SAFETY DATA SHEET
PennGrade Select (All Viscosities)

Prepared according to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Union REACH Regulations

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PennGrade Select (All Viscosities)

PRODUCT NAME:PRODUCT USE:
PRODUCT DESCRIPTION:
CAS#MANUFACTURER’S NAME:
ADDRESS:EMERGENCY PHONE:
BUSINESS PHONE:WEB SITE:DATE OF PREPARATION:DATE OF LAST REVISION:

Engine Oils
Base Oil and Additives
MixtureD-A Lubricant Company, Inc.
801 Edwards Drive, Lebanon, IN 46052 USA
1-800-899-9004 TOLL-FREE in USA/Canada
1-317-923-5321 (Product Information)www.dalube.com
20 October 2015
20 October 2015

SECTION 2 - HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW: This product is a amber colored liquid with a petroleum hydrocarbon odor.
HEALTH HAZARDS: Prolonged or repeated exposure may cause irritation to eyes, respiratory system and skin.
Repeated exposure may cause dryness of the skin.
FLAMMABILITY: This product is not classified as a flammable liquid. Flashpoint: >185°C (>365°F) ASTM D-92
ENVIRONMENTAL EFFECTS: The Environmental effects of this product have not been investigated. Floats on water.
If it enters soil, it will be absorbed to soil particles and will not be mobile. This product may cause gastrointestinal
distress in birds and mammals through ingestion during pelage grooming.
US DOT SYMBOLSCANADA (WHMIS) SYMBOLS

Non-Regulated

Not Controlled

EUROPEAN and (GHS) Hazard Symbols

Signal Word: Warning!
EU LABELING AND CLASSIFICATION:Classification of the substance or mixture according to Regulation (EC) No1272/2008 Annex 1
EC# Various Highly Refined Petroleum Base Stocks – Listed in Annex I All are Severely Hydrotreated withless than 3 % DMSO extract as measured by IP 346
Substances not listed either individually or in group entries must be self classified
Components Contributing to Hazard:
Highly refined Mineral Oil
GHS Hazard Classification(s):Skin Irritation Category 2
Eye Irritation Category 2B
Hazard Statement(s):H320: Causes eye irritation
H315: Causes skin irritation

Precautionary Statement(s):P264: Wash hands thoroughly after handlingP280: Wear protective gloves/protective
clothing/eye protection/face protectionEU HAZARD CLASSIFICATION PER DIRECTIVE 1999/45/EC:[Xi] Irritant
Risk Phrases:
R36/38: Irritating to eyes and skin

Last Revision Date 10/20/2015

Safety Phrases:
S24/25: Avoid contact with skin and eyes
S37/39: Wear suitable gloves and eye/faceprotection
Page 1 of 6

SAFETY DATA SHEET
PennGrade Select (All Viscosities)
HEALTH HAZARDS OR RISKS FROM EXPOSURE:
ACUTE:
EYE: Expected to cause mild irritation of the eye if exposed to liquid spray or mist. May cause tearing, or burning ofthe eyes.
SKIN: May cause mild skin irritation from prolonged or repeated skin contact. Symptoms of irritation may include
redness, drying, and cracking of the skin.
INHALATION: No significant adverse health effects are expected to occur upon short-term exposure
INGESTION: Ingestion can cause mild irritation of the digestive tract or cause a laxative effect. Because of the low
viscosity of this material, this material can enter the lungs directly by aspiration during swallowing or vomiting. If
aspirated into lungs, this material can cause severe lung damage.
CHRONIC: Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying,cracking, (dermatitis) or oil acne.
ACUTE: Eye, Skin
CHRONIC: Skin
TARGET ORGANS:SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTSHAZARDOUS INGREDIENTS:

CAS #EINECS #ICSC #WT %Highly Refined Mineral Oil

See Note
Below

VariousNot Listed>70%

HAZARD CLASSIFICATION;RISK PHRASESHAZARD CLASSIFICATION: Self
Classified: [Xi] Irritant
RISK PHRASES: R36/38

Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for
carcinogens, reproductive toxins, or respiratory sensitizers).
NOTE:

This product can contain any of the following highly refined petroleum base stocks: 64742-01-4, 64742-54-7, 64742-58-1, 64741-88-4,
72623-84-8, 72623-87-1, 64742-46-7, 64742-57-0, 64742-62-7, 64741-89-5, 72623-85-9, 8042-47-5, 64742-52-5, 64742-55-8,64742-65-0, 72623-83-7, 72623-86-0
ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format. This product has beenclassified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU
Directives and the Japanese Industrial Standard JIS Z 7250: 2000.

