# Bifunctional molybdenum and vanadium materials: semiconductor properties for advanced electronics and catalytic efficiency in linalool oxidation

Josipa Sarjanović, Mateja Cader, Edi Topić, Marta Razum, Dominique

Agustin, Mirta Rubčić, Luka Pavić, Jana Pisk

► To cite this version:

Josipa Sarjanović, Mateja Cader, Edi Topić, Marta Razum, Dominique Agustin, et al. Bifunctional molybdenum and vanadium materials: semiconductor properties for advanced electronics and catalytic efficiency in linalool oxidation. Materials Advances, 2024, 5 (23), pp.9391-9402. 10.1039/d4ma00790e. hal-04932460

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Cite this: Mater. Adv., 2024, 5, 9391

# Bifunctional molybdenum and vanadium materials: semiconductor properties for advanced electronics and catalytic efficiency in linalool oxidation†

Josipa Sarjanović, ID a Mateja Cader, a Edi Topić, ID a Marta Razum, ID b

Dominique Agustin, ID cd Mirta Rubčić, ID a Luka Pavić ID *b and Jana Pisk ID *a

Polynuclear and mononuclear molybdenum(vi) complexes, coordinated with water or methanol, were synthesized using acyl-hydrazone ligands, derived from the reactions of 2-hydroxy-3-methoxybenzaldehyde with formic – (H₂L¹) or acetic acid hydrazide (H₂L²). Characterization of the complexes was conducted utilizing advanced spectroscopic techniques and elemental analysis. Crystal and molecular structures of ligand H₂L², and complexes [MoO₂(L¹)(H₂O)], [MoO₂(L²)(MeOH)], together with (Hpy)₂-Mo₈O₂₆ were determined by single crystal X-ray diffraction. The thermogravimetry provided insights into the thermal stability and decomposition patterns of the complexes. In situ solid-state impedance spectroscopy was employed, revealing correlations between the electrical properties and the thermal and structural transformations of Mo complexes. This multifaceted approach enabled a profound understanding of the interplay between structure, thermal behaviour, and electrical characteristics. The polynuclear complex [MoO₂(L¹)]n exhibited remarkable conductivity, achieving values up to 10⁻⁸ (Ω cm)⁻¹ at room temperature. This performance, compared to previously reported vanadium-based analogues, highlights its considerable potential for integration into electronic device manufacturing. Additionally, the catalytic efficiency of these newly synthesized molybdenum complexes was evaluated in linalool oxidation, alongside previously reported vanadium compounds, further demonstrating their promising applications in catalysis.

Received 5th August 2024,
Accepted 27th October 2024

DOI: 10.1039/d4ma00790e

rsc.li/materials-advances

## Introduction

Molybdenum(vi) and vanadium(v, iv) coordination complexes are renowned for their versatile applications, primarily due to their biological significance and potential as antitumor and antiviral agents.¹,² These complexes also have extensive industrial applications, capitalising on catalytic capabilities in sulfoxidation, epoxidation, and oxidation processes.³⁻⁵ Additionally, materials containing molybdenum, due to good electrical properties, are suitable for semiconductor use, with DC conductivity on the

order of magnitude up to 10⁻⁹–10⁻¹² (Ω cm)⁻¹.⁶,⁷ Furthermore, vanadium(iv) complexes with tetradentate Schiff bases and vanadium(iv) indanone derivatives show semiconductor characteristics, making them suitable for use in manufacturing electronic devices such as light-emitting diodes, rechargeable batteries, sensors, and other electronic devices.⁸,⁹ In our recent publication,¹⁰ we investigated electrical properties of oxo- and dioxo vanadium(v) complexes coordinated by ligands derived from 2-hydroxy-3-methoxybenzaldehyde and acetic acid hydrazide, Scheme 1, ligand H₂L², with general formulas [VO(L²)(OMe)(MeOH)], [VO(L²)(OEt)(H₂O)], and [VO₂(HL²)]₂·2H₂O. Furthermore, we studied similar vanadium coordination compounds: (NH₄)[VO₂(L¹*)], [VO₂(HL²*)], and [VO(L¹*)(OMe)(MeOH)], where the ligands were derivatives of acetic acid hydrazide (ESI,† Scheme S1).¹⁰ One of the investigated compounds, [VO(L²)(OEt)(H₂O)], exhibited high conductivity being 10⁻⁷ (Ω cm)⁻¹ at 120 °C, while others from the study are in the range of 10⁻¹¹–10⁻¹³ (Ω cm)⁻¹.

Previously, we studied the variation of the aldehyde component of the acyl hydrazine.¹⁰ In this study, we focused on the hydrazide part of the acyl hydrazone and examined how the presence of hydrogen (H) or methyl (CH₃) group at the end of

<figure><img src="image_3.png" /></figure>

<footnote>a Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia. E-mail: jana.pisk@chem.pmf.hr</footnote>

<footnote>b Division of Materials Chemistry, Ruđer Bošković Institute, Bijenička 54, 10000 Zagreb, Croatia. E-mail: luka.pavic@irb.hr</footnote>

<footnote>c LCC-CNRS (Laboratoire de Chimie de Coordination), 205 Route de Narbonne, BP44099, CEDEX 4, 31077 Toulouse, France</footnote>

<footnote>d Department of Chemistry, IUT Paul Sabatier, Université Paul Sabatier, University of Toulouse, Av. G. Pompidou, CS20258, 81104 Castres, France</footnote>

<footnote>† Electronic supplementary information (ESI) available. CCDC 2367284–2367289. For ESI and crystallographic data in CIF or other electronic format see DOI: https://doi.org/10.1039/d4ma00790e</footnote>
<figure><img src="image_4.png" /><figcaption>Scheme 1 Ligands used for the presented investigation.</figcaption></figure>

the chain affected the structural and consequently electrical properties of Mo coordination complexes (Schemes 1 and 2). Therefore, solid-state impedance spectroscopy was employed to conduct an in-depth analysis of the *in situ* transformation of molybdenum compounds.

Mo complexes derived from aroyl-hydrazones and thiosemicarbazones are well-studied in the literature.¹¹⁻¹⁵ On the contrary, it is worth noting that molybdenum (Mo) compounds derived from acyl-hydrazone ligands are to the best of our knowledge rarely reported in the literature, presenting challenges for material production.¹⁶ To understand the full potential of these systems, catalytic studies on linalool oxidation were explored and further broadened towards previously characterised vanadium coordination compounds. Linalool is an interesting substrate due to its biological origin,¹⁷,¹⁸ while its oxidation products (pyranoid and furanoid) are essential in biochemistry, medicine, and the food industry, due to their structural properties and biological activities.¹⁹⁻²¹ Further, the number of publications reporting linalool oxidation employing transition metal-based catalysts is quite limited.⁷,²²⁻²⁵ Our approach includes a horizontal comparison between Mo and V catalysts, and a vertical comparison among Mo catalysts featuring two types of ligands and coordination complexes. This dual comparative viewpoint provides a deeper understanding of the catalytic and electrical properties and potential

<figure><img src="image_5.png" /><figcaption>Scheme 2 The solution-based synthetic route towards Mo complexes. MeCN = acetonitrile, DCM = dichloromethane (gentle heating), MeOH = methanol.</figcaption></figure>

applications of these compounds. While a direct correlation between these properties cannot be established, given that electrical properties and semiconducting potential are assessed in the solid state, while catalytic reactions occur in solution, indirect correlations are possible. Namely, obvious correlations exist between structural and electrical properties, as well as between structural and catalytic performance. Ultimately, our goal is to develop materials exhibiting dual functionalities, capable of serving simultaneously as catalysts and semiconductors.

## Results and discussion

### Synthesis, IR characterisation and thermal behaviour of molybdenum(vi) compounds

Both ligands were synthesized using standard solution-based methods as well as mechanochemical techniques. While the solution-based method yielded high product quantities, the mechanochemical approach minimized solvent usage, aligning with green chemistry principles. IR characterisation and DSC data are presented in Table 1 and ESI,† Fig. S1, S2, S8 and S9. Further, the reactions of the prepared ligands $H_2L^{1,2}$ with the starting molybdenum(vi) precursor $[MoO_2(acac)_2]$ were carried out in different solvents (methanol, acetonitrile, dichloromethane), in a 1:1 molar ratio (Scheme 2).

