Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 1 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

1.

Product and Company Identification

Product Name

: Sb210 maintenance washing liquid

Product Code: SPC-0701

General Use: Machine maintenance

Product Description: Washing liquid

MSDS Number: 031-37C110B

Manufacture-Company Name

: Mimaki Engineering Co., LtdAddress: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 JapanTelephone No.

: +81-268-64-2413

Importer/Distributor Established in USA
Company Name

: MIMAKI USA. INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.ATelephone No.

: 1-678-730-0170

Emergency Telephone No.

: +81-268-64-2281

2.

Hazards Identification

WARNING!
Emergency Overview: May be harmful if swallowed or if inhaled, or absorbed throughakin
May cause skin, eye, and respiratory tract irritation
May produce an allergic reaction
Vapors may be irritating to eyes, nose, throat, and lungs
May cause central nervous system depression
Contains a known or suspected reproductive toxin

Appearance: ClearPhysical State: LiquidOdor: SpecificPotential Health Effects
Principle Routes of Exposure : Inhalation. Skin contact. Eye contact.
Acute Toxicity
Eyes: May cause irritation.

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 2 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

Skin: May be harmful in contact with skin. May be harmful if absorbedthrough skin. May cause irritation. Repeated or prolonged skincontact may cause allergic reactions with susceptible persons.

Inhalation: May be harmful if inhaled. May cause irritation of respiratory tract.
Exposure to high concentrations of vapor may cause central
nervous system depression.

Ingestion: May be harmful if swallowed. May cause additional affects as listed
under "Inhalation".

Chronic Effects: May cause central nervous system depression. Repeated contact
may cause allergic reactions in very susceptible persons. Avoid
repeated exposure. Contains a known or suspected reproductivetoxin.

Aggravated Medical: Allergies. Skin disorders. Respiratory disorders. Central nervous

Conditions

system. Pre-existing eye disorders. Reproductive toxicity.

Environmental Hazard: See Section 12 for additional Ecological Information.

3.

Composition / Information On Ingredients

SUBSTANCE/MIXTURE: MixtureNo

Chemical Name

Wt%CAS No.

1

Benzisothiazolinone l

15-40

2634-33-5

1-534590-94-8

2

Dipropylene glycol monomethylether

3

Methyl pyrrolidone

1-5872-50-4

4

Water

50-70

7732-18-5

OSHA HazardousComponents(29 CFR 1910. 1200): Not hazardous.

ChemicalFormula

H2O

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 3 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

4.

First Aid Measures

General Advice: If symptoms persist, call a physician.

Eye Contact: I Rinse immediately with plenty of water, also under the eyelids, for at least
15 minutes. Keep eye wide open while rinsing. If symptoms persist, call aphysician.

Skin Contact: Wash off immediately with soap and plenty of water removing all
contaminated clothes and shoes. In the case of skin irritation or allergic
reactions see a physician.

Inhalation: Move to fresh air in case of accidental inhalation of vapors. If breathing isdifficult, give oxygen. If symptoms persist, call a physician.

Ingestion: Call a physician or Poison Control Center immediately. Do NOT induce
vomiting. Rinse mouth. Drink plenty of water. Never give anything bymouth to an unconscious person.

Notes to Physician
5.

: May cause sensitization of susceptible persons. Treat symptomatically.

Fire Fighting Measures

Flammable Properties: Not flammable.

Flash Point: Not determined.

Suitable Extinguishing: Use extinguishing measures that are appropriate to localMedia

circumstances and the surrounding environment.

Explosion Data
Sensitivity to Mechanical Impact: NoneSensitivity to Static Discharge: NoneProtective Equipment and: As in any fire, wear self-contained breathing apparatus

Precautions for Firefighterspressure-demand, MSHA/NIOSH (approved orequivalent) and full protective gear.

NFPAHMIS

Health Hazard : 2

Health Hazard : 2Flammability : 0Instability : 0
Physical and Chemical Hazards : -200Flammability : 0
Physical Hazard : 0Personal Protection : -200B

Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 4 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

6.

Accidental Release Measures

Personal Precautions: Use personal protective equipment. Avoid contact with the skin andthe eyes. Evacuate personnel to safe areas. Keep people away fromand upwind of spill/leak.

Environmental Precautions: Prevent entry into waterways, sewers, basements or confinedareas. Do not flush into surface water or sanitary sewer system.
Refer to protective measures listed in Sections 7 and 8.

