# Characterization of Clay Raw Materials from Three Kankan Clay Deposits with a View to Their Use as Building Materials

Thierno Abdoulaye Barry, Abdou Mbaye, Insa Badiane, Albert Manga Badiane, Stéphane Freslon, Bérenger Aranda, Laurent Molez, Magatte Camara

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## To cite this version:

Thierno Abdoulaye Barry, Abdou Mbaye, Insa Badiane, Albert Manga Badiane, Stéphane Freslon, et al.. Characterization of Clay Raw Materials from Three Kankan Clay Deposits with a View to Their Use as Building Materials. Journal of Materials Science and Chemical Engineering, 2025, 13 (02), pp.31-52. 10.4236/msce.2025.132003. hal-04963535

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# Characterization of Clay Raw Materials from Three Kankan Clay Deposits with a View to Their Use as Building Materials

Thierno Abdoulaye Barry<fnref n="1" />,<fnref n="2" />*, Abdou Mbaye<fnref n="1" />, Insa Badiane<fnref n="1" />, Albert Manga Badiane<fnref n="1" />, Stéphane Freslon<fnref n="3" />, Bérenger Aranda<fnref n="4" />, Laurent Molez<fnref n="4" />, Magatte Camara<fnref n="1" />

**How to cite this paper:** Barry, T.A., Mbaye, A., Badiane, I., Badiane, A.M., Freslon, S., Aranda, B., Molez, L. and Camara, M. (2025) Characterization of Clay Raw Materials from Three Kankan Clay Deposits with a View to Their Use as Building Materials. *Journal of Materials Science and Chemical Engineering*, **13**, 31-52.

https://doi.org/10.4236/msce.2025.132003

Received: January 8, 2025

Accepted: February 17, 2025

Published: February 20, 2025

Copyright © 2025 by author(s) and
Scientific Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution International
License (CC BY 4.0).

http://creativecommons.org/licenses/by/4.0/

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Open Access

## Abstract

Clays are a constituent of the earth. As a result, the discovery and traditional use of clays in construction and pottery worldwide dates back to antiquity. Guinea has several deposits of clay minerals whose chemical and mineralogical compositions have been little studied. Despite lacking of scientific data on these clay minerals, they are used today in pottery and habitat construction. As a step towards promoting the use of clay materials in Guinea, we conducted a study of the physicochemical and mineralogical properties of three natural clays from Kakan in the Republic of Guinea (AKKB, AKKE, AKKO) used in habitat construction. The aims of this work were to better understand their properties, but above all to be able to act on them to improve and broaden their applications, which until now have been limited to construction. These clays were studied by X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF), moisture content (%W), laser granulometry, Atterberg limits, specific surface area, infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis and differential thermal analysis (TGA/DTA). These analyses revealed that the main clay minerals present in our samples are kaolinite, illite and, montmorillonite, with the addition of impurities, the most abundant of which is quartz.

<footnote n="1">¹Laboratoire de Chimie et physique des Matériaux (LCPM), UFR des Sciences Techniques et Ingénierie (STI) de l'Université Assane Seck de Ziguinchor (UASZ), Ziguinchor, Sénégal</footnote>

<footnote n="2">²Laboratoire de Chimie Analytique, Département de Chimie, Université Gamal Abdel Nasser de Conakry, Conakry, Guinée</footnote>

<footnote n="3">³Laboratoire de Chimie du solide et Matériaux, Institut des Sciences Chimiques de Rennes, Coësmes, France</footnote>

<footnote n="4">⁴Laboratoire de Génie Civil et Génie Mécanique (LGCGM) de l'Institut National des Sciences Appliquées de Rennes, Coësmes, France</footnote>

<footnote>Email: ta.b1@zig.univ.sn, abdou.mbaye@univ-zig.sn, magatte.camara@univ-zig.sn</footnote>
Keywords

Characterization, Clay Minerals, Kankan, Habitat Construction

# 1. Introduction

Clay science is a pluridisciplinary field that brings together researchers from a va-
riety of specialities (geology, mineralogy, cristallography, chemistry and geotech-
nics), with different objectives in mind [1] [2].

Interest in this field has been growing recently as its industrial applications con-
tinue to diversify. Clay is the oldest mineral used by man in pottery and habitat
construction [2].

The term “clay” has been defined as a natural material composed mainly of fine-
grained minerals (clay minerals), generally plastic at appropriate water contents
and hardening when dried or fired [3].

The discovery and traditional use of clay materials dates back to antiquity
throughout the world: in Africa (Egypt), the Middle East (Turkey), Asia (China),
America (Mexico), Europe (Rome), etc. [4].

In recent years, clay, which had been abandoned in favor of cement, has enjoyed
renewed interest thanks to its availability, reduced ecological impact and hygro-
scopic and thermal properties [5].

In several sub-Saharan African countries, including Burkina Faso and Guinea,
numerous studies are being carried out to evaluate the properties of clay as a raw
material for eco-construction [6] [7].