The reaction between $[MoO_2(acac)_2]$ and $H_2L^1$ in methanol and acetonitrile yielded a polynuclear complex $[MoO_2(L^1)]_n$ (2), while with $H_2L^2$ in dichloromethane, under vigorous heating, produced $[MoO_2(L^2)]_n$ (5). Both brown-coloured complexes were analysed via IR-ATR spectroscopy (Tables 1, 2 and ESI,† Fig. S3 and S4). Broad bands at $922 \text{ cm}^{-1}$ and $877 \text{ cm}^{-1}$ $[MoO_2(L^1)]_n$ (2)) and $834 \text{ cm}^{-1}$ $[MoO_2(L^2)]_n$ (5)) were attributed to intramolecular stretching of Mo=O···Mo bonds.²⁶,²⁷ On the other hand, gentle heating in DCM, yielded mononuclear complexes of general formula $[MoO_2(L^{1 or 2})(H_2O)]$ (1) and (3), respectively. Interestingly, the complex $[MoO_2(L^2)(H_2O)]$ (3) could be obtained if the reaction of $[MoO_2(acac)_2]$ and $H_2L^2$ was provided in acetonitrile, also under gentle heating, suggesting the moisture from the solvent facilitates the coordination of a water molecule at the sixth coordination site of Mo. IR analysis (ESI,† Fig. S5 and S6) showed that bands at $895 \text{ cm}^{-1}$ $[MoO_2(L^1)(H_2O)]$ (1)) and $906 \text{ and } 866 \text{ cm}^{-1}$ $[MoO_2(L^2)(H_2O)]$ (3)) are characteristic of stretching of the O=Mo=O group, while the band around $3250 \text{–}3350 \text{ cm}^{-1}$ corresponds to O–H

<table><caption>Table 1 IR-ATR analysis of Mo compounds</caption><thead><tr><th rowspan="2">Compound</th><th colspan="6">IR bands/cm<sup>-1</sup></th></tr><tr><th>C=N</th><th>C=O<sub>hydr</sub></th><th>C=O<sub>phe</sub></th><th>Mo=O</th><th>H<sub>2</sub>O</th><th>MeOH</th></tr></thead><tbody><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)]<sub>n</sub> (2)</td><td>1595</td><td>1308</td><td>1259</td><td>922, 877</td><td>—</td><td>—</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)]<sub>n</sub> (5)</td><td>1608</td><td>1310</td><td>1265</td><td>922, 834</td><td>—</td><td>—</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)(H<sub>2</sub>O)] (1)</td><td>1599</td><td>1319</td><td>1264</td><td>895, 861</td><td>3343</td><td>—</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(H<sub>2</sub>O)] (3)</td><td>1596</td><td>1328</td><td>1254</td><td>906, 866</td><td>3244</td><td>—</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(MeOH)] (4)</td><td>1612</td><td>1337</td><td>1259</td><td>906, 868</td><td>—</td><td>1028</td></tr><tr><td>Ligand</td><td colspan="2">C=N</td><td colspan="2">C=O</td><td colspan="2"></td></tr><tr><td>H<sub>2</sub>L<sup>1</sup></td><td colspan="2">1605</td><td colspan="2">3195</td><td colspan="2">1688</td></tr><tr><td>H<sub>2</sub>L<sup>2</sup></td><td colspan="2">1609</td><td colspan="2">3185</td><td colspan="2">1672</td></tr></tbody></table>

<figure><img src="image_6.png" /></figure>
<table><caption>**Table 2** Thermal behaviour of Mo compounds</caption><thead><tr><th rowspan="2">Compound</th><th colspan="2">TGA analysis/°C</th><th rowspan="2">Complex<br>decomposition</th></tr><tr><th>H<sub>2</sub>O</th><th>MeOH</th></tr></thead><tbody><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)]<sub>n</sub> (2)</td><td>—</td><td>—</td><td>275-475</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)]<sub>n</sub> (5)</td><td>—</td><td>—</td><td>280-545</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)(H<sub>2</sub>O)] (1)</td><td>110-125</td><td>—</td><td>270-520</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(H<sub>2</sub>O)] (3)</td><td>120-140</td><td>—</td><td>280-535</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(MeOH)] (4)</td><td>—</td><td>100-140</td><td>265-525</td></tr></tbody></table>

stretching of the water molecule.⁷ Additionally, the reaction with H₂L², in methanol, produced the mononuclear complex [MoO₂(L²)(MeOH)] (4), in which the methanol molecule occupied the sixth coordination site. Bands at 906 and 868 cm⁻¹ were observed, indicating stretching of the O=Mo=O bond, while a band at 1028 cm⁻¹ was characteristic for MeOH (ESI,† Fig. S7).²⁶,²⁷ In all the complexes, the coordination of the ligand to the Mo centre is confirmed through the absence of the band characterizing C=O groups of the neutral ligand at 1688 (H₂L¹) and 1672 cm⁻¹ (H₂L²), implying keto-enol tautomerization and consequential appearance of the band at ~1250 cm⁻¹ characteristic for C=O.²⁶,²⁷

Upon heating in an oxygen atmosphere, both polynuclear complexes [MoO₂(L¹)]n (2) and [MoO₂(L²)]n (5) exhibited a single-step mass loss, with decomposition occurring within distinct temperature ranges: 275-475 °C for [MoO₂(L¹)]n (2) and 280-545 °C for [MoO₂(L²)]n (5), ESI,† Fig. S10 and S11. Decomposition of [MoO₂(L¹)(H₂O)] (1), ESI,† Fig. S12, occurred in two steps: first, the release of a water molecule between 110 and 125 °C, followed by the complex decomposition between 270 and 520 °C. A similar analysis was conducted for [MoO₂(L²)(H₂O)] (3), ESI,† Fig. S13, revealing analogous decomposition steps in the temperature range of 120-140 °C and 280-535 °C, respectively. TGA for [MoO₂(L¹)(H₂O)] were heated at 145 °C for one hour, transformation to polynuclear species [MoO₂(L¹)]n occurred. While [MoO₂(L¹)]n (2) remained stable and did not convert to the mononuclear complex upon exposure to water vapours, [MoO₂(L²)]n (5) transformed into [MoO₂(L²)(H₂O)] (3) after 24 hours of exposure. The transitions were confirmed via IR-ATR spectra comparison.

The experimentally obtained amounts of MoO₃ corresponded to the theoretically calculated ones.

When the mononuclear complexes [MoO₂(L¹)(H₂O)] were heated at 145 °C for one hour, transformation to polynuclear species [MoO₂(L¹)]n occurred. While [MoO₂(L¹)]n (2) remained stable and did not convert to the mononuclear complex upon exposure to water vapours, [MoO₂(L²)]n (5) transformed into [MoO₂(L²)(H₂O)] (3) after 24 hours of exposure. The transitions were confirmed via IR-ATR spectra comparison.

Furthermore, the mononuclear complex [MoO₂(L¹)(H₂O)] (1) and [MoO₂(L²)(MeOH)] (4) could also be obtained via mechanochemical synthesis using methanol as solvent. At the same time, no reaction occurred when methanol was substituted by dichloromethane or acetonitrile, as evidenced by IR spectra comparison. The unexpected formation of [MoO₂(L¹)(H₂O)] (1), assisted by MeOH, can likely be explained by the ball milling

energy and the presence of water in the MeOH solvent, which together promote the formation of a water-coordinated species.

## Crystal and molecular structure

In this work a total of six crystal structures were determined (ESI,† Table S1), that of side-product (pyH)₄(Mo₈O₂₆), ligands H₂L¹, H₂L², and complexes [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)-(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4). The ligand H₂L¹ and complex [MoO₂(L²)(H₂O)] (3) were known in the database as references CCDC 698812²⁸ and 2001210,¹⁶ respectively. Surprisingly, and to the best of our knowledge, the crystal structure of (pyH)₄(Mo₈O₂₆) (Fig. 1a and ESI,† Fig. S15) was not reported before, even though a significant number of pyridinium polyoxomolybdates are known. The structure features a centrosymmetric β-octa molybdate anion and pyridinium cations that engage in linear and bifurcated hydrogen bonds with the axial oxygen atoms.

H₂L¹ and H₂L² hydrazones (Fig. 1b and ESI,† Fig. S16 and S17) are in the expected keto-amino tautomeric form as evidenced by relevant bond lengths (ESI,† Table S2) and anti-conformation. Both form supramolecular homodimers through amide (C=O)-NH synths. Significant differences however exist in the arrangement of the dimers. While in H₂L¹ the dimers pack in parallel stacks forming a zig-zag arrangement, the presence of an auxiliary methyl group in H₂L² causes the dimers to extend into sheets through (C=O)-CH₃ short contacts (ESI,† Table S3).

