OCIQL201811-100 SDS

EAT-OC-FD-Series (1/7)

Safety Data Sheet
Reference number: OCIQL201811-100
1.

Product andcompany
identification

Issue date: December 13, 2016
Revision date: June 1, 2019

: EAT-OC-FD-BK (OC Color FD-BK)
EAT-OC-FD-LBK (OC Color FD-LBK)
EAT-OC-FD-M (OC Color FD-M)
EAT-OC-FD-LM (OC Color FD-LM)
EAT-OC-FD-Y(OC Color FD-Y)
EAT-OC-FD-C (OC Color FD-C)
EAT-OC-FD-LC(OC Color FD-LC)
Cleaning agent EAT-OC-CL: OCI CO., LTD.
: 4-3-6, Takatsukadai, Nishi-ku, Kobe, 651-2271 Japan: Quality Assurance Department: 078-992-1106: 078-992-1108: Same as above

Product nameCompany name
Address
Department (Person) in charge
Phone number
Fax number
Contact2Hazards
identification

N/A as compound
GHS classification: Category 3 [GHS Classification] (glycerin information)
Skin corrosion/irritation
Serious eye damage/irritation : Category 2B (glycerin information)

3

Composition/infor
mation on
ingredients

Discrimination of single
substance or mixture
Common chemical name or
general name

: Mixture: Food additive, Coloring agent formulation effective colors; 7colors
Food additive, Food machinery cleaning agent (cleaning agent
EAT-OC-CL): As shown in the table below

Composition and content

Product name

EAT-OC-FD-BK

EAT-OC-FD-LB K

EAT-OC-FD-M

EAT-OC-FD-LM

EAT-OC-FD-Y

Effective color

Black

Light black

Red

Light red

Yellow

Material nameContent%

Content%

Content%

Content%

Content%

Food Red No.40

2.60

0.65

3.00

0.75

-

Food Red No.3
(Erythrosine)

0.40

0.10

1.00

0.25

-

Food Blue No.1
(Brilliant Blue FCF)

1.60

0.40

0.05

0.01

-

Food Yellow No.4
(Tartrazine)

0.40

0.10

--5.00Glycerin

15.00

15.00

15.00

15.00

15.00Propylene glycol

15.00

15.00

15.00

15.00

15.00

(Allura Red AC)

Polysorbate 80

0.20

0.20

0.20

0.20

0.20

Water

64.80

68.55

65.75

68.79

64.80

OCIQL201811-100 SDS

EAT-OC-FD-Series (2Product name

EAT-OCFD-C

EAT-OCFD-LC

EAT-OC- CL

Effective color

Blue

Pale blue

Material nameContent%

Content%

Colorlesstransparent
Content%---25956-17-6

N/A

Food Red No.3---

16423-68-0

5-1503

Food Blue No.1

3.00

0.75

-3844-45-9

5-1732---

1934-21-05-1402

15.00

15.00

-56-81-5Glycerin
Propylene glycol

615.0019.00

57-55-6

Polysorbate 80

0.20

0.20-9005-65-6

8-55

Water

66.80

69.05

81.00

7732-18-5-First aid measures

If in eye
If on skin
If inhaled

Priority assessment: Immediately flush eyes with clean water for at least 15
minutes.
: Immediately flush with clean water or lukewarm water.
: Immediately remove the victim to fresh air.
: Rinse mouth. May give 1-2 glasses of milk or water to dilutein the stomach. Then, contact a doctor and seek medical
help if needed.

Fire-fighting measures Extinguishing media
Prohibited media
Specific methods of firefighting: Water, sand, extinguishing powder, carbon dioxide, foam
: None: Combustion gas contains toxic gases such as carbon monoxide,
and avoid smoke inhalation when extinguishing a fire.

Fire-fighting instruction: Cut off the combustion source and use an extinguishing agent to
extinguish the fire. Move containers from the fire area
immediately if it can be done without risk. Use water spray tokeep fire-exposed containers cool.
: Firefighters should wear appropriate protective equipment.
: Ventilate well indoors until the work is finished. Useappropriate personal protective equipment during theoperation to avoid skin contact, splash, etc., and inhalation ofdust and gas.
: Prevent the products from being released into sewers or rivers
that may affect the environment. Prevent contaminatedwastes from being released into the environment without
appropriate treatment.
: Immediately remove adjacent ignition sources and collectleaked and spilled liquid as much as possible. A small
amount is collected by wiping it up with a waste cloth.
Wash away the remainder with plenty of water. Incineratecontaminated clothes immediately in small quantities.

Protection of fire-fighters
Accidental release measures Personal precautions

Environmental precautions

Methods of cleaning up

7(2)-242(2)-234

15.00

If swallowed

5JCSCA No.

Food Red No.40

Food Yellow No.4

4CAS No.

