# Brittle tectonics and fluids overpressure during the early stage of the Bay of Biscay opening in the Jard-sur-Mer area, (northern Aquitaine Basin, France)

Pierre Strzerzynski, Louise Lenoir, Paul Bessin, Loïc Bouat

► To cite this version:

Pierre Strzerzynski, Louise Lenoir, Paul Bessin, Loïc Bouat. Brittle tectonics and fluids overpressure during the early stage of the Bay of Biscay opening in the Jard-sur-Mer area, (northern Aquitaine Basin, France). Bulletin de la Société Géologique de France, 2020, 191, 10.1051/bsgf/2020025. insu-03231747

HAL Id: insu-03231747

https://insu.hal.science/insu-03231747

Submitted on 21 May 2021

HAL is a multi-disciplinary open access
archive for the deposit and dissemination of sci-
entific research documents, whether they are pub-
lished or not. The documents may come from
teaching and research institutions in France or
abroad, or from public or private research centers.

L'archive ouverte pluridisciplinaire HAL, est
destinée au dépôt et à la diffusion de documents
scientifiques de niveau recherche, publiés ou non,
émanant des établissements d'enseignement et de
recherche français ou étrangers, des laboratoires
publics ou privés.

<figure><img src="image_1.png" /></figure>

Distributed under a Creative Commons Attribution 4.0 International License
# Brittle tectonics and fluids overpressure during the early stage of the Bay of Biscay opening in the Jard-sur-Mer area, (northern Aquitaine Basin, France)

Pierre Strzerzynski<fnref n="1" />*, Louise Lenoir<fnref n="2" />, Paul Bessin<fnref n="1" /> and Loic Bouat<fnref n="1" />

Received: 21 November 2019 / Accepted: 26 June 2020

**Abstract** – Ba, F, Pb, Ag, Zn mineral deposits are widespread at the northern and eastern boundaries of the Aquitaine Basin. In most cases, they are hosted within high permeability carbonates that rest over the Hercynian basement and below an impermeable layer. Such a position suggests a Mississippi Valley Type (MVT) model for the formation of these deposits. This model is characterized by the lateral flow of sedimentary fluids expelled from the deeper part of the basin and mixed with other sources of water as they reach the basin boundaries. In the Jard-sur-Mer area, which sits in the north of the Basin, these deposits are also found higher in the sedimentary series suggesting that fluids have flown through the impermeable layer. Our field observations demonstrate that a brittle deformation episode, compatible with an upper-Jurassic N-S direction of extension, occurred as the mineralizing fluids were over pressured. The overpressure was the result of a large input of hydrothermal water ascending along inherited faults affecting the Hercynian basement and released at the onset of the tectonics event. When compared with the rest of the basin, these new results at the northern boundary suggests that the Aquitaine Basin recorded several stages of fluid overpressure both at the onset and during the opening of the Bay of Biscay.

**Keywords:** fluids / overpressure / Aquitaine Basin / brittle tectonics / mineral deposits

**Résumé** – **Tectonique fragile et surpression de fluides au début de l'ouverture du golfe de Gascogne dans la région de Jard-sur-Mer (nord du bassin Aquitain, France).** Les gîtes minéraux Ba, F, Pb, Ag, Zn sont fréquents aux limites nord et est du bassin Aquitain. Dans la plupart des cas, ils sont hébergés dans des carbonates de forte perméabilité et limités par le socle hercynien à la base et une couche imperméable à leur sommet. Une telle position suggère un modèle de gisement du type « vallée du Mississippi » (MVT) caractérisés par l'écoulement latéral de fluides sédimentaires expulsés de la partie la plus profonde du bassin et mélangés à d'autres sources d'eau lorsqu'ils atteignent les limites du bassin. Sur la zone de Jard-sur-Mer, au Nord du bassin, ces dépôts se retrouvent également plus hauts dans la série sédimentaire suggérant que des fluides ont traversé la couche imperméable. L'étude, sur le terrain, des structures tectoniques et des dépôts minéraux met en évidence qu'un épisode de déformation fragile, compatible avec une direction d'extension N-S du Jurassique supérieur, s'est produit lorsque les fluides minéralisateurs étaient sous pression. La surpression des fluides résulte d'un apport important d'eau hydrothermale, issues du socle hercynien, qui ont remonté le long des failles héritées et ont été libérée au début de l'événement tectonique. Comparées au reste du bassin, ces nouveaux résultats suggèrent que le bassin aquitain a enregistré plusieurs stades de surpression fluide au début et pendant la phase de rifting associées à l'ouverture du Golfe de Gascogne.

**Mots clés** : fluides / surpression / Bassin Aquitain / tectonique cassante / minéralisations

## 1 Introduction

Fluid migration in sedimentary basins is a first order process that controls the formation of hydrological, geothermal, mineral

or hydrocarbon resources (Bjørlykke, 1993; Andresen 2012; Gay and Migeon, 2017). Fluids usually migrate through the natural porosity of sedimentary rocks. However, when the fluid pressure is greater than the lithostatic pressure, hydraulic fracturing generates open fractures, which provide additional migration paths for the fluids though brittle structures (Swarbrick

<footnote n="1">¹ Laboratoire de Planétologie et Géodynamique, UMR 6112, CNRS, Le Mans Université, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France</footnote>

<footnote n="2">² UMR CNRS/UPS Géosciences Paris Sud (GEOPS), Bât. 504, Université Paris-Sud, 91405 Orsay, France</footnote>

<footnote>*Corresponding author: pierre.strzerzynski@univ-lemans.fr</footnote>
et al., 2004; Tingay et al., 2009). Hydraulic fracturing can be initiated in a wide range of geological contexts: 1) as a consequence of a porosity decrease during burial (Bureau et al., 2013; Frazer et al., 2014; Suppe, 2014) or sea level rise (Gay and Migeon, 2017), 2) during fluids production associated with devolatilisation reactions (Aarnes et al., 2012), ice melting (Lelandais et al., 2016) or hydrocarbon maturation (Zanella et al., 2015), 3) as the result of heat advection or the build-up of a hydraulic head (Rice, 1992; Laurent et al., 2017), or 4) deformations (Beaudoin et al., 2014). In the field, widely accepted geological evidence for fluids overpressures can be 1) breccias characterized by *in-situ* angular fragments organized in a jigsaw puzzle pattern (Sibson 1986; Jebrak, 1997; Tartarotti and Pasquaré, 2003; Chi and Xue, 2011), 2) coexisting vertical and horizontal veins (Cobbold et al., 2013; Zanella et al., 2015) and 3) decreasing fault dip angles induced by the lowering of the friction angle (Davis et al., 1983; Dahlen 1984; Mourgues and Cobbold, 2006; Collettini, 2011).

Basal unconformities in sedimentary basins are preferen-
tial interfaces for fluid circulation as shown by the ubiquity of
fluid-related mineral resources located in the first meters of
numerous basin deposits (Anderson and Macqueen, 1982;
Sverjensky, 1986; Leach et al., 2001). Mississippi Valley Type
deposits (MVT), where abundant Cu and U ore fields and half
of the worldwide Pb and Zn extraction worldwide are located,
represent the striking examples of such fluid circulations
(Frazer et al., 2014). In MVT deposits, Pb and Zn deposits are
formed through the migration of saline brines from the basin
center toward its border within carbonate sequences below a
low-porosity layer (Robb, 2005; Leach et al., 2010). In such
context, fluid migration can be either due to gravity (e.g.
hydrostatic head during an uplift), to orogeny (e.g. rock
compaction and deformation in a fold-and-thrust belt) or to a
thermal gradient (e.g. thermally induced circulation in
permeable sedimentary units; Garven and Raffensperger,
1997, Robb, 2005).

