# Discovery of a Hot Corino in the Bok Globule B335

Muneaki Imai, Nami Sakai, Yoko Oya, Ana López-Sepulcre, Yoshimasa Watanabe, Cecilia Ceccarelli, Bertrand Lefloch, Emmanuel Caux, Charlotte Vastel, Claudine Kahane, et al.

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Muneaki Imai, Nami Sakai, Yoko Oya, Ana López-Sepulcre, Yoshimasa Watanabe, et al.

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DISCOVERY OF A HOT CORINO IN THE BOK GLOBULE B335

MUNEAKI IMAI<fnref n="1" />, NAMI SAKAI<fnref n="2" />, YOKO OYA<fnref n="1" />, ANA LÓPEZ-SEPULCRE<fnref n="1" />,<fnref n="3" />, YOSHIMASA WATANABE<fnref n="1" />, CECILIA CECCARELLI⁴,<fnref n="5" />,
BERTRAND LEFLOCH⁴,<fnref n="5" />, EMMANUEL CAUX<fnref n="6" />,<fnref n="7" />, CHARLOTTE VASTEL<fnref n="6" />,<fnref n="7" />, CLAUDINE KAHANE⁴,<fnref n="5" />, TAKESHI SAKAI<fnref n="8" />,
TOMOYA HIROTA<fnref n="9" />, YURI AIKAWA<fnref n="10" />, AND SATOSHI YAMAMOTO<fnref n="1" />,<fnref n="11" />

ABSTRACT

We report the first evidence of a hot corino in a Bok globule. This is based on ALMA observations in the 1.2 mm band toward the low-mass Class 0 protostar IRAS 19347+0727 in B335. Saturated complex organic molecules (COMs), CH₃CHO, HCOOCH₃, and NH₂CHO, are detected in a compact region within a few 10 au around the protostar. Additionally, CH₃OCH₃, C₂H₅OH, C₂H₅CN, and CH₃COCH₃ are tentatively detected. Carbon-chain related molecules, CCH and c-C₃H₂, are also found in this source, whose distributions are extended over a scale of a few 100 au. On the other hand, sulfur-bearing molecules CS, SO, and SO₂ have both compact and extended components. Fractional abundances of the COMs relative to H₂ are found to be comparable to those in known hot corino sources. Though the COMs lines are as broad as 5–8 km s⁻<fnref n="1" />, they do not show obvious rotation motion in the present observation. Thus, the COMs mainly exist in a structure whose distribution is much smaller than the synthesized beam (0.⁷⁵⁸ × 0.⁷⁵²).

Key words: ISM: abundances – ISM: individual objects (B335) – ISM: molecules – stars: formation

1. INTRODUCTION

During the last decade it has been established that chemical
compositions of protostellar cores show significant diversity,
even among those in similar evolutionary stages (Class 0/I).
One distinct case is hot corino chemistry, which is character-
ized by the rich existence of saturated complex organic
molecules (COMs: molecules consisting of six or more atoms)
such as HCOOCH₃ and CH₃OCH₃. A prototypical case is
IRAS 16293-2422 in Ophiuchus (e.g., Cazaux et al. 2003;
Bottinelli et al. 2004; Kuan et al. 2004). Another distinct case is
warm-carbon-chain chemistry (WCCC), which is characterized
by abundant unsaturated organic molecules (carbon-chain
molecules and their related species) in a warm and dense
region around a protostar (Sakai et al. 2008, 2009, 2010). A
prototypical source is IRAS 04368+2557 in L1527 in the
Taurus molecular cloud. These two cases have exclusive
chemical compositions: carbon-chain molecules are deficient in
hot corinos, while COMs are deficient in the WCCC sources.
Since the chemical composition can reflect the past evolu-
tionary history of the source, a duration time of a starless core
phase after shielding of the interstellar UV radiation is
proposed as a possible origin of the chemical diversity (Sakai
& Yamamoto 2013). A longer duration time of the starless core
phase tends to result in hot corino chemistry, while a shorter
duration time leads to WCCC. Environmental effects such as a
location in a larger-scale molecular cloud, the influence of
nearby protostellar sources, and the strength of the UV
radiation field (e.g., Watanbe et al. 2012; Lindberg

et al. 2015; Spezzano et al. 2016) may also affect the chemical
composition.

Since the chemical composition of the protostellar cores
could reflect not only current physical conditions but also
evolution histories, exploring the total picture of chemical
diversity is a fundamental issue both for astrochemistry and star
formation studies. However, so far only a few hot corinos and
only a few WCCC sources have been detected definitively, and
hence it is still essential to study chemical compositions of
other protostars to unveil the total picture. In particular, it is
important to study the chemical composition of a protostellar
core in an isolated condition, which is thought to be free from
various environmental effects caused by other protostars.

