# A journey towards the forbidden zone: a new, cold, UHP unit in the Dora-Maira Massif (Western Alps)

Paola Manzotti, Federica Schiavi, Francesco Nosenzo, Pavel Pitra, Michel Ballèvre

► To cite this version:

Paola Manzotti, Federica Schiavi, Francesco Nosenzo, Pavel Pitra, Michel Ballèvre. A journey towards the forbidden zone: a new, cold, UHP unit in the Dora-Maira Massif (Western Alps). Contributions to Mineralogy and Petrology, 2022, 177 (6), pp.59. 10.1007/s00410-022-01923-8. insu-03695671

HAL Id: insu-03695671

https://insu.hal.science/insu-03695671

Submitted on 15 Jun 2022

HAL is a multi-disciplinary open access
archive for the deposit and dissemination of sci-
entific research documents, whether they are pub-
lished or not. The documents may come from
teaching and research institutions in France or
abroad, or from public or private research centers.

L'archive ouverte pluridisciplinaire HAL, est
destinée au dépôt et à la diffusion de documents
scientifiques de niveau recherche, publiés ou non,
émanant des établissements d'enseignement et de
recherche français ou étrangers, des laboratoires
publics ou privés.

<figure><img src="image_1.png" /></figure>

Distributed under a Creative Commons Attribution 4.0 International License
# A journey towards the forbidden zone: a new, cold, *UHP* unit in the Dora-Maira Massif (Western Alps)

Paola Manzotti<fnref n="1" />* · Federica Schiavi<fnref n="2" /> · Francesco Nosenzo<fnref n="1" /> · Pavel Pitra<fnref n="3" />,<fnref n="4" /> · Michel Ballèvre<fnref n="3" />

Received: 11 February 2022 / Accepted: 16 May 2022

© The Author(s) 2022

## Abstract

The distribution of ultrahigh-pressure metamorphism (*UHP*) at the scale of a mountain belt is of prime importance for deciphering its past subduction history. In the Western Alps, coesite has been recognized in the southern Dora-Maira Massif, in the lens-shaped Brossasco-Isasca Unit, but has not been found up to now in the other parts of the massif. We report the discovery of a new *UHP* unit in the northern Dora-Maira Massif (Western Alps), named Chasteiran Unit. It is only a few tens of metres thick and consists of graphite-rich, garnet-chloritoid micaschists, whose protoliths may be black shales of Silurian age. Garnet inclusions (chloritoid, rutile) and its growth zoning allow to precisely model the *P-T* evolution. Coesite crystals, which are pristine or partially transformed to palisade quartz occur as inclusions in the garnet outer cores. According to thermodynamic modelling, garnet displays a continuous record of growth during the prograde increase in *P* and *T* (25–27 kbar 470–500 °C) (stage 1), up to the coesite stability field (27–28 kbar 510–530 °C) (stage 2), as well as sub-isothermal decompression of about 10 kbar (down to 15 kbar 500–515 °C) (stage 3). The main regional, composite, foliation, marked by chloritoid and rutile, began to develop during this stage, and was then overprinted by chlorite-ilmenite (stage 4). The Chasteiran Unit is discontinuously exposed in the immediate hangingwall of the Pinerolo Unit, and it is located far away from, and without physical links to the classic *UHP* Brossasco-Isasca Unit. Moreover, it records a different, much colder, *P-T* evolution, showing that different slices were detached from the downgoing subduction slab. The Chasteiran Unit is the fourth and the coldest Alpine *UHP* unit known so far in the entire Alpine belt. Its *P-T* conditions are comparable to the ones of the Tian Shan coesite-chloritoid-bearing rocks.

**Keywords** Coesite · Ultra-high pressure · Continental subduction · Dora-Maira · Alps

## Introduction

Since the first discovery in the Italian Alps (Chopin 1984) and in the Norwegian Caledonides (Smith 1984), coesite is considered as the iconic mineral for ultrahigh-pressure (*UHP*) metamorphism. It is now known from many localities worldwide (Coleman and Wang 1995; Carswell and Compagnoni 2003; Chopin 2003; Gilotti 2013). Coesite-bearing metamorphic rocks represent deeply subducted oceanic and continental rocks, which occur in two main types of domains (Kylander-Clark et al. 2012). Large domains, typified by the Norwegian Caledonides (e.g., Wain 1997) and the Dabie Shan (e.g., Rolfo et al. 2004), display coesite-bearing rocks occurring over hundreds to thousands of square kilometres. Small domains, such as the Brossasco-Isasca Unit in the Dora-Maira Massif and the Cignana Unit in the Alps, show *UHP* rocks on a much smaller scale, of the order of a square kilometre (e.g., Compagnoni and Rolfo, 2003). This

Communicated by Hans Keppler.

<figure><img src="image_2.png" /></figure>

Paola Manzotti
paola.manzotti@geo.su.se

<footnote n="1">¹ Department of Geological Sciences, Stockholm University, 106 91 Stockholm, Sweden</footnote>

<footnote n="2">² Université Clermont Auvergne, CNRS, IRD, OPGC, Laboratoire Magmas et Volcans, 63000 Clermont-Ferrand, France</footnote>

<footnote n="3">³ Univ Rennes, CNRS, Géosciences Rennes-UMR 6118, 35000 Rennes, France</footnote>

<footnote n="4">⁴ Česká geologická služba (Czech Geol. Survey), 118 21 Prague 1, Czech Republic</footnote>
<figure><img src="image_3.png" /><figcaption>Tectonic map</figcaption></figure>

<figure><img src="image_4.png" /><figcaption>Metamorphic map</figcaption></figure>

Helvetic Domain

Subbriançonnais / Flysch

Briançonnais Domain

Dora-Maira Massif

Mesozoic sediments

Carboniferous sediments & dioritic/granitic orthogneisses (Pinerolo - Sanfront)

Polycyclic basement + Permian intrusives (Brossasco-Isasca BI, Rocca Solei RS, Dronero D)

Piemonte-Liguria Ocean

Adriatic Domain

Late Cretaceous - Palaeocene
80-60 Ma

Eclogite facies (Sesia Zone)

Early Eocene
60-55 Ma

Blueschist facies (Queyras)

Eclogite facies (Lanzo)

Middle Eocene
50-45 Ma

Eclogite facies (Viso)

Late Eocene
40-35 Ma

law-ab facies

law-gl blueschist facies

g blueschist facies

q eclogite facies

coe-ky eclogite facies (BI)

coe-ctd eclogite facies (Chasteiran)

<figure><img src="image_5.png" /></figure>
►Fig.1 Simplified tectonic (a) and metamorphic (b) maps of the SW Alps (modified after Ballèvre et al. 2020). Colour coding refers to both metamorphic facies and ages. The red star indicates the location of the studied sample. PF penninic front

difference has implications for the potential exhumation mechanism of *UHP* rocks, and reveals that in some cases only a very small fraction of the subducted material went back to the surface. While exploring the structure and the history of the Dora-Maira Massif, focussing on its much less well-known northern part (Manzotti et al. 2016; Nosenzo et al. 2022), we discovered a new outcrop of coesite-bearing rocks that deserves a special attention for two main reasons. First, it is located far away from, and without physical links to the classic Brossasco-Isasca Unit. Second, the newly discovered *UHP* rocks indicate much lower *P*–*T* conditions (characterised by the association of coesite with almandine-rich garnet and Fe-rich chloritoid) than the Brossasco-Isasca rocks (where the stability field of chloritoid was largely exceeded during coesite stability). This paper is, therefore, devoted to a detailed description of these rocks, to properly characterize their *P*–*T* evolution and discuss the new constraint that they yield on the extent of the *UHP* units in the Western Alps.

## The Dora-Maira Massif in the Western Alps

The Dora-Maira, Gran Paradiso, and Monte Rosa Massifs in the Western Alps constitute the Internal Crystalline Massifs and belong to the distal part of the Briançonnais palaeomargin (Schmid et al. 2004; Handy et al. 2010; Ballèvre et al. 2020; Michard et al. 2022; Manzotti and Ballèvre 2022). They are made of slices of Palaeozoic basement and minor remnants of dismembered Mesozoic covers. The Dora-Maira Massif extends from the Susa valley in the north to the Maira valley in the south, over a length of ~70 km. The internal geometry of the southern Dora-Maira Massif is relatively well known (Fig. 1a): several tectonic units have been identified on the basis of lithological, structural and petrological data and they are separated by thrust sheets and slivers of Mesozoic meta-sediments and ophiolites (e.g., Chopin 1984; Chopin et al. 1991; Kienast et al. 1991; Compagnoni et al. 1995; Michard et al. 1995; Chopin and Schertl 1999; Compagnoni and Hirajima 2001; Rubatto and Hermann 2001; Compagnoni and Rolfo 2003 and refs therein; Compagnoni et al. 2012; Groppo et al. 2019; Bonnet et al. 2022; Michard et al. 2022). The Alpine metamorphism reached by these units varies from garnet blueschist (Dronero Unit), to quartz eclogite (Rocca Solei) to coesite eclogite facies (Brossasco-Isasca) conditions (Fig. 1b). For the lowermost unit of the nappe stack (i.e., Sanfront Unit), Alpine peak *P*–*T* conditions have been estimated at 14–16 kbar 400–500 °C

(Avigad et al. 2003) or 20–23 kbar 500–515 °C (Groppo et al. 2019).

By contrast, very few studies have focused on the northern Dora-Maira Massif and little is known so far about its internal architecture and metamorphic evolution. There, the Pinerolo Unit is the structurally deepest unit of the Massif and comprises Upper Carboniferous graphite-rich meta-sediments intruded by Permian granites and diorites (Bussy and Cadoppi 1996; Manzotti et al. 2016). No *P*–*T* estimates have been done in this unit, although it is generally considered that it belongs to the upper blueschist facies (defined by chloritoid–phengite ± garnet assemblage in meta-sediments and glaucophane–epidote–garnet assemblage in mafic rocks, Bousquet et al. 2012).

In the northern Dora-Maira Massif, a single tectonic unit has been identified on top of the Pinerolo Unit (Borghi et al. 1996; Sandrone et al. 1993) and has been named the Muret Unit (Nosenzo et al. 2022). It mainly consists of polycyclic rocks (garnet micaschist intruded by an Ordovician granitoid, minor metabasite and marble) (Sandrone et al. 1993; Bussy and Cadoppi 1996; Cadoppi et al. 2016; Nosenzo et al. 2022). In this unit, Variscan Barrovian *P*–*T* conditions (6–7 kbar ~ 650 °C at 324 ± 6 Ma) have been recently characterised in a km-scale low strain domain (Nosenzo et al. 2022). A few bodies of Permian granitoids (e.g., Sangone monzogranite, Bussy and Cadoppi 1996) occur in the Muret unit. An Alpine mineral assemblage indicative of eclogite-facies conditions (garnet, omphacite, rutile) has been described (Borghi et al. 1985; Pognante and Sandrone 1989; Borghi and Sandrone 1990) and peak *P*–*T* conditions of 9–14 kbar ~500 °C have been estimated (Pognante and Sandrone 1989). According to Sandrone and Borghi (1992) and Borghi et al. (1996), the decompressional path of the Internal Crystalline Massifs was characterised by a first retrograde stage associated with moderate cooling at *P*–*T* conditions lower than the garnet stability field. This stage was followed by a re-heating (at 500–550 °C, on the basis of garnet–biotite geothermometer) at *P*<5 kbar (on the basis of garnet–plagioclase–biotite–quartz geobarometer), resulting in the growth of a second generation of garnet, oligoclase rim around albite, calcic amphibole and replacement of chlorite by biotite in metapelites.

