Safety Data Sheets
1.

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Identification

Product Name

: Textile Pigment Ink TP250 Magenta

Order No.

: SPC-0730M-1

General Use: Inkjet printing ink

Product Description: Pigment ink

SDS Number: 037-W250949

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Eye Damage / Irritation: Category 2ASpecific Target Organ Toxicity: Category 2 (kidneys)(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolPage 1 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Signal Word
Warning
Hazard Statements
H319 Cause serious eye irritation
H373 May cause damage to organs through prolonged or repeated exposure(kidney)
Precautionary Statements[Prevention]
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/attention if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).
Other hazards
The following percentage of the mixture consists of ingredient(s) with unknown acutetoxicity: 42.6643 %3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1Ethane-1,2-diol<10107-21-1

2

Diglycol ether derivative<5

Trade Secret3

Humectant<30

Trade Secret

4

Cyclic amide<5

Trade Secret52-(2-(2-Butoxyethoxy)ethoxy)ethanol

1-5

143-22-6

6

Non regulated ingredients>50

Trade Secret

1-5%

9014-85-1

7Polyethylene oxide ether with
2,4,7,9-tetramethyl-5-decyne-4,7-diol (2:1)

The specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.

Page 2 of 14

Safety Data Sheets
4.

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

First Aid Measures

General advice: Never give anything by mouth to an unconscious person. Whensymptoms persist or in all cases of doubt seek medical advice.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen.
If breathing is irregular or stopped, administer artificial respiration.
Get medical attention.

Eye Contact: In case of eye contact, remove contact lens and rinse immediately
with plenty of water, also under the eyelids, for at least 15 minutes.
Get medical advice/ attention.

Skin Contact: In case of contact, immediately flush skin with plenty of water for atleast 15 minutes while removing contaminated clothing and shoes.
Get medical attention if irritation develops and persists. Wash
contaminated clothing before re-use.

Ingestion: If swallowed, call a poison control center or doctor immediately.
Rinse mouth with water. DO NOT induce vomiting unless directed
to do so by a physician or poison control center.

Most important: No applicable data available.

symptoms/effects, acuteand delayed
Protection of first-aiders: No applicable data available.

Notes to physician: No specific intervention is indicated. Treat symptomatically.

5.

Fire Fighting Measures

Flammable Properties: Flash point : >93.3℃

Extinguishing Media: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. Water spray, Dry
chemical, Carbon dioxide (CO2)

Unsuitable Extinguishing: No applicable data available.

Media
Special Hazards: Hazardous decomposition products formed under fire conditions.
(see also section 10) Avoid breathing decomposition products.

Page 3 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Special protective: Exposure to decomposition products may be a hazard to health.

equipment for firefighters

Wear self-contained breathing apparatus for firefighting if
necessary.

Further information: Evacuate personnel to safe areas. Stop spill/release if it can be donewith minimal risk. Do not allow run-off from fire fighting to enterdrains or water courses.

6.

Accidental Release Measures

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before
proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during
clean-up.
Safeguards (Personnel): Avoid contact with skin, eyes and clothing. Ensure adequate
ventilation. Wear suitable protective equipment.

Environmental: Prevent further leakage or spillage if safe to do so. Prevent productprecautions

from entering drains. Clean contaminated floors and objects
thoroughly while observing environmental regulations.

Spill Cleanup: Contain spill. Soak up with inert absorbent material. Collect andcontain contaminated absorbent and dike material for disposal.
Keep in suitable, closed containers for disposal. Ventilate the area.
Clean contaminated floors and objects thoroughly while observing
environmental regulations.

Accidental Release: Dispose of in accordance with local regulations.

Measures7.

Handling and Storage

Handling (Personnel): Avoid inhalation, ingestion and contact with skin and eyes. Do notuse in areas without adequate ventilation. For personal protection
see section "Exposure controls/personal protection"
Handle in accordance with good industrial hygiene and safety
practice. Keep container closed. Keep away from food and drink.
Wash hands before eating, drinking, or smoking. Remove
contaminated clothing and protective equipment before entering
eating areas. Wash contaminated clothing before re-use.
Page 4 of 14

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Safety Data Sheets
Handling (Physical: Normal measures for preventive fire protection.

