<figure><img src="image_46.png" /><figcaption>**Figure 32.** (a) Schematic loop representing the proposed computational steps and workflow required to model the reciprocal interaction between LSPs and acoustic vibrations. (b) Protocol for the export/import of the deformed surface into the Comsol modules.</figcaption></figure>

Once the Maxwell stress tensor is constructed, we will then be able to compute the optical forces induced on the nanoparticle surface (Figure 31a). By introducing the strain tensor and some notions of elastic theory, we will be able to visualize the NP deformation under the action of the elastic energy imposed by the quantum fluctuations of the electromagnetic field (Figure 31b). These optomechanical constraints will then be used as input into the elastodynamics calculations (Comsol's *Structural Mechanics* module) to study the effect of the plasmon-induced optical forces on the acoustic vibrations. This can be done *via* a surface-force formalism where we directly import the optical forces into the FEM model.

## B. Multidimensional Periodic Systems

### 1. Surface Lattice Resonances in Plasmonic Periodic Structures

My research activity on periodic nanoparticle arrangements, including 1D chains, 2D arrays, and 3D supercrystals has increased over the recent years. Currently, I have an ongoing collaboration with Dr. Rémi Vincent at the Université de Technologie de Troyes (UTT), which focuses on the optical properties of 2D hybrid arrays composed of aluminum nanoparticles. This collaboration, currently funded by the Thomas Jefferson Fund of the FACE Foundation, will be continued and expanded. Plans for a 3-month long research visit at UTT are currently underway. The newly-developed photonic band structure calculation method, will allow me to model the experimentally-fabricated finite-size arrays with greater accuracy and study photonic edge modes and in-plane Fabry-Pérot resonances. One of my former undergraduate students (Rudin Kraja) has already obtained very promising results on finite-size effects in 2D nanoparticle arrays (cf. Section D.5. in Chapter 2). This study, which used EELS calculations to investigate these effects, has led a publication. Further work will make complementary use of both EELS and photonic band structure calculations to study the plasmonic properties of a wider range of periodic structures. One system of interest consists of a periodic array of plasmonic nanoparticles with interparticle distances satisfying the conditions to sustain Rayleigh anomalies (RAs). When RAs are formed, they can couple to the LSP modes of the individual nanoparticles and form surface lattice resonances (SLRs), also known as lattice plasmons (Figure 33a, blue spectrum). These delocalized hybrid
polaritonic modes will be the subject of futures research efforts I will lead as they have yet to be fully studied using electron-based spectroscopies such as EELS.

## 2. New Polaritonic Modes in Hybrid Plexcitonic Periodic Structures

Another major long-term project concerns the fundamental study of multi-dimensional, multi-composition periodic nanoparticle arrangements. The goal is to computationally design new hybrid multidimensional arrangements of plasmonic and excitonic materials (1D chains, 2D arrays, 3D superlattices). I hypothesized that these hybrid systems, if carefully designed, can sustain new polaritonic modes resulting from the threefold interaction between the localized surface plasmon, exciton, and photonic modes. Preliminary results obtained by one of my graduate students (Michael Brinkman) suggest that such complex interactions occur in 2D plexcitonic arrays (Figure 33a,b). It will be important to determine their dispersion relation, their dependence on optical excitation and geometrical parameters and finite-size effects. In addition to EELS and photonic band structure calculations, we will also focus on the development of a generalized framework for modeling coupled harmonic oscillators (Figure 33c), obtaining the scattering and absorption spectra of coupled systems. The proposed generalized method will be applied to our periodic plexcitonic arrangements, which exhibit three resonances (photonic, plasmonic, and excitonic). In particular, we will use the coupled mode theory (CMT), which takes a perturbative approach to analyzing the coupling of resonators in space or time. Here, we are interested in generalizing the temporal CMT and extending the formalism presented by Suh et al.¹⁴⁴ The development of such tool will be very valuable for identifying and establishing that novel hybrid excitations observed in the photonic band structures and imaged in EELS are the result of trifold hybridizations between the excitonic, plasmonic, and photonic modes. It will allow for (i) a rapid scan of the parameter space to identify the key parameters, which will lead to specific coupling regimes, and (ii) extracting relevant physical quantities such as coupling constants, Rabi splitting energy, and damping rates.

<figure><img src="image_47.png" /><figcaption>**Figure 33.** (a) Calculated transmission spectra of a AuNP (blue), PbS QD (green), and hybrid Au@PbS NP (red) arrays showing the formation of 3 hybrid polaritonic modes. (b) Photonic band structure of a Au@PbS array showing complex hybridization between the plasmon, exciton, and photonic modes. (c) Simple model of 3 coupled harmonic oscillators representing the trifold photonic-plasmonic-excitonic hybridization scheme.</figcaption></figure>

Finally, if some hybrid periodic structures are found to be of interest and sustain new hybrid polaritonic modes, I will further engage in collaborations with experimental group. In particular, the group of Dr. Teri Odom at Northwestern University, which has pioneered the field of lattice plasmons,⁷¹ will be valuable for the experimental validation of my theoretical results. Currently, Dr. Odom and I serve as co-PIs on a NSF-funded project which focuses on
the use of 2D plasmonic arrays as optical cavities for polariton-driven chemistry. This project is still in the early stage and will be further expanded in the coming years.

