottle is dry. Do not dismantle cartridge.
Avoid contact with skin, eyes or clothing. In the case of skin contact,Page 4 of 9

Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Safety Data Sheets

wash with soap and water.
Storage: Do not store the cartridge or bottle in high or freezing temperatures.
Keep cartridge or bottle out of direct sunlight. Do not store thecartridge or bottle with oxidizing agents or explosives.

8.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical Name

TWA

STEL

600mg/m3

900mg/m3

100ppm150ppmACGIH TLV

100ppmCalifornia

600mg/m3

OELs (8h)100ppmDiethylene glycol

California

33mg/m3

diethyl ether

OELs (8h)5ppm

OSHA PEL
12

Dipropylene glycol
monomethyl ether

Ceiling

Skin

SEN

N.E.

N.E.

N.E.

150ppmN.E

N.E

N.EN.E

N.E

N.E

N.E

N.E

N.E

N.E

N.E

Exposure Controls
Occupational Exposure Controls
Engineering Controls: Use exhaust ventilation to keep airborne concentration below
exposure limits.

Personal Protection
Respiratory: Put self-contained breathing apparatus or organic canister mask.

Protection

Hand Protection: Put safety gloves that resist organic solvents and chemicals.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,Page 5 of 9

Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Safety Data Sheets

apron, boots, or whole body suits made from neoprene, asappropriate.
Environmental Exposure Controls: Not established9.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: ClearOdor: Slightly

pH: Not Applicable

Boiling Point / Boiling Range: No data available

Melting Point / Melting Range: No data available

Flash Point: 76 °C / 169 ° F (Cleveland open cup method, JISK2265-4 )Flammability (Solid, Gas)

: Not Applicable

Explosive Limits: No data available

Relative Density: No data available

Solubility: No data available

Water Solubility: Slightly soluble

Partition Coefficient (n-octanol / Water): No data available

Viscosity: No data available

Vapor Density: No data available

10. Stability and Reactivity
Conditions to Avoid: High and freezing temperatures

Stability: Stable under normal temperature

Materials to Avoid: Oxidizers and explosives

Hazardous Reactions /: Harmful gas may produce when the fire broke out.

Decomposition Products
11. Toxicological Information
Acute Toxicity

Oral LD50: >2500mg/kg (rat)Page 6 of 9

Safety Data Sheets

Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Dermal LD50 : >2000mg/kg (rat)
Eye Irritation: Mild irritant (Rabbit, OECD405)

Skin Irritation: Mild irritant (Rabbit OECD 404)

Corrosivity: Not meet the criteria for classification according to EU Directive
1999/45/EC

Skin Sensitization: Non-sensitizer (LLNA, OECD429)

Mutagenicity: Not meet the criteria for classification according to EU Directive
1999/45/EC: Negative (by Ames Test)

Carcinogenicity: Not meet the criteria for classification according to EU Directive
1999/45/EC: Not contain any substances listed in IARC Monographs (1,2A and 2B)

Toxicity for reproduction: Not meet the criteria for classification according to EU Directive
1999/45/EC

12. Ecological Information
Ecotoxicity: No data available on the adverse effects of this ink on theenvironment

Persistence and: No data available on the adverse effects of this ink on theDegradability

environment

Bioaccumulative: No data available on the adverse effects of this ink on thePotentialenvironment

Results of PBT and: Has not carried out PBT and vPvB assessment

vPvB assessment
Other Adverse Effects: No data available on the adverse effects of this ink on theenvironment

13. Disposal Considerations: Dispose of contents/container to an appropriate treatment anddisposal facility in accordance with applicable laws and regulations,and product characteristics at time of disposal.
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
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Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05

Safety Data Sheets
14. Transport Information

Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
US DOT Information: Not regulated as dangerous goods for transport. *1*1 Class combustible liquid (NA1993), Packing group III for
quantities of 450 liters (119 gallons) or more; not regulated forsmaller quantities

UN number: Not Applicable

UN proper shipping name: Not Applicable

Transport hazard class: Not Applicable

Packing group: Not Applicable

Environmental hazards: Not ApplicableSpecial precautions for user

: Not Applicable

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not Applicable
15. Regulatory Information
OSHA Status：Dipropylene glycol monomethyl ether is hazardous under 29 CFR
1910. 1200. (CAS No. 34590-94-8)

TSCA Status：All components on TSCA INVENTORY.

TSCA Section 4(a)：Not regulated

Final Test Rules
Regulated:
TSCA Section 5
Significant New Use：Ingredient: Diethylene glycol diethyl ether(CAS No. 112-36-7)
Reference: 76FR40850

Rule Regulation:
proposed
TSCA Section 8(a)Preliminary Assessment
Information Rule(PAIR)
TSCA Section 12(b)One-Time Export：Ingredient: Dipropylene glycol monomethyl ether(CAS No.34590-94-8)
Reference: 60FR34879 (The reporting date, 10/3/1995 has passed.)：Ingredient: Diethylene glycol diethyl ether(CAS No. 112-36-7)
Reference: TSCA 5 Proposed SUNR.

Notification Regulated:
Page 8 of 9

Safety Data Sheets
Clean Air Act Section
112, Hazardous Air

Product Name: PRE FILL UP SOLUTIONSDS No. 037-C170266
First issue: 2014/06/26
Revised: 2019/07/05：Diethylene glycol diethyl ether(CAS No. 112-36-7)
Triethylene glycol monomethyl ether(CAS No. 112-35-6)

Pollutants
CERCLA
Reportable Quantity(40 CFR 302)

：Diethylene glycol diethyl ether(CAS No. 112-36-7)
RQ : Not established
Triethylene glycol monomethyl ether(CAS No. 112-35-6)
RQ : Not established

SARA TitleⅢ
Section 302: Not Applicable(40 CFR 355)
Section 313: Diethylene glycol diethyl ether (CAS No. 112-36-7)(40 CFR 372)

Triethylene glycol monomethyl ether (CAS No. 112-35-6)

California Proposition: Not regulated

65
Canada Information: WHMIS Controlled Product:
Not applicable (Manufactured article)

Australia Information: Statement of Hazardous Nature:
Classified as Toxic and Irritant according to criteria of NOHSCNew Zealand: Hazardous Substances and New Organisms Act 1996:

Information

Not regulated

Others: Please refer to any other federal, state and local regulations.

16. Other Information
References

1) Occupational Safety & Health Administration (OSHA)
Hazard Communication Standard (HCS)
2) US Environmental Protection Agency(EPA)
Substance Registry Services(SRS)This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

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