B335 is an ideal target for this goal. It is a representative Bok globule (Keene et al. 1980) that harbors the Class 0 low-mass protostar IRAS 19347+0727. Its distance and bolometric luminosity are reported to be 100 pc (Olofsson & Olofsson 2009) and 0.72 $L_\odot$ (Evans et al. 2015), respectively. This source is regarded as the best “test-bed” for detailed studies of simple models of star formation (e.g., Hirano et al. 1988, 1992; Chandler & Sargent 1993; Zhou et al. 1993; Wilner et al. 2000; Harvey et al. 2001). Yen et al. (2015) recently conducted an ALMA observation at a resolution of 0.′34 × 0.′28, and reported that the protostar in B335 has no Keplerian disk with a radius of 10 au or larger. Evans et al. (2015) also reported on the basis of their ALMA observations that HCN and HCO⁺ lines show absorption features against continuum, which are well reproduced by the model of inside-out collapse. In addition to these physical studies, its chemical composition at a

<footnote n="1">¹Department of Physics, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan</footnote>

<footnote n="2">²The Institute of Physical and Chemical Research (RIKEN), 2-1, Hirosawa, Wako-shi, Saitama 351-0198, Japan</footnote>

<footnote n="3">³Institut de Radioastronomie Millimétrique (IRAM), 300 rue de la Piscine, F-38406 Saint-Martin-d'Héres, France
⁴Université de Grenoble Alpes, IPAG, F-38000 Grenoble, France</footnote>

<footnote n="5">⁵CNRS, IPAG, F-38000 Grenoble, France</footnote>

<footnote n="6">⁶Université de Toulouse, UPS-OMP, IRAP, Toulouse, France</footnote>

<footnote n="7">⁷CNRS, IRAP, 9 Av. Colonel Roche, BP 44346, F-31028 Toulouse Cedex 4, France</footnote>

<footnote n="8">⁸Department of Communication Engineering and Informatics, Graduate School of Informatics and Engineering,
The University of Electro-Communications, Chofugaoka, Chofu, Tokyo 182-8585, Japan</footnote>

<footnote n="9">⁹National Astronomical Observatory of Japan, Osawa, Mitaka, Tokyo 181-8588, Japan</footnote>

<footnote n="10">¹⁰Center for Computational Science, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan</footnote>

<footnote n="11">¹¹Research Center for the Early universe, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Received 2016 September 16; revised 2016 October 3; accepted 2016 October 3; published 2016 October 20</footnote>
<figure><img src="image_3.png" /><figcaption>**Figure 1.** The continuum map and the moment 0 maps of HCOOCH₃ (20s,16–19s,15), NH₂CHO (12s,12–11s,11), HNCO (12s,12–11s,11), CH₃CHO (14s,14–13s,13 E), HCOOH (12s,12–11s,11), CCH (N = 3–2, J = 5/2–3/2, F = 3–2), CS (5–4), and SO (N<sub>J</sub> = 6<sub>7</sub>–5<sub>6</sub>). The contours represent the continuum flux of 10σ, 20σ, 40σ, 80σ levels, where σ is 0.3 mJy beam⁻¹. Compared with the synthesized beam size shown in the bottom left of each figure, distributions of COMs are not resolved. The velocity range is 5.06–11.67 km s⁻¹ for HCOOCH₃, 5.20–10.22 km s⁻¹ for NH₂CHO, 5.89–10.82 km s⁻¹ for HNCO, 5.03–11.62 km s⁻¹ for CH₃CHO, 2.85–13.66 km s⁻¹ for HCOOH, 7.02–9.46 km s⁻¹ for CCH, 6.28–10.54 km s⁻¹ for CS, and 6.69–9.27 km s⁻¹ for SO.</figcaption></figure>

scale of a few 1000 au has been observed and modeled (Evans et al. 2005), where fundamental molecules such as CO, CN, HCO⁺, HCN, HN, N₂H⁺, and H₂CO were studied. For full understandings of chemical evolution to the protoplanetary disk, the chemical composition in the closest vicinity of the protostar has to be explored. With this in mind, here we report the first chemical characterization of this source at a scale of a few 10 au with ALMA.

## 2. OBSERVATION

We conducted the 1.2 mm (250 GHz) observation (Band 6) of B335 with ALMA (Cycle 2) on 2015 May 18. In total, 37 antennas were used for the observation. The field center is α (J2000) = 19h37m0s93, δ(J2000) = 7°34′9″9. The minimum and maximum baselines are 15 kλ and 444 kλ, respectively. A primary beam size is 23″6, and a synthesized beam size is 0″58 × 0″52 (P.A. = 75°). We used 16 spectral windows whose bandwidth and channel spacing are 58.6 MHz and 61.027 kHz, respectively. The velocity resolution is 0.1404 km s⁻¹. On-source integration time was 34 minutes, which

resulted in an rms noise of 3–7 mJy beam⁻¹. Titan was observed as a flux calibrator. J1955+1358 and J1751+0939 were observed as a phase calibrator and a bandpass calibrator, respectively. Self-calibration was not applied for simplicity. The calibration accuracy is 10%.

We used CASA for the data reduction. A continuum image was prepared by averaging line-free channels. Maps of the spectral line emission were obtained by CLEANing the dirty images (Briggs robust = 0.5) after subtracting the continuum directly from the visibility data.

## 3. RESULTS

### 3.1. Dust Continuum

Figure 1(a) shows the 1.2 mm continuum map. The peak position is determined by the Gaussian fit to be: (α<sub>2000</sub>, δ<sub>2000</sub>) = (19h37m0s90, 7°34′9″62). The continuum emission consists of compact and extended components. A deconvolved size of the compact component of the continuum emission is 0″43 × 0″28, with a position angle of 23 ± 15°. The extended
<figure><img src="image_4.png" /><figcaption>**Figure 2.** Spectrum toward the continuum peak of B335 observed with ALMA.</figcaption></figure>

component has a structure extended along the north-south direction that is perpendicular to the outflow direction (Hirano et al. 1988). The total integrated flux is $92.8 \pm 2.1$ mJy. This result is consistent with the total continuum flux (compact + extended) of $87.5 \pm 2.8$ mJy at 1.3 mm reported by Yen et al. (2015).