In France, MVT deposits of fluorite and/or barite are documented in the Paris Basin and the Aquitaine Basin (Boiron et al., 2002; Fourcade et al., 2002; Leach et al., 2006; Sizaret et al., 2009, 2004; Cathelineau et al., 2012; Gigoux et al., 2015, 2016). In the Aquitaine Basin (Fig. 1), most of the mineralization have been observed in the Hettangian (ca. 201–199 Ma) units, which are considered as a high permeability layers and below the Toarcian (ca. 182–174 Ma) unit, which forms an impermeable barrier (Boiron et al., 2002; Fourcade et al., 2002; Cathelineau et al., 2012) (Fig. 2). Fluid temperatures and salinity measurements obtained from baryte and fluorite deposits at the northern and eastern boundaries of the Aquitaine Basin, indicate fluid migration from the evaporitic units located in the deeper parts of the Basin (Boiron et al., 2002) (Fig. 1). The age of this fluid event has been estimated at 145–155 Ma (Kimmeridgian to Tithonian times) by $^{40}$Ar/$^{39}$Ar on adularia and K/Ar dating on illite (Cathelineau et al., 2012) (Fig. 1).

In this context, the mineral deposits of the Jard-sur-Mer area (northern edge of the Aquitaine Basin, Fig. 1) are an exception because their presence in Callovian units shows that particularly hot fluids have crossed the low-permeability Toarcian unit (Cathelineau et al., 2012).

Recently, several episodes of fluid overpressure-related
fracturing have been documented at the southern boundary of
the Aquitaine Basin: during the Lower Cretaceous first

(Salardon et al., 2017; Renard et al., 2019) and then during the
Eocene (Crognier et al., 2018). We focus here on an area that
offers good outcropping conditions in the north of the Basin
and shows a thick mineralization-bearing cover (Fig. 1). Our
objectives are to investigate fluid overpressure occurrences
and to explain why mineralization affects a thicker part of the
sedimentary series in this area compared to the rest of the
Basin. We performed a new structural analysis and mapped
observations of fluid/mineral relationships. These new con-
straints allow us to unravel the relationships between brittle
deformation and fluid-related mineralization within the
structural framework of this poorly described region.

## 2 Geological setting

The Aquitaine Basin is located in the southwest of France. This 35 000 km² triangular shaped domain is limited to the north by the Armorican Massif, to the east by the French Massif Central, to the south by the Pyrenean mountain belt and to the west by the Bay of Biscay deep basin (Fig. 1). The Armorican Massif and the French Massif Central were intensely deformed as parts of the Hercynian belt from the late Devonian to Carboniferous times. They mainly consist of metamorphic rocks intruded by granitoïds (Ballèvre et al., 2009) and equivalent rocks probably form the basement underlying the Aquitaine Basin.

The Aquitaine Basin recorded a complex Mesozoic to
Cenozoic tectonic and sedimentary evolution. During the
Mesozoic, the opening of the Atlantic Ocean induced two
rifting events. The first one was distributed over the Basin and
associated with the deposition of a thick evaporitic sequence; it
took place from the Triassic to the Lower Jurassic, prior to the
development of an extended Jurassic carbonate platform made
up of dolomitic limestones, limestones and marls (Fig. 1; Biteau
et al., 2006). The second event occurred in transtension from
latest Jurassic to Lower Cretaceous (early Aptian) times, and
induced the main rifting phase of the Bay of Biscay (Berriasian to
Barremian; Nirrengarten et al., 2018). In the Aquitaine Basin,
this event saw the formation of two E-W elongated rift basins, the
Parentis and the Arzacq subbasins, which were later aborted
(Tithonian to early Aptian; Biteau et al., 2006; Tugend et al.,
2015). This rifting phase also led to extreme crustal thinning
prior to the onset of oceanic accretion in the Bay of Biscay in
latest Aptian-earliest Albian (Montadert et al., 1979; Curnelle
and Dubois, 1986; Jammes et al., 2010; Tugend et al., 2015;
Nirrengarten et al., 2018). Then, the Iberia-Eurasia convergence
resulted in the onset of compression from late Albian to
Campanian times (Biteau et al., 2006; Tugend et al., 2015) prior
to the main compression phase from uppermost Cretaceous-
Paleocene to Chattian (Biteau et al., 2006; Ortiz et al., 2020).
Related tectonic inversions were mainly recorded by the
southern margin edge of the Aquitaine Basin which became a
retro-foreland basin of the growing Pyrenean mountain belt
(Biteau et al., 2006; Ford et al., 2016; Angrand et al., 2018; Ortiz
et al., 2020). Additionally, seismic profiles indicate that Jurassic
deposits in the northern Aquitaine Basin are affected by
numerous normal faults that do not affect Upper Cretaceous
formations (Huerta et al., 2010; Fig. 1). Faulting is therefore
inherited from latest Jurassic transtensional and/or from latest
Aptian-earliest Albian crustal thinning (Huerta et al., 2010).
<figure><img src="image_2.png" /><figcaption>**Fig. 1.** A: Structural framework of the Aquitaine Basin (after Chantraine *et al.*, 1996). The ages and temperatures of fluorine fluid inclusions and barite deposits are indicated (Boiron *et al.*, 2002; Fourcade *et al.*, 2002; Munoz *et al.*, 2005; Cathelineau *et al.*, 2012). The mapping of the lower Jurassic evaporites is from (Curnelle and Dubois, 1986). B: Cross-section of the southern part of the Poitou High ("Seuil du Poitou", after Karnay *et al.*, 2004).</figcaption></figure>

**2.1 Sedimentary formations and basement of the Jard-sur-Mer area (northern edge of the Aquitaine Basin)**

The Jard-sur-Mer area is located at northern edge of the Aquitaine Basin, at its present-day boundary with the

Armorian Massif (Fig. 1). The Armorian basement which is mainly composed of metamorphic rocks in its southern part here consists of kyanite-, garnet- and staurotide-bearing micaschists with a well-expressed eastward dipping foliation. This foliation is related to at least two folding events caused by
<figure><img src="image_3.png" /><figcaption>**Fig. 2.** Location of the photographs and diagrams shown in Figures 4–6: on a geological map and on a stratigraphic column (inset, after Goujou *et al.*, 1994).</figcaption></figure>

a complex polyphased tectonic history during the Hercynian orgeny (Fig. 2; Goujou *et al.*, 1994). The micaschists crop out to the west of the Jard-sur-Mer area where they are topped by the Hercynian unconformity (Fig. 2; Ters and Gabilly, 1986; Goujou *et al.*, 1994). Geomorphological analysis have shown that the Hercynian belt was almost leveled through denudation processes that resulted in a first generation of pre-Hettangian (ca. pre-200 Ma) planation surfaces. The Hercynian unconformity corresponds here to these surfaces associated with partly stripped weathering products (Ters, 1988; Wyns, 1991; Bétard, 2010).

The basement and this unconformity are overlain by the transgressive Jurassic cover that gently dips to the southwest. The sedimentary succession is composed of four units that consist of 10 m to 30 m thick carbonates alternating with 10 m to 40 m thick marls and can be described in details as follows (Fig. 3; Goujou *et al.*, 1994):

- *Hettangian to Piensbachian unit* (201–183 Ma; 13 m thick);

- Dolomitic limestones that laterally grades to dolomitic clays and locally overlain a thin transgressive dolomitic conglomerate composed the base of the unit whereas argillaceous limestones forms its upper part. This unit is locally strongly silicified and some dolomitic limestones have penetrated the basement through foliation planes;

- *Toarcian to Aalenian unit* (183–170 Ma; 18 m thick) – Blue marls form most of the unit with some argillaceous limestones and nodular limestone levels;

- *Bajocian–athonian unit* (170–166 Ma; 37 m thick)– Fossiliferous grey limestones that stand upon a thin conglomerate are located at the base of the unit. Most of the succession is made of sandy to pebbly limestones that are locally ferruginous. Thin levels of phosphate cobbles occur close to the top of the unit, which ends with a hardground;

- *Callovian unit* (166–163 Ma; more than 60 m) – The basal part consists of argillaceous limestone that grades into 30 m thick grey marls, which subsequently grade to alternating argillaceous limestones and marls. These limestones are overlain by impermeable blue marls that are at least 10 m thick.