## Methods

### Textural observations, petrography, mineral and bulk-rock chemistry

Thin sections were studied with the optical microscope and backscattered electron (BSE) images. Chemical mapping of all garnet crystals including coesite (three porphyroblasts in two thin sections) as well as point analyses of all minerals
<figure><img src="image_6.png" /></figure>

<figure><img src="image_7.png" /></figure>

### Piemonte-Liguria Ocean

Dismembered ophiolites, minor meta-sediments (Orsiera-Raccias and Rocciavré Units, eclogite-facies)

Meta-sediments, minor ophiolites (Quyeras Unit, blueschist-facies)

### Dora-Maira Massif (?)

#### Fenestrelle Unit (HP)

Undifferentiated polycyclic basement and dismembered Mesozoic cover

### Dora-Maira Massif

#### Serre Unit (HP)

Dolomite, marble, calcschist, ankerite-micaschist (Mesozoic)
Felsic gneiss (Permian?)

#### Muret Unit (HP)

Polycyclic basement (micaschist, marble and garnet-blueschist)
Granitic orthogneiss (undated)
Granitic orthogneiss (Ordovician)

#### Chasteiran Unit (UHP)

Graphite-rich, garnet-chloritoid micaschist

#### Pinerolo Unit (HP)

Dioritic orthogneiss (Permian)
Granitic orthogneiss (Permian)
Graphitic meta-conglomerate and meta-sandstone (Upper Carboniferous)

present were performed using an electron microprobe. Details on the operating conditions are given in Table S1 (Supporting Information). Inclusions in garnet have been

carefully examined using Raman spectroscopy for phase identification in all thin sections (see paragraph ‘Raman spectroscopy of inclusions in garnet’ in the Supporting
◄ **Fig. 2** a Tectonic map of the northern Dora-Maira Massif in the Chisone and Germanasca valleys. The Chasteiran Unit (in yellow) is discontinuously exposed above the contact with the Pinerolo Unit. The geological map results from original fieldwork at 1:10,000 scale using the topographic base of the Carta Tecnica Regionale (CTR map) of the Piemonte region, Italy (coordinate system WGS84, UTM, zone 32 N) and by the integration of published geological maps (Mattirolo et al. 1913; Mattirolo et al. 1951 [reprinted]; Vialon 1966; Borghi et al. 1984; Cadoppi et al. 2002; Piana et al. 2017). Field data were digitized and projected on a digital topographic base (DTM of Piemonte region, http://webgis.arpa.piemonte.it). b W–E cross sections displaying the internal geometry of the northern Dora-Maira Massif and its structural relations with the overlying Piemonte–Liguria oceanic units. For sake of clarity, the Serre Unit is depicted with only one colour

Information for details on the method). Mineral abbreviations are those used by THERMOCALC (Holland and Powell 1998, Table S2, Supporting Information) along with a list of other symbols used in this study. Muscovite is used hereafter for all potassic white micas, whatever the Si content. Representative analyses of selected minerals are given in Tables S3, S4, and S5 (Supporting Information).

The bulk composition of sample CH11 (Table S6, Supporting Information) used for phase diagram calculations was determined by ICP-OES (CRPG, Nancy). A bulk-rock glass was prepared by mixing appropriate proportions (1:5) of fine-grained rock powder with di-lithium tetraborate. Details about the method used for the analyses are available in Carignan et al. (2001).

## Thermodynamic modelling

$P-T$ pseudosections were calculated in the chemical system MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (MnNCKFMASHTO). Given the pelitic character of the studied sample, the amount of Fe³⁺ was set to 5% of total Fe [X(Fe³⁺)=Fe³⁺/Feₜotal], an arbitrary low value, considered appropriate for pelites (see Manzotti et al. 2018). The fluid phase was fixed as pure H₂O. Phase diagrams were calculated with the Theriak/Domino software (de Capitani and Brown 1987; de Capitani and Petrakakis 2010), using the internally consistent thermodynamic data set 6.2 (Holland and Powell 2011) and the suitable mixing models for solid solutions (converted for Theriak/Domino by D. K. Tinkham, http://dtinkham.net/peq.html). The phases considered in the calculations and the activity-composition models are given in Table S7 (Supporting Information).

Raman spectroscopy on carbonaceous material (RSCM, Beyssac et al. 2002) was applied to estimate the maximum $T$ registered by the studied sample (details on the method are given in the paragraph ‘Raman spectroscopy on carbonaceous material (RSCM) method’ in the Supporting Information). Raman spectroscopy on quartz inclusions in garnet was performed to estimate the entrapment pressure of these

inclusions (using the calibration and the method described in Mazzucchelli et al. 2021). These two methods allow an estimation of $T$ and $P$, respectively, which are independent from the equilibrium thermodynamics approach used by Theriak/Domino.

## The Chasteiran Unit in the northern Dora-Maira Massif

In the northern part of the Dora-Maira Massif, west of Torino (Fig. 2), the Chisone and Germanasca valleys carve deeply into the nappe stack. From top to bottom, the main tectonic units exposed in these valleys are:

* A blueschist-facies unit (Queyras Unit), part of the Piemonte–Liguria Ocean and essentially made of meta-sediments with subordinate dismembered ophiolitic bodies.

* Eclogite-facies units (Orsiera-Raccias and Rocciavré Units) derived from the Piemonte–Liguria Ocean and made of dismembered ophiolites (serpentinised peridotites, meta-gabbros and meta-basalts and minor meta-sediments).

* A polycyclic basement associated with a dismembered Mesozoic cover (Fenestrelle Unit) possibly part of the Dora-Maira Massif (Carraro et al. 2002).

* Felsic gneisses and associated volcano-sedimentary successions considered to be Permian in age, and remnants of a dismembered Mesozoic cover (mainly dolomites and marbles with minor calcschists and ankerite micaschists), discontinuously exposed at the contact with the oceanic units derived from the Piemonte–Liguria Ocean. These lithologies are hereafter referred to as the Serre Unit.

* A polycyclic basement unit belonging to the Dora-Maira Massif (Muret Unit). This unit consists of polycyclic micaschists, marbles and minor meta-basites, with an Ordovician orthogneiss. Relicts of pre-Alpine metamorphic assemblages (a first generation of garnet, staurolite, ilmenite) have been used to constrain its pre-Alpine history, culminating at 6 kbar, 650 °C, and dated at ~325 Ma (Nosenzo et al. 2022). In the micaschist, the Alpine metamorphism is recorded by the development of a second generation of garnet + chloritoid + Si-rich muscovite + rutile ± glaucophane.

* The Pinerolo Unit, the deepest structural unit of this part of the Dora-Maira Massif, is essentially made of Upper Carboniferous graphitic meta-conglomerates and meta-sandstones (Manzotti et al. 2016), intruded by Permian dioritic and granitic orthogneisses (Bussy and Cadoppi 1996).

Our detailed field mapping, aimed at characterising the contact between the Pinerolo Unit and the overlying Muret
Unit, has revealed the existence, at the contact between the two units, of a thin (10 to 50 m thick) layer of garnet-chloritoid micaschists (hereafter referred to as *Chasteiran Unit*, Fig. 2). The Chasteiran Unit is discontinuously exposed along the contact with the Pinerolo Unit, from the town of Villaretto in the Chisone Valley to the crest Truc Lausa in the Germanasca valley. The micaschist has a peculiar appearance, due to the numerous, strongly flattened, blackish lenses essentially consisting of chloritoid and metamorphosed carbonaceous material (hereafter called graphite), alternating with whitish, quartz- and mica-rich lenses. Garnet is dispersed in the rock as idioblastic or sub-idioblastic grains 1 to 5 mm in diameter. The main composite foliation, which wraps around garnet porphyroblasts, is parallel to the contact between the Pinerolo and Muret Units. We collected a large number of samples from all units (a total of 250 samples). One sample (CH11) collected close to the Chasteiran church attracted our attention, because, in thin section, there were radiating cracks around quartz polycrystalline inclusions in garnet, a potential indication of the former presence of coesite (e.g., Chopin, 1984; Boyer

et al., 1985). Consequently, we have done many thin sections in this sample (Tab. S8 in the Supporting Information) and indeed we were able to positively identify coesite in two of them. Therefore, the present study aims to characterize the petrological evolution of the Chasteiran Unit, whereas following papers will detail its field relations, geometry, and geochronology (work in progress).

## Petrography and mineral chemistry

Sample CH11 (from the type locality of the unit, namely, Chasteiran, Lat/Long coordinates 44° 59' 21.75" N–7° 06' 29.03" E; Figs. S1, S2) is dark grey in colour and consists of muscovite (20–30%), quartz (15–20%), chloritoid (15–20%), garnet (5–10%), chlorite (5–10%), paragonite (5–10%), graphite (5–10%), as well as minor rutile, ilmenite, epidote, albite and, importantly, coesite. Accessory tourmaline also occurs (Fig. 3).