As for the Republic of Guinea, it abounds in large deposits of useful minerals
such as clays, sand, granite, laterite, limestone, etc. [8]; some of which are tradi-
tionally exploited by communities. Clays, long neglected after the discovery of hy-
draulic binders and their derivatives, are now used throughout Guinea in the hab-
itat sector, particularly in Kankan.

This widespread use of clay in housing construction in the city of Kankan is
justified on the one hand by a demographic increase from 392.768 inhabitants
(10.7%) in 2014 to 472.505 inhabitants (10.9%) in 2019 [9], making it the 3rd most
populous city in the country after the capital Conakry and Kindia, and on the
other hand by the high cost of hydraulic binders. Added to this is the environ-
mental problem caused by the pollution generated by the production of these ma-
terials known as hydraulic binders.

Integrating these clay materials into the construction of decent, accessible and
sustainable housing, infrastructure and facilities is therefore a crucial challenge on
an international scale.

Against this backdrop of high building material prices, sustainable develop-
ment, and technological innovation in the field of research, clays offer a viable
alternative for a wide variety of applications.

Earth used in construction requires sufficient cohesion, provided by the clay
that acts as a natural binder [5].

The use of clays is intrinsically linked to knowledge of their properties, which is why we have undertaken the physicochemical, mineralogical and geotechnical characterization of clay raw materials from three clay deposits in Kankan (Republic of Guinea) with a view to their use as building materials.

## 2. Materials and Methods

### 2.1. Study Area

The Kankan area is located in the north-east of the Republic of Guinea, 635 km from the capital Conakry. Its surface area is approximately 72,145 km² with a population of 472.505 habitant inhabitants in 2019 [9]. In geographical coordinates, it extends from 10°23' North latitude and 9°18' West longitude. See **Figure 1**, which shows the map of Kankan and its position within the Republic of Guinea.

<figure><img src="image_4.png" /><figcaption>**Figure 1.** Map of the Kankan region showing sampling zones [10].</figcaption></figure>

### 2.2. Geological Setting

Guinea's geology is dominated by Paleozoic terrains with Mesozoic zones. In the northeastern region around Kankan, Proterozoic facies predominate, alternating with Archean formations [11] [12].

The Kankan region has a varied geology:

* Lower Proterozoic: Mainly present, with sedimentary and effusive layers.

* Upper Proterozoic: Located in the northwest, composed of sandstones and conglomerates, forming plateaus bordered by cliffs.

* Paleozoic: Outcrops to the north, with a base of quartz conglomerates resting on Proterozoic granites [13].
## 2.3. Sample Collection and Preparation

Clay samples were taken from representative areas to accurately reflect local geo-logical and mineralogical characteristics. Samples were taken at depths of 1 m (AKKB), 3 m (AKKE) and 3 m (AKKO) to study depth-related variations. A quantity of 5 kg per site was collected to enable in-depth analysis.

The Process used appropriate tools, including a geological map, shovel, spatula, hammer, bags, GPS, labels and marker. Each sample was labelled with precise information (date, location and coordinates). Samples were packaged in airtight plastic bags to preserve their physical and chemical properties.

For the present work, we took three clay samples from the areas deemed to be the most exploited in Kankan. The samples were taken in such a way as to be able to characterize both the clays from the Balandougou Sub-Prefecture (AKKB) and the clays from the Energie (AKKE) and Kankankoura (AKKO) urban districts.

Table 1 shows the clay sampling areas and their geographical coordinates.

<table><caption>Table 1. Sampling of Kankan clays.</caption><thead><tr><th>Area</th><th>Sampling zone</th><th>N</th><th>W</th></tr></thead><tbody><tr><td rowspan="6">Kankan</td><td rowspan="3">Sub-Prefecture of Balandougou</td><td>10°36'08.7"</td><td>- 09°30'15.5"</td></tr><tr><td>10°39'44.9"</td><td>- 09°26'98.5"</td></tr><tr><td>10°36'11.3"</td><td>- 09°30'15.2"</td></tr><tr><td rowspan="2">Kankankoura district</td><td>10°36'68.4"</td><td>- 09°28'70.2"</td></tr><tr><td>10°36'08.7"</td><td>- 09°01'55.0"</td></tr><tr><td>Energie district</td><td>10°36'15.4"</td><td>- 09°30'13.1"</td></tr></tbody></table>

## 2.4. Analytical Methods and Materials

### 2.4.1. Moisture Content

The moisture content of clays was determined using a “Despatch 2000” oven calibrated at 105°C.

The following formula was used to calculate the natural moisture content (%W):

$$ \%W = \frac{P_1 - P_2}{P_e} \times 100 \quad (1) $$

*P₁*: weight of bin plus sample before drying.

*P₂*: weight of bin plus sample after drying.

*P₃*: test plug weight.

