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# Advances in oxychalcogenide materials for hydrogen evolution photocatalysis in aqueous media

Sandy Al Bacha, Emma Mccabe, Houria Kabbour

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Sandy Al Bacha, Emma Mccabe, Houria Kabbour. Advances in oxychalcogenide materials for hydrogen evolution photocatalysis in aqueous media. Chemical Communications, 2025, 61 (62), pp.11510-11528. 10.1039/d5cc01448d. hal-05172856

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https://hal.science/hal-05172856v1

Submitted on 11 Dec 2025

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# Advances in Oxychalcogenide Materials For Solar Water-Splitting
## Photocatalysis

Sandy Al Bacha<sup>a,b,c*</sup>, Emma E. McCabe<sup>c*</sup>, Houria Kabbour<sup>a,d*</sup>

Corresponding authors: [sandy.albacha@univ-lille.fr](mailto:sandy.albacha@univ-lille.fr), [emma.mccabe@durham.ac.uk](mailto:emma.mccabe@durham.ac.uk), [houria.kabbour@cnrs-imn.fr](mailto:houria.kabbour@cnrs-imn.fr)

## ABSTRACT

The growing demand for sustainable energy solutions has led to significant research in photocatalytic water splitting, a promising approach for clean hydrogen production. Oxychalcogenide materials have emerged as a compelling class of photocatalysts due to their tunable electronic structures, various architectures, and favorable band edge positions for solar water splitting. This review provides a comprehensive analysis of recent advances in oxychalcogenide photocatalysts, emphasizing their structural diversity, composition-property relationships, and key design strategies. We highlight the impact of anion selection, cation contributions, charge carrier dynamics, and material stability on photocatalytic performance. Furthermore, we discuss innovative experimental approaches, such as surface modifications that have been employed to enhance activity. By consolidating existing knowledge and identifying critical parameters for optimization, this review aims to shed into light this class of photocatalysts and help guiding the rational design of next-generation oxychalcogenide photocatalysts for efficient and scalable solar hydrogen production.

## 1. Introduction

Solar energy, the most abundant energy source<sup>1,2,3,4</sup> can be converted into chemical energy, for instance in the case of water-splitting photocatalysis<sup>5</sup>, other photocatalytic reactions<sup>6</sup> or

<footnote><sup>a</sup> Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille, France</footnote>

<footnote><sup>b</sup> University of Kent, School of Physical Sciences, Canterbury, Kent CT2 7NH, U.K</footnote>

<footnote><sup>c</sup> Durham University, Department of Physics, Durham DH1 3LE, U.K.</footnote>

<footnote><sup>d</sup> Nantes Université, CNRS, Institut des Matériaux de Nantes Jean Rouxel – UMR6502, F-44000, Nantes, France.</footnote>
photoelectrochemistry⁷; and into electrical energy by means of the photovoltaic effect. Photocatalysis has been developing for a long time, with early work on oxides like ZnO that introduced the concept of photo-reduction.⁸ The observation that TiO₂ could catalyse the decomposition of organic materials (under UV light),⁹ and then catalyse water splitting to give O₂ and H₂¹⁰ has motivated research into new and efficient photocatalysts.¹¹,¹²,¹³ A schematic illustration of the photocatalytic reaction process indicating factors that may affect photocatalytic activity is presented in Figure 1a.

For photocatalysis, first the semiconductor has to be irradiated by incident photons of energy greater than or equal to the bandgap energy of the material. The absorption of photons will cause the excitation of electrons (e⁻) from the valence band (VB) to the conduction band (CB) leaving then a positive hole (h⁺) in the valence band. The e⁻/h⁺ pairs will separate and migrate to the reaction sites on the surface of the material or recombine. In an ideal photocatalytic reaction, after the adsorption of the molecules (H₂O for the water-splitting) involved in the reaction to be catalyzed, electrons and holes migrate to reaction sites and take part in reduction and oxidation reactions, respectively. In addition to the desired photocatalytic redox reactions, the e⁻/h⁺ pairs could recombine a short time after their separation which is detrimental to the photocatalytic activity.¹⁴,¹⁵ This recombination can result from various phenomena and was documented in various reports.¹⁶,¹⁷ Some intrinsic properties of the photocatalysts such as built-in electrical field or high mobility charge carriers for instance are reported to enhance e⁻/h⁺ separation and rapid migration.¹⁸ On the other hand, approaches exploiting extrinsic factors, such as heterostructures and p-n junctions, can enhance this e⁻/h⁺ separation.

It is therefore, important to develop new and more sustainable strategies that can anticipate the future energy transition and maintain technological progress. In this context, fuel cells are one such example, as they use renewable sources (oxygen and hydrogen) to give electrical energy.¹⁹ Since oxygen is readily available, the challenge is to produce the required hydrogen. To this purpose, solar photocatalytic water splitting is very attractive due to its simplicity: if the photocatalyst in appropriate conditions (solution, co-catalyst) is directly active using only sunlight to efficiently produce renewable hydrogen. Figure 1b illustrates the process of the water splitting reaction in a typical semiconductor material on the conduction and the valence band level, with a suitable bandgap for the solar spectrum.²⁰,¹⁵
However, carrying out solar photocatalytic water splitting imposes constraints on the semiconductor, such as the magnitude of the bandgap (between 1.23 and 3.10 eV, where 1.23 eV is the theoretical minimum bandgap, and 3.10 eV corresponds to the wavelength of the visible light ranging from 400 nm to 700 nm). Secondly, the conduction band potential must be more negative than the reduction potential of H₂O/H₂ (0 V) and the valence band potential must be more positive potential than the oxidation potential of O₂/H₂O (1.23 V)²¹, to satisfy relations (1) and (2):

$$ \text{Oxidation: } H_2O + 2h^+ \rightarrow 2H^+ + \frac{1}{2}O_2 \quad (1) $$

$$ \text{Reduction: } 2H^+ + 2e^- \rightarrow H_2 \quad (2) $$

Oxychalcogenide photocatalytic materials gained considerable attention in recent years.²²,²³ To understand their photocatalytic properties (and to design optimized oxychalcogenide photocatalysts), it is essential to understand their rich chemistry and structural diversity. Our review focuses on oxychalcogenide photocatalysts with bandgaps well-matched to the solar spectrum and with band edges of appropriate energies for photocatalytical water splitting. We explore compositions and structural features that play key roles in determining the photocatalytic activity of these oxychalcogenides. This understanding of structure – composition – property relationships allow us to propose some strategies to predict and design new oxychalcogenide photocatalysts.

<figure><img src="image_3.png" /><figcaption>**Figure 1** : Schematic illustration of the entire photocatalytic reaction process in a semiconductor photocatalyst.</figcaption></figure>
## 2. Oxychalcogenides for photocatalysis

A mixed-anion compound is a material containing more than one anion in a single phase such as oxychalcogenides, oxypnictides,²⁴ oxyhydrides²⁵ and oxyhalides.²⁶ The coexistence of more than one anion type in the material is a promising strategy to control various properties, giving them a range of applications (photocatalytic activity²⁷,²⁸,²⁹,³⁰ superconductivity,³¹,³²,³³ magnetic,³⁴,³⁵,³⁶ non-linear optic (NLO),³⁷ battery material,³⁸ thermoelectricity³⁹ and photoluminescence⁴⁰).

There are several reviews which highlight the importance of mixed-anion materials in general or for specific applications. Kageyama et al.⁴¹ reviewed the great achievements and potential of mixed-anion materials, emphasizing some important factors in designing new materials. The different characters of the anions, such as charge, ionic radii, electronegativity and bonding character, can give rise to anion-order/disorder giving access to new structural types. ²⁴ For example, oxynitrides often exhibit correlated disorder instead of a long-range one;⁴² oxyarsenides show a long-range order of O²⁻ and As³⁻ anions (e.g. iron-based superconductors with insulating oxide layers and more delocalized (even superconducting) iron arsenide layers.⁴³,⁴⁴

Among mixed-anion materials, layered oxychalcogenides are a promising family that has gained more attention recently. Oxychalcogenides contain an oxide as well as a chalcogenide (sulfide/selenide/ telluride) anion. These materials adopt a diversity of structure types and show a range of properties related to the ordering of the small oxide and the larger chalcogenide, likely due to their different sizes and bonding characters.²⁴

Several excellent reviews have explored the structural chemistry of oxychalcogenides and their broader applications. Clarke et al.²⁴ examined the relationships between crystal structures and physical properties, while Orr et al.⁴⁵ focused on the structural diversity of rare-earth oxychalcogenides. Additional studies have highlighted their thermoelectric, optoelectronic, and infrared nonlinear optical properties.⁴⁶,⁴⁷,⁴⁸ Reviews on photocatalysis have also discussed mixed-anion materials, including oxychalcogenides, with key contributions from the Domen group⁴⁹,⁵⁰ and others covering water-splitting, CO₂ reduction,⁵¹ and heteroanionic photocatalysts.⁵²,⁵³

While these reviews provide valuable insights, our work offers a timely and dedicated focus on photocatalytic oxychalcogenides for solar water splitting. We consolidate recent advances,
highlight critical structure-property relationships, and explore emerging strategies to enhance their photocatalytic performance. To our knowledge, no prior review has specifically addressed this class of materials with such depth in the context of solar-driven hydrogen production. In particular, we emphasize their potential for direct H₂ generation under sunlight, excluding more complex PEC systems and composite catalysts that combine sulfides and oxides.

## 2.1. Structures of oxychalcogenide materials

Oxychalcogenides, containing oxide anions as well as second larger and softer chalcogenide anion (e.g. S²⁻, Se²⁻, Te²⁻), tend to stabilize lower transition metal oxidation states and lower coordination numbers, compared with oxides. As mentioned before, this family of materials show structural diversity, but they often adopt layered structures due to anion order that can lead to segregation of the different anions into different layers.²⁴ This layered arrangement of anions can depend on the relative electronegativities of the accompanying cations.⁴⁵ For instance, in the case of a significant difference in hardness/softness of cations, stronger bonds can be formed with either hard oxide or soft chalcogenide anions and so layered structures with a greater proportion of homoleptic (single anion) coordinations are favoured;⁴¹ whilst in the case of similar hardness/softness of the cations, heteroleptic coordination (mixed anion) can be more favourable.⁵⁴

These oxychalcogenides present some common structural features such as the building blocks that they contain (Figure 2). For example, OLn₄ units in fluorite-like sheets, ribbons or chains (consisting of edge-linked units);⁴⁵,⁵⁵,⁵⁶ MQ₄ tetrahedra edge-linked into chains or antifluorite-like sheets⁵⁷ or square-based pyramid MQ₅ or MOQ₄ units for Bi, Sb with their 6s² or 5s² inert pairs.⁵⁸

Having this layered aspect in most oxychalcogenides can give rise to a wide range of promising properties, due to the potential for chemical substitutions that can be done in both layers; such as highly anisotropic electronic structure and properties and high mobility semiconduction favored by the covalent aspect of the chalcogenide.⁵⁹ For example, layered LaOCuS⁶⁰ and BiCuOSe⁶¹ are known as important thermoelectrics, due to the presence of the insulating oxide layers and the semiconducting copper chalcogenide layers (see Figure 2).⁴⁶ As another example, Ln₂O₂M₂OQ₂, with M cations coordinated by both O²⁻ and Q²⁻ anions with long-range magnetic order, but electronically quite separated by the insulating [La₂O₂]²⁺ layers.⁶² These materials may have numerous properties such as magnetism;⁶³,⁶⁴,⁶⁵ thermoelectricity;⁴⁸,⁶⁶ IR-nonlinear optical
materials;⁶⁷,⁴⁷,⁶⁸,⁶⁹,⁷⁰

second harmonic

generation SHG;⁷¹,⁷²,⁷³

semiconductors;⁷⁴,⁷⁵,⁷⁶

photocatalysts⁵³ and piezoelectricity.⁷⁷

<figure><img src="image_4.png" /><figcaption>**Figure 2:** (a) Schematic summarizing some coordination environments in oxychalcogenides. (b) Example of the ZrCuSiAs structure packing motifs from panel 1, adopted by BiCuOQ, BiAgOQ and LnFeAsO (as discussed in section 2.2.8).</figcaption></figure>
## 2.2. Photocatalytic properties and band gap feature of oxychalcogenides

Several examples of oxychalcogenides for photocatalytic water splitting have been reported but to date there has not been a systematic exploration of their properties and features. A survey of the literature helped identify oxychalcogenides and their important characteristics (band gap, semiconduction type, cation choice, coordination environment, anion ratio and polarity); the band edge positions have also been estimated, which allowed the identification of some potential candidates for possible future characterizations (see Supporting information). In the following section, the top materials with proven capacity to evolve H₂ and/or O₂ are discussed. These H₂(g) and/or O₂(g) evolution experiments have been reported for relatively few oxyselenides.

