Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets
1.

Identification

Product Name

: AS5 ink Yellow

Order No.

: AS5-Y-60 / AS5-Y-2L

Ink Ver.

:1

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037-S285815

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Serious Eye Damage / Irritation: Category 2ASpecific Target Organ Toxicity: Category 2(central nervous system）(Single Exposure)
The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolPage 1 of 10Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets
Signal WordWarning
Hazard Statements
H227 Combustible liquid.
H319 Causes serious eye irritation.
H371 May cause damage to organs (central nervous system).

Precautionary Statements[Prevention]
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P260 Do not breathe gas/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P337+P313 If eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use appropriate media for extinction[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).
NFPA Rating (scale 0 – 4)
Health = 22

Flammability = 22

Instability = 00

Special =CANADIAN WHMIS SYMBOLS : B3 , D2A , D2B

3.

Composition / Information on Ingredients

No1

Chemical Name
Glycol ether solventsWt%

CAS No.

70-80

Trade Secret
Page 2 of 10

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets
2γ-Butyrolactone

10-20

96-48-0

3Azo nickel pigment

1-10

Trade Secret1-10

Trade Secret

4Chlorinated Ethylene-Vinyl Acetate Copolymer(CEVA)

5

Acrylic Type Compound

1-10

Trade Secret

6

Additive 1

0.1-5

Trade Secret

7

Additive 20.1-5

Trade Secret

The chemical identity and/or percentage of composition is being withheld as a trade secret.
4.

First Aid Measures

Description of Necessary Measures
Inhalation: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor/physician.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes. Removecontact lenses, if present and easy to do. Continue rinsing. Get
immediate medical attention.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before re-use. Get medical attention if irritation develops.

Ingestion: If swallowed, get medical attention.

Most Important Symptoms/Effects
Acute: eye irritation, central nervous system damage

Delayed: No information on significant adverse effects.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash Point: 70 °C
Auto Ignition Temperature: 169 °C (Glycol ether type solvent)
Flammable Point:2.5vol%-33.0Vol% (Glycol ether type solvent)Extinguishing Media: carbon dioxide, regular dry chemical, water spray, alcohol resistantfoam

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

MediaPage 3 of 10

Safety Data Sheets
Special Hazards Arising

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:: Combustible liquid and vapor.

from the Chemical
Hazardous Combustion: Combustion: oxides of carbon, oxides of nitrogen

Products
Fire Fighting Measures: Move container from fire area if it can be done without risk. Do not
scatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stay awayfrom the ends of tanks. Avoid inhalation of material or combustion
by-products. For fires in cargo or storage area: Cool containers withwater from unmanned hose holder or monitor nozzles until well after
fire is out. If this is impossible then take the following precautions:
Keep unnecessary people away, isolate hazard area and deny entry.
Let the fire burn. Withdraw immediately in case of rising sound fromventing safety device or any discoloration of tanks due to fire.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible exposure.

Precautions for
Firefighters
6.

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment
and Emergency
Procedures
Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas.

7.

Handling and Storage

Precautions for Safe

: Keep away from heat, sparks, open flame, and hot surfaces - No
Page 4 of 10

Safety Data Sheets
Handling

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:smoking. Do not breathe vapor or mist. Do not eat, drink, or smoke
when using this product. Wear protective gloves/clothing and eye/faceprotection. Wash thoroughly after handling.

Conditions for Safe

: Store and handle in accordance with all current regulations andStorage, including any

standards. Store in a well-ventilated place. Keep container tightly

Incompatibilities

closed. Keep cool. Grounding and bonding required. Store locked up.
Keep separated from incompatible substances. Incompatible materials
include acids, bases, oxidizing materials, and halogens.

8.

Exposure Controls / Personal Protection

Exposure Limit Values: ACGIH, OSHA, and NIOSH have not developed exposure limits forany of this product's components.

Component Biological: There are no biological limit values for the component(s) of thisLimit Values

product.

Exposure Controls
Occupational Exposure Controls
Appropriate: Ventilation equipment should be explosion-resistant if explosive

Engineering Controls

concentrations of material are present. Provide local exhaust or
process enclosure ventilation system. Ensure compliance withapplicable exposure limits.

Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: Consult with a health and safety professional for specific respirators
appropriate for your use.

Glove: Wear appropriate chemical resistant gloves.

Recommendations

Eye /Face: Wear splash resistant safety goggles with a faceshield. Provide anProtection

emergency eye wash fountain and quick drench shower in theimmediate work area.

Page 5 of 10

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets

Skin Protection: Wear appropriate chemical resistant clothing.

Environmental Exposure Controls: Not available
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: YellowOdor: solvent odorpH

: Not Applicable

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Flash Point: 70℃

Auto ignition temperature: 169 °C (Glycol ether type solvent)

Flammability (Solid, Gas)

: Not available

Upper / Lower Flammability or: 2.5 vol %-33.0 vol % (Glycol ether type solvent)

Explosive Limits
Vapor Pressure: <=0.1 kPa (20°C) (Glycol ether type solvent)Density: 0.971 g/cm3

Water Solubility: Not available

Viscosity: 4.0-4.5 mPa/s @25 °C

Vapor Density: Not available

Evaporation Rate

: Not available

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Containers may
rupture or explode if exposed to heat. Avoid contact with incompatible
materials.
Page 6 of 10

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets
Stability: Stable under normal conditions of use.

