File No. TFQC302

Creation Date : November 22,2017

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1.CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME

: QC INK BLACKCOMPANY: TSUKINEKO CO., LTD.

ADDRESS: 5F SUEHIRO JF BLDG., 5-1-5, SOTOKANDA, CHIYODA-KU, TOKYO,
101-0021 JAPANTELEPHONE NO.

: +81-3-3834-1080

2.HAZARDS IDENTIFICATIONGHS Classification
Physical hazards
Flammable liquid: Category 3

Health hazards
Acute toxicity (Oral): Category 5

Acute toxicity (Dermal): Category 5

Acute toxicity (Inhalation): Category 4Skin corrosion/irritation: Category 2

Serious eye damage/eye irritation: Category 1

Reproductive toxicity: Category 1BSpecific target organ toxicity-single: Category 1(liver, kidney, central nervous system, testis)

exposure

Category 3(respiratory tract irritation, narcotic effects)

Specific target organ toxicity-repeated: Category 1(hematopoietic system, central nervous system, auditory

exposuresystem, testis)

Environmental hazards
Acute toxicity to the aquatic environment: Category 2

Chronic toxicity to the aquatic environment: Category 2

Label
Signal word: Danger

Hazard pictogram

Hazard statement: Flammable liquid and vapor.
: May be harmful if swallowed.
: May be harmful in contact with skin.

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File No. TFQC302

Creation Date : November 22,2017: Harmful if inhaled.
: Causes skin irritation.
: Causes serious eye damage.
: May damage fertility or the unborn child.
: Causes damages to organs: liver, kidney, central nervous system,testis.
: May cause respiratory irritation.
: May cause drowsiness or dizziness.
: Causes damages to organs through prolonged or exposure:hematopoietic system, central nervous system, auditory system,testis.
: Toxic to aquatic life.
: Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention: Do not handle until all safety precautions have been read andunderstood.
: Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
: Keep container tightly closed.
: Use explosion-proof electrical/ventilation/lighting equipment. Take
precautionary measures against ignition by the static discharge andthe spark.
: Do not breathe.
: Use only outdoors or in a well-ventilated area.
: Do not eat, drink or smoke when using this product.
: Wash hands thoroughly after handling.
: Wear protective gloves/eye protection/face protection.

Response: If inhaled: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a poison center or doctor/physician if
you feel unwell.
: If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
: If eye irritation persists: Get medical advice/attention.
: If on skin (or hair): Remove/take off immediately all contaminatedclothing. Rinse skin with water/shower.
: If skin irritation occurs: Get medical advice/attention.
: If exposed or concerned: Get medical advice/attention.

Storage: Store in a well-ventilated place. Keep cool.
: Store locked up.

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File No. TFQC302

DisposalCreation Date : November 22,2017: Dispose of contest/container through a waste management company
authorized by the local government.

Other hazards which do not result in: May form explosive peroxides.

classification

3.COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients

CAS No.

Wt%

Ethylene glycol monoethyl ether

110-80-5

50-60

1-Butanol

71-36-3

10-15

Synthetic resin

Registered

10-15

Dye

Registered

10-15

Alcohols

Registered7.0-152-Ethylhexan-1-yl diphenyl phosphate

1241-94-7

1.0-4.0

Diphenyl amine

122-39-4<0.1

Other Limit

4.FIRST-AID MEASURESSkin contact:
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Cover the irritated skin with an emollient. Cold water may be used. Get medical attention immediately.
Eye contact:
Check for and remove any contact lenses. Immediately hold eyelids open and rinse with a stream of water
for at least 15 minutes. Cold water may be used. Get medical attention.
Ingestion:
Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt orwaistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouthresuscitation. It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when
the inhaled material is toxic, infectious or corrosive. Seek medical attention.

