<figure><img src="image_381.png" /></figure>

623 J. Han, Y. Zheng, C. Wang, Y. Zhu, Z.-B. Huang, D.-Q. Shi, R. Zeng and Y. Zhao, *J. Org. Chem.*, **2016**, *81*, 5681-5689.

624 M. Wang, Y. Yang, Z. Fan, Z. Cheng, W. Zhu and A. Zhang, *Chem. Commun.*, **2015**, *51*, 3219-3222.

625 N. Chatani, Y. Ie, F. Kakiuchi and S. Murai, *J. Org. Chem.*, **1997**, *62*, 2604-2610.

626 N. Chatani, T. Asaumi, S. Yorimitsu, T. Ikeda, F. Kakiuchi and S. Murai, *J. Am. Chem. Soc.*, **2001**, *123*, 10935-10941.

627 N. Chatani, S. Yorimitsu, T. Asaumi, F. Kakiuchi and S. Murai, *J. Org. Chem.*, **2002**, *67*, 7557-7560.

628 L. V. Desai, K. L. Hull and M. S. Sanford, *J. Am. Chem. Soc.*, **2004**, *126*, 9542-9543.

629 A. R. Dick, K. L. Hull and M. S. Sanford, *J. Am. Chem. Soc.*, **2004**, *126*, 2300-2301.

630 D. Shabashov and O. Daugulis, *Org. Lett.*, **2005**, *7*, 3657-3659.

631 S. Schröter, C. Stock and T. Bach, *Tetrahedron*, **2005**, *61*, 2245-2267.

632 L.-C. Campeau and K. Fagnou, *Chem. Soc. Rev.*, **2007**, *36*, 1058-1068.

633 J. De Houwer and B. U. W. Maes, *Synthesis*, **2014**, 2533-2550.

634 K. Murakami, S. Yamada, T. Kaneda and K. Itami, *Chem. Rev.*, **2017**, *117*, 9302-9332.

635 J. A. Leitch and C. G. Frost, *Chem. Soc. Rev.*, **2017**, *46*, 7145-7153.

636 F. Juliá-Hernández, M. Simonetti and I. Larrosa, *Angew. Chem., Int. Ed.*, **2013**, *52*, 11458-11460.

637 G. Meng and M. Szostak, *ACS Catal.*, **2017**, *7*, 7251-7256.

638 G. M. Reddy, N. S. S. Rao, P. Satyanarayana and H. Maheswaran, *RSC Adv.*, **2015**, *5*, 105347-105352.

639 Y. Kita, H. Tohma, K. Hatanaka, T. Takada, S. Fujita, S. Mitoh, H. Sakurai and S. Oka, *J. Am. Chem. Soc.*, **1994**, *116*, 3684-3691.

640 R. A. Jagtap, V. Soni and B. Punji, *ChemSusChem*, **2017**, *10*, 2242-2248.

641 L. Su, D.-D. Guo, B. Li, S.-H. Guo, G.-F. Pan, Y.-R. Gao and Y.-Q. Wang, *ChemCatChem*, **2017**, *9*, 2001-2008.

642 P. Nareddy, F. Jordan and M. Szostak, *Org. Biomol. Chem.*, **2017**, *15*, 4783-4788.

643 Y.-L. Zou, Z.-Y. Wang, Y.-M. Feng, Y.-G. Li and E. A. B. Kantchev, *Eur. J. Org. Chem.*, **2017**, 6274-6282.

644 S.-S. Zhang, C.-Y. Jiang, J.-Q. Wu, X.-G. Liu, Q. Li, Z.-S. Huang, D. Li and H. Wang, *Chem. Commun.*, **2015**, *51*, 10240-10243.

645 Z. Li, X. Zhou, P. Lu and Y. Wang, *J. Org. Chem.*, **2016**, *81*, 9433-9437.

646 H. Wu, T. Liu, M. Cui, Y. Li, J. Jian, H. Wang and Z. Zeng, *Org. Biomol. Chem.*, **2017**, *15*, 536-540.

647 V. K. Tiwari, N. Kamal and M. Kapur, *Org. Lett.*, **2015**, *17*, 1766-1769.

648 A. Schischko, H. Ren, N. Kaplaneris and L. Ackermann, *Angew. Chem., Int. Ed.*, **2017**, *56*, 1576-1580.

649 R. Odani, K. Hirano, T. Satoh and M. Miura, *Angew. Chem., Int. Ed.*, **2014**, *53*, 10784-10788.

650 D. Das, P. Poddar, S. Maity and R. Samanta, *J. Org. Chem.*, **2017**, *82*, 3612-3621.

651 P. Peng, J. Wang, H. Jiang and H. Liu, *Org. Lett.*, **2016**, *18*, 5376-5379.

652 K. Anil Kumar, P. Kannaboina and P. Das, *Org. Biomol. Chem.*, **2017**, *15*, 5457-5461.

653 D. Zell, S. Warratz, D. Gelman, S. J. Garden and L. Ackermann, *Chem. - Eur. J.*, **2016**, *22*, 1248-1252.

654 Y. Ebe and T. Nishimura, *J. Am. Chem. Soc.*, **2015**, *137*, 5899-5902.

655 Y. Ebe, M. Onoda, T. Nishimura and H. Yorimitsu, *Angew. Chem., Int. Ed.*, **2017**, *56*, 5607-5611.

656 Y. Wu and B. Zhou, *ACS Catal.*, **2017**, *7*, 2213-2217.

657 G.-F. Zhang, Y. Li, X.-Q. Xie and C.-R. Ding, *Org. Lett.*, **2017**, *19*, 1216-1219.

658 B. Zhou, Y. Hu and C. Wang, *Angew. Chem., Int. Ed.*, **2015**, *54*, 13659-13663.

659 Y. Hara, S. Onodera, T. Kochi and F. Kakiuchi, *Org. Lett.*, **2015**, *17*, 4850-4853.

660 J. A. Boerth and J. A. Ellman, *Chem. Sci.*, **2016**, *7*, 1474-1479.

661 T. J. Potter and J. A. Ellman, *Org. Lett.*, **2016**, *18*, 3838-3841.

662 J. Kim, S.-W. Park, M.-H. Baik and S. Chang, *J. Am. Chem. Soc.*, **2015**, *137*, 13448-13451.

663 H. Cheng, W. Dong, C. A. Dannenberg, S. Dong, Q. Guo and C. Bolm, *ACS Catal.*, **2015**, *5*, 2770-2773.

664 Y.-F. Liang, L. Massignan, W. Liu and L. Ackermann, *Chem. - Eur. J.*, **2016**, *22*, 14856-14859.

665 S.-L. Liu, Y. Li, J.-R. Guo, G.-C. Yang, X.-H. Li, J.-F. Gong and M.-P. Song, *Org. Lett.*, **2017**, *19*, 4042-4045.

666 C. Zhu, J. L. Schwarz, S. Cembellín, S. Greßies and F. Glorius, *Angew. Chem., Int. Ed.*, **2018**, *57*, 437-441.

667 Q. Lu, S. Cembellín, S. Greßies, S. Singha, C. G. Daniliuc and F. Glorius, *Angew. Chem., Int. Ed.*, **2018**, *57*, 1399-1403.

668 W. Miura, K. Hirano and M. Miura, *J. Org. Chem.*, **2017**, *82*, 5337-5344.

669 M. Barday, C. Janot, N. R. Halcovitch, J. Muir and C. Aïssa, *Angew. Chem., Int. Ed.*, **2017**, *56*, 13117-13121.

670 A. C. B. Burtoloso, R. M. P. Dias and I. A. Leonarczyk, *Eur. J. Org. Chem.*, **2013**, 5005-5016.

671 H. Wang, S. Yu, Z. Qi and X. Li, *Org. Lett.*, **2015**, *17*, 2812-2815.

672 D. Das, A. Biswas, U. Karmakar, S. Chand and R. Samanta, *J. Org. Chem.*, **2016**, *81*, 842-848.

673 V. Soni, R. A. Jagtap, R. G. Gonnade and B. Punji, *ACS Catal.*, **2016**, *6*, 5666-5672.

674 T. Yamakawa, Y. W. Seto and N. Yoshikai, *Synlett*, **2015**, 340-344.

675 D. Zhao, J. H. Kim, L. Stegemann, C. A. Strassert and F. Glorius, *Angew. Chem., Int. Ed.*, **2015**, *54*, 4508-4511.

676 J. H. Kim, T. Gensch, D. Zhao, L. Stegemann, C. A. Strassert and F. Glorius, *Angew. Chem., Int. Ed.*, **2015**, *54*, 10975-10979.

677 X. Cong, S. Zhai and X. Zeng, *Org. Chem. Front.*, **2016**, *3*, 673-677.

678 G. S. Kumar and M. Kapur, *Org. Lett.*, **2016**, *18*, 1112-1115.
<figure><img src="image_382.png" /></figure>

679 Q. Lu, F. J. R. Klauck and F. Glorius, *Chem. Sci.*, 2017, **8**, 3379-3383.

680 H. Wang, M. M. Lorion and L. Ackermann, *Angew. Chem., Int. Ed.*, 2017, **56**, 6339-6342.

681 T. H. Meyer, W. Liu, M. Feldt, A. Wuttke, R. A. Mata and L. Ackermann, *Chem. - Eur. J.*, 2017, **23**, 5443-5447.

682 D. Zell, Q. Bu, M. Feldt and L. Ackermann, *Angew. Chem., Int. Ed.*, 2016, **55**, 7408-7412.

683 D. Zell, U. Dhawa, V. Müller, M. Bursch, S. Grimme and L. Ackermann, *ACS Catal.*, 2017, **7**, 4209-4213.

684 D. Zell, V. Müller, U. Dhawa, M. Bursch, R. R. Presa, S. Grimme and L. Ackermann, *Chem. - Eur. J.*, 2017, **23**, 12145-12148.

685 J. Ni, H. Zhao and A. Zhang, *Org. Lett.*, 2017, **19**, 3159-3162.

686 X. Xue, J. Xu, L. Zhang, C. Xu, Y. Pan, L. Xu, H. Li and W. Zhang, *Adv. Synth. Catal.*, 2016, **358**, 573-583.

687 R. Qiu, L. Zhang, C. Xu, Y. Pan, H. Pang, L. Xu and H. Li, *Adv. Synth. Catal.*, 2015, **357**, 1229-1236.

688 S. Wang, J.-T. Hou, M.-L. Feng, X.-Z. Zhang, S.-Y. Chen and X.-Q. Yu, *Chem. Commun.*, 2016, **52**, 2709-2712.

689 H. Wang, F. Pesciaioli, J. C. A. Oliveira, S. Warratz and L. Ackermann, *Angew. Chem., Int. Ed.*, 2017, **56**, 15063-15067.

690 Q. Lu, S. Gressies, F. J. R. Klauck and F. Glorius, *Angew. Chem., Int. Ed.*, 2017, **56**, 6660-6664.

691 X.-F. Yang, X.-H. Hu, C. Feng and T.-P. Loh, *Chem. Commun.*, 2015, **51**, 2532-2535.

692 Y. Segawa, T. Maekawa and K. Itami, *Angew. Chem., Int. Ed.*, 2015, **54**, 66-81.

693 S. Prakash, K. Muralirajan and C.-H. Cheng, *Angew. Chem., Int. Ed.*, 2016, **55**, 1844-1848.

694 Y.-X. Lao, S.-S. Zhang, X.-G. Liu, C.-Y. Jiang, J.-Q. Wu, Q. Li, Z.-S. Huang and H. Wang, *Adv. Synth. Catal.*, 2016, **358**, 2186-2191.

