Laser induced breakdown spectroscopy library for the
Martian environment

A. Cousin, O. Forni, S. Maurice, O. Gasnault, C. Fabre, V. Sautter, R.C.

Wiens, Johan Mazoyer

► To cite this version:

A. Cousin, O. Forni, S. Maurice, O. Gasnault, C. Fabre, et al. Laser induced breakdown spectroscopy library for the Martian environment. Spectrochimica Acta Part B: Atomic Spectroscopy, 2011, 66 (11-12), pp.805-814. 10.1016/j.sab.2011.10.004. hal-04973810

HAL Id: hal-04973810

https://hal.science/hal-04973810v1

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Distributed under a Creative Commons Attribution 4.0 International License
Laser Induced Breakdown Spectroscopy (LIBS)
Library for the Martian Environment

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¹,²A. Cousin, ¹,²O. Forni, ¹,²S. Maurice, ¹,²O. Gasnault, ³C. Fabre, ⁴V. Sautter, ⁵R.C. Wiens, ¹,²J. Mazoyer

¹Université de Toulouse; UPS (Université Paul Sabatier)-OMP (Observatoire Midi Pyrénées); IRAP (Institut de Recherche en Astrophysique et Planétologie), Toulouse, France

²CNRS (Centre National de la Recherche Scientifique); IRAP, 9 Av. colonel Roche, BP 44346, F-31028 Toulouse cedex 4, France (a.cousin@cesr.fr; o.forni@cesr.fr; s.maurice@cesr.fr; o.gasnault@cesr.fr)

³G2R (Nancy Université, France ; Cecile.Fabre@g2r.uhp-nancy.fr)

⁴MNHN (Paris, France ; vsautter@mnhn.fr)

⁵Los Alamos National Laboratory (Los Alamos, NM, USA ; rwiens@lanl.gov)

Corresponding author: Agnes Cousin, agnes.cousin@cesr.fr, IRAP 9 avenue du Colonel Roche BP 44346, 31028 Toulouse cedex 4, FRANCE. Telephone: 0561556644
18 Abstract

19 The NASA Mars Science Laboratory (MSL) rover will carry the first LIBS experiment (ChemCam) in space. We have developed a laboratory model which mimics ChemCam's main characteristics. We used a set of target samples relevant to Mars geochemistry, and we recorded individual spectra. We propose a data reduction scheme for LIBS data incorporating de-noising, continuum removal, and peak fitting. Known effects of the Martian atmosphere are confirmed with our experiment: better signal-to-noise ratio (SNR) on Mars compared to Earth, narrower peak width, and essentially no self-absorption. The wavelength shift of emission lines from air to Mars pressure is discussed. The NIST vacuum database is used for wavelength calibration and to identify the elemental lines. Our Martian database contains 1336 lines for 32 elements: H, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl, K, Ar, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Rb, Sr, Cs, Ba, and Pb. It is a subset of the NIST database to be used for Martian geochemistry. Finally, synthetic spectra can be built from the Martian database. Correlation calculations help to distinguish between elements in case of uncertainty. This work is used to create tools and support data for the interpretation of ChemCam results.

33 Keywords: ChemCam, LIBS, Mars, Emission Lines, Spectroscopy.

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## 1. Introduction

37 ChemCam is the first Laser Induced Breakdown Spectroscopy (LIBS) instrument for

38 planetary exploration. It will fly on NASA's Mars Science Laboratory (MSL) rover named

39 *Curiosity*, with launch in late 2011 and arrival on Mars in August, 2012. The primary science

40 goal of ChemCam is to investigate the diversity of Martian geochemistry [1]. It will analyze

41 soil and rock elemental composition at stand-off distances from 1 to 7 m. In the LIBS method,

42 a high power pulsed laser is focused onto a target, resulting in the creation of a plasma from

43 ablated material. Electronically excited atoms and ions in the plasma decay to lower energy

44 states, emitting photons at wavelengths that are specific to the elements present in the target.

45 Light is then collected and analysed by means of spectrometers.

46 LIBS is the topic of different studies in plasma physics, particularly investigating various

47 parameters influencing the emission [2-6] for a variety of applications: industry, environment,

48 art, and for our concern, space exploration [7-11]. In parallel with the development of the

49 ChemCam instrument, studies have been performed to set requirements for instrument-critical

50 parameters [1,12], to assess its capability to detect specific elements [13-15], and to

51 implement multivariate methods for rock classification and quantification methods [16-19].

52 Emission line identification is of fundamental importance to LIBS data processing. The

54 purpose of this paper is to identify the elements and energy levels responsible for each peak in

55 a given spectrum. The National Institute of Standards and Technology (NIST) maintains an

56 Atomic Line Database [20], which serves that purpose: in emission spectroscopy, each peak

57 should correspond to an entry in the NIST database. Since the NIST database relies on a large

58 number of laboratory measurements and theoretical calculations, it is very extensive, and so it
59 is extremely rare – often questionable – to identify a LIBS line which is not part of the NIST database. As a result, we generally consider NIST database as error-free with regards to peak identification, position, and ionization level unless shown otherwise.

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62 The NIST database also provides a relative intensity index for most peaks, with a warning: "... relative intensities are source dependent and typically are useful only as guidelines for low density sources. These are values that are intended to represent the strengths of the lines of a spectrum as they would appear in emission. The values in the Database are taken from the cited publications (...) The relative intensities should be considered as qualitative values..." This is also clear considering the physics of the emission lines, where the probability of any given electronic transition is strongly dependent on the plasma temperature, which varies significantly between different experimental conditions. The conclusion is that the NIST relative intensity index should not be trusted to identify the brightest peaks, as will be demonstrated later. The only way to reproduce lines of interest in representative proportions to those seen on Mars is to generate spectra with apparatus and environmental conditions as close as possible to the expected ones.

74 There are several reports in the literature on subsets of the NIST database for the specific use of the LIBS technique [21], each with some explicit instrument parameters or environmental conditions which influence plasma generation and expansion. This work aims at extracting from the NIST database a subset of LIBS emission lines appropriate for the Martian atmospheric environment and ChemCam irradiance levels. It is an essential work for processing the ChemCam data. The objective of this manuscript is to create a library of emission lines for major, minor, and trace elements which are relevant to soil and rock chemistry on Mars. The scope is not to cover the whole Mendeleev table but rather to adequately study elements which are most significant to Martian geochemistry [22-24] and known to be detectable with the LIBS technique [25].
84 The experimental setup is described in Section 2, together with the targets which have been used. In the course of establishing the LIBS Martian database, we found it critical to revisit the major atmospheric parameters which cause specificity in the database: absolute pressure and gas composition (Section 3). Key data processing steps are described Section 4. They lead to the characterization of LIBS peaks and their elemental identification, from which the Martian database can be created. A synthetic spectrum serves as a test for peak identification and comparison with results from NIST. Finally the Martian database is applied to the identification of minerals and complex targets (Section 5).

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## 2. Experimental Setup and Samples

93 The ChemCam team has recently built LIBS instruments similar to ChemCam in France and in the United States to create spectral databases under hardware and environmental conditions similar to those on MSL. The setup at the Institut de Recherche en Astrophysique et Planétologie, Toulouse, France is used for this study (Figure 1a). ChemCam consists of two major sections: A Mast Unit (MU) on the mast of the rover which includes the laser and a 110 mm diameter Schmidt-Cassegrain telescope. The telescope focuses the laser beam on the target and collects the returning plasma light and launches it into an optical fiber extending into the rover body. The Body Unit (BU) receives the plasma light via the fiber and records the spectrum using an optical demultiplexer and three spectrometers [1].

102 The laboratory model, as used for the data described in this paper, consists of the Engineering and Qualification Model for the MU and commercial spectrometers for the BU. The two sections are connected to each other via a 6 m long flight-like optical fiber. The MU is an exact copy of the Flight Model. It uses a pulsed Nd:KGW laser at 1067 nm, operating at 10 Hz. The pulse duration is 5 nsec, with energies, measured at the laser, ranging from 15 to 30 mJ depending on the diode stack temperature. The Gaussian quality ($M_2$) of the beam at the
108 laser output is less than 2 [26]. The laser beam is first expanded by a Galilean telescope, and
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2 then focused on the target with the telescope. Only half of the laser energy is deposited onto
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4 the target due to losses in the telescope. A focus mechanism is used to optimize the
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6 laser/matter interaction [27]. The mean spot size is ~300 µm at 3m, providing irradiances
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8 greater than 2 GW/cm² [26]. The same telescope collects the LIBS plasma light. The
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10 incoming optical path is diverted from the outgoing beam by a custom dichroic mirror, and
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12 finally the light is launched into a 300 µm core fiber..

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18 Whereas on Mars the three BU spectrometers are operated simultaneously [28], for the
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20 current setup the spectrometers are used without the demultiplexer and are thus operated
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22 sequentially, requiring the operator to reconnect the fiber to each spectrometer. As a
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24 consequence, three separate laser bursts are required to record data over the entire wavelength
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26 range. The BU spectrometers in this setup consist of three commercial spectrometers from
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28 Ocean Optics. A gap in the spectral range in the near UV is imposed by λ/3 harmonic of the
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30 dichroic which reflects the laser beam and transmits the LIBS plasma light. As a result, the
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32 wavelength ranges are 240 – 340 nm (hereafter named UV range), 380 – 470 nm (VIS range),
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34 and 480 – 950 nm (VNIR range). The pixel resolutions are 0.049 nm for the UV, 0.043 nm for
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36 the VIS, and ranging from 0.19 nm at one end of the VNIR to 0.23 nm at the long wavelength
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38 extremity. The spectrometers resolve peaks at roughly 3.5 pixels full width half maximum
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40 (FWHM). The commercial spectrometers use a single row of 2048 pixels each, while the
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42 flight unit collapses 2D images into spectra.
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51 The operating software is identical to the flight instrument for the MU. The spectrometer
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53 throughput is ultimately poorer than on ChemCam, because the alignment is better and the
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55 optical elements and electronic components are higher quality on the flight unit. For this
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58 study, the configuration was run at room temperature, which results in lower laser energy, as
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the crystals were optimized near 0 deg C for the Mars environment. However, at the target distance (3 m) the irradiance threshold of 1 GW/cm² [29] is still obtained.

To reproduce the Martian environment, a dedicated chamber was developed (figure 1b) and placed on 10 m long tracks to account for the remote sensing aspect of the ChemCam experiment. For this work the distance was fixed at 3 m. The chamber volume is 70 l. The 200 mm diameter window is stood off 1 m from the samples to avoid focusing the laser beam on it. The chamber is regularly pumped at 10⁻³ mbar and then filled with 95.7% CO₂, 1.6% Ar, 2.7% N₂ to reproduce the Martian atmosphere. The initial pump-down to near-vacuum purges the chamber of Earth atmosphere, and also degasses the targets. A continuous flow of gas is regulated to maintain a pressure of 7 mbar. Up to five targets are placed in the chamber at a time and a carousel allows the operator to successively expose each target to the laser beam. The chamber is kept at room temperature, which is a difference from flight-like conditions, but it should be generally of no importance because of the high temperature of the plasma [~8000°K, [30]] with respect to ambient temperature. The only difference could be for the preservation of water or other volatiles in special targets, such as phyllosilicates.

A major difference between the lab setup and ChemCam on Mars is the end-to-end transmission and efficiency budget. The Martian chamber is closed by a thick fused silica window, which attenuates the signal and modifies the spectral response function. Conversely, on MSL, ChemCam is located in the rover remote-warm-electronic-box, which is itself closed by a glass window not reproduced on the ground. Finally, the commercial spectrometers are not optimized as precisely as the flight units. As a result the collection efficiency is lower for the lab unit than for ChemCam. Since we are interested here in the LIBS line locations and not by the radiometric intensity of such lines, this discrepancy is not significant. To account for the spectral transmission, the lab setup has been radiometrically calibrated using a broad spectrum halogen lamp.
157 The Ocean Optics spectrometers are calibrated accurately for wavelength for this study.
1 158 Under Martian conditions, a spectrum is generated using a well-known basalt target for which
2 159 a large number of emission lines are observed and identified. Using the NIST database for the
3 160 wavelengths lines under vacuum as a reference, a channel-to-wavelength correlation is
4 161 determined for each spectrometer. At least 7 to 10 lines are used per spectrometer. A
5 162 quadratic relation is used for the correlation. Analyses of many emission lines shows that the
6 163 final accuracy is ±0.04 nm for the UV, ±0.04 nm for the VIS, and near ±0.2 nm for the VNIR,
7 164 values below the intrinsic FWHM resolutions of the spectrometers and reaches the pixel
8 165 resolution.
9 166 To ease unambiguous line identification during data processing, whenever it was possible, we
10 166 used pure targets with only one or two elements (purity > 99.98 %), such as sheets or coupons
11 167 of Titanium, Aluminium (88%) – Silicon (12%), Iron, Sulphur, Manganese, Copper, Carbon,
12 168 Nickel, Lead, Fluorite (CaF₂), Magnesium, Salt (NaCl), Zinc, and Pyrite (FeS₂). Other more
13 169 complex targets were also used: potassium nitrate (KNO₃) to focus on K, celestite (SrSO₄) for
14 170 Sr, lepidolite ((KLi₂Al(Al,Si)₃O₁₀(F,OH)₂) and spodumene ((Li,Al)Si₂O₆) for Li, vanadinite
15 171 (Pb₅(VO₄)3Cl) for V and Cl, Melanterite (MHC2319) doped with Arsenic for As, and
16 172 sphalerite (ZnS) for Zn. We also used well-characterized calibration targets on MSL [15] for
17 173 the special cases of Be, B, P, Cr, Cs, and Ba. H and Rb were found in numerous targets. Thus
18 174 LIBS lines that could be detected represented 31 elements: H, Li, Be, B, C, N, O, F, Na, Mg,
19 175 Al, Si, P, S, Cl, K, Ar, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Rb, Sr, Cs, Ba, and Pb. On a few
20 176 occasions, we used data from the flight model, taken at Los Alamos, together with data from
21 177 the setup in Toulouse.
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23 179 To build the database, samples were placed in the Martian chamber, their main surface being
24 179 perpendicular to the incident laser beam. For each spectrum, five bursts of 10 laser shots were
25 180 fired at 10 Hz. The CCD integration time was 1 sec, collecting 10 shots in each exposure. On
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27 2015
homogenous targets (the series of high purity samples) bursts were aimed at the same spot.

For other samples, the targets were moved to acquire a new analysis location after each burst.

A dark spectrum, e.g., without the laser, was taken to account for the ambient illumination.

The camera automatically removed the electronic bias.

## 3. Atmosphere Pressure and Composition

The rationale behind a Martian database, beyond the reference to specific ChemCam parameters, is the influence of the Martian atmosphere on LIBS line emissions. As it is well known, the pressure on Mars is typically 6 mbar, and the atmosphere is nearly all (~96%) CO₂. Under this environment, the physical properties of the plasma are different compared to Earth. Studies [7,29,31,35-37] have been performed to understand the effect of the pressure on the LIBS spectra. These showed that under Martian conditions the plasma is much brighter, with more intense lines, and therefore the signal acquired is higher under this environment than under ambient or vacuum conditions. Moreover, the line widths and the self absorption effects are also dependent on the gas pressure [7,8,29,32]. To characterize these effects with ChemCam, several analyses were performed with different gas compositions (including nitrogen) at different pressures, from near-vacuum to one atmosphere.

### 3.1 Line Positions

The refractive index depends on the wavelength and on the medium. Consequently, the wave velocity, $c$, and the wavelength, $\lambda$, depend also on the medium ($\lambda=c/v$, where $v$ is the frequency). Therefore, emission line positions are slightly different in vacuum compared to ambient pressure. The maximum wave velocity is found under vacuum, and hence the line positions in vacuum are at longer wavelengths than under ambient (the mean shift is 0.076 nm in UV, 0.120 nm in VIS, and 0.191 nm in VNIR). The position of the lines under Martian conditions will be shifted relative to terrestrial pressure but not quite as far as vacuum, given
the Martian pressure of ~1% of terrestrial sea level. Here, we adopt the following convention: all wavelengths are reported as they would be observed in vacuum, independently of the actual environment, such that spectra acquired in the Martian environment show lines at the same positions than those acquired in vacuum. For example, the Al line at 396.26 nm (from NIST under vacuum) is observed under vacuum conditions with our experimental setup at 396.28 nm (the 0.02 nm difference due to slight inaccuracy of calibration), and under Martian conditions after calibration using vacuum wavelengths it is forced to be at the same position.

## 3.2 Broadening effect

The main line-broadening mechanisms are the Doppler and collision effects. Higher power lasers induce more broadening [33]. The Doppler broadening is related to the plasma temperature, while the collision broadening (or pressure broadening) is related to the electronic density [8, 29]. These broadening effects are variable during the lifetime of the plasma, as well as spatially within the plasma, and affect plasma lines differently depending on the abundance of the studied component and the transition considered [29, 34]. Generally, when the elemental abundance is more than a few percent, the lines having their lower level of transition close to the ground state are broader at higher pressure, in contrast to those ending at higher energy levels; their FWHM can be estimated with fitting routines, assuming the instrument resolution is sufficient.

Experiments were performed in order to evaluate these broadening effects with ChemCam using the aluminium and silicon target, fluorite target, as well as the iron target, placed at 3 m from the instrument. Two gas compositions and pressures were tested: Earth-like (ambient gas at 1 bar), and Mars-like (Martian composition at 6 mbar). Table 1 shows the FWHM of these lines (calculated using a Lorenzian fit) for each pressure, with the error returned by the fit. The Al and Ca lines, which have low energy final levels (transitions from < 3.15 eV to 0.0
eV), are clearly broader at ambient than under Martian pressure, whereas the FWHM of the Fe line is nearly constant. The Fe line has a higher energy final level (transition to 1.48 eV) and does not present significant broadening behaviour.

The broadening effect was also studied using a basalt spectrum acquired under 6 mbar and ambient pressure. In the 390-405 nm range, the four lines of Al and Ca all show broadening at higher pressure, contrary to the Fe line (Table 1). The basalt data seem consistent with the results obtained with pure targets, suggesting that the pressure effects on the line widths are more important than the effects from the matrix components, at least over such large differences in pressure.

## 3.3 Line intensities and self absorption effects

As the surrounding pressure increases, the electron density, the conductivity and also the plasma shielding increase. The increase in electron density, also responsible for the collision broadening (see 4.2), implies a signal increase due to a higher number of emitting atoms. Instead, the increase in conductivity and plasma shielding results in a decrease in signal. Indeed, when the pressure increases, the plasma cools faster because of higher conductivity. Moreover, with increasing plasma shielding, part of the laser energy is absorbed by the plasma, and therefore the signal decreases. The plasma shielding is also responsible for the self-absorption effect.

The fact that the plasma under Martian pressure is brighter than at higher or lower pressures is explained as the result of a reduced cooling rate compared to the ambient environment [7,29,31,35-37]. Moreover, the CO₂ which comprises 96 % of the Mars atmosphere has a lower conductivity than air, which also lowers the cooling rate, such that the plasma lifetime is extended. Therefore, the Martian conditions are optimal for ablation and ionization. As ChemCam by default uses long exposure times of several ms due to the fact
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that its CCDs are not gated, it takes full advantage of the extended lifetimes of plasmas under

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Mars conditions.

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Table 2 shows the intensities of the Al and Ca lines from the basalt, under ambient and

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Martian conditions. Intensities at ambient conditions are lower than at Martian pressure, with

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a loss of 25 % to 70 % of the signal. These results are consistent with the literature cited

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above. Figure 2 shows that the best signal-to-noise ratio (SNR) is obtained under Martian

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conditions, as presented in [29] and consistent with results given in [38]. The data in Fig. 2

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were taken on pure targets. For each spectrum, the noise was estimated by computing the

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standard deviation of that spectrum for a range of wavelengths without any detectable line

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(these regions were: 420-425 nm for the Al lines; 410-420 nm for the Ca line; 460-470 nm for

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the Fe line; 384-388 nm for the Ti line; and 320-330 nm for Si the line).

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When increasing the pressure up to 1 bar, the self absorption effect was not observed, due in

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part to the relatively low laser intensity.

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Figure 3 reveals the combined effects of the surrounding gas composition and pressure on the

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Mg line at 518.5 nm. Note that this line has quite a high final energy level (transition from 5.1

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to 2.7 eV). Experiments were done using a picrite target, which is a homogeneous synthetic

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basalt glass calibration target [15]. Several gases were tested: Earth-like atmosphere, nitrogen

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and Mars-like atmosphere, with pressures ranging from 5 x 10⁻³ mbar to 1 bar. The intensity

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of the magnesium line increases with pressure until about 50 mbar, and then the intensity

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decreases at higher pressure. This trend is observed independently of the gas composition.

