Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

Safety Data Sheets
1.

Identification

Product Name

: ES3 ink White

Order No.

: SPC-0433W-2

General Use: Ink for ink jet plotter

Product Description: Solvent pigment ink

SDS Number: 037-S040569

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Acute Toxicity – Inhalation: Not classified

Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2

Sensitization – Respiratory: Not classified

Sensitization – Skin

: Not classified

Germ Cell Mutagenicity: Not classified

Carcinogenicity: Not classified

Toxic to Reproduction: Not classified

Page 1 of 10

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

Safety Data Sheets
Specific Target Organ Toxicity: Not classified(Single Exposure)Specific Target Organ Toxicity: Not classified(Repeated Exposure)
Aspiration Hazard: Not classified

The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
WarningHazard Statements
H227 Combustible liquidH315 Causes skin irritation
H319 Causes serious eye irritation
Precautionary Statements[Prevention]
P210 Keep away from open flames and other ignition sources.-No smoking.
P264 Wash hands and eyes thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use alcohol-resistant-related fire foam, dry chemical, carbon
dioxide, water spray, dry sand for extinguish.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international regulation (to be specified).

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Product Name: ES3 ink WhiteSDS No. 037-S040569First issue: 2015/06/22
Revised: 2019/10/30

Safety Data Sheets
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 1

1

Flammability= 2

2 Flammability

Flammability = 2

Reactivity = 1

1Instability = 1

Protective Equipment = B

B Protective Equipment

HealthReactivity

Health = 1211Special = 0

CANADIAN WHMIS SYMBOLS : Not applicable
3.

Composition / Information on Ingredients
ChemicalNo

Chemical Name

Wt%CAS No.

1Diethylene Glycol Diethyl ether

50-65

112-36-7

C8H18O3

2Diethylene Glycol Methyl Ethyl Ether

15-25

1002-67-1

C7H16O3

3

Titanium dioxide

10-2013463-67-7

TiO2

4

Proprietary organic materials

5-15

Trade Secret-4.

FormulaFirst Aid Measures

Inhalation: Remove subject to ventilated fresh air. If not breathing, give
artificial respiration right away. If breathing is difficult, giveoxygen.. Seek immediate medical attention.

Eye Contact: Immediately flush with room temperature, low pressure and cleanwater for at least 15 minutes. Seek medical attention if eyeirritation continues.

Skin Contact: IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash before reuse.
If skin irritation occurs: Get medical advice/attention.

Ingestion: Seek medical advice; and attention if stomach continues to be upset.
IF SWALLOWED: Do not induce vomiting.

Most important symptoms and effects, both acute and delayed: Skin: Ink contact with skin may cause irritation, swelling orredness.
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Safety Data Sheets
5.

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

Fire Fighting Measures

Flammable Properties: Combustible liquid under Hazard Communication Standard (HCS,U.S.A).
Flash point : about 73.7℃ (Closed cup)
Autoflammability: None

Extinguishing Media: Water spray, dry chemical, carbon dioxide or, alcohol foam

Unsuitable Extinguishing: NoneMedia
Fire Fighting: Extinguish to use fire fighting media or plentiful fog water.

Instructions

Put protection wear without fail in case of firefighting work.
Wear full fire-fighting turn-out gear (full bunker gear) andrespiratory protection (self-contained breathing apparatus).
Do not work in the leeward.

6.

Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
For non-emergency: Eye or Skin protection required during clean-up. Use proper

personnelventilation.

For emergency: Noneresponders
Environmental: Do not release to sewer, surface- or ground-water.

precautions:
Methods and material for containment and cleaning up
Advice on how to contain: Use sponges to wipe-up ink.

a spill
Advice how to clean-up: Rinse area with damp cloth. Place waste in closed container fora spilldisposal. Wash hands with soap and water.

Any other information:: Do not dispose of waste to the sewer.

Reference to other: Please refer SECTION 13 for disposal.

sections

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Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

Safety Data Sheets
7.

Handling and Storage

Handling: Use proper ventilation and no fire in work place. Keep out of reach ofchildren and do not drink ink. Do not dismantle cartridge. Avoid
contact with skin, eyes or clothing. In the case of skin contact, wash
hands with soap and water.

Storage: Do not store the cartridge in high or freezing temperatures. Keepcartridge out of direct sunlight. Do not store the cartridge withoxidizing agents or explosives. Make sure cartridge is dry before
insertion into printer housing.
: Not specified

SPECIFIC USES
8.

Exposure Controls / Personal Protection

Exposure Limit ValuesNo
1Chemical Name

TWA

Diethylene glycol diethyl ether

California

The 8-Hour TWA Exposure(CAS No. 112-36-7)

OELs

Value : 5 ppm (33mg/m3)

Titanium dioxide

OSHA PEL

15mg/m3(CAS No. 13463-67-7)

ACGIH TLV

10mg/m3

2

California OELs : California Code of Regulations, Title 8, Section 5155. Airborne ContaminantsExposure Controls
Occupational Exposure Controls
Engineering Controls: Use exhaust ventilation to avoid from exposure.

