Product Name : T-REZ R series

Revision date: 1 April 2024___________________________________________________________________________________________________________________SAFETY DATA SHEET
1. IDENTIFICATIONPRODUCT IDENTIFIER
Product Name:
Synonyms:

SUPPLIER’S DETAILS
Name
Address
Phone
Contact
Emergency Phone Number
RECOMMENEDED USE OF THE CHEMICALAND REATRICTIONS OF USE

T-REZ R series
T-REZ RA100, T-REZ RB093, T-REZ RB100, T-REZ RC093,
T-REZ RC100, T-REZ RC115, T-REZ RD104, T-REZ RE100,
TR0001, TR0002i
ENEOS Materials Corporation

1-5-2 Higashi-shimbashi Minato-ku, Tokyo 105-7109 Japan+81-(0)3-6685-3815
Sales & Marketing Dept.3 Group3+81-(0)3-6685-3815(Available time; 9:00am - 5:00pm JST on Monday - Friday)
Tackifier resin/Adhesive component, Road marking
Industrial use only. Do not use for medical or food without advice ofexperts.

2. HAZARDS IDENTIFICATIONThis material is not hazardous according to regulatory guidelines (see SDS Section 15).
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
Physical/Chemical Hazards
Contact with hot material can cause thermal burns which may result in permanent damage.
May form combustible dust concentrations in air (during processing/handling). Material can accumulate
static charges which may cause an ignition. Ignition on material dust can cause dust explosion.
Spilled pellets present a slipping hazard on hard surfaces.
Health Hazards
If dust is generated, it could scratch the eyes and cause minor irritation to the respiratory tract.
When heated, the vapors/fumes given off may cause eye and respiratory tract irritation. Excessive
exposure may result in skin irritation.
Environmental Hazards
No additional hazards.
Note:

When heated, exposure for material fume given off may result in eye, nose, skin, or lung irritation.
Contact with hot molten material can cause thermal burns.
Excessive exposure of dust could scratch the eyes and cause minor irritation to the respiratory tract.
This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which
may vary from person to person.

3. COMPOSITION / INFORMATION ON INGREDIENTSThis material is defined as a substance.
No Hazardous Substance(s) or Complex Substance(s) required for disclosure.

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Note: The product may contain varying levels of additives such as slip and antiblocking agents, antioxidants andstabilizers.

4. FIRST-AID MEASURESDESCRIPTION OF NECESSARY FIRST-AID MEASURE
Inhalation
Remove from further exposure. If respiratory irritation, dizziness, nausea, or unconsciousness occurs,
seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device
or use mouth-to-mouth resuscitation. When mouth-to-mouth resuscitation, responder should be careful to
not expose material. For those providing assistance, avoid exposure to yourself or others. Use adequate
respiratory protection.
Skin contact
If burned by contact with hot material, molten material adhering to skin should be cooled as quickly as
possible with water, and see a physician for removal of adhering material and treatment of burn.
Eye contact
Flush thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists, get medical attention.
Ingestion
No adverse effects due to ingestion are expected.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DALAY
Exposure for material fume given off on heating may result in eye, skin, or respiratory irritation.
Contact with hot material can cause thermal burns.
INDICATION OF MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF NECESSARY
None

5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Suitable Extinguishing Media:
Inappropriate Media: NoneFoam, dry chemical, carbon dioxide (CO2), plenty of water

SPECIFIC HAZARDS ARISING FROM THE CHEMICALSSpecific Hazards Arising from the Chemicals: May form combustible dust. Fine dust dispersed in air
in sufficient concentration and in the presence of an ignition source is a potential dust explosion hazard.
Hazardous Combustion Products:
Incomplete combustion products, carbon monoxide, smoke, fume
SPECIFIC PROTECTIVE ACTIONS FOR FIRE-FIGHTERS
Specific protective actions for fire-fighter:
Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathingapparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Fire Fighting Instructions:
Evacuate non-emergency personal to safe area. Extinguish fire with appropriate media. Stop leak if you
can do it without risk.
Move container if you can do it without risk. Use water spray or fog for coolingtanks or containers surround fire. If a leak or spill has not ignited, use water spray to disperse the vapors
and to protect personnel attempting to stop a leak or to move container. Prevent runoff from fire control or
dilution from entering streams, sewers, or drinking water supply.

6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
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Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required due to toxicity or flammability of the material. See Section 5 for fire fighting information. See theHazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8
for advice on the minimum requirements for personal protective equipment. Additional protective measures
may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency
responders.
For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for spilledmaterial and, when applicable, Self Contained Breathing Apparatus (SCBA) can be used depending on thesize of spill and potential level of exposure. If the exposure cannot be completely characterized or an
oxygen deficient atmosphere is possible or anticipated, SCBA is recommended.
If contact with hot material is likely, thermally protective work gloves are recommended. Chemical goggles
are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes
are usually adequate. Large spills: full body suit of antistatic material is recommended.
Notification Procedures
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicableregulations. Material is combustible. Evacuate non-emergency personal to safe area.
ENVIRONMENTAL PRECAUTIONSNo additional information
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
Land Spill:
Spilled pellets present a slipping hazard on hard surfaces. Prevent dust cloud.
Small
Dry Spills: With clean shovel place material into clean, dry container and cover loosely; move containers
from spill area.
Water Spill:
Stop leak if you can do it without risk. Material will sink. Consult an expert.
Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current
direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts
should be consulted. Note: Local regulations may prescribe or limit action to be taken.

7. HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING
Material may generate dust. Minimize dust generation and accumulation. Routine housekeeping should
be instituted to ensure that dusts do not accumulate on surfaces. Dust from material can accumulate
electrostatic charges due to friction from transfer and mixing operations and cause an electrical spark(ignition source). Provide adequate precautions to ignition sources, such as electrical grounding andbonding, inert atmosphere or non-sparking tools. However, bonding and grounds may not eliminate thehazard for static accumulation. Consult local applicable standards for guidance.
Material can generate combustible dust during transportation and handling. When transfer material intoanother container, pay attention not to generate dust.
Material can accumulate static charges.
Protect material from direct sunlight. Care should be taken when storing and handling this product. Apartfrom the specific nature of the polymer product, conditions such as humidity, sunlight, and temperature havean influence on the way the product behaves during storage and handling. Special attention should be paid
to avoid inappropriate stacking of palletized bags or other package units. Indeed, polymer products may bedimensionally unstable under certain conditions. Avoid conditions generating heat during transfer
operations.
Material can generate combustible dust during transportation and handling. When transfer container, pay
attention to dust.
Material can accumulate static charges.
Avoid contact with hot material.
CONDITION FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIESStore in a cool, dry place. Avoid storing material with 80 degrees C or less as softening point at 25 degrees
C or more for long time.
Avoid storing material with 80 - 90 degrees C or less as softening point at 30
degrees C or more for long time. The container choice, for example storage vessel, may effect static
accumulation and dissipation.
Suitable Materials and Coatings (Chemical Compatibility):
Paper, Stainless Steel, Steel, Teflon,
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Unsuitable Materials and Coatings:

No additional information

8. EXPOSURE CONTROLS / PERSONAL PROTECTIONCONTROL PARAMETERS
Occupational exposure limits/standards (Note: Exposure limits are not additive)
Substance Name

Particles(insoluble or poor
soluble) Not Otherwise
Specified

Form
Dust

Limit / Standard

NOTE

TLV:3mg/m3(respirabl e particles),
10mg/m3(inhalable
particles) ppm

SourceACGIH(2020)

Biological limit values
No biological limits allocated
NOTE: Limits/standards shown for guidance only.

Follow applicable regulations.

APPROPRIATE ENGINEERING CONTROLSThe level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider: Adequate ventilation should be provided so that exposure
limits are not exceeded.
SPECIAL PRECAUTIONS: Should significant vapors/fumes be generated during thermal processing of
this product, it is recommended that work stations be monitored for the presence of thermal degradation
by-products which may evolve at elevated temperatures (for example, oxygenated components). Processorsof this product should assure that adequate ventilation or other controls are used to control exposure. It is
recommended that all dust control equipment such as local exhaust ventilation and material transportsystems involved in handling of this product are designed and maintained to minimize dust generation andaccumulation. Ensure that dust-handling systems (such as exhaust ducts, dusts collectors, vessels, andprocessing equipment) are designed to minimize the potential for dust ignition and prevent explosion
propagation.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT (PPE)
Personal protective equipment selections vary based on potential exposure conditions such as applications,handling practices, concentration and ventilation. Information on the selection of protective equipment for
use with this material, as provided below, is based upon intended, normal usage. Any specific protective
equipment information provided is based on published literature and protective equipment manufacturer
data.
Eye/Face Protection:
Chemical goggles are recommended.
Skin and Body Protection:
The types of clothing to be considered for this material include: If product is hot, thermally protective apron
and long sleeves are recommended.
Respiratory Protection:
If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate toprotect worker health, an approved respirator may be appropriate. Respirator selection, use, andmaintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to beconsidered for this material include: for mist/dust
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressuremode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are
inadequate, if concentration is high, gas/vapor warning properties are poor, or if air purifying filter
capacity/rating may be exceeded.
Hand Protection:
Use suitable protective glove. Glove suitability and breakthrough time will differ depending on the specificuse conditions. Contact the glove manufacturer for specific advice on glove selection and breakthroughtimes for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be
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considered for this material include:
When handling hot materials, thermally protective gloves are recommended. If contact with forearms islikely, wear gauntlet style gloves.
Specific Hygiene Measures:
Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing andprotective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot becleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect theenvironment by applying appropriate control measures to prevent or limit emissions.

9. PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations
only and may not fully represent product specifications. Contact the Supplier for additional information.
Physical State:
Colour:Odour:
Melting Point/Freezing Point:
Boiling Point or Initial Boiling Point
and Boiling Range:
Flammability :Lower and Upper Explosion Limit/Flammable Limits (Approximate volume % in air):Flash Point:
Auto-ignition Temperature:
Decomposition Temperature:
pH:
Kinematic Viscosity:
Solubility:
Partition Coefficient n-Octanol/Water (log value):
Vapor Pressure:
Density and/or Relative Density (at 20 ºC):
Relative Vapour Density (Air = 1):

SolidPale yellow
None to Mild
No data (Softening Point 80°C – 120 °C)
No dataCombustible solid
N/A
N/A
No data
No data
N/A
N/A
Negligible
N/A
N/A
0.95 – 1.02 g/cm³ @25°C
N/A

10. STABILITY AND REACTIVITY
REACTIVITY:

No reactivity under normal conditions.

CHEMICAL STABILITY:

Material is stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS:CONDITIONS TO AVOID:

Hazardous polymerization or reaction will not occur.

Flame and high energy source of ignition.
Heating for long time

INCOMPATIBLE MATERIALS: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS:
In fire, carbon monoxide can be generated.

Material does not decompose at ambient temperatures.

11. TOXICOLOGICAL INFORMATION
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Information described here are based on the data for this material, structurally similar materials and/or components.
Information
Conclusion/Remarks
Acute toxicity
Oral
Classification not possible
No data available (This material is hydrocarbon polymer, and it is notexpected to be harmful.)DermalNo data available (This material is hydrocarbon polymer, and it is notexpected to be harmful.)Classification not possible

Inhalation （Dust）
No data available (This material is hydrocarbon polymer, and it is notexpected to be harmful.)Classification not possible

Skin corrosion/irritation
No data available

Classification not possible

Serious eye damage/irritation
No data available

Classification not possible

Sensitization
Respiratory
No data available
Skin
No data available

Classification not possible
Classification not possible

CMR hazard
Germ cell mutagenicity
No data available

Classification not possible

Carcinogenicity
No data available

Classification not possible

Reproductive toxicity
No data available
Additional category for effects on or via lactation
No data available

Classification not possible
Classification not possible

Specific target organ toxicity
Single exposure
No data available
Repeated exposure
No data available

Classification not possible
Classification not possible

Aspiration hazard
This material is solid.

Not classified

OTHER INFORMATIONIARC Classification: None

12. ECOLOGICAL INFORMATION
Information described here are based on the data for this material, structurally similar materials and/or components.
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Revision date: 1 April 2024___________________________________________________________________________________________________________________TOXICITY
No information available for toxicity to aquatic organisms.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
No information available for biodegradation.
Hydrolysis:
Transformation due to hydrolysis not expected to be significant.
Photolysis:
Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
No additional information
BIOACCUMULATION POTENTIAL
Expected that potential to bioaccumulate is low.
MOBILITY IN SOIL
Material -- Low solubility and floats and is expected to migrate from water to the land.
partition to sediment and wastewater solids.

Expected to

OTHER ADVERSE EFFECTS
Hazard to the Ozone Layer
Not expected to be harmful to ozone layer.

13. DISPOSAL CONSIDERATIONSDISPOSAL METHODS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicablelaws and regulations, and material characteristics at time of disposal.
Disposal Recommendations
Dispose of waste in an enclosed controlled burner (preferentially with energy recovery), or appropriate
recycling methods in accordance with applicable laws and regulations, and product characteristics at time ofdisposal.
Empty Container Warning
Empty Container Warning (where applicable): Empty containers may contain residue and can be
dangerous. Do not attempt to refill or clean containers without proper instructions. Empty containers
should be completely drained and safely stored until appropriately reconditioned or disposed. Empty
containers should be taken for recycling, recovery, or disposal through suitably contractor and in accordancewith governmental regulations.

14. TRANSPORT INFORMATIONLAND - Precautionary Transportation Measures & Conditions:
Comply with applicable laws and regulations.
SEA (IMDG) / AIR (IATA)
UN Number:
UN Proper Shipping Name:Transport Hazard Class(es):Packing Group:
Environmental hazards:
EMS Number:

No-

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code：
Not applicableThis product is not liquid substances.
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15. REGULATORY INFORMATIONThis material is not considered hazardous according to the Classification of Chemicals based on Globally
Harmonized System of Classification and Labelling of Chemicals (GHS).
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT IN QUESTION
National Laws and Regulations:
Comply with applicable laws and regulations.

16. OTHER INFORMATION
N/A = Not applicable----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best knowledge and belief of ENEOS
Corporation, accurate and reliable as of the date issued. You can contact ENEOS Materials Corporation to insurethat this document is the most current available from ENEOS Materials Corporation. The information andrecommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy
itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility
to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate
warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document isstrictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole
or in part, is not permitted.

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