695 Y. Yang, B. Li, W. Liu, R. Zhang, L. Yu, Q.-G. Ma, R. Lv, D. Du and T. Li, *J. Org. Chem.*, 2016, **81**, 11335-11345.

696 J. Sanjosé-Orduna, D. Gallego, A. Garcia-Roca, E. Martin, J. Benet-Buchholz and M. H. Pérez-Temprano, *Angew. Chem., Int. Ed.*, 2017, **56**, 12137-12141.

697 C.-Z. Luo, P. Gandeepan, Y.-C. Wu, C.-H. Tsai and C.-H. Cheng, *ACS Catal.*, 2015, **5**, 4837-4841.

698 Y. R. Han, S.-H. Shim, D.-S. Kim and C.-H. Jun, *Org. Lett.*, 2017, **19**, 2941-2944.

699 N. S. Upadhyay, J. Jayakumar and C.-H. Cheng, *Adv. Synth. Catal.*, 2016, **358**, 3381-3386.

700 B. Butschke and H. Schwarz, *Chem. Sci.*, 2012, **3**, 308-326.

701 D. Ghorai, C. Dutta and J. Choudhury, *ACS Catal.*, 2016, **6**, 709-713.

702 R. Morioka, K. Nobushige, T. Satoh, K. Hirano and M. Miura, *Org. Lett.*, 2015, **17**, 3130-3133.

703 T. Li, Z. Wang, W.-B. Qin and T.-B. Wen, *ChemCatChem*, 2016, **8**, 2146-2154.

704 T. Li, Z. Wang, M. Zhang, H.-J. Zhang and T.-B. Wen, *Chem. Commun.*, 2015, **51**, 6777-6780.

705 Y. Li, F. Xie and X. Li, *J. Org. Chem.*, 2016, **81**, 715-722.

706 S. M. Khake, V. Soni, R. G. Gonnade and B. Punji, *Chem. - Eur. J.*, 2017, **23**, 2907-2914.

707 A. Funayama, T. Satoh and M. Miura, *J. Am. Chem. Soc.*, 2005, **127**, 15354-15355.

708 S. B. Wang, Q. Gu and S. L. You, *J. Org. Chem.*, 2017, **82**, 11829-11835.

709 T. Li, Z. Wang, K. Xu, W. Liu, X. Zhang, W. Mao, Y. Guo, X. Ge and F. Pan, *Org. Lett.*, 2016, **18**, 1064-1067.

710 T. Li, C. Fu, Q. Ma, Z. Sang, Y. Yang, H. Yang, R. Lv and B. Li, *J. Org. Chem.*, 2017, **82**, 10263-10270.

711 (a) J. Li and L. Ackermann, *Angew. Chem., Int. Ed.*, 2015, **54**, 3635-3638; (b) A. B. Pawar and S. Chang, *Org. Lett.*, 2015, **17**, 660-663.

712 C. Qi, X. Hu and H. Jiang, *Chem. Commun.*, 2017, **53**, 7994-7997.

713 Z.-B. Chen, F.-L. Zhang, Q. Yuan, H.-F. Chen, Y.-M. Zhu and J.-K. Shen, *RSC Adv.*, 2016, **6**, 64234-64238.

714 W. Liu, S. C. Richter, R. Mei, M. Feldt and L. Ackermann, *Chem. - Eur. J.*, 2016, **22**, 17958-17961.

715 M. Chaitanya and P. Anbarasan, *J. Org. Chem.*, 2015, **80**, 3695-3700.

716 M. Chaitanya and P. Anbarasan, *Org. Lett.*, 2015, **17**, 3766-3769.

717 Y.-F. Liang, X. Li, X. Wang, Y. Yan, P. Feng and N. Jiao, *ACS Catal.*, 2015, **5**, 1956-1963.

718 Y.-S. Bao, D. Zhang, M. Jia and B. Zhaorigetu, *Green Chem.*, 2016, **18**, 2072-2077.

719 X. Liu, Z. Yi, J. Wang and G. Liu, *RSC Adv.*, 2015, **5**, 10641-10646.

720 F. Xiao, S. Chen, H. Huang and G.-J. Deng, *Eur. J. Org. Chem.*, 2015, 7919-7925.

721 S. Yu, Y. Li, L. Kong, X. Zhou, G. Tang, Y. Lan and X. Li, *ACS Catal.*, 2016, **6**, 7744-7748.

722 S. Maiti, L. Burgula, G. Chakraborti and J. Dash, *Eur. J. Org. Chem.*, 2017, 332-340.

723 Z. Wang, Y. Li, F. Zhu and X.-F. Wu, *Adv. Synth. Catal.*, 2016, **358**, 2855-2859.

724 F. Zhou, D.-S. Wang, X. Guan and T. G. Driver, *Angew. Chem.*, 2017, **129**, 4601-4605.

725 W. Liu, J. Bang, Y. Zhang and L. Ackermann, *Angew. Chem., Int. Ed.*, 2015, **54**, 14137-14140.

726 J. R. Hummel, J. A. Boerth and J. A. Ellman, *Chem. Rev.*, 2017, **117**, 9163-9227.

727 M. Yoshida, K. Kawai, R. Tanaka, T. Yoshino and S. Matsunaga, *Chem. Commun.*, 2017, **53**, 5974-5977.

728 X.-G. Liu, Q. Li and H. Wang, *Adv. Synth. Catal.*, 2017, **359**, 1942-1946.

729 P. Sharma, S. Rohilla and N. Jain, *J. Org. Chem.*, 2015, **80**, 4116-4122.

730 X.-S. Zhang, G. Li, X.-G. Zhang and X.-H. Zhang, *Tetrahedron*, 2015, **71**, 5458-5464.

731 F. Wang, X. Yu, Z. Qi and X. Li, *Chem. - Eur. J.*, 2016, **22**, 511-516.

732 T. Liu, W. Zhou and J. Wu, *Org. Lett.*, 2017, **19**, 6638-6641.

733 Q. Wang, F. Xie and X. Li, *J. Org. Chem.*, 2015, **80**, 8361-8366.

734 P. Peng, J. Wang, C. Li, W. Zhu, H. Jiang and H. Liu, *RSC Adv.*, 2016, **6**, 57441-57445.
735 C. Cheng and J. F. Hartwig, *Chem. Rev.*, 2015, **115**, 8946-8975.

736 A. C. Shaikh, D. S. Ranade, S. Thorat, A. Maity, P. P. Kulkarni, R. G. Gonnade, P. Munshi and N. T. Patil, *Chem. Commun.*, 2015, **51**, 16115-16118.

737 V. F. Pais, M. M. Alcaide, R. López-Rodríguez, D. Collado, F. Nájera, E. Pérez-Inestrosa, E. Álvarez, J. M. Lassaletta, R. Fernández, A. Ros and U. Pischel, *Chem. - Eur. J.*, 2015, **21**, 15369-15376.

738 N. Kano, M. Yamamura and T. Kawashima, *Dalton Trans.*, 2015, **44**, 16256-16265.

739 Y. Yoshigoe and Y. Kuninobu, *Org. Lett.*, 2017, **19**, 3450-3453.

740 S. D. Sarkar, N. Y. P. Kumar and L. Ackermann, *Chem. - Eur. J.*, 2017, **23**, 84-87.

741 W. Miura, K. Hirano and M. Miura, *Org. Lett.*, 2016, **18**, 3742-3745.

742 S. Okada, T. Namikoshi, S. Watanabe and M. Murata, *ChemCatChem*, 2015, **7**, 1531-1534.

743 L. Rubio-Perez, M. Iglesias, J. Munarriz, V. Polo, V. Passarelli, J. J. Perez-Torrente and L. A. Oro, *Chem. Sci.*, 2017, **8**, 4811-4822.

744 T. Wakaki, M. Kanai and Y. Kuninobu, *Org. Lett.*, 2015, **17**, 1758-1761.

745 X.-H. Hu, X.-F. Yang and T.-P. Loh, *ACS Catal.*, 2016, **6**, 5930-5934.

746 A. A. Kantak, L. Marchetti and B. DeBoef, *Chem. Commun.*, 2015, **51**, 3574-3577.

747 M. A. Ali, X. Yao, H. Sun and H. Lu, *Org. Lett.*, 2015, **17**, 1513-1516.

748 P. Patel and S. Chang, *ACS Catal.*, 2015, **5**, 853-858.

749 G. Li, C. Jia, Q. Chen, K. Sun, F. Zhao, H. Wu, Z. Wang, Y. Lv and X. Chen, *Adv. Synth. Catal.*, 2015, **357**, 1311-1315.

750 Y. Park, K. T. Park, J. G. Kim and S. Chang, *J. Am. Chem. Soc.*, 2015, **137**, 4534-4542.

751 Y. Park, S. Jee, J. G. Kim and S. Chang, *Org. Process Res. Dev.*, 2015, **19**, 1024-1029.

752 J. Park and S. Chang, *Angew. Chem., Int. Ed.*, 2015, **54**, 14103-14107.

753 Y. Liang, Y.-F. Liang, C. Tang, Y. Yuan and N. Jiao, *Chem. - Eur. J.*, 2015, **21**, 16395-16399.

754 R. Mei, J. Loup and L. Ackermann, *ACS Catal.*, 2016, **6**, 793-797.

755 S.-B. Wang, Q. Gu and S.-L. You, *Organometallics*, 2017, **36**, 4359-4362.

756 D. Das and R. Samanta, *Adv. Synth. Catal.*, 2018, **360**, 379-384.

757 M. A. Ali, X. Yao, G. Li and H. Lu, *Org. Lett.*, 2016, **18**, 1386-1389.

758 L. Shi and B. Wang, *Org. Lett.*, 2016, **18**, 2820-2823.

759 S. Yu, Y. Li, X. Zhou, H. Wang, L. Kong and X. Li, *Org. Lett.*, 2016, **18**, 2812-2815.

760 C. S. Azad and A. K. Narula, *RSC Adv.*, 2015, **5**, 100223-100227.

761 Y. Wu and B. Zhou, *Org. Lett.*, 2017, **19**, 3532-3535.

762 S. K. Santra, A. Banerjee, N. Khatun and B. K. Patel, *Eur. J. Org. Chem.*, 2015, 350-356.

763 S. Korwar, K. Brinkley, A. R. Siamaki, B. F. Gupton and K. C. Ellis, *Org. Lett.*, 2015, **17**, 1782-1785.

764 Y. Zhang, Y. Zhao, Y. Luo, L. Xiao, Y. Huang, X. Li, Q. Peng, Y. Liu, B. Yang, C. Zhu, X. Zhou and J. Zhang, *Org. Lett.*, 2017, **19**, 6470-6473.