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The behaviour displayed with this Mg line is typical of emission lines having the same range

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of energy over this pressure range.

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These intensity variations as a function of pressure confirm the fact that the Martian

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conditions are optimal with effectively greater line intensities than under vacuum or ambient
278 conditions. These observations reveal the combined effects of various parameters (plasma shielding, conductivity, and density) which occur in the plasma when increasing the pressure.
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286 Figure 3 also reveals the importance of the surrounding gas composition on the intensity of the lines. Up to few mbar, the Mg line intensity is always higher in the Martian composition 287 atmosphere. Indeed, the plasma life must be longer under Martian conditions, because the 288 lower conductivity of CO2, compared to N2 and air, implies a longer time to cool the plasma. 289 Around 7 mbar, i.e. at typical Martian pressures, other mechanisms seem to become 300 dominant. At higher pressures, the Mg line is more intense when the target is in a nitrogen 301 32 atmosphere. This may be explained by reduced shielding effects. In fact, nitrogen has the 33 35 highest energy of ionisation [20] and therefore it is more difficult to ionize this gas. A similar 36 38 behaviour has been observed with the calcium line at 616 nm (which has nearly the same 40 41 energy levels). 295

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Our experiments used 6 mbar as the Martian pressure. If we consider the pressure variations during one year at the Martian surface, for example at Gale crater, which is chosen as the MSL landing site, the pressure can vary from 5.3 mbar to 6.3 mbar. Looking at Figure 3, only one mbar in pressure variation should have no effect on the signal acquired, which is also supported by [36] and [7].

4. Martian Database
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The purpose of this section is to describe the different steps and hypotheses that lead to the

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Martian LIBS line database.

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## 4.1 Data Processing

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For each target there are five 2048-channel spectra (each are averages of multiple laser shots)

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times three spectral ranges and one dark spectrum over the same ranges. The dark spectrum is

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first subtracted. The following processes are implemented in the order given.

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**Denoising.** The presence and the amplitude of noise depend on the experimental conditions.

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Such noise is approximated as a “white Gaussian noise”, which is a random signal with a

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Gaussian amplitude distribution. A series of cubic-spline undecimated wavelet functions are

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computed for all possible $2^k$ scales. Then at each scale, the noise standard deviation is

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iteratively computed, assuming a white Gaussian noise. Only the wavelet coefficients with

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values greater than a defined threshold, typically 3 times the noise standard deviation, are

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returned. Finally, the denoised spectrum is obtained by summing all modified wavelet scales

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[39]. When the white noise is removed, it was rarely more than half a dozen counts per

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channel.

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**Continuum removal.** For LIBS plasmas, background continuum is due to Bremsstrahlung

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emission and ion/electron recombination processes [40]. As such, the background continuum

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contains little or no spectral information, in contrast to emission lines; it is removed from each

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spectrum applying the following procedure. Similar to the previous step, we decompose the

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spectrum into a set of undecimated wavelet scales. In this space, we iteratively find the local

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minima or convex hulls. The search for these minima starts from the larger scales to the

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smallest. It is stopped at a scale which is fixed by the user. At the end, a spline function is

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**Peak fitting.** The characterization of each LIBS peak is the final step of our processing. It returns the line intensity in DN, the position, and the FWHM in decimal fraction of a channel or nanometers. Spectral intensities greater than three times the noise level are fitted simultaneously by a series of Lorentzian functions [10]. The Lorentz shape is indeed predicted by LIBS physics [29]. However, when convolved by the response function of the instrument, namely a Gaussian, it yields a Voigt function, which is in reality a convolution of the two. The Voigt function is more accurate than a fit by a Lorentz function, but the Lorentz shape relies on fewer parameters: three versus four for the Voigt function. Our fitting algorithm uses the Levenberg-Marquardt technique [41] to solve the least-squares problem, which optimizes the adjustment of Lorentz parameters to the data points. A few limits are set to constrain the fitting routine: the peak position must be within ±0.1 nm of the measured maximum intensity, the FWHM must be at least 0.06 nm.

## 4.2 Peak Identification

Once the spectrometers are calibrated for wavelength and the LIBS peaks are fitted, each line is manually identified with respect to the NIST vacuum database. The approach described by [29] was applied. Around each peak, within ±1.2 times the resolution of the spectrometers, the NIST database is searched for likely elements and lines. To isolate the correct element and line: 1) using pure targets, there is no ambiguity on the element, but it can still be difficult to determine between lines that are very close together. The choice of the appropriate one is made by comparison of their ionization levels (prefer low levels: neutral or singly ionized), their relative intensities given by NIST (prefer highest values), and also their energy level (prefer low values). 2) Using complex targets, several lines from the same or different elements are possible. The same methodology applies: ionization level, relative intensity and energy level are observed. If several lines from different elements are still candidates, the
349 composition of the target helps. If ambiguity remains, several candidates are kept in our database.

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As an example, pure forsteritic olivine (Mg₂SiO₄) displays a peak at 285.26 nm. From the NIST database, no Si or O lines are candidates but there are two Mg lines at 285.25 nm and 285.29 nm that are not resolved by the UV spectrometer. These two lines are neutral, but the one at 285.29 nm yields a higher relative intensity (50 vs. 16) in the NIST database and lower energy levels (transition from 4 eV to 0 eV). This one is therefore kept in our database.

However, when analyzing a natural olivine ((Mg,Fe)₂SiO₄) several lines are candidates around 285.26 nm: the two Mg lines we mentioned earlier and also four Fe lines (285.23, 285.26, 285.28, and 285.30 nm). The one at 285.26 has the highest relative intensity (15100 vs. ~100) and lower energy levels than others (transitions from ~5 eV to 1 eV vs. ~7 eV to ~1.5 eV). This one is therefore preferred for Fe. Since the sample contains significant amounts of both Mg and Fe, it is not possible to differentiate between Mg and Fe lines. A pure Fe target was then checked to determine if it still has an emission line at this position, in which case both Mg and Fe lines have to be kept in our database. Ideally, a much higher resolution spectrometer could be used with the same environmental conditions and the same sample to distinguish between line pairs that were undetermined in our database.

As known in LIBS physics, Fe, Ti, and Mn have many lines. On the other extreme, elements of astrobiological interest (C, H, N, O, P, S) have only a few lines, and often more singly ionized than neutral ones. Carbon lines were studied using a graphite target. Twenty-three lines were identified between 240 nm and 730 nm, with only two of them being neutral. The three most intense observed lines are singly ionized and are located at 426.84 nm, 657.98 nm, and 723.84 nm, and do not suffer interference from other elemental lines. Only one hydrogen line is observed on several targets at 656.46 nm. This line can suffer from interference from
several other lines, including an O line at 656.22 nm and an Ar line at 656.6 nm. Fifteen nitrogen lines were identified. All of them are located in the VNIR range. The two most intense ones are seen at 500.66 nm and 568.11 nm and are singly ionized. The first one suffers interference from the Pb line located at 500.68 nm. The oxygen lines are always present because of O in the atmosphere. They are located in the VNIR range between 600 and 850 nm. The most intense lines correspond to the triplet at 777,41 nm, 777.63 nm and 777.75 nm, as well as a line at 844.86 nm. No single target was used to study the phosphorous lines. These were observed using the standard deviation spectrum of calibration data acquired in Los Alamos (see below for more explanation about this spectrum). Only four lines were identified as P, located between 530 nm and 610 nm. The most intense is the one at 537.97 nm. From the NIST database, the most intense one is located at 253.63 nm, but is not observed with our experiment. Sulfur lines were identified using a sphalerite target (ZnS). Twenty-seven lines were observed and only one is neutral; the others are singly ionized. The most intense are located at 402.98 nm and 468.27 nm. A Ti line at 402.94 nm and a Zn line located at 468.15 nm interfere with these S lines. See [14] for more information about the Sulfur detection by LIBS.

Some other trace elements are important to constrain geological processes. However, these lines are sometimes difficult to identify. Chromium is known to be present in some igneous minerals (like pyroxenes), but also to be mobilized into clays. Only two lines are identified, using the picrite calibration target [15]. These two lines are neutral and located in the VIS range, at 425.55 nm and 427.6 nm. The last one can be interfered by a copper line at 427.63 nm (the eleventh brighter for 66 copper lines) and/or an iron line at 427.29 nm. Some elements like the lithium or arsenic can be used as indicator for aqueous alteration. However, lithium can also be observed in some igneous rocks. Five neutral lines are identified. The most important ones are located in the VNIR range at 610.52 nm and 670.97 nm. The first one
398 has interference from a Ca line at 610.44 nm which is a bright Ca line in this region.
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10 402 lines are located in the VIS, at 460.87 nm, 421.67 nm, and 407.88 nm. The last one can suffer
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## 5. Discussion & Conclusion

415 Our database concerns 32 elements of interest for Martian geochemistry: 1336 lines are
416 identified unambiguously. The observed emission lines are compiled with their position, their
417 ionisation level, and their relative intensity from NIST, but also their observed intensity with
418 our setup, the spectral range (UV, VIS or VNIR), and the target name where this line was
419 observed. The complete list can be found as an electronic document attached to this
420 manuscript. Table 3 summarizes the number of observed lines per element, and the most
421 intense lines per spectral range for each of them. More neutral lines are observed than singly
422 or doubly ionized states. On average, the ratio of neutral-to-singly ionized lines is 1.9 for the
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NIST database and 1.6 for this one. However, some elements still have more singly ionized lines than neutral states. Very few double ionization states are observed.

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The Martian data set reported here is a subset of the whole NIST database, which accounts for 17,553 lines (all ionization stages) for the same wavelength range and elements, for which a third of the lines are for Fe. As mentioned in the introduction, lines in the Martian database do not necessarily correspond to those with the highest "relative intensity" indices of the NIST database. As an illustration (Figure 4) the NIST relative intensity for iron is plotted as a function of wavelength, successively for three levels of ionization. Iron has 4,988/382/138 lines for neutral/singly/doubly ionized states. Lines which have been identified in the Martian database are over-plotted in red. We observe no correlation between the Martian selection and NIST relative intensity values.

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To emphasize the value of the Martian database, the peak identification scheme is applied to a common spectrum, using alternatively the Martian and NIST databases. During ChemCam calibration tests in the spring of 2010 using the Los Alamos National Laboratory Thermal and Vacuum Chamber (TVAC), the flight instrument was held at -45°C and the laser warmed to -10°C, where its energy output is optimum [26] as planned on Mars. Twenty eight targets were placed 1.56 m from the instrument in a Martian chamber similar to the one described earlier.

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See [45] for details on the ChemCam calibration suite. A standard deviation spectrum was created from all data acquired during this test using data from all 28 samples except graphite and titanium. Therefore, this spectrum contains most of LIBS lines relevant to Mars igneous and sedimentary rocks, astrobiological targets being beyond the scope of the present study.

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A list of 247 peaks ≥ 3σ above the background was compiled and the peaks were fitted simultaneously. With one or the other database, twenty-one elements were identified: H, Li, C, O, Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Mn, Fe, Ni, Zn, Rb, Sr, and Ba. At the resolution of

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the spectrometers 1809 lines have been suggested by NIST database and 543 by the Martian database. There is no peak without a match in one or the other database. Figure 5 is a 10 nm region in the UV range of the standard deviation spectrum. There are 21 peaks that have been identified above the background and fitted simultaneously. The individual fits are shown. For each peak the NIST database proposes several possibilities, often for the same elements within the resolution of the spectrometers. For each peak, the solution for the Martian database is shown in red. This region is rich in Ti, Fe, Mn, and V peaks, and also contains one or more peaks of Mg, Ni, Cu, Al, and Na. Although NIST proposes elements such as Cr, Ar, Li, S, Be, Si, Zn, Rb, and O, according to the Martian database, these are not observed with ChemCam in this spectral region. The Al lines seen at 308.31 nm and 309.36 nm are major Al peaks in this spectral range, more intense than the other peaks that interfere with them. Effectively, the Al peak located at 308.31 nm has an interfering Mn peak at 308.29 nm. This Mn peak is weakly observed with ChemCam: this is the 191st most intense Mn peak, considering there are 196 Mn peaks in the Martian database. The Al peak located at 309.36 nm overlaps with a Mg peak at 309.39 nm and a V peak at 309.40 nm. This Mg peak is the 21st peak out for 29 Mg peaks in intensity. Therefore, if other weak Mg peaks (as 293 nm for example) are not clearly observed, there is much more probability that Al is observed, likely with little or no interference from Mg at 309.40 nm. Moreover, the V peak is relatively bright for ChemCam (10th peak in intensity out of V 71 peaks), but this element is rarely observed in rocks. Finally, to resolve ambiguities, a correlation method is used to discriminate the several peaks (see below).

To follow on the comparison of NIST and Martian databases, Figure 6 is a histogram of the number of identifications per peak. The NIST database includes a number of lines per peak, up to ten and above. The Martian database shows fewer possibilities: For more than 40% of the peaks, only one solution is proposed, and for another 25% two solutions are possible.
To discriminate between different solutions for a single peak, correlations across the spectrum are required. To that end, the Martian database was used to build synthetic LIBS spectra for each element. As stated in the Introduction and demonstrated in Figure 4 for Fe, relative intensities from NIST can hardly be used to identify lines. However, for the Martian database all data were acquired with similar setups (in Toulouse, France and the flight model) and under the same observational conditions (distance, gas composition and pressure). In general LIBS lines for a given element were obtained from a single target. Where it was obtained from several targets, normalization was applied to match lines that are common to distinct targets. In both cases, relative intensities among the different lines of an element are meaningful. As a result, synthetic spectra, normalized to one for the brightest peak, can be built for each element. Figure 7 shows synthetic spectra for Al, Mn and Ni. They were generally produced from a single target, and lines were easily added from other targets. The Flight Model and the Engineering and Qualification Model Mast Unit are also very similar concerning their response function. They are radiometrically calibrated; therefore it is possible to switch between these two models in order to recreate synthetic spectra with the response function of ChemCam on Mars. Such spectra help to predict which lines should be most intense and should give a reasonable estimate of relative intensities. When it is difficult to distinguish between two elements or lines for a given peak, cross-correlations are calculated between synthetic spectra of those two elements and the rest of the spectrum: if the difference is largely in favor of one of the elements (by a factor > 3 on the correlation), the other can be rejected. The correlation method helps for decision making with regards to line identification. However, users should be aware that matrix effects in LIBS can significantly modify relative line intensities [29,46].

The Martian database is the first step for LIBS data processing on Mars. We use peak positions to identify lines, and peak intensity (with care) to distinguish between ambiguous
detections. To assess on the usefulness of the Martian database, we have performed automatic peak identification on three pyroxenes. Pyroxenes are major mineral constituents in basalts on Earth and Mars. Their formula is [(X,Y)(Si,Al)₂O₆], where X is a large cation and Y is a smaller one. We focused on ferromagnesian and calcium-rich pyroxenes, such as Enstatite (Mg₂Si₂O₆) for the Mg end-member, Diopside (MgCaSi₂O₆) for the Mg+Ca end-member, and Augite ((Ca,Na)(Mg,Fe,Al)(Si,Al)₂O₆) which is located between the Mg+Ca and Fe+Ca poles. In Figure 8, spectra are normalized to their standard deviation. The bottom spectrum (Enstatite) is rich in Mg and Si, with no Ca and traces of Fe and Al. The middle one (Diopside) is also rich in Si, it has less Mg than the bottom one, and a lot of Ca. The top one (Augite) has Ca, Al, and Si, even less Mg than the previous ones and, almost no Fe. These observations are in agreement with the definitions of these minerals. However, this qualitative comparison allows us to conclude that the Enstatite sample is not the pure Mg end-member, but rather a solid solution between the Enstatite and the Ferrosilite (Fe end-member), as the Fe lines are well identified. The Augite sample is clearly more Mg-rich than Fe-rich, which implies that this augite is closer to the Mg-pole than the Fe one.

Line identification is a key practice of LIBS data processing. However, in the LIBS technique the relative intensities of observed lines depend on instrument parameters and on the surrounding environment. We have presented the methodology used to build a dedicated database for ChemCam spectra on Mars. This database is a subset of the NIST vacuum database, and it is used to automatically identify spectral lines.
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[45] R. Wiens, S. Clegg, S. Bender, N. Lanza, B. Barraclough, R. Perez, O. Forni, S. Maurice, M.D. Dyar, H. Newsom, Progress on calibration of ChemCam LIBS instrument for the Mars Science Laboratory (MSL) rover, *Lunar and Planet. Sci.* (2010) 2205.

[46] A. Eppler, D. Cremers, D. Hickmott, M. Ferris and A. Koskelo, Matrix effects in the detection of Pb and Ba in soils using laser-induced breakdown spectroscopy, *Appl. Spectrosc.* 50 (1996) 1175-1181.
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Figure 1a: Mast Unit – Engineering and Qualification Model- used for the ChemCam lab unit in Toulouse

Figure 1b: Martian Chamber used for the lab unit in Toulouse. The ChemCam lab unit is positioned several meters to the left.

Figure 2: SNR obtained for selected lines in the Martian environment and at ambient pressure. Here the elements are arranged by increasing lower energy levels. Below each element label is the wavelength in nm of the lines.

Figure 3: Intensity obtained for the Mg line at 518.5 nm versus pressure for several atmosphere compositions: air (black), Mars (blue), nitrogen (red). Error bars are given by the fit of the line.

Figure 4: Iron LIBS lines from the NIST database (black dots) for the lowest three ionization levels. Those lines which are part of the Martian database are in red.

Figure 5: Standard deviation spectrum for a 10 nm wavelength range (blue continuous line). Twenty one peaks have been detected. For each, the fit by a Lorentzian is shown in gray and the series of elements that have been detected in NIST database are given. Those lines that are also in the Martian database are in red.

Figure 6: Histogram of the peak identification from the NIST and Martian databases. When the number of identifications is greater than 10, it is displayed as 10.

Figure 7: Synthetic spectra for Al, Mn, and Ni, from the Martian database.

