Crystal structure of dicarbonyl[μ 2 -methylenebis(diphenylphosphane)-κ 2 P : P '][μ 2 -2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κ P )ironplatinum( Fe - Pt )-dichloromethane–toluene (1/1/2), [(OC) 2 Fe(μ-dppm)(μ-C(=O)C(2,4,5-C 6 H 2 Me 3 )=CH)Pt(PPh 3 )]

Lukas Brieger, Isabelle Jourdain, Michael Knorr, Carsten Strohmann

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Lukas Brieger, Isabelle Jourdain, Michael Knorr, Carsten Strohmann. Crystal structure of dicarbonyl[μ 2 -methylenebis(diphenylphosphane)-κ 2 P : P '][μ 2 -2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κ P )ironplatinum( Fe - Pt )-dichloromethane–toluene (1/1/2), [(OC) 2 Fe(μ-dppm)(μ-C(=O)C(2,4,5-C 6 H 2 Me 3 )=CH)Pt(PPh 3 )]. Acta crystallographica Section E: Crystallographic communications [2015-..], 2019, 75 (12), pp.1902-1906. 10.1107/S2056989019015573 . hal-02393655

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Acta Cryst.

E

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN 2056-9890

Received 12 November 2019

Accepted 18 November 2019

Edited by H. Stoeckli-Evans, University of
Neuchâtel, Switzerland

**Keywords:** crystal structure; terminal alkyne; iron; platinum; heterobimetallic; metal–metal bond dimetallacyclopentenone; bis(diphenylphosphino)methane; hydrogen bonding; C–H···π interactions.

CCDC reference: 1964051

**Supporting information:** this article has
supporting information at journals.iucr.org/e

# Crystal structure of dicarbonyl[μ₂-methylenebis(diphenylphosphane)-κ²P:P'][μ₂-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe–Pt)–dichloromethane–toluene (1/1/2), [(OC)₂Fe(μ-dppm)(μ-C(=O)C(2,4,5-C₆H₂Me₃)=CH)Pt(PPh₃)]

Lukas Brieger,ª Isabelle Jourdain,ᵇ Michael Knorrᵇ* and Carsten Strohmannª*

ªTechnical University Dortmund, Chemistry and Chemical Biology, Inorganic Chemistry, Otto-Hahn Str. 6, 44227 Dortmund, Germany, and ᵇInstitut UTINAM UMR 6213 CNRS, Université Bourgogne Franche-Comté, 16, Route de Gray, 25030 Besançon Cedex, France. *Correspondence e-mail: michael.knorr@univ-fcomte.fr, carsten.strohmann@tu-dortmund.de

The title compound, [FePt(C₁₂H₁₂O)(C₁₈H₁₅P)(C₂₅H₂₂P₂)(CO)₂]·2C₇H₈·CH₂Cl₂ or [(OC)₂Fe(μ-dppm)(μ-C(=O)C(2,4,5-C₆H₂Me₃)=CH)Pt(PPh₃)], represents an example of a diphosphane-bridged heterobimetallic dimetallacyclopentenone complex resulting from a bimetallic activation of 1-ethynyl-2,4,5-trimethylbenzene and a metal-coordinated carbonyl ligand. The bridging μ₂-C(=O)C(2,4,5-C₆H₂Me₃)=CH unit (stemming from a carbon–carbon coupling reaction between CO and the terminal alkyne) forms a five-membered dimetallacyclopentenone ring, in which the C=O bond is π-coordinated to the Fe centre. The latter is connected to the Pt centre through a short metal–metal bond of 2.5770 (5) Å. In the crystal, the complex is solvated by one dichloromethane and two toluene molecules.

## 1. Chemical context

The coordination and transformation of alkynes on homobimetallic transition-metal complexes, in which the two metal centres are in close contact *via* a metal–metal bond, has been investigated intensively (Liddle, 2015). For example, during the course of a Pauson–Khand reaction, an acetylenic triple bond is added across [Co₂(CO)₈], yielding a dimetallatetrahedrane [Co₂(CO)₆(μ-C₂RR')] (Bennett *et al.*, 1992; Clément *et al.*, 2007).

The activation of alkynes by heterodinuclear transition-metal complexes L_nM–M'L_n has also stimulated much interest because of possible synergic effects exerted by the close proximity of metal centres (with different coordination spheres, oxidation states, ...; Stephan, 1989; Ritleng & Chetcuti, 2007; Cooper *et al.*, 2012). Among the different heterobimetallic combinations, the investigation of the group 8–10 Fe–Pt couple has been pioneered by Fontaine *et al.* (1988), who has shown that, upon treatment of the μ-carbonyl complex [(OC)₃Fe(μ-dppm)(μ-CO)Pt(PPh₃)] (dppm = bis(diphenylphosphino)methane) with ArC≡CH (Ar = Ph, p-Tol), dimetallacyclopentone complexes are formed, stemming from a carbon–carbon coupling reaction between CO and the alkyne. The first step involves formation of a kinetic isomer [(OC)₂Fe(μ-dppm){μ-C(=O)C(H)=C(Ar)}Pt(PPh₃)], which then evolves to the thermodynamic one [(OC)₂Fe(μ-dppm)-

<figure><img src="image_2.png" /></figure>

<figure><img src="image_3.png" /></figure>

OPEN

<figure><img src="image_4.png" /></figure>

ACCESS
<figure><img src="image_2.png" /></figure>

Acta Cryst.

E

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN 2056-9890

Received 12 November 2019

Accepted 18 November 2019

Edited by H. Stoeckli-Evans, University of
Neuchâtel, Switzerland

**Keywords:** crystal structure; terminal alkyne; iron; platinum; heterobimetallic; metal–metal bond dimetallacyclopentenone; bis(diphenylphosphino)methane; hydrogen bonding; C–H···π interactions.

CCDC reference: 1964051

**Supporting information:** this article has
supporting information at journals.iucr.org/e

# Crystal structure of dicarbonyl[μ₂-methylenebis-(diphenylphosphane)-κ²P:P'][μ₂-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe–Pt)–dichloromethane–toluene (1/1/2), [(OC)₂Fe(μ-dppm)(μ-C(=O)C(2,4,5-C₆H₂Me₃)=CH)Pt(PPh₃)]

Lukas Brieger,ª Isabelle Jourdain,ᵇ Michael Knorrᵇ* and Carsten Strohmannª*

ªTechnical University Dortmund, Chemistry and Chemical Biology, Inorganic Chemistry, Otto-Hahn Str. 6, 44227 Dortmund, Germany, and ᵇInstitut UTINAM UMR 6213 CNRS, Université Bourgogne Franche-Comté, 16, Route de Gray, 25030 Besançon Cedex, France. *Correspondence e-mail: michael.knorr@univ-fcomte.fr, carsten.strohmann@tu-dortmund.de

The title compound, [FePt(C₁₂H₁₂O)(C₁₈H₁₅P)(C₂₅H₂₂P₂)(CO)₂]·2C₇H₈·CH₂Cl₂ or [(OC)₂Fe(μ-dppm)(μ-C(=O)C(2,4,5-C₆H₂Me₃)=CH)Pt(PPh₃)], represents an example of a diphosphane-bridged heterobimetallic dimetallacyclopentenone complex resulting from a bimetallic activation of 1-ethynyl-2,4,5-trimethylbenzene and a metal-coordinated carbonyl ligand. The bridging μ₂-C(=O)C(2,4,5-C₆H₂Me₃)=CH unit (stemming from a carbon–carbon coupling reaction between CO and the terminal alkyne) forms a five-membered dimetallacyclopentenone ring, in which the C=O bond is π-coordinated to the Fe centre. The latter is connected to the Pt centre through a short metal–metal bond of 2.5770 (5) Å. In the crystal, the complex is solvated by one dichloromethane and two toluene molecules.

## 1. Chemical context

The coordination and transformation of alkynes on homobimetallic transition-metal complexes, in which the two metal centres are in close contact *via* a metal–metal bond, has been investigated intensively (Liddle, 2015). For example, during the course of a Pauson–Khand reaction, an acetylenic triple bond is added across [Co₂(CO)₈], yielding a dimetallatetrahedrane [Co₂(CO)₆(μ-C₂RR')] (Bennett *et al.*, 1992; Clément *et al.*, 2007).

The activation of alkynes by heterodinuclear transition-metal complexes L_nM–M'L_n has also stimulated much interest because of possible synergic effects exerted by the close proximity of metal centres (with different coordination spheres, oxidation states, ...; Stephan, 1989; Ritleng & Chetcuti, 2007; Cooper *et al.*, 2012). Among the different heterobimetallic combinations, the investigation of the group 8–10 Fe–Pt couple has been pioneered by Fontaine *et al.* (1988), who has shown that, upon treatment of the μ-carbonyl complex [(OC)₃Fe(μ-dppm)(μ-CO)Pt(PPh₃)] (dppm = bis-(diphenylphosphino)methane) with ArC≡CH (Ar = Ph, p-Tol), dimetallacyclopentone complexes are formed, stemming from a carbon–carbon coupling reaction between CO and the alkyne. The first step involves formation of a kinetic isomer [(OC)₂Fe(μ-dppm){μ-C(=O)C(H)=C(Ar)}Pt(PPh₃)], which then evolves to the thermodynamic one [(OC)₂Fe(μ-dppm)-

<figure><img src="image_3.png" /></figure>

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OPEN

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ACCESS
<figure><img src="image_5.png" /><figcaption>**Figure 1**
Reaction scheme for the synthesis of the title compound.</figcaption></figure>

$\{\mu-C(=O)C(Ar)=C(H)\}$Pt(PPh$_3$)]. Other strategies leading to structurally characterized dimetallacyclopentones have been reported by Yamazaki *et al.* (2005, 2006), implying the reaction of $Fe(CO)_5$ with the $\pi$-alkyne-Pt$^0$ complex Pt($\eta^2$-PhC≡CC≡CPh)(PPh$_3$)$_2$ or the bis-acetylide-Pt$^{II}$ compound Pt(C≡CTp)$_2$(dppe) ($Tp$ = 3-thiophene, dppe = 1,2-bis(diphenylphosphino)ethane), and leading to $[(OC)_3Fe\{\mu-C(=O)C(Ph)=C(C≡C-Ph)\}]Pt(PPh$_3$)$_2$ and $[(OC)_2Fe(\mu-CO)\{\mu-C(=O)C(Tp)=C(C≡C-Tp)\}]Pt(dppe)$, respectively.

Our investigations on the reactivity of bimetallic silyl-substituted hydride complexes, $[(OC)_3Fe\{Si(OMe)_3\}(\mu-PPh$_2$XPPh$_2$)](\mu-C≡C(R)H)Pt(PPh$_3$)]$ (X = CH$_2$, NH), toward a huge panel of terminal aliphatic and aromatic alkynes led to $\sigma$-alkenyl complexes $[(OC)_3Fe\{\mu-Si(OMe)_2(OMe)\}(\mu-PPh$_2$XPPh$_2$)]Pt(RC=CH$_2$)$, resulting from initial insertion into the Pt-H bond. The latter can then, depending on the function of the R substituent, convert to dimetallacyclopentones or to isomeric $\mu$-vinylidene complexes $[(OC)_3Fe(\mu-PPh$_2$XPPh$_2$)\{\mu-C≡C(R)H}\{\mu-PPh$_3$}]$ (Jourdain *et al.*, 2006). A third type of complex crystallographically characterized by our group is the dimetallacyclobutene $[(OC)_3Fe(\mu-dppm)\{\mu-C(o-CF$_3$-C$_6$H$_4$)C≡C(H)\}]Pt(PPh$_3$)]. This latter compound was obtained by treatment of $[(OC)_3Fe\{Si(OMe)$_3$}(\mu-dppm)-Pt(H)(PPh$_3$)]$ or $[(OC)_3Fe(\mu-dppm)(\mu-CO)Pt(PPh$_3$)]$ with $o-CF$_3$-C$_6$H$_4$C≡CH$, bearing a sterically crowded -CF$_3$ substituent at the *ortho*-position of the aryl group (Jourdain *et al.*, 2013). To probe whether other sterically crowded alkynes may lead to the formation of dimetallacyclobutenes or rather dimetallacyclopentones, we also reacted $[(OC)_3Fe(\mu-dppm)(\mu-CO)Pt(PPh$_3$)]$ with 1-ethynyl-2,4,5-trimethylbenzene bearing three methyl groups on the aromatic cycle; see Fig. 1.

<figure><img src="image_6.png" /></figure>

## 2. Structural commentary

The molecular structure of the title heterobimetallic complex is depicted in Fig. 2. It crystallized from $CH_2Cl_2$/toluene in the

<table><caption>**Table 1**
Selected geometric parameters (Å, °).</caption><tr><td>Pt1-Fe1</td><td>2.5770 (5)</td><td>Fe1-C2</td><td>2.109 (4)</td></tr><tr><td>Pt1-P2</td><td>2.2700 (9)</td><td>Fe1-C12</td><td>1.929 (4)</td></tr><tr><td>Pt1-P3</td><td>2.2529 (9)</td><td>Fe1-C13</td><td>1.749 (4)</td></tr><tr><td>Pt1-C1</td><td>2.023 (3)</td><td>Fe1-C14</td><td>1.781 (4)</td></tr><tr><td>Fe1-P1</td><td>2.1857 (11)</td><td>O1-C12</td><td>1.207 (4)</td></tr><tr><td>Fe1-C1</td><td>2.107 (3)</td><td>C1-C2</td><td>1.386 (4)</td></tr><tr><td>P2-Pt1-Fe1</td><td>102.03 (3)</td><td>C1-Fe1-C2</td><td>38.38 (12)</td></tr><tr><td>P3-Pt1-Fe1</td><td>152.88 (3)</td><td>C13-Fe1-P1</td><td>95.17 (13)</td></tr><tr><td>C1-Pt1-Fe1</td><td>52.87 (10)</td><td>C14-Fe1-P1</td><td>104.63 (12)</td></tr><tr><td>P3-Pt1-P2</td><td>105.07 (3)</td><td>C12-Fe1-P1</td><td>94.69 (11)</td></tr><tr><td>C1-Pt1-P2</td><td>152.26 (10)</td><td>C1-Fe1-P1</td><td>137.46 (10)</td></tr><tr><td>C1-Pt1-P3</td><td>100.38 (10)</td><td>C2-Fe1-P1</td><td>135.94 (10)</td></tr><tr><td>Pt1-C1-Fe1</td><td>77.18 (12)</td><td>C13-Fe1-Pt1</td><td>170.69 (12)</td></tr><tr><td>C13-Fe1-C14</td><td>96.51 (17)</td><td>C14-Fe1-Pt1</td><td>91.16 (13)</td></tr><tr><td>C13-Fe1-C12</td><td>96.59 (16)</td><td>C12-Fe1-Pt1</td><td>74.38 (10)</td></tr><tr><td>C14-Fe1-C12</td><td>155.50 (17)</td><td>C1-Fe1-Pt1</td><td>49.95 (9)</td></tr><tr><td>C13-Fe1-C1</td><td>125.43 (16)</td><td>C2-Fe1-Pt1</td><td>74.35 (9)</td></tr><tr><td>C14-Fe1-C1</td><td>84.72 (15)</td><td>P1-Fe1-Pt1</td><td>87.95 (3)</td></tr><tr><td>C12-Fe1-C1</td><td>70.81 (14)</td><td>C2-C1-Pt1</td><td>112.5 (3)</td></tr><tr><td>C13-Fe1-C2</td><td>97.50 (15)</td><td>C2-C1-Fe1</td><td>70.9 (2)</td></tr><tr><td>C14-Fe1-C2</td><td>115.51 (16)</td><td>P1-C45-P2</td><td>108.83 (17)</td></tr><tr><td>C12-Fe1-C2</td><td>42.03 (13)</td><td></td><td></td></tr></table>

monoclinic crystal system, space group $P2_1/n$, together with one molecule of $CH_2Cl_2$ and two molecules of toluene. Selected bond lengths and bond angles are given in Table 1.

The Fe-Pt bond is bridged by a dppm ligand, forming a five-membered ring that adopts an envelope conformation, with angle P1-C45-P2 = 108.83 (17)°, and the metal-phosphorus bonds Pt-P2 and Fe-P1 being 2.2700 (9) and 2.1857 (11) Å, respectively. These structural features are in line with those of other related structures published by our

<figure><img src="image_7.png" /><figcaption>**Figure 2**
The molecular structure of the title complex, with atom labelling. Displacement ellipsoids are drawn at the 30% probability level. For clarity, only H atom H1 has been included, and the solvent molecules have been omitted.</figcaption></figure>
<figure><img src="image_6.png" /><figcaption>**Figure 1**
Reaction scheme for the synthesis of the title compound.</figcaption></figure>

`{μ-C(=O)C(Ar)=C(H)}Pt(PPh₃)`. Other strategies leading to structurally characterized dimetallacyclopentones have been reported by Yamazaki *et al.* (2005, 2006), implying the reaction of Fe(CO)₅ with the π-alkyne-Pt⁰ complex Pt(η²-PhC≡CC≡CPh)(PPh₃)₂ or the bis-acetylide-Pt¹¹ compound Pt(C≡CTp)₂(dppe) (Tp = 3-thiophene, dppe = 1,2-bis(diphenylphosphino)ethane), and leading to [(OC)₃Fe{μ-C(=O)C(Ph)=C(C≡C-Ph)}Pt(PPh₃)₂] and [(OC)₂Fe(μ-CO){μ-C(=O)C(Tp)=C(C≡C-Tp)}Pt(dppe)], respectively.

Our investigations on the reactivity of bimetallic silyl-substituted hydride complexes, [(OC)₃Fe{Si(OMe)₃}(μ-PPh₂XPPh₂)Pt(H)(PPh₃)] (X = CH₂, NH), toward a huge panel of terminal aliphatic and aromatic alkynes led to σ-alkenyl complexes [(OC)₃Fe{μ-Si(OMe)₂(OMe)}(μ-PPh₂XPPh₂)Pt(RC≡CH₂)], resulting from initial insertion into the Pt-H bond. The latter can then, depending on the function of the R substituent, convert to dimetallacyclopentones or to isomeric μ-vinylidene complexes [(OC)₃Fe(μ-PPh₂XPPh₂){μ-C≡C(R)H}Pt(PPh₃)] (Jourdain *et al.*, 2006). A third type of complex crystallographically characterized by our group is the dimetallacyclobutene [(OC)₃Fe(μ-dppm){μ-C(o-CF₃-C₆H₄)C≡C(H)}Pt(PPh₃)]. This latter compound was obtained by treatment of [(OC)₃Fe{Si(OMe)₃}(μ-dppm)-Pt(H)(PPh₃)] or [(OC)₃Fe(μ-dppm)(μ-CO)Pt(PPh₃)] with o-CF₃-C₆H₄C≡CH, bearing a sterically crowded -CF₃ substituent at the *ortho*-position of the aryl group (Jourdain *et al.*, 2013). To probe whether other sterically crowded alkynes may lead to the formation of dimetallacyclobutenes or rather dimetallacyclopentones, we also reacted [(OC)₃Fe(μ-dppm)(μ-CO)Pt(PPh₃)] with 1-ethynyl-2,4,5-trimethylbenzene bearing three methyl groups on the aromatic cycle; see Fig. 1.

<figure><img src="image_7.png" /></figure>

## 2. Structural commentary

The molecular structure of the title heterobimetallic complex is depicted in Fig. 2. It crystallized from CH₂Cl₂/toluene in the

<table><caption>**Table 1**
Selected geometric parameters (Å, °).</caption><tr><td>Pt1-Fe1</td><td>2.5770 (5)</td><td>Fe1-C2</td><td>2.109 (4)</td></tr><tr><td>Pt1-P2</td><td>2.2700 (9)</td><td>Fe1-C12</td><td>1.929 (4)</td></tr><tr><td>Pt1-P3</td><td>2.2529 (9)</td><td>Fe1-C13</td><td>1.749 (4)</td></tr><tr><td>Pt1-C1</td><td>2.023 (3)</td><td>Fe1-C14</td><td>1.781 (4)</td></tr><tr><td>Fe1-P1</td><td>2.1857 (11)</td><td>O1-C12</td><td>1.207 (4)</td></tr><tr><td>Fe1-C1</td><td>2.107 (3)</td><td>C1-C2</td><td>1.386 (4)</td></tr><tr><td>P2-Pt1-Fe1</td><td>102.03 (3)</td><td>C1-Fe1-C2</td><td>38.38 (12)</td></tr><tr><td>P3-Pt1-Fe1</td><td>152.88 (3)</td><td>C13-Fe1-P1</td><td>95.17 (13)</td></tr><tr><td>C1-Pt1-Fe1</td><td>52.87 (10)</td><td>C14-Fe1-P1</td><td>104.63 (12)</td></tr><tr><td>P3-Pt1-P2</td><td>105.07 (3)</td><td>C12-Fe1-P1</td><td>94.69 (11)</td></tr><tr><td>C1-Pt1-P2</td><td>152.26 (10)</td><td>C1-Fe1-P1</td><td>137.46 (10)</td></tr><tr><td>C1-Pt1-P3</td><td>100.38 (10)</td><td>C2-Fe1-P1</td><td>135.94 (10)</td></tr><tr><td>Pt1-C1-Fe1</td><td>77.18 (12)</td><td>C13-Fe1-Pt1</td><td>170.69 (12)</td></tr><tr><td>C13-Fe1-C14</td><td>96.51 (17)</td><td>C14-Fe1-Pt1</td><td>91.16 (13)</td></tr><tr><td>C13-Fe1-C12</td><td>96.59 (16)</td><td>C12-Fe1-Pt1</td><td>74.38 (10)</td></tr><tr><td>C14-Fe1-C12</td><td>155.50 (17)</td><td>C1-Fe1-Pt1</td><td>49.95 (9)</td></tr><tr><td>C13-Fe1-C1</td><td>125.43 (16)</td><td>C2-Fe1-Pt1</td><td>74.35 (9)</td></tr><tr><td>C14-Fe1-C1</td><td>84.72 (15)</td><td>P1-Fe1-Pt1</td><td>87.95 (3)</td></tr><tr><td>C12-Fe1-C1</td><td>70.81 (14)</td><td>C2-C1-Pt1</td><td>112.5 (3)</td></tr><tr><td>C13-Fe1-C2</td><td>97.50 (15)</td><td>C2-C1-Fe1</td><td>70.9 (2)</td></tr><tr><td>C14-Fe1-C2</td><td>115.51 (16)</td><td>P1-C45-P2</td><td>108.83 (17)</td></tr><tr><td>C12-Fe1-C2</td><td>42.03 (13)</td><td></td><td></td></tr></table>

monoclinic crystal system, space group P2₁/n, together with one molecule of CH₂Cl₂ and two molecules of toluene. Selected bond lengths and bond angles are given in Table 1.

The Fe-Pt bond is bridged by a dppm ligand, forming a five-membered ring that adopts an envelope conformation, with angle P1-C45-P2 = 108.83 (17)°, and the metal-phosphorus bonds Pt-P2 and Fe-P1 being 2.2700 (9) and 2.1857 (11) Å, respectively. These structural features are in line with those of other related structures published by our

<figure><img src="image_8.png" /><figcaption>**Figure 2**
The molecular structure of the title complex, with atom labelling. Displacement ellipsoids are drawn at the 30% probability level. For clarity, only H atom H1 has been included, and the solvent molecules have been omitted.</figcaption></figure>
<caption>**Table 2**

Hydrogen-bond geometry (Å, °).</caption>

Cg3, Cg6, Cg8, Cg9 and Cg10 are the centroids of the C21–C26, C39–C44, C52–C57, C59–C64 and C66–C71 rings, respectively.

<table><thead><tr><th>D–H···A</th><th>D–H</th><th>H···A</th><th>D···A</th><th>D–H···A</th></tr></thead><tbody><tr><td>C11–H11A···O1</td><td>0.96</td><td>2.36</td><td>3.193 (4)</td><td>145</td></tr><tr><td>C31–H31···O1<sup>i</sup></td><td>0.93</td><td>2.55</td><td>3.370 (5)</td><td>147</td></tr><tr><td>C41–H41···O2<sup>ii</sup></td><td>0.93</td><td>2.49</td><td>3.202 (5)</td><td>134</td></tr><tr><td>C48–H48···O3<sup>iii</sup></td><td>0.93</td><td>2.46</td><td>3.325 (5)</td><td>154</td></tr><tr><td>C11–H11B···Cg9<sup>iv</sup></td><td>0.96</td><td>2.80</td><td>3.719 (4)</td><td>160</td></tr><tr><td>C22–H22···Cg6</td><td>0.93</td><td>2.80</td><td>3.597 (3)</td><td>145</td></tr><tr><td>C34–H34···Cg3</td><td>0.93</td><td>2.98</td><td>3.519 (4)</td><td>118</td></tr><tr><td>C38–H38···Cg10</td><td>0.93</td><td>2.82</td><td>3.694 (4)</td><td>156</td></tr><tr><td>C60–H60···Cg8</td><td>0.93</td><td>2.81</td><td>3.543 (5)</td><td>137</td></tr></tbody></table>

Symmetry codes: (i) $x+1, y, z$; (ii) $-x+\frac{1}{2}, y+\frac{1}{2}, -z+\frac{3}{2}$; (iii) $x-1, y, z$; (iv) $x-\frac{1}{2}, -y+\frac{1}{2}, z-\frac{1}{2}$.

group and the Fe1–Pt1 bond length of 2.5770 (5) Å is in the range, 2.5453 (9) to 2.597 (4) Å, encountered for similar dppm-bridged compounds, e.g. [(OC)₂Fe(μ-dppm){μ-C(=O)C(CH₂)₂=C(H)}Pt(PPh₃)]₂ and [(OC)₂Fe(μ-C(=O)C(H)=C(H))(μ-dppm)Pt(PPh₃)] (Mohamed *et al.*, 2019; Fontaine *et al.*, 1988). When the metals are not spanned by a diphosphane ligand, the Fe–Pt bond distance is slightly longer, as in [(OC)₃Fe(μ-C(=O)C(Ph)=C(C≡C-Ph))-Pt(PPh₃)₂] and [(OC)₂Fe(μ-CO){μ-C(=O)C(Tp)=C(C≡C-Tp)}Pt(dppe)] with Fe–Pt distances of 2.608 (2) and 2.605 (2) Å, respectively (Yamazaki *et al.*, 2005, 2006). Both

metals are also incorporated in a dimetallacyclopentenone unit resulting from a carbon–carbon coupling reaction between CO and the terminal alkyne giving rise to an iron–acyl group [C12–O1 = 1.207 (4) Å]. The geometry at Fe1 can be considered as distorted octahedral resulting from π-coordination of the C1=C2 bond of the five-membered [FeC(=O)CR=C(H)Pt] unit [C1–Fe1 = 2.107 (3) and C2–Fe1 = 2.109 (4) Å]. The C1=C2 bond length compares well with that of [(OC)₂Fe{μ-C(=O)C(o,p-C₆H₃-F₂)=C(H)}(μ-dppm)Pt(PPh₃)] [1.386 (4) vs 1.382 (5) Å; Jourdain *et al.*, 2013]. The formation of the thermodynamic isomer, already evidenced by ¹H NMR spectroscopy, is indicated by the attachment of the aromatic C₆H₂Me₃ ring at the C2 atom in the β position relative to platinum. The C(=O)C(C₆H₂Me₃)=C(H) moiety is σ-bonded to the platinum atom [C1–Pt1 = 2.023 (3) Å], which adopts an irregular shape; see Table 1. The τ₄ descriptor for four-coordination is 0.39 (τ₄ = 0 for a perfect square-planar geometry and = 1 for a perfect tetrahedral geometry; for intermediate structures, including trigonal–pyramidal and seesaw, τ₄ falls within the range 0 to 1; Yang *et al.*, 2007).

### 3. Supramolecular features

In the crystal, molecules are linked by a number of C–H···O hydrogen bonds, forming layers parallel to the *ab* plane (Fig. 3 and Table 2). There are also a number of intra- and inter-

<figure><img src="image_8.png" /><figcaption>**Figure 3**</figcaption></figure>

A partial view along the *c* axis of the crystal packing of the title compound. The C–H···O hydrogen bonds (Table 2) are shown as dashed lines. For clarity, only the H atoms (grey balls) involved in these interactions have been included. Colour code: the two toluene molecules are red and blue and the dichloromethane molecule is green.
<caption>**Table 2**
Hydrogen-bond geometry (Å, °).</caption>

Cg3, Cg6, Cg8, Cg9 and Cg10 are the centroids of the C21–C26, C39–C44, C52–C57, C59–C64 and C66–C71 rings, respectively.

<table><thead><tr><th>D–H···A</th><th>D–H</th><th>H···A</th><th>D···A</th><th>D–H···A</th></tr></thead><tbody><tr><td>C11–H11A···O1</td><td>0.96</td><td>2.36</td><td>3.193 (4)</td><td>145</td></tr><tr><td>C31–H31···O1<sup>i</sup></td><td>0.93</td><td>2.55</td><td>3.370 (5)</td><td>147</td></tr><tr><td>C41–H41···O2<sup>ii</sup></td><td>0.93</td><td>2.49</td><td>3.202 (5)</td><td>134</td></tr><tr><td>C48–H48···O3<sup>iii</sup></td><td>0.93</td><td>2.46</td><td>3.325 (5)</td><td>154</td></tr><tr><td>C11–H11B···Cg9<sup>iv</sup></td><td>0.96</td><td>2.80</td><td>3.719 (4)</td><td>160</td></tr><tr><td>C22–H22···Cg6</td><td>0.93</td><td>2.80</td><td>3.597 (3)</td><td>145</td></tr><tr><td>C34–H34···Cg3</td><td>0.93</td><td>2.98</td><td>3.519 (4)</td><td>118</td></tr><tr><td>C38–H38···Cg10</td><td>0.93</td><td>2.82</td><td>3.694 (4)</td><td>156</td></tr><tr><td>C60–H60···Cg8</td><td>0.93</td><td>2.81</td><td>3.543 (5)</td><td>137</td></tr></tbody></table>

Symmetry codes: (i) $x+1, y, z$; (ii) $-x+\frac{1}{2}, y+\frac{1}{2}, -z+\frac{3}{2}$; (iii) $x-1, y, z$; (iv) $x-\frac{1}{2}, -y+\frac{1}{2}, z-\frac{1}{2}$.

group and the Fe1–Pt1 bond length of 2.5770 (5) Å is in the range, 2.5453 (9) to 2.597 (4) Å, encountered for similar dppm-bridged compounds, e.g. [(OC)₂Fe(μ-dppm){μ-C(=O)C(CH₂)₂=C(H)}Pt(PPh₃)]₂ and [(OC)₂Fe(μ-C(=O)C(H)=C(H))(μ-dppm)Pt(PPh₃)] (Mohamed *et al.*, 2019; Fontaine *et al.*, 1988). When the metals are not spanned by a diphosphane ligand, the Fe–Pt bond distance is slightly longer, as in [(OC)₃Fe(μ-C(=O)C(Ph)=C(C=C-Ph))-Pt(PPh₃)₂] and [(OC)₂Fe(μ-CO){μ-C(=O)C(Tp)=C(C=C-Tp)}Pt(dppe)] with Fe–Pt distances of 2.608 (2) and 2.605 (2) Å, respectively (Yamazaki *et al.*, 2005, 2006). Both

metals are also incorporated in a dimetallacyclopentenone unit resulting from a carbon–carbon coupling reaction between CO and the terminal alkyne giving rise to an iron–acyl group [C12–O1 = 1.207 (4) Å]. The geometry at Fe1 can be considered as distorted octahedral resulting from π-coordination of the C1=C2 bond of the five-membered [FeC(=O)CR=C(H)Pt] unit [C1–Fe1 = 2.107 (3) and C2–Fe1 = 2.109 (4) Å]. The C1=C2 bond length compares well with that of [(OC)₂Fe{μ-C(=O)C(o,p-C₆H₃-F₂)=C(H)}(μ-dppm)Pt(PPh₃)] [1.386 (4) vs 1.382 (5) Å; Jourdain *et al.*, 2013]. The formation of the thermodynamic isomer, already evidenced by ¹H NMR spectroscopy, is indicated by the attachment of the aromatic C₆H₂Me₃ ring at the C2 atom in the β position relative to platinum. The C(=O)C(C₆H₂Me₃)=C(H) moiety is σ-bonded to the platinum atom [C1–Pt1 = 2.023 (3) Å], which adopts an irregular shape; see Table 1. The τ₄ descriptor for four-coordination is 0.39 (τ₄ = 0 for a perfect square-planar geometry and = 1 for a perfect tetrahedral geometry; for intermediate structures, including trigonal–pyramidal and seesaw, τ₄ falls within the range 0 to 1; Yang *et al.*, 2007).