## 3.2. Detected Molecules and Their Distribution

Figure 2 shows the 16 spectral windows observed toward the continuum peak position. In this observation, B335 is found to be rich in molecular lines. We assigned 31 spectral lines using the Cologne Database for Molecular Spectroscopy (CDMS; Müller et al. 2005) and Jet Propulsion Laboratory (JPL) (Pickett et al. 1998) databases, assuming a systemic velocity of $8.34 \text{ km s}^{-1}$ (Yen et al. 2015), while five lines were left unidentified. They are summarized in Table 1, as well as the line parameters obtained by the Gaussian fit. The most noteworthy result is the detection of CH$_3CHO$, HCOOCH$_3$, and NH$_2CHO$. Additionally, CH$_3OCH_3$, C$_2H_5OH, C$_2H_5CN$, and CH$_3COCH_3$ are tentatively detected, each of which is identified only by a single faint feature. These saturated COMs are characteristic of hot corinos and hot cores of star-forming regions. This is the first detection of COMs in this source. In addition to saturated COMs, the carbon-chain molecule CCH and the carbon-chain related molecule c-C$_3$H$_2$ are also detected.

Spectral line profiles are different from molecule to molecule, as shown in Figure 2 and Table 1. Based on the FWHM width of the line ($\Delta v$), they are roughly classified into the following three categories:

(1) Broad lines ($\Delta v \gtrsim 5 \text{ km s}^{-1}$): 21 lines of the 11 molecular species, including tentatively detected ones, are classified in this group. They are mostly saturated COMs and related molecules (Table 1). They do not show absorption below the continuum emission level (i.e., the baseline).

(2) Narrow lines ($\Delta v < 1.6 \text{ km s}^{-1}$): CCH and c-C$_3$H$_2$ show the narrow line width with a double-peak structure due to absorption by the foreground gas. Five lines of these two species are classified into this category.

(3) Intermediate lines ($\Delta v \approx 3.0 \text{ km s}^{-1}$): sulfur-bearing molecules such as SO, $ ^{34}\text{SO}$, SO$_2$, $ ^{34}\text{SO}_2$, and CS belong to this category. These species have an intermediate line width between the first and second categories. Five lines of the above five species are classified into this category.

Figures 1(b)–(i) show moment 0 maps of HCOOCH$_3$, NH$_2CHO$, HNCO, CH$_3CHO$, HCOOH, CCH, CS, and SO. Molecular distributions are different among the above three categories. The moment 0 maps of the COM related lines (HCOOCH$_3$, NH$_2CHO$, HNCO, CH$_3CHO$, and HCOOH), which have broad line widths, reveal a compact distribution concentrated around the protostar (Figures 1(b)–(f)). They are not resolved with the synthesized beam of this observation ($0.5'' \times 0.5''$, P.A. = 55°): the deconvolved sizes of the emitting region (FWHM) for HCOOCH$_3$ and NH$_2CHO$
<table><caption>**Table 1**

