Electromechanical transducer device and method of making the same

Provided is an electromechanical transducer device including a substrate that is conductive, and a plurality of electromechanical transducer elements disposed on a first surface of the substrate. A groove that electrically isolates the plurality of electromechanical transducer elements from each other is formed in the substrate, the groove extending from a second surface side of the substrate toward the first surface side of the substrate, the second surface being opposite the first surface. The width of the groove on the first surface side of the substrate is smaller than the width of the groove on the second surface side of the substrate.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to an electromechanical transducer device, such as an ultrasonic transducer, and to a method of making the electromechanical transducer device.

2. Description of the Related Art

Ultrasonic transducers, which convert an electric signal into ultrasound and vice versa, are used as probes for medical imaging and non-destructive testing. There is a type of ultrasonic transducer called a capacitive micromachined ultrasound transducer (CMUT). A CMUT includes, for example, a substrate including a lower electrode, a membrane that is supported by a supporting unit formed on the substrate, and an upper electrode. The lower electrode, the membrane, the upper electrode, and the supporting unit surround a cavity. The CMUT emits a sound wave (oscillatory wave) when a voltage is applied between the lower electrode and the upper electrode and thereby the membrane is vibrated. On the other hand, a CMUT detects a sound wave (oscillatory wave) when the sound wave is received and vibrates the membrane and thereby the capacitance between the lower electrode and the upper electrode is changed.

Traditionally, CMUTs have been made by so-called surface micromachining, bulk micromachining, and the like. Examples of wiring methods include a method of forming an element including a plurality of membranes and cavities on a silicon substrate and connecting the element to a circuit board through the silicon substrate that serves as a lower electrode and a through-hole interconnection (US 2006/0075818 A1). Referring toFIG. 6, this method will be described. A CMUT1007includes a plurality of elements1008, and each of the elements1008individually sends and receives ultrasound. Each of the elements1008includes an upper electrode1000, a membrane1001, a cavity1002, and a lower electrode1003. Grooves1004are formed so as to electrically isolate and insulate the elements1008that are adjacent to each other. The CMUT1007is connected to an ASIC substrate1006through bumps1005.

In the existing CMUT, it is necessary to form the separation grooves each having a width of several hundred micrometers in order to electrically isolate the elements from each other, each of the elements including one or a plurality of cavities. Because the mechanical strength of a portion surrounding a cavity is low, it is necessary to support the portion with a supporting member. However, cavities cannot be formed in a region that corresponds to the separation groove (directly above the separation groove) and for which it is difficult to support a cavity. Therefore, the number of cavities that can be formed per unit area of a substrate is limited. As a result, the fill factor (which refers to the proportion of the area occupied by electromechanical transducer elements in the present specification) is reduced. Therefore, the sensitivity of the device is reduced.

SUMMARY OF THE INVENTION

The present invention provides an electromechanical transducer device including a substrate that is conductive; and a plurality of electromechanical transducer elements disposed on a first surface of the substrate. A groove that electrically isolates the plurality of electromechanical transducer elements from each other is formed in the substrate, the groove extending from a second surface side of the substrate toward the first surface side of the substrate, the second surface being opposite the first surface. The width of the groove on the first surface side of the substrate is smaller than the width of the groove on the second surface side of the substrate.

The present invention also provides a method of making an electromechanical transducer device, the method including forming a groove in a silicon substrate by performing alkali wet etching to form a plurality of first electrodes that are separated from each other, forming cavities that face the first electrodes, forming a membrane that faces the cavities, and forming second electrodes on the membrane. In the above method, forming a groove in a silicon substrate by performing alkali wet etching to form a plurality of first electrodes that are separated from each other may be replaced by forming a groove in a silicon substrate by performing dry etching a plurality of times to form a plurality of first electrodes that are separated from each other.

According to the present invention, by making the width of the groove on the first surface side of the substrate smaller than the width of the groove on the second surface side, a plurality of electromechanical transducer elements can be disposed with a comparatively high density on the first surface side. By making the width of the groove become larger from the first surface side toward the second surface side, a sufficient width is provided to the separation groove as a whole. Therefore, electrical isolation between electromechanical transducer elements can be secured and the parasitic capacity can be reduced. As a result, decrease in sensitivity, which occurs due to a small width of the groove on the first surface side, can be suppressed. Moreover, because the width of the groove on the first surface side can be reduced while suppressing decrease in sensitivity, electromechanical transducer elements can be disposed with a high density, whereby the fill factor can be increased. Also in this respect, the sensitivity of the electromechanical transducer device, such as a CMUT, can be increased. In other words, according to the present invention, the parasitic capacity between electromechanical transducer elements can be reduced while increasing the signal output of the electromechanical transducer device.

