Material Safety Data Sheets
Sheets1.

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 1 of 10

Product and Company
Company Identification

Product Name

: Pigment Ink For Textile Black

Product Code: SPC-0350K

General Use: Ink jet printing ink

Product Description: Pigment ink

MSDS Number: 031-33W03KC

Manufacture
Company Name

: Mimaki Engineering Co., LtdAddress: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 Japan

Telephone No.

: +81-268-64-2413

Importer/Distributor Established in USA
Company Name

: MIMAKI USA. INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.ATelephone No.

: 1-678-730-0100

Emergency Telephone No.

: +81-268-64-2413

2.

Hazards Identification

Emergency Overview: Causes severe eye irritation. Prolonged or repeated overexposure tothe solvent(s) in this material can cause the following: liver damage,kidney damage, embryofetotoxic effects. Prolonged or repeatedoverexposure to carbon black can cause lung effects.

Potential Health Effects
Inhalation: Inhalation of solvent vapor or mist can cause the following:
irritation of nose, throat, and lungs, headache, nausea.

Eye Contact: Direct contact with material can cause the following: severe
irritation, tearing, reddening.

Skin Contact: Material can cause the following: slight irritation.

Ingestion: Material is possibly harmful if swallowed. Material can cause thefollowing: abdominal pain, vomiting, nausea, depression, diarrhea,gastrointestinal irritation, dizziness.

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 2 of 10

Material Safety Data Sheets
Sheets
Carcinogens: Prolonged or repeated overexposure to carbon black can cause lungeffects.
Modified Carbon black
ACGIH: Not classifiable as a human carcinogen.
IARC: Possible carcinogen.
US CA CRT: Carcinogenic.
NIOSH Potentially carcinogenic.

Potential Environmental: Not available

Effects
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 2*

Health =Flammability= 0

Flammability =Reactivity = 0

Instability =Special =3.

Composition / Information On IngredientsNo

Chemical Name

Wt%

CAS No.

ChemicalFormula1

Acrylic polymer(s)3.0-6.0%

Not Hazardous

Trade Secret2

Modified Carbon black

2.0-4.0%

Trade SecretTrade Secret3

Residual monomers<100.0 PPM

Not Required

4Glycols

11.0-13.0%

Trade SecretTrade Secret5

Pyrrolidone

7.0-9.0%616-45-5

C4H7NO

6

Anionic / nonionic surfactant(s)2.0-4.0%

Trade SecretTrade Secret

7

Water

66.0-69.0%

7732-18-5

H2O

OSHA Hazardous: This product is considered hazardous under the OSHA Hazard

Components

Communication Standard.

(29 CFR 1910. 1200)

Material Safety Data Sheets
Sheets4.

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 3 of 10

First Aid Measures
Measures
Inhalation: Move to fresh air. Give artificial respiration if breathing has
stopped. Consult a physician.

Eye Contact: Immediately flush eye(s) with plenty of water. Get prompt medical
attention.

Skin Contact: Wash with water and soap as a precaution. If skin irritation
persists, call a physician. Wash contaminated clothing before reuse.

Ingestion: Drink 1 or 2 glasses of water. Consult a physician. Never give
anything by mouth to an unconscious person. If vomiting occurs
spontaneously, keep airway clear.

Protection to first-aiders

5.

Fire Fighting Measures
Measures
Flammable Properties

Flash point: Noncombustible
Lower explosion limit: Not applicable
Upper explosion limit: Not applicable

ThermalCombustion generates toxic fumes of the following:, nitrogen oxides

decomposition(NOx), Carbon oxides, sulfur oxides.

Extinguishing Media: Use the following extinguishing media when fighting fires involving
this material:polar solvent (alcohol) foam
Water spray
Dry chemical
Carbon dioxide (CO2)Fire Fighting: Wear full fire-fighting turn-out gear (full bunker gear) andInstructions

respiratory protection (self-contained breathing apparatus).
Evacuate area and fight fire from a safe distance. Containers canrupture and release highly toxic vapors or decomposition products if
exposed to heat. Dried product can burn. Material can splatter above
100C/212F.

Further information: Remain upwind.
Avoid breathing smoke.
Use water spray to cool unopened containers.

Material Safety Data Sheets
Sheets6.

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 4 of 10

Accidental Release Measures
Measures

Methods for cleaning up: Contain spilled liquid with sand or earth. DO NOT use combustible
materials, such as sawdust.
Eliminate all ignition sources, use explosion-proof equipment.
Vacuum or sweep material and place in a disposal container.
The material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems
and bodies of water.