Detected Molecular Lines</caption><thead><tr><th>Molecule<sup>a</sup></th><th>Transition</th><th>Frequency<sup>b</sup><br>GHz</th><th>E<sub>u</sub><br>cm<sup>-1</sup></th><th>S<sub>μ</sub><sup>2</sup><br>...</th><th>F<sub>integ</sub><br>mJy beam<sup>-1</sup> km s<sup>-1</sup></th><th>I<br>mJy beam<sup>-1</sup></th><th>Δ<sub>V</sub><br>km s<sup>-1</sup></th><th>v<sub>lsr</sub><br>km s<sup>-1</sup></th><th>rms<br>mJy beam<sup>-1</sup> ch<sup>-1</sup></th><th>Type<sup>c</sup></th></tr></thead><tbody><tr><td>CS<sup>d</sup></td><td>5-4</td><td>244.935644</td><td>24.51</td><td>19.1</td><td>1301(4)</td><td>...</td><td>...</td><td>...</td><td>5.39</td><td>I</td></tr><tr><td>SO<sub>2</sub></td><td>10<sub>3,7</sub>-10<sub>2,8</sub></td><td>245.563423</td><td>50.54</td><td>14.5</td><td>228(2)</td><td>61.1(14)</td><td>3.58(9)</td><td>7.77(4)</td><td>3.13</td><td>I</td></tr><tr><td>CH<sub>3</sub>CHO<sup>e</sup></td><td>13<sub>0,13</sub>-12<sub>0,12</sub> E v<sub>t</sub> = 1</td><td>245.583105</td><td>199.84</td><td>163</td><td>39(2)</td><td>8.2(7)</td><td>4.6(5)</td><td>8.59(19)</td><td>3.13</td><td>B</td></tr><tr><td>C<sub>2</sub>H<sub>5</sub>OH?</td><td>14<sub>3,11</sub>-13<sub>3,10</sub></td><td>246.414762</td><td>108.23</td><td>21.3</td><td>30(2)</td><td>5.6(6)</td><td>5.3(7)</td><td>7.8(3)</td><td>3.17</td><td>B</td></tr><tr><td>C<sub>2</sub>H<sub>5</sub>CN?</td><td>28<sub>2,27</sub>-27<sub>2,26</sub></td><td>246.421918</td><td>123.20</td><td>412</td><td>20(3)</td><td>3.5(4)</td><td>8(2)</td><td>7.1(8)</td><td>3.17</td><td>B</td></tr><tr><td>U-line</td><td>...</td><td>246.63899(19)</td><td>...</td><td>...</td><td>20(3)</td><td>5.5(6)</td><td>4.5(5)</td><td>...</td><td>3.74</td><td>...</td></tr><tr><td><sup>34</sup>SO</td><td>6<sub>5</sub>-5<sub>4</sub></td><td>246.663470</td><td>34.68</td><td>11.4</td><td>92(3)</td><td>20.1(9)</td><td>3.9(2)</td><td>8.17(8)</td><td>3.74</td><td>I</td></tr><tr><td>NH<sub>2</sub>CHO?</td><td>12<sub>0,12</sub>-11<sub>0,11</sub> v<sub>12</sub> = 1</td><td>247.327322</td><td>343.26</td><td>156</td><td>56(2)</td><td>10.8(8)</td><td>5.3(5)</td><td>8.82(18)</td><td>3.24</td><td>B</td></tr><tr><td>CH<sub>3</sub>CHO<sup>f</sup></td><td>14<sub>0,14</sub>-13<sub>1,13</sub> E</td><td>247.341332</td><td>66.56</td><td>11.3</td><td>15.1(19)</td><td>...</td><td>...</td><td>...</td><td>3.24</td><td>B</td></tr><tr><td>NH<sub>2</sub>CHO</td><td>12<sub>0,12</sub>-11<sub>0,11</sub></td><td>247.390719</td><td>107.25</td><td>0.319</td><td>206(4)</td><td>35.9(7)</td><td>5.80(14)</td><td>8.12(6)</td><td>4.57</td><td>B</td></tr><tr><td>HCOOH<sup>g</sup></td><td>11<sub>8</sub>-10<sub>8</sub></td><td>247.412546</td><td>190.76</td><td>20.9</td><td>...</td><td>...</td><td>...</td><td>...</td><td>4.57</td><td>B</td></tr><tr><td>HCOOH<sup>g</sup></td><td>11<sub>7</sub>-10<sub>7</sub></td><td>247.418230</td><td>157.69</td><td>26.4</td><td>...</td><td>...</td><td>...</td><td>...</td><td>4.57</td><td>B</td></tr><tr><td>CH<sub>3</sub>COCH<sub>3</sub><sup>h</sup></td><td>24<sub>2,23</sub>-23<sub>1,22</sub> EE</td><td>248.681568</td><td>108.64</td><td>3050</td><td>52(3)</td><td>9.7(6)</td><td>7.5(5)</td><td>10.2(2)</td><td>3.78</td><td>B</td></tr><tr><td><sup>34</sup>SO<sub>2</sub>?</td><td>13<sub>1,13</sub>-12<sub>0,12</sub></td><td>248.698604</td><td>56.86</td><td>26.0</td><td>16(2)</td><td>7.4(8)</td><td>2.4(3)</td><td>7.69 (13)</td><td>3.78</td><td>I</td></tr><tr><td>HCOOCH<sub>3</sub>?</td><td>20<sub>3,14</sub>-19<sub>3,16</sub> A v<sub>t</sub> = 1</td><td>248.715840</td><td>223.01</td><td>102</td><td>25(3)</td><td>4.8(5)</td><td>7.6(10)</td><td>6.6(4)</td><td>2.97</td><td>B</td></tr><tr><td>HCOOCH<sub>3</sub></td><td>20<sub>5,16</sub>-19<sub>5,15</sub> E</td><td>249.031002</td><td>98.39</td><td>49.8</td><td>60(2)</td><td>10.0(7)</td><td>5.7(5)</td><td>8.31(19)</td><td>2.97</td><td>B</td></tr><tr><td>HCOOCH<sub>3</sub></td><td>20<sub>5,16</sub>-19<sub>5,15</sub> A</td><td>249.047428</td><td>98.39</td><td>49.3</td><td>56(2)</td><td>11.9(6)</td><td>5.0(3)</td><td>8.61(13)</td><td>2.97</td><td>B</td></tr><tr><td>c-C<sub>3</sub>H<sub>2</sub><sup>d</sup></td><td>5<sub>2,3</sub>-4<sub>3,2</sub></td><td>249.054368</td><td>24.51</td><td>19.1</td><td>41.1(14)</td><td>...