### 3. Supramolecular features

In the crystal, molecules are linked by a number of C–H···O hydrogen bonds, forming layers parallel to the *ab* plane (Fig. 3 and Table 2). There are also a number of intra- and inter-

<figure><img src="image_9.png" /><figcaption>**Figure 3**</figcaption></figure>

A partial view along the *c* axis of the crystal packing of the title compound. The C–H···O hydrogen bonds (Table 2) are shown as dashed lines. For clarity, only the H atoms (grey balls) involved in these interactions have been included. Colour code: the two toluene molecules are red and blue and the dichloromethane molecule is green.
molecular C–H···π interactions present (Table 2). The methyl group involving atom C11 forms an intramolecular C11–H11A···O1 hydrogen bond and an intermolecular C11–H11B···π interaction (Table 2).

## 4. Database survey

Other examples of crystallographically characterized dimetallacyclopentenone complexes are Fe₂Cp₂(CO)(μ-CO){μ-CH=C(Ph)C(=O)} (Boni et al., 2011), Fe₂Cp*₂(CO)(μ-CO){μ-C(C=CH)CHC(=O)} (Akita et al., 1993), Fe₂(CO)₅(μ-dppm){μ-C(=O)CH=CH} (Knox et al., 1995), Fe₂(CO)₅(μ-dppm){μ-C(=O)C(Ph)=CH} (Hitchcock et al., 1993), Fe₂Cp₂(CO)(μ-CO){μ-C(COR)=C(Me)C(=O)}, where R = Ph, Bu (Wong et al., 1991), Fe₂[(η-C₅H₄)₂SiMe₂]-(CO)₂(μ-CO){μ-C(Ph)=C(H)C(=O)} (McKee et al., 1994), Ru₂(CO)₄(μ-dppm)₂{μ-CH=CHC(=O)} (Mirza et al., 1994), Ru₂(η-C₅HMe₄)₂(CO)(μ-CO){μ-C(=O)C(R)=C(R)}, where R = Et, Me (Horiuchi et al., 2012), Rh₂Cp₂(CO)₄{μ-C(CF₃)=C(CF₃)C(=O)} (Dickson et al., 1981), Re₂Cp*₂(CO)₂{μ-CH=C{C(=CH₂)CH₃}-C(=O)} (Casey et al., 1994). A rare example of a heterodinuclear combination is CpFe{μ-C(=O)C(CMe₂OH)=CH}- (μ-CO)Ru(CO)Cp* (Dennett et al., 2005).

## 5. Synthesis and crystallization

[(OC)₃Fe(μ-CO)μ-Ph₂PCH₂PPh₂)Pt(PPh₃)] (110 mg, 0.1 mmol) was treated with an excess of 1-ethynyl-2,4,5-trimethylbenzene (30 mg, 0.2 mmol) in toluene (3 ml). The solution was stirred at 343 K for 2 h. The reaction mixture was filtered, and all volatiles removed under reduced pressure. The red residue was redissolved in a minimum of a dichloromethane/toluene mixture (50:50). Yellow crystals were isolated by layering with heptane (yield 123 mg, 88%).

Elemental analysis calculated for C₅₇H₄₉FeO₃P₃Pt, CH₂Cl₂, 2(C₇H₈) (Mw = 1395.09): C, 61.99; H, 4.84%. Found: C, 61.75; H, 4.78%. ¹H NMR: δ 2.14 (s, 3H, CH₃), 2.17 (s, 3H, CH₃), 2.43 (s, 3H, CH₃), 4.64 (m, 2H, PCH₂P, ²JₚH = 8.5, ²JₚH = 42), 6.81–7.55 (m, 37H, Ph), 8.07 (dd, 1H, =CH, ³JₚH = 8.2, ³JₚH = 5.0, ²JₚH = 32). ³¹P{1H} NMR: δ 8.6 (d, P₃DPPM Pt, ²JₚP = 58, ¹JₚP = 2641), 33.7 (d, P₃PPh₃ Pt, ³JₚP = 36, ¹JₚP = 3432), 61.3 (dd, P₃DPPM Fe, ²JₚP = 58, ³JₚP = 36). IR(ATR): 1962, 1913vs ν(CO), 1686m ν(C=O).

## 6. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 3. All of the hydrogen atoms were placed in geometrically calculated positions (C–H = 0.93–0.98 Å) and refined as riding on the parent C atom, with Uiso(H) = 1.5Ueq(C-methyl) and 1.2Ueq(C) for other H atoms.

<table><caption>Table 3
Experimental details.</caption><thead><tr><th></th><th></th></tr></thead><tbody><tr><td>Crystal data</td><td></td></tr><tr><td>Chemical formula</td><td>[FePt(C<sub>12</sub>H<sub>12</sub>O)(C<sub>18</sub>H<sub>15</sub>P)- (C<sub>25</sub>H<sub>22</sub>P<sub>2</sub>)(CO)<sub>2</sub>]-2C<sub>7</sub>H<sub>8</sub>-CH<sub>2</sub>Cl<sub>2</sub></td></tr><tr><td>M<sub>r</sub></td><td>1395.00</td></tr><tr><td>Crystal system, space group</td><td>Monoclinic, P2<sub>1</sub>/n</td></tr><tr><td>Temperature (K)</td><td>293</td></tr><tr><td>a, b, c (Å)</td><td>10.2117 (3), 24.7895 (6), 24.6241 (7)</td></tr><tr><td>β (°)</td><td>92.056 (3)</td></tr><tr><td>V (Å<sup>3</sup>)</td><td>6229.4 (3)</td></tr><tr><td>Z</td><td>4</td></tr><tr><td>Radiation type</td><td>Mo Kα</td></tr><tr><td>μ (mm<sup>-1</sup>)</td><td>2.69</td></tr><tr><td>Crystal size (mm)</td><td>0.49 × 0.39 × 0.15</td></tr><tr><td>Data collection</td><td></td></tr><tr><td>Diffractometer</td><td>Oxford Diffraction Xcalibur, Sapphire3</td></tr><tr><td>Absorption correction</td><td>Multi-scan (CrysAlis PRO; Oxford Diffraction, 2010)</td></tr><tr><td>T<sub>min</sub>, T<sub>max</sub></td><td>0.923, 1.000</td></tr><tr><td>No. of measured, independent and observed [I > 2σ(I)] reflections</td><td>52106, 14857, 8982</td></tr><tr><td>R<sub>int</sub></td><td>0.070</td></tr><tr><td>(sin θ/λ)<sub>max</sub> (Å<sup>-1</sup>)</td><td>0.687</td></tr><tr><td>Refinement</td><td></td></tr><tr><td>R[F<sup>2</sup> > 2σ(F<sup>2</sup>)], wR(F<sup>2</sup>), S</td><td>0.035, 0.054, 0.81</td></tr><tr><td>No. of reflections</td><td>14857</td></tr><tr><td>No. of parameters</td><td>744</td></tr><tr><td>H-atom treatment</td><td>H-atom parameters constrained</td></tr><tr><td>Δρ<sub>max</sub>, Δρ<sub>min</sub> (e Å<sup>-3</sup>)</td><td>1.52, -0.97</td></tr></tbody></table>

Computer programs: *CrysAlis PRO* (Oxford Diffraction, 2010), *SHELXT* (Sheldrick, 2015a), *SHELXL* (Sheldrick, 2015b), *OLEX2* (Dolomanov et al., 2009), *Mercury* (Macrae et al., 2008), *PLATON* (Spek, 2009) and *publCIF* (Westrip, 2010).

## Funding information

We are grateful to the Deutsche Forschungsgemeinschaft (DFG) for financial support. LB thanks the Fonds der Chemischen Industrie (FCI) for doctoral fellowships.

## References

Akita, M., Sugimoto, S., Terada, M. & Moro-oka, Y. (1993). *J. Organomet. Chem.* **447**, 103–106.

Bennett, S. C., Gelling, A. & Went, M. J. (1992). *J. Organomet. Chem.* **439**, 189–199.

Boni, A., Funaioli, T., Marchetti, F., Pampaloni, G., Pinzino, C. & Zacchini, S. (2011). *J. Organomet. Chem.* **696**, 3551–3556.

Casey, C. P., Ha, Y. & Powell, D. R. (1994). *J. Am. Chem. Soc.* **116**, 3424–3428.

Clément, S., Guyard, L., Knorr, M., Dilsky, S., Strohmann, C. & Arroyo, M. (2007). *J. Organomet. Chem.* **692**, 839–850.

Cooper, B. G., Napoline, J. W. & Thomas, C. M. (2012). *Catal. Rev.* **54**, 1–40.

Dennett, J. N. L., Knox, S. A. R., Anderson, K. M., Charmant, J. P. H. & Orpen, A. G. (2005). *Dalton Trans.* pp. 63–73.

Dickson, R. S., Gatehouse, B. M., Nesbit, M. C. & Pain, G. N. (1981). *J. Organomet. Chem.* **215**, 97–109.

Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. (2009). *J. Appl. Cryst.* **42**, 339–341.

Fontaine, X. L. R., Jacobsen, G. B., Shaw, B. L. & Thornton-Pett, M. (1988). *J. Chem. Soc. Dalton Trans.* pp. 741–750.
molecular C—H···π interactions present (Table 2). The methyl group involving atom C11 forms an intramolecular C11—H11A···O1 hydrogen bond and an intermolecular C11—H11B···π interaction (Table 2).

## 4. Database survey

Other examples of crystallographically characterized dimetallacyclopentenone complexes are Fe₂Cp₂(CO)(μ-CO){μ-CH=C(Ph)C(=O)} (Boni et al., 2011), Fe₂Cp*₂(CO)(μ-CO){μ-C(C=CH)CHC(=O)} (Akita et al., 1993), Fe₂(CO)₅(μ-dppm){μ-C(=O)CH=CH} (Knox et al., 1995), Fe₂(CO)₅(μ-dppm){μ-C(=O)C(Ph)=CH} (Hitchcock et al., 1993), Fe₂Cp₂(CO)(μ-CO){μ-C(COR)=C(Me)C(=O)}, where R = Ph, Bu (Wong et al., 1991), Fe₂[(η-C₅H₄)₂SiMe₂]-(CO)₂(μ-CO){μ-C(Ph)=C(H)C(=O)} (McKee et al., 1994), Ru₂(CO)₄(μ-dppm)₂{μ-CH=CHC(=O)} (Mirza et al., 1994), Ru₂(η-C₅HMe₄)₂(CO)(μ-CO){μ-C(=O)C(R)=C(R)}, where R = Et, Me (Horiuchi et al., 2012), Rh₂Cp₂(CO)₄{μ-C(CF₃)=C(CF₃)C(=O)} (Dickson et al., 1981), Re₂Cp*₂(CO)₂{μ-CH=C[C(=CH₂)CH₃]-C(=O)} (Casey et al., 1994). A rare example of a heterodinuclear combination is CpFe{μ-C(=O)C(CMe₂OH)=CH}- (μ-CO)Ru(CO)Cp* (Dennett et al., 2005).

## 5. Synthesis and crystallization

[(OC)₃Fe(μ-CO)μ-Ph₂PCH₂PPh₂)Pt(PPh₃)] (110 mg, 0.1 mmol) was treated with an excess of 1-ethynyl-2,4,5-trimethylbenzene (30 mg, 0.2 mmol) in toluene (3 ml). The solution was stirred at 343 K for 2 h. The reaction mixture was filtered, and all volatiles removed under reduced pressure. The red residue was redissolved in a minimum of a dichloromethane/toluene mixture (50:50). Yellow crystals were isolated by layering with heptane (yield 123 mg, 88%).

Elemental analysis calculated for C₅₇H₄₉FeO₃P₃Pt, CH₂Cl₂, 2(C₇H₈) (Mw = 1395.09): C, 61.99; H, 4.84%. Found: C, 61.75; H, 4.78%. ¹H NMR: δ 2.14 (s, 3H, CH₃), 2.17 (s, 3H, CH₃), 2.43 (s, 3H, CH₃), 4.64 (m, 2H, PCH₂P, ²JₚH = 8.5, ²JₚH = 42), 6.81–7.55 (m, 37H, Ph), 8.07 (dd, 1H, =CH, ³JₚH = 8.2, ³JₚH = 5.0, ²JₚH = 32). ³¹P{1H} NMR: δ 8.6 (d, P₃Dppm Pt, ²JₚP = 58, ¹JₚP = 2641), 33.7 (d, P₃PPh₃ Pt, ³JₚP = 36, ¹JₚP = 3432), 61.3 (dd, P₃Dppm Fe, ²JₚP = 58, ³JₚP = 36). IR(ATR): 1962, 1913vs ν(CO), 1686m ν(C=O).

## 6. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 3. All of the hydrogen atoms were placed in geometrically calculated positions (C—H = 0.93–0.98 Å) and refined as riding on the parent C atom, with Uiso(H) = 1.5Ueq(C-methyl) and 1.2Ueq(C) for other H atoms.

<table><caption>Table 3
Experimental details.</caption><thead><tr><th></th><th></th></tr></thead><tbody><tr><td>Crystal data</td><td></td></tr><tr><td>Chemical formula</td><td>[FePt(C<sub>12</sub>H<sub>12</sub>O)(C<sub>18</sub>H<sub>15</sub>P)- (C<sub>25</sub>H<sub>22</sub>P<sub>2</sub>)(CO)<sub>2</sub>]-2C<sub>7</sub>H<sub>8</sub>-CH<sub>2</sub>Cl<sub>2</sub></td></tr><tr><td>M<sub>r</sub></td><td>1395.00</td></tr><tr><td>Crystal system, space group</td><td>Monoclinic, P2<sub>1</sub>/n</td></tr><tr><td>Temperature (K)</td><td>293</td></tr><tr><td>a, b, c (Å)</td><td>10.2117 (3), 24.7895 (6), 24.6241 (7)</td></tr><tr><td>β (°)</td><td>92.056 (3)</td></tr><tr><td>V (Å<sup>3</sup>)</td><td>6229.4 (3)</td></tr><tr><td>Z</td><td>4</td></tr><tr><td>Radiation type</td><td>Mo Kα</td></tr><tr><td>μ (mm<sup>-1</sup>)</td><td>2.69</td></tr><tr><td>Crystal size (mm)</td><td>0.49 × 0.39 × 0.15</td></tr><tr><td>Data collection</td><td></td></tr><tr><td>Diffractometer</td><td>Oxford Diffraction Xcalibur, Sapphire3</td></tr><tr><td>Absorption correction</td><td>Multi-scan (CrysAlis PRO; Oxford Diffraction, 2010)</td></tr><tr><td>T<sub>min</sub>, T<sub>max</sub></td><td>0.923, 1.000</td></tr><tr><td>No. of measured, independent and observed [I > 2σ(I)] reflections</td><td>52106, 14857, 8982</td></tr><tr><td>R<sub>int</sub></td><td>0.070</td></tr><tr><td>(sin θ/λ)<sub>max</sub> (Å<sup>-1</sup>)</td><td>0.687</td></tr><tr><td>Refinement</td><td></td></tr><tr><td>R[F<sup>2</sup> > 2σ(F<sup>2</sup>)], wR(F<sup>2</sup>), S</td><td>0.035, 0.054, 0.81</td></tr><tr><td>No. of reflections</td><td>14857</td></tr><tr><td>No. of parameters</td><td>744</td></tr><tr><td>H-atom treatment</td><td>H-atom parameters constrained</td></tr><tr><td>Δρ<sub>max</sub>, Δρ<sub>min</sub> (e Å<sup>-3</sup>)</td><td>1.52, -0.97</td></tr></tbody></table>

Computer programs: CrysAlis PRO (Oxford Diffraction, 2010), SHELXT (Sheldrick, 2015a), SHELXL (Sheldrick, 2015b), OLEX2 (Dolomanov et al., 2009), Mercury (Macrae et al., 2008), PLATON (Spek, 2009) and publCIF (Westrip, 2010).

## Funding information

We are grateful to the Deutsche Forschungsgemeinschaft (DFG) for financial support. LB thanks the Fonds der Chemischen Industrie (FCI) for doctoral fellowships.

## References

* Akita, M., Sugimoto, S., Terada, M. & Moro-oka, Y. (1993). *J. Organomet. Chem.* **447**, 103–106.

* Bennett, S. C., Gelling, A. & Went, M. J. (1992). *J. Organomet. Chem.* **439**, 189–199.

* Boni, A., Funaioli, T., Marchetti, F., Pampaloni, G., Pinzino, C. & Zacchini, S. (2011). *J. Organomet. Chem.* **696**, 3551–3556.

* Casey, C. P., Ha, Y. & Powell, D. R. (1994). *J. Am. Chem. Soc.* **116**, 3424–3428.

* Clément, S., Guyard, L., Knorr, M., Dilsky, S., Strohmann, C. & Arroyo, M. (2007). *J. Organomet. Chem.* **692**, 839–850.

* Cooper, B. G., Napoline, J. W. & Thomas, C. M. (2012). *Catal. Rev.* **54**, 1–40.

* Dennett, J. N. L., Knox, S. A. R., Anderson, K. M., Charmant, J. P. H. & Orpen, A. G. (2005). *Dalton Trans.* pp. 63–73.

* Dickson, R. S., Gatehouse, B. M., Nesbit, M. C. & Pain, G. N. (1981). *J. Organomet. Chem.* **215**, 97–109.

* Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. (2009). *J. Appl. Cryst.* **42**, 339–341.

* Fontaine, X. L. R., Jacobsen, G. B., Shaw, B. L. & Thornton-Pett, M. (1988). *J. Chem. Soc. Dalton Trans.* pp. 741–750.
Hitchcock, P. B., Madden, T. J. & Nixon, J. F. (1993). *J. Organomet. Chem.* **463**, 155–162.

Horiuchi, S., Murase, T. & Fujita, M. (2012). *Angew. Chem. Int. Ed.* **51**, 12029–12031.

Johnson, K. A. & Gladfelter, W. L. (1991). *J. Am. Chem. Soc.* **113**, 5097–5099.

Jourdain, I., Knorr, M., Strohmann, C., Unkelbach, C., Rojo, S., Gómez-Iglesias, P. & Villafañe, F. (2013). *Organometallics*, **32**, 5343–5359.

Jourdain, I., Vieille-Petit, L., Clément, S., Knorr, M., Villafañe, F. & Strohmann, C. (2006). *Inorg. Chem. Commun.* **9**, 127–131.

Knox, S. A. R., Lloyd, B. R., Morton, D. A. V., Orpen, A. G., Turner, M. L. & Hogarth, G. (1995). *Polyhedron*, **14**, 2723–2743.

Liddle, S. T. (2015). *Molecular Metal–Metal Bonds*. Weinheim: Wiley-VCH.

Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). *J. Appl. Cryst.* **41**, 466–470.

McKee, S. D., Krause, J. A., Lunder, D. M. & Bursten, B. E. (1994). *J. Coord. Chem.* **32**, 249–259.

Mirza, H. A., Vittal, J. J. & Puddephatt, R. J. (1994). *Organometallics*, **13**, 3063–3067.

Mohamed, A. S., Jourdain, I., Knorr, M., Boullanger, S., Brieger, L. & Strohmann, C. (2019). *J. Clust Sci.* **30**, 1211–1225.

Oxford Diffraction (2010). *CrysAlis PRO*. Oxford Diffraction Ltd, Yarnton, England.

Ritleng, V. & Chetcuti, M. J. (2007). *Chem. Rev.* **107**, 797–858.

Sheldrick, G. M. (2015a). *Acta Cryst.* **A71**, 3–8.

Sheldrick, G. M. (2015b). *Acta Cryst.* **C71**, 3–8.

Spek, A. L. (2009). *Acta Cryst.* **D65**, 148–155.

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Wong, A., Pawlick, R. V., Thomas, C. G., Leon, D. R. & Liu, L.-K. (1991). *Organometallics*, **10**, 530–532.

Yamazaki, S., Taira, Z., Yonemura, T. & Deeming, A. J. (2005). *Organometallics*, **24**, 20–27.

Yamazaki, S., Taira, Z., Yonemura, T. & Deeming, A. J. (2006). *Organometallics*, **25**, 849–853.

Yang, L., Powell, D. R. & Houser, R. P. (2007). *Dalton Trans.* pp. 955–964.
Hitchcock, P. B., Madden, T. J. & Nixon, J. F. (1993). *J. Organomet. Chem.* **463**, 155–162.

Horiuchi, S., Murase, T. & Fujita, M. (2012). *Angew. Chem. Int. Ed.* **51**, 12029–12031.

Johnson, K. A. & Gladfelter, W. L. (1991). *J. Am. Chem. Soc.* **113**, 5097–5099.

Jourdain, I., Knorr, M., Strohmann, C., Unkelbach, C., Rojo, S., Gómez-Iglesias, P. & Villafañe, F. (2013). *Organometallics*, **32**, 5343–5359.

Jourdain, I., Vieille-Petit, L., Clément, S., Knorr, M., Villafañe, F. & Strohmann, C. (2006). *Inorg. Chem. Commun.* **9**, 127–131.

Knox, S. A. R., Lloyd, B. R., Morton, D. A. V., Orpen, A. G., Turner, M. L. & Hogarth, G. (1995). *Polyhedron*, **14**, 2723–2743.

Liddle, S. T. (2015). *Molecular Metal–Metal Bonds*. Weinheim: Wiley-VCH.

Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). *J. Appl. Cryst.* **41**, 466–470.

McKee, S. D., Krause, J. A., Lunder, D. M. & Bursten, B. E. (1994). *J. Coord. Chem.* **32**, 249–259.

Mirza, H. A., Vittal, J. J. & Puddephatt, R. J. (1994). *Organometallics*, **13**, 3063–3067.

Mohamed, A. S., Jourdain, I., Knorr, M., Boullanger, S., Brieger, L. & Strohmann, C. (2019). *J. Clust Sci.* **30**, 1211–1225.

Oxford Diffraction (2010). *CrysAlis PRO*. Oxford Diffraction Ltd, Yarnton, England.

Ritleng, V. & Chetcuti, M. J. (2007). *Chem. Rev.* **107**, 797–858.

Sheldrick, G. M. (2015a). *Acta Cryst.* **A71**, 3–8.

Sheldrick, G. M. (2015b). *Acta Cryst.* **C71**, 3–8.

Spek, A. L. (2009). *Acta Cryst.* **D65**, 148–155.

Stephan, D. W. (1989). *Coord. Chem. Rev.* **95**, 41–107.

Westrip, S. P. (2010). *J. Appl. Cryst.* **43**, 920–925.

Wong, A., Pawlick, R. V., Thomas, C. G., Leon, D. R. & Liu, L.-K. (1991). *Organometallics*, **10**, 530–532.

Yamazaki, S., Taira, Z., Yonemura, T. & Deeming, A. J. (2005). *Organometallics*, **24**, 20–27.

Yamazaki, S., Taira, Z., Yonemura, T. & Deeming, A. J. (2006). *Organometallics*, **25**, 849–853.

Yang, L., Powell, D. R. & Houser, R. P. (2007). *Dalton Trans.* pp. 955–964.
supporting information

Acta Cryst. (2019). E75, 1902-1906 [https://doi.org/10.1107/S2056989019015573]

Crystal structure of dicarbonyl[μ₂-methylenebis(diphenylphosphane)-κ²P:P'] [μ₂-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)-dichloromethane-toluene (1/1/2), [(OC)₂Fe(μ-dppm)(μ-C(&z-dbnd;O)C(2,4,5-C₆H₂Me₃)&z-dbnd;CH)Pt(PPh₃)]

Lukas Brieger, Isabelle Jourdain, Michael Knorr and Carsten Strohmann

Computing details

Data collection: *CrysAlis PRO* (Oxford Diffraction, 2010); cell refinement: *CrysAlis PRO* (Oxford Diffraction, 2010);

data reduction: *CrysAlis PRO* (Oxford Diffraction, 2010); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: *OLEX2* (Dolomanov *et al.*, 2009) and *Mercury* (Macrae *et al.*, 2008); software used to prepare material for publication: *OLEX2* (Dolomanov *et al.*, 2009), *SHELXL* (Sheldrick, 2015b), *PLATON* (Spek, 2009) and *publCIF* (Westrip, 2010).

Dicarbonyl[μ₂-methylenebis(diphenylphosphane)-κ²P:P'] [μ₂-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl] (triphenylphosphane-κP)ironplatinum(Fe—Pt)-dichloromethane-toluene (1/1/2)

Crystal data

[FePt(C₁₂H₁₂O)(C₁₈H₁₅P)(C₂₅H₂₂P₂)
(CO)₂]·2C₇H₈·CH₂Cl₂

M_r = 1395.00

Monoclinic, P2₁/n

a = 10.2117 (3) Å

b = 24.7895 (6) Å

c = 24.6241 (7) Å

β = 92.056 (3)°

V = 6229.4 (3) Å³

Z = 4

F(000) = 2824

Dₓ = 1.487 Mg m⁻³

Mo Kα radiation, λ = 0.71073 Å

Cell parameters from 14906 reflections

θ = 2.1–29.2°

μ = 2.69 mm⁻¹

T = 293 K

Block, yellow

0.49 × 0.39 × 0.14 mm

Data collection

Oxford Diffraction Xcalibur, Sapphire3
diffractometer

Radiation source: microfocus sealed X-ray tube

Grahpite monochromator

Detector resolution: 16.0560 pixels mm⁻¹

ω and φ scans

Absorption correction: multi-scan
(CrysAlisPro; Oxford Diffraction, 2010)

T_min = 0.923, T_max = 1.000

52106 measured reflections

14857 independent reflections

8982 reflections with *I* > 2σ(*I*)

R_int = 0.070

θ_max = 29.2°, θ_min = 2.1°

h = −13→13

k = −33→33

l = −33→33
supporting information

*Acta Cryst.* (2019). **E75**, 1902-1906 [https://doi.org/10.1107/S2056989019015573]

Crystal structure of dicarbonyl[μ₂-methylenebis(diphenylphosphane)-κ²P:P'] [μ₂-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)-dichloromethane-toluene (1/1/2), [(OC)₂Fe(μ-dppm)(μ-C(&z-dbnd;O)C(2,4,5-C₆H₂Me₃)&z-dbnd;CH)Pt(PPh₃)]

Lukas Brieger, Isabelle Jourdain, Michael Knorr and Carsten Strohmann

Computing details

Data collection: *CrysAlis PRO* (Oxford Diffraction, 2010); cell refinement: *CrysAlis PRO* (Oxford Diffraction, 2010);

data reduction: *CrysAlis PRO* (Oxford Diffraction, 2010); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: *OLEX2* (Dolomanov *et al.*, 2009) and *Mercury* (Macrae *et al.*, 2008); software used to prepare material for publication: *OLEX2* (Dolomanov *et al.*, 2009), *SHELXL* (Sheldrick, 2015b), *PLATON* (Spek, 2009) and *publCIF* (Westrip, 2010).