### 2.2.1. Ln₂Ti₂S₂O₅ (Ln = Y, Nd, Sm, Gd, Tb, Dy, Ho and Er) series

The series Ln₂Ti₂S₂O₅ (Ln = Y, lanthanide) adopt a tetragonal Ruddlesden-Popper crystal structure.⁷⁸,⁷⁹ It is built from double-layers of corner-linked TiO₅ square-based pyramids separated by [Ln₂S₂]²⁺ rocksalt slabs (Figure 3); where this separation between the covalency of the sulfide layers and the ionicity of oxide layers results in an intermediate situation of strong interlayer connections. Optical band gaps of these phases were found to match the solar spectrum,⁸⁰ and under visible-light (λ = 440 - 650 nm) irradiation they demonstrated their capacity to evolve both O₂ and H₂ (Table 1).⁸¹ Studies on Sm₂Ti₂S₂O₅ highlight the importance of the pH and the surface modification on the photocatalytic activity;⁸² and the influence of the synthetic route with lower temperatures and reduced heating time to increase the photocatalytic activity, due to the formation of smaller particle sizes and, consequently, an increased surface area.⁸³ In addition, the n-type Y₂Ti₂O₅S₂⁸⁴ was the first to demonstrate a capacity to evolve both hydrogen and oxygen in a stoichiometric ratio, under visible irradiation.⁸⁵,⁸⁶,⁸⁷

The fact of having suitable band gaps as well as a layered structure definitely contributed to the good activity demonstrated by this series. Another common factor is the presence of Ti 3d orbitals in the CBM; whilst for the VBM the lanthanide based phases have partially filled, highly localized, Ln 4f orbitals which are less effective in photoconductivity or photocatalysis and are usually ignored.⁸² Finally some of these phases exhibited lower activities than others which could be related to the larger amounts of sulfur defects or the thermodynamically less favorable VB position.⁸¹ More recently, Sc-doping of Y₂Ti₂O₅S₂ followed by an etching process to “clean” the surface, considerably increased the photocatalytic activity to 445 mmol h⁻¹, which is 3.4 times
higher than that for the pristine compound. The authors attribute this enhancement to a decrease of the defect density with Sc doping.⁸⁸ In another article, Y₂Ti₂O₅S₂ nanosheets are synthesized by a flux-assisted solid-state reaction which exposed {101} and {001} facets that provides an anisotropic charge migration, which were found to be responsible for the reduction and oxidation of the water-splitting photocatalytic reaction, respectively. It is striking that selective photo-deposition of cocatalysts (on a particular facet) was possible and resulted in enhanced reactivity (H₂ production, (536 µmol/h)).⁸⁴

Several studies focused on this particular Y₂Ti₂O₅S₂ photocatalyst, each of them bringing innovative approaches to design the particles, the surface or the contact with the co-catalyst. Another study focused on the solid-state reaction mechanism and intermediate.⁸⁹ They thus found that from the traditional precursors Y₂O₃, TiO₂ and Y₂S₃, the three intermediate phases Y₂Ti₂O₇, Y₂O₂S and TiS₂ appear during the formation of the final oxysulfide. The formation of agglomerates involving Y₂Ti₂O₇ and Y₂O₂S which react with the third intermediate TiS₂ (carried by the sulfur vapor) was a critical step impacting the morphology of the crystallites. With this knowledge, the authors could reduce the particle size by increasing the heating rate which resulted in improved photocatalytic performances.

These advances on those compositions show that the intrinsic properties of the crystalline phases are as important as the morphology (particle size and surface design). In the case of Ln= Gd, outstanding results were reported with recent advances.⁹⁰ Gd₂Ti₂O₅S₂ with atomically ordered surfaces could be obtained using flux synthesis followed by acidic etching of the surface. The outstanding enhancement of the photocatalytic activity (3 mmol/h for H₂ production) is attributed to the crystals shape (platelet) combined with the surface design and optimized contact between the particles and a composite cocatalyst (Cr₂O₃/Pt/IrO₂).⁹¹
<figure><img src="image_5.png" /><figcaption>**Figure 3:** Structural representation of the Ruddlesden-Popper structure of the Ln₂Ti₂S₂O₅ series of 14/mmm symmetry.</figcaption></figure>

### 2.2.2. SrZn₂S₂O₃

The Zn-based oxysulfide SrZn₂S₂O₃ adopts a wurtzite-derived crystal structure consisting of double layers of corner-shared ZnS₃O tetrahedra separated by Sr²⁺ ions (Figure 4).⁹²,⁹³ SrZn₂S₂O₃ is an n-type semiconductor with a 3.86 eV direct band gap; the CB is dominated by the Zn 4s and 4p orbitals and the Sr 4d orbitals while the VB is mainly composed of O 2p and S 3p orbitals. SrZn₂S₂O₃ was capable on reducing and oxidizing water under UV-light irradiation, with a certain photocorrosive resistance.⁹⁴

Compared to the Ln₂Ti₂S₂O₅ series discussed above, the O₂ evolution rate is similar but the H₂ evolution is slightly higher for SrZn₂S₂O₃ (Table 1). This indicates the advantage of having the Zn orbitals contributing to the CB compared to the Ti orbitals. SrZn₂S₂O₃ exhibits a structure with the presence of heteroleptic coordination environment (ZnS₃O) connected three dimensionally unlike the layered Ln₂Ti₂S₂O₅, which could also have an impact on the transport properties of the charge carriers.
<figure><img src="image_6.png" /><figcaption>**Figure 4:** Structural representation of SrZn₂S₂O oxysulfide of *Pmn*2₁ symmetry.</figcaption></figure>

### 2.2.3. LnOInS₂ (Ln = La, Ce, Pr)

Yellow LaOInS₂ has a band gap of 2.73 eV and is a p-type semiconductor that adopts an orthorhombic structure.⁹⁵ Its crystal structure is composed of NaCl-type slabs made of InS₄ tetrahedra and InS₆, InS₅O octahedra, and [LaO]⁺ fluorite-type ribbons alternating in different directions (Figure 5a).⁹⁶ Under Xe lamp irradiation, the sample exhibited a reproducible photocatalytic activity, and showed H₂ evolution. On the other hand, using a metathesis reaction, the metastable layered polymorph of LaOInS₂ (also predicted in ref 97), was synthesized. It has a direct band gap of ~2.64 eV, and it adopts a monoclinic structure consisting of alternately stacked [InS₂] layers (rock-salt type) composed of InS₆ octahedra and oxide [LaO]⁺ layers (PbO-type), with a split in the In sites (Figure 5b). This polymorph was reported with higher rates of H₂ and O₂ evolution under visible light (420 < λ < 800 nm).⁹⁷

Then again, CeOInS₂ and PrOInS₂ phases were found to be isostructural to the monoclinic layered LaOInS₂,⁹⁷ except that the indium in these phases is on-center unlike in LaOInS₂, which is off-center. They revealed direct band gaps of 2.41 and 2.43 eV, respectively. Compared to LaOInS₂, these phases showed reduced H₂ evolution (it decreased by 10% under visible light).⁹⁸

The CBM in the La-based phases is mainly composed of In 5s/5p orbitals, whilst O 2p and S 3p contribute most to the VBM. The In states seem beneficial in that they contribute to the higher dispersion of the CBM (that should be associated with lower effective masses of the charge carriers
and thus higher mobilities) and thus increase the capacity to evolve H₂. However, the layered polymorph exhibited higher rates, probably related to the structure dimensionality (compared to the α-LaOInS₂): the layered character gives efficient separation of the charge carriers and helps to avoid their recombination, and thus benefits to the photocatalytic reaction. However, measurements with the same conditions are needed to evaluate accurately the difference in H₂ release rate for the two polymorphs.

As for CeOInS₂ and PrOInS₂ phases, the presence of the on-center indium decreased the hybridization of the In 5p – S 3p orbitals, which resulted in an increase in the energy difference of these hybridized orbitals, slightly shifting the optical absorption edge of these phases.⁹⁸ Even though the 4f orbitals of Ln are negligible when highly localized, it seems that their presence might increase the electron–hole recombination rates.⁹⁹,¹⁰⁰

<figure><img src="image_7.png" /><figcaption>**Figure 5** : Structural representation of LaOInS₂ material with (a) alpha model of *Pbcm* symmetry and (b) metastable layered model of *P2₁/m* symmetry.</figcaption></figure>

### 2.2.4. La<sub>5</sub>In<sub>3</sub>S<sub>9</sub>O<sub>3</sub>

The structure of La<sub>5</sub>In<sub>3</sub>S<sub>9</sub>O<sub>3</sub> consists of fluorite-type ribbons of lanthanide ions alternating with rocksalt InS layers to form 2D La<sub>5</sub>In<sub>3</sub>S<sub>6</sub>O<sub>3</sub> layers in a zigzag pattern (Figure 6).<sup>95</sup> In<sup>3+</sup> cations are only coordinated by sulfur, while La<sup>3+</sup> ions are coordinated by both oxide and sulfide ions (similar to other La-In based compounds<sup>101</sup>). The optical band gap of the yellow powder was
2.60 eV, slightly smaller than that of LaInS<sub>2</sub>O (2.73 eV), probably due to the increased sulfur coordination in La<sub>5</sub>In<sub>3</sub>S<sub>9</sub>O<sub>3</sub> decreasing the band gap.<sup>95</sup> Even though a pure polycrystalline phase was not obtained for the p-type semiconductor La<sub>5</sub>In<sub>3</sub>S<sub>9</sub>O<sub>3</sub>, it was able to reduce and oxidize water under visible irradiation.<sup>102</sup> A stable H<sub>2</sub> evolution occurred, unlike the O<sub>2</sub> evolution where it decreased over time (due to the deposition of metallic silver).

Similar to the LnOInS<sub>2</sub> (Ln = La, Ce, Pr) series, the presence of the In 5s-5p orbitals contributes to the higher H<sub>2</sub> evolution efficiency.<sup>82</sup> This is similar to SrZn<sub>2</sub>S<sub>2</sub>O, with the presence of the Zn 4s-4p orbitals contributing to the enhanced H<sub>2</sub> evolution.

<figure><img src="image_8.png" /><figcaption>**Figure 6** : Structural representation of La<sub>5</sub>In<sub>3</sub>S<sub>9</sub>O<sub>3</sub> oxysulfide (*Pbcm* symmetry) with the 2D La<sub>5</sub>In<sub>3</sub>S<sub>6</sub>O<sub>3</sub> layers consisting of two building blocks: rock-salt layers formed by both indium and lanthanum and fluorite-type ribbons formed by lanthanum atoms; alternating regularly along *b*.</figcaption></figure>

### 2.2.5. La-Ga based oxysulfides (LaGaS<sub>2</sub>O and La<sub>3</sub>GaS<sub>5</sub>O)

LaGaS<sub>2</sub>O adopts an orthorhombic KVO<sub>3</sub>-type structure consisting of layers of corner-shared distorted GaO<sub>2</sub>S<sub>2</sub> tetrahedra sharing oxygen with La<sup>3+</sup> cations (Figure 7a).<sup>103</sup> La<sub>3</sub>GaS<sub>5</sub>O adopts an orthorhombic shear type structure consisting of corner-shared GaS<sub>4</sub> tetrahedra layers and a second layer of (La<sub>2</sub>O)<sub>n</sub> formed by edge sharing LaS<sub>2</sub>, LaS<sub>2</sub>O and LaSO<sub>2</sub>, both parallel to the *b* direction (Figure 7b).<sup>104</sup>
LaGaS₂O demonstrated a n-type semiconduction with an indirect band gap of 3 eV whilst La₃GaS₅O exhibited a n-type semiconduction with a direct band gap of 2.3 eV. The CBM level is similar in both phases, whereas the VBM in La₃GaS₅O is higher than LaGaS₂O, due to the higher sulfur content. Both phases were found to be potential photocatalysts but only La₃GaS₅O was tested for water reduction and oxidation reactions under visible light, whilst LaGaS₂O produced anodic photocurrent under ultraviolet light.¹⁰⁵ The comparison of these phases highlights the importance of the chalcogen ratio in narrowing the band gaps.