### 2.4.2. Mineralogical Analysis

Mineralogical phases were identified using a Panalytical X'Pert Pro diffractometer equipped with an X' Celerator detector. Experimental conditions were as follows: Cu Kα radiation (λ = 1.542 Å), I = 40 mA, V = 45 kV. Peaks were identified using X'Pert HighScore software.

### 2.4.3. Characterization Techniques

Chemical composition in terms of major oxides was determined by X-ray fluorescence spectrometry (XRF). This analysis was carried out using the “AXIOS FAST,
PANAlytical 206204" instrument.

### 2.4.4. FTIR Spectroscopy

FT-IR measurements were carried out on a Perkin Elmer Frontier spectrometer using the UATR (Universal Attenuated Total Reflectance) accessory. Spectra were recorded between 650 and 4000 cm⁻¹, on the clay samples.

### 2.4.5. Physical Properties

The Atterberg limit is determined by the falling cone method, which measures the penetration of the cone into the soil after release, with better resolution.

The Malvern Mastersizer 2000 manufactured by Malvern Instruments was used as a laser particle analyzer for clays. This device works on the basis of Mie theory to obtain particle size distribution by converting light-scattering data.

The specific surface area was measured using a Dewar "vacprep 061" gas vacuum spectrometer coupled to a TriStar II Plus Porosimeter.

### 2.4.6. Morphological Study

SEM images were obtained with a Hitachi TM 1000 tabletop microscope, version 02.11 (Hitachi High Technologies, Corporation Tokyo Japan). Samples were assembled on carbon disks, glued to a carbon stub. The reproducibility of the elemental analyses was checked by repeating the measurements several times for several spots per sample.

### 2.4.7. Thermal Analysis

Thermal analyses were carried out with a Perkin Elmer Pyris Diamond ATG/ATD analyzer between room temperature and 950°C at a rate of 5 °C/minute in platinum crucibles under a nitrogen atmosphere. Compounds were held for 1 hour at 950°C in an air atmosphere to ensure complete combustion.

## 3. Results and Discussion

### 3.1. Structural Analysis

#### 3.1.1. Phase Identification

X-ray diffraction patterns for the three clays AKKB, AKKE, and AKKO are shown in Figure 2. The main lines observed on the diffractogram of the clay fraction are attributed to kaolinite (Al₂Si₂O₅(OH)₄), illite[(K, H₃O)Al₂Si₃AlO₁₀(OH)₂], and montmorillonite (bentonite) [(Na, Ca)₀.₃(Al, Mg)₂Si₄O₁₀(OH)₂H₂O]. These raw samples also contain quartz (SiO₂), magnetite (Fe₃O₄), and, in smaller proportions, muscovite [(K, NH₄, Ca)Al₂(Si, Al)₄O₁₀(OH)₂], gibbsite [Al(OH)₃] in sample AKKE, and feldspar such as microcline (KAlSi₃O₈) in sample AKKB. Clinochlore [(Mg₅Al(Si₃Al)O₁₀(OH)₈] is also present, except in sample AKKE, which is not as similar in mineralogical composition to the other two samples. The relatively high intensity of quartz peaks in all samples indicates a significant presence of free silica. This can be confirmed by a higher SiO₂/Al₂O₃ ratio (2.61 to 3.45) and lower loss on ignition [14].

The presence of illite in clays can lead to the formation of a glassy phase and
lower the melting point while reducing linear shrinkage and the formation of cris-
tobalite and mullite. Clinochlore, one of the most abundant elements in the chlo-
rite group, is composed mainly of magnesium, with moderate amounts of silicon,
aluminum, and iron. Iron oxidation in clinochlore gives it an attractive appear-
ance, making AKKB and AKKO clays suitable for decorative and sculptural
stones. They can also be used to prepare bricks for exterior walls for aesthetic pur-
poses [15].

The clays mainly reveal the presence of two intense peaks, one corresponding
to Quartz and the other to a mixture of Kaolinite, illite, and Montmorillonite
sometimes stratified with illite, magnetite, and muscovite, implying that our clay
is heterogeneous. This confirms the results of the particle size distribution, which
shows bimodal forms, especially on AKKB and AKKE.

<figure><img src="image_5.png" /><figcaption>**Figure 2.** Diffractograms of Kankan natural clays.</figcaption></figure>

The existence of peaks from the smectite group implies further treatments of
our clays, namely solvating with glycerol and heating to 550°C, to obtain more
precision on their mineralogical composition.

The reflection peaks of kaolinite, visible at around 12.29 Å and 26.57 Å, re-
mained unchanged when the samples were solvated with glycerol, but disappeared
when heated to 550°C due to structural destruction. This behavior is characteristic
of kaolinite (Hong *et al.*, 2012; Tsao *et al.*, 2013).

The presence of illite is confirmed by reflection peaks at 8.76 Å and 26.57 Å,
which remained unchanged when the samples were subjected to glycolation and
heat treatment at 550°C.

