EN   EN 
 
 
 EUROPEAN  
COMMISSION   
Brussels, XXX   
[…](2023) XXX  draft  
ANNEX  
 
ANNEXES  
to the  
Commission Delegated Regulation  
amending Regulation (EC) No 1272/2008 as regards the harmonised classification and 
labelling of certain substances   
   
EN 1  EN ANNEX  
In Annex VI  , Table 3 of Part 3 is amended as follows:  
 
(1) the following entries are inserted  following the order of the index numbers corresponding to each entry : 
 
Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
‘015-204-00-5 benzyl(diethylamino)diphe
nylphosphonium 4 -
[1,1,1,3,3,3 -hexafluoro -2-
(4-hydroxyphenyl)propan -
2-yl]phenolate  479-100-5 577705 -90-9 Repr. 1B  H360F  GHS08  
Dgr H360F ’   
 
‘015-205-00-0 benzyltriphenylphosphoni
um, salt with 4,4' -[2,2,2 -
trifluoro -1-
(trifluoromethyl)ethyliden
e]bis[phenol] (1:1)  278-305-5 75768 -65-9 Repr. 1B  H360F  GHS08  
Dgr H360F ’    
‘015-206-00-6 reaction mass of 4,4'-
[2,2,2 -trifluoro -1-
(trifluoromethyl)ethyliden
e]diphenol and 
benzyl(diethylamino)diphe
nylphosphonium 4 -
[1,1,1,3,3,3 -hexafluoro -2-
(4-hydroxyphenyl)propan -
2-yl]phenolate (1:1)  - - Repr. 1B  H360F  GHS08  
Dgr H360F ’     
EN 2  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
‘015-207-00-1 reaction mass of 4,4'-
[2,2,2 -trifluoro -1-
(trifluoromethyl)ethyliden
e]diphenol and 
benzyltriphenylphosphoni
um, salt with 4,4' -[2,2,2 -
trifluoro -1-
(trifluoromethyl)ethyliden
e]bis[phenol] (1:1)  - - Repr. 1B  H360F  GHS08  
Dgr H360F ’    
‘015-208-00-7 dimethyl 
propylphosphonate  242-555-3 18755 -43-6 Muta. 1B  
Repr. 1B  H340  
H360Df  GHS08  
Dgr H340  
H360D f’    
‘050-034-00-5 dibutyltin maleate  201-077-5 78-04-6 Muta. 2  
Repr. 1B  
Acute Tox. 2  
Acute Tox. 4  
STOT RE 1  
Skin Corr. 1  
Eye Dam. 1  H341  
H360FD  
H330  
H302  
H372 
(immune 
system)  
H314  
H318  GHS08  
GHS06  
GHS05  
Dgr 
 H341  
H360FD  
H330  
H302  
H372 
(immune 
system)  
H314   inhalation:  
ATE = 0,317 
mg/L (dusts or 
mists)  
oral:  
ATE = 510 
mg/kg bw ’  
‘050-035-00-0 dibutyltin oxide  212-449-1 818-08-6 Muta. 2  
Repr. 1B  
Acute Tox. 3  
STOT RE 1  
Skin Irrit. 2  
Eye Dam. 1  H341  
H360FD  
H301  
H372 
(immune 
system)  
H315  GHS08  
GHS06  
GHS05  
Dgr H341  
H360FD  
H301  
H372 
(immune 
system)  
H315   oral:  
ATE = 170 
mg/kg bw    
EN 3  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
H318  H318 ‘ 
‘603-244-00-1 reaction mass of 1 -(2,3-
epoxypropoxy) -2,2-bis 
((2,3 -
epoxypropoxy)methyl) 
butane and 1 -(2,3-
epoxypropoxy) -2-((2,3 -
epoxypropoxy)methyl) -2-
hydroxymethyl butane  -   -  Muta. 2  
Repr. 1B  H341  
H360F  GHS08  
Dgr H341  
H360F ’    
‘603-245-00-7 2,2'-[[3-methyl -4-[(4-
nitrophenyl)azo]phenyl]im
ino]bisethanol  221-665-5 3179 -89-3 Skin Sens. 1  H317  GHS07  
Wng  H317 ’    
‘603-246-00-2 3,3,4,4,5,5,6,6,7,7,8,8,8 -
tridecafluorooctan -1-ol 211-477-1 647-42-7 STOT RE 2  
Aquatic Chronic 1  H373 
(teeth, 
bones)  
H410  GHS08  
GHS09  
Wng  H373 (teeth, 
bones)  
H410    
M = 1 ’  
‘604-099-00-7 4,4'-[2,2,2 -trifluoro -1-
(trifluoromethyl)ethyliden
e]diphenol; bisphenol AF  216-036-7 1478 -61-1 Repr. 1B  H360F  GHS08  
Dgr H360F ’    
‘604-100-00-0 nonylphenol, branched and 
linear, ethoxylated (with 
average molecular weight 
≤ 1540 g/mol) [includes 
ortho -, meta -, para - 500-315-8; 
500-024-6; 
500-045-0; 
500-209-1; 
248-762-5; 127087 -87-0; 
9016 -45-9; 
26027 -38-3; 
68412 -54-4; 
27986 -36-3; Aquatic Acute 1  
Aquatic Chronic 1  H400  
H410  GHS09  
Wng  H410   M = 1  
M = 10 ’   
EN 4  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
isomers or any 
combination thereof]  
 