<figure><img src="image_9.png" /><figcaption>**Figure 7:** Structural representation of (a) LaGaS₂O (Pmca symmetry) and (b) La₃GaS₅O (Pnma symmetry), highlighting the different layers between the two compounds.</figcaption></figure>

### 2.2.6. La₅Ti₂MS₅O₇ (M = Cu, Ag) systems

La₅Ti₂MS₅O₇ (M = Cu, Ag) oxysulfides adopt an orthorhombic structure that is not layered but rather presents condensed fragments of layers that form a building unit repeating periodically along the *b* direction (Figure 8). It consists of: i) rock-salt-type fragment containing CuS₄ tetrahedra, ii) perovskite building block made of double chains of corner-sharing Ti-centered octahedra (TiO₄S₂ or TiO₅S). The orange-yellow powder revealed an optical band gap of 2.02 and 2.17 eV for Cu and Ag phases, respectively.¹⁰⁶ Preliminary photoelectrochemical measurements revealed p-type semiconduction and a photocatalytic activity under visible light;¹⁰⁷ with higher rates occurring when loaded with convenient amount of cocatalysts.¹⁰⁸
Various synthesis methods to produce the photocathode La₅Ti₂CuS₅O₇ were investigated to further enhance its photocatalytic properties.¹⁰⁹,¹¹⁰ The electronic band structures of these phases were found to be suitable for charge separation and revealed a CBM consisting of Ti 3d orbitals whilst the VBM was formed by hybridized Cu 3d and S 3p orbitals in La₅Ti₂CuS₅O₇, rather than just S 3p orbitals in La₅Ti₂AgS₅O₇, responsible for the longer absorption edge wavelength.¹⁰⁸ The study of these materials highlights the importance of having disassociated paths for accelerating the charge separation while inhibiting the recombination process.¹¹¹

Substituted phases were also investigated for their photocatalytic properties in this system such as La₅Ti₂Cu(S₁-xSeₓ)₅O₇ photocatalysts and their hydrogen evolution activity. The authors show that performances decrease with Se content due to excessive crystals growth which can be limited by controlling the calcination temperature.¹¹²

On the other hand, the experimental study of Ga doped-La₅Ti₂Cu₀.₉Ag₀.₁O₇S₅ synthesized using thermal sulfidation show that post annealing in sulfur vapor improved its properties (H₂ production of 464 µmol/h) by reducing the defect concentration at the surface and achieving smaller particle sizes. The best samples reached H₂ production of 400 µmol after 4 hours in Na₂S-Na₂SO₃ solution and with Rh as cocatalyst.¹¹³

<figure><img src="image_10.png" /><figcaption>**Figure 8**: Structural representation of (a) La₅Ti₂MS₅O₇, (M = Cu, Ag) oxysulfides (Pnma symmetry) highlighting the different building blocks within the structure.</figcaption></figure>
### 2.2.7. La₃NbS₂O₅

For the oxysulfide La₃NbS₂O₅ (Figure 9), the preparation was carried out by sulfurization (with H₂S) of a reactive oxide precursor La₃NbO₇; the longer the treatment, the greater the particle size which decreased the BET surface area. The H₂ production was measured (3-11 µmol/h with Pt as co-catalyst.)¹¹⁴

<figure><img src="image_11.png" /><figcaption>**Figure 9:** Structural representation of the Ruddlesden-Popper-related phase La₃NbS₂O₅ oxysulfide (I4mmm symmetry), neglecting disorder in O(2) site positions.</figcaption></figure>

### 2.2.8. Oxysulfide photocatalysts with ZrSiCuAs structural type

BiOAgS which crystallizes in the ZrSiCuAs structure type has been reported to be active for water-splitting. It exhibits (BiO) fluorite layers stacked with deficient (Ag₁-xS) antifluorite layers, (see Figure 2b). With its more ionic character than the well-known BiOCuS, it presents a larger dielectric constant and is interesting for photoconversion (efficient screening of photogenerated charges). It exhibits low effective masses, a band gap of 1.5 eV, a p-type character and the authors showed its ability to evolve H₂ with preliminary measurements using ruthenium as co-catalyst photo-deposited in a Na₂S-Na₂SO₃ solution), which is not observed for BiOCuS.¹¹⁵
### 2.2.9. A pyrochlore oxysulfide

The Sn²⁺-based pyrochlore oxysulfide Sn₂Nb₂O₇-xSx (up to x = 0.6) (Figure 10) is derived from the pyrochlore oxide Sr₂Nb₂O₇ and is synthesized using solid state reaction in an evacuated sealed quartz tube. The authors could incorporate different O:S ratios up to x = 0.6 and observe a gradual decrease in band gap with increasing sulfur content. The resulting narrow band gap materials are active for water-splitting photocatalysis under visible light with highest amount of H₂ obtained for x= 0.4 (6 µmol/h).¹¹⁶

<figure><img src="image_12.png" /><figcaption>**Figure 10:** Structural representation of the Sn²⁺-based pyrochlore oxysulfide Sn₂Nb₂O₇-xSx (x = 0.23) (Sn₂.55Nb₁.95O₆.26S₀.23); where some anion-order occurs and the sulfide anion preferentially occupying the larger 8b site in the cubic pyrochlore structure.</figcaption></figure>

### 2.2.10. Other oxysulfide types

Simple compounds such as mono-cationic oxides substituted with sulfur also offer great potential to design functional oxysulfides. This is the case of ZnO₀.6S₀.4 which was reported with concomitant photocatalytic H₂ production (147.5 µmol/h) and pollutant degradation in a Na₂S-Na₂SO₃ solution, the two processes acting synergistically to reinforce the reactivity. Indeed, electron-donating intermediates (identified from FTIR) induced by the photodegradation reaction are suggested to boost the H₂ production at a particular concentration of the dye. This later approach constitutes another innovative experiment design to complement the intrinsic features of the oxysulfide matrix, in order to enhance reactivity.¹¹⁷ Ni-doped Zn(O, S) oxysulfides were also reported based on simple low temperature methods.¹¹⁸ In the later study, the highest H₂ production
(14 800 µmol/g/h) was reached in a 50% ethanol solution.

The spinel compound Zn(Zn,Ni,In)₂(O,S)₄-x is one of the few oxysulfides reported for this structure-type which have a complex non-stoichiometric composition. The later feature and its associate defect states are believed to enhance the photocatalytic H₂ production under visible light, which has been reported as 1700 µmol/g/h.¹¹⁹

Finally, we can cite another complex material which was designed with simple binary parent compounds as models. It is the defect-(Bi, Ce)₂(O, S)₃-x nanorods in which the control of oxygen vacancies led to rapid electron transport resulting in excellent photocatalytic properties (526.5 µmol/h for H₂).¹²⁰

### 2.3. Summary of composition and structural features observed in photocatalytic oxychalcogenides:

A range of factors can affect the outcome of the overall water splitting photocatalytic reaction: i) morphology and microstructure such as defects and crystallinity (intrinsic features) and ii) pH, temperature, concentration of the catalyst, type and amount of cocatalyst loading, incident light intensity (extrinsic features). The focus of this survey is to compare the structural (connectivity, polarity) and electronic (band gap magnitude and nature, density of states, charge carriers' behaviour) properties, which allowed us to identify some key features/characteristics (including structural and relating to connectivity, and compositional) that contribute to the good activity of these materials:

* Higher sulfur content can increase the VBM position (as illustrated by comparison of LaGaS₂O with La₃GaS₅O, Section 2.2.5), more suitable for the oxygen evolution but this can create larger amounts of defects within the structure which can be a disadvantage for the photocatalytic activity result.

* The charge carriers' behavior is a very important factor and having a structure that enables disassociated paths for the photoexcited electrons and holes enhances their separation and decreases the rate of their recombination, as discussed for La₅Ti₂MS₅O₇ (Section 2.2.6).

* The presence of a cation with highly localized 4f orbitals, such as Sm, are less effective in photocatalysis and their contribution is usually ignored. On the other hand, cations with less
localized 4f orbitals, such as Ce or Pr, can potentially increase the recombination rate of the photoexcited charges therefore decrease the photocatalytic activity, as suggested for the LnOInS₂ series (Section 2.2.3).

* Highly dispersed conduction and valence bands are definitely an asset for better H₂ and O₂ evolution, respectively. Examples include the presence of 5s-5p orbitals (in In or Zn containing materials) highly hybridizing in the CBM, or the addition presence of 3d orbitals (in Y or Cu containing materials) strongly hybridizing with the S 3p and O 2p orbitals gives a better VBM position.

* A greater energy difference between cation and anion orbitals can reduce their hybridization, which in turn may lower photocatalytic activity. This effect can be influenced by structural factors, such as cation displacement, either on or off-center, particularly in the case of ns² cations. The second-order Jahn-Teller effect plays a key role here, as the stereochemical activity of the lone pair can distort the local coordination environment, altering orbital overlap and hybridization strength.¹²¹ This strategy has not yet been fully explored and is discussed below (Section 3.1.2).

<table><caption>**Table 1.** Photocatalytic activity of the oxysulfides discussed in this review. Rates are taken from the references or estimated from the reported gas evolution with time. Properties are given for photocatalysis (PC) except for La₅Ti₂Cu₁-xAgₓS₅O₇ which was measured as a photocathode in a photoelectrochemical (PEC) system (unassisted)</caption><thead><tr><th rowspan="2">Compounds</th><th colspan="2">Cocatalysts</th><th colspan="2">Rate of gas evolution (µmol/h)</th></tr><tr><th>H₂ promotor</th><th>O₂ promotor</th><th>H₂</th><th>O₂</th></tr></thead><tbody><tr><td>Pr₂Ti₂S₂O₅</td><td></td><td></td><td>0</td><td>0</td></tr><tr><td>Nd₂Ti₂S₂O₅</td><td></td><td></td><td>4</td><td>3</td></tr><tr><td>Gd₂Ti₂S₂O₅</td><td></td><td></td><td>24</td><td>21</td></tr><tr><td>Ln₂Ti₂S₂O₅<sup>81</sup></td><td>Pt</td><td>-</td><td></td><td></td></tr><tr><td>Gd₂Ti₂O₅S₂ with atomically ordered surfaces<sup>90</sup></td><td></td><td></td><td>3000</td><td></td></tr><tr><td>Tb₂Ti₂S₂O₅</td><td></td><td></td><td>19</td><td>20</td></tr><tr><td>Dy₂Ti₂S₂O₅</td><td></td><td></td><td>10</td><td>9</td></tr></tbody></table>
<table><tbody><tr><td></td><td>Ho<sub>2</sub>Ti<sub>2</sub>S<sub>2</sub>O<sub>5</sub></td><td>22</td><td>5</td></tr><tr><td></td><td>Er<sub>2</sub>Ti<sub>2</sub>S<sub>2</sub>O<sub>5</sub></td><td>21</td><td>1</td></tr><tr><td></td><td>Y<sub>2</sub>Ti<sub>2</sub>S<sub>2</sub>O<sub>5</sub><sup>87</sup></td><td>Cr<sub>2</sub>O<sub>3</sub>/Rh/IrO<sub>2</sub></td><td>~50</td><td>~25</td></tr><tr><td></td><td>Y<sub>2</sub>Ti<sub>2</sub>S<sub>2</sub>O<sub>5</sub> nanosheets<sup>122</sup></td><td>Pt IrO<sub>2</sub></td><td>536</td><td></td></tr><tr><td></td><td>Sc-doped Y<sub>2</sub>Ti<sub>2</sub>O<sub>5</sub>S<sub>2</sub><sup>123</sup></td><td>Rh</td><td>445</td><td></td></tr><tr><td></td><td>Sm<sub>2</sub>Ti<sub>2</sub>S<sub>2</sub>O<sub>5</sub><sup>82,83</sup></td><td>Pt IrO<sub>2</sub></td><td>22</td><td>22</td></tr><tr><td></td><td>SrZn<sub>2</sub>S<sub>2</sub>O<sub>9</sub><sup>94</sup></td><td>Pt IrO<sub>2</sub></td><td>67.8</td><td>26.9</td></tr><tr><td rowspan="2">LaInOS<sub>2</sub></td><td>α-LaInOS<sub>2</sub><sup>96</sup></td><td>Pt</td><td>5.1</td><td>-</td></tr><tr><td>Layered-LaInOS<sub>2</sub><sup>97</sup></td><td>Pt IrO<sub>2</sub></td><td>~25</td><td>~6</td></tr><tr><td rowspan="2">AInOS<sub>2</sub><sup>98</sup></td><td>CeInOS<sub>2</sub></td><td>Pt</td><td>&lt;2.5</td><td>-</td></tr><tr><td>PrInOS<sub>2</sub></td><td>Pt</td><td>&lt;2.5</td><td>-</td></tr><tr><td></td><td>La<sub>5</sub>In<sub>3</sub>S<sub>9</sub>O<sub>3</sub><sup>102</sup></td><td>Pt IrO<sub>2</sub></td><td>~50</td><td>~12</td></tr><tr><td></td><td>La<sub>3</sub>GaS<sub>5</sub>O<sub>105</sub></td><td>RuCl<sub>3.3</sub>H<sub>2</sub>O</td><td>80.7</td><td>~12</td></tr><tr><td></td><td>La<sub>3</sub>NbS<sub>2</sub>O<sub>5</sub><sup>114</sup></td><td>Pt (1 wt%)</td><td>3-11</td><td>-</td></tr><tr><td rowspan="2">La<sub>5</sub>Ti<sub>2</sub>MS<sub>5</sub>O<sub>7</sub><sup>107,108</sup></td><td>La<sub>5</sub>Ti<sub>2</sub>CuS<sub>5</sub>O<sub>7</sub></td><td>Pt IrO<sub>2</sub></td><td>110</td><td>24</td></tr><tr><td>La<sub>5</sub>Ti<sub>2</sub>AgS<sub>5</sub>O<sub>7</sub></td><td>Pt IrO<sub>2</sub></td><td>220</td><td>12</td></tr><tr><td></td><td>La<sub>5</sub>Ti<sub>2</sub>Cu<sub>1-x</sub>Ag<sub>x</sub>S<sub>5</sub>O<sub>7</sub><sup>124</sup></td><td>Pt</td><td>~32</td><td>-</td></tr><tr><td>Ga doped - La<sub>5</sub>Ti<sub>2</sub>Cu<sub>0.9</sub>Ag<sub>0.1</sub>O<sub>7</sub>S<sub>5</sub><sup>113</sup></td><td>Rh (imp+ph)</td><td>464 µmol H<sub>2</sub> during the first hour</td><td></td><td></td></tr><tr><td></td><td>La<sub>5</sub>Ti<sub>2</sub>Cu(S<sub>1-x</sub>Se<sub>x</sub>)<sub>5</sub>O<sub>7</sub><sup>112</sup></td><td>Pt/NiS</td><td></td><td></td></tr><tr><td></td><td>BiOAgS<sup>115</sup></td><td>Ru</td><td>~10</td><td>-</td></tr><tr><td></td><td>ZnO<sub>0.6</sub>S<sub>0.4</sub><sup>117</sup></td><td></td><td></td><td></td></tr><tr><td>InMnO<sub>3-x</sub>S<sub>x</sub><sup>125</sup></td><td></td><td>158 (sacrificial S<sup>2-</sup>/SO<sub>3</sub><sup>2-</sup>)</td><td>649 (with specific AgNO<sub>3</sub> sacrificial agent)</td><td></td></tr><tr><td>Defect-(Bi, Ce)<sub>2</sub>(O, S)<sub>3-x</sub> nanorods<sup>120</sup></td><td></td><td>526.5</td><td></td><td></td></tr><tr><td>Sn<sub>2</sub>Nb<sub>2</sub>O<sub>7-x</sub>S<sub>x</sub> (up to x = 0.6)<sup>116</sup></td><td></td><td>6</td><td></td><td></td></tr><tr><td>Zn(Zn,Ni,In)<sub>2</sub>(O,S)<sub>4-x</sub><sup>119</sup></td><td></td><td>1700</td><td></td><td></td></tr></tbody></table>
# 3. Proposed design strategy for active oxychalcogenide photocatalysts