DESCRIPTION OF THE EMBODIMENTS

Hereinafter, embodiments of the present invention will be described. An electromechanical transducer device and a method of making the electromechanical transducer device according to the present invention is characterized by the following point. That is, in correspondence with the disposition of a plurality of electromechanical transducer elements, a conductive substrate is divided into a plurality of portions by forming narrow grooves in the substrate so that the width of the grooves on a first surface side (also referred to as the width at a bottom portion) is smaller than the width of the grooves on a second surface side (also referred to as the width at an opening), whereby a plurality of portions of the substrate that serve as electrodes are insulated from each other.

Based on this idea, the electromechanical transducer device and the method of making the electromechanical transducer device according to the invention have basic configurations described in the summary of the invention. Based on the basic configurations, the following embodiments can be realized.

Each of the groove, for example, may have a cross-sectional shape in which the width continuously or discontinuously decreases from the opening to the bottom portion (continuously or discontinuously increases from the first surface side to the second surface side). This structure has a benefit in that the parasitic capacity between electromechanical transducer elements, such as those of capacitance-type, is reduced and the fill factor of the electromechanical transducer elements can be increased. Moreover, the structure can be easily realized by forming the groove in a silicon substrate by alkali wet etching. With this method, the groove described above can be easily formed because walls of the groove can be formed so as to have an angle of 54.7 degrees with respect to the substrate by appropriately setting the thickness of the substrate and the width of the opening of the etching mask (see the second embodiment below). In this case, the side walls of the groove are inclined flat surfaces.

The side walls of the groove may be stepped surfaces. Such a structure can be easily made by performing dry etching a plurality of times, i.e., multi-step dry etching. To be specific, a first dry etching is performed after forming a mask that has an appropriate pattern corresponding to the disposition of a plurality of electromechanical transducer elements on a bottom surface of a silicon substrate, and a second dry etching is performed after appropriately enlarging the openings of the mask. A groove having stepped side walls can be made by successively performing such etching processes to gradually deepen the groove until the bottom of the groove reaches the other side of the substrate. Also with this method, the width of the groove at the bottom portion can be made smaller than the width at the opening.

Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. However, the present invention is not limited to the specifics of the embodiments.

First Embodiment

Referring toFIGS. 1A to 1C, a first embodiment will be described. The first embodiment is a capacitance-type ultrasonic transducer device that includes a silicon substrate in which elements are separated by grooves and a membrane105is made by joining a silicon-on-insulator (SOI) substrate to the silicon substrate.FIG. 1Ais a sectional view of an electromechanical transducer device100according to the first embodiment. As illustrated inFIG. 1A, the electromechanical transducer device100includes a circuit board101and a silicon substrate103. The circuit board101is disposed directly below the silicon substrate103.

FIG. 1Bis a top view ofFIG. 1A. As illustrated inFIG. 1B, the electromechanical transducer device100according to the first embodiment includes 4×4 elements104. A region surrounded by a dotted line inFIG. 1Bcorresponds to one of the elements104. Each of the elements104, which is a capacitance-type electromechanical transducer element, individually sends and receives ultrasound. The element104includes a lower electrode108and a through-hole interconnection109connected to the lower electrode108. The arrangement of the elements104is not limited to 4×4.FIG. 1Cis a partial enlarged view ofFIG. 1B.FIG. 1Ais a sectional view taken along line IA-IA ofFIG. 1C. Referring toFIGS. 1A to 1C, the elements104will be described. The elements104are disposed on a first surface of the silicon substrate103. Each of the elements104includes the membrane105, cavities106, upper electrodes107, and the lower electrode108. The membrane is made of Si, a portion surrounding the cavities106(excluding a portion adjacent to the membrane105) is made of SiO2, the upper electrodes107are made of Al, the lower electrode108is made of Si, and a lower lead line, i.e., the through-hole interconnection, is made of Si. The silicon substrate103and the circuit board101are joined to each other with solder110and electrode pads116disposed therebetween. As described above, in the first embodiment, each of the elements104, which corresponds to an electromechanical transducer element, includes a supporting unit, a membrane that is disposed on the supporting unit115, a lower electrode that faces the membrane, and an upper electrode that is disposed on the membrane. The lower electrode corresponds to a first electrode, and the upper electrode corresponds to a second electrode. The lower electrode108is electrically connected to a part of the silicon substrate103surrounded by a groove111(the through-hole interconnection109). The membrane may also serve as the upper electrode. In the first embodiment, the lower electrode108and the through-hole interconnection109are independent members. However, in the present invention, the lower electrode108and the through-hole interconnection109may be integrated with each other.