Several authors provides geomorphological (e.g. Bétard, 2010), sedimentological (e.g. Enay *et al.*, 1980) and thermochronological (e.g. François *et al.*, 2020) evidence for a larger extension of the Aquitaine Basin across the Hercynian basement during Jurassic times and even during Upper Cretaceous times whereas denudation during the Early Cretaceous and the Eocene induce the formation of two generations of planation surfaces (Wyns, 1991; Bétard, 2010; Bessin *et al.*, 2015).

## 2.2 Occurrence of mineralization in the Jard-sur-Mer area (northern edge of the Aquitaine Basin)

The occurrences of mineralization of Jard-sur-Mer area were described by Cathelineau *et al.* (2012). These authors show that the widespread mineralization within the first metres of the dolomitic to argillaceous limestones of the Hettangian to Pliensbachian unit (Fig. 3), under the blue marls of the Toarcian to Aalenian unit (Fig. 3) are related to fluid circulations. The evidence is the almost complete silicification of the Hettangian to Pliensbachian unit (Fig. 2; Goujou *et al.*, 1994) together with occurrences of mineralized lenses and veins composed of quartz, barite, sulfides, Ag-rich galena and sphalerite within this unit. Quartz and calcite veins located upward in the sedimentary units especially within argillaceous limestones of the Callovian unit were also described by Cathelineau *et al.* (2012). Fluid inclusion microthermometry, oxygen and carbon stable isotope analysis, and Sr analysis on the Aquitaine Basin edges have shown heterogeneous compositions and heterogeneous trapping temperatures of the fluids (see compilation in Fig. 1; Boiron *et al.*, 2002; Fourcade *et al.*, 2002; Cathelineau *et al.*, 2012).

At least three possible sources of fluid have been identified (Boiron *et al.*, 2002; Fourcade *et al.*, 2002; Cathelineau *et al.*, 2012):

- *Sedimentary brines:* this source is indicated by highly saline brines trapped at temperature ranging between 100 and 200 °C. Brines were expelled from the Triassic evaporites that migrated from the central part of the basin along the sediment cover/basement;

- *Meteoric/Hydrothermal waters:* low salinity water trapped at temperature higher than 250 °C indicate such a source. Meteoric waters infiltrated from emerged zones and
<figure><img src="image_4.png" /><figcaption>**Fig. 3.** Synthetic log of the sedimentary succession of the Jard-sur-Mer area (drawn after Goujou *et al.*, 1994).</figcaption></figure>

underwent convection when heated at depth prior to their
ascension;

- Penetrating seawater: this source is typically associated with low salinity and low temperature (around 50 °C) fluids. Seawater penetrating sedimentary cover (and basement) or connate water released during dissolution of carbonate.

**3 Data and methods**

In this study, we mapped brittle structures and performed
structural field work focused on faults and mineralized veins
within a coastal area near Jard-sur-Mer (northern Aquitaine

Basin) to unravel relationships between deformation and fluid-
related mineralization. We use GIS program to map at a
1:1500 scale the sedimentary layers and brittle structures
(lineaments) affecting mainly the Bajocian-Bathonian and
Callovian units. These structures can be identified easily on
this high-resolution imagery thanks to the low dip angles of the
layers and the favorable outcropping conditions. Mapping is
based on high-resolution (ca. 5 cm) aerial and satellite imagery
dataset available in Google Earth®. Secondly, we performed
field observations in the Jard-sur-Mer area, mainly focusing on
the sea-cliffs where mineralized veins and faults are well
exposed. Along the study area, we measured and geolocalized
faults and mineralized veins directions, dips and striae plunges
(120 measures). We paid a peculiar attention to the structural and
chronological relationships between faults and mineralizations,
which are best observed in six stations (S1 to S6, Fig. 2). We also
conducted a field petrography analysis on outcrops in order to
define the paragenetic succession within the mineralized
deposits. During low tides, we made further structural
observations on the rocky foreshore to control our GIS mapping
of faults and to determine if they are associated with mineralized
deposits or not. We used the Stereonet® and Faultkin® computer
programs to plot our structural measurements in stereographic
canvas and to produce stress tensor inversions following the
stress inversion method of Allmendinger *et al.* (2011).

4 GIS mapping and structural analysis
results

Thanks to its location on the present-day shore of the
Atlantic Ocean, at the edge between the Armorican Massif and
the Aquitaine Basin (Fig. 1), the Jard-sur-Mer area provides
excellent conditions for field observations of the Hercynian
basement and the Lower to Middle Jurassic sedimentary cover
over several kilometres. The Hercynian basement and
unconformity can be exceptionally well observed all along
the 2 kilometers long cliff of the Pointe du Payré. The
Hettangian to Pliensbachian unit outcrops along the 300 m
long rocky foreshore of the Anse St-Nicolas (Fig. 2 and Fig. 4-
P1; Ters and Gabilly, 1986). The Bajocian–Bathonian and the
Callovian units outcrop well from the east of the Anse St-
Nicolas to Le Goulet whereas the Toarcian to Aalenian unit
only outcrops at low tide in the Anse St-Nicolas where it is
covered by algae (Fig. 2).

On every unit, we observed fault planes (which typically bear striae) and mineralized veins (Fig. 4 and Fig. 5). Mineralized veins are filled with quartz (e.g. Fig. 4-P4, Fig. 5-P5, P8 and P10), barite (e.g. Fig. 4-P2 and P4, Fig. 5-P8 and P9), calcite, and sulfides crystals (e.g. Fig. 4-P4). Veins are generally 3 to 4 cm thick in the sedimentary cover (Fig. 4-P2 and P4) and can be followed over tens of metres. We also observed the same mineral association on the fault planes and the striae indicate normal displacements, sometimes combined with strike-slip movements (e.g. Fig. 4-P3 and Fig. 5-P10).

4.1 Brittle structures and mineralized veins within the Hercynian basement

Most of the basement deformation is recorded in the
eastward dipping foliation of the garnet-, kyanite- and
<figure><img src="image_5.png" /></figure>

**Fig. 4.** Interpreted photographs of brittle structures in the Armorican Massif and Aquitaine Basin. See Figure 2 for location. P1: panoramic view of the discontinuity between foliated micaschists and the Hettangian sedimentary unit. Note the alteration of the basement below the discontinuity and along inherited late hercynian faults. P2: horizontal veins crosscutting the Hettangian unit. P3: hydraulic breccias sealed by barite and quartz deposits. P4: vertical vein crosscutting the Hettangian unit. S2: Stereographic projection of faults and schistosity planes; late hercynian and Jurassic faults planes have been recognized on the basis of their relationship with the discontinuity.

staurotide-bearing micaschists (Fig. 4-P1). However, we observed several brittle structures that cross-cut the foliation and are almost all truncated by the Hercynian unconformity and sealed by transgressive dolomitic limestones of the Hettangian to Pliensbachian unit (Fig. 4-P1). The strike directions of these fault planes range from N-S to NNW-SSE, dipping mostly westward (Fig. 4-S2). Fault plane surface is covered by clay and per place baryte masking the striaes. Drag folds within the micaschists foliation indicate normal motions associated with faulting.

We observed only two occurrences of a fault affecting both the basement and the overlying Hettangian to Pliensbachian sedimentary unit along the 2-km long cliff where the basement outcrops (Fig. 4-P1). These fault planes have a E-W strike directions and show normal displacement similar to those observed in the Mesozoic sedimentary cover (Fig. 4-S2; see §4.2).

