Organic light emitting diode and method for fabricating the same

A method for fabricating the organic light emitting diode includes providing a substrate, forming an anode electrode layer on the substrate, forming a passivation layer on the anode electrode layer, the passivation layer having an area smaller than that of the anode electrode layer, performing ion bombardment of the anode electrode layer and the passivation layer, and removing the passivation layer.

CROSS REFERENCE

The present application is based on International Application No. PCT/CN2018/078650, filed on Mar. 11, 2018, which is based upon and claims priority to Chinese Patent Application No. 201710340284.2, filed on May 15, 2017, and the entire contents thereof are incorporated herein by reference.

TECHNICAL FIELD

The present disclosure relates to the field of display technology, and in particular, to an organic light emitting diode and a method for fabricating the same.

BACKGROUND

Recently, high-resolution displays have become the goal of people, especially organic light-emitting diode (OLED) high-resolution displays have received much attention from the market with its unique advantages, such as fast response, full curing, self-illumination or the like.

During the process of fabricating high-resolution OLED display, a pixel define layer (PDL) limits the aperture ratio. However, if there is no pixel define layer, there will be a problem of short circuit caused by the overlap of the anode and the cathode.

SUMMARY

The present disclosure provides a method for fabricating an organic light emitting diode. The method includes providing a substrate. The method includes forming an anode electrode layer on the substrate. The method includes forming a passivation layer on the anode electrode layer. The passivation layer has an area smaller than an area of the anode electrode layer. The method includes performing ion bombardment on the anode electrode layer and the passivation layer. The method includes removing the passivation layer.

In an exemplary arrangement, the method for fabricating the organic light emitting diode further includes forming an organic electroluminescent layer on the anode electrode layer, and forming a cathode layer on the organic electroluminescent layer.

In an exemplary arrangement, the method for fabricating the organic light emitting diode further includes forming a pixel driving circuit structure layer between the substrate and the anode electrode layer.

In an exemplary arrangement, a slope angle of a corner of the anode electrode layer is between 10 and 60 degrees.

In an exemplary arrangement, the area of the passivation layer is 90% of that of the anode electrode layer.

The present disclosure also provides an organic light emitting diode. The organic light emitting diode includes a substrate and an anode electrode layer disposed on the substrate. A corner of the anode electrode layer has an obtuse angle with circular arc. The organic light emitting diode includes an organic electroluminescent layer covering the anode electrode layer and a cathode electrode layer disposed on the organic electroluminescent layer.

In an exemplary arrangement, a slope angle of the corner of the anode electrode layer is between 10 and 60 degrees.

In an exemplary arrangement, the corner of the anode electrode layer is a circular obtuse angle.

In an exemplary arrangement, the corner of the anode electrode layer is subject to a plasma treatment.

In an exemplary arrangement, the anode electrode layer is formed of indium tin oxide.

In an exemplary arrangement, the organic light emitting diode further includes a pixel driving circuit structure layer formed between the substrate and the anode electrode layer.

DETAILED DESCRIPTION

The present disclosure will be further described in detail below in conjunction with the accompanying drawings and arrangements. It can be understood that the specific arrangements described herein are merely used for explaining the present disclosure and are not intended to be limiting of the present disclosure. It is also to be noted that, for the convenience of description, only some but not all of the structures related to the present disclosure are shown in the drawings.

FIGS. 1 to 3are process flow diagrams showing the fabrication of an organic light emitting diode in the related art.

In the related art, as shown inFIG. 1, first, a pixel driving circuit (array) structure layer2is fabricated on a substrate1, and then a metal oxide layer, such as indium tin oxide (ITO), is fabricated on the pixel driving circuit structure layer2, and a patterned anode electrode layer3is obtained by etching the ITO layer.

However, as shown in the portion11shown by the circled portion inFIG. 1, the etching angle of the anode electrode layer3has sharp edges.FIG. 4is an electron scanning photograph of the ITO anode electrode layer after being etched, andFIG. 4is a scanning view of an object. As can be seen fromFIG. 4, the corners of the ITO anode electrode layer formed by etching are very sharp.

Next, as shown inFIG. 2, the organic electroluminescent layer5is formed on the anode electrode layer3by evaporating, since the etching edge angle of the anode electrode layer3is has sharp edges, the organic electroluminescent layer5cannot completely cover the anode electrode layer3, as shown by the circled portion denoted by12inFIG. 2.

Next, as shown inFIG. 3, the cathode layer6is formed on the organic electroluminescent layer5by evaporating, since the organic electroluminescent layer5does not completely cover the anode electrode layer3, the cathode and the anode are overlapped at the corners when the cathode if formed by evaporating, causing a cathode-anode short circuit, as shown by the circled portion denoted by13inFIG. 2.

In the related art, in order to avoid this, after the anode electrode layer3is etched, a pixel define layer (PDL)4is fabricated to cover sharp corners, and then the organic electroluminescent layer5and the cathode layer6are formed on the pixel define layer4by evaporating, such that the evaporated organic electroluminescent layer5completely isolates the anode electrode layer3from the cathode layer6. A cross-sectional view of the obtained organic light-emitting diode is shown inFIG. 4.

However, the pixel define layer may block part of the anode and thus reduce the aperture ratio. Nowadays, the display is having higher resolution, and the pixel region is getting smaller and smaller, especially for the OLED display applied in the micro display field, which the pixel region has a size of only a few microns or even several microns. Therefore, it is especially important to remove the pixel define layer. That the pixel define layer is removed without causing the overlap of the cathode and the anode is the problem to be solved by the present disclosure.

