Safety Data Sheets
1.

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:

Identification

Product Name

: Pigment Ink 3 For Textile Magenta

Order No.

: TP3-M-22

Ink Ver.

:2General Use: Inkjet printing ink

Product Description: Pigment ink

SDS Number: 037-W146050

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +81-268-64-2281

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Toxic to Reproduction: Category 2

Specific Target Organ Toxicity: Category 1(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolPage 1 of 11Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:

Safety Data Sheets
Signal WordDanger

Hazard Statements
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P308+P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).
Other Information[Hazards not otherwise classified (HNOC)]
Not Applicable[Other hazards]
Not Applicable[Unknown Acute Toxicity]
25% of the mixture consists of ingredient(s) of unknown toxicity
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 1

1

Flammability= 00 Flammability

Flammability = 0

Reactivity = 00

Instability = 0

Protective Equipment = X

X Protective Equipment

HealthReactivity

Health = 1010

Special = -CANADIAN WHMIS SYMBOLS : Non-controlled

Page 2 of 11

Safety Data Sheets3.

Composition / Information on IngredientsNo

4.

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:Chemical Name

Wt%

CAS No.

1Water55-65

7732-18-5

2Solvent

10-20

Trade Secret3Diethylene glycol

5-15

111-46-6

4Glycerin1-5

56-81-5

5Polymer

1-5

Trade Secret

6

Colorant

1-5

Trade Secret7Others

1-5

Trade SecretFirst Aid Measures

Inhalation: Remove to fresh air.

Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting
lower and upper eyelids. Consult a physician.

Skin Contact: Wash skin with soap and water.

Ingestion: Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects, both acute and delayed
Symptoms: Not Available

Indication of any immediate medical attention and special treatment needed
Note to physicians5.

: Treat symptomatically.

Fire Fighting Measures

Flammable Properties: Flash point ; Not flammable
Explosion data ; No data available

Extinguishing Media: CO2, dry chemical, dry sand, alcohol-resistant foam. Use
extinguishing measures that are appropriate to local circumstances
and the surrounding environment.

Page 3 of 11

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:

Safety Data Sheets
Unsuitable Extinguishing: Caution: Use of water spray when fighting fire may be inefficient.

MediaFire Fighting: As in any fire, wear self-contained breathing apparatus

Instructions

pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6.

Accidental Release Measures

Personal Precautions: Use personal protection recommended in Section 8. Avoid contact
with eyes and skin.

Environmental: Do not allow into any sewer, on the ground or into any body of water.

precautions

See Section 12 for additional Ecological Information.

Methods for containment: Prevent further leakage or spillage if safe to do so.

Methods for cleaning up: Take up with sand or other non-combustible absorbent material andplace into containers for later disposal. Use personal protective
equipment as required.

7.

Handling and Storage

Handling: Handle in accordance with good industrial hygiene and safety
practice.

Storage: No special requirements for writing instruments.

Incompatible materials: None known based on information supplied.

8.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical NameACGIH

OSHA PELNIOSH IDLH

TWA: 15 mg/m3 mist, total particulate
TWA: 5 mg/m3 mist, respirable
2Glycerin(56-81-5)

fractionN.E.

(vacated) TWA: 10 mg/m3 mist, total

N.E.

particulate(vacated) TWA: 5 mg/m3 mist,
respirable fraction
Page 4 of 11

Safety Data Sheets

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:

NIOSH IDLH Immediately Dangerous to Life or Health
Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO
v. OSHA, 965 F.2d 962 (11th Cir., 1992).

Exposure Controls
Occupational Exposure Controls
Engineering Controls: Showers
Eyewash stations
Ventilation systems.

Personal ProtectionRespiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Gloves made of plastic or rubber.

Eye Protection: Wear safety glasses with side shields (or goggles).

Skin Protection: Suitable protective clothing. Apron.

Environmental Exposure Controls: Not available

Page 5 of 11

Safety Data Sheets
9.

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:Physical and Chemical Properties

Appearance- Physical State: liquid- Color: RedOdor: Characteristic odor

pH: 7-9

Boiling Point / Boiling Range: Not Available

Melting Point / Melting Range: Not Available

Decomposition Temperature: Not Available

Flash Point: Not flammable

Auto ignition temperature: Not Available

Upper / Lower Flammability or: Not Available

Explosive Limits
Vapor Pressure: Not Available

Specific Gravity: Not Available

Solubility: Not Available

Water Solubility: dispersible

Viscosity: <10 mPa∙s (25 ℃)

VOC: Not Available

10. Stability and Reactivity
Conditions to Avoid: None known based on information supplied.

Reactivity: No reactivity under the normal usage

Stability: Stable under recommended storage conditions.

Materials to Avoid: None known based on information supplied.

Possibility of Hazardous: None under normal processing.

Reactions
Decomposition Products: None known based on information supplied.