</td><td>...</td><td>...</td><td>2.97</td><td>N</td></tr><tr><td>U-line</td><td>...</td><td>260.5227(3)</td><td>...</td><td>...</td><td>67(3)</td><td>15.5(12)</td><td>5.2(9)</td><td>...</td><td>5.45</td><td>...</td></tr><tr><td>CH<sub>3</sub>CHO</td><td>14<sub>1,14</sub>-13<sub>1,13</sub> E</td><td>260.530403</td><td>67.00</td><td>176</td><td>223(4)</td><td>37.0(9)</td><td>6.16(19)</td><td>8.37(7)</td><td>5.45</td><td>B</td></tr><tr><td>CH<sub>3</sub>CHO</td><td>14<sub>1,14</sub>-13<sub>1,13</sub> A</td><td>260.544020</td><td>66.95</td><td>176</td><td>265(4)</td><td>54.2(11)</td><td>4.80(12)</td><td>8.59(5)</td><td>5.45</td><td>B</td></tr><tr><td>SO</td><td>N<sub>J</sub> = 67-5<sub>6</sub></td><td>261.843684</td><td>33.05</td><td>16.4</td><td>847(3)</td><td>245(3)</td><td>3.13(4)</td><td>8.09(2)</td><td>3.30</td><td>I</td></tr><tr><td>U-line</td><td>...</td><td>261.96932(16)</td><td>...</td><td>...</td><td>69(5)</td><td>13.5(11)</td><td>4.4(4)</td><td>...</td><td>5.65</td><td>...</td></tr><tr><td>CCH<sup>d</sup></td><td>N = 3-2, J = 7/2-5/2, F = 4-3</td><td>262.004260</td><td>17.48</td><td>194</td><td>136(3)</td><td>...</td><td>...</td><td>...</td><td>5.65</td><td>N</td></tr><tr><td>CCH<sup>d</sup></td><td>N = 3-2, J = 7/2-5/2, F = 3-2</td><td>262.006482</td><td>17.48</td><td>51.4</td><td>129(2)</td><td>...</td><td>...</td><td>...</td><td>5.65</td><td>N</td></tr><tr><td>CCH<sup>d</sup></td><td>N = 3-2, J = 5/2-3/2, F = 3-2</td><td>262.064986</td><td>17.49</td><td>1.63</td><td>100(3)</td><td>...</td><td>...</td><td>...</td><td>5.70</td><td>N</td></tr><tr><td>CCH<sup>d</sup></td><td>N = 3-2, J = 5/2-3/2, F = 2-1</td><td>262.067469</td><td>17.49</td><td>1.07</td><td>89(3)</td><td>...</td><td>...</td><td>...</td><td>5.70</td><td>N</td></tr><tr><td>HCOOH</td><td>12<sub>0,12</sub>-11<sub>0,11</sub></td><td>262.103480</td><td>57.53</td><td>24.2</td><td>190(5)</td><td>29.5(8)</td><td>6.4(2)</td><td>8.39(9)</td><td>5.70</td><td>B</td></tr><tr><td>CH<sub>3</sub>OCH<sub>3</sub><sup>i</sup></td><td>13<sub>5,8</sub>-13<sub>4,9</sub> EE</td><td>262.393513</td><td>82.02</td><td>148</td><td>44(3)</td><td>9.2(8)</td><td>5.2(6)</td><td>8.7(2)</td><td>5.12</td><td>B</td></tr><tr><td>CH<sub>3</sub>OCH<sub>3</sub><sup>i</sup></td><td>13<sub>5,8</sub>-13<sub>4,9</sub> AA</td><td>262.395111</td><td>82.02</td><td>108</td><td>44(3)</td><td>9.2(8)</td><td>5.2(6)</td><td>10.6(2)</td><td>5.12</td><td>B</td></tr><tr><td>HNCO</td><td>12<sub>0,12</sub>-11<sub>0,11</sub></td><td>263.748625</td><td>57.19</td><td>30.0</td><td>389(6)</td><td>72.8(11)</td><td>5.19(9)</td><td>8.01(4)</td><td>7.65</td><td>B</td></tr><tr><td>U-line</td><td>...</td><td>263.7680(3)</td><td>...</td><td>...</td><td>72(5)</td><td>12.1(15)</td><td>5.3(7)</td><td>...</td><td>6.71</td><td>...</td></tr><tr><td>HC<sub>3</sub>N<sup>l</sup></td><td>29-28</td><td>263.792308</td><td>132.00</td><td>404</td><td>763(6)</td><td>141.4(13)</td><td>5.17(6)</td><td>6.99(2)</td><td>6.71</td><td>B</td></tr><tr><td>CH<sub>3</sub>COCH<sub>3</sub><sup>2k</sup></td><td>22<sub>6,17</sub>-21<sub>5,16</sub> EA</td><td>263.816703</td><td>114.36</td><td>534</td><td>81(5)</td><td>4.5(3)</td><td>18.4(11)</td><td>6.66(13)</td><td>6.71</td><td>B</td></tr><tr><td>CH<sub>2</sub>DOH<sup>2k</sup></td><td>2<sub>2,1</sub>-2<sub>1,2</sub></td><td>263.818884</td><td>29.13</td><td>0.419</td><td>81(5)</td><td>4.5(3)</td><td>18.4(11)</td><td>9.14(13)</td><td>6.71</td><td>B</td></tr><tr><td>U-line</td><td>...</td><td>264.241808(9)</td><td>...</td><td>...</td><td>129(4)</td><td>24.3(9)</td><td>5.9(3)</td><td>...</td><td>6.03</td><td>...</td></tr></tbody></table>