The present arrangement provides a method for fabricating an organic light emitting diode, andFIGS. 6 to 8are process flow diagrams showing the fabrication of an organic light emitting diode according to an arrangement of the present disclosure.

As shown inFIG. 6, first, a substrate301is provided. A pixel driving circuit (array) structure layer302is fabricated on the substrate301. A metal oxide layer, such as an indium tin oxide (ITO) layer, is fabricated on the pixel driving circuit structure layer302as the anode electrode layer303.

Next, as shown inFIG. 7, a passivation layer307is fabricated on the anode electrode layer303, and the material of the passivation layer307may be a dense inorganic film, such as SiN3, SiO2. The passivation layer is then etched into a pattern that is slightly smaller than the anode pattern, as shown inFIG. 7. In an exemplary arrangement, the size of the passivation layer is 90% of the size of the anode electrode layer303, so that the processing cost and the subsequent etching effect on the anode pattern can be achieved.

Then, the anode electrode layer303is ion bombarded with ion bombardment equipment (e.g., dry etching equipment) using the passivation layer307as a mask. The ion bombardment conditions can be selected as follows. The power (W) is 500 W; the pressure (mT) is 60 mT; the temperature (° C.) is 50° C.; the gases (sccm) are chlorine gas 20 sccm, argon gas 400 sccm, and helium gas 300 sccm; and time (sec) is 80 seconds. The ion bombardment conditions described herein are exemplary conditions and are not intended to limit the present arrangement.

Since there is no protection of the passivation layer307at the corners of the anode electrode layer303, the sharp corners are bombarded by ions into a an obtuse angle with circular arc. After the passivation layer is etched away, a pattern as shown inFIG. 8can be obtained. As shown inFIG. 8, the corners of the anode electrode layer303are obtuse angles with circular arc. The slope angle of the corner of the anode electrode layer303is in the range of 10 to 60 degrees, and within this range, it is more advantageous to completely cover the anode electrode layer303by the organic electroluminescent layer305to be formed by evaporating below. Here, the slope angle of the corner of the anode electrode layer303is defined as the angle between the arc tangent at the corner of the anode electrode layer and the plane of the anode electrode layer303, as shown by the angle denoted by a inFIG. 9.

FIG. 10is an electron scanning photograph of an ITO anode electrode layer303after being performed by ion bombardment, as can be seen fromFIG. 10, after the anode electrode layer303is performed by the ion bombardment, the angle with sharp edges becomes an angle with circular arc.

Then, the organic electroluminescent layer305and the cathode layer306are formed on the anode electrode layer303by evaporating, and the schematic structural view of the obtained organic light-emitting diode is shown inFIG. 11

Since the corner of the anode electrode layer303is an obtuse angle with circular arc, the organic electroluminescent layer305can completely cover the anode electrode layer303when forming the organic electroluminescent layer305on the anode electrode layer303by evaporating. Then it is possible to prevent a short circuit caused by the overlap of the anode and the cathode when forming the cathode306by evaporating. In addition, a pixel define layer is not needed for achieving isolation of the cathode layer from the anode electrode layer.

According to the method for fabricating the organic light emitting diode of the present arrangement, an anode electrode layer having an obtuse angle with circular arc can be obtained, preventing a short circuit caused by the overlap of the anode and the cathode, and there is also no need a pixel define layer to achieve isolation of the cathode layer from the anode electrode layer at the same time, improving the aperture ratio and yield of the organic light emitting diode.

The present arrangement provides an organic light emitting diode.

FIG. 11is a schematic structural view of an organic light emitting diode according to an arrangement of the present disclosure. As shown inFIG. 11, the organic light emitting diode according to the present arrangement includes a substrate301, a pixel driving circuit structure layer302disposed on the substrate301, an anode electrode layer303disposed on the pixel driving circuit structure layer302, an organic electroluminescent layer305completely covering the anode electrode layer303, and a cathode electrode layer306disposed on the organic electroluminescent layer305.

In this arrangement, the anode electrode layer303is subject to a plasma treatment, and has an obtuse angle with circular arc. The slope angle of the corner of the anode electrode layer303is between 10 and 60 degrees. Within this range, the coverage of the anode electrode layer303by the organic electroluminescent layer305is more advantageous.

The specific plasma treatment method is as follows. Fabricating a passivation layer having a smaller area than the anode electrode layer303on the anode electrode layer303, and treating the anode electrode layer303by plasma with the passivation layer as a mask to obtain an anode electrode layer303having a circular obtuse angle, and then removing the passivation layer. For example, the anode electrode layer may be formed of indium tin oxide.

According to the organic light emitting diode of the present arrangement, wherein the corner of the anode electrode layer has an obtuse angle with circular arc, so that the organic electroluminescent layer can completely cover the anode electrode layer, preventing short circuit caused by the overlap of the anode and the cathode. In addition, a pixel define layer is not needed for achieving isolation of the cathode layer from the anode electrode layer, and the aperture ratio and yield of the organic light emitting diode is improved.

It is noted that the foregoing is only the preferred arrangement of the present disclosure and the principles of the techniques employed. It should be understood by those skilled in the art that the present disclosure is not limited to the specific arrangements described herein, and that various modifications, changes and substitutions may be made without departing from the scope of the present disclosure. Therefore, although the present disclosure has been described in detail by the above arrangements, the present disclosure is not limited to the above arrangements, and further arrangements may be included without departing from the inventive concept, and the scope of the present disclosure is determined by the appended claims.