Figure 8: Spectra of three pyroxenes: Enstatite (blue), Diopside (Red), Augite (Black). Each spectrum is normalized to its standard deviation. Enstatite and Diopside spectra are offset for clarity.
<figure><img src="image_2.png" /><figcaption>**Figure(s)**
Click here to download high resolution image</figcaption></figure>
<figure><img src="image_3.png" /><figcaption>**Figure(s)**
Click here to download high resolution image</figcaption></figure>
<figure><img src="image_4.png" /></figure>
<figure><img src="image_5.png" /></figure>
<figure><img src="image_6.png" /></figure>
<figure><img src="image_7.png" /><figcaption>Figure(s)
Click here to download high resolution image</figcaption></figure>
<figure><img src="image_8.png" /></figure>
<figure><img src="image_9.png" /></figure>
<figure><img src="image_10.png" /></figure>
<table><caption>Table 1: Widths of emission lines in the 390-405 nm range under various conditions</caption><thead><tr><th rowspan="3">Line</th><th rowspan="3">Wavelength<br>(nm)</th><th colspan="2">Transition energy levels</th><th colspan="4">Full width half maximum (FWHM; nm)</th></tr><tr><th rowspan="2">Upper<br>(eV)</th><th rowspan="2">Lower<br>(eV)</th><th colspan="2">Pure element targets</th><th colspan="2">Basalt target</th></tr><tr><th>Mars atm.</th><th>Earth atm.</th><th>Mars atm.</th><th>Earth atm.</th></tr></thead><tbody><tr><td>Ca II</td><td>393.477</td><td>3.151</td><td>0.000</td><td>0.108±.011</td><td>0.944±.077</td><td>0.107±.002</td><td>0.235±.001</td></tr><tr><td>Ca II</td><td>396.959</td><td>3.123</td><td>0.000</td><td>0.173±.009</td><td>0.669±.053</td><td>0.097±.004</td><td>0.188±.002</td></tr><tr><td>Al I</td><td>394.512</td><td>3.143</td><td>0.000</td><td>0.068±.004</td><td>0.184±.004</td><td>0.090±.005</td><td>0.164±.003</td></tr><tr><td>Al I</td><td>396.264</td><td>3.143</td><td>0.000</td><td>0.078±.003</td><td>0.242±.003</td><td>0.090±.002</td><td>0.156±.006</td></tr><tr><td>Fe I</td><td>404.696</td><td>4.549</td><td>1.484</td><td>0.117±.012</td><td>0.133±.019</td><td>0.112±.016</td><td>0.138±.028</td></tr></tbody></table>
<table><caption>Table 2: Intensities of emission lines in the 390-405 nm range in Mars and Earth atmospheres</caption><thead><tr><th rowspan="2"></th><th rowspan="2">Wavelength (nm)</th><th colspan="2">Intensities (arbitrary units)</th></tr><tr><th>Mars atm.</th><th>Earth atm.</th></tr></thead><tbody><tr><td>Ca II</td><td>393.477</td><td>1018±34</td><td>578±42</td></tr><tr><td>Ca II</td><td>396.959</td><td>1027±35</td><td>709±47</td></tr><tr><td>Al I</td><td>394.512</td><td>373±42</td><td>95.1±1.5</td></tr><tr><td>Al I</td><td>396.264</td><td>748±43</td><td>232±63</td></tr></tbody></table>
<table><caption>Table(s)</caption><thead><tr><th rowspan="2"></th><th rowspan="2">I</th><th rowspan="2">II</th><th rowspan="2">III</th><th colspan="3">λ (nm) for brightest lines</th></tr><tr><th>UV (239.15 nm - 339.66 nm)</th><th>VIS (383.82 nm - 471.44 nm)</th><th>VNIR (490.61 nm - 928.02 nm)</th></tr></thead><tbody><tr><td>H</td><td>2</td><td>-</td><td>-</td><td>-</td><td>-</td><td><strong>656.46</strong></td></tr><tr><td>Li</td><td>5</td><td>-</td><td>-</td><td>-</td><td>460.42</td><td><strong>670.97</strong>, 610.52, 812.88</td></tr><tr><td>Be</td><td>-</td><td>1</td><td>-</td><td><strong>313.19</strong></td><td>-</td><td>-</td></tr><tr><td>B</td><td>-</td><td>1</td><td>-</td><td>-</td><td><strong>412.31</strong></td><td>-</td></tr><tr><td>C</td><td>4</td><td>15</td><td>8</td><td>247.93, 283.75</td><td>426.82</td><td><strong>657.99</strong>, 589.14</td></tr><tr><td>N</td><td>4</td><td>11</td><td>-</td><td>-</td><td>-</td><td><strong>500.65</strong></td></tr><tr><td>O</td><td>7</td><td>1</td><td>-</td><td>-</td><td>-</td><td><strong>777.41</strong>, <strong>777.63</strong>, 844.86</td></tr><tr><td>F</td><td>11</td><td>3</td><td>1</td><td>-</td><td>393.53</td><td><strong>601.75</strong>, 603.97, 604.92</td></tr><tr><td>Na</td><td>4</td><td>4</td><td>-</td><td>312.53</td><td>-</td><td><strong>589.16</strong>, <strong>589.76</strong>, 819.71, 818.55</td></tr><tr><td>Mg</td><td>21</td><td>8</td><td>-</td><td><strong>279.63</strong>, 280.35, 279.88, 285.29</td><td>448.24</td><td>518.51, 517.41</td></tr><tr><td>Al</td><td>9</td><td>20</td><td>1</td><td>309.36, 308.31</td><td><strong>396.21</strong>, 394.56</td><td>704.4, 705.85</td></tr><tr><td>Si</td><td>16</td><td>16</td><td>1</td><td><strong>288.24</strong></td><td>412.92, 413.42, 390.66</td><td>634.88, 637.31</td></tr><tr><td>P</td><td>-</td><td>4</td><td>-</td><td>-</td><td>-</td><td><strong>537.97</strong>, 550.87, 558.48</td></tr><tr><td>S</td><td>1</td><td>26</td><td>-</td><td>330.33</td><td>402.99, <strong>468.26</strong></td><td>639.91, 639.97</td></tr><tr><td>Cl</td><td>10</td><td>13</td><td>2</td><td>310.53</td><td>426.57</td><td><strong>771.97</strong>, 521.94, 507.97, 837.82</td></tr><tr><td>K</td><td>11</td><td>9</td><td>-</td><td>-</td><td>418.74</td><td><strong>766.70</strong>, 770.11</td></tr><tr><td>Ar</td><td>3</td><td>1</td><td>-</td><td>-</td><td>-</td><td><strong>750.59</strong>, 795.04</td></tr><tr><td>Ca</td><td>36</td><td>10</td><td>3</td><td>318.02, 315.98</td><td><strong>393.48</strong>, 396.96, 422.79</td><td>616.3, 559.60</td></tr><tr><td>Ti</td><td>164</td><td>104</td><td>-</td><td>308.89, 307.3, 309.03, 307.95, <strong>335.04</strong></td><td>430.71, 439.51, 455.01</td><td>626.28, 503.73, 522.57</td></tr><tr><td>V</td><td>52</td><td>19</td><td>-</td><td><strong>306.73</strong>, 307.62</td><td>455.09, 439.65</td><td>626.03, 500.37</td></tr><tr><td>Cr</td><td>2</td><td>-</td><td>-</td><td>-</td><td><strong>427.60</strong>, 425.55</td><td>-</td></tr><tr><td>Mn</td><td>137</td><td>56</td><td>3</td><td><strong>295.01</strong>, 294.01, 289.04</td><td>446.32, 423.63</td><td>601.51, 537.91</td></tr><tr><td>Fe</td><td>242</td><td>64</td><td>11</td><td><strong>275.01</strong>, 275.65</td><td>438.48, 427.23, 432.7, 404.69</td><td>516.89, 521.77, 522.86</td></tr><tr><td>Ni</td><td>45</td><td>8</td><td>-</td><td><strong>310.28</strong>, 301.29</td><td>440.28</td><td>510.14</td></tr><tr><td>Cu</td><td>25</td><td>33</td><td>8</td><td>324.85, 327.49</td><td>406.38</td><td><strong>521.97</strong>, 515.47</td></tr><tr><td>Zn</td><td>6</td><td>2</td><td>-</td><td><strong>330.35</strong>, 334.59, 328.32</td><td>468.15</td><td>780.15, 761.5, 776.0</td></tr><tr><td>As</td><td>-</td><td>1</td><td>-</td><td>-</td><td><strong>450.89</strong></td><td>-</td></tr><tr><td>Rb</td><td>3</td><td>-</td><td>-</td><td>-</td><td>-</td><td><strong>794.98</strong>, 780.24</td></tr><tr><td>Sr</td><td>16</td><td>4</td><td>-</td><td>-</td><td><strong>407.88</strong>, 421.67, 460.86</td><td>525.84, 689.45, 644.85, 515.75</td></tr><tr><td>Cs</td><td>-</td><td>1</td><td>-</td><td>-</td><td><strong>460.51</strong></td><td>-</td></tr><tr><td>Ba</td><td>1</td><td>2</td><td>-</td><td>-</td><td><strong>455.53</strong></td><td>-</td></tr><tr><td>Pb</td><td>15</td><td>6</td><td>3</td><td>280.28</td><td><strong>405.89</strong>, 424.61, 438.77</td><td>666.20</td></tr><tr><td><strong>Total</strong></td><td><strong>852</strong></td><td><strong>443</strong></td><td><strong>41</strong></td><td></td><td></td><td></td></tr></tbody></table>

