Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
1.

Identification

Product Name

: HS ink Black

Order No.

: SPC-0473K-5, SPC-0589K-5

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037-S060578

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPANTelephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 1

Specific Target Organ Toxicity: Category 3 (Narcotic effects)(Single Exposure)Environmental Hazards
Hazardous to the Aquatic: Category 2

Environment - Acute Hazard
The above list does not include category being non-classifiable or not-applicable.

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Safety Data Sheets

Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H227 Combustible liquid
H315 Cause skin irritation
H318 Cause serious eye damage
H336 May cause drowsiness or dizziness
H401 Toxic to aquatic life
Precautionary Statements[Prevention]
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P261 Avoid breathing gas/mist.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see 4-Response on our website/SDS URL:
www.mimaki.co.jp/sds).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire: Use appropriate media for extinction.
[Storage]
P403+P233+P235 Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents and container in accordance with local, regional, national andinternational regulation.

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Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
HMIS Rating (scale 0 – 4)

NFPA Rating (scale 0 – 4)

Health = 1

1

Flammability= 2

2 Flammability

Flammability = 2

Reactivity = 1

1

Reactivity

Instability = 1

Protective Equipment = G

G Protective Equipment

Special = None3.

Health = 1211Composition / Information on Ingredients

No4.

HealthChemical NameWt%

CAS No.

1Carbon black

0.1-5

Registered

2Cupper compound

0.1-5

Registered

3Vinyl chloride / Vinyl acetate copolymer resin

0.1-5

Registered

4Polyester resin

0.1-5

Registered

5Dipropylene glycol methyl ether acetate

10-2088917-22-0

6

Dipropylene glycol dimethyl ether

30-60

111109-77-4

7

Gamma-Butyrolactone

10-40

96-48-08Additives

0.1-5

RegisteredFirst Aid Measures

Inhalation: If inhaled, immediately remove to fresh air and keep warm andcalm. If breathing irregularly or not breathing, give artificial
respiration and consult a doctor immediately.

Eye Contact: Flush eyes thoroughly with water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Consult an ophthalmologist
immediately.

Skin Contact: Wash skin thoroughly with plenty of water. If on clothing, remove
immediately contaminated clothing.

Ingestion: Do not induce vomiting. If swallowed, keep calm and consult adoctor immediately. Keep from swallowing vomit.

Protection To First-Aiders: Wear tools for appropriate protection. Ventilate. See section 7 and 8.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Page 3 of 10Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Avoid breathing combustion products.
Flash point: 74℃

Ignition point : Not available
Explosion point : 0.85～15.60 vol%Extinguishing Media: Foam, carbon dioxide, dry chemical, water spray

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams

MediaFire Fighting Measures: Move container from fire area if it can be done without risk. Do not
scatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stay
away from the ends of tanks. Avoid inhalation of material or
combustion by-products. For fires in cargo or storage area: Coolcontainers with water from unmanned hose holder or monitor
nozzles until well after fire is out. If this is impossible then take thefollowing precautions: Keep unnecessary people away, isolate
hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or
any discoloration of tanks due to fire.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible

Precautions forexposure.

Firefighters
6.

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment

Avoid release to the environment.

and Emergency
Procedures

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Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of lowareas.

7.

Handling and Storage

Handling: Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
Avoid breathing gas/mist. Wash hands thoroughly after handling.
Use only outdoors or in a well-ventilated area. Avoid release to theenvironment. Wear protective gloves/protective clothing/eye
protection/face protection.

Storage: Store and handle in accordance with all current regulations andstandards. Keep container tightly closed. Keep cool. Grounding andbonding required. Store locked up. Keep separated from incompatible
substances.

8.

Exposure Controls / Personal Protection

Exposure Limit ValuesNo3

Chemical Name

Carbon black(1333-86-4)

TWA
ACGIH

3 mg/m3 TWA (inhalable fraction)

OSHA

3.5 mg/m3 TWA
3.5 mg/m3 TWA; 0.1 mg/m3 TWA (Carbon black inNIOSH

presence of Polycyclic aromatic hydrocarbons, asPAH)

Mexico

3.5 mg/m3 TWA LMPE-PPT
7 mg/m3 STEL [LMPE-CT]

Page 5 of 10

Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Exposure Controls
Occupational Exposure Controls
Engineering Controls: Ventilation equipment should be explosion-resistant if explosive
concentrations of material are present. Provide local exhaust orprocess enclosure ventilation system. Ensure compliance withapplicable exposure limits.

