# Australian Fires 2019–2020: Tropospheric and Stratospheric Pollution Throughout the Whole Fire Season

Corinna Kloss, Pasquale Sellitto, Marc von Hobe, Gwenaël Berthet, Dan Smale, Gisèle Krysztofiak, Chaoyang Xue, Chenxi Qiu, Fabrice Jégou, Inès Ouerghemmi, et al.

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## To cite this version:

Corinna Kloss, Pasquale Sellitto, Marc von Hobe, Gwenaël Berthet, Dan Smale, et al.. Australian Fires 2019–2020: Tropospheric and Stratospheric Pollution Throughout the Whole Fire Season. Frontiers in Environmental Science, 2021, 9, 10.3389/fenvs.2021.652024. insu-03469261

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# Australian Fires 2019–2020: Tropospheric and Stratospheric Pollution Throughout the Whole Fire Season

Corinna Kloss<fnref n="1" />*, Pasquale Sellitto<fnref n="2" />, Marc von Hobe³, Gwenaël Berthet<fnref n="1" />, Dan Smale⁴, Gisèle Krysztofiak<fnref n="1" />, Chaoyang Xue<fnref n="1" />, Chenxi Qiu³, Fabrice Jégou<fnref n="1" />, Inès Ouerghemmi<fnref n="1" /> and Bernard Legras<fnref n="5" />

## OPEN ACCESS

**Edited by:**

Bin Yuan,
Jinan University, China

**Reviewed by:**

Pengfei Yu,
Jinan University, China

Richard Pope,
University of Leeds, United Kingdom

**\*Correspondence:**

Corinna Kloss
corinna.kloss@cnrs-orleans.fr

**Specialty section:**

This article was submitted to *Atmosphere and Climate*, a section of the journal *Frontiers in Environmental Science*

**Received:** 11 January 2021

**Accepted:** 03 June 2021

**Published:** 08 July 2021

**Citation:**

Kloss C, Sellitto P, von Hobe M, Berthet G, Smale D, Krysztofiak G, Xue C, Qiu C, Jégou F, Ouerghemmi I and Legras B (2021) Australian Fires 2019–2020: Tropospheric and Stratospheric Pollution Throughout the Whole Fire Season. *Front. Environ. Sci.* 9:652024. doi: 10.3389/fenvs.2021.652024

The historically large and severe wildfires in Australia from September 2019 to March 2020 are known to have injected a smoke plume into the stratosphere around New Year, due to pyro-cumulonimbus (pyro-Cb) activity, that was subsequently distributed throughout the Southern Hemisphere (SH). We show with satellite, ground based remote sensing, and *in situ* observations that the fires before New Year, had already a substantial impact on the SH atmosphere, starting as early as September 2019, with subsequent long-range transport of trace gas plumes in the upper-troposphere. Airborne *in situ* measurements above Southern Argentina in November 2019 show elevated CO mixing ratios at an altitude of 11 km and can be traced back using FLEXPART trajectories to the Australian fires in mid-November 2019. Ground based solar-FTS (Fourier Transform Spectroscopy) observations of biomass burning tracers CO, HCN and C₂H₆ at Lauder, South Island, New Zealand show enhanced tropospheric columns already starting in September 2019. In MLS observations averaged over 30°–60°S, enhanced CO mixing ratios compared to previous years become visible in late October 2019 only at and below the 147 hPa pressure level. Peak differences are found with satellite and ground-based observations for all altitude levels in the Southern Hemisphere in January. With still increased aerosol values following the Ulawun eruption in 2019, averaged satellite observations show no clear stratospheric and upper-tropospheric aerosol enhancements from the Australian fires, before the pyro-Cb events at the end of December 2019. However, with the clear enhancement of fire tracers, we suggest the period September to December 2019 (prior to the major pyro-Cb events) should be taken into account in terms of fire pollutant emissions when studying the impact of the Australian fires on the SH atmosphere.

