Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets
1.

Identification

Product Name

: SS21 ink Light Magenta

Order No.

: SPC-0501LM-2 / SPC-0588LM-2 / SS21-LM-60-2

General Use: Ink for ink jet printer

Product Description: Solvent pigment ink

SDS Number: 037-S080500

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 4

Health Hazards
Eye Damage / Irritation: Category 1

Toxic to Reproduction: Category 1BSpecific Target Organ Toxicity: Category 2(Single Exposure)Specific Target Organ Toxicity: Category 2(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]

Page 1 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets
SymbolSignal Word
DangerHazard Statements
H227 Combustible liquid.
H318 Cause serious eye damage.
H360 May damage fertility or the unborn child.
H371 May cause damage to organs.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from open flames and other ignition sources. No smoking.
P260 Do not breathe gas/mist/vapours.
P264 Wash hands and eyes thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
(P305+)P310 (IF IN EYES) Immediately call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.
P370+P378 In case of fire: Use foam, carbon dioxide, dry chemical for extinguish.
[Storage]
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
NFPA Rating (scale 0 – 4)
Health = 3
Flammability = 2
Instability = 0

CANADIAN WHMIS SYMBOLS

2
3

0

Special = None
3.

Composition / Information on Ingredients

Mixtures
Page 2 of 13

Safety Data SheetsNo

Chemical Name

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Wt%

CAS No.

1Glycol ether solvents

65-75

Trade Secret2Lactone solvent series

15-25

Trade Secret3

Vinyl resin

1-10

Trade Secret

4

Propyleneglycol monomethylether acetate

1-5

Trade Secret5

Pigment

0.1-1

Trade Secret

The specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
4.

First Aid Measures

Description of first aid measures
Eye Contact: If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously withrunning water. Ensure complete irrigation of the eye by keeping
eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids. Continue flushing until
advised to stop by the Poisons Information Centre or a doctor, or forat least 15 minutes. Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only beundertaken by skilled personnel.

Skin Contact: If skin or hair contact occurs:
Flush skin and hair with running water (and soap if available). Seek
medical attention in event of irritation.

Inhalation: If fumes, aerosols or combustion products are inhaled remove fromcontaminated area. Other measures are usually unnecessary.

Ingestion: Immediately give a glass of water. First aid is not generally
required. If in doubt, contact a Poisons Information Centre or adoctor.

Most important symptoms and effects, both acute and delayed
See Section 11.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.

Fire Fighting Measures

Flammable Properties: Flash point 69.2 degree C
Auto Ignition Temperature: 169 degree C
Page 3 of 13

Safety Data Sheets

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Explosive Limit : 2% to 33.0%
Extinguishing Media: Foam, Dry chemical powder, BCF (where regulations permit),
Carbon dioxide, Water spray or fog - Large fires only.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

Media
Special hazards arising from the substrate or mixture
Fire: None known.

Incompatibility
Special protective equipment and precautions for fire-fighters
Fire Fighting: Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or
water course. Use water delivered as a fine spray to control fire andcool adjacent area. Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot. Cool fire exposedcontainers with water spray from a protected location.
If safe to do so, remove containers from path of fire.

Fire/Explosion: Combustible.

HazardSlight fire hazard when exposed to heat or flame. Heating may
cause expansion or decomposition leading to violent rupture ofcontainers. On combustion, may emit irritating/ toxic fumes. May
emit acrid smoke. Mists containing combustible materials may be
explosive.
May emit poisonous fumes.
May emit corrosive fumes.

6.

Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
See section 8.
Environmental precautions
See section 12.
Methods and material for containment and cleaning up
Minor Spills: Remove all ignition sources. Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes. Control
personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material orPage 4 of 13

Safety Data Sheets

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

vermiculite. Wipe up. Place in a suitable, labelled container for waste
disposal.
Major Spills: Moderate hazard.
Clear area of personnel and move upwind. Alert Fire Brigade andtell them location and nature of hazard. Wear breathing apparatus
plus protective gloves. Prevent, by any means available, spillage
from entering drains or water course. No smoking, naked lights orignition sources. Increase ventilation. Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite. Collect recoverable
product into labelled containers for recycling. Absorb remaining
product with sand, earth or vermiculite. Collect solid residues andseal in labelled drums for disposal. Wash area and prevent runoff
into drains. If contamination of drains or waterways occurs, advise
emergency services.

7.

Handling and Storage

Precautions for Safe

: Avoid all personal contact, including inhalation. Wear protective

Handling

clothing when risk of exposure occurs. Use in a well-ventilated area.
Avoid smoking, naked lights or ignition sources. Avoid contact withincompatible materials. When handling, DO NOT eat, drink or
smoke. Keep containers securely sealed when not in use. Avoid
physical damage to containers. Always wash hands with soap andwater after handling. Work clothes should be laundered separately.

Conditions for Safe

: Store in original containers. Keep containers securely sealed.

Storage

No smoking, naked lights or ignition sources. Store in a cool, dry,well-ventilated area. Store away from incompatible materials andfoodstuff containers. Protect containers against physical damage andcheck regularly for leaks. Observe manufacturer's storage andhandling recommendations contained within this SDS.

Storage: None known.

incompatibility
8.

Exposure Controls / Personal Protection

Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
Page 5 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets
INGREDIENT DATA
Not Available.
EMERGENCY LIMITS
IngredientMaterial name

TEEL-1

TEEL-2

TEEL-3

Vinyl resin

Trade secret

120 mg/m3

1,300 mg/m3

7,900 mg/m3

Lactone solvent series

Trade secret

3.6 mg/m3

39 mg/m3

310 mg/m3

monomethyl ether acetate,

Not

Not

Not

alpha-isomer;

Available

Available

Available

Propylene glycol

Propyleneglycol
monomethylether
acetate(1-Methoxypropyl-2-acetate)
Ingredient

Original IDLH

Revised IDLH

Pigment

Not Available

Not Available

Vinyl resin

Not Available

Not Available

Glycol ether solvents

Not Available

Not Available

Lactone solvent series

Not Available

Not Available

Not Available

Not Available

Propyleneglycol
monomethylether acetate
Exposure Controls
Occupational Exposure Controls
Appropriate: General exhaust is adequate under normal operating conditions. If

Engineering Controls

risk of overexposure exists, wear SAA approved respirator. Correct fit
is essential to obtain adequate protection. Provide adequate
ventilation in warehouse or closed storage areas.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear chemical protective gloves, e.g. PVC.

Eye Protection: Safety glasses with side shields. Chemical goggles. Contact lenses
Page 6 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets

may pose a special hazard; soft contact lenses may absorb andconcentrate irritants.
Skin Protection: Wear safety footwear or safety gumboots, e.g. Rubber. Overalls.
P.V.C. apron.

9.

Physical and Chemical Properties

Information on basic physical and chemical properties
Appearance: Light Magenta liquid
Physical state

LiquidRelative density (Water = 1)

0.984

Odour

SlightPartition coefficient

Not Available

n-octanol / water
Odour threshold

Not Available

Auto-ignition

temperature

169

(°C)
pH (as supplied)

Not Available

Decomposition temperature

Not Available

Melting point /freezing point

Not Available

Viscosity (cSt)

Not Available

176-204

Molecular weight (g/mol)

Not Available

Flash point (°C)

69.2 (closed cup)

Taste

Not Available

Evaporation rate

Not Available

Explosive properties

Not Available

Flammability

Combustible

Oxidising properties

Not Available

Upper Explosive Limit (%)

33

Surface Tension (dyn/cm or

Not Available(°C)
Initial boiling point andboiling range (°C)mN/m)
Lower Explosive Limit (%)

2

Volatile Component (%vol)

Not Available

Vapour pressure (kPa)

2.67

Gas group

Not Available

Solubility in water (g/L)

Immiscible

pH as a solution (1%)

Not Available

Vapour density (Air = 1)

Not Available

VOC g/L

Not Available

10. Stability and Reactivity
Reactivity: Stable under normal conditions of use.

Chemical Stability: Unstable in the presence of incompatible materials.
Product is considered stable.
Page 7 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets
Possibility of Hazardous: Hazardous polymerisation will not occur.

