Material Safety Data Sheet
Revision Date

20.05.2020

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name

BsoB I

Product code

FG-BsoBI

Recommended use of the chemical and restrictions on use
Recommended use

For research use only

Restrictions on use

For research use only

Details of the supplierCompany name

Nippon Genetics Europe GmbHAddress

Mariaweilerstraße 28-30, 52349 Dueren, Germany

Emergence contact number(+49)2421554960

2. HAZARDS IDENTIFICATIONClassification of Hazards and dangerousness

No relevant classification

Warning article including prevention methodsPictorial symbol

No information available

Category

No information available

Hazards and dangerousness

No information available

Prevention methods
Prevention

No information available

ActionNo information available

Store

No information available

Discard

No information available

Other hazards and dangerousness (NFPA) not included in classification
Health1Fire1Reactivity

0

3. COMPOSITION/INFORMATION ON INGREDIENTS
Material name
Glycerin

Usual name

CAS No.

Amount (%)

GLYCEROL

56-81-5

40 ~ 60

4. FIRST AID MEASURES
Eye contact

Take medical action immediately.

Skin contact

Immediately rinse skin and eyes thoroughly with plenty of runningwater for at least 20 minutes.
Take medical action immediately.
Immediately rinse skin and eyes thoroughly with plenty of running water for at least
20 minutes.
Remove contaminated clothes and shoes and isolate contaminated area
Completely wash clothes and shoes before reuse
Remove to fresh airInhalation

CPR when there is no breathing
Provide Oxygen when breathing is difficult
Take medical action immediately.
Ingestion

Do not provide any food for unconscious person

Note to physicians

Take protective action according to the material
Do not inject adrenalin

5. FIRE FIGHTING MEASURES
Small fire: dry sand, dry chemical, alcohol-resistant foam, water spray, regular foam,
CO2 (suitable extinguishing agent)
Large fires: water spray / mist, regular foam (suitable extinguishing agent)

Proper (improper) fire extinguishing agentsHigh pressure water (improper extinguishing agent)
Can be ignited by heat, spark, flame

Specific hazards from chemical compounds

Container may explode on heating
Some can ride, but not easily ignite
May cause irritation and poisonous gas in case of fire
Inhalation of the substance may be harmfulSome fluids may cause dizziness, suffocation-inducing vapors
Protective equipment and precautions for fire fighting
Glycerin

No information available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective
equipment and emergency procedures

Micro particles can ignite fire or explosion therefore remove all the sources of fire.
Stop leak if it is not dangerous
Give attention to materials and conditions that should be avoid
Do not enter the space without proper respirator or respirator until proper air (oxygenconcentration 18 ~ 23.5%) is available.

Environmental precautions

Prevent entry into waterways, sewers, basements, and confined spaces.

Containment and cleaning up

In case of small leakage, flush contaminated area with large amount of water
In case of small leakage, absorb with sand and non-combustible material and placein container.
In case of large leakage, make a ditch away from liquid spills
Put spills into a clean, dry container with clean shovel, loosely closed, then transfer
container from leak area
In case of powder leakage, cover with plastic sheet to prevent spread and keep dry7. HANDLING AND STORAGE
Precautions for safe handling

Note the substances and conditions to avoid
Wash thoroughly after handling
Note the high temperature
In case of material leakage, reduce the oxygen concentration in the air and cause
suffocation in an enclosed space, so be careful not to spill
Check the oxygen concentration before entering the place because there is a risk ofloss of consciousness or death due to oxygen deficiency at high concentration in theair
Keep this temperature below 20℃ because this material evaporates slowly andreaches hazardous concentrations.
Do not spray because it will evaporate faster if sprayed

Conditions for safe storage

Keep it tightly closed
Store in a cool, dry place

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure standard of chemical compound, biological exposure standard
Domestic regulations
Glycerin