### C. Photothermal and Thermo-Optical Properties

#### 1. Temperature Effects on the Plasmon-Exciton Coupling

In the area of photothermal effects the development of a self-consistent approach for the modeling of temperature-dependent optical properties in plasmon-exciton and plasmon-phonon models is critical. Plasmon-induced heating can lead to temperature changes of tens of degrees. Excitons in low-dimensional semiconductors and confined acoustic phonons are temperature-dependent. Therefore, our method can provide the platform for investigating the effect of plasmonic heating on these elementary excitations and on their coupling with the localized surface plasmons. Having a deep understanding of such effects is critical for applications such as quantum sensing and quantum computing. While I have not identified immediate experimental collaborations for this research project, my short-term plans involved some theoretical and computational studies of the effect of temperature increase on the optical properties of various nanostructures.

One my newest graduate students (Fathiya Thini) will start her doctoral work on the implementation of thermo-optical models in hybrid metallic-semiconducting nanostructures. In these hybrid structures, the dispersive, complex dielectric permittivity of the excitonic materials will be modeled using an extension of the Lorentz model, which uses a superposition of oscillators:

$$ \varepsilon(\omega) = \varepsilon_{\infty} + \sum_{k=1}^{N} \frac{f_k \omega_k^2(T)}{\omega_k^2(T) - \omega^2 + i\gamma_k(T)\omega}, \quad (25) $$

where $\varepsilon_{\infty}$ is the high-frequency component of the excitonic material dielectric function, $f_k$ is the reduced strength of the $k$th oscillator, $\hbar\omega_k(T)$ and $\gamma_k(T)$ are the corresponding exciton transition energy and linewidth at temperature $T$, respectively. This model been shown to accurately describe quantum dots, organic semiconductors, and TMD materials and is, therefore, well-suited for the study of a wide range of systems.¹⁴⁵, ¹⁴⁶ It will also provide complete control of the exciton resonance characteristics such as frequency, oscillator strength, and linewidth. It will also allow us to directly integrate the temperature dependence of the exciton frequency and linewidth as:¹⁴⁷

$$ h\omega_0(T) = h\omega_0(0) - S\langle h\omega \rangle \left[ \coth\left(\frac{\hbar\omega}{2k_B T}\right) - 1 \right], \quad (26) $$

$$ \frac{1}{\gamma_0}(T) = \frac{1}{\gamma_0}(0) \frac{3k_B T}{4} \left[ \frac{2(m_e + m_h)c^2}{(\hbar\omega_0(0))^2} \right], \quad (27) $$

where $\gamma_0(0)$ and $h\omega_0(0)$ are the zero-temperature exciton damping and energy, $S$ is a coupling constant to the phonons, and $\langle h\omega \rangle$ is an average phonon energy. This simple temperature dependence model is justified on both experimental and theoretical grounds and has been proven to be more accurate than other widely used models such as Varshni's model.¹⁴⁷ Self-consistently combining Eqs. (25), (26), and (27) then yields the temperature-dependent optical properties of the excitonic materials.

It is important to note that a temperature increase in metals results in (i) a decrease of the plasmon lifetime, which is caused by an increase in the electron-electron and electron-phonon scattering rates, and (ii) a change in the bulk plasma frequency which originates from a reduction of the carrier density under volume thermal expansion. These effects are noticeable
for temperature increases of the order of a few hundreds of degrees but are generally negligible, for temperatures typically observed in plasmonic heating (few tens of degrees).

Lastly, another direction worth exploring is the transient regime of these photothermal effects. With the method my group has developed, it is possible to study time-resolved transient effects that may occur. This can open-up some interesting perspective for the study of hot carrier dynamics, plasmon-driven photochemistry, and phonon dynamics.

## 2. Temperature Effects on the Plasmon-Phonon Coupling

Similarly, the temperature dependence can be taken into account in the acousto-plasmonic interactions. Another graduate student (Julia Kise) is currently working on the implementation of a temperature-dependent model for the modeling of acoustic vibrations. The temperature dependence will be introduced through Young's modulus of the nanoparticle material using Wachtman's model:¹⁴⁸, ¹⁴⁹

$$Y(T) = Y_0 - B_1 T e^{-T_0/T}, \qquad (28)$$

where $Y_0$ is Young's modulus at 0 K, $B_1$ is the slope of Young's modulus-temperature curve at high temperatures, and $T_0$ is a parameter which is materials-dependent. The temperature-dependent Young's modulus will then be used as input in the elastodynamic simulations (Figure 32a), which will be performed using Comsol's *Structural Mechanics* module and its *Elastic Linear Material* submodule (Figure 34). Equation (28) is one of the most frequently used temperature-dependent Young's modulus models and it gives the best over-all results of the various available models.¹⁴⁸, ¹⁴⁹