Reactions
Conditions to Avoid: See section 7.

Incompatible Materials: See section 7.

Hazardous: See section 5.

decomposition products
11. Toxicological Information
Information on toxicological effects
Inhaled: The material is not thought to produce adverse health effects orirritation of the respiratory tract (as classified by EC Directives using
animal models). Nevertheless, good hygiene practice requires that
exposure be kept to a minimum and that suitable control measures beused in an occupational setting.

Ingestion: The material has NOT been classified by EC Directives or otherclassification systems as 'harmful by ingestion'. This is because of thelack of corroborating animal or human evidence.

Skin Contact: The liquid may be miscible with fats or oils and may degrease the skin,producing a skin reaction described as non-allergic contact dermatitis.
The material is unlikely to produce an irritant dermatitis as describedin EC Directives.
Open cuts, abraded or irritated skin should not be exposed to thismaterial
Entry into the blood-stream, through, for example, cuts, abrasions or
lesions, may produce systemic injury with harmful effects. Examine
the skin prior to the use of the material and ensure that any external
damage is suitably protected.

Eye: If applied to the eyes, this material causes severe eye damage.

Chronic: Substance accumulation, in the human body, is likely and may causesome concern following repeated or long-term occupational exposure.
Ample evidence exists from experimentation that reduced human
fertility is directly caused by exposure to the material. Ample evidence
exists, from results in experimentation, that developmental disorders
are directly caused by human exposure to the material.
IngredientTOXICITYIRRITATION
Page 8 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets
As a productNot Available

Not Available

Pigment

Not Available

Not Available

Vinyl resin

Not Available

Not Available

Glycol ether solvents

Not Available

Not Available

Lactone solvent series

Not Available

Not Available

Not Available

Not Available

Propyleneglycol
monomethylether acetate
Acute Toxicity: Data Not Available to make classification.

Skin: Data Not Available to make classification.

Irritation/Corrosion
Serious Eye: Data available to make classification.

Damage/Irritation
Respiratory or Skin

: Data Not Available to make classification.

sensitisation
Mutagenicity: Data Not Available to make classification.

Carcinogenicity: Data Not Available to make classification.

Reproductivity: Data available to make classification.

STOT - Single Exposure: Data available to make classification.

STOT - Repeated: Data available to make classification.

Exposure
Aspiration Hazard: Data Not Available to make classification.

12. Ecological Information
Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
IngredientEndpoint

Test Duration

Species

Value

Source713.772mg/L

34246.290mg/L

3(hr)
Glycol ether
solvents

Lactone solvent
series

LC50

96

Fish

EC50

96

EC50

384

Crustacea

163.553mg/L

3

LC50

96

Fish

220mg/L

1

EC50

48

Crustacea>500mg/L

1

EC50

96

Algae or other16.400mg/L

3Algae or otheraquatic plants

Page 9 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets

aquatic plants

Propyleneglycol
monomethylether

EC20

72

NOEC

24

LC50

Algae or other=14mg/L

1

Fish=5mg/L

1

96

Fish

100mg/L

1

EC50

48

Crustacea=408mg/L

1

EC50

96

9.337mg/L

3

EC0

24

Crustacea=500mg/L

1

NOEC

336

Fish

47.5mg/L

2

acetateaquatic plants

Algae or otheraquatic plants

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances – Ecotoxicological
Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated)

DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient

Persistence: Water/Soil

Persistence: Air

Glycol ether solvents

LOW

LOW

Lactone solvent series

LOW

LOW

LOW

LOW

Propyleneglycol
monomethylether acetate
Bioaccumulative potential
Ingredient

Bioaccumulation

Glycol ether solvents

LOW (LogKOW = 0.0093)

Lactone solvent series

LOW (BCF = 1.8)

Propyleneglycol

LOW (LogKOW = -0.56)

monomethylether acetate
Mobility in soil
Ingredient

Mobility

Glycol ether solvents

LOW (KOC = 10)

Lactone solvent series

LOW (KOC = 7.134)

Propyleneglycol

HIGH (KOC = 1.838)

monomethylether acetate
13. Disposal Considerations
Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any body of water.
Page 10 of 13

Safety Data Sheets

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Disposal Methods: Dispose in accordance with all applicable regulations.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Labels Required: Marine Pollutant; NO

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS.
*1

Air transport: NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS.

(ICAO-IATA / DGR)
Sea transport: NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS.

(IMDG-Code / GGVSee)Transport in bulk

: Not Applicableaccording to Annex II of
MARPOL and the IBC
code*1 Class combustible liquid (NA1993), Packing group III for quantities of 450 liters (119 gallons) or
more; not regulated for smaller quantities
15. Regulatory Information
Safety, health and environmental regulations / legislation specific for the substance or mixture
PIGMENT IS FOUND ON THE FOLLOWING REGULATORY LISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
VINYL RESIN IS FOUND ON THE FOLLOWING REGULATORY LISTSUS Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
GLYCOL ETHER SOLVENTS ARE FOUND ON THE FOLLOWING REGULATORY LISTS
US - California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs (RELs)
US - California OEHHA/ARB - Chronic Reference Exposure Levels and Target Organs (CRELs)
US - Pennsylvania - Hazardous Substance List
US Clean Air Act - Hazardous Air Pollutants
US EPCRA Section 313 Chemical List
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
Page 11 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets

LACTONE SOLVENT SERIES ARE FOUND ON THE FOLLOWING REGULATORY LISTSUS Drug Enforcement Administration (DEA) List I and II Regulated Chemicals
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
PROPYLENEGLYCOL MONOMETHYLETHER ACETATE IS FOUND ON THE FOLLOWINGREGULATORY LISTS
US - California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs (RELs)
US - California OEHHA/ARB - Chronic Reference Exposure Levels and Target Organs (CRELs)
US - California Permissible Exposure Limits for Chemical Contaminants
US - Pennsylvania - Hazardous Substance List
US AIHA Workplace Environmental Exposure Levels (WEELs)
US Clean Air Act - Hazardous Air Pollutants
US EPCRA Section 313 Chemical List
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
Federal Regulations
Superfund Amendments and Reauthorization Act of 1986 (SARA)SECTION 311/312 HAZARD CATEGORIES
Immediate (acute) health hazard

Yes

Delayed (chronic) health hazard

Yes

Fire hazard

Yes

Pressure hazard

No

Reactivity hazard

No

US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR
302.4)
None Reported.
State Regulations
US. CALIFORNIA PROPOSITION 65: WARNING:
This product can expose you to chemicals including Vinyl Chloride, Ethylene Glycol
Monoethyl Ether, Acetaldehyde and Methanol which are known to the State of California
to cause cancer/ birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.

Page 12 of 13

Product Name: SS21 ink Light Magenta
SDS No. 037-S080500
First issue: 2007/07/31
Revised: 2022/05/18

Safety Data Sheets
Inventory
National Inventory

StatusAustralia - AICSY

Canada - DSLYCanada - NDSLY

China - IECSC

Y

Europe - EINEC / ELINCS / NLPYJapan - ENCS

Y

Korea - KECIYNew Zealand - NZIoC

YPhilippines - PICCS

N

USA - TSCAY

Legend: Y = All ingredients are on the inventory.
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets).

16. Other Information
Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13