Temperature history indicatiang label

A temperature indicating label includes a rectangular, insulative panel scribed on its faces with intersecting grooves in which electrodes of a galvanic reaction are bedded. One of the electrode sets is consumed in the course of electrolytic reaction and when consumed will expose the electrolyte admixed with a dye. A switching circuit selectively steps in sequence across the consummable electrodes while another portion of the circuit selects the other electrodes in accordance with temperature.

BACKGROUND OF THE INVENTION 
1. FIELD OF THE INVENTION 
The present invention relates to temperature sensing devices and more 
particularly to time-temperature patches for use with foodstuffs and the 
like. 
2. DESCRIPTION OF THE PRIOR ART 
The consumption of a galvanic cell with time and temperature is a well 
known phenomenon, particularly in the familiar zinc-carbon cell. Galvanic 
cells of this type have been extensively studied and the charge capacity 
of zinc is well known. Thus the consumption rate (coulombs) of the well 
known Leclanche cell is widely appreciated by those skilled in the art. 
A Leclanche cell typically includes a zinc anode, a carbon cathode, and an 
ammonium chloride electrolyte with the positive and negative terminals 
connected to the carbon and zinc electrodes respectively. Since the charge 
capacity of zinc is well known (0.81 amp hours per gram) its consumption, 
through ionization, is also well known and predictable. Simply, a zinc 
electrode of a known mass provides a known number of atoms for ionic 
consumption and thus will consume itself in the course of producing 
current. 
This galvanic consumption of a cell is well appreciated and has led to 
various developments including the time-temperature indicators described 
in U.S. Pat. No. 4,277,974 to Karr et al. These teachings, while suitable 
for their purpose, consume a single electrode as a combined function of 
temperature and time. Thus the foregoing indicator is primarily useful 
with foodstuffs which, like the cell, exhibit an exponential combination 
of time and temperature in their useful life. Since time and temperature 
are thus combined only a combined result is perceptible. 
Unlike ordinary foodstuffs, wine and other liquors entail prolonged organic 
processes including residual fermentation and aging which ordinarily are a 
normal incident of production. Consequently, such products are not well 
suited for exponential indicators since a prolonged shelf life is a normal 
event of their use. 
Nonetheless, such extended shelf life history is subject to its own 
constraints. Most frequently such constraints are in the form of upper 
temperature limits which, when exceeded, commence their deleterious 
effects on the product. An exponential galvanic cell under these 
circumstances will eventually consume itself, by the simple extent of its 
shelf life, and thus becomes useless as an indicator with time. 
An indicator which is essentially rendered inactive under ordinary storage 
conditions is thus extensively sought and it is one such indicator that is 
disclosed herein. 
SUMMARY OF THE INVENTION 
Accordingly, it is the general purpose and object of the present invention 
to provide a temperature history indicator useful over long periods of 
time. 
Other objects of the invention are to provide a temperature indicating 
patch which remains useful over extended periods of storage. 
Yet further objects of the invention are to provide a temperature 
indicating patch which is convenient in fabrication and use. 
Briefly, these and other objects are accomplished within the present 
invention by providing a regularly perforated insulative screen in the 
form of a rectangular patch or label having the rear surface thereof 
grooved with regularly spaced horizontal grooves of even depth and 
section. A set of evenly spaced vertical grooves is then formed an the 
front insulator surface each of a shaped and tapered section along the 
length thereof. Thus at each intersection of the vertical and horizontal 
grooves an opening is formed, defined in size by the depth and taper of 
the vertical grooves. 
Each of the vertical grooves receives a conformingly elongate, tapered, 
strip of pure zinc intimately connected at the large end to a 
corresponding terminal. The horizontal grooves, in turn, each receive a 
fibrous deformable separator strip onto which the electrolyte is 
deposited. Thereafter each of the horizontal grooves is capped or covered 
by a graphite electrode strip again connected to a corresponding terminal. 
On this form an orthogonal grid is formed which at every intersection 
defines a singular, isolated, cell. Of course, each cell includes a 
sufficient quantity of electrolyte and electrodes to effect the desired 
galvanic reaction. 
The terminals at the carbon electrodes are then each connected to its 
corresponding reed switch selected to close at a predetermined 
temperature. A corresponding current limiting circuit is then connected to 
each reed switch for controlling the galvanic rate of reaction. These 
circuits are then fed back to the corresponding cells, in a stepped 
sequence enabled by a mechanical switch. This sequence is set out by a 
current division along the lowermost carbon rank. 
As result, the individual vertical zinc strips are galvanically eroded at 
their corresponding perforations, exposing the subjacent dark colored 
electrolyte to view. Thus a dot matrix histogram becomes visible to the 
user indicating a weighted temperature history of the product to which it 
is attached. 
One should note that the foregoing assembly lends itself well for 
integrated production. Thus the patch can be conveniently fabricated on a 
large quantity scale including the well known processes of solid state 
integration. Of course, various insulative coverings and shields may be 
employed with the exterior shield appropriately marked or scribed to 
inform the user of the temperature record displayed.