Similarly, the dioxomolybdenum(vi) complexes (Fig. 1c and d) derived from H₂L¹ and H₂L² also show features well-established in the related works. The dianion L²⁻ is in an enol-imino tautomeric form (ESI,† Table S2) in all three cases, forming an ONO chelating pocket. The sixth coordination site of {MoO₂}²⁺ core is occupied by the solvent molecule. However, the packing of the molecules in the crystal structures differs greatly between the three complexes.

<figure><img src="image_7.png" /><figcaption>**Fig. 1** (Supra)molecular structures of (a) pyridinium octamolybdate, (b) H₂L¹, (c) [MoO₂(L²)(H₂O)] and (d) [MoO₂(L²)(MeOH)], showcasing differences in hydrogen bonding.</figcaption></figure>

<figure><img src="image_8.png" /></figure>
The complex [MoO₂(L¹)(H₂O)] (1), ESI,† Fig. S18, is noteworthy for reassessment as it presents the sturdiest supramolecular architecture in the presented set of crystal structures. The molecules form unusually complex R₆⁶(24) and larger supramolecular rings through OₓH··O=Mo and OₓH··Nₐmide hydrogen bonds. Additional hydrogen bonds from the water ligand, not involved in a ring formation, interact with neighbouring complex molecules, creating an extended supramolecular network.

In contrast, the [MoO₂(L²)(H₂O)] (3) complex, previously reported,¹⁶ (Fig. 1c and ESI,† Fig. S19) forms somewhat less interwined supramolecular chains *via* OₓH··Oₚhen, OₓH··Oₘethoxy, and OₓH··Nₐmide hydrogen bonds. These chains are weakly interconnected through numerous Mo=Oₓax··H·C contacts, differing from the L¹ counterpart by exhibiting a linear rather than a net-like arrangement. The structure of [MoO₂(L²)(MeOH)] (4) (Fig. 1d and ESI,† Fig. S20) lacks a ditopical hydrogen bond donor, resulting in the formation of non-interacting homodimers through OₘeOH-H···Nₐmide hydrogen bonds. These dimers, formed between symmetrically equivalent molecules, produce two geometrically distinct but similar types, stabilized by various weak C-H···O contacts. The differences in supramolecular architectures can be correlated with observed distinctions in electrical measurements obliterated with impedance spectroscopy, discussed in detail *vide infra*, paragraph on electrical properties.

## Catalytic properties of molybdenum- and vanadium-based materials for linalool oxidation

Five molybdenum complexes [MoO₂(L¹)]ₙ (2), [MoO₂(L²)]ₙ (5), [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)(H₂O)] (3), [MoO₂(L²)(MeOH)] (4), and five vanadium complexes (NH₄)[VO₂(L¹*)], [VO₂(HL²*)],

[VO(L¹*)(OMe)(MeOH)], [VO(L²)(OEt)(H₂O)], [VO(L²)(OMe)-(MeOH)] were used as catalysts for linalool oxidation. The initial idea was the comparison of the catalytic activity based on (i) different metal centres (Mo vs. V), (ii) the use of oxidant in different solvents (TBHP in decane vs. TBHP in water), and (iii) the addition of organic solvent to the reaction media (H₂O₂ vs. H₂O₂ and MeCN). The obtained data are presented in Table 3 and ESI,† Fig. S22-S25, and Table S4. Generally, Mo compounds are superior catalysts for linalool epoxidation, exhibiting higher activity and selectivity towards the formation of furanoid and pyranoid products. For Mo catalysts, TBHP in decane or water as a solvent did not affect the maximum conversion rate. However, the furanoid yield remained consistent, regardless of the TBHP used, ranging from 55% to 70%, with the highest yield achieved by [MoO₂(L²)(MeOH)] (4). The pyranoid yield was approximately 10% higher when TBHP in water was used, resulting in around 30% yield compared to around 20% with TBHP in decane, and this trend was similar across all the Mo catalysts tested. The highest TOF value, 598, was achieved with TBHP in decane in the presence of the catalyst [MoO₂(L²)(H₂O)] (3), indicating the fastest conversion of the complex into the pentacoordinated active species that was proven to be the first step of linalool oxidation,³ since it was proven that those oxacycles are obtained from a transient epoxide.²² This was proven by TOF values for [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)]ₙ (5), and [MoO₂(L¹)]ₙ (2), in descending order. Unlike TBHP, using H₂O₂ as an oxidant did not enhance activity or selectivity towards furanoid and pyranoid products. Adding MeCN to the reaction mixture significantly increased linalool conversion and tremendously boosted the TOF parameter. However, the furanoid yield was three times lower compared to TBHP. The pyranoid yield was generally lower with H₂O₂.

<table><caption>**Table 3** Catalytic results of linalool oxidation. The reaction was carried out at 80 °C with TBHP in decane and TBHP in water, and at 70 °C with H₂O₂. *n(catalyst)/n(linalool)/n(oxidant) = 0.05 mmol/10 mmol/20 mmol*</caption><thead><tr><th rowspan="2">Catalyst</th><th colspan="2">Conversion<sup>a</sup>/%</th><th colspan="2">TOF20min<sup>b</sup></th><th colspan="2">TON<sup>c</sup></th><th colspan="2">Furanoid yield/%</th><th colspan="2">Pyranoid yield/%</th></tr><tr><th>TBHPdec</th><th>TBHPaq</th><th>TBHPdec</th><th>TBHPaq</th><th>TBHPdec</th><th>TBHPaq</th><th>TBHPdec</th><th>TBHPaq</th><th>TBHPdec</th><th>TBHPaq</th></tr></thead><tbody><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)(H<sub>2</sub>O)] (1)</td><td></td><td></td><td>547</td><td>270</td><td></td><td></td><td>61</td><td>57</td><td>20</td><td>28</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)]<sub>n</sub> (2)</td><td>&gt; 99</td><td></td><td>511</td><td>435</td><td>200</td><td></td><td>56</td><td>57</td><td>18</td><td>29</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(H<sub>2</sub>O)] (3)</td><td></td><td></td><td>598</td><td>234</td><td></td><td></td><td>57</td><td>58</td><td>18</td><td>29</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(MeOH)] (4)</td><td></td><td></td><td>437</td><td>280</td><td></td><td></td><td>71</td><td>61</td><td>18</td><td>29</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)]<sub>n</sub> (5)</td><td></td><td></td><td>523</td><td>405</td><td></td><td></td><td>59</td><td>57</td><td>18</td><td>33</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)(H<sub>2</sub>O)] (1)</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)]<sub>n</sub> (2)</td><td>39</td><td>79</td><td>21</td><td>104</td><td>78</td><td>157</td><td>21</td><td>25</td><td>16</td><td>14</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(H<sub>2</sub>O)] (3)</td><td>50</td><td>85</td><td>71</td><td>301</td><td>100</td><td>167</td><td>21</td><td>18</td><td>16</td><td>8</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(MeOH)] (4)</td><td>45</td><td>84</td><td>21</td><td>187</td><td>91</td><td>169</td><td>23</td><td>17</td><td>15</td><td>7</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)]<sub>n</sub> (5)</td><td>59</td><td>85</td><td>15</td><td>429</td><td>119</td><td>167</td><td>19</td><td>19</td><td>13</td><td>9</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)]<sub>n</sub> (5)</td><td>69</td><td>83</td><td>87</td><td>357</td><td>138</td><td>165</td><td>11</td><td>23</td><td>5</td><td>10</td></tr><tr><td>[VO(L<sup>2</sup>)(OEt)(H<sub>2</sub>O)]</td><td>TBHPdec</td><td>TBHPaq</td><td>TBHPdec</td><td>TBHPaq</td><td>TBHPdec</td><td>TBHPaq</td><td>TBHPdec</td><td>TBHPaq</td><td>TBHPdec</td><td>TBHPaq</td></tr><tr><td>[VO(L<sup>2</sup>)(OMe)(MeOH)]</td><td>&gt; 99</td><td>&gt; 99</td><td>351</td><td>345</td><td>198</td><td>200</td><td>12</td><td>20</td><td>4</td><td>14</td></tr><tr><td></td><td></td><td></td><td>325</td><td>349</td><td>200</td><td></td><td>12</td><td>19</td><td>2</td><td>14</td></tr><tr><td>[VO(L<sup>2</sup>)(OEt)(H<sub>2</sub>O)]</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td><td>H<sub>2</sub>O<sub>2</sub></td><td>H<sub>2</sub>O<sub>2</sub> + MeCN</td></tr><tr><td>[VO(L<sup>2</sup>)(OMe)(MeOH)]</td><td>24</td><td>81</td><td>63</td><td>469</td><td>48</td><td>162</td><td>6</td><td>27</td><td>3</td><td>33</td></tr><tr><td></td><td>22</td><td>81</td><td>60</td><td>479</td><td>44</td><td>161</td><td>7</td><td>27</td><td>4</td><td>15</td></tr></tbody></table>

<footnote>* TBHP stands for test-butyl hydroperoxide, H₂O₂ for hydrogen peroxide, MeCN acetonitrile, dec for decane and aq for aqueous. a Linalool consumed at the end of reaction. b *n(linalool) transformed/*n(catalyst)/time(h) at 20 min. c *n(linalool) transformed/*n(catalyst) at the end of reaction.</footnote>
than with TBHP, and surprisingly, the addition of MeCN to H₂O₂ further reduced the catalytic efficiency for pyranoid formation, negatively impacting its yield.

