Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Safety Data Sheets
1.

Identification

Product Name

: Reactive Dye Ink Rc400 Yellow

Order No.

: RC400-Y-2L

Ink Ver.

:1

General Use: Ink jet printing ink

Product Description: Ink jet printing ink

SDS Number: 037-W461427

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2

Sensitization – Skin

: Category 1

Specific Target Organ Toxicity: Category 1 (central nervous system, kidneys, heart,(Single Exposure)respiratory system)

Specific Target Organ Toxicity: Category 1 (central nervous system, heart,(Repeated Exposure)respiratory system)

The above list does not include category being non-classifiable or not-applicable.

Page 1 of 10

Safety Data Sheets

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H370 Causes damage to central nervous system, kidneys, heart, and respiratory system.
H372 Causes damage to central nervous system, heart, and respiratory system throughprolonged or repeated exposure
Precautionary Statements[Prevention]
P260 Do not breathe gas/mist.
P264 Wash hands and eyes thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor.
P314 Get medical advice/attention if you feel unwell.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international regulation (to be specified).
3.

Composition / Information on IngredientsNo

Chemical NameWt%

CAS No.

1

Water

30-50

7732-18-52Ethylene glycol

10-30

107-21-1

3Glycerols

5-15

Trade Secret

4Urea

5-15

57-13-6
Page 2 of 10

Safety Data Sheets

4.

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

5

Reactive Dye

10-20

Trade Secret

6

Additives

1-5

Trade SecretFirst Aid Measures

Inhalation: Remove person to fresh air and keep comfortable for breathing. Calla POISON CENTER or doctor/physician.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Get immediate medical attention.

Skin Contact: Wash with plenty of soap and water. Take off contaminated clothing
and wash before re-use. If skin irritation or rash occurs: Get medical
advice/attention.

Ingestion
5.

: If swallowed, get medical attention.

Fire Fighting Measures

Flammable Properties: Flash point Not flammable

Extinguishing Media: carbon dioxide, regular dry chemical, water spray, alcohol resistantfoam

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

MediaSpecial Hazards Arising: Negligible fire hazard.

from the Chemical
Hazardous Combustion: oxides of carbon, cyanide compounds, ammonia, and oxides ofProductsnitrogen.

Fire Fighting: Move container from fire area if it can be done without risk. Do not

Measuresscatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stayaway from the ends of tanks. Avoid inhalation of material or
combustion by-products.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible

Precautions forexposure.

Firefighters

Page 3 of 10

Safety Data Sheets
6.

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment

Avoid release to the environment.

and Emergency
Procedures
Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of lowareas.

7.

Handling and Storage

Precautions for Safe

: Do not breathe gas/mist. Wash hands thoroughly after handling. DoHandling

not eat, drink or smoke when using this product. Contaminated workclothing should not be allowed out of the workplace. Wear protective
gloves/protective clothing/eye protection/face protection.

Conditions for Safe

: Store locked up.Store and handle in accordance with all current

Storage, including any

regulations and standards. Store in a well-ventilated place. Keep

Incompatibilities

container tightly closed. Keep cool. Keep separated from incompatible
substances.

8.

Exposure Controls / Personal Protection

Exposure Limit Values: Ethylene glycol (107-21-1)
OSHA PEL: 50ppm Ceiling; 125mg/m3 Ceiling
ACGIH TLV-C: 100 mg/m3 Ceiling (aerosol only)
NIOSH: 50ppm Ceiling
Mexico 100 mg/m3 Ceiling (aerosol)

Component Biological: There are no biological limit values for the component(s) of thisLimit Values

product.

Exposure Controls
Page 4 of 10

Safety Data Sheets

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Occupational Exposure Controls
Appropriate: Provide local exhaust or process enclosure ventilation system. Ensure

Engineering Controls

compliance with applicable exposure limits.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear appropriate chemical resistant gloves.

Eye Protection: Wear splash resistant safety goggles with a faceshield. Provide anemergency eye wash fountain and quick drench shower in theimmediate work area.

Skin Protection

9.

: Wear appropriate chemical resistant clothing.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: YellowOdor: characteristic odor

pH: 8-10 (25℃)

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: Not flammable

Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not available

Explosive Properties: Not available

Oxidizing Properties: Not available
Page 5 of 10

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Safety Data Sheets
Upper / Lower Flammability or: Not available

Explosive Limits
Vapor Pressure
Specific Gravity: 1.1-1.2 (25 °C)Solubility: Not available

Water Solubility: Soluble

Partition Coefficient (n-octanol / Water): Not available

Viscosity: 4-6 mPa∙s (25 °C)

Vapor Density: Not available

Evaporation Rate

: Not available

Surface tension: 30-36mN/m

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Will not polymerize.

Reactions
Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Avoid contactwith incompatible materials.

Incompatible Materials: acids, bases, combustible materials, oxidizing materials, reducing
agents, metals, metal salts, combustible materials

Hazardous: Combustion: oxides of carbon, cyanide compounds, ammonia, andDecompositionoxides of nitrogen

11. Toxicological Information
Acute Toxicity: The component(s) of this material have been reviewed in various

Component Analysis -sources and the following selected endpoints are published:

LD50/LC50

Ethylene glycol (107-21-1)
Oral LD50 Rat 4700 mg/kg; Dermal LD50 Rabbit 10600mg/kg
Urea (57-13-6)
Oral LD50 Rat 8471 mg/kg

Immediate Effects: mild skin irritation, eye irritation, allergic skin reaction, central
nervous system damage, heart damage, kidney damage, respiratorydamage.
Page 6 of 10

Safety Data Sheets
Delayed Effects

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10: allergic skin reaction, central nervous system damage, heart damage,respiratory damage,.

