Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets
1.

Identification

Product Name

: BS3 ink Magenta

Order No.

: SPC-0667M / SPC-0693M

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037-S130527

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Eye Damage / Irritation: Category 1

Toxic to Reproduction: Category 1BSpecific Target Organ Toxicity: Category 1 (blood, central nervous system,(Single Exposure)systemic toxicity)

Specific Target Organ Toxicity: Category 2 (kidneys, hematopoietic system)(Single Exposure)Specific Target Organ Toxicity: Category 2(blood, kidneys)(Repeated Exposure)Environmental Hazards

Page 1 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets
Hazardous to the Aquatic: Category 3

Environment - Acute Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H227 Combustible liquid
H318 Cause serious eye damage
H360 May damage fertility or the unborn childH370 Causes damage to blood, central nervous system, central nervous system,
systemic toxicity
H371 May cause damage to kidneys and hematopoietic system
H373 May cause damage to blood and kidneys through prolonged or repeated exposure.
H402 Harmful to aquatic life
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P260 Do not breathe vapor or mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/clothing and eye/face protection.
[Response]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P305+P310 IF IN EYES: Immediately call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.
P370+P378 In case of fire: Use appropriate media for extinction.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents and container in accordance with local, regional, national andinternational regulation.

Page 2 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets

NFPA Rating (scale 0 – 4)
Health = 32

Flammability = 2
Instability = 030Special = None
CANADIAN WHMIS SYMBOLS3.

Composition / Information on Ingredients

NoWt%CAS No.

1Ethylene

glycolbuthyl ether acetate

50-60

112-07-2

2Propylene glycolmethyl ether acetate

15-25

108-65-63Gamma-butyrolactone

15-25

96-48-0

1-10

Trade Secret44.

Chemical Name

Vinyl chloride / Vinyl acetate copolymer
resin

5Quinacridone Magenta

1-10

Trade Secret

6Additives

0.1-5

Trade SecretFirst Aid Measures

Inhalation: Remove person to fresh air and keep comfortable for breathing. Calla POISON CENTER or doctor/physician.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get
immediate medical attention.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before re-use. Get medical attention if irritation develops.

Ingestion: If swallowed, get medical attention.

Page 3 of 12

Safety Data Sheets

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Most Important Symptoms/Effects
Acute: eye damage, blood damage, central nervous system damage,systemic toxicity damage, kidney damage

Delayed: reproductive effects, blood damage, kidney damage

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash point 66±1℃ (TCC)
Auto Ignition Temperature: Not available
Flammable point : Not available

Extinguishing Media: carbon dioxide, regular dry chemical, water spray, alcohol resistantfoam

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

MediaSpecial Hazards Arising: Combustible liquid and vapor.

from the Chemical
Hazardous Combustion: oxides of carbon, oxides of nitrogen

ProductsFire Fighting: Move container from fire area if it can be done without risk. Do notMeasures

scatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stay
away from the ends of tanks. Avoid inhalation of material orcombustion by-products. For fires in cargo or storage area: Coolcontainers with water from unmanned hose holder or monitor
nozzles until well after fire is out. If this is impossible then take thefollowing precautions: Keep unnecessary people away, isolate
hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or
any discoloration of tanks due to fire.

Page 4 of 12

Safety Data Sheets

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible

Precautions forexposure.

Firefighters
6.

Accidental Release MeasuresPersonal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment

Avoid release to the environment.

and Emergency
Procedures
Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas.

7.

Handling and Storage

Precautions for Safe

: Obtain special instructions before use. Do not handle until all safety

Handling

precautions have been read and understood. Keep away from heat,sparks, open flame, and hot surfaces - No smoking. Do not breathe
vapor or mist. Avoid contact with eyes, skin and clothing. Do not eat,drink, or smoke when using this product. Wear protective gloves andeye/face protection. Wash thoroughly after handling. Avoid release tothe environment.

Conditions for Safe

: Store and handle in accordance with all current regulations andStorage, including anystandards. Store in a well-ventilated place. Keep container tightly

Incompatibilities

closed. Keep cool. Grounding and bonding required. Store locked up.
Keep separated from incompatible substances.

Page 5 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets
8.