The main composite foliation is defined by the alternation of mm-thick layers of either muscovite + graphite or chloritoid + graphite, which are parallel to elongated quartz

<table><caption>**Fig. 3** Deformation/mineral growth relationships for sample CH11. Grey lines indicate pseudomorphed minerals. Question marks refer to phases that may have been present according to the phase diagram modelling, but for which no petrographic evidence has been found</caption><thead><tr><th></th><th>STAGE 1</th><th>STAGE 2</th><th>STAGE 3</th><th>STAGE 4</th></tr></thead><tbody><tr><td><strong>Mineral</strong></td><td><em>g inner core</em></td><td><em>g outer core</em></td><td><em>g rim / foliation</em></td><td><em>pseudomorphs, overgrowths on foliation</em></td></tr><tr><td><strong>q</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>coe</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>mu</strong></td><td><em>Si</em> 3.49–3.50 a.p.f.u.</td><td><em>Si</em> 3.40–3.45 a.p.f.u.</td><td><em>Si</em> 3.30–3.37 a.p.f.u.</td><td></td></tr><tr><td><strong>g</strong></td><td><em>alm</em><sub>75-78</sub> <em>spss</em><sub>12.9</sub> <em>py</em><sub>6.7</sub> <em>grs</em><sub>5.6</sub></td><td><em>alm</em><sub>79-80</sub> <em>spss</em><sub>8.3</sub> <em>py</em><sub>7.9</sub> <em>grs</em><sub>5.9</sub></td><td><em>alm</em><sub>80-67</sub> <em>spss</em><sub>3.1</sub> <em>py</em><sub>9.3</sub> <em>grs</em><sub>9</sub> →30 →22</td><td></td></tr><tr><td><strong>ctd</strong></td><td><em>X</em><sub>Mg</sub> 0.14–0.15</td><td><em>X</em><sub>Mg</sub> 0.16–0.18</td><td><em>X</em><sub>Mg</sub> 0.16–0.18</td><td><em>X</em><sub>Mg</sub> 0.09–0.12</td></tr><tr><td><strong>chl</strong></td><td></td><td></td><td></td><td><em>X</em><sub>Mg</sub> 0.31–0.34</td></tr><tr><td><strong>law</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>ep</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>jd</strong></td><td>?</td><td>?</td><td></td><td></td></tr><tr><td><strong>gl</strong></td><td>?</td><td></td><td></td><td></td></tr><tr><td><strong>pa</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>ab</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>ru</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>ilm</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>tur</strong></td><td></td><td></td><td></td><td></td></tr><tr><td><strong>gph</strong></td><td></td><td></td><td></td><td></td></tr></tbody></table>
lenses (Figs. S2, S3, S4). Within the layers, muscovite, chloritoid, rutile, and ilmenite/rutile display a strong shape preferred orientation. Muscovite marking the main foliation shows chemical zoning (Fig. S5), with decreasing Si content and $X_{Mg}$ and increasing $X_{Na}$ from core (Si = 3.40–3.45 a.p.f.u., locally up to 3.50 a.p.f.u.; $X_{Na}$ = 0.01–0.04; and $X_{Mg}$ = 0.67–0.72) to rim (Si = 3.30–3.37 a.p.f.u.; $X_{Na}$ = 0.04–0.05; and $X_{Mg}$ = 0.52–0.60). Chloritoid aligned along the main foliation is zoned (Fig. S6) with a magnesium-rich core ($X_{Mg}$ = 0.16–0.18) and more iron-rich rim ($X_{Mg}$ = 0.09–0.12). Chloritoid cores contain inclusions of rutile, whereas chloritoid rims are in contact with ilmenite.

Idioblastic porphyroblasts (up to 5 mm in size) of garnet are found in high-Si muscovite layers (Fig. 4) and they are wrapped by the matrix foliation. Garnet crystals are optically zoned and display large (up to 4.5 mm-thick) colourless cores and thin (up to 500 µm-thick) light pink rims. Inclusions are mainly concentrated in garnet inner cores, whereas they are less abundant in garnet outer cores and rims (Figs. 4, 5a). Garnet inner cores contain monocrystalline inclusions of chloritoid ($X_{Mg}$ = 0.14–0.15, Figs. S6 and S7a), rutile, quartz, and tourmaline, and polymineralic aggregates of paragonite ($X_{Na}$ = 0.90–0.98) + minor epidote ($Fe^{3+}$/$[Al^{3+} + Fe^{3+}] = 0.07–0.08$) ± muscovite (Si = 3.28–3.37

<figure><img src="image_8.png" /><figcaption>**Fig. 4** Photomicrographs (plane-polarised light) for sample CH11. **a** Fractured garnet porphyroblast wrapped by the matrix foliation. Numerous inclusions of chloritoid, quartz, and rutile occur in the inner core, whereas garnet outer core displays only a few inclusions of coesite (red arrow) and rutile. Inclusions are almost absent in garnet rim, with the exception of a few rutile crystals. **b** Close-up of the coesite inclusion (partially transformed to quartz) enclosed in garnet, shown in (a). Note the radial fractures around the inclusion in the host garnet and the higher relief of coesite with respect to quartz. **c** Garnet porphyroblast with a coesite inclusion in the outer core (red</figcaption></figure>

arrow right) and a polycrystalline aggregate of quartz surrounded by radial cracks (red arrow left). Garnet is partially replaced by chlorite at the rim. The matrix foliation is marked by chloritoid and high-Si muscovite and wraps around garnet. **d** Enlargement of the coesite included in garnet outer core. A tiny (~ 10 µm in size) coesite inclusion is surrounded by a narrow quartz rim (see also Fig. S2 in the Supporting Information). Radial cracks developed in the host garnet around a coesite inclusion (~ 30 µm in size) that is completely transformed to quartz
<figure><img src="image_9.png" /><figcaption>**Fig. 5** a Photomicrograph (plane-polarised light) of a garnet porphyroblast displaying rutile inclusions in the core and rim. The red arrow indicates a coesite inclusion. b Enlargement (reflected light) of</figcaption></figure>

the tiny (~10 µm in size) pristine coesite inclusion in garnet with no radial cracks c, d X-ray maps of Ca and Mn

a.p.f.u.; $X_{Na}=0.04–0.06$; and $X_{Mg}=0.47–0.55$; Figs. S5 and S7b). These aggregates may be interpreted as pseudomorphs after lawsonite, as reported in other high-pressure metapelite from the Dora-Maira Massif (e.g., Groppo et al. 2019). Garnet outer cores contain inclusions of coesite (Figs. 6, S8 see below), polycrystalline aggregates of quartz, and rare monomineralic inclusions of chloritoid ($X_{Mg}=0.16–0.18$, Fig. S6) graphite, and rutile (Figs. 4, 5). A few polymineralic inclusions consisting of paragonite ($X_{Na}=0.90–0.98$) + minor epidote ($Fe^{3+}/[Al^{3+} + Fe^{3+}] = 0.12–0.15$) are also observed in this domain. Rare monomineralic inclusions of rutile, quartz, tourmaline, and epidote occur in garnet rims (Figs. 5a, S7c).

Garnet cores display growth zoning (Figs. 5c, d, 7, 8, 9), with a decrease in spessartine (from 12 to 3 mol%) compensated by an increase in almandine (from 75 to 80 mol%), pyrope (from 6 to 9 mol%) and grossular (from 5 to 9 mol%). Despite the similarity of the absolute values, however,

pyrope and grossular zoning display subtle, but significant differences. The grossular content remains approximately constant over the inner core and most of the outer core (~5–6 mol%) and increases significantly at the outermost core. On the other hand, the increase of the proportion of pyrope is continuous from the centre of the core to the edge of the outer core.

Garnet rim shows an abrupt decrease in almandine (from 80 to 67 mol%) and spessartine (from 3 to 1 mol%). Grossular strongly increases (from 9 to 29–30 mol%) and then slightly decreases (from 29–30 to 22 mol%). Pyrope mostly decreases (from 9 to 3 mol%). However, locally a slight increase is observed in the outermost rim (Fig. 9, right rim of profile G–H). X-ray mapping shows that in this domain Ca locally displays patchy zoning (Fig. 5c).

The garnet chemical composition close to the coesite inclusions (measured in the three

<figure><img src="image_10.png" /></figure>
<figure><img src="image_11.png" /><figcaption>**Fig. 6** **a** Raman map showing the distribution of coesite (light blue), quartz (in black), garnet (in orange), and chlorite (in green). Coesite is included in the garnet porphyroblast shown in Fig. 4a, b. **b** From top to bottom: Raman spectra of coesite (main peak at ~521 cm⁻¹) and quartz (main peak at 464–469 cm⁻¹) hosted in garnet (main peak at ~915 cm⁻¹) outer core. Spectra are offset for clarity</figcaption></figure>

garnet porphyroblasts, where coesite has been identified) is alm<sub>80–81</sub>-prp<sub>7</sub>-grs<sub>6</sub>-spss<sub>6</sub> (Tab. S3 in the Supporting Information) and corresponds to the composition of garnet outer core. It is likely, therefore, that the garnet section shown in Fig. 5 does not pass through the centre (i.e., the inner core) of the crystal. Alternatively, garnet crystals may have nucleated at different stages during the history of the rock.

No optical discontinuity (beyond the colour change) separates garnet outer cores from garnet rims. X-ray mapping shows that the interface between garnet outer cores and rims is regularly shaped with only very rare and small embayments (Figs. 5c, d, 7 and 8). One garnet crystal displays mm-long fractures (up to 200 µm-thick) filled by quartz (Figs. 4a, 7) and dissecting the garnet crystal in several fragments (from 1 to 2 mm in size). X-ray mapping reveals that the walls of the fractures are overgrown by a thin layer of a

new garnet with the composition of garnet rim (Fig. 7). Most garnet crystals display narrow fractures filled by chlorite.

Lozenge-shaped pseudomorphs occur in quartz-rich domains and consist of chlorite + albite + quartz (Fig. S7d). Their shape and replacement minerals suggest that they represent pseudomorphs after sodic amphibole, as reported in other high-pressure Alpine units (e.g., Compagnoni, 1977; Manzotti et al. 2021; Nosenzo et al. 2022). Rare albite porphyroblasts overgrow the foliation. Rutile in the matrix is partially rimmed by ilmenite. Garnet is partially replaced by chlorite ($X_{Mg}$=0.31–0.34 $X_{Mn}$=0.001–0.003) both at the rims and along fractures. Paragonite ($X_{Na}$=0.93–0.95) and chlorite ($X_{Mg}$=0.32–0.33 $X_{Mn}$=0.002) statically overgrow the main foliation.

To sum up, the following mineral assemblages developed during garnet growth (Fig. 3):

garnet inner cores + quartz + muscovite + chloritoid + lawsonite + rutile (stage 1); garnet outer cores + coesite + muscovite + chloritoid + lawsonite + rutile (stage 2); garnet rims + quartz + muscovite + chloritoid ± epidote + glaucophane + rutile (stage 3). Lawsonite and glaucophane were completely replaced by retrograde phases that developed during stage 3 or 4.