Peaks of non-clay minerals, such as silica, were recognized as very intense at 20.84 Å and 26.51 Å, indicating the importance of the silica or quartz present [16] [17].

After heating, peaks were observed at around 8.64 Å, 17.98 Å, and 26.51 Å, at-
tributed to the interlayered clay minerals montmorillonite-chlorite.

Heat treatment at 550°C transformed magnetite (Fe₃O₄) into hematite (Fe₂O₃)
[18].

Diffraction peaks at around 8.76 Å and 27.44 Å are not displaced during
glycolation, confirming the presence of muscovite-illite. After heating to 550°C, illite and microcline diffraction peaks at 8.71 Å and 27.78 Å can be observed. The increase in intensity of the microcline diffraction peak at 26.51 Å is further evidence of the presence of microcline [19] [20].

In summary, the glycolation of AKKE clay showed weak sepiolite and anorthite peaks.

Figures 3 and 4 show diffractograms of the three clay samples treated with ethyl glycerol and thermolysis respectively.

<figure><img src="image_6.png" /><figcaption>Figure 3. Diffractograms of glycerol-treated Kankan clays.</figcaption></figure>

<figure><img src="image_7.png" /><figcaption>Figure 4. Diffractograms of Kankan clays after thermolysis.</figcaption></figure>

### 3.1.2. Microstructural Characterization

SEM images of the clays (AKKB, AKKE and AKKO), are shown in Figures 5, 6 and 7 respectively, reveal pseudo-hexagonal plates characteristic of kaolinite, as well as flaky lamellae or aggregates containing cavities [21] [22]. These structures show various alterations depending on the degree of crystallinity, typical of kaolinite [23] [24].

The samples also contain illite smectite, characterized by long, continuous, wavy structures [25].

SEM images suggest that montmorillonite forms an edge-to-edge and edge-to-
face contact structure, while kaolinite and illite platelets are mainly associated in a face-to-face mode [26].

They show the presence of muscovite in the form of flakes [27].

In addition, a significant quantity of grains, probably quartz, is observed. This mineral constitutes impurities, such as the magnetite detected by XRD in sample AKKO [22].

**Figures 5, 6 and 7** show scanning electron micrographs of the AKKB, AKKE and AKKO clays respectively.

<figure><img src="image_8.png" /><figcaption>**Figure 5.** Scanning electron microscopy image of some AKKB clay seeds.</figcaption></figure>

<figure><img src="image_9.png" /><figcaption>**Figure 6.** Scanning electron microscopy image of some AKKE clay seeds.</figcaption></figure>

<figure><img src="image_10.png" /><figcaption>**Figure 7.** Scanning electron microscopy image of some AKKO clay seeds.</figcaption></figure>
## 3.2. Elemental Chemical Composition

X-ray fluorescence spectrometry analyses of the AKKB, AKKE, and AKKO clay samples quantified the major chemical elements, in the form of oxides, which are shown in **Table 2**. The three samples are mainly composed of silicon oxide (SiO₂), aluminum oxide (Al₂O₃), iron oxide (Fe₂O₃) and potassium oxide (K₂O).

The mass contents of SiO₂ are 61.62%, 56.91%, and 66.42% respectively, while those of Al₂O₃ are 18.83%, 22.91%, and 19.23%, giving SiO₂/Al₂O₃ mass ratios of 3.27, 2.61 and 3.45 respectively. The high SiO₂/Al₂O₃ ratios suggest the possible presence of free quartz in a significant proportion within the clay fraction (Gourouza *et al.*, 2013) and/or compounds such as 2/1 clay minerals like illite and muscovite (Coulibaly *et al.*, 2020).

The alumina/silica ratio provides information on the material's permeability to moisture. The higher the ratio, the greater the permeability, indicating that our samples are less permeable [28].

From an industrial standpoint, the Al₂O₃/Fe₂O₃ mass ratio could be used to define the use of clays in the formulation of ceramic bodies. The Al₂O₃/Fe₂O₃ mass ratio of AKKB, AKKE and AKKO clays is less than 5.5, indicating that these clays are rich in iron and would be better suited to the manufacture of building materials (bricks, tiles, etc.) [29].

Loss of ignition is surely due to silicate dehydroxylation reactions, and organic matter combustion (Eliche-Quesada *et al.*, 2018), however, it varies from (6.89% to 9.43%) [30].

