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3-Acrylamidophenyl boronic acid,
JUNSEI CHEMICAL CO., LTD.,10111jis_J_E1-1,04/06/2015
Date of issue: 04/06/2015

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertaking
Product identifier:Product name: 3-Acrylamidophenyl boronic acid
Product code(SDS NO): 10111jis_J_E1-1
Details of the supplier of the safety data sheet
Manufacturer/Supplier: JUNSEI CHEMICAL CO., LTD.
Address: 1-6, Ohmano-Cho, Koshigaya, Saitama 343-0844, Japan
Competent section: Quality Assurance Department
Telephone number: +81-48-986-6161
FAX: +81-48-989-2787
e-mail address: shiyaku-t@junsei.co.jp

2. Hazards identification
GHS classification and label elements of the product
Classification of the substance or mixture
HEALTH HAZARDS
Acute toxicity Oral: Category 4
Skin corrosion/irritation: Category 2Serious eye damage/eye irritation: Category 2
Specific target organ toxicity - single exposure: Respiratory tract irritation Category 3(Note) GHS classification without description: Not applicable/Out of classification/Not
classifiable
Label elements

Signal word: Warning
HAZARD STATEMENT
Harmful if swallowed
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
PRECAUTIONARY STATEMENT
Prevention
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wash contaminated parts thoroughly after handling.
Wear protective gloves.
Wear eye protection/face protection.
Do not eat, drink or smoke when using this product.
Response
Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.

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3-Acrylamidophenyl boronic acid,JUNSEI CHEMICAL CO., LTD.,10111jis_J_E1-1,04/06/2015
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Rinse mouth.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Disposal
Dispose of contents/container in accordance with local/national regulation.

3. Composition/information on ingredients
Substance/Mixture:
Substance
Ingredient name:3-Acrylamidophenylboronic acidContent(%):97.0 <Chemical formula:C9H10BNO3
CAS No.:99349-68-5
MW:190.99

4. First-aid measures
Descriptions of first-aid measures
General measures
Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED
Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN（or hair）
Take off immediately all contaminated clothing. Rinse skin with water/shower.
Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.
IF IN EYES
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED
Rinse mouth.
Call a POISON CENTER or doctor/physician if you feel unwell.

5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media
In case of fire, use water mist, foam, dry powder, CO2.
Specific hazards arising from the substance or mixture
Containers may explode when heated.
Fire may produce irritating, corrosive and/or toxic gases.
Runoff from fire control or dilution water may cause pollution.
Advice for firefighters
Specific fire-fighting measures
Evacuate non-essential personnel to safe area.

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3-Acrylamidophenyl boronic acid,
JUNSEI CHEMICAL CO., LTD.,10111jis_J_E1-1,04/06/2015
Special protective equipment and precautions for fire-fighters
Wear fire/flame resistant/retardant clothing.
Wear cold insulating gloves/face shield/eye protection.
Firefighters should wear self-contained breathing apparatus with full face peace operated
positive pressure mode.

6. Accidental release measures
Personnel precautions, protective equipment and emergency procedures
Ventilate area after material pick up is complete.
Wear proper protective equipment.
Environmental precautions
Avoid release to the rivers, lakes, ocean, groundwater.
Methods and materials for containment and cleaning up
Sweep up, place in a bag and hold for waste disposal.
Preventive measures for secondary accident
Collect spillage.

7. Handling and storage
Precautions for safe handling
Preventive measures(Exposure Control for handling personnel)
Avoid breathing dust/fume/gas/mist/vapors/spray.
(Protective measures against fire & explosion)
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Exhaust/ventilator
Exhaust/ventilator should be available.
Safety treatments
Avoid contact with skin.
Avoid contact with eyes.
Avoid breathing dust, vapor, mist, or gas.
Safety Measures/Incompatibility
Use only outdoors or in a well-ventilated area.
Wear protective gloves, protective clothing or face protection.
Wear protective gloves.
Wear eye protection/face protection.
Use personal protective equipment as required.
When using do not eat, drink or smoke.
Conditions for safe storage, including any incompatibilities
Recommendation for storage
Store in a well-ventilated place. Keep container tightly closed.
Keep cool. Protect from sunlight.
Store locked up.