Personal Protection
Respiratory: An air purifying respirator with organic vapor cartridge or canister

Protection

may be permissible under certain circumstances where air-borne
concentrations are expected to exceed exposure limits. Protection
provided by air purifying respirators is limited. Use apositive-pressure, air-supplied respirator if there is any potential for
uncontrolled release, exposure levels are unknown, or in any othercircumstances where air-purifying respirators may not provide
adequate protection.

Page 5 of 10

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

Safety Data Sheets
Hand Protection: Wear gloves that resist organic solvents and chemicals.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, asappropriate.

Environmental Exposure Controls: Not available
9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: WhiteOdor: SlightlypH: Not Applicable

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: about 73.7℃ (Closed cup)

Auto ignition temperature: Not available

Explosive Properties: Not available

Relative Density: Not available

Solubility (ies): Soluble

Viscosity: Less than 5 mPa・s at 20℃

Vapor Density: Greater than 1 (air = 1)

Evaporation Rate

: Not available

VOC: Not available

Page 6 of 10Safety Data Sheets

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

10. Stability and Reactivity
Conditions to Avoid: High and freezing temperatures

Stability: Stable under normal temperature

Materials to Avoid: Oxidizers and explosives

Hazardous Reactions /: To burn this product may be produce toxic gases.

Decomposition Products
11. Toxicological Information
Acute Toxicity: Not meet the criteria for classification according to EU Directive
1999/45/EC

Eye Irritation: Category 2 as a product (GHS Classification).
Diethylene Glycol Diethyl ether : Category 2A

Skin Irritation: Category 2 as a product (GHS Classification).
Diethylene Glycol Diethyl ether : Category 2

Skin Sensitization: Not meet the criteria for classification according to EU Directive

1999/45/EC
Mutagenicity: Not meet the criteria for classification according to EU Directive
1999/45/EC

Carcinogenicity: Titanium dioxide is classified as “possibly carcinogen to human”(Group 2B) in animal chronic inhalation studies. The tumor
formulation observed in only rats with animal chronic inhalation
study are attributed to “lung overloading”, a generic response toexcessive amounts of any dust retained in the lungs for a prolonged
interval. Use of this product, as intended does not result in inhalationof excessive dust. Epidemiological study to date have not revealed any
evidence of the relation between exposure to titanium dioxide anddiseases of the reparatory tract beyond general effects of dust.

Reproductive Toxicity: Not meet the criteria for classification according to EU Directive
1999/45/EC

Page 7 of 10

Safety Data Sheets

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/3012. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Not available

Persistence and: Not available

Degradability
Bioaccumulative: Not available

Potential
Other Adverse Effects: Not available

13. Disposal Considerations: Dispose of contents/container to an appropriate treatment anddisposal facility in accordance with applicable laws and regulations,and product characteristics at time of disposal.
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Number: Not Applicable

UN proper shipping: Not Applicable

nameTransport hazard: Not Applicableclass(es)Packing group: Not Applicable

Environmental hazards: Not ApplicableSpecial precautions for: Not ApplicableuserPage 8 of 10

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

Safety Data Sheets
15. Regulatory Information
TSCA Section 4(a): Not regulated

Final Test RulesRegulated
TSCA Section 5: Ingredient : Diethylene glycol diethyl ether (CAS No. 112-36-7)

Significant New Use

Reference: 76FR40850

Rule Regulation
proposed
TSCA Section 8(a): Not regulated

Preliminary Assessment
Information Rule (PAIR)
TSCA Section 12(b): Ingredient : Diethylene glycol diethyl ether (CAS No. 112-36-7)

One-Time Export

Reference: TSCA 5 Proposed SNUR

Notification Regulated
Clean Air Act Section: Diethylene glycol diethyl ether (CAS No. 112-36-7)

112, Hazardous Air

Diethylene Glycol Methyl Ethyl Ether (CAS No. 1002-67-1)

Pollutants
EPCRA: Diethylene glycol diethyl ether (CAS No. 112-36-7)(SARA Title III)

Diethylene Glycol Methyl Ethyl Ether (CAS No. 1002-67-1)

Section 313
California Proposition: WARNING:

65

This product can expose you to chemicals including Titanium
dioxide, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.

Canada Information: WHMIS Controlled Product:
Not applicable (Manufactured article)

Australia Information: Statement of Hazardous Nature:
Classified as Irritant according to criteria of NOHSCNew Zealand: Hazardous Substances and New Organisms Act 1996:Information

Not applicable (Manufactured article)

Others: Please refer to any other federal, state and local regulations.

Page 9 of 10

Safety Data Sheets

Product Name: ES3 ink WhiteSDS No. 037-S040569
First issue: 2015/06/22
Revised: 2019/10/30

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 10 of 10