 243-816-4; 
248-291-5; 
230-770-5; 
248-743-1; 
247-555-7; 
248-293-6  and 
others   20427 -84-3; 
27176-93-8; 
1119449 -38-5; 
7311 -27-5; 
27942 -27-4; 
26264 -02-8; 
27177 -05-5; 
14409 -72-4 
and others  
‘606-155-00-6 cinnamaldehyde; 3 -
phenylprop -2-enal;  
cinnamic aldehyde; 
cinnamal [1],  
(2E)-3-phenylprop -2-enal 
[2] 203-213-9 [1], 
604-377-8 [2]  104-55-2 [1], 
14371 -10-9 [2]  Skin Sens. 1A  H317  GHS07  
Wng  H317   Skin Sens. 1; 
H317: C ≥ 
0,01 % ’  
‘607-766-00-0 tetramethylene 
dimethacrylate  218-218-1 2082 -81-7 Skin Sens. 1B  H317  GHS07  
Wng  H317 ’    
‘607-767-00-6 7,7,9(or 7,9,9) -trimethyl -
4,13-dioxo -3,14-dioxa -
5,12-diazahexadecane -
1,16-diyl bismethacrylate  276-957-5 72869 -86-4 Skin Sens. 1B  H317  GHS07  
Wng  H317 ’    
‘607-768-00-1 2,2'-ethylenedioxydiethyl 
dimethacrylate  203-652-6  109-16-0  Skin Sens. 1B  H317  GHS07  
Wng  H317 ’    
‘607-769-00-7 bifenox (ISO); methyl 5 -
(2,4-dichlorophenoxy) -2-255-894-7 42576 -02-3 Acute Tox. 4  
Aquatic Acute 1  H302  
H400  GHS07  
GHS09  H302   oral:  
ATE = 1500   
EN 5  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
nitrobenzoate  Aquatic Chronic 1  H410  Wng  H410  mg/kg bw  
M = 1000  
M = 1000 ’ 
‘612-295-00-9 benfluralin (ISO); N-butyl -
N-ethyl -α,α,α -trifluoro -
2,6-dinitro -p-toluidine  217-465-2 1861 -40-1 Carc. 2  
Repr. 2  
Skin Irrit. 2  
Eye Irrit. 2 
Skin Sens. 1  
Aquatic Acute 1  
Aquatic Chronic 1  H351  
H361d  
H315  
H319  
H317  
H400  
H410  GHS08  
GHS07  
GHS09  
Wng  H351  
H361d  
H315  
H319  
H317  
H410   M = 10  
M = 10 ’  
‘612-296-00-4 N,N-dimethyl -p-toluidine  202-805-4 99-97-8 Carc. 1B  
Acute Tox. 4  
Acute Tox. 3  
STOT RE 2  
Aquatic Chronic 3  H350  
H332  
H301  
H373 
(blood 
system, 
respiratory 
tract)  
H412  GHS08  
GHS06  
Dgr H350  
H332  
H301  
H373 (blood 
system, 
respiratory 
tract)  
H412   inhalation:  
ATE = 1,4 
mg/L (mists)  
oral:  
ATE = 140 
mg/kg bw ’  
‘612-297-00-X 1-phenylethan -1-one (1 -
phenylethylidene)hydrazo
ne 211-979-0 729-43-1 Skin Sens. 1  H317  GHS07  
Wng  H317 ’    
‘612-298-00-5 1,4-Benzenediamine, N,N'-
mixed Ph and tolyl derivs.; 
Reaction mass of N-273-227-8 68953 -84-4 Repr. 1B  
Skin Sens. 1  H360FD  
H317  GHS08  
GHS07  
Dgr H360FD  
H317 ’     
EN 6  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
phenyl, N’-o-tolyl-