Irritation/Corrosivity: mild skin irritation, eye irritation.

DataRespiratory: No information available for the product.

Sensitization
Dermal Sensitization: Available data characterizes components of this product as dermal
sensitization hazards.

Carcinogenicity: Component Carcinogenicity
Ethylene glycol (107-21-1)
ACGIH: A4 - Not Classifiable as a Human Carcinogen

Mutagenic Data

: No information available for the product.

Reproductive Effects: No information available for the product.

Data
Specific Target Organ: central nervous system, respiratory, kidneys, heart

Toxicity - Single
Exposure
Specific Target Organ: central nervous system, respiratory, heart

Toxicity - RepeatedExposure
Aspiration Hazard: Not expected to be an aspiration hazard.

Medical Conditions: kidney disorders, skin disorders and allergies, eye disorders,

Aggravated by Exposure

respiratory disorders, heart disorders.

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Component Analysis -: Ethylene glycol (107-21-1)

Aquatic Toxicity

Fish: 96 Hr LC50 Oncorhynchus mykiss: 41000 mg/L; 96 Hr LC50
Oncorhynchus mykiss: 14 - 18 mL/L [static]; 96 Hr LC50 Lepomis
macrochirus: 27540 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss:40761 mg/L [static]; 96 Hr LC50 Pimephales promelas: 40000 - 60000
mg/L [static]; 96 Hr LC50 Poecilia reticulata: 16000 mg/L [static]
Page 7 of 10

Safety Data Sheets

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Algae: 96 Hr EC50 Pseudokirchneriella subcapitata: 6500 - 13000
mg/L Invertebrate: 48 Hr EC50 Daphnia magna: 46300 mg/L
Urea (57-13-6)
Fish: 96 Hr LC50 Poecilia reticulata: 16200-18300 mg/L
Invertebrate: 24 Hr EC50 Daphnia magna Straus: >10000 mg/L; 48Hr EC50 Daphnia magna: 3910 mg/L [Static]
Persistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

Other Toxicity: No additional information is available.

13. Disposal Considerations: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Disposal Methods: Dispose in accordance with all applicable regulations.

Component Waste: The U.S. EPA has not published waste numbers for this product's

Numberscomponents.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
US DOT Information: Not regulated as a hazardous material for transport.

TDG Information: Not regulated as dangerous goods for transport.

IATA Information: Not regulated as dangerous goods for transport.

ICAO Information: Not regulated as dangerous goods for transport.

IMDG Information: Not regulated as dangerous goods for transport.

UN Number: Not regulated

Marine Pollutants: Not regulated as dangerous goods for transport.

(IMDG)
Page 8 of 10

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Safety Data Sheets
International Bulk

: This material contains one or more of the following chemicals

Chemical Coderequired by the IBC Code to be identified as dangerous chemicals inbulk.
NoChemical Name (CAS No.)IBC Code1Ethylene glycol (107-21-1)

Category Y

2Glycerols(Trade Secret)Category Z

3

Urea (57-13-6)

Category Z

15. Regulatory Information
U.S. Federal: This material contains one or more of the following chemicals

Regulations

required to be identified under SARA Sections 302/304 (40 CFR 355
Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section
313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or
require an OSHA process safety plan.
Ethylene glycol (107-21-1)
SARA 313: 1.0 % de minimis concentration
CERCLA: 5000 lb final RQ; 2270 kg final RQ

U.S. State Regulations: The following components appear on one or more of the following
state hazardous substances lists
Component
Ethylene glycol(CAS No. 107-21-1)
Urea(CAS No. 57-13-6)

CAMA

MN

NJPA

Yes

Yes

Yes

Yes

Yes

NoNo

Yes

No

No

California Proposition: WARNING:

65

This product can expose you to chemicals including Ethylene
glycol, which is known to the State of California to cause
birth defects or other reproductive harm. For more
information go to www.P65Warnings.ca.gov.

Canadian WHMIS: Components of this material have been checked against theIngredient Disclosure

Canadian WHMIS Ingredients Disclosure List. The List is composed

List (IDL)of chemicals which must be identified on MSDSs if they are included
in products which fall under WHMIS criteria specified in theControlled Products Regulations and present above the threshold
limits listed on the IDL.
Page 9 of 10

Safety Data Sheets

Product Name: Reactive Dye Ink Rc400 Yellow
SDS No. 037-W461427
First issue: 2016/08/18
Revised: 2019/12/10

Ethylene glycol (107-21-1) 1 %16. Other Information
Key/Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European RoadTransport; CAS - Chemical Abstracts Service; CLP - Classification, Labelling and Packaging;
EEC - European Economic Community; EIN (EINECS) - European Inventory of Existing
Commercial Chemical Substances; ELN (ELINCS) - European List of Notified Chemical
Substances; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IMDG - International Maritime Dangerous Goods; IBC Code International Bulk Chemical Code; Kow - Octanol/water partition coefficient; LEL - Lower
Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NTP =National Toxicology Program; REACH - Registration, Evaluation, Authorisation and Restrictionof Chemicals; RID - European Rail Transport; STEL - Short-term Exposure Limit;
TWA - Time Weighted Average; UEL - Upper Explosive Limit
Other Information
This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 10 of 10