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MATERIAL SAFETY DATA SHEETRINSYUNDOU Co.,Ltd.
RSD Building 2F
2-32 Nagarahigashi, Gifu
Gifu, Japan 502-0082

1.

Emergency telephone number
Phone Number: 0081+58295-5755
Fax Number: 0081+58294-0020

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product Name:
CAS-No.:Recommended use:
Product Code:

GSLA LMC-6044P Black
Aerosol,Glass/Ceram
MixtureIndustrial Use Only
1379493

Date of Preparation: 03/04/2013

2. HAZARDS IDENTIFICATION
Emergency Overview
Warning
Highly flammable liquid and vapor. Vapors may travel to a source and flash back. Vapors may cause flash fire or explosion. May cause
respiratory tract, eye and skin irritation. May cause allergic skin or respiratory reaction. May be harmful if absorbed through skin. May be
harmful by inhalation. May be harmful if swallowed. Contains titanium dioxide which may cause lung damage including cancer. Contains
crystalline silica which causes silicosis and lung cancer.

Health:Flammability:
Physical Hazard:

Color: Black
Physical Liquidstate:
Alcohol-like
Odor:

PPE:

NFPA 704
2
3
0

HMIS
2*
3
0
X

Potential Health Effects
Principle routes of exposure:

Inhalation, ingestion, skin and eye contact.

Eye contact:

Contact with eyes may cause irritation.

Skin contact:

Prolonged skin contact may cause skin irritation. May be harmful if absorbed through skin. May
cause allergic skin reaction.

Inhalation:

May cause irritation of respiratory tract. May be harmful by inhalation. May cause severe
allergic respiratory reaction.

Ingestion:

May irritate digestive tract. May be harmful if swallowed.

Chronic toxicity:

Chronic inhalation exposure can cause lung damage. Titanium Dioxide is listed by IARC as
possibly carcinogenic to humans (Group 2B) based on inadequate evidence of carcinogenicity
in humans and sufficient evidence in experimental animals. Long term inhalation causes lungdamage (silicosis and cancer). Respirable crystalline silica has been classified as a Group I(sufficient evidence in humans for carcinogenicity) carcinogenic by IARC and is listed by NTP
as a substance which may reasonably be anticipated to be a carcinogen. Suspect cancer
hazard (cobalt compound).

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Petroleum gases, liquefied, sweetened
Proprietary complex inorganic compound
2-Butoxyethanol
1-Methoxy-2-propanol acetate
Frit*

CAS Number
68476-86-8
111-76-2
108-65-6

Weight %20 - 30%
20 - 30%
10 - 20%
5 - 10%20 - 30% (May contain - see below)____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

Page 1 of 7

3. COMPOSITION/INFORMATION ON INGREDIENTS
Titanium Dioxide
Quartz silica

13463-67-7
14808-60-7

<0.5%
<0.5%

The specific chemical identities are being withheld as a trade secret (29CFR1910.1200).
* Frit, with CAS # [65997-18-4], is a mixture of inorganic chemical substances produced by rapidly quenching a molten, complex
combination of materials, confining the chemical substances thus manufactured as non-migratory components of glassy solid flakes or
granules. These components are present as part of the Frit.

4. FIRST AID MEASURES
Eye contact:

Rinse immediately with plenty of water, also under the eyelids. Get medical attention if irritation
develops.

Skin contact:

Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing
before re-use. If symptoms persist, call a physician.

Inhalation:

Exposures require specialized first aid with contact and medical follow-up.

Ingestion:

Drink plenty of water. Do not induce vomiting. Consult a physician if necessary.

Notes to physician:Treat symptomatically

5. FIRE-FIGHTING MEASURES
Flash point (°C): 14( 57°F) Method: EstimatedSuitable extinguishing media:

Use dry chemical, CO2, water spray or "alcohol" foam.

Hazardous decomposition products Carbon oxides. Heavy metal compounds.
under fire conditions:
Special protective equipment for
firefighters:

As in any fire, wear self-contained breathing apparatus (pressure-demand, NIOSH approved orequivalent) and full protective gear

Unusual hazards:

Flammable. Vapors may form explosive mixture with air. Vapors are heavier than air and may
spread along floors. Vapor may travel considerable distance to source of ignition and flashback.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Flammable liquid. Remove all sources of ignition. Remove all non-essential people from theaffected area. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable
respiratory equipment. Avoid contact with skin, eyes and clothing. Wear personal protective
equipment.

Environmental precautions:

Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do
not flush into surface water or sanitary sewer system. Do not allow material to contaminate
ground water system.

Methods for cleaning up:

Wear personal protective equipment. Absorb spill with inert material (e.g. dry sand or earth),then place in a chemical waste container. Clean contaminated surface thoroughly. Dispose ofpromptly.