Aspects)
Dust explosion class: No applicable data available.

Storage: Keep containers tightly closed in a cool, well-ventilated place. Do notstore or consume food, drink or tobacco in areas where they may
become contaminated with this material. Do not reuse empty
container.
Stable under normal conditions.

Storage period: No applicable data available.

Storage temperature: No applicable data available.

8.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical Name

1

Ethane-1,2-diol

ACGIH

TLV-C 100 mg/m3 (Aerosol)

Diglycol ether

OSHA PEL

100 ppm, 600 mg/m3 (8 hr. TWA)

derivative

ACGIH TLV

100 ppm TWA, 150 ppm STEL

Humectant

OSHA PEL

2
3

Component Biological

5 mg/m3 8 hr. TWA Respirable fraction.
15 mg/m3 8 hr. TWA Total dust.

:

Limit Values
Exposure Controls
Occupational Exposure Controls
Appropriate: Ensure adequate ventilation. Maintain air concentrations below

Engineering Controls

occupational exposure standards. General mechanical ventilation isnormally adequate but use local exhaust where necessary tomaintain exposures below acceptable limits.

Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: No personal respiratory protective equipment normally required.
When workers are facing concentrations above the exposure limit
they must use appropriate certified respirators. Consult the
respirator manufacturer to determine the appropriate type ofequipment for a given application. Observe respirator use limitations
Page 5 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

specified by the manufacturer.
Glove: Material: Impervious gloves

Recommendations

Additional protection: Gloves must be inspected prior to use., Gloves
should be discarded and replaced if there is any indication of
degradation or chemical breakthrough., The choice of an appropriate
glove does not only depend on its material but also on other quality
features and is different from one producer to the other., The exact
break through time can be obtained from the protective glove
producer and this has to be observed., Please observe the instructions
regarding permeability and breakthrough time which are provided by
the supplier of the gloves. Also take into consideration the specificlocal conditions under which the product is used, such as the dangerof cuts, abrasion, and the contact time.

Eye /Face: Wear safety glasses or coverall chemical splash goggles.

Protection

Skin Protection: Choose body protection in relation to its type, to the concentration
and amount of dangerous substances, and to the specific work-place.
Lightweight protective clothing and safety shoes are recommended.

Environmental Exposure Controls: Not Available
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color

: red

Odor

: slight

pH: 7.0-9.0

Boiling Point / Boiling Range: Not Available

Melting Point / Melting Range: Not Available

Flash Point: > 93.3℃ Method: closed cup

Upper / Lower Flammability or: Not Available

Explosive Limits
Page 6 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Relative Density: Not Available

Solubility: Not Available

Water Solubility: Not Available

10. Stability and Reactivity
Reactivity: No dangerous reaction known under conditions of normal use.

Conditions to Avoid: Avoid extreme heat. Do not freeze.

Stability: The product is chemically stable under recommended conditions ofstorage, use and temperature.
Stable at normal temperatures and storage conditions.

Possibility of hazardous: None reasonably foreseeable.

reactions
Materials to Avoid: Acids, bases and strong oxidizing agents

Hazardous Reactions /: No decomposition if stored and applied as directed.

Decomposition Products

Under fire conditions:, Carbon monoxide, carbon dioxide andunburned hydrocarbons (smoke).

11. Toxicological Information
No data is available on the product itself. Information given is based on data on the components.
Ethane-1,2-diol
Inhalation: no data available

Dermal LD50

: > 3,500 mg/kg , Mouse

Oral LD50: 1,650 mg/kg , Cat

Skin irritation: No skin irritation, Rabbit

Eye irritation: No eye irritation, Rabbit

Skin sensitization: Does not cause skin sensitization., human

Repeated dose toxicity: Oral(Rat)Target Organs: Kidney
Kidney damage

Carcinogenicity: Not classifiable as a human carcinogen.
Animal testing did not show any carcinogenic effects.