Page 6 of 11

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:

Safety Data Sheets
11. Toxicological Information
Acute Toxicity: 25% of the mixture consists of ingredient(s) of unknown toxicity
Chemical Name

OralDermalInhalation

LD50

LD50LC50Glycerin-(56-81-5)
Diethylene glycol(111-46-6)
Eye Irritation: Not Available

Skin Irritation: Not Available

Sensitization: Not Available

SpecificTarget

Organ> 570> 10 g/kg( Rabbit )

12565

11890

mg/kg

mg/kg

( Rat )( Rabbit )mg/m3( Rat ) 1 h: Category 1 as a product.

Toxicity(Repeated Exposure)
Chronic Toxicity: May cause adverse liver effects.

Carcinogenicity: This product does not contain any carcinogens or potential
carcinogens as listed by OSHA, IARC or NTP.

Reproductive and Developmental Toxicity: Category 2 as a product.
12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.

Page 7 of 11

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:

Safety Data Sheets
Ecotoxicity: Toxic to aquatic life with long lasting effects. Toxic to aquatic life.
38% of the mixture consists of component(s) of unknown hazards tothe aquatic environment
Chemical Name

Fish75200: 96 hGlycerin

Pimephales promelas(56-81-5)

mg/L LC50
flow-throughDiethylene glycol(111-46-6)
Persistence andCrustaces
84000: 48 h
Daphnia magna
mg/L EC50

51 - 57: 96 h
Oncorhynchus mykiss-mL/L LC50 static: Not Available

Degradability
Bioaccumulative: Not Available

Potential
Other Adverse Effects: Not Available

13. Disposal Considerations: Disposal should be in accordance with applicable regional, national and local laws andregulations.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Us Department of Transportation (DOT)
UN Number: Not regulated

Proper Shipping: Not regulated

Name
Hazardous Class: Not regulated

Packing Group (PG)

: Not regulated

Special Provisions: nonePage 8 of 11

Safety Data Sheets
Marine pollutant

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:: Not Applicable

TDG
UN Number: Not regulated

Proper Shipping: Not regulated

Name
Hazardous Class: Not regulated

Packing Group (PG)

: Not regulated

Special Provisions: noneMarine pollutant: Not regulated

MEX
UN Number: Not regulated

Proper Shipping: Not regulated

Name
Hazardous Class: Not regulated

Special Provisions: nonePacking Group (PG)

: Not regulated

IATA
UN Number: Not regulated

Proper Shipping: Not regulated

Name
Hazardous Class: Not regulated

Packing Group (PG)

: Not regulated

Special Provisions: noneSea Transport (IMDG)
UN Number: Not regulated

Proper Shipping: Not regulated

Name
Hazardous Class: Not regulated

Packing Group (PG)

: Not regulated

Special Provisions: noneMarine Pollutant: Not regulated

Environmental hazard: Not Applicable

Page 9 of 11

Safety Data Sheets

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:15. Regulatory Information
U.S. Federal Regulations
CERCLA: This material, as supplied, does not contain any substances regulated

Reportable Quantity

as hazardous substances under the Comprehensive Environmental(40 CFR 302)

Response Compensation and Liability Act (CERCLA) (40 CFR 302) orthe Superfund Amendments and Reauthorization Act (SARA) (40CFR 355). There may be specific reporting requirements at the local,regional, or state level pertaining to releases of this material

SARA TitleⅢ
Section 311/312: Acute health hazard

No(40 CFR 370)

Chronic Health Hazard

NoFire hazard

No

Sudden release of pressure hazard No
Reactive Hazard

No

Section 313: Section 313 of Title III of the Superfund Amendments and(40 CFR 372)

Reauthorization Act of 1986 (SARA). This product contains achemical or chemicals which are subject to the reporting
requirements of the Act and Title 40 of the Code of Federal
Regulations, Part 372

Chemical Name
Triethylene glycol monobutyl ether(143-22-6)
CWA (Clean Water Act)CAS Noweight-%143-22-6<5SARA 313 - Threshold
Values %1.0: This product does not contain any substances regulated as pollutants
pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

U.S. State Regulations
California Proposition: This product does not contain any Proposition 65 chemicals

65
U.S.State: This product contains substances regulated by state right-to-know

Right-to-Know

regulations.

Regulations
Chemical NameGlycerin(56-81-5)

New Jersey

Massachusetts

Pennsylvania

XXX
Page 10 of 11Safety Data Sheets

Product Name: Pigment Ink 3 For Textile Magenta
SDS No. 037-W146050
First issue: 2021/04/26
Revised:Triethylene glycol
monobutyl ether

X-X(143-22-6)
U.S.EPA Label Information
EPA Pesticide: Not Applicable

Registration Number
Canada: This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the SDS
contains all the information required by the CPR

WHMIS Hazard Class: Non-controlledOthers: Please refer to any other federal, state and local regulations.

16. Other InformationReferences

1) LOLI Database (ChemADVISOR, Inc.)
2) Japan National Institute of Technology and Evaluation
3) EU CLP(1272/2008)Annex VI Table 3.1

This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 11 of 11