Linalool oxidation reactions were also tested with V compounds. The most interesting comparison is between catalysts [VO(L²)(OMe)(MeOH)] with the [MoO₂(L²)(MeOH)] (4). As shown in Table 3 and ESI,† Table S4, the V catalyst achieves the highest conversion and TON in reactions with TBHP. However, its TOF is lower compared to [MoO₂(L²)(MeOH)] (4). Additionally, the yields of desired pyranoid and furanoid products are significantly lower with the V catalyst than with [MoO₂(L²)-(MeOH)] (4). Furthermore, reactions utilizing H₂O₂ as the oxidizing agent are less effective than those using TBHP. Detailed discussion about linalool oxidation assisted by vanadium catalysts can be found in ESI,† When comparing to the previously published results, where the Mo loading was 0.25 mol%, and an oxidising agent was TBHP in water, the furanoid yield was 44% for the [MoO₂(L)(H₂O)] and 27% for [MoO₂(L)(MeOH)] (L stands for the doubly deprotonated form of the ligand obtained by the synthesis of 2-hydroxy-5-nitrobenzaldehyde and benzhydrazide) while pyranoid was 18 and 11%, respectively.⁷ On the other hand, [MoO₂(SAP)]₂ (SAP is the doubly deprotonated form of salicyli-deneaminophenol) catalyst,²² operating under the same conditions provided a furanoid yield of 27% and pyranoid yield of 11%. Significant improvement was noticed when employing TBHP in decane, since the furanoid yield was 52%, and the pyranoid 13%.

## Electrical properties of molybdenum-based materials and comparison with vanadium-based ones

The electrical properties of molybdenum complexes were investigated employing solid-state impedance spectroscopy (ss-IS), a powerful technique applied to various materials, amorphous and/or crystalline ones.²⁹⁻³² Five distinct complexes [MoO₂(L¹)]ₙ (2), [MoO₂(L²)]ₙ (5), [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)(H₂O)] (3), [MoO₂(L²)(MeOH)] (4), utilizing two ligands (H₂L¹ and H₂L²) and synthesized from methanol, acetonitrile, and dichloromethane, were studied over a broad frequency and temperature range. Due to the potential decomposition of these complexes with temperature increase (loss of solvent or amorphization of the complex itself), results of thermal analysis were carefully evaluated to guide the planning of electrical measurements, thereby ensuring accuracy and reliability. All IS measurements incorporated a thermal cycling process, where the temperature was ramped from 30 °C to 200 °C (heating run) and subsequently back to 30 °C (cooling run) across a wide frequency spectrum.

Fig. 2(a) and (b) illustrates the conductivity spectra for polynuclear compounds [MoO₂(L¹)]ₙ (2) and [MoO₂(L²)]ₙ (5), respectively, during the cooling cycle. These spectra are characteristic of all measured samples and exhibit two distinct regions. The first region is the frequency-dependent part (dispersion), which is prominent in the high-frequency domain and is more significant at lower temperatures. As the temperature rises, the frequency-dependent region shifts beyond the measurement frequency range, giving way to the second frequency-independent section (i.e. plateau), known as DC (direct current) conductivity, which becomes dominant part of the

<figure><img src="image_9.png" /><figcaption>Fig. 2 Conductivity spectra for polynuclear (a) [MoO₂(L¹)]ₙ (2) compound and (b) [MoO₂(L²)]ₙ (5) compound in the cooling run, along with (c) Arrhenius plots for DC conductivity in both runs for both polynuclear complexes (red circle – heating, blue circle – cooling).</figcaption></figure>

spectrum. The extent of this plateau, indicative of the material's electrical properties, varies among samples. Accordingly, it can be observed that in [MoO₂(L¹)]ₙ (2), the DC plateau spans a larger frequency range compared to [MoO₂(L²)]ₙ (5) one.

Furthermore, it is noteworthy that both [MoO₂(L¹or²)]ₙ compounds exhibited no significant changes during the heating/cooling run. This observation aligns with the TG analysis, which indicates a single-step decomposition occurring at 275–280 °C, Table 2. Such thermal stability is anticipated, given that these compounds lack coordinated or crystalline solvent molecules that could be lost during the heating run.

All studied compounds exhibit semiconductive behaviour, characterized by an Arrhenius-type dependence of DC conductivity, from which the characteristic activation energy can be derived.

The activation energy for DC conductivity, E<sub>DC</sub>, is determined from the slope of log(σ<sub>DC</sub>) vs. 1000/T using the following equation:

$$ \sigma_{\text{DC}} = \sigma_0 * \exp(-E_{\text{DC}}/k_B T), \quad (1) $$

where σ<sub>DC</sub> is DC conductivity, σ₀* pre-exponential factor, E<sub>DC</sub> is the activation energy, k<sub>B</sub> is the Boltzmann constant and T is the temperature (K) and obtained values are listed in Table 4. Observed values are in the range from ~40 kJ mol⁻¹ to ~95 kJ mol⁻¹ and are in line with observed values for various complexes (metal, ligand).

This range aligns with those seen in a variety of semiconductive materials,⁶,⁷,¹⁰,³³⁻³⁹ both amorphous and crystalline,

<table><caption>Table 4 DC conductivity and different parameters from IS analysis for all compounds in this study</caption><thead><tr><th>Compound</th><th>σ<sub>DC</sub><sup>a</sup> / (Ω cm)<sup>-1</sup></th><th>log σ<sup>*</sup><sub>0</sub> / (Ω cm)<sup>-1</sup></th><th>E<sub>DC</sub> / kJ mol<sup>-1</sup> (h)</th><th>E<sub>DC</sub> / kJ mol<sup>-1</sup> (c)</th></tr></thead><tbody><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)(H<sub>2</sub>O)] (1)</td><td>1.72 × 10<sup>-11</sup></td><td>-4.29</td><td>—</td><td>60</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>1</sup>)]<sub>n</sub> (2)</td><td>8.77 × 10<sup>-8</sup></td><td>-2.69</td><td>42</td><td>40</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(H<sub>2</sub>O)] (3)</td><td>1.80 × 10<sup>-10</sup></td><td>-0.78</td><td>—</td><td>84</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(MeOH)] (4)</td><td>8.96 × 10<sup>-11</sup></td><td>-1.32</td><td>—</td><td>81</td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)]<sub>n</sub> (5)</td><td>2.66 × 10<sup>-9</sup></td><td>1.58</td><td>97</td><td>95</td></tr></tbody></table>

<figure><img src="image_10.png" /></figure>

<footnote>a Measured at 200 °C.</footnote>
indicating in our case dominant electronic transport mechanisms. Furthermore, considering low conductivity values at lower temperatures, and the absence of a well-defined DC plateau in conductivity spectra, the DC conductivity values were determined by analysing the impedance spectra using equivalent electrical circuit (EEC) modelling, specifically through the complex nonlinear least squares (CNLLS) method. The employed simple EEC model is based on the R-CPE parallel circuit, where R denotes the resistor corresponding to the sample resistance, and the constant phase element, CPE, determines the sample capacitance.