The groove111and the lower electrode108will be described. As illustrated inFIGS. 1A to 1C, the groove111is formed in a portion of the silicon substrate103that substantially corresponds to a region between the elements104that are adjacent to each other. This is for the purpose of insulating the adjacent elements104from each other. As illustrated inFIG. 1A, it is necessary that the groove111entirely extend through a portion of the silicon substrate103corresponding to the lower electrode108and the through-hole interconnection109. The groove111has a cross-sectional shape in which the width at a bottom portion, which is on a first surface side of the silicon substrate, is smaller than the width of an opening, which is on a second surface side of the substrate. Thus, parasitic capacity between adjacent elements104can be reduced, and the effective area per element can be increased. In the first embodiment, side walls of the groove111are flat and inclined with respect to the silicon substrate103. Thus, electric discharge between adjacent element104is suppressed. The side walls of the groove may be continuously inclined flat or curved surfaces or, for example, surfaces that are discontinuously stepped.

Referring toFIGS. 1A to 1C, the upper electrodes107will be described. Wiring112is formed in order to connect the upper electrodes107of each element104to each other. In order to electrically connect the upper electrodes107of adjacent elements104to each other, wiring is formed on a beam113of the membrane105that substantially corresponds to the groove111. As a result, all upper electrodes107are connected to lead wiring114. As illustrated inFIG. 1A, the upper electrodes107are connected to the circuit board101through the lead wiring114and the silicon substrate103.

Dimensions of each elements will be described. The membrane105of each cell having the cavities106has a width wmof 200 μm and a thickness tmof 1.5 μm. The cavities106have a width of 200 μm, which is the same as that of the membrane, and a depth tcof 1 μm. The bottom portion of the groove111has a width wtof 100 μm and a depth tt1of 100 μm. The upper electrode107illustrated inFIG. 1Chas a width we1of 100 μm and a thickness te1of 330 nm. The wiring112illustrated inFIG. 1C, which connects the upper electrodes107to each other, has a width we2of 10 μm and a thickness the same as that of the upper electrode. The lead wiring114has a width we3of 100 μm. The lower electrode108has a width we4of 900 μm and a thickness the same as the depth tt1of the groove111(including the through-hole interconnection109). The electrode pad116has a horizontal size of 100 μm×100 μm and a thickness of 330 nm. These dimensions are examples, and may have other values. In the figures, the elements are shown in different scales for convenience of illustration. Assuming that the groove111, which has side walls each having an angle of 54.7 degrees with respect to the surface of the substrate, is made by anisotropic etching, the groove111having the aforementioned width and can be easily provided with a width that is larger than 200 μm at the opening portion. Thus, the groove111can be easily provided with a structure in which the width on the first surface side is smaller than the width at the second surface side.

The operating principle behind the CMUT will be described. When ultrasound is received, the membrane105is displaced and the gap between the upper electrode107and the lower electrode108changes. By detecting and signal-processing the change in capacitance due to the change in the gap, an ultrasonic image and the like can be obtained. When emitting ultrasound, the membrane105is vibrated by applying a modulation voltage to the upper electrode107or the lower electrode108from the circuit board101.

With the first embodiment, the effect of parasitic capacity between adjacent elements can be reduced, the effective area per element can be increased, and the sensitivity of the CMUT can be increased. Because the silicon substrate is used as the wiring, the structure described above has a benefit in that the cavities can be formed by surface micromachining or by bulk micromachining, which will be described in the second embodiment. A through-hole interconnection can be formed by using a method of forming a through-hole in a silicon substrate and depositing polysilicon or the like in the through hole, or by using a method of plating Cu or the like so as to form wiring. However, such methods are disadvantageous in that the cavities cannot be formed in a variety of ways.