**Table 2** shows the elemental chemical analysis of the three clay samples.

<table><caption>**Table 2.** Chemical composition of the raw clay samples.</caption><thead><tr><th rowspan="2">Oxides</th><th colspan="3">Samples</th></tr><tr><th>AKKB</th><th>AKKE</th><th>AKKO</th></tr></thead><tbody><tr><td><b>SiO<sub>2</sub></b></td><td>61.62</td><td>56.91</td><td>66.42</td></tr><tr><td><b>Al<sub>2</sub>O<sub>3</sub></b></td><td>18.83</td><td>22.91</td><td>19.23</td></tr><tr><td><b>Fe<sub>2</sub>O<sub>3</sub></b></td><td>7.08</td><td>6.93</td><td>3.61</td></tr><tr><td><b>K<sub>2</sub>O</b></td><td>1.81</td><td>1.51</td><td>1.83</td></tr><tr><td><b>TiO<sub>2</sub></b></td><td>1.12</td><td>1.20</td><td>1.08</td></tr><tr><td><b>CaO</b></td><td>0.47</td><td>0.33</td><td>0.42</td></tr><tr><td><b>LOI</b></td><td>8.33</td><td>9.43</td><td>6.89</td></tr><tr><td><b>Total</b></td><td>99.26</td><td>99.22</td><td>99.48</td></tr><tr><td>SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub></td><td>3.27</td><td>2.61</td><td>3.45</td></tr><tr><td>Al<sub>2</sub>O<sub>3</sub>/Fe<sub>2</sub>O<sub>3</sub></td><td>2.65</td><td>3.30</td><td>5.32</td></tr></tbody></table>

The chemical analysis of the major elements in the form of oxides in the clay materials also enabled us to identify, from the Augustinik diagram of chemical composition (Figure 8), the different areas of use of our raw materials in the manufacture of ceramic products.
<figure><img src="image_11.png" /><figcaption>Figure 8. Positioning of the clays studied on the Augustinik diagram.</figcaption></figure>

The location of the samples in this diagram aptly describes the deficiencies in alkaline and alkaline-earth elements, especially for the AKKE clay. For industrial use in traditional ceramics, it would therefore be necessary to consider the addition of compounds rich in melting oxides to facilitate consolidation through the development of viscous flows.

### 3.3. FTIR Infrared Spectroscopy

The absorption bands located in the high-frequency regions appearing at 3693, 3655 and 3620 cm⁻¹ are related to the vibrations of OH hydroxyl groups in kaolinite. The first two bands are respectively attributed to the symmetrical stretching vibrations of the internal surface OH groups and the stretching vibrations of the out-of-plane OH groups. Whereas the band at 3620 cm⁻¹ is related to the stretching vibrations of the internal OH groups of kaolinite [31]. The sharp absorption band at 1633 cm⁻¹, attributed to the deformation vibration of H-O-H [31], and the absence of the elongation vibration at around 3400 cm⁻¹ point to the low water content of our samples.

The absorption bands at 1114 and 1000 cm⁻¹ represent asymmetric and symmetrical stretching of Si-O groups, while the bands around 900 cm⁻¹ (945 and 911 cm⁻¹) correspond to the deformation of the Al-OH bond in kaolinite [32].

The presence of kaolinite and muscovite can be confirmed by the stretched Si-O bands at 1113 cm⁻¹ and 1040 cm⁻¹ respectively (Vedder, 1964; Kristof et al., 1993) [17].

The simultaneous presence of bands at 3620 and 910 cm⁻¹ indicates that smectite is dioctahedral (Borchardt, 1977). According to Van Olphen and Fripiat (Van Olphen and Fripiat, 1979), the band near 750 cm⁻¹ indicates the presence of illite. These results concur with those of the XRD. They confirm the presence of
montmorillonite, kaolinite, and illite in the clay studied [33].

Bands close to 831 and 795 cm⁻¹ are attributed to Al-Mg-OH and Si-O-Si bending vibrations respectively and indicate the presence of smectite (Farmer, 1974; Arab *et al.*, 2015). The bands near 777 cm⁻¹ have been assigned to the Si-O stretching vibration of quartz (Madejová, 2003; Madejová *et al.*, 2011) [34].

The broad OH extension band near 3625 cm⁻¹, down to less than 3620 cm⁻¹ in some cases, coupled with the 825, 750 cm⁻¹ doublet (820 and 750 cm⁻¹ for our case) confirms the presence of illite [35].

**Figure 9** shows the infrared spectra of the three Kankan clays.

<figure><img src="image_12.png" /><figcaption>**Figure 9.** FT-IR spectra of Kankan raw clays.</figcaption></figure>

**3.4. Thermogravimetric and Differential Thermal Analysis**

Figure 10 shows the ATG/ATD curves for Kankan clays (AKKB - AKKE - AKKO). The ATG curves show three levels of mass loss corresponding to three endothermic peaks at the level of the ATD curves.