SECTION 4 - FIRST-AID MEASURES
Contaminated individuals of chemical exposure must be taken for medical attention if any adverse effect occurs.
Rescuers should be taken for medical attention, if necessary. Take copy of label, bill of lading and/or MSDS to healthprofessional with contaminated individual.
EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes.
Remove contact lenses if worn. Seek medical attention if irritation persists.
SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists.
Remove contaminated clothing. Launder before re-use.
INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to
support vital functions. Seek medical attention if breathing dificulty continues.
INGESTION: If product is swallowed, call physician or poison control center for most current information. If
professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) tosomeone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of thelabel and/or MSDS with the victim to the health professional.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin problems may be aggravated byprolonged contact.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.

SECTION 5 - FRE-FIGHTING MEASURESFLASH POINT:AUTOIGNITION TEMPERATURE:
FLAMMABLE LIMITS (in air by volume, %):FIRE EXTINGUISHING MATERIALS:

Last Revision Date 10/20/2015>185ºC (>365°F) ASTM D-92
Not Established
Lower (LEL): Not Available
Upper (UEL): Not Available
Use water fog, foam, dry chemical or carbon dioxide (CO2) toextinguish flames.
Page 2 of 6

SAFETY DATA SHEET
PennGrade Select (All Viscosities)
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Explosion Sensitivity to Mechanical Impact:
Explosion Sensitivity to Static Discharge:

SPECIAL FIRE-FIGHTING PROCEDURES:

Do not use straight streams of water. This product is a combustible
liquid at temperatures above flash point.
Not Sensitive.
Not Sensitive
Incipient fire responders should wear eye protection. Structural
firefighters must wear Self-Contained Breathing Apparatus and full
protective equipment. Isolate materials not yet involved in the fire
and protect personnel. Move containers from fire area if this can bedone without risk; otherwise, cool with carefully applied water spray.
If possible, prevent runoff water from entering storm drains, bodiesof water, or other environmentally sensitive areas.

NFPA RATING SYSTEMHMIS RATING SYSTEM
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM

Flammability

1Health

10Reactivity

HEALTH HAZARD (BLUE)

1FLAMMABILITY HAZARD (RED)

1PHYSICAL HAZARD (YELLOW)0PROTECTIVE EQUIPMENTEYESRESPIRATORY

HANDS

Other
See Sect 8

BODYSeeSect 8For Routine Industrial Use and Handling Applications

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

SECTION 6 - ACCIDENTAL RELEASE MEASURESSPILL AND LEAK RESPONSE: Personnel should be trained for spill response operations.
SPILLS: Contain spill if safe to do so. Product may create a slip hazard if not cleaned up. Prevent entry into drains, sewers, and otherwaterways. Soak up with an absorbent material and place in an appropriate container for disposal. Dispose of in accordance withapplicable Federal, State, and local procedures (see Section 13, Disposal Considerations).

If spill of any amount is made into or upon navigable waters, the contiguous zone or adjoining shorelines, notify theNational Response Center (phone number 800-424-8802).
Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations).