Second Embodiment

A second embodiment will be described. The embodiment relates to a method of making the CMUT described in the first embodiment.FIGS. 2A-1to2I-2illustrate a method of making a CMUT according to a second embodiment of the present invention. For convenience of illustration, sectional views of two elements are illustrated inFIGS. 2A-1to2I-2. Other elements can be made in the similar manner. InFIGS. 2A-1to2I-2, portions of the CMUT that function in the similar manner as those illustrated inFIGS. 1A to 1Care denoted by the same numerals.

First, the silicon substrate103is prepared. Typically, the silicon substrate103is a single crystal silicon, to which semiconductor processing techniques can be easily applied. The silicon substrate103may have a low resistivity (i.e., a certain degree of conductivity), because the silicon substrate103becomes the lower electrode108and the through-hole interconnection109. In the second embodiment, an Si substrate having a resistivity lower than 0.02 Ω·cm is used. Next, an oxide film201is formed on the silicon substrate103by pyrogenic oxidation, and a cavity pattern is formed by photolithography. Moreover, the cavities106are formed by etching the oxide film201using buffered hydrogen fluoride (BHF). For example, the silicon substrate103has a thickness of 525 μm, and the oxide film201has a thickness of 1 μm.FIG. 2A-1is a top view andFIG. 2A-2is a sectional view taken along line IIA-2-IIA-2after the cavity pattern has been formed.

Next, the silicon substrate103is thermally oxidized to insulate the bottom surfaces of the cavities106. An oxide film203having a thickness 1500 Å is formed. Another oxide film203is formed also on the lower surface of the silicon substrate103.FIG. 2B-1is a top view andFIG. 2B-2is a sectional view taken along line IIB-2-IIB-2after the oxide films203has been formed.

Next, an SOI substrate205is joined to the silicon substrate103illustrated inFIGS. 2B-1and2B-2.FIG. 2C-1is a top view andFIG. 2C-2is a sectional view taken along line IIC-2-IIC-2after the SOI substrate205has been joined to the silicon substrate103. The SOI substrate205includes a device layer (thickness 1.5 μm), an embedded oxide film layer (thickness 0.4 μm), and a supporting substrate layer (thickness 500 μm). The joining process is as follows. First, surfaces of the silicon substrate103and the SOI substrate205that are joined to each other are subjected to N2plasma treatment. Next, the silicon substrate103and the SOI substrate205are aligned to each other so that the orientation flats match with each other. Lastly, the silicon substrate103and the SOI substrate205are joined to each other in a vacuum chamber at a temperature of 300° C. and under a load of 500 N.

Next, a supporting substrate layer and an embedded oxide film layer of the SOI substrate205are removed by etching. The supporting substrate layer of the SOI substrate205is removed by etching using SF6, and the embedded oxide film layer is removed by etching using buffered hydrogen fluoride (BHF). Thus, the membrane105is formed.FIG. 2D-1is a top view andFIG. 2D-2is a sectional view taken along line IID-2-IID-2after the supporting substrate layer and the embedded oxide film layer have been etched.

Next, the lead wiring114is formed. A resist pattern for the lead wiring114is formed by performing photolithography on the membrane105side of the silicon substrate103, which has been formed in the process illustrated inFIGS. 2D-1and2D-2. By using the resist a mask, the membrane105is dry etched using CF4gas. Likewise, by using the resist as a mask, the oxide films201and203are dry etched using CF4gas.FIG. 2E-1is a top view andFIG. 2E-2is a sectional view taken along line IIE-2-IIE-2after the lead wiring114has been formed.

Next, the upper electrode107is formed. The resist is removed from the substrate, which has been made in the step illustrated inFIGS. 2E-1and2E-2, and Al is deposited on the substrate. The resist pattern for the upper electrode is formed by performing photolithography on the surface on which Al has been deposited. Lastly, by using the resist pattern as a mask, the Al is wet etched to form the upper electrode107.FIG. 2F-1is a top view andFIG. 2F-2is a sectional view taken along line IIF-2-IIF-2after the upper electrode107has been formed.