## 3.1. Key structural and electronic structure features of oxychalcogenides for photocatalysis from experimental and theoretical work

**3.1.1. Choice of anion:** Mixed-anion materials allow some tuning of the bandgap by choice of anion, particularly relevant for solar photocatalysis. For example, introducing softer anions (chalcogenides) in an oxide sublattice to give mixed-anion oxychalcogenides can introduce higher energy states at the top of the valence band, reducing the bandgap. This strategy is effective to tune the bandgap and meet the requirements of water splitting under visible light and give effective photocatalysis.<sup>126,127</sup> For example, antimony oxides such as α-Sb<sub>2</sub>O<sub>3</sub> present large bandgaps (3.38 eV),<sup>128</sup> whilst antimony chalcogenides such as Sb<sub>2</sub>S<sub>3</sub> and Sb<sub>2</sub>Se<sub>3</sub> present narrower bandgaps (2.16 and 1.66 eV for S and Se, respectively).<sup>129</sup> Therefore, a mix of both oxide and sulfide can give a moderate bandgap, e.g. Sn<sup>2+</sup>-based pyrochlore oxysulfide Sn<sub>2</sub>Nb<sub>2</sub>O<sub>7-x</sub>S<sub>x</sub><sup>116</sup> suitable for the solar spectrum such as Sr<sub>6</sub>Cd<sub>2</sub>Sb<sub>6</sub>O<sub>7</sub>S<sub>10</sub> and Sr<sub>6</sub>Cd<sub>2</sub>Sb<sub>6</sub>O<sub>7</sub>Se<sub>10</sub> (1.89 and 1.55 eV for S and Se, respectively).<sup>71,73</sup>

**3.1.2. Choice of cation:** Cation choice for photocatalysts can be a key feature. Lone pair cations for example (Bi<sup>3+</sup>, Sb<sup>3+</sup>, Sn<sup>2+</sup>) can induce oriented dipoles<sup>130</sup> which favour lower-symmetry coordination environments.<sup>131</sup> The relative energy of the *ns*<sup>2</sup> lone pair electrons to the anion *p* orbitals can determine the energy of states at the top of the valence band which are key to explaining the optical response of these materials.<sup>132,133</sup> This key feature was found to be effective in designing photocatalytic and photovoltaic materials.<sup>134,135,136</sup> Metal cations in higher oxidation states are not always compatible with the oxychalcogenide redox chemistry (there's increased risk of the metal cation oxidizing the chalcogenide).<sup>137</sup> Then again, cations with slightly localized *nf* orbitals can increase the recombination rates<sup>98</sup> and cations with the presence of *nd* orbitals or highly hybridizing *ns*-*np* orbitals can increase the dispersion of the valence and conduction bands, respectively, giving more efficient charge carrier transport.<sup>102,124</sup>

**3.1.3. Connectivity:** The impact of the connectivity of the photoactive units on the photocatalytic outcome is still under investigated but it is certain that having a layered structure is advantageous, especially for the transport properties of the photoexcited charges.<sup>138</sup> The connectivity of the different building blocks within the structure can give different pathways for the electrons and the holes which can diminish their recombination during the photocatalytic reaction. The presence of
this feature in most oxychalcogenides can promote the fast mobility which favors the charge migration to the surface of the photocatalyst to participate in the reaction, whilst slow mobility is more prone to result in charge recombination. Consequently, having distinct pathways for the mobility of charge carriers could be useful for the separation of e⁻ and h⁺, reduction of the e⁻ and h⁺ recombination rate, and improvement of the photocatalytic activity.<sup>139,140,141,142</sup> Besides this general tendency, high H₂ photocatalytic production was also demonstrated in a few non-layered oxysulfides, as discussed above, such as the spinel compound Zn(Zn,Ni,In)₂(O,S)₄-x. This might also offer structural types less encountered for oxysulfides to design photocatalysts, and their better comprehension would be also of great interest. Overall, this issue should be possible to address more accurately using specific theoretical calculations. For instance, in a recent study, the electron and hole transport properties could be investigated based on real-time time-dependent density functional theory (TDDFT) and nonadiabatic molecular dynamics (NAMD) [https://doi.org/10.1039/d3cp02860g]. Based on the excited-state dynamics, Y₂Ti₂O₅S₂ was found to exhibit a carrier lifetime much longer than that reported for lead-halide Perovskites. The authors identify a key factor underlying the high photocatalytic activity of this oxysulfide: the presence of distinct vibrational modes within different structural sublayers that contribute to non-adiabatic coupling (NAC). NAC describes how electronic transitions are influenced by atomic vibrations, and in this case, it facilitates efficient and spatially separated transport paths for electrons and holes, thereby enhancing charge separation and suppressing recombination.

**3.1.4. Stability with respect to oxidation:** Another key feature is the materials' stability in water/aqueous solution, which needs to be adequate for successful photocatalytic applications. As mentioned earlier, oxides have demonstrated good stability as photocatalysts but on the other hand, chalcogenides haven't, and can suffer from sulfide and/or cation oxidation.<sup>137</sup> Oxychalcogenides offer a moderate stability (better than the sulfide/selenides), where the introduction of the O 2p orbitals gives more stability to the system.<sup>143</sup> Future work should focus on optimizing the morphology of oxychalcogenides to enhance their stability in aqueous environments. Strategies such as nanostructuring, surface modification, and heterostructure formation could help mitigate degradation while maintaining photocatalytic efficiency. Additionally, tailoring electrolyte compositions, such as adjusting pH levels or incorporating stabilizing agents may further improve the long-term durability of these materials. These strategies will be key to overcoming degradation challenges and ensuring long-term photocatalytic performance.<sup>144</sup>
**3.1.5. Polarity:** Lastly, polarity in heterogeneous photocatalysts has been shown to enhance charge-carrier separation, resulting in superior efficiency for example for photocatalytic water splitting.<sup>145</sup> Having polar distortions can also increase the bandgaps, although this increase is minimal in the case of oxides (SrTiO<sub>3</sub> for example<sup>146</sup>), it is much larger in the case of oxysulfides, and because of the lower electronegativity of the sulfide.<sup>147</sup> This hypothesis was further investigated by Vonruti and Aschauer<sup>148</sup> using DFT to study the suitability of polar AB(O<sub>x</sub>S<sub>1-x</sub>)<sub>3</sub> perovskites for photocatalytic water splitting. It was found that the presence of polar distortions, induced by epitaxial strain (for oxynitrides<sup>149</sup>) or substitution of sulfur by oxygen (for oxysulfides) can be a promising route to suppress the recombination phenomena of the charge carriers. This is due to the out-of-plane spontaneous polarization arising from epitaxial strain on the anion order within the structure, which creates an electric field gradient across the active cation or even the entire material. This field is thought to enhance electron-hole separation, reducing recombination and thereby improving photocatalytic efficiency. It is important to distinguish between the polarity of the overall crystal structure and the local polarity of the cation coordination environments. While global polar distortions can give rise to a macroscopic electric field that enhances charge separation, local polarity in heteroleptic coordination environments (where a cation is coordinated by two types of anions) may also play a crucial role. Such local distortions can modify the electronic structure at the active site, further improving charge separation and transport. In particular, materials with heteroleptic units, which are often intrinsically polar, may exhibit enhanced electron-hole separation, which is crucial for improved photocatalytic activity<sup>148</sup>

**3.2. Design strategy for oxychalcogenide photocatalysts**

Based on the key features in oxychalcogenide photocatalysts discussed in the previous section, we will therefore propose a potential design strategy that could be useful as a useful tool for designing new efficient oxychalcogenide materials for photocatalysis specifically, solar water splitting photocatalysis. A schematic diagram of a potential design strategy for efficient oxychalcogenide materials is presented in Figure 9.

First, the nature of the bandgap (direct or indirect), the semiconduction type (n or p-type) are not of great influence on the properties of the photocatalysts as both types were exhibited by the materials, we discussed in section 2.2. However, ensuring that the oxychalcogenide has a band gap well-matched in magnitude to the solar spectrum is essential. This can be achieved by selecting a
softer chalcogenide anion $Q^{2-}$ and by tuning the O:Q ratio. Additionally, incorporating chalcogenides can increase bandgaps due to enhanced covalency, resulting from their lower electronegativity compared to oxygen.¹⁴⁷

The structure and its connectivity are important for the transport properties of the photoexcited charges. Different pathways for the electrons and the holes help reduce the probability of recombination and this is often observed for layered or segmented structures. The band structure gives insight to the electronic properties of the material, in particular the effective masses of the charge carriers which describes their mobilities: higher dispersion of the bands close to the Fermi level indicate lower effective masses and hence higher carrier mobility and therefore enhanced transfer process. Recently, Li et al.¹⁵⁰ reported that the recombination of photogenerated electrons and holes can be much faster than the transport from bulk to the surface reactive site and the catalytic reaction. Thus, fast mobility favors the charge migration to the surface of the photocatalyst to participate in the reaction, whilst slow mobility is more prone to result in charge recombination. Therefore, having a large mobility difference could be useful for the separation of $e^-$ and $h^+$, reduction of the $e^-$ and $h^+$ recombination rate, and improvement of the photocatalytic activity.

Cation choice is another important feature due to the contributions of their corresponding orbitals to the band edges; this can therefore tune the band gap as well as the charge carriers' transport properties. Lastly, the polarity, is not widely studied as a design feature in photocatalysis, but it could enhance a catalyst's performance by improving charge carrier separation, as seen in ferroelectrics such as $AB(O_xS_{1-x})_3$¹⁴⁸ and $LaTiO_2N$.¹⁴⁹ In this study they demonstrated, via density functional theory calculations, the potential of suppressing the recombination phenomena of the charge carriers due to the out-of-plane spontaneous polarization that has risen from the epitaxial strain on the anion order within the structure. Experimental studies on $Sr_6Cd_2Sb_6O_7S_{10}$¹⁴⁴ and $Sr_2Sb_2O_2Q_3$ ($Q$ = S, Se)¹⁵¹ provide a direct comparison of polar vs. non-polar structures and different coordination environments for the same cation, supporting this theoretical proposal. $Sr_6Cd_2Sb_6O_7S_{10}$, with its polar structure and zigzag [CdSb₂OS₅] layers, exhibits built-in polarization fields that enhance charge separation and suppress recombination, as confirmed by its strong photocurrent response. In contrast, $Sr_2Sb_2O_2Q_3$, despite its layered but non-centrosymmetric structure, lacks significant internal polarization and relies solely on heteroleptic $SbOQ_4$ coordination, leading to high charge mobility but weaker polarization-driven separation.
Thus, the presence of polar distortions, can indeed be a promising route to adopt for increasing the band gap and design new materials with efficient photocatalytic properties.