<caption>**Table 3:** Number of LIBS lines in the Martian database. First three columns are a different oxidation state. Brighter lines are presented for each spectral range. The brightest line per element is presented in bold.</caption>
<table><thead><tr><th>elt ex</th><th>wav_nist</th><th>wav_mars</th><th>ReInt</th><th>Intensity Base Target</th></tr></thead><tbody><tr><td>Ni II</td><td>241.686</td><td>241.703</td><td>2000.00</td><td>27.3480 MARS Ni</td></tr><tr><td>Mn II</td><td>242.812</td><td>242.841</td><td>20.0000</td><td>49.9940 MARS Mn</td></tr><tr><td>Mn II</td><td>242.846</td><td>242.841</td><td>50.0000</td><td>49.9940 MARS Mn</td></tr><tr><td>Mn II</td><td>243.811</td><td>243.789</td><td>30.0000</td><td>64.6990 MARS Mn</td></tr><tr><td>Mn II</td><td>243.858</td><td>243.789</td><td>20.0000</td><td>64.6990 MARS Mn</td></tr><tr><td>Ni II</td><td>243.863</td><td>243.857</td><td>500.000</td><td>27.6680 MARS Ni</td></tr><tr><td>Mn II</td><td>245.323</td><td>245.319</td><td>30.0000</td><td>91.1710 MARS Mn</td></tr><tr><td>C I</td><td>247.930</td><td>247.957</td><td>800.000</td><td>11.1600 MARS cibles</td></tr><tr><td>C I</td><td>247.931</td><td>247.930</td><td>800.000</td><td>67.0390 MARS C</td></tr><tr><td>Fe I</td><td>248.402</td><td>248.357</td><td>10000.0</td><td>67.1240 MARS Fe</td></tr><tr><td>Cu III</td><td>248.721</td><td>248.677</td><td>700.000</td><td>6.98400 MARS Cu</td></tr><tr><td>Fe I</td><td>249.139</td><td>249.103</td><td>3000.00</td><td>91.7880 MARS Fe</td></tr><tr><td>Fe I</td><td>249.191</td><td>249.103</td><td>2000.00</td><td>91.7880 MARS Fe</td></tr><tr><td>Fe II</td><td>249.401</td><td>249.439</td><td>500.000</td><td>73.5680 MARS cibles</td></tr><tr><td>Fe I</td><td>249.475</td><td>249.439</td><td>60.0000</td><td>73.5680 MARS cibles</td></tr><tr><td>Fe I</td><td>249.965</td><td>249.902</td><td>150.000</td><td>70.9940 MARS Fe</td></tr><tr><td>Mn II</td><td>249.975</td><td>249.909</td><td>50.0000</td><td>58.8180 MARS Mn</td></tr><tr><td>Fe I</td><td>250.189</td><td>250.381</td><td>1000.00</td><td>80.1420 MARS Fe</td></tr><tr><td>Zn II</td><td>250.274</td><td>250.266</td><td>1000.00</td><td>64.3420 MARS sphalerite</td></tr><tr><td>Cu II</td><td>250.703</td><td>250.700</td><td>150.000</td><td>17.4050 MARS Cu</td></tr><tr><td>Fe II</td><td>250.756</td><td>250.760</td><td>40.0000</td><td>129.132 MARS cibles</td></tr><tr><td>Si I</td><td>250.766</td><td>250.760</td><td>425.000</td><td>129.132 MARS cibles</td></tr><tr><td>C II</td><td>250.988</td><td>250.966</td><td>250.000</td><td>14.7440 MARS C</td></tr><tr><td>Fe I</td><td>251.159</td><td>251.231</td><td>1000.00</td><td>145.216 MARS Fe</td></tr><tr><td>Ni II</td><td>251.163</td><td>251.125</td><td>500.000</td><td>145.846 MARS Ni</td></tr><tr><td>C II</td><td>251.281</td><td>251.285</td><td>350.000</td><td>18.2590 MARS C</td></tr><tr><td>Si I</td><td>251.687</td><td>251.709</td><td>500.000</td><td>292.948 MARS cibles</td></tr><tr><td>Fe I</td><td>251.733</td><td>251.709</td><td>80.0000</td><td>292.948 MARS cibles</td></tr><tr><td>Mn II</td><td>251.736</td><td>251.694</td><td>20.0000</td><td>135.288 MARS Mn</td></tr><tr><td>Mn II</td><td>251.750</td><td>251.694</td><td>20.0000</td><td>135.288 MARS Mn</td></tr><tr><td>Si I</td><td>251.996</td><td>252.025</td><td>350.000</td><td>137.978 MARS cibles</td></tr><tr><td>Fe I</td><td>252.039</td><td>252.025</td><td>150.000</td><td>137.978 MARS cibles</td></tr><tr><td>Fe I</td><td>252.361</td><td>252.240</td><td>4000.00</td><td>92.8990 MARS Fe</td></tr><tr><td>Fe I</td><td>252.442</td><td>252.499</td><td>200.000</td><td>164.201 MARS cibles</td></tr><tr><td>Si I</td><td>252.487</td><td>252.499</td><td>425.000</td><td>164.201 MARS cibles</td></tr><tr><td>Fe I</td><td>252.505</td><td>252.499</td><td>500.000</td><td>164.201 MARS cibles</td></tr><tr><td>Cu II</td><td>252.735</td><td>252.981</td><td>120.000</td><td>10.1530 MARS Cu</td></tr><tr><td>Fe I</td><td>252.820</td><td>252.611</td><td>2000.00</td><td>178.828 MARS Fe</td></tr><tr><td>V II</td><td>252.866</td><td>252.867</td><td>210.000</td><td>2728.14 MARS Ti_LANL</td></tr><tr><td>Ti I</td><td>252.874</td><td>252.847</td><td>29.0000</td><td>1.89700 MARS titane</td></tr><tr><td>Si I</td><td>252.926</td><td>252.867</td><td>450.000</td><td>99.8080 MARS ecart-type</td></tr><tr><td>Si I</td><td>252.927</td><td>252.972</td><td>450.000</td><td>191.034 MARS cibles</td></tr><tr><td>Fe II</td><td>252.980</td><td>252.972</td><td>800.000</td><td>191.034 MARS cibles</td></tr><tr><td>Fe I</td><td>252.990</td><td>252.972</td><td>25.0000</td><td>191.034 MARS cibles</td></tr><tr><td>Mn II</td><td>253.354</td><td>253.369</td><td>50.0000</td><td>94.1110 MARS Mn</td></tr><tr><td>Mn II</td><td>253.382</td><td>253.369</td><td>75.0000</td><td>94.1110 MARS Mn</td></tr><tr><td>Mn II</td><td>253.409</td><td>253.369</td><td>50.0000</td><td>94.1110 MARS Mn</td></tr><tr><td>Fe II</td><td>253.439</td><td>253.458</td><td>120.000</td><td>143.164 MARS Fe</td></tr><tr><td>Fe I</td><td>253.456</td><td>253.458</td><td>60.0000</td><td>143.164 MARS Fe</td></tr><tr><td>Fe I</td><td>253.637</td><td>253.722</td><td>400.000</td><td>225.982 MARS Fe</td></tr><tr><td>Fe I</td><td>253.755</td><td>253.722</td><td>200.000</td><td>225.982 MARS Fe</td></tr></tbody></table>
<table>
  <tr>
    <td>Mn II</td>
    <td>253.868</td>
    <td>253.843</td>
    <td>100.000</td>
    <td>135.288 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>253.897</td>
    <td>253.934</td>
    <td>50.0000</td>
    <td>324.953 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>253.926</td>
    <td>253.934</td>
    <td>40.0000</td>
    <td>324.953 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>253.944</td>
    <td>253.934</td>
    <td>20.0000</td>
    <td>324.953 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>253.956</td>
    <td>253.934</td>
    <td>100.000</td>
    <td>324.953 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>253.967</td>
    <td>253.934</td>
    <td>100.000</td>
    <td>324.953 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>253.975</td>
    <td>253.934</td>
    <td>150.000</td>
    <td>324.953 MARS Fe</td>
  </tr>
  <tr>
    <td>Al II</td>
    <td>254.094</td>
    <td>254.075</td>
    <td>150.000</td>
    <td>385.667 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>254.128</td>
    <td>254.075</td>
    <td>20.0000</td>
    <td>385.667 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Si III</td>
    <td>254.258</td>
    <td>254.251</td>
    <td>25.0000</td>
    <td>40.2790 MARS alsi</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>254.368</td>
    <td>254.390</td>
    <td>80.0000</td>
    <td>229.406 MARS Mn</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>254.557</td>
    <td>254.568</td>
    <td>300.000</td>
    <td>58.9620 MARS Cu</td>
  </tr>
  <tr>
    <td>Ni II</td>
    <td>254.666</td>
    <td>254.673</td>
    <td>0.00000</td>
    <td>84.4360 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>254.952</td>
    <td>254.972</td>
    <td>100.000</td>
    <td>223.523 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>255.038</td>
    <td>254.990</td>
    <td>600.000</td>
    <td>243.638 MARS Fe</td>
  </tr>
  <tr>
    <td>Zn II</td>
    <td>255.872</td>
    <td>255.820</td>
    <td>1000.00</td>
    <td>291.274 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>255.936</td>
    <td>255.914</td>
    <td>95.0000</td>
    <td>361.759 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>256.105</td>
    <td>256.117</td>
    <td>40.0000</td>
    <td>0.408000 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>256.330</td>
    <td>256.307</td>
    <td>400.000</td>
    <td>328.057 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>256.442</td>
    <td>256.430</td>
    <td>150.000</td>
    <td>426.464 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni II</td>
    <td>256.669</td>
    <td>256.676</td>
    <td>500.000</td>
    <td>29.1390 MARS Ni</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>256.768</td>
    <td>256.728</td>
    <td>60.0000</td>
    <td>157.641 MARS Fe</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>256.875</td>
    <td>256.834</td>
    <td>10.0000</td>
    <td>39.1510 MARS alsi</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>257.514</td>
    <td>257.464</td>
    <td>150.000</td>
    <td>125.573 MARS Fe</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>257.587</td>
    <td>257.570</td>
    <td>10.0000</td>
    <td>143.582 MARS alsi</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>257.616</td>
    <td>257.570</td>
    <td>3.00000</td>
    <td>143.582 MARS alsi</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>257.628</td>
    <td>257.675</td>
    <td>480.000</td>
    <td>829.155 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>257.687</td>
    <td>257.675</td>
    <td>12000.0</td>
    <td>829.155 MARS Mn</td>
  </tr>
  <tr>
    <td>Pb II</td>
    <td>257.737</td>
    <td>257.780</td>
    <td>8.00000</td>
    <td>71.4510 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>257.746</td>
    <td>257.832</td>
    <td>300.000</td>
    <td>155.536 MARS Fe</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>257.803</td>
    <td>257.780</td>
    <td>80.0000</td>
    <td>71.4510 MARS Pb</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>258.159</td>
    <td>258.118</td>
    <td>50.0000</td>
    <td>0.780000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>258.307</td>
    <td>258.305</td>
    <td>50.0000</td>
    <td>206.764 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>258.335</td>
    <td>258.305</td>
    <td>100.000</td>
    <td>206.764 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>258.508</td>
    <td>258.612</td>
    <td>550.000</td>
    <td>247.052 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>258.531</td>
    <td>258.619</td>
    <td>1500.00</td>
    <td>330.714 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>258.633</td>
    <td>258.673</td>
    <td>2.00000</td>
    <td>106.699 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>258.665</td>
    <td>258.619</td>
    <td>650.000</td>
    <td>330.714 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>258.877</td>
    <td>258.829</td>
    <td>90.0000</td>
    <td>110.876 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>259.130</td>
    <td>259.143</td>
    <td>150.000</td>
    <td>8.02100 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>259.232</td>
    <td>259.300</td>
    <td>90.0000</td>
    <td>203.684 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>259.356</td>
    <td>259.300</td>
    <td>30.0000</td>
    <td>203.684 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>259.372</td>
    <td>259.405</td>
    <td>250.000</td>
    <td>959.154 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>259.451</td>
    <td>259.405</td>
    <td>6200.00</td>
    <td>959.154 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>259.915</td>
    <td>259.929</td>
    <td>650.000</td>
    <td>574.499 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>259.968</td>
    <td>259.929</td>
    <td>95.0000</td>
    <td>467.873 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>260.018</td>
    <td>260.025</td>
    <td>2000.00</td>
    <td>574.499 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>260.035</td>
    <td>260.025</td>
    <td>300.000</td>
    <td>320.571 MARS cibles</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>260.105</td>
    <td>260.085</td>
    <td>200.000</td>
    <td>26.0580 MARS Cu</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>260.647</td>
    <td>260.608</td>
    <td>4300.00</td>
    <td>1113.17 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni II</td>
    <td>260.704</td>
    <td>260.660</td>
    <td>500.000</td>
    <td>45.7120 MARS Ni</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>260.730</td>
    <td>260.713</td>
    <td>300.000</td>
    <td>427.578 MARS Fe</td>
  </tr>
</table>
<table>
  <tr>
    <td>Mg I</td>
    <td>260.740</td>
    <td>260.781</td>
    <td>5.00000</td>
    <td>394.453 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>260.761</td>
    <td>260.803</td>
    <td>800.000</td>
    <td>134.612 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>260.787</td>
    <td>260.781</td>
    <td>500.000</td>
    <td>394.453 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ni II</td>
    <td>261.072</td>
    <td>261.078</td>
    <td>500.000</td>
    <td>78.7940 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>261.098</td>
    <td>261.078</td>
    <td>190.000</td>
    <td>833.105 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>261.185</td>
    <td>261.248</td>
    <td>20.0000</td>
    <td>449.386 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>261.226</td>
    <td>261.248</td>
    <td>0.00000</td>
    <td>449.386 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>261.265</td>
    <td>261.270</td>
    <td>600.000</td>
    <td>166.464 MARS cibles</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>261.444</td>
    <td>261.444</td>
    <td>500.000</td>
    <td>536.442 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>261.460</td>
    <td>261.456</td>
    <td>0.00000</td>
    <td>272.566 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>261.461</td>
    <td>261.444</td>
    <td>320.000</td>
    <td>387.580 MARS Fe</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>261.496</td>
    <td>261.444</td>
    <td>900.000</td>
    <td>536.442 MARS Pb</td>
  </tr>
  <tr>
    <td>Ni II</td>
    <td>261.584</td>
    <td>261.548</td>
    <td>500.000</td>
    <td>55.3070 MARS Ni</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>261.829</td>
    <td>261.819</td>
    <td>3.00000</td>
    <td>179.743 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>261.840</td>
    <td>261.809</td>
    <td>320.000</td>
    <td>325.665 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>261.880</td>
    <td>261.819</td>
    <td>2140.00</td>
    <td>179.743 MARS Basalte</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>261.892</td>
    <td>261.861</td>
    <td>500.000</td>
    <td>862.291 MARS Mn</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>261.915</td>
    <td>261.913</td>
    <td>2500.00</td>
    <td>66.2160 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.119</td>
    <td>262.174</td>
    <td>90.0000</td>
    <td>181.893 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.148</td>
    <td>262.174</td>
    <td>20.0000</td>
    <td>181.893 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.245</td>
    <td>262.233</td>
    <td>40.0000</td>
    <td>76.5730 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>262.432</td>
    <td>262.590</td>
    <td>400.000</td>
    <td>647.810 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>262.482</td>
    <td>262.590</td>
    <td>150.000</td>
    <td>712.692 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>262.558</td>
    <td>262.590</td>
    <td>40.0000</td>
    <td>712.692 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.627</td>
    <td>262.667</td>
    <td>50.0000</td>
    <td>99.5000 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>262.636</td>
    <td>262.590</td>
    <td>200.000</td>
    <td>712.692 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.645</td>
    <td>262.647</td>
    <td>200.000</td>
    <td>380.139 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.907</td>
    <td>262.906</td>
    <td>150.000</td>
    <td>284.236 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>262.908</td>
    <td>262.903</td>
    <td>150.000</td>
    <td>364.237 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>262.945</td>
    <td>262.906</td>
    <td>3.00000</td>
    <td>284.236 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>263.183</td>
    <td>263.163</td>
    <td>250.000</td>
    <td>964.594 MARS Fe</td>
  </tr>
  <tr>
    <td>Si I</td>
    <td>263.207</td>
    <td>263.215</td>
    <td>190.000</td>
    <td>391.535 MARS alsi</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>263.210</td>
    <td>263.216</td>
    <td>250.000</td>
    <td>727.327 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>263.239</td>
    <td>263.235</td>
    <td>50.0000</td>
    <td>240.589 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>263.313</td>
    <td>263.267</td>
    <td>190.000</td>
    <td>706.212 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>263.603</td>
    <td>263.319</td>
    <td>0.00000</td>
    <td>30.6110 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>263.896</td>
    <td>263.839</td>
    <td>130.000</td>
    <td>797.040 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>264.063</td>
    <td>264.046</td>
    <td>80.0000</td>
    <td>98.9780 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>264.479</td>
    <td>264.254</td>
    <td>200.000</td>
    <td>39.1300 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>264.743</td>
    <td>264.688</td>
    <td>950.000</td>
    <td>0.955000 MARS titane</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>265.327</td>
    <td>265.311</td>
    <td>10.0000</td>
    <td>31.6540 MARS alsi</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>265.670</td>
    <td>265.654</td>
    <td>60.0000</td>
    <td>699.275 MARS Mn</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>266.118</td>
    <td>266.068</td>
    <td>10.0000</td>
    <td>105.292 MARS alsi</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>266.395</td>
    <td>266.378</td>
    <td>700.000</td>
    <td>388.937 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>266.545</td>
    <td>266.515</td>
    <td>60.0000</td>
    <td>150.431 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>266.546</td>
    <td>266.482</td>
    <td>60.0000</td>
    <td>385.275 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>266.708</td>
    <td>266.689</td>
    <td>200.000</td>
    <td>11.2690 MARS Cu</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>266.756</td>
    <td>266.740</td>
    <td>30.0000</td>
    <td>1117.69 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>266.760</td>
    <td>266.772</td>
    <td>3630.00</td>
    <td>135.520 MARS Basalte</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>266.779</td>
    <td>266.740</td>
    <td>45.0000</td>
    <td>1117.69 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>266.782</td>
    <td>266.740</td>
    <td>30.0000</td>
    <td>1117.69 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>267.338</td>
    <td>267.309</td>
    <td>110.000</td>
    <td>860.776 MARS Mn</td>
  </tr>
</table>
<table>
  <tbody>
    <tr>
      <td>Mn II</td>
      <td>267.416</td>
      <td>267.515</td>
      <td>55.0000</td>
      <td>986.751 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>267.522</td>
      <td>267.309</td>
      <td>55.0000</td>
      <td>860.776 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>267.986</td>
      <td>267.979</td>
      <td>600.000</td>
      <td>22.1230 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>268.114</td>
      <td>268.083</td>
      <td>45.0000</td>
      <td>923.320 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>268.148</td>
      <td>268.083</td>
      <td>30.0000</td>
      <td>923.320 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe II</td>
      <td>268.555</td>
      <td>268.567</td>
      <td>500.000</td>
      <td>80.6720 MARS Basalte</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>268.905</td>
      <td>268.855</td>
      <td>110.000</td>
      <td>713.522 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>269.001</td>
      <td>268.958</td>
      <td>400.000</td>
      <td>33.8120 MARS Fe</td>
    </tr>
    <tr>
      <td>Cu II</td>
      <td>269.010</td>
      <td>269.010</td>
      <td>750.000</td>
      <td>31.4240 MARS Cu</td>
    </tr>
    <tr>
      <td>Fe II</td>
      <td>269.340</td>
      <td>269.334</td>
      <td>6.00000</td>
      <td>85.5280 MARS Basalte</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>269.346</td>
      <td>269.370</td>
      <td>85.0000</td>
      <td>750.555 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>269.399</td>
      <td>269.370</td>
      <td>27.0000</td>
      <td>753.856 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>269.616</td>
      <td>269.576</td>
      <td>55.0000</td>
      <td>500.418 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>269.708</td>
      <td>269.781</td>
      <td>50.0000</td>
      <td>59.3880 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>269.977</td>
      <td>269.936</td>
      <td>27.0000</td>
      <td>202.763 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>269.991</td>
      <td>270.141</td>
      <td>200.000</td>
      <td>9.01300 MARS Fe</td>
    </tr>
    <tr>
      <td>Cu II</td>
      <td>270.176</td>
      <td>270.398</td>
      <td>700.000</td>
      <td>23.6930 MARS Cu</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>270.180</td>
      <td>270.192</td>
      <td>85.0000</td>
      <td>1199.55 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>270.197</td>
      <td>270.192</td>
      <td>50.0000</td>
      <td>1199.55 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>270.250</td>
      <td>270.192</td>
      <td>160.000</td>
      <td>1199.55 MARS Mn</td>
    </tr>
    <tr>
      <td>Cu II</td>
      <td>270.399</td>
      <td>270.192</td>
      <td>650.000</td>
      <td>32.6690 MARS Cu</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>270.478</td>
      <td>270.449</td>
      <td>100.000</td>
      <td>398.980 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe II</td>
      <td>270.479</td>
      <td>270.449</td>
      <td>60.0000</td>
      <td>234.357 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>270.654</td>
      <td>270.603</td>
      <td>130.000</td>
      <td>951.952 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>270.681</td>
      <td>270.706</td>
      <td>80.0000</td>
      <td>102.612 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>270.738</td>
      <td>270.706</td>
      <td>400.000</td>
      <td>102.612 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>270.833</td>
      <td>270.860</td>
      <td>80.0000</td>
      <td>725.737 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>271.113</td>
      <td>271.116</td>
      <td>80.0000</td>
      <td>910.114 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>271.238</td>
      <td>271.219</td>
      <td>110.000</td>
      <td>654.711 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>271.246</td>
      <td>271.219</td>
      <td>200.000</td>
      <td>181.142 MARS Fe</td>
    </tr>
    <tr>
      <td>Cu II</td>
      <td>271.431</td>
      <td>271.424</td>
      <td>700.000</td>
      <td>29.2570 MARS Cu</td>
    </tr>