Handling andstorage

Handling
Technical measures
Precautions

Precautions for safe handling
Storage
Storage conditions: Do not use in areas without ventilation.
: Close the container tightly after use.
Avoid leakage, overflow, dispersal and generating steam
without any good reason. Avoid improper handling liketipping over, dropping, strong impact to or dragging thecontainer.
: Desirable to wear appropriate protective equipment to prevent
inhalation or contact with eyes, skin, and clothing.
: Store in a cool, dark place.
After opening the container, seal it immediately and store
it in a refrigerated dark place. Avoid frozen.

OCIQL201811-100 SDS

89Exposure
controls/personalprotection

Physical andchemicalproperties

EAT-OC-FD-Series (3/7)

Personal protective equipment
Respiratory protection
Hand protection
Eye protection
Skin and body protection
Physical properties
Physical stateColorOdor
pH10 Stability andreactivity

11 Toxicologicalinformation
Acute toxicity

Specific temperatures/temperature ranges atwhich changes in physicalstate occur
Flash point
Explosion properties
Specific gravity
Solubility
Stability
Reactivity
Conditions to avoid
Hazardous decomposition
products

Material name: It is not particularly necessary for normal handling, but
desirable to wear.
: Gas mask
: Protective gloves: Safety glasses: Protective boots, protective clothing: Liquid: Each effective color (3 compositions; described in
information on ingredients) Colorless transparent (cleaningagent EAT-OC-CL): Characteristic odor
：5.5 to 7.5 (EAT-OC-FD-BK and other 6 types),
5.5 to 8.0 (EAT-OC-CL only): No data available: No data available: No data available: Approx. 1.0 to 1.1: Soluble in water: Stable under normal conditions of use: No data available: Sunlight, heat, high temperature: Toxic gases (carbon monoxide, nitrogen oxides, sulfuroxides) may be generated when incinerated.

Toxicological information

Food Red No.40

Oral Mouse LD50 > 10,000 mg/kg(Allura Red AC)

Dermal Rabbit LD50 > 10,000 mg/kg
Oral (forced feeding) Dog LD50 > 5,000 mg/kg

Food Red No.3

Oral Mouse LD50 6,800 mg/kg(Erythrosine)

Oral Rat LD50 > 2,700mg/kg
Oral Rat LD50 7,100mg/kg
Intravenous Rabbit LD50 200mg/kg

Food Blue No.1
(Brilliant Blue FCF)
Food yellow No.4
(Tartrazine)
Glycerin

Rat

Oral LD50 >2g/kg

No information
Oral: Not classified because of Rat LD50 = 27,200mg/kg (SIDS)
Dermal: Not classified because it is used in cosmetics, medicines for external
application, etc. and has low toxicity.

Propylene glycol

Inhalation (mist): No data available. Inhalation produces low irritation to themucous membrane of throat, trachea and nose.
Rat Oral LD50 > 20,000 mg/kg
Rabbit Dermal LD50 20,800 mg/kg(male)

Polysorbate 80

Rat

Oral LD50 = 25g/kg

OCIQL201811-100 SDS

EAT-OC-FD-Series (4Skin corrosion/irritation
Material name
Food Red No.40

Toxicological information
No information(Allura Red AC)
Food Red No.3
(Erythrosine)
Food Blue No.1
(Brilliant Blue FCF)
Food Yellow No.4
(Tartrazine)

No information

No information
No information

Glycerin

Category 3 (GHS classification) based on Rabbit 500mg/24H MildHowever, it is not classified in JIS Classification.

Propylene glycol

No information

Polysorbate 80

No information

Severe eye damage/irritation
Material name
Food Red No.40(Allura Red AC)
Food Red No.3
(Erythrosine)
Food Blue No.1
(Brilliant Blue FCF)

Toxicological information
No information
No information

No information

Food Yellow No.4
(Tartrazine)

No information

Glycerin

Irritation Category 2B based on Rabbit 126mg/24H Mild

Propylene glycol

No information

Polysorbate 80

Category 2B based on Mild results of rabbit eye irritation test (RTECS). Eyeirritation (Category 2B)

Respiratory or skin sensitization: No information
Germ cell mutagenicity: No informationOCIQL201811-100 SDS

EAT-OC-FD-Series (5/7)

Reproductive toxicity
Material name
Food Red No.40

Toxicological information
No information(Allura Red AC)
Food Red No.3
(Erythrosine)
Food Blue No.1
(Brilliant Blue FCF)
Food Yellow No.4
(Tartrazine)
Glycerin

No information

No information
No information

Propylene glycol

Not classified because in a two-generation oral reproductive toxicity study in rats,
no effects are observed on sexual function and fertility in adult rats and on
reproductive indicators in postnatal rats. In addition, no teratogenicity was observedin an oral administration study in rabbits, rats, and mice in periods including theirorganogenic stage (JETOC).
No information

Polysorbate 80

No information

Specific target organ systemic toxicity (single exposure): No information
Carcinogenicity
Material name
Food Red No.40(Allura Red AC)

Toxicological information
No information

Food Red No.3(Erythrosine)

No information

Food Blue No.1

No malignant tumor was observed in mice when mice were fed with a dietincluding this coloring agent 1mg/day for 500 to 700 days.