**Keywords:** australian wildfires, biomass burning tracers, upper troposphere/lower stratosphere, fire plume, long range transport

<footnote n="1">¹Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (UMR 7328), CNRS/Université d'Orléans, Orléans, France,</footnote>

<footnote n="2">²Laboratoire Interuniversitaire des Systèmes Atmosphériques (UMR 7583), CNRS/ Université Paris-Est Créteil/ Université de Paris/ Institut Pierre Simon Laplace (IPSL), Créteil, France, ³Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-7), Jülich, Germany, ⁴National Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New Zealand,</footnote>

<footnote n="5">⁵Laboratoire de Météorologie Dynamique (UMR 8539), ENS-PSL/ Sorbonne Université/ École Polytechnique, Paris, France</footnote>
# 1 INTRODUCTION

As a result of the anthropogenic induced global warming, the global frequency and/or severity of wildfires has been shown to increase in more than 100 studies published since 2013 (Smith et al., 2020). Especially in Australia, projections show a clear trend toward fire weather (Dowdy et al., 2019). From September 2019 to March 2020 Australia experienced the largest recorded wildfire ever recorded in Australia (Boer et al., 2020). The year 2019 was the warmest and driest spring on record in Australia (Bureau of Meteorology, Australia). Around New Year 2020, several strong Pyro-Cbs (Pyro-cumulonimbus) developed and injected gaseous and particulate combustion products into the Upper-Troposphere and Lower-Stratosphere (UTLS) (Khaykin et al., 2020; Boer et al., 2020). Khaykin et al. (2020) find that $0.4 \pm 0.2$ Tg of particulate matter was injected into the stratosphere and show that the stratospheric Aerosol Optical Depth (AOD) perturbation was the highest ever measured for wildfires and comparable to that of moderate stratospheric volcanic eruptions (e.g. Calbuco in 2015, Raikoke in 2019). Furthermore, Ohneiser et al. (2020) show observations of elevated aerosol over Punta Arenas (in Chile) originating from the Australian fires in January and February 2020. Through solar heating of a smoke patch, at least three self-maintaining anticyclonic vortices formed and were observed (Khaykin et al., 2020; Kablick et al., 2020). A particularly stable vortex was larger than 1,000 km in diameter, rose up to 35 km altitude and traveled 66,000 km over a 13 week period (Khaykin et al., 2020). The last major fires in Australia with a subsequent stratospheric plume were reported in 2009. This fire event, labeled “black Saturday” (Siddaway and Petelina, 2011), caused smoke particles to remain in the UTLS for around 4 months. The burned area of the Australian fires in 2019/2020, was by a factor of more than 10 larger (5.8 million compared to 450,000 hectar) than what was reported for the fires in 2009 (Khaykin et al., 2020; Siddaway and Petelina, 2011). The Australian fire season 2019/2020 has been reported to be the strongest on record in terms of aerosol injected into the stratosphere and consequential radiative forcing (Khaykin et al., 2020). The recent historically severe wildfire season in Canada in 2017 is another example for significant UTLS aerosol perturbation. A family of self-maintaining rising vortices, as described for the Australian fires 2019–2020, was also observed (Lestrelin et al., 2020). The aerosol depolarization ratios observed in Chile from the Australian fires agree well with what has been seen above Europe after the Canadian wildfires in 2017 (Ohneiser et al., 2020).

Besides the direct injection of aerosols, wildfires release trace gases into the atmosphere. For CO (carbon monoxide), $C_2H_6$ (ethane) and HCN (hydrogen cyanide) biomass burning emission is the main direct atmospheric source (Watson et al., 1990; Rinsland et al., 1998; Lobert et al., 1990) in the SH and the main factor driving their seasonal cycle in the SH sub-tropics (Rinsland et al., 1998; Zeng et al., 2012; Schaefer et al., 2018). For OCS, the main atmospheric sources are oceans and anthropogenic emissions. Nevertheless, biomass burning is estimated to contribute more than 10% to the atmospheric OCS budget (Stinecipher et al., 2019). The main sink is uptake by

vegetation. The atmospheric lifetime of OCS is estimated at approximately 2 years (Campbell et al., 2008), with a stratospheric lifetime between 58 and 68 years (Krysztofiak et al., 2015). The latitude dependent CO lifetime is between ~1 month and 1 year. It is mainly removed by oxidation, with a longer lifetime toward the poles (Staudt et al., 2001). HCN has a tropospheric lifetime of around 5 months (Li et al., 2009) and a photochemical, stratospheric lifetime of >10 years (below 30 km altitude) (Kleinböhl et al., 2006). The dominant sink for HCN is ocean uptake. In the Northern Hemisphere (NH), the main atmospheric source for $C_2H_6$ is of anthropogenic nature from biofuel combustion and transport, around 18% stems from biomass burning (Xiao et al., 2008). In the SH, however, biomass burning together with interhemispherical transport are the main sources (Xiao et al., 2008). The main sink is the reaction with OH. It has a tropospheric lifetime of 30 days to 10 months depending on latitude and season (shorter in the tropics and during summer) (Xiao et al., 2008).