5.FIRE FIGHTING MEASURES
Firefighting media and instructions: Flammable liquid, soluble or dispersed in water.
Small fire: Use dry chemical, foam, carbon dioxide.
Large fire: Use dry chemical, foam, carbon dioxide. Cool containing vessels with water jet in order to prevent
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File No. TFQC302

Creation Date : November 22,2017pressure build-up, auto-ignition or explosion.
Special firefighting procedures: Not available
Unusual fire and explosion hazards: Not available

6.ACCIDENTAL RELEASE MEASURES
Small spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate
waste disposal container.
Large spill: Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without
risk. Absorb with dry earth, sand or other non-combustible material. Do not touch spilled material. Prevent
entry into sewers, basements or confined areas; dike if needed. Be careful that the product is not present ata concentration level above TLV.

7.HANDLING AND STORAGE
Handling: Handle in well-ventilated areas.
: Wear suitable protective clothing.
: Avoid contact with eyes and skin.
: Do not inhale fume and mist.
: In case of insufficient ventilation, wear suitable respiratory equipment.
: If ingested, seek medical advice immediately and show the container or the label.

Storage: Keep away from heat sources.
: Keep container tightly closed.
: Store in a dark and well-ventilated place.

8.EXPOSURE CONTROL/PERSONAL PROTECTIONACGIH: TLV 5ppm(TWA) skin (Ethylene glycol monoethyl ether): TLV 20ppm(TWA) (1-butanol)

OSHA

: PEL

200ppm(TWA) skin( Ethylene glycol monoethyl ether): PEL

100ppm(TWA) (1-butanol)

Ventilation: Use local exhaust ventilation.

Protective measures: Wear impervious protective clothing, including boots, gloves, lab coat, apron orSkin protection

coveralls, as appropriate, to prevent skin contact.
: Use chemical safety goggles and/or a full face shield where splashing is possible.

Eye protection

Maintain eye wash fountain and quick-drench facilities in work area.

9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance and odor

: Colored liquid, specific odor

Boiling point: 118℃

Melting point: Not available

Vapor density: Not available

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Creation Date : November 22,2017

Vapor pressure: Not available

Solubility in water: InsolublepH: Not applicableSpecific gravity: Not available

Flash point: 38℃

Auto-ignition point: Not available

10.STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.

Hazardous reaction: Carbon dioxide and carbon monoxide may form when heated todecomposition.

Polymerization: Will not occur

Conditions to avoid: Avoid heat, flames, sparks and other sources of ignition.

11.TOXICOLOGICAL INFORMATION
Acute toxicity
Oral rat LD50

: 2230mg/kg

Dermal rat LD50

: 2293mg/kg

Inhalation rat LC50

: 14.5mg/L/4H

Skin corrosion/irritation: skn-rbt 20mg/24H MOD (1-butanol)

Serious eye: eye rbt 2mg/24H SEV (1-butanol)

damage/irritation
Reproductive toxicity: May damage fertility or the unborn child.

Specific target organ: Causes damages to organs: liver, kidney, central nervous system, testis

toxicity-single exposure
Specific target organ: May causes damages to organs through prolonged or exposure:

toxicity-repeated exposure

hematopoietic system, central nervous system, auditory system, testis

12.ECOLOGICAL INFORMATION
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.

13.DISPOSAL CONSIDERATIONS
Dispose of waste in accordance with national, state and local regulations.

14.TRANSPORT INFORMATION
Follow all regulations in your country or region.
Precautions: Pack, label and transport according to regulation.
: Ensure containers without breakage or leakage.

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Creation Date : November 22,2017: Ensure containers tightly fixed.
Proper shipping name: Printing ink

Hazard class: 3 Flammable liquidUN No.

: 1210

Packing group: Ⅲ

15.REGULATORY INFORMATION
Follow all regulations in your country or region.

16.OTHER INFORMATIONThis information is furnished without warranty, express or implied, except that it is accurate to the best
knowledge of Tsukineko Co., Ltd. It relates only to the specific material designated herein, and does not
relate to use in combination with any other material or in any process. Tsukineko Co., Ltd. assumes no legal
responsibility for use of or reliance upon this information.

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