    <tr>
      <td>Fe II</td>
      <td>271.522</td>
      <td>271.475</td>
      <td>80.0000</td>
      <td>346.166 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe II</td>
      <td>271.702</td>
      <td>271.680</td>
      <td>50.0000</td>
      <td>162.493 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>271.706</td>
      <td>271.680</td>
      <td>50.0000</td>
      <td>162.493 MARS Fe</td>
    </tr>
    <tr>
      <td>Cu II</td>
      <td>271.958</td>
      <td>271.936</td>
      <td>650.000</td>
      <td>20.7470 MARS Cu</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>271.982</td>
      <td>271.987</td>
      <td>30.0000</td>
      <td>873.007 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>271.983</td>
      <td>271.936</td>
      <td>4000.00</td>
      <td>127.517 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>272.055</td>
      <td>271.987</td>
      <td>50.0000</td>
      <td>873.007 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>272.171</td>
      <td>272.192</td>
      <td>1500.00</td>
      <td>13.6040 MARS Fe</td>
    </tr>
    <tr>
      <td>Cu II</td>
      <td>272.248</td>
      <td>272.243</td>
      <td>300.000</td>
      <td>6.91200 MARS Cu</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>272.291</td>
      <td>272.243</td>
      <td>30.0000</td>
      <td>310.390 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>272.439</td>
      <td>272.499</td>
      <td>400.000</td>
      <td>41.8400 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>272.527</td>
      <td>272.499</td>
      <td>30.0000</td>
      <td>310.390 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>272.576</td>
      <td>272.499</td>
      <td>150.000</td>
      <td>41.8400 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>272.883</td>
      <td>272.806</td>
      <td>200.000</td>
      <td>487.376 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn II</td>
      <td>272.942</td>
      <td>272.908</td>
      <td>55.0000</td>
      <td>523.769 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>272.963</td>
      <td>273.112</td>
      <td>50.0000</td>
      <td>193.800 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>273.439</td>
      <td>273.368</td>
      <td>1000.00</td>
      <td>19.3100 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>273.812</td>
      <td>273.725</td>
      <td>500.000</td>
      <td>299.935 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>273.967</td>
      <td>273.776</td>
      <td>30.0000</td>
      <td>277.995 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe II</td>
      <td>274.036</td>
      <td>274.025</td>
      <td>400.000</td>
      <td>163.543 MARS cibles</td>
    </tr>
    <tr>
      <td>C II</td>
      <td>274.209</td>
      <td>274.388</td>
      <td>350.000</td>
      <td>7.06600 MARS C</td>
    </tr>
  </tbody>
</table>
<table>
  <tr>
    <td>Fe I</td>
    <td>274.306</td>
    <td>274.337</td>
    <td>250.000</td>
    <td>515.558 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>274.322</td>
    <td>274.337</td>
    <td>800.000</td>
    <td>515.558 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>274.401</td>
    <td>274.380</td>
    <td>200.000</td>
    <td>97.2710 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>274.438</td>
    <td>274.380</td>
    <td>150.000</td>
    <td>97.2710 MARS cibles</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>274.608</td>
    <td>274.592</td>
    <td>270.000</td>
    <td>11.3200 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>274.729</td>
    <td>274.734</td>
    <td>300.000</td>
    <td>222.896 MARS cibles</td>
  </tr>
  <tr>
    <td>C II</td>
    <td>274.730</td>
    <td>274.796</td>
    <td>250.000</td>
    <td>20.5110 MARS C</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.013</td>
    <td>274.999</td>
    <td>100.000</td>
    <td>1436.57 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.029</td>
    <td>275.037</td>
    <td>500.000</td>
    <td>263.368 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.030</td>
    <td>274.999</td>
    <td>500.000</td>
    <td>1436.57 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>275.095</td>
    <td>275.037</td>
    <td>1200.00</td>
    <td>263.368 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.296</td>
    <td>275.356</td>
    <td>20.0000</td>
    <td>515.680 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.296</td>
    <td>275.290</td>
    <td>20.0000</td>
    <td>300.847 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.410</td>
    <td>275.356</td>
    <td>80.0000</td>
    <td>515.680 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>275.450</td>
    <td>275.356</td>
    <td>50.0000</td>
    <td>515.680 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>275.485</td>
    <td>275.356</td>
    <td>150.000</td>
    <td>515.680 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>275.524</td>
    <td>275.356</td>
    <td>100.000</td>
    <td>515.680 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.654</td>
    <td>275.694</td>
    <td>800.000</td>
    <td>215.414 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>275.655</td>
    <td>275.610</td>
    <td>800.000</td>
    <td>1280.24 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>275.714</td>
    <td>275.610</td>
    <td>250.000</td>
    <td>1280.24 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>276.175</td>
    <td>276.118</td>
    <td>45.0000</td>
    <td>444.026 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>276.260</td>
    <td>276.220</td>
    <td>120.000</td>
    <td>185.777 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>276.263</td>
    <td>276.220</td>
    <td>150.000</td>
    <td>185.777 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>276.284</td>
    <td>276.220</td>
    <td>150.000</td>
    <td>185.777 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>276.359</td>
    <td>276.220</td>
    <td>120.000</td>
    <td>185.777 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>276.392</td>
    <td>276.220</td>
    <td>120.000</td>
    <td>185.777 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>276.719</td>
    <td>276.677</td>
    <td>2500.00</td>
    <td>24.2960 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>276.834</td>
    <td>276.778</td>
    <td>250.000</td>
    <td>731.145 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>276.834</td>
    <td>276.854</td>
    <td>250.000</td>
    <td>156.931 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>277.049</td>
    <td>277.032</td>
    <td>800.000</td>
    <td>49.1100 MARS Cu</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>277.168</td>
    <td>277.100</td>
    <td>300.000</td>
    <td>81.5480 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>277.180</td>
    <td>277.100</td>
    <td>300.000</td>
    <td>81.5480 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>277.226</td>
    <td>277.235</td>
    <td>30.0000</td>
    <td>61.2430 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>277.405</td>
    <td>277.539</td>
    <td>50.0000</td>
    <td>17.1680 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>277.551</td>
    <td>277.539</td>
    <td>20.0000</td>
    <td>17.1680 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>277.705</td>
    <td>277.640</td>
    <td>30.0000</td>
    <td>584.065 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>277.904</td>
    <td>277.995</td>
    <td>600.000</td>
    <td>371.610 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>278.064</td>
    <td>278.045</td>
    <td>20.0000</td>
    <td>86.7390 MARS olivine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>278.082</td>
    <td>278.248</td>
    <td>30.0000</td>
    <td>263.248 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>278.451</td>
    <td>278.400</td>
    <td>50.0000</td>
    <td>455.291 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>278.892</td>
    <td>278.855</td>
    <td>3000.00</td>
    <td>115.806 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>279.002</td>
    <td>279.057</td>
    <td>55.0000</td>
    <td>421.310 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>279.118</td>
    <td>279.057</td>
    <td>60.0000</td>
    <td>421.310 MARS Mn</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>279.160</td>
    <td>279.166</td>
    <td>9.00000</td>
    <td>560.427 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>279.190</td>
    <td>279.057</td>
    <td>60.0000</td>
    <td>421.310 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>279.471</td>
    <td>279.410</td>
    <td>20.0000</td>
    <td>127.515 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>279.564</td>
    <td>279.562</td>
    <td>6200.00</td>
    <td>1424.46 MARS Mn</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>279.635</td>
    <td>279.617</td>
    <td>13.0000</td>
    <td>1900.24 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>279.860</td>
    <td>279.966</td>
    <td>200.000</td>
    <td>66.7530 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>279.875</td>
    <td>279.865</td>
    <td>10.0000</td>
    <td>1116.67 MARS olivine</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>279.882</td>
    <td>279.918</td>
    <td>10.0000</td>
    <td>1019.83 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>279.909</td>
    <td>279.865</td>
    <td>5100.00</td>
    <td>466.964 MARS Mn</td>
  </tr>
</table>
<table>
  <tr>
    <td>Ni I</td>
    <td>279.947</td>
    <td>279.915</td>
    <td>150.000</td>
    <td>54.8070 MARS Ni</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>280.170</td>
    <td>280.140</td>
    <td>400.000</td>
    <td>294.478 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>280.189</td>
    <td>280.167</td>
    <td>3700.00</td>
    <td>217.407 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>280.189</td>
    <td>280.369</td>
    <td>3700.00</td>
    <td>262.339 MARS Mn</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>280.189</td>
    <td>280.140</td>
    <td>100.000</td>
    <td>294.478 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>280.190</td>
    <td>280.199</td>
    <td>3700.00</td>
    <td>11.1840 MARS cibles</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>280.282</td>
    <td>280.268</td>
    <td>25000.0</td>
    <td>1452.81 MARS Pb</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>280.353</td>
    <td>280.369</td>
    <td>12.0000</td>
    <td>1512.38 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>280.493</td>
    <td>280.571</td>
    <td>70.0000</td>
    <td>539.173 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>280.535</td>
    <td>280.571</td>
    <td>400.000</td>
    <td>35.9750 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>280.781</td>
    <td>281.024</td>
    <td>1500.00</td>
    <td>14.9420 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>280.994</td>
    <td>280.973</td>
    <td>110.000</td>
    <td>297.155 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>281.113</td>
    <td>281.074</td>
    <td>75.0000</td>
    <td>3.54500 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>281.367</td>
    <td>281.275</td>
    <td>60.0000</td>
    <td>1020.47 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>281.412</td>
    <td>281.376</td>
    <td>2500.00</td>
    <td>106.515 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>281.430</td>
    <td>281.577</td>
    <td>70.0000</td>
    <td>601.476 MARS Mn</td>
  </tr>
  <tr>
    <td>Al II</td>
    <td>281.701</td>
    <td>281.678</td>
    <td>4000.00</td>
    <td>1486.36 MARS alsi</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>281.867</td>
    <td>281.834</td>
    <td>65.0000</td>
    <td>3.59100 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>282.228</td>
    <td>282.281</td>
    <td>55.0000</td>
    <td>91.0610 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>282.338</td>
    <td>282.532</td>
    <td>55.0000</td>
    <td>281.882 MARS Mn</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>282.402</td>
    <td>282.381</td>
    <td>14000.0</td>
    <td>436.511 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>282.411</td>
    <td>282.381</td>
    <td>300.000</td>
    <td>33.4830 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>282.520</td>
    <td>282.482</td>
    <td>1250.00</td>
    <td>39.7390 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>282.639</td>
    <td>282.632</td>
    <td>600.000</td>
    <td>42.4330 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>282.890</td>
    <td>282.883</td>
    <td>65.0000</td>
    <td>5.62100 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>282.964</td>
    <td>282.883</td>
    <td>120.000</td>
    <td>63.4020 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>283.162</td>
    <td>283.134</td>
    <td>80.0000</td>
    <td>590.243 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>283.299</td>
    <td>283.283</td>
    <td>130.000</td>
    <td>1.63100 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>283.327</td>
    <td>283.234</td>
    <td>1500.00</td>
    <td>237.752 MARS Fe</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>283.389</td>
    <td>283.384</td>
    <td>35000.0</td>
    <td>775.086 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>283.678</td>
    <td>283.635</td>
    <td>120.000</td>
    <td>130.860 MARS Fe</td>
  </tr>
  <tr>
    <td>C II</td>
    <td>283.754</td>
    <td>283.785</td>
    <td>1000.00</td>
    <td>113.004 MARS C</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>283.820</td>
    <td>283.785</td>
    <td>350.000</td>
    <td>20.1110 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>283.895</td>
    <td>284.086</td>
    <td>200.000</td>
    <td>323.789 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>284.278</td>
    <td>284.233</td>
    <td>190.000</td>
    <td>2.12400 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>284.481</td>
    <td>284.586</td>
    <td>1000.00</td>
    <td>34.6560 MARS Fe</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>284.741</td>
    <td>284.705</td>
    <td>120.000</td>
    <td>552.617 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>284.894</td>
    <td>284.886</td>
    <td>15.0000</td>
    <td>122.510 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>285.194</td>
    <td>285.182</td>
    <td>110.000</td>
    <td>1.06100 MARS titane</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>285.250</td>
    <td>285.300</td>
    <td>16.0000</td>
    <td>566.630 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>285.263</td>
    <td>285.235</td>
    <td>800.000</td>
    <td>26.0310 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>285.297</td>
    <td>285.300</td>
    <td>50.0000</td>
    <td>566.630 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>285.775</td>
    <td>285.746</td>
    <td>30.0000</td>
    <td>216.966 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>285.918</td>
    <td>285.884</td>
    <td>25.0000</td>
    <td>327.320 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>286.316</td>
    <td>286.281</td>
    <td>95.0000</td>
    <td>2.95200 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>286.958</td>
    <td>286.931</td>
    <td>55.0000</td>
    <td>1.59800 MARS titane</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>286.997</td>
    <td>286.983</td>
    <td>140.000</td>
    <td>1279.89 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>287.015</td>
    <td>286.931</td>
    <td>50.0000</td>
    <td>46.8650 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>287.092</td>
    <td>287.080</td>
    <td>60.0000</td>
    <td>1022.11 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>287.318</td>
    <td>287.378</td>
    <td>50.0000</td>
    <td>243.059 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>287.378</td>
    <td>287.378</td>
    <td>30.0000</td>
    <td>631.949 MARS Mn</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>287.415</td>
    <td>287.378</td>
    <td>14000.0</td>
    <td>708.522 MARS Pb</td>
  </tr>
</table>
<table>
  <tr>
    <td>Fe I</td>
    <td>287.501</td>
    <td>287.726</td>
    <td>80.0000</td>
    <td>38.4230 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>287.794</td>
    <td>287.875</td>
    <td>600.000</td>
    <td>13.8900 MARS Cu</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>287.853</td>
    <td>287.822</td>
    <td>110.000</td>
    <td>1947.76 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>288.033</td>
    <td>288.024</td>
    <td>80.0000</td>
    <td>1154.42 MARS Mn</td>
  </tr>
  <tr>
    <td>Al II</td>
    <td>288.229</td>
    <td>288.223</td>
    <td>500.000</td>
    <td>624.080 MARS alsi</td>
  </tr>
  <tr>
    <td>Si I</td>
    <td>288.242</td>
    <td>288.223</td>
    <td>1000.00</td>
    <td>624.080 MARS alsi</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>288.375</td>
    <td>288.471</td>
    <td>40.0000</td>
    <td>339.156 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>288.496</td>
    <td>288.470</td>
    <td>280.000</td>
    <td>3.27900 MARS titane</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>288.504</td>
    <td>288.422</td>
    <td>270.000</td>
    <td>12.3930 MARS Cu</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>288.563</td>
    <td>288.513</td>
    <td>380.000</td>
    <td>1985.57 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>288.753</td>
    <td>288.719</td>
    <td>70.0000</td>
    <td>1235.95 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>288.978</td>
    <td>288.910</td>
    <td>65.0000</td>
    <td>2.10700 MARS titane</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>289.043</td>
    <td>289.017</td>
    <td>160.000</td>
    <td>2040.48 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>289.324</td>
    <td>289.265</td>
    <td>55.0000</td>
    <td>1005.42 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>289.535</td>
    <td>289.562</td>
    <td>50.0000</td>
    <td>91.6540 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>289.955</td>
    <td>290.057</td>
    <td>50.0000</td>
    <td>967.030 MARS Mn</td>
  </tr>
  <tr>
    <td>Ca III</td>
    <td>290.064</td>
    <td>290.007</td>
    <td>21.0000</td>
    <td>49.4700 MARS fluorine</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>290.101</td>
    <td>290.057</td>
    <td>80.0000</td>
    <td>967.030 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>290.332</td>
    <td>290.304</td>
    <td>9.00000</td>
    <td>6.91100 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>290.651</td>
    <td>290.716</td>
    <td>55.0000</td>
    <td>2.06800 MARS titane</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>290.665</td>
    <td>290.699</td>
    <td>8.00000</td>
    <td>16.6600 MARS Fe</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>290.698</td>
    <td>290.725</td>
    <td>150.000</td>
    <td>1607.33 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>290.731</td>
    <td>290.725</td>
    <td>900.000</td>
    <td>1607.33 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>290.807</td>
    <td>290.551</td>
    <td>40.0000</td>
    <td>193.074 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>290.807</td>
    <td>290.848</td>
    <td>40.0000</td>
    <td>89.3530 MARS Mn</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>290.967</td>
    <td>290.971</td>
    <td>2400.00</td>
    <td>1661.88 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>291.301</td>
    <td>291.243</td>
    <td>120.000</td>
    <td>14.8960 MARS Fe</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>291.486</td>
    <td>291.440</td>
    <td>25.0000</td>
    <td>45.8950 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>291.545</td>
    <td>291.440</td>
    <td>140.000</td>
    <td>240.643 MARS Mn</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>292.448</td>
    <td>292.488</td>
    <td>710.000</td>
    <td>1818.37 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>292.488</td>
    <td>292.488</td>
    <td>2400.00</td>
    <td>1818.37 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>292.643</td>
    <td>292.623</td>
    <td>190.000</td>
    <td>205.251 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>292.920</td>
    <td>292.907</td>
    <td>340.000</td>
    <td>0.844000 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>292.954</td>
    <td>293.066</td>
    <td>27.0000</td>
    <td>116.775 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>292.986</td>
    <td>292.977</td>
    <td>120.000</td>
    <td>119.280 MARS cibles</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>293.167</td>
    <td>293.172</td>
    <td>710.000</td>
    <td>1405.36 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>293.392</td>
    <td>293.361</td>
    <td>1100.00</td>
    <td>1766.30 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>293.488</td>
    <td>293.361</td>
    <td>27.0000</td>
    <td>1766.30 MARS Mn</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>293.673</td>
    <td>293.660</td>
    <td>110.000</td>
    <td>866.852 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>293.737</td>
    <td>293.758</td>
    <td>10.0000</td>
    <td>244.088 MARS cibles</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>293.760</td>
    <td>293.758</td>
    <td>10.0000</td>
    <td>244.088 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>293.776</td>
    <td>293.758</td>
    <td>1200.00</td>
    <td>244.088 MARS cibles</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>293.818</td>
    <td>293.855</td>
    <td>150.000</td>
    <td>1.62100 MARS titane</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>294.016</td>
    <td>293.999</td>
    <td>1500.00</td>
    <td>2195.35 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>294.125</td>
    <td>293.999</td>
    <td>250.000</td>
    <td>2195.35 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>294.134</td>
    <td>293.999</td>
    <td>0.00000</td>
    <td>2195.35 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>294.190</td>
    <td>293.999</td>
    <td>60.0000</td>
    <td>2195.35 MARS Mn</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>294.223</td>
    <td>294.245</td>
    <td>900.000</td>
    <td>2188.96 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>294.235</td>
    <td>294.245</td>
    <td>450.000</td>
    <td>2188.96 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>294.286</td>
    <td>294.225</td>
    <td>1100.00</td>
    <td>2.92600 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>294.477</td>
    <td>294.490</td>
    <td>500.000</td>
    <td>48.0040 MARS Ni</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>294.526</td>
    <td>294.490</td>
    <td>12.0000</td>
    <td>223.893 MARS Fe</td>
  </tr>
</table>
VII 294.543 294.586 1100.00 2127.43 MARS Ti_LANL