Dicarbonyl[μ₂-methylenebis(diphenylphosphane)-κ²P:P'] [μ₂-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl] (triphenylphosphane-κP)ironplatinum(Fe—Pt)-dichloromethane-toluene (1/1/2)

Crystal data

[FePt(C₁₂H₁₂O)(C₁₈H₁₅P)(C₂₅H₂₂P₂)
(CO)₂]·2C₇H₈·CH₂Cl₂

M_r = 1395.00

Monoclinic, P2₁/n

a = 10.2117 (3) Å

b = 24.7895 (6) Å

c = 24.6241 (7) Å

β = 92.056 (3)°

V = 6229.4 (3) Å³

Z = 4

F(000) = 2824

Dₓ = 1.487 Mg m⁻³

Mo Kα radiation, λ = 0.71073 Å

Cell parameters from 14906 reflections

θ = 2.1–29.2°

μ = 2.69 mm⁻¹

T = 293 K

Block, yellow

0.49 × 0.39 × 0.14 mm

Data collection

Oxford Diffraction Xcalibur, Sapphire3
diffractometer

Radiation source: microfocus sealed X-ray tube

Grahpite monochromator

Detector resolution: 16.0560 pixels mm⁻¹

ω and φ scans

Absorption correction: multi-scan
(CrysAlisPro; Oxford Diffraction, 2010)

T_min = 0.923, T_max = 1.000

52106 measured reflections

14857 independent reflections

8982 reflections with *I* > 2σ(*I*)

R_int = 0.070

θ_max = 29.2°, θ_min = 2.1°

h = −13→13

k = −33→33

l = −33→33
Refinement

Refinement on F²

Least-squares matrix: full

$R[F^2 > 2\sigma(F^2)] = 0.035$

$wR(F^2) = 0.054$

$S = 0.81$

14857 reflections

744 parameters

0 restraints

Primary atom site location: dual

Secondary atom site location: difference Fourier map

Hydrogen site location: mixed

H-atom parameters constrained

$$w = 1/[\sigma^2(F_o^2) + (0.0167P)^2]$$
$$\text{where } P = (F_o^2 + 2F_c^2)/3$$

$(\Delta/\sigma)_{\text{max}} = 0.004$

$\Delta\rho_{\text{max}} = 1.52 \text{ e Å}^{-3}$

$\Delta\rho_{\text{min}} = -0.97 \text{ e Å}^{-3}$

Special details

**Geometry.** All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

<table><thead><tr><th></th><th>x</th><th>y</th><th>z</th><th>U<sub>iso</sub>*/U<sub>eq</sub></th></tr></thead><tbody><tr><td>Pt1</td><td>0.54891 (2)</td><td>0.43749 (2)</td><td>0.70894 (2)</td><td>0.01562 (4)</td></tr><tr><td>Fe1</td><td>0.51432 (5)</td><td>0.33557 (2)</td><td>0.72321 (2)</td><td>0.01800 (12)</td></tr><tr><td>P1</td><td>0.41192 (9)</td><td>0.35546 (4)</td><td>0.79703 (4)</td><td>0.0181 (2)</td></tr><tr><td>P2</td><td>0.42967 (9)</td><td>0.47366 (4)</td><td>0.77594 (4)</td><td>0.0166 (2)</td></tr><tr><td>P3</td><td>0.63044 (9)</td><td>0.50877 (4)</td><td>0.66456 (4)</td><td>0.0174 (2)</td></tr><tr><td>O1</td><td>0.2571 (2)</td><td>0.36786 (10)</td><td>0.67002 (10)</td><td>0.0277 (7)</td></tr><tr><td>O2</td><td>0.4463 (3)</td><td>0.22195 (10)</td><td>0.72360 (12)</td><td>0.0468 (8)</td></tr><tr><td>O3</td><td>0.7908 (3)</td><td>0.32228 (13)</td><td>0.75629 (11)</td><td>0.0529 (9)</td></tr><tr><td>C1</td><td>0.5924 (3)</td><td>0.37724 (14)</td><td>0.65717 (13)</td><td>0.0202 (9)</td></tr><tr><td>H1</td><td>0.680375</td><td>0.370787</td><td>0.643864</td><td>0.024*</td></tr><tr><td>C2</td><td>0.4823 (3)</td><td>0.34885 (14)</td><td>0.63921 (15)</td><td>0.0207 (9)</td></tr><tr><td>C3</td><td>0.4833 (3)</td><td>0.30712 (15)</td><td>0.59518 (14)</td><td>0.0211 (9)</td></tr><tr><td>C4</td><td>0.5756 (4)</td><td>0.26604 (15)</td><td>0.59748 (15)</td><td>0.0278 (10)</td></tr><tr><td>H4</td><td>0.632062</td><td>0.264056</td><td>0.627904</td><td>0.033*</td></tr><tr><td>C5</td><td>0.5883 (4)</td><td>0.22799 (16)</td><td>0.55717 (16)</td><td>0.0317 (10)</td></tr><tr><td>C6</td><td>0.6912 (4)</td><td>0.18437 (17)</td><td>0.56150 (17)</td><td>0.0565 (14)</td></tr><tr><td>H6A</td><td>0.747993</td><td>0.190977</td><td>0.592699</td><td>0.085*</td></tr><tr><td>H6B</td><td>0.741631</td><td>0.184430</td><td>0.529337</td><td>0.085*</td></tr><tr><td>H6C</td><td>0.649419</td><td>0.149939</td><td>0.565208</td><td>0.085*</td></tr><tr><td>C7</td><td>0.5028 (4)</td><td>0.23059 (15)</td><td>0.51200 (16)</td><td>0.0323 (10)</td></tr><tr><td>C8</td><td>0.5085 (4)</td><td>0.19051 (17)</td><td>0.46646 (16)</td><td>0.0475 (12)</td></tr><tr><td>H8A</td><td>0.500249</td><td>0.154669</td><td>0.480700</td><td>0.071*</td></tr><tr><td>H8B</td><td>0.590835</td><td>0.193877</td><td>0.449098</td><td>0.071*</td></tr><tr><td>H8C</td><td>0.438224</td><td>0.197341</td><td>0.440447</td><td>0.071*</td></tr><tr><td>C9</td><td>0.4092 (4)</td><td>0.27137 (16)</td><td>0.50997 (15)</td><td>0.0304 (10)</td></tr><tr><td>H9</td><td>0.351454</td><td>0.272838</td><td>0.479938</td><td>0.036*</td></tr><tr><td>C10</td><td>0.3974 (3)</td><td>0.30992 (15)</td><td>0.55019 (14)</td><td>0.0240 (9)</td></tr><tr><td>C11</td><td>0.2989 (4)</td><td>0.35501 (16)</td><td>0.54280 (15)</td><td>0.0372 (11)</td></tr><tr><td>H11A</td><td>0.248433</td><td>0.358014</td><td>0.574796</td><td>0.056*</td></tr></tbody></table>
Refinement

Refinement on F²

Least-squares matrix: full

$R[F^2 > 2\sigma(F^2)] = 0.035$

$wR(F^2) = 0.054$

$S = 0.81$

14857 reflections

744 parameters

0 restraints

Primary atom site location: dual

Secondary atom site location: difference Fourier map

Hydrogen site location: mixed

H-atom parameters constrained

$$w = 1/[\sigma^2(F_o^2) + (0.0167P)^2]$$
$$\text{where } P = (F_o^2 + 2F_c^2)/3$$

$(\Delta/\sigma)_{\text{max}} = 0.004$

$\Delta\rho_{\text{max}} = 1.52 \text{ e Å}^{-3}$

$\Delta\rho_{\text{min}} = -0.97 \text{ e Å}^{-3}$

Special details

**Geometry.** All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

<table><thead><tr><th></th><th>x</th><th>y</th><th>z</th><th>U<sub>iso</sub>*/U<sub>eq</sub></th></tr></thead><tbody><tr><td>Pt1</td><td>0.54891 (2)</td><td>0.43749 (2)</td><td>0.70894 (2)</td><td>0.01562 (4)</td></tr><tr><td>Fe1</td><td>0.51432 (5)</td><td>0.33557 (2)</td><td>0.72321 (2)</td><td>0.01800 (12)</td></tr><tr><td>P1</td><td>0.41192 (9)</td><td>0.35546 (4)</td><td>0.79703 (4)</td><td>0.0181 (2)</td></tr><tr><td>P2</td><td>0.42967 (9)</td><td>0.47366 (4)</td><td>0.77594 (4)</td><td>0.0166 (2)</td></tr><tr><td>P3</td><td>0.63044 (9)</td><td>0.50877 (4)</td><td>0.66456 (4)</td><td>0.0174 (2)</td></tr><tr><td>O1</td><td>0.2571 (2)</td><td>0.36786 (10)</td><td>0.67002 (10)</td><td>0.0277 (7)</td></tr><tr><td>O2</td><td>0.4463 (3)</td><td>0.22195 (10)</td><td>0.72360 (12)</td><td>0.0468 (8)</td></tr><tr><td>O3</td><td>0.7908 (3)</td><td>0.32228 (13)</td><td>0.75629 (11)</td><td>0.0529 (9)</td></tr><tr><td>C1</td><td>0.5924 (3)</td><td>0.37724 (14)</td><td>0.65717 (13)</td><td>0.0202 (9)</td></tr><tr><td>H1</td><td>0.680375</td><td>0.370787</td><td>0.643864</td><td>0.024*</td></tr><tr><td>C2</td><td>0.4823 (3)</td><td>0.34885 (14)</td><td>0.63921 (15)</td><td>0.0207 (9)</td></tr><tr><td>C3</td><td>0.4833 (3)</td><td>0.30712 (15)</td><td>0.59518 (14)</td><td>0.0211 (9)</td></tr><tr><td>C4</td><td>0.5756 (4)</td><td>0.26604 (15)</td><td>0.59748 (15)</td><td>0.0278 (10)</td></tr><tr><td>H4</td><td>0.632062</td><td>0.264056</td><td>0.627904</td><td>0.033*</td></tr><tr><td>C5</td><td>0.5883 (4)</td><td>0.22799 (16)</td><td>0.55717 (16)</td><td>0.0317 (10)</td></tr><tr><td>C6</td><td>0.6912 (4)</td><td>0.18437 (17)</td><td>0.56150 (17)</td><td>0.0565 (14)</td></tr><tr><td>H6A</td><td>0.747993</td><td>0.190977</td><td>0.592699</td><td>0.085*</td></tr><tr><td>H6B</td><td>0.741631</td><td>0.184430</td><td>0.529337</td><td>0.085*</td></tr><tr><td>H6C</td><td>0.649419</td><td>0.149939</td><td>0.565208</td><td>0.085*</td></tr><tr><td>C7</td><td>0.5028 (4)</td><td>0.23059 (15)</td><td>0.51200 (16)</td><td>0.0323 (10)</td></tr><tr><td>C8</td><td>0.5085 (4)</td><td>0.19051 (17)</td><td>0.46646 (16)</td><td>0.0475 (12)</td></tr><tr><td>H8A</td><td>0.500249</td><td>0.154669</td><td>0.480700</td><td>0.071*</td></tr><tr><td>H8B</td><td>0.590835</td><td>0.193877</td><td>0.449098</td><td>0.071*</td></tr><tr><td>H8C</td><td>0.438224</td><td>0.197341</td><td>0.440447</td><td>0.071*</td></tr><tr><td>C9</td><td>0.4092 (4)</td><td>0.27137 (16)</td><td>0.50997 (15)</td><td>0.0304 (10)</td></tr><tr><td>H9</td><td>0.351454</td><td>0.272838</td><td>0.479938</td><td>0.036*</td></tr><tr><td>C10</td><td>0.3974 (3)</td><td>0.30992 (15)</td><td>0.55019 (14)</td><td>0.0240 (9)</td></tr><tr><td>C11</td><td>0.2989 (4)</td><td>0.35501 (16)</td><td>0.54280 (15)</td><td>0.0372 (11)</td></tr><tr><td>H11A</td><td>0.248433</td><td>0.358014</td><td>0.574796</td><td>0.056*</td></tr></tbody></table>
<table>
  <tr>
    <td>H11B</td>
    <td>0.241625</td>
    <td>0.347360</td>
    <td>0.512004</td>
    <td>0.056*</td>
  </tr>
  <tr>
    <td>H11C</td>
    <td>0.344170</td>
    <td>0.388334</td>
    <td>0.536886</td>
    <td>0.056*</td>
  </tr>
  <tr>
    <td>C12</td>
    <td>0.3729 (4)</td>
    <td>0.35839 (14)</td>
    <td>0.67444 (14)</td>
    <td>0.0207 (9)</td>
  </tr>
  <tr>
    <td>C13</td>
    <td>0.4732 (4)</td>
    <td>0.26710 (16)</td>
    <td>0.72377 (15)</td>
    <td>0.0272 (9)</td>
  </tr>
  <tr>
    <td>C14</td>
    <td>0.6811 (4)</td>
    <td>0.32730 (16)</td>
    <td>0.74531 (15)</td>
    <td>0.0289 (10)</td>
  </tr>
  <tr>
    <td>C15</td>
    <td>0.5260 (3)</td>
    <td>0.53319 (15)</td>
    <td>0.60843 (14)</td>
    <td>0.0185 (8)</td>
  </tr>
  <tr>
    <td>C16</td>
    <td>0.4393 (3)</td>
    <td>0.49690 (15)</td>
    <td>0.58390 (14)</td>
    <td>0.0241 (9)</td>
  </tr>
  <tr>
    <td>H16</td>
    <td>0.435154</td>
    <td>0.461613</td>
    <td>0.596549</td>
    <td>0.029*</td>
  </tr>
  <tr>
    <td>C17</td>
    <td>0.3586 (4)</td>
    <td>0.51324 (17)</td>
    <td>0.54045 (15)</td>
    <td>0.0319 (10)</td>
  </tr>
  <tr>
    <td>H17</td>
    <td>0.301231</td>
    <td>0.488704</td>
    <td>0.523745</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C18</td>
    <td>0.3630 (4)</td>
    <td>0.56526 (19)</td>
    <td>0.52205 (15)</td>
    <td>0.0367 (10)</td>
  </tr>
  <tr>
    <td>H18</td>
    <td>0.309049</td>
    <td>0.575926</td>
    <td>0.492759</td>
    <td>0.044*</td>
  </tr>
  <tr>
    <td>C19</td>
    <td>0.4470 (4)</td>
    <td>0.60178 (16)</td>
    <td>0.54680 (16)</td>
    <td>0.0357 (11)</td>
  </tr>
  <tr>
    <td>H19</td>
    <td>0.448309</td>
    <td>0.637397</td>
    <td>0.534981</td>
    <td>0.043*</td>
  </tr>
  <tr>
    <td>C20</td>
    <td>0.5286 (4)</td>
    <td>0.58554 (16)</td>
    <td>0.58877 (15)</td>
    <td>0.0282 (10)</td>
  </tr>
  <tr>
    <td>H20</td>
    <td>0.587186</td>
    <td>0.610160</td>
    <td>0.604539</td>
    <td>0.034*</td>
  </tr>
  <tr>
    <td>C21</td>
    <td>0.6723 (3)</td>
    <td>0.56935 (14)</td>
    <td>0.70350 (13)</td>
    <td>0.0184 (8)</td>
  </tr>
  <tr>
    <td>C22</td>
    <td>0.5742 (3)</td>
    <td>0.60459 (14)</td>
    <td>0.71862 (14)</td>
    <td>0.0228 (9)</td>
  </tr>
  <tr>
    <td>H22</td>
    <td>0.488474</td>
    <td>0.599401</td>
    <td>0.705593</td>
    <td>0.027*</td>
  </tr>
  <tr>
    <td>C23</td>
    <td>0.6035 (4)</td>
    <td>0.64710 (15)</td>
    <td>0.75278 (15)</td>
    <td>0.0285 (10)</td>
  </tr>
  <tr>
    <td>H23</td>
    <td>0.537028</td>
    <td>0.670266</td>
    <td>0.762908</td>
    <td>0.034*</td>
  </tr>
  <tr>
    <td>C24</td>
    <td>0.7283 (4)</td>
    <td>0.65583 (15)</td>
    <td>0.77201 (15)</td>
    <td>0.0300 (10)</td>
  </tr>
  <tr>
    <td>H24</td>
    <td>0.747113</td>
    <td>0.684953</td>
    <td>0.794782</td>
    <td>0.036*</td>
  </tr>
  <tr>
    <td>C25</td>
    <td>0.8256 (4)</td>
    <td>0.62155 (15)</td>
    <td>0.75764 (15)</td>
    <td>0.0295 (10)</td>
  </tr>
  <tr>
    <td>H25</td>
    <td>0.910855</td>
    <td>0.627190</td>
    <td>0.771023</td>
    <td>0.035*</td>
  </tr>
  <tr>
    <td>C26</td>
    <td>0.7987 (4)</td>
    <td>0.57856 (14)</td>
    <td>0.72340 (14)</td>
    <td>0.0246 (9)</td>
  </tr>
  <tr>
    <td>H26</td>
    <td>0.866047</td>
    <td>0.555636</td>
    <td>0.713645</td>
    <td>0.030*</td>
  </tr>
  <tr>
    <td>C27</td>
    <td>0.7855 (3)</td>
    <td>0.49061 (14)</td>
    <td>0.63509 (15)</td>
    <td>0.0220 (9)</td>
  </tr>
  <tr>
    <td>C28</td>
    <td>0.8308 (4)</td>
    <td>0.51595 (17)</td>
    <td>0.58964 (15)</td>
    <td>0.0350 (11)</td>
  </tr>
  <tr>
    <td>H28</td>
    <td>0.782037</td>
    <td>0.543429</td>
    <td>0.573041</td>
    <td>0.042*</td>
  </tr>
  <tr>
    <td>C29</td>
    <td>0.9485 (5)</td>
    <td>0.5005 (2)</td>
    <td>0.56880 (19)</td>
    <td>0.0564 (15)</td>
  </tr>
  <tr>
    <td>H29</td>
    <td>0.978621</td>
    <td>0.517932</td>
    <td>0.538205</td>
    <td>0.068*</td>
  </tr>
  <tr>
    <td>C30</td>
    <td>1.0213 (5)</td>
    <td>0.4604 (2)</td>
    <td>0.5922 (2)</td>
    <td>0.0582 (16)</td>
  </tr>
  <tr>
    <td>H30</td>
    <td>1.099617</td>
    <td>0.449824</td>
    <td>0.577150</td>
    <td>0.070*</td>
  </tr>
  <tr>
    <td>C31</td>
    <td>0.9788 (4)</td>
    <td>0.43555 (18)</td>
    <td>0.63789 (19)</td>
    <td>0.0445 (12)</td>
  </tr>
  <tr>
    <td>H31</td>
    <td>1.029448</td>
    <td>0.408646</td>
    <td>0.654527</td>
    <td>0.053*</td>
  </tr>
  <tr>
    <td>C32</td>
    <td>0.8601 (3)</td>
    <td>0.45036 (14)</td>
    <td>0.65964 (16)</td>
    <td>0.0306 (10)</td>
  </tr>
  <tr>
    <td>H32</td>
    <td>0.831182</td>
    <td>0.433221</td>
    <td>0.690593</td>
    <td>0.037*</td>
  </tr>
  <tr>
    <td>C33</td>
    <td>0.5029 (3)</td>
    <td>0.49956 (13)</td>
    <td>0.83862 (14)</td>
    <td>0.0163 (8)</td>
  </tr>
  <tr>
    <td>C34</td>
    <td>0.6295 (4)</td>
    <td>0.51743 (14)</td>
    <td>0.83861 (15)</td>
    <td>0.0240 (9)</td>
  </tr>
  <tr>
    <td>H34</td>
    <td>0.676634</td>
    <td>0.514638</td>
    <td>0.807096</td>
    <td>0.029*</td>
  </tr>
  <tr>
    <td>C35</td>
    <td>0.6883 (4)</td>
    <td>0.53955 (16)</td>
    <td>0.88470 (16)</td>
    <td>0.0315 (10)</td>
  </tr>
  <tr>
    <td>H35</td>
    <td>0.774147</td>
    <td>0.552029</td>
    <td>0.884128</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C36</td>
    <td>0.6194 (4)</td>
    <td>0.54305 (16)</td>
    <td>0.93152 (16)</td>
    <td>0.0342 (11)</td>
  </tr>
  <tr>
    <td>H36</td>
    <td>0.658776</td>
    <td>0.557529</td>
    <td>0.962884</td>
    <td>0.041*</td>
  </tr>
  <tr>
    <td>C37</td>
    <td>0.4921 (4)</td>
    <td>0.52508 (16)</td>
    <td>0.93185 (14)</td>
    <td>0.0294 (10)</td>
  </tr>
  <tr>
    <td>H37</td>
    <td>0.444711</td>
    <td>0.527762</td>
    <td>0.963299</td>
    <td>0.035*</td>
  </tr>
  <tr>
    <td>C38</td>
    <td>0.4356 (3)</td>
    <td>0.50336 (14)</td>
    <td>0.88599 (14)</td>
    <td>0.0223 (9)</td>
  </tr>
</table>
<table>
  <tr>
    <td>H11B</td>
    <td>0.241625</td>
    <td>0.347360</td>
    <td>0.512004</td>
    <td>0.056*</td>
  </tr>
  <tr>
    <td>H11C</td>
    <td>0.344170</td>
    <td>0.388334</td>
    <td>0.536886</td>
    <td>0.056*</td>
  </tr>
  <tr>
    <td>C12</td>
    <td>0.3729 (4)</td>
    <td>0.35839 (14)</td>
    <td>0.67444 (14)</td>
    <td>0.0207 (9)</td>
  </tr>
  <tr>
    <td>C13</td>
    <td>0.4732 (4)</td>
    <td>0.26710 (16)</td>
    <td>0.72377 (15)</td>
    <td>0.0272 (9)</td>
  </tr>
  <tr>
    <td>C14</td>
    <td>0.6811 (4)</td>
    <td>0.32730 (16)</td>
    <td>0.74531 (15)</td>
    <td>0.0289 (10)</td>
  </tr>
  <tr>
    <td>C15</td>
    <td>0.5260 (3)</td>
    <td>0.53319 (15)</td>
    <td>0.60843 (14)</td>
    <td>0.0185 (8)</td>
  </tr>
  <tr>
    <td>C16</td>
    <td>0.4393 (3)</td>
    <td>0.49690 (15)</td>
    <td>0.58390 (14)</td>
    <td>0.0241 (9)</td>
  </tr>
  <tr>
    <td>H16</td>
    <td>0.435154</td>
    <td>0.461613</td>
    <td>0.596549</td>
    <td>0.029*</td>
  </tr>
  <tr>
    <td>C17</td>
    <td>0.3586 (4)</td>
    <td>0.51324 (17)</td>
    <td>0.54045 (15)</td>
    <td>0.0319 (10)</td>
  </tr>
  <tr>
    <td>H17</td>
    <td>0.301231</td>
    <td>0.488704</td>
    <td>0.523745</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C18</td>
    <td>0.3630 (4)</td>
    <td>0.56526 (19)</td>
    <td>0.52205 (15)</td>
    <td>0.0367 (10)</td>
  </tr>
  <tr>
    <td>H18</td>
    <td>0.309049</td>
    <td>0.575926</td>
    <td>0.492759</td>
    <td>0.044*</td>
  </tr>
  <tr>
    <td>C19</td>
    <td>0.4470 (4)</td>
    <td>0.60178 (16)</td>
    <td>0.54680 (16)</td>
    <td>0.0357 (11)</td>
  </tr>
  <tr>
    <td>H19</td>
    <td>0.448309</td>
    <td>0.637397</td>
    <td>0.534981</td>
    <td>0.043*</td>
  </tr>
  <tr>
    <td>C20</td>
    <td>0.5286 (4)</td>
    <td>0.58554 (16)</td>
    <td>0.58877 (15)</td>
    <td>0.0282 (10)</td>
  </tr>
  <tr>
    <td>H20</td>
    <td>0.587186</td>
    <td>0.610160</td>
    <td>0.604539</td>
    <td>0.034*</td>
  </tr>
  <tr>
    <td>C21</td>
    <td>0.6723 (3)</td>
    <td>0.56935 (14)</td>
    <td>0.70350 (13)</td>
    <td>0.0184 (8)</td>
  </tr>
  <tr>
    <td>C22</td>
    <td>0.5742 (3)</td>
    <td>0.60459 (14)</td>
    <td>0.71862 (14)</td>
    <td>0.0228 (9)</td>
  </tr>
  <tr>
    <td>H22</td>
    <td>0.488474</td>
    <td>0.599401</td>
    <td>0.705593</td>
    <td>0.027*</td>
  </tr>
  <tr>
    <td>C23</td>
    <td>0.6035 (4)</td>
    <td>0.64710 (15)</td>
    <td>0.75278 (15)</td>
    <td>0.0285 (10)</td>
  </tr>
  <tr>
    <td>H23</td>
    <td>0.537028</td>
    <td>0.670266</td>
    <td>0.762908</td>
    <td>0.034*</td>
  </tr>
  <tr>
    <td>C24</td>
    <td>0.7283 (4)</td>
    <td>0.65583 (15)</td>
    <td>0.77201 (15)</td>
    <td>0.0300 (10)</td>
  </tr>
  <tr>
    <td>H24</td>
    <td>0.747113</td>
    <td>0.684953</td>
    <td>0.794782</td>
    <td>0.036*</td>
  </tr>
  <tr>
    <td>C25</td>
    <td>0.8256 (4)</td>
    <td>0.62155 (15)</td>
    <td>0.75764 (15)</td>
    <td>0.0295 (10)</td>
  </tr>
  <tr>
    <td>H25</td>
    <td>0.910855</td>
    <td>0.627190</td>
    <td>0.771023</td>
    <td>0.035*</td>
  </tr>
  <tr>
    <td>C26</td>
    <td>0.7987 (4)</td>
    <td>0.57856 (14)</td>
    <td>0.72340 (14)</td>
    <td>0.0246 (9)</td>
  </tr>
  <tr>
    <td>H26</td>
    <td>0.866047</td>
    <td>0.555636</td>
    <td>0.713645</td>
    <td>0.030*</td>
  </tr>
  <tr>
    <td>C27</td>
    <td>0.7855 (3)</td>
    <td>0.49061 (14)</td>
    <td>0.63509 (15)</td>
    <td>0.0220 (9)</td>
  </tr>
  <tr>
    <td>C28</td>
    <td>0.8308 (4)</td>
    <td>0.51595 (17)</td>
    <td>0.58964 (15)</td>
    <td>0.0350 (11)</td>
  </tr>
  <tr>
    <td>H28</td>
    <td>0.782037</td>
    <td>0.543429</td>
    <td>0.573041</td>
    <td>0.042*</td>
  </tr>
  <tr>
    <td>C29</td>
    <td>0.9485 (5)</td>
    <td>0.5005 (2)</td>
    <td>0.56880 (19)</td>
    <td>0.0564 (15)</td>
  </tr>
  <tr>
    <td>H29</td>
    <td>0.978621</td>
    <td>0.517932</td>
    <td>0.538205</td>
    <td>0.068*</td>
  </tr>
  <tr>
    <td>C30</td>
    <td>1.0213 (5)</td>
    <td>0.4604 (2)</td>
    <td>0.5922 (2)</td>
    <td>0.0582 (16)</td>
  </tr>
  <tr>
    <td>H30</td>
    <td>1.099617</td>
    <td>0.449824</td>
    <td>0.577150</td>
    <td>0.070*</td>
  </tr>
  <tr>
    <td>C31</td>
    <td>0.9788 (4)</td>
    <td>0.43555 (18)</td>
    <td>0.63789 (19)</td>
    <td>0.0445 (12)</td>
  </tr>
  <tr>
    <td>H31</td>
    <td>1.029448</td>
    <td>0.408646</td>
    <td>0.654527</td>
    <td>0.053*</td>
  </tr>
  <tr>
    <td>C32</td>
    <td>0.8601 (3)</td>
    <td>0.45036 (14)</td>
    <td>0.65964 (16)</td>
    <td>0.0306 (10)</td>
  </tr>
  <tr>
    <td>H32</td>
    <td>0.831182</td>
    <td>0.433221</td>
    <td>0.690593</td>
    <td>0.037*</td>
  </tr>
  <tr>
    <td>C33</td>
    <td>0.5029 (3)</td>
    <td>0.49956 (13)</td>
    <td>0.83862 (14)</td>
    <td>0.0163 (8)</td>
  </tr>
  <tr>
    <td>C34</td>
    <td>0.6295 (4)</td>
    <td>0.51743 (14)</td>
    <td>0.83861 (15)</td>
    <td>0.0240 (9)</td>
  </tr>
  <tr>
    <td>H34</td>
    <td>0.676634</td>
    <td>0.514638</td>
    <td>0.807096</td>
    <td>0.029*</td>
  </tr>
  <tr>
    <td>C35</td>
    <td>0.6883 (4)</td>
    <td>0.53955 (16)</td>
    <td>0.88470 (16)</td>
    <td>0.0315 (10)</td>
  </tr>
  <tr>
    <td>H35</td>
    <td>0.774147</td>
    <td>0.552029</td>
    <td>0.884128</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C36</td>
    <td>0.6194 (4)</td>
    <td>0.54305 (16)</td>
    <td>0.93152 (16)</td>
    <td>0.0342 (11)</td>
  </tr>
  <tr>
    <td>H36</td>
    <td>0.658776</td>
    <td>0.557529</td>
    <td>0.962884</td>
    <td>0.041*</td>
  </tr>
  <tr>
    <td>C37</td>
    <td>0.4921 (4)</td>
    <td>0.52508 (16)</td>
    <td>0.93185 (14)</td>
    <td>0.0294 (10)</td>
  </tr>
  <tr>
    <td>H37</td>
    <td>0.444711</td>
    <td>0.527762</td>
    <td>0.963299</td>
    <td>0.035*</td>
  </tr>
  <tr>
    <td>C38</td>
    <td>0.4356 (3)</td>
    <td>0.50336 (14)</td>
    <td>0.88599 (14)</td>
    <td>0.0223 (9)</td>
  </tr>
</table>
<table>
  <tr>
    <td>H38</td>
    <td>0.349785</td>
    <td>0.490820</td>
    <td>0.886621</td>
    <td>0.027*</td>
  </tr>
  <tr>
    <td>C39</td>
    <td>0.3165 (3)</td>
    <td>0.52640 (13)</td>
    <td>0.75401 (14)</td>
    <td>0.0157 (8)</td>
  </tr>
  <tr>
    <td>C40</td>
    <td>0.3041 (3)</td>
    <td>0.57485 (13)</td>
    <td>0.78128 (15)</td>
    <td>0.0250 (9)</td>
  </tr>
  <tr>
    <td>H40</td>
    <td>0.349673</td>
    <td>0.580082</td>
    <td>0.814244</td>
    <td>0.030*</td>
  </tr>
  <tr>
    <td>C41</td>
    <td>0.2253 (4)</td>
    <td>0.61542 (15)</td>
    <td>0.76031 (16)</td>
    <td>0.0316 (10)</td>
  </tr>
  <tr>
    <td>H41</td>
    <td>0.218062</td>
    <td>0.647762</td>
    <td>0.779109</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C42</td>
    <td>0.1575 (4)</td>
    <td>0.60827 (15)</td>
    <td>0.71186 (16)</td>
    <td>0.0298 (10)</td>
  </tr>
  <tr>
    <td>H42</td>
    <td>0.104378</td>
    <td>0.635668</td>
    <td>0.697618</td>
    <td>0.036*</td>
  </tr>
  <tr>
    <td>C43</td>
    <td>0.1685 (3)</td>
    <td>0.56021 (17)</td>
    <td>0.68438 (15)</td>
    <td>0.0319 (9)</td>
  </tr>
  <tr>
    <td>H43</td>
    <td>0.122081</td>
    <td>0.555114</td>
    <td>0.651600</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C44</td>
    <td>0.2475 (3)</td>
    <td>0.51976 (14)</td>
    <td>0.70495 (14)</td>
    <td>0.0232 (9)</td>
  </tr>
  <tr>
    <td>H44</td>
    <td>0.254809</td>
    <td>0.487621</td>
    <td>0.685819</td>
    <td>0.028*</td>
  </tr>
  <tr>
    <td>C45</td>
    <td>0.3186 (3)</td>
    <td>0.41845 (12)</td>
    <td>0.79317 (13)</td>
    <td>0.0167 (8)</td>
  </tr>
  <tr>
    <td>H45A</td>
    <td>0.279720</td>
    <td>0.425680</td>
    <td>0.827798</td>
    <td>0.020*</td>
  </tr>
  <tr>
    <td>H43B</td>
    <td>0.248605</td>
    <td>0.415473</td>
    <td>0.765633</td>
    <td>0.020*</td>
  </tr>
  <tr>
    <td>C46</td>
    <td>0.2875 (3)</td>
    <td>0.30636 (14)</td>
    <td>0.81481 (13)</td>
    <td>0.0171 (8)</td>
  </tr>
  <tr>
    <td>C47</td>
    <td>0.1619 (4)</td>
    <td>0.30890 (15)</td>
    <td>0.79365 (15)</td>
    <td>0.0307 (10)</td>
  </tr>
  <tr>
    <td>H47</td>
    <td>0.137670</td>
    <td>0.337375</td>
    <td>0.770842</td>
    <td>0.037*</td>
  </tr>
  <tr>
    <td>C48</td>
    <td>0.0702 (4)</td>
    <td>0.26986 (17)</td>
    <td>0.80557 (17)</td>
    <td>0.0406 (12)</td>
  </tr>
  <tr>
    <td>H48</td>
    <td>-0.014739</td>
    <td>0.272452</td>
    <td>0.790848</td>
    <td>0.049*</td>
  </tr>
  <tr>
    <td>C49</td>
    <td>0.1037 (4)</td>
    <td>0.22774 (15)</td>
    <td>0.83871 (16)</td>
    <td>0.0323 (10)</td>
  </tr>
  <tr>
    <td>H49</td>
    <td>0.041725</td>
    <td>0.201813</td>
    <td>0.847043</td>
    <td>0.039*</td>
  </tr>
  <tr>
    <td>C50</td>
    <td>0.2290 (4)</td>
    <td>0.22384 (15)</td>
    <td>0.85963 (15)</td>
    <td>0.0310 (10)</td>
  </tr>
  <tr>
    <td>H50</td>
    <td>0.253127</td>
    <td>0.195127</td>
    <td>0.882155</td>
    <td>0.037*</td>
  </tr>
  <tr>
    <td>C51</td>
    <td>0.3195 (4)</td>
    <td>0.26267 (15)</td>
    <td>0.84714 (15)</td>
    <td>0.0294 (10)</td>
  </tr>
  <tr>
    <td>H51</td>
    <td>0.404964</td>
    <td>0.259288</td>
    <td>0.861023</td>
    <td>0.035*</td>
  </tr>
  <tr>
    <td>C52</td>
    <td>0.5016 (3)</td>
    <td>0.36484 (14)</td>
    <td>0.86208 (14)</td>
    <td>0.0198 (9)</td>
  </tr>
  <tr>
    <td>C53</td>
    <td>0.6322 (4)</td>
    <td>0.37850 (14)</td>
    <td>0.86408 (15)</td>
    <td>0.0255 (9)</td>
  </tr>
  <tr>
    <td>H53</td>
    <td>0.677321</td>
    <td>0.381007</td>
    <td>0.832040</td>
    <td>0.031*</td>
  </tr>
  <tr>
    <td>C54</td>
    <td>0.6971 (4)</td>
    <td>0.38856 (16)</td>
    <td>0.91340 (16)</td>
    <td>0.0318 (10)</td>
  </tr>
  <tr>
    <td>H54</td>
    <td>0.785234</td>
    <td>0.398083</td>
    <td>0.914070</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C55</td>
    <td>0.6334 (4)</td>
    <td>0.38468 (16)</td>
    <td>0.96099 (16)</td>
    <td>0.0348 (11)</td>
  </tr>
  <tr>
    <td>H55</td>
    <td>0.678280</td>
    <td>0.390548</td>
    <td>0.994001</td>
    <td>0.042*</td>
  </tr>
  <tr>
    <td>C56</td>
    <td>0.5024 (4)</td>
    <td>0.37203 (15)</td>
    <td>0.95967 (15)</td>
    <td>0.0340 (11)</td>
  </tr>
  <tr>
    <td>H56</td>
    <td>0.458020</td>
    <td>0.369732</td>
    <td>0.991924</td>
    <td>0.041*</td>
  </tr>
  <tr>
    <td>C57</td>
    <td>0.4365 (4)</td>
    <td>0.36275 (14)</td>
    <td>0.91088 (15)</td>
    <td>0.0251 (9)</td>
  </tr>
  <tr>
    <td>H57</td>
    <td>0.347377</td>
    <td>0.354967</td>
    <td>0.910412</td>
    <td>0.030*</td>
  </tr>
  <tr>
    <td>C58</td>
    <td>0.7015 (5)</td>
    <td>0.21333 (19)</td>
    <td>0.86522 (18)</td>
    <td>0.0629 (15)</td>
  </tr>
  <tr>
    <td>H58A</td>
    <td>0.767069</td>
    <td>0.185760</td>
    <td>0.862975</td>
    <td>0.094*</td>
  </tr>
  <tr>
    <td>H58B</td>
    <td>0.742922</td>
    <td>0.247326</td>
    <td>0.873172</td>
    <td>0.094*</td>
  </tr>
  <tr>
    <td>H58C</td>
    <td>0.652954</td>
    <td>0.215744</td>
    <td>0.831189</td>
    <td>0.094*</td>
  </tr>
  <tr>
    <td>C59</td>
    <td>0.6110 (5)</td>
    <td>0.1997 (2)</td>
    <td>0.90902 (19)</td>
    <td>0.0455 (12)</td>
  </tr>
  <tr>
    <td>C60</td>
    <td>0.5850 (5)</td>
    <td>0.23732 (19)</td>
    <td>0.9492 (2)</td>
    <td>0.0520 (13)</td>
  </tr>
  <tr>
    <td>H60</td>
    <td>0.626737</td>
    <td>0.270661</td>
    <td>0.948931</td>
    <td>0.062*</td>
  </tr>
  <tr>
    <td>C61</td>
    <td>0.4975 (5)</td>
    <td>0.2259 (2)</td>
    <td>0.9899 (2)</td>
    <td>0.0636 (16)</td>
  </tr>
  <tr>
    <td>H61</td>
    <td>0.482133</td>
    <td>0.251653</td>
    <td>1.016462</td>
    <td>0.076*</td>
  </tr>
  <tr>
    <td>C62</td>
    <td>0.4343 (5)</td>
    <td>0.1775 (2)</td>
    <td>0.9912 (2)</td>
    <td>0.0716 (17)</td>
  </tr>
  <tr>
    <td>H62</td>
    <td>0.374855</td>
    <td>0.169870</td>
    <td>1.017964</td>
    <td>0.086*</td>
  </tr>
</table>
<table>
  <tr>
    <td>H38</td>
    <td>0.349785</td>
    <td>0.490820</td>
    <td>0.886621</td>
    <td>0.027*</td>
  </tr>
  <tr>
    <td>C39</td>
    <td>0.3165 (3)</td>
    <td>0.52640 (13)</td>
    <td>0.75401 (14)</td>
    <td>0.0157 (8)</td>
  </tr>
  <tr>
    <td>C40</td>
    <td>0.3041 (3)</td>
    <td>0.57485 (13)</td>
    <td>0.78128 (15)</td>
    <td>0.0250 (9)</td>
  </tr>
  <tr>
    <td>H40</td>
    <td>0.349673</td>
    <td>0.580082</td>
    <td>0.814244</td>
    <td>0.030*</td>
  </tr>
  <tr>
    <td>C41</td>
    <td>0.2253 (4)</td>
    <td>0.61542 (15)</td>
    <td>0.76031 (16)</td>
    <td>0.0316 (10)</td>
  </tr>
  <tr>
    <td>H41</td>
    <td>0.218062</td>
    <td>0.647762</td>
    <td>0.779109</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C42</td>
    <td>0.1575 (4)</td>
    <td>0.60827 (15)</td>
    <td>0.71186 (16)</td>
    <td>0.0298 (10)</td>
  </tr>
  <tr>
    <td>H42</td>
    <td>0.104378</td>
    <td>0.635668</td>
    <td>0.697618</td>
    <td>0.036*</td>
  </tr>
  <tr>
    <td>C43</td>
    <td>0.1685 (3)</td>
    <td>0.56021 (17)</td>
    <td>0.68438 (15)</td>
    <td>0.0319 (9)</td>
  </tr>
  <tr>
    <td>H43</td>
    <td>0.122081</td>
    <td>0.555114</td>
    <td>0.651600</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C44</td>
    <td>0.2475 (3)</td>
    <td>0.51976 (14)</td>
    <td>0.70495 (14)</td>
    <td>0.0232 (9)</td>
  </tr>
  <tr>
    <td>H44</td>
    <td>0.254809</td>
    <td>0.487621</td>
    <td>0.685819</td>
    <td>0.028*</td>
  </tr>
  <tr>
    <td>C45</td>
    <td>0.3186 (3)</td>
    <td>0.41845 (12)</td>
    <td>0.79317 (13)</td>
    <td>0.0167 (8)</td>
  </tr>
  <tr>
    <td>H45A</td>
    <td>0.279720</td>
    <td>0.425680</td>
    <td>0.827798</td>
    <td>0.020*</td>
  </tr>
  <tr>
    <td>H43B</td>
    <td>0.248605</td>
    <td>0.415473</td>
    <td>0.765633</td>
    <td>0.020*</td>
  </tr>
  <tr>
    <td>C46</td>
    <td>0.2875 (3)</td>
    <td>0.30636 (14)</td>
    <td>0.81481 (13)</td>
    <td>0.0171 (8)</td>
  </tr>
  <tr>
    <td>C47</td>
    <td>0.1619 (4)</td>
    <td>0.30890 (15)</td>
    <td>0.79365 (15)</td>
    <td>0.0307 (10)</td>
  </tr>
  <tr>
    <td>H47</td>
    <td>0.137670</td>
    <td>0.337375</td>
    <td>0.770842</td>
    <td>0.037*</td>
  </tr>
  <tr>
    <td>C48</td>
    <td>0.0702 (4)</td>
    <td>0.26986 (17)</td>
    <td>0.80557 (17)</td>
    <td>0.0406 (12)</td>
  </tr>
  <tr>
    <td>H48</td>
    <td>-0.014739</td>
    <td>0.272452</td>
    <td>0.790848</td>
    <td>0.049*</td>
  </tr>
  <tr>
    <td>C49</td>
    <td>0.1037 (4)</td>
    <td>0.22774 (15)</td>
    <td>0.83871 (16)</td>
    <td>0.0323 (10)</td>
  </tr>
  <tr>
    <td>H49</td>
    <td>0.041725</td>
    <td>0.201813</td>
    <td>0.847043</td>
    <td>0.039*</td>
  </tr>
  <tr>
    <td>C50</td>
    <td>0.2290 (4)</td>
    <td>0.22384 (15)</td>
    <td>0.85963 (15)</td>
    <td>0.0310 (10)</td>
  </tr>
  <tr>
    <td>H50</td>
    <td>0.253127</td>
    <td>0.195127</td>
    <td>0.882155</td>
    <td>0.037*</td>
  </tr>
  <tr>
    <td>C51</td>
    <td>0.3195 (4)</td>
    <td>0.26267 (15)</td>
    <td>0.84714 (15)</td>
    <td>0.0294 (10)</td>
  </tr>
  <tr>
    <td>H51</td>
    <td>0.404964</td>
    <td>0.259288</td>
    <td>0.861023</td>
    <td>0.035*</td>
  </tr>
  <tr>
    <td>C52</td>
    <td>0.5016 (3)</td>
    <td>0.36484 (14)</td>
    <td>0.86208 (14)</td>
    <td>0.0198 (9)</td>
  </tr>
  <tr>
    <td>C53</td>
    <td>0.6322 (4)</td>
    <td>0.37850 (14)</td>
    <td>0.86408 (15)</td>
    <td>0.0255 (9)</td>
  </tr>
  <tr>
    <td>H53</td>
    <td>0.677321</td>
    <td>0.381007</td>
    <td>0.832040</td>
    <td>0.031*</td>
  </tr>
  <tr>
    <td>C54</td>
    <td>0.6971 (4)</td>
    <td>0.38856 (16)</td>
    <td>0.91340 (16)</td>
    <td>0.0318 (10)</td>
  </tr>
  <tr>
    <td>H54</td>
    <td>0.785234</td>
    <td>0.398083</td>
    <td>0.914070</td>
    <td>0.038*</td>
  </tr>
  <tr>
    <td>C55</td>
    <td>0.6334 (4)</td>
    <td>0.38468 (16)</td>
    <td>0.96099 (16)</td>
    <td>0.0348 (11)</td>
  </tr>
  <tr>
    <td>H55</td>
    <td>0.678280</td>
    <td>0.390548</td>
    <td>0.994001</td>
    <td>0.042*</td>
  </tr>
  <tr>
    <td>C56</td>
    <td>0.5024 (4)</td>
    <td>0.37203 (15)</td>
    <td>0.95967 (15)</td>
    <td>0.0340 (11)</td>
  </tr>
  <tr>
    <td>H56</td>
    <td>0.458020</td>
    <td>0.369732</td>
    <td>0.991924</td>
    <td>0.041*</td>
  </tr>
  <tr>
    <td>C57</td>
    <td>0.4365 (4)</td>
    <td>0.36275 (14)</td>
    <td>0.91088 (15)</td>
    <td>0.0251 (9)</td>
  </tr>
  <tr>
    <td>H57</td>
    <td>0.347377</td>
    <td>0.354967</td>
    <td>0.910412</td>
    <td>0.030*</td>
  </tr>
  <tr>
    <td>C58</td>
    <td>0.7015 (5)</td>
    <td>0.21333 (19)</td>
    <td>0.86522 (18)</td>
    <td>0.0629 (15)</td>
  </tr>
  <tr>
    <td>H58A</td>
    <td>0.767069</td>
    <td>0.185760</td>
    <td>0.862975</td>
    <td>0.094*</td>
  </tr>
  <tr>
    <td>H58B</td>
    <td>0.742922</td>
    <td>0.247326</td>
    <td>0.873172</td>
    <td>0.094*</td>
  </tr>
  <tr>
    <td>H58C</td>
    <td>0.652954</td>
    <td>0.215744</td>
    <td>0.831189</td>
    <td>0.094*</td>
  </tr>
  <tr>
    <td>C59</td>
    <td>0.6110 (5)</td>
    <td>0.1997 (2)</td>
    <td>0.90902 (19)</td>
    <td>0.0455 (12)</td>
  </tr>
  <tr>
    <td>C60</td>
    <td>0.5850 (5)</td>
    <td>0.23732 (19)</td>
    <td>0.9492 (2)</td>
    <td>0.0520 (13)</td>
  </tr>
  <tr>
    <td>H60</td>
    <td>0.626737</td>
    <td>0.270661</td>
    <td>0.948931</td>
    <td>0.062*</td>
  </tr>
  <tr>
    <td>C61</td>
    <td>0.4975 (5)</td>
    <td>0.2259 (2)</td>
    <td>0.9899 (2)</td>
    <td>0.0636 (16)</td>
  </tr>
  <tr>
    <td>H61</td>
    <td>0.482133</td>
    <td>0.251653</td>
    <td>1.016462</td>
    <td>0.076*</td>
  </tr>
  <tr>
    <td>C62</td>
    <td>0.4343 (5)</td>
    <td>0.1775 (2)</td>
    <td>0.9912 (2)</td>
    <td>0.0716 (17)</td>
  </tr>
  <tr>
    <td>H62</td>
    <td>0.374855</td>
    <td>0.169870</td>
    <td>1.017964</td>
    <td>0.086*</td>
  </tr>
</table>
<table><tr><td>C63</td><td>0.4614 (5)</td><td>0.1401 (2)</td><td>0.9516 (2)</td><td>0.0700 (17)</td></tr><tr><td>H63</td><td>0.420309</td><td>0.106633</td><td>0.951855</td><td>0.084*</td></tr><tr><td>C64</td><td>0.5489 (5)</td><td>0.1516 (2)</td><td>0.9113 (2)</td><td>0.0532 (14)</td></tr><tr><td>H64</td><td>0.565255</td><td>0.125629</td><td>0.885175</td><td>0.064*</td></tr><tr><td>C65</td><td>-0.0246 (4)</td><td>0.4584 (2)</td><td>0.8046 (2)</td><td>0.085 (2)</td></tr><tr><td>H65A</td><td>-0.025429</td><td>0.419702</td><td>0.804299</td><td>0.128*</td></tr><tr><td>H65B</td><td>0.028702</td><td>0.471343</td><td>0.776000</td><td>0.128*</td></tr><tr><td>H65C</td><td>-0.112369</td><td>0.471694</td><td>0.799097</td><td>0.128*</td></tr><tr><td>C66</td><td>0.0300 (4)</td><td>0.4778 (2)</td><td>0.8576 (2)</td><td>0.0549 (14)</td></tr><tr><td>C67</td><td>0.0512 (5)</td><td>0.5325 (3)</td><td>0.8671 (3)</td><td>0.085 (2)</td></tr><tr><td>H67</td><td>0.032387</td><td>0.557028</td><td>0.839253</td><td>0.102*</td></tr><tr><td>C68</td><td>0.0994 (6)</td><td>0.5514 (3)</td><td>0.9166 (4)</td><td>0.099 (3)</td></tr><tr><td>H68</td><td>0.112688</td><td>0.588053</td><td>0.922887</td><td>0.119*</td></tr><tr><td>C69</td><td>0.1268 (5)</td><td>0.5136 (3)</td><td>0.9564 (3)</td><td>0.082 (2)</td></tr><tr><td>H69</td><td>0.157815</td><td>0.525130</td><td>0.990425</td><td>0.098*</td></tr><tr><td>C70</td><td>0.1098 (5)</td><td>0.4592 (3)</td><td>0.9473 (2)</td><td>0.0660 (16)</td></tr><tr><td>H70</td><td>0.131156</td><td>0.434384</td><td>0.974479</td><td>0.079*</td></tr><tr><td>C71</td><td>0.0617 (4)</td><td>0.4422 (2)</td><td>0.89843 (19)</td><td>0.0512 (13)</td></tr><tr><td>H71</td><td>0.049822</td><td>0.405504</td><td>0.892407</td><td>0.061*</td></tr><tr><td>Cl1</td><td>0.61998 (19)</td><td>0.31739 (7)</td><td>1.11202 (6)</td><td>0.1133 (6)</td></tr><tr><td>Cl2</td><td>0.47570 (16)</td><td>0.22636 (7)</td><td>1.14958 (6)</td><td>0.0936 (5)</td></tr><tr><td>C72</td><td>0.6305 (5)</td><td>0.2515 (2)</td><td>1.1363 (2)</td><td>0.0799 (17)</td></tr><tr><td>H72A</td><td>0.685110</td><td>0.250711</td><td>1.169320</td><td>0.096*</td></tr><tr><td>H72B</td><td>0.671131</td><td>0.228837</td><td>1.109553</td><td>0.096*</td></tr></table>