Khaykin et al. (2020) show that biomass burning trace gases (i.e. CO and $CH_3CN$), as well as aerosols, experience a sharp increase in stratospheric burden starting in January 2020. The bulk of trace gas and aerosol injection into the UTLS occurred between December 29th and 31st. One major event on January 5th has been extensively analyzed in the aforementioned studies. However, extensive and significant bush fire activities already started in September 2019. Here, we investigate the impact of the Australian fires on the atmosphere already prior to the stratospheric injection phase in December 2019.

The data sets and methods used within this study are introduced in **Section 2**. **Section 3.1** discusses a case study of an intercontinental transport of emitted fire air masses. In **Section 3.2** we investigate the possibility and the significance of a possible stratospheric impact of fire tracers and aerosols in two time intervals, one before the major injection phase in SH spring 2019/2020 (September 01, 2019 to December 20, 2019) and one including the injection phase around New Year (December 01, 2019 to February 20, 2020). Conclusions are drawn in **Section 4**.

# 2 METHODS

## 2.1 AMICA

The Airborne Mid-Infrared Cavity enhanced Absorption spectrometer (AMICA) employs Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS) to measure trace gases including CO, OCS, $CO_2$ and $H_2O$ [for a detailed instrument description, see Kloss et al. (2021b), and von Hobe et al. (2020)]. From September to November 2019, AMICA was deployed on the German research aircraft HALO (High Altitude and LOng Range Research Aircraft) during the SouthTRAC campaign based in Rio Grande in southern Argentina. In this study we use CO measurements from a flight on November 12, 2019, specifically focusing on the data obtained at altitudes between 8 and 12 km at approximately 55°S and 68°W. Data are averaged over 30 s and have a precision of around $\pm 3$ ppb (nmol/mol) (Kloss et al., 2021b). It should be noted that the AMICA OCS
measurements from SouthTRAC are still undergoing quality checks and these observations will be subject of a future paper.

## 2.2 MIR FTS Partial and Total Column Observations

The ground-based solar Mid-Infrared Fourier Transform Spectrometer (MIR FTS) obtains spectra over the wavenumber region 700–4,000 cm⁻¹ at a spectral resolution of 0.0035 cm⁻¹. The MIR FTS instrument is located at NIWA’s (National Institute of Water and Atmospheric Research) atmospheric research laboratory located at Lauder, New Zealand (45°S, 170°E, 370 AMSL) (see also Supplementary material). Measurements are taken year-round in direct Sun cloud free conditions. Observations are taken under the auspices of the Network for the Detection of Atmospheric Composition Change (NDACC) (De Mazière et al., 2018). Trends and variations of HCN, CO and C₂H₆ at NIWA have been analyzed in Zeng et al. (2012); Rinsland et al. (2002). The OCS retrieval strategy is an updated version to that used in Kremser et al. (2015). Here, we use the Lauder CO, HCN, C₂H₆ and OCS data sets from 2002 to mid-2020. The optimal estimation retrieval strategies for the trace gases CO, OCS and HCN contain enough information (degrees of freedom) to allow partitioning of the retrieved profiles into stratospheric (~11–100 km) and tropospheric (0–~11 km) partial columns. There is not enough information in the C₂H₆ retrieval to extract an independent stratospheric partial column.

## 2.3 MLS: CO and HCN Observations

The Microwave Limb Sounder (MLS) performs vertical profile measurements of water vapor and multiple trace gases in the UTLS on the National Aronautics and Space Administration’s Aura satellite since 2004 (Waters et al., 2006). Here, we use the CO and HCN observations (version 5) between July 2019 and June 2020 for the area 160–175°E, 32–58°S. Data are filtered according to the data screening guidelines (Livesey et al., 2020). MLS has a dense sampling, obtaining one vertical profile each 165 km (3,500 profiles per day), with a vertical resolution of ~2–5 km. World Meteorological Organization (WMO) tropopause pressure levels are provided within the MLS data set. The MLS data product is on a pressure resolved vertical grid. For the tested time frame and area, CO observations are available above the 316 hPa (with six given pressure levels between 316 and 32 hPa) and 100 hPa for HCN (with four pressure levels between 100 and 32 hPa).