Mutagenicity: Animal testing did not show any mutagenic effects. Tests on bacterial
or mammalian cell cultures did not show mutagenic effects.

Reproductive toxicity: No toxicity to reproduction. No effects on or via lactation.
Page 7 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Animal testing showed no reproductive toxicity.
Teratogenicity: Evidence suggests the substance is not a developmental toxin inanimals.

Diglycol ether derivative
Inhalation 4 h Acute: > 20 mg/l , Rat

toxicity estimate

An LC50/inhalation/4h/rat could not be determined because no
mortality of rats was observed at the maximum achievable
concentration.

Dermal LD50

: 9,500 mg/kg , Rabbit

Oral LD50: 5,180 mg/kg , Rat

Skin irritation: No skin irritation, Rabbit

Eye irritation: slight irritation, Rabbit

Skin sensitization: Patch test on human volunteers did not demonstrate sensitisation
properties., human

Repeated dose toxicity: Oral (Rat) No toxicologically significant effects were found.
Inhalation(multiple species) No toxicologically significant effects were found.
Dermal (Rabbit) - 90 dSkin irritation

Carcinogenicity: Not classifiable as a human carcinogen. Animal testing did not show
any carcinogenic effects. Information given is based on data obtained
from similar substances.

Mutagenicity: Tests on bacterial or mammalian cell cultures did not show
mutagenic effects. Evidence suggests this substance does not cause
genetic damage in animals.

Reproductive toxicity: No toxicity to reproduction. Animal testing showed no reproductive
toxicity. Information given is based on data obtained from similar
substances.

Teratogenicity: Animal testing showed no developmental toxicity.

Humectant
Dermal LD50

: 56,750 mg/kg , Guinea pig

Oral LD50: 27,260 mg/kg , Rat

Skin irritation: No skin irritation, Rabbit

Eye irritation: No eye irritation, Rabbit

Skin sensitization: Does not cause skin sensitization., human

Repeated dose toxicity: Oral(Rat) NOAEL: 8,000 mg/kg
Page 8 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

No toxicologically significant effects were found.
Carcinogenicity: Not classifiable as a human carcinogen.
Animal testing did not show any carcinogenic effects.

Mutagenicity: Tests on bacterial or mammalian cell cultures did not show
mutagenic effects.

Reproductive toxicity: No toxicity to reproduction.
Animal testing showed no reproductive toxicity.

Teratogenicity: Animal testing showed no developmental toxicity.

Cyclic amide
Inhalation: Rat
An LC50/inhalation/4h/rat could not be determined because no
mortality of rats was observed at the maximum achievable
concentration.

Dermal LD50

: > 2,000 mg/kg , Rat

Oral LD50: 8,000 mg/kg , Rat

Skin irritation: No skin irritation, Rabbit

Eye irritation: Eye irritation, Rabbit

Skin sensitization: Does not cause skin sensitization., Mouse
Information given is based on data obtained from similar substances.

Repeated dose toxicity: Oral (Rat) NOAEL: 207 mg/kg Method: OECD Test Guideline 408
Kidney effects

Mutagenicity: Animal testing did not show any mutagenic effects. Tests on bacterial
or mammalian cell cultures did not show mutagenic effects.

Reproductive toxicity: No toxicity to reproduction.
Animal testing showed no reproductive toxicity.

Teratogenicity: Animal testing showed effects on embryo-fetal development at levels
equal to or above those causing maternal toxicity.

2-(2-(2-Butoxyethoxy)ethoxy)ethanol
Dermal LD50

: > 3,540 mg/kg , Rabbit

Oral LD50: > 5,170 mg/kg , Rat

Skin irritation: No skin irritation, Rabbit

Eye irritation: Risk of serious damage to eyes., Rabbit
Information given is based on data obtained from similar substances.