Personal precaution: Appropriate protective equipment must be worn when handling aspill of this material. See SECTION 8, Exposure Controls/PersonalProtection, for recommendations. If exposed to material during
clean-up operations, see SECTION 4, First Aid Measures, for actions
to follow.

7.

Handling And
And Storage

Handling: Keep from freezing - product stability may be affected.
Avoid contact with skin, eyes and clothing.
Wash thoroughly after handling.
Keep container tightly closed.
Store in a cool, dry, well ventilated place.
Do not dismantle a cartridge.
Formaldehyde will be generated under acidic conditions.
Maintain adequate ventilation under these conditions to prevent
exposure to formaldehyde above ceiling of 0.3 ppm.

Storage: 5 - 25 °C (41 - 77 °F)

FURTHER: Monomer vapors can be evolved when material is heated during

INFORMATION

processing operations. See SECTION 8, for types of ventilation
required.
Improper disposal or re-use of this container may be dangerous andillegal. Refer to applicable local, state and federal regulations.
Dispose empty container in a sanitary landfill or by incineration asallowed by state and local authorities.

Material Safety Data Sheets
Sheets8.

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 5 of 10

Exposure Controls / Personal Protection

Exposure Limit Values
No1

Chemical Name

TWASTELCeiling

Skin

SEN

Modified Carbon

OSHA PEL

3.5 mg/m3

N.E

N.E

N.E

N.E

black

ACGIH

3.5 mg/m3

N.E

N.E

N.E

N.E

Exposure Controls
Occupational Exposure Controls
Engineering: Use local exhaust ventilation with a minimum capture velocity of 100

Controls

ft/min. (0.5 m/sec.) at the point of vapor evolution. Refer to the current
edition of Industrial Ventilation: A Manual of Recommended Practice
published by the American Conference of Governmental Industrial
Hygienists for information on the design, installation, use, andmaintenance of exhaust systems.

Personal Protection
Respiratory: A respiratory protection program meeting OSHA 1910.134 and ANSI

Protection

Z88.2 requirements or equivalent must be followed wheneverworkplace conditions warrant a respirator's use. None required if
airborne concentrations are maintained below the exposure limit
listed in Exposure Limit Information. Up to 10 times the exposure
limit: Wear a properly fitted NIOSH approved (or equivalent)
half-mask, air-purifying respirator. Up to 1000 ppm organic vapor:
Wear a properly fitted NIOSH approved (or equivalent) full-facepiece,
air-purifying respirator, OR full-facepiece, airline respirator in thepressure demand mode. Above 1000 ppm organic vapor or Unknown:
Wear a properly fitted NIOSH approved (or equivalent) self-contained
breathing appartus in the pressure demand mode, OR full-facepiece,
airline respirator in the pressure demand mode with emergency
escape provision. Air-purifying respirators should be equipped withNIOSH approved (or equivalent) organic vapor cartridges and R95 orP95 filters.

Hand Protection

Chemical-resistant gloves should be worn whenever this material ishandled. The glove(s) listed below may provide protection againstpermeation. (Gloves of other chemically resistant materials may notprovide adequate protection): Neoprene gloves, Gloves should beMaterial Safety Data Sheets
Sheets

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 6 of 10

removed and replaced immediately if there is any indication ofdegradation or chemical breakthrough. Rinse and remove gloves
immediately after use. Wash hands with soap and water.
Eye Protection

Use chemical splash goggles (ANSI Z87. 1 or approved equivalent).
Eye protection worn must be compatible with respiratory protection
system employed.

Skin Protection

Use chemically resistant apron or other impervious clothing to avoid
prolonged or repeated skin contact.
To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, as appropriate.

Environmental Exposure Controls: Not available

9.

Physical
hysical And
And Chemical Properties

Appearance- Physical state: liquid- Colour: blackOdour: mildpH: 7.5 - 9.5

Boiling Point / Boiling Range: 100 °C ( 212.00 °F) Water

Melting Point / Merting Range: Not available

Decomposition Temperature: Not available

Flash Point: Noncombustible

Auto-Ignition Temperature: Not available

Flammability(solid, gas)

: Not available

Vapour Pressure: 17.0 mmHg at 20 °C (68 °F) Water

Specific Gravity: 0.95 - 1.05Solubility: Not available

Water solubility: DilutableViscosity: 2.500 - 4.000 mPa.s

Vapour density: <1.0Water

Evaporation Rate

: <1.00 Water

VOC: 14.0g/l

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 7 of 10

Material Safety Data Sheets
Sheets
10. Stability
tability And Reactivity
Reactivity
Conditions To Avoid: Avoid temperatures above 177C/350F, the onset of polymer
decomposition.
Thermal decomposition is dependent on time and temperature.