Next, the resist is removed from the substrate, which has been made in the step illustrated inFIGS. 2F-1and2F-2, and a resist pattern for separating the substrate into 4×4 elements104is formed by photolithography. The oxide film203is etched using BHF, and subsequently the resist is removed. The oxide film203, which has been etched, serves as an etching mask for forming the groove111.FIG. 2G-1is a top view andFIG. 2G-2is a sectional view taken along line IIG-2-IIG-2after the etching mask has been formed.

Next, the grooves111are formed in the silicon substrate103.FIG. 2H-1is a top view andFIG. 2H-2is a sectional view taken along line IIH-2-IIH-2after the groove has been formed. The silicon substrate103is wet etched by using the oxide film203, which has been made in the step illustrated inFIGS. 2G-1and2G-2, as an etching mask. The wet etching method is anisotropic wet etching using an alkaline solution. As the alkaline solution, for example, potassium hydroxide aqueous solution or tetramethylammonium hydroxide aqueous solution (TMAH) may be used. After the etching, the oxide film203is removed. The cross-section of the groove111has a trapezoidal shape such that a side at the opening is larger than the side at the bottom surface.

Lastly, the substrate made in the step illustrated inFIGS. 2H-1and2H-2is joined to the circuit board101.FIG. 2I-1is a top view andFIG. 2I-2is a sectional view taken along line III-2-III-2after the circuit board101has been joined. Solder is used for joining the substrate to the circuit board101. Solder paste is printed on a part of the substrate101that corresponds to the electrode pad116. Next, the solder paste is reflowed so as to form a solder ball. Lastly, the positions of the electrode pads116of circuit elements on the circuit board101is aligned with the lower electrodes of the silicon substrate103, and the circuit board101and the silicon substrate103are joined to each other by reflowing the solder110. Thus, a structure capable of performing signal processing for sending and receiving ultrasound is formed.

As described above, the second embodiment includes forming a plurality of lower electrodes by forming grooves in a substrate by alkali wet etching, forming cavities that face the lower electrodes, forming a membrane that faces the cavities, and forming upper electrodes on the membranes. In the second embodiment, bulk micromachining is used to form a cavity structure on the silicon substrate and to join the SOI substrate to the silicon substrate. By using this method, the mechanical characteristics of the membrane is improved because a single crystal silicon is used as the membrane. Alternatively, a method using surface micromachining may be used. To be specific, for example, the method is used as follows. On a substrate on which a polysilicon layer has been formed as a sacrificial layer, a silicone nitride film is deposited so as to form a membrane, and etching holes are formed in the membrane. The polysilicon layer on the sacrificial layer is etched through the etching holes, so that cavities are formed. Lastly, the etching holes are filled with a silicone nitride film to seal the cavities. Also in this method, grooves can be formed in the substrate on which the elements have been formed.

Third Embodiment

Referring toFIG. 3A, a third embodiment will be described. The third embodiment is a CMUT that is basically the same as that of the first embodiment, but differs from the first embodiment in that the groove111has a cross-sectional shape that is step-like. The groove111is characterized in that the groove111has a small width at a portion that is close to the element104. By providing the groove111with such a cross-sectional shape, a larger number of cavities can be disposed while minimizing an increase in the parasitic capacity generated between the elements104that are adjacent to each other.FIG. 3Billustrates the groove111that has a larger width at a position that is away from the element104. Although the number of cavities that can be disposed is the same as the case ofFIG. 3A, the parasitic capacity between the adjacent element104increases, and the noise increases. The larger the average width of the groove in the depth direction, the smaller becomes the parasitic capacity generated between the elements104that are adjacent to each other. Therefore, by making the width of the groove111at a portion close to the element104smaller and the width of other portions larger, the sensitivity can be improved by increasing the number of cavities while minimizing an increase in noise due to an increase in the parasitic capacity.

Next, referring toFIG. 4, a method of making a CMUT illustrated inFIG. 3Awill be described. The method is basically the same as the second embodiment, but the step of forming the groove111, which is illustratedFIGS. 2H-1and2H-2, is different. Only the method of making groove will be described here. First, a resist mask301is formed on the oxide film203that has been formed in the step illustrated inFIGS. 2G-1and2G-2, and the silicon substrate103is dry etched to some extent (FIGS. 4A-1and4A-2). The opening in the resist mask301is narrower than the opening in the oxide film203. Next, the resist mask301is stripped and a resist mask302is formed on the oxide film203, and dry etching is performed until the oxide film201(seeFIG. 2B-2) is exposed (FIGS. 4B-1and4B-2). The dry etching is performed by using the Bosch process. In the Bosch process, etching and forming of a protective layer are alternately performed, so that a high etching rate and a high aspect ratio can be realized. After the dry etching, the resist mask302is stripped and the oxide film203is removed. The groove111has a cross-sectional shape having a substantially reduced width at the bottom.