Within the first metres of basement rocks below the Hercynian unconformity, we also identified an upward colour change from grey or blue-grey to pale yellow (Fig. 4-P1). We observed a similar colour change within the rocks adjacent to each fault plane in the basement (Fig. 4-P1).

## 4.2 Brittle structures and mineralized veins within the Hettangian to Pliensbachian unit

According to our field observations, the Hettangian to Pliensbachian unit is the most intensely faulted and mineralized sedimentary unit in the Jard-sur-Mer area. Numerous normal faults strike W-E to WNW-ESE (Fig. 6-S1). Their dip directions are homogeneously distributed between N and S directions and define dihedral patterns. Dip values range between 80° and 20° (Fig. 6-S1) and several fault planes present the arcuate shape of listric faults (Fig. 5-P5). Only a few of these faults cross-cut the Hercynian unconformity and affect the basement (see §4.1). The stress tensor we calculated for the Hettangian to Pliensbachian unit is characterized by a vertical $σ_1$ whereas the horizontal $σ_2$ and $σ_3$ are striking between N90 to N110 and N0 to N20, respectively (Fig. 6-S1).

On the coastal cliff of the *Pointe du Payré* and the foreshore of the *Anse St-Nicolas*, we could observe mineralized veins very well (Fig. 2). They are filled by barite, sulfides and quartz. The geometric relationships between mineral phases indicate that barite crystallized first, followed by sulfides and
<figure><img src="image_6.png" /><figcaption>**Fig. 5.** Interpreted photographs of brittle structures in the Jard-sur-Mer area (Aquitaine Basin). P5: listric normal faults located near the discontinuity and crossing the Bathonian unit; P6: conjugated normal faults crossing the Bathonian unit; P7: high angle normal fault located forming the contact between Bathonian unit to the left and Callovian unit to the right; P8: barite and subsequent quartz fillings in a vertical vein in the Bajocian unit; P9 and P10: fault planes within the Bathonian unit. The geodic quartz and the striated quartz and barite suggest that faulting is coeval with mineral crystallization. See Figure 2 for the location of each picture.</figcaption></figure>

then quartz (Fig. 4-P4). We can distinguish two groups of veins from their orientation and size. The first group consists of vertical veins striking between N90 to N120 affecting the whole Hettangian to Pliensbachian unit (Fig. 4-S2). Most of these veins contain barite and quartz, while thin layers of sulfides are sometimes located between these two minerals (Fig. 4-P4). Along the *Anse St-Nicolas* rocky foreshore where veins can be followed for more than 10 m, a very large amount of veins is concentrated within the heterogeneous few metres of the Hettangian to Pliensbachian unit composed of dolomitic limestones alternating with dolomitic clays and thin marl and sandy to conglomeratic levels (Fig. 3). The second group consists of nearly horizontal and bedding-parallel barite veins located in 2 to 3 m long for 0.5 m thick lenses where several veins are stacked (Fig. 4-P2). This group is only observed in the first few metres of the Hettangian to Pliensbachian unit and outcrops along the coastal cliff of the Pointe du Payré (Fig. 2 and Fig. 4-P1). When automorphic crystals are present, their growth directions are orthogonal to the vein boundaries (Fig. 5-P4).

Near the base of Hettangian to Pliensbachian unit in the neighborhood of the horizontal veins, we also noticed breccias locally following the bedding. They are composed of angular

Hettangian dolomitic clasts suggesting an in situ formation. The cement is made of barite (Fig. 4-P3).

**4.3 Brittle structures and mineralized veins within the Bajocian-Bathonian and the Callovian units**

Brittle structures and mineralized veins are less abundant within the Bajocian-Bathonian and the Callovian units and they could not be observed within the marly Toarcian to Aalenian unit due to bad outcrop conditions. The strike directions of fault planes range from W-E to WNW-ESE and their dip directions between N and S (Fig. 5-P6 and Fig. 6). Striated elements related to these faults are made of Jurassic carbonate and mineralized deposits. Depending on their position along fault planes, these deposits often form automorphic to sub-automorphic crystals preserved in cavities. They can be striated in several places, and automorphic and striated crystal often coexists (Fig. 5-P9 and P10). The fault dips are greater in the Bajocian-Bathonian and Callovian units (Fig. 5-P6 and P7) than in the Hettangian to Pliensbachian unit (Fig. 5-P5). In addition, dip angles increase upward from the old to the younger sedimentary units (Fig. 6). The stress tensors we calculated for each station are consistent with one another: $σ_1$ is vertical while the
<figure><img src="image_7.png" /><figcaption>**Fig. 6.** Structural data of the Jard-sur-Mer sedimentary cover. A: Stereographic projection of faults and related stress tensors (full circles), and fault dips (quarter circles); B: Rose diagrams of vein strikes. See Figure 2 for the location of structural measurements in map and in the stratigraphic series.</figcaption></figure>

horizontal $σ_2$ and $σ_3$ are striking between N90 to N110 and N0 to N20, respectively (Fig. 6). In addition, we mapped 183 lineaments on Google Earth® from aerial and satellite imagery and controlled their occurrence on the rocky foreshore during field work (Fig. 7). These lineaments can reach up to 1 km long because they are roughly parallel to the shoreline and not limited by the width of the rocky foreshore. These lineaments display consistent apparent directions: 80% of their strikes range between N100 and N130 (Fig. 7E). Our field observations indicate that these lineaments correspond to brittle structures, i.e. faults and mineralized veins. While their orientations seem relatively constant, there is a noticeable decrease in their density from the base of the Bajocian-Bathonian unit to the top of the Callovian one (Figs. 7A–7D). This upward decrease is validated by our field observations of the coastal cliff. Indeed, we carried out 36 measurements of striated fault planes at the base of the Bajocian-Bathonian unit (Fig. 2 and Fig. 6-S4), 18 measurements in its middle part (Fig. 6-S5) but we found only 12 striated planes on the 2500 m long shoreline east of the Jard-sur-Mer harbor (Fig. 6-S6).

Within the lower part of the well-exposed Bajocian-Bathonian unit immediately east of the Anse St-Nicolas, we observed mineralized veins that contain barite, sulfides and quartz crystals following the same crystallization sequence as in the previously detailed Hettangian to Pliensbachian unit (Fig. 5-P8; see Sect. 4.2). Going upward within the Bajocian-Bathonian and the Callovian units, the veins are mostly composed of calcite. However, calcite was not observed in direct association with other minerals and its timing of

crystallization relative to barite, sulfides and quartz remains unconstrained.

# 5 Interpretation and discussion

## 5.1 The structural record of the late Jurassic N-S tectonic extension

Our observations and measurements of faults in the Jard-sur-Mer area are consistent within the Hettangian to Pliensbachian, Bajocian-Bathonian and Callovian units, including the pair that affects the basement. They indicate the preservation of a normal faulting event with a vertical $σ_1$ and horizontal $σ_2$ and $σ_3$ with striking direction ranging between N90° to N110 and between N0 to N20, respectively (Fig. 6-S1, S4, S5, S6). These results are coherent with the orientation of mineralized veins with strike directions ranging from N90 to N120 and nearly vertical dips (Fig. 6-S3, S4, S6), and with crystal growth directions orthogonal to vein boundaries. We interpret this good agreement between fault and vein orientations, together with the coexistence of automorphic and striated crystals of quartz and barite along fault planes (Fig. 5-P9 and P10) as evidence that the tectonic and fluid migration events are coeval.