<figure><img src="image_48.png" /><figcaption>**Figure 34.** Dependence of the isotropic breathing mode frequency (fundamental, $S_{00}^1$, and first harmonic, $S_{00}^2$) on Young's modulus for a temperature range 20–200°C.</figcaption></figure>
Summary

Over the past 11 years, I have theoretically and computationally investigated the optical, photothermal, and thermo-optical properties of a wide range of nanostructures (from single nanoparticles to multi-dimensional arrangements) and materials (semiconductors, plasmonic and catalytic metals, biomaterials, dielectrics, and their hybrids). The breadth of my research activity ranges from performing numerical simulations for the interpretation of experiments, to computationally designing new nanostructures with interesting properties, to developing new computational methods and theoretical approaches. This manuscript should have convinced the reader that, while a significant part of my research has been done in collaboration with experimental groups, independent research involving the development of new methods and models has constituted the main direction of my research activity. Moreover, I would like to emphasize that these methods and models are developed as tools to provide a deeper fundamental understanding of the nanomaterial properties and physical processes involved in these systems.

The first major contribution I have discussed in Chapter 2 concerns the development of the new computational method for the modeling of electron energy-loss spectroscopy (EELS) in plasmonic nanostructures.<sup>150</sup> To the best of my knowledge, this is the first and only implementation of EELS modeling in a time-domain framework. This original approach, opened new opportunities for the modeling of EELS in complex systems. After its development, the new EELS-FDTD method has been successful at interpreting experimental EELS results for complex systems, including (i) high-density homo- and hetero-dimers<sup>62</sup> and AuAg-alloy hollow nanorod.<sup>151</sup>

Another of my core research thrusts is dedicated to the study of the fundamental mechanisms mediating the interaction between elementary excitations such as plasmon-exciton, plasmon-phonon, and plasmon-photonic mode. While my work on plasmon-exciton has not been discussed in this manuscript, my contribution to the understanding of plasmon-photonic mode and plasmon-phonon interaction processes has been discussed in Chapters 3 and 4, respectively. In particular, the new concept of acousto-plasmonic interaction, which I pioneered,<sup>91</sup> unveiled the strong impact of phonons on the optical properties of nanomaterials. More recently, I have developed a new theoretical formalism and computational method for the modeling of these effects in the framework of acoustic-phonon Raman scattering.<sup>119</sup> This has recently led to the introduction of a new physical quantity, the Raman energy density (RED), which provides further insight into these effects. This new method is the first non-atomistic approach that allows for computing acoustic Raman spectra, not only for plasmonic nanoparticles, but for nanostructures of any composition, size, shape, and arrangements.

In Chapter 4, I reported on the photonic band structure calculation of finitely sized 3D plasmonic supercrystals consisting of periodic microscale arrangements of plasmonic nanoparticles.<sup>41</sup> The photonic band structures of finite-size supercrystals with cubic, rhombic
dodecahedral, and spherical crystal habits were calculated using our new method. We reported the appearance of finite-size effects that other standard approaches (namely effective medium theory and standard photonic band structure calculation from a unit-cell with periodic boundary conditions) failed to predict and describe. In particular we found a significant broadening of the photonic bands for the finite-size supercrystals, in comparison with the infinite supercrystals, which arise from the surface/edge scattering of the photonic modes. More interestingly, we unraveled multiple dispersion lines at low energies, corresponding to Fabry-Pérot resonances and whispering gallery modes, which are modes that are only sustained in finite-size structures. This computational work on the optical properties of plasmonic superlattices with diverse morphology, composition, size, and unit cell symmetries is important for the development of high-quality plasmonic photonic structures and novel functional and optical materials.

Furthermore, in Chapter 5, I have discussed my major contributions to the fundamental understanding of photothermal effects in nanomaterials. These effects, which occur upon optical excitation of plasmonic nanostructures, are responsible for significant effects on the optical properties of these nanomaterials. The major contribution in this research area has been the development of a complete and self-consistent computational approach for the rigorous modeling of photothermal processes.⁴² Following the development of this method, I have conducted subsequent work that showed that plasmonic heating has a significant impact on the nanomaterial surrounding environment, including: (i) triggering the contraction of thermo-responsive polymers,⁴³ (ii) inducing molecular degradation in TERS experiments,⁴⁴ (iii) inducing hyperthermia cellular damage for cancer therapy,¹¹, ⁴⁵ (iv) triggering conformal changes in polyelectrolyte coating on metallic nanoparticles,¹⁵² and (v) having a non-negligible effect on plasmon-exciton coupling in hybrid plasmonic-TMD systems.³³ Additionally, I have also shown that photothermal processes do not always contribute to plasmon-driven catalysis.⁴⁶, ⁴⁷

Finally, in Chapter 6, I have discussed some important perspectives and future research directions I plan on pursuing in the areas of (i) acousto-plasmonics, (ii) multidimensional periodic systems, and (iii) photothermal and thermo-optical properties of nanomaterials. While several of my students are already working on some specific tasks, as discussed above, these projects are either just starting or will started in the short term. It is also worth noting that although all these projects are computational and theoretical in nature, they all carry a strong potential for experimental collaboration.
# CV