Exposure Controls / Personal Protection

Exposure Limit Values
No

Chemical Name
Ethylene

1TWAglycol

ACGUH

20 ppm TWANIOSH

5 ppm TWA; 33 mg/m3 TWA

monobuthyl ether
acetate (112-07-2)

Component Biological: There are no biological limit values for the component(s) of thisLimit Values

product.

Exposure Controls
Occupational Exposure Controls
Appropriate: Ventilation equipment should be explosion-resistant if explosive

Engineering Controls

concentrations of material are present. Provide local exhaust or
process enclosure ventilation system. Ensure compliance withapplicable exposure limits.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear appropriate chemical resistant gloves.

Eye Protection: Wear splash resistant safety goggles with a faceshield. Provide anemergency eye wash fountain and quick drench shower in theimmediate work area.

Skin Protection: Wear appropriate chemical resistant clothing.

Page 6 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets
OTHER: Overalls. P.V.C. apron. Barrier cream.
Skin cleansing cream.Eye wash unit.

9.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: MagentaOdor: Solvent odor

pH: Not available

Boiling Point / Boiling Range: 145~209 ℃

Melting Point / Melting Range: <-30 ℃

Decomposition Temperature: Not available

Flash Point: 66±1 ℃

Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not applicable

Explosive Properties: Not available

Oxidizing Properties: Not available

Upper / Lower Flammability or: Not available

Explosive Limits
Vapor Pressure: 0.493kPa (20 ℃)

Specific Gravity: 0.995±0.01 (25 ℃)

Solubility: Very small amount

Water Solubility: Not available

Partition Coefficient (n-octanol / Water): Not available

Viscosity: 4.0±0.3 mPa･s (25 ℃)

Vapor Density: Not available

Evaporation Rate

: Not available

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Will not polymerize.

ReactionsPage 7 of 12

Safety Data Sheets
Conditions to Avoid

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31: Avoid flames, sparks, and other sources of ignition. Containers may
rupture or explode if exposed to heat. Avoid contact with incompatible
materials.

Incompatible Materials: acids, bases, oxidizing materials, amines

Hazardous: Combustion: oxides of carbon, oxides of nitrogen

Decomposition
11. Toxicological Information
Acute Toxicity: The component(s) of this material have been reviewed in various

Component Analysis -sources and the following selected endpoints are published:

LD50/LC50
Ethylene glycol monobutyl ether acetate (112-07-2)
Dermal LD50 Rabbit 1480 mg/kg; Oral LD50 Rat 1600 mg/kg
Propylene glycol monomethyl ether acetate (108-65-6)
Dermal LD50 Rabbit >5 g/kg; Oral LD50 Rat 8532 mg/kg
γ-Butyrolactone (96-48-0)
Inhalation LC50 Rat >5100 mg/m3 4 h; Oral LD50 Rat 1540 mg/kg
Information on Likely Routes of Exposure
Inhalation: irritation, chest pain, difficulty breathing, headache, hearing loss,nausea, drowsiness, dizziness, loss of coordination, unconsciousness,cough, reproductive effects, kidney damage, systemic toxicity damage

Ingestion: irritation, nausea, headache, drowsiness, dizziness, loss ofcoordination, unconsciousness, coma, sore throat, vomiting, stomachpain

Skin Contact: irritation, nausea, headache, drowsiness, dizziness, unconsciousness,coma

Eye Contact: eye damage

Immediate Effects: eye damage, blood damage, central nervous system damage, systemic
toxicity damage, kidney damage

Delayed Effects: reproductive effects, blood damage, kidney damage

Medical Conditions: respiratory disorders

Aggravated by Exposure
Irritation/Corrosivity: eye damage

DataPage 8 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets
Respiratory: No information available for the product.

Sensitization
Dermal Sensitization: No information available for the product.

Germ Cell Mutagenicity: No information available for the product.

Carcinogenicity: Component Carcinogenicity
Ethylene glycol monobutyl ether acetate (112-07-2)
ACGIH:DFG:

A3 - Confirmed Animal Carcinogen with Unknown
Relevance to Humans
Category 4 (no significant contribution to humancancer)

γ-Butyrolactone (96-48-0)
IARC:

Monograph 71 [1999]; Supplement 7 [1987];
Monograph 11 [1976] (Group 3 (not classifiable))Vinyl chloride / Vinyl acetate copolymer resin(Proprietary)
IARC:
Reproductive Toxicity

Supplement 7 [1987]; Monograph 19 [1979] (Group 3(not classifiable)): Available data characterizes components of this product asreproductive hazards.