**Notes.**

<sup>a</sup> Tentative detections are indicated by a question mark.

<sup>b</sup> Rest frequencies for the identified lines. Fitted rest frequencies assuming the $v_{lsr}$ of 8.34 km s⁻¹ for the unidentified lines.

<sup>c</sup> B: broad line. I: intermediate line. N: narrow line. See Section 3.2.

<sup>d</sup> I and Δν are not derived by the Gaussian fit, due to the existence of the absorption feature.

<sup>e</sup> This line may be blended with the 20<sub>16,4</sub> - 19<sub>16,3</sub> E line of HCOOCH<sub>3</sub> (245.583970 GHz).

<sup>f</sup> I and Δν are not derived by the Gaussian fit because the line is too weak.

<sup>g</sup> $F_{integ}$, I and Δν are not derived by the Gaussian fit because of heavy blending. The K-doublet lines are also unresolved.

<sup>h</sup> This line is blended with the 24<sub>1,23</sub>-23<sub>2,22</sub> EE line of CH<sub>3</sub>COCH<sub>3</sub> (248.6815860 GHz).

<sup>i</sup> $F_{integ}$, I and Δν are values for the blended lines.

<sup>j</sup> This line is likely blended with the 5<sub>1,5</sub>-4<sub>2,4</sub> A<sup>h</sup> v<sub>t</sub> = 1 line of CH<sub>3</sub>OH (263.7938560 GHz).

<sup>k</sup> These lines are blended with each other. Furthermore, these lines are blended with the 22<sub>6,17</sub>-21<sub>5,16</sub> AE (263.8167120 GHz), 22<sub>5,17</sub>-21<sub>6,16</sub> AE (263.8167120 GHz), and 22<sub>5,17</sub>-21<sub>6,16</sub> EA (263.8167027 GHz) lines of CH<sub>3</sub>COCH<sub>3</sub>.
are $(0''42 \pm 0''07) \times (0''31 \pm 0''08)$ and $(0''42 \pm 0''06) \times (0''30 \pm 0''07)$, respectively. According to the previous studies (Hirano et al. 1988), the outflow is extended along the east-west direction, and the protostellar disk/envelope system would have a nearly edge-on configuration with respect to the line of sight ($i \sim 10^\circ$). Nevertheless, the rotation motion cannot be identified in the COMs spectrum. This result is consistent with the results reported by Yen et al. (2015) and Evans et al. (2015). Hence, the broad line width of the COMs means that the COMs mainly exist in a structure whose distribution is much smaller than the synthesized beam.

On the other hand, the CCH emission, which shows the narrow line width, is extended over a scale of a few 100 au from the protostar (Figure 1(g)). Such an extended distribution is consistent with the self-absorption feature seen in the spectra. A part of the extended component would trace an outflow cavity wall, whose direction (east-west) is consistent with previous studies (Hirano et al. 1988). Although this source harbors a hot corino, carbon-chain related species can be observed in the protostellar core. The moment 0 maps of the sulfur-bearing molecules, showing the intermediate line width, reveal the compact distribution (Figures 1(h), (i)), although a weak extended component can also be seen.

### 3.3. Derivation of Column Density and Fractional Abundance

We derive the beam-averaged column densities of HCOOCH$_3$, CH$_3$OCH$_3$, CH$_3$CHO, NH$_2$CHO, HNCO, c-C$_3$H$_2$, SO$_2$, HC$_3$N, HCOOH, CH$_3$COCH$_3$, SO, and CS toward the continuum peak, assuming the local thermodynamic equilibrium (LTE) and optically thin conditions:

$$N(X) = U(T) \frac{3k_B W}{8\pi^3 \nu S \mu^2} \exp\left(\frac{E_u}{k_B T}\right), \quad (1)$$

where $U(T)$ denotes the partition function of the molecule at the temperature $T$, $W$ is the integrated intensity, and $E_u$ is the upper state energy. Since a single line or multiple lines with similar upper state energies are observed in this study, the column densities are calculated for the excitation temperature of 100 K. This temperature is a typical excitation temperature for COMs in the hot corino source IRAS 16293–2422 (Richard et al. 2013; Jaber et al. 2014; Oya et al. 2016), and is also close to the mass-weighted dust temperature (Kauffmann et al. 2008) at a roughly 0''5 beam (111 K) reported for B335 by Evans et al. (2015). Although the detection of CH$_3$OCH$_3$ and CH$_3$COCH$_3$ is tentative in this study, we calculate their column densities for comparison with other sources. The results are shown in Table 2.

To derive the fractional abundances relative to H$_2$, the beam-averaged column density of H$_2$ is estimated using the following equation:

$$N(H_2) = \frac{F(\nu)N_A}{\nu^3 \kappa_\nu \Omega \rho (2h/c^2)} [\exp(h\nu/k_B T_d) - 1], \quad (2)$$

where $\nu$ denotes the frequency, $F(\nu)$ is the peak integrated flux of dust continuum emission, $\kappa_\nu$ is the mass absorption coefficient with respect to the gas mass, $T_d$ is the dust temperature, $\Omega$ is the solid angle of the synthesized beam, $\rho$ is the average molecular weight (2.33) in atomic mass units, and $N_A$ is Avogadro's number (Ward-Thompson et al. 2000). The

<table><caption>**Table 2**

Column Densities and the Fractional Abundances Relative to H$_2$$^a$</caption><thead><tr><th>Molecule</th><th>Column Density<br>/10<sup>14</sup> cm<sup>-3</sup></th><th>Fractional Abun-<br>dance /10<sup>-10</sup></th></tr></thead><tbody><tr><td>HCOOCH<sub>3</sub><sup>b,c</sup></td><td>26(3)</td><td>46(5)</td></tr><tr><td>CH<sub>3</sub>CHO<sup>d</sup></td><td>14(2)</td><td>24(4)</td></tr><tr><td>NH<sub>2</sub>CHO</td><td>2.4(2)</td><td>4.3(4)</td></tr><tr><td>HNCO</td><td>96(10)</td><td>170(17)</td></tr><tr><td>HCOOH<sup>e</sup></td><td>27(3)</td><td>47(5)</td></tr><tr><td>c-C<sub>3</sub>H<sub>2</sub><sup>f</sup></td><td>&gt;0.80(8)</td><td>&gt;1.41(15)</td></tr><tr><td>SO<sub>2</sub></td><td>16.9(17)</td><td>30(3)</td></tr><tr><td>SO</td><td>13.6(14)</td><td>24(2)</td></tr><tr><td>CS<sup>f</sup></td><td>&gt;5.4(5)</td><td>&gt;9.6(10)</td></tr><tr><td colspan="3" style="text-align: center;">Tentative Detection</td></tr><tr><td>CH<sub>3</sub>OCH<sub>3</sub></td><td>19(2)</td><td>34(4)</td></tr><tr><td>CH<sub>3</sub>COCH<sub>3</sub><sup>b</sup></td><td>4.7(5)</td><td>8.4(10)</td></tr><tr><td>C<sub>2</sub>H<sub>5</sub>OH</td><td>21(3)</td><td>38(5)</td></tr><tr><td>C<sub>2</sub>H<sub>5</sub>CN</td><td>0.96(15)</td><td>1.7(3)</td></tr></tbody></table>