## Nicolas Large, Ph.D.

Department of Physics & Astronomy
The University of Texas at San Antonio
One UTSA Circle, San Antonio, TX 78249
+1 (210)458-8279

NicolasLarge@utsa.edu

http://physics.utsa.edu/nlarge

## A. Education

2011 Ph.D., Physics of Nanostructures and Advanced Materials, The University of the Basque Country, San Sebastián, Spain

2011 Ph.D., Nanophysics, Paul Sabatier University of Toulouse, France

2007 M.S. Fundamental Physics, Paul Sabatier University of Toulouse, France

2005 B.S., Physics, Paul Sabatier University of Toulouse, France

## B. Positions

2022-present Associate Professor, Department of Physics & Astronomy, University of Texas at San Antonio (UTSA)

Spring 2022 NanoX Visiting Professor, Center for Material Elaboration and Structural Studies (CNRS), Paul Sabatier University of Toulouse, Toulouse, France

2016-present Assistant Professor, Department of Physics & Astronomy, University of Texas at San Antonio (UTSA)

2014-2016 Senior Research Fellow, Department of Chemistry, International Institute for Nanotechnology, Northwestern University, Evanston, IL

2012-2014 Postdoctoral Research Associate, Department of Electrical and Computer Engineering, Laboratory for Nanophotonics, Rice University, Houston, TX

2007-2011 Joint Doctoral Researcher, Center for Material Elaboration and Structural Studies (CNRS, Toulouse), Materials Physics Center & Donostia International Physics Center (CSIC & DIPC, San Sebastián)

2005-2007 Graduate Research Assistant, Solid State Physics Laboratory, Toulouse

## C. Fellowships, Honors, and Awards

2022 President's Distinguished Achievement Award for *Advancing Globalization* ($2,000), UTSA

2021 NanoX Visiting Researcher Fellowship (8,000€), NanoX

2012 C'Nano National Award for best doctoral thesis in *Nanoscience Research*

2010-2011 Doctoral Fellowship (26,210€), DIPC Foundation

2007-2010 MESR Doctoral Fellowship (63,290€), French Ministry of Higher Education

2009 ImagineNano Award (2,000€), Phantoms Foundation

2007 Master's Merit Fellowship (5,500€), French Ministry of Higher Education
## D. Funded Research Grants

### 1. Active

N. Large (PI), "Acousto-Plasmonic Interaction for Unconventional Nanoscale Light Manipulation and Integrated High Accuracy Sensors", Office of Naval Research (ONR) | HBCU/MI, $434,446 (7/2021 - 6/2024) N00014-21-2729

N. Large (PI), Z.J. Tonzetich (co-PI), "NSF Center for Quantum Electrodynamics for Selective Transformations", sub-award University of Rochester [T. Krauss (PI), National Science Foundation (NSF) - CCI, $1,800,000], $59,997 (9/2021 - 8/2024)

K. Mayer (PI), N. Large (co-PI), N. Ornelas-Soto (co-PI), "Nano-colloids of core-shell particles as a new approach for the optical sensing of contaminants of emerging concern", ConTex, $70,000 (9/2020 - 8/2023)

N. Large (PI), R.P. Vincent (co-PI), "HYMNE: unravel novel polaritonic states in hybrid metasurfaces and nanomaterials", FACE Foundation - Thomas Jefferson Fund, $20,000 (9/2019 - 8/2023)

### 2. Completed

N. Large (PI), A. Mlayah (co-PI), "Theoretical investigation of the optical and photothermal properties of plasmonic-based nanostructures", Embassy of France in the U.S. - Chateaubriand Fellowship, $12,000 (9/2019 - 8/2020)

N. Large (PI), A. Mlayah (co-PI), "Optical properties of plexcitonic nanostructures", Embassy of France in the U.S. - Chateaubriand Fellowship, $12,000 (9/2020 - 8/2021)

K. Mayer (PI), N. Large (co-PI), A. Ponce Pedraza (co-PI), K.L. Nash (co-PI), L. Brancaleon (co-PI), "Hybrid plasmonics at UTSA: Investigating plasmonic/magnetic and plasmonic/biomolecular systems", Army Research Office (ARO) - HBCU/MI, $599,989 (9/2018 - 9/2021) W911NF-18-1-0439

N. Large (PI), A. Reyes Coronado (co-PI), "Theoretical modeling of magneto-plasmonic effects in electrodynamic calculations", American Physical Society (APS), $2,000 (3/2019 - 2/2024)

K. Mayer (PI), N. Large (co-PI), A. Ponce Pedraza (co-PI), K.L. Nash (co-PI), L. Brancaleon (co-PI), "2021 HSAP/URAP supplement: Hybrid plasmonics at UTSA", Army Research Office (ARO), $22,500 (6/2021 - 8/2021)

K. Mayer (PI), N. Large (co-PI), A. Ponce Pedraza (co-PI), K.L. Nash (co-PI), L. Brancaleon (co-PI), "HSAP/URAP supplement: Hybrid plasmonics at UTSA", Army Research Office (ARO), $22,500 (6/2020 - 8/2020)