Skin sensitization: Does not cause skin sensitization. Guinea pig
Information given is based on data obtained from similar substances.
Does not cause respiratory sensitisation., Guinea pig
Page 9 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

Information given is based on data obtained from similar substances.
Repeated dose toxicity: Oral (Rat) NOAEL: 320 mg/kg
LOAEL: 1,270 mg/kg Method: OECD Test Guideline 408
No toxicologically significant effects were found., Information given isbased on data obtained from similar substances.

Carcinogenicity: Not classifiable as a human carcinogen. Animal testing did not show
any carcinogenic effects. Information given is based on data obtained
from similar substances.

Mutagenicity: Tests on bacterial or mammalian cell cultures did not show
mutagenic effects. Animal testing did not show any mutagenic effects.
Information given is based on data obtained from similar substances.

Reproductive toxicity: No toxicity to reproduction.
Animal testing showed no reproductive toxicity.
Information given is based on data obtained from similar substances.

Teratogenicity: Animal testing showed no developmental toxicity.

Polyethylene oxide ether with 2,4,7,9-tetramethyl-5-decyne-4,7-diol (2:1)
Inhalation 4 h LC50

: > 5 mg/l , Rat
Information given is based on data obtained from similar substances.

Dermal LD50

: > 2,000 mg/kg , Rat
Information given is based on data obtained from similar substances.

Oral LD50: 6,370 mg/kg , Rat

Skin irritation: No skin irritation, Rabbit

Eye irritation: Risk of serious damage to eyes., Rabbit

Skin sensitization: Does not cause skin sensitization., Mouse
Information given is based on data obtained from similar substances.

Repeated dose toxicity: Ingestion(Rat) - 91 d NOAEL: 200 mg/kg
No toxicologically significant effects were found.

Mutagenicity: Tests on bacterial or mammalian cell cultures did not show
mutagenic effects. Evidence suggests this substance does not cause
genetic damage in animals. Information given is based on dataobtained from similar substances.

Reproductive toxicity: No toxicity to reproduction.
Animal testing showed no reproductive toxicity.

Teratogenicity: Animal testing showed no developmental toxicity.

Product
Carcinogenicity: The carcinogenicity classifications for this product and/or its
Page 10 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

ingredients have been determined according to HazCom 2012,
Appendix A.6. The classifications may differ from those listed in the
National Toxicology Program (NTP) Report on Carcinogens (latest
edition) or those found to be a potential carcinogen in theInternational Agency for Research on Cancer (IARC) Monographs(latest edition).
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, or OSHA, as a
carcinogen.

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Aquatic Toxicity:

Ethane-1,2-diol
96 h LC50

Pimephales promelas (fathead minnow) 72,860 mg/l

96 h ErC50

Pseudokirchneriella subcapitata (green algae) 6,500 mg/l

48 h EC50

Daphnia magna (Water flea) > 100 mg/l OECD Test Guideline 202

Diglycol ether derivative
96 h LC50

Pimephales promelas (fathead minnow) > 10,000 mg/l

72 h ErC50

Selenastrum capricornutum (green algae) > 969 mg/l

48 h EC50

Daphnia magna (Water flea) 1,919 mg/l

Humectant
96 h LC50

Oncorhynchus mykiss (rainbow trout) 54,000 mg/l

48 h EC50

Daphnia magna (Water flea) 1,955 mg/l

Cyclic amide
72 h ErC50

Desmodesmus subspicatus (green algae) > 500 mg/l

48 h EC50

Daphnia magna (Water flea) > 500 mg/l Directive 67/548/EEC, Annex
V, C.2.

Page 11 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

2-(2-(2-Butoxyethoxy)ethoxy)ethanol
96 h LC50

Leuciscus idus (Golden orfe) 2,200 mg/l DIN 38412

72 h ErC50

Desmodesmus subspicatus (green algae) > 612 mg/l

48 h EC50

Daphnia magna (Water flea) 2,210 mg/l

21d

NOEC Danio rerio (zebra fish) > 174.6 mg/l OECD Test Guideline 204
Information given is based on data obtained from similar substances.