<figure><img src="image_13.png" /><figcaption>**Figure 10.** ATG/ATD curves of Kankan raw clays (AKKB - AKKE - AKKO).</figcaption></figure>

The nature of the peak, the mass losses and the physicochemical phenomena responsible for these transformations are summarized in **Table 3**.
<table><caption>**Table 3.** Nature of peaks, mass loss and physicochemical phenomena in clays.</caption><thead><tr><th rowspan="2">Nature of pic</th><th colspan="4">Loss of mass (%)</th><th rowspan="2">Comments</th><th rowspan="2">Moisture water discharge</th></tr><tr><th>AKKB</th><th>AKKE</th><th>AKKO</th><th>Comments</th></tr></thead><tbody><tr><td>Endo (55°C)</td><td>2.5</td><td>2.6</td><td>3.3</td><td>(Moisture water discharge)</td><td></td></tr><tr><td>Endo (260°C)</td><td>1.9</td><td>1.7</td><td>2</td><td>(Organic matter decomposition, iron oxidation)</td><td></td></tr><tr><td>Endo (485°C)</td><td>4.8</td><td>5.1</td><td>6.4</td><td>(Dehydroxylation of kaolinite)</td><td></td></tr><tr><td>Endo (573°C)</td><td>-</td><td>-</td><td>-</td><td>Transformation quartz α into quartz β</td><td></td></tr><tr><td>Exo (923°C)</td><td>-</td><td>-</td><td>-</td><td>Recrystallization phenomena</td><td></td></tr></tbody></table>

For the AKKB, AKKE and AKKO clays (Table 3), we observe 4 endothermic peaks and 1 exothermic peak. The first endothermic peak, at 55°C, corresponds to the departure of moisture water, accompanied by a loss of mass varying from 2.5% to 3.3%. The second peak at 260°C reflects the loss of inter-foliar water, the transformation of iron oxide and/or organic matter resulting in a mass loss of around 2% [36].

Montmorillonite shows an initial endothermic peak at a temperature of between 100 and 250°C due to the loss of water retained between the basal planes of the lattice structure [37].

An (OH) component is released from the mineral at temperature between 260 and 400°C, where the conversion of Fe₂O₃ to Fe₃O₄ occurs after the hydroxylation process. The phenomenon is observed in the AKKO sample, which contains magnetite according to XRD [38].

$$2\text{Fe}_2\text{O}_3 \text{ (Ferric oxide)} \rightarrow 2\text{Fe}_3\text{O}_4 \text{ (Magnetic oxide)} + \text{O}_2$$

The endothermic peak at 485°C is characteristic of the elimination of the constitutive water resulting from the release of hydroxides belonging to the kaolinite lattice according to the following equation $Al_2Si_2O_5(OH)_4 \rightarrow Al_2Si_2O_7 + 2H_2O$ (Hajjaji *et al.*, 2001; Bennadji *et al.*, 2008 and Ozkan *et al.*, 2010) [39].

This phase is accompanied by a mass loss of between 4.8% and 6.4%. This event can be attributed mainly to kaolinite dehydroxylation, although illite dehydroxylation may also make a minor contribution [40].

A weak hook at 573°C was noted, highlighting the transformation of α-quartz into β-quartz [41]. Finally, an exothermic peak at 923°C corresponds to the formation of mullite, pseudo-mullite, spinel, amorphous silica, and γ-Al₂O₃ (Földvári, 2011) [42].

## 3.5. Geotechnical Analyses

### 3.5.1. Moisture Content

The moisture content of a clay sample is the water content present in the clay as found in its natural state, before any treatment or drying, expressed as a percentage
of the dry weight of the clay. The moisture content of the three clay samples is shown in **Table 4**.

<table><caption>**Table 4.** Moisture content of Kankan raw clays.</caption><thead><tr><th rowspan="2">Parameter</th><th colspan="3">Samples</th></tr><tr><th>AKKB</th><th>AKKE</th><th>AKKO</th></tr></thead><tbody><tr><td>Humidity (%)</td><td>4.91</td><td>7.17</td><td>12.10</td></tr></tbody></table>

The water content of Kankan clays (AKKB, AKKE, and AKKO) is 4.91, 7.17, and 12.10 respectively. These low values, compared with the literature, are explained by the low natural permeability of the raw materials, and remain below the water content of pure kaolinitic clay (14%) [43].

### 3.5.2. Particle Size Analysis

Granulometric analysis consists of determining the size distribution of the grains making up a granulate. The results of particle size analysis are presented in **Table 5**.

<table><caption>**Table 5.** Particle size distribution of Kankan raw clays.</caption><thead><tr><th rowspan="2">Particle size</th><th colspan="3">Samples</th></tr><tr><th>AKKB</th><th>AKKE</th><th>AKKO</th></tr></thead><tbody><tr><td>Clay (%)</td><td>25.9</td><td>23.1</td><td>20.0</td></tr><tr><td>Sand (%)</td><td>21.14</td><td>23.3</td><td>17.3</td></tr><tr><td>Silt (%)</td><td>52.6</td><td>51.2</td><td>62.7</td></tr></tbody></table>

**Figures 11, 12 and 13** show the grain size distribution of samples AKKB, AKKE and AKKO respectively.

<figure><img src="image_14.png" /><figcaption>**Figure 11.** Grain size distribution of AKKB sample showing a bimodal pattern.</figcaption></figure>