8. Exposure controls/personal protection
Exposure controls
Appropriate engineering controls
Do not use in areas without adequate ventilation.
Eye wash station should be available.
Washing facilities should be available.
Individual protection measures
Respiratory protection

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3-Acrylamidophenyl boronic acid,JUNSEI CHEMICAL CO., LTD.,10111jis_J_E1-1,04/06/2015
Wear positive pressure self-contained breathing apparatus (SCBA).
Hand protection
Wear protective gloves.
Eye protection
Wear eye/face protection.
Safety and Health measures
Wash … thoroughly after handling.
Do not eat, drink or smoke when using this product.
Take off contaminated clothing and wash it before reuse.

9. Physical and Chemical Properties
Information on basic physical and chemical properties
Physical properties
Appearance: Solid
Color: Off-whiteOdor data N.A.
pH data N.A.
Phase change temperature
Initial Boiling Point/Boiling point data N.A.
Melting point/Freezing point data N.A.
Decomposition temperature data N.A.
Flash point data N.A.
Auto-ignition temperature data N.A.
Explosive properties data N.A.
Vapor pressure data N.A.
Vapor density data N.A.
Specific gravity/Density data N.A.
Solubility
Solubility in water: Insoluble
n-Octanol /water partition coefficient data N.A.

10. Stability and Reactivity
Chemical stability
Stable under normal storage/handling conditions.
Conditions to avoidContact with incompatible materials.
Open flames. Heat.
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Carbon oxides, Nitrogen oxides, Boron oxides

11. Toxicological Information
Information on toxicological effects
No Acute toxicity data available
No Irritant properties data available
No Allergenic and sensitizing effects data available
No Mutagenic effects data available
No Teratogenic effects data available
No Carcinogenic effects data available
No reproductive toxicity data available

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3-Acrylamidophenyl boronic acid,JUNSEI CHEMICAL CO., LTD.,10111jis_J_E1-1,04/06/2015
No STOT-single/repeated exposure data available
No Aspiration hazard data available

12. Ecological Information
Toxicity
No Aquatic toxicity data available
No Persistence and degradability data available
No Bioaccumulative potential data available

13. Disposal considerations
Waste treatment methods
Dispose of contents/container in accordance with local/national regulation.

14. Transport Information
UN No, UN CLASS
Not applicable to UN NO.

15. Regulatory Information
Other regulatory information
We are not able to check up the regulatory information in regard to the substances in yourcountry or region, therefore, we request this matter would be filled by your responsibility.
Regulatory information with regard to this substance in your country or in your region
should be examined by your own responsibility.
Ensure this material in compliance with federal requirements and ensure conformity to local
regulations.

16. Other information
GHS classification and labelling
Acute Tox. 4: H302 Harmful if swallowed
Skin Irrit. 2: H315 Causes skin irritation
Eye Irrit. 2: H319 Causes serious eye irritation
STOT SE 3: H335 May cause respiratory irritation
Reference Book
Globally Harmonized System of classification and labelling of chemicals, (5th ed., 2013), UN
Recommendations on the TRANSPORT OF DANGEROUS GOODS 18th edit., 2013 UN
Classification, labelling and packaging of substances and mixtures (table3-1 ECNO6182012)2012 EMERGENCY RESPONSE GUIDEBOOK(US DOT)
2014 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php
Supplier's data/information
Chemical Risk Information Platform (CHRIP)(NITE) http://www.safe.nite.go.jp/japan/db.html
GHS Classification Guidance for Enterprises 2013 Revised Edition （August, 2013,METI)
Other information
This information contained in this data sheet represents the best information currently
available to us. However, no warranty is made with respect to its completeness and weassume no liability resulting from its use. It are advised to make their own tests todeterminate the safety and suitability of each such product or combination for their own
purposes.
The data given here is based on current knowledge and experience. The purpose of this

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3-Acrylamidophenyl boronic acid,
JUNSEI CHEMICAL CO., LTD.,10111jis_J_E1-1,04/06/2015
Safety Data Sheet is to describe the products in terms of their safety requirements. The
data does not signify any warranty with regard to the products' properties.
The GHS classification data given here is based on current Japan official data.