## 2.4 SAGE III/ISS: Aerosol Extinction Observations

The Stratospheric Aerosol and Gas Experiment on the International Space Station (SAGE III/ISS) is a solar (and lunar) occultation spectrometer operating since 2017 (Cisewski et al., 2014). Here, we use the aerosol extinction observations (version 5.1) at 521 nm for a limited area (160°–175°E, 32–58°S) for the Australian wildfire season 2019–2020. Data are provided between 0.5 and 40 km altitude with a vertical resolution of ~1 km and a

horizontal resolution of ~200 km. Tropopause height values within the data set originate from MERRA-2 [Modern-Era Retrospective analysis for Research and Applications, Version 2, (Gelaro et al., 2017)]. Data have been cloud-filtered according to the method described in Thomason and Vernier (2013).

## 2.5 OMPS: Aerosol Extinction Observations

The Ozone Mapping and Profiler Suite (OMPS) Limb Profiler (LP) is a limb-instrument on the Suomi National Polar-orbiting Partnership satellite since 2012 (Loughman et al., 2018; Bhartia and Torres, 2019). With the new data version 2.0, OMPS provides aerosol extinction measurements at six different wavelengths (510, 600, 675, 745, 869 and 997 nm). The dense sampling results in a global coverage within 3–4 days. The vertical resolution is estimated to be ~1.6 km (Bhartia and Torres, 2019). Tropopause height values within the data set originate from MERRA-2 (as with SAGE III/ISS). Here, we use the 675 nm channel measurements for the same time and area as described for SAGE III/ISS. Data have not been cloud filtered.

## 2.6 FLEXPART: Back-Trajectory Simulations and Limitations

The Lagrangian transport and diffusion model FLEXPART version 9.0.3 is used to simulate long-range transport of atmospheric tracers (Stohl et al., 2005) with a similar set up as in Brocchi et al. (2018). Model calculations are based on ERA5 (Hersbach et al., 2020) meteorological data from the European Center for Medium-Range Weather Forecasts (ECMWF) extracted at hourly intervals with a horizontal resolution of 0.5 × 0.5 and a vertical resolution of 137 model hybrid levels (from the ground to 0.01 hPa pressure altitude). Backward trajectories are released from the location of the *in situ* observations and the FLEXPART model outputs are distributed over a regular vertical grid from the surface to 45 km in altitude. Here, we use the integration of the trajectory positions over this altitude range. A few limitations have to be taken into consideration when interpreting the calculated back-trajectories in this study. Firstly, the vertical motion induced by aerosol heating (typical for forest fire plumes) is not included in FLEXPART or any reanalysis driven trajectory simulations. For the Australian fire plume, the largest observed sustained ascent rate was 10 K per day (potential temperature), that is about 1 km/day (Khaykin et al., 2020). Secondly, the reanalysis tends to produce a cooling/descent at warm anomalies, forced by the assimilation. However, because we are only performing trajectory simulations of one week and less and focus on a plume emitted before the major events in December, we believe FLEXPART simulations in our study to be largely representative. Real et al. (2010) indicate that model induced errors in concentration between two airborne observations of the same plume are not significant for a back-trajectory time frame of less than a week. And lastly, Podglajen et al. (2014) describe balloon experiments, in which trajectories over the Pacific are often not completely reliable because of the lack of observations constraining Kelvin waves. Hence, we take
<figure><img src="image_4.png" /></figure>

**FIGURE 1** | Airborne CO (blue) *in situ* observations and respective altitude information (black) on November 12th 2019 at around 57°S and 67°W. The two vertical lines (a, b) indicate initialization times for back trajectory calculations (**Figure 2**).

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**FIGURE 2** | FLEXPART 10-day back trajectories (total column), originating from the respective points (as shown in **Figure 1**). (A1) and (B-1) correspond to an integration of the trajectory positions over the whole altitude range (surface to 45 km altitude). (A-1) Trajectories initialized at point a: 12/11, 11 h 25 (UTC), 53.68°S, 68.60°W, 9 km, (B-1) point b: 12/11, 11 h 35 (UTC), 54.86°S, 68.18°W, 11.18 km. The red cross (South Argentina) represents the initialization point of the back-trajectories. Numbers indicate the number of days along the trajectories. (A-2) The vertical view of the back trajectories respective to (A-1) and (B-2) respective to (B-1).

the presented trajectory simulations of position and timing as estimations rather than detailed facts.