SECTION 7 - HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU.
Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product.
Avoid breathing vapors/mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: Containers of this product must be properly labeled. Store containers in acool, dry location. Keep container tightly closed when not in use. Protect from physical damage.
Other precautions: For professional industrial use only. Good personal hygiene is important. Empty containers retain
residue which can be dangerous. DO NOT pressurize, cut, weld, braze, solder, drill, grind, or expose such containers
to heat, flame, sparks, or other ignition sources; they may explode and cause injury or death

SECTION 8 - EXPOSURE CONTROLS - PERSONAL PROTECTIONEXPOSURE LIMITS/GUIDELINES:

Chemical Name

CAS#ACGIH TWAOSHA TWA

SWA

Highly Refined Petroleum BaseStocks

Various

5 mg/m³ Oil Mist

5 mg/m³ Oil Mist

5 mg/m³ Oil Mist

Last Revision Date 10/20/2015

Page 3 of 6

SAFETY DATA SHEET
PennGrade Select (All Viscosities)
Currently, International exposure limits are not established for the components of this product. Please check withcompetent authority in each country for the most recent limits in place.
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels aremaintained below the limits provided above. Use local exhaust ventilation to control airborne vapor. Ensureeyewash/safety shower stations are available near areas where this product is used.
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying
with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, orstandards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and thoseof Japan. Please reference applicable regulations and standards for relevant details.
RESPIRATORY PROTECTION: Not normally required. Maintain airborne contaminant concentrations below guidelines
listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory
Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, theEuropean Standard EN149, or EU member states.
EYE PROTECTION: Safety glasses or chemical goggles as appropriate to prevent eye contact. If necessary, refer toU.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards.
HAND PROTECTION: Use chemical resistant gloves to prevent skin contact. If necessary, refer to U.S. OSHA 29 CFR
1910.138 or appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate to prevent contact (e.g. lab coat, overalls). If necessary, refer toappropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant JapaneseStandards.

SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
LiquidAmber colored liquid with a petroleum hydrocarbon odor.
Mild<0.013 kPa (0.1 mm Hg) at 20°C
No Data Available
No Data Available>°260C (>500°F)
No Data Available
No Data Available
0.88 @ 60˜F
No Data Available
Negligible

PHYSICAL STATE:APPEARANCE & ODOR:ODOR THRESHOLD (PPM):
VAPOR PRESSURE (mmHg):
VAPOR DENSITY (AIR=1):
EVAPORATION RATE (nBuAc = 1):
BOILING POINT (C°):
MELTING POINT (C°):
pH:
SPECIFIC GRAVITY:
VISCOSITY:
SOLUBILITY IN WATER (%)

SECTION 10 - STABILITY and REACTIVITY
STABILITY: Product is stable
DECOMPOSITION PRODUCTS: Material does not decompose under normal storage conditions. When heated todecomposition this product produces carbon dioxide and carbon monoxide.

MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible materials. Excessive heat and high energy sources of ignition.

SECTION 11 - TOXICOLOGICAL INFORMATIONTOXICITY DATA: Toxicity data is not available for mixture: Information given is based on data on the components andtoxicology of similar products.
Acute Oral Toxicity LD50 >5,000 mg/kg
Acute Dermal Toxicity LD50 >5,000 mg/kg
SUSPECTED CANCER AGENT: This product does not contain an ingredient(s) that are found on one or more of thefollowing lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC and therefore is not considered to be, or suspected
to be a cancer-causing agent by these agencies.
IRRITANCY OF PRODUCT: Contact with this product can be irritating to exposed skin and eyes.
Last Revision Date 10/20/2015

Page 4 of 6

SAFETY DATA SHEET
PennGrade Select (All Viscosities)
REPRODUCTIVE TOXICITY INFORMATION: No information concerning the effects of this product and its components
on the human reproductive system.
ADDITIONAL INFORMATION: Used oils may contain harmful impurities that have accumulated during use. The
concentration of such impurities will depend on use and they may present risks to health and the environment ondisposal. ALL used oil should be handled with caution and skin contact avoided as far as possible.
Continuous contact with used engine oils has caused skin cancer in animal tests

SECTION 12 - ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: It is not expected to be biodegradable. Liquid under most environmental conditions.
Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: If applied to leaves, this product may kill grasses and small plants
by interfering with transpiration and respiration. This product is not toxic to fish but may coat gill structures resulting insuffocation if spilled in shallow, running water. Product may be moderately toxic to amphibians by preventing dermal
respiration. This product may cause gastrointestinal distress in birds and mammals through ingestion during pelage
grooming.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product’s effects on aquatic life.