## Coesite inclusions in garnet

Coesite occurs either as tiny pristine crystals (~ 10 µm in size) without radial cracks in the garnet host (Fig. 5), or as larger crystals (up to ~ 100 µm in size) partially transformed to palisade quartz (Figs. 4, 6a, S8). Coesite partially transformed to quartz is surrounded by radial cracks that result from the volume increase related to the coesite–quartz transformation (Fig. 4b,d). Micro-Raman investigations on exposed inclusions (Fig. 6) confirm the presence of coesite, which displays the diagnostic Raman spectrum, characterized by more than fifteen vibrational modes (e.g., Hemley 1987; Gillet et al. 1990) with the most intense band at 521 cm⁻¹ (Fig. 6b). Mixed Raman spectra of coesite and quartz were measured in coesite crystals partially transformed to quartz. A tiny coesite inclusion surrounded by a thin (< 3 µm) quartz shell (Figs. 4d and S8a) displays a slight Raman shift of its main coesite band ($ν$=521.7 cm⁻¹, Fig. 6b) indicating that a residual pressure is retained by the coesite inclusion in the garnet. A residual pressure is also recorded by the shift in the main Raman band of quartz measured in this shell around coesite ($ν$=466.8 cm⁻¹; Fig. 6b, Table S12 and Fig. S8 in the Supporting Information). Raman mapping confirms the presence of quartz replacing coesite at the inclusion–host interface, as well as minuscule relict coesite within quartz (Fig. 6a). Quartz observed within coesite may be associated with thin veinlets, as observed in coesite inclusions in garnet from other UHP terranes (e.g., Korsakov et al. 2007).
<figure><img src="image_12.png" /><figcaption>**Fig. 7** X-ray maps of a garnet from sample CH11. Fractures dissect garnet core and are sealed by quartz and by a garnet that has the same composition as the garnet rim. Therefore, fractures are interpreted to have developed before the growth of garnet rim. The interface between garnet core and garnet rim is regular, suggesting no or limited dissolution of garnet core before the growth of garnet rim. The white arrow in the Ca map indicates a coesite relict surrounded by a thin rim consisting of a polycrystalline quartz aggregate (see also Figs. 4 and 6)</figcaption></figure>

## Elastic barometry using quartz inclusions in garnet

We collected 64 Raman spectra on exposed quartz grains included in the cores and rims of 15 garnet crystals (Fig. S8, Tab. S12 in the Supporting Information). Negligible or low residual pressures are retained in a large number of quartz inclusions. The largest residual pressure (highest Raman shift for quartz band is 468.8 cm⁻¹) is provided by a sub-rounded, fracture-free quartz inclusion (<5 µm in size) located in the garnet rim. The entrapment conditions have been calculated from the residual strain measured in this inclusion, following Mazzucchelli et al. (2021). The residual pressure ($P_{\text{inc}}$) obtained using the EoS of the inclusion is $P_{\text{inc}}^{\text{V}} = 5.44 \pm 0.16$ kbar, whereas the residual pressure calculated using the strain through the stiffness tensor is $P_{\text{inc}}^{\text{strain}} = 5.09 \pm 0.09$ kbar. The isomeke calculated from the $P_{\text{inc}}^{\text{V}}$ and $P_{\text{inc}}^{\text{strain}}$ provides a pressure of $P_{\text{trap}} = 14.3 \pm 0.2$ kbar at 520 °C and of $P_{\text{trap}} = 13.7 \pm 0.2$ kbar at 520 °C, respectively (Table S13). Because the analysed inclusion was exposed,

it is likely that a relaxation of residual pressure may have taken place. Therefore, this *P* estimate should be considered as minimum value. Similar residual pressures of max 5 kbar were measured in unexposed coesite grains in the Lago di Cignana Unit in the Western Alps (Taguchi et al. 2021).

## RSCM temperature

RSCM temperatures were estimated on two thin sections (CH11 and CH11-5) cut from sample CH11 (results are given in Table S9 and Fig. S9 in the Supporting Information). Similar *T* (CH11 = 486 ± 19 °C, CH11-5 = 481 ± 15 °C) are estimated in the two thin sections, with an average of 483 ± 17 °C. Graphite yields rather constant *R*² values in the range 0.25–0.40 with the exception of two crystals characterised by higher *R*² values (*R*² = 0.44 in CH11 and *R*² = 0.45 in CH11-5).
<figure><img src="image_13.png" /><figcaption>**Fig. 8** X-ray maps of a garnet from sample CH11. The white arrows in the Ca map indicate coesite and a polycrystalline aggregate of quartz included in garnet. The surface between garnet core and rim</figcaption></figure>

is quite regular, suggesting no or limited dissolution of garnet core before the growth of garnet rim. By contrast, garnet rim is partially dissolved and replaced by chlorite

# Thermodynamic modelling

## *P*–*T* pseudosections

*P*–*T* mineral assemblage diagrams (pseudosections: Hensen 1971) and various key compositional and modal isopleths have been calculated for the studied coesite-bearing garnet–chloritoid micaschist sample (Figs. 10 and 11). The effects of fractionation of the zoned garnet as well as possible H₂O undersaturation have been considered. The results have been compared with the observed mineral assemblages, inclusion suites and chemical zoning of garnet to infer the *P*–*T* path of the sample.

## Garnet cores

Two pseudosections were calculated in the system MnNCKFMASHTO in the *P*–*T* range 15–35 kbar and 400–600 °C. A pure H₂O fluid phase was considered in excess. In the first pseudosection, calculated using the ICP–OES-measured whole-rock bulk composition, comparison of the measured garnet inner core composition (py = 6–7 mol%, grs = 5–6 mol%) and the corresponding isopleths suggests that the garnet inner core crystallised at ~ 470–500 °C ~ 25–27 kbar, in the g-ctd-jd-gl-law-mu-q-ru field, just below the quartz–coesite transition, compatible with the observed mineral assemblage. The occurrence of lawsonite in this field is consistent with the pseudomorphs
<figure><img src="image_14.png" /><figcaption>**Fig. 9** Compositional profiles of garnet for sample CH11. The position of the profiles is reported in Figs. 4 (lines A–B, C–D, E–F) and 5 (G–H)</figcaption></figure>

observed. Calculated garnet and lawsonite modal abundances are less than 1 vol% and 1.5 vol%, respectively (Figs. 10, S10). The modelled content of spessartine is slightly higher than the observations, but decreases then with increasing temperature. The measured Si content in muscovite and $X_{Mg}$ of chloritoid inclusions in the garnet inner core are consistent with the values (Si = 3.45–3.5 a.p.f.u., $X_{Mg}$ = 0.14–0.15, Fig. S11) modelled in the *P*–*T* range inferred from the garnet inner core composition. The observed garnet zoning (continuous increase in pyrope, and decrease in spessartine and a roughly constant content of grossular) suggests subsequent garnet growth along a prograde up-pressure up-temperature *P*–*T* path, subparallel to the grossular isopleths (grey arrow in Fig. 10c), that enters finally the stability field of coesite.

To estimate the conditions corresponding to the growth of the garnet outer core, a second pseudosection was calculated in the same *P*–*T* range considering progressive garnet fractionation and subtracting the composition of garnet inner core from the measured bulk composition. Details on garnet fractionation are given in the Supporting Information. With respect to the first pseudosection,

garnet fractionation results in the displacement of the garnet-in line towards higher temperatures by ~30–40 °C, but the general topology as well as the position of the compositional isopleths are affected only marginally. Whereas the inner part of the outer core is characterised by the grossular content similar to that of the inner core (5–6 mol%), the outer part displays an increase in grossular (~6 → 9 mol%). This is compatible with a *P*–*T* path that first follows the grossular isopleths and reaches maximum pressures in the coesite stability field at about 27–28 kbar 510–530 °C. Subsequently, the increase of the proportion of grossular indicates pressure decrease, while the temperature still slightly increases (allowing further crystallisation of garnet—see the position of the garnet mode isopleths in Fig. 10d). The crystallisation of the edge of the outer core corresponds to *P*–*T* condition of ~25–26 kbar, 540 °C. The Si content of muscovite modelled in this field is of the order 3.40–3.45 a.p.f.u., consistent with the values measured in the studied sample. The measured $X_{Mg}$ of chloritoid inclusions in the garnet outer core ($X_{Mg}$ = 0.16–0.18, Fig. S11) are slightly lower than the values modelled in the *P*–*T* range inferred from the garnet
<figure><img src="image_15.png" /><figcaption>**Fig. 10** H₂O-saturated P–T pseudosections calculated for sample CH11 using the unfractionated bulk-rock composition (Tab. S6) (a) and a composition from which the garnet inner core has been subtracted (b). Some fields are not labelled for the sake of clarity; their assemblages can be deduced from the assemblages in adjacent fields.</figcaption></figure>

The grey circles indicate the P–T conditions for the growth of garnet inner and outer core. The grey arrow is the inferred prograde P–T path. c, d Garnet isopleths and its modal amount calculated for (a) and (b), respectively. Colours for the garnet isopleths correspond to the ones used for the chemical profile in Fig. 9

outer core composition ($X_{Mg}$ = 0.21–0.22). The inferred peak T is within uncertainties (Beyssac et al. 2002, 2019) similar to the one calculated for this sample using the RSCM method (Table S9).

## Garnet rims

Garnet rims are characterised by a significantly higher content of grossular (up to ~30 mol%; see above). Taking into
<figure><img src="image_16.png" /><figcaption>**Fig. 11** *P–T* pseudosections calculated for the sample CH11, considering progressive garnet fractionation. **a** *P–T* pseudosections calculated in the range 15–30 kbar and 400–600 °C, using a fixed amount of H₂O and the bulk-rock composition obtained by garnet core (inner</figcaption></figure>

<figure><img src="image_17.png" /><figcaption>and outer) fractionation. **b** Garnet isopleths and its modal amount. The grey arrow in (a) and (b) is the inferred *P–T* path followed during the growth of garnet rim. Colours for the garnet isopleths correspond to the ones used for the chemical profile in Fig. 9</figcaption></figure>

account the corresponding isopleths in Fig. 10, this implies
growth at significantly lower pressures. Since decompression
may lead to H₂O undersaturation (e.g., Le Bayon et al., 2006;
Pitra et al., 2010; Manzotti et al., 2018), one pseudosection
was calculated in the *P–T* range 15–30 kbar 400–600 °C with
a fixed amount of H₂O. This amount was determined so that
the proportion of the fluid phase in the rock does not exceed
1 vol% (Thompson and Connolly 1990) at peak *T* (inferred
from Fig. 10b). In the pseudosection calculated in the *P–T*
range 15–30 kbar, 400–600 °C the H₂O-saturation limit (blue
line) has a positive slope and goes from 400 °C ~ 24 kbar,
to 450 °C ~ 30 kbar and most of the diagram displays fluid-
present assemblages (Fig. 11a). The trend of the isopleths for
the grossular content in garnet is very sensitive to the presence
of lawsonite (Fig. 11b). Whereas decompression or heating
lead to an increase in grossular when lawsonite is present, they
have the opposite effect in the lawsonite-absent domain. The
trend of the isopleths of garnet mode (slightly positive slope)
also shows that garnet can keep on crystallising upon decom-
pression. The *P–T* path (grey arrow in Figs. 11a,b), inferred
from the zoning of the garnet rim, is characterised by strong
decompression (from ~25 to ~17 kbar) accompanied by slight
cooling (from ~540 to ~500 °C) in the lawsonite-present part
of the diagram. This accounts for the strong increase in gros-
sular and decrease in pyrope while ensuring continuous lim-
ited garnet growth (*P–T* path continuously approaching the 2

vol% garnet mode isopleth). The final decrease in grossular (30→22 mol%), recorded in the outermost garnet rim, points to further decompression, possibly associated with slight heating (~15 °C) in the lawsonite-absent domain, to about 15 kbar, 500 to 515 °C. This is consistent with the final increase of pyrope observed locally in the outermost garnet rim, the sub-isothermal trend of the isopleths of pyrope in the field g-ctd-gl-ta-pa-mu-ru-q, and the negative slope of both grossular and pyrope isopleths in the chlorite-bearing fields (Fig. 11b). Although this temperature increase is quantitatively negligible and well below the uncertainties on the absolute values estimated, it does have an indubitable qualitative significance.