7. HANDLING AND STORAGE____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

Page 2 of 7

7. HANDLING AND STORAGE
Handling:
Keep away from open flames, hot surfaces and sources of ignition. Handle in accordance with good industrial hygiene and safety
practice. Use only in area provided with appropriate exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory
equipment. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Do not eat, drink, or smoke in areas of use
or storage. Do not take internally. Wash thoroughly after handling.
Storage:
Keep containers tightly closed in a cool, well-ventilated place. Keep product and empty container away from heat and sources ofignition.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limits
Minimize exposure in accordance with good hygiene practice.
Components
Frit

2-Butoxyethanol

Titanium Dioxide
Quartz silica

OSHA
0.5 mg/m3 TWA Sb
5 mg/m3 TWA Zr
5 mg/m3 Ceiling Mn
50 ppm TWA
240 mg/m3 TWA
prevent or reduce skin absorption
15 mg/m3 TWA total dust
0.1 mg/m3 TWA (respirable dust)

ACGIH
0.5 mg/m3 TWA Sb
5 mg/m3 TWA Zr
0.2 mg/m3 TWA Mn
20 ppm TWA

10 mg/m3 TWA
0.025 mg/m3 TWA respirable fraction

Engineering measures:

Provide appropriate exhaust ventilation wherever dust, mist, vapors, or fumes can begenerated. Ensure that eyewash stations and safety showers are proximal to the work-station
location.

Eye protection:

Safety glasses with side-shields.

Skin and body protection:

Lightweight protective clothing. Keep working clothes separately. Remove and wash
contaminated clothing before re-use.

Hand protection:

Impervious gloves. Follow the recommendations given by the manufacturer of protective
gloves.

Respiratory protection:

In case of insufficient ventilation, wear suitable respiratory equipment. NIOSH-approved
respirators should be worn where engineering controls and work practices do not reduce
exposure to or below the PEL. Seek professional advice prior to respirator selection and use.

Hygiene measures:

Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES
Color:
Odor:
Boiling point/range (°C):
Melting point/range (°C):
Vapor density:
Evaporation Rate (Water = 1)
VOC content

Black
Alcohol-likeNo data available
No data available
Non-volatile
Non-volatile0

Physical state:
Molecular weight:
pH:
Specific gravity (Water =1):
Vapor pressure :Water solubility:

LiquidNo data available
No data available
No data available
No data available
Insoluble

10. STABILITY AND REACTIVITY
Stability:

Stable at normal conditions

Polymerization

Will not occur.

Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Heavy metal compounds.

____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

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Materials to avoid:

None known

Conditions to avoid

Remove all sources of ignition.

11. TOXICOLOGICAL INFORMATION
Acute toxicity:

Information given is based on data on the components and the toxicology of similar products

Chronic Toxicity:

In lifetime inhalation studies of rats, airborne respirable size titanium dioxide particles havebeen shown to cause lung tumors at concentrations associated with substantial particle lungburdens and consequential pulmonary overload and inflammation. However, other laboratory
animals such as mice and hamsters did not develop lung tumors under similar testing withtitanium dioxide. Human epidemiology studies do not suggest an association between
occupational exposure to titanium dioxide and risk for cancer. Contains crystalline silica whichcauses silicosis and lung cancer.

Carcinogenic Effects:

Respirable crystalline silica has been classified as a Group I (sufficient evidence in humans for
carcinogenicity) carcinogenic by IARC and is listed by NTP as a substance which may
reasonably be anticipated to be a carcinogen. Crystalline silica is also a known cause ofsilicosis, a non-cancerous lung disease caused by excessive exposure to crystalline silica.
IARC has identified Cobalt and Cobalt compounds as "possibly carcinogenic" as a group.

Components
2-Butoxyethanol

NIOSH - Pocket Guide - Target Organs
liver kidneys lymphoid system skin blood eyes CNS respiratory system hematopoietic
systemeyes respiratory system skin
respiratory system skin
respiratory systemeyes respiratory system

Chromium
CobaltTitanium Dioxide
Quartz silica

Component information, if any, is listed below

Frit
Oral LD50 (Rat) = 2000 mg/kg
LD50s and LC50s:
Known Human Carcinogen
NTP:
Reasonably Anticipated To Be A Human Carcinogen
NTPS. Carcinogen:
ListedIARC - Group 1:
ListedIARC - Group 2A:
ListedIARC - Group 2B:
Proprietary complex inorganic compound
ListedIARC - Group 2B:
2-Butoxyethanol
Inhalation LC50 (Rat) = 2.21 mg/L
LD50s and LC50s:
Dermal LD50 (Rabbit) = 220 mg/kg
Dermal LD50 (Rat) = 2270 mg/kg
Inhalation LC50 (Rat) = 450 ppm
Oral LD50 (Rat) = 470 mg/kg
1-Methoxy-2-propanol acetate
Oral LD50 (Rat) = 8532 mg/kg
LD50s and LC50s:
Dermal LD50 (Rabbit) = 5000 mg/kg
Titanium Dioxide
Oral LD50 (Rat) = 10000 mg/kg
LD50s and LC50s:
Present
OSHA - Select Carcinogens:
ListedIARC - Group 2B:
Quartz silica
Oral LD50 (Rat) = 500 mg/kg
LD50s and LC50s:
Present
OSHA - Select Carcinogens:
Known Human Carcinogen
NTP:
ListedIARC - Group 1:____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

Page 4 of 7

12. ECOLOGICAL INFORMATION
Aquatic toxicity:

No data is available on the product itself. Information given is based on data on thecomponents and the ecotoxicology of similar products.

