3C07(DMEDO-EBDT)2PF6 !"#$%&'()!
*+,-./0 112-345 267
89:7 ; 11<=7 > 11?@7 AB 11CD7 EF 21GH7 IJ 21KL7 MN 17!
OPQ7 RSTUVWXYZ[\]^_`abcdVefghWX(TTF)ij' EDO-TTF ! PF6 klm
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Pv!l]"#$%&'()yv^ona [1b]~!vl]x()4!^T2-g ¡ ¢ ^ C £ l EDO-TTF ! ¤  g ¥ ¦ !  ¥ ¦ § ¨ ' (EDO-TTF-d2)© ª «¬V g '(MeEDO-TTF)!­®¯°!±VZXdY±gk!4ltno²³|}o´(µ¶)[2]~·T¸¹!º»¼½¾¿ÀlmnoÁ0-Â< g¡¢¯!ÃÄ²³lÅT(DMEDO-TTF)2PF6 !"#$%&'()ltnoz{ona[3]~BÆT+,- g¡¢^C£l EDO-TTF !¤Ç¡ ÈÉÊËÌ¡EDO-EBDT ij'(µ 1)!²³yÍÎÏ}ona~ÐÑ4Òa(DMEDO-EBDT)2PF6
 185 K ÓS"#$%&'()^Ô`¯yÕÏ}OS[4]onayT°!¬±Ö×FÏsl|}onvn ~@²³!4! 185 K lmax()!¬±Ö×^ØÙaÚT3ÛÜÝÞßàá^ânãÛäåSO

ROSS

R1OSS

R2SSR
R = H: EDO-EBDT
R = Me: DMEDO-EBDT
R = SMe: BTMEDO-EBDTælmaËÌ¡çC!èéêë^ì!

R1 = R2 = H: EDO-TTF
R1 = R2 = D: EDO-TTF-d2
R1 = Me; R2 = H: MeEDO-TTF
R1 = R2 = Me: DMEDO-TTFµ¶7 EDO-EBDT, EDO-TTF ij'!Þß7z{`a~OíîQ (DMEDO-EBDT)2PF6 !ïÜÝ DMEDO-EBDT ¯ TBA·PF6 ^Uð«¡gCT5 °C ñºà`a¯lÅòó~ôõ!ö÷nøùÝmúûõ!üÇýþùÝyÿÏ}ayTôõ!
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ZX;ºy./Òa~<=>sÏ?()Ûä 185 K Å@©©qnÛä 200 K ÞßÐ¶ (DMEDO-EBDT)2PF6 !ÜÝd¬¡ð
T/K
Crystal system
Space groupa/Å
b/Å
c/Å
!/°"/°#/°
V / Å3R 1; R w
GOF

300
triclinicP"1 (#2)
7.145(3)8.067(4)13.884(6)99.530(6)91.515(6)102.187(6)769.86(6)0.0429; 0.1364
0.919

200
triclinic
P1 (#1)
7.0563(16)8.0588(19)13.755(3)99.289(3)91.350(3)102.655(3)751.7(3)0.0285; 0.0586
1.070

150
triclinic
P"1 (#2)
14.041(4)15.467(5)16.036(5)65.380(4)77.672(4)71.310(4)2985.9(15)0.0652; 0.1413
1.731

100
triclinic
P"1 (#2)
13.980(4)15.467(4)15.933(4)65.537(3)78.223(3)71.397(3)2961.6(14)0.0716; 0.1566
2.388

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(--- ]aAq%P]bA- (200 K).

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H¦§¤VW!"7¨©FGR<ªk«5 150 K q¬­RVW!"-y®*¯FC°±²-+,7'oq 2 ³q¤%PQR<?@AB,Cy´µ¶q 4 B,DE·B,A, B, C, D¸Fn¹ºq»····BADC···¸#U*:iq c ¼¹ºq½¾-MoNOPQ
R·¿¸<?@AB,Z[-\]^_`CB, B q¬QPcdeaAbA-&pªkÀ,7ÁOÂ¤%PQR<?@AB, A, B, C, D -IJ#B,rs-tuvAwx+-ylzÃimno%&y®*Ä;Å;+0.5, +1, +0.5, 0 'mnoi;*¯F
C 200 K FÆi;&Ç¤B,IJKLMC¤
Q<+0.5 È-B, A, C CÄ;Å; c ¼qÉ%PÊ

¿!(DMEDO-EBDT)2PF6 -y´VW (150 K);a) a ¼éê; b) ?@AB,ÔËëìIJÖ×ØÙA_.

ËUÌÍÎÏ#Ð%PQR<(- c ¼qÉ%&-ÌÍÎÏ-Ñq+1 È-B, B*0 È-B, D
7ÒÓqÔËU&ÌÍÎÏ7:;PQRÕUQIJÖ×ØÙA_#SU&<Ú*(-Û-4ª¯-`ÜÝÞ#ß|Rà¶F SQUID qRáMâ-9ã#äåUP¬H*(-y®qQPoæçèR<íîïðñ[1] a) M. Chollet et al., Science 2005, 307, 86; b) A. Ota et al., J. Mater. Chem. 2002, 12, 2600.
[2] a) Y. Nakano et al., Solid State Science 2008, 10, 1780; b) X. Shao et al., J. Mater. Chem. 2008, 18, 2131;c) X. Shao et al., Chem. Mater. 2008, 20, 7551; d) X. Shao et al. Chem. Mater. 2009, 21, 1085.
[3] òóô, !"#$%&'()* 2008, 3A12.
[4] õöô, +,-'*! 89 ./0*, 2009, 3E7-26.