Pb II 294.829 295.029 2.00000 41.1910 MARS Pb

Fe I 294.874 294.882 1000.00 212.742 MARS Fe

Pb II 294.939 295.029 3.00000 41.1910 MARS Pb

Mn II 295.006 294.980 1900.00 2350.34 MARS Mn

Fe I 295.480 295.421 600.000 152.850 MARS Fe

VI 295.519 295.559 120.000 2003.56 MARS Ti_LANL

Ti I 295.699 295.688 1600.00 7.34300 MARS titane

Fe I 296.085 296.056 80.0000 51.2540 MARS Fe

Cu I 296.203 296.203 2500.00 25.8200 MARS Cu

Fe I 296.612 296.545 150.000 110.509 MARS Fe

Fe I 296.776 296.545 1500.00 110.509 MARS Fe

Fe I 297.023 297.082 120.000 124.315 MARS Fe

Fe I 297.097 297.082 800.000 124.315 MARS Fe

Fe I 297.400 297.423 1200.00 62.9730 MARS Fe

Fe I 297.410 297.423 500.000 62.9730 MARS Fe

CIII 298.298 298.543 200.000 5.98900 MARS C

Ni VII 298.390 298.251 0.00000 64.4970 MARS Ni

Fe I 298.444 298.592 1000.00 495.584 MARS Fe

Ni I 298.500 298.495 250.000 36.8100 MARS Ni

Fe I 298.564 298.592 60.0000 495.584 MARS Fe

Ca III 298.950 298.932 20.0000 23.0290 MARS fluorine

Ni I 299.347 299.515 500.000 100.576 MARS Ni

C II 299.349 299.661 800.000 6.80400 MARS C

Fe I 299.530 299.515 1000.00 34.5070 MARS Fe

Ni I 299.533 299.515 1000.00 100.576 MARS Ni

Fe I 299.538 299.515 250.000 34.5070 MARS Fe

Cl II 299.752 299.758 950.000 25.6740 MARS Cl

Fe I 300.039 300.049 500.000 76.9940 MARS Fe

Fe I 300.182 300.340 800.000 258.952 MARS Fe

VII 300.207 300.203 260.000 522.527 MARS Ti_LANL

Ni I 300.337 300.337 4000.00 11.1840 MARS cibles

Fe II 300.352 300.340 15.0000 258.952 MARS Fe

Ni I 300.451 300.388 2200.00 236.055 MARS Ni

Fe I 300.816 300.921 200.000 86.9700 MARS Fe

Mn I 300.854 300.873 40.0000 28.1070 MARS Mn

Fe I 300.902 300.921 500.000 86.9700 MARS Fe

Cu I 301.172 301.211 2000.00 8.22800 MARS Cu

Mn I 301.204 301.211 40.0000 41.1850 MARS Mn

Mn I 301.226 301.211 40.0000 41.1850 MARS Mn

Ni I 301.288 301.260 3700.00 288.071 MARS Ni

Fe III 301.405 301.453 15.0000 10.4240 MARS Fe

Mn I 301.555 301.550 40.0000 43.7000 MARS Mn

Ti II 301.807 301.758 120.000 2.61900 MARS titane

Ni I 302.002 302.033 350.000 39.1550 MARS Ni

Mn II 302.080 302.081 30.0000 476.444 MARS Mn

Fe I 302.137 302.130 500.000 204.569 MARS Fe

Fe I 302.152 302.173 1500.00 132.304 MARS cibles

Fe I 302.195 302.173 600.000 132.304 MARS cibles

Mn I 302.363 302.412 70.0000 182.195 MARS ecart-type

Fe I 302.672 302.709 500.000 60.7100 MARS Fe

Ti II 303.061 303.007 140.000 2.22100 MARS titane
<table>
  <tr>
    <td>Mn II</td>
    <td>303.194</td>
    <td>303.191</td>
    <td>55.0000</td>
    <td>594.236 MARS Mn</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>303.433</td>
    <td>303.418</td>
    <td>270.000</td>
    <td>886.474 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>303.470</td>
    <td>303.418</td>
    <td>290.000</td>
    <td>886.474 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>303.623</td>
    <td>303.624</td>
    <td>30.0000</td>
    <td>360.566 MARS Mn</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>303.666</td>
    <td>303.570</td>
    <td>200.000</td>
    <td>36.2110 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>303.698</td>
    <td>303.720</td>
    <td>2500.00</td>
    <td>8.53900 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>303.827</td>
    <td>303.817</td>
    <td>800.000</td>
    <td>46.5090 MARS Fe</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>303.882</td>
    <td>303.882</td>
    <td>1700.00</td>
    <td>11.1840 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>304.148</td>
    <td>303.961</td>
    <td>95.0000</td>
    <td>334.049 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>304.252</td>
    <td>304.298</td>
    <td>80.0000</td>
    <td>28.5510 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>304.546</td>
    <td>304.538</td>
    <td>330.000</td>
    <td>209.186 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>304.757</td>
    <td>304.766</td>
    <td>110.000</td>
    <td>1.76000 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>304.793</td>
    <td>304.738</td>
    <td>200.000</td>
    <td>209.186 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>304.849</td>
    <td>304.849</td>
    <td>800.000</td>
    <td>11.1840 MARS cibles</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>304.911</td>
    <td>304.946</td>
    <td>230.000</td>
    <td>1097.24 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>305.154</td>
    <td>305.162</td>
    <td>30.0000</td>
    <td>349.718 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>305.170</td>
    <td>305.162</td>
    <td>3500.00</td>
    <td>189.878 MARS Ni</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>305.428</td>
    <td>305.422</td>
    <td>180.000</td>
    <td>117.904 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>305.520</td>
    <td>305.546</td>
    <td>1500.00</td>
    <td>41.3080 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>305.525</td>
    <td>305.594</td>
    <td>250.000</td>
    <td>42.5580 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>305.829</td>
    <td>305.834</td>
    <td>130.000</td>
    <td>3.63100 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>305.833</td>
    <td>305.833</td>
    <td>600.000</td>
    <td>132.755 MARS Fe</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>305.853</td>
    <td>305.853</td>
    <td>1900.00</td>
    <td>11.1840 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>305.997</td>
    <td>305.833</td>
    <td>1000.00</td>
    <td>132.755 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>305.998</td>
    <td>305.997</td>
    <td>1000.00</td>
    <td>11.1840 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>306.301</td>
    <td>306.360</td>
    <td>140.000</td>
    <td>54.2010 MARS Mn</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>306.414</td>
    <td>306.421</td>
    <td>140.000</td>
    <td>227.820 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>306.430</td>
    <td>306.456</td>
    <td>2500.00</td>
    <td>12.1760 MARS Cu</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>306.551</td>
    <td>306.552</td>
    <td>500.000</td>
    <td>58.9640 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>306.691</td>
    <td>306.695</td>
    <td>170.000</td>
    <td>39.9530 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>306.711</td>
    <td>306.693</td>
    <td>1300.00</td>
    <td>4.82700 MARS titane</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>306.727</td>
    <td>306.706</td>
    <td>2400.00</td>
    <td>5244.59 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>306.814</td>
    <td>306.839</td>
    <td>250.000</td>
    <td>53.3760 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>307.116</td>
    <td>307.173</td>
    <td>170.000</td>
    <td>93.7780 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>307.300</td>
    <td>307.312</td>
    <td>600.000</td>
    <td>5.94400 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>307.402</td>
    <td>307.460</td>
    <td>160.000</td>
    <td>40.2980 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>307.611</td>
    <td>307.552</td>
    <td>1600.00</td>
    <td>5.27000 MARS titane</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>307.616</td>
    <td>307.608</td>
    <td>100.000</td>
    <td>4939.93 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>307.661</td>
    <td>307.794</td>
    <td>120.000</td>
    <td>84.9760 MARS Fe</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>307.679</td>
    <td>307.640</td>
    <td>150.000</td>
    <td>39.1830 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>307.953</td>
    <td>307.940</td>
    <td>2300.00</td>
    <td>1065.41 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>307.953</td>
    <td>307.853</td>
    <td>2300.00</td>
    <td>5.39000 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>308.052</td>
    <td>308.080</td>
    <td>90.0000</td>
    <td>40.7020 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>308.165</td>
    <td>308.175</td>
    <td>420.000</td>
    <td>50.1060 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>308.222</td>
    <td>308.271</td>
    <td>50.0000</td>
    <td>38.7200 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>308.295</td>
    <td>308.271</td>
    <td>23.0000</td>
    <td>38.7200 MARS Mn</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>308.305</td>
    <td>308.318</td>
    <td>24.0000</td>
    <td>797.742 MARS alsi</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>308.892</td>
    <td>308.830</td>
    <td>3600.00</td>
    <td>6.73100 MARS titane</td>
  </tr>
  <tr>
    <td>Al II</td>
    <td>308.941</td>
    <td>308.795</td>
    <td>800.000</td>
    <td>44.8270 MARS alsi</td>
  </tr>
  <tr>
    <td>Pb III</td>
    <td>308.998</td>
    <td>308.985</td>
    <td>4.00000</td>
    <td>44.8430 MARS Pb</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>309.030</td>
    <td>308.980</td>
    <td>180.000</td>
    <td>5.74800 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>309.247</td>
    <td>309.271</td>
    <td>120.000</td>
    <td>10.8390 MARS Fe</td>
  </tr>
</table>
<table>
  <tr>
    <td>Al I</td>
    <td>309.361</td>
    <td>309.359</td>
    <td>26.0000</td>
    <td>718.594 MARS cibles</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>309.374</td>
    <td>309.366</td>
    <td>20.0000</td>
    <td>1369.83 MARS alsi</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>309.388</td>
    <td>309.414</td>
    <td>22.0000</td>
    <td>46.6160 MARS olivine</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>309.401</td>
    <td>309.406</td>
    <td>3800.00</td>
    <td>2648.71 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Na II</td>
    <td>309.645</td>
    <td>309.595</td>
    <td>650.000</td>
    <td>69.9780 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>309.779</td>
    <td>309.794</td>
    <td>24.0000</td>
    <td>94.8350 MARS olivine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>309.796</td>
    <td>309.746</td>
    <td>40.0000</td>
    <td>24.3190 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>309.802</td>
    <td>309.794</td>
    <td>260.000</td>
    <td>26.3210 MARS Ni</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>309.909</td>
    <td>310.126</td>
    <td>80.0000</td>
    <td>88.1490 MARS Fe</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>310.001</td>
    <td>309.836</td>
    <td>210.000</td>
    <td>387.646 MARS Ni</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>310.079</td>
    <td>310.126</td>
    <td>100.000</td>
    <td>88.1490 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>310.087</td>
    <td>310.126</td>
    <td>100.000</td>
    <td>88.1490 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>310.120</td>
    <td>310.126</td>
    <td>60.0000</td>
    <td>88.1490 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>310.156</td>
    <td>310.126</td>
    <td>100.000</td>
    <td>88.1490 MARS Fe</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>310.245</td>
    <td>310.269</td>
    <td>2600.00</td>
    <td>387.646 MARS Ni</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>310.278</td>
    <td>310.269</td>
    <td>1300.00</td>
    <td>387.646 MARS Ni</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>310.470</td>
    <td>310.444</td>
    <td>230.000</td>
    <td>694.416 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Cl III</td>
    <td>310.532</td>
    <td>310.696</td>
    <td>600.000</td>
    <td>16.9030 MARS Cl</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>310.713</td>
    <td>310.727</td>
    <td>260.000</td>
    <td>589.683 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>310.950</td>
    <td>310.980</td>
    <td>2000.00</td>
    <td>7.31800 MARS Cu</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>311.157</td>
    <td>311.108</td>
    <td>50.0000</td>
    <td>2.17400 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>311.158</td>
    <td>311.122</td>
    <td>40.0000</td>
    <td>78.2290 MARS Mn</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>311.161</td>
    <td>311.151</td>
    <td>2600.00</td>
    <td>1992.87 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>311.503</td>
    <td>311.549</td>
    <td>270.000</td>
    <td>28.7040 MARS Ni</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>311.857</td>
    <td>311.817</td>
    <td>140.000</td>
    <td>2.26800 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>312.062</td>
    <td>312.091</td>
    <td>720.000</td>
    <td>327.822 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>312.062</td>
    <td>311.996</td>
    <td>720.000</td>
    <td>2.57600 MARS titane</td>
  </tr>
  <tr>
    <td>Na II</td>
    <td>312.612</td>
    <td>312.607</td>
    <td>600.000</td>
    <td>80.8080 MARS ecart-type</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>312.619</td>
    <td>312.607</td>
    <td>1500.00</td>
    <td>878.609 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>312.702</td>
    <td>312.778</td>
    <td>1400.00</td>
    <td>8.73000 MARS Cu</td>
  </tr>
  <tr>
    <td>Be II</td>
    <td>313.130</td>
    <td>313.184</td>
    <td>2360.00</td>
    <td>12.3510 MARS cibles</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>313.171</td>
    <td>313.125</td>
    <td>240.000</td>
    <td>1.52400 MARS titane</td>
  </tr>
  <tr>
    <td>Be II</td>
    <td>313.190</td>
    <td>313.184</td>
    <td>2160.00</td>
    <td>12.3510 MARS cibles</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>313.501</td>
    <td>313.533</td>
    <td>2900.00</td>
    <td>173.817 MARS Ni</td>
  </tr>
  <tr>
    <td>Pb III</td>
    <td>313.872</td>
    <td>313.910</td>
    <td>10.0000</td>
    <td>229.490 MARS Pb</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>314.467</td>
    <td>314.433</td>
    <td>220.000</td>
    <td>178.701 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>314.895</td>
    <td>314.900</td>
    <td>240.000</td>
    <td>205.151 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>314.909</td>
    <td>314.992</td>
    <td>60.0000</td>
    <td>15.4160 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>315.316</td>
    <td>315.320</td>
    <td>240.000</td>
    <td>252.842 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>315.512</td>
    <td>315.555</td>
    <td>12.0000</td>
    <td>77.2370 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>315.658</td>
    <td>315.611</td>
    <td>240.000</td>
    <td>1.38700 MARS titane</td>
  </tr>
  <tr>
    <td>Ca II</td>
    <td>315.978</td>
    <td>315.973</td>
    <td>170.000</td>
    <td>449.694 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>316.196</td>
    <td>316.212</td>
    <td>90.0000</td>
    <td>26.2440 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>316.212</td>
    <td>316.261</td>
    <td>500.000</td>
    <td>4.91900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>316.269</td>
    <td>316.261</td>
    <td>780.000</td>
    <td>4.91900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>316.349</td>
    <td>316.261</td>
    <td>1000.00</td>
    <td>4.91900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>316.944</td>
    <td>316.918</td>
    <td>1600.00</td>
    <td>4.91900 MARS titane</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>317.501</td>
    <td>317.475</td>
    <td>10.0000</td>
    <td>4.46000 MARS Fe</td>
  </tr>
  <tr>
    <td>Pb III</td>
    <td>317.742</td>
    <td>317.802</td>
    <td>10.0000</td>
    <td>310.515 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>317.893</td>
    <td>317.896</td>
    <td>10.0000</td>
    <td>37.4260 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>317.942</td>
    <td>317.989</td>
    <td>140.000</td>
    <td>22.8440 MARS Mn</td>
  </tr>
  <tr>
    <td>Ca II</td>
    <td>318.025</td>
    <td>318.017</td>
    <td>180.000</td>
    <td>700.170 MARS cibles</td>
  </tr>
</table>
<table>
  <tr>
    <td>Fe I</td>
    <td>318.582</td>
    <td>318.409</td>
    <td>150.000</td>
    <td>11.8530 MARS Fe</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>319.160</td>
    <td>319.175</td>
    <td>750.000</td>
    <td>4275.69 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>319.179</td>
    <td>319.160</td>
    <td>1000.00</td>
    <td>4.91900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>319.291</td>
    <td>319.287</td>
    <td>3100.00</td>
    <td>4.91900 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>319.415</td>
    <td>319.480</td>
    <td>500.000</td>
    <td>56.3730 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>319.422</td>
    <td>319.480</td>
    <td>800.000</td>
    <td>56.3730 MARS Fe</td>
  </tr>
  <tr>
    <td>Si II</td>
    <td>319.561</td>
    <td>319.591</td>
    <td>50.0000</td>
    <td>254.413 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>319.785</td>
    <td>319.806</td>
    <td>200.000</td>
    <td>46.5880 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>320.084</td>
    <td>320.082</td>
    <td>3800.00</td>
    <td>0.425000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>320.140</td>
    <td>320.178</td>
    <td>60.0000</td>
    <td>19.6430 MARS Fe</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>320.331</td>
    <td>320.330</td>
    <td>750.000</td>
    <td>4001.47 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>320.347</td>
    <td>320.304</td>
    <td>780.000</td>
    <td>3.68300 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>320.632</td>
    <td>320.689</td>
    <td>50.0000</td>
    <td>9.14000 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>321.381</td>
    <td>321.430</td>
    <td>220.000</td>
    <td>31.9500 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>321.494</td>
    <td>321.523</td>
    <td>200.000</td>
    <td>97.6920 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>321.517</td>
    <td>321.503</td>
    <td>260.000</td>
    <td>1.11700 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>321.533</td>
    <td>321.523</td>
    <td>200.000</td>
    <td>97.6920 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>321.788</td>
    <td>321.893</td>
    <td>65.0000</td>
    <td>-4.28800 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>321.799</td>
    <td>321.732</td>
    <td>1100.00</td>
    <td>3.24900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>321.887</td>
    <td>321.862</td>
    <td>110.000</td>
    <td>3.56600 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>321.920</td>
    <td>321.862</td>
    <td>260.000</td>
    <td>3.56600 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>322.014</td>
    <td>322.052</td>
    <td>110.000</td>
    <td>0.993000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>322.051</td>
    <td>322.125</td>
    <td>80.0000</td>
    <td>5.41500 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>322.070</td>
    <td>322.125</td>
    <td>60.0000</td>
    <td>5.41500 MARS Fe</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>322.146</td>
    <td>322.263</td>
    <td>600.000</td>
    <td>40.7430 MARS Pb</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>322.297</td>
    <td>322.356</td>
    <td>300.000</td>
    <td>23.4990 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>322.377</td>
    <td>322.331</td>
    <td>1300.00</td>
    <td>2.80700 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>322.445</td>
    <td>322.461</td>
    <td>220.000</td>
    <td>3.51600 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>322.517</td>
    <td>322.461</td>
    <td>240.000</td>
    <td>3.51600 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>322.671</td>
    <td>322.726</td>
    <td>600.000</td>
    <td>42.0450 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>322.706</td>
    <td>322.691</td>
    <td>140.000</td>
    <td>0.860000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>322.873</td>
    <td>322.910</td>
    <td>80.0000</td>
    <td>146.498 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>322.902</td>
    <td>322.957</td>
    <td>1000.00</td>
    <td>185.736 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>322.953</td>
    <td>322.970</td>
    <td>530.000</td>
    <td>4.31100 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.012</td>
    <td>322.970</td>
    <td>780.000</td>
    <td>4.31100 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.035</td>
    <td>322.970</td>
    <td>530.000</td>
    <td>4.31100 MARS titane</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>323.135</td>
    <td>323.187</td>
    <td>20.0000</td>
    <td>23.6620 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>323.165</td>
    <td>323.233</td>
    <td>300.000</td>
    <td>46.5520 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.225</td>
    <td>323.240</td>
    <td>110.000</td>
    <td>1.30500 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.321</td>
    <td>323.332</td>
    <td>240.000</td>
    <td>5.05700 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>323.389</td>
    <td>323.464</td>
    <td>1100.00</td>
    <td>41.4890 MARS Ni</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>323.490</td>
    <td>323.556</td>
    <td>50.0000</td>
    <td>10.8330 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.545</td>
    <td>323.551</td>
    <td>6600.00</td>
    <td>5.05700 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>323.555</td>
    <td>323.556</td>
    <td>120.000</td>
    <td>10.8330 MARS Fe</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>323.558</td>
    <td>323.464</td>
    <td>290.000</td>
    <td>41.4890 MARS Ni</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.705</td>
    <td>323.699</td>
    <td>220.000</td>
    <td>5.89200 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.750</td>
    <td>323.699</td>
    <td>5200.00</td>
    <td>5.89200 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>323.771</td>
    <td>323.833</td>
    <td>850.000</td>
    <td>140.916 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.997</td>
    <td>324.005</td>
    <td>4100.00</td>
    <td>1122.54 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>323.997</td>
    <td>323.929</td>
    <td>4100.00</td>
    <td>5.26000 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>324.293</td>
    <td>324.289</td>
    <td>2600.00</td>
    <td>4.42600 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>324.400</td>
    <td>324.477</td>
    <td>600.000</td>
    <td>30.0600 MARS Ni</td>
  </tr>
</table>
<table>
  <tr>
    <td>Cu I</td>
    <td>324.410</td>
    <td>324.431</td>
    <td>1500.00</td>
    <td>10.1860 MARS Cu</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>324.472</td>
    <td>324.569</td>
    <td>330.000</td>
    <td>34.3060 MARS Mn</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>324.848</td>
    <td>324.937</td>
    <td>10000.0</td>
    <td>287.289 MARS Cu</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>324.946</td>
    <td>325.029</td>
    <td>650.000</td>
    <td>57.7830 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>324.954</td>
    <td>324.937</td>
    <td>1200.00</td>
    <td>4.30800 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>325.208</td>
    <td>325.488</td>
    <td>100.000</td>
    <td>27.9440 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>325.285</td>
    <td>325.296</td>
    <td>950.000</td>
    <td>4.45900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>325.385</td>
    <td>325.436</td>
    <td>1200.00</td>
    <td>4.16600 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>325.389</td>
    <td>325.488</td>
    <td>310.000</td>
    <td>27.9440 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>325.498</td>
    <td>325.488</td>
    <td>65.0000</td>
    <td>27.9440 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>325.519</td>
    <td>325.523</td>
    <td>1200.00</td>
    <td>4.16600 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>325.530</td>
    <td>325.580</td>
    <td>60.0000</td>
    <td>3.60500 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>325.708</td>
    <td>325.810</td>
    <td>310.000</td>
    <td>33.8760 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>325.935</td>
    <td>326.039</td>
    <td>220.000</td>
    <td>19.8910 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>326.117</td>
    <td>326.222</td>
    <td>180.000</td>
    <td>14.8490 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>326.254</td>
    <td>326.261</td>
    <td>1200.00</td>
    <td>4.74200 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>326.565</td>
    <td>326.680</td>
    <td>180.000</td>
    <td>13.5670 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>326.599</td>
    <td>326.772</td>
    <td>80.0000</td>
    <td>8.50500 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>326.656</td>
    <td>326.772</td>
    <td>50.0000</td>
    <td>8.50500 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>326.782</td>
    <td>326.772</td>
    <td>13.0000</td>
    <td>8.50500 MARS Fe</td>
  </tr>
  <tr>
    <td>V II</td>
    <td>327.206</td>
    <td>327.242</td>
    <td>900.000</td>
    <td>3698.19 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>327.259</td>
    <td>327.213</td>
    <td>310.000</td>
    <td>3.41800 MARS titane</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>327.490</td>
    <td>327.595</td>
    <td>10000.0</td>
    <td>205.832 MARS Cu</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>327.923</td>
    <td>327.892</td>
    <td>200.000</td>
    <td>3.76600 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>327.986</td>
    <td>327.968</td>
    <td>260.000</td>
    <td>802.591 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>328.328</td>
    <td>328.270</td>
    <td>500.000</td>
    <td>238.495 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>328.367</td>
    <td>328.280</td>
    <td>1400.00</td>
    <td>8.78900 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>328.770</td>
    <td>328.872</td>
    <td>150.000</td>
    <td>20.5250 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn III</td>
    <td>328.844</td>
    <td>328.918</td>
    <td>100.000</td>
    <td>2.61300 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>328.861</td>
    <td>328.800</td>
    <td>530.000</td>
    <td>3.55500 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>329.917</td>
    <td>330.009</td>
    <td>65.0000</td>
    <td>13.7160 MARS Mn</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>330.336</td>
    <td>330.364</td>
    <td>10.0000</td>
    <td>234.910 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>330.353</td>
    <td>330.310</td>
    <td>800.000</td>
    <td>494.343 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>330.389</td>
    <td>330.310</td>
    <td>700.000</td>
    <td>494.343 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>330.731</td>
    <td>330.872</td>
    <td>200.000</td>
    <td>26.2600 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>330.890</td>
    <td>331.053</td>
    <td>2500.00</td>
    <td>13.9370 MARS Cu</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>331.045</td>
    <td>330.969</td>
    <td>260.000</td>
    <td>33.8830 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>331.537</td>
    <td>331.600</td>
    <td>840.000</td>
    <td>30.4800 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>331.537</td>
    <td>331.545</td>
    <td>840.000</td>
    <td>1.01000 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>331.897</td>
    <td>331.870</td>
    <td>330.000</td>
    <td>28.7370 MARS Basalte</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>332.165</td>
    <td>332.275</td>
    <td>65.0000</td>
    <td>0.812000 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>332.266</td>
    <td>332.304</td>
    <td>550.000</td>
    <td>2.84600 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>332.390</td>
    <td>332.364</td>