N. Large (PI), "Plasmonic-dielectric metamaterials for enhanced spectroscopy and controlled chemistry", sub-award Northwestern University [R.P. Van Duyne (PI), Office of Naval Research (ONR) - NSSEFF, $927,465, N00014-17-1-3024], $36,531 (9/2017 - 9/2019) SP0042269-PROJ0011928

## E. Certifications

ACUE Teaching Fellow, American Council on Education (ACE) and Association of College and University Educators (ACUE):

* Certificate in *Effective College Instruction*, 2021

* Certificate in *Inclusive Teaching for Equitable Learning*, 2022
## F. Teaching

**2016-present** University of Texas at San Antonio:
*   *Nanophotonics & Plasmonics* [PHY 7603], graduate, 3 SCH (40h / semester)
*   *Electrodynamics* [PHY 3513], undergraduate, 3 SCH (40h / sem.)
*   *Mathematical Physics I* [PHY 2823], undergraduate, 3 SCH (40h / sem.)
*   *Modern Physics* [PHY 2103], undergraduate, 3 SCH (40h / sem.)
*   *Independent Studies* [PHY 4911-13], undergraduate, 1-3 SCH (16-40h / sem.)

**2013** Rice University:
*   *Electrodynamics & Nanophotonics* [PHYS 605], graduate, 1 SCH (12h / sem.)

**2007-2008** National Polytechnic Institute of Toulouse (INPT):
*   *Geometrical and Wave Optics*, undergraduate (License 2), 25h / sem.

## G. Professional Activities and Services

**2018-present** Proposal Reviewer for the *Condensed Matter and Materials Theory (CMMT)* program at the National Science Foundation (NSF), the *Frontier Science* program at the National Council of Science and Technology of Mexico (CONACYT), and the Israel Science Foundation (ISF).

**2009-present** Reviewer for: Chemical Reviews, Nature Materials, ACS Nano, Nano Letters, Nature Communications, Scientific Reports, Nanoscale, ACS Photonics, Journal of Physical Chemistry, RSC Advances, Nanotechnology, Optics Express, Optics Letters, Journal of the Optical Society of America B

**2017-2018** Chair, Physics Symposium, COS Research Conference, San Antonio, TX

**2016** Co-organizer, 13th International Conference Nanotek, Phoenix, AZ

**2013** Session chair, ARO Workshop on Surface Plasmon & Catalysis, Houston, TX

## H. Professional Memberships

**2016-present** Materials Research Society (MRS) – Member

**2012-present** The International Society for Optics and Photonics (SPIE) – Member

**2011-present** American Chemical Society (ACS) – Member & Reviewer

**2008-present** American Physics Society (APS) – Member

**2011-2016** Optical Society of America (OSA) – Member & Reviewer

**2011-2016** National Postdoctoral Association – Affiliate Member

## I. Publications

**Publications:** 47 published **International conferences:** 42 talks

**Citations/h-index:** 4574/24 (Google Scholar), 3581/24 (Web of Science), 3661/24 (Scopus)

### 1. Peer-Reviewed Publications

1. *Photoconductive control of higher-order localized surface plasmon modes in Au-Si-Au nanodisk stacking.*
   V. Nooshnab, N. Large: *J. Nanopart. Res.* **2023**, *25*, 127

2. *Photonic band structure calculation of 3D finite nanostructured supercrystals.*
   J.L. Montaño-Priede, N. Large: *Nanoscale Adv.* **2022**, *4*, 4589
3. Raman energy density in the context of acoustoplasmonics.
J.L. Montaño-Priede, A. Mlayah, N. Large: Phys. Rev. B 2022, 106, 165425

4. Plasmonic heating effects in tip-enhanced Raman spectroscopy (TERS).
J. Rigor, D. Kurouski, N. Large: J. Phys. Chem. C 2022, 126, 13986

5. Computational analysis of drug free silver triangular nanoprism theranostic probe plasmonic behavior for in-situ tumor imaging and photothermal therapy.
S. Mondal, J.L. Montaño-Priede, V.T. Nguyen, S. Park, J. Choi, V.H. Minh Doan, T.M. Thien Vo, T.H. Vo, N. Large, J. Oh: J. Adv. Res. 2022, 41, 23-38

6. Enhanced dual plasmonic photocatalysis through plasmon coupling in eccentric noble metal-nonstoichiometric copper chalcogenide hetero-nanostructures.
M. Ivanchenko, V. Nooshnab, A.F. Myers, A.J. Evangelista, N. Large, H. Jing: Nano Res. 2022, 15, 1579-1586

7. Underlying mechanisms of hot carrier-driven reactivity on bimetallic nanostructures.
Z. Li, J. Rigor, N. Large, P.Z. El-Khoury, D. Kurouski: J. Phys. Chem. C 2021, 125, 2492

8. Magneto-plasmonic biocompatible nanorice.
C.M. García-Rosas, L.A. Medina, P. Lopez, N. Large, A. Reyes-Coronado: J. Nanopart. Res. 2021, 23, 144