**Notes.**

a The excitation temperature is assumed to be 100 K.

b Derived from the 20$_{5,16}$–19$_{5,15}$ E line (249.031 GHz) and the 20$_{5,16}$–19$_{5,15}$ A line (249.047 GHz).

c The vibrationally excited states are not considered in the partition function.

d Derived from the 14$_{1,14}$–13$_{1,13}$ E line (260.530 GHz).

e Derived from the 12$_{0,12}$–11$_{0,11}$ line (262.103 GHz).

f The lower limit is estimated, due to the absorption feature.

<table><caption>**Table 3**

Fractional Abundances of COMs$^a$</caption><thead><tr><th>Molecule</th><th>B335<sup>b</sup></th><th>IRAS 16293–2422<sup>c</sup></th><th>IRAS 4A</th><th>IRAS 2A<sup>d</sup></th></tr></thead><tbody><tr><td>X(HCOOH)</td><td>4.7</td><td>≈0.3</td><td>...</td><td>...</td></tr><tr><td>X(CH<sub>3</sub>CHO)</td><td>2.4</td><td>3</td><td>...</td><td>...</td></tr><tr><td>X(HCOOCH<sub>3</sub>)</td><td>4.6</td><td>9</td><td>1.4<sup>d</sup></td><td>13</td></tr><tr><td>X(CH<sub>3</sub>OCH<sub>3</sub>)</td><td>3.4</td><td>40</td><td>0.85<sup>d</sup></td><td>8.2</td></tr><tr><td>X(HNCO)</td><td>17</td><td>...</td><td>0.8<sup>e</sup></td><td>...</td></tr><tr><td>X(NH<sub>2</sub>CHO)</td><td>0.4</td><td>0.6</td><td>0.2<sup>e</sup></td><td>2.3</td></tr><tr><td>X(C<sub>2</sub>H<sub>5</sub>OH)</td><td>3.8</td><td>≈5</td><td>1.2<sup>d</sup></td><td>10</td></tr><tr><td>X(C<sub>2</sub>H<sub>5</sub>CN)</td><td>0.2</td><td>≈0.2</td><td>0.062<sup>d</sup></td><td>0.24</td></tr></tbody></table>

**Notes.**

a X represents the fractional abundance relative to H$_2$ in units of $10^{-9}$.

b The temperature is assumed to be 100 K.

c Jaber et al. (2014).

d Taquet et al. (2015).

e López-Sepulcre et al. (2015).

mass absorption coefficient at 1.2 mm is calculated to be 0.0068 cm$^2$ g$^{-1}$, using the average value of $\kappa_\nu$ at 850 $\mu$m (1.48 $\times 10^{-2}$) with a $\beta$ index of 2.38, which were reported for B335 by Shirley et al. (2011). Then the column density of H$_2$ is derived to be $(5.66 \pm 0.11) \times 10^{23}$ cm$^{-2}$ for the dust temperature of 100 K. Using the H$_2$ column density, the fractional abundances of the observed molecules relative to H$_2$ are evaluated, as summarized in Table 2. Here, we simply assume that the dust temperature equals the LTE temperature. If the line-of-sight depth of the molecular distribution (L) were the same as the FWHM of the continuum peak (L $\simeq 1.1 \times 10^{15}$ cm), the H$_2$ density is roughly estimated to
be $n(H_2) \sim 5 \times 10^8$ cm$^{-3}$. Such a relatively high density justifies the LTE assumption employed in derivation of the column densities.

In the following section, we discuss the abundances of the saturated COMs and their related species. The abundances of sulfur-bearing molecules and carbon-chain molecules will be discussed in a separate publication (N. Sakai et al. 2016, in preparation).

## 4. DISCUSSION

In this observation, we detected the lines of CH$_3$CHO, HCOOCH$_3$, and NH$_2$CHO, and tentatively detected the lines of CH$_3$OCH$_3$, C$_2$H$_5$OH, C$_2$H$_5$CN, and CH$_3$COCH$_3$. These COM lines show a broad line width and a very compact distribution around the protostar. The fractional abundances of COMs relative to H$_2$ in B335 are compared with those in other sources in Table 3. The fractional abundance of HCOOCH$_3$ is evaluated to be $4.6 \times 10^{-9}$, which is comparable to that reported for the prototypical hot corino IRAS 16293-2422 ($9 \times 10^{-9}$) (Jaber et al. 2014) and NGC1333 IRAS 4A ($1.4 \times 10^{-9}$) (Taquet et al. 2015). The fractional abundance of CH$_3$OCH$_3$ in B335 ($3.4 \times 10^{-9}$) is smaller than that reported for IRAS 16293-2422 ($4 \times 10^{-8}$) (Jaber et al. 2014), but is slightly higher than that for NGC1333 IRAS 4A. Thus, B335 is confirmed to be rich in COMs. The HCOOCH$_3$ abundance is also comparable to that in the outflow shocked region L1157 B1 (Sugimura et al. 2011). On the other hand, the fractional abundances of HCOOCH$_3$ and CH$_3$OCH$_3$ in B335 are much higher than those found in the prestellar core L1689B ($10^{-10}-10^{-9}$) (Bacmann et al. 2012). This comparison indicates that the abundances of COMs are enhanced in the compact region near the protostar of B335, and thus we conclude that B335 harbors a hot corino.