<figure><img src="image_15.png" /><figcaption>**Figure 12.** Grain size distribution of AKKE sample showing a bimodal pattern.</figcaption></figure>
<figure><img src="image_16.png" /><figcaption>**Figure 13.** Grain size distribution of AKKO sample showing a Unimodal pattern.</figcaption></figure>

The particle size analyses show:

- An overall bimodal distribution, i.e. only the two most important fractions, silt and clay, appear, as shown in figures 2 and 3 for samples AKKB and AKKE. The respective percentages of silt (2 - 20 µm) are 52.6% and 51.2%, while the percentages of clay (0 - 2 µm) are relatively low, at 25.9% and 23.1% respectively.

- Clay and silt fractions are present in over 82.7%, while the sand fraction represents only a small proportion (17.3%), justifying the unimodal distribution of the particle size curves obtained in the case of the AKKO sample.

The GL shows that our samples are less rich in clay fraction (19.6% - 32.8%), but rich in silt fraction (41.8% - 64.2%). This observation is consistent with the particle size classification of ceramic raw materials from Cameroon, Morocco, and Turkey [44]. The predominance of silt-sized fractions (including quartz and feldspar grains) explains why the materials can contribute positively to the clay body skeleton, glass formation, and lowering of vitrification temperature [45].

Evaluation of the three clays on the basis of average grain size was carried out using a Winkler diagram shown in **Figure 14**.

<figure><img src="image_17.png" /><figcaption>**Figure 14.** Texture triangle and Winkler diagram of Kankan clays (Dondi, Fannri, and Guarini 1998).</figcaption></figure>

The projection indicates the clays' suitability for the production of perforated bricks (AKKB and AKKE) and common bricks (AKKO) (Winkler, 1954; Dondi
et al., 1998; Boussen et al., 2016) [46].

### 3.5.3. Specific Surface Area

The specific surface area of clays is a measure of the total surface area available per unit mass of clay. It includes the external surfaces of particles as well as the internal surfaces of pores and interstices. The specific surface areas of the samples are shown in the table below.

The specific surface of Kankan clays is 23.22 m²/g (AKKO), 30.29 m²/g (AKKB) and 33.48 m²/g (AKKE). According to these specific surface values, AKKO seems to contain less illite and smectite. In general, the specific surface area of kaolinite is generally between (10 - 30 m²/g), and that of illite (80 - 100 m²/g); values around 750 - 800 m²/g are observed for pure smectite [47] [33].

The AKKO clay sample has a lower specific surface area than AKKB and AKKE. Total specific surface area is influenced, among other things, by particle size: the greater the quantity of fine particles, the greater the increase in specific surface area. According to the literature, we can conclude that AKKO contains kaolinite, as its specific surface area is between 10 and 30 m²/g. This is in agreement with the results of the particle size distribution, where the fine fraction (<2 µm) is less important (20%) for AKKO [48].

The mean pore diameter equals 3.8 nm, ranging from 2 to 50 nm, showing that Kankan clays belong to the IUPAC mesopore class (Figure 15).

<figure><img src="image_18.png" /><figcaption>Figure 15. Discrete pore size distribution of Kankan raw clays.</figcaption></figure>

The Brunauer, Emmett, and Teller (BET) method is one of the most commonly used techniques for measuring the specific surface area of materials, applying nitrogen adsorption-desorption at its boiling point of 77°K [49].

According to the classification of the International Union of Pure and Applied Chemistry (IUPAC), the three clays show isotherms similar to type IV isotherms (Figure 16). These isotherms show a hysteresis loop and an adsorption limit in the high relative pressure region. The hysteresis loop is of type H3, indicating the presence of slit-shaped pores [50].

These types of curves exhibit three characteristic pressure intervals: (1) a rapid increase in the amount of gas adsorbed at relatively low pressure (< 0.10), (2) a stable increase at medium relative pressure (0.10 - 0.90), and (3) a sudden increase
at high relative pressure [51].

The notable feature observed in many hysteresis patterns is the forced closure of the desorption branch, where the isotherm “closes” at relative pressures P/P0 around 0.45 - 0.50 for N₂ isotherms, as illustrated by our **Figure 16** [51] [52].

Furthermore, the N₂ adsorption isotherms of our samples do not show a steep initial portion at low relative pressure, indicating a low presence of micropores (< 2 nm) (Deng *et al.*, 2017) [53]. The shape of the isotherms gives a qualitative assessment of the porous structure of the materials [54].

In summary, the profile of isotherms and their hysteresis loops indicate that clays have a porous structure mainly composed of mesopores. This type of pore is characteristic of the lamellar structure of clays [50].

The nitrogen adsorption-desorption isotherms for the three clays are shown in **Figure 16**.