9. Plasmonic-induced luminescence of MoSe₂ monolayers in a scanning tunneling microscope.
R. Péchou, J. Shuai, J. Rigor, O. Guillermet, G. Seine, J. Lou, A. Mlayah, N. Large, R. Coratger: ACS Photonics 2020, 7, 3061

10. Wavelength and polarization dependence of second harmonic responses from gold nanocrescent arrays.
H. Maekawa, E. Drobnykh, C.A. Lancaster, N. Large, G.C. Schatz, J.S. Shumaker-Parry, M. Sukharev, N.-H. Ge: J. Phys. Chem. C 2020, 124, 20424

11. Multiphysics modeling of plasmonic photothermal heating effects in gold nanoparticles and nanoparticle arrays.
S. Manrique-Bedoya, M. Abdul-Moqueet, P. Lopez, T. Gray, M. Disiena, A. Locket, S. Kwee, L. Tang, R.L. Hood, Y. Feng, N. Large, K.M. Mayer: J. Phys. Chem. C 2020, 124, 17172

12. Direct experimental evidence of hot-carrier-driven chemical processes in tip-enhanced Raman spectroscopy (TERS).
R. Wang, J. Li, J. Rigor, N. Large, P.Z. El-Khoury, A.Y. Rogachev, D. Kurouski: J. Phys. Chem. C 2020, 124, 2238

13. Controlled overgrowth of five-fold concave nanoparticles into plasmonic nanostars and their single-particle scattering properties.
J.J. Velázquez-Salazar, L. Bazán-Díaz, Q. Zhang, R. Mendoza-Cruz, J.L. Montaño-Priede, G. Guisbiers, N. Large, S. Link, M. José-Yacamán: ACS Nano 2019, 13, 10113

14. Detection of Discosoma Red fluorescent proteins adhered on silver nanoparticles based nanocomposites via surface-enhanced Raman scattering.
A. Scarangella, M. Soumbo, A. Mlayah, C. Bonafos, M.-C. Monje, C. Roques, C. Mercelot, T. Dammak, N. Large, K. Makasheva: Nanotechnology 2019, 30, 165101

15. Surface enhanced resonant Raman scattering in hybrid MoSe₂@Au nanostructures.
I. Abid, W. Chen, J. Yuan, S. Najmaei, E.C. Peñafiel, R. Péchou, N. Large, J. Lou, A. Mlayah: Opt. Express 2018, 26, 29411
16. On the efficient excitation of higher order modes in the plasmonic response of individual gold nanocubes.

A. Maiti, A. Maity, B. Satpati, N. Large, T.K. Chini: *J. Phys. Chem. C* **2017**, *121*, 731

17. Unraveling near- and far-field relationship of 2D SERS substrates using wavelength-scanned surface-enhanced Raman excitation spectroscopy (WS-SERES).

D. Kurouski, N. Large, N. Chiang, A.-I. Henry, T. Seideman, G.C. Schatz, R.P. Van Duyne: *J. Phys. Chem. C* **2017**, *121*, 14737

18. Reversible shape and plasmon tuning in hollow AgAu nanorods.

S. Yazdi, J. Daniel, N. Large, G. Schatz, D. Boudreau, E. Ringe: *Nano Lett.* **2016**, *16*, 6939

19. High-Resolution Distance Dependence Study of Surface-Enhanced Raman Scattering Enabled by Atomic Layer Deposition.

S.S. Masango, R.A. Hackler, N. Large, A.-I. Henry, M.O. McAnally, G.C. Schatz, P.C. Stair, R.P. Van Duyne: *Nano Lett.* **2016**, *19*, 4251

20. Ag–Ag₂S hybrid nanoprisms: structural versus plasmonic evolution.

M.M. Shahjamali, Y. Zhou, N. Zaraee, C. Xue, J. Wu, N. Large, M. McGuirk, F. Boey, V. Dravid, G.C. Schatz, C.A. Mirkin: *ACS Nano* **2016**, *10*, 5362

21. Unraveling near-field and far-field relationships for 3D SERS substrates: a combined experimental and theoretical analysis.

D. Kurouski, N. Large, N. Chiang, N. Greeneltch, K.T. Carron, T. Seideman, G.C. Schatz, R.P. Van Duyne: *Analyst* **2016**, *141*, 1779

22. Influence of surfactant bilayers on the refractive index sensitivity and catalytic properties of anisotropic gold nanoparticles.

E. Martinsson, M.M. Shahjamali, N. Large, N. Zaraee, Y. Zhou, G.C. Schatz, C.A. Mirkin, D. Aili: *Small* **2016**, *12*, 330

23. High-density 2D homo- and hetero- plasmonic dimers with universal sub-10-nm gaps.

M. Zhang, N. Large, A.L. Koh, Y. Cao, A. Manjavacas, P. Nordlander, R. Sinclair, S.X. Wang: *ACS Nano* **2015**, *9*, 9331

24. Electron energy-loss spectroscopy calculations in finite-difference time-domain package.

Y. Cao, A. Manjavacas, N. Large, P. Nordlander: *ACS Photonics* **2015**, *2*, 369

25. Standing wave plasmon modes interact in an antenna-coupled nanowire.

J.K. Day, N. Large, P. Nordlander, N.J. Halas: *Nano Lett.* **2015**, *15*, 1324

26. Gold nanoparticles with tipped surface structures as substrates for single-particle SERS: concave nanocubes, nanotrisoctahedra, and nanostars.