Atomic displacement parameters (Å²)

<table><thead><tr><th></th><th>U<sup>11</sup></th><th>U<sup>22</sup></th><th>U<sup>33</sup></th><th>U<sup>12</sup></th><th>U<sup>13</sup></th><th>U<sup>23</sup></th></tr></thead><tbody><tr><td>Pt1</td><td>0.01643 (7)</td><td>0.01350 (6)</td><td>0.01695 (7)</td><td>0.00082 (8)</td><td>0.00098 (5)</td><td>-0.00172 (8)</td></tr><tr><td>Fe1</td><td>0.0182 (3)</td><td>0.0137 (3)</td><td>0.0221 (3)</td><td>0.0020 (2)</td><td>0.0000 (2)</td><td>-0.0001 (2)</td></tr><tr><td>P1</td><td>0.0171 (5)</td><td>0.0158 (5)</td><td>0.0214 (6)</td><td>-0.0004 (4)</td><td>-0.0008 (5)</td><td>0.0012 (4)</td></tr><tr><td>P2</td><td>0.0173 (5)</td><td>0.0152 (5)</td><td>0.0174 (5)</td><td>0.0013 (4)</td><td>0.0009 (4)</td><td>-0.0023 (4)</td></tr><tr><td>P3</td><td>0.0183 (5)</td><td>0.0155 (5)</td><td>0.0184 (5)</td><td>0.0000 (4)</td><td>0.0018 (4)</td><td>-0.0015 (4)</td></tr><tr><td>O1</td><td>0.0141 (15)</td><td>0.0360 (17)</td><td>0.0330 (17)</td><td>0.0090 (12)</td><td>-0.0007 (13)</td><td>-0.0043 (13)</td></tr><tr><td>O2</td><td>0.062 (2)</td><td>0.0146 (15)</td><td>0.064 (2)</td><td>-0.0073 (15)</td><td>0.0116 (17)</td><td>-0.0017 (15)</td></tr><tr><td>O3</td><td>0.0243 (18)</td><td>0.080 (3)</td><td>0.054 (2)</td><td>0.0202 (17)</td><td>-0.0047 (17)</td><td>-0.0024 (18)</td></tr><tr><td>C1</td><td>0.016 (2)</td><td>0.023 (2)</td><td>0.021 (2)</td><td>0.0030 (16)</td><td>-0.0019 (17)</td><td>0.0014 (17)</td></tr><tr><td>C2</td><td>0.023 (2)</td><td>0.0132 (19)</td><td>0.026 (2)</td><td>0.0020 (16)</td><td>0.0043 (18)</td><td>-0.0015 (17)</td></tr><tr><td>C3</td><td>0.022 (2)</td><td>0.020 (2)</td><td>0.021 (2)</td><td>-0.0015 (17)</td><td>0.0039 (18)</td><td>-0.0013 (18)</td></tr><tr><td>C4</td><td>0.030 (2)</td><td>0.028 (2)</td><td>0.025 (2)</td><td>0.0030 (19)</td><td>-0.0074 (19)</td><td>-0.009 (2)</td></tr><tr><td>C5</td><td>0.037 (3)</td><td>0.028 (2)</td><td>0.030 (2)</td><td>0.009 (2)</td><td>0.002 (2)</td><td>-0.012 (2)</td></tr><tr><td>C6</td><td>0.069 (4)</td><td>0.047 (3)</td><td>0.052 (3)</td><td>0.028 (3)</td><td>-0.014 (3)</td><td>-0.024 (3)</td></tr><tr><td>C7</td><td>0.045 (3)</td><td>0.023 (2)</td><td>0.029 (3)</td><td>0.000 (2)</td><td>0.001 (2)</td><td>-0.010 (2)</td></tr><tr><td>C8</td><td>0.062 (3)</td><td>0.038 (3)</td><td>0.042 (3)</td><td>0.004 (2)</td><td>-0.001 (2)</td><td>-0.015 (2)</td></tr><tr><td>C9</td><td>0.036 (3)</td><td>0.032 (2)</td><td>0.022 (2)</td><td>-0.003 (2)</td><td>-0.007 (2)</td><td>-0.003 (2)</td></tr><tr><td>C10</td><td>0.024 (2)</td><td>0.026 (2)</td><td>0.021 (2)</td><td>-0.0031 (18)</td><td>-0.0033 (18)</td><td>-0.0031 (19)</td></tr><tr><td>C11</td><td>0.040 (3)</td><td>0.037 (3)</td><td>0.034 (3)</td><td>0.006 (2)</td><td>-0.010 (2)</td><td>-0.003 (2)</td></tr><tr><td>C12</td><td>0.025 (2)</td><td>0.016 (2)</td><td>0.022 (2)</td><td>-0.0022 (17)</td><td>0.0021 (19)</td><td>0.0028 (17)</td></tr></tbody></table>
<table><tr><td>C63</td><td>0.4614 (5)</td><td>0.1401 (2)</td><td>0.9516 (2)</td><td>0.0700 (17)</td></tr><tr><td>H63</td><td>0.420309</td><td>0.106633</td><td>0.951855</td><td>0.084*</td></tr><tr><td>C64</td><td>0.5489 (5)</td><td>0.1516 (2)</td><td>0.9113 (2)</td><td>0.0532 (14)</td></tr><tr><td>H64</td><td>0.565255</td><td>0.125629</td><td>0.885175</td><td>0.064*</td></tr><tr><td>C65</td><td>-0.0246 (4)</td><td>0.4584 (2)</td><td>0.8046 (2)</td><td>0.085 (2)</td></tr><tr><td>H65A</td><td>-0.025429</td><td>0.419702</td><td>0.804299</td><td>0.128*</td></tr><tr><td>H65B</td><td>0.028702</td><td>0.471343</td><td>0.776000</td><td>0.128*</td></tr><tr><td>H65C</td><td>-0.112369</td><td>0.471694</td><td>0.799097</td><td>0.128*</td></tr><tr><td>C66</td><td>0.0300 (4)</td><td>0.4778 (2)</td><td>0.8576 (2)</td><td>0.0549 (14)</td></tr><tr><td>C67</td><td>0.0512 (5)</td><td>0.5325 (3)</td><td>0.8671 (3)</td><td>0.085 (2)</td></tr><tr><td>H67</td><td>0.032387</td><td>0.557028</td><td>0.839253</td><td>0.102*</td></tr><tr><td>C68</td><td>0.0994 (6)</td><td>0.5514 (3)</td><td>0.9166 (4)</td><td>0.099 (3)</td></tr><tr><td>H68</td><td>0.112688</td><td>0.588053</td><td>0.922887</td><td>0.119*</td></tr><tr><td>C69</td><td>0.1268 (5)</td><td>0.5136 (3)</td><td>0.9564 (3)</td><td>0.082 (2)</td></tr><tr><td>H69</td><td>0.157815</td><td>0.525130</td><td>0.990425</td><td>0.098*</td></tr><tr><td>C70</td><td>0.1098 (5)</td><td>0.4592 (3)</td><td>0.9473 (2)</td><td>0.0660 (16)</td></tr><tr><td>H70</td><td>0.131156</td><td>0.434384</td><td>0.974479</td><td>0.079*</td></tr><tr><td>C71</td><td>0.0617 (4)</td><td>0.4422 (2)</td><td>0.89843 (19)</td><td>0.0512 (13)</td></tr><tr><td>H71</td><td>0.049822</td><td>0.405504</td><td>0.892407</td><td>0.061*</td></tr><tr><td>Cl1</td><td>0.61998 (19)</td><td>0.31739 (7)</td><td>1.11202 (6)</td><td>0.1133 (6)</td></tr><tr><td>Cl2</td><td>0.47570 (16)</td><td>0.22636 (7)</td><td>1.14958 (6)</td><td>0.0936 (5)</td></tr><tr><td>C72</td><td>0.6305 (5)</td><td>0.2515 (2)</td><td>1.1363 (2)</td><td>0.0799 (17)</td></tr><tr><td>H72A</td><td>0.685110</td><td>0.250711</td><td>1.169320</td><td>0.096*</td></tr><tr><td>H72B</td><td>0.671131</td><td>0.228837</td><td>1.109553</td><td>0.096*</td></tr></table>

Atomic displacement parameters (Å²)