The trend of the isopleths of chloritoid mode (Fig. S12)
indicates that chloritoid is consumed during decompression
along the *P–T* path (grey arrow in Fig. 11a, b), inferred from
the zoning of the garnet rim. The growth of the thin rim in
chloritoid (X<sub>Mg</sub>=0.12–0.09) marking the main foliation is
modelled at ~ 16 kbar and is associated with a decrease in
temperature (Fig. S12).

Discussion

Since 1984, Brossasco-Isasca was the only *UHP* unit
recognized in the Dora-Maira Massif. Its peculiarity
inspired a large number of studies and attracted hundreds
of geologists in the field (up to the woeful point that today nothing is left of some of its most spectacular outcrops). Key distinctive features of the Brossasco-Isasca Unit are (i) the pyrope–kyanite–coesite whiteschists, derived from hydrothermally altered granitoids (Ferrando et al. 2009; Gauthiez-Putallaz et al. 2016), (ii) garnet–kyanite–jadeite assemblages in metapelites, with rare relicts of a pre-Alpine garnet, (iii) *UHP* assemblages in mafic boudins and interbedded marbles in the metapelites, and (iv) the scarcity of *UHP* relicts in the granitic orthogneisses (Compagnoni and Rolfo 2003 and refs therein).

Thirty-eight years after the identification of the Bro-
ssasco-Isasca Unit (Chopin 1984), we have discovered
a new, colder UHP unit, the Chasteiran Unit, in the less
explored northern Dora-Maira Massif (Fig. 2). Pending
further exploration, we adopted the name Chasteiran Unit
for the distinctive garnet–chloritoid layer characterized
by its structural position in the immediate hangingwall of
the Pinerolo Unit, and by the occurrence—at least in one
locality, namely, the Chasteiran church—of coesite. The
true extent of the UHP metamorphism will be defined in
the future using further petrological studies aimed at dis-
covering other examples of coesite inclusions preserved
in garnet cores, and/or garnet core composition indicative
of UHP conditions, for the appropriate bulk chemistry. In
a few cases, we found strongly foliated augengneisses that
may be part of the Chasteiran Unit, although their exact
relationship with the garnet–chloritoid micaschist needs
further clarification. Given the poor outcrop conditions in
the forest, we have not been able to find an exposed con-
tact between the two lithologies. The age of the protoliths
of the graphite-rich, garnet–chloritoid micaschist from
the Chasteiran Unit is uncertain. The most straightforward
hypothesis is to derive them from the (graptolite-bearing)
black shales so common in the Silurian successions found
throughout the Palaeozoic of Western and Central Europe
(e.g., Kříž et al. 2003; Corradini et al. 2009). This would
be consistent with (i) the much higher amount of graph-
ite in the Chasteiran micaschist, compared to other gar-
net–chloritoid micaschists from the Dora-Maira Massif
and (ii) the lack of interbedded quartzite and/or marble
within the graphite-rich micaschist, suggesting an epi-
sode of anoxic sedimentation during a rather large time
interval. Last, we also envisaged that the protolith of the
distinctive garnet–chloritoid layer may have been depos-
ited in a Carboniferous basin, similar to the Pinerolo Unit,
but this hypothesis faces several difficulties, e.g., the lack
of meta-conglomerates or meta-sandstones. To the best
of our present knowledge, the Chasteiran Unit is only a
few tens of metres thick and consists of graphite-rich,
garnet–chloritoid micaschist.

The garnet record

Garnet is scarce, concentrated in mica-rich domains, and is
optically and chemically zoned. Cores are colourless and
characterised by a prograde growth zoning with a decrease
in spessartine and increase in pyrope. Thermodynamic mod-
elling indicates that garnet inner cores and outer cores crys-
tallised at ~470–500 °C ~25–27 kbar and ~510–530 °C
~27–28 kbar, respectively. Garnet outer cores crystallised
in the coesite stability field as also indicated by pristine as
well as partly pseudomorphed coesite inclusions identified
in this domain.

Garnet rims are light pink in colour and display a decrease
in pyrope and a continuous and significant increase in gros-
sular followed by a slight decrease in this end-member.
Petrographic and microstructural observations indicate no
other optical discontinuity than a colour change between
garnet outer cores and rims, suggesting no or very lim-
ited dissolution and resorption of garnet cores before the
growth of garnet rims. A break in chemical composition at
the interface between garnet outer cores and garnet rims (see
chemical profiles of Fig. 9) is observed and this resembles
those found in multistage garnet associated with two oro-
genic cycles (e.g., Karabinos 1984; Ganne et al. 2003; Gai-
dies et al. 2006; Le Bayon et al. 2006; Feenstra et al 2007;
Sandmann et al 2014; Giuntoli et al. 2018; Cruciani et al.
2021; Klug and Froitzheim 2021; Nosenzo et al. 2022) or in
metamorphic garnet overgrowths on detrital grains (Yardley
et al. 1996; Manzotti and Ballèvre 2013). The chemistry of
garnet core may be marginally compatible with its growth
at low *P* in a biotite–talc–amphibole–ilmenite with plagio-
clase or paragonite assemblage. However, this hypothesis
can be excluded given the presence of chloritoid (not stable
below 14kbar) and rutile inclusions in garnet inner as well
as outer cores (see Fig. S13). The strongest evidence against
the hypothesis of a pre-Alpine garnet core is that coesite
inclusions do occur in the garnet outer cores, not in the rims.
For the latter, thermodynamic modelling indicates that the
*P*–*T* evolution occurred under fluid-present conditions and
that garnet rims crystallised during decompression between
~25–15 kbar ~540–500 °C.

Strain history of the studied sample

Garnet porphyroblasts are excellent recorders of the strain
history with respect to the metamorphic history, and the
studied sample is no exception to this rule. Four metamor-
phic stages have been distinguished (Fig. 3). Stages 1 and
2 occurred during growth of garnet cores, into which the
inclusions do not display a preferential shape orientation. It
is, therefore, difficult to assess the strain history during this
time period. Inclusions in garnet rims (stage 3) occasion-
ally display a preferential orientation, indicating that garnet
overgrew a foliation ($S_1$) during the growth of the garnet rim. This early foliation is also recorded by isoclinal, intrafolial folds observed in the muscovite- and chloritoid-rich layers. The main foliation ($S_2$) is a composite foliation, resulting from the folding and flattening of an earlier fabric ($S_1$, Fig. S4a), defined by the shape preferred orientation of muscovite, chloritoid and rutile, overgrown during stage 4 by a new generation of chloritoid (i.e., the rims with a lower $X_{Mg}$), chlorite (also partly dissolving garnet rims), and ilmenite.

Several observations may help to understand the rheological behaviour of garnet during this multistage history. In one instance, the occurrence of thin and discontinuous domains consisting of garnet rim compositions around dissected garnet fragments indicates that garnet fractures developed after the growth of garnet core (stages 1 and 2) and before the crystallization of garnet rim (stage 3), between 28 and 25 kbar. This texture indicates that some garnet crystals may display brittle deformation in a ductilely deforming matrix during decompression at high pressure. In this case, the timing of garnet fracturation is unambiguously defined because of its relationships with the growth zoning. Other fractures, filled with chlorite, have developed in most garnet grains during stage 4.

With respect to the regional geology, the strain history of the sample would be compatible with a model, where the continental crust does not deform pervasively during the burial stage (stages 1 and 2), and where the foliation initiation took place at the beginning of the exhumation history (stage 3). This may be related to a rigid behaviour of the downgoing slab (with metamorphic reactions proceeding from the quartz into the coesite stability fields), or to a significant strain partitioning, leaving some undeformed pods, such as the famous Brossasco granite (e.g., Biino and Compagnoni 1992; Lenze and Stöckhert 2007). The onset of the ductile deformation would then record the detachment of the Chasteiran Unit from the downgoing slab, and ultimately its emplacement over the Pinerolo Unit. Consequently, the main regional foliation, which is parallel to the main tectonic boundary with the underlying Pinerolo Unit (see Fig. 2), developed during exhumation of the coesite-bearing Chasteiran Unit, most probably during thrusting of the Chasteiran Unit over the Pinerolo Unit. A similar history has been inferred for the *UHP* Brossasco-Isasca Unit (Henry et al. 1993; Avigad et al. 2003).

## Lack of evidence for polycyclic garnets in the Chasteiran Unit

Polycyclic garnets associated with two orogenic cycles are commonly observed in the micaschist of the *HP* Muret Unit (Nosenzo et al. 2022 and refs therein). However, we have not been able to identify multistage garnets in the *UHP* Chasteiran Unit. Garnet-chloritoid micaschist similar to

the one constituting the Chasteiran Unit has been described in other units from the southern Dora-Maira Massif, such as the *UHP* Brossasco-Isasca and the *HP* Rocca-Solei, San Chiaffredo and Ricordone Units (e.g., Henry et al. 1993; Groppo et al. 2019). These units are considered as portions of the pre-Alpine continental crust that experienced Variscan amphibolite-facies metamorphism (e.g., Matsumoto and Hirajima 2000; Compagnoni and Rolfo 2003) as suggested by garnet and staurolite relicts. However, in the Chasteiran Unit staurolite relicts are not observed. Therefore, if the Chasteiran Unit is also a slice of Palaeozoic basement (and thus polycyclic), the absence of multistage garnets may be attributed to a complete rock re-equilibration occurring during the Alpine history or to a heterogeneous distribution of polycyclic garnet inside the unit. Alternatively, a relatively low-grade pre-Alpine metamorphism (at lower *P*–*T* conditions than the garnet-staurolite stability field) may explain the absence of multistage garnets. Such a low-grade pre-Alpine metamorphism characterizes for example the Palaeozoic basement of part of the Vanoise Massif (Briançonnais domain; for a summary and a discussion see Bergomi et al. 2017; Ballèvre et al. 2018). Finally, we cannot a priori exclude on a petrological basis the hypothesis that the Chasteiran Unit is monocyclic and made of Mesozoic sediments. Mesozoic continental sediments in the Alps are by far dominated by meta-limestones and meta-marls, i.e., calcite-bearing schists (e.g., Michard et al. 2022). Calcium-poor or calcium-absent lithologies derived from pelitic schists developed during the anoxic events, mainly of mid-Cretaceous age. These considerations would narrow the temporal range for the deposition of the protolith of the studied meta-sediments, and would require an additional (tectonic?) explanation for the lack of any other Mesozoic sediment. As a whole, this latter hypothesis seems very unlikely.