phenylene diamine, N,N’-
diphenyl -p-phenylene 
diamine and N,N’ -di-o-
tolyl-phenylene diamine  
‘613-346-00-8 4-nitrosomorpholine   -  59-89-2 Carc. 1B  
Muta. 2  
STOT RE 1  H350  
H341  
H372 
(liver)  GHS08  
Dgr H350  
H341  
H372 (liver)   Carc. 1B; 
H350: C ≥ 
0,001% ’  
‘613-347-00-3 difenoconazole (ISO); 1-
({2-[2-chloro -4-(4-
chlorophenoxy)phenyl] -4-
methyl -1,3-dioxolan -2-
yl}methyl) -1H-1,2,4 -
triazole; 3 -chloro -4-
[(2RS,4RS;2RS,4SR) -4-
methyl -2-(1H-1,2,4 -
triazol -1-ylmethyl) -1,3-
dioxolan -2-yl]phenyl 4 -
chlorophenyl ether   -  119446 -68-3 Carc. 2  
Acute Tox. 4  
Eye Irrit. 2  
Aquatic Acute 1  
Aquatic Chronic 1  H351  
H302  
H319  
H400  
H410  GHS08  
GHS07  
GHS09  
Wng  H351  
H302  
H319  
H410   oral:  
ATE = 1450 
mg/kg bw  
M = 10  
M = 10 ’  
‘613-348-00-9 9-[2-
(ethoxycarbonyl)phenyl] -
3,6-bis(ethylamino) -2,7-
dimethylxanthylium 
chloride; Basic  Red 1  213-584-9 989-38-8 Acute Tox. 3  
Eye Dam. 1  
Skin Sens. 1  
Aquatic Acute 1  
Aquatic Chronic 1  H301  
H318  
H317  
H400  
H410  GHS06  
GHS05  
GHS09  
Dgr H301  
H318  
H317  
H410   oral: 
ATE = 280 
mg/kg bw  
M = 10  
M = 1 ’   
EN 7  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M - 
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
‘613-349-00-4 4-methylimidazole  212-497-3 822-36-6 Carc. 1B  
Repr. 1B  H350  
H360Fd  GHS08  
Dgr H350  
H360Fd ’    
‘615-051-00-X 3,3'-dimethylbiphenyl -
4,4'-diyl diisocyanate  202-112-7 91-97-4 Carc. 2  
Resp. Sens. 1  
Skin Sens. 1A  H351  
H334  
H317  GHS08  
Dgr H351  
H334  
H317   Skin Sens. 1A; 
H317: C ≥ 
0,001 % ’  
‘616-241-00-5 foramsulfuron (ISO); 2 -
{[(4,6 -
dimethoxypyrimidin -2-
yl)carbamoyl]sulfamoyl} -
4-formamido -N,N-
dimethylbenzamide; 1 -
(4,6-dimethoxypyrimidin -
2-yl)-3-(2-
dimethylcarbamoyl -5-
formamidophenylsulfonyl)
urea - 173159 -57-4 Carc. 2  
Aquatic Acute 1  
Aquatic Chronic 1  H351  
H400  
H410  GHS08  
GHS09  
Wng  H351  
H410    
M = 1000  
M = 100 ’  
‘616-242-00-0 picolinafen (ISO); N-(4-
fluorophenyl) -6-[3-
(trifluoromethyl)phenoxy]
pyridine -2-carboxamide; 
4′-fluoro -6-[(α,α,α -
trifluoro -m-
tolyl)oxy]picolinanilide  none  137641 -05-5 STOT RE 2  
Aquatic Acute 1  
Aquatic Chronic 1  H373 
(blood 
system, 
thyroid)  
H400  
H410  GHS08  
GHS09  
Wng  H373 (blood 
system, 
thyroid)  
H410    
M = 1000  
M = 1000 ’;  
  