For polynuclear compounds [MoO₂(L¹or²)]n (2 and 5, respectively) there are negligible differences in different runs (heating vs. cooling) which is an indicator of temperature stability and absence of compound transformations in the studied temperature range, Fig. 2(c). For [MoO₂(L¹)]n (2) the EDC value is determined to be ~40 kJ mol⁻¹, whereas for [MoO₂(L²)]n (5) is ~95 kJ mol⁻¹ correlating with their differences in conductivity.

At 200 °C during the cooling run polynuclear compound [MoO₂(L¹)]n (2) exhibits a DC conductivity of 8.77 × 10⁻⁸ (Ω cm)⁻¹, which is almost two orders of magnitude higher than polynuclear compound [MoO₂(L²)]n (5), with DC conductivity being 2.66 × 10⁻⁹ (Ω cm)⁻¹. In both cases, the dominant transport is electronic, while EDC and higher DC conductivity of the polynuclear compound [MoO₂(L¹)]n (2) suggest a more facile and continuous transfer of charge carriers through its structure. Despite the only structural difference between ligands H₂L¹ and H₂L² being a single methyl group, this small variation seems to significantly impact conductivity and activation energy. Typically, an electron-donating group like methyl (CH₃) is expected to enhance conductivity compared to a hydrogen atom (H). However, in this case, replacing the methyl group with a hydrogen atom results in higher conductivity values comparing the [MoO₂(L¹or²)]n (2 and 5) compounds. The hydrogen atom is smaller than the methyl group, which may lead to better planarity of the molecule. Enhanced planarity can facilitate better π-π stacking interactions between molecules, creating more efficient charge transport pathways. Additionally, the absence of the methyl group reduces steric hindrance, allowing for tighter molecular packing, which should strengthen intermolecular interactions, and potentially improve conductivity.

Conversely, the mononuclear compounds [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4), exhibit discrepancies during measuring cycles. Representative spectra of the heating vs. cooling run for compound [MoO₂(L¹)(H₂O)] (1) are shown in Fig. 3(a) and (b), while those for [MoO₂(L²)(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4) are in the ESI,† Fig. S26 and S27, respectively. For all three mononuclear compounds, in both runs, one can observe the predominance of the frequency-dependent component in the conductivity spectra, consequently having lower DC values compared to the polynuclear ones [MoO₂(L¹or²)]n (2 and 5, respectively), see Table 4. The observed differences in heating and cooling conductivity spectra could be related to structural changes associated with the release of coordinated solvent, i.e. H₂O and MeOH, during IS measurements from 100 to 140 °C, Table 2. Furthermore, the changes in DC conductivity values in the different runs are more pronounced in the Arrhenius plots, Fig. 3(c) and ESI,† Fig. S26 and S27(c). Notably, the heating run exhibits non-monotonic DC conductivity changes, while the cooling shows a monotonic change, suggesting structural transformations in heating while being stable in cooling. Activation energies obtained from cooling run for mononuclear compounds after transformation, are listed in Table 4.

Comparison of complex [MoO₂(L₁)(H₂O)] (1) with [MoO₂(L²)-(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4) before structural transformations, reveals interesting trends which can be correlated to structural features. One can conjecture that the more complex arrangement of [MoO₂(L₁)(H₂O)] (1) with an extended supra-molecular network present, has a positive effect on conductivity at RT (1.45 × 10⁻¹⁵ (Ω cm)⁻¹ for (1) vs. 1.07 × 10⁻¹⁵ (Ω cm)⁻¹ (3) and 6.92 × 10⁻¹⁶ (4)), but more interestingly, shows an impact on temperature dependence. At RT, complex [MoO₂(L₁)(H₂O)] (1) shows slightly higher DC conductivity, whereas temperature-dependent measurements reveal moderate differences between the mentioned complexes (up to one order of magnitude at 120 °C, 4.17 × 10⁻¹⁴ (Ω cm)⁻¹ for (1) vs. 3.98 × 10⁻¹⁵ (Ω cm)⁻¹ (3) and 5.50 × 10⁻¹⁵ (Ω cm)⁻¹ (4)).

Correlation between electrical properties of all five complexes in this study, based on different ligands (H₂L¹ and H₂L²) and type of Mo-complex (poly- vs. mononuclear and coordinated solvent, H₂O vs. MeOH, for mononuclear complexes), can be done, Fig. 4. One can see that transformed complexes (mono/polynuclear) with

<figure><img src="image_11.png" /><figcaption>Fig. 3 Conductivity spectra for mononuclear [MoO₂(L¹)(H₂O)] (1) compound in heating (a) and cooling (b) runs, along with (c) Arrhenius plots for DC conductivity for both runs (red circle – heating, blue circle – cooling).</figcaption></figure>

<figure><img src="image_12.png" /></figure>
the H₂L¹ ligand exhibit significantly lower activation energy values (60 and 40 kJ mol⁻¹, respectively) compared to those with the H₂L² ligand (81–95 kJ mol⁻¹). As mentioned above, this indicates that the H₂L¹ ligand facilitates easier electron transfer, resulting in lower energy barriers for conduction processes.

The mononuclear complexes with H₂L², namely [MoO₂(L²)-(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4), after structural transformation demonstrate similar activation energies, as shown in Table 4 and Fig. 4, which suggests that even though different solvent molecules (H₂O and MeOH) are present before transformation, the resulting transformed compound is the same. This transformation likely involves the loss of the solvent molecules in complexes [MoO₂(L²)(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4) above 140 °C, and subsequent polymerization to [MoO₂(L²)]ₙ (5) species, leading to changes in their electrical properties. In the cooling run, we do not observe non-monotonic changes, indicating the stability of the transformed complexes. The DC conductivity at 200 °C, and EₐDC values of the transformed mononuclear complexes [MoO₂(L²)(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4) and the polynuclear complex [MoO₂(L²)]ₙ (5) are comparable (84 and 81 vs. 95 kJ mol⁻¹), Table 4., and this consistency suggests the polymerisation process. The intrinsic factors, such as the ligand structure and the coordination environment around the molybdenum centre, play a crucial role and affect the electrical properties of these compounds. The ligand structure influences the electronic distribution and steric effects, while molybdenum centre's coordination environment affects the overall stability and conductivity of the complexes.

On the other hand, in the case of complexes with H₂L¹ ligand, mononuclear complex [MoO₂(L¹)(H₂O)] (1) and polynuclear complex [MoO₂(L¹)]ₙ (2) exhibit noticeable differences in their electrical properties, see Fig. 4. Compound [MoO₂(L¹)(H₂O)] (1), which includes a coordinated water molecule, exhibits after transformation DC conductivity of 1.72 × 10⁻¹¹ (Ω cm)⁻¹ and EₐDC of 60 kJ mol⁻¹, which is following the previously reported Mo compounds with the similar type of ligands.⁶ In contrast, we should emphasize here the interesting behaviour observed for the polynuclear [MoO₂(L¹)]ₙ (2) that shows significantly higher

<figure><img src="image_13.png" /><figcaption>Fig. 4 Conductivity at 200 °C and activation energy in the cooling run after transformation from IS analysis for all compounds in this study.</figcaption></figure>

<table><caption>**Table 5** Conductivity from IS analysis for [MoO₂(L²)(H₂O)] (3), [MoO₂(L²)-(MeOH)] (4), [VO(L²)(OEt)(H₂O)], [VO(L²)(OMe)(MeOH)] and [VO₂(L²)]₂ × H₂O measured at 100 °C in heating run</caption><thead><tr><th>Compound</th><th>σ<sub>DC</sub><sup>a</sup>/(Ω cm)<sup>-1</sup></th></tr></thead><tbody><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(H<sub>2</sub>O)] (3)</td><td>2.43 × 10<sup>-15</sup></td></tr><tr><td>[VO(L<sup>2</sup>)(OEt)(H<sub>2</sub>O)]</td><td>1.53 × 10<sup>-11</sup></td></tr><tr><td>[VO<sub>2</sub>(L<sup>2</sup>)]<sub>2</sub> × 2H<sub>2</sub>O</td><td>3.00 × 10<sup>-12</sup></td></tr><tr><td>[MoO<sub>2</sub>(L<sup>2</sup>)(MeOH)] (4)</td><td>5.91 × 10<sup>-15</sup></td></tr><tr><td>[VO(L<sup>2</sup>)(OMe)(MeOH)]</td><td>7.02 × 10<sup>-14</sup></td></tr></tbody><tfoot><tr><td colspan="2"><sup>a</sup> Measured at 200 °C.</td></tr></tfoot></table>

DC conductivity of 8.77 × 10⁻⁸ (Ω cm)⁻¹ (an increase of 4 order of magnitude) and lower activation energy (40 kJ mol⁻¹) in comparison to complex [MoO₂(L¹)(H₂O)] (1) where polymerization is expected upon heating. This pronounced difference, with DC conductivity being the highest while at the same time the lowest activation energy, observed among the five studied complexes, is both intriguing and promising for potential tuning of the material's properties. Further investigation into this effect is warranted to understand better and exploit these properties.