Q. Zhang, N. Large, and H. Wang: *ACS Appl. Mater. Interfaces* **2014**, *6*, 17255

27. Epitaxial growth of Cu₂O on Ag allows for fine control over particle geometries and optical properties of Ag–Cu₂O core-shell nanoparticles.

H. Jing, N. Large, Q. Zhang, H. Wang: *J. Phys. Chem. C* **2014**, *118*, 19948

28. Tunable plasmonic nanoparticles with catalytically active high-index facets.

H. Jing, Q. Zhang, N. Large, C. Yu, D.A. Blom, P. Nordlander, H. Wang: *Nano Lett.* **2014**, *14*, 3674

29. Porous Au nanoparticles with tunable plasmon resonances and intense field enhancement for single-particle SERS.

Q. Zhang, N. Large, P. Nordlander, H. Wang: *J. Phys. Chem. Lett.* **2014**, *5*, 370
30. Hot-electron-induced dissociation of H₂ on gold nanoparticles supported on SiO₂.
S. Mukherjee, L. Zhou, A.M. Goodman, N. Large, C. Ayala Orozco, Y. Zhang, P. Nordlander, N.J. Halas: *J. Am. Chem. Soc.* **2014**, *136*, 64

31. Local electron beam excitation and substrate effect on the response of single Au nanostar
P. Das, A. Kedia, P.S. Kumar, N. Large, T.K. Chini: *Nanotechnology* **2013**, *24*, 405704

32. Orienting nanoantennas in 3D to control light scattering across a dielectric interface.
N.S. King, M.W. Knight, N. Large, A.M. Goodman, P. Nordlander, N.J. Halas: *Nano Lett.* **2013**, *13*, 5997

33. Near-field mediated plexcitonic coupling and giant Rabi splitting in individual metallic dimer
A.E. Schlather, N. Large, A. Urban, P. Nordlander, N.J. Halas: *Nano Lett.* **2013**, *13*, 3281

34. Three-dimensional plasmonic nanoclusters.
A.S. Urban, X. Shen, Y. Wang, N. Large, H. Wang, M.W. Knight, P. Nordlander, H. Chen, N.J. Halas: *Nano Lett.* **2013**, *13*, 4399

35. Hot electrons do the impossible: plasmon-induced dissociation of H₂ on Au.
S. Mukherjee, F. Libisch, N. Large, O. Neumann, L.V. Brown, J. Cheng, B. Lassiter, E. Carter, P. Nordlander, N.J. Halas: *Nano Lett.* **2013**, *13*, 240

36. Plasmonic properties of gold ring-disk nano-resonators: fine shape details matter.
N. Large, J. Aizpurua, V.K. Lin, S.L. Teo, R. Marty, S. Tripathy, A. Mlayah: *Opt. Express* **2011**, *19*, 5587

37. Gold nanoring trimers: a versatile structure for infrared sensing.
S.L. Teo, V.K. Lin, R. Marty, N. Large, E. Alarcon Llado, A. Arbouet, C. Girard, J. Aizpurua, S. Tripathy, A. Mlayah: *Opt. Express* **2010**, *18*, 22271

38. Raman-Brillouin electronic density in short period superlattices.
N. Large, J. Huntzinger, J. Aizpurua, B. Jusserand, A. Mlayah: *Phys. Rev. B* **2010**, *82*, 07531

39. Photoconductively loaded plasmonic nanoantennas as building block for ultracompact optical switches.
N. Large, M. Abb, J. Aizpurua, O.L. Muskens: *Nano Lett.* **2010**, *10*, 1741

40. Acousto-plasmonic hot spots in metallic nano-objects.
N. Large, L. Saviot, J. Margueritat, J. Gonzalo, C.N. Afonso, A. Arbouet, P. Langot, A. Mlayah, J. Aizpurua: *Nano Lett.* **2009**, *9*, 3732

41. Raman-Brillouin light scattering in low-dimensional systems: photoelastic model versus quantum model.
A. Mlayah, J.-R. Huntzinger, N. Large: *Phys. Rev. B* **2007**, *75*, 245303

## 2. Proceedings

1. A new approach for the optical sensing of contaminants of emerging concern based upon core-shell nanoparticles.
C. Marquez Ibarra, G. Morales-Luna, N. Large, N. Ornelas-Soto, and K. M. Mayer: *Proc. SPIE* 12196, 121960B, **2022**

2. An opinion on virtual conferences.
N. Large: ResearchGate (2020), dx.doi.org/10.13140/RG.2.2.33010.02241

3. Synthesis, characterization, and computational modeling of polyelectrolyte-coated plasmonic gold nanorods for photothermal heating studies.
P. Lopez, K. Mayer, and N. Large: *Proc. SPIE* 11082, 11082W1-5, **2019**
4. Fabrication and characterization of thermo-responsive gold nanorod assemblies.
G. Bustamante, K. Carrizales, F. DeLuna, N. Large, J.Y. Ye: Proc. SPIE 10507, 105070B1-10, 2018