<figure><img src="image_19.png" /><figcaption>**Figure 16.** Adsorption and desorption isotherms for Kankan clays.</figcaption></figure>

### 3.5.4. Plasticity Index

The plasticity index (IP = LL – LP) specifies the numerical difference between the Atterberg liquid limit (LL) and the Atterberg plastic limit (LP). Expressed as a percentage of the dry weight of a soil sample, it indicates the range of water contents between which the soil remains plastic. The Atterberg limits for clays are given in **Table 6**.

<table><caption>**Table 6.** Atterberg limits for Kankan clays.</caption><thead><tr><th rowspan="2">Atterberg limits (%)</th><th colspan="3">Samples</th></tr><tr><th>AKKB</th><th>AKKE</th><th>AKKO</th></tr></thead><tbody><tr><td>Liquidity limit</td><td>45.03</td><td>50.22</td><td>39.08</td></tr><tr><td>Plasticity limit</td><td>26.88</td><td>26.08</td><td>27.01</td></tr><tr><td>Plasticity index</td><td>18.15</td><td>24.14</td><td>12.07</td></tr><tr><td>Consistency index</td><td>2.39</td><td>1.87</td><td>3.13</td></tr></tbody></table>

The plasticity limits (LP) of samples AKKB, AKKE, and AKKO lie between 26.08 and 27.01%, and their liquidity limits (LL) are between 39.08% and 50.22%.
The plasticity index (PI) is in the range (12.07% - 24.14%); and the consistency index between (1.87% and 3.13%). The PI of clay samples between 12% and 25% shows that they are not very plastic.

According to Abdelmalek *et al.* (2017), the differences in the plasticity of the samples studied can be explained mainly by the nature of the particle size distribution. These relatively low plasticity index values are directly related to the clay content of our samples.

According to Abdelmalek *et al.* (2017), other factors can affect plasticity properties, such as geological formation, the presence of impurities (*i.e.* non-clay minerals), and organic matter [55]. The plasticity index of our samples is lower than Turkish clay (31% - 33%) (Celik, 2010), and high compared to Brazilia clay (6.5% - 9.8%) (Azzi *et al.*, 2018), Ngaye alluvial clay in Cameroon (9.8% - 20.8%) (Fadil-Djenabou *et al.*, 2015).

Plasticity indices between 5% and 30% confirm the presence of kaolinite in our samples [29]. These results are in line with the range defined in the literature for ceramic production (Célic, 2010; Dondi *et al.*, 2014; Boussen *et al.*, 2016; Mahmoud *et al.*, 2017).

## 4. Conclusions

The Kankan clays studied display promising characteristics for fabricating construction materials.

The results of mineralogical, physicochemical, geotechnical, and structural characterization of these samples revealed the presence of kaolinite, illite, and montmorillonite, as well as quartz. Clinochlore, muscovite, microcline, gibbsite, and magnetite are also present. Quartz and alumina act as natural binders. Alkalis and alkaline earth are present in small quantities (around 1%), classifying these clays as sandy-clay soils with low plasticity.

According to the Winkler diagram, these clays are suitable for the production of perforated bricks (AKKB and AKKE) and common bricks (AKKO). The location of the samples on the Augustinik diagram clearly shows the deficiencies in alkaline and alkaline-earth elements, especially for the AKKE clay.

The silica-alumina (2.61 - 3.45) and alumina-iron oxide (2.65 - 5.32) ratios not only provide information on the moisture permeability of the raw materials, but also indicate the possibility of their use in the manufacture of building materials (bricks, tiles). The specific surface shows type IV isotherms indicating that the clays possess a mesoporous structure, which has important implications for their adsorption properties and industrial applications. The presence of mesopores and the associated hysteresis loop show a significant capacity to adsorb and retain molecules, which can be useful in many chemical and environmental processes.

The plasticity limits (LP) of samples AKKB, AKKE, and AKKO range from 26.08% to 27.01%, and their liquidity limits (LL) from 39.08% to 50.22%. The relatively low plasticity index of the clay samples (12.07% to 24.14%) shows that they are not very plastic, which is linked to the particle size distribution.
On the basis of their mineralogical, particle size and chemical composition, as well as their geotechnical properties, our clays offer promising potential for use in eco-construction. However, specific additions may be required to optimize their performance, as suggested by Augustinik's figure.

## 5. Perspectives

This study opens up new perspectives highlighting the potential of the clays studied for effective exploitation in the construction and environmental fields:

* Carry out tests on the mechanical and thermal resistance and carbon footprint of natural and stabilized materials, which will be the subject of the next publication.

* Exploit these clays for the manufacture of perforated bricks (AKKB and AKKE), common bricks (AKKO), and roof tiles, taking advantage of their mineralogical composition and silica-alumina and alumina-iron oxide ratios.

* Studying mesoporous clays for use in pollutant management and the creation of geotechnical barriers in environmental projects.

## Conflicts of Interest

The authors declare no conflicts of interest regarding the publication of this paper.

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