Materials to Avoid: acids, bases, oxidizing materials, halogens

Hazardous Reactions /: Combustion: oxides of carbon, oxides of nitrogen

Decomposition Products
11. Toxicological Information
Acute Toxicity
Component Analysis - LD50/LC50

The component(s) of this material have been reviewed in various sources and the following
selected endpoints are published:
Glycol ether solvents (Trade Secret)
Oral LD50 Rat 6500 µL/kg
γ-Butyrolactone (96-48-0)
Oral LD50 Rat 1540 mg/kg Inhalation LC50 Rat >5100 mg/m3 4 h
Additive 2 (Trade Secret)
Oral LD50 Rat 40 g/kg Dermal LD50 Rabbit >20 mL/kg
Information on Likely Routes of Exposure
Inhalation: irritation, nausea, headache, drowsiness, dizziness,unconsciousness, coma.

Ingestion: irritation, nausea, headache, drowsiness, dizziness,unconsciousness, coma.

Skin Contact: irritation, nausea, headache, drowsiness, dizziness,unconsciousness, coma.

Eye Contact: irritation.

Immediate Effects: eye irritation, central nervous system damage.

Delayed Effects: No information on significant adverse effects.

Medical Conditions Aggravated: No information available for the product.

by Exposure
Irritation/Corrosivity Data

: Causes serious eye irritation.

Respiratory Sensitization: No information available for the product.

Dermal Sensitization: No information available for the product.

Germ Cell Mutagenicity: No information available for the product.

Carcinogenicity
Component Carcinogenicity
γ-Butyrolactone (96-48-0)
Page 7 of 10

Safety Data Sheets

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

IARC: Monograph 71 [1999]; Supplement 7 [1987]; Monograph 11 [1976] (Group 3 (notclassifiable))
Chlorinated Ethylene-Vinyl Acetate Copolymer (CEVA) (Trade Secret)
IARC: Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))
Reproductive Toxicity
No information available for the product.
Specific Target Organ Toxicity - Single Exposure
central nervous system.
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
Aspiration Hazard
No information available for the product.
12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Ecotoxicity: Components of this product are hazardous to aquatic life.

Component Analysis - Aquatic Toxicity
γ-Butyrolactone (96-48-0)
Algae: 72 Hr EC50 Desmodesmus subspicatus: 360 mg/L;
96 Hr EC50 Desmodesmus subspicatus: 79 mg/L
Invertebrate: 48 Hr EC50 Daphnia magna Straus: >500 mg/L
Additive 2 (Trade Secret)
Algae: 72 Hr EC50 Desmodesmus subspicatus: 8 mg/L
Mobility: No information available for the product.

Persistence and: No information available for the product.

Degradability
Bioaccumulative: No information available for the product.

Potential
Other Adverse Effects: No additional information is available.

13. Disposal Considerations
Disposal Methods: Empty containers may contain product residue.
Dispose in accordance with all applicable regulations.
Page 8 of 10

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets
Component Waste: The U.S. EPA has not published waste numbers for this product'sNumberscomponents.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

PackagingComply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
IATA Information: Not regulated as dangerous goods for transport.

ICAO Information: Not regulated as dangerous goods for transport.

IMDG Information: Not regulated as dangerous goods for transport.

Marine Pollutant: γ-Butyrolactone (96-48-0)
IBC Code: Category Y

TDG Information: Not regulated as dangerous goods for transport.

US DOT Information: Not regulated as dangerous goods for transport. *1*1 Class combustible liquid (NA1993), Packing group III for quantities of 450 liters (119 gallons) ormore; not regulated for smaller quantities
15. Regulatory Information
U.S. Federal: None of this products components are listed under SARA Sections

Regulations

302/304 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4),
TSCA 12(b), or require an OSHA process safety plan.

SARA 311/312: Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No
Reactive: No

U.S. State Regulations: None of this product's components are listed on the state lists fromCA, MA, MN, NJ or PA.

California Proposition: WARNING:

65

This product can expose you to chemicals including Nickel
compounds, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.
Page 9 of 10

Product Name:AS5 ink Yellow
SDS No. 037-S285815
First issue: 2020/10/06
Revised:

Safety Data Sheets
Canada: WHMIS CLASSIFICATION: B3, D2A, D2B.

Canadian WHMIS Ingredient Disclosure List (IDL): None of the product component(s) are listed on the Ingredients
Disclosure List (IDL).
Chemical Inventory Listings
Component Analysis - Inventory
Component

CASUSCAEUAUPHILJPKR

CNNZ

Glycol ether solvents

Trade SecretYes

NSL

EIN

NoNo

Yes

No

Yes

Yes

γ-Butyrolactone

96-48-0

Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

Yes

Additive 2

Trade Secret

Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

Yes

Azo nickel pigment

Trade Secret

Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

Yes

Chlorinated Ethylene-Vinyl

Trade SecretYes

DSL

No

Yes

Yes

Yes

Yes

Yes

Yes

Acetate Copolymer (CEVA)
16. Other Information
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road
Transport; CAS - Chemical Abstracts Service; CLP - Classification, Labelling and Packaging;
EEC - European Economic Community; EIN (EINECS) - European Inventory of Existing
Commercial Chemical Substances; ELN (ELINCS) - European List of Notified Chemical
Substances; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IMDG - International Maritime Dangerous Goods; IBC Code International Bulk Chemical Code; Kow - Octanol/water partition coefficient; LC50 - Lethal
Concentration, 50%; LD50 - Lethal Dose, 50%; LEL - Lower Explosive Limit; LOLI - List Of
LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value inthe Workplace; MEL - Maximum Exposure Limits; NTP = National Toxicology Program;
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals; RID European Rail Transport; STEL - Short-term Exposure Limit; TWA - Time Weighted Average;
UEL - Upper Explosive Limit
Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.
Page 10 of 10