In this review, we have focused on structural and electronic features which may determine the water-splitting photocatalytic properties of active oxychalcogenides. However, for some of the oxysulfides discussed there are several further studies with drastic enhancement of the H₂ production based on different strategies to those mentioned above including optimization of surface morphology (some of which is covered in specific reviews dealing with the photocatalytic measurement design and optimization of the photocatalysts/co-catalysts). The example of Gd₂Ti₂S₂O₅ or Y₂Ti₂S₂O₅ for instance, where the particle size and shape and the surface engineering allow drastic enhancement of H₂ release, are very informative.⁸⁷,⁹⁰ The role of defects can also vary by being either counter-productive or helpful such as defect-(Bi, Ce)₂(O, S)₃-x nanorods¹²⁰ where the multi-valence states and the surface defects facilitate the kinetic reactions, here the defects are controlled and induced during the synthetic process by reduction using hydrazine to incorporate oxygen vacancies. Therefore, beyond intrinsic properties, there is the synthesis design, the cocatalysts type and their interaction with the photocatalyst which play also a crucial role and should be fully considered when designing a photocatalyst. Depending on how the later aspects are handled, the activity might be hampered or improved.

It is also interesting to consider the potential of hybrid compounds explicitly combining (oxy)chalcogenides with organic components which are extremely limited. There are a few instructive examples involving chalcogen elements in hybrid systems. For instance, metal-organic chalcogenide semiconductors nanocrystals [https://doi.org/10.1021/acs.chemmater.3c02275] have demonstrated the feasibility of incorporating soft chalcogen ligands into hybrid materials. The later study describes metal-chalcogenide layers stacked with organic ligand layers, both layers can be altered to tune the properties. Another example includes a cystamine-based hybrid perovskite, where noncovalent chalcogen bonding involving the cystamine disulfide bridges, influences the structure and properties [https://doi.org/10.1002/ejic.201301017]. These studies show that combining soft chalcogen chemistry with organic-inorganic frameworks is chemically viable and could inspire future exploration in oxychalcogenide-based hybrids that may be useful in the photocatalytic field.
A broader overview of these approaches is presented in a review about the current status and future
of organic-inorganic hybrid perovskites for photoelectrocatalysis devices
[https://doi.org/10.1021/acs.energyfuels.3c02680], which discusses both hybrid molecular systems
and composite architectures used in water-splitting. It highlights how the integration of organic
macromolecules (such as oligomers, polymers, or MOFs) with inorganic frameworks can provide
synergistic benefits, including improved photocatalytic activity, enhanced stability, and interfacial
tunability. On another hand, it is interesting to consider the design of hybrid (composite)
photocatalysts that integrate oxychalcogenides with additional materials to form heterostructures
or tandem systems. These systems can enhance light absorption, extend charge carrier lifetimes, or
spatially separate redox reactions. For example, recent studies report hybrid nanostructures of PBA
(Prussian blue analogues) nanocubes wrapped with transition-metal oxysulfides and all together
grafted on CC (Carbon cloth) substrate (PBA@Co-W-O-S/CC heterostructure), as efficient OER
electrocatalysts [https://doi.org/10.1002/ijch.202100110]. Besides, the dye modified Bi<sub>2</sub>O<sub>2</sub>S/In<sub>2</sub>O<sub>3</sub>
showed promise for the catalysis of water splitting thanks to the formation of a heterojunction
between the oxide-chalcogenide and In<sub>2</sub>O<sub>3</sub> [https://doi.org/10.1016/j.jphotochem.2013.12.007].
Although such strategies are promising, our review deliberately focuses on single-phase
oxychalcogenide materials, aiming to clarify intrinsic structure-composition-property relationships
without convolution from multicomponent effects. Nonetheless, we now briefly acknowledge these
composite designs as a complementary future strategy for improving photocatalytic performance.
Lastly, it is interesting to mention theoretical prediction of a fully inorganic, single-phase
oxychalcogenides as a good alternative to hybrids and oxides in photovoltaics with an enhanced
shift current. The authors put forward this strategy to reinforce the idea that simplifying material
systems, rather than increasing complexity, can also be a viable and appealing route when structural
and electronic requirements are met. [https://doi.org/10.1021/acs.jpcc.2c01848]
<figure><img src="image_13.png" /><figcaption>**Figure 11** : Schematic diagram of a potential design strategy for oxysulfide photocatalysts.</figcaption></figure>

4. CONCLUSION

In this review, we discussed the concept of photocatalytic water splitting alongside the
necessary requirements for a successful reaction in the solar light with a specific focus on layered
oxychalcogenides (oxysulfides and oxyselenides). We discussed several oxysulfide materials that are known for their capacity to split water, comparing their different structures and connectivities, band gaps (direct or indirect), semiconduction types (n or p-type), polarity as well as their photocatalytic activity (O₂ and/or H₂ evolution, solar or UV irradiation). This allowed us to extract some key features that can be beneficial for designing new photocatalysts and to propose a potential design strategy for photocatalytic oxychalcogenides consisting on several key points which are exploring the polarity, anion ratio, cation choice (transition metals, lone pairs cations) and connectivity regarding what was reported in the literature; and further work is needed for polarity as well as morphology.

## ASSOCIATED CONTENT

**Supporting Information.** The supporting Information is available free of charge.

Comparison tables of the structural and physical properties of oxysulfide, oxyselenide and oxytelluride materials. Estimated band edge positions using the empirical method of different oxychalcogenides.

## ACKNOWLEDGMENTS

I-Site (ULNE), University of Lille and University of Kent are thanked for cotutelle funding (S. Al Bacha). Durham University is thanked for hosting research visit. Dr. Donna Arnold is thanked for helpful discussions. This study was supported by the French government through the Programme Investissement d'Avenir (I-SITE ULNE / ANR-16-IDEX-0004 ULNE) managed by the Agence Nationale de la Recherche (Project ANION-COMBO).

## REFERENCES

(1) Nzihou, A.; Flamant, G.; Stanmore, B. Synthetic Fuels from Biomass Using Concentrated Solar Energy-a Review. *Energy* **2012**, *42* (1), 121–131.
(2) Yang, Y.; Zhao, R.; Zhang, T.; Zhao, K.; Xiao, P.; Ma, Y.; Ajayan, P. M.; Shi, G.; Chen, Y. Graphene-Based Standalone Solar Energy Converter for Water Desalination and Purification. ACS nano 2018, 12 (1), 829-835.

(3) Mekhilef, S.; Saidur, R.; Safari, A. A Review on Solar Energy Use in Industries. Renewable and sustainable energy reviews 2011, 15 (4), 1777-1790.

(4) Martinez, B.; Roig, A.; Obradors, X.; Molins, E.; Rouanet, A.; Monty, C. Magnetic Properties of γ-Fe2O3 Nanoparticles Obtained by Vaporization Condensation in a Solar Furnace. Journal of applied physics 1996, 79 (5), 2580-2586.

(5) Qi, J.; Zhang, W.; Cao, R. Solar-to-hydrogen Energy Conversion Based on Water Splitting. Advanced Energy Materials 2018, 8 (5), 1701620.

(6) Zhang, P.; Lou, X. W. Design of Heterostructured Hollow Photocatalysts for Solar-to-chemical Energy Conversion. Advanced Materials 2019, 31 (29), 1900281.

(7) Shiyani, T.; Agrawal, S.; Banerjee, I. Natural-Dye-Sensitized Photoelectrochemical Cells for Solar Energy Conversion. Nanomaterials and Energy 2020, 9 (2), 215-226.

(8) Goodeve, C. F.; Kitchener, J. A. Photosensitisation by Titanium Dioxide. Transactions of the Faraday Society 1938, 34, 570-579.

(9) Hashimoto, K.; Irie, H.; Fujishima, A. TiO2 Photocatalysis: A Historical Overview and Future Prospects. Japanese journal of applied physics 2005, 44 (12R), 8269.

(10) Fujishima, A.; Honda, K. Electrochemical Photolysis of Water at a Semiconductor Electrode. nature 1972, 238 (5358), 37-38.

(11) Fujishima, A.; Rao, T. N.; Tryk, D. A. Titanium Dioxide Photocatalysis. Journal of photochemistry and photobiology C: Photochemistry reviews 2000, 1 (1), 1-21.

(12) Fujishima, A.; Zhang, X.; Tryk, D. A. TiO2 Photocatalysis and Related Surface Phenomena. Surface science reports 2008, 63 (12), 515-582.

(13) Hashimoto, K.; Irie, H.; Fujishima, A. TiO2 Photocatalysis: A Historical Overview and Future Prospects. Japanese journal of applied physics 2005, 44 (12R), 8269.

(14) LEROY, S. Etude Des Propriétés Photocatalytiques et Photoélectriques Du Dititanate de Lanthane (La2Ti2O7) à Structure Pérovskite En Feuillets et Son Utilisation Dans Des Hétérojonctions Tout Oxyde Pour La Conversion d'énergie.

(15) Jafari, T.; Moharreri, E.; Amin, A. S.; Miao, R.; Song, W.; Suib, S. L. Photocatalytic Water Splitting—the Untamed Dream: A Review of Recent Advances. Molecules 2016, 21 (7), 900.

(16) Liang, Z.; Yan, C.-F.; Rtimi, S.; Bandara, J. Piezoelectric Materials for Catalytic/Photocatalytic Removal of Pollutants: Recent Advances and Outlook. Applied Catalysis B: Environmental 2019, 241, 256-269.

(17) Wang, M.; Wang, B.; Huang, F.; Lin, Z. Enabling PIEZOpotential in PIEZOElectric Semiconductors for Enhanced Catalytic Activities. Angew Chem Int Ed 2019, 58 (23), 7526-7536. https://doi.org/10.1002/anie.201811709.

(18) Chen, F.; Huang, H.; Guo, L.; Zhang, Y.; Ma, T. The Role of Polarization in Photocatalysis. Angewandte Chemie International Edition 2019, 58 (30), 10061-10073.

(19) Wachsman, E. D.; Lee, K. T. Lowering the Temperature of Solid Oxide Fuel Cells. Science 2011, 334 (6058), 935-939. https://doi.org/10.1126/science.1204090.

(20) Staykov, A.; Lyth, S. M.; Watanabe, M. Photocatalytic Water Splitting. In Hydrogen Energy Engineering; Springer, 2016; pp 159-174.

(21) Kong, D.; Zheng, Y.; Kobielusz, M.; Wang, Y.; Bai, Z.; Macyk, W.; Wang, X.; Tang, J. Recent Advances in Visible Light-Driven Water Oxidation and Reduction in Suspension Systems. Materials Today 2018, 21 (8), 897-924.

(22) Luan, Y.; Li, Y.; Li, Z.; Zhang, B. Y.; Ou, J. Z. Layered Anion-Mixed Oxycompounds: Synthesis, Properties, and Applications. Advanced Science n/a (n/a), 2500477. https://doi.org/10.1002/advs.202500477.
(23) Li, M.; Wang, N.; Zhang, S.; Hu, J.; Xiao, H.; Gong, H.; Liu, Z.; Qiao, L.; Zu, X. A Review of the Properties, Synthesis and Applications of Lanthanum Copper Oxychalcogenides. *J. Phys. D: Appl. Phys.* **2022**, *55* (27), 273002. https://doi.org/10.1088/1361-6463/ac4b71.

(24) Clarke, S. J.; Adamson, P.; Herkelrath, S. J.; Rutt, O. J.; Parker, D. R.; Pitcher, M. J.; Smura, C. F. Structures, Physical Properties, and Chemistry of Layered Oxychalcogenides and Oxypnictides. *Inorganic chemistry* **2008**, *47* (19), 8473–8486.

(25) Kobayashi, Y.; Hernandez, O.; Tassel, C.; Kageyama, H. New Chemistry of Transition Metal Oxyhydrides. *Science and Technology of advanced Materials* **2017**, *18* (1), 905–918.

(26) Wang, L.; Wang, L.; Du, Y.; Xu, X.; Dou, S. X. Progress and Perspectives of Bismuth Oxyhalides in Catalytic Applications. *Materials Today Physics* **2021**, *16*, 100294.

(27) Nakada, A.; Kato, D.; Nelson, R.; Takahira, H.; Yabuuchi, M.; Higashi, M.; Suzuki, H.; Kirsanova, M.; Kakudou, N.; Tassel, C. Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis. *Journal of the American Chemical Society* **2021**, *143* (6), 2491–2499.

(28) Li, Y.; Jiang, H.; Wang, X.; Hong, X.; Liang, B. Recent Advances in Bismuth Oxyhalide Photocatalysts for Degradation of Organic Pollutants in Wastewater. *RSC advances* **2021**, *11* (43), 26855–26875.

(29) Cho, E. J.; Oh, S.-J.; Jo, H.; Lee, J.; You, T.-S.; Ok, K. M. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties. *Inorganic chemistry* **2019**, *58* (3), 2183–2190.

(30) Kobayashi, Y.; Tang, Y.; Kageyama, T.; Yamashita, H.; Masuda, N.; Hosokawa, S.; Kageyama, H. Titanium-Based Hydrides as Heterogeneous Catalysts for Ammonia Synthesis. *Journal of the American Chemical Society* **2017**, *139* (50), 18240–18246.

