Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Safety Data Sheets
1.

Identification

Product Name

: Acid Dye Ink Ac400 Magenta

Order No.

: AC400-M-2L

General Use: Ink jet printing ink

Product Description: Acid Dye Ink

SDS Number: 037-W451842

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Category Not classifiedHealth Hazards
Sensitization – Skin

: Category 1A

The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolSignal WordWarning
Hazard Statements
H317 May cause an allergic skin reaction.
Page 1 of 11Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Safety Data Sheets

Precautionary Statements[Prevention]
P261 Avoid breathing gas/mist/vapors.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
[Storage]
None.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
NFPA Rating (scale 0 – 4)
Health = 1

1

Flammability = 1

1

Instability = 00

Special =3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1

Waterbalance7732-18-5

2

Proprietary Glycol

30-50Trade Secret3

Pigment

1-5

Trade Secret4

Other additives<3

Trade Secret5

Preservative<0.5

MixtureComponent Related Regulatory Information.
The chemical identity and/or percentage of composition is being withheld as a trade secret.
4.

First Aid Measures

Inhalation: Remove to fresh air and keep at rest in a position comfortable forbreathing. Call a POISON CENTER or doctor/physician if you feelunwell.
Page 2 of 11

Safety Data Sheets
Eye Contact

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. If eye irritation
persists, get medical advice/attention.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before reuse. If skin irritation or rash occurs: Get medical
advice/attention.

Ingestion: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.

Most Important Symptoms/Effects
Acute: mild skin irritation, allergic skin reaction.

Delayed: allergic skin reaction.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Not flammable.

Extinguishing Media: Regular dry chemical, carbon dioxide, water spray, foam.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

MediaSpecial Hazards Arising: Negligible fire hazard during intended use. Irritating and/or toxic

from the Chemical

fumes and gases may be emitted upon the product's decomposition.

Hazardous Combustion: Oxides of carbon.

ProductsFire Fighting Measures: Move material from fire area if it can be done without risk. Use
extinguishing agents appropriate for surrounding fire. Do not scatterspilled material with high-pressure water streams. Cool containers
with water spray until well after the fire is out. Avoid inhalation ofmaterial or combustion by-products. Stay upwind and keep out of lowareas.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible exposure.

Precautions forFirefighters
Page 3 of 11

Safety Data Sheets
6.

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment
and Emergency
Procedures
Methods and Materials: Avoid heat, flames, sparks and other sources of ignition. Stop leak iffor Containment andpossible without personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,isolate hazard area and deny entry. Stay upwind and keep out of lowareas.

Environmental: Avoid release to the environment.

Precautions7.

Handling and Storage

Precautions for Safe

: Avoid breathing vapor or mist. Avoid contact with eyes, skin andHandlingclothing. Wear protective gloves/clothing and eye/face protection. Wash
thoroughly after handling. Contaminated work clothing must not beallowed out of the workplace.

Conditions for Safe

: None needed according to classification criteria.

Storage, including any

Further information on storage conditions: Store and handle in

Incompatibilities

accordance with all current regulations and standards. Store in awell-ventilated area. Keep container tightly closed. Keep cool. Keepseparated from incompatible substances.

Incompatible Materials: oxidizing materials, acids, combustible materials, bases, reducing
agents, metals, metal salts, halocarbons.

8.

Exposure Controls / Personal Protection

Exposure Limit Values: The following constituents are the only constituents of the productwhich have a PEL, TLV or other recommended exposure limit. At thistime, the other constituents have no known exposure limits.
Page 4 of 11

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Safety Data Sheets
ACGIH - Threshold: There are no biological limit values for any of this product's

Limit Values - Biologicalcomponents.

Exposure Indices (BEI)
Exposure Controls
Occupational Exposure Controls
Appropriate: Provide local exhaust or process enclosure ventilation system.

Engineering Controls
Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: Consult with a health and safety professional for specific respirators
appropriate for your use.

Glove

: Wear appropriate chemical resistant gloves.

Recommendations

9.

Eye /Face: Wear splash resistant safety goggles. Provide an emergency eye

Protectionwash fountain and quick drench shower in the immediate work area.

Skin Protection: Wear appropriate chemical resistant clothing.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: redOdor: faint odor

pH: 7 - 10 (20 °C )Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available
Page 5 of 11

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Safety Data Sheets
Decomposition Temperature: Not available

Flash Point: not flammable

Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not available

Explosive Properties: Not available

Oxidizing Properties: Not available

Upper / Lower Flammability or: Not available

Explosive Limits
Vapor Pressure: Not available

Specific Gravity: 1 - 1.1

Solubility: Not available

Water Solubility: soluble

Partition Coefficient (n-octanol / Water): Not available

Viscosity: 3 - 10 mPa・s (20 °C )Vapor Density: Not available

Evaporation Rate

: Not available

10. Stability and ReactivityReactivity: No reactivity hazard is expected.

Chemical Stability: Stable at normal temperatures and pressure.

Possibility of Hazardous: Will not polymerize.

Reactions
Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Containers may
rupture or explode if exposed to heat. Avoid contact with incompatiblematerials.

Incompatible Materials: oxidizing materials, acids, combustible materials, bases, reducing
agents, metals, metal salts, halocarbons.

Hazardous: Oxides of carbon.

Decomposition
11. Toxicological Information
Information on Likely Routes of Exposure
Inhalation: irritation.