# 3 RESULTS

## 3.1 Case Study November 12th 2019: Elevated CO Over Southern Argentina

CO mixing ratios up to 400 ppb at approximately ~ 11 km altitude (Figure 1) were observed near the southern tip of South America by the AMICA instrument onboard HALO during the first hour of a SouthTRAC measurement flight of November 12th 2019. This significantly exceeds background CO mixing ratios below 50 ppb observed at altitudes between 11 and 14 km throughout the rest of the measurement flight. Staudt et al. (2001) estimate the atmospheric CO lifetime in the SH south of 45°S greater than 100 days, making CO a suitable direct biomass burning tracer for long-range transport at the investigated latitudes. In the following, we investigate the origin of the observed CO plume, choosing two points along the flight path (marked in Figure 1) for trajectory analysis (Point a at 11 h 25 UTC 53.68°S, 68.60°W, 9 km, 305 hPa and Point b at 11 h 35, 54.86°S,

68.18°W, 11.18 km, 216 hPa). Point b along the flight path is chosen because of the observed high mixing ratios especially considering the altitude (11 km). Point a is chosen as a reference point with no significant CO enhancement, observed only 10 min prior to point b (with peak CO values) along the measurement flight path. The respective FLEXPART total column back trajectory simulations initialized at points a and b (indicating the residence time of particles) are presented in Figure 2. Figure 2A-1 and Figure 2B-1 display the horizontal trajectory paths, whilst vertical movement is shown in Figure 2A-2 and Figure 2B-2, respectively. Trajectories from point b pass over the south west tip of the South Island, New Zealand and South-East Australia 3-4 days prior to AMICA observations, remaining at altitudes mostly above 10 km with a significant component at ground level in South East Australia. Simulated trajectories for point a take a different path, i.e. the total column values are higher further North over New Zealand compared to Figure 2B-1 and the trajectories mainly remain there for several days. It is only around ~ 10 days before the initialization (i.e. before AMICA observations at point a) trajectories passed over South Australia, a time when no significant plumes have been observed (Supplementary Figure S1).
<figure><img src="image_7.png" /><figcaption>**FIGURE 3** | MLS mean CO mixing ratios along the orbit, between the tropopause and 100 hPa below the tropopause (~ 9 km) on a 2° latitude and 5° longitude grid, from November 6th to 8th (A), 8th to 10th (B) and 10th to 12th 2019 (C). The chosen grid roughly represents the horizontal resolution of MLS. The red box indicates an area that is later used for aerosol analysis in this study (160–175°E, 32–58°S). The red cross (within the red box) indicates the location of Lauder.</figcaption></figure>

The contribution of emissions from South Australia is particularly evident for point b. However, due to the limitations of such simulations (as discussed in **Section 2.6**), we see the presented trajectories as a rough guideline rather than trusting each single coordinate in location and time. According to the position and time of the back-trajectory simulations initialized at point b, we investigate space-borne MLS CO observations over South-East Australia and the South Island, New Zealand (**Figure 3**). Between November 8th and 10th large increases of CO mixing ratios, up to 500 ppb, are observed by MLS below the tropopause (~ 9 km altitude) south of New Zealand. Substantial enhancements of CO (and H₂O) mixing ratios after the pyro-convection events in December 2019 were also observed by MLS (Khaykin et al., 2020). No substantial increases of CO mixing ratios with MLS are observed prior to November 8th, probably due to plume altitudes being too low to be detected by MLS. Computed FLEXPART trajectories from **Figure 2B** pass over the region with enhanced CO mixing ratios (**Figure 3**). This suggests that MLS CO satellite observations and AMICA *in situ* measurements have looked at the same plume 3 days and 8,000 km apart. The vertical view of FLEXPART back trajectories in **Figure 2A–2** and **Figure 2B–2** (respectively to point a and b) confirms a high probability of contribution to the measured air mass by AMICA from the surface level in South-East Australia. Hence, the air masses with enhanced CO mixing ratios measured by AMICA in Argentina are very likely to originate from the wildfires in Australia. Partial CO column values were measured by the MIR FTS at Lauder (indicated with a red cross in **Figure 3**). Unfortunately, no measurements between the 8th and 12th of