<table><thead><tr><th></th><th>U<sup>11</sup></th><th>U<sup>22</sup></th><th>U<sup>33</sup></th><th>U<sup>12</sup></th><th>U<sup>13</sup></th><th>U<sup>23</sup></th></tr></thead><tbody><tr><td>Pt1</td><td>0.01643 (7)</td><td>0.01350 (6)</td><td>0.01695 (7)</td><td>0.00082 (8)</td><td>0.00098 (5)</td><td>-0.00172 (8)</td></tr><tr><td>Fe1</td><td>0.0182 (3)</td><td>0.0137 (3)</td><td>0.0221 (3)</td><td>0.0020 (2)</td><td>0.0000 (2)</td><td>-0.0001 (2)</td></tr><tr><td>P1</td><td>0.0171 (5)</td><td>0.0158 (5)</td><td>0.0214 (6)</td><td>-0.0004 (4)</td><td>-0.0008 (5)</td><td>0.0012 (4)</td></tr><tr><td>P2</td><td>0.0173 (5)</td><td>0.0152 (5)</td><td>0.0174 (5)</td><td>0.0013 (4)</td><td>0.0009 (4)</td><td>-0.0023 (4)</td></tr><tr><td>P3</td><td>0.0183 (5)</td><td>0.0155 (5)</td><td>0.0184 (5)</td><td>0.0000 (4)</td><td>0.0018 (4)</td><td>-0.0015 (4)</td></tr><tr><td>O1</td><td>0.0141 (15)</td><td>0.0360 (17)</td><td>0.0330 (17)</td><td>0.0090 (12)</td><td>-0.0007 (13)</td><td>-0.0043 (13)</td></tr><tr><td>O2</td><td>0.062 (2)</td><td>0.0146 (15)</td><td>0.064 (2)</td><td>-0.0073 (15)</td><td>0.0116 (17)</td><td>-0.0017 (15)</td></tr><tr><td>O3</td><td>0.0243 (18)</td><td>0.080 (3)</td><td>0.054 (2)</td><td>0.0202 (17)</td><td>-0.0047 (17)</td><td>-0.0024 (18)</td></tr><tr><td>C1</td><td>0.016 (2)</td><td>0.023 (2)</td><td>0.021 (2)</td><td>0.0030 (16)</td><td>-0.0019 (17)</td><td>0.0014 (17)</td></tr><tr><td>C2</td><td>0.023 (2)</td><td>0.0132 (19)</td><td>0.026 (2)</td><td>0.0020 (16)</td><td>0.0043 (18)</td><td>-0.0015 (17)</td></tr><tr><td>C3</td><td>0.022 (2)</td><td>0.020 (2)</td><td>0.021 (2)</td><td>-0.0015 (17)</td><td>0.0039 (18)</td><td>-0.0013 (18)</td></tr><tr><td>C4</td><td>0.030 (2)</td><td>0.028 (2)</td><td>0.025 (2)</td><td>0.0030 (19)</td><td>-0.0074 (19)</td><td>-0.009 (2)</td></tr><tr><td>C5</td><td>0.037 (3)</td><td>0.028 (2)</td><td>0.030 (2)</td><td>0.009 (2)</td><td>0.002 (2)</td><td>-0.012 (2)</td></tr><tr><td>C6</td><td>0.069 (4)</td><td>0.047 (3)</td><td>0.052 (3)</td><td>0.028 (3)</td><td>-0.014 (3)</td><td>-0.024 (3)</td></tr><tr><td>C7</td><td>0.045 (3)</td><td>0.023 (2)</td><td>0.029 (3)</td><td>0.000 (2)</td><td>0.001 (2)</td><td>-0.010 (2)</td></tr><tr><td>C8</td><td>0.062 (3)</td><td>0.038 (3)</td><td>0.042 (3)</td><td>0.004 (2)</td><td>-0.001 (2)</td><td>-0.015 (2)</td></tr><tr><td>C9</td><td>0.036 (3)</td><td>0.032 (2)</td><td>0.022 (2)</td><td>-0.003 (2)</td><td>-0.007 (2)</td><td>-0.003 (2)</td></tr><tr><td>C10</td><td>0.024 (2)</td><td>0.026 (2)</td><td>0.021 (2)</td><td>-0.0031 (18)</td><td>-0.0033 (18)</td><td>-0.0031 (19)</td></tr><tr><td>C11</td><td>0.040 (3)</td><td>0.037 (3)</td><td>0.034 (3)</td><td>0.006 (2)</td><td>-0.010 (2)</td><td>-0.003 (2)</td></tr><tr><td>C12</td><td>0.025 (2)</td><td>0.016 (2)</td><td>0.022 (2)</td><td>-0.0022 (17)</td><td>0.0021 (19)</td><td>0.0028 (17)</td></tr></tbody></table>
<table>
  <tr>
    <td>C13</td>
    <td>0.025 (2)</td>
    <td>0.027 (2)</td>
    <td>0.030 (2)</td>
    <td>0.0008 (19)</td>
    <td>0.0043 (19)</td>
    <td>0.002 (2)</td>
  </tr>
  <tr>
    <td>C14</td>
    <td>0.032 (3)</td>
    <td>0.029 (2)</td>
    <td>0.025 (2)</td>
    <td>0.004 (2)</td>
    <td>0.000 (2)</td>
    <td>-0.0013 (19)</td>
  </tr>
  <tr>
    <td>C15</td>
    <td>0.020 (2)</td>
    <td>0.020 (2)</td>
    <td>0.016 (2)</td>
    <td>0.0008 (17)</td>
    <td>0.0064 (17)</td>
    <td>0.0031 (17)</td>
  </tr>
  <tr>
    <td>C16</td>
    <td>0.024 (2)</td>
    <td>0.026 (2)</td>
    <td>0.022 (2)</td>
    <td>0.0020 (18)</td>
    <td>-0.0017 (18)</td>
    <td>0.0048 (19)</td>
  </tr>
  <tr>
    <td>C17</td>
    <td>0.030 (3)</td>
    <td>0.039 (3)</td>
    <td>0.026 (2)</td>
    <td>-0.009 (2)</td>
    <td>-0.007 (2)</td>
    <td>0.000 (2)</td>
  </tr>
  <tr>
    <td>C18</td>
    <td>0.038 (3)</td>
    <td>0.050 (3)</td>
    <td>0.021 (2)</td>
    <td>0.014 (3)</td>
    <td>-0.0043 (19)</td>
    <td>0.008 (3)</td>
  </tr>
  <tr>
    <td>C19</td>
    <td>0.048 (3)</td>
    <td>0.027 (2)</td>
    <td>0.032 (3)</td>
    <td>0.002 (2)</td>
    <td>-0.002 (2)</td>
    <td>0.009 (2)</td>
  </tr>
  <tr>
    <td>C20</td>
    <td>0.036 (3)</td>
    <td>0.024 (2)</td>
    <td>0.024 (2)</td>
    <td>-0.0014 (19)</td>
    <td>-0.003 (2)</td>
    <td>0.0008 (19)</td>
  </tr>
  <tr>
    <td>C21</td>
    <td>0.023 (2)</td>
    <td>0.0134 (19)</td>
    <td>0.0191 (19)</td>
    <td>-0.0069 (17)</td>
    <td>0.0025 (16)</td>
    <td>0.0014 (17)</td>
  </tr>
  <tr>
    <td>C22</td>
    <td>0.023 (2)</td>
    <td>0.020 (2)</td>
    <td>0.025 (2)</td>
    <td>-0.0041 (17)</td>
    <td>0.0030 (18)</td>
    <td>0.0003 (18)</td>
  </tr>
  <tr>
    <td>C23</td>
    <td>0.034 (3)</td>
    <td>0.023 (2)</td>
    <td>0.029 (2)</td>
    <td>0.0077 (19)</td>
    <td>0.011 (2)</td>
    <td>-0.0020 (19)</td>
  </tr>
  <tr>
    <td>C24</td>
    <td>0.041 (3)</td>
    <td>0.020 (2)</td>
    <td>0.029 (2)</td>
    <td>-0.008 (2)</td>
    <td>0.002 (2)</td>
    <td>-0.0083 (19)</td>
  </tr>
  <tr>
    <td>C25</td>
    <td>0.027 (2)</td>
    <td>0.030 (2)</td>
    <td>0.030 (2)</td>
    <td>-0.0094 (19)</td>
    <td>-0.006 (2)</td>
    <td>0.001 (2)</td>
  </tr>
  <tr>
    <td>C26</td>
    <td>0.028 (2)</td>
    <td>0.019 (2)</td>
    <td>0.027 (2)</td>
    <td>0.0013 (16)</td>
    <td>0.0004 (19)</td>
    <td>-0.0024 (17)</td>
  </tr>
  <tr>
    <td>C27</td>
    <td>0.022 (2)</td>
    <td>0.021 (2)</td>
    <td>0.023 (2)</td>
    <td>-0.0045 (17)</td>
    <td>-0.0017 (18)</td>
    <td>-0.0068 (18)</td>
  </tr>
  <tr>
    <td>C28</td>
    <td>0.039 (3)</td>
    <td>0.044 (3)</td>
    <td>0.023 (2)</td>
    <td>-0.004 (2)</td>
    <td>0.003 (2)</td>
    <td>-0.009 (2)</td>
  </tr>
  <tr>
    <td>C29</td>
    <td>0.046 (3)</td>
    <td>0.088 (4)</td>
    <td>0.037 (3)</td>
    <td>-0.020 (3)</td>
    <td>0.017 (3)</td>
    <td>-0.027 (3)</td>
  </tr>
  <tr>
    <td>C30</td>
    <td>0.031 (3)</td>
    <td>0.070 (4)</td>
    <td>0.075 (4)</td>
    <td>-0.001 (3)</td>
    <td>0.019 (3)</td>
    <td>-0.044 (3)</td>
  </tr>
  <tr>
    <td>C31</td>
    <td>0.019 (2)</td>
    <td>0.032 (2)</td>
    <td>0.083 (4)</td>
    <td>0.002 (2)</td>
    <td>0.000 (2)</td>
    <td>-0.019 (3)</td>
  </tr>
  <tr>
    <td>C32</td>
    <td>0.020 (2)</td>
    <td>0.023 (2)</td>
    <td>0.049 (3)</td>
    <td>-0.0016 (17)</td>
    <td>0.002 (2)</td>
    <td>-0.003 (2)</td>
  </tr>
  <tr>
    <td>C33</td>
    <td>0.020 (2)</td>
    <td>0.0106 (18)</td>
    <td>0.018 (2)</td>
    <td>0.0033 (16)</td>
    <td>-0.0008 (17)</td>
    <td>-0.0029 (16)</td>
  </tr>
  <tr>
    <td>C34</td>
    <td>0.025 (2)</td>
    <td>0.026 (2)</td>
    <td>0.022 (2)</td>
    <td>0.0025 (18)</td>
    <td>0.0084 (19)</td>
    <td>0.0006 (19)</td>
  </tr>
  <tr>
    <td>C35</td>
    <td>0.023 (2)</td>
    <td>0.038 (3)</td>
    <td>0.034 (3)</td>
    <td>-0.0082 (19)</td>
    <td>-0.004 (2)</td>
    <td>-0.007 (2)</td>
  </tr>
  <tr>
    <td>C36</td>
    <td>0.039 (3)</td>
    <td>0.040 (3)</td>
    <td>0.023 (2)</td>
    <td>-0.004 (2)</td>
    <td>-0.005 (2)</td>
    <td>-0.007 (2)</td>
  </tr>
  <tr>
    <td>C37</td>
    <td>0.036 (3)</td>
    <td>0.039 (3)</td>
    <td>0.013 (2)</td>
    <td>0.001 (2)</td>
    <td>0.0035 (19)</td>
    <td>-0.002 (2)</td>
  </tr>
  <tr>
    <td>C38</td>
    <td>0.023 (2)</td>
    <td>0.023 (2)</td>
    <td>0.022 (2)</td>
    <td>-0.0012 (17)</td>
    <td>-0.0012 (18)</td>
    <td>-0.0043 (18)</td>
  </tr>
  <tr>
    <td>C39</td>
    <td>0.015 (2)</td>
    <td>0.0116 (18)</td>
    <td>0.020 (2)</td>
    <td>0.0006 (15)</td>
    <td>0.0014 (17)</td>
    <td>0.0026 (16)</td>
  </tr>
  <tr>
    <td>C40</td>
    <td>0.029 (2)</td>
    <td>0.019 (2)</td>
    <td>0.026 (2)</td>
    <td>0.0088 (17)</td>
    <td>-0.0024 (18)</td>
    <td>-0.0027 (17)</td>
  </tr>
  <tr>
    <td>C41</td>
    <td>0.033 (3)</td>
    <td>0.021 (2)</td>
    <td>0.040 (3)</td>
    <td>0.0089 (19)</td>
    <td>0.001 (2)</td>
    <td>-0.008 (2)</td>
  </tr>
  <tr>
    <td>C42</td>
    <td>0.028 (2)</td>
    <td>0.025 (2)</td>
    <td>0.036 (3)</td>
    <td>0.0117 (19)</td>
    <td>-0.003 (2)</td>
    <td>0.010 (2)</td>
  </tr>
  <tr>
    <td>C43</td>
    <td>0.031 (2)</td>
    <td>0.033 (2)</td>
    <td>0.031 (2)</td>
    <td>0.002 (2)</td>
    <td>-0.0112 (18)</td>
    <td>-0.005 (2)</td>
  </tr>
  <tr>
    <td>C44</td>
    <td>0.027 (2)</td>
    <td>0.019 (2)</td>
    <td>0.025 (2)</td>
    <td>0.0036 (18)</td>
    <td>0.0025 (19)</td>
    <td>-0.0036 (18)</td>
  </tr>
  <tr>
    <td>C45</td>
    <td>0.018 (2)</td>
    <td>0.0178 (19)</td>
    <td>0.0144 (19)</td>
    <td>0.0003 (15)</td>
    <td>-0.0032 (16)</td>
    <td>-0.0026 (16)</td>
  </tr>
  <tr>
    <td>C46</td>
    <td>0.016 (2)</td>
    <td>0.018 (2)</td>
    <td>0.017 (2)</td>
    <td>0.0009 (16)</td>
    <td>-0.0001 (17)</td>
    <td>-0.0047 (17)</td>
  </tr>
  <tr>
    <td>C47</td>
    <td>0.029 (2)</td>
    <td>0.023 (2)</td>
    <td>0.040 (3)</td>
    <td>-0.0050 (19)</td>
    <td>-0.005 (2)</td>
    <td>0.012 (2)</td>
  </tr>
  <tr>
    <td>C48</td>
    <td>0.021 (2)</td>
    <td>0.039 (3)</td>
    <td>0.060 (3)</td>
    <td>-0.003 (2)</td>
    <td>-0.013 (2)</td>
    <td>0.012 (2)</td>
  </tr>
  <tr>
    <td>C49</td>
    <td>0.030 (3)</td>
    <td>0.024 (2)</td>
    <td>0.043 (3)</td>
    <td>-0.0107 (19)</td>
    <td>0.006 (2)</td>
    <td>0.003 (2)</td>
  </tr>
  <tr>
    <td>C50</td>
    <td>0.034 (3)</td>
    <td>0.023 (2)</td>
    <td>0.035 (3)</td>
    <td>-0.0045 (19)</td>
    <td>-0.007 (2)</td>
    <td>0.011 (2)</td>
  </tr>
  <tr>
    <td>C51</td>
    <td>0.019 (2)</td>
    <td>0.030 (2)</td>
    <td>0.039 (3)</td>
    <td>0.0005 (18)</td>
    <td>-0.0033 (19)</td>
    <td>0.002 (2)</td>
  </tr>
  <tr>
    <td>C52</td>
    <td>0.020 (2)</td>
    <td>0.017 (2)</td>
    <td>0.022 (2)</td>
    <td>-0.0002 (16)</td>
    <td>-0.0040 (18)</td>
    <td>0.0018 (17)</td>
  </tr>
  <tr>
    <td>C53</td>
    <td>0.024 (2)</td>
    <td>0.026 (2)</td>
    <td>0.026 (2)</td>
    <td>-0.0038 (18)</td>
    <td>-0.0051 (19)</td>
    <td>-0.0004 (19)</td>
  </tr>
  <tr>
    <td>C54</td>
    <td>0.026 (2)</td>
    <td>0.031 (2)</td>
    <td>0.038 (3)</td>
    <td>-0.0014 (19)</td>
    <td>-0.010 (2)</td>
    <td>-0.002 (2)</td>
  </tr>
  <tr>
    <td>C55</td>
    <td>0.045 (3)</td>
    <td>0.033 (2)</td>
    <td>0.025 (3)</td>
    <td>-0.003 (2)</td>
    <td>-0.013 (2)</td>
    <td>-0.003 (2)</td>
  </tr>
  <tr>
    <td>C56</td>
    <td>0.049 (3)</td>
    <td>0.034 (3)</td>
    <td>0.019 (2)</td>
    <td>0.000 (2)</td>
    <td>0.004 (2)</td>
    <td>-0.004 (2)</td>
  </tr>
  <tr>
    <td>C57</td>
    <td>0.024 (2)</td>
    <td>0.027 (2)</td>
    <td>0.024 (2)</td>
    <td>-0.0006 (18)</td>
    <td>-0.0008 (19)</td>
    <td>-0.0027 (19)</td>
  </tr>
  <tr>
    <td>C58</td>
    <td>0.071 (4)</td>
    <td>0.061 (4)</td>
    <td>0.057 (3)</td>
    <td>0.012 (3)</td>
    <td>-0.002 (3)</td>
    <td>0.008 (3)</td>
  </tr>
  <tr>
    <td>C59</td>
    <td>0.051 (3)</td>
    <td>0.041 (3)</td>
    <td>0.043 (3)</td>
    <td>0.010 (3)</td>
    <td>-0.017 (3)</td>
    <td>0.000 (3)</td>
  </tr>
  <tr>
    <td>C60</td>
    <td>0.057 (3)</td>
    <td>0.036 (3)</td>
    <td>0.062 (4)</td>
    <td>0.006 (3)</td>
    <td>-0.021 (3)</td>
    <td>-0.003 (3)</td>
  </tr>
</table>
<table>
  <tr>
    <td>C13</td>
    <td>0.025 (2)</td>
    <td>0.027 (2)</td>
    <td>0.030 (2)</td>
    <td>0.0008 (19)</td>
    <td>0.0043 (19)</td>
    <td>0.002 (2)</td>
  </tr>
  <tr>
    <td>C14</td>
    <td>0.032 (3)</td>
    <td>0.029 (2)</td>
    <td>0.025 (2)</td>
    <td>0.004 (2)</td>
    <td>0.000 (2)</td>
    <td>-0.0013 (19)</td>
  </tr>
  <tr>
    <td>C15</td>
    <td>0.020 (2)</td>
    <td>0.020 (2)</td>
    <td>0.016 (2)</td>
    <td>0.0008 (17)</td>
    <td>0.0064 (17)</td>
    <td>0.0031 (17)</td>
  </tr>
  <tr>
    <td>C16</td>
    <td>0.024 (2)</td>
    <td>0.026 (2)</td>
    <td>0.022 (2)</td>
    <td>0.0020 (18)</td>
    <td>-0.0017 (18)</td>
    <td>0.0048 (19)</td>
  </tr>
  <tr>
    <td>C17</td>
    <td>0.030 (3)</td>
    <td>0.039 (3)</td>
    <td>0.026 (2)</td>
    <td>-0.009 (2)</td>
    <td>-0.007 (2)</td>
    <td>0.000 (2)</td>
  </tr>
  <tr>
    <td>C18</td>
    <td>0.038 (3)</td>
    <td>0.050 (3)</td>
    <td>0.021 (2)</td>
    <td>0.014 (3)</td>
    <td>-0.0043 (19)</td>
    <td>0.008 (3)</td>
  </tr>
  <tr>
    <td>C19</td>
    <td>0.048 (3)</td>
    <td>0.027 (2)</td>
    <td>0.032 (3)</td>
    <td>0.002 (2)</td>
    <td>-0.002 (2)</td>
    <td>0.009 (2)</td>
  </tr>
  <tr>
    <td>C20</td>
    <td>0.036 (3)</td>
    <td>0.024 (2)</td>
    <td>0.024 (2)</td>
    <td>-0.0014 (19)</td>
    <td>-0.003 (2)</td>
    <td>0.0008 (19)</td>
  </tr>
  <tr>
    <td>C21</td>
    <td>0.023 (2)</td>
    <td>0.0134 (19)</td>
    <td>0.0191 (19)</td>
    <td>-0.0069 (17)</td>
    <td>0.0025 (16)</td>
    <td>0.0014 (17)</td>
  </tr>
  <tr>
    <td>C22</td>
    <td>0.023 (2)</td>
    <td>0.020 (2)</td>
    <td>0.025 (2)</td>
    <td>-0.0041 (17)</td>
    <td>0.0030 (18)</td>
    <td>0.0003 (18)</td>
  </tr>
  <tr>
    <td>C23</td>
    <td>0.034 (3)</td>
    <td>0.023 (2)</td>
    <td>0.029 (2)</td>
    <td>0.0077 (19)</td>
    <td>0.011 (2)</td>
    <td>-0.0020 (19)</td>
  </tr>
  <tr>
    <td>C24</td>
    <td>0.041 (3)</td>
    <td>0.020 (2)</td>
    <td>0.029 (2)</td>
    <td>-0.008 (2)</td>
    <td>0.002 (2)</td>
    <td>-0.0083 (19)</td>
  </tr>
  <tr>
    <td>C25</td>
    <td>0.027 (2)</td>
    <td>0.030 (2)</td>
    <td>0.030 (2)</td>
    <td>-0.0094 (19)</td>
    <td>-0.006 (2)</td>
    <td>0.001 (2)</td>
  </tr>
  <tr>
    <td>C26</td>
    <td>0.028 (2)</td>
    <td>0.019 (2)</td>
    <td>0.027 (2)</td>
    <td>0.0013 (16)</td>
    <td>0.0004 (19)</td>
    <td>-0.0024 (17)</td>
  </tr>
  <tr>
    <td>C27</td>
    <td>0.022 (2)</td>
    <td>0.021 (2)</td>
    <td>0.023 (2)</td>
    <td>-0.0045 (17)</td>
    <td>-0.0017 (18)</td>
    <td>-0.0068 (18)</td>
  </tr>
  <tr>
    <td>C28</td>
    <td>0.039 (3)</td>
    <td>0.044 (3)</td>
    <td>0.023 (2)</td>
    <td>-0.004 (2)</td>
    <td>0.003 (2)</td>
    <td>-0.009 (2)</td>
  </tr>
  <tr>
    <td>C29</td>
    <td>0.046 (3)</td>
    <td>0.088 (4)</td>
    <td>0.037 (3)</td>
    <td>-0.020 (3)</td>
    <td>0.017 (3)</td>
    <td>-0.027 (3)</td>
  </tr>
  <tr>
    <td>C30</td>
    <td>0.031 (3)</td>
    <td>0.070 (4)</td>
    <td>0.075 (4)</td>
    <td>-0.001 (3)</td>
    <td>0.019 (3)</td>
    <td>-0.044 (3)</td>
  </tr>
  <tr>
    <td>C31</td>
    <td>0.019 (2)</td>
    <td>0.032 (2)</td>
    <td>0.083 (4)</td>
    <td>0.002 (2)</td>
    <td>0.000 (2)</td>
    <td>-0.019 (3)</td>
  </tr>
  <tr>
    <td>C32</td>
    <td>0.020 (2)</td>
    <td>0.023 (2)</td>
    <td>0.049 (3)</td>
    <td>-0.0016 (17)</td>
    <td>0.002 (2)</td>
    <td>-0.003 (2)</td>
  </tr>
  <tr>
    <td>C33</td>
    <td>0.020 (2)</td>
    <td>0.0106 (18)</td>
    <td>0.018 (2)</td>
    <td>0.0033 (16)</td>
    <td>-0.0008 (17)</td>
    <td>-0.0029 (16)</td>
  </tr>
  <tr>
    <td>C34</td>
    <td>0.025 (2)</td>
    <td>0.026 (2)</td>
    <td>0.022 (2)</td>
    <td>0.0025 (18)</td>
    <td>0.0084 (19)</td>
    <td>0.0006 (19)</td>
  </tr>
  <tr>
    <td>C35</td>
    <td>0.023 (2)</td>
    <td>0.038 (3)</td>
    <td>0.034 (3)</td>
    <td>-0.0082 (19)</td>
    <td>-0.004 (2)</td>
    <td>-0.007 (2)</td>
  </tr>
  <tr>
    <td>C36</td>
    <td>0.039 (3)</td>
    <td>0.040 (3)</td>
    <td>0.023 (2)</td>
    <td>-0.004 (2)</td>
    <td>-0.005 (2)</td>
    <td>-0.007 (2)</td>
  </tr>
  <tr>
    <td>C37</td>
    <td>0.036 (3)</td>
    <td>0.039 (3)</td>
    <td>0.013 (2)</td>
    <td>0.001 (2)</td>
    <td>0.0035 (19)</td>
    <td>-0.002 (2)</td>
  </tr>
  <tr>
    <td>C38</td>
    <td>0.023 (2)</td>
    <td>0.023 (2)</td>
    <td>0.022 (2)</td>
    <td>-0.0012 (17)</td>
    <td>-0.0012 (18)</td>
    <td>-0.0043 (18)</td>
  </tr>
  <tr>
    <td>C39</td>
    <td>0.015 (2)</td>
    <td>0.0116 (18)</td>
    <td>0.020 (2)</td>
    <td>0.0006 (15)</td>
    <td>0.0014 (17)</td>
    <td>0.0026 (16)</td>
  </tr>
  <tr>
    <td>C40</td>
    <td>0.029 (2)</td>
    <td>0.019 (2)</td>
    <td>0.026 (2)</td>
    <td>0.0088 (17)</td>
    <td>-0.0024 (18)</td>
    <td>-0.0027 (17)</td>
  </tr>
  <tr>
    <td>C41</td>
    <td>0.033 (3)</td>
    <td>0.021 (2)</td>
    <td>0.040 (3)</td>
    <td>0.0089 (19)</td>
    <td>0.001 (2)</td>
    <td>-0.008 (2)</td>
  </tr>
  <tr>
    <td>C42</td>
    <td>0.028 (2)</td>
    <td>0.025 (2)</td>
    <td>0.036 (3)</td>
    <td>0.0117 (19)</td>
    <td>-0.003 (2)</td>
    <td>0.010 (2)</td>
  </tr>
  <tr>
    <td>C43</td>
    <td>0.031 (2)</td>
    <td>0.033 (2)</td>
    <td>0.031 (2)</td>
    <td>0.002 (2)</td>
    <td>-0.0112 (18)</td>
    <td>-0.005 (2)</td>
  </tr>
  <tr>
    <td>C44</td>
    <td>0.027 (2)</td>
    <td>0.019 (2)</td>
    <td>0.025 (2)</td>
    <td>0.0036 (18)</td>
    <td>0.0025 (19)</td>
    <td>-0.0036 (18)</td>
  </tr>
  <tr>
    <td>C45</td>
    <td>0.018 (2)</td>
    <td>0.0178 (19)</td>
    <td>0.0144 (19)</td>
    <td>0.0003 (15)</td>
    <td>-0.0032 (16)</td>
    <td>-0.0026 (16)</td>
  </tr>
  <tr>
    <td>C46</td>
    <td>0.016 (2)</td>
    <td>0.018 (2)</td>
    <td>0.017 (2)</td>
    <td>0.0009 (16)</td>
    <td>-0.0001 (17)</td>
    <td>-0.0047 (17)</td>
  </tr>
  <tr>
    <td>C47</td>
    <td>0.029 (2)</td>
    <td>0.023 (2)</td>
    <td>0.040 (3)</td>
    <td>-0.0050 (19)</td>
    <td>-0.005 (2)</td>
    <td>0.012 (2)</td>
  </tr>
  <tr>
    <td>C48</td>
    <td>0.021 (2)</td>
    <td>0.039 (3)</td>
    <td>0.060 (3)</td>
    <td>-0.003 (2)</td>
    <td>-0.013 (2)</td>
    <td>0.012 (2)</td>
  </tr>
  <tr>
    <td>C49</td>
    <td>0.030 (3)</td>
    <td>0.024 (2)</td>
    <td>0.043 (3)</td>
    <td>-0.0107 (19)</td>
    <td>0.006 (2)</td>
    <td>0.003 (2)</td>
  </tr>
  <tr>
    <td>C50</td>
    <td>0.034 (3)</td>
    <td>0.023 (2)</td>
    <td>0.035 (3)</td>
    <td>-0.0045 (19)</td>
    <td>-0.007 (2)</td>
    <td>0.011 (2)</td>
  </tr>
  <tr>
    <td>C51</td>
    <td>0.019 (2)</td>
    <td>0.030 (2)</td>
    <td>0.039 (3)</td>
    <td>0.0005 (18)</td>
    <td>-0.0033 (19)</td>
    <td>0.002 (2)</td>
  </tr>
  <tr>
    <td>C52</td>
    <td>0.020 (2)</td>
    <td>0.017 (2)</td>
    <td>0.022 (2)</td>
    <td>-0.0002 (16)</td>
    <td>-0.0040 (18)</td>
    <td>0.0018 (17)</td>
  </tr>
  <tr>
    <td>C53</td>
    <td>0.024 (2)</td>
    <td>0.026 (2)</td>
    <td>0.026 (2)</td>
    <td>-0.0038 (18)</td>
    <td>-0.0051 (19)</td>
    <td>-0.0004 (19)</td>
  </tr>
  <tr>
    <td>C54</td>
    <td>0.026 (2)</td>
    <td>0.031 (2)</td>
    <td>0.038 (3)</td>
    <td>-0.0014 (19)</td>
    <td>-0.010 (2)</td>
    <td>-0.002 (2)</td>
  </tr>
  <tr>
    <td>C55</td>
    <td>0.045 (3)</td>
    <td>0.033 (2)</td>
    <td>0.025 (3)</td>
    <td>-0.003 (2)</td>
    <td>-0.013 (2)</td>
    <td>-0.003 (2)</td>
  </tr>
  <tr>
    <td>C56</td>
    <td>0.049 (3)</td>
    <td>0.034 (3)</td>
    <td>0.019 (2)</td>
    <td>0.000 (2)</td>
    <td>0.004 (2)</td>
    <td>-0.004 (2)</td>
  </tr>
  <tr>
    <td>C57</td>
    <td>0.024 (2)</td>
    <td>0.027 (2)</td>
    <td>0.024 (2)</td>
    <td>-0.0006 (18)</td>
    <td>-0.0008 (19)</td>
    <td>-0.0027 (19)</td>
  </tr>
  <tr>
    <td>C58</td>
    <td>0.071 (4)</td>
    <td>0.061 (4)</td>
    <td>0.057 (3)</td>
    <td>0.012 (3)</td>
    <td>-0.002 (3)</td>
    <td>0.008 (3)</td>
  </tr>
  <tr>
    <td>C59</td>
    <td>0.051 (3)</td>
    <td>0.041 (3)</td>
    <td>0.043 (3)</td>
    <td>0.010 (3)</td>
    <td>-0.017 (3)</td>
    <td>0.000 (3)</td>
  </tr>
  <tr>
    <td>C60</td>
    <td>0.057 (3)</td>
    <td>0.036 (3)</td>
    <td>0.062 (4)</td>
    <td>0.006 (3)</td>
    <td>-0.021 (3)</td>
    <td>-0.003 (3)</td>
  </tr>
</table>
<table><tr><td>C61</td><td>0.071 (4)</td><td>0.059 (4)</td><td>0.060 (4)</td><td>0.023 (3)</td><td>-0.017 (3)</td><td>-0.015 (3)</td></tr><tr><td>C62</td><td>0.067 (4)</td><td>0.061 (4)</td><td>0.085 (5)</td><td>-0.003 (3)</td><td>-0.018 (3)</td><td>0.001 (4)</td></tr><tr><td>C63</td><td>0.067 (4)</td><td>0.053 (4)</td><td>0.088 (5)</td><td>-0.010 (3)</td><td>-0.023 (4)</td><td>-0.006 (4)</td></tr><tr><td>C64</td><td>0.060 (4)</td><td>0.040 (3)</td><td>0.058 (4)</td><td>-0.002 (3)</td><td>-0.018 (3)</td><td>-0.010 (3)</td></tr><tr><td>C65</td><td>0.037 (3)</td><td>0.151 (6)</td><td>0.069 (4)</td><td>0.026 (3)</td><td>0.001 (3)</td><td>0.019 (4)</td></tr><tr><td>C66</td><td>0.022 (3)</td><td>0.076 (4)</td><td>0.068 (4)</td><td>0.016 (3)</td><td>0.017 (3)</td><td>0.025 (3)</td></tr><tr><td>C67</td><td>0.034 (4)</td><td>0.075 (5)</td><td>0.148 (7)</td><td>0.020 (3)</td><td>0.036 (4)</td><td>0.042 (5)</td></tr><tr><td>C68</td><td>0.042 (4)</td><td>0.087 (6)</td><td>0.172 (8)</td><td>0.003 (4)</td><td>0.045 (5)</td><td>0.000 (6)</td></tr><tr><td>C69</td><td>0.049 (4)</td><td>0.103 (6)</td><td>0.096 (5)</td><td>-0.021 (4)</td><td>0.043 (4)</td><td>-0.041 (5)</td></tr><tr><td>C70</td><td>0.053 (4)</td><td>0.086 (5)</td><td>0.060 (4)</td><td>-0.008 (3)</td><td>0.022 (3)</td><td>0.007 (3)</td></tr><tr><td>C71</td><td>0.037 (3)</td><td>0.067 (4)</td><td>0.050 (3)</td><td>0.000 (3)</td><td>0.011 (2)</td><td>0.019 (3)</td></tr><tr><td>Cl1</td><td>0.1933 (19)</td><td>0.0721 (12)</td><td>0.0726 (11)</td><td>-0.0196 (12)</td><td>-0.0191 (12)</td><td>-0.0096 (9)</td></tr><tr><td>Cl2</td><td>0.0980 (13)</td><td>0.0890 (13)</td><td>0.0943 (12)</td><td>0.0133 (10)</td><td>0.0097 (10)</td><td>0.0026 (10)</td></tr><tr><td>C72</td><td>0.083 (4)</td><td>0.055 (4)</td><td>0.101 (5)</td><td>0.008 (3)</td><td>-0.002 (4)</td><td>-0.002 (3)</td></tr></table>

Geometric parameters (Å, °)

<table><tr><td>Pt1—Fe1</td><td>2.5770 (5)</td><td>C33—C38</td><td>1.379 (4)</td></tr><tr><td>Pt1—P2</td><td>2.2700 (9)</td><td>C34—C35</td><td>1.378 (5)</td></tr><tr><td>Pt1—P3</td><td>2.2529 (9)</td><td>C34—H34</td><td>0.9300</td></tr><tr><td>Pt1—C1</td><td>2.023 (3)</td><td>C35—C36</td><td>1.375 (5)</td></tr><tr><td>Fe1—P1</td><td>2.1857 (11)</td><td>C35—H35</td><td>0.9300</td></tr><tr><td>Fe1—C1</td><td>2.107 (3)</td><td>C36—C37</td><td>1.375 (5)</td></tr><tr><td>Fe1—C2</td><td>2.109 (4)</td><td>C36—H36</td><td>0.9300</td></tr><tr><td>Fe1—C12</td><td>1.929 (4)</td><td>C37—C38</td><td>1.360 (5)</td></tr><tr><td>Fe1—C13</td><td>1.749 (4)</td><td>C37—H37</td><td>0.9300</td></tr><tr><td>Fe1—C14</td><td>1.781 (4)</td><td>C38—H38</td><td>0.9300</td></tr><tr><td>P1—C46</td><td>1.824 (4)</td><td>C39—C40</td><td>1.384 (4)</td></tr><tr><td>P1—C45</td><td>1.830 (3)</td><td>C39—C44</td><td>1.386 (4)</td></tr><tr><td>P1—C52</td><td>1.831 (3)</td><td>C40—C41</td><td>1.377 (5)</td></tr><tr><td>P2—C33</td><td>1.809 (3)</td><td>C40—H40</td><td>0.9300</td></tr><tr><td>P2—C39</td><td>1.814 (3)</td><td>C41—C42</td><td>1.369 (5)</td></tr><tr><td>P2—C45</td><td>1.837 (3)</td><td>C41—H41</td><td>0.9300</td></tr><tr><td>P3—C15</td><td>1.819 (4)</td><td>C42—C43</td><td>1.377 (5)</td></tr><tr><td>P3—C27</td><td>1.822 (4)</td><td>C42—H42</td><td>0.9300</td></tr><tr><td>P3—C21</td><td>1.824 (3)</td><td>C43—C44</td><td>1.372 (5)</td></tr><tr><td>O1—C12</td><td>1.207 (4)</td><td>C43—H43</td><td>0.9300</td></tr><tr><td>O2—C13</td><td>1.152 (4)</td><td>C44—H44</td><td>0.9300</td></tr><tr><td>O3—C14</td><td>1.149 (4)</td><td>C45—H45A</td><td>0.9700</td></tr><tr><td>C1—C2</td><td>1.386 (4)</td><td>C45—H43B</td><td>0.9700</td></tr><tr><td>C1—H1</td><td>0.9806</td><td>C46—C47</td><td>1.369 (4)</td></tr><tr><td>C2—C12</td><td>1.458 (5)</td><td>C46—C51</td><td>1.376 (5)</td></tr><tr><td>C2—C3</td><td>1.499 (5)</td><td>C47—C48</td><td>1.386 (5)</td></tr><tr><td>C3—C4</td><td>1.387 (5)</td><td>C47—H47</td><td>0.9300</td></tr><tr><td>C3—C10</td><td>1.390 (4)</td><td>C48—C49</td><td>1.362 (5)</td></tr><tr><td>C4—C5</td><td>1.379 (5)</td><td>C48—H48</td><td>0.9300</td></tr><tr><td>C4—H4</td><td>0.9300</td><td>C49—C50</td><td>1.366 (5)</td></tr><tr><td>C5—C7</td><td>1.391 (5)</td><td>C49—H49</td><td>0.9300</td></tr></table>
<table><tr><td>C61</td><td>0.071 (4)</td><td>0.059 (4)</td><td>0.060 (4)</td><td>0.023 (3)</td><td>-0.017 (3)</td><td>-0.015 (3)</td></tr><tr><td>C62</td><td>0.067 (4)</td><td>0.061 (4)</td><td>0.085 (5)</td><td>-0.003 (3)</td><td>-0.018 (3)</td><td>0.001 (4)</td></tr><tr><td>C63</td><td>0.067 (4)</td><td>0.053 (4)</td><td>0.088 (5)</td><td>-0.010 (3)</td><td>-0.023 (4)</td><td>-0.006 (4)</td></tr><tr><td>C64</td><td>0.060 (4)</td><td>0.040 (3)</td><td>0.058 (4)</td><td>-0.002 (3)</td><td>-0.018 (3)</td><td>-0.010 (3)</td></tr><tr><td>C65</td><td>0.037 (3)</td><td>0.151 (6)</td><td>0.069 (4)</td><td>0.026 (3)</td><td>0.001 (3)</td><td>0.019 (4)</td></tr><tr><td>C66</td><td>0.022 (3)</td><td>0.076 (4)</td><td>0.068 (4)</td><td>0.016 (3)</td><td>0.017 (3)</td><td>0.025 (3)</td></tr><tr><td>C67</td><td>0.034 (4)</td><td>0.075 (5)</td><td>0.148 (7)</td><td>0.020 (3)</td><td>0.036 (4)</td><td>0.042 (5)</td></tr><tr><td>C68</td><td>0.042 (4)</td><td>0.087 (6)</td><td>0.172 (8)</td><td>0.003 (4)</td><td>0.045 (5)</td><td>0.000 (6)</td></tr><tr><td>C69</td><td>0.049 (4)</td><td>0.103 (6)</td><td>0.096 (5)</td><td>-0.021 (4)</td><td>0.043 (4)</td><td>-0.041 (5)</td></tr><tr><td>C70</td><td>0.053 (4)</td><td>0.086 (5)</td><td>0.060 (4)</td><td>-0.008 (3)</td><td>0.022 (3)</td><td>0.007 (3)</td></tr><tr><td>C71</td><td>0.037 (3)</td><td>0.067 (4)</td><td>0.050 (3)</td><td>0.000 (3)</td><td>0.011 (2)</td><td>0.019 (3)</td></tr><tr><td>Cl1</td><td>0.1933 (19)</td><td>0.0721 (12)</td><td>0.0726 (11)</td><td>-0.0196 (12)</td><td>-0.0191 (12)</td><td>-0.0096 (9)</td></tr><tr><td>Cl2</td><td>0.0980 (13)</td><td>0.0890 (13)</td><td>0.0943 (12)</td><td>0.0133 (10)</td><td>0.0097 (10)</td><td>0.0026 (10)</td></tr><tr><td>C72</td><td>0.083 (4)</td><td>0.055 (4)</td><td>0.101 (5)</td><td>0.008 (3)</td><td>-0.002 (4)</td><td>-0.002 (3)</td></tr></table>