## Fe-rich chloritoid stability at UHP conditions

A distinctive characteristic of the Chasteiran Unit, compared to the Brossasco-Isasca Unit, is the widespread occurrence of chloritoid in the coesite-bearing micaschist. Field data and thermodynamic modelling show that, in normal pelitic composition (i.e., rather aluminous with $X_{Mg}$ ratios in the range of 0.20–0.50), chloritoid stability field is bounded towards higher *T* by staurolite-producing reactions (at *P* lower than ~ 14 kbar), and by garnet-kyanite producing reactions at *P* higher than ~ 14 kbar (Fig. 12). A narrow subisothermal band (c. 600–650 °C) with garnet-chloritoid-kyanite assemblages separates a low-*T* garnet-chloritoid domain from the high-*T* garnet-kyanite assemblages (e.g., Smye et al. 2010). The question, therefore, arises, in the studied sample, whether chloritoid was stable throughout the metamorphic history, or whether its stability field has been exceeded at peak
**Fig. 12** *P*–*T* diagram displaying the peak *P*–*T* conditions reached by the UHP Chasteiran, Cignana, Brossasco-Isasca, and Pohorje Units. The peak *P*–*T* conditions reached by the HP Gran Paradiso Unit are also reported for comparison. The univariant reactions depicted in this figure have been calculated using THERMOCALC. Selection of *P*–*T* conditions estimated for the different Units are from: (i) Gran Paradiso Unit: M15—Manzotti et al. 2015; (ii) Lago di Cignana Unit: R91—Reinecke 1991, R98—Reinecke 1998, G09—Groppo et al. 2009; (iii) Brossasco-Isasca Unit: K91—Kienast et al. 1991, C95—Compagnoni et al. 1995, RH01—Rubatto and Hermann 2001, H03—Hermann 2003; G19—Groppo et al. 2019; (iv) Dora-Maira Units: G19—Groppo et al. 2019; (v) Monte Rosa: L19—Luisier et al. 2019: V21—Vaughan-Hammon et al. 2021; (vi) Pohorje: V12—Vrabec et al. 2012; J15—Janák et al. 2015. For comparison, we chose to show only the prograde *P*–*T* paths calculated by modeling the garnet growth zonings

<figure><img src="image_18.png" /></figure>

(*UHP*) conditions, in which case chloritoid may result of a retrograde development during decreasing *T* at decreasing *P* and the Chasteiran micaschist could then be a northern equivalent of the Brossasco-Isasca rocks, strongly sheared and retrogressed in the chloritoid stability field. This question is not just a petrological issue, because it has significant tectonic implications.

There are three lines of evidence against such a hypothesis. First, textural observations indicate that chloritoid was present in the studied rock during its entire life cycle (Fig. 3). Chloritoid is found included in garnet inner cores (stage 1, Figs. 3 and 4) as well as outer cores (where coesite is also found, stage 2), and defines the foliation synchronous of the growth of garnet rims (stage 3). Moreover, there is a
systematic change in chemistry of chloritoid with chloritoid associated with stage 1 being less Mg-rich and more Mn-rich than chloritoid stable during stages 2 and 3, consistent with the evolution of garnet composition (Figs. 3, S6 and S14). The same holds for the rims of the matrix chloritoid that grew during stage 4.

Second, thermodynamic modelling of garnet composition predicts its stability in a large part of the *P–T* space, in the chloritoid-bearing as well as chloritoid-absent assemblages. However, a garnet with the observed chemical composition is only stable in chloritoid-bearing assemblages, in agreement with textural observations.

Third, RSCM data (*T* of 483 ± 17 °C) validate the ‘cold’ nature of the Chasteiran *UHP* metamorphism. Given the absolute uncertainties associated with the RSCM method (50 °C or 25 °C, according to Beyssac et al. 2002 and Beyssac et al. 2019, respectively), such values are in agreement with those derived from the pseudosection modelling. These *T* conditions are ~ 200 C° lower than the one experienced by the Brossasco-Isasca Unit (e.g., Chopin et al. 1991; Compagnoni et al. 1995; Beyssac et al. 2002; Coggon and Holland 2002; Compagnoni and Rolfo 2003; Hermann 2003; Castelli et al. 2007; Ferrando et al. 2017; Campomenosi et al. 2021). These higher *T* estimates for the Brossasco-Isasca Unit are consistent with the observation that chloritoid (and staurolite) may have been present during the prograde history of the Brossasco-Isasca micaschists, but the *UHP* equilibration took place outside their stability field, when kyanite was an essential component of the mineral assemblage.

## A new, colder, UHP Unit in the Alpine belt

We are, therefore, quite confident that the Chasteiran Unit equilibrated at *UHP* conditions in the chloritoid stability field and, therefore, represents a distinct, colder, *UHP* unit with respect to the Brossasco-Isasca Unit. It is, in fact, the coldest reported *UHP* unit in the Alpine belt (Fig. 12), given the *P–T* values estimated for the Pohorje Mountains (Vrabeč et al. 2012; Janák et al. 2015), and the Lago di Cignana (Reinecke 1991, 1998; Groppo et al. 2009). The latter may have been equilibrated close to the upper boundary of the chloritoid stability field. Outside the Alpine belt, chloritoid-bearing *UHP* rocks are extremely rare (see compilations in Coleman and Wang 1995; Carswell and Compagnoni 2003; Gilotti 2013). The presence of chloritoid-bearing *UHP* rocks in the Western Alps has been, however, suspected following the discovery of a Roman quern-stone made of a garnet–chloritoid talcschist, with relict coesite observed as inclusions in garnet (Groppo et al. 2016). Our discovery does not provide an answer about the location of the rock used as a primary material for the quern-stone, because this lithology is very different from the ones constituting the Chasteiran Unit. A survey of the worldwide occurrences of

coesite-bearing rocks indicates that, other than the occurrence described here, the only coesite- and chloritoid-bearing rocks are found in the Tian Shan in Kirghizistan (Tagiri and Bakirov 1990; Orozbaev et al. 2015) and neighbouring Xinjiang (Zhang et al. 2003; Lü et al. 2008, 2009, 2014).

## Conclusions and perspectives

This study leads to the following conclusions:

1. We identified a new *UHP* unit, named Chasteiran Unit, in the northern Dora-Maira Massif. It is only a few tens of metres thick and discontinuously exposed above the contact with the lower grade Pinerolo Unit. The Chasteiran Unit is the fourth and the coldest Alpine *UHP* unit known so far in the entire Alpine belt.

2. Pristine and relict coesite occur in garnet outer cores together with chloritoid inclusions suggesting that the Chasteiran Unit equilibrated at *UHP* conditions in the chloritoid stability field. Thermodynamic modelling indicates peak *P–T* conditions at 27–28 kbar, 510–530 °C, consistent within uncertainty with the RSCM estimates. Amongst the other *UHP* terranes known around the world, these conditions are only recorded by some *UHP* rocks found in the Tian Shan.

3. Identification of this new, colder, *UHP* unit has been possible through a systematic, detailed study of minute (at most 20 µm long) coesite inclusions, the largest of which displaying palisade quartz, the smallest being pristine (no partial pseudomorph, no radial cracks). Our discovery shows that some *UHP* rocks may have escaped the attention of the petrologists, and that *UHP* units may be more common in low-temperature rocks (i.e., in garnet–chloritoid bearing assemblages) than previously thought.

4. From a tectonic perspective, the discovery of coesite-bearing rocks in the northern Dora-Maira Massif, in the immediate hangingwall of the Sanfront–Pinerolo Unit, implies that the *UHP* rocks from the southern (Brossasco-Isasaca) and northern (Chasteiran) Dora-Maira Massif occupy the same structural position, unambiguously displaying thrusting of higher over lower *P* rocks. However, the two *UHP* units (Brossasco-Isasca and Chasteiran) record different peak *P–T* conditions (30–40 kbar ~ 700–750 °C and 27–28 kbar 510–530 °C, respectively), indicating that they represent different slices detached from the downgoing slab.

Further investigations are now underway about the Chasteiran Unit, to better characterize its geometry (requiring further mapping in a densely forested area), and to determine the timing and rate of its burial and exhumation. These
data integrated with the tectonic evolution are critical to resolve the debate regarding collisional processes and exhumation mechanisms. Specifically, this will allow us to understand when and how thin tectonic **UHP** units were sliced off, this process being a characteristic of the Alpine belt along its entire length (i.e., from Dora-Maira to Pohorje), in contrast with other belts, where huge and thick **UHP** domains have been exhumed (e.g., Kylander-Clark et al. 2012).

**Supplementary Information** The online version contains supplementary material available at https://doi.org/10.1007/s00410-022-01923-8.

**Acknowledgements** This study was financially supported by a Starting Grant from Stockholm University to Paola Manzotti (Fund 4615701). Jessica Langlade (Micosonde Ouest, Brest, France) and Martin Robyr (University of Lausanne, Switzerland) are thanked for assistance during EPMA data acquisition. Discussions in the field in September 2021 with Stefan Schmid were strongly appreciated. We thank Christian Chopin and Guillaume Bonnet for their detailed constructive reviews. The editorial work of Hans Keppler has been highly appreciated.