765 J. Dong, P. Liu and P. Sun, *J. Org. Chem.*, 2015, **80**, 2925-2929.

766 T. Yamaguchi, E. Yamaguchi, N. Tada and A. Itoh, *Adv. Synth. Catal.*, 2015, **357**, 2017-2021.

767 W. Lu, H. Xu and Z. Shen, *Org. Biomol. Chem.*, 2017, **15**, 1261-1267.

768 P. Das, D. Saha, D. Saha and J. Guin, *ACS Catal.*, 2016, **6**, 6050-6054.

769 N. Khatun, A. Banerjee, S. K. Santra, W. Ali and B. K. Patel, *RSC Adv.*, 2015, **5**, 36461-36466.

770 S. Han, S. Sharma, J. Park, M. Kim, Y. Shin, N. K. Mishra, J. J. Bae, J. H. Kwak, Y. H. Jung and I. S. Kim, *J. Org. Chem.*, 2014, **79**, 275-284.

771 T. Okada, K. Nobushige, T. Satoh and M. Miura, *Org. Lett.*, 2016, **18**, 1150-1153.

772 P. Zhang, L. Hong, G. Li and R. Wang, *Adv. Synth. Catal.*, 2015, **357**, 345-349.

773 V. Pascanu, F. Carson, M. V. Solano, J. Su, X. Zou, M. J. Johansson and B. Martín-Matute, *Chem. - Eur. J.*, 2016, **22**, 3729-3737.

774 H. Fei and S. M. Cohen, *J. Am. Chem. Soc.*, 2015, **137**, 2191-2194.

775 G. Zhang, S. Sun, F. Yang, Q. Zhang, J. Kang, Y. Wu and Y. Wu, *Adv. Synth. Catal.*, 2015, **357**, 443-450.

776 F. Xie, Z. Zhang, X. Yu, G. Tang and X. Li, *Angew. Chem., Int. Ed.*, 2015, **54**, 7405-7409.

777 J. C. K. Chu and T. Rovis, *Angew. Chem., Int. Ed.*, 2018, **57**, 62-101.

778 G. Qiu and J. Wu, *Org. Chem. Front.*, 2015, **2**, 169-178.

779 D. Kalyani, N. R. Deprez, L. V. Desai and M. S. Sanford, *J. Am. Chem. Soc.*, 2005, **127**, 7330-7331.

780 F. Kakiuchi, K. Tsuchiya, M. Matsumoto, E. Mizushima and N. Chatani, *J. Am. Chem. Soc.*, 2004, **126**, 12792-12793.

781 B. Liu, P. Hu, X. Zhou, D. Bai, J. Chang and X. Li, *Org. Lett.*, 2017, **19**, 2086-2089.

782 S. Han, J. Park, S. Kim, S. H. Lee, S. Sharma, N. K. Mishra, Y. H. Jung and I. S. Kim, *Org. Lett.*, 2016, **18**, 4666-4669.

783 S. Kim, S. Han, J. Park, S. Sharma, N. K. Mishra, H. Oh, J. H. Kwak and I. S. Kim, *Chem. Commun.*, 2017, **53**, 3006-3009.

784 W. Hou, Y. Yang, Y. Wu, H. Feng, Y. Li and B. Zhou, *Chem. Commun.*, 2016, **52**, 9672-9675.

785 S.-Y. Yan, P.-X. Ling and B.-F. Shi, *Adv. Synth. Catal.*, 2017, **359**, 2912-2917.

786 X. Wang, D.-G. Yu and F. Glorius, *Angew. Chem., Int. Ed.*, 2015, **54**, 10280-10283.

787 P. Gao, W. Guo, J. Xue, Y. Zhao, Y. Yuan, Y. Xia and Z. Shi, *J. Am. Chem. Soc.*, 2015, **137**, 12231-12240.

788 J. H. Kim, S. Greßies, M. Boultadakis-Arapinis, C. Daniliuc and F. Glorius, *ACS Catal.*, 2016, **6**, 7652-7656.

789 G. Tan and J. You, *Org. Lett.*, 2017, **19**, 4782-4785.
<figure><img src="image_383.png" /></figure>

790 X. Zhou, S. Yu, L. Kong and X. Li, ACS Catal., 2016, **6**, 647-651.

791 S. Han, W. Ma, Z. Zhang, L. Liu, M. Tang and J. Li, Asian J. Org. Chem., 2017, **6**, 1014-1018.

792 M. Sen, B. Emayavaramban, N. Barsu, J. R. Premkumar and B. Sundararaju, ACS Catal., 2016, **6**, 2792-2796.

793 L. Kong, B. Liu, X. Zhou, F. Wang and X. Li, Chem. Commun., 2017, **53**, 10326-10329.

794 V. G. Landge, M. K. Sahoo, S. P. Midya, G. Jaiswal and E. Balaraman, Dalton Trans., 2015, **44**, 15382-15386.

795 L. Kong, X. Zhou, Y. Xu and X. Li, Org. Lett., 2017, **19**, 3644-3647.

796 B. Liu, B. Li and B. Wang, Chem. Commun., 2015, **51**, 16334-16337.

797 H. Wang, G. Tang and X. Li, Angew. Chem., Int. Ed., 2015, **54**, 13049-13052.

798 N. Barsu, M. A. Rahman, M. Sen and B. Sundararaju, Chem. - Eur. J., 2016, **22**, 9135-9138.

799 X. Huang, Y. Wang, J. Lan and J. You, Angew. Chem., Int. Ed., 2015, **54**, 9404-9408.

800 T. Jeong, N. K. Mishra, P. Dey, H. Oh, S. Han, S. H. Lee, H. S. Kim, J. Park and I. S. Kim, Chem. Commun., 2017, **53**, 11197-11200.

801 X. Zhang, R. Wu, W. Liu, D.-W. Qian, J. Yang, P. Jiang and Q.-Z. Zheng, Org. Biomol. Chem., 2016, **14**, 4789-4793.

802 S. Yu, G. Tang, Y. Li, X. Zhou, Y. Lan and X. Li, Angew. Chem., Int. Ed., 2016, **55**, 8696-8700.

803 C. Tang, M. Zou, J. Liu, X. Wen, X. Sun, Y. Zhang and N. Jiao, Chem. - Eur. J., 2016, **22**, 11165-11169.

804 W. Zhang, S. Ren, J. Zhang and Y. Liu, J. Org. Chem., 2015, **80**, 5973-5978.

805 G. S. Kumar, J. W. Boyle, C. Tejo and P. W. H. Chan, Chem. - Asian J., 2016, **11**, 385-389.

806 J. De Houwer, K. Abbaspour Tehrani and B. U. W. Maes, Angew. Chem., Int. Ed., 2012, **51**, 2745-2748.

807 H. Sterckx, J. De Houwer, C. Mensch, I. Caretti, K. A. Tehrani, W. A. Herrebout, S. Van Doorslaer and B. U. W. Maes, Chem. Sci., 2016, **7**, 346-357.

808 G. Wang, L. Liu, H. Wang, Y.-S. Ding, J. Zhou, S. Mao and P. Li, J. Am. Chem. Soc., 2017, **139**, 91-94.

809 E. A. Mitchell, A. Peschiulli, N. Lefevre, L. Meerpoel and B. U. W. Maes, Chem. - Eur. J., 2012, **18**, 10092-10142.

810 W. Li, X. Huang and J. You, Org. Lett., 2016, **18**, 666-668.

811 L. Kong, S. Yu, G. Tang, H. Wang, X. Zhou and X. Li, Org. Lett., 2016, **18**, 3802-3805.

812 K. Muralirajan, S. Prakash and C.-H. Cheng, Adv. Synth. Catal., 2017, **359**, 513-518.

813 Y. Unoh, T. Satoh, K. Hirano and M. Miura, ACS Catal., 2015, **5**, 6634-6639.

814 Z. Qi and X. Li, Angew. Chem., Int. Ed., 2013, **52**, 8995-9000.

815 C. Sollert, K. Devaraj, A. Orthaber, P. J. Gates and L. T. Pilarski, Chem. - Eur. J., 2015, **21**, 5380-5386.

816 X. Zhu, J.-H. Su, C. Du, Z.-L. Wang, C.-J. Ren, J.-L. Niu and M.-P. Song, Org. Lett., 2017, **19**, 596-599.

817 X. Zhou, Y. Pan and X. Li, Angew. Chem., Int. Ed., 2017, **56**, 8163-8167.

818 M. Gao, Y. Yang, H. Chen and B. Zhou, Adv. Synth. Catal., 2018, **360**, 100-105.

819 S.-S. Zhang, J. Xia, J.-Q. Wu, X.-G. Liu, C.-J. Zhou, E. Lin, Q. Li, S.-L. Huang and H. Wang, Org. Lett., 2017, **19**, 5868-5871.

820 P. Lu, C. Feng and T.-P. Loh, Org. Lett., 2015, **17**, 3210-3213.

821 Y. Xu, X. Zhou, G. Zheng and X. Li, Org. Lett., 2017, **19**, 5256-5259.

822 Z. Zhang, S. Han, M. Tang, L. Ackermann and J. Li, Org. Lett., 2017, **19**, 3315-3318.

823 S.-Y. Yan, Z.-Z. Zhang and B.-F. Shi, Chem. Commun., 2017, **53**, 10287-10290.

824 J. Xia, L. Kong, X. Zhou, G. Zheng and X. Li, Org. Lett., 2017, **19**, 5972-5975.

825 Z. Qi, L. Kong and X. Li, Org. Lett., 2016, **18**, 4392-4395.

826 M. Choi, J. Park, S. Sharma, H. Jo, S. Han, M. Jeon, N. K. Mishra, S. H. Han, J. S. Lee and I. S. Kim, J. Org. Chem., 2016, **81**, 4771-4778.

827 X. Jiang, J. Chen, W. Zhu, K. Cheng, Y. Liu, W.-K. Su and C. Yu, J. Org. Chem., 2017, **82**, 10665-10672.

828 S.-Y. Chen, Q. Li and H. Wang, J. Org. Chem., 2017, **82**, 11173-11181.

829 X. Zhou, Y. Luo, L. Kong, Y. Xu, G. Zheng, Y. Lan and X. Li, ACS Catal., 2017, **7**, 7296-7304.

830 L. Shi, X. Zhong, H. She, Z. Lei and F. Li, Chem. Commun., 2015, **51**, 7136-7139.

831 C. Wang, A. Wang and M. Rueping, Angew. Chem., Int. Ed., 2017, **56**, 9935-9938.

832 S.-Y. Chen, X.-L. Han, J.-Q. Wu, Q. Li, Y. Chen and H. Wang, Angew. Chem., Int. Ed., 2017, **56**, 9939-9943.

833 X. Zhou, Z. Fan, Z. Zhang, P. Lu and Y. Wang, Org. Lett., 2016, **18**, 4706-4709.

834 M. Moselage, N. Sauermann, S. C. Richter and L. Ackermann, Angew. Chem., Int. Ed., 2015, **54**, 6352-6355.

835 S.-H. Cai, L. Ye, D.-X. Wang, Y.-Q. Wang, L.-J. Lai, C. Zhu, C. Feng and T.-P. Loh, Chem. Commun., 2017, **53**, 8731-8734.