The fluid event, that is assumed to be of regional importance (Fig. 1) was dated between 146 and 156 Ma (Kimmeridgian to Tithonian) in several places of the Poitou High (Cathelineau *et al.*, 2012). This lead us to propose a similar age for the fluid and brittle tectonic event in the Jard-sur-Mer area. In addition, very consistent NNE-SSW
<figure><img src="image_8.png" /><figcaption>**Fig. 7.** A, B, C and D lineament maps of the Jard sur mer area plotted over Google Earth images (acquisition date: 03/09/2014) and E: rose diagram of the lineament strikes. See Figure 2 for location.</figcaption></figure>

directions of extension dated from late Jurassic time are deduced i) from brittle structures analysis of the Poitou High area (Karnay et al., 2004; Cariou et al., 2006), ii) from a mineralized veins study of the western boundary of the French Massif Central (Munoz et al., 2005) and iii) from regional thickness variations of Kimmeridgian deposits (Thomas et al., 1996). These results suggest a Kimmeridgian-Tithonian tectonic event of regional importance (Fig. 1) and lead us to interpret i) the NNE-SSE extension faulting we observed as part of this event and ii) that fluids-related mineralization are coeval with it.

At the scale of the Aquitaine Basin, this event is interpreted as the onset of individualization of the sub-basins to extreme crustal thinning prior to the onset of oceanic accretion in the Bay of Biscay in latest Aptian-earliest Albian (Montadert et al., 1979; Curnelle and Dubois, 1986; Jammes et al., 2010; Tugend et al., 2015; Nirrengarten et al., 2018). Thus, our observations on the Jard-sur-Mer area, together with previous studies (Thomas et al., 1996; Karnay et al., 2004; Munoz et al., 2005; Cariou et al., 2006) suggest that the earliest stage of extension propagates far from the central part of the Aquitaine Basin and reaches its northern boundaries.

## 5.2 Geological evidences for fluid overpressure

In addition to coeval fluids circulations and brittle tectonics, our results show three main points regarding fluid overpressure within the Hettangian unit. First, we document for the first time the occurrence of breccias characterized by angular fragments of dolomitic limestones cemented by barite (Fig. 4-P3). These form a peculiar jigsaw puzzle pattern often interpreted as fluid-assisted brecciation in a context of fluid overpressure (Jebrak, 1997; Sibson 1986; Tartarotti and Pasquaré, 2003; Chi and Xue, 2011).

Second, we describe flat lying veins with crystals that grow orthogonally to vein borders (Fig. 4-P2 and P4). Following other studies in different basin areas, we propose that such horizontal veins and crystal growth indicate that fluid pressure has exceeded the lithostatic pressure and produced hydraulic fractures (Cobbold and Rodrigues, 2007; Chi and Xue, 2011; Cobbold et al., 2013).

Third, we illustrate that normal fault dip angles decrease downward within the sedimentary cover to display listric pattern near the Hercynian unconformity (Fig. 5-P5). Such a decrease corresponds to a decrease of the internal friction angle of the faulted material near the base of the Mesozoic series that cannot be explained by lithological changes. We propose that the decrease of the internal friction angle was due to an increase of the fluid pressure and lead to the formation of a “décollement” level as observed in several other tectonic contexts (Davis et al., 1983; Dahlen 1984; Mourgues and Cobbold, 2006; Collettini, 2011).

Because these structures are limited to the Hettangian to Pliensbachian unit, we propose that fluid overpressure is partly responsible for the rupture of the sedimentary cover in a state of stress compatible with the N-S to NNE-SSW direction of extension. Fluid overpressure might also explain mechanical decoupling at the base of the sedimentary cover.

## 5.3 Fluids and tectonics interaction in the Jard-sur-Mer area

Cathelineau et al. (2012) provided Th and salinities estimates on fluids related to mineralization of the Anse St-Nicolas and an area located 6 km north called Les Sards mine. These authors estimated Th and salinities ranging from 100 to 280 °C and from 4–7 to 20–21 wt.% eq. NaCl on quartz and geodic quartz within the Hettangian to Pliensbachian units (Fig. 8B). Within fractures of the Callovian unit, they obtained temperature and salinities ranging from 120 to 220 °C and from 2–3 to 3–5 wt.% eq. NaCl (Fig. 8B).

Assuming this and considering fluids mixing as already proposed on the northern part of Aquitaine basin (Boiron et al., 2002; Fourcade et al., 2002; Cathelineau et al., 2012), we propose that the fluids of highest salinity values were probably present within the Hettangian to Pliensbachian units prior to faulting event, as this is not documented above in faults and veins affecting the Mesozoic series. Such fluids could represent the earliest sources of mineralization on our area and are related to sedimentary brines (Fig. 8B). Following this assumption, the decrease of salinity values together with the slight increase of Th within the Hettangian to Pliensbachian units could be related to the increase of the amount of low
<figure><img src="image_9.png" /><figcaption>**Fig. 8.** A: a possible five-step fluid and tectonic evolution of the Aquitaine basin in the Jard-sur-Mer Area during the Jurassic (see text for explanations). B: Salinity and temperature evolution of fluids during stages 3 to 5 (modified after Cathelineau *et al.*, 2012). 1: anhedral quartz from Hettangian unit, 2: geodic quartz from Hettangian unit, 3: quartz within fault planes of the Bathonian unit, 4: geodic quartz following barite from the Hettangian unit.</figcaption></figure>

salinity and high temperature hydrothermal water released from the Hercynian basement at the onset N-S extension. Graded color changes observed in the basement below the Hercynian unconformity of the Jard-sur-Mer area (Fig. 4-P1) have also been described in the Seuil du Poitou area (Cathelineau *et al.*, 2012) and interpreted as alteration related to fluids circulations. Similar observations around of basement fault planes lead us to propose that fluids related to baryte deposits have circulated within the inherited basement faults.

In the Jard-sur-Mer area, mixing fluids are also described in veins from the Callovian unit (Cathelineau *et al.*, 2012) suggesting that overpressure results from the inflow of low salinity and high temperature water within the Hettangian to Pliensbachian units (Fig. 8B). The wide range of Th with no significant salinity changes in veins present in the Callovian unit is explained by the cooling of mixed fluids as they flow through the sedimentary cover.

Therefore, we propose that an inflow of a low salinity water heated at depth as already described (Boiron *et al.*, 2002; Fourcade *et al.*, 2002; Cathelineau *et al.*, 2012) is responsible for fluids overpressure at the base of the Aquitaine Basin and the formation of brittle structures such as veins and normal faults in the overlying cover.

## 5.4 possible scenario for fluids and tectonic interaction (Fig. 8)

This scenario of fluids and tectonic structures interactions is summarized in a five-stage scenario (Fig. 8):

- **Stage 1 (Middle Jurassic):** High salinity and low temperature (hs-lt) brines were expelled from Triassic to Lower Jurassic evaporites located in the central part of the Aquitaine Basin according to Boiron *et al.* (2002), Fourcade *et al.* (2002) and Cathelineau *et al.* (2012). Brines migrated along the sediment cover/basement and reached the Jard-sur-Mer area in a context of Mississipi Valley type deposit. Long lasting subsidence during the Jurassic (Brunet, 1994) suggests that such a process may have occurred prior to the tectonic event.

- **Stage 2 (Upper Jurassic):** The Aquitaine Basin recorded an N-S extensional tectonic phase. This was responsible for the formation of several E-W normal fault affecting the basement and cover (Fig. 1B) while this change of stress constraints probably affected the preexisting fracture network, therefore inducing porosity changes. Deformation is dated from the upper Jurassic (Thomas *et al.*, 1996; Karnay *et al.*, 2004; Cariou *et al.*, 2006).

- **Stage 3 (Upper Jurassic):** A second fluids consisting of Low salinity and high temperature hydrothermal water (ls-ht) was released from the Hercynian basement (Boiron *et al.*, 2002; Fourcade *et al.*, 2002; Cathelineau *et al.*, 2012). It migrated upward along inherited late Hercynian brittle structures and reached the discontinuity.