**Funding** Open access funding provided by Stockholm University.

**Open Access** This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

## References

Avigad D, Chopin C, Le Bayon R (2003) Thrusting and extension in the southern Dora-Maira ultra-high pressure Massif (Western Alps): view from below the coesite-bearing Unit. J Geol 111:57–70

Ballèvre M, Manzotti P, Dal Piaz GV (2018) Pre-Alpine (Variscan) inheritance: a key for the location of the future Valaisan Basin (Western Alps). Tectonics 37:876–817

Ballèvre M, Camonin A, Manzotti P, Poujol M (2020) A step towards unravelling the paleogeographic attribution of pre-Mesozoic basement complexes in the Western Alps based on U-Pb geochronology of Permian magmatism. Swiss J Geosci 113:12

Bergomi MA, Dal Piaz GV, Malusà MG, Monopoli B, Tunesi A (2017) The Grand St Bernard-Briançonnais nappe system and the Paleozoic inheritance of the Western Alps unraveled by zircon U-Pb dating. Tectonics 36:2950–2972

Beyssac O, Goffé B, Chopin C, Rouzaud JN (2002) Raman spectra of carbonaceous material in metasediments: a new geothermometer. J Metamorph Geol 20:859–871

Beyssac O, Pattison DRM, Bourdelle F (2019) Contrasting degrees of recrystallization of carbonaceous material in the Nelson aureole, British Columbia and Ballachulish aureole, Scotland, with implications for thermometry based on Raman spectroscopy of carbonaceous material. J Metamorph Geol 37:71–95

Biino GG, Compagnoni R (1992) Very-high pressure metamorphism of the Brossasco coronate metagranite, southern Dora Maira Massif, Western Alps. Schweiz Mineral Petrogr Mitt 72:347–363

Bonnet G, Chopin C, Locatelli M, Kylander-Clark ARC, Hacker BR (2022) Protracted subduction of the European hyperextended margin revealed by rutile U-Pb geochronology across the Dora-Maira Massif (Western Alps). Tectonics 41:e202TC007170

Borghi A, Cadoppi P, Porro A, Sacchi R, Sandrone R (1984) Osservazioni geologiche nella Valle Germanasca e nella media Val Chisone (Alpi Cozie). Boll Mus Reg Sci Nat Torino 2:503–530

Borghi A, Cadoppi P, Porro A, Sacchi R (1985) Metamorphism in the north part of the Dora-Maira Massif (Cottian Alps). Boll Mus Reg Sci Nat Torino 3:369–380

Borghi A, Sandrone A (1990) Structural and metamorphic constraints to the evolution of a NW sector of Dora-Maira Massif (Western Alps). Mem Soc Geol It 45:135–141

Borghi A, Compagnoni R, Sandrone R (1996) Composite P-T paths in the Internal Penninic massifs of the Western Alps: petrological constraints to their thermomechanical evolution. Eclogae Geol Helv 89:345–367

Bousquet R, Oberhänsli R, Schmid SM, Berger A, Wiederkehr M, Robert C, Möller A, Rosenberg C, Zeilinger G, Molli G, Koller F (2012) Metamorphic framework of the Alps. Commission for the geological map of the world; subcommission for magmatic and metamorphic maps. IUGS and IUGG, Paris. http://www.ccgm.org

Boyer H, Smith DC, Chopin C, Lasnier B (1985) Raman microprobe (RMP) determinations of natural and synthetic coesite. Phys Chem Miner 12:45–48

Bussy F, Cadoppi P (1996) U-Pb dating of granitoids from the Dora-Maira massif (western Italian Alps). Schweiz Mineral Petrogr Mitt 76:217–233

Cadoppi P, Castelletto M, Sacchi R, Baggio P, Carraro F, Giraud V, Bellardone G (2002) Carta geologica d'Italia alla scala 1:50.000, Foglio 154 Susa. Geol Surv It

Cadoppi P, Camanni G, Balestro G, Perrone G (2016) Geology of the Fontane talc mineralization (Germanasca valley, Italian Western Alps). J Maps 12:1170–1177

Campomenosi N, Scambelluri M, Angel RJ, Hermann J, Mazzucchelli ML, Mihailova B, Piccoli F, Alvaro M (2021) Using the elastic properties of zircon-garnet host-inclusion pairs for thermobarometry of the ultrahigh-pressure Dora-Maira whitechists: problems and perspectives. Contrib Mineral Petrol 176:36

Carignan J, Hild P, Mevelle G, Morel J, Yeghicheyan D (2001) Routine analyses of trace elements in geological samples using flow injection and low pressure on-line liquid chromatography coupled to ICP-MS: a study of geochemical reference materials, BR, DRN, UB-N, AN-G and GH. Geostandard Newslett 25:187–198

Carraro F, Cadoppi P, Castelletto M, Sacchi R, Baggio P, Giraud V, Bellardone G (2002) Note illustrative della carta geologica d'Italia alla scala 1:50.000, Foglio 154 Susa. Servizio Geologico d'Italia

Carswell DA, Compagnoni R (eds) (2003) Ultrahigh Pressure metamorphism. European Mineralogical Union Notes in Mineralogy, vol 5

Castelli D, Rolfo F, Groppo C, Compagnoni R (2007) Impure marbles from the UHP Brossasco-Isasca Unit (Dora-Maira Massif, Western Alps): evidence for Alpine equilibration in the diamond stability field and evaluation of the X(CO₂) fluid evolution. J Metamorph Geol 25:587–603

Chopin C (1984) Coesite and pure pyrope in high-grade blueschists of the Western Alps: a first record and some consequences. Contrib Mineral Petrol 86:107–118

Chopin C, Schertl H-P (1999) The UHP Unit in the Dora Maira Massif, Western Alps. Int Geol Rev 41:765–780
Chopin C (2003) Ultrahigh-pressure metamorphism: tracing continental crust into the mantle. Earth Planet Sci Lett 212:1–14

Chopin C, Henry C, Michard A (1991) Geology and petrology of the coesite-bearing terrain, Dora Maira massif, Western Alps. Eur J Mineral 3:263–291

Coggon R, Holland TJB (2002) Mixing properties of phengitic micas and revised garnet-phengite thermobarometers. J Metamorph Geol 20:683–696

Coleman RG, Wang X (eds) (1995) Ultrahigh pressure metamorphism. Cambridge University Press, Cambridge, p 528p

Compagnoni R (1977) The Sesia-Lanzo Zone: high pressure-low temperature metamorphism in the Austroalpine continental margin. Rend Soc Ital Min Petrol 33:335–378

Compagnoni R, Hirajima T (2001) Superzoned garnets in the coesite-bearing Brossasco-Isasca Unit, Dora-Maira massif, Western Alps, and the origin of the whiteschist. Lithos 57:219–236

Compagnoni R, Rolfo F (2003) UHPM units in the Western Alps. EMU Notes Mineral 5:13–49

Compagnoni R, Hirajima T, Chopin C (1995) Ultra-high-pressure metamorphic rocks in the Western Alps. In: Coleman RG, Wang X (eds) Ultrahigh pressure metamorphism. Cambridge University Press, Cambridge, pp 206–243

Compagnoni R, Rolfo F, Groppo C, Hirajima TR (2012) Geological map of the ultra-high pressure Brossasco-Isasca unit (Western Alps, Italy). J Maps 8:465–472

Corradini C, Ferretti A, Storch P (2009) The Silurian of Sardinia. Rend Soc Pal It 3:1–167

Cruciani G, Franceschelli M, Massonne H-J, Musumeci G (2021) Evidence of two metamorphic cycles preserved in garnet from felsic granulite in the southern Variscan belt of Corsica. France Lithos 380–381:105919

de Capitani C, Brown TH (1987) The computation of chemical equilibrium in complex systems containing non-ideal solutions. Geo-chim Cosmochim Acta 51:2639–2652

de Capitani C, Petrakakis K (2010) The computation of equilibrium assemblage diagrams with Theriak/Domino software. Amer Miner 95:1006–1016

Feenstra A, Petrakakis K, Rhede D (2007) Variscan relicts in Alpine high-P pelitic rocks from Samos (Greece): evidence from multi-stage garnet and its included minerals. J Metamorph Geol 25:1011–1033

Ferrando S, Frezzotti ML, Petrelli M, Compagnoni R (2009) Metasomatism of continental crust during subduction: the UHP whiteschists from the Southern Dora-Maira Massif (Italian Western Alps). J Metamorph Geol 27:739–756

Ferrando S, Groppo C, Frezzotti ML, Castelli D, Proyer A (2017) Dissolving dolomite in a stable UHP mineral assemblage: evidence from Cal-Dol marbles of the Dora-Maira Massif (Italian Western Alps). Am Mineral 102:42–60

Gaidies F, Abart R, De Capitani C, Schuster R, Connolly AD, Reusser E (2006) Characterization of polymetamorphism in the Austroalpine basement east of the Tauern Window using garnet isopleth thermobarometry. J Metamorph Geol 24:451–475

Ganne J, Bussy F, Vidal O (2003) Multi-stage garnet in the internal Briançonnais basement (Ambin Massif, Savoy): new petrological constraints on the blueschist-facies metamorphism in the Western Alps and tectonic implications. J Petrol 44:1281–1308

Gauthiez-Putallaz L, Rubatto D, Hermann J (2016) Dating prograde fluid pulses during subduction by in situ U-Pb and oxygen isotope analysis. Contrib Mineral Petrol 171:1–20

Gillet P, Le Cléac'h A, Madon M (1990) High-temperature Raman spectroscopy of SiO₂ and GeO₂ polymorphs: anharmonicity and thermodynamic properties at high temperatures. J Geophys Res 95:21635–21655

Gilotti JA (2013) The realm of ultrahigh-pressure metamorphism. Elements 9:255–260

Giuntoli F, Lanari P, Engi M (2018) Deeply subducted continental fragments—part 1: fracturing, dissolution-precipitation, and diffusion processes recorded by garnet textures of the central Sesia Zone (western Italian Alps). Solid Earth 9:167–189

Groppo C, Beltrando M, Compagnoni R (2009) The P-T path of the ultra-high pressure Lago Di Cignana and adjoining high-pressure meta-ophiolitic units: insights into the evolution of the subducting Tethyan slab. J Metamorph Geol 27:207–231

Groppo C, Ferrando S, Castelli D, Elia D, Meirano V, Facchinetti L (2016) A possible new UHP unit in the Western Alps as revealed by ancient Roman quern-stones from Costigliole Saluzzo, Italy. Eur J Mineral 28:1215–1232

Groppo C, Ferrando S, Gilio M, Botta S, Nosenzo F, Balestro G, Festa A, Rolfo F (2019) What's in the sandwich? New P-T constraints for the (U)HP nappe stack of southern Dora-Maira Massif (Western Alps). Eur J Mineral 31:665–683

Handy MR, Schmid SM, Bousquet R, Kissling E, Bernoulli D (2010) Reconciling plate-tectonic reconstructions of Alpine Tethys with the geological-geophysical record of spreading and subduction in the Alps. Earth-Sci Rev 102:121–158

Hemley RJ (1987) Pressure dependence of Raman spectra of SiO₂ polymorphs: α-quartz, coesite, and stishovite. Geophys Monogr Ser 39:347–359

Henry C, Michard A, Chopin C (1993) Geometry and structural evolution of ultra-high-pressure and high-pressure rocks from the Dora-Maira massif, Western Alps, Italy. J Struct Geol 8:965–981

Hensen BJ (1971) Theoretical phase relations involving garnet and cordierite in the system MgO-FeO-Al₂O₃-SiO₂. Contrib Mineral Petrol 33:191–214

Hermann J (2003) Experimental evidence for diamond-facies metamorphism in the Dora-Maira massif. Lithos 70:163–182

Holland TJB, Powell R (1998) An internally consistent thermodynamic data set for phases of petrological interest. J Metamorph Geol 16:309–343

Holland TJB, Powell R (2011) An improved and extended internally consistent thermodynamic dataset for phases of petrological interest, involving a new equation of state for solids. J Metamorph Geol 29:333–383

Janák M, Froitzheim N, Yoshida K, Sasinková V, Nosko M, Kobayashi T, Hirajima T, Vrabec M (2015) Diamond in metasedimentary crustal rocks from Pohorje, Eastern Alps: a window to deep continental subduction. J Metamorph Geol 33:495–512