836 L. Kong, X. Zhou and X. Li, Org. Lett., 2016, **18**, 6320-6323.

837 N. Sauermann, M. J. González and L. Ackermann, Org. Lett., 2015, **17**, 5316-5319.

838 Z. Ruan, N. Sauermann, E. Manoni and L. Ackermann, Angew. Chem., Int. Ed., 2017, **56**, 3172-3176.

839 Z.-Z. Zhang, B. Liu, C.-Y. Wang and B.-F. Shi, Org. Lett., 2015, **17**, 4094-4097.

840 Y. Wu, Y. Yang, B. Zhou and Y. Li, J. Org. Chem., 2015, **80**, 1946-1951.

841 D. Kang and S. Hong, Org. Lett., 2015, **17**, 1938-1941.

842 N. K. Mishra, T. Jeong, S. Sharma, Y. Shin, S. Han, J. Park, J. S. Oh, J. H. Kwak, Y. H. Jung and I. S. Kim, Adv. Synth. Catal., 2015, **357**, 1293-1298.

843 G. Kumar and G. Sekar, RSC Adv., 2015, **5**, 28292-28298.

844 C. Li, W. Zhu, S. Shu, X. Wu and H. Liu, Eur. J. Org. Chem., 2015, 3743-3750.

845 Y. Zhao, U. K. Sharma, F. Schröder, N. Sharma, G. Song and E. V. Van der Eycken, RSC Adv., 2017, **7**, 32559-32563.

846 U. K. Sharma, H. P. L. Gemoets, F. Schröder, T. Noël and E. V. Van der Eycken, ACS Catal., 2017, **7**, 3818-3823.
<figure><img src="image_384.png" /></figure>

847 M. K. Manna, G. Bairy and R. Jana, *Org. Biomol. Chem.*, 2017, **15**, 5899-5903.

848 T. Jeong, S. Han, N. K. Mishra, S. Sharma, S.-Y. Lee, J. S. Oh, J. H. Kwak, Y. H. Jung and I. S. Kim, *J. Org. Chem.*, 2015, **80**, 7243-7250.

849 J. Xu, N. Sharma, U. K. Sharma, Z. Li, G. Song and E. V. Van der Eycken, *Adv. Synth. Catal.*, 2015, **357**, 2615-2621.

850 A. S. Tsai, M. E. Tauchert, R. G. Bergman and J. A. Ellman, *J. Am. Chem. Soc.*, 2011, **133**, 1248-1250.

851 J. Shi, B. Zhou, Y. Yang and Y. Li, *Org. Biomol. Chem.*, 2012, **10**, 8953-8955.

852 B. Sun, T. Yoshino, S. Matsunaga and M. Kanai, *Chem. Commun.*, 2015, **51**, 4659-4661.

853 M. Jeon, N. K. Mishra, U. De, S. Sharma, Y. Oh, M. Choi, H. Jo, R. Sachan, H. S. Kim and I. S. Kim, *J. Org. Chem.*, 2016, **81**, 9878-9885.

854 N. K. Mishra, M. Jeon, Y. Oh, H. Jo, J. Park, S. Han, S. Sharma, S. H. Han, Y. H. Jung and I. S. Kim, *Org. Chem. Front.*, 2017, **4**, 241-249.

855 H. Li, J. Jie, S. Wu, X. Yang and H. Xu, *Org. Chem. Front.*, 2017, **4**, 250-254.

856 L. Zhu, X. Cao, R. Qiu, T. Iwasaki, V. P. Reddy, X. Xu, S.-F. Yin and N. Kambe, *RSC Adv.*, 2015, **5**, 39358-39365.

857 R. Qiu, V. P. Reddy, T. Iwasaki and N. Kambe, *J. Org. Chem.*, 2015, **80**, 367-374.

858 W. Xie, B. Li and B. Wang, *J. Org. Chem.*, 2016, **81**, 396-403.

859 T. Gensch, F. J. R. Klauck and F. Glorius, *Angew. Chem., Int. Ed.*, 2016, **55**, 11287-11291.

860 P. Gandeepan, J. Koeller and L. Ackermann, *ACS Catal.*, 2017, **7**, 1030-1034.

861 C. K. Jana, S. Grimme and A. Studer, *Chem. - Eur. J.*, 2009, **15**, 9078-9084.

862 V. Smout, A. Peschiulli, S. Verbeeck, E. A. Mitchell, W. Herrebout, P. Bultinck, C. M. L. Vande Velde, D. Berthelot, L. Meerpoel and B. U. W. Maes, *J. Org. Chem.*, 2013, **78**, 9803-9814.

863 S. Pan, K. Endo and T. Shibata, *Org. Lett.*, 2011, **13**, 4692-4695.

864 S. J. Pastine, D. V. Gribkov and D. Sames, *J. Am. Chem. Soc.*, 2006, **128**, 14220-14221.

865 J.-H. Chu, P.-S. Lin and M.-J. Wu, *Organometallics*, 2010, **29**, 4058-4065.

866 M. Tobisu, J. Zhao, H. Kinuta, T. Furukawa, T. Igarashi and N. Chatani, *Adv. Synth. Catal.*, 2016, **358**, 2417-2421.

867 H. Kinuta, M. Tobisu and N. Chatani, *J. Am. Chem. Soc.*, 2015, **137**, 1593-1600.

868 J. Li and Z.-X. Wang, *Org. Lett.*, 2017, **19**, 3723-3726.

869 C. Huang, N. Chernyak, A. S. Dudnik and V. Gevorgyan, *Adv. Synth. Catal.*, 2011, **353**, 1285-1305.

870 A. García-Rubia, M. Á. Fernández-Ibáñez, R. Gómez Arrayás and J. C. Carretero, *Chem. - Eur. J.*, 2011, **17**, 3567-3570.

871 M. Sun, Z. Wang, J. Wang, P. Guo, X. Chen and Y.-M. Li, *Org. Biomol. Chem.*, 2016, **14**, 10585-10588.

872 H. Richter, S. Beckendorf and O. G. Mancheño, *Adv. Synth. Catal.*, 2011, **353**, 295-302.

873 N. K. Mishra, M. Choi, H. Jo, Y. Oh, S. Sharma, S. H. Han, T. Jeong, S. Han, S.-Y. Lee and I. S. Kim, *Chem. Commun.*, 2015, **51**, 17229-17232.

874 H. Jiang, S. Gao, J. Xu, X. Wu, A. Lin and H. Yao, *Adv. Synth. Catal.*, 2016, **358**, 188-194.

875 G.-D. Tang, C.-L. Pan and X. Li, *Org. Chem. Front.*, 2016, **3**, 87-90.

876 Z. Ruan, S. Lackner and L. Ackermann, *Angew. Chem., Int. Ed.*, 2016, **55**, 3153-3157.

877 Z. Ruan, S. Lackner and L. Ackermann, *ACS Catal.*, 2016, **6**, 4690-4693.

878 T. Müller and L. Ackermann, *Chem. - Eur. J.*, 2016, **22**, 14151-14154.

879 S. Yang, B. Feng and Y. Yang, *J. Org. Chem.*, 2017, **82**, 12430-12438.

880 L. Wang, Z. Yang, M. Yang, R. Zhang, C. Kuai and X. Cui, *Org. Biomol. Chem.*, 2017, **15**, 8302-8307.

881 G. G. Pawar, A. Brahmanandan and M. Kapur, *Org. Lett.*, 2016, **18**, 448-451.

882 D. Nageswar Rao, S. Rasheed, G. Raina, Q. N. Ahmed, C. K. Jaladanki, P. V. Bharatam and P. Das, *J. Org. Chem.*, 2017, **82**, 7234-7244.

883 M. Spettel, R. Pollice and M. Schnürch, *Org. Lett.*, 2017, **19**, 4287-4290.

884 K. Yu, Y. Liang, B. Li and B. Wang, *Adv. Synth. Catal.*, 2016, **358**, 661-666.

885 S. Bai, X. Chen, X. Hu, Y. Deng, H. Jiang and W. Zeng, *Org. Biomol. Chem.*, 2017, **15**, 3638-3647.

886 P. V. Reddy, M. Annapurna, P. Srinivas, P. R. Likhar and M. Lakshmi Kantam, *New J. Chem.*, 2015, **39**, 3399-3404.

887 X. Hu, X. Chen, Y. Zhu, Y. Deng, H. Zeng, H. Jiang and W. Zeng, *Org. Lett.*, 2017, **19**, 3474-3477.

888 Z.-J. Wu, K. L. Huang and Z.-Z. Huang, *Org. Biomol. Chem.*, 2017, **15**, 4978-4983.

889 J. Xia, X. Yang, Y. Li and X. Li, *Org. Lett.*, 2017, **19**, 3243-3246.

890 M. Ravi, S. Allu and K. C. K. Swamy, *J. Org. Chem.*, 2017, **82**, 2355-2363.

891 L. Wang, Y. Yu, M. Yang, C. Kuai, D. Cai, J. Yu and X. Cui, *Adv. Synth. Catal.*, 2017, **359**, 3818-3825.

892 J.-H. Chu, S.-T. Chen, M.-F. Chiang and M.-J. Wu, *Organometallics*, 2015, **34**, 953-966.

893 D. C. McAteer, E. Javed, L. Huo and S. Huo, *Org. Lett.*, 2017, **19**, 1606-1609.

894 L. Wang, Z. Yang, M. Yang, M. Tian, C. Kuai and X. Cui, *Chem. - Asian J.*, 2017, **12**, 2634-2643.

895 L. Wang, L. Pan, Y. Huang, Q. Chen and M. He, *Eur. J. Org. Chem.*, 2016, 3113-3118.

896 K. Raghuvanshi, K. Rauch and L. Ackermann, *Chem. - Eur. J.*, 2015, **21**, 1790-1794.

897 Y. Xu, P. Liu, S.-L. Li and P. Sun, *J. Org. Chem.*, 2015, **80**, 1269-1274.

898 C. Gao, H. Li, M. Liu, J. Ding, X. Huang, H. Wu, W. Gao and G. Wu, *RSC Adv.*, 2017, **7**, 46636-46643.
899 S.-J. Lou, Q. Chen, Y.-F. Wang, D.-Q. Xu, X.-H. Du, J.-Q. He, Y.-J. Mao and Z.-Y. Xu, ACS Catal., 2015, 5, 2846-2849.

900 D. Sarkar and V. Gevorgyan, Chem. - Eur. J., 2016, 22, 11201-11204.

901 Y. Zhang, H. Jiang, D. Chen and Y. Zhang, Org. Biomol. Chem., 2016, 14, 4585-4589.

902 Y. Wang and V. Gevorgyan, Angew. Chem., Int. Ed., 2017, 56, 3191-3195.

903 D. Sarkar, A. V. Gulevich, F. S. Melkonyan and V. Gevorgyan, ACS Catal., 2015, 5, 6792-6801.

904 J. Guilbaud, M. Labonde, H. Cattey, S. Contal, C. Montalbetti, N. Pirio, J. Roger and J.-C. Hierso, Adv. Synth. Catal., 2017, 359, 3792-3804.