- **Stage 4 (Upper Jurassic):** hs-lt brines and ascending ls-ht hydrothermal water mixed together and lead to the formation of the first mineral deposits. Mean salinity decreased whilst temperature increased up to 250 °C. Assuming a possible 30 to 50 °C geothermal gradient, such a temperature suggests that ascending ls-ht water were released several kilometers deep. As a consequence of the new influx at the base of the Aquitaine Basin, fluid overpressure started to increase within the Hettangian to Pliensbachian unit, and internal friction angle began to progressively decrease.

- **Stage 5 (Upper Jurassic):** Under sufficiently overpressured conditions the sedimentary cover started to fracture, leading to the formation of E-W veins and normal faults filled with mineral deposits. Within the Hettangian to Pliensbachian units, the low internal friction angle was responsible for the formation of listric faults and fault dip angles became steeper in the overlying Bajocian-Bathonian and Callovian units.

Such a scenario is possibly unique in the northern part of the Aquitaine Basin as mineral deposits are limited to Hettangian to Pliensbachian units elsewhere (Boiron *et al.*, 2002; Fourcade *et al.*, 2002; Cathelineau *et al.*, 2012). In these locations, higher minimum salinity and lower maximum
temperature suggests a smaller contribution of ascending Is-ht
hydrothermal water than in the Jard-sur-Mer area. Thus fluids
overpressure cannot be ruled out but it was probably not
sufficient to initiate brittle structures.

In the southern part of the Aquitaine Basin, structures and mineral deposits related to fluid overpressure have also been described (Salardon et al., 2017; Renard et al., 2019). However, fluid circulations and fluid overpressure are suspected to have occurred during extreme crustal extension associated with the opening of the Bay of Biscay and to interact with exhumed mantle (Salardon et al., 2017; Corre et al., 2018, Renard et al., 2019).

6 Conclusion

Structural analysis of brittle structures together with field
observations of numerous mineralized deposits of the Jard-sur-
Mer area (north of the Aquitaine Basin) highlight the record of
a N-S to NNE-SSW extension phase dated from Kimmeridgian
to Tithonian times representative of a regional state of stress.
Major decoupling between basement and cover, horizontal
veins and hydraulic breccias suggest that basement-trapped
fluids and sedimentary brines interacted at the Hercynian
unconformity and underwent overpressure. The fluid over-
pressure is proposed to have resulted from the ascent of low
salinity water along inherited late Hercynian brittle structures
and released at the onset of the N-S to NNE-SSW extension
phase. Observed fluid temperatures are consistent with a fluid
source several kilometre deep into the continental crust.

*Acknowledgments*. Research presented in this article has been supported by the INSU-CNRS program: TELLUS-CESSUR. The authors thank Guillaume Barré and Joseph Barraud. The manuscript was greatly improved by constructive reviews from Aurélien Gay and Philippe Boulvais.

References

Aarnes I, Podladchikov Y, Svensen H. 2012. Devolatilization-induced pressure build-up: Implications for reaction front movement and breccia pipe formation. *Geofluids*. https://doi.org/10.1111/j.1468-8123.2012.00368.x

Allmendinger RW, Cardozo N, Fisher DM. 2011. Structural Geology Algorithms: Vectors and Tensors. https://doi.org/10.1017/CBO9780511920202.

Anderson GM, Macqueen RW. 1982. Ore deposit models. 6. Mississippi valley-type lead-zinc deposits. *Geosci. Canada* 9: 108-117.

Andresen KJ. 2012. Fluid flow features in hydrocarbon plumbing systems: What do they tell us about the basin evolution? *Mar. Geol.* https://doi.org/10.1016/j.margeo.2012.07.006.

Angrand P, Ford M, Watts AB. 2018. Lateral Variations in Foreland Flexure of a Rifted Continental Margin: The Aquitaine basin (SW France). *Tectonics*. https://doi.org/10.1002/2017TC004670.

Ballèvre M, Bosse V, Ducassou C, Pitra P. 2009. Palaeozoic history of the Armorican Massif: Models for the tectonic evolution of the suture zones. *Comptes Rendus Geosci*. https://doi.org/10.1016/j.crte.2008.11.009.

Barré G, Strzerzynski P, Michels R, Guillot S, Cartigny P, Thomassot E, et al. 2020. Tectono-metamorphic evolution of an evaporitic décollement as recorded by mineral and fluid geochemistry:

The "Nappe des Gypses" (Western Alps) case study. *Lithos*. https://doi.org/10.1016/j.lithos.2020.105419.

Beaudoin N, Lacombe O, Bellahsen N, Amrouch K, Daniel JM. 2014. Evolution of pore-Fluid pressure during folding and basin contraction in overpressured reservoirs: Insights from the Madison-Phosphoria carbonate formations in the Bighorn basin (Wyoming, USA). *Mar. Pet. Geol.* 55: 214–229. https://doi.org/10.1016/j.marpetgeo.2013.12.009.

Bessin P, Guillocheau F, Robin C, Schroëtter J-M, Bauer H. 2015. Planation surfaces of the Armorican Massif (western France): Denudation chronology of a Mesozoic land surface twice exhumed in response to relative crustal movements between Iberia and Eurasia. *Geomorphology* 233. https://doi.org/10.1016/j.geo morph.2014.09.026.

Bétard F. 2010. Uplift and denudation history at low-elevation passive margins: Insights from morphostratigraphic analysis in the SE Armorican Massif along the French Atlantic margin. *Comptes Rendus Geosci*. https://doi.org/10.1016/j.crte.2010.02.004.

Biteau J-J, Le Marrec A, Le Vot M, Masset J-M. 2006. The Aquitaine basin. *Pet. Geosci.* 12: 247–273. https://doi.org/10.1144/1354-079305-674.

Boiron MC, Cathelineau M, Banks DA, Buschaert S, Fourcade S, Coulibaly Y, et al. 2002. Fluid transfers at a basement/cover interface Part II. Large-scale introduction of chlorine into the basement by Mesozoic basinal brines. *Chem. Geol.* 192: 121–140. https://doi.org/10.1016/S0009-2541(02)00191-2.

Brunet MF. 1994. Subsidence in the Parentis Basin (Aquitaine, France): Implications of the thermal evolution. In: Mascle A, ed. *Exploration and Petroleum Geology of France*. Eur. Assoc. Petrol. Geosci. Spec. Publ. 4: 181–192. https://doi.org/10.1007/978-3-642-78849-9_14.

Bureau D, Mourgues R, Cartwright J, Foschi M, Abdelmalak MM. 2013. Characterisation of interactions between a pre-existing polygonal fault system and sandstone intrusions and the determination of paleo-stresses in the Faroe-Shetland basin. *J. Struct. Geol.* 46: 186–199. https://doi.org/10.1016/j.jsg.2012.09.003.

Bjørlykke K. 1993. Fluid flow in sedimentary basins. *Sediment. Geol.* https://doi.org/10.1016/0037-0738(93)90137-T.

Cariou É, Poncet D, Colchen M, Karnay G, Becq-Giraudon J-F, Lemordant Y, et al. 2006. Notice explicative, Carte géol. France (1/50 000), feuille Saint-Maixent-l'École (611). Orléans: BRGM, 132 p.

Cathelineau M, Boiron MC, Fourcade S, Ruffet G, Clauer N, Belcourt O, et al. 2012. A major Late Jurassic Fluid event at the basin/basement unconformity in western France: 40Ar/39Ar and K-Ar dating, Fluid chemistry, and related geodynamic context. *Chem. Geol.* 322-323: 99–120. https://doi.org/10.1016/j.chem geo.2012.06.008.

Chantraine J, Autran A, Cavelier C, et al. 1996. Carte géologique de la France à l'échelle du millionième, 6ᵉ éd. Orléans: BRGM.

Chi G, Xue C. 2011. An overview of hydrodynamic studies of mineralization. *Geosci. Front.* 2: 423–438. https://doi.org/10.1016/j.gsf.2011.05.001.