Here, it is noteworthy to make the correlation between the electrical properties of molybdenum complexes in this study and corresponding vanadium complexes with the same H₂L² ligand, from our previous work,¹⁰ Table 5 and ESI,† Table S5. Comparison between mononuclear [MoO₂(L²)(H₂O)] (3) and [VO(L²)(OEt)(H₂O)], as well as dinuclear [VO₂(L²)]₂ × 2H₂O, reveals that [VO(L²)(OEt)(H₂O) shows the highest conductivity. This suggests a strong positive effect of the vanadium centre in conjunction with water on electrical properties, being both much higher (3–4 orders of magnitude) in comparison to Mo-based one with H₂L² ligand.

On the other, a comparison for complexes containing coordinated MeOH and different metal centres (Mo/V), namely [MoO₂(L²)(MeOH)] (4) and [VO(L²)(OMe)(MeOH)], reveals that the latter shows one order of magnitude higher conductivity, thereby, one more time, reinforcing the improved electrical properties of vanadium over molybdenum. The presence of methoxy ligand in [VO(L²)(OMe)(MeOH)], in addition to methanol in both complexes, exhibit a positive effect on conductivity also.

Overall, the study underscores the critical role of the metal centre in the resulting electrical properties of the complexes. The coordination environment, including the type of ligand and coordinated solvent, additionally plays a significant role in modulating electrical characteristics, albeit to a lesser extent compared to the influence of the metal centre. In molybdenum complexes, the coordinated solvent shows minimal effect compared to vanadium complexes, where coordinated water results in complexes with improved conductivity.

# Experimental

## Materials

### Ligand synthesis

*Solution-based synthesis.* Yellow 2-hydroxy-3-methoxybenzaldehyde (0.5292 g, 3.478 mmol) was dissolved in 30 mL of methanol in a 100 mL round bottom flask. White formic or

<figure><img src="image_14.png" /></figure>
acetic acid hydrazide (0.2090 g, 3.478 mmol) was added to the colourless solution. The reaction was refluxed for two hours and left at room temperature. The obtained yellow crystals were separated by filtration and analysed.

**Mechanochemically-based synthesis.** 2-Hydroxy-3-methoxybenzaldehyde was placed in a stainless-steel crucible (14.5 mg, 0.0954 mmol), formic acid hydrazide (5.7 mg, 0.0954 mmol) and 30 µL of methanol. The mechanochemical synthesis was carried out for 30 minutes at a frequency of 3 Hz. Mechanochemical synthesis provides yields of >99%.

$H_2L^1$. Colour: white. Yield for solution-based synthesis: 0.5372 g, 79.5%. IR-ATR $\nu$/cm$^{-1}$: 3300, 3195 $\nu$ O-H, 2943 $\nu$ C-H (CH$_3$), 2859 $\nu_{as}$ C-H (CH$_2$), 2845 $\nu_{s}$ C-H (CH$_2$), 1688 $\nu$ C=O, 1605 C=N.

DSC: $T_e$ = 174.97 °C, $E$ = 32.01 kJ mol$^{-1}$.

¹H NMR (DMSO) $\delta$/ppm: 3,81 (d, 3H, C-H, 2, 3, 4) $J$ = 1.96 Hz, 6,83 (m, 1H, H-Ar, 6) $J_1$ = 15.28 Hz $J_2$ = $J_3$ = 5.2 Hz, 6,99 (dd, 1H, N-H, 9) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 7,03 (dd, 1H, H-Ar, 5) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 7,16 (dd, 1H, H-Ar, 7) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 8,37 (s, 1H, C-H, 10), 8,69 (d, 1H, C-H, 8) $J$ = 4.16 Hz, 11,68 (s, 1H, O-H, 1).

¹³C NMR (DMSO) $\delta$/ppm: 56,30 (b), 113,47 (d), 114,29 (e), 119,59 (g), 120,76 (f), 143,30 (h), 147,94 (c), 157,39 (a), 165,22 (i).

$H_2L^2$. Colour: white. Yield for solution-based synthesis: 0.5911 g, 83.6%. IR-ATR: $\nu$/cm$^{-1}$: 3317 i 3185 $\nu$ O-H, 2939 $\nu$ C-H (CH$_3$), 2868 $\nu_{as}$ C-H (CH$_2$), 2838 $\nu_{s}$ C-H (CH$_2$), 1672 $\nu$ C=O, 1609 C=N.

DSC: $T_e$ = 179.98 °C, $E$ = 33.24 kJ mol$^{-1}$.

¹H NMR (DMSO) $\delta$/ppm: 1,97 (s, 3H, C-H, 10, 11, 12) 3,81 (d, 3H, C-H, 2, 3, 4) $J_1$ = 5.2 Hz, 6,83 (m, 1H, H-Ar, 6) $J_1$ = 11.32 Hz $J_2$ = $J_3$ = 5.2 Hz, 7,01 (dd, 1H, H-Ar, 5) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 7,10 (dd, 1H, H-Ar, 7) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 8,33 (d, 1H, C-H, 8) $J$ = 18.52 Hz, 11,24 (s, 1H, N-H, 9), 11,59 (s, 1H, O-H, 1).

¹³C NMR (DMSO) $\delta$/ppm: 20,78 (j), 56,29 (b), 113,26 (d), 114,13 (e), 119,51 (g), 120,10 (f), 141,05 (h), 147,47 (c), 165,84 (a), 172,00 (i).

### Molybdenum(vi) complexes

#### Mononuclear complexes

Water-coordinated complexes [MoO$_2$(L)(H$_2$O)]. In a 100 mL round bottom flask, the ligand $H_2L^1$ (53.0 mg, 0.2728 mmol) was dissolved in 30 mL of dichloromethane with heating. [MoO$_2$(acac)$_2$] (88.9 mg, 0.2728 mmol) was then added. The reaction was refluxed for two hours. Precipitate appears immediately. The products were analyzed using IR-ATR spectroscopy, TGA/DSC analysis and NMR spectroscopy.

[MoO$_2$(L$^1$)(H$_2$O)] (1). Colour: orange. Yield for solution-based synthesis: 48.8%.

IR-ATR: $\nu$/cm$^{-1}$: 3343 $\nu$ O-H, 2958 $\nu$ C-H (CH$_3$), 2934 $\nu_{as}$ C-H (CH$_2$), 2839 $\nu_{s}$ C-H (CH$_2$), 1599 C=N (imin), 1264 C=O, 895 i 861 $\nu$ O=Mo=O.

TGA: $w_t$ (H$_2$O) = 5.30%, $w_{exp}$ (H$_2$O) = 5.77%, $w_t$ (MoO$_3$) = 42.32%, $w_{exp}$ (MoO$_3$) = 42.27%.

EA: $C_t$: 31.97, $C_{exp}$: 31.02, $H_t$: 2.98, $H_{exp}$: 2.81, $N_t$: 8.28, $N_{exp}$: 7.87.

¹H NMR (DMSO) $\delta$/ppm: 3,80 (d, 3H, C-H, 1, 2, 3) $J$ = 5.2 Hz, 7,01 (t, 1H, H-Ar, 5) $J$ = 5.2 Hz, 7,24 (dd, 1H, H-Ar, 4) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 7,29 (dd, 1H, H-Ar, 6) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 7,76 (s, 1H, C-H, 8), 8,82 (s, 1H, C-H, 7).

¹³C NMR (DMSO) $\delta$/ppm: 56,30 (b), 117,66 (e), 120,48 (d), 121,88 (g), 125,88 (f), 148,97 (a), 149,71 (c), 157,55 (i), 163,15 (h).

The same complex can be obtained by mechanochemical synthetic approach: [MoO$_2$(acac)$_2$] (19,0 mg, 0,5186 µmol), and ligand $H_2L^1$ (11,3 mg, 0,5186 µmol) are put in the stainless-steel crucible. 45 µL methanol was added and milled for 60 min at 25 Hz. Mechanochemical synthesis provides yields of >99%.