905 H. Andersson, R. Olsson and F. Almqvist, Org. Biomol. Chem., 2011, 9, 337-346.

906 G. Yan, A. J. Borah and M. Yang, Adv. Synth. Catal., 2014, 356, 2375-2394.

907 Y. Wang and L. Zhang, Synthesis, 2015, 289-305.

908 H. Sterckx, C. Sambiagio, V. Médran-Navarrete and B. U. W. Maes, Adv. Synth. Catal., 2017, 359, 3226-3236.

909 H. Hwang, J. Kim, J. Jeong and S. Chang, J. Am. Chem. Soc., 2014, 136, 10770-10776.

910 S. Yu, B. Wan and X. Li, Org. Lett., 2015, 17, 58-61.

911 X. Chen, X. Cui and Y. Wu, Org. Lett., 2016, 18, 2411-2414.

912 X. Chen, X. Cui and Y. Wu, Org. Lett., 2016, 18, 3722-3725.

913 D. E. Stephens, J. Lakey-Beitia, A. C. Atesin, T. A. Ateşin, G. Chavez, H. D. Arman and O. V. Larionov, ACS Catal., 2015, 5, 167-175.

914 D. E. Stephens, J. Lakey-Beitia, G. Chavez, C. Ilie, H. D. Arman and O. V. Larionov, Chem. Commun., 2015, 51, 9507-9510.

915 J. Jeong, P. Patel, H. Hwang and S. Chang, Org. Lett., 2014, 16, 4598-4601.

916 R. Sharma, I. Kumar, R. Kumar and U. Sharma, Adv. Synth. Catal., 2017, 359, 3022-3028.

917 X. Zhang, Z. Qi and X. Li, Angew. Chem., Int. Ed., 2014, 53, 10794-10798.

918 U. Sharma, Y. Park and S. Chang, J. Org. Chem., 2014, 79, 9899-9906.

919 N. Barsu, M. Sen, J. R. Premkumar and B. Sundararaju, Chem. Commun., 2016, 52, 1338-1341.

920 D. Kalsi, R. A. Laskar, N. Barsu, J. R. Premkumar and B. Sundararaju, Org. Lett., 2016, 18, 4198-4201.

921 B. Wang, C. Li and H. Liu, Adv. Synth. Catal., 2017, 359, 3029-3034.

922 T. Shibata and Y. Matsuo, Adv. Synth. Catal., 2014, 356, 1516-1520.

923 R. Sharma, R. Kumar, I. Kumar and U. Sharma, Eur. J. Org. Chem., 2015, 7519-7528.

924 T. Asaumi, N. Chatani, T. Matsuo, F. Kakiuchi and S. Murai, J. Org. Chem., 2003, 68, 7538-7540.

925 A. Armstrong, L. H. Jones, J. D. Knight and R. D. Kelsey, Org. Lett., 2005, 7, 713-716.

926 N. Gulia and O. Daugulis, Angew. Chem., Int. Ed., 2017, 56, 3630-3634.

927 M. Moselage, J. Li, F. Kramm and L. Ackermann, Angew. Chem., Int. Ed., 2017, 56, 5341-5344.

928 C. Yuan, G. Tu and Y. Zhao, Org. Lett., 2017, 19, 356-359.

929 C. J. Teskey, S. M. A. Sohel, D. L. Bunting, S. G. Modha and M. F. Greaney, Angew. Chem., Int. Ed., 2017, 56, 5263-5266.

930 N. Barsu, B. Emayavaramban and B. Sundararaju, Eur. J. Org. Chem., 2017, 4370-4374.

931 J. A. Boerth, J. R. Hummel and J. A. Ellman, Angew. Chem., Int. Ed., 2016, 55, 12650-12654.

932 A. Wangweerawong, J. R. Hummel, R. G. Bergman and J. A. Ellman, J. Org. Chem., 2016, 81, 1547-1557.

933 Y. Takahama, Y. Shibata and K. Tanaka, Org. Lett., 2016, 18, 2934-2937.

934 S. Shome and S. P. Singh, Eur. J. Org. Chem., 2015, 6025-6032.

935 M. Sen, P. Dahiya, J. R. Premkumar and B. Sundararaju, Org. Lett., 2017, 19, 3699-3702.

936 J. Li and L. Ackermann, Angew. Chem., Int. Ed., 2015, 54, 8551-8554.

937 J. R. Hummel and J. A. Ellman, Org. Lett., 2015, 17, 2400-2403.

938 S. Shu, Z. Fan, Q. Yao and A. Zhang, J. Org. Chem., 2016, 81, 5263-5269.

939 C. Testa, J. Roger, S. Scheib, P. Fleurat-Lessard and J.-C. Hierso, Adv. Synth. Catal., 2015, 357, 2913-2923.

940 X.-M. Fan, Y. Guo, Y.-D. Li, K.-K. Yu, H.-W. Liu, D.-H. Liao and Y.-F. Ji, Asian J. Org. Chem., 2016, 5, 499-505.

941 J. Shi, J. Zhou, Y. Yan, J. Jia, X. Liu, H. Song, H. E. Xu and W. Yi, Chem. Commun., 2015, 51, 668-671.

942 N. Umeda, K. Hirano, T. Satoh, N. Shibata, H. Sato and M. Miura, J. Org. Chem., 2011, 76, 13-24.

943 D. L. Davies, C. E. Ellul, S. A. Macgregor, C. L. McMullin and K. Singh, J. Am. Chem. Soc., 2015, 137, 9659-9669.

944 J. Jie, H. Li, S. Wu, Q. Chai, H. Wang and X. Yang, RSC Adv., 2017, 7, 20548-20552.

945 A. G. Algarra, D. L. Davies, Q. Khamker, S. A. Macgregor, C. L. McMullin, K. Singh and B. Villa-Marcos, Chem. - Eur. J., 2015, 21, 3087-3096.

946 W. Yang, S. Ye, D. Fanning, T. Coon, Y. Schmidt, P. Krenitsky, D. Stamos and J.-Q. Yu, Angew. Chem., Int. Ed., 2015, 54, 2501-2504.

947 W. Yang, S. Ye, Y. Schmidt, D. Stamos and J.-Q. Yu, Chem. - Eur. J., 2016, 22, 7059-7062.

948 F. Zhao, Y. Liu, S. Yang, K. Xie and Y. Jiang, Org. Chem. Front., 2017, 4, 1112-1115.

949 S. Zhao, F. Wu, Y. Ma, W. Chen, M. Liu and H. Wu, Org. Biomol. Chem., 2016, 14, 2550-2555.

950 F. Zhao, Z. Chen, Y. Liu, K. Xie and Y. Jiang, Eur. J. Org. Chem., 2016, 5971-5979.

951 A. Irastorza, J. M. Aizpurua and A. Correa, Org. Lett., 2016, 18, 1080-1083.

952 A. Goitia, E. Gomez-Bengoa and A. Correa, Org. Lett., 2017, 19, 962-965.

953 T. L. Mindt, H. Struthers, L. Brans, T. Anguelov, C. Schweinsberg, V. Maes, D. Tourwé and R. Schibli, J. Am. Chem. Soc., 2006, 128, 15096-15097.

954 N. Belskaya, J. Subbotina and S. Lesogorova, in Chemistry of 1,2,3-triazoles, ed. W. Dehaen and V. A. Bakulev,
Springer International Publishing, Cham, 2015, pp. 51–116, DOI: 10.1007/7081_2014_125.

955 C. Premi, S. S. Patel and N. Jain, *Eur. J. Org. Chem.*, 2016, 3788–3795.

956 X. Yu, Q. Ma, S. Lv, J. Li, C. Zhang, L. Hai, Q. Wang and Y. Wu, *Org. Chem. Front.*, 2017, **4**, 2184–2190.

957 X. Wang, C. Zhang, J. Li, C. Jiang, F. Su, Z. Zhan, L. Hai, Z. Chen and Y. Wu, *RSC Adv.*, 2016, **6**, 68929–68933.

958 B. Zhu, X. Cui, C. Pi, D. Chen and Y. Wu, *Adv. Synth. Catal.*, 2016, **358**, 326–332.

959 V. Gayakhe, Y. S. Sanghvi, I. J. S. Fairlamb and A. R. Kapdi, *Chem. Commun.*, 2015, **51**, 11944–11960.

960 L. Liang, M.-S. Xie, H.-X. Wang, H.-Y. Niu, G.-R. Qu and H.-M. Guo, *J. Org. Chem.*, 2017, **82**, 5966–5973.

961 Y. Bunno, N. Murakami, Y. Suzuki, M. Kanai, T. Yoshino and S. Matsunaga, *Org. Lett.*, 2016, **18**, 2216–2219.

962 A. B. Pawar and D. M. Lade, *Org. Biomol. Chem.*, 2016, **14**, 3275–3283.

963 M. Yu, Z. Wang, M. Tian, C. Lu, S. Li and H. Du, *J. Org. Chem.*, 2016, **81**, 3435–3442.

964 S.-S. Li, W.-H. Li, G.-T. Zhang, Y.-Q. Xia, C.-F. Liu, F. Su, X.-M. Zhang and L. Dong, *Org. Biomol. Chem.*, 2016, **14**, 7859–7863.

965 B. Liu, R. Li, W. Zhan, X. Wang, Z. Ge and R. Li, *RSC Adv.*, 2016, **6**, 48205–48211.

966 W.-H. Li, L. Wu, S.-S. Li, C.-F. Liu, G.-T. Zhang and L. Dong, *Chem. – Eur. J.*, 2016, **22**, 17926–17929.

967 R. Morioka, T. Satoh and M. Miura, *Chem. Lett.*, 2016, **45**, 682–684.

968 B. Liu, X. Wang, Z. Ge and R. Li, *Org. Biomol. Chem.*, 2016, **14**, 2944–2949.

969 A. Mishra, T. K. Vats and I. Deb, *J. Org. Chem.*, 2016, **81**, 6525–6534.

970 M. Jeon, J. Park, P. Dey, Y. Oh, H. Oh, S. Han, S. H. Um, H. S. Kim, N. K. Mishra and I. S. Kim, *Adv. Synth. Catal.*, 2017, **359**, 3471–3478.

971 A. Mishra, T. K. Vats, M. P. Nair, A. Das and I. Deb, *J. Org. Chem.*, 2017, **82**, 12406–12415.

972 C.-F. Liu, G.-T. Zhang, J.-S. Sun and L. Dong, *Org. Biomol. Chem.*, 2017, **15**, 2902–2905.

973 S.-S. Li, C.-F. Liu, Y.-Q. Xia, W.-H. Li, G.-T. Zhang, X.-M. Zhang and L. Dong, *Org. Biomol. Chem.*, 2016, **14**, 5214–5218.