TWA - 10 mg/m3

ACGIH regulation
Glycerin

TWA - 10 mg/m3

Biological release regulation
Glycerin

No information applicable

Individual protection equipment
Respiratory protection
Use respiratory protection equipment certified by Korea occupational safety andhealth agency in a release of gas/liquid according to their chemical physicalproperties.
Use proper filter or half-circled respiratory protection cartridge equipment if the3concentration of release material is lower than 100mg/m
Use proper filter or loose-fitting respiratory protection cartridge equipment such as
hood/helmet shape motor operated equipment or continuous flow protection mask if
the concentration of release material is lower than 250mg/m3

Eye protection

Use proper filter or full face cartridge or motor operated half-circled equipment or
half circled continuous flow air supply respiratory protection equipment if theconcentration of release material is lower than 500mg/m3
Use proper filter or full faced respiratory protection cartridge equipment orhood/helmet type, pressurized mask if the concentration of release material is lower
than 10000mg/m3
Use proper filter or auto air supply (SCBA) equipment or pressurized auto air supply(SCBA) respiratory protection equipment if the concentration of release material islower than 100000mg/m3
Use chemical protection glasses and safety glasses
Install eyewash and emergency shower near work area

Hand protection

Wear suitable chemical resistant gloves

Body protection

Wear suitable chemical resistant clothing

9. PHYSICAL AND CHEMICAL PROPERTIES
AppearanceStateLiquidColor

Dark color to yellow color

Odor

DullOdor thresholdNo information available

pHNeutral

Melting point/freezing point

20 ℃

Early boiling point and range

171 ℃

Flashing point

160 ℃ ((c.c.))

Evaporation rate

No information available

Evaporation rate (solid/liquid)

LiquidMaximum / minimum evaporation or explosion range

19 / 2.7 %Steam pressure

0.0025 ㎜Hg (at 50 ℃)

Solubility

water solubility :1000 g/L at 25 ℃ solvent solubility: alcohol, ethyl acetate, ether
insolubility, benzene, chloroform, carbon tetrachloride, carbon disulfide, oil ether, oil

Vapor density

3.1 ((air=1))

Specific gravity

1.2613 ((water=1))n-octanol/ distribution coefficient

No information available

Self-ignition temperature

370 ℃

Disassemble temperature

290 ℃

Viscosity

954 cP (at 25 C)

Molecular weight

92.09

10. STABILITY AND REACTIVITY
Chemical stability and possibility of hazardous reactions
Glycerin

No information available

Situation to avoid
Glycerin

No information available

Materials to avoid
GlycerinNo information available

Harmful material produce by degradation
Glycerin

No information available

11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Glycerin

irritation, difficult to breathe, area, vomit, diarrhea, headache, dizziness, Sleep
disorder, kidney problem, paralyzed
Can absorb body by suction
Can be absorbed by suction and extinguisher
Through skin, digestive system, can absorb body by inhalation of aerosol
Able to absorb body by suction of steam
Can be absorbed by inhalation, skin and digestive system

Health maleficence information
Acute poison
Oral
Glycerin

LD50 27200 mg/kg Rat (rat/LD50/12600mg/kg(IUCLID))

Ingestion
Glycerin

LD50 > 10000 mg/kg Rat

Inhalation
Glycerin

No information available

Skin corrosion or irritant agent
Glycerin

No irritation on skin

Serious eye damage or irritation
Glycerin

No irritation on eyes

Respiratory organ hypersensitiveness
Glycerin

No information available

Skin hypersensitiveness
Glycerin

No information available

Carcinogenic
Occupational safety and health acts
Glycerin

No information available

Employment announcement
Glycerin

No information available

IARCGlycerin

No information available

OSHAGlycerinNo information available

ACGIH
Glycerin

No information available

NTP
Glycerin

No information available

EU CLP
Glycerin

No information available

Germ cell mutagenicity
Glycerin

Many color mammal red blood cell/negative

Reproduction toxicity test
Glycerin

No information available

Special target poison (1 time exposer)
Glycerin

No information available

Special target poison (long exposer)
Glycerinrat(inhale):1-4mg/l
epiglottis epithelium