Geometric parameters (Å, °)

<table><tr><td>Pt1—Fe1</td><td>2.5770 (5)</td><td>C33—C38</td><td>1.379 (4)</td></tr><tr><td>Pt1—P2</td><td>2.2700 (9)</td><td>C34—C35</td><td>1.378 (5)</td></tr><tr><td>Pt1—P3</td><td>2.2529 (9)</td><td>C34—H34</td><td>0.9300</td></tr><tr><td>Pt1—C1</td><td>2.023 (3)</td><td>C35—C36</td><td>1.375 (5)</td></tr><tr><td>Fe1—P1</td><td>2.1857 (11)</td><td>C35—H35</td><td>0.9300</td></tr><tr><td>Fe1—C1</td><td>2.107 (3)</td><td>C36—C37</td><td>1.375 (5)</td></tr><tr><td>Fe1—C2</td><td>2.109 (4)</td><td>C36—H36</td><td>0.9300</td></tr><tr><td>Fe1—C12</td><td>1.929 (4)</td><td>C37—C38</td><td>1.360 (5)</td></tr><tr><td>Fe1—C13</td><td>1.749 (4)</td><td>C37—H37</td><td>0.9300</td></tr><tr><td>Fe1—C14</td><td>1.781 (4)</td><td>C38—H38</td><td>0.9300</td></tr><tr><td>P1—C46</td><td>1.824 (4)</td><td>C39—C40</td><td>1.384 (4)</td></tr><tr><td>P1—C45</td><td>1.830 (3)</td><td>C39—C44</td><td>1.386 (4)</td></tr><tr><td>P1—C52</td><td>1.831 (3)</td><td>C40—C41</td><td>1.377 (5)</td></tr><tr><td>P2—C33</td><td>1.809 (3)</td><td>C40—H40</td><td>0.9300</td></tr><tr><td>P2—C39</td><td>1.814 (3)</td><td>C41—C42</td><td>1.369 (5)</td></tr><tr><td>P2—C45</td><td>1.837 (3)</td><td>C41—H41</td><td>0.9300</td></tr><tr><td>P3—C15</td><td>1.819 (4)</td><td>C42—C43</td><td>1.377 (5)</td></tr><tr><td>P3—C27</td><td>1.822 (4)</td><td>C42—H42</td><td>0.9300</td></tr><tr><td>P3—C21</td><td>1.824 (3)</td><td>C43—C44</td><td>1.372 (5)</td></tr><tr><td>O1—C12</td><td>1.207 (4)</td><td>C43—H43</td><td>0.9300</td></tr><tr><td>O2—C13</td><td>1.152 (4)</td><td>C44—H44</td><td>0.9300</td></tr><tr><td>O3—C14</td><td>1.149 (4)</td><td>C45—H45A</td><td>0.9700</td></tr><tr><td>C1—C2</td><td>1.386 (4)</td><td>C45—H43B</td><td>0.9700</td></tr><tr><td>C1—H1</td><td>0.9806</td><td>C46—C47</td><td>1.369 (4)</td></tr><tr><td>C2—C12</td><td>1.458 (5)</td><td>C46—C51</td><td>1.376 (5)</td></tr><tr><td>C2—C3</td><td>1.499 (5)</td><td>C47—C48</td><td>1.386 (5)</td></tr><tr><td>C3—C4</td><td>1.387 (5)</td><td>C47—H47</td><td>0.9300</td></tr><tr><td>C3—C10</td><td>1.390 (4)</td><td>C48—C49</td><td>1.362 (5)</td></tr><tr><td>C4—C5</td><td>1.379 (5)</td><td>C48—H48</td><td>0.9300</td></tr><tr><td>C4—H4</td><td>0.9300</td><td>C49—C50</td><td>1.366 (5)</td></tr><tr><td>C5—C7</td><td>1.391 (5)</td><td>C49—H49</td><td>0.9300</td></tr></table>
<table>
  <tr>
    <td>C5—C6</td>
    <td>1.509 (5)</td>
    <td>C50—C51</td>
    <td>1.376 (5)</td>
  </tr>
  <tr>
    <td>C6—H6A</td>
    <td>0.9600</td>
    <td>C50—H50</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C6—H6B</td>
    <td>0.9600</td>
    <td>C51—H51</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C6—H6C</td>
    <td>0.9600</td>
    <td>C52—C53</td>
    <td>1.375 (4)</td>
  </tr>
  <tr>
    <td>C7—C9</td>
    <td>1.391 (5)</td>
    <td>C52—C57</td>
    <td>1.395 (5)</td>
  </tr>
  <tr>
    <td>C7—C8</td>
    <td>1.501 (5)</td>
    <td>C53—C54</td>
    <td>1.385 (5)</td>
  </tr>
  <tr>
    <td>C8—H8A</td>
    <td>0.9600</td>
    <td>C53—H53</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C8—H8B</td>
    <td>0.9600</td>
    <td>C54—C55</td>
    <td>1.364 (5)</td>
  </tr>
  <tr>
    <td>C8—H8C</td>
    <td>0.9600</td>
    <td>C54—H54</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C9—C10</td>
    <td>1.385 (5)</td>
    <td>C55—C56</td>
    <td>1.374 (5)</td>
  </tr>
  <tr>
    <td>C9—H9</td>
    <td>0.9300</td>
    <td>C55—H55</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C10—C11</td>
    <td>1.510 (5)</td>
    <td>C56—C57</td>
    <td>1.375 (5)</td>
  </tr>
  <tr>
    <td>C11—H11A</td>
    <td>0.9600</td>
    <td>C56—H56</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C11—H11B</td>
    <td>0.9600</td>
    <td>C57—H57</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C11—H11C</td>
    <td>0.9600</td>
    <td>C58—C59</td>
    <td>1.484 (6)</td>
  </tr>
  <tr>
    <td>C15—C16</td>
    <td>1.386 (5)</td>
    <td>C58—H58A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C15—C20</td>
    <td>1.386 (5)</td>
    <td>C58—H58B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C16—C17</td>
    <td>1.387 (5)</td>
    <td>C58—H58C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C16—H16</td>
    <td>0.9300</td>
    <td>C59—C64</td>
    <td>1.351 (6)</td>
  </tr>
  <tr>
    <td>C17—C18</td>
    <td>1.368 (5)</td>
    <td>C59—C60</td>
    <td>1.393 (6)</td>
  </tr>
  <tr>
    <td>C17—H17</td>
    <td>0.9300</td>
    <td>C60—C61</td>
    <td>1.395 (6)</td>
  </tr>
  <tr>
    <td>C18—C19</td>
    <td>1.375 (5)</td>
    <td>C60—H60</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C18—H18</td>
    <td>0.9300</td>
    <td>C61—C62</td>
    <td>1.365 (7)</td>
  </tr>
  <tr>
    <td>C19—C20</td>
    <td>1.364 (5)</td>
    <td>C61—H61</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C19—H19</td>
    <td>0.9300</td>
    <td>C62—C63</td>
    <td>1.382 (7)</td>
  </tr>
  <tr>
    <td>C20—H20</td>
    <td>0.9300</td>
    <td>C62—H62</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C21—C26</td>
    <td>1.383 (4)</td>
    <td>C63—C64</td>
    <td>1.389 (6)</td>
  </tr>
  <tr>
    <td>C21—C22</td>
    <td>1.390 (4)</td>
    <td>C63—H63</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C22—C23</td>
    <td>1.375 (5)</td>
    <td>C64—H64</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C22—H22</td>
    <td>0.9300</td>
    <td>C65—C66</td>
    <td>1.481 (6)</td>
  </tr>
  <tr>
    <td>C23—C24</td>
    <td>1.361 (5)</td>
    <td>C65—H65A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C23—H23</td>
    <td>0.9300</td>
    <td>C65—H65B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C24—C25</td>
    <td>1.364 (5)</td>
    <td>C65—H65C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C24—H24</td>
    <td>0.9300</td>
    <td>C66—C71</td>
    <td>1.366 (6)</td>
  </tr>
  <tr>
    <td>C25—C26</td>
    <td>1.380 (5)</td>
    <td>C66—C67</td>
    <td>1.393 (7)</td>
  </tr>
  <tr>
    <td>C25—H25</td>
    <td>0.9300</td>
    <td>C67—C68</td>
    <td>1.382 (8)</td>
  </tr>
  <tr>
    <td>C26—H26</td>
    <td>0.9300</td>
    <td>C67—H67</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C27—C28</td>
    <td>1.378 (5)</td>
    <td>C68—C69</td>
    <td>1.377 (8)</td>
  </tr>
  <tr>
    <td>C27—C32</td>
    <td>1.381 (5)</td>
    <td>C68—H68</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C28—C29</td>
    <td>1.377 (6)</td>
    <td>C69—C70</td>
    <td>1.377 (7)</td>
  </tr>
  <tr>
    <td>C28—H28</td>
    <td>0.9300</td>
    <td>C69—H69</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C29—C30</td>
    <td>1.358 (6)</td>
    <td>C70—C71</td>
    <td>1.349 (6)</td>
  </tr>
  <tr>
    <td>C29—H29</td>
    <td>0.9300</td>
    <td>C70—H70</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C30—C31</td>
    <td>1.368 (6)</td>
    <td>C71—H71</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C30—H30</td>
    <td>0.9300</td>
    <td>C11—C72</td>
    <td>1.741 (5)</td>
  </tr>
  <tr>
    <td>C31—C32</td>
    <td>1.392 (5)</td>
    <td>C12—C72</td>
    <td>1.741 (5)</td>
  </tr>
  <tr>
    <td>C31—H31</td>
    <td>0.9300</td>
    <td>C72—H72A</td>
    <td>0.9700</td>
  </tr>
  <tr>
    <td>C32—H32</td>
    <td>0.9300</td>
    <td>C72—H72B</td>
    <td>0.9700</td>
  </tr>
</table>
<table>
  <tr>
    <td>C5—C6</td>
    <td>1.509 (5)</td>
  </tr>
  <tr>
    <td>C6—H6A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C6—H6B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C6—H6C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C7—C9</td>
    <td>1.391 (5)</td>
  </tr>
  <tr>
    <td>C7—C8</td>
    <td>1.501 (5)</td>
  </tr>
  <tr>
    <td>C8—H8A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C8—H8B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C8—H8C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C9—C10</td>
    <td>1.385 (5)</td>
  </tr>
  <tr>
    <td>C9—H9</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C10—C11</td>
    <td>1.510 (5)</td>
  </tr>
  <tr>
    <td>C11—H11A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C11—H11B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C11—H11C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C15—C16</td>
    <td>1.386 (5)</td>
  </tr>
  <tr>
    <td>C15—C20</td>
    <td>1.386 (5)</td>
  </tr>
  <tr>
    <td>C16—C17</td>
    <td>1.387 (5)</td>
  </tr>
  <tr>
    <td>C16—H16</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C17—C18</td>
    <td>1.368 (5)</td>
  </tr>
  <tr>
    <td>C17—H17</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C18—C19</td>
    <td>1.375 (5)</td>
  </tr>
  <tr>
    <td>C18—H18</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C19—C20</td>
    <td>1.364 (5)</td>
  </tr>
  <tr>
    <td>C19—H19</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C20—H20</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C21—C26</td>
    <td>1.383 (4)</td>
  </tr>
  <tr>
    <td>C21—C22</td>
    <td>1.390 (4)</td>
  </tr>
  <tr>
    <td>C22—C23</td>
    <td>1.375 (5)</td>
  </tr>
  <tr>
    <td>C22—H22</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C23—C24</td>
    <td>1.361 (5)</td>
  </tr>
  <tr>
    <td>C23—H23</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C24—C25</td>
    <td>1.364 (5)</td>
  </tr>
  <tr>
    <td>C24—H24</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C25—C26</td>
    <td>1.380 (5)</td>
  </tr>
  <tr>
    <td>C25—H25</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C26—H26</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C27—C28</td>
    <td>1.378 (5)</td>
  </tr>
  <tr>
    <td>C27—C32</td>
    <td>1.381 (5)</td>
  </tr>
  <tr>
    <td>C28—C29</td>
    <td>1.377 (6)</td>
  </tr>
  <tr>
    <td>C28—H28</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C29—C30</td>
    <td>1.358 (6)</td>
  </tr>
  <tr>
    <td>C29—H29</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C30—C31</td>
    <td>1.368 (6)</td>
  </tr>
  <tr>
    <td>C30—H30</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C31—C32</td>
    <td>1.392 (5)</td>
  </tr>
  <tr>
    <td>C31—H31</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C32—H32</td>
    <td>0.9300</td>
  </tr>
</table>

<table>
  <tr>
    <td>C50—C51</td>
    <td>1.376 (5)</td>
  </tr>
  <tr>
    <td>C50—H50</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C51—H51</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C52—C53</td>
    <td>1.375 (4)</td>
  </tr>
  <tr>
    <td>C52—C57</td>
    <td>1.395 (5)</td>
  </tr>
  <tr>
    <td>C53—C54</td>
    <td>1.385 (5)</td>
  </tr>
  <tr>
    <td>C53—H53</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C54—C55</td>
    <td>1.364 (5)</td>
  </tr>
  <tr>
    <td>C54—H54</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C55—C56</td>
    <td>1.374 (5)</td>
  </tr>
  <tr>
    <td>C55—H55</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C56—C57</td>
    <td>1.375 (5)</td>
  </tr>
  <tr>
    <td>C56—H56</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C57—H57</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C58—C59</td>
    <td>1.484 (6)</td>
  </tr>
  <tr>
    <td>C58—H58A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C58—H58B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C58—H58C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C59—C64</td>
    <td>1.351 (6)</td>
  </tr>
  <tr>
    <td>C59—C60</td>
    <td>1.393 (6)</td>
  </tr>
  <tr>
    <td>C60—C61</td>
    <td>1.395 (6)</td>
  </tr>
  <tr>
    <td>C60—H60</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C61—C62</td>
    <td>1.365 (7)</td>
  </tr>
  <tr>
    <td>C61—H61</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C62—C63</td>
    <td>1.382 (7)</td>
  </tr>
  <tr>
    <td>C62—H62</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C63—C64</td>
    <td>1.389 (6)</td>
  </tr>
  <tr>
    <td>C63—H63</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C64—H64</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C65—C66</td>
    <td>1.481 (6)</td>
  </tr>
  <tr>
    <td>C65—H65A</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C65—H65B</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C65—H65C</td>
    <td>0.9600</td>
  </tr>
  <tr>
    <td>C66—C71</td>
    <td>1.366 (6)</td>
  </tr>
  <tr>
    <td>C66—C67</td>
    <td>1.393 (7)</td>
  </tr>
  <tr>
    <td>C67—C68</td>
    <td>1.382 (8)</td>
  </tr>
  <tr>
    <td>C67—H67</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C68—C69</td>
    <td>1.377 (8)</td>
  </tr>
  <tr>
    <td>C68—H68</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C69—C70</td>
    <td>1.377 (7)</td>
  </tr>
  <tr>
    <td>C69—H69</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C70—C71</td>
    <td>1.349 (6)</td>
  </tr>
  <tr>
    <td>C70—H70</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C71—H71</td>
    <td>0.9300</td>
  </tr>
  <tr>
    <td>C11—C72</td>
    <td>1.741 (5)</td>
  </tr>
  <tr>
    <td>C12—C72</td>
    <td>1.741 (5)</td>
  </tr>
  <tr>
    <td>C72—H72A</td>
    <td>0.9700</td>
  </tr>
  <tr>
    <td>C72—H72B</td>
    <td>0.9700</td>
  </tr>
</table>
<table>
  <tbody>
    <tr>
      <td>C33—C34</td>
      <td>1.367 (4)</td>
      <td></td>
      <td></td>
    </tr>
    <tr>
      <td>P2—Pt1—Fe1</td>
      <td>102.03 (3)</td>
      <td>C28—C29—H29</td>
      <td>119.4</td>
    </tr>
    <tr>
      <td>P3—Pt1—Fe1</td>
      <td>152.88 (3)</td>
      <td>C29—C30—C31</td>
      <td>119.6 (4)</td>
    </tr>
    <tr>
      <td>C1—Pt1—Fe1</td>
      <td>52.87 (10)</td>
      <td>C29—C30—H30</td>
      <td>120.2</td>
    </tr>
    <tr>
      <td>P3—Pt1—P2</td>
      <td>105.07 (3)</td>
      <td>C31—C30—H30</td>
      <td>120.2</td>
    </tr>
    <tr>
      <td>C1—Pt1—P2</td>
      <td>152.26 (10)</td>
      <td>C30—C31—C32</td>
      <td>120.3 (4)</td>
    </tr>
    <tr>
      <td>C1—Pt1—P3</td>
      <td>100.38 (10)</td>
      <td>C30—C31—H31</td>
      <td>119.8</td>
    </tr>
    <tr>
      <td>Pt1—C1—Fe1</td>
      <td>77.18 (12)</td>
      <td>C32—C31—H31</td>
      <td>119.8</td>
    </tr>
    <tr>
      <td>C13—Fe1—C14</td>
      <td>96.51 (17)</td>
      <td>C27—C32—C31</td>
      <td>119.7 (4)</td>
    </tr>
    <tr>
      <td>C13—Fe1—C12</td>
      <td>96.59 (16)</td>
      <td>C27—C32—H32</td>
      <td>120.1</td>
    </tr>
    <tr>
      <td>C14—Fe1—C12</td>
      <td>155.50 (17)</td>
      <td>C31—C32—H32</td>
      <td>120.1</td>
    </tr>
    <tr>
      <td>C13—Fe1—C1</td>
      <td>125.43 (16)</td>
      <td>C34—C33—C38</td>
      <td>118.6 (3)</td>
    </tr>
    <tr>
      <td>C14—Fe1—C1</td>
      <td>84.72 (15)</td>
      <td>C34—C33—P2</td>
      <td>118.5 (3)</td>
    </tr>
    <tr>
      <td>C12—Fe1—C1</td>
      <td>70.81 (14)</td>
      <td>C38—C33—P2</td>
      <td>122.9 (3)</td>
    </tr>
    <tr>
      <td>C13—Fe1—C2</td>
      <td>97.50 (15)</td>
      <td>C33—C34—C35</td>
      <td>120.8 (3)</td>
    </tr>
    <tr>
      <td>C14—Fe1—C2</td>
      <td>115.51 (16)</td>
      <td>C33—C34—H34</td>
      <td>119.6</td>
    </tr>
    <tr>
      <td>C12—Fe1—C2</td>
      <td>42.03 (13)</td>
      <td>C35—C34—H34</td>
      <td>119.6</td>
    </tr>
    <tr>
      <td>C1—Fe1—C2</td>
      <td>38.38 (12)</td>
      <td>C36—C35—C34</td>
      <td>119.6 (4)</td>
    </tr>
    <tr>
      <td>C13—Fe1—P1</td>
      <td>95.17 (13)</td>
      <td>C36—C35—H35</td>
      <td>120.2</td>
    </tr>
    <tr>
      <td>C14—Fe1—P1</td>
      <td>104.63 (12)</td>
      <td>C34—C35—H35</td>
      <td>120.2</td>
    </tr>
    <tr>
      <td>C12—Fe1—P1</td>
      <td>94.69 (11)</td>
      <td>C37—C36—C35</td>
      <td>119.8 (4)</td>
    </tr>
    <tr>
      <td>C1—Fe1—P1</td>
      <td>137.46 (10)</td>
      <td>C37—C36—H36</td>
      <td>120.1</td>
    </tr>
    <tr>
      <td>C2—Fe1—P1</td>
      <td>135.94 (10)</td>
      <td>C35—C36—H36</td>
      <td>120.1</td>
    </tr>
    <tr>
      <td>C13—Fe1—Pt1</td>
      <td>170.69 (12)</td>
      <td>C38—C37—C36</td>
      <td>119.8 (4)</td>
    </tr>
    <tr>
      <td>C14—Fe1—Pt1</td>
      <td>91.16 (13)</td>
      <td>C38—C37—H37</td>
      <td>120.1</td>
    </tr>
    <tr>
      <td>C12—Fe1—Pt1</td>
      <td>74.38 (10)</td>
      <td>C36—C37—H37</td>
      <td>120.1</td>
    </tr>
    <tr>
      <td>C1—Fe1—Pt1</td>
      <td>49.95 (9)</td>
      <td>C37—C38—C33</td>
      <td>121.3 (3)</td>
    </tr>
    <tr>
      <td>C2—Fe1—Pt1</td>
      <td>74.35 (9)</td>
      <td>C37—C38—H38</td>
      <td>119.3</td>
    </tr>
    <tr>
      <td>P1—Fe1—Pt1</td>
      <td>87.95 (3)</td>
      <td>C33—C38—H38</td>
      <td>119.3</td>
    </tr>
    <tr>
      <td>C2—C1—Pt1</td>
      <td>112.5 (3)</td>
      <td>C40—C39—C44</td>
      <td>118.2 (3)</td>
    </tr>
    <tr>
      <td>C2—C1—Fe1</td>
      <td>70.9 (2)</td>
      <td>C40—C39—P2</td>
      <td>123.3 (3)</td>
    </tr>
    <tr>
      <td>C46—P1—C45</td>
      <td>102.47 (15)</td>
      <td>C44—C39—P2</td>
      <td>118.2 (3)</td>
    </tr>
    <tr>
      <td>C46—P1—C52</td>
      <td>101.87 (16)</td>
      <td>C41—C40—C39</td>
      <td>120.9 (3)</td>
    </tr>
    <tr>
      <td>C45—P1—C52</td>
      <td>100.39 (15)</td>
      <td>C41—C40—H40</td>
      <td>119.5</td>
    </tr>
    <tr>
      <td>C46—P1—Fe1</td>
      <td>114.02 (11)</td>
      <td>C39—C40—H40</td>
      <td>119.5</td>
    </tr>
    <tr>
      <td>C45—P1—Fe1</td>
      <td>114.40 (11)</td>
      <td>C42—C41—C40</td>
      <td>120.2 (4)</td>
    </tr>
    <tr>
      <td>C52—P1—Fe1</td>
      <td>121.13 (12)</td>
      <td>C42—C41—H41</td>
      <td>119.9</td>
    </tr>
    <tr>
      <td>C33—P2—C39</td>
      <td>103.75 (16)</td>
      <td>C40—C41—H41</td>
      <td>119.9</td>
    </tr>
    <tr>
      <td>C33—P2—C45</td>
      <td>107.90 (16)</td>
      <td>C41—C42—C43</td>
      <td>119.5 (3)</td>
    </tr>
    <tr>
      <td>C39—P2—C45</td>
      <td>102.34 (15)</td>
      <td>C41—C42—H42</td>
      <td>120.2</td>
    </tr>
    <tr>
      <td>C33—P2—Pt1</td>
      <td>122.98 (12)</td>
      <td>C43—C42—H42</td>
      <td>120.2</td>
    </tr>
    <tr>
      <td>C39—P2—Pt1</td>
      <td>114.88 (11)</td>
      <td>C44—C43—C42</td>
      <td>120.5 (3)</td>
    </tr>
    <tr>
      <td>C45—P2—Pt1</td>
      <td>103.02 (11)</td>
      <td>C44—C43—H43</td>
      <td>119.7</td>
    </tr>
    <tr>
      <td>C15—P3—C27</td>
      <td>105.92 (16)</td>
      <td>C42—C43—H43</td>
      <td>119.7</td>
    </tr>
    <tr>
      <td>C15—P3—C21</td>
      <td>104.21 (16)</td>
      <td>C43—C44—C39</td>
      <td>120.6 (3)</td>
    </tr>
    <tr>
      <td>C27—P3—C21</td>
      <td>102.83 (16)</td>
      <td>C43—C44—H44</td>
      <td>119.7</td>
    </tr>
    <tr>
      <td>C15—P3—Pt1</td>
      <td>114.37 (12)</td>
      <td>C39—C44—H44</td>
      <td>119.7</td>
    </tr>
  </tbody>
</table>
<table>
  <tr>
    <td>C33—C34</td>
    <td>1.367 (4)</td>
    <td></td>
    <td></td>
  </tr>
  <tr>
    <td>P2—Pt1—Fe1</td>
    <td>102.03 (3)</td>
    <td>C28—C29—H29</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>P3—Pt1—Fe1</td>
    <td>152.88 (3)</td>
    <td>C29—C30—C31</td>
    <td>119.6 (4)</td>
  </tr>
  <tr>
    <td>C1—Pt1—Fe1</td>
    <td>52.87 (10)</td>
    <td>C29—C30—H30</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>P3—Pt1—P2</td>
    <td>105.07 (3)</td>
    <td>C31—C30—H30</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C1—Pt1—P2</td>
    <td>152.26 (10)</td>
    <td>C30—C31—C32</td>
    <td>120.3 (4)</td>
  </tr>
  <tr>
    <td>C1—Pt1—P3</td>
    <td>100.38 (10)</td>
    <td>C30—C31—H31</td>
    <td>119.8</td>
  </tr>
  <tr>
    <td>Pt1—C1—Fe1</td>
    <td>77.18 (12)</td>
    <td>C32—C31—H31</td>
    <td>119.8</td>
  </tr>
  <tr>
    <td>C13—Fe1—C14</td>
    <td>96.51 (17)</td>
    <td>C27—C32—C31</td>
    <td>119.7 (4)</td>
  </tr>
  <tr>
    <td>C13—Fe1—C12</td>
    <td>96.59 (16)</td>
    <td>C27—C32—H32</td>
    <td>120.1</td>
  </tr>
  <tr>
    <td>C14—Fe1—C12</td>
    <td>155.50 (17)</td>
    <td>C31—C32—H32</td>
    <td>120.1</td>
  </tr>
  <tr>
    <td>C13—Fe1—C1</td>
    <td>125.43 (16)</td>
    <td>C34—C33—C38</td>
    <td>118.6 (3)</td>
  </tr>
  <tr>
    <td>C14—Fe1—C1</td>
    <td>84.72 (15)</td>
    <td>C34—C33—P2</td>
    <td>118.5 (3)</td>
  </tr>
  <tr>
    <td>C12—Fe1—C1</td>
    <td>70.81 (14)</td>
    <td>C38—C33—P2</td>
    <td>122.9 (3)</td>
  </tr>
  <tr>
    <td>C13—Fe1—C2</td>
    <td>97.50 (15)</td>
    <td>C33—C34—C35</td>
    <td>120.8 (3)</td>
  </tr>
  <tr>
    <td>C14—Fe1—C2</td>
    <td>115.51 (16)</td>
    <td>C33—C34—H34</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C12—Fe1—C2</td>
    <td>42.03 (13)</td>
    <td>C35—C34—H34</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C1—Fe1—C2</td>
    <td>38.38 (12)</td>
    <td>C36—C35—C34</td>
    <td>119.6 (4)</td>
  </tr>
  <tr>
    <td>C13—Fe1—P1</td>
    <td>95.17 (13)</td>
    <td>C36—C35—H35</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C14—Fe1—P1</td>
    <td>104.63 (12)</td>
    <td>C34—C35—H35</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C12—Fe1—P1</td>
    <td>94.69 (11)</td>
    <td>C37—C36—C35</td>
    <td>119.8 (4)</td>
  </tr>
  <tr>
    <td>C1—Fe1—P1</td>
    <td>137.46 (10)</td>
    <td>C37—C36—H36</td>
    <td>120.1</td>
  </tr>
  <tr>
    <td>C2—Fe1—P1</td>
    <td>135.94 (10)</td>
    <td>C35—C36—H36</td>
    <td>120.1</td>
  </tr>
  <tr>
    <td>C13—Fe1—Pt1</td>
    <td>170.69 (12)</td>
    <td>C38—C37—C36</td>
    <td>119.8 (4)</td>
  </tr>
  <tr>
    <td>C14—Fe1—Pt1</td>
    <td>91.16 (13)</td>
    <td>C38—C37—H37</td>
    <td>120.1</td>
  </tr>
  <tr>
    <td>C12—Fe1—Pt1</td>
    <td>74.38 (10)</td>
    <td>C36—C37—H37</td>
    <td>120.1</td>
  </tr>
  <tr>
    <td>C1—Fe1—Pt1</td>
    <td>49.95 (9)</td>
    <td>C37—C38—C33</td>
    <td>121.3 (3)</td>
  </tr>
  <tr>
    <td>C2—Fe1—Pt1</td>
    <td>74.35 (9)</td>
    <td>C37—C38—H38</td>
    <td>119.3</td>
  </tr>
  <tr>
    <td>P1—Fe1—Pt1</td>
    <td>87.95 (3)</td>
    <td>C33—C38—H38</td>
    <td>119.3</td>
  </tr>
  <tr>
    <td>C2—C1—Pt1</td>
    <td>112.5 (3)</td>
    <td>C40—C39—C44</td>
    <td>118.2 (3)</td>
  </tr>
  <tr>
    <td>C2—C1—Fe1</td>
    <td>70.9 (2)</td>
    <td>C40—C39—P2</td>
    <td>123.3 (3)</td>
  </tr>
  <tr>
    <td>C46—P1—C45</td>
    <td>102.47 (15)</td>
    <td>C44—C39—P2</td>
    <td>118.2 (3)</td>
  </tr>
  <tr>
    <td>C46—P1—C52</td>
    <td>101.87 (16)</td>
    <td>C41—C40—C39</td>
    <td>120.9 (3)</td>
  </tr>
  <tr>
    <td>C45—P1—C52</td>
    <td>100.39 (15)</td>
    <td>C41—C40—H40</td>
    <td>119.5</td>
  </tr>
  <tr>
    <td>C46—P1—Fe1</td>
    <td>114.02 (11)</td>
    <td>C39—C40—H40</td>
    <td>119.5</td>
  </tr>
  <tr>
    <td>C45—P1—Fe1</td>
    <td>114.40 (11)</td>
    <td>C42—C41—C40</td>
    <td>120.2 (4)</td>
  </tr>
  <tr>
    <td>C52—P1—Fe1</td>
    <td>121.13 (12)</td>
    <td>C42—C41—H41</td>
    <td>119.9</td>
  </tr>
  <tr>
    <td>C33—P2—C39</td>
    <td>103.75 (16)</td>
    <td>C40—C41—H41</td>
    <td>119.9</td>
  </tr>
  <tr>
    <td>C33—P2—C45</td>
    <td>107.90 (16)</td>
    <td>C41—C42—C43</td>
    <td>119.5 (3)</td>
  </tr>
  <tr>
    <td>C39—P2—C45</td>
    <td>102.34 (15)</td>
    <td>C41—C42—H42</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C33—P2—Pt1</td>
    <td>122.98 (12)</td>
    <td>C43—C42—H42</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C39—P2—Pt1</td>
    <td>114.88 (11)</td>
    <td>C44—C43—C42</td>
    <td>120.5 (3)</td>
  </tr>
  <tr>
    <td>C45—P2—Pt1</td>
    <td>103.02 (11)</td>
    <td>C44—C43—H43</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C15—P3—C27</td>
    <td>105.92 (16)</td>
    <td>C42—C43—H43</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C15—P3—C21</td>
    <td>104.21 (16)</td>
    <td>C43—C44—C39</td>
    <td>120.6 (3)</td>
  </tr>
  <tr>
    <td>C27—P3—C21</td>
    <td>102.83 (16)</td>
    <td>C43—C44—H44</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C15—P3—Pt1</td>
    <td>114.37 (12)</td>
    <td>C39—C44—H44</td>
    <td>119.7</td>
  </tr>
</table>
<table>
  <tr>
    <td>C27—P3—Pt1</td>
    <td>109.93 (12)</td>
  </tr>
  <tr>
    <td>C21—P3—Pt1</td>
    <td>118.32 (11)</td>
  </tr>
  <tr>
    <td>C2—C1—H1</td>
    <td>123.6</td>
  </tr>
  <tr>
    <td>Pt1—C1—H1</td>
    <td>123.7</td>
  </tr>
  <tr>
    <td>Fe1—C1—H1</td>
    <td>123.7</td>
  </tr>
  <tr>
    <td>C1—C2—C12</td>
    <td>111.0 (3)</td>
  </tr>
  <tr>
    <td>C1—C2—C3</td>
    <td>123.7 (3)</td>
  </tr>
  <tr>
    <td>C12—C2—C3</td>
    <td>124.6 (3)</td>
  </tr>
  <tr>
    <td>C1—C2—Fe1</td>
    <td>70.8 (2)</td>
  </tr>
  <tr>
    <td>C12—C2—Fe1</td>
    <td>62.4 (2)</td>
  </tr>
  <tr>
    <td>C3—C2—Fe1</td>
    <td>126.7 (2)</td>
  </tr>
  <tr>
    <td>C4—C3—C10</td>
    <td>118.5 (3)</td>
  </tr>
  <tr>
    <td>C4—C3—C2</td>
    <td>120.0 (3)</td>
  </tr>
  <tr>
    <td>C10—C3—C2</td>
    <td>121.4 (3)</td>
  </tr>
  <tr>
    <td>C5—C4—C3</td>
    <td>123.6 (3)</td>
  </tr>
  <tr>
    <td>C5—C4—H4</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C3—C4—H4</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C4—C5—C7</td>
    <td>118.1 (4)</td>
  </tr>
  <tr>
    <td>C4—C5—C6</td>
    <td>121.5 (3)</td>
  </tr>
  <tr>
    <td>C7—C5—C6</td>
    <td>120.4 (3)</td>
  </tr>
  <tr>
    <td>C5—C6—H6A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C5—C6—H6B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H6A—C6—H6B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C5—C6—H6C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H6A—C6—H6C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H6B—C6—H6C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C5—C7—C9</td>
    <td>118.3 (4)</td>
  </tr>
  <tr>
    <td>C5—C7—C8</td>
    <td>121.8 (4)</td>
  </tr>
  <tr>
    <td>C9—C7—C8</td>
    <td>120.0 (4)</td>
  </tr>
  <tr>
    <td>C7—C8—H8A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C7—C8—H8B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H8A—C8—H8B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C7—C8—H8C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H8A—C8—H8C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H8B—C8—H8C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C10—C9—C7</td>
    <td>123.6 (4)</td>
  </tr>
  <tr>
    <td>C10—C9—H9</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C7—C9—H9</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C9—C10—C3</td>
    <td>117.8 (3)</td>
  </tr>
  <tr>
    <td>C9—C10—C11</td>
    <td>120.0 (3)</td>
  </tr>
  <tr>
    <td>C3—C10—C11</td>
    <td>122.1 (3)</td>
  </tr>
  <tr>
    <td>C10—C11—H11A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C10—C11—H11B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H11A—C11—H11B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C10—C11—H11C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H11A—C11—H11C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H11B—C11—H11C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>O1—C12—C2</td>
    <td>138.3 (3)</td>
  </tr>
</table>