5. Acousto-plasmonic coupling in engineered in metal nanocomposites.
N. Large, A. Mlayah, L. Saviot, J. Margueritat, J. Gonzalo, C.N. Afonso, J. Aizpurua: CLEO, 2010, 1, doi: 10.1364/CLEO.2010.CFM2

6. Plasmonic nanoantennas as building blocks for ultracompact photonic devices.
J. Aizpurua, N. Large, M. Abb, O.L. Muskens: IEEE Photonics Society Summer Topical Meeting Series, 2010, 70, doi:10.1109/PHOSST.2010.5553675

# J. Advising and Mentoring

## 1. Post-doctoral Researchers (1)

2017 – 2021 José Luis Montaño-Priede (100%)
– Now postdoctoral researcher at CFM-CSIC, Spain

## 2. Doctoral Students (10)

2023 – ... Fathiya Thini (100%), Physics, “Modeling of the thermo-optical properties of plexcitonic systems”

2022 – ... Alex B. Ferere (100%), Physics, “Plasmon-induced optical forces in acousto-plasmonics”

2022 – ... Arash Edrisi (50%, w/ J. Morales), Physics, “Thermo-optical properties of plexcitonic systems”

2021 – ... John Leblanc (100%), Physics, “Acousto-plasmonic interaction for unconventional nanoscale light manipulation and integrated high accuracy sensors”

2021 – ... Julia Kise (100%), Physics, “Acousto-plasmonic interaction in complex plasmonic nanostructures”

2018 – 2023 Priscilla Lopez (50%, w/ K. Mayer), Physics, “An Investigation of Hybrid Plasmonic Systems for Biomedical Applications”
– now Research Fellow at Air Force Research Laboratory (AFRL), San Antonio, TX, US

2017 – 2022 Joel Rigor (100%), Physics, “Optical, thermal, and vibrational, properties or hybrid nanomaterials”
– now Process engineer at Applied Materials, Santa Clara, CA, US

2018 – 2021 Emil C. Peñafiel (100%), Physics, “Theoretical study of coupled-excited states in hybrid nanomaterials: a road toward artificial photosynthesis”
– now Physics and Math Teacher at Living Rock Academy (high school), San Antonio, TX, US

2018 – 2021 Vida Nooshnab (100%), Physics, “Active hybrid plasmonics for ultrafast optoelectronic devices”
– now Ph.D. student at University of Wisconsin (ECE), Madison, WI, US

2016 – 2019 Gesuri Morales Luna (50%, w/ A. Reyes Coronado), ECE, “Theoretical study of magneto-plasmonic interactions in hybrid nanostructures”
– now Assistant Professor at Universidad Iberoamericana (IBERO), Mexico
### 3. Masters Students (4)

2020 – ... Michael Brinkman (100%), Applied Mathematics, "Unravel Novel Polariton States in Hybrid Metasurfaces and Nanomaterials"

2022 (3 mo) Angélica Orona Návar (50%, w/ K. Mayer), Applied Physics, "Optical Properties of Au@Fe Nanocolloids for the Detection of Water Contaminants" – now Ph.D. student at TEC (Biophysics), Monterrey, Mexico

2019 (6 mo) Jesús Castrejón Figueroa (100%), Physics "Electron energy-loss spectroscopy simulations for hybrid plasmon-exciton nanostructures" – now Ph.D. student at UNAM (Physics), Mexico, Mexico

2019 (4 mo) Aurélien Goerlinger (100%), Materials Science, "Acousto-plasmonic interaction in Raman scattering" – now Ph.D. student at the University of Lille, IEMN (Physics), Lille, France

### 4. Undergraduate Students (21)

2023 – ... Cheyenne Valles (100%), Physics

2023 – ... Tiffany Jensen (100%), Physics

2022 – ... Mariano Alcalde (100%), Physics

2023 (6 mo) Eric Austin (100%), Physics

2022 (6 mo) Hamza Patwa (100%), Physics

2022 (6 mo) Esteban Ramirez (100%), Physics

2021 – 2022 Alex B. Ferere (100%), Physics

2019 – 2022 Rudin Kraja (100%), Physics

2021 (6 mo) Miguel Hernandez (100%), Physics

2021 (6 mo) Zain Manasia (100%), Biology

2018 – 2020 Michael Brinkman (100%), Mathematics

2019 – 2020 Ray Hagimoto (100%), Physics

2018 – 2019 Joseph I. Garcia (100%), Physics

2017 – 2019 Brandon E. Rangel (100%), Physics

2019 (6 mo) Reid Shillingburg (100%), Physics

2018 (3 mo) Ramón Amezquita Vizcarra (100%), Physics

2018 (6 mo) Daniel Angel (100%), Physics

2018 (6 mo) Mauricio Martinez (100%), Computational Science

2017 – 2018 Emil C. Peñafiel (100%), Physics

2017 – 2018 Nelson Umanzor Meija (100%), Physics

2016 (9 mo) Negin Zaraee (100%), Chemistry
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