November were taken. Therefore, either; 1) the plume (as seen in **Figure 3**) was spatially narrow with no significant contribution above South New Zealand, or 2) it was limited in time to less than 3 days and therefore not detected within the data gap. This is entirely possible as plumes typically pass over Lauder within a day or two (as will also be shown for a plume on January 1st 2020 in **Section 3.2**). Furthermore, independent and decoupled boundary layer *in situ* FTIR analyzer observations at Lauder (Smale et al., 2019) also recorded sharp increases in CO mixing ratios in November (see **Supplementary Figure S2a**). HYSPLIT trajectories initialized at the location and time of the first peak (**Supplementary Figure S2a**) confirm that air masses partly originate from the South-East of Australia 3 days prior to the observed peak values (**Supplementary Figure S2b**). This supports the suggestion that significant smoke patches have been released by the fires already in November.

## 3.2 Fire Tracer and Aerosol Evolution Throughout the Australian Fire Season 2019/2020: Pre- and Post-Stratospheric Injection of December 2019

**Figure 4** shows total column FTS observations at the NIWA station in Lauder for the biomass burning tracers CO, HCN, C₂H₆ and for OCS (Figures 4A,C,E,G respectively). With the predominant westerly winds, Lauder is at a good location to likely observe “fresh” plumes coming from Australia. Significant increases in total column values and variability throughout the whole fire season are observed for CO, HCN and C₂H₆ (September 2019–March 2020). Sharp (almost visible as a line) increases observed at the end of December/beginning of January (left column in **Figure 4**), indicate the major events which led to the stratospheric perturbation with consequent stratospheric smoke vortices, discussed in Khaykin et al. (2020); Kablick et al. (2020). To account for seasonal variations in column abundances and to have a quantitative comparison to the fire seasons of previous years, the second column in **Figure 4** shows 14-day mean total column of CO, HCN, C₂H₆, and OCS averaged for the measurement record from 2002 to 2018 with respective mean 14-day standard deviations. The standard deviation is an indicator for the variability of the plume composition and density. Because composition and properties of fire and volcano plumes are more variable at distances closer to the source, and become increasingly diluted with increasing distances (Sellitto et al., 2020), the observed larger standard deviations starting from end of December 2019, in **Figure 4**, point to a series of denser and dispersing/evolving fire plumes in this period. The climatological mean includes the fire season from 2009. However, comparisons (not shown) have revealed that the 2009 fire season has not had a significant impact on the observations made at Lauder. This is in accordance to Siddaway and Petelina (2011), who state that most of the smoke plumes remained between the latitudes range 5–25°S.

In **Figure 4B**, the seasonal cycle of CO is evident with increasing values during July-October and decreasing CO values during November-January. Through the impact of the extreme fire event in 2019/2020, CO total column values decrease
<figure><img src="image_8.png" /></figure>

<figure><img src="image_9.png" /></figure>

<figure><img src="image_10.png" /></figure>

<figure><img src="image_11.png" /></figure>

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**FIGURE 4** | (A), (C), (E) and (G) CO, HCN, C₂H₆ and OCS total column NDACC MIR FTS observations at Lauder, New Zealand, May 2019 to June 2020 respectively. The yellow background indicates the fire season from September 2019 to March 2020. (B), (D), (F) and (H) are 14-day mean total columns (with 1-sigma standard deviation) averaged over the period 2002 to 2018 (red) and for the 2019/2020 period (black).

later (in February–March) than usual (black line compared to red line in **Figure 4B**). As a biomass burning tracer, the seasonal cycle of HCN at Lauder depends largely on the extent of the seasonally occurring wild fires (Jones et al., 2001; Zeng et al., 2012). Abundances of HCN in the SH peak during October through November as seen for the 2002–2018 average. Because of the fire event in 2019/2020, maximum total column HCN values are shifted by around two months (to January). The underlying variation of the C₂H₆ column values displayed in **Figure 4** follows the climatological seasonal cycle with maximum values in September/October (transport from the NH to the SH is highest in NH winter combined with the SH summer biomass burning source) (Xiao et al., 2008).