2-Butoxyethanol
Ecotoxicity - Fish Species Data:
96 h LC50 (Lepomis macrochirus) = 1490 mg/L static
96 h LC50 (Lepomis macrochirus) = 2950 mg/L
Ecotoxicity - Water Flea Data:
24 h EC50 (Daphnia magna) = 1698 - 1940 mg/L
48 h EC50 (Daphnia magna) = 1000 mg/L
1-Methoxy-2-propanol acetate
Ecotoxicity - Fish Species Data:
96 h LC50 (Pimephales promelas) = 161 mg/L static
Ecotoxicity - Water Flea Data:
48 h EC50 (Daphnia magna) = 500 mg/L
Not determined
Persistence and degradability:

13. DISPOSAL CONSIDERATIONS
Waste from residues / unused
products:

Waste must be disposed of in accordance with federal, state and local environmental control
regulations. Where possible recycling is preferred to disposal or incineration.

14. TRANSPORT INFORMATION
DOT (U.S.)
UN/ID No:
Proper shipping name:
Hazard Class:
ERG No:

UN1950Aerosols
2.1
126

TDG (Canada)
UN-No
Proper Shipping Name
Hazard Class

UN1950Aerosols
2.1

IMDG
UN-No
Proper Shipping Name
Hazard ClassEms:
Description

UN1950Aerosols
2.1
F-D, S-U
UN1950, Aerosols, 2.1

IATA
UN-No
Proper shipping name
Hazard ClassERG Code
Shipping Description

UN1950Aerosols, flammable
2.1
10P
UN1950,Aerosols, flammable,2.1____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

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15. REGULATORY INFORMATION
U.S. Regulations:
Not subject to TSCA 12(b) Export Notification

TSCA:

SARA 313:
Components
Chromium (1 - 5%)
Cobalt (1 - 5%)
Cobalt inorganic compounds (20 - 30%)
Chromium (III) Compound (20 - 30%)
Zinc compounds (5 - 10%)

U.S. - CERCLA/SARA - Section 313 - Emission Reporting
1.0 % de minimis concentration
0.1 % de minimis concentration
0.1 % de minimis concentration
1.0 % de minimis concentration
1.0 % de minimis concentration

State Regulations
This product or its ingredients have been evaluated for New Jersey, Pennsylvania, and California Prop 65 supplier notification
requirements. Substances that are subject to notification requirements, if any, are listed below.
Components
Chromium
CobaltCobalt inorganic compounds
Chromium (III) Compound
Zinc compounds

PARTK:
Listed (PARTK)
Listed (PARTK)
ListedListedListed (PARTK)

Components
Toluene2-Butoxyethanol
Ethanolamine
Chromium (III) compounds
Cobalt compounds
Quartz silica
Zinc compounds

NJRTK:
1866
Listed (NJRTK)
0835
0432
0520
1660
2021

Components
TolueneState Regulation - CA Prop65
Developmental Toxicity
Reproductive Female
Carcinogen
Carcinogen
Carcinogen

CobaltTitanium Dioxide
Quartz silica

Canadian WHMIS
WHMIS hazard class:

D2B Toxic materials D2A Very toxic materials B2 Flammable liquid

Canadian Ingredient Disclosure List (IDL):
Components
2-Butoxyethanol
Cobalt compounds
Chromium (III) Compound

Canada - WHMIS Ingredient Disclosure:1
0.1
1International Inventories
TSCA 8(b):Canadian DSL/NDSL list
EC-No.
Philippines (PICCS):
Japan (ENCS):
Korea (KECL):
China (IECS):
Australia (AICS):New Zealand (NZloC):

Listed or exempt.
All ingredient(s) are listed on the DSL or NDSL
Listed or exempt.
Listed.
One or more ingredient(s) are not on the ENCS list.
Listed.
Listed.
One or more ingredient(s) are not on the AICS list.
One or more ingredient(s) are not on the NZloC list.

____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

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16. OTHER INFORMATIONFor Industrial Use Only
Prepared by: Ferro Technical Center
Disclaimer: The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources
believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. No
warranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this product must
decide what safety measures are necessary to safely use this product, either alone or in combination with other products, anddetermine its environmental regulatory compliance obligations under any applicable federal or state laws.

End of Safety Data Sheet____________________________________________________________________________________________
Product name: GSLA LMC-6044P Black Aerosol,Glass/Ceram

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