    <td>2900.00</td>
    <td>257.151 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>332.390</td>
    <td>332.401</td>
    <td>2900.00</td>
    <td>1.81700 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>332.772</td>
    <td>332.748</td>
    <td>380.000</td>
    <td>117.343 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>333.042</td>
    <td>333.038</td>
    <td>2100.00</td>
    <td>159.410 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>333.042</td>
    <td>333.018</td>
    <td>2100.00</td>
    <td>1.77600 MARS titane</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>333.082</td>
    <td>333.061</td>
    <td>110.000</td>
    <td>2059.51 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>333.307</td>
    <td>333.307</td>
    <td>550.000</td>
    <td>88.2220 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>333.307</td>
    <td>333.242</td>
    <td>550.000</td>
    <td>1.77600 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>333.616</td>
    <td>333.621</td>
    <td>1800.00</td>
    <td>101.760 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>333.616</td>
    <td>333.552</td>
    <td>1800.00</td>
    <td>1.45200 MARS titane</td>
  </tr>
</table>
<table>
  <tr>
    <td>Ti II</td>
    <td>334.130</td>
    <td>334.069</td>
    <td>1100.00</td>
    <td>41.0930 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>334.130</td>
    <td>334.139</td>
    <td>1100.00</td>
    <td>2.88900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>334.284</td>
    <td>334.293</td>
    <td>5700.00</td>
    <td>367.587 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>334.284</td>
    <td>334.220</td>
    <td>5700.00</td>
    <td>2.88900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>334.473</td>
    <td>334.517</td>
    <td>260.000</td>
    <td>61.1750 MARS Basalte</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>334.653</td>
    <td>334.570</td>
    <td>500.000</td>
    <td>476.184 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Zn I</td>
    <td>334.690</td>
    <td>334.570</td>
    <td>150.000</td>
    <td>476.184 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>334.769</td>
    <td>334.761</td>
    <td>330.000</td>
    <td>237.000 MARS ecart-type</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>334.837</td>
    <td>334.885</td>
    <td>16.0000</td>
    <td>123.958 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>335.000</td>
    <td>334.939</td>
    <td>4300.00</td>
    <td>5.23800 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>335.037</td>
    <td>335.032</td>
    <td>12000.0</td>
    <td>46.1030 MARS cibles</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>335.037</td>
    <td>334.939</td>
    <td>12000.0</td>
    <td>5.23800 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>335.560</td>
    <td>335.521</td>
    <td>4100.00</td>
    <td>0.467000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>335.619</td>
    <td>335.830</td>
    <td>400.000</td>
    <td>3.40300 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>336.196</td>
    <td>336.206</td>
    <td>290.000</td>
    <td>3.17300 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>336.218</td>
    <td>336.228</td>
    <td>7200.00</td>
    <td>30.4900 MARS cibles</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>336.218</td>
    <td>336.206</td>
    <td>7200.00</td>
    <td>3.17300 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>337.053</td>
    <td>336.904</td>
    <td>2900.00</td>
    <td>31.5500 MARS Ni</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>337.141</td>
    <td>337.187</td>
    <td>1100.00</td>
    <td>2.46400 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>337.175</td>
    <td>337.261</td>
    <td>120.000</td>
    <td>6.18700 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>337.242</td>
    <td>337.235</td>
    <td>4300.00</td>
    <td>2.46400 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>337.296</td>
    <td>337.261</td>
    <td>400.000</td>
    <td>31.8040 MARS Ni</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>337.318</td>
    <td>337.324</td>
    <td>140.000</td>
    <td>2.46400 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>337.370</td>
    <td>337.380</td>
    <td>5700.00</td>
    <td>11.1840 MARS cibles</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>337.377</td>
    <td>337.324</td>
    <td>5700.00</td>
    <td>2.46400 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>338.108</td>
    <td>338.109</td>
    <td>50.0000</td>
    <td>2.18000 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>338.125</td>
    <td>338.192</td>
    <td>1400.00</td>
    <td>2.46400 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>338.182</td>
    <td>338.465</td>
    <td>240.000</td>
    <td>34.0240 MARS Ni</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>338.473</td>
    <td>338.521</td>
    <td>5700.00</td>
    <td>2.46400 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>338.495</td>
    <td>338.465</td>
    <td>60.0000</td>
    <td>2.62300 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>338.692</td>
    <td>338.670</td>
    <td>1400.00</td>
    <td>133.184 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>338.881</td>
    <td>338.891</td>
    <td>1400.00</td>
    <td>247.429 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>339.555</td>
    <td>339.553</td>
    <td>1100.00</td>
    <td>144.330 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>382.891</td>
    <td>382.929</td>
    <td>590000.</td>
    <td>123.040 MARS Basalte</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>383.339</td>
    <td>383.361</td>
    <td>38.0000</td>
    <td>348.572 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>383.531</td>
    <td>383.554</td>
    <td>590000.</td>
    <td>119.010 MARS Basalte</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>383.938</td>
    <td>383.972</td>
    <td>40.0000</td>
    <td>550.271 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>384.214</td>
    <td>384.227</td>
    <td>457000.</td>
    <td>124.963 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>384.435</td>
    <td>384.404</td>
    <td>120.000</td>
    <td>170.888 MARS ecart-type</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>384.553</td>
    <td>384.595</td>
    <td>380.000</td>
    <td>174.877 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>384.789</td>
    <td>384.834</td>
    <td>80.0000</td>
    <td>180.731 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>385.105</td>
    <td>385.134</td>
    <td>200.000</td>
    <td>25.0790 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>385.148</td>
    <td>385.137</td>
    <td>7.00000</td>
    <td>27.2500 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>385.191</td>
    <td>385.134</td>
    <td>120.000</td>
    <td>25.0790 MARS Fe</td>
  </tr>
  <tr>
    <td>Si II</td>
    <td>385.711</td>
    <td>385.759</td>
    <td>500.000</td>
    <td>97.8160 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>385.747</td>
    <td>385.759</td>
    <td>1.10000e+06</td>
    <td>97.8160 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>385.939</td>
    <td>385.961</td>
    <td>1200.00</td>
    <td>47.9550 MARS Ni</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>386.032</td>
    <td>386.040</td>
    <td>12.0000</td>
    <td>17.4340 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>386.100</td>
    <td>385.095</td>
    <td>10000.0</td>
    <td>99.8960 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>386.662</td>
    <td>386.666</td>
    <td>178000.</td>
    <td>29.4850 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>387.360</td>
    <td>387.369</td>
    <td>250.000</td>
    <td>28.3000 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>387.912</td>
    <td>387.950</td>
    <td>250.000</td>
    <td>42.9530 MARS Fe</td>
  </tr>
</table>
<table>
  <tr>
    <td>Fe I</td>
    <td>387.967</td>
    <td>387.964</td>
    <td>2000.00</td>
    <td>87.6290 MARS cibles</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>388.325</td>
    <td>388.380</td>
    <td>170.000</td>
    <td>30.9810 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>388.738</td>
    <td>387.745</td>
    <td>4000.00</td>
    <td>87.0090 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>388.815</td>
    <td>388.771</td>
    <td>200.000</td>
    <td>38.7160 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>388.961</td>
    <td>388.964</td>
    <td>300.000</td>
    <td>29.9440 MARS Fe</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>389.668</td>
    <td>389.708</td>
    <td>3.00000</td>
    <td>25.1160 MARS Basalte</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>389.676</td>
    <td>389.688</td>
    <td>800.000</td>
    <td>11.3790 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>390.081</td>
    <td>390.073</td>
    <td>1200.00</td>
    <td>16.8240 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>390.165</td>
    <td>390.181</td>
    <td>530.000</td>
    <td>126.093 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>390.165</td>
    <td>390.110</td>
    <td>530.000</td>
    <td>2.20000 MARS titane</td>
  </tr>
  <tr>
    <td>Al II</td>
    <td>390.178</td>
    <td>390.181</td>
    <td>100.000</td>
    <td>126.093 MARS Basalte</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>390.226</td>
    <td>390.206</td>
    <td>140.000</td>
    <td>1925.80 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>390.405</td>
    <td>390.410</td>
    <td>400.000</td>
    <td>40.8570 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>390.589</td>
    <td>390.582</td>
    <td>2600.00</td>
    <td>2.26600 MARS titane</td>
  </tr>
  <tr>
    <td>Si I</td>
    <td>390.663</td>
    <td>390.653</td>
    <td>400.000</td>
    <td>92.2650 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>390.759</td>
    <td>390.842</td>
    <td>250.000</td>
    <td>7.71800 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>391.457</td>
    <td>391.456</td>
    <td>500.000</td>
    <td>93.6750 MARS Basalte</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>391.457</td>
    <td>391.448</td>
    <td>500.000</td>
    <td>2.26600 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>391.943</td>
    <td>391.945</td>
    <td>65.0000</td>
    <td>21.1170 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>392.137</td>
    <td>392.137</td>
    <td>600.000</td>
    <td>17.8910 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>392.253</td>
    <td>392.268</td>
    <td>290.000</td>
    <td>0.0800000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>392.402</td>
    <td>392.424</td>
    <td>1200.00</td>
    <td>21.3240 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>392.564</td>
    <td>392.586</td>
    <td>1100.00</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>392.758</td>
    <td>392.759</td>
    <td>120.000</td>
    <td>37.0370 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>392.903</td>
    <td>392.902</td>
    <td>1200.00</td>
    <td>27.2160 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>393.099</td>
    <td>393.133</td>
    <td>890.000</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>393.141</td>
    <td>393.141</td>
    <td>2000.00</td>
    <td>28.1360 MARS Fe</td>
  </tr>
  <tr>
    <td>Ca II</td>
    <td>393.477</td>
    <td>393.475</td>
    <td>230.000</td>
    <td>2055.65 MARS fluorine</td>
  </tr>
  <tr>
    <td>F I</td>
    <td>393.537</td>
    <td>393.475</td>
    <td>5.00000</td>
    <td>2055.65 MARS fluorine</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>394.478</td>
    <td>394.527</td>
    <td>150.000</td>
    <td>638.925 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>394.512</td>
    <td>394.524</td>
    <td>24.0000</td>
    <td>1719.22 MARS alsi</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>394.890</td>
    <td>394.888</td>
    <td>1100.00</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>394.979</td>
    <td>394.955</td>
    <td>4500.00</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>394.989</td>
    <td>394.952</td>
    <td>60.0000</td>
    <td>16.2260 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>395.228</td>
    <td>395.237</td>
    <td>50.0000</td>
    <td>7.75100 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>395.396</td>
    <td>395.379</td>
    <td>65.0000</td>
    <td>32.4280 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>395.746</td>
    <td>395.730</td>
    <td>4500.00</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>395.757</td>
    <td>395.807</td>
    <td>60.0000</td>
    <td>28.6460 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>395.780</td>
    <td>395.807</td>
    <td>250.000</td>
    <td>28.6460 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>395.933</td>
    <td>395.912</td>
    <td>5200.00</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Al I</td>
    <td>396.264</td>
    <td>396.281</td>
    <td>26.0000</td>
    <td>2529.36 MARS alsi</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>396.397</td>
    <td>396.368</td>
    <td>950.000</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>396.539</td>
    <td>396.577</td>
    <td>950.000</td>
    <td>222.814 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>396.539</td>
    <td>396.504</td>
    <td>950.000</td>
    <td>0.140000 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>396.774</td>
    <td>396.754</td>
    <td>60.0000</td>
    <td>22.0270 MARS Fe</td>
  </tr>
  <tr>
    <td>Ca II</td>
    <td>396.959</td>
    <td>396.948</td>
    <td>220.000</td>
    <td>3839.89 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>397.038</td>
    <td>397.038</td>
    <td>100.000</td>
    <td>139.231 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>397.701</td>
    <td>397.794</td>
    <td>55.0000</td>
    <td>14.6890 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>397.821</td>
    <td>397.794</td>
    <td>65.0000</td>
    <td>14.6890 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>397.887</td>
    <td>397.841</td>
    <td>80.0000</td>
    <td>13.2070 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>398.289</td>
    <td>398.230</td>
    <td>4800.00</td>
    <td>0.701000 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>398.361</td>
    <td>398.324</td>
    <td>570.000</td>
    <td>100.702 MARS Basalte</td>
  </tr>
</table>
<table>
  <tr>
    <td>Mn I</td>
    <td>398.371</td>
    <td>398.360</td>
    <td>130.000</td>
    <td>33.7700</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>398.508</td>
    <td>398.501</td>
    <td>50.0000</td>
    <td>13.0170</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>398.796</td>
    <td>398.784</td>
    <td>190.000</td>
    <td>82.8820</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>398.823</td>
    <td>398.784</td>
    <td>150.000</td>
    <td>82.8820</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>399.089</td>
    <td>399.124</td>
    <td>5700.00</td>
    <td>110.631</td>
    <td>MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>399.089</td>
    <td>399.030</td>
    <td>5700.00</td>
    <td>0.766000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>399.524</td>
    <td>399.395</td>
    <td>60.0000</td>
    <td>6.94500</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>399.852</td>
    <td>399.865</td>
    <td>200.000</td>
    <td>28.3340</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>399.918</td>
    <td>399.865</td>
    <td>40.0000</td>
    <td>28.3340</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>399.977</td>
    <td>400.000</td>
    <td>7800.00</td>
    <td>136.989</td>
    <td>MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>399.977</td>
    <td>399.920</td>
    <td>7800.00</td>
    <td>0.960000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>399.986</td>
    <td>400.000</td>
    <td>430.000</td>
    <td>622.948</td>
    <td>MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>400.637</td>
    <td>400.615</td>
    <td>400.000</td>
    <td>125.929</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>401.085</td>
    <td>401.083</td>
    <td>60.0000</td>
    <td>11.2590</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>401.566</td>
    <td>401.551</td>
    <td>80.0000</td>
    <td>16.1930</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>401.924</td>
    <td>401.925</td>
    <td>1500.00</td>
    <td>418.546</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>402.077</td>
    <td>402.065</td>
    <td>15000.0</td>
    <td>131.867</td>
    <td>MARS Pb</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>402.300</td>
    <td>402.298</td>
    <td>100.000</td>
    <td>14.9200</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>402.377</td>
    <td>402.344</td>
    <td>1250.00</td>
    <td>51.1090</td>
    <td>MARS Cu</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>402.571</td>
    <td>402.563</td>
    <td>1200.00</td>
    <td>1.22200</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>F II</td>
    <td>402.587</td>
    <td>402.578</td>
    <td>240.000</td>
    <td>66.9510</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>F II</td>
    <td>402.615</td>
    <td>402.578</td>
    <td>220.000</td>
    <td>66.9510</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>F II</td>
    <td>402.663</td>
    <td>402.578</td>
    <td>230.000</td>
    <td>66.9510</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>402.758</td>
    <td>402.717</td>
    <td>150.000</td>
    <td>59.1910</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>402.948</td>
    <td>402.936</td>
    <td>40.0000</td>
    <td>189.955</td>
    <td>MARS ecart-type</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>402.989</td>
    <td>402.973</td>
    <td>21.0000</td>
    <td>257.542</td>
    <td>MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>403.190</td>
    <td>403.183</td>
    <td>27000.0</td>
    <td>747.747</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>403.392</td>
    <td>403.429</td>
    <td>19.0000</td>
    <td>185.723</td>
    <td>MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>403.421</td>
    <td>403.416</td>
    <td>19000.0</td>
    <td>737.918</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>403.563</td>
    <td>403.555</td>
    <td>11000.0</td>
    <td>537.491</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>403.687</td>
    <td>403.648</td>
    <td>1500.00</td>
    <td>537.491</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>403.987</td>
    <td>403.927</td>
    <td>55.0000</td>
    <td>35.7250</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>404.178</td>
    <td>404.112</td>
    <td>50.0000</td>
    <td>8.99600</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>404.250</td>
    <td>404.205</td>
    <td>5600.00</td>
    <td>877.563</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>K I</td>
    <td>404.528</td>
    <td>404.484</td>
    <td>18.0000</td>
    <td>89.6820</td>
    <td>MARS K</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>404.627</td>
    <td>404.623</td>
    <td>210.000</td>
    <td>94.0710</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>404.696</td>
    <td>404.714</td>
    <td>4000.00</td>
    <td>331.939</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>K I</td>
    <td>404.835</td>
    <td>404.854</td>
    <td>17.0000</td>
    <td>57.2370</td>
    <td>MARS K</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>404.990</td>
    <td>404.947</td>
    <td>1100.00</td>
    <td>454.181</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>405.014</td>
    <td>404.947</td>
    <td>80.0000</td>
    <td>454.181</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>405.287</td>
    <td>405.317</td>
    <td>55.0000</td>
    <td>51.9100</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>405.361</td>
    <td>405.317</td>
    <td>65.0000</td>
    <td>51.9100</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>405.636</td>
    <td>405.641</td>
    <td>150.000</td>
    <td>664.928</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>405.669</td>
    <td>405.641</td>
    <td>1900.00</td>
    <td>664.928</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>405.895</td>
    <td>405.872</td>
    <td>95000.0</td>
    <td>3517.75</td>
    <td>MARS Pb</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>405.910</td>
    <td>406.011</td>
    <td>210.000</td>
    <td>355.426</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>406.008</td>
    <td>406.011</td>
    <td>1100.00</td>
    <td>355.426</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>406.054</td>
    <td>406.011</td>
    <td>150.000</td>
    <td>355.426</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>406.289</td>
    <td>406.246</td>
    <td>730.000</td>
    <td>106.413</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>406.328</td>
    <td>406.288</td>
    <td>14000.0</td>
    <td>749.429</td>
    <td>MARS Pb</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>406.379</td>
    <td>406.380</td>
    <td>2000.00</td>
    <td>145.924</td>
    <td>MARS Cu</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>406.468</td>
    <td>406.426</td>
    <td>730.000</td>
    <td>246.417</td>
    <td>MARS Mn</td>
  </tr>
</table>
<table>
  <tbody>
    <tr>
      <td>Fe I</td>
      <td>406.474</td>
      <td>406.484</td>
      <td>1500.00</td>
      <td>226.243 MARS cibles</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>406.812</td>
      <td>406.841</td>
      <td>50.0000</td>
      <td>19.0290 MARS Fe</td>
    </tr>
    <tr>
      <td>C III</td>
      <td>406.909</td>
      <td>406.841</td>
      <td>200.000</td>
      <td>11.8360 MARS C</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>406.913</td>
      <td>406.841</td>
      <td>50.0000</td>
      <td>19.0290 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>406.915</td>
      <td>406.887</td>
      <td>80.0000</td>
      <td>11.4140 MARS Mn</td>
    </tr>
    <tr>
      <td>C III</td>
      <td>407.006</td>
      <td>407.163</td>
      <td>250.000</td>
      <td>22.4560 MARS C</td>
    </tr>
    <tr>
      <td>C III</td>
      <td>407.141</td>
      <td>407.163</td>
      <td>250.000</td>
      <td>22.4560 MARS C</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>407.143</td>
      <td>407.117</td>
      <td>290.000</td>
      <td>77.0340 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>407.289</td>
      <td>407.297</td>
      <td>1200.00</td>
      <td>295.711 MARS cibles</td>
    </tr>
    <tr>
      <td>C II</td>
      <td>407.567</td>
      <td>407.669</td>
      <td>250.000</td>
      <td>34.0640 MARS C</td>
    </tr>
    <tr>
      <td>C II</td>
      <td>407.700</td>
      <td>407.669</td>
      <td>350.000</td>
      <td>34.0640 MARS C</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>407.778</td>
      <td>407.761</td>
      <td>40.0000</td>
      <td>24.4730 MARS Fe</td>
    </tr>
    <tr>
      <td>Sr II</td>
      <td>407.886</td>
      <td>407.884</td>
      <td>46000.0</td>
      <td>524.764 MARS cibles</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>408.039</td>
      <td>408.037</td>
      <td>730.000</td>
      <td>641.618 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>408.057</td>
      <td>408.037</td>
      <td>730.000</td>
      <td>641.618 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>408.409</td>
      <td>408.404</td>
      <td>1100.00</td>
      <td>738.949 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>408.478</td>
      <td>408.404</td>
      <td>1100.00</td>
      <td>738.949 MARS Mn</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>409.109</td>
      <td>409.092</td>
      <td>65.0000</td>
      <td>45.9080 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>410.189</td>
      <td>410.189</td>
      <td>40.0000</td>
      <td>16.8180 MARS Fe</td>
    </tr>
    <tr>
      <td>F II</td>
      <td>410.423</td>
      <td>410.417</td>
      <td>190.000</td>
      <td>67.5000 MARS fluorine</td>
    </tr>
    <tr>
      <td>F II</td>
      <td>410.438</td>
      <td>410.417</td>
      <td>170.000</td>
      <td>67.5000 MARS fluorine</td>
    </tr>
    <tr>
      <td>F II</td>
      <td>410.467</td>
      <td>410.417</td>
      <td>200.000</td>
      <td>67.5000 MARS fluorine</td>
    </tr>
    <tr>
      <td>F II</td>
      <td>410.487</td>
      <td>410.417</td>
      <td>180.000</td>
      <td>67.5000 MARS fluorine</td>
    </tr>
    <tr>
      <td>F II</td>
      <td>410.503</td>
      <td>410.417</td>
      <td>170.000</td>
      <td>67.5000 MARS fluorine</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>410.652</td>
      <td>410.600</td>
      <td>55.0000</td>
      <td>63.7480 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>410.865</td>
      <td>410.782</td>
      <td>40.0000</td>
      <td>13.7710 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>411.206</td>
      <td>411.146</td>
      <td>200.000</td>
      <td>87.7010 MARS Mn</td>
    </tr>
    <tr>
      <td>V I</td>
      <td>411.294</td>
      <td>411.295</td>
      <td>8900.00</td>
      <td>359.584 MARS Ti_LANL</td>
    </tr>
    <tr>
      <td>K II</td>
      <td>411.615</td>
      <td>411.556</td>
      <td>6.00000</td>
      <td>53.8800 MARS K</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>411.971</td>
      <td>411.920</td>
      <td>150.000</td>
      <td>63.1040 MARS Fe</td>
    </tr>
    <tr>
      <td>B II</td>
      <td>412.309</td>
      <td>412.317</td>
      <td>1500.00</td>
      <td>5.61900 MARS cibles</td>
    </tr>
    <tr>
      <td>Fe III</td>
      <td>412.318</td>
      <td>412.374</td>
      <td>11.0000</td>
      <td>11.3240 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe III</td>
      <td>412.394</td>
      <td>412.374</td>
      <td>11.0000</td>
      <td>11.3240 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>412.877</td>
      <td>412.827</td>
      <td>40.0000</td>
      <td>7.30500 MARS Fe</td>
    </tr>
    <tr>
      <td>V I</td>
      <td>412.923</td>
      <td>412.900</td>
      <td>3100.00</td>
      <td>330.232 MARS Ti_LANL</td>
    </tr>
    <tr>
      <td>Si II</td>
      <td>412.923</td>
      <td>412.899</td>
      <td>300.000</td>
      <td>224.761 MARS cibles</td>
    </tr>
    <tr>
      <td>Si II</td>
      <td>413.206</td>
      <td>413.199</td>
      <td>500.000</td>
      <td>228.972 MARS cibles</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>413.229</td>
      <td>413.189</td>
      <td>150.000</td>
      <td>106.497 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>413.322</td>
      <td>413.280</td>
      <td>400.000</td>
      <td>174.742 MARS Fe</td>
    </tr>
    <tr>
      <td>Cl II</td>
      <td>413.367</td>
      <td>413.325</td>
      <td>10000.0</td>
      <td>90.2010 MARS Cl</td>
    </tr>
    <tr>
      <td>Li I</td>
      <td>413.372</td>
      <td>413.144</td>
      <td>40.0000</td>
      <td>65.0610 MARS lepidolite</td>
    </tr>
    <tr>
      <td>Li I</td>
      <td>413.379</td>
      <td>413.144</td>
      <td>40.0000</td>
      <td>65.0610 MARS lepidolite</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>413.584</td>
      <td>413.551</td>
      <td>80.0000</td>
      <td>31.7840 MARS Fe</td>
    </tr>
    <tr>
      <td>K II</td>
      <td>413.589</td>
      <td>413.325</td>
      <td>7.00000</td>
      <td>90.2010 MARS K</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>413.621</td>
      <td>413.597</td>
      <td>120.000</td>
      <td>108.777 MARS Mn</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>413.816</td>
      <td>413.823</td>
      <td>40.0000</td>
      <td>9.70100 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>414.223</td>
      <td>414.184</td>
      <td>80.0000</td>