[MoO$_2$(L$^2$)(H$_2$O)] (3). Colour: yellow. Yield: 59.6%.

IR-ATR: $\nu$/cm$^{-1}$: 3440 $\nu$ N-H, 3244 $\nu$ O-H, 2951 $\nu$ C-H (CH$_3$), 2848 $\nu$ C-H (CH$_2$), 1596 C=N (imin), 1254 C=O, 906 i 866 $\nu$ O=Mo=O.

TGA: $w_t$ (H$_2$O) = 5.09%, $w_{exp}$ (H$_2$O) = 5.79%, $w_t$ (MoO$_3$) = 40.64%, $w_{exp}$ (MoO$_3$) = 39.29%.

EA: $C_t$: 34.11, $C_{exp}$: 34.05, $H_t$: 3.43, $H_{exp}$: 3.11, $N_t$: 7.95, $N_{exp}$: 7.15.

¹H NMR (DMSO) $\delta$/ppm: 2,06 (s, 3H, C-H, 8, 9, 10), 3,79 (d, 3H, C-H, 1, 2, 3) $J$ = 5.2 Hz, 6,99 (t, 1H, H-Ar, 5) $J$ = 4.72 Hz, 7,21 (dd, 1H, H-Ar, 4) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 7,24 (dd, 1H, H-Ar, 6) $J_1$ = 5.2 Hz $J_2$ = 0.9 Hz, 8,70 (s, 1H, C-H, 7).

¹³C NMR (DMSO) $\delta$/ppm: 16,79 (j), 55,19 (b), 116,20 (e), 119,67 (d), 120,66 (g), 124,53 (f), 147,82 (a), 148,40 (c), 154,19 (h), 171,90 (i).

Methanol-coordinated complex [MoO$_2$(L$^2$)(MeOH)]. In a 100 mL round bottom flask, the ligand $H_2L^2$ (49.5 mg, 0.2376 mmol) was dissolved in 30 mL of methanol. [MoO$_2$(acac)$_2$] (77.6 mg, 0.2376 mmol) was then added. The reaction was, refluxed for two hours and left until the appearance of a precipitate at room temperature. The resulting yellow crystals were analyzed using IR-ATR spectroscopy, TGA/DSC analysis and single-crystal X-ray diffraction.

[MoO$_2$(L$^2$)(MeOH)] (4). Colour: orange. Yield for solution-based synthesis: 25.0%.

IR-ATR: $\nu$/cm$^{-1}$: 2964 $\nu$ C-H (CH$_3$), 2933 $\nu$ C-H (CH$_2$), 1612 C=N (imin), 1259 C=O, 906 i 868 $\nu$ O=Mo=O.

TGA: $w_t$ (MeOH) = 8.70%, $w_{exp}$ (MeOH) = 8.97%, $w_t$ (MoO$_3$) = 39.09%, $w_{exp}$ (MoO$_3$) = 38.40%.

EA: $C_t$: 36.08, $C_{exp}$: 35.57, $H_t$: 3.85, $H_{exp}$: 3.21, $N_t$: 7.68, $N_{exp}$: 7.16.

The same complex can be obtained by mechanochemical synthetic approach: [MoO$_2$(acac)$_2$] (14.4 mg, 0.0442 mmol), and ligand $H_2L^1$ (9.2 mg, 0.0442 mmol) are put in the stainless-steel jar. 45 µL methanol was added and milled for 60 min at 25 Hz. Mechanochemical synthesis provides yields of >99%.

Polynuclear complexes [MoO$_2$(L$^{1or2}$)]$_n$. Ligand $H_2L^1$ (49.5 mg, 0.2548 mmol) was dissolved in 30 mL of methanol or acetonitrile with heating. [MoO$_2$(acac)$_2$] (83.1 mg, 0.2548 mmol) was added to the reaction mixture. The reaction was refluxed for two hours and left at room temperature until a precipitate appeared. The resulting brown precipitate was filtered off and analyzed using IR-ATR spectroscopy and TGA/DSC analysis.

<figure><img src="image_15.png" /></figure>
In a 100 mL round bottom flask, the ligand H₂L² (44.8 mg, 0.2151 mmol) was dissolved in 30 mL of dichloromethane with heating. [MoO₂(acac)₂] (70.16 mg, 0.2151 mmol) was then added. The reaction was refluxed for two hours. Precipitate appears immediately. The products were analyzed using IR-ATR spectroscopy and TGA/DSC analysis.

[MoO₂(L¹)]ₙ (2). Colour: brown. Yield: 36.1%.

IR-ATR: ν/cm⁻¹: 2938 ν C–H (CH₃), 2839 ν C–H (CH₂), 1595 C≡N, 1259 C–O, 922 i 877 ν O=Mo=O.

TGA: *w*<sub>t</sub> (MoO<sub>3</sub>) = 44.8%, *w*<sub>exp</sub> (MoO<sub>3</sub>) = 48.70%.

EA: C<sub>t</sub>: 33.77, C<sub>exp</sub>: 33.23, H<sub>t</sub>: 2.52, H<sub>exp</sub>: 2.12, N<sub>t</sub>: 8.75, N<sub>exp</sub>: 8.23.

[MoO₂(L²)]ₙ (5). Colour: brown. Yield: 39.5%.

IR-ATR: ν/cm⁻¹: 2965 ν C–H (CH₃), 2935 νₐs C–H (CH₂), 2843 νₛ C–H (CH₂), 1618 C≡N, 1265 C–O, 834 ν O=Mo=O.

TGA: *w*<sub>t</sub> (MoO<sub>3</sub>) = 42.82%, *w*<sub>exp</sub> (MoO<sub>3</sub>) = 42.66%.

EA: C<sub>t</sub>: 35.95, C<sub>exp</sub>: 35.16, H<sub>t</sub>: 3.02, H<sub>exp</sub>: 3.23, N<sub>t</sub>: 8.38, N<sub>exp</sub>: 8.60.

## Methods

The prepared compounds were characterized and identified using elemental analysis (EA), infrared spectroscopy (IR-ATR, Infrared spectroscopy - Attenuated Total Reflectance), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), Single Crystal X-ray Diffraction (SCXRD), and impedance spectroscopy (IS).

IR-ATR spectroscopic analysis was performed on a PerkinElmer Spectrum Two spectrometer equipped with a diamond ATR attachment. The recording was carried out in the 4000–400 cm⁻¹ range with four scans. The spectra were processed and analysed with the Excel program. Nuclear magnetic resonance (NMR) spectra were recorded on a Bruker Avance III HD 400 spectrometer operating at 400 MHz. Compounds were dissolved in dmso-d₆ and measured in 5 mm NMR tubes at 298 K with TMS as an internal standard. The proton and carbon NMR chemical shifts of all compounds in dmso-d₆ solution were deduced by combined use of one (¹H, ¹³C APT) and two-dimensional NMR techniques (COSY, HMQC and HMBC). NMR spectra are available in ESI,† Scheme S2 and Fig. S28–S35.

Differential scanning calorimetry (DSC) analysis was performed on a Mettler-Toledo DSC823e instrument in the range from 25 °C to 300 °C in an inert nitrogen atmosphere with a flow rate of 50 mL min⁻¹ and heating of 10 °C min⁻¹. The samples were recorded in closed aluminium containers. The measurement results were processed with the Mettler STARe Evaluation Software v17.00 program.

Thermogravimetric (TGA) analyses were performed using a Mettler-Toledo TGA/DSC 3+ in closed aluminium oxide containers. All experiments were performed in an oxygen atmosphere with a flow rate of 200 cm³ min⁻¹ and heating at 10 °C min⁻¹. The recording was carried out in the temperature range from 25 °C to 600 °C. The measurement results were processed with the Mettler STARe Evaluation Software v17.00 program.