Cobbold PR, Rodrigues N. 2007. Seepage forces, important factors in the formation of horizontal hydraulic fractures and bedding-parallel fibrous veins ("beef" and "cone-in-cone"). *Geo Fluids* 7: 313–322. https://doi.org/10.1111/j.1468-8123.2007.00183.x.

Cobbold PR, Zanella A, Rodrigues N, Løseth H. 2013. Bedding-parallel fibrous veins (beef and cone-in-cone): Worldwide occurrence and possible significance in terms of Fluid overpressure, hydrocarbon generation and mineralization. *Mar. Pet. Geol.* 43: 1–20. https://doi.org/10.1016/j.marpetgeo.2013.01.010.
Collettini C. 2011. The mechanical paradox of low-angle normal faults: Current understanding and open questions. *Tectonophysics*. https://doi.org/10.1016/j.tecto.2011.07.015.

Corre B, Boulvais P, Boiron MC, Lagabrielle Y, Marasi L, Clerc C. 2018. Fluid circulations in response to mantle exhumation at the passive margin setting in the north Pyrenean zone, France. *Mineral. Petrol.* 112: 647–670. https://doi.org/10.1007/s00710-018-0559-x.

Crognier N, Hoareau G, Aubourg C, Dubois M, Lacroix B, Branellec M, et al. 2018. Syn-orogenic fluid flow in the Jaca basin (south Pyrenean fold and thrust belt) from fracture and vein analyses. *Basin Res.* 30: 187–216. https://doi.org/10.1111/bre.12249.

Curnelle R, Dubois P. 1986. Evolution mesozoique des grands basins sedimentaires français; basins de Paris, d'Aquitaine et du Sud-Est. *Bull. la Société Géologique Fr.* II: 529–546. https://doi.org/10.2113/gsgfbull.II.4.529.

Dahlen FA. 1984. Noncohesive Critical Coulomb Wedges: An Exact Solution. *J. Geophys. Res.* https://doi.org/10.1029/JB089iB12p10125.

Davis D, Suppe J, Dahlen FA. 1983. Mechanics of fold-and-thrust belts and accretionary wedges. *J. Geophys. Res.* https://doi.org/10.1029/JB088iB02p01153.

Enay R, Mangold C, Cariou E, Contini D, Debrand-Passard S, Donze P, et al. 1980. Synthèse paléogéographique du Jurassique Français. Doc. du Lab. géologie, Lyon Hors-Série, 210.

Ford M, Hemmer L, Vacherat A, Gallagher K, Christophoul F. 2016. Retro-wedge foreland basin evolution along the ECORS line, eastern Pyrenees, France. *J. Geol. Soc.* London. https://doi.org/10.1144/jgs2015-129.

Fourcade S, Michelot JL, Buschaert S, Cathelineau M, Freiberger R, Coulibaly Y, et al. 2002. Fluid transfers at the basement/cover interface: Part I. Subsurface recycling of trace carbonate from granitoid basement rocks (France). *Chem. Geol.* 192: 99–119. https://doi.org/10.1016/S0009-2541(02)00192-4.

François T, Barbarand J, Wyns R. In press. Early Cretaceous inversion of the European Variscan basement: record from the Vendée and Limousin (France). *International Journal of Earth Sciences*.

Frazer M, Whitaker F, Hollis C. 2014. Fluid expulsion from overpressured basins: Implications for Pb-Zn mineralisation and dolomitisation of the East Midlands platform, northern England. *Mar. Pet. Geol.* 55: 68–86. https://doi.org/10.1016/j.marpetgeo.2014.01.004.

Freiberger R, Boiron M-C, Cathelineau M, Cuney M, Buschaert S. 2001. Retrograde P–T evolution and high temperature–low pressure Fluid circulation in relation to late Hercynian intrusions: a mineralogical and Fluid inclusion study of the Charroux-Civray plutonic complex (north-western Massif Central, France). *Geo Fluids* 1: 241–256. https://doi.org/10.1046/j.1468-8123.2001.00019.x.

Garven G, Raffensperger JP. 1997. Hydrogeology and geochemistry of ore genesis in sedimentary basins. In: Barnes HL, ed. *Geochemistry of Hydrothermal Ore Deposits*, 3rd ed. New York: John Wiley and Sons, pp. 125–189.

Gay A, Migeon S. 2017. Geological fluid flow in sedimentary basins. *Bull. la Société Géologique Fr.* 188. https://doi.org/10.1051/bsgf/2017200.

Gigoux M, Delpech G, Guerrot C, Pagel M, Augé T, Négrel P, et al. 2015. Evidence for an Early Cretaceous mineralizing event above the basement/sediment unconformity in the intracratonic Paris basin: paragenetic sequence and Sm-Nd dating of the world-class Pierre-Perthuis stratabound fluorite deposit. *Miner. Depos*. https://doi.org/10.1007/s00126-015-0592-1.

Gigoux M, Brigaud B, Pagel M, Delpech G, Guerrot C, Augé T, et al. 2016. Genetic constraints on world-class carbonate- and silici-

clastic-hosted stratabound fluorite deposits in Burgundy (France) inferred from mineral paragenetic sequence and Fluid inclusion studies. *Ore Geol. Rev.* https://doi.org/10.1016/j.oregeov.2015.09.013.

Goujou JC, Debrand-Passard S, Hantzpergue P, Lebret P, Blouin JP, Callier L, et al. 1994. Notice explicative, Carte géol. France (1/50 000), feuille Les Sables d'Olonne-Longeville (584). Orléans: BRGM, 95 p. Carte géologique par M. Ters, J. Gabilly (1986).

Huerta P, Proust J-N, Guennoc P, Thinon I. 2010. Seismic stratigraphy of the Vendean-Armorican platform of the French Atlantic shelf: new insights into the history of the North Atlantic ocean. *Bull. la Société Géologique Fr.* 181: 37–50. https://doi.org/10.2113/gsgfbull.181.1.37.

Jammes S, Tiberi C, Manatschal G. 2010. 3D architecture of a complex transcurrent rift system: The example of the Bay of Biscay-Western Pyrenees. *Tectonophysics*. https://doi.org/10.1016/j.tecto.2010.04.023.

Jebrak M. 1997. Hydrothermal breccias in vein-type ore deposits: A review of mechanisms, morphology and size distribution. *Ore Geology Reviews* 12: 111–134.

Karnay G, Tereygeol F, Charnet F, Chevremont P, Thieblemont D, Becq-Giraudon J-F, et al. 2004. Notice explicative, Carte géol. France (1/50 000), feuille Melle (636). Orléans: BRGM, 82 p.

Laurent D, Lopez M, Chauvet A, Sauvage AC, Buatier M. Spangenberg JE. 2017. Sedimentary fluids/fault interaction during syn-rift burial of the Lodève Permian basin (Hérault, France): An example of seismic-valve mechanism in active extensional faults. *Mar. Pet. Geol.* https://doi.org/10.1016/j.marpetgeo.2017.08.021.

Leach DL, Dwight B, Lewchuk MT, Symons DTA, de Marsily G, Brannon J. 2001. Mississippi Valley-type lead-zinc deposits through geological time: implications from recent age-dating research. *Miner. Depos.* 36: 711–740. https://doi.org/10.1007/s001260100208.

Leach D, Macquar JC, Lagneau V, Leventhal J, Emsbo P, Premo W. 2006. Precipitation of lead-zinc ores in the Mississippi Valley-type deposit at Trèves, Cévennes region of southern France. *Geo Fluids*. https://doi.org/10.1111/j.1468-8123.2006.00126.x.

Leach DL, Taylor RD, Fey DL, Diehl SF, Saltus RW. 2010. A deposit model for Mississippi Valley-Type lead-zinc ores, chap. A. In: *Mineral Deposit Models for Resource Assessment*. U.S. Geological Survey Scientific Investigations Report 2010-5070-A, 52 p.