SECTION 13 - DISPOSAL CONSIDERATIONSPREPARING WASTES FOR DISPOSAL: It is the responsibility of the waste generator to determine the toxicity andphysical properties of the material generated to determine the proper waste classification and disposal methods incompliance with applicable regulations. Do not dispose into the environment, in drains, or in water courses. Waste
disposal must be in accordance with appropriate Federal, State, and local regulations, those of Canada, Australia, EUMember States and Japan.

SECTION 14 - TRANSPORTATION INFORMATIONUS DOT; IATA; IMO; ADR:THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.

PROPER SHIPPING NAME: Non-Regulated Material
HAZARD CLASS NUMBER and DESCRIPTION: : None
UN IDENTIFICATION NUMBER: None
PACKING GROUP: None
DOT LABEL(S) REQUIRED: NoneNORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2004): None
MARINE POLLUTANT: None of the ingredients are classified by the DOT as a Marine Pollutant (as defined by 49
CFR 172.101, Appendix B)
U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS:This product is not classified as dangerous goods, per U.S. DOT regulations, under 49 CFR 172.101.
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:This product is not classified as Dangerous Goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):This product is not classified as Dangerous Goods, by rules of IATA:
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
This product is not classified as Dangerous Goods by the International Maritime Organization.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR):
This product is not classified by the United Nations Economic Commission for Europe to be dangerous goods.

SECTION 15 - REGULATORY INFORMATIONUNITED STATES REGULATIONSSARA REPORTING REQUIREMENTS: This product components are subject to the reporting requirements of Sections 302, 304
and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows:
SARA 313 Reporting: Zinc Dialkyl Dithiophosphate CAS#68649-42-3 <0.12%
TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of chemicals.
Last Revision Date 10/20/2015

Page 5 of 6

SAFETY DATA SHEETPennGrade Select (All Viscosities)
SARA 311/312:
Acute Health:Yes

Chronic Health:

No

Fire:

No

Reactivity:

No

U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this product. The
default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR
370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): NoneCALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): This product does not containingredient(s) which are on the California Proposition 65 lists.
ANADIAN REGULATIONS:CANADIAN DSL/NDSL INVENTORY STATUS: All of the components of this product are on the DSL Inventory
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS:
on the CEPA First Priorities Substance Lists.

No component of this product isCANADIAN WHMIS CLASSIFICATION and SYMBOLS: This product is categorized as “Not Controlled”, as per the Controlled
Product Regulations
EUROPEAN ECONOMIC COMMUNITY INFORMATION:
EU LABELING AND CLASSIFICATION:Classification of the mixture according to Regulation (EC) No1272/2008. See section 2 for details.
AUSTRALIAN INFORMATION FOR PRODUCT:
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: All components of this product are listed or exempt on
the AICS.
STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable.
JAPANESE INFORMATION FOR PRODUCT:JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are notlisted as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances bythe Japanese MITI.
INTERNATIONAL CHEMICAL INVENTORIES:
Listing of the components on individual country Chemical Inventories is as follows:
Asia-Pac:
Australian Inventory of Chemical Substances (AICS):
Korean Existing Chemicals List (ECL):
Japanese Existing National Inventory of Chemical Substances (ENCS):
Philippines Inventory if Chemicals and Chemical Substances (PICCS):
Swiss Giftliste List of Toxic Substances:
U.S. TSCA:

ListedListedListedListedListedListedListedSECTION 16 - OTHER INFORMATION
Last Revision Date: 20 October 2015
Disclaimer: The information in this document is believed to be correct as of the date issued. HOWEVER, NOWARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHERWARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF
THIS INFORMATION, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE
PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. This information andproduct are furnished on the condition that the person receiving them shall make his own determination as to thesuitability of the product for his particular purpose and on the condition that he assume the risk of his use thereof.

Last Revision Date 10/20/2015

Page 6 of 6