With the method of the second embodiment, which uses wet etching, the disposition of the groove111is limited due to crystal anisotropy of silicon. However, the method of making the third embodiment, which uses dry etching, is free from such limitation, and the groove111can be more flexibly disposed.

Fourth Embodiment

Referring toFIGS. 5A and 5B, the fourth embodiment will be described. A CMUT according to the fourth embodiment is a modification of the CMUT of the first embodiment. As illustrated in the sectional view ofFIG. 5A, the CMUT of the fourth embodiment has a structure in which the CMUT illustrated inFIG. 1Ais filled with an underfill117that is an epoxy filler.FIG. 5Bis a top view ofFIG. 5A. As illustrated inFIG. 5A, a space between the silicon substrate103and the circuit board101is filled with the underfill117and the silicon substrate103is joined to the circuit board101with the filler therebetween. The underfill117is used in order to reinforce a part that is fragile because of the use of trench (groove) structure and to reduce deformation that is generated due to difference in the thermal expansion coefficients between the silicon substrate103and the circuit board101when the silicon substrate103is soldered to the circuit board101.

Moreover, the underfill117is used in order to achieve match of acoustic impedance in a region between the silicon substrate103and the circuit board101and to minimize the effect of reflection of ultrasound (suppress reflection). The acoustic impedance is adjusted to a target value by mixing fine particles of tungsten or alumina with DEVCON-B (registered trade mark), which is epoxy filler. For example, the acoustic impedance of the circuit board101is 5.6 kg/s·cm2, and the acoustic impedance of DEVCON-B is 4.7 kg/s·cm2. For example, by mixing fine particles of tungsten with DEVCON-B with a mass ratio of about 40% so that the fine particles are uniformly dispersed in DEVCON-B, the target acoustic impedance of 5.6 kg/s·cm2can be realized. However, the larger the amount of tungsten, the higher the viscosity is. Therefore, air bubbles may be generated when the underfill117is poured into the space. The bubbles remain in a perpendicular trench, from which air is not easily vented, and may cause an acoustic problem. That is, if bubbles remain, most of ultrasound that comes from the upper side ofFIG. 5Ais reflected by the bubbles due to the difference in acoustic impedance between the bubbles and the epoxy filler, and a part of the reflected ultrasound returns to the CMUT and generates a new signal. The signal becomes noise, which may cause reduction in the signal strength or may interfere with the signal so that the strength of the signal varies.

In the fourth embodiment, which has a tapered trench structure, when epoxy filler is poured into the groove111, the epoxy filler flows along side walls of the groove111. At this time, even when drops of the epoxy filler have large sizes due to viscosity, the epoxy filler can be smoothly poured into the groove111without being obstructed at the opening of the groove111because the groove111is tapered. In order to smoothly pour the epoxy filler into the groove111, the surface of the groove111of the trench structure may be activated by subjecting the surface to plasma treatment. Also at this time, plasma can easily reach the bottom of the groove111because the groove111is tapered. As a result, the epoxy filler can be easily poured into the bottom of the groove111. Moreover, because the groove111is tapered, the epoxy filler can be poured into the groove111while maintaining a gap between the side wall and the epoxy filler so that air can be vented through the gap. As a result, the amount of air that remains in the epoxy resin is reduced, generation of bubbles is suppressed, so that acoustic problem can be reduced or eliminated and wide band characteristics can be realized. That is, in general, a capacitance-type electromechanical transducer device has band characteristics that are wider than those of a piezoelectric transducer. The fourth embodiment realizes such characteristics more securely and stably than a general capacitance-type electromechanical transducer device.

This application claims the benefit of Japanese Patent Application No. 2009-172723 filed Jul. 24, 2009 and No. 2010-096557 filed Apr. 20, 2010, which are hereby incorporated by reference herein in their entirety.