Lelandais T, Mourgues R, Ravier É, Pochat S, Strzerzynski P, Bourgeois O. 2016. Experimental modeling of pressurized subglacial water flow: Implications for tunnel valley formation. *J. Geophys. Res. Earth Surf.* 121: 2022–2041. https://doi.org/10.1002/2016JF003957.

Masson DG, Miles PR. 1984. Mesozoic sea-floor spreading between Iberia, Europe and North America. *Marine Geology* 56: 279–289.

Mouchet JP, Mitchell A. 1989. Abnormal Pressure While Drilling. Manuals Techniques 2. Boussens, France: Elf Aquitaine Editions.

Mourgues R, Cobbold PR. 2006. Sandbox experiments on gravitational spreading and gliding in the presence of fluid overpressures. *J. Struct. Geol.* https://doi.org/10.1016/j.jsg.2005.12.013.

Montadert L, Roberts DG, De Charpal O, Guennoc P. 1979. Rifting and subsidence of the northern continental margin of the Bay of Biscay. Initial reports Deep Sea Drill. Proj. Leg 48, Brest, Fr. to Aberdeen, Scotland, 1976, (Scripps Inst. Oceanogr. UK Distrib. IPOD Committee, NERC, Swindon). https://doi.org/10.2973/dsdp.proc.48.154.1979.

Munoz M, Premo WR, Courjault-Radé P. 2005. Sm-Nd dating of fluorite from the worldclass Montroc fluorite deposit, southern
Massif Central, France. *Miner. Depos*. https://doi.org/10.1007/s00126-004-0453-9.

Nirrengarten M, Manatschal G, Tugend J, Kusznir N, Sauter D. 2018. Kinematic Evolution of the Southern North Atlantic: Implications for the Formation of Hyperextended Rift Systems. *Tectonics*. https://doi.org/10.1002/2017TC004495.

Ortiz A, Guillocheau F, Lasseur E, Briais J, Robin C, Serrano O, et al. 2020. Sediment routing system and sink preservation during the post-orogenic evolution of a retro-foreland basin: The case example of the North Pyrenean (Aquitaine, Bay of Biscay) Basins. *Mar. Pet. Geol*. https://doi.org/10.1016/j.marpetgeo.2019.104085.

Osborne MJ, Swarbrick RE. 1997. Mechanisms for generating overpressure in sedimentary basins: A reevaluation. *AAPG Bulletin* 81: 1023–1041.

Paradis S, Hannigan P, Dewing K. 2007, Mississippi Valley-type lead-zinc deposits. In: Goodfellow WD, ed. *Mineral Deposits of Canada: A Synthesis of Major Deposit-Types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods*. Geological Association of Canada, Mineral Deposits Division, Special Publication No. 5, pp. 185–203.

Renard S, Pironon J, Sterpenich J, Carpentier C, Lescanne M, Gaucher EC. 2019. Diagenesis in Mesozoic carbonate rocks in the North Pyrénées (France) from mineralogy and Fluid inclusion analysis: Example of Rousse reservoir and caprock. *Chem. Geol*. https://doi.org/10.1016/j.chemgeo.2018.06.017.

Rice JR. 1992. Fault Mechanics and Transport Properties of Rocks – A Festschrift in Honor of W.F. Brace. *International Geophysics*. https://doi.org/10.1016/S0074-6142(08)62835-1.

Robb L. 2005. Introduction to ore-forming processes. Blackwell Science, 373 p.

Salardon R, Carpentier C, Bellahsen N, Pironon J, France-Lanord C. 2017. Interactions between tectonics and Fluid circulations in an inverted hyper-extended basin: Example of mesozoic carbonate rocks of the western North Pyrenean Zone (Chaînons Béarnais, France). *Mar. Pet. Geol*. https://doi.org/10.1016/j.marpetgeo.2016.11.018.

Sibson RH. 1986. Brecciation processes in fault zones: Inferences from earthquake rupturing. *Pure Appl. Geophys*. PAGEOPH. https://doi.org/10.1007/BF00875724.

Sizaret S, Marcoux E, Jebrak M, Touray JC. 2004. The Rossignol fluorite Vein, Chaillac, France: Multiphase hydrothermal activity and intravein sedimentation. *Econ. Geol*. https://doi.org/10.2113/gsecongeo.99.6.1107.

Sizaret S, Marcoux E, Boyce A, Jebrak M, Stevenson R, Ellam R. 2009. Isotopic (S, Sr, Sm/Nd, D, Pb) evidences for multiple sources

in the Early Jurassic Chaillac F-Ba ore deposit (Indre, France). *Bull. la Soc. Geol. Fr*. https://doi.org/10.2113/gsgfbull.180.2.83.

Suppe J. 2014. Fluid overpressures and strength of the sedimentary upper crust. *J. Struct. Geol*. https://doi.org/10.1016/j.jsg.2014.07.009.

Sverjensky DA. 1986. Genesis Of Mississippi Valley Type Lead-Zinc Deposits. *Ann. Rev. Earth Planet. Sci.* 14: 177–199. https://doi.org/10.1146/annurev.ea.14.050186.001141.

Swarbrick RE, Osborne MJ, Yardley GS. 2004. Comparison of overpressure magnitude resulting from the main generating mechanisms. *AAPG Mem*.

Tartarotti P, Pasquaré FA. 2003. Basaltic breccias in the upper oceanic crust, hole 504B (Costa Rica Rift, Pacific ocean). *Ofioliti*.

Ters M. 1988. La Vendée littorale. Étude géomorphologique. Thèse de Doctorat d'État. Université Rennes 1, France.

Thomas G, Permanyer A, Delfaud J, Biteau JJ, Lagarigue JL, Le Marrec A. 1996. Géométrie des dépôts de la formation de Lons (Kimméridgien, bassin d'Aquitaine). Interprétation structurale. *Bull. la Soc. Geol. Fr*.

Tingay MRP, Hillis RR, Swarbrick RE, Morley CK, Damit AR. 2009. Origin of overpressure and pore-pressure prediction in the Baram province, Brunei. *Am. Assoc. Pet. Geol. Bull*. https://doi.org/10.1306/08080808016.

Tugend J, Manatschal G, Kusznir NJ. 2015. Spatial and temporal evolution of hyperextended rift systems: Implication for the nature, kinematics, and timing of the Iberian–European plate boundary. *Geology*. https://doi.org/10.1130/G36072.1.

Turrillot P, Augier R, Monié P, Faure M. 2011. Late orogenic exhumation of the variscan high-grade units (South Armorican Domain, western France), combined structural and $^{40}$Ar/$^{39}$Ar constraints. *Tectonics*. https://doi.org/10.1029/2010TC002788.

Vergés J, García Senz JM. 2001. Mesozoic Evolution and Cenozoic Inversion of the Pyrenean Rift. In: Ziegler PA, Cavazza W, Robertson AHF, Crasquin-Soleau S, eds. *Peri-Tethys Memoir 6: Pery-Tethyan Rift/Wrench basins and Passive Margins*. Mémोires Muséum National d'Histore Naturelle, 186: Paris, pp. 187–212.

Wyns R. 1991. Evolution tectonique du bati armoricain oriental au Cenozoique d'après l'analyse des paleosurfaces continentales et des formations geologiques associees. *Geol. la Fr*. 1991: 11-42.

Zanella A, Cobbold PR, Boassen T. 2015. Natural hydraulic fractures in the Wessex basin, SW England: Widespread distribution, composition and history. *Mar. Pet. Geol*. https://doi.org/10.1016/j.marpetgeo.2015.09.005.

**Cite this article as:** Strzerzynski P, Lenoir L, Bessin P, Bouat L. 2020. Brittle tectonics and fluids overpressure during the early stage of the Bay of Biscay opening in the Jard-sur-Mer area, (northern Aquitaine Basin, France), BSGF - *Earth Sciences Bulletin* 191: 38.