974 S.-S. Li, C.-Q. Wang, H. Lin, X.-M. Zhang and L. Dong, *Org. Lett.*, 2015, **17**, 3018–3021.

975 S.-S. Li, C.-F. Liu, G.-T. Zhang, Y.-Q. Xia, W.-H. Li and L. Dong, *Chem. – Asian J.*, 2017, **12**, 415–418.

976 S.-S. Li, H. Lin, C.-F. Liu, Y.-Q. Xia, X.-M. Zhang and L. Dong, *Adv. Synth. Catal.*, 2016, **358**, 1595–1601.

977 F. Yang, J. Yu, Y. Liu and J. Zhu, *Org. Lett.*, 2017, **19**, 2885–2888.

978 Y. Nishii, A.-K. Bachon, S. Moon, C. Bolm and M. Miura, *Chem. Lett.*, 2017, **46**, 1347–1349.

979 X. Yu, K. Chen, F. Yang, S. Zha and J. Zhu, *Org. Lett.*, 2016, **18**, 5412–5415.

980 Y. Xiaolong, C. Kehao, W. Qi, G. Shan, Z. Shanke and Z. Jin, *Angew. Chem., Int. Ed.*, 2017, **56**, 5222–5226.

981 T. Noguchi, Y. Nishii and M. Miura, *Chem. Lett.*, 2017, **46**, 1512–1514.

982 M. Suresh Babu and K. M. Lokanatha Rai, *Tetrahedron Lett.*, 2004, **45**, 7969–7970.

983 T. G. Gant and A. I. Meyers, *Tetrahedron*, 1994, **50**, 2297–2360.

984 T. M. M. Maiden, S. Swanson, P. A. Procopiou and J. P. A. Harrity, *Chem. – Eur. J.*, 2015, **21**, 14342–14346.

985 R. Mei and L. Ackermann, *Adv. Synth. Catal.*, 2016, **358**, 2443–2448.

986 M. Tobisu, K. Yasui, Y. Aihara and N. Chatani, *Angew. Chem., Int. Ed.*, 2017, **56**, 1877–1880.

987 Q. Zhou, J.-F. Zhang, H. Cao, R. Zhong and X.-F. Hou, *J. Org. Chem.*, 2016, **81**, 12169–12180.

988 T. M. M. Maiden, S. Swanson, P. A. Procopiou and J. P. A. Harrity, *J. Org. Chem.*, 2016, **81**, 10641–10650.

989 K. Seth, M. Nautiyal, P. Purohit, N. Parikh and A. K. Chakraborti, *Chem. Commun.*, 2015, **51**, 191–194.

990 K. Kon, H. Suzuki, K. Takada, Y. Kohari, T. Namikoshi, S. Watanabe and M. Murata, *ChemCatChem*, 2016, **8**, 2202–2205.

991 F. Babudri, G. Bartoli, F. Ciminale, S. Florio and G. Ingrosso, *Tetrahedron Lett.*, 1984, **25**, 2047–2050.

992 J. Yan, Y. Zhou, N. Zhang, H. Chen, X. He, S. Xiao and K. Zheng, *Res. Chem. Intermed.*, 2017, **43**, 5395–5402.

993 S. S. Ramos, L. V. Reis, R. E. F. Boto, P. F. Santos and P. Almeida, *Tetrahedron Lett.*, 2013, **54**, 5441–5444.

994 J. Rashkova, P. Tzvetkova, S. Simova, L. Viteva and T. Gospodova, *Dyes Pigm.*, 2009, **82**, 360–364.

995 L. Viteva, T. Gospodova, J. Rashkova, I. Abrahams, I. Timtcheva, S. Simova, M. R. Mazieres and J. G. Wolf, *Eur. J. Org. Chem.*, 2007, 3102–3114.

996 B. V. Pipaliya and A. K. Chakraborti, *ChemCatChem*, 2017, **9**, 4191–4198.

997 B. V. Pipaliya and A. K. Chakraborti, *J. Org. Chem.*, 2017, **82**, 3767–3780.

998 P. Ranjan Mohanta, A. Banerjee, S. Kumar Santra, A. Behera and B. K. Patel, *Adv. Synth. Catal.*, 2016, **358**, 2047–2052.

999 B. Vinayak, A. Ashok and M. Chandrasekharam, *Eur. J. Org. Chem.*, 2017, 7127–7132.

1000 M. Yu, Y. Xie, C. Xie and Y. Zhang, *Org. Lett.*, 2012, **14**, 2164–2167.

1001 J. Yao, M. Yu and Y. Zhang, *Adv. Synth. Catal.*, 2012, **354**, 3205–3210.

1002 X.-S. Zhang, Q.-L. Zhu, Y.-F. Zhang, Y.-B. Li and Z.-J. Shi, *Chem. – Eur. J.*, 2013, **19**, 11898–11903.

1003 X.-S. Zhang, Y.-F. Zhang, K. Chen and Z.-J. Shi, *Org. Chem. Front.*, 2014, **1**, 1096–1100.

1004 P. Villuendas and E. P. Urriolabeitia, *Org. Lett.*, 2015, **17**, 3178–3181.

1005 B. Wang, C. Lin, Y. Liu, Z. Fan, Z. Liu and Y. Zhang, *Org. Chem. Front.*, 2015, **2**, 973–977.

1006 M. Tobisu, Y. Masuya, K. Baba and N. Chatani, *Chem. Sci.*, 2016, **7**, 2587–2591.

1007 R. Che, Z. Wu, Z. Li, H. Xiang and X. Zhou, *Chem. – Eur. J.*, 2014, **20**, 7258–7261.

<figure><img src="image_385.png" /></figure>
Review Article

1008 X.-S. Zhang, Y.-F. Zhang, Z.-W. Li, F.-X. Luo and Z.-J. Shi, *Angew. Chem., Int. Ed.*, 2015, **54**, 5478-5482.

1009 H. L. Li, Y. Kuninobu and M. Kanai, *Angew. Chem., Int. Ed.*, 2017, **56**, 1495-1499.

1010 H.-L. Li, M. Kanai and Y. Kuninobu, *Org. Lett.*, 2017, **19**, 5944-5947.

1011 Y. Unoh, K. Hirano, T. Satoh and M. Miura, *Org. Lett.*, 2015, **17**, 704-707.

1012 L. Liu, G. Wang, J. Jiao and P. Li, *Org. Lett.*, 2017, **19**, 6132-6135.

1013 D. Wang, X. Yu, W. Yao, W. Hu, C. Ge and X. Shi, *Chem. - Eur. J.*, 2016, **22**, 5543-5546.

1014 L. Wang, Y.-B. Xie, N.-Y. Huang, N.-N. Zhang, D.-J. Li, Y.-L. Hu, M.-G. Liu and D.-S. Li, *Adv. Synth. Catal.*, 2017, **359**, 779-785.

1015 R. Samanta and A. P. Antonchick, *Angew. Chem., Int. Ed.*, 2011, **50**, 5217-5220.

1016 B. Wang, Y. Liu, C. Lin, Y. Xu, Z. Liu and Y. Zhang, *Org. Lett.*, 2014, **16**, 4574-4577.

1017 B. Wang, C. Shen, J. Yao, H. Yin and Y. Zhang, *Org. Lett.*, 2014, **16**, 46-49.

1018 K. Nobushige, K. Hirano, T. Satoh and M. Miura, *Org. Lett.*, 2014, **16**, 1188-1191.

1019 K. Padala and M. Jeganmohan, *Chem. Commun.*, 2014, **50**, 14573-14576.

1020 T. Wesch, F. R. Leroux and F. Colobert, *Adv. Synth. Catal.*, 2013, **355**, 2139-2144.

1021 G. Solladié, J. Hutt and A. Girardin, *Synthesis*, 1987, 173.

1022 Q. Dherbassy, G. Schwertz, M. Chesse, C. K. Hazra, J. Wencel-Delord and F. Colobert, *Chem. - Eur. J.*, 2016, **22**, 1735-1743.

1023 C. K. Hazra, Q. Dherbassy, J. Wencel-Delord and F. Colobert, *Angew. Chem., Int. Ed.*, 2014, **53**, 13871-13875.

1024 Q. Dherbassy, J. Wencel-Delord and F. Colobert, *Tetrahedron*, 2016, **72**, 5238-5245.

1025 Q. Dherbassy, J. P. Djukic, J. Wencel-Delord and F. Colobert, *Angew. Chem., Int. Ed.*, 2018, **57**, 4668-4672.

1026 T. Wesch, A. Berthelot-Bréhier, F. R. Leroux and F. Colobert, *Org. Lett.*, 2013, **15**, 2490-2493.

1027 Q. Huang, S. Fu, S. Ke, H. Xiao, X. Zhang and S. Lin, *Eur. J. Org. Chem.*, 2015, 6602-6605.

1028 B. Li, D. D. Guo, S. H. Guo, G. F. Pan, Y. R. Gao and Y. Q. Wang, *Chem. - Asian J.*, 2017, **12**, 130-144.

1029 K. Nobushige, K. Hirano, T. Satoh and M. Miura, *Tetrahedron*, 2015, **71**, 6506-6512.

1030 D. Chen, G. Xing and H. Zhou, *Org. Chem. Front.*, 2015, **2**, 947-950.

1031 H.-X. Dai, A. F. Stepan, M. S. Plummer, Y.-H. Zhang and J.-Q. Yu, *J. Am. Chem. Soc.*, 2011, **133**, 7222-7228.

1032 R. Vanjari, T. Guntreddi and K. N. Singh, *Chem. - Asian J.*, 2016, **11**, 696-699.

1033 W. J. Kerr, M. Reid and T. Tuttle, *ACS Catal.*, 2015, **5**, 402-410.

1034 A. Burhop, R. Weck, J. Atzrodt and V. Derdau, *Eur. J. Org. Chem.*, 2017, 1418-1424.

1035 G. Cheng, P. Wang and J.-Q. Yu, *Angew. Chem., Int. Ed.*, 2017, **56**, 8183-8186.

1036 W. Dong, L. Wang, K. Parthasarathy, F. Pan and C. Bolm, *Angew. Chem., Int. Ed.*, 2013, **52**, 11573-11576.

1037 Y. Cheng and C. Bolm, *Angew. Chem., Int. Ed.*, 2015, **54**, 12349-12352.

1038 W. H. Jeon, J.-Y. Son, J. E. Kim and P. H. Lee, *Org. Lett.*, 2016, **18**, 3498-3501.

1039 G. H. Ko, J.-Y. Son, H. Kim, C. Maeng, Y. Baek, B. Seo, K. Um and P. H. Lee, *Adv. Synth. Catal.*, 2017, **359**, 3362-3370.

1040 J. Huang, Y. Huang, T. Wang, Q. Huang, Z. Wang and Z. Chen, *Org. Lett.*, 2017, **19**, 1128-1131.

1041 Y. Li and L. Dong, *Org. Biomol. Chem.*, 2017, **15**, 9983-9986.

1042 J. Wen, H. Cheng, G. Raabe and C. Bolm, *Org. Lett.*, 2017, **19**, 6020-6023.

1043 J. Wen, D. P. Tiwari and C. Bolm, *Org. Lett.*, 2017, **19**, 1706-1709.

1044 G. Zheng, M. Tian, Y. Xu, X. Chen and X. Li, *Org. Chem. Front.*, 2018, **5**, 998-1002.

1045 Y. Cheng, W. Dong, H. Wang and C. Bolm, *Chem. - Eur. J.*, 2016, **22**, 10821-10824.

1046 Y. Cheng, W. Dong, K. Parthasarathy and C. Bolm, *Org. Lett.*, 2017, **19**, 726-729.

1047 M. R. Yadav, R. K. Rit and A. K. Sahoo, *Chem. - Eur. J.*, 2012, **18**, 5541-5545.

1048 R. K. Rit, M. R. Yadav and A. K. Sahoo, *Org. Lett.*, 2014, **16**, 968-971.

1049 M. R. Yadav, R. K. Rit and A. K. Sahoo, *Org. Lett.*, 2013, **15**, 1638-1641.

1050 M. R. Yadav, R. K. Rit, M. Shankar and A. K. Sahoo, *J. Org. Chem.*, 2014, **79**, 6123-6134.

1051 M. R. Yadav, M. Shankar, E. Ramesh, K. Ghosh and A. K. Sahoo, *Org. Lett.*, 2015, **17**, 1886-1889.

1052 K. Ghosh, R. K. Rit, E. Ramesh and A. K. Sahoo, *Angew. Chem., Int. Ed.*, 2016, **55**, 7821-7825.

1053 M. Shankar, T. Guntreddi, E. Ramesh and A. K. Sahoo, *Org. Lett.*, 2017, **19**, 5665-5668.

1054 M. Shankar, K. Ghosh, K. Mukherjee, R. K. Rit and A. K. Sahoo, *Org. Lett.*, 2016, **18**, 6416-6419.

1055 K. Raghuvanshi, D. Zell and L. Ackermann, *Org. Lett.*, 2017, **19**, 1278-1281.

1056 Y. Yokoyama, Y. Unoh, R. A. Bohmann, T. Satoh, K. Hirano, C. Bolm and M. Miura, *Chem. Lett.*, 2015, **44**, 1104-1106.