Complex impedance was measured across a broad frequency range (0.01 Hz to 1 MHz) and temperature range (30–200 °C, in 10 °C increments) using a Novocontrol Alpha-AN dielectric

spectrometer. Temperature control was maintained within ±0.2 °C. Measurements were conducted on powder samples pressed into cylindrical disks with a diameter of 5 mm and a thickness of 1 mm under a uniform load of 2 × 10³ kg using a hydraulic press. Gold electrodes, 3.8 mm in diameter, were sputtered on both sides of the disk using a Quorum Technologies SC7620 magnetron for electrical contact. The sample was then positioned between the two electrodes of the BDS cell in a sandwich configuration. Impedance spectra were analyzed using equivalent electrical circuits (EEC) modelling, with parameters obtained through complex non-linear least square (CNLLSQ) fitting with WinFit software.⁴⁰ The system shows resistance (R) and capacitance (C) related to the sample and can be modelled with an RC element in a sandwich configuration. The impedance spectrum exhibited a single semicircle related to bulk effects for all studied complexes. The complex impedance plots typically consisted of a single depressed semicircle with the center below the real axis. Therefore, a constant-phase element (CPE) was used in the equivalent circuits rather than a simple capacitor. The empirical function defines the CPE: Z<sup>*</sup><sub>CPE</sub> = 1/A(jω)<sup>z</sup>, where A and z are the constants, 0 ≤ α ≤ 1, a being 1 for the ideal capacitor, and 0 for the ideal resistor. In a rough approximation, the parameter A can be equated with the value of the “real” capacity. From the resistance values obtained through the fitting procedures, and the electrode dimensions (sample thickness d and electrode area A), the DC conductivity was calculated.

The catalytic reactions were followed by GC techniques on Agilent 6890A chromatograph equipped with an FID detector and Agilent CP7495 (25 m × 0.25 mm × 0.12 µm). The GC parameters were quantified using authentic samples of the reactants and products. The conversion of linalool and formation of 2-(5-methyl-5-vinyl-tetrahydrofuran-2-yl propan-2-ol) and 2,2,6-trimethyl-6-vinyltetrahydropyran-3-ol were calculated from calibration curves using authentic samples of the studied species relative to dodecane or ethylbenzene as an internal standard (r² = 0.999).

## Linalool oxidation

**Using TBHP.** A mixture of linalool (1.54 g, 10 mmol), dodecane (0.1 mL) as internal standard, and catalyst (0.05 mmol) was mixed and heated at 80 °C before adding TBHP in water (70% w/w) (2.47 mL, 20 mmol) or in decane (5.0–6.0 M) (3.64 mL, 20 mmol). The reaction was monitored for five hours by taking and analyzing aliquots of the organic phase (0.1 mL) at defined time points (0, 20, 60, 120, 180, 240, and 300 minutes). Each sample taken was mixed with one mL of MeCN and analyzed using GC.

**Using H₂O₂.** A mixture of linalool (1.54 g, 10 mmol), dodecane (0.1 mL) as internal standard, and catalyst (0.05 mmol) was mixed and heated at 70 °C before adding H₂O₂ in water (30% w/w) (2.06 mL, 2 mol). The reaction was monitored for five hours by taking and analyzing aliquots of the organic phase (0.1 mL) at defined time points (0, 20, 60, 120, 180, 240, and 300 minutes). Each sample taken was mixed with one mL of MeCN and analyzed using GC.

<figure><img src="image_16.png" /></figure>
A mixture of linalool (1.54 g, 10 mmol), ethylbenzene (0.3 mL) as internal standard, vanadium catalyst (0.05 mmol), and acetonitrile (5 mL) was mixed and heated at 70 °C before adding H₂O₂ in water (30% w/w) (2.06 mL, 20 mmol). The reaction was monitored for five hours by taking and analyzing aliquots of the organic phase (0.6 mL) at defined time points (0, 20, 60, 120, 180, 240, and 300 minutes). Each sample taken was mixed with 0.4 mL of MeCN and analyzed using GC.

## Crystallography

Single crystals of [pyH]₄(Mo₈O₂₆), H₂L¹, H₂L², [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)(H₂O)] (3) and [MoO₂(L²)(MeOH)] (4) of appropriate quality were selected for the diffraction experiments. Data were compiled using a Rigaku XtaLAB Synergy-S diffractometer equipped with a Dualflex source (Cu Kα radiation, λ = 1.54184 Å) and a HyPix detector. Data were gathered via ω-scans at 170 K and data were processed with the CrysAlis program package.⁴¹ A summary of the general crystallographic data is presented in Table S1 (ESI†). The structures were solved by dual-space methods with SHELXT.⁴² The refinement was done via full-matrix least-squares methods based on *F*² values against all reflections, including the anisotropic displacement parameters for all non-H atoms. Hydrogen atoms attached to carbon atoms were placed in geometrically idealized positions and refined by using the riding model, with *U*<sub>iso</sub> = 1.2*U*<sub>eq</sub> of the connected carbon atom, or as ideal CH₃ groups, with *U*<sub>iso</sub> = 1.5*U*<sub>eq</sub>. Hydrogen atoms attached to heteroatoms were located in the difference Fourier map in the final stages of the refinement procedure. All refinements were conducted using SHELXL.⁴³ The SHELX programs were operated within the Olex2 suite.⁴⁴ Geometrical calculations were performed by Platon⁴⁵ and molecular graphics were produced using Mercury.⁴⁶ CCDC 2367284–2367289† contains the supplementary crystallographic data for this paper.

## Conclusions

In the synthesis of molybdenum complexes, two distinct ligands characterized by variations in substituent groups on the hydrazide chain end were employed. Five novel molybdenum complexes were prepared from different solvents and subsequently characterised via different analytical techniques. These compounds encompassed the following entities: [MoO₂(L¹)]ₙ (2), [MoO₂(L²)]ₙ (5), [MoO₂(L¹)(H₂O)] (1), [MoO₂(L²)(H₂O)] (3), [MoO₂(L²)(MeOH)] (4). In all instances, the ligand established coordination with the metal centre through the ONO atom, resulting in mononuclear or polynuclear Mo moiety.

Building on our previous work with vanadium coordination compounds, we extended our research to molybdenum complexes, investigating them using impedance spectroscopy. We recognized the complexity associated with the liberation of coordinated solvents and the decomposition stages of the complexes, which we correlated with thermogravimetric analysis. This approach provided valuable insights into optimizing ss-IS measurements, determining appropriate heating temperatures,

and identifying potential sample transformations (e.g., from mononuclear to polynuclear forms). All examined molybdenum complexes exhibited a temperature-dependent increase in conductivity, characteristic of semiconducting behaviour. Notably, the polynuclear samples [MoO₂(L¹)]ₙ (2) and [MoO₂(L²)]ₙ (5) demonstrated high conductivities of 8.77 × 10⁻⁸ (Ω cm)⁻¹ and 2.39 × 10⁻⁹ (Ω cm)⁻¹, respectively. These values surpass those of previously published vanadium coordination complexes with acylhydrazone ligands, suggesting potential applications in various electronic devices, such as light-emitting diodes, rechargeable batteries, sensors, and other electronic components.

Furthermore, this research highlights the dual functionality of the synthesized molybdenum complexes, which, along with recently reported vanadium complexes, show promise not only for electronic applications but also for catalytic activities. The catalytic potential was evaluated using linalool as a bio-based substrate, revealing the significant efficacy of molybdenum catalysts in producing furanoid and pyranoid compounds when employing TBHP as an oxidant.

Bifunctionality is a pivotal factor in the evolution of next-generation materials, critically enabling innovative applications for future technologies. This principle underpins the objectives of our research investigations.

## Author contributions

Conceptualization: D. A., L. P., J. P. Data curation: J. S., M. C., E. T., M. R., L. P., J. P. Formal analysis: J. S., M. C., E. T., M. R., L. P., J. P. Funding acquisition: D. A., L. P., J. P. Investigation: J. S., E. T., J. P., L. P. Methodology: E. T., D. A., L. P., J. P. Project administration: D. A., J. P., L. P. Resources: M. R., D. A., L. P., J. P. Software: J. S., E. T., L. P. Supervision: D. A., L. P., J. P. Validation: J. S., M. C. Visualization: J. S., E. T., L. P., J. P. Writing – original draft: L. P., J. P. Writing – review & editing: J. S., E. T., L. P., J. P.

## Conflicts of interest

There are no conflicts to declare.

## Acknowledgements

This research was funded in part by COGITO 2023–2024: Sustainable polyesters using Mo and V catalysts (SusPolMoV) and CNRS: International Emerging Actions 2023–2024: Solvent-isober Processes-Organic solvent-free polyterpenes oxidation assisted by mechanochemically synthesized catalysts (SoSoPro). E. T., M. R., and J. P. acknowledge the support of project CIuK (grant KK.01.1.1.02.0016) co-financed by the Croatian Government and the European Union through the European Regional Development Fund-Competitiveness and Cohesion Operational Programme. LCC CNRS and IUT Chem Dpt are acknowledged for all the facilities needed during catalytic experiments.

<figure><img src="image_17.png" /></figure>
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