Karabinos P (1984) Polymetamorphic garnet zoning from southeastern Vermont. Am J Sci 284:1008–1025

Kienast JR, Lombardo B, Biino G, Pinardon JL (1991) Petrology of very-high-pressure eclogitic rocks from the Brossasco-Isasca Complex, Dora-Maira Massif, Italian Western Alps. J Metamorph Geol 9:19–34

Klug L, Froitzheim N (2021) Reuniting the Ötztal Nappe: the tectonic evolution of the Schneeberg Complex. Int J Earth Sci. https://doi.org/10.1007/s00531-021-02127-4

Korsakov AV, Hutsebaut D, Theunissen K, Vandenabeele P, Stepanov AS (2007) Raman mapping of coesite inclusions in garnet from the Kokchetav Massif (Northern Kazakhstan). Spetrochim Acta A 68:1046–1052

Kříž J, Degardin JM, Ferretti A, Hansch W, Gutiérrez Marco JC, Paris F, Piçarra D-Almeida JM, Robardet M, Schönlaub HP, Serpagli E (2003) Silurian stratigraphy and paleogeography of Gondwanan and Perunican Europe. New York State Mus Bull 493:105–178

Kylander-Clark ARC, Hacker BR, Mattinson CG (2012) Size and exhumation rate of ultrahigh-pressure terranes linked to orogenic stage. Earth Planet Sci Lett 321–322:115–120

Le Bayon B, Pitra P, Ballèvre M, Bohn M (2006) Reconstructing P-T paths during continental collision using multi-stage garnet (Gran Paradiso nappe, Western Alps). J Metamorph Geol 24:477–496
Lenze A, Stöckhert B (2007) Microfabrics of UHP metamorphic granites in the Dora Maira Massif, western Alps—no evidence of deformation at great depth. J Metamorph Geol 25:461–475

Luisier C, Baumgartner L, Schmalholz SM, Siron G, Vennemann T (2019) Metamorphic pressure variation in a coherent Alpine nappe challenges lithostatic pressure paradigm. Nat Commun 10:1–11

Lü Z, Zhang L, Du J, Bucher K (2008) Coesite inclusions in garnet from eclogitic rocks in western Tianshan, northwest China: convincing proof of UHP metamorphism. Am Mineral 93:1845–1850

Lü Z, Zhang L, Du J, Bucher K (2009) Petrology of coesite-bearing eclogite from Habutengsu Valley, western Tianshan, NW China and its tectonometamorphic implication. J Metamorph Geol 27:773–787

Lü Z, Zhang LF, Chen ZY (2014) Jadeite- and dolomite-bearing coesite from western Tianshan, NW China. Eur J Mineral 26:245–256

Manzotti P, Ballèvre M (2013) Multistage garnet in high-pressure metasediments: Alpine ovegrowths on Variscan detrital grains. Geology 41:1151–1154

Manzotti P, Pitra P, Langlade M, Ballèvre M (2015) Constraining *P-T* condition during thrusting of a higher pressure unit over a lower pressure one (Gran Paradiso, Western Alps). J Metamorph Geol 33:981–1002

Manzotti P, Ballèvre M, Poujol M (2016) Detrital zircon geochronology in the Dora-Maira and Zone Houillère: a record of sediment travel paths in the Carboniferous. Terra Nova 28:279–288

Manzotti P, Bosse V, Pitra P, Robyr M, Schiavi F, Ballèvre M (2018) Exhumation rates in the Gran Paradiso Massif (Western Alps) constrained by in situ U-Th-Pb dating of accessory phases (monazite, allanite and xenotime). Contrib Mineral Petrol 173:24

Manzotti P, Ballèvre M, Pitra P, Schiavi F (2021) Missing lawsonite and aragonite found: *P-T* and fluid composition in meta-marls from the Combin Zone (Western Alps). Contrib Mineral Petrol 176:60. https://doi.org/10.1007/s00410-021-01818-0

Manzotti P, Ballèvre M (2022) Chapter 8: Continental subduction in the Alps: from field data to kinematic models. In: Bellahsen N (ed) Rosenberg C. Geodynamics of the Alps Wiley, Hoboken

Matsumoto N, Hirajima T (2000) Garnet in pelitic schist from a quartz-eclogite unit of the southern Dora-Maira massif, Western Alps. Schweiz Mineral Petrogr Mitt 80:53–62

Mattirolo E, Novarese V, Franchi S, Stella A (1913) Carta Geologica d'Italia alla scala 1:100.000, Foglio 55 Susa, Geol Surv It

Mattirolo E, Novarese V, Franchi S, Stella A (1951) Carta Geologica d'Italia alla scala 1:100.000, Foglio 67 Pinerolo. Geol Surv It

Mazzucchelli ML, Angel RJ, Alvaro M (2021) EntraPT: an online platform for elastic geothermobarometry. Am Mineral 106:830–837

Michard A, Henry C, Chopin C (1995) Structures in UHPM: a case study from the Alps. In: Coleman RG, Wang X (eds) Ultrahigh pressure metamorphism. Cambridge University Press, Cambridge, pp 132–158

Michard A, Schmid SM, Lahfid A, Ballèvre M, Manzotti P, Chopin C, Iaccarino S, Dana D (2022) The Maira-Sampeyre and Val Grana Allochthons (south Western Alps): review and new data on the tectonometamorphic evolution of the Briançonnais distal margin. Swiss J Geosci 115:19 (in press)

Nosenzo F, Manzotti P, Poujol M, Ballèvre M, Langlade M (2022) A window into an older orogenic cycle: *P-T* conditions and timing of the pre-Alpine history of the Dora-Maira Massif (Western Alps). J Metamorph Geol 40:789–821. https://doi.org/10.1111/jmg.12646

Orozbaev R, Hirajima T, Bakirov A, Takasu A, Maki K, Yoshida K, Sakiev K, Bakirov A, Hirata T, Tagiri M, Togonbaeva A (2015) Trace element characteristics of clinozoisite pseudomorphs after lawsonite in talc-garnet-chloritoid schists from the Makbal UHP Complex, northern Kyrgyz Tian-Shan. Lithos 226:98–115

Piana F, Fioraso G, Irace A, Mosca P, d'Atri A, Barale L, Falletti P, Monegato G, Morelli M, Tallone S, Vigna GB (2017) Geology of Piemonte region (NW Italy, Alps-Apennines interference zone). J Maps 13:395–405

Pitra P, Ballèvre M, Ruffet G (2010) Inverted metamorphic field gradient towards a Variscan suture zone (Champtoceaux Complex, Armorican Massif, France). J Metamorph Geol 28:183–208

Pognante U, Sandrone R (1989) Eclogites in the northern Dora-Maira Nappe (Western Alps, Italy). Min Pet 40:57–71

Reinecke T (1991) Very-high-pressure metamorphism and uplift of coesite-bearing metasediments from the Zermatt-Saas zone, Western Alps. Eur J Mineral 3:7–17

Reinecke T (1998) Prograde high- to ultrahigh-pressure metamorphism and exhumation of oceanic sediments at Lago di Cignana, Zermatt-Saas Zone, western Alps. Lithos 42:147–189

Rolfo F, Compagnoni R, Wu X, Xu S (2004) A coherent lithostratigraphic unit in the coesite-eclogite complex of Dabie Shan, China: geologic and petrologic evidence. Lithos 73:71–94

Rubatto D, Hermann J (2001) Exhumation as fast as subduction? Geology 29:3–6

Sandmann S, Nagel TJ, Herwartz D, Fonseca ROC, Kurzawski RM, Münker C, Froitzheim N (2014) Lu-Hf garnet systematics of a polymetamorphic basement unit: new evidence for coherent exhumation of the Adula Nappe (Central Alps) from eclogite-facies conditions. Contrib Mineral Petrol 168:1075

Sandrone R, Borghi A (1992) Zoned garnets in the northern Dora-Maira Massif and their contribution to a reconstruction of the regional metamorphic evolution. Eur J Mineral 4:465–474

Sandrone R, Cadoppi P, Sacchi R, Vialon P (1993) The Dora-Maira massif. In: Von Raumer JF (ed) Pre-Mesozoic geology in the Alps. Springer, Berlin, pp 317–325

Schmid SM, Fügenschuh B, Kissling E, Schuster R (2004) Tectonic map and overall architecture of the Alpine orogeny. Eclogae Geol Helv 97:93–117

Smye AJ, Greenwood LV, Holland TJB (2010) Garnet-chloritoid-kyanite assemblages: eclogite facies indicators of subduction constraints in orogenic belts. J Metamorph Geol 28:753–768

Smith DC (1984) Coesite in clinopyroxene in the Caledonides and its implications for geodynamics. Nature 310:641–644

Tagiri M, Bakirov A (1990) Quartz pseudomorph after coesite in garnet from a garnet-chloritoid-talc schist, Northern Tien-Shan, Kirghiz SSR. Proc Jpn Assoc Sci 66:135–139

Taguchi T, Kouketsu Y, Igami Y, Kobayashi T, Miyake A (2021) Hidden intact coesite in deeply subducted rocks. Earth Planet Sci Lett 558:116763

Thompson AB, Connolly JAD (1990) Metamorphic fluids and anomalous porosities in the lower crust. Tectonophysics 182:47–55

Vaughan-Hammon JD, Luisier C, Baumgartner LP, Schmalholz SM (2021) Peak Alpine metamorphic conditions from staurolite-bearing metapelites in the Monte Rosa nappe (Central European Alps) and geodynamic implications. J Metamorph Geol 39:897–917

Vialon P (1966) Étude géologique du massif cristallin Dora-Maira, Alpes Cottiennes Internes, Italie. Travaux du Laboratoire de Géologie de la Faculté des Sciences de Grenoble, Mémoires, 4. https://hal.archives-ouvertes.fr/tel-00723197

Vrabec M, Janák M, Froitzheim N, Hoog JCM (2012) Phase relations during peak metamorphism and decompression of the UHP kyanite eclogites, Pohorje Mountains (Eastern Alps, Slovenia). Lithos 144–145:40–55

Wain A (1997) New evidence for coesite in eclogite and gneisses: defining an ultrahigh-pressure province in the Western Gneiss region of Norway. Geology 25:927–930

Yardley BWD, Condliffe E, Lloyd GE, Harris HM (1996) Polyphase garnets from western Ireland: two-phase intergrowths in the grossular-almandine series. Eur J Mineral 8:383–392
Zhang L, Ellis DJ, Arculus RJ, Jiang W, Wei C (2003) 'Forbidden
zone' subduction of sediments to 150 km depth—the reaction of
dolomite + magnesite in the UHPM metapelites from western
Tianshan, China. J Metamorph Geol 21:523–529

**Publisher's Note** Springer Nature remains neutral with regard to
jurisdictional claims in published maps and institutional affiliations.

<figure><img src="image_19.png" /></figure>