Personal Protection
Respiratory: Wear protective masks for hazardous materials.

Protection

Hand Protection: Wear gloves resistant to organic solvents and chemicals.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, asappropriate.

Environmental Exposure Controls: Not available
9.

Physical and Chemical PropertiesAppearance- Physical State: liquid (25℃)- Color: BlackOdor: Solvent odor

pH: Not available

Boiling Point / Boiling Range: 175～209 ℃

Melting Point / Melting Range: < －30℃
Page 6 of 10

Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Flash Point: 74℃

Flammability (Solid, Gas)

: Not Applicable

Upper / Lower Flammability or: 0.85～15.60 vol%Explosive Limits
Vapor Pressure: 257Pa (20℃)

Vapor Density: 6.6

Relative Density: 1.00 (25℃)

Solubility (Ies): Very small amountPartition Coefficient (n-octanol / Water): Not available

Viscosity: 4.0 mPa・s (25℃)

10. Stability and Reactivity
Conditions to Avoid: Excessive heat and cold, sparks, ignition sources, direct sunlight andhigh humidity. Gamma-Butyrolactone is hydrolyzed by thermal
decomposition.

Stability: Stable

Materials to Avoid: Oxidant, reducing agent, strong acid, strong base, inert gas,deoxidant

Hazardous Reactions /: Combustion: toxic gases, oxides of carbon, oxides of nitrogen

Decomposition Products
Other: Plastic and rubbers might be melted.

11. Toxicological Information
Acute Toxicity:

ProductEye Contact: eye damage

Skin Contact: irritation

Sensitization: Not Available

Mutagenicity: Not Available

Oral（rat）
LD50>2,000mg/kg
Not classified

Dermal（rabbit）
LD50>2,000mg/kg
Not classified

Page 7 of 10

Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
Carcinogenicity: Component Carcinogenicity
Carbon black (1333-86-4) (Not possible to classify as a printing ink)
ACGIH:
IARC:
DFG:
OSHA:

Specific Target Organ

A3 - Confirmed Animal Carcinogen with Unknown
Relevance to Humans
Monograph 93 [2010]; Monograph 65 [1996] (Group2B (possibly carcinogenic to humans))
Category 3B (could be carcinogenic for man,inhalable fraction)
Present: drowsiness or dizzinessToxicity - Single
Exposure
Specific Target Organ: Not Available

Toxicity - Repeated
Exposure
Reproductive and: Not Available

Developmental Toxicity
Others: Not Available

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Hazardous to the Aquatic Environment - Acute Hazard
Calculated value : L(E)C50 >5.0mg/L Category 2

Persistence and: Not available

Degradability
Bioaccumulative: Not available

Potential
Other Adverse Effects: Not available

Page 8 of 10

Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

Safety Data Sheets
13. Disposal Considerations

Have waste inks, containers and other materials disposed by licensed industrial waste disposer.
Adsorb to diatom earth and others to dispose waste inks, and use open incinerator.
Dispose of wastes by licensed industrial waste disposer to comply with the local laws andregulations. Empty inks and other materials out of containers if disposed.
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Number: Not Applicable

US DOT Information: Not regulated as dangerous goods for transport. *1*1 Class combustible liquid (NA1993), Packing group III for quantities of 450 liters (119 gallons) ormore; not regulated for smaller quantities
15. Regulatory Information
TSCA Status: All components on TSCA INVENTORY.

SARA TitleⅢ
Section 311/312: Fire Hazard: Yes(40 CFR 370)

Pressure Hazard: No
Reactivity Hazard: No
Immediate Hazard: Yes
Delayed Hazard: Yes

California Proposition: WARNING:

65

This product can expose you to chemicals including
Acetaldehyde, Benzene, Carbon black, Methanol,Naphthalene, Toluene, Vinyl chloride, which are known to theState of California to cause cancer/ birth defects or otherreproductive harm. For more information go towww.P65Warnings.ca.gov.

Others: Please refer to any other federal, state and local regulations.
Page 9 of 10

Safety Data Sheets

Product Name: HS ink BlackSDS No. 037-S060578
First issue: 2011/09/30
Revised: 2019/10/30

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

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