For the three biomass burning tracers CO, HCN and C₂H₆, total column values are elevated from November to April during the Australian fire season 2019/2020 compared to the climatological average. Variability of all three trace gases is elevated throughout the whole fire season starting from

September, pointing to overpasses of fresh fire plumes. This indicates that the fires already had a notable influence on the SH atmosphere, well before the pyro-Cb injection events around New Year (2019/2020). However, we cannot dismiss contributions from other biomass burning events [e.g. the Amazonian fires from 2019, Lizundia-Loiola et al. (2020)].

Respective to **Figures 4B,D, Supplementary Figure S3** shows the stratospheric (12–120 km) column values for CO and HCN measured at Lauder. For CO, stratospheric column values (**Supplementary Figure S3a**) only show a significant increase (compared to the months prior to the fire: May to August 2019) for the December to February time frame, while the total column (**Figure 4B**) was already visibly impacted by the fires in September 2019 for all three gases. Within biomass burning plumes, increased OH values might lead to a faster depletion of CO and C₂H₆, while HCN has a longer photochemical lifetime. The biomass burning tracer HCN shows a significant increase in the stratosphere already in October. However, because an
<figure><img src="image_16.png" /><figcaption>**FIGURE 5** | MLS 15-day mixing ratio zonal averages for 2019/2020 (black) and 2005–2018 (red, with the respective inter-annual standard deviations) for CO at 68 (A), 100 (B), 147 (C) and 215 hPa (D) pressure levels.</figcaption></figure>

increase in stratospheric column values is common in October (e.g. **Supplementary Figure S3b**, red line), it cannot be clearly attributed to the Australian fires. Hence, the troposphere was clearly impacted throughout the whole fire season (September to March). The stratosphere was only clearly impacted following the pyro-Cb events in December 2019/January 2020.

Because of its long lifetime in the free troposphere, sharp increases as seen for CO, HCN and C₂H₆ column values are not expected for OCS. The observed OCS column values (**Figure 4H**) follow the typical OCS seasonality in the SH. Lowest concentrations are detected during winter (July) because of high oceanic fluxes of OCS (and CS₂, DMS as OCS precursors) in summer (Kettle et al., 2002). Even in January 2020, when other biomass burning tracers (CO, HCN and C₂H₆) show a very large increase, total column values do not significantly deviate from the climatological pattern. In order to detect a biomass burning induced increase of OCS, it would likely be necessary to study a fresh,

concentrated plume, which is outside of the scope of the present study.

In **Figure 5**, we show the evolution of CO mixing ratios observed by MLS zonally averaged over the 30–60°S latitude range compared to the climatological average (2005–2018) on different pressure levels within the UTLS (68, 100, 147 and 215 hPa). For the two higher levels (at 68 and 100 hPa) CO mixing ratios in 2019 closely follow the climatological average until the pyro-Cb events in January, confirming that there is no significant impact of the earlier fires at these levels. On the lower levels (at 215 and 147 hPa) a slight CO enhancement above the climatological average becomes visible in late October that might be attributed to the earlier part of the fire season. The enhancement becomes very pronounced with the pyro-Cb events around New Year.

To investigate aerosol increases within the plumes passing over the defined region in **Figure 3**, we look at SAGE III/ISS and OMPS aerosol extinction observations averaged over the
<figure><img src="image_17.png" /><figcaption>**FIGURE 6** | (A) SAGE III/ISS 15-day mean Aerosol extinction values at 521 nm over the region 160–175°E, 32–58°S (red box, as indicated in **Figure 3**). The red vertical, dashed line represents the time of the observed enhanced CO values from **Figure 3**. The black dashed line represents the average tropopause altitude. (B) OMPS 2-day mean Aerosol extinction values at 675 nm for the red box.</figcaption></figure>

defined red box from 2018–2020. Tropospheric aerosols are rapidly dispersed and because of wet deposition, they have a significantly shorter lifetime than aerosols in the stratosphere. It is therefore expected that the impact on the stratosphere of the Australian fires before the pyro-Cb events was significantly smaller. Both SAGE III/ISS and OMPS (Figures 6A,B respectively) reveal limited aerosol extinction enhancements in the lower stratosphere September-November 2019 (around the red vertical line in Figure 6), before the January 2020 pyro-Cb events in the red box. For the SAGE III/ISS data set, clouds have been filtered according to Thomason and Vernier (2013). Smoke aerosols in clouds may therefore not be visible in **Figure 6A**. Aerosol enhancements in the lower stratosphere around November 2019 coincide with zonally averaged peak stratospheric Aerosol Optical Depth (AOD) values in the SH (30–50°S) following the Ulawun eruption in 2019 [see Figure 8 in Kloss et al. (2021a)]. Thus aerosol extinction attribution to stratospheric injections during the Australian fires before New Year (pyro-Cb events) are hard to segregate out (Figure 6). Enhanced aerosol extinction values in the lower stratosphere at the end of 2018 can be attributed to the

Ambae eruption in 2018, with peak stratospheric AOD values in the SH in October 2018 (Kloss et al., 2020; 2021a).