(31) Ai-Mamouri, M.; Edwards, P. P.; Greaves, C.; Slaski, M. Synthesis and Superconducting Properties of the Strontium Copper Oxy-Fluoride Sr2CuO2F2+ δ. *Nature* **1994**, *369* (6479), 382–384.

(32) Kamihara, Y.; Hiramatsu, H.; Hirano, M.; Kawamura, R.; Yanagi, H.; Kamiya, T.; Hosono, H. Iron-Based Layered Superconductor: LaOFeP. *Journal of the American Chemical Society* **2006**, *128* (31), 10012–10013.

(33) Kamihara, Y.; Watanabe, T.; Hirano, M.; Hosono, H. Iron-Based Layered Superconductor La [O1-x F x] FeAs (X= 0.05–0.12) with T C= 26 K. *Journal of the American Chemical Society* **2008**, *130* (11), 3296–3297.

(34) Oogarah, R. K.; Suard, E.; McCabe, E. E. Magnetic Order and Phase Transition in the Iron Oxysulfide La2O2Fe2OS2. *Journal of Magnetism and Magnetic Materials* **2018**, *446*, 101–107.

(35) Okada, S.; Matoba, M.; Fukumoto, S.; Soyano, S.; Kamihara, Y.; Takeuchi, T.; Yoshida, H.; Ohoyama, K.; Yamaguchi, Y. Magnetic Properties of Layered Oxysulfide Sr 2 Cu 2 (Co, Cu) O 2 S 2 with Cu-Doped CoO 2 Square Planes. *Journal of applied physics* **2002**, *91* (10), 8861–8863.

(36) Ryan, F. M.; Pugh, E. W.; Smoluchowski, R. Superparamagnetism, Nonrandomness, and Irradiation Effects in Cu-Ni Alloys. *Physical Review* **1959**, *116* (5), 1106.

(37) Li, Y.-Y.; Wang, W.-J.; Wang, H.; Lin, H.; Wu, L.-M. Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials. *Crystal Growth & Design* **2019**, *19* (7), 4172–4192.

(38) Sauvage, F.; Bodenez, V.; Vezin, H.; Albrecht, T. A.; Tarascon, J.-M.; Poeppelmeier, K. R. Ag4V2O6F2 (SVOF): A High Silver Density Phase and Potential New Cathode Material for Implantable Cardioverter Defibrillators. *Inorganic chemistry* **2008**, *47* (19), 8464–8472.

(39) Li, J.; Zhai, W.; Zhang, C.; Yan, Y.; Liu, P.-F.; Yang, G. Anharmonicity and Ultralow Thermal Conductivity in Layered Oxychalcogenides BiAgOCh (Ch= S, Se, and Te). *Materials Advances* **2021**, *2* (14), 4876–4882.

(40) Hirosaki, N.; Xie, R.-J.; Kimoto, K.; Sekiguchi, T.; Yamamoto, Y.; Suehiro, T.; Mitomo, M. Characterization and Properties of Green-Emitting β-SiAlON: Eu 2+ Powder Phosphors for White Light-Emitting Diodes. *Applied Physics Letters* **2005**, *86* (21), 211905.
(41) Kageyama, H.; Hayashi, K.; Maeda, K.; Attfield, J. P.; Hiroi, Z.; Rondinelli, J. M.; Poeppelmeier, K. R. Expanding Frontiers in Materials Chemistry and Physics with Multiple Anions. *Nature communications* **2018**, *9* (1), 1–15.

(42) Attfield, J. P. Principles and Applications of Anion Order in Solid Oxynitrides. *Crystal growth & design* **2013**, *13* (10), 4623–4629.

(43) G. Shi, Y.; Yu, S.; A. Belik, A.; Matsushita, Y.; Tanaka, M.; Katsuya, Y.; Kobayashi, K.; Yamaura, K.; Takayama-Muromachi, E. Synthesis and Superconducting Properties of the Iron Oxyarsenide TbFeAsO. 85. *Journal of the Physical Society of Japan* **2008**, *77* (Suppl. C), 155–157.

(44) Chong, S. V.; Mochiji, T.; Kadowaki, K. Superconductivity in Yttrium Iron Oxyarsenide System. In *Journal of Physics: Conference Series*; IOP Publishing, 2009; Vol. 150, p 052036.

(45) Orr, M.; Hebberd, G. R.; McCabe, E. E.; Macaluso, R. T. Structural Diversity of Rare-Earth Oxychalcogenides. *ACS Omega* **2022**.

(46) Luu, S. D.; Vaqueiro, P. Layered Oxychalcogenides: Structural Chemistry and Thermoelectric Properties. *Journal of Materiomics* **2016**, *2* (2), 131–140.

(47) Shi, Y.-F.; Wei, W.-B.; Wu, X.-T.; Lin, H.; Zhu, Q.-L. Recent Progress in Oxychalcogenides as IR Nonlinear Optical Materials. *Dalton Transactions* **2021**, *50* (12), 4112–4118.

(48) Parida, A.; Senapati, S.; Naik, R. Recent Developments on Bi-Based Oxychalcogenide Materials with Thermoelectric and Optoelectronic Applications: An Overview. *Materials Today Chemistry* **2022**, *26*, 101149.

(49) Maeda, K.; Domen, K. New Non-Oxide Photocatalysts Designed for Overall Water Splitting under Visible Light. *J. Phys. Chem. C* **2007**, *111* (22), 7851–7861. https://doi.org/10.1021/jp070911w.

(50) Takata, T.; Domen, K. Development of Non-Oxide Semiconductors as Light Harvesting Materials in Photocatalytic and Photoelectrochemical Water Splitting. *Dalton transactions* **2017**, *46* (32), 10529–10544.

(51) Miyoshi, A.; Maeda, K. Recent Progress in Mixed-Anion Materials for Solar Fuel Production. *Solar RRL* **2021**, *5* (6), 2000521.

(52) Chatterjee, K.; Skrabalak, S. E. Durable Metal Heteroanionic Photocatalysts. *ACS Appl. Mater. Interfaces* **2021**, *13* (31), 36670–36678. https://doi.org/10.1021/acsmi.1c09774.

(53) Subramanian, Y.; Dhanasekaran, A.; Omeiza, L. A.; Somalu, M. R.; Azad, A. K. A Review on Heteroanionic-Based Materials for Photocatalysis Applications. *Catalysts* **2023**, *13* (1), 173.

(54) Salter, E. J.; Blandy, J. N.; Clarke, S. J. Crystal and Magnetic Structures of the Oxide Sulfides CaCoSO and BaCoSO. *Inorganic Chemistry* **2016**, *55* (4), 1697–1701.

(55) Shah, K.; Ćirić, A.; Murthy, K. V. R.; Chakrabarty, B. S. Investigation of a New Way of Synthesis for Nano Crystallites of La2O2S & 1% Ln3+ (Ln= Pr, Eu, Tb, Dy, Er) Doped La2O2S and Study Their Structural and Optical Properties. *Journal of Alloys and Compounds* **2021**, *851*, 156725.

(56) Strobel, S.; Choudhury, A.; Dorhout, P. K.; Lipp, C.; Schleid, T. Rare-Earth Metal (III) Oxide Selenides M4O4Se [Se2](M= La, Ce, Pr, Nd, Sm) with Discrete Diselenide Units: Crystal Structures, Magnetic Frustration, and Other Properties. *Inorganic chemistry* **2008**, *47* (11), 4936–4944.

(57) Johnson, V.; Jeitschko, W. ZrCuSiAs: A “Filled” PbFCl Type. *Journal of Solid State Chemistry* **1974**, *11* (2), 161–166.

(58) Phelan, W. A.; Wallace, D. C.; Arpino, K. E.; Neilson, J. R.; Livi, K. J.; Seabourne, C. R.; Scott, A. J.; McQueen, T. M. Stacking Variants and Superconductivity in the Bi–O–S System. *Journal of the American Chemical Society* **2013**, *135* (14), 5372–5374.

(59) Ueda, K.; Hiramatsu, H.; Hirano, M.; Kamiya, T.; Hosono, H. Wide-Gap Layered Oxychalcogenide Semiconductors: Materials, Electronic Structures and Optoelectronic Properties. *Thin Solid Films* **2006**, *496* (1), 8–15.

(60) Palazzi, M.; Carcaly, C.; Laruelle, P.; Flahaut, J. Crystal Structure and Properties of (LaO) CuS and (LaO) AgS. In *The Rare Earths in Modern Science and Technology*; Springer, 1982; pp 347–350.
(61)Zhao, L.-D.; He, J.; Berardan, D.; Lin, Y.; Li, J.-F.; Nan, C.-W.; Dragoe, N. BiCuSeO Oxyselenides: New Promising Thermoelectric Materials. *Energy & Environmental Science* **2014**, *7* (9), 2900–2924.

(62)Zhu, J.-X.; Yu, R.; Wang, H.; Zhao, L. L.; Jones, M. D.; Dai, J.; Abrahams, E.; Morosan, E.; Fang, M.; Si, Q. Band Narrowing and Mott Localization in Iron Oxychalcogenides
${\mathrm{La}}_{2}{\mathbf{O}}_{2}\{{\mathbf{La}}_{2}{\mathbf{O}}_{2}\{{\mathbf{Fe}}_{2}{\mathbf{O}}_{2}\}\{{\mathbf{Se}}_{2}\}$.
*Phys. Rev. Lett.* **2010**, *104* (21), 216405. https://doi.org/10.1103/PhysRevLett.104.216405.

(63) Lü, M.; Mentré, O.; Gordon, E. E.; Whangbo, M.-H.; Wattiaux, A.; Duttine, M.; Tiercelin, N.; Kabbour, H. A Comprehensive Study of Magnetic Exchanges in the Layered Oxychalcogenides Sr3Fe2O5Cu2O2 (Q=S, Se). *Journal of Magnetism and Magnetic Materials* **2017**, *444*, 147–153.
https://doi.org/10.1016/j.jmmm.2017.07.026.

(64) McCabe, E. E.; Free, D. G.; Mendis, B. G.; Higgins, J. S.; Evans, J. S. Preparation, Characterization, and Structural Phase Transitions in a New Family of Semiconducting Transition Metal Oxychalcogenides β-La2O2 M Se2 (M= Mn, Fe). *Chemistry of Materials* **2010**, *22* (22), 6171–6182.

(65) Gál, Z. A.; Rutt, O. J.; Smura, C. F.; Overton, T. P.; Barrier, N.; Clarke, S. J.; Hadermann, J. Structural Chemistry and Metamagnetism of an Homologous Series of Layered Manganese Oxysulfides. *Journal of the American Chemical Society* **2006**, *128* (26), 8530–8540.

(66) Reshak, A. H. CaCoSO Diluted Magnetic Antiferromagnet Semiconductor as Efficient Thermoelectric Materials. *Materials Research Bulletin* **2017**, *94*, 22–30.

(67) Shi, Y.-F.; Wei, W.-B.; Wu, X.-T.; Lin, H.; Zhu, Q.-L. Recent Progress in Oxychalcogenides as IR Nonlinear Optical Materials. *Dalton Transactions* **2021**, *50* (12), 4112–4118.

(68) Liu, B.-W.; Jiang, X.-M.; Wang, G.-E.; Zeng, H.-Y.; Zhang, M.-J.; Li, S.-F.; Guo, W.-H.; Guo, G.-C. Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response. *Chemistry of Materials* **2015**, *27* (24), 8189–8192.

(69) Xing, W.; Fang, P.; Wang, N.; Li, Z.; Lin, Z.; Yao, J.; Yin, W.; Kang, B. Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence. *Inorganic Chemistry* **2020**, *59* (22), 16716–16724.

(70) Liu, B.-W.; Jiang, X.-M.; Wang, G.-E.; Zeng, H.-Y.; Zhang, M.-J.; Li, S.-F.; Guo, W.-H.; Guo, G.-C. Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response. *Chemistry of Materials* **2015**, *27* (24), 8189–8192.

(71) Wang, R.; Liang, F.; Wang, F.; Guo, Y.; Zhang, X.; Xiao, Y.; Bu, K.; Lin, Z.; Yao, J.; Zhai, T. Sr6Cd2Sb6O7S10: Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups. *Angewandte Chemie International Edition* **2019**, *58* (24), 8078–8081.

(72) Wang, Y.; Luo, M.; Zhao, P.; Che, X.; Cao, Y.; Huang, F. Sr 4 Pb 1.5 Sb 5 O 5 Se 8: A New Mid-Infrared Nonlinear Optical Material with a Moderate SHG Response. *CrystEngComm* **2020**, *22* (20), 3526–3530.

(73) Wang, R.; Wang, F.; Zhang, X.; Feng, X.; Zhao, C.; Bu, K.; Zhang, Z.; Zhai, T.; Huang, F. Improved Polarization in the Sr6Cd2Sb6O7Se10 Oxyselenide through Design of Lateral Sublattices for Efficient Photoelectric Conversion. *Angewandte Chemie* **2022**.

(74) Zhu, W. J.; Hor, P. H. Unusual Layered Transition-Metal Oxysulfides: Sr2Cu2MO2S2 (M= Mn, Zn). *Journal of Solid State Chemistry* **1997**, *130* (2), 319–321.