      <td>86.5940 MARS Mn</td>
    </tr>
    <tr>
      <td>S II</td>
      <td>414.342</td>
      <td>414.380</td>
      <td>21.0000</td>
      <td>29.0580 MARS sphalerite</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>414.458</td>
      <td>414.455</td>
      <td>200.000</td>
      <td>303.647 MARS Fe</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>414.503</td>
      <td>414.498</td>
      <td>800.000</td>
      <td>159.629 MARS cibles</td>
    </tr>
    <tr>
      <td>Fe I</td>
      <td>414.504</td>
      <td>414.455</td>
      <td>800.000</td>
      <td>303.647 MARS Fe</td>
    </tr>
    <tr>
      <td>Mn I</td>
      <td>414.870</td>
      <td>414.951</td>
      <td>55.0000</td>
      <td>69.1960 MARS Mn</td>
    </tr>
  </tbody>
</table>
<table>
  <tr>
    <td>Mn I</td>
    <td>414.997</td>
    <td>414.951</td>
    <td>80.0000</td>
    <td>69.1960 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>414.997</td>
    <td>415.028</td>
    <td>80.0000</td>
    <td>154.275 MARS ecart-type</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>415.036</td>
    <td>414.951</td>
    <td>7.00000</td>
    <td>60.4290 MARS K</td>
  </tr>
  <tr>
    <td>Al III</td>
    <td>415.208</td>
    <td>415.221</td>
    <td>12.0000</td>
    <td>85.7530 MARS alsi</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>415.423</td>
    <td>415.420</td>
    <td>23.0000</td>
    <td>29.3820 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>415.507</td>
    <td>415.491</td>
    <td>40.0000</td>
    <td>71.1950 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>415.567</td>
    <td>415.491</td>
    <td>50.0000</td>
    <td>71.1950 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>415.797</td>
    <td>415.850</td>
    <td>60.0000</td>
    <td>38.5730 MARS Fe</td>
  </tr>
  <tr>
    <td>Sr II</td>
    <td>416.297</td>
    <td>416.299</td>
    <td>200.000</td>
    <td>4.20500 MARS celestite</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>416.348</td>
    <td>416.360</td>
    <td>70.0000</td>
    <td>44.4550 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>416.482</td>
    <td>416.483</td>
    <td>70.0000</td>
    <td>706.936 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>416.590</td>
    <td>416.613</td>
    <td>18.0000</td>
    <td>15.8510 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>416.609</td>
    <td>416.613</td>
    <td>9.00000</td>
    <td>15.8510 MARS Fe</td>
  </tr>
  <tr>
    <td>Pb I</td>
    <td>416.921</td>
    <td>416.867</td>
    <td>10000.0</td>
    <td>120.042 MARS Pb</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>417.221</td>
    <td>417.260</td>
    <td>120.000</td>
    <td>4.86000 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>417.308</td>
    <td>417.319</td>
    <td>40.0000</td>
    <td>546.683 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>417.308</td>
    <td>417.260</td>
    <td>40.0000</td>
    <td>4.86000 MARS titane</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>417.518</td>
    <td>417.480</td>
    <td>19.0000</td>
    <td>30.1980 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>417.609</td>
    <td>417.688</td>
    <td>60.0000</td>
    <td>27.3410 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>417.681</td>
    <td>417.688</td>
    <td>50.0000</td>
    <td>27.3410 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>417.778</td>
    <td>417.733</td>
    <td>150.000</td>
    <td>103.329 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>417.877</td>
    <td>417.956</td>
    <td>50.0000</td>
    <td>8.81500 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>418.293</td>
    <td>418.268</td>
    <td>120.000</td>
    <td>69.2830 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>418.607</td>
    <td>418.536</td>
    <td>50.0000</td>
    <td>13.3710 MARS Fe</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>418.742</td>
    <td>418.670</td>
    <td>8.00000</td>
    <td>481.104 MARS K</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>418.822</td>
    <td>418.848</td>
    <td>120.000</td>
    <td>150.691 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>418.897</td>
    <td>418.848</td>
    <td>120.000</td>
    <td>150.691 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>419.117</td>
    <td>419.071</td>
    <td>120.000</td>
    <td>91.9800 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>419.261</td>
    <td>419.249</td>
    <td>80.0000</td>
    <td>69.6800 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>419.651</td>
    <td>419.604</td>
    <td>40.0000</td>
    <td>42.8130 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>419.949</td>
    <td>419.960</td>
    <td>150.000</td>
    <td>204.584 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>420.294</td>
    <td>420.270</td>
    <td>65.0000</td>
    <td>75.7710 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>420.321</td>
    <td>420.270</td>
    <td>300.000</td>
    <td>210.757 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>421.153</td>
    <td>421.112</td>
    <td>80.0000</td>
    <td>39.8600 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>421.294</td>
    <td>421.245</td>
    <td>65.0000</td>
    <td>94.5180 MARS Mn</td>
  </tr>
  <tr>
    <td>Sr II</td>
    <td>421.671</td>
    <td>421.682</td>
    <td>32000.0</td>
    <td>327.919 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>421.737</td>
    <td>421.803</td>
    <td>400.000</td>
    <td>23.5020 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>422.055</td>
    <td>422.040</td>
    <td>100.000</td>
    <td>51.8410 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>422.340</td>
    <td>422.305</td>
    <td>50.0000</td>
    <td>40.0760 MARS Fe</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>422.416</td>
    <td>422.349</td>
    <td>7.00000</td>
    <td>82.1810 MARS K</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>422.686</td>
    <td>422.614</td>
    <td>7.00000</td>
    <td>57.8180 MARS K</td>
  </tr>
  <tr>
    <td>Cl I</td>
    <td>422.761</td>
    <td>422.614</td>
    <td>50.0000</td>
    <td>57.8180 MARS Cl</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>422.792</td>
    <td>422.790</td>
    <td>50.0000</td>
    <td>1379.45 MARS fluorine</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>422.861</td>
    <td>422.834</td>
    <td>200.000</td>
    <td>234.184 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe II</td>
    <td>423.436</td>
    <td>423.450</td>
    <td>11.0000</td>
    <td>109.488 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>423.479</td>
    <td>423.450</td>
    <td>100.000</td>
    <td>109.488 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>423.633</td>
    <td>423.625</td>
    <td>370.000</td>
    <td>1259.34 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>423.648</td>
    <td>423.625</td>
    <td>510.000</td>
    <td>1259.34 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>423.675</td>
    <td>423.669</td>
    <td>13.0000</td>
    <td>213.962 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>423.713</td>
    <td>423.669</td>
    <td>250.000</td>
    <td>213.962 MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>424.000</td>
    <td>424.020</td>
    <td>50.0000</td>
    <td>47.5250 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>424.091</td>
    <td>424.064</td>
    <td>190.000</td>
    <td>185.555 MARS Mn</td>
  </tr>
</table>
<table>
  <tr>
    <td>Pb II</td>
    <td>424.612</td>
    <td>424.634</td>
    <td>20.0000</td>
    <td>2274.83</td>
    <td>MARS Pb</td>
  </tr>
  <tr>
    <td>Mn III</td>
    <td>424.737</td>
    <td>424.853</td>
    <td>100.000</td>
    <td>13.2440</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>424.862</td>
    <td>424.809</td>
    <td>50.0000</td>
    <td>46.6430</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>425.132</td>
    <td>425.159</td>
    <td>200.000</td>
    <td>291.699</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>425.198</td>
    <td>425.159</td>
    <td>300.000</td>
    <td>291.699</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Cr I</td>
    <td>425.555</td>
    <td>425.562</td>
    <td>2000.00</td>
    <td>1.22000</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>425.886</td>
    <td>425.858</td>
    <td>290.000</td>
    <td>245.909</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>426.167</td>
    <td>426.163</td>
    <td>800.000</td>
    <td>524.923</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>426.433</td>
    <td>426.380</td>
    <td>330.000</td>
    <td>0.648000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>426.460</td>
    <td>426.424</td>
    <td>7.00000</td>
    <td>154.450</td>
    <td>MARS K</td>
  </tr>
  <tr>
    <td>Cl I</td>
    <td>426.578</td>
    <td>426.424</td>
    <td>60.0000</td>
    <td>154.450</td>
    <td>MARS Cl</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>426.712</td>
    <td>426.686</td>
    <td>290.000</td>
    <td>349.719</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>C II</td>
    <td>426.820</td>
    <td>426.816</td>
    <td>800.000</td>
    <td>272.355</td>
    <td>MARS C</td>
  </tr>
  <tr>
    <td>C II</td>
    <td>426.846</td>
    <td>426.852</td>
    <td>1000.00</td>
    <td>3.27900</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>427.236</td>
    <td>427.251</td>
    <td>250.000</td>
    <td>691.293</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>427.296</td>
    <td>427.314</td>
    <td>1200.00</td>
    <td>254.822</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>Cr I</td>
    <td>427.600</td>
    <td>427.572</td>
    <td>16000.0</td>
    <td>285.036</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>Cu I</td>
    <td>427.631</td>
    <td>427.642</td>
    <td>950.000</td>
    <td>64.8540</td>
    <td>MARS Cu</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>428.230</td>
    <td>428.205</td>
    <td>270.000</td>
    <td>368.836</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>428.361</td>
    <td>428.335</td>
    <td>1200.00</td>
    <td>60.7980</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>428.422</td>
    <td>428.422</td>
    <td>24.0000</td>
    <td>279.915</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>428.529</td>
    <td>428.552</td>
    <td>65.0000</td>
    <td>76.2370</td>
    <td>MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>428.620</td>
    <td>428.630</td>
    <td>160.000</td>
    <td>0.753000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>428.722</td>
    <td>428.713</td>
    <td>890.000</td>
    <td>0.753000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>428.737</td>
    <td>428.768</td>
    <td>14.0000</td>
    <td>8.52600</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>428.861</td>
    <td>428.880</td>
    <td>840.000</td>
    <td>1.38900</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>429.028</td>
    <td>429.032</td>
    <td>950.000</td>
    <td>5.33000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>429.057</td>
    <td>429.027</td>
    <td>22.0000</td>
    <td>241.265</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>429.144</td>
    <td>429.110</td>
    <td>120.000</td>
    <td>5.33000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>429.215</td>
    <td>429.214</td>
    <td>840.000</td>
    <td>5.33000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>429.267</td>
    <td>429.114</td>
    <td>80.0000</td>
    <td>9.97700</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>429.533</td>
    <td>429.523</td>
    <td>140.000</td>
    <td>455.709</td>
    <td>MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>429.697</td>
    <td>429.670</td>
    <td>840.000</td>
    <td>5.33000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>429.987</td>
    <td>429.988</td>
    <td>2000.00</td>
    <td>5.33000</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>430.020</td>
    <td>430.020</td>
    <td>22.0000</td>
    <td>250.365</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>F II</td>
    <td>430.037</td>
    <td>430.020</td>
    <td>200.000</td>
    <td>250.365</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>430.044</td>
    <td>430.020</td>
    <td>250.000</td>
    <td>191.510</td>
    <td>MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>430.044</td>
    <td>430.060</td>
    <td>200.000</td>
    <td>9.97800</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>430.085</td>
    <td>430.060</td>
    <td>200.000</td>
    <td>9.97800</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>430.177</td>
    <td>430.171</td>
    <td>2900.00</td>
    <td>9.97800</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>430.230</td>
    <td>430.262</td>
    <td>4100.00</td>
    <td>9.97800</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>430.374</td>
    <td>430.369</td>
    <td>25.0000</td>
    <td>318.780</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>Ca III</td>
    <td>430.402</td>
    <td>430.364</td>
    <td>20.0000</td>
    <td>588.191</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>430.621</td>
    <td>430.622</td>
    <td>7.00000</td>
    <td>161.914</td>
    <td>MARS K</td>
  </tr>
  <tr>
    <td>Sr II</td>
    <td>430.666</td>
    <td>430.708</td>
    <td>340.000</td>
    <td>7.40700</td>
    <td>MARS celestite</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>430.713</td>
    <td>430.660</td>
    <td>6000.00</td>
    <td>3.02800</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>430.742</td>
    <td>430.706</td>
    <td>170.000</td>
    <td>1683.35</td>
    <td>MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>430.895</td>
    <td>430.880</td>
    <td>23.0000</td>
    <td>244.050</td>
    <td>MARS fluorine</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>430.911</td>
    <td>430.917</td>
    <td>1200.00</td>
    <td>359.488</td>
    <td>MARS cibles</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>430.911</td>
    <td>430.870</td>
    <td>180.000</td>
    <td>3.31500</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>431.286</td>
    <td>431.340</td>
    <td>40.0000</td>
    <td>3.47500</td>
    <td>MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>431.376</td>
    <td>431.395</td>
    <td>65.0000</td>
    <td>49.9740</td>
    <td>MARS Mn</td>
  </tr>
</table>
<table>
  <tr>
    <td>Ti I</td>
    <td>431.556</td>
    <td>431.550</td>
    <td>85.0000</td>
    <td>4.62500 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>431.601</td>
    <td>431.550</td>
    <td>120.000</td>
    <td>4.62500 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>431.630</td>
    <td>431.609</td>
    <td>150.000</td>
    <td>49.3090 MARS Fe</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>431.986</td>
    <td>431.995</td>
    <td>22.0000</td>
    <td>284.822 MARS fluorine</td>
  </tr>
  <tr>
    <td>Mn II</td>
    <td>432.485</td>
    <td>432.465</td>
    <td>50.0000</td>
    <td>24.9340 MARS Mn</td>
  </tr>
  <tr>
    <td>C III</td>
    <td>432.678</td>
    <td>432.508</td>
    <td>200.000</td>
    <td>12.8960 MARS C</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>432.698</td>
    <td>432.722</td>
    <td>1500.00</td>
    <td>614.552 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>433.914</td>
    <td>433.938</td>
    <td>160.000</td>
    <td>403.394 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Zr I</td>
    <td>434.911</td>
    <td>435.001</td>
    <td>1000.00</td>
    <td>5.81500 MARS cibles</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>435.313</td>
    <td>435.062</td>
    <td>20.0000</td>
    <td>20.6700 MARS olivine</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>435.319</td>
    <td>435.105</td>
    <td>500.000</td>
    <td>36.2740 MARS Cu</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>435.396</td>
    <td>435.359</td>
    <td>80.0000</td>
    <td>34.5810 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>435.402</td>
    <td>435.401</td>
    <td>1000.00</td>
    <td>29.9920 MARS Cu</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>435.646</td>
    <td>435.824</td>
    <td>500.000</td>
    <td>27.0840 MARS Cu</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>436.660</td>
    <td>436.711</td>
    <td>400.000</td>
    <td>21.8730 MARS Cu</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>436.927</td>
    <td>436.889</td>
    <td>150.000</td>
    <td>804.718 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>436.927</td>
    <td>436.889</td>
    <td>150.000</td>
    <td>154.969 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>437.100</td>
    <td>437.133</td>
    <td>80.0000</td>
    <td>26.4220 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>437.207</td>
    <td>437.133</td>
    <td>500.000</td>
    <td>24.3070 MARS Cu</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>437.466</td>
    <td>437.469</td>
    <td>500.000</td>
    <td>23.2060 MARS Cu</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>437.618</td>
    <td>437.637</td>
    <td>45.0000</td>
    <td>55.3730 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>437.716</td>
    <td>437.722</td>
    <td>800.000</td>
    <td>8.65800 MARS Fe</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>437.834</td>
    <td>437.974</td>
    <td>1000.00</td>
    <td>46.1780 MARS Cu</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>438.047</td>
    <td>438.044</td>
    <td>12000.0</td>
    <td>374.749 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>438.047</td>
    <td>438.044</td>
    <td>12000.0</td>
    <td>82.6580 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Mg I</td>
    <td>438.161</td>
    <td>438.184</td>
    <td>6.00000</td>
    <td>21.5370 MARS olivine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>438.293</td>
    <td>438.393</td>
    <td>45.0000</td>
    <td>98.6360 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>438.478</td>
    <td>438.497</td>
    <td>3000.00</td>
    <td>433.668 MARS cibles</td>
  </tr>
  <tr>
    <td>Cu III</td>
    <td>438.765</td>
    <td>438.980</td>
    <td>200.000</td>
    <td>26.5870 MARS Cu</td>
  </tr>
  <tr>
    <td>Pb II</td>
    <td>438.769</td>
    <td>438.812</td>
    <td>20.0000</td>
    <td>2023.76 MARS Pb</td>
  </tr>
  <tr>
    <td>K II</td>
    <td>438.939</td>
    <td>438.938</td>
    <td>7.00000</td>
    <td>78.3630 MARS K</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>439.515</td>
    <td>439.560</td>
    <td>170.000</td>
    <td>9.83900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>439.627</td>
    <td>439.647</td>
    <td>330.000</td>
    <td>901.787 MARS ecart-type</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>439.646</td>
    <td>439.647</td>
    <td>3600.00</td>
    <td>4424.69 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>439.646</td>
    <td>439.647</td>
    <td>3600.00</td>
    <td>901.787 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>440.101</td>
    <td>440.060</td>
    <td>60.0000</td>
    <td>2.21800 MARS titane</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>440.278</td>
    <td>440.316</td>
    <td>110.000</td>
    <td>242.336 MARS Ni</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>440.597</td>
    <td>440.560</td>
    <td>12.0000</td>
    <td>48.3710 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>440.599</td>
    <td>440.629</td>
    <td>1200.00</td>
    <td>208.096 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>441.312</td>
    <td>441.356</td>
    <td>55.0000</td>
    <td>112.875 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>441.612</td>
    <td>441.619</td>
    <td>350.000</td>
    <td>4.87200 MARS cibles</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>441.636</td>
    <td>441.688</td>
    <td>300.000</td>
    <td>175.574 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>441.852</td>
    <td>441.840</td>
    <td>220.000</td>
    <td>3.02500 MARS titane</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>441.896</td>
    <td>441.893</td>
    <td>60.0000</td>
    <td>258.136 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>441.896</td>
    <td>441.840</td>
    <td>60.0000</td>
    <td>3.02500 MARS titane</td>
  </tr>
  <tr>
    <td>Fe III</td>
    <td>442.084</td>
    <td>442.144</td>
    <td>12.0000</td>
    <td>17.5830 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>442.102</td>
    <td>442.144</td>
    <td>55.0000</td>
    <td>96.6180 MARS Mn</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>442.668</td>
    <td>442.672</td>
    <td>25.0000</td>
    <td>233.212 MARS fluorine</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>442.834</td>
    <td>442.780</td>
    <td>890.000</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>442.854</td>
    <td>442.889</td>
    <td>600.000</td>
    <td>14.3970 MARS Fe</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>442.855</td>
    <td>442.827</td>
    <td>120.000</td>
    <td>555.097 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>F III</td>
    <td>442.859</td>
    <td>442.724</td>
    <td>120.000</td>
    <td>233.212 MARS fluorine</td>
  </tr>
</table>
<table>
  <tr>
    <td>Fe III</td>
    <td>443.226</td>
    <td>443.261</td>
    <td>9.00000</td>
    <td>6.20700 MARS Fe</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>443.620</td>
    <td>443.673</td>
    <td>26.0000</td>
    <td>471.583 MARS fluorine</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>443.621</td>
    <td>443.637</td>
    <td>26.0000</td>
    <td>264.176 MARS cibles</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>443.692</td>
    <td>443.673</td>
    <td>25.0000</td>
    <td>471.583 MARS fluorine</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>443.694</td>
    <td>443.673</td>
    <td>25.0000</td>
    <td>471.583 MARS fluorine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>443.760</td>
    <td>443.796</td>
    <td>210.000</td>
    <td>324.016 MARS Mn</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>444.546</td>
    <td>444.526</td>
    <td>640.000</td>
    <td>3065.55 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Cu II</td>
    <td>444.608</td>
    <td>444.537</td>
    <td>100.000</td>
    <td>9.64800 MARS Cu</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>445.040</td>
    <td>445.068</td>
    <td>840.000</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>445.196</td>
    <td>445.200</td>
    <td>11.0000</td>
    <td>32.1800 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>445.215</td>
    <td>445.230</td>
    <td>550.000</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.284</td>
    <td>445.312</td>
    <td>800.000</td>
    <td>3.17200 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.425</td>
    <td>445.357</td>
    <td>160.000</td>
    <td>855.718 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>445.457</td>
    <td>445.463</td>
    <td>840.000</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>445.496</td>
    <td>445.464</td>
    <td>290.000</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>445.603</td>
    <td>445.612</td>
    <td>30.0000</td>
    <td>383.171 MARS cibles</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.626</td>
    <td>445.726</td>
    <td>130.000</td>
    <td>737.652 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.657</td>
    <td>445.726</td>
    <td>160.000</td>
    <td>737.652 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>445.658</td>
    <td>445.660</td>
    <td>950.000</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.707</td>
    <td>445.726</td>
    <td>110.000</td>
    <td>737.652 MARS Mn</td>
  </tr>
  <tr>
    <td>Ca I</td>
    <td>445.714</td>
    <td>445.685</td>
    <td>28.0000</td>
    <td>603.055 MARS fluorine</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.829</td>
    <td>445.971</td>
    <td>55.0000</td>
    <td>1015.83 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>445.868</td>
    <td>445.888</td>
    <td>1100.00</td>
    <td>1.10900 MARS titane</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>445.873</td>
    <td>445.893</td>
    <td>410.000</td>
    <td>750.607 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.880</td>
    <td>445.971</td>
    <td>210.000</td>
    <td>1015.83 MARS Mn</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>445.901</td>
    <td>445.893</td>
    <td>120.000</td>
    <td>750.607 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>445.951</td>
    <td>445.971</td>
    <td>270.000</td>
    <td>1015.83 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>446.029</td>
    <td>446.094</td>
    <td>85.0000</td>
    <td>100.103 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>446.163</td>
    <td>445.971</td>
    <td>55.0000</td>
    <td>1015.83 MARS Mn</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>446.233</td>
    <td>446.380</td>
    <td>150.000</td>
    <td>1360.61 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>446.290</td>
    <td>446.380</td>
    <td>400.000</td>
    <td>20.7400 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>446.327</td>
    <td>446.380</td>
    <td>510.000</td>
    <td>1360.61 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>446.371</td>
    <td>446.461</td>
    <td>18.0000</td>
    <td>29.4530 MARS Ni</td>
  </tr>
  <tr>
    <td>S II</td>
    <td>446.568</td>
    <td>446.540</td>
    <td>19.0000</td>
    <td>32.7530 MARS sphalerite</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>446.593</td>
    <td>446.665</td>
    <td>290.000</td>
    <td>447.840 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>446.780</td>
    <td>446.869</td>
    <td>120.000</td>
    <td>41.4740 MARS Fe</td>
  </tr>
  <tr>
    <td>Ti II</td>
    <td>446.975</td>
    <td>447.015</td>
    <td>240.000</td>
    <td>651.254 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>447.139</td>
    <td>447.195</td>
    <td>200.000</td>
    <td>168.025 MARS Mn</td>
  </tr>
  <tr>
    <td>Ni I</td>
    <td>447.173</td>
    <td>447.236</td>
    <td>55.0000</td>
    <td>59.6710 MARS Ni</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>447.405</td>
    <td>447.480</td>
    <td>130.000</td>
    <td>103.077 MARS Mn</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>447.727</td>
    <td>447.805</td>
    <td>80.0000</td>
    <td>35.0130 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>448.066</td>
    <td>448.130</td>
    <td>40.0000</td>
    <td>101.264 MARS Mn</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>448.185</td>
    <td>448.190</td>
    <td>50.0000</td>
    <td>0.886000 MARS titane</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>448.238</td>
    <td>448.228</td>
    <td>14.0000</td>
    <td>786.985 MARS cibles</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>448.239</td>
    <td>448.333</td>
    <td>14.0000</td>
    <td>379.627 MARS olivine</td>
  </tr>
  <tr>
    <td>Mg II</td>
    <td>448.258</td>
    <td>448.333</td>
    <td>13.0000</td>
    <td>379.627 MARS olivine</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>448.343</td>
    <td>448.333</td>
    <td>80.0000</td>
    <td>379.627 MARS olivine</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>448.351</td>
    <td>448.333</td>
    <td>200.000</td>
    <td>379.627 MARS olivine</td>
  </tr>
  <tr>
    <td>V I</td>
    <td>449.015</td>
    <td>448.967</td>
    <td>380.000</td>
    <td>975.348 MARS Ti_LANL</td>
  </tr>
  <tr>
    <td>Ti I</td>
    <td>449.035</td>
    <td>449.007</td>
    <td>260.000</td>
    <td>213.795 MARS ecart-type</td>
  </tr>
  <tr>
    <td>Fe I</td>
    <td>449.100</td>
    <td>448.900</td>
    <td>50.0000</td>
    <td>14.7560 MARS Fe</td>
  </tr>
  <tr>
    <td>Mn I</td>
    <td>449.134</td>
    <td>449.223</td>
    <td>170.000</td>
    <td>133.804 MARS Mn</td>
  </tr>
</table>