(Brilliant Blue FCF)
Food yellow No.4(Tartrazine)

No information

Glycerin

Not listed (IARC, ACGIH, NTP, EPA)

Propylene glycol

No information

Polysorbate 80

Not listed (IARC, ACGIH, NTP, EPA)OCIQL201811-100 SDS

EAT-OC-FD-Series (6Specific target organ systemic toxicity (repeated exposure)
Material name
Food Red No.40(Allura Red AC)

Food Red No.3
(Erythrosine)
Food Blue No.1
(Brilliant Blue FCF)
Food Yellow No.5
(Tartrazine)

Toxicological information

No embryotoxicity or fetotoxicity was observed at any of the administration paths
evaluated either when this coloring agent was administered orally (intubation) toOsborne-Mendel rats during gestation days 0-19 in a rate of 5, 7, 15, 30, 100, and200mg/kg/day or when a 0.2% water solution of this coloring agent wasadministered daily in drinking water to Osborne-Mendel rats during gestation days
0-20 (equivalent to 230.2mg/kg/day).
No tumor was observed in an injected site or other sites when 1ml of 2% or 3%
solution of this coloring agent was injected subcutaneously into 18 rats for weeks
94-99.
No information

Propylene glycol

No abnormality was observed when effects on mortality, development, intake,hematologic findings, and tumor development were monitored in the study where
the groups of 60 male and 60 female mice were fed with diets containing 0.5, 1.5,
and 5.0％ concentrations of this coloring agent for 24 months.
No adverse effects were observed in the two-year oral administration study in rats,
with NOEL = 1000 mg/kg and a dose 10 times the upper limit of the guidancevalue of Category 2. In addition, a 13-day absorption study in rats showed mild
squamous metaplasia in the airway (epiglottis) with local stimuli at doses of0.662mg/L which exceeds the upper limit of the guidance value of Category 2.
Still, no significant toxic effects or other significant toxic effects were observed(JETOC). Based on the above, not classified.
No information

Polysorbate 80

No information

Glycerin

Aspiration hazard: No information: There is almost no effect in normal handling, but if on the skin or in the eye, follow first aid measures in Section 4.
12 Ecological information Ecological information: Not classified Estimated low toxicity.
Prevent the products from being released into sewers orrivers that may affect the environment.
13 Disposal considerations: Spray into the incinerator fire chamber and incinerate.
Remaining wastes
If a small amount, absorb with sawdust, waste cloth, etc., andincinerate contaminated clothes in small quantities. Thewastewater, including the products, is purified by the activatedsludge process, etc., before disposal.
Containers and: If any products remain in the container, remove them, rinse
packagesthe container with water, and incinerate it in small quantities.
: No data available
14 Transport precautions International: When transporting, make sure the container is not leaked.
restrictions
Avoid collision, tipping, falling, or damage while loading.
Precautions

OCIQL201811-100 SDS

1516

EAT-OC-FD-Series (7/7)

Regulatory information
Food Sanitation Act: Because the products have not undergone inspections by therelevant authority, they cannot be used in food products inJapan. (Except EAT-OC-CL )Example of food labeling
U.S. FDA
Fire Service Act
Poisonous and Deleterious
Substances Control Act
Industrial Safety and Health
Act
Ship Safety Act (regulations
for the carriage and storage ofdangerous goods in ship)
Civil Aeronautics Act
Pollutant. Release andTransfer Register Act(PRTR)
Act for the Prevention ofMarine Pollution andMaritime Disasters
Cabinet Order on Export
Trade Control: Check for each country.
: Compatible materials are used for each synthetic dye
: N/A
: N/A
: N/A
: N/A
: N/A
: N/A
: Noxious liquid substance category Z (for glycerin and propyleneglycol) Noxious liquid substance category Y (for polysorbate 80): Appendix 1, Section 16 (catch-all control)
Chapter 29 Organic chemicals (for glycerin and propylene glycol)
Chapter 34 Organic chemicals (for polysorbate 80)

OtherUse as a food coloring agent for export to the U.S. The coloring agents used in the products have been approvedby the U.S. Food and Drug Administration (FDA) but have not been inspected by the relevant authorities in Japan.
Using them in foods for domestic use in Japan constitutes a violation of the Food Sanitation Act. Please be carefulwith the management of the products.
The information above is a reference representing the best available information. We make any warranty,
express or implied, concerning such information,
In addition, the precautions apply only to normal handling, and in the case of special handling, please takeappropriate safety measures for use or purposes.
The information contained herein may be revised according to new findings.