1057 J. E. Spangler, Y. Kobayashi, P. Verma, D.-H. Wang and J.-Q. Yu, *J. Am. Chem. Soc.*, 2015, **137**, 11876-11879.

1058 P. Jain, P. Verma, G. Xia and J.-Q. Yu, *Nat. Chem.*, 2016, **9**, 140-144.

1059 C. Zhong-Jian, L. Chen-Xu, G. Qing and Y. Shu-Li, *Angew. Chem., Int. Ed.*, 2018, **57**, 1296-1299.

1060 A. T. Tran and J.-Q. Yu, *Angew. Chem., Int. Ed.*, 2017, **56**, 10530-10534.

1061 Y. Zhao, F. Han, L. Yang and C. Xia, *Org. Lett.*, 2015, **17**, 1477-1480.

1062 Y.-N. Ma, S.-X. Li and S.-D. Yang, *Acc. Chem. Res.*, 2017, **50**, 1480-1492.

<figure><img src="image_386.png" /></figure>
<figure><img src="image_387.png" /></figure>

1063 (a) Y.-N. Ma, H.-Y. Zhang and S.-D. Yang, *Org. Lett.*, 2015, **17**, 2034–2037; (b) Z. S. Han, L. Zhang, Y. Xu, J. D. Sieber, M. A. Marsini, Z. Li, J. T. Reeves, K. R. Fandrick, N. D. Patel, J.-N. Desrosiers, B. Qu, A. Chen, D. M. Rudzinski, L. P. Samankumara, S. Ma, N. Grinberg, F. Roschangar, N. K. Yee, G. Wang, J. J. Song and C. H. Senanayake, *Angew. Chem., Int. Ed.*, 2015, **54**, 5474–5477; (c) S.-B. Yan, S. Zhang and W.-L. Duan, *Org. Lett.*, 2015, **17**, 2458–2461.

1064 S.-X. Li, Y.-N. Ma and S.-D. Yang, *Org. Lett.*, 2017, **19**, 1842–1845.

1065 C.-S. Wang, P. H. Dixneuf and J.-F. Soulé, *ChemCatChem*, 2017, **9**, 3117–3120.

1066 Y. Unoh, T. Satoh, K. Hirano and M. Miura, *ACS Catal.*, 2015, **5**, 6634–6639.

1067 Z. Liu, J.-Q. Wu and S.-D. Yang, *Org. Lett.*, 2017, **19**, 5434–5437.

1068 Y. Yang, X. Qiu, Y. Zhao, Y. Mu and Z. Shi, *J. Am. Chem. Soc.*, 2016, **138**, 495–498.

1069 R. J. Phipps, N. P. Grimster and M. J. Gaunt, *J. Am. Chem. Soc.*, 2008, **130**, 8172–8174.

1070 Y. Yang, R. Li, Y. Zhao, D. Zhao and Z. Shi, *J. Am. Chem. Soc.*, 2016, **138**, 8734–8737.

1071 Y. Yokoyama, Y. Unoh, K. Hirano, T. Satoh and M. Miura, *J. Org. Chem.*, 2014, **79**, 7649–7655.

1072 Y. Unoh, Y. Yokoyama, T. Satoh, K. Hirano and M. Miura, *Org. Lett.*, 2016, **18**, 5436–5439.

1073 W. H. Jeon, J.-Y. Son, S.-E. Kim and P. H. Lee, *Adv. Synth. Catal.*, 2015, **357**, 811–817.

1074 J.-Y. Son, H. Kim, W. H. Jeon, Y. Baek, B. Seo, K. Um, K. Lee and P. H. Lee, *Adv. Synth. Catal.*, 2017, **359**, 3194–3206.

1075 L. Y. Chan, X. Meng and S. Kim, *J. Org. Chem.*, 2013, **78**, 8826–8832.

1076 B. C. Chary, S. Kim, Y. Park, J. Kim and P. H. Lee, *Org. Lett.*, 2013, **15**, 2692–2695.

1077 L. Y. Chan, S. Kim, T. Ryu and P. H. Lee, *Chem. Commun.*, 2013, **49**, 4682.

1078 L. Y. Chan, L. Cheong and S. Kim, *Org. Lett.*, 2013, **15**, 2186–2189.

1079 X.-H. Hu, X.-F. Yang and T.-P. Loh, *Angew. Chem., Int. Ed.*, 2015, **54**, 15535–15539.

1080 L.-Y. Jiao, A. V. Ferreira and M. Oestreich, *Chem. – Asian J.*, 2016, **11**, 367–370.

1081 Z.-J. Du, J. Guan, G.-J. Wu, P. Xu, L.-X. Gao and F.-S. Han, *J. Am. Chem. Soc.*, 2015, **137**, 632–635.

1082 Y. Sun and N. Cramer, *Angew. Chem., Int. Ed.*, 2017, **56**, 364–367.

1083 Y. Sun and N. Cramer, *Chem. Sci.*, 2018, **9**, 2981–2985.

1084 K. M. Crawford, T. R. Ramseyer, C. J. A. Daley and T. B. Clark, *Angew. Chem., Int. Ed.*, 2014, **53**, 7589–7593.

1085 X. Qiu, M. Wang, Y. Zhao and Z. Shi, *Angew. Chem., Int. Ed.*, 2017, **56**, 7233–7237.

1086 Q. Ge, J. Zong, B. Li and B. Wang, *Org. Lett.*, 2017, **19**, 6670–6673.

1087 F. Zhang and D. R. Spring, *Chem. Soc. Rev.*, 2014, **43**, 6906–6919.

1088 G. R. Jones and Y. Landais, *Tetrahedron*, 1996, **52**, 7599–7662.

1089 S. E. Denmark and C. S. Regens, *Acc. Chem. Res.*, 2008, **41**, 1486–1499.

1090 M. Parasram and V. Gevorgyan, *Acc. Chem. Res.*, 2017, **50**, 2038–2053.

1091 J. F. Hartwig, *Acc. Chem. Res.*, 2012, **45**, 864–873.

1092 P. I. Djurovich, A. R. Dolich and D. H. Berry, *J. Chem. Soc., Chem. Commun.*, 1994, 1897–1898.

1093 E. M. Simmons and J. F. Hartwig, *Nature*, 2012, **483**, 70–73.

1094 Y. Kuninobu, T. Nakahara, H. Takeshima and K. Takai, *Org. Lett.*, 2013, **15**, 426–428.

1095 M. Murai, H. Takeshima, H. Morita, Y. Kuninobu and K. Takai, *J. Org. Chem.*, 2015, **80**, 5407–5414.

1096 B. Su and J. F. Hartwig, *J. Am. Chem. Soc.*, 2017, **139**, 12137–12140.

1097 Y. Kuninobu, K. Yamauchi, N. Tamura, T. Seiki and K. Takai, *Angew. Chem., Int. Ed.*, 2013, **52**, 1520–1522.

1098 Q.-W. Zhang, K. An, L.-C. Liu, Q. Zhang, H. Guo and W. He, *Angew. Chem., Int. Ed.*, 2017, **56**, 1125–1129.

1099 T. Shibata, T. Shizuno and T. Sasaki, *Chem. Commun.*, 2015, **51**, 7802–7804.

1100 M. Murai, K. Matsumoto, Y. Takeuchi and K. Takai, *Org. Lett.*, 2015, **17**, 3102–3105.

1101 Q.-W. Zhang, K. An, L.-C. Liu, Y. Yue and W. He, *Angew. Chem., Int. Ed.*, 2015, **54**, 6918–6921.

1102 E. M. Simmons and J. F. Hartwig, *J. Am. Chem. Soc.*, 2010, **132**, 17092–17095.

1103 T. Lee, T. W. Wilson, R. Berg, P. Ryberg and J. F. Hartwig, *J. Am. Chem. Soc.*, 2015, **137**, 6742–6745.

1104 T. Lee and J. F. Hartwig, *J. Am. Chem. Soc.*, 2017, **139**, 4879–4886.

1105 B. Su, T.-G. Zhou, X.-W. Li, X.-R. Shao, P.-L. Xu, W.-L. Wu, J. F. Hartwig and Z.-J. Shi, *Angew. Chem., Int. Ed.*, 2017, **56**, 1092–1096.

1106 B. Li, M. Driess and J. F. Hartwig, *J. Am. Chem. Soc.*, 2014, **136**, 6586–6589.

1107 C. Karmel, B. Li and J. F. Hartwig, *J. Am. Chem. Soc.*, 2018, **140**, 1460–1470.

1108 A. Bunescu, T. W. Butcher and J. F. Hartwig, *J. Am. Chem. Soc.*, 2018, **140**, 1502–1507.

1109 T. Lee and J. F. Hartwig, *Angew. Chem., Int. Ed.*, 2016, **55**, 8723–8727.

1110 T. A. Boebel and J. F. Hartwig, *J. Am. Chem. Soc.*, 2008, **130**, 7534–7535.

1111 S. H. Cho and J. F. Hartwig, *J. Am. Chem. Soc.*, 2013, **135**, 8157–8160.

1112 D. W. Robbins, T. A. Boebel and J. F. Hartwig, *J. Am. Chem. Soc.*, 2010, **132**, 4068–4069.

1113 M. A. Larsen, S. H. Cho and J. Hartwig, *J. Am. Chem. Soc.*, 2016, **138**, 762–765.

1114 B. Su, T.-G. Zhou, P.-L. Xu, Z.-J. Shi and J. F. Hartwig, *Angew. Chem., Int. Ed.*, 2017, **56**, 7205–7208.

1115 C. Huang and V. Gevorgyan, *J. Am. Chem. Soc.*, 2009, **131**, 10844–10845.
Review Article

1116 C. Huang and V. Gevorgyan, *Org. Lett.*, 2010, **12**, 2442-2445.

1117 M. Mewald, J. A. Schiffner and M. Oestreich, *Angew. Chem., Int. Ed.*, 2012, **51**, 1763-1765.

1118 C. Huang, B. Chattopadhyay and V. Gevorgyan, *J. Am. Chem. Soc.*, 2011, **133**, 12406-12409.

1119 C. Huang, N. Ghavtadze, B. Chattopadhyay and V. Gevorgyan, *J. Am. Chem. Soc.*, 2011, **133**, 17630-17633.

1120 C. Wang and H. Ge, *Chem. - Eur. J.*, 2011, **17**, 14371-14374.

1121 Y. Wang and V. Gevorgyan, *Angew. Chem., Int. Ed.*, 2015, **54**, 2255-2259.

1122 Y. Lin, K.-Z. Jiang, J. Cao, Z.-J. Zheng, Z. Xu, Y.-M. Cui and L.-W. Xu, *Adv. Synth. Catal.*, 2017, **359**, 2247-2252.