21d

NOEC Daphnia magna (Water flea) > 174.6 mg/l OECD Test
Guideline 211
Information given is based on data obtained from similar substances.

Polyethylene oxide ether with 2,4,7,9-tetramethyl-5-decyne-4,7-diol (2:1)
96 h LC50

Fish 52.5 mg/l OECD Test Guideline 203

72 h EC50

Pseudokirchneriella subcapitata (green algae) 15 mg/l
Information given is based on data obtained from similar substances.

72 h NOEC

Pseudokirchneriella subcapitata (green algae) 1 mg/l OECD Test
Guideline 201
Information given is based on data obtained from similar substances.

48 h EC50

Aquatic invertebrates 166 mg/l

Environmental Fate
Ethane-1,2-diol
Biodegradability

Readily biodegradable 90 - 100 % OECD Test Guideline 301

Bioaccumulation

Bioaccumulation is unlikely.

Diglycol ether derivative
Biodegradability

Readily biodegradable

Bioaccumulation

Bioaccumulation is unlikely.

Cyclic amide
Biodegradability

Biodegradable
Readily biodegradable

Bioaccumulation

Bioaccumulation is unlikely.

2-(2-(2-Butoxyethoxy)ethoxy)ethanol
Biodegradability

rapidly biodegradable OECD Test Guideline 301D
Readily biodegradable

Polyethylene oxide ether with 2,4,7,9-tetramethyl-5-decyne-4,7-diol (2:1)
Bioaccumulation

Bioaccumulation is unlikely.

Additional ecological information

No data is available on the product itself. Information given is based on data on the components.
Page 12 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

13. Disposal Considerations
Waste disposal methods: If recycling is not practicable, dispose of in compliance with local- Product

regulations. Never place unused product down any indoor or outdoor
drain.

Waste disposal methods: Do not reuse empty container.

- Container

Contaminated/not cleaned containers should be treated/handled like
product waste.
Dispose of container properly.
Refer to applicable Local, State/Provincial, and Federal Regulations,as well as industry Standards.

Contaminated: No applicable data available.

packaging
14. Transport Information
Us Department of: Not regulated

Transportation (DOT)ICAO/IATA: Not regulated

IMO/IMDG: Not regulated

15. Regulatory Information
TSCA: On the inventory, or in compliance with the inventory

SARA 313 Regulated: Ethane-1,2-diol, 2-(2-(2-Butoxyethoxy)ethoxy)ethanol

Chemical(s)PA Right to Know

: Substances on the Pennsylvania Hazardous Substances List present

Regulated Chemical(s)at a concentration of 1% or more (0.01% for Special Hazardous
Substances): Humectant, Ethane-1,2-diol, Diglycol ether derivative,
Cyclic amide, 2-(2-(2-Butoxyethoxy)ethoxy)ethanol

NJ Right to Know

: Substances on the New Jersey Workplace Hazardous Substance List

Regulated Chemical(s)present at a concentration of 1% or more (0.1% for substances
identified as
carcinogens, mutagens or teratogens): Humectant, Ethane-1,2-diol,
Diglycol ether derivative, 2-(2-(2-Butoxyethoxy)ethoxy)ethanol
Page 13 of 14

Safety Data Sheets

Product Name: Textile Pigment Ink TP250 Magenta
SDS No. 037-W250949
First issue: 2011/10/01
Revised: 2019/11/28

CERCLA Reportable: 88 lbs

Quantity

Based on the percentage composition of this chemical in the product.:2-(2-(2-Butoxyethoxy)ethoxy)ethanol

California Proposition: WARNING:

65

This product can expose you to chemicals including Ethylene
glycol(Ethane-1,2-diol), which is known to the State ofCalifornia to cause birth defects or other reproductive harm.
For more information go to www.P65Warnings.ca.gov.

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 14 of 14