A substantial increase of aerosol extinction values is observed starting from January 2020 [as also shown in Khaykin et al. (2020)]. Enhanced aerosol observations up to ~ 30 km altitude in February 2020 (26 km in SAGE III/ISS data, **Figure 6**) correspond in position and time to the described vortex in Khaykin et al. (2020) passing above the South Island, New Zealand on February 17th. The visible increases above 15 km altitude in **Figure 6A** can be attributed to the ascending smoke vortices or the trails they leave behind along the way.

## 4 CONCLUSION

A record-breaking fire season in terms of intensity, duration and atmospheric impacts took place in Eastern Australia from late 2019 to early 2020. This event caused exceptionally strong pyro-Cb events (starting at the end of December 2019) that injected trace gases and aerosols into the stratosphere.
A substantial increase in aerosol extinction above 10 km altitude is only observed starting from January 2020, while aerosol enhancements before the pyro-Cb injection events (December 2019/January 2020) might have been masked by clouds and still elevated background conditions from the Ulawun eruption (August 2019). Biomass burning tracer mixing ratios peak in January 2020 (in the troposphere and stratosphere). However, we find that total column measurements of CO, HCN and C₂H₆ above Lauder, New Zealand significantly increased from November 2019 and lasting until April 2020. Furthermore, we find that the frequency of fresh bypassing trace gas plumes is higher than the climatological average throughout the whole fire season.

When studying the atmospheric impact of the historically severe wildfires in Australia 2019/2020 especially in terms of emitted trace gases, we recommend considering the whole Australian fire season (September 2019 to March 2020) rather than only focusing on the stratospheric impact after the pyro-Cb events around New Year.

## DATA AVAILABILITY STATEMENT

The AMICA CO data will be made available in the HALO data base under https://doi.org/10.17616/R39Q0T. The Lauder MIR FTS data sets are available on the NDACC public database ftp.cpc.ncep.noaa.gov/ndacc/station/ lauder/hdf/ftir. The Lauder *in situ* CO data set can be obtained by directly contacting Dan Smale, until it is made publicly available on the World Data Centre for Greenhouse Gases (https://gaw.kishou.go.jp). MLS data are available at http://disc.sci.gsfc.nasa.gov/Aura/data-holdings/MLS. The SAGE III/ISS aerosol extinction data set (v5.1) is available at https://eosweb.larc.nasa.gov and OMPS v2.0 data at https://daac.gsfc.nasa.gov/.

## AUTHOR CONTRIBUTIONS

CK designed and managed the research. PS, GB, BL, MV, and DS contributed to the analysis of results. MV, CQ, and DS contributed

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## FUNDING

CK was funded by Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)—409585735. CQ is supported by the graduate school HITEC (Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research). Measurements made at Lauder are core funded by NIWA through New Zealand's Ministry of Business, Innovation and Employment Strategic Science Investment Fund. This work has been supported by the Programme National de Télédétection Spatiale (PNTS, http://www.insu.cnrs.fr/pnts), grant n°. PNTS-2019-9 and by the CNES (Centre National d'Études Spatiales), TOSCA/IASI grant.

## ACKNOWLEDGMENTS

The authors are grateful for the support of Agence Nationale de La Recherche under grant ANR-17-CE01-0015 (TTL-Xing). Support from the VOLTAIRE project (ANR-10-1ABX-100-01) funded by ANR through the PIA (Program d'Investissement d'Avenir) is gratefully acknowledged. The authors acknowledge NASA, SAGE III/ISS and OMPS teams. The SouthTRAC campaign is a joint atmospheric research project by German research centers and universities within the DFG HALO-SPP 1294 framework; the authors would also like to thank the SouthTRAC coordinators as well as the flight and ground teams for their support during the campaign.

## SUPPLEMENTARY MATERIAL

The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fenvs.2021.652024/full#supplementary-material

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**Conflict of Interest:** The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

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