Ingestion: irritation.
Page 6 of 11

Safety Data Sheets

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Skin Contact: mild skin irritation, allergic skin reaction

Eye Contact: mild eye irritation

Acute and Chronic Toxicity
Component Analysis -: Product Toxicity Data (Acute Toxicity Estimate)

LD50/LC50

Dermal > 2000 mg/kg
Inhalation – Vapor > 20 mg/L
Oral > 2000 mg/kg

Immediate Effects: mild skin irritation, allergic skin reaction.

Delayed Effects: allergic skin reaction.

Irritation/Corrosivity: mild skin irritation.

DataRespiratory: No information available for the product.

Sensitization
Dermal Sensitization: Available data characterizes components of this product as dermal
sensitization hazards.

Germ Cell: No information available for the product.

Mutagenicity
Carcinogenicity: No information available for the product.

Component: None of this product's components are listed by ACGIH, IARC, NTP,

Carcinogenicity

DFG or OSHA.

Tumorigenic Data

: No information available for the product.

Reproductive Toxicity: No information available for the product.

Specific Target Organ: No target organs identified.

Toxicity - Single
Exposure
Specific Target Organ: No target organs identified.

Toxicity - Repeated
Exposure
Aspiration Hazard: Not expected to be an aspiration hazard.

Medical Conditions: skin disorders and allergies.

Aggravated by Exposure
12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Page 7 of 11

Safety Data Sheets

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Component Analysis -: No LOLI ecotoxicity data are available for this product's

Aquatic Toxicity

components.

Persistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

13. Disposal Considerations
Disposal Methods: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

Component Waste: The U.S. EPA has not published waste numbers for this product'sNumberscomponents.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
US DOT Information: No Classification assigned.

International Bulk

: This material does not contain any chemicals required by the IBC

Chemical Code

Code to be identified as dangerous chemicals in bulk.

15. Regulatory Information
U.S. Federal: None of this products components are listed under SARA SectionsRegulations

302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65),
CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process
safety plan.

SARA Section 311/312: Respiratory/Skin Sensitization.

(40 CFR 370 Subparts Band C) reporting
Page 8 of 11

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Safety Data Sheets
categories
U.S. State Regulations: None of this product's components are listed on the state lists from
CA, MA, MN, NJ or PA

California Proposition: Not listed under California Proposition 65.

65
Canada Regulations: Canadian WHMIS Ingredient Disclosure List (IDL)
The components of this product are either not listed on the IDL or arepresent below the threshold limit listed on the IDL.

Component Analysis – Inventory
Glycols (Trade Secret)
US

Yes

CADSL

EU

No

AU

Yes

PH

Yes

JP-JP-

KR

KECI-

KR

KECI-

KR - REACH

CN

NZ

MXTW

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Yes

Yes

No

Yes

KR - REACHCNNZMXTW

Pigment (Trade Secret)USYes

CANSLEU

EINAU

Yes

PHNoJP-JP-KR

KECI-

KR

KECI-ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

No

Yes

No

Yes

NoNo

Yes

KR - REACH

CN

NZ

MXTW

Other additives (Trade Secret)
US

Yes

CADSL

EU

No

AU

Yes

PH

Yes

JP-JP-

KR

KECI-

KR

KECI-

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

NoNo

Yes

Yes

No

Yes

KR - REACH

CN

NZ

MX

TW

Yes

Yes

Yes

Yes

Preservative (Mixture)
US

Yes

CA

DSL

EU

EIN

AU

Yes

PH

Yes

JP-JP-

KR

KECI-

KR

KECI-ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

16. Other Information
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European RoadTransport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada;
CA/MA/MN/NJ/PA - California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS Page 9 of 11

Safety Data Sheets

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation,and Liability Act; CFR - Code of Federal Regulations (US); CLP - Classification, Labelling, andPackaging; CN - China; CPR - Controlled Products Regulations; DFG - DeutscheForschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous SubstanceDirective; DSL - Domestic Substances List; EC – European Commission; EEC - European
Economic Community; EIN - European Inventory of (Existing Commercial Chemical Substances);
EINECS - European Inventory of Existing Commercial Chemical Substances; ENCS - Japan
Existing and New Chemical Substance Inventory; EPA - Environmental Protection Agency; EU European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA International Air Transport Association; ICAO - International Civil Aviation Organization; IDL Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG International Maritime Dangerous Goods; ISHL - Japan Industrial Safety and Health Law;IUCLID - International Uniform Chemical Information Database; JP - Japan; Kow Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing Chemicals Inventory(KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing Chemicals
Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 - Lethal
Dose/ Lethal Concentration; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List
Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in theWorkplace; MEL - Maximum Exposure Limits; MX – Mexico; NDSL – Non-Domestic Substance
List (Canada); NFPA - National Fire Protection Agency; NIOSH - National Institute for
Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National
Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration;
PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation and Recovery
Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL Short-term Exposure Limit; TCCA – Korea Toxic Chemicals Control Act; TDG - Transportation ofDangerous Goods; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act; TW –Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UN/NA - United Nations/North American; US - United States; VLE - Exposure Limit Value (Mexico); WHMIS - Workplace
Hazardous Materials Information System (Canada).
Disclaimer:This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use in combination
with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.
Page 10 of 11

Safety Data Sheets

Product Name: Acid Dye Ink Ac400 Magenta
SDS No. 037- W451842
First issue: 2017/01/19
Revised: 2019/09/26

Page 11 of 11