(75) Zhu, W. J.; Hor, P. H. Sr2CuGaO3S, a Rare Example of Square Pyramidal Gallium. *Inorganic chemistry* **1997**, *36* (17), 3576–3577.

(76) Guittard, M.; Benazeth, S.; Dugue, J.; Jaulmes, S.; Palazzi, M.; Laruelle, P.; Flahaut, J. Oxysulfides and Oxyselenides in Sheets, Formed by a Rare Earth Element and a Second Metal. *Journal of Solid State Chemistry* **1984**, *51* (2), 227–238.

(77) Sambrook, T.; Smura, C. F.; Clarke, S. J.; Ok, K. M.; Halasyamani, P. S. Structure and Physical Properties of the Polar Oxysulfide CaZnOS. *Inorganic chemistry* **2007**, *46* (7), 2571–2574.
(78) Boyer, C.; Deudon, C.; Meerschaut, A. Synthesis and Structure Determination of the New Sm2Ti2O5S2 Compound. *Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry* **1999**, *2* (2), 93-99. https://doi.org/10.1016/S1387-1609(99)80007-3.

(79) Goga, M.; Seshadri, R.; Ksenofontov, V.; Gütlich, P.; Tremel, W. Ln 2 Ti 2 S 2 O 5 (Ln= Nd, Pr, Sm): A Novel Series of Defective Ruddlesden-Popper Phases. *Chemical Communications* **1999**, No. 11, 979-980.

(80) Boyer-Candalen, C.; Derouet, J.; Porcher, P.; Moëlo, Y.; Meerschaut, A. The Family of Ln2Ti2S2O5 Compounds (Ln= Nd, Sm, Gd, Tb, Dy, Ho, Er, and Y): Optical Properties. *Journal of Solid State Chemistry* **2002**, *165* (2), 228-237.

(81) Ishikawa, A.; Takata, T.; Matsumura, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K. Oxysulfides Ln2Ti2S2O5 as Stable Photocatalysts for Water Oxidation and Reduction under Visible-Light Irradiation. *The Journal of Physical Chemistry B* **2004**, *108* (8), 2637-2642.

(82) Ishikawa, A.; Takata, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K. Oxysulfide Sm2Ti2S2O5 as a Stable Photocatalyst for Water Oxidation and Reduction under Visible Light Irradiation (Λ≤ 650 Nm). *Journal of the American Chemical Society* **2002**, *124* (45), 13547-13553.

(83) Ishikawa, A.; Yamada, Y.; Takata, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K. Novel Synthesis and Photocatalytic Activity of Oxysulfide Sm2Ti2S2O5. *Chemistry of materials* **2003**, *15* (23), 4442-4446.

(84) Zhang, J.; Liu, K.; Zhang, B.; Zhang, J.; Liu, M.; Xu, Y.; Shi, K.; Wang, H.; Zhang, Z.; Zhou, P.; Ma, G. Anisotropic Charge Migration on Perovskite Oxysulfide for Boosting Photocatalytic Overall Water Splitting. *J. Am. Chem. Soc.* **2024**, *146* (6), 4068-4077. https://doi.org/10.1021/jacs.3c12417.

(85) Denis, S. G.; Clarke, S. J. Two Alternative Products from the Intercalation of Alkali Metals into Cation-Defective Ruddlesden-Popper Oxysulfides. *Chemical Communications* **2001**, No. 22, 2356-2357.

(86) Hyett, G.; Rutt, O. J.; Gál, Z. A.; Denis, S. G.; Hayward, M. A.; Clarke, S. J. Electronically Driven Structural Distortions in Lithium Intercalates of the N= 2 Ruddlesden-Popper-Type Host Y2Ti2O5S2: Synthesis, Structure, and Properties of Li x Y2Ti2O5S2 (0< x< 2). *Journal of the American Chemical Society* **2004**, *126* (7), 1980-1991.

(87) Wang, Q.; Nakabayashi, M.; Hisatomi, T.; Sun, S.; Akiyama, S.; Wang, Z.; Pan, Z.; Xiao, X.; Watanabe, T.; Yamada, T. Oxysulfide Photocatalyst for Visible-Light-Driven Overall Water Splitting. *Nature materials* **2019**, *18* (8), 827-832.

(88) Yoshida, H.; Pan, Z.; Shoji, R.; Nandal, V.; Matsuzaki, H.; Seki, K.; Hisatomi, T.; Domen, K. Heterogeneous Doping of Visible-Light-Responsive Y2Ti2O5S2 for Enhanced Hydrogen Evolution. *J. Mater. Chem. A* **2022**, *10* (46), 24552-24560. https://doi.org/10.1039/D2TA06895H.

(89) Lin, L.; Nakabayashi, M.; Lu, D.; Hisatomi, T.; Takata, T.; Domen, K. Formation Mechanism for Particulate Y2Ti2O5S2 Photocatalyst by the Solid-State Reaction. *Chem. Mater.* **2024**, *36* (3), 1612-1620. https://doi.org/10.1021/acs.chemmater.3c02929.

(90) Yoshida, H.; Pan, Z.; Shoji, R.; Nandal, V.; Matsuzaki, H.; Seki, K.; Lin, L.; Kaneko, M.; Fukui, T.; Yamashita, K.; Takata, T.; Hisatomi, T.; Domen, K. An Oxysulfide Photocatalyst Evolving Hydrogen with an Apparent Quantum Efficiency of 30 % under Visible Light. *Angewandte Chemie* **2023**, *135* (46), e202312938. https://doi.org/10.1002/ange.202312938.

(91) Yoshida, H.; Pan, Z.; Shoji, R.; Nandal, V.; Matsuzaki, H.; Seki, K.; Lin, L.; Kaneko, M.; Fukui, T.; Yamashita, K.; Takata, T.; Hisatomi, T.; Domen, K. An Oxysulfide Photocatalyst Evolving Hydrogen with an Apparent Quantum Efficiency of 30 % under Visible Light. *Angewandte Chemie* **2023**, *135* (46), e202312938. https://doi.org/10.1002/ange.202312938.

(92) Tsujimoto, Y.; Juillerat, C. A.; Zhang, W.; Fujii, K.; Yashima, M.; Halasyamani, P. S.; zur Loye, H.-C. Function of Tetrahedral ZnS3O Building Blocks in the Formation of SrZn2S2O: A Phase Matchable Polar Oxysulfide with a Large Second Harmonic Generation Response. *Chemistry of Materials* **2018**, *30* (18), 6486-6493.
(93) Reshak, A. H. Sulfide Oxide XZnSO (X= Ca or Sr) as Novel Active Photocatalytic Water Splitting Solar-to-Hydrogen Energy Conversion. *Applied Catalysis B: Environmental* **2018**, *225*, 273-283.

(94) Nishioka, S.; Kanazawa, T.; Shibata, K.; Tsujimoto, Y.; Zur Loye, H.-C.; Maeda, K. A Zinc-Based Oxysulfide Photocatalyst SrZn 2 S 2 O Capable of Reducing and Oxidizing Water. *Dalton Transactions* **2019**, *48* (42), 15778-15781.

(95) Kabbour, H.; Cario, L.; Moëlo, Y.; Meerschaut, A. Synthesis, X-Ray and Optical Characterizations of Two New Oxysulfides: LaInS2O and La5In3S9O3. *Journal of Solid State Chemistry* **2004**, *177* (4-5), 1053-1059.

(96) Kabbour, H.; Sayede, A.; Saitzek, S.; Lefevre, G.; Cario, L.; Trentesaux, M.; Roussel, P. Structure of the Water-Splitting Photocatalyst Oxysulfide α-LaOInS 2 and Ab Initio Prediction of New Polymorphs. *Chemical Communications* **2020**, *56* (11), 1645-1648.

(97) Miura, A.; Oshima, T.; Maeda, K.; Mizuguchi, Y.; Moriyoshi, C.; Kuroiwa, Y.; Meng, Y.; Wen, X.-D.; Nagao, M.; Higuchi, M. Synthesis, Structure and Photocatalytic Activity of Layered LaOInS 2. *Journal of Materials Chemistry A* **2017**, *5* (27), 14270-14277.

(98) Ito, H.; Miura, A.; Goto, Y.; Mizuguchi, Y.; Moriyoshi, C.; Kuroiwa, Y.; Azuma, M.; Liu, J.; Wen, X.-D.; Nishioka, S. An Electronic Structure Governed by the Displacement of the Indium Site in In-S 6 Octahedra: LnOInS 2 (Ln= La, Ce, and Pr). *Dalton transactions* **2019**, *48* (32), 12272-12278.

(99) Machida, M.; Murakami, S.; Kijima, T.; Matsushima, S.; Arai, M. Photocatalytic Property and Electronic Structure of Lanthanide Tantalates, LnTaO4 (Ln= La, Ce, Pr, Nd, and Sm). *The Journal of Physical Chemistry B* **2001**, *105* (16), 3289-3294.

(100) Wakayama, H.; Hibino, K.; Fujii, K.; Oshima, T.; Yanagisawa, K.; Kobayashi, Y.; Kimoto, K.; Yashima, M.; Maeda, K. Synthesis of a Layered Niobium Oxynitride, Rb2NdNb2O6N·H2O, Showing Visible-Light Photocatalytic Activity for H2 Evolution. *Inorganic Chemistry* **2019**, *58* (9), 6161-6166.

(101) Gastaldi, L.; Carre, D.; Pardo, M. P. Structure de l'oxysulfure d'indium et de Lanthane In6La10O6S17. *Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry* **1982**, *38* (9), 2365-2367.

(102) Ogisu, K.; Ishikawa, A.; Teramura, K.; Toda, K.; Hara, M.; Domen, K. Lanthanum-Indium Oxysulfide as a Visible Light Driven Photocatalyst for Water Splitting. *Chemistry letters* **2007**, *36* (7), 854-855.

(103) Jaulmes, S. Oxysulfure de Gallium et de Lanthane LaGaOS2. *Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry* **1978**, *34* (8), 2610-2612.

(104) Jaulmes, S.; Mazurier, A.; Guittard, M. Structure de l'oxypentasulfure de Gallium et de Trilanthane, GaLa3OS5. *Acta Crystallographica Section C: Crystal Structure Communications* **1983**, *39* (12), 1594-1597.

(105) Ogisu, K.; Ishikawa, A.; Shimodaira, Y.; Takata, T.; Kobayashi, H.; Domen, K. Electronic Band Structures and Photochemical Properties of La-Ga-Based Oxysulfides. *The Journal of Physical Chemistry C* **2008**, *112* (31), 11978-11984.

(106) Meignen, V.; Cario, L.; Lafond, A.; Moëlo, Y.; Guillot-Deudon, C.; Meerschaut, A. Crystal Structures of Two New Oxysulfides La5Ti2MS5O7 (M= Cu, Ag): Evidence of Anionic Segregation. *Journal of Solid State Chemistry* **2004**, *177* (8), 2810-2817.

(107) Katayama, M.; Yokoyama, D.; Maeda, Y.; Ozaki, Y.; Tabata, M.; Matsumoto, Y.; Ishikawa, A.; Kubota, J.; Domen, K. Fabrication and Photoelectrochemical Properties of La5Ti2MS5O7 (M= Ag, Cu) Electrodes. *Materials Science and Engineering: B* **2010**, *173* (1-3), 275-278.

(108) Suzuki, T.; Hisatomi, T.; Teramura, K.; Shimodaira, Y.; Kobayashi, H.; Domen, K. A Titanium-Based Oxysulfide Photocatalyst: La 5 Ti 2 MS 5 O 7 (M= Ag, Cu) for Water Reduction and Oxidation. *Physical Chemistry Chemical Physics* **2012**, *14* (44), 15475-15481.
(109) Liu, J.; Hisatomi, T.; Ma, G.; Iwanaga, A.; Minegishi, T.; Moriya, Y.; Katayama, M.; Kubota, J.; Domen, K. Improving the Photoelectrochemical Activity of La5Ti2CuS5O7 for Hydrogen Evolution by Particle Transfer and Doping. *Energy & Environmental Science* **2014**, *7* (7), 2239–2242.

(110) Ma, G.; Suzuki, Y.; Singh, R. B.; Iwanaga, A.; Moriya, Y.; Minegishi, T.; Liu, J.; Hisatomi, T.; Nishiyama, H.; Katayama, M. Photoanodic and Photocathodic Behaviour of La 5 Ti 2 CuS 5 O 7 Electrodes in the Water Splitting Reaction. *Chemical Science* **2015**, *6* (8), 4513–4518.

(111) Hirose, H.; Ueda, K.; Kawazoe, H.; Hosono, H. Electronic Structure of Sr2Cu2ZnO2S2 Layered Oxysulfide with CuS Layers. *Chemistry of materials* **2002**, *14* (3), 1037–1041.