1123 S. De Sarkar, W. Liu, S. I. Kozhushkov and L. Ackermann, *Adv. Synth. Catal.*, 2014, **356**, 1461-1479.

1124 D.-G. Yu, F. de Azambuja and F. Glorius, *Angew. Chem., Int. Ed.*, 2014, **53**, 7710-7712.

1125 R. Kuppusamy, K. Muralirajan and C.-H. Cheng, *ACS Catal.*, 2016, **6**, 3909-3913.

1126 B. Chattopadhyay, J. E. Dannatt, I. L. Andujar-De Sanctis, K. A. Gore, R. E. Maleczka, D. A. Singleton and M. R. Smith, *J. Am. Chem. Soc.*, 2017, **139**, 7864-7871.

1127 G. Li, D. Leow, L. Wan and J.-Q. Yu, *Angew. Chem., Int. Ed.*, 2013, **52**, 1245-1247.

1128 S. Kawamorita, H. Ohmiya, K. Hara, A. Fukuoka and M. Sawamura, *J. Am. Chem. Soc.*, 2009, **131**, 5058-5059.

1129 E. Tan, O. Quinonero, M. E. de Orbe and A. M. Echavarren, *ACS Catal.*, 2018, **8**, 2166-2172.

1130 S. Xiaochao, N. Masayoshi and H. Zhaomin, *Angew. Chem., Int. Ed.*, 2016, **55**, 14812-14817.

1131 X. Shi, M. Nishiura and Z. Hou, *J. Am. Chem. Soc.*, 2016, **138**, 6147-6150.

1132 Y.-F. Han and G.-X. Jin, *Chem. Soc. Rev.*, 2014, **43**, 2799-2823.

1133 D.-W. Gao, Q. Gu, C. Zheng and S.-L. You, *Acc. Chem. Res.*, 2017, **50**, 351-365.

1134 L. A. López and E. López, *Dalton Trans.*, 2015, **44**, 10128-10135.

1135 D.-Y. Zhu, P. Chen and J.-B. Xia, *ChemCatChem*, 2016, **8**, 68-73.

1136 W. C. P. Tsang, N. Zheng and S. L. Buchwald, *J. Am. Chem. Soc.*, 2005, **127**, 14560-14561.

1137 W. C. P. Tsang, R. H. Munday, G. Brasche, N. Zheng and S. L. Buchwald, *J. Org. Chem.*, 2008, **73**, 7603-7610.

1138 B.-J. Li, S.-L. Tian, Z. Fang and Z.-J. Shi, *Angew. Chem., Int. Ed.*, 2008, **47**, 1115-1118.

1139 J. A. Jordan-Hore, C. C. C. Johansson, M. Gulias, E. M. Beck and M. J. Gaunt, *J. Am. Chem. Soc.*, 2008, **130**, 16184-16186.

1140 M. Miura, T. Tsuda, T. Satoh, S. Pivsa-Art and M. Nomura, *J. Org. Chem.*, 1998, **63**, 5211-5215.

1141 Z. Liang, L. Ju, Y. Xie, L. Huang and Y. Zhang, *Chem. - Eur. J.*, 2012, **18**, 15816-15821.

1142 V. Rajeshkumar, T.-H. Lee and S.-C. Chuang, *Org. Lett.*, 2013, **15**, 1468-1471.

1143 Z. Liang, J. Zhang, Z. Liu, K. Wang and Y. Zhang, *Tetrahedron*, 2013, **69**, 6519-6526.

1144 Z. Liang, R. Feng, H. Yin and Y. Zhang, *Org. Lett.*, 2013, **15**, 4544-4547.

1145 Z. Liang, J. Yao, K. Wang, H. Li and Y. Zhang, *Chem. - Eur. J.*, 2013, **19**, 16825-16831.

1146 Z.-J. Cai, C. Yang, S.-Y. Wang and S.-J. Ji, *J. Org. Chem.*, 2015, **80**, 7928-7936.

1147 K. Takamatsu, K. Hirano, T. Satoh and M. Miura, *Org. Lett.*, 2014, **16**, 2892-2895.

1148 S. H. Cho, J. Yoon and S. Chang, *J. Am. Chem. Soc.*, 2011, **133**, 5996-6005.

1149 C. Jean-Ho, L. Pi-Shan, L. Ya-Ming, S. Wei-Ting and W. Ming-Jung, *Chem. - Eur. J.*, 2011, **17**, 13613-13620.

1150 C. Suzuki, K. Hirano, T. Satoh and M. Miura, *Org. Lett.*, 2015, **17**, 1597-1600.

1151 A. McNally, B. Haffemayer, B. S. L. Collins and M. J. Gaunt, *Nature*, 2014, **510**, 129-133.

1152 A. P. Smalley, J. D. Cuthbertson and M. J. Gaunt, *J. Am. Chem. Soc.*, 2017, **139**, 1412-1415.

1153 M. Nappi, C. He, W. G. Whitehurst, B. G. N. Chappell and M. J. Gaunt, *Angew. Chem., Int. Ed.*, 2018, **57**, 3178-3182.

1154 D. Willcox, B. G. N. Chappell, K. F. Hogg, J. Calleja, A. P. Smalley and M. J. Gaunt, *Science*, 2016, **354**, 851-857.

1155 J. R. Cabrera-Pardo, A. Trowbridge, M. Nappi, K. Ozaki and M. J. Gaunt, *Angew. Chem., Int. Ed.*, 2017, **56**, 11958-11962.

1156 K. F. Hogg, A. Trowbridge, A. Alvarez-Pérez and M. J. Gaunt, *Chem. Sci.*, 2017, **8**, 8198-8203.

1157 C. He and M. J. Gaunt, *Chem. Sci.*, 2017, **8**, 3586-3592.

1158 C. He and M. J. Gaunt, *Angew. Chem., Int. Ed.*, 2015, **54**, 15840-15844.

1159 J. C. Fox, R. E. Gilligan, A. K. Pitts, H. R. Bennett and M. J. Gaunt, *Chem. Sci.*, 2016, **7**, 2706-2710.

1160 M. Catellani, F. Frignani and A. Rangoni, *Angew. Chem., Int. Ed. Engl.*, 1997, **36**, 119-122.

1161 Q. Ding, S. Ye, G. Cheng, P. Wang, M. E. Farmer and J.-Q. Yu, *J. Am. Chem. Soc.*, 2017, **139**, 417-425.

1162 H. J. Davis, M. T. Mihai and R. J. Phipps, *J. Am. Chem. Soc.*, 2016, **138**, 12759-12762.

1163 H. J. Davis, G. R. Genov and R. J. Phipps, *Angew. Chem., Int. Ed.*, 2017, **56**, 13351-13355.

1164 G. Olivo, G. Farinelli, A. Barbieri, O. Lanzalunga, S. Di Stefano and M. Costas, *Angew. Chem., Int. Ed.*, 2017, **56**, 16347-16351.

1165 T. Nakamura, K. Suzuki and M. Yamashita, *J. Am. Chem. Soc.*, 2017, **139**, 17763-17766.

1166 Z. Qi, M. Wang and X. Li, *Org. Lett.*, 2013, **15**, 5440-5443.

1167 Z. Zhou, G. Liu, Y. Chen and X. Lu, *Adv. Synth. Catal.*, 2015, **357**, 2944-2950.

1168 H. Wang, M. Moselage, M. J. González and L. Ackermann, *ACS Catal.*, 2016, **6**, 2705-2709.

1169 X. Guo, J. Han, Y. Liu, M. Qin, X. Zhang and B. Chen, *J. Org. Chem.*, 2017, **82**, 11505-11511.

1170 Y. Li, F. Xie, Y. Liu, X. Yang and X. Li, *Org. Lett.*, 2018, **20**, 437-440.

1171 F. Xie, S. Yu, Z. Qi and X. Li, *Angew. Chem., Int. Ed.*, 2016, **55**, 15351-15355.

<figure><img src="image_388.png" /></figure>
<figure><img src="image_389.png" /></figure>

1172 Q. Wang, Y. Xu, X. Yang, Y. Li and X. Li, *Chem. Commun.*, 2017, **53**, 9640–9643.

1173 D. Bai, Q. Jia, T. Xu, Q. Zhang, F. Wu, C. Ma, B. Liu, J. Chang and X. Li, *J. Org. Chem.*, 2017, **82**, 9877–9884.

1174 H. Deng, H. Li, W. Zhang and L. Wang, *Chem. Commun.*, 2017, **53**, 10322–10325.

1175 C. Jimenez-Gonzalez, C. S. Ponder, Q. B. Broxterman and J. B. Manley, *Org. Process Res. Dev.*, 2011, **15**, 912–917.

1176 D. Prat, J. Hayler and A. Wells, *Green Chem.*, 2014, **16**, 4546–4551.

1177 D. Prat, A. Wells, J. Hayler, H. Sneddon, C. R. McElroy, S. Abou-Sehada and P. J. Dunn, *Green Chem.*, 2016, **18**, 288–296.

1178 C. Sambiagio, R. H. Munday, A. John Blacker, S. P. Marsden and P. C. McGowan, *RSC Adv.*, 2016, **6**, 70025–70032.

1179 C. J. Pink, H.-T. Wong, F. C. Ferreira and A. G. Livingston, *Org. Process Res. Dev.*, 2008, **12**, 589–595.

1180 Akanksha and D. Maiti, *Green Chem.*, 2012, **14**, 2314–2320.

1181 A. Mouret, L. Leclercq, A. Muhlbauer and V. Nardello-Rataj, *Green Chem.*, 2014, **16**, 269–278.

1182 R. Savela, J. Warna, D. Y. Murzin and R. Leino, *Catal. Sci. Technol.*, 2015, **5**, 2406–2417.

1183 http://www.ema.europa.eu/docs/en_GB/documentLibrary/Scientific_guideline/2015/01/WC500180284.pdf.

1184 S. Santoro, S. I. Kozhushkov, L. Ackermann and L. Vaccaro, *Green Chem.*, 2016, **18**, 3471–3493.

1185 A. J. Hunt, *Green and Sustainable Medicinal Chemistry: Methods, Tools and Strategies for the 21st Century Pharmaceutical Industry*, The Royal Society of Chemistry, 2016, pp. 54–62, DOI: 10.1039/9781782625940-00054.

1186 C. A. Hone, D. M. Roberge and C. O. Kappe, *ChemSusChem*, 2017, **10**, 32–41.

1187 L. V. Desai, K. J. Stowers and M. S. Sanford, *J. Am. Chem. Soc.*, 2008, **130**, 13285–13293.

1188 H. Wang, M. M. Lorion and L. Ackermann, *Angew. Chem., Int. Ed.*, 2016, **55**, 10386–10390.

1189 D. Lapointe, T. Markiewicz, C. J. Whipp, A. Toderian and K. Fagnou, *J. Org. Chem.*, 2010, **76**, 749–759.

1190 Y. J. Liu, H. Xu, W. J. Kong, M. Shang, H. X. Dai and J. Q. Yu, *Nature*, 2014, **515**, 389–393.