EN 8  EN (2) the entries corresponding to index numbers  006-015-00-9; 015-203-00-X; 016 -001-00-4; 016-011-00-9; 017 -004-00-3; 017 -005-00-9; 
082-013-00-1; 082 -014-00-7; 603 -057-00-5; 604 -010-00-1; 604 -074-00-0; 606 -034-00-8; 607-032-00-X; 607 -034-00-0; 607 -223-00-8; 
607-246-00-3; 612-004-00-5; 612-049-00-0; 613 -088-00-6; 613 -127-00-7; 613-307-00-5; 616-035-00-5; 616 -104-00-X are replaced by 
the following entries respectively:   
 
Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
‘006-015-00-9 diuron (ISO); 3 -(3,4-
dichlorophenyl) -1,1-
dimethylurea  206-354-4  330-54-1  Carc. 1B  
STOT RE 2  
Aquatic Acute 1  
Aquatic Chronic 1  H350  
H373 (blood 
system)  
H400  
H410  GHS08  
GHS09  
Dgr H350  
H373 (blood 
system)  
H410   M = 100  
M = 100 ’  
‘015-203-00-X diphenyl(2,4,6 -
trimethylbenzoyl)ph
osphine oxide  278-355-8 75980 -60-8 Repr. 1B  
Skin Sens. 1B  H360Fd  
H317  GHS08  
GHS07  
Dgr H360Fd  
H317 ’    
‘016-001-00-4 hydrogen sulphide, 
hydrogen sulfide  231-977-3 7783 -06-4 Flam. Gas 1A  
Press. Gas  
Acute Tox. 2  
Aquatic Acute 1  H220  
H330  
H400  GHS02  
GHS06  
GHS09  
Dgr H220  
H330  
H400   inhalation:  
ATE = 440 
ppmV (gases)  U’ 
‘016-011-00-9 sulfur dioxide  231-195-2  7446 -09-5 Press. Gas  
Acute Tox. 3  
STOT SE 1  
Skin. Corr. 1B  H331  
H370 
(respiratory 
system) 
(inhalation)  
H314  GHS04  
GHS06  
GHS08  
GHS05  
Dgr H331  
H370 
(respiratory 
system) 
(inhalation)  
H314   inhalation:  
ATE = 1000 
ppmV (gases)  U, 5’  
EN 9  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
‘017-004-00-3 potassium chlorate  223-289-7 3811 -04-9 Ox. Sol. 1  
Acute Tox. 3  H271  
H301  GHS03  
GHS06  
Dgr H271  
H301 ’    
‘017-005-00-9 sodium chlorate  231-887-4 7775 -09-9 Ox. Sol. 1  
Acute Tox. 3  H271  
H301  GHS03  
GHS06  
Dgr H271  
H301 ’    
‘082-013-00-1 lead powder;  
[particle diameter < 1  
mm]  231-10 
0-4 7439 -92- 
1 Repr. 1A  
Lact.  
Aquatic Acute 1  
Aquatic Chronic 1  H360FD  
H362  
H400  
H410  GHS08  
GHS09  
Dgr H360FD  
H362  
H410   Repr. 1A;  
H360D: C ≥ 
0,03 %  
M = 10  
M = 100 ’  
‘082-014-00-7 lead massive:  
[particle diameter ≥ 1  
mm]  231-10 
0-4 7439 -92- 
1 Repr. 1A  
Lact.  
 
Aquatic Chronic 1  H360FD  
H362  
 
H410  GHS08  
GHS09  
Dgr H360FD  
H362  
H410   M = 10 ’ 
  
‘603-057-00-5 benzyl alcohol  202-859-9 100-51-6 Acute Tox. 4  
Eye Irrit. 2  
Skin Sens. 1B  H302  
H319  
H317  GHS07  
Wng  H302  
H319  
H317   oral:  
ATE = 1200 
mg/kg bw ’  
‘604-010-00-1 resorcinol; 1,3 -
benzenediol  203-585-2 108-46-3 Acute Tox. 4  
STOT SE 1  
Skin Irrit. 2  
Eye Irrit. 2  
Skin Sens. 1B  
Aquatic Acute 1  H302  
H370 (nervous 
system)  
H315  
H319  
H317  GHS07  
GHS08  
GHS09  
Dgr H302  
H370 (nervous 
system)  
H315  
H319  
H317   oral:  
ATE  = 500 
mg/kg bw  
 