Absorption injurious
Glycerin

No information available

12. ECOLOGICAL INFORMATION
Ecotoxicity
FishGlycerin

LC50 5000 ㎎/ℓ 24 hr Carassius auratus

Crustacean
Glycerin

EC50 > 10000 ㎎/ℓ 24 hr Daphnia magna (Daphnia magna EC50(24HR)
10000mg/L(US EPA ECOTOX); Daphnia magna EC50(24HR) >10000 mg/L (EUIUCLID))

Algae
Glycerin(LC50(96hr) 77712.039 mg/L)

Residual fungicide and resolvability
Residual fungicide
Glycerin

No information available

Resolvability
Glycerin

No information available

Life enrichment
Enrichment
Glycerin

No expected life enrichment

Biodegradability
Glycerin63 (%) 14 day Fast biodegradability (OECD SIDS),
93% biodegradability in 30 days (OECD TG 301D) (IUCLID))

SoilGlycerin

No information available

Other harmful influences
GlycerinEnvironmental summary : No information on toxicity on aquatic organisms

13. DISPOSAL CONSIDERATIONS
Waste treatment method
Glycerin

No information available

Disposal considerations
Glycerin

Dispose container and content according to the waster control act

14. TRANSPORT INFORMATION
IATA
Propriety shipping name
Glycerin

No dangerous good in sense of these transport regulations

Hazard class
Glycerin

No information available

Subsidiary class
Glycerin

No information available

Packing groupGlycerin

No information available

UN-No
Glycerin

No information available

Environmental hazards
Glycerin

No information available

15. REGULATORY INFORMATION
Regulations of occupational safety and health act

No information available

Glycerin

Exposure standard materials

Regulations of toxic chemicals regulation act
Glycerin

No information available

Regulations of safety control of dangerous
substances act
Glycerin

4th class The third kind Petroleum(Receptivity) 4000 L

Regulations of waste control act
Glycerin

Designated waste

Regulations of other domestic and international act
Domestic act
Persistent organic pollutants control act
Glycerin

No information applicable

Foreign act
American supervision information
Glycerin

No information applicable

CERCLAGlycerin

No information applicable

EPCRA 302Glycerin

No information applicable

EPCRA 304
Glycerin

No information applicable

EPCRA 313
Glycerin

No information applicable

American supervision information(Rotterdam agreement material)
Glycerin

No information applicable

American supervision information(Stockholm agreement material)
Glycerin

No information applicable

American supervision information(Montreal protocol material)
Glycerin

No information applicableEU Classification information(Confirmed classification results)
Glycerin

No information applicable

EU Classification information(Danger expression)
Glycerin

No information applicable

EU Classification information(Safety expression)
Glycerin

No information applicable

16. OTHER INFORMATION
Source of material
IUCLID (oral)
SIDS (oral)
SIDS (skin corrosive or irritant)
SIDS (severe eye damage or irritation)
NLM (Germ Cell Mutagenesis)
IUCLID (specific target organ toxicity (repeated exposure))
OECD SIDS (fish)
EU IUCLID (Crustaceans)
OECD SIDS (Crustaceans)
US EPA ECOTOX (Crustaceans)
ECOSAR (agar)
OECD SIDS (Enrichment)
IUCLDE (biodegradable)
OECD SIDS (biodegradable)
OECD TG 301C (biodegradable)
OEDC TG 301D (biodegradable)
The above information was acquired by diligent search and/or investigation and the recommendations are based on prudent application of professional
judgment. The information shall not be taken as being all inclusive and is to be used only as a guide. All materials and mixtures may present unknown
hazards and should be used with caution. Since Nippon Genetics Europe cannot control the actual methods, volumes, or conditions of use, thecompany shall not be held liable for any damages or losses resulting from the handling or from contact with the product as described herein.
Questions about the information found on this MSDS should be directed to info@nippongenetics.de.

End of Material Safety Data Sheet