<table>
  <tr>
    <td>P1—C45—P2</td>
    <td>108.83 (17)</td>
  </tr>
  <tr>
    <td>P1—C45—H45A</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>P2—C45—H45A</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>P1—C45—H43B</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>P2—C45—H43B</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>H45A—C45—H43B</td>
    <td>108.3</td>
  </tr>
  <tr>
    <td>C47—C46—C51</td>
    <td>117.1 (3)</td>
  </tr>
  <tr>
    <td>C47—C46—P1</td>
    <td>122.0 (3)</td>
  </tr>
  <tr>
    <td>C51—C46—P1</td>
    <td>120.8 (3)</td>
  </tr>
  <tr>
    <td>C46—C47—C48</td>
    <td>121.2 (4)</td>
  </tr>
  <tr>
    <td>C46—C47—H47</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C48—C47—H47</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C49—C48—C47</td>
    <td>120.4 (4)</td>
  </tr>
  <tr>
    <td>C49—C48—H48</td>
    <td>119.8</td>
  </tr>
  <tr>
    <td>C47—C48—H48</td>
    <td>119.8</td>
  </tr>
  <tr>
    <td>C48—C49—C50</td>
    <td>119.5 (4)</td>
  </tr>
  <tr>
    <td>C48—C49—H49</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C50—C49—H49</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C49—C50—C51</td>
    <td>119.6 (4)</td>
  </tr>
  <tr>
    <td>C49—C50—H50</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C51—C50—H50</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C46—C51—C50</td>
    <td>122.2 (3)</td>
  </tr>
  <tr>
    <td>C46—C51—H51</td>
    <td>118.9</td>
  </tr>
  <tr>
    <td>C50—C51—H51</td>
    <td>118.9</td>
  </tr>
  <tr>
    <td>C53—C52—C57</td>
    <td>118.0 (3)</td>
  </tr>
  <tr>
    <td>C53—C52—P1</td>
    <td>121.1 (3)</td>
  </tr>
  <tr>
    <td>C57—C52—P1</td>
    <td>120.7 (3)</td>
  </tr>
  <tr>
    <td>C52—C53—C54</td>
    <td>120.6 (4)</td>
  </tr>
  <tr>
    <td>C52—C53—H53</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C54—C53—H53</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C55—C54—C53</td>
    <td>120.8 (4)</td>
  </tr>
  <tr>
    <td>C55—C54—H54</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C53—C54—H54</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C54—C55—C56</td>
    <td>119.3 (4)</td>
  </tr>
  <tr>
    <td>C54—C55—H55</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C56—C55—H55</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C55—C56—C57</td>
    <td>120.3 (4)</td>
  </tr>
  <tr>
    <td>C55—C56—H56</td>
    <td>119.9</td>
  </tr>
  <tr>
    <td>C57—C56—H56</td>
    <td>119.9</td>
  </tr>
  <tr>
    <td>C56—C57—C52</td>
    <td>120.9 (4)</td>
  </tr>
  <tr>
    <td>C56—C57—H57</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C52—C57—H57</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C59—C58—H58A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C59—C58—H58B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H58A—C58—H58B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C59—C58—H58C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H58A—C58—H58C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H58B—C58—H58C</td>
    <td>109.5</td>
  </tr>
</table>
<table>
  <tr>
    <td>C27—P3—Pt1</td>
    <td>109.93 (12)</td>
  </tr>
  <tr>
    <td>C21—P3—Pt1</td>
    <td>118.32 (11)</td>
  </tr>
  <tr>
    <td>C2—C1—H1</td>
    <td>123.6</td>
  </tr>
  <tr>
    <td>Pt1—C1—H1</td>
    <td>123.7</td>
  </tr>
  <tr>
    <td>Fe1—C1—H1</td>
    <td>123.7</td>
  </tr>
  <tr>
    <td>C1—C2—C12</td>
    <td>111.0 (3)</td>
  </tr>
  <tr>
    <td>C1—C2—C3</td>
    <td>123.7 (3)</td>
  </tr>
  <tr>
    <td>C12—C2—C3</td>
    <td>124.6 (3)</td>
  </tr>
  <tr>
    <td>C1—C2—Fe1</td>
    <td>70.8 (2)</td>
  </tr>
  <tr>
    <td>C12—C2—Fe1</td>
    <td>62.4 (2)</td>
  </tr>
  <tr>
    <td>C3—C2—Fe1</td>
    <td>126.7 (2)</td>
  </tr>
  <tr>
    <td>C4—C3—C10</td>
    <td>118.5 (3)</td>
  </tr>
  <tr>
    <td>C4—C3—C2</td>
    <td>120.0 (3)</td>
  </tr>
  <tr>
    <td>C10—C3—C2</td>
    <td>121.4 (3)</td>
  </tr>
  <tr>
    <td>C5—C4—C3</td>
    <td>123.6 (3)</td>
  </tr>
  <tr>
    <td>C5—C4—H4</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C3—C4—H4</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C4—C5—C7</td>
    <td>118.1 (4)</td>
  </tr>
  <tr>
    <td>C4—C5—C6</td>
    <td>121.5 (3)</td>
  </tr>
  <tr>
    <td>C7—C5—C6</td>
    <td>120.4 (3)</td>
  </tr>
  <tr>
    <td>C5—C6—H6A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C5—C6—H6B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H6A—C6—H6B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C5—C6—H6C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H6A—C6—H6C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H6B—C6—H6C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C5—C7—C9</td>
    <td>118.3 (4)</td>
  </tr>
  <tr>
    <td>C5—C7—C8</td>
    <td>121.8 (4)</td>
  </tr>
  <tr>
    <td>C9—C7—C8</td>
    <td>120.0 (4)</td>
  </tr>
  <tr>
    <td>C7—C8—H8A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C7—C8—H8B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H8A—C8—H8B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C7—C8—H8C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H8A—C8—H8C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H8B—C8—H8C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C10—C9—C7</td>
    <td>123.6 (4)</td>
  </tr>
  <tr>
    <td>C10—C9—H9</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C7—C9—H9</td>
    <td>118.2</td>
  </tr>
  <tr>
    <td>C9—C10—C3</td>
    <td>117.8 (3)</td>
  </tr>
  <tr>
    <td>C9—C10—C11</td>
    <td>120.0 (3)</td>
  </tr>
  <tr>
    <td>C3—C10—C11</td>
    <td>122.1 (3)</td>
  </tr>
  <tr>
    <td>C10—C11—H11A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C10—C11—H11B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H11A—C11—H11B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C10—C11—H11C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H11A—C11—H11C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H11B—C11—H11C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>O1—C12—C2</td>
    <td>138.3 (3)</td>
  </tr>
</table>

<table>
  <tr>
    <td>P1—C45—P2</td>
    <td>108.83 (17)</td>
  </tr>
  <tr>
    <td>P1—C45—H45A</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>P2—C45—H45A</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>P1—C45—H43B</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>P2—C45—H43B</td>
    <td>109.9</td>
  </tr>
  <tr>
    <td>H45A—C45—H43B</td>
    <td>108.3</td>
  </tr>
  <tr>
    <td>C47—C46—C51</td>
    <td>117.1 (3)</td>
  </tr>
  <tr>
    <td>C47—C46—P1</td>
    <td>122.0 (3)</td>
  </tr>
  <tr>
    <td>C51—C46—P1</td>
    <td>120.8 (3)</td>
  </tr>
  <tr>
    <td>C46—C47—C48</td>
    <td>121.2 (4)</td>
  </tr>
  <tr>
    <td>C46—C47—H47</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C48—C47—H47</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C49—C48—C47</td>
    <td>120.4 (4)</td>
  </tr>
  <tr>
    <td>C49—C48—H48</td>
    <td>119.8</td>
  </tr>
  <tr>
    <td>C47—C48—H48</td>
    <td>119.8</td>
  </tr>
  <tr>
    <td>C48—C49—C50</td>
    <td>119.5 (4)</td>
  </tr>
  <tr>
    <td>C48—C49—H49</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C50—C49—H49</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C49—C50—C51</td>
    <td>119.6 (4)</td>
  </tr>
  <tr>
    <td>C49—C50—H50</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C51—C50—H50</td>
    <td>120.2</td>
  </tr>
  <tr>
    <td>C46—C51—C50</td>
    <td>122.2 (3)</td>
  </tr>
  <tr>
    <td>C46—C51—H51</td>
    <td>118.9</td>
  </tr>
  <tr>
    <td>C50—C51—H51</td>
    <td>118.9</td>
  </tr>
  <tr>
    <td>C53—C52—C57</td>
    <td>118.0 (3)</td>
  </tr>
  <tr>
    <td>C53—C52—P1</td>
    <td>121.1 (3)</td>
  </tr>
  <tr>
    <td>C57—C52—P1</td>
    <td>120.7 (3)</td>
  </tr>
  <tr>
    <td>C52—C53—C54</td>
    <td>120.6 (4)</td>
  </tr>
  <tr>
    <td>C52—C53—H53</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C54—C53—H53</td>
    <td>119.7</td>
  </tr>
  <tr>
    <td>C55—C54—C53</td>
    <td>120.8 (4)</td>
  </tr>
  <tr>
    <td>C55—C54—H54</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C53—C54—H54</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C54—C55—C56</td>
    <td>119.3 (4)</td>
  </tr>
  <tr>
    <td>C54—C55—H55</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C56—C55—H55</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C55—C56—C57</td>
    <td>120.3 (4)</td>
  </tr>
  <tr>
    <td>C55—C56—H56</td>
    <td>119.9</td>
  </tr>
  <tr>
    <td>C57—C56—H56</td>
    <td>119.9</td>
  </tr>
  <tr>
    <td>C56—C57—C52</td>
    <td>120.9 (4)</td>
  </tr>
  <tr>
    <td>C56—C57—H57</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C52—C57—H57</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C59—C58—H58A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C59—C58—H58B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H58A—C58—H58B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C59—C58—H58C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H58A—C58—H58C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>H58B—C58—H58C</td>
    <td>109.5</td>
  </tr>
</table>
<table>
  <tr>
    <td>O1—C12—Fe1</td>
    <td>145.3 (3)</td>
    <td>C64—C59—C60</td>
    <td>117.4 (5)</td>
  </tr>
  <tr>
    <td>C2—C12—Fe1</td>
    <td>75.6 (2)</td>
    <td>C64—C59—C58</td>
    <td>122.4 (5)</td>
  </tr>
  <tr>
    <td>O2—C13—Fe1</td>
    <td>179.3 (4)</td>
    <td>C60—C59—C58</td>
    <td>120.2 (5)</td>
  </tr>
  <tr>
    <td>O3—C14—Fe1</td>
    <td>175.8 (4)</td>
    <td>C59—C60—C61</td>
    <td>121.2 (5)</td>
  </tr>
  <tr>
    <td>C16—C15—C20</td>
    <td>118.4 (3)</td>
    <td>C59—C60—H60</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C16—C15—P3</td>
    <td>117.6 (3)</td>
    <td>C61—C60—H60</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C20—C15—P3</td>
    <td>124.0 (3)</td>
    <td>C62—C61—C60</td>
    <td>120.7 (5)</td>
  </tr>
  <tr>
    <td>C15—C16—C17</td>
    <td>120.0 (4)</td>
    <td>C62—C61—H61</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C15—C16—H16</td>
    <td>120.0</td>
    <td>C60—C61—H61</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C17—C16—H16</td>
    <td>120.0</td>
    <td>C61—C62—C63</td>
    <td>117.8 (6)</td>
  </tr>
  <tr>
    <td>C18—C17—C16</td>
    <td>120.3 (4)</td>
    <td>C61—C62—H62</td>
    <td>121.1</td>
  </tr>
  <tr>
    <td>C18—C17—H17</td>
    <td>119.8</td>
    <td>C63—C62—H62</td>
    <td>121.1</td>
  </tr>
  <tr>
    <td>C16—C17—H17</td>
    <td>119.8</td>
    <td>C62—C63—C64</td>
    <td>121.2 (5)</td>
  </tr>
  <tr>
    <td>C17—C18—C19</td>
    <td>120.1 (4)</td>
    <td>C62—C63—H63</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C17—C18—H18</td>
    <td>120.0</td>
    <td>C64—C63—H63</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C19—C18—H18</td>
    <td>120.0</td>
    <td>C59—C64—C63</td>
    <td>121.7 (5)</td>
  </tr>
  <tr>
    <td>C20—C19—C18</td>
    <td>119.7 (4)</td>
    <td>C59—C64—H64</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C20—C19—H19</td>
    <td>120.1</td>
    <td>C63—C64—H64</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C18—C19—H19</td>
    <td>120.1</td>
    <td>C66—C65—H65A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C19—C20—C15</td>
    <td>121.5 (4)</td>
    <td>C66—C65—H65B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C19—C20—H20</td>
    <td>119.3</td>
    <td>H65A—C65—H65B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C15—C20—H20</td>
    <td>119.3</td>
    <td>C66—C65—H65C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C26—C21—C22</td>
    <td>118.3 (3)</td>
    <td>H65A—C65—H65C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C26—C21—P3</td>
    <td>121.3 (3)</td>
    <td>H65B—C65—H65C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C22—C21—P3</td>
    <td>120.0 (3)</td>
    <td>C71—C66—C67</td>
    <td>118.3 (6)</td>
  </tr>
  <tr>
    <td>C23—C22—C21</td>
    <td>120.1 (3)</td>
    <td>C71—C66—C65</td>
    <td>120.8 (6)</td>
  </tr>
  <tr>
    <td>C23—C22—H22</td>
    <td>119.9</td>
    <td>C67—C66—C65</td>
    <td>120.9 (6)</td>
  </tr>
  <tr>
    <td>C21—C22—H22</td>
    <td>119.9</td>
    <td>C68—C67—C66</td>
    <td>121.7 (7)</td>
  </tr>
  <tr>
    <td>C24—C23—C22</td>
    <td>121.0 (4)</td>
    <td>C68—C67—H67</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C24—C23—H23</td>
    <td>119.5</td>
    <td>C66—C67—H67</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C22—C23—H23</td>
    <td>119.5</td>
    <td>C69—C68—C67</td>
    <td>117.0 (7)</td>
  </tr>
  <tr>
    <td>C23—C24—C25</td>
    <td>119.5 (4)</td>
    <td>C69—C68—H68</td>
    <td>121.5</td>
  </tr>
  <tr>
    <td>C23—C24—H24</td>
    <td>120.2</td>
    <td>C67—C68—H68</td>
    <td>121.5</td>
  </tr>
  <tr>
    <td>C25—C24—H24</td>
    <td>120.2</td>
    <td>C68—C69—C70</td>
    <td>122.0 (7)</td>
  </tr>
  <tr>
    <td>C24—C25—C26</td>
    <td>120.6 (4)</td>
    <td>C68—C69—H69</td>
    <td>119.0</td>
  </tr>
  <tr>
    <td>C24—C25—H25</td>
    <td>119.7</td>
    <td>C70—C69—H69</td>
    <td>119.0</td>
  </tr>
  <tr>
    <td>C26—C25—H25</td>
    <td>119.7</td>
    <td>C71—C70—C69</td>
    <td>119.4 (6)</td>
  </tr>
  <tr>
    <td>C25—C26—C21</td>
    <td>120.4 (4)</td>
    <td>C71—C70—H70</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C25—C26—H26</td>
    <td>119.8</td>
    <td>C69—C70—H70</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C21—C26—H26</td>
    <td>119.8</td>
    <td>C70—C71—C66</td>
    <td>121.6 (6)</td>
  </tr>
  <tr>
    <td>C28—C27—C32</td>
    <td>119.3 (4)</td>
    <td>C70—C71—H71</td>
    <td>119.2</td>
  </tr>
  <tr>
    <td>C28—C27—P3</td>
    <td>122.2 (3)</td>
    <td>C66—C71—H71</td>
    <td>119.2</td>
  </tr>
  <tr>
    <td>C32—C27—P3</td>
    <td>118.5 (3)</td>
    <td>Cl1—C72—Cl2</td>
    <td>110.8 (3)</td>
  </tr>
  <tr>
    <td>C29—C28—C27</td>
    <td>119.9 (4)</td>
    <td>Cl1—C72—H72A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C29—C28—H28</td>
    <td>120.0</td>
    <td>Cl2—C72—H72A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C27—C28—H28</td>
    <td>120.0</td>
    <td>Cl1—C72—H72B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C30—C29—C28</td>
    <td>121.2 (5)</td>
    <td>Cl2—C72—H72B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C30—C29—H29</td>
    <td>119.4</td>
    <td>H72A—C72—H72B</td>
    <td>108.1</td>
  </tr>
</table>
<table>
  <tr>
    <td>O1—C12—Fe1</td>
    <td>145.3 (3)</td>
    <td>C64—C59—C60</td>
    <td>117.4 (5)</td>
  </tr>
  <tr>
    <td>C2—C12—Fe1</td>
    <td>75.6 (2)</td>
    <td>C64—C59—C58</td>
    <td>122.4 (5)</td>
  </tr>
  <tr>
    <td>O2—C13—Fe1</td>
    <td>179.3 (4)</td>
    <td>C60—C59—C58</td>
    <td>120.2 (5)</td>
  </tr>
  <tr>
    <td>O3—C14—Fe1</td>
    <td>175.8 (4)</td>
    <td>C59—C60—C61</td>
    <td>121.2 (5)</td>
  </tr>
  <tr>
    <td>C16—C15—C20</td>
    <td>118.4 (3)</td>
    <td>C59—C60—H60</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C16—C15—P3</td>
    <td>117.6 (3)</td>
    <td>C61—C60—H60</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C20—C15—P3</td>
    <td>124.0 (3)</td>
    <td>C62—C61—C60</td>
    <td>120.7 (5)</td>
  </tr>
  <tr>
    <td>C15—C16—C17</td>
    <td>120.0 (4)</td>
    <td>C62—C61—H61</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C15—C16—H16</td>
    <td>120.0</td>
    <td>C60—C61—H61</td>
    <td>119.6</td>
  </tr>
  <tr>
    <td>C17—C16—H16</td>
    <td>120.0</td>
    <td>C61—C62—C63</td>
    <td>117.8 (6)</td>
  </tr>
  <tr>
    <td>C18—C17—C16</td>
    <td>120.3 (4)</td>
    <td>C61—C62—H62</td>
    <td>121.1</td>
  </tr>
  <tr>
    <td>C18—C17—H17</td>
    <td>119.8</td>
    <td>C63—C62—H62</td>
    <td>121.1</td>
  </tr>
  <tr>
    <td>C16—C17—H17</td>
    <td>119.8</td>
    <td>C62—C63—C64</td>
    <td>121.2 (5)</td>
  </tr>
  <tr>
    <td>C17—C18—C19</td>
    <td>120.1 (4)</td>
    <td>C62—C63—H63</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C17—C18—H18</td>
    <td>120.0</td>
    <td>C64—C63—H63</td>
    <td>119.4</td>
  </tr>
  <tr>
    <td>C19—C18—H18</td>
    <td>120.0</td>
    <td>C59—C64—C63</td>
    <td>121.7 (5)</td>
  </tr>
  <tr>
    <td>C20—C19—C18</td>
    <td>119.7 (4)</td>
    <td>C59—C64—H64</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C20—C19—H19</td>
    <td>120.1</td>
    <td>C63—C64—H64</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C18—C19—H19</td>
    <td>120.1</td>
    <td>C66—C65—H65A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C19—C20—C15</td>
    <td>121.5 (4)</td>
    <td>C66—C65—H65B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C19—C20—H20</td>
    <td>119.3</td>
    <td>H65A—C65—H65B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C15—C20—H20</td>
    <td>119.3</td>
    <td>C66—C65—H65C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C26—C21—C22</td>
    <td>118.3 (3)</td>
    <td>H65A—C65—H65C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C26—C21—P3</td>
    <td>121.3 (3)</td>
    <td>H65B—C65—H65C</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C22—C21—P3</td>
    <td>120.0 (3)</td>
    <td>C71—C66—C67</td>
    <td>118.3 (6)</td>
  </tr>
  <tr>
    <td>C23—C22—C21</td>
    <td>120.1 (3)</td>
    <td>C71—C66—C65</td>
    <td>120.8 (6)</td>
  </tr>
  <tr>
    <td>C23—C22—H22</td>
    <td>119.9</td>
    <td>C67—C66—C65</td>
    <td>120.9 (6)</td>
  </tr>
  <tr>
    <td>C21—C22—H22</td>
    <td>119.9</td>
    <td>C68—C67—C66</td>
    <td>121.7 (7)</td>
  </tr>
  <tr>
    <td>C24—C23—C22</td>
    <td>121.0 (4)</td>
    <td>C68—C67—H67</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C24—C23—H23</td>
    <td>119.5</td>
    <td>C66—C67—H67</td>
    <td>119.1</td>
  </tr>
  <tr>
    <td>C22—C23—H23</td>
    <td>119.5</td>
    <td>C69—C68—C67</td>
    <td>117.0 (7)</td>
  </tr>
  <tr>
    <td>C23—C24—C25</td>
    <td>119.5 (4)</td>
    <td>C69—C68—H68</td>
    <td>121.5</td>
  </tr>
  <tr>
    <td>C23—C24—H24</td>
    <td>120.2</td>
    <td>C67—C68—H68</td>
    <td>121.5</td>
  </tr>
  <tr>
    <td>C25—C24—H24</td>
    <td>120.2</td>
    <td>C68—C69—C70</td>
    <td>122.0 (7)</td>
  </tr>
  <tr>
    <td>C24—C25—C26</td>
    <td>120.6 (4)</td>
    <td>C68—C69—H69</td>
    <td>119.0</td>
  </tr>
  <tr>
    <td>C24—C25—H25</td>
    <td>119.7</td>
    <td>C70—C69—H69</td>
    <td>119.0</td>
  </tr>
  <tr>
    <td>C26—C25—H25</td>
    <td>119.7</td>
    <td>C71—C70—C69</td>
    <td>119.4 (6)</td>
  </tr>
  <tr>
    <td>C25—C26—C21</td>
    <td>120.4 (4)</td>
    <td>C71—C70—H70</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C25—C26—H26</td>
    <td>119.8</td>
    <td>C69—C70—H70</td>
    <td>120.3</td>
  </tr>
  <tr>
    <td>C21—C26—H26</td>
    <td>119.8</td>
    <td>C70—C71—C66</td>
    <td>121.6 (6)</td>
  </tr>
  <tr>
    <td>C28—C27—C32</td>
    <td>119.3 (4)</td>
    <td>C70—C71—H71</td>
    <td>119.2</td>
  </tr>
  <tr>
    <td>C28—C27—P3</td>
    <td>122.2 (3)</td>
    <td>C66—C71—H71</td>
    <td>119.2</td>
  </tr>
  <tr>
    <td>C32—C27—P3</td>
    <td>118.5 (3)</td>
    <td>Cl1—C72—Cl2</td>
    <td>110.8 (3)</td>
  </tr>
  <tr>
    <td>C29—C28—C27</td>
    <td>119.9 (4)</td>
    <td>Cl1—C72—H72A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C29—C28—H28</td>
    <td>120.0</td>
    <td>Cl2—C72—H72A</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C27—C28—H28</td>
    <td>120.0</td>
    <td>Cl1—C72—H72B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C30—C29—C28</td>
    <td>121.2 (5)</td>
    <td>Cl2—C72—H72B</td>
    <td>109.5</td>
  </tr>
  <tr>
    <td>C30—C29—H29</td>
    <td>119.4</td>
    <td>H72A—C72—H72B</td>
    <td>108.1</td>
  </tr>
</table>
<table>
  <tr>
    <td>Pt1—C1—C2—C12</td>
    <td>-17.8 (4)</td>
  </tr>
  <tr>
    <td>Fe1—C1—C2—C12</td>
    <td>48.8 (3)</td>
  </tr>
  <tr>
    <td>Pt1—C1—C2—C3</td>
    <td>171.6 (3)</td>
  </tr>
  <tr>
    <td>Fe1—C1—C2—C3</td>
    <td>-121.8 (3)</td>
  </tr>
  <tr>
    <td>Pt1—C1—C2—Fe1</td>
    <td>-66.57 (17)</td>
  </tr>
  <tr>
    <td>C1—C2—C3—C4</td>
    <td>50.4 (5)</td>
  </tr>
  <tr>
    <td>C12—C2—C3—C4</td>
    <td>-118.9 (4)</td>
  </tr>
  <tr>
    <td>Fe1—C2—C3—C4</td>
    <td>-39.8 (5)</td>
  </tr>
  <tr>
    <td>C1—C2—C3—C10</td>
    <td>-126.4 (4)</td>
  </tr>
  <tr>
    <td>C12—C2—C3—C10</td>
    <td>64.3 (5)</td>
  </tr>
  <tr>
    <td>Fe1—C2—C3—C10</td>
    <td>143.4 (3)</td>
  </tr>
  <tr>
    <td>C10—C3—C4—C5</td>
    <td>0.9 (6)</td>
  </tr>
  <tr>
    <td>C2—C3—C4—C5</td>
    <td>-176.0 (4)</td>
  </tr>
  <tr>
    <td>C3—C4—C5—C7</td>
    <td>-0.8 (6)</td>
  </tr>
  <tr>
    <td>C3—C4—C5—C6</td>
    <td>179.5 (4)</td>
  </tr>
  <tr>
    <td>C4—C5—C7—C9</td>
    <td>0.0 (6)</td>
  </tr>
  <tr>
    <td>C6—C5—C7—C9</td>
    <td>179.7 (4)</td>
  </tr>
  <tr>
    <td>C4—C5—C7—C8</td>
    <td>-179.3 (4)</td>
  </tr>
  <tr>
    <td>C6—C5—C7—C8</td>
    <td>0.4 (6)</td>
  </tr>
  <tr>
    <td>C5—C7—C9—C10</td>
    <td>0.7 (6)</td>
  </tr>
  <tr>
    <td>C8—C7—C9—C10</td>
    <td>-180.0 (4)</td>
  </tr>
  <tr>
    <td>C7—C9—C10—C3</td>
    <td>-0.6 (6)</td>
  </tr>
  <tr>
    <td>C7—C9—C10—C11</td>
    <td>175.8 (4)</td>
  </tr>
  <tr>
    <td>C4—C3—C10—C9</td>
    <td>-0.2 (5)</td>
  </tr>
  <tr>
    <td>C2—C3—C10—C9</td>
    <td>176.7 (3)</td>
  </tr>
  <tr>
    <td>C4—C3—C10—C11</td>
    <td>-176.5 (4)</td>
  </tr>
  <tr>
    <td>C2—C3—C10—C11</td>
    <td>0.4 (6)</td>
  </tr>
  <tr>
    <td>C1—C2—C12—O1</td>
    <td>135.7 (5)</td>
  </tr>
  <tr>
    <td>C3—C2—C12—O1</td>
    <td>-53.8 (7)</td>
  </tr>
  <tr>
    <td>Fe1—C2—C12—O1</td>
    <td>-171.1 (5)</td>
  </tr>
  <tr>
    <td>C1—C2—C12—Fe1</td>
    <td>-53.2 (3)</td>
  </tr>
  <tr>
    <td>C3—C2—C12—Fe1</td>
    <td>117.2 (3)</td>
  </tr>
  <tr>
    <td>C27—P3—C15—C16</td>
    <td>96.0 (3)</td>
  </tr>
  <tr>
    <td>C21—P3—C15—C16</td>
    <td>-155.9 (3)</td>
  </tr>
  <tr>
    <td>Pt1—P3—C15—C16</td>
    <td>-25.2 (3)</td>
  </tr>
  <tr>
    <td>C27—P3—C15—C20</td>
    <td>-83.6 (3)</td>
  </tr>
  <tr>
    <td>C21—P3—C15—C20</td>
    <td>24.5 (4)</td>
  </tr>
  <tr>
    <td>Pt1—P3—C15—C20</td>
    <td>155.2 (3)</td>
  </tr>
  <tr>
    <td>C20—C15—C16—C17</td>
    <td>0.5 (5)</td>
  </tr>
  <tr>
    <td>P3—C15—C16—C17</td>
    <td>-179.1 (3)</td>
  </tr>
  <tr>
    <td>C15—C16—C17—C18</td>
    <td>-0.8 (6)</td>
  </tr>
  <tr>
    <td>C16—C17—C18—C19</td>
    <td>-0.4 (6)</td>
  </tr>
  <tr>
    <td>C17—C18—C19—C20</td>
    <td>1.8 (6)</td>
  </tr>
  <tr>
    <td>C18—C19—C20—C15</td>
    <td>-2.1 (6)</td>
  </tr>
  <tr>
    <td>C16—C15—C20—C19</td>
    <td>0.9 (6)</td>
  </tr>
  <tr>
    <td>P3—C15—C20—C19</td>
    <td>-179.4 (3)</td>
  </tr>
  <tr>
    <td>C15—P3—C21—C26</td>
    <td>-136.5 (3)</td>
  </tr>
</table>