   
EN 10  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
H400  H400  M = 1 ’ 
‘604-074-00-0 2,2',6,6' -tetrabromo -
4,4'-
isopropylidenediphe
nol; 
tetrabromobisphenol -
A 201-236-9 79-94-7 Carc. 1B  
Aquatic Acute 1  
Aquatic Chronic 1  H350  
H400  
H410  GHS08  
GHS09  
Dgr H350  
H410 ’    
‘606-034-00-8 metribuzin (ISO); 4-
amino -6-tert-butyl -3-
methylthio -1,2,4 -
triazin -5(4H)-one; 4 -
amino -4,5-dihydro -
6-(1,1-
dimethylethyl) -3-
methylthio -1,2,4 -
triazin -5-one 244-209-7 21087 -64-9 Acute Tox. 4  
STOT RE 2  
Aquatic Acute 1  
Aquatic Chronic 1  H302  
H373 (blood 
system)  
H400  
H410  GHS07  
GHS08  
GHS09  
Wng  H302  
H373 (blood 
system)  
H410 ’    
‘607-032-00-X ethyl acrylate  205-438-8 140-88-5 Flam. Liq. 2  
Acute Tox. 3  
Acute Tox. 4  
Acute Tox. 4  
STOT SE 3  
Skin Irrit. 2 
Eye Irrit. 2  
Skin Sens. 1  H225  
H331  
H312  
H302  
H335  
H315  
H319  
H317  GHS02  
GHS06  
Dgr H225  
H331  
H312  
H302  
H335  
H315  
H319  
H317   inhalation:  
ATE = 9 
mg/L 
(vapours)  
dermal:  
ATE = 1800 
mg/kg bw  
oral:  
ATE = 1120 
mg/kg bw  D'  
EN 11  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
STOT SE 3; 
H335: C ≥ 5 
% 
Skin Irrit. 2; 
H315: C ≥ 5 
% 
Eye Irrit. 2; 
H319: C ≥ 5 
% 
‘607-034-00-0 methyl acrylate;  
methyl  propenoate  202-500-6 96-33-3 Flam. Liq. 2  
Acute Tox. 3  
Acute Tox. 4  
Acute Tox. 4  
STOT SE 3  
Skin Irrit. 2  
Eye Irrit. 2  
Skin Sens. 1  H225  
H331  
H312  
H302  
H335  
H315  
H319  
H317  GHS02  
GHS06  
Dgr H225  
H331  
H312  
H302  
H335  
H315  
H319  
H317   inhalation:  
ATE = 3 
mg/L 
(vapours)  
dermal:  
ATE = 1100 
mg/kg bw  
oral:  
ATE = 500 
mg/kg bw  D’ 
‘607-223-00-8 transfluthrin (ISO); 
2,3,5,6 -
tetrafluorobenzyl 
(1R,3S) -3-(2,2-
dichlorovinyl) -2,2-
dimethylcyclopropan
ecarboxylate  405-060-5 118712 -89-3 Carc. 2  
Acute Tox. 4  
STOT SE 1  
Aquatic Acute 1  
Aquatic Chronic 1  H351  
H302  
H370 (nervous 
system)  
H400  
H410  GHS08  
GHS07  
GHS09  
Wng  H351  
H302  
H370 (nervous 
system)  
H410  EUH066  oral:  
ATE = 580 
mg/kg bw  
 