Stability: This material is considered stable.
Product will not undergo polymerization.

Materials To Avoid: Avoid contact with acids, alkalies and strong oxidizing agents.

Hazardous Reactions/: Thermal decomposition may yield acrylic monomers.

Decomposition Products

11. Toxicologocal Information
Acute Toxicity

Component: Glycols
Oral LD50

Dermal LD50

>10,000 mg/kg(rat)>10,000 mg/kg(rabbit)

Inhalant LC50

Component: Modified Carbon black
Oral LD50

Dermal LD50

> 5,000 mg/kg(rabbit)

Inhalant LC50

1 h 27,000 mg/l(rat)

Eye Irritation: Not available

Skin Irritation: rabbit slight irritation

Sensitization: Patch test on human volunteers did not demonstrate sensitization
properties.

Mutagenicity: Not available

Carcinogenicity: Modified Carbon black
ACGIH: Not classifiable as a human carcinogen.
IARC: Possible carcinogen.
US CA CRT: Carcinogenic.
NIOSH Potentially carcinogenic.

12. Ecological Information
Information
Handling is noted because it might influence the environment whenleaking and abandoning it.

Material Safety Data Sheets
Sheets

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 8 of 10

Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Toxicity to fish
LC50 100 mg/l
Toxicity to aquatic invertebrates
EC50 Daphnia magna 100 mg/l

Persistence And: Not available

Degradability
Bioaccumulative: Not available

Potential
Other Adverse Effects: Not available

13. Disposal Considerations
Considerations
When a decision is made to discard this material as supplied, it does not meet RCRA's
characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40 CFR 261.33.
The toxicity characteristic (TC), however, has not been evaluated by the Toxicity Characteristic
Leaching Procedure (TCLP).
Incinerate liquid and contaminated solids in accordance with local, state, and federal regulations.
Do not dump this product into sewers, on the ground or into any body of water.

14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Class/UN Number: Not applicable
DOT, IMO/IMDG : Not regulated
Transportation classification may vary by container volume and may be influenced by regional orcountry variations in regulations.

15. Regulatory
egulatory InformationOSHA Status: This product is considered hazardous under the OSHA Hazard
Communication Standard (29 CFR 1910.1200).

TSCA Status: All components of this product are in compliance with the inventory

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 9 of 10

Material Safety Data Sheets
Sheetslisting requirements of the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.
Cercle Reportable: Not Applicable

Quantity(40 CFR 117, 302)
SARA TitleⅢ
Section 302(40 CFR 355)
Section 311/312: Chronic Health Hazard(40 CFR 370)

Acute Health Hazard

Section 313: This product does not contain a chemical which is listed in Section(40 CFR 372)

313 at or above de minimis concentrations.

CERCLA: Releases of this material to air, land, or water are not reportable to(40 CFR 302. 4)

the National Response Center under the Comprehensive
Environmental Response, Compensation, and Liability Act (CERCLA)or to state and local emergency planning committees under theSuperfund Amendments and Reauthorization Act (SARA) Title III
Section 304.

Pennsylvania: The following chemicals are listed because of the additionalrequirements of Pennsylvania law:
Components:
Formaldehyde
Any material listed as "Not Hazardous" in the CAS REG NO. columnof SECTION 3, Composition/Information On Ingredients, of thisMSDS is a trade secret under the provisions of the Pennsylvania
Worker and Community Right-to-Know Act.

California: This product contains trace levels of a component or components(Proposition 65)

known to the state of California to cause cancer:
Components:

OthersEthyl acrylate

140-88-5

Formaldehyde

50-00-0: This product is a 'controlled product' under the Canadian Workplace
Hazardous Materials Information System (WHMIS).
Please refer to any other federal, state and local regulations.

Material Safety Data Sheets
Sheets

Product Name：Pigment Ink For Textile BlackMSDS No. 031-33W03KC
First issue：Oct 18, 2007
Revised：Jun 13, 2008
Page 10 of 10

16. Other Information
Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and dose not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.
Revision history
VersionDate

Content

1.00

Oct 18, 2007

First issue

2.00

Jun 13, 2008

No.9 VOC