Methods for Containment: Prevent further leakage or spillage if safe to do so. Prevent spillage
from entering drains.

Methods for Cleaning Up: Use personal protective equipment. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeledcontainers. After cleaning, flush away traces with water.

7.

Handling And Storage

Handling: Handle in accordance with good industrial hygiene and safety practice.
Avoid contact with skin, eyes and clothing. Wear personal protectiveequipment. Ensure adequate ventilation. Keep away from open flames, hot
surfaces and sources of ignition.

Storage: Keep containers tightly closed in a cool, well-ventilated place. Keep inproperly labeled containers. Keep out of the reach of children.

Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 5 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

8.

Exposure Controls / Personal Protection

Exposure Guidelines
Chemical Name

OSHA PELNIOSH IDLH

Dipropylene

STEL: 150 ppm (vacated) TWA: 100 ppm

IDLH: 600 ppm

glycol

TWA: 100 ppm (vacated) TWA: 600 mg/m3

TWA: 100 ppm

S*(vacated) STEL: 150 ppm

TWA: 600 mg/m3(vacated) STEL: 900 mg/m3

STEL: 150 ppm(vacated) S*

STEL: 900 mg/m3

monomethyl

ACGIH TLV

ether
34590-94-8
SodiumCeiling: 2mg/m3 TWA: 2 mg/m3

hydroxide(vacated) Ceiling: 2 mg/m3

IDLH: 10 mg/m3
Ceiling: 2 mg/m3

1310-73-2
OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits.
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value.
NIOSH IDLH: Immediately Dangerous to Life or Health.
Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision inAFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Engineering Measures: Showers
Eyewash stations
Ventilation systems

Personal Protective Equipment
Eye/Face Protection: Safety glasses with side-shields.

Skin and Body: Wear protective gloves/clothing.

Protection

Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 6 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

Respiratory Protection : If exposure limits are exceeded or irritation is experienced,
NIOSH/MSHA approved respiratory protection should be worn.
Positive-pressure supplied air respirators may be required for highairborne contaminant concentrations. Respiratory protection mustbe provided in accordance with current local regulations.

Hygiene Measures: When using, do not eat, drink or smoke. Remove and wash
contaminated clothing before re-use. Provide regular cleaning ofequipment, work area and clothing.

9.

Physical And Chemical Properties

Appearance- Physical state: Liquid- Color: ClearOdor: Specific

Odor Threshold: No information available.

pH: 6-8

Boiling Point / Boiling Range: No information available.

Melting Point / Melting Range: No information available.

Decomposition Temperature: No information available.

Flash Point: No information available.

Autoignition Temperature: No information available.

Flammability Limits in Air: No information available.

Explosion Limits: No information available.

Vapor Pressure: No data available

Specific Gravity: 1.0-1.2(25 degree C)

Solubility: No information available.

Water solubility: Soluble in water

Viscosity: 9-11mPa.s(25 degree C)

Vapor Density: No data available

Evaporation Rate

: No information available

VOC Content (%): 4.32Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018Page 7 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

10. Stability And Reactivity
Conditions to Avoid: None known based on information supplied.

Stability: Stable under recommended storage conditions.

Incompatible Products: Strong oxidizing agents. Alkalis. Acid anhydrides. Halogens.

Hazardous: Carbon oxides. Nitrogen oxides (NOx). Sulfur oxides.

Decomposition Products
Hazardous: Hazardous polymerization does not occur.

Polymerization
11. Toxicologocal Information
Acute Toxicity
Product Information: May be harmful by inhalation, ingestion, or skin absorption.

Component Information
Chemical Name

LD50 Oral

LD50 Dermal

LC50 Inhalation

Dipropylene glycol

5230 mg/kg ( Rat )9500 mg/kg ( Rabbit )-3598 mg/kg ( Rat )2000 mg/kg ( Rabbit )3.1 mg/L ( Rat ) 4 h

monomethyl ether
Methyl pyrrolidone

2500 mg/kg ( Rat )Chronic Toxicity
Chronic Toxicity: May cause central nervous system depression. Repeated contact
may cause allergic reactions in very susceptible persons. Avoid
repeated exposure. Contains a known or suspected reproductivetoxin.

Target Organ Effects: Central nervous system (CNS). Eyes. Respiratory system. Bonemarrow. Lymphatic System. Thymus.

Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 8 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

12. Ecological Information
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Chemical Name
Toxicity to Algae Toxicity to Fish
Dipropylene glycol Toxicity toLC50 96 h: > 10000 mg/L static (Pimephales promelas)-monomethyl ether Microorganisms
Daphnia Magna

LC50 48 h: = 1919 mg/L (Daphnia magna)(Water Flea)
Methyl pyrrolidone Toxicity to Algae EC50 72 h: > 500 mg/L (Desmodesmus subspicatus)
Toxicity to Fish

LC50 96 h: = 1072 mg/L static (Pimephales promelas)
LC50 96 h: = 1400 mg/L static (Poecilia reticulata)
LC50 96 h: = 4000 mg/L static (Leuciscus idus)
LC50 96 h: = 832 mg/L static (Lepomis macrochirus)

Toxicity to-Microorganisms
Daphnia Magna

EC50 48 h: = 4897 mg/L (Daphnia magna)(Water Flea)
Chemical NameLog PowBenzisothiazolinone

1.3

Dipropylene glycol monomethyl ether-0.064

Methyl pyrrolidone-0.46

Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 9 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

13. Disposal Considerations
Waste Disposal Methods: This material, as supplied, is not a hazardous waste according toFederal regulations (40 CFR 261). This material could become ahazardous waste if it is mixed with or otherwise comes in contact witha hazardous waste, if chemical additions are made to this material, orif the material is processed or otherwise altered. Consult 40 CFR 261
to determine whether the altered material is a hazardous waste.
Consult the appropriate state, regional, or local regulations for
additional requirements.

Contaminated Packaging: Do not re-use empty containers.

14. Transport Information
DOT: Not regulated

TDG: Not regulated

MEX: Not regulated

ICAO: Not regulated

IATA: Not regulated

IMDG/IMO: Not regulated

RID: Not regulated

ADR: Not regulated

ADN: Not regulated

UN No.: Not regulated
15. Regulatory Information
International Inventories
TSCA: Complies

DSL: Complies

LegendTSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 10 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).
This product contains a chemical or chemicals which are subject to the reporting requirements ofthe Act and Title 40 of the Code of Federal Regulations, Part 372:
SARA 311/312 Hazard Categories
Acute Health Hazard: Yes

Chronic Health Hazard: Yes

Fire Hazard: No

Sudden Release of Pressure Hazard: No

Reactive Hazard: No

Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to theClean Water Act (40 CFR 122.21 and 40 CFR 122.42):

Chemical NameCWACWACWACWA– Reportable Quantities- Toxic Pollutants- Priority Pollutants- Hazardous Substances

Sodium hydroxideX

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substanceunder the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40
CFR 302):
Chemical Name Hazardous Substances RQs

Extremely Hazardous

RQ

Substances RQs
Sodium hydroxide1000 lb

RQ 1000 lb final RQ
RQ 454 kg final RQ

U.S. State Regulations
California Proposition: WARNING:

65

This product can expose you to chemicals includingN-Methylpyrrolidone, which is known to the State of California tocause birth defects or other reproductive harm. For more
information go to www.P65Warnings.ca.gov.

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110B
First issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 11 of 12

Material Safety Data Sheets

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

U.S. State Right-to-Know Regulations
Chemical NameNew Jersey Massachusetts Pennsylvania

Dipropylene glycolIllinois

Rhode IslandXXXXX

Methyl pyrrolidone

XXX--Sodium hydroxide

XXX

-X

monomethyl ether

International Regulations
Chemical Name

Carcinogen Status

Exposure Limits

Dipropylene glycol monomethyl

Mexico: TWA 100 ppm

ether

Mexico: TWA 60 mg/m3
Mexico: STEL 150 ppm
Mexico: STEL 900 mg/m3

Sodium hydroxide
CanadaMexico: Ceiling 2 mg/m3: This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and theMSDS contains all the information required by the CPR.

WHMIS Hazard Class: D2B Toxic materials

16. Other Information
General Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guide for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered
as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material orin any process, unless specified in the text.

Revision history

Material Safety Data Sheets

Product Name: Sb210 maintenanceWashing liquid
MSDS No.: 031-37C110BFirst issue: Apr 20, 2011
Revised: Aug 31, 2018
Page 12 of 12

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

VersionDateContent

1.0

Apr 20, 2011

First issue.

2.0

Aug 31, 2018

Section15: Proposition65 Information Described