<table>
  <tr>
    <td>Pt1—P2—C33—C34</td>
    <td>25.8 (3)</td>
  </tr>
  <tr>
    <td>C39—P2—C33—C38</td>
    <td>71.6 (3)</td>
  </tr>
  <tr>
    <td>C45—P2—C33—C38</td>
    <td>-36.5 (3)</td>
  </tr>
  <tr>
    <td>Pt1—P2—C33—C38</td>
    <td>-156.0 (3)</td>
  </tr>
  <tr>
    <td>C38—C33—C34—C35</td>
    <td>-0.9 (5)</td>
  </tr>
  <tr>
    <td>P2—C33—C34—C35</td>
    <td>177.4 (3)</td>
  </tr>
  <tr>
    <td>C33—C34—C35—C36</td>
    <td>0.9 (6)</td>
  </tr>
  <tr>
    <td>C34—C35—C36—C37</td>
    <td>-0.8 (6)</td>
  </tr>
  <tr>
    <td>C35—C36—C37—C38</td>
    <td>0.8 (6)</td>
  </tr>
  <tr>
    <td>C36—C37—C38—C33</td>
    <td>-0.9 (6)</td>
  </tr>
  <tr>
    <td>C34—C33—C38—C37</td>
    <td>1.0 (5)</td>
  </tr>
  <tr>
    <td>P2—C33—C38—C37</td>
    <td>-177.3 (3)</td>
  </tr>
  <tr>
    <td>C33—P2—C39—C40</td>
    <td>3.1 (3)</td>
  </tr>
  <tr>
    <td>C45—P2—C39—C40</td>
    <td>115.3 (3)</td>
  </tr>
  <tr>
    <td>Pt1—P2—C39—C40</td>
    <td>-133.9 (3)</td>
  </tr>
  <tr>
    <td>C33—P2—C39—C44</td>
    <td>177.3 (3)</td>
  </tr>
  <tr>
    <td>C45—P2—C39—C44</td>
    <td>-70.5 (3)</td>
  </tr>
  <tr>
    <td>Pt1—P2—C39—C44</td>
    <td>40.3 (3)</td>
  </tr>
  <tr>
    <td>C44—C39—C40—C41</td>
    <td>0.0 (6)</td>
  </tr>
  <tr>
    <td>P2—C39—C40—C41</td>
    <td>174.2 (3)</td>
  </tr>
  <tr>
    <td>C39—C40—C41—C42</td>
    <td>0.1 (6)</td>
  </tr>
  <tr>
    <td>C40—C41—C42—C43</td>
    <td>0.1 (6)</td>
  </tr>
  <tr>
    <td>C41—C42—C43—C44</td>
    <td>-0.5 (6)</td>
  </tr>
  <tr>
    <td>C42—C43—C44—C39</td>
    <td>0.6 (6)</td>
  </tr>
  <tr>
    <td>C40—C39—C44—C43</td>
    <td>-0.4 (5)</td>
  </tr>
  <tr>
    <td>P2—C39—C44—C43</td>
    <td>-174.9 (3)</td>
  </tr>
  <tr>
    <td>C46—P1—C45—P2</td>
    <td>179.53 (17)</td>
  </tr>
  <tr>
    <td>C52—P1—C45—P2</td>
    <td>74.8 (2)</td>
  </tr>
  <tr>
    <td>Fe1—P1—C45—P2</td>
    <td>-56.55 (18)</td>
  </tr>
  <tr>
    <td>C33—P2—C45—P1</td>
    <td>-87.49 (19)</td>
  </tr>
  <tr>
    <td>C39—P2—C45—P1</td>
    <td>163.46 (17)</td>
  </tr>
  <tr>
    <td>Pt1—P2—C45—P1</td>
    <td>43.94 (17)</td>
  </tr>
  <tr>
    <td>C45—P1—C46—C47</td>
    <td>38.0 (3)</td>
  </tr>
  <tr>
    <td>C52—P1—C46—C47</td>
    <td>141.6 (3)</td>
  </tr>
  <tr>
    <td>Fe1—P1—C46—C47</td>
    <td>-86.2 (3)</td>
  </tr>
  <tr>
    <td>C45—P1—C46—C51</td>
    <td>-146.9 (3)</td>
  </tr>
  <tr>
    <td>C52—P1—C46—C51</td>
    <td>-43.3 (3)</td>
  </tr>
  <tr>
    <td>Fe1—P1—C46—C51</td>
    <td>88.9 (3)</td>
  </tr>
  <tr>
    <td>C51—C46—C47—C48</td>
    <td>1.7 (6)</td>
  </tr>
  <tr>
    <td>P1—C46—C47—C48</td>
    <td>176.9 (3)</td>
  </tr>
  <tr>
    <td>C46—C47—C48—C49</td>
    <td>-0.2 (7)</td>
  </tr>
  <tr>
    <td>C47—C48—C49—C50</td>
    <td>-0.8 (7)</td>
  </tr>
  <tr>
    <td>C48—C49—C50—C51</td>
    <td>0.3 (6)</td>
  </tr>
  <tr>
    <td>C47—C46—C51—C50</td>
    <td>-2.2 (6)</td>
  </tr>
  <tr>
    <td>P1—C46—C51—C50</td>
    <td>-177.5 (3)</td>
  </tr>
  <tr>
    <td>C49—C50—C51—C46</td>
    <td>1.2 (6)</td>
  </tr>
  <tr>
    <td>C46—P1—C52—C53</td>
    <td>150.9 (3)</td>
  </tr>
</table>
<table>
  <tbody>
    <tr>
      <td>Pt1—C1—C2—C12</td>
      <td>-17.8 (4)</td>
    </tr>
    <tr>
      <td>Fe1—C1—C2—C12</td>
      <td>48.8 (3)</td>
    </tr>
    <tr>
      <td>Pt1—C1—C2—C3</td>
      <td>171.6 (3)</td>
    </tr>
    <tr>
      <td>Fe1—C1—C2—C3</td>
      <td>-121.8 (3)</td>
    </tr>
    <tr>
      <td>Pt1—C1—C2—Fe1</td>
      <td>-66.57 (17)</td>
    </tr>
    <tr>
      <td>C1—C2—C3—C4</td>
      <td>50.4 (5)</td>
    </tr>
    <tr>
      <td>C12—C2—C3—C4</td>
      <td>-118.9 (4)</td>
    </tr>
    <tr>
      <td>Fe1—C2—C3—C4</td>
      <td>-39.8 (5)</td>
    </tr>
    <tr>
      <td>C1—C2—C3—C10</td>
      <td>-126.4 (4)</td>
    </tr>
    <tr>
      <td>C12—C2—C3—C10</td>
      <td>64.3 (5)</td>
    </tr>
    <tr>
      <td>Fe1—C2—C3—C10</td>
      <td>143.4 (3)</td>
    </tr>
    <tr>
      <td>C10—C3—C4—C5</td>
      <td>0.9 (6)</td>
    </tr>
    <tr>
      <td>C2—C3—C4—C5</td>
      <td>-176.0 (4)</td>
    </tr>
    <tr>
      <td>C3—C4—C5—C7</td>
      <td>-0.8 (6)</td>
    </tr>
    <tr>
      <td>C3—C4—C5—C6</td>
      <td>179.5 (4)</td>
    </tr>
    <tr>
      <td>C4—C5—C7—C9</td>
      <td>0.0 (6)</td>
    </tr>
    <tr>
      <td>C6—C5—C7—C9</td>
      <td>179.7 (4)</td>
    </tr>
    <tr>
      <td>C4—C5—C7—C8</td>
      <td>-179.3 (4)</td>
    </tr>
    <tr>
      <td>C6—C5—C7—C8</td>
      <td>0.4 (6)</td>
    </tr>
    <tr>
      <td>C5—C7—C9—C10</td>
      <td>0.7 (6)</td>
    </tr>
    <tr>
      <td>C8—C7—C9—C10</td>
      <td>-180.0 (4)</td>
    </tr>
    <tr>
      <td>C7—C9—C10—C3</td>
      <td>-0.6 (6)</td>
    </tr>
    <tr>
      <td>C7—C9—C10—C11</td>
      <td>175.8 (4)</td>
    </tr>
    <tr>
      <td>C4—C3—C10—C9</td>
      <td>-0.2 (5)</td>
    </tr>
    <tr>
      <td>C2—C3—C10—C9</td>
      <td>176.7 (3)</td>
    </tr>
    <tr>
      <td>C4—C3—C10—C11</td>
      <td>-176.5 (4)</td>
    </tr>
    <tr>
      <td>C2—C3—C10—C11</td>
      <td>0.4 (6)</td>
    </tr>
    <tr>
      <td>C1—C2—C12—O1</td>
      <td>135.7 (5)</td>
    </tr>
    <tr>
      <td>C3—C2—C12—O1</td>
      <td>-53.8 (7)</td>
    </tr>
    <tr>
      <td>Fe1—C2—C12—O1</td>
      <td>-171.1 (5)</td>
    </tr>
    <tr>
      <td>C1—C2—C12—Fe1</td>
      <td>-53.2 (3)</td>
    </tr>
    <tr>
      <td>C3—C2—C12—Fe1</td>
      <td>117.2 (3)</td>
    </tr>
    <tr>
      <td>C27—P3—C15—C16</td>
      <td>96.0 (3)</td>
    </tr>
    <tr>
      <td>C21—P3—C15—C16</td>
      <td>-155.9 (3)</td>
    </tr>
    <tr>
      <td>Pt1—P3—C15—C16</td>
      <td>-25.2 (3)</td>
    </tr>
    <tr>
      <td>C27—P3—C15—C20</td>
      <td>-83.6 (3)</td>
    </tr>
    <tr>
      <td>C21—P3—C15—C20</td>
      <td>24.5 (4)</td>
    </tr>
    <tr>
      <td>Pt1—P3—C15—C20</td>
      <td>155.2 (3)</td>
    </tr>
    <tr>
      <td>C20—C15—C16—C17</td>
      <td>0.5 (5)</td>
    </tr>
    <tr>
      <td>P3—C15—C16—C17</td>
      <td>-179.1 (3)</td>
    </tr>
    <tr>
      <td>C15—C16—C17—C18</td>
      <td>-0.8 (6)</td>
    </tr>
    <tr>
      <td>C16—C17—C18—C19</td>
      <td>-0.4 (6)</td>
    </tr>
    <tr>
      <td>C17—C18—C19—C20</td>
      <td>1.8 (6)</td>
    </tr>
    <tr>
      <td>C18—C19—C20—C15</td>
      <td>-2.1 (6)</td>
    </tr>
    <tr>
      <td>C16—C15—C20—C19</td>
      <td>0.9 (6)</td>
    </tr>
    <tr>
      <td>P3—C15—C20—C19</td>
      <td>-179.4 (3)</td>
    </tr>
    <tr>
      <td>C15—P3—C21—C26</td>
      <td>-136.5 (3)</td>
    </tr>
  </tbody>
</table>

<table>
  <tbody>
    <tr>
      <td>Pt1—P2—C33—C34</td>
      <td>25.8 (3)</td>
    </tr>
    <tr>
      <td>C39—P2—C33—C38</td>
      <td>71.6 (3)</td>
    </tr>
    <tr>
      <td>C45—P2—C33—C38</td>
      <td>-36.5 (3)</td>
    </tr>
    <tr>
      <td>Pt1—P2—C33—C38</td>
      <td>-156.0 (3)</td>
    </tr>
    <tr>
      <td>C38—C33—C34—C35</td>
      <td>-0.9 (5)</td>
    </tr>
    <tr>
      <td>P2—C33—C34—C35</td>
      <td>177.4 (3)</td>
    </tr>
    <tr>
      <td>C33—C34—C35—C36</td>
      <td>0.9 (6)</td>
    </tr>
    <tr>
      <td>C34—C35—C36—C37</td>
      <td>-0.8 (6)</td>
    </tr>
    <tr>
      <td>C35—C36—C37—C38</td>
      <td>0.8 (6)</td>
    </tr>
    <tr>
      <td>C36—C37—C38—C33</td>
      <td>-0.9 (6)</td>
    </tr>
    <tr>
      <td>C34—C33—C38—C37</td>
      <td>1.0 (5)</td>
    </tr>
    <tr>
      <td>P2—C33—C38—C37</td>
      <td>-177.3 (3)</td>
    </tr>
    <tr>
      <td>C33—P2—C39—C40</td>
      <td>3.1 (3)</td>
    </tr>
    <tr>
      <td>C45—P2—C39—C40</td>
      <td>115.3 (3)</td>
    </tr>
    <tr>
      <td>Pt1—P2—C39—C40</td>
      <td>-133.9 (3)</td>
    </tr>
    <tr>
      <td>C33—P2—C39—C44</td>
      <td>177.3 (3)</td>
    </tr>
    <tr>
      <td>C45—P2—C39—C44</td>
      <td>-70.5 (3)</td>
    </tr>
    <tr>
      <td>Pt1—P2—C39—C44</td>
      <td>40.3 (3)</td>
    </tr>
    <tr>
      <td>C44—C39—C40—C41</td>
      <td>0.0 (6)</td>
    </tr>
    <tr>
      <td>P2—C39—C40—C41</td>
      <td>174.2 (3)</td>
    </tr>
    <tr>
      <td>C39—C40—C41—C42</td>
      <td>0.1 (6)</td>
    </tr>
    <tr>
      <td>C40—C41—C42—C43</td>
      <td>0.1 (6)</td>
    </tr>
    <tr>
      <td>C41—C42—C43—C44</td>
      <td>-0.5 (6)</td>
    </tr>
    <tr>
      <td>C42—C43—C44—C39</td>
      <td>0.6 (6)</td>
    </tr>
    <tr>
      <td>C40—C39—C44—C43</td>
      <td>-0.4 (5)</td>
    </tr>
    <tr>
      <td>P2—C39—C44—C43</td>
      <td>-174.9 (3)</td>
    </tr>
    <tr>
      <td>C46—P1—C45—P2</td>
      <td>179.53 (17)</td>
    </tr>
    <tr>
      <td>C52—P1—C45—P2</td>
      <td>74.8 (2)</td>
    </tr>
    <tr>
      <td>Fe1—P1—C45—P2</td>
      <td>-56.55 (18)</td>
    </tr>
    <tr>
      <td>C33—P2—C45—P1</td>
      <td>-87.49 (19)</td>
    </tr>
    <tr>
      <td>C39—P2—C45—P1</td>
      <td>163.46 (17)</td>
    </tr>
    <tr>
      <td>Pt1—P2—C45—P1</td>
      <td>43.94 (17)</td>
    </tr>
    <tr>
      <td>C45—P1—C46—C47</td>
      <td>38.0 (3)</td>
    </tr>
    <tr>
      <td>C52—P1—C46—C47</td>
      <td>141.6 (3)</td>
    </tr>
    <tr>
      <td>Fe1—P1—C46—C47</td>
      <td>-86.2 (3)</td>
    </tr>
    <tr>
      <td>C45—P1—C46—C51</td>
      <td>-146.9 (3)</td>
    </tr>
    <tr>
      <td>C52—P1—C46—C51</td>
      <td>-43.3 (3)</td>
    </tr>
    <tr>
      <td>Fe1—P1—C46—C51</td>
      <td>88.9 (3)</td>
    </tr>
    <tr>
      <td>C51—C46—C47—C48</td>
      <td>1.7 (6)</td>
    </tr>
    <tr>
      <td>P1—C46—C47—C48</td>
      <td>176.9 (3)</td>
    </tr>
    <tr>
      <td>C46—C47—C48—C49</td>
      <td>-0.2 (7)</td>
    </tr>
    <tr>
      <td>C47—C48—C49—C50</td>
      <td>-0.8 (7)</td>
    </tr>
    <tr>
      <td>C48—C49—C50—C51</td>
      <td>0.3 (6)</td>
    </tr>
    <tr>
      <td>C47—C46—C51—C50</td>
      <td>-2.2 (6)</td>
    </tr>
    <tr>
      <td>P1—C46—C51—C50</td>
      <td>-177.5 (3)</td>
    </tr>
    <tr>
      <td>C49—C50—C51—C46</td>
      <td>1.2 (6)</td>
    </tr>
    <tr>
      <td>C46—P1—C52—C53</td>
      <td>150.9 (3)</td>
    </tr>
  </tbody>
</table>
<table><tr><td>C27—P3—C21—C26</td><td>-26.2 (3)</td><td>C45—P1—C52—C53</td><td>-103.8 (3)</td></tr><tr><td>Pt1—P3—C21—C26</td><td>95.1 (3)</td><td>Fe1—P1—C52—C53</td><td>23.1 (3)</td></tr><tr><td>C15—P3—C21—C22</td><td>50.2 (3)</td><td>C46—P1—C52—C57</td><td>-34.5 (3)</td></tr><tr><td>C27—P3—C21—C22</td><td>160.5 (3)</td><td>C45—P1—C52—C57</td><td>70.8 (3)</td></tr><tr><td>Pt1—P3—C21—C22</td><td>-78.1 (3)</td><td>Fe1—P1—C52—C57</td><td>-162.3 (2)</td></tr><tr><td>C26—C21—C22—C23</td><td>-0.4 (5)</td><td>C57—C52—C53—C54</td><td>1.5 (5)</td></tr><tr><td>P3—C21—C22—C23</td><td>173.1 (3)</td><td>P1—C52—C53—C54</td><td>176.2 (3)</td></tr><tr><td>C21—C22—C23—C24</td><td>0.6 (6)</td><td>C52—C53—C54—C55</td><td>0.6 (6)</td></tr><tr><td>C22—C23—C24—C25</td><td>-0.7 (6)</td><td>C53—C54—C55—C56</td><td>-1.7 (6)</td></tr><tr><td>C23—C24—C25—C26</td><td>0.7 (6)</td><td>C54—C55—C56—C57</td><td>0.8 (6)</td></tr><tr><td>C24—C25—C26—C21</td><td>-0.5 (6)</td><td>C55—C56—C57—C52</td><td>1.4 (6)</td></tr><tr><td>C22—C21—C26—C25</td><td>0.4 (5)</td><td>C53—C52—C57—C56</td><td>-2.5 (5)</td></tr><tr><td>P3—C21—C26—C25</td><td>-173.0 (3)</td><td>P1—C52—C57—C56</td><td>-177.2 (3)</td></tr><tr><td>C15—P3—C27—C28</td><td>29.2 (4)</td><td>C64—C59—C60—C61</td><td>-0.5 (7)</td></tr><tr><td>C21—P3—C27—C28</td><td>-79.8 (3)</td><td>C58—C59—C60—C61</td><td>178.2 (4)</td></tr><tr><td>Pt1—P3—C27—C28</td><td>153.3 (3)</td><td>C59—C60—C61—C62</td><td>-0.4 (7)</td></tr><tr><td>C15—P3—C27—C32</td><td>-151.3 (3)</td><td>C60—C61—C62—C63</td><td>1.0 (8)</td></tr><tr><td>C21—P3—C27—C32</td><td>99.6 (3)</td><td>C61—C62—C63—C64</td><td>-0.8 (8)</td></tr><tr><td>Pt1—P3—C27—C32</td><td>-27.3 (3)</td><td>C60—C59—C64—C63</td><td>0.7 (7)</td></tr><tr><td>C32—C27—C28—C29</td><td>0.9 (6)</td><td>C58—C59—C64—C63</td><td>-177.9 (4)</td></tr><tr><td>P3—C27—C28—C29</td><td>-179.7 (3)</td><td>C62—C63—C64—C59</td><td>-0.1 (8)</td></tr><tr><td>C27—C28—C29—C30</td><td>0.3 (7)</td><td>C71—C66—C67—C68</td><td>-1.8 (8)</td></tr><tr><td>C28—C29—C30—C31</td><td>-1.5 (7)</td><td>C65—C66—C67—C68</td><td>178.6 (5)</td></tr><tr><td>C29—C30—C31—C32</td><td>1.6 (7)</td><td>C66—C67—C68—C69</td><td>0.6 (9)</td></tr><tr><td>C28—C27—C32—C31</td><td>-0.7 (6)</td><td>C67—C68—C69—C70</td><td>1.2 (9)</td></tr><tr><td>P3—C27—C32—C31</td><td>179.8 (3)</td><td>C68—C69—C70—C71</td><td>-1.7 (8)</td></tr><tr><td>C30—C31—C32—C27</td><td>-0.5 (6)</td><td>C69—C70—C71—C66</td><td>0.3 (7)</td></tr><tr><td>C39—P2—C33—C34</td><td>-106.7 (3)</td><td>C67—C66—C71—C70</td><td>1.4 (7)</td></tr><tr><td>C45—P2—C33—C34</td><td>145.2 (3)</td><td>C65—C66—C71—C70</td><td>-179.0 (4)</td></tr></table>

### Hydrogen-bond geometry (Å, °)

Cg3, Cg6, Cg8, Cg9 and Cg10 are the centroids of the C21–C26, C39–C44, C52–C57, C59–C64 and C66–C71 rings, respectively.

<table><thead><tr><th>D—H···A</th><th>D—H</th><th>H···A</th><th>D···A</th><th>D—H···A</th></tr></thead><tbody><tr><td>C11—H11A···O1</td><td>0.96</td><td>2.36</td><td>3.193 (4)</td><td>145</td></tr><tr><td>C31—H31···O1<sup>i</sup></td><td>0.93</td><td>2.55</td><td>3.370 (5)</td><td>147</td></tr><tr><td>C41—H41···O2<sup>ii</sup></td><td>0.93</td><td>2.49</td><td>3.202 (5)</td><td>134</td></tr><tr><td>C48—H48···O3<sup>iii</sup></td><td>0.93</td><td>2.46</td><td>3.325 (5)</td><td>154</td></tr><tr><td>C11—H11B···Cg9<sup>iv</sup></td><td>0.96</td><td>2.80</td><td>3.719 (4)</td><td>160</td></tr><tr><td>C22—H22···Cg6</td><td>0.93</td><td>2.80</td><td>3.597 (3)</td><td>145</td></tr><tr><td>C34—H34···Cg3</td><td>0.93</td><td>2.98</td><td>3.519 (4)</td><td>118</td></tr><tr><td>C38—H38···Cg10</td><td>0.93</td><td>2.82</td><td>3.694 (4)</td><td>156</td></tr><tr><td>C60—H60···Cg8</td><td>0.93</td><td>2.81</td><td>3.543 (5)</td><td>137</td></tr></tbody></table>

Symmetry codes: (i) $x+1/2, y, z$; (ii) $-x+1/2, y+1/2, -z+3/2$; (iii) $x-1/2, y, z$; (iv) $x-1/2, -y+1/2, z-1/2$.
<table><tr><td>C27—P3—C21—C26</td><td>-26.2 (3)</td><td>C45—P1—C52—C53</td><td>-103.8 (3)</td></tr><tr><td>Pt1—P3—C21—C26</td><td>95.1 (3)</td><td>Fe1—P1—C52—C53</td><td>23.1 (3)</td></tr><tr><td>C15—P3—C21—C22</td><td>50.2 (3)</td><td>C46—P1—C52—C57</td><td>-34.5 (3)</td></tr><tr><td>C27—P3—C21—C22</td><td>160.5 (3)</td><td>C45—P1—C52—C57</td><td>70.8 (3)</td></tr><tr><td>Pt1—P3—C21—C22</td><td>-78.1 (3)</td><td>Fe1—P1—C52—C57</td><td>-162.3 (2)</td></tr><tr><td>C26—C21—C22—C23</td><td>-0.4 (5)</td><td>C57—C52—C53—C54</td><td>1.5 (5)</td></tr><tr><td>P3—C21—C22—C23</td><td>173.1 (3)</td><td>P1—C52—C53—C54</td><td>176.2 (3)</td></tr><tr><td>C21—C22—C23—C24</td><td>0.6 (6)</td><td>C52—C53—C54—C55</td><td>0.6 (6)</td></tr><tr><td>C22—C23—C24—C25</td><td>-0.7 (6)</td><td>C53—C54—C55—C56</td><td>-1.7 (6)</td></tr><tr><td>C23—C24—C25—C26</td><td>0.7 (6)</td><td>C54—C55—C56—C57</td><td>0.8 (6)</td></tr><tr><td>C24—C25—C26—C21</td><td>-0.5 (6)</td><td>C55—C56—C57—C52</td><td>1.4 (6)</td></tr><tr><td>C22—C21—C26—C25</td><td>0.4 (5)</td><td>C53—C52—C57—C56</td><td>-2.5 (5)</td></tr><tr><td>P3—C21—C26—C25</td><td>-173.0 (3)</td><td>P1—C52—C57—C56</td><td>-177.2 (3)</td></tr><tr><td>C15—P3—C27—C28</td><td>29.2 (4)</td><td>C64—C59—C60—C61</td><td>-0.5 (7)</td></tr><tr><td>C21—P3—C27—C28</td><td>-79.8 (3)</td><td>C58—C59—C60—C61</td><td>178.2 (4)</td></tr><tr><td>Pt1—P3—C27—C28</td><td>153.3 (3)</td><td>C59—C60—C61—C62</td><td>-0.4 (7)</td></tr><tr><td>C15—P3—C27—C32</td><td>-151.3 (3)</td><td>C60—C61—C62—C63</td><td>1.0 (8)</td></tr><tr><td>C21—P3—C27—C32</td><td>99.6 (3)</td><td>C61—C62—C63—C64</td><td>-0.8 (8)</td></tr><tr><td>Pt1—P3—C27—C32</td><td>-27.3 (3)</td><td>C60—C59—C64—C63</td><td>0.7 (7)</td></tr><tr><td>C32—C27—C28—C29</td><td>0.9 (6)</td><td>C58—C59—C64—C63</td><td>-177.9 (4)</td></tr><tr><td>P3—C27—C28—C29</td><td>-179.7 (3)</td><td>C62—C63—C64—C59</td><td>-0.1 (8)</td></tr><tr><td>C27—C28—C29—C30</td><td>0.3 (7)</td><td>C71—C66—C67—C68</td><td>-1.8 (8)</td></tr><tr><td>C28—C29—C30—C31</td><td>-1.5 (7)</td><td>C65—C66—C67—C68</td><td>178.6 (5)</td></tr><tr><td>C29—C30—C31—C32</td><td>1.6 (7)</td><td>C66—C67—C68—C69</td><td>0.6 (9)</td></tr><tr><td>C28—C27—C32—C31</td><td>-0.7 (6)</td><td>C67—C68—C69—C70</td><td>1.2 (9)</td></tr><tr><td>P3—C27—C32—C31</td><td>179.8 (3)</td><td>C68—C69—C70—C71</td><td>-1.7 (8)</td></tr><tr><td>C30—C31—C32—C27</td><td>-0.5 (6)</td><td>C69—C70—C71—C66</td><td>0.3 (7)</td></tr><tr><td>C39—P2—C33—C34</td><td>-106.7 (3)</td><td>C67—C66—C71—C70</td><td>1.4 (7)</td></tr><tr><td>C45—P2—C33—C34</td><td>145.2 (3)</td><td>C65—C66—C71—C70</td><td>-179.0 (4)</td></tr></table>

### Hydrogen-bond geometry (Å, °)

Cg3, Cg6, Cg8, Cg9 and Cg10 are the centroids of the C21–C26, C39–C44, C52–C57, C59–C64 and C66–C71 rings, respectively.

<table><thead><tr><th>D—H···A</th><th>D—H</th><th>H···A</th><th>D···A</th><th>D—H···A</th></tr></thead><tbody><tr><td>C11—H11A···O1</td><td>0.96</td><td>2.36</td><td>3.193 (4)</td><td>145</td></tr><tr><td>C31—H31···O1<sup>i</sup></td><td>0.93</td><td>2.55</td><td>3.370 (5)</td><td>147</td></tr><tr><td>C41—H41···O2<sup>ii</sup></td><td>0.93</td><td>2.49</td><td>3.202 (5)</td><td>134</td></tr><tr><td>C48—H48···O3<sup>iii</sup></td><td>0.93</td><td>2.46</td><td>3.325 (5)</td><td>154</td></tr><tr><td>C11—H11B···Cg9<sup>iv</sup></td><td>0.96</td><td>2.80</td><td>3.719 (4)</td><td>160</td></tr><tr><td>C22—H22···Cg6</td><td>0.93</td><td>2.80</td><td>3.597 (3)</td><td>145</td></tr><tr><td>C34—H34···Cg3</td><td>0.93</td><td>2.98</td><td>3.519 (4)</td><td>118</td></tr><tr><td>C38—H38···Cg10</td><td>0.93</td><td>2.82</td><td>3.694 (4)</td><td>156</td></tr><tr><td>C60—H60···Cg8</td><td>0.93</td><td>2.81</td><td>3.543 (5)</td><td>137</td></tr></tbody></table>

Symmetry codes: (i) x+1, y, z; (ii) -x+1/2, y+1/2, -z+3/2; (iii) x-1, y, z; (iv) x-1/2, -y+1/2, z-1/2.