Among the various COMs, NH$_2$CHO is proposed to be a key species in pre-biological evolution (Saladino et al. 2012). This molecule has been detected in hot corinos and hot cores in star-forming regions (Bisschop et al. 2007; Adande et al. 2013; Kahane et al. 2013). It is reported that the abundance of NH$_2$CHO shows a good correlation with that of HNCO, implying that these two species are related to each other in their production mechanisms (López-Sepulcre et al. 2015). In B335, the NH$_2$CHO/HNCO ratio is 0.024, which is almost comparable to the range of the ratios found in star-forming regions (0.03-0.25). Hence, the positive correlation between the abundances of these two species indeed holds in B335.

Detection of acetone (CH$_3$COCH$_3$) is tentative in this source. If the 248.682 GHz line originates from acetone, as in the case of NGC1333 IRAS 4A (A. López-Sepulcre et al., in preparation), the fractional abundance of acetone in B335 is determined to be $0.8 \times 10^{-9}$. The acetone abundance is lower than the value reported toward the acetone peaks in Orion KL (hot core) ($(0.4-1.6) \times 10^{-8}$ by Friedel et al. 2005). According to the interferometric observations toward Orion KL by Friedel & Snyder (2008) and Peng et al. (2013), acetone shows a different distribution from the other O-bearing COMs (HCOOCH$_3$ and CH$_3$OCH$_3$), and its distribution tends to be similar to the N-bearing COMs (C$_2$H$_5$CN). In B335, the distribution of acetone is similar to those of the other COMs, and we cannot find any specific trend in its distribution, which is unlike the Orion KL case, probably because of the insufficient angular resolution in this study. Definitive

identification of acetone in this source, with multiple lines and high-resolution imaging, will be the aim of future studies.

So far, hot corino sources have been found in large cloud complexes with active star formation: IRAS 16293-2422 is in the Ophiuchus molecular cloud complex (Cazaux et al. 2003), NGC1333 IRAS 4A, IRAS 4B, and IRAS 2A (Bottinelli et al. 2004; Jørgensen et al. 2005; Sakai et al. 2006) are in the Perseus molecular cloud complex, Serpens SMM4 is in the Serpens molecular cloud (Öberg et al. 2011), and HH212 is in the Orion molecular cloud (Codella et al. 2016). In contrast, B335 is the first hot corino source identified in a Bok globule isolated from a large molecular cloud complex. It is generally thought that a star-forming region in a molecular cloud complex will be affected by the various activities of the other protostars in the same cloud complex. Likewise, the chemical composition of the protostellar core will also be affected by such environmental effects. In contrast, B335 is thought to be almost free from them. Its chemical composition could be regarded as a "standard" template for chemical compositions of isolated protostellar cores. It will also be very useful for comparison with chemical model calculations in order to understand chemical evolution during star formation.

Finally, we note an implication for the protostellar mass in this source. Although the compact distributions of the COMs are not spatially resolved, we may be able to constrain the size of the emitting region and the protostellar mass on the basis of the following rough argument. Among the lines that have a compact distribution and a broad line width, the brightest one is the HNCO line, excluding tentative detections and blended lines. Its peak flux and the line width are $72.8$ mJy beam$^{-1}$ and $5.19$ km s$^{-1}$, respectively. The peak flux corresponds to the brightness temperature of $4.2$ K for the $0.58 \times 0.52$ (58 au × 52 au) beam. Judging from the distribution and the line width, HNCO is most likely present in the same region where the COMs exist. If this emission comes from such a compact region, the actual brightness temperature corrected for the beam dilution should be higher. If COMs and related species, including HNCO, are assumed to be distributed within a region whose average temperature is $100$ K (a typical hot corino temperature), the brightness temperature has to be lower than $100$ K. From this condition, the diameter of the emitting region is estimated to be $11$ au or larger. To explain the line width at this range of the radius, the protostellar mass is estimated to be $0.04$ $M_{\odot}$ or higher, if the motion responsible for the line width is Keplerian. It is $0.02$ $M_{\odot}$ or higher if the motion is in infall. These mass estimates are consistent with those reported by Yen et al. (2015) ($>0.05$ $M_{\odot}$).

The authors are grateful to the reviewer of this paper for invaluable comments. This paper makes use of the following ALMA data: ADS/JAO.ALMA#2013.1.01102.S. ALMA is a partnership of ESO (representing its member states), NSF (USA), and NINS (Japan), together with NRC (Canada), NSC and ASIAA (Taiwan), and KASI (Republic of Korea), in cooperation with the Republic of Chile. The Joint ALMA Observatory is operated by ESO, AUI/NRAO, and NAOJ. This study is financially supported by KAKENHI (21224002, 25400223, and 25108005). The authors acknowledge the financial support by JSPS and MAEE under the Japan-France integrated action programme (SAKURA: 25765VC).
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