Specific Target Organ
Toxicity - Single: blood, central nervous system, systemic toxicity, kidneys,
hematopoietic system

Exposure
Specific Target Organ: blood, kidneys

Toxicity - Repeated
Exposure
Aspiration Hazard: No information available for the product.

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Harmful to aquatic life.

Component Analysis -: Ethylene glycol monobutyl ether acetate (112-07-2)

Aquatic Toxicity

Algae:
Invertebrate:

72 Hr EC50 Desmodesmus subspicatus: >500 mg/L
48 Hr EC50 Daphnia magna: 37 mg/L
Page 9 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets

Propylene glycol monomethyl ether acetate (108-65-6)
Fish:
Invertebrate:

96 Hr LC50 Pimephales promelas: 161 mg/L [static]
48 Hr EC50 Daphnia magna: >500 mg/L

γ-Butyrolactone (96-48-0)
Algae:
Invertebrate:
Persistence and72 Hr EC50 Desmodesmus subspicatus: 360 mg/L;
96 Hr EC50 Desmodesmus subspicatus: 79 mg/L
48 Hr EC50 Daphnia magna Straus: >500 mg/L

: Not available

Degradability
Bioaccumulation: Not available

Mobility: Not available

Other Toxicity: Not available

13. Disposal Considerations: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Disposal Methods: Dispose in accordance with all applicable regulations.

Component Waste: The U.S. EPA has not published waste numbers for this product'sNumberscomponents.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
IATA Information: Not regulated as dangerous goods for transport.

ICAO Information: Not regulated as dangerous goods for transport.

IMDG Information: Not regulated as dangerous goods for transport.

Page 10 of 12

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

Safety Data Sheets
Marine Pollutant: Ethylene glycol monobutyl ether acetate (112-07-2)
IBC Code: Category Y
Propylene glycol monomethyl ether acetate (108-65-6)
IBC Code: Category Z
γ-Butyrolactone (96-48-0)
IBC Code: Category Y

TDG Information: Not regulated as dangerous goods for transport.

US DOT Information: Not regulated as dangerous goods for transport. *1*1 Class combustible liquid (NA1993), Packing group III for quantities of 450 liters (119 gallons) ormore; not regulated for smaller quantities
15. Regulatory Information
U.S. Federal: None of this products components are listed under SARA Sections

Regulations

302/304 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR
370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4),
TSCA 12(b), or require an OSHA process safety plan.

SARA TitleⅢ: Acute Health: Yes

Section 311/312

Chronic Health: Yes
Fire: Yes
Pressure: No
Reactive: NoU.S. State Regulations: The following components appear on one or more of the following statehazardous substances lists:

Component
Ethylene glycol monobutylether acetate

CAS No.

CAMAMN

NJPA

112-07-2

NoNoNoYesNo

Not regulated under California Proposition 65
Canada: WHMIS CLASSIFICATION: B3, D2A, D2B.

Canadian WHMIS: None of the product component(s) are listed on the Ingredients

Ingredient Disclosure

Disclosure List (IDL).

List (IDL)

Page 11 of 12

Safety Data Sheets

Product Name: BS3 ink Magenta
SDS No. 037-S130527
First issue: 2011/01/13
Revised: 2019/10/31

16. Other Information
Key/Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road
Transport; CAS - Chemical Abstracts Service; CLP - Classification, Labelling and Packaging;
EEC - European Economic Community; EIN (EINECS) - European Inventory of Existing
Commercial Chemical Substances; ELN (ELINCS) - European List of Notified Chemical
Substances; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IMDG - International Maritime Dangerous Goods; IBC Code International Bulk Chemical Code; Kow - Octanol/water partition coefficient; LEL - Lower
Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NTP =National Toxicology Program; REACH - Registration, Evaluation, Authorisation and Restrictionof Chemicals; RID - European Rail Transport; STEL - Short-term Exposure Limit; TWA - Time
Weighted Average; UEL - Upper Explosive Limit
Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 12 of 12