M = 1000  
M = 1000 ’   
EN 12  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
‘607-246-00-3 allyl methacrylate;  
2-methyl -2-
propenoic  acid 2 -
propenyl ester  202-473-0 96-05-9 Flam. Liq. 3  
Acute Tox. 2  
Acute Tox. 3  
Acute Tox. 4  
Aquatic Acute 1  H226  
H330  
H311  
H302  
H400  GHS02  
GHS06  
GHS09  
Dgr H226  
H330  
H311  
H302  
H400   inhalation:  
ATE = 1,5 
mg/L 
(vapours)  
dermal:  
ATE = 300 
mg/kg bw  
oral:  
ATE = 400 
mg/kg bw ’  
‘612-004-00-5 triethylamine  204-469-4 121-44-8 Flam. Liq. 2  
Acute Tox. 3  
Acute Tox. 3  
Acute Tox. 3  
Skin Corr. 1A  
Eye Dam. 1  H225  
H331  
H311  
H301  
H314  
H318  GHS02  
GHS06  
GHS05  
Dgr H225  
H331  
H311  
H301  
H314 ’    
‘612-049-00-0 di-n-butylamine  203-921-8 111-92-2 Flam. Liq. 3  
Acute Tox. 2  
Acute Tox. 3  
Acute Tox. 3  
Skin Corr. 1B  
Eye Dam. 1  H226  
H330  
H311  
H301  
H314  
H318  GHS02  
GHS06  
GHS05  
Dgr H226  
H330  
H311  
H301  
H314 ’    
‘613-088-00-6 1,2-benzisothiazol -
3(2H) -one; 1,2-
benzisothiazolin -3-220-120-9 2634 -33-5 Acute Tox. 2  
Acute Tox. 4  
Skin Irrit. 2 H330  
H302  
H315  GHS06  
GHS05  
GHS09  H330  
H302  
H315   oral:  
ATE = 450 
mg/kg  bw   
EN 13  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
one Eye Dam. 1  
Skin Sens. 1A  
Aquatic Acute 1  
Aquatic Chronic 1  H318  
H317  
H400  
H410  Dgr H318  
H317  
H410  inhalation:  
ATE = 0,21 
mg/L (dusts or 
mists)  
Skin Sens. 
1A; H317: C 
≥ 0,036 %  
M = 1  
M = 1 ’ 
‘613-127-00-7 mepiquat chloride 
(ISO); 1,1 -
dimethylpiperidiniu
m chloride  246-147-6 24307 -26-4 Acute Tox. 4  
Acute Tox. 3  
Aquatic Chronic 3  H332  
H301  
H412  GHS06  
Dgr H332  
H301  
H412   inhalation:  
ATE = 2,8 
mg/L (dusts or 
mists)  
oral:  
ATE = 270 
mg/kg bw ’  
‘613-307-00-5 clothianidin (ISO); 
(E)-1-(2-chloro -1,3-
thiazol -5-ylmethyl) -
3-methyl -2-
nitroguanidine  433-460-1 210880 -92-5 Repr. 2  
Acute Tox. 4  
STOT SE 1  
Aquatic Acute 1  
Aquatic Chronic 1  H361f  
H302  
H370 (nervous 
system)  
H400  
H410  GHS08  
GHS07  
GHS09  
Dgr H361f  
H302  
H370 (nervous 
system)  
H410   oral:  
ATE = 390 
mg/kg bw  
M = 10  
M = 100 ’  
‘616-035-00-5 cymoxanil (ISO); 2 -
cyano -N-
[(ethylamino)carbon
yl]-2-261-043-0; 
[1] 57966 -95-7; 
[1] 
  
166900 -80-Repr. 2  
Acute Tox. 4  
STOT RE 2  
Skin Sens. 1  H361fd  
H302  
H373 (blood 
system, GHS08  
GHS07  
GHS09  H361fd  
H302  
H373 (blood 
system, thymus,  oral:  
ATE = 360 
mg/kg bw  
   
EN 14  EN Index No  Chemical Name  EC No  CAS No  Classification  Labelling  Specific 
Conc. 
Limits, M-
factors and 
ATE  Notes  
Hazard Class 
and Category 
Code(s)  Hazard 
statement 
Code(s)  Pictogram, 
Signal 
Word 
Code(s)  Hazard 
statement 
Code(s)  Suppl. 
Hazard 
statement 
Code(s)  
(methoxyimino)aceta
mide; [1]  
  
(2E)-2-cyano -N-
[(ethylamino)carbon
yl]-2-
(methoxyimino)aceta
mide; [2]  7; [2]  Aquatic Acute 1  
Aquatic Chronic 1  thymus, eyes)  
H317  
H400  
H410  Wng  eyes)  
H317  
H410  M = 1  
M = 1 ’ 
‘616-104-00-X benalaxyl (ISO); 
methyl N-(2,6-
dimethylphenyl) -N-
(phenylacetyl) -DL-
alaninate  275-728-7 71626 -11-4 Acute Tox. 4  
Aquatic Acute 1  
Aquatic Chronic 1  H302  
H400  
H410  GHS07  
GHS09  
Wng  H302  
H410   oral:  
ATE = 1000 
mg/kg bw  
M = 1  
M = 1 ’