(112) Nandy, S.; Hisatomi, T.; Katayama, M.; Minegishi, T.; Domen, K. Effects of Calcination Temperature on the Physical Properties and Hydrogen Evolution Activities of La5Ti2Cu(S1-Se)5O7 Photocatalysts. *Particle & Particle Systems Characterization* **2018**, *35* (1), 1700275. https://doi.org/10.1002/ppsc.201700275.

(113) Pan, Z.; Xiao, Q.; Chen, S.; Wang, Z.; Lin, L.; Nakabayashi, M.; Shibata, N.; Takata, T.; Hisatomi, T.; Domen, K. Synthesis of a Ga-Doped La5Ti2Cu0.9Ag0.107S5 Photocatalyst by Thermal Sulfidation for Hydrogen Evolution under Visible Light. *Journal of Catalysis* **2021**, *399*, 230–236. https://doi.org/10.1016/j.jcat.2021.05.015.

(114) Tang, X.; Ye, H.; Hu, H. Sulfurization Synthesis and Photocatalytic Activity of Oxysulfide La3NbS2O5. *Transactions of Nonferrous Metals Society of China* **2013**, *23* (9), 2644–2649. https://doi.org/10.1016/S1003-6326(13)62780-6.

(115) BaQais, A.; Curutchet, A.; Ziani, A.; Ait Ahsaine, H.; Sautet, P.; Takanabe, K.; Le Bahers, T. Bismuth Silver Oxysulfide for Photoconversion Applications: Structural and Optoelectronic Properties. *Chem. Mater.* **2017**, *29* (20), 8679–8689. https://doi.org/10.1021/acs.chemmater.7b02664.

(116) Ogawa, M.; Suzuki, H.; Tomita, O.; Nakada, A.; Abe, R. Sn2+-Based Pyrochlore Oxysulfides with Narrow Band Gaps for Photocatalytic Water Splitting. *Journal of Photochemistry and Photobiology A: Chemistry* **2023**, *444*, 114895. https://doi.org/10.1016/j.jphotochem.2023.114895.

(117) Chu, K. H.; Ye, L.; Wang, W.; Wu, D.; Chan, D. K. L.; Zeng, C.; Yip, H. Y.; Yu, J. C.; Wong, P. K. Enhanced Photocatalytic Hydrogen Production from Aqueous Sulfide/Sulfite Solution by ZnO0.6S0.4 with Simultaneous Dye Degradation under Visible-Light Irradiation. *Chemosphere* **2017**, *183*, 219–228. https://doi.org/10.1016/j.chemosphere.2017.05.112.

(118) Gultom, N. S.; Abdullah, H.; Kuo, D.-H. Enhanced Photocatalytic Hydrogen Production of Noble-Metal Free Ni-Doped Zn(O,S) in Ethanol Solution. *International Journal of Hydrogen Energy* **2017**, *42* (41), 25891–25902. https://doi.org/10.1016/j.ijhydene.2017.08.198.

(119) Gultom, N. S.; Abdullah, H.; Xie, J.-C.; Shuwanto, H.; Kuo, D.-H. Improved Hydrogen Production Rate of a Nickel-Doped Zinc Indium Oxysulfide Visible-Light Catalyst: Comparative Study of Stoichiometric and Nonstoichiometric Compounds. *ACS Appl. Energy Mater.* **2022**, *5* (2), 1755–1766. https://doi.org/10.1021/acsaem.1c03200.

(120) Chen, X.; Wu, Q.; Kuo, D.-H.; Abdeta, A. B.; Zhang, H.; Li, P.; Huang, T.; Zelekew, O. A.; Lin, J. Initiating Highly Efficient (Bi,Ce)2(O,S)3–x Oxysulfide Catalysts with Rich Oxygen Vacancies for Hydrogen Evolution via Adjusting Valence Band Configuration. *J. Mater. Chem. A* **2023**, *11* (8), 4126–4141. https://doi.org/10.1039/D2TA09780J.

(121) Mallick, S.; Orlandi, F.; Manuel, P.; Zhang, W.; Halasyamani, P. S.; Hayward, M. A. MnCaTa2O7–A Magnetically Ordered Polar Phase Prepared via Cation Exchange. *Chem. Mater.* **2023**, *35* (18), 7839–7846. https://doi.org/10.1021/acs.chemmater.3c01850.

(122) *Anisotropic Charge Migration on Perovskite Oxysulfide for Boosting Photocatalytic Overall Water Splitting* | *Journal of the American Chemical Society*.
https://pubs.acs.org/doi/abs/10.1021/jacs.3c12417 (accessed 2025-01-31).
(123) Heterogeneous doping of visible-light-responsive Y2Ti2O5S2 for enhanced hydrogen evolution - Journal of Materials Chemistry A (RSC Publishing).
https://pubs.rsc.org/en/content/articlelanding/2022/ta/d2ta06895h/unauth (accessed 2025-01-31).

(124) Hisatomi, T.; Okamura, S.; Liu, J.; Shinohara, Y.; Ueda, K.; Higashi, T.; Katayama, M.; Minegishi, T.; Domen, K. La 5 Ti 2 Cu 1- x Ag x S 5 O 7 Photocathodes Operating at Positive Potentials during Photoelectrochemical Hydrogen Evolution under Irradiation of up to 710 Nm. Energy & Environmental Science 2015, 8 (11), 3354-3362.

(125) Liang, H.; Sun, H.; Jiang, S.; Cui, S.; Song, F.; Fan, L.; Xu, Q. Two-Dimensional (2D) Oxysulfide Nanosheets with Sulfur-Rich Vacancy as an Visible-Light-Driven Difunctional Photocatalyst for Hydrogen and Oxygen Evolution. Journal of Alloys and Compounds 2024, 1004, 175898.
https://doi.org/10.1016/j.jallcom.2024.175898.

(126) Cui, J.; Li, C.; Zhang, F. Development of Mixed-Anion Photocatalysts with Wide Visible-Light Absorption Bands for Solar Water Splitting. ChemSusChem 2019, 12 (9), 1872-1888.

(127) Goto, Y.; Seo, J.; Kumamoto, K.; Hisatomi, T.; Mizuguchi, Y.; Kamihara, Y.; Katayama, M.; Minegishi, T.; Domen, K. Crystal Structure, Electronic Structure, and Photocatalytic Activity of Oxysulfides: La2Ta2ZrS2O8, La2Ta2TiS2O8, and La2Nb2TiS2O8. Inorganic Chemistry 2016, 55 (7), 3674-3679.

(128) Allen, J. P.; Carey, J. J.; Walsh, A.; Scanlon, D. O.; Watson, G. W. Electronic Structures of Antimony Oxides. The Journal of Physical Chemistry C 2013, 117 (28), 14759-14769.

(129) Vadapoo, R.; Krishnan, S.; Yilmaz, H.; Marin, C. Self-Standing Nanoribbons of Antimony Selenide and Antimony Sulfide with Well-Defined Size and Band Gap. Nanotechnology 2011, 22 (17), 175705.

(130) Liang, F.; Kang, L.; Lin, Z.; Wu, Y. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure-Property Relationship. Crystal growth & design 2017, 17 (4), 2254-2289.

(131) Sayama, K.; Nomura, A.; Zou, Z.; Abe, R.; Abe, Y.; Arakawa, H. Photoelectrochemical Decomposition of Water on Nanocrystalline BiVO 4 Film Electrodes under Visible Light. Chemical Communications 2003, No. 23, 2908-2909.

(132) Kavanagh, S. R.; Savory, C. N.; Scanlon, D. O.; Walsh, A. Hidden Spontaneous Polarisation in the Chalcohalide Photovoltaic Absorber Sn 2 SbS 2 I 3. Materials horizons 2021, 8 (10), 2709-2716.

(133) Wang, X.; Li, Z.; Kavanagh, S. R.; Ganose, A. M.; Walsh, A. Lone Pair Driven Anisotropy in Antimony Chalcogenide Semiconductors. Physical Chemistry Chemical Physics 2022, 24 (12), 7195-7202.

(134) Ok, K. M. Functional Layered Materials with Heavy Metal Lone Pair Cations, Pb 2+, Bi 3+, and Te 4+. Chemical Communications 2019, 55 (85), 12737-12748.

(135) Handy, J. V.; Zaheer, W.; Rothfuss, A. R.; McGranahan, C. R.; Agbeworvi, G.; Andrews, J. L.; García-Pedraza, K. E.; Ponis, J. D.; Ayala, J. R.; Ding, Y. Lone but Not Alone: Precise Positioning of Lone Pairs for the Design of Photocatalytic Architectures. Chemistry of Materials 2022.

(136) Suzuki, H.; Kunioku, H.; Higashi, M.; Tomita, O.; Kato, D.; Kageyama, H.; Abe, R. Lead Bismuth Oxyhalides PbBiO2X (X= Cl, Br) as Visible-Light-Responsive Photocatalysts for Water Oxidation: Role of Lone-Pair Electrons in Valence Band Engineering. Chemistry of Materials 2018, 30 (17), 5862-5869.

(137) Al Bacha, S.; Saitzek, S.; Kabbour, H.; McCabe, E. E. Iron Oxychalcogenides and Their Photocurrent Responses. Inorg. Chem. 2024, 63 (7), 3292-3302.
https://doi.org/10.1021/acs.inorgchem.3c03672.

(138) Cui, J.; Li, C.; Zhang, F. Development of Mixed-Anion Photocatalysts with Wide Visible-Light Absorption Bands for Solar Water Splitting. ChemSusChem 2019, 12 (9), 1872-1888.
https://doi.org/10.1002/cssc.201801829.
(139) Zhang, H.; Liu, L.; Zhou, Z. Towards Better Photocatalysts: First-Principles Studies of the Alloying Effects on the Photocatalytic Activities of Bismuth Oxyhalides under Visible Light. *Physical Chemistry Chemical Physics* **2012**, *14* (3), 1286–1292.

(140) Zhang, J.; Zhou, P.; Liu, J.; Yu, J. New Understanding of the Difference of Photocatalytic Activity among Anatase, Rutile and Brookite TiO2. *Physical Chemistry Chemical Physics* **2014**, *16* (38), 20382–20386.

(141) Zhang, J.; Yu, W.; Liu, J.; Liu, B. Illustration of High-Active Ag2CrO4 Photocatalyst from the First-Principle Calculation of Electronic Structures and Carrier Effective Mass. *Applied Surface Science* **2015**, *358*, 457–462.

(142) Yang, J.; Jiang, P.; Yue, M.; Yang, D.; Cong, R.; Gao, W.; Yang, T. Bi2Ga4O9: An Undoped Single-Phase Photocatalyst for Overall Water Splitting under Visible Light. *Journal of Catalysis* **2017**, *345*, 236–244.

(143) Vonrüti, N. Ferroelectricity and Metastability in (Mixed-Anion) Perovskite Oxides for Improved Solar Water Splitting, 2019.

(144) Al Bacha, S.; Saitzek, S.; McCabe, E. E.; Kabbour, H. Photocatalytic and Photocurrent Responses to Visible Light of the Lone-Pair-Based Oxysulfide Sr6Cd2Sb6S10O7. *Inorg. Chem.* **2022**, *61* (46), 18611–18621. https://doi.org/10.1021/acs.inorgchem.2c03040.

(145) Vonrüti, N.; Aschauer, U. Catalysis on Oxidized Ferroelectric Surfaces—Epitaxially Strained LaTiO2N and BaTiO3 for Photocatalytic Water Splitting. *The Journal of Chemical Physics* **2020**, *152* (2), 024701.

(146) Berger, R. F.; Fennie, C. J.; Neaton, J. B. Band Gap and Edge Engineering via Ferroic Distortion and Anisotropic Strain: The Case of SrTiO 3. *Physical review letters* **2011**, *107* (14), 146804.

(147) Vonrüti, N.; Aschauer, U. Epitaxial Strain Dependence of Band Gaps in Perovskite Oxynitrides Compared to Perovskite Oxides. *Physical review materials* **2018**, *2* (10), 105401.

(148) Vonrüti, N.; Aschauer, U. Band-Gap Engineering in AB (O x S 1–x) 3 Perovskite Oxysulfides: A Route to Strongly Polar Materials for Photocatalytic Water Splitting. *Journal of Materials Chemistry A* **2019**, *7* (26), 15741–15748.

(149) Vonrüti, N.; Aschauer, U. Anion Order and Spontaneous Polarization in LaTiO 2 N Oxynitride Thin Films. *Physical review letters* **2018**, *120* (4), 046001.

(150) Li, J.; Cai, L.; Shang, J.; Yu, Y.; Zhang, L. Giant Enhancement of Internal Electric Field Boosting Bulk Charge Separation for Photocatalysis. *Advanced Materials* **2016**, *28* (21), 4059–4064.

(151) Al Bacha, S.; Saitzek, S.; Roussel, P.; Huvé, M.; McCabe, E. E.; Kabbour, H. Low Carrier Effective Masses in Photoactive Sr2Sb2O2Q3 (Q = S, Se): The Role of the Lone Pair. *Chem. Mater.* **2023**, *35* (22), 9528–9541. https://doi.org/10.1021/acs.chemmater.3c01298.