DESCRIPTION OF THE PREFERRED EMBODIMENT 
As shown in FIGS. 1-6 the inventive temperature sensing patch, generally 
designated by the numeral 10, comprises a substantially rectangular 
separation screen 11 formed of an inert insulative, material structure 
like one of the polymeric materials in the Mylar of Teflon group. This 
screen 11 is defined by an upper and a lower surface, 12 and 13 
respectively, with the upper surface 12 grooved by a plurality of 
parallel, elongate, vertical grooves 20-1 through 20-9. Grooves 20-1 
through 20-9 are each identical in shape, each taking the form of a 
progressively increasing tapered section, from a narrow end to a larger 
end. 
The lower surface 13 is similarly grooved with a horizontal groove array 
comprising parallel, elongate, grooves 30-1 through 30-5, each of equal, 
fixed, section along its length. Preferrably screen 11 is formed of 
material stock 25 to 40 mils in thickness as with grooves 20-1 through 
20-9 and 30-1 through 30-5 cut to interfering depths. Thus, as illustrated 
in detail in FIG. 5 an array of perforations or openings 35 is formed at 
the groove crossings which increase in sectional area with the increasing 
taper of the vertical grooves. 
Each of the foregoing vertical grooves 20 then receive a corresponding 
conformingly tapered zinc strip 28-1 through 28-9 separated from each 
other by the interspaced screen material. Similarly each of the horizontal 
grooves 30 is first layered at its bottom by a fibrous conforming strip 37 
and thereafter filled with electrolyte 38 and sealed at the exterior by a 
carbon or graphite cover strip 39, preferrably in the form of a graphite 
loaded polymer to insure flexure. 
By way of example herein electrolyte 38 may be in the form of a black, 
pasty, mixture of the constituents normally found in a dry cell battery 
hydrated to some extent to pass by wick action through the fibrous layer 
37. Those skilled in the art will appreciate that a mixture of hydrated 
manganese dioxide, ammonium chloride, and/or zinc chloride is effective 
for the purposes herein, admixted with an inert dye to enhance visual 
perception by enhancing the optical distinction of the electrolyte from 
the optical characteristics of the zinc. 
In this form a groove lattice in an inert sheet defines an array of 
discrete galvanic cells each containing a zinc mass defined by the taper 
of the vertical grooves 20. As set out above it is this zinc mass that is 
eroded by ionization in direct proportion to the current rate. This 
rectangular screen 11 is then fitted within the interior aperture of a 
rectangular edge insulator 71 onto which the various electrical leads E 
may be bedded in the form of a printed circuit extending onto a tab 72 
aligned for connection with an integrated circuit 1C. This peripheral 
insulating shield 71 is then inserted into a conforming aperture in yet 
another peripheral electrolyte stratum 112 adhered to a graphite layer 
113. When thus positioned the screen 11 and the peripheral strip 71 are 
overlayed with a slightly larger transparent insulating sheet 75 onto 
which a rectangularly shaped zinc electrode sheet 111 is aligned conformed 
to register with the electrolyte layer 112. The combination of sheet 111, 
electrolyte 112 and carbon layer 113 form a large planar storage cell 110 
useful for the signal flow described herein. The combined assembly is then 
sheathed in transparent coverings 501 and 502 to complete the assembly. 
The circuit effected in the chip IC is shown in its diagrammatic equivalent 
at FIG. 6. For convenience in this presentation the foregoing individual 
galvanic cells formed in screen 11 shall be designated by the row and 
column crossings, as for example cells C11 through C59. For the purposes 
herein cells C11 through C19 each contain an equal lowermost zinc mass for 
erosion while cells C21-C29 increase in zinc mass, and so on. Thus, by 
selecting the correct current rate around each cell its time interval for 
complete erosion can be conveniently determined. Of course, such current 
draw can be effected by installing suitable impedances into the cell loop. 
While the electrolyte consumption of zinc is well known the realistic 
volumetric constraints of the label 10 confine the zinc mass to very low 
levels. Thus for a useful life in the domain measured by months the 
current levels must of necessity be extremely low. Any logical switching, 
therefore, occurs at very low current regions of a solid state device. 
Even at these low levels the static base current of a typical transistor 
junction is measured in nanoamperes, or greater, and thus a large current 
source is required for extended operation. This current source is effected 
by the planar battery segment 110 deployed peripherally around the screen 
11, as described above. This planar battery may include appropriate 
protection against internal shorts effected by way of a permeable, inert, 
fibrous separator sheet 114. Preferrably the planar dimensions of the zinc 
electrode sheet 111 are greater than 20 square centimeters with a 
thickness of 1 to 2 mils, thereby providing a useful life in multiple 
month denomination. 
With the foregoing scales in mind the electrical circuit shown in FIG. 6 
will now be treated in detail. In this circuit implemented in the 
integrated circuit chip IC, the large capacity cell 110 provides the 
effective potential reference for sequential timing. This sequence is 
initiated by a mechanically collapsed switch 121 which is rendered closed 
upon sale (or bottling) of the liquid into the container onto which the 
inventive label 10 is adhered. Once the circuit is thus closed battery 110 
is connected in circuit with a cascaded arrangement of transistors which 
sequentially connect cells C11, C21 through C91 for galvanic dissipation. 
By way of example, and in the interest of clarity only, cells C11 and C21 
are shown, it being understood that the remaining cells are similarly set 
off along the horizontal graphite electrode 39-1 in groove 30-1. Thus, the 
positive side of battery 110 connects across a base bias resistor 122 to 
the base of a transistor 123 which at its collector receives, across a 
collector resistor 124, the positive side of cell C11. Transistor 123 is 
connected in an emitter-follower circuit with an emitter resistor 125 
returning back to the negative side of battery 110. Since at full 
potential the charge of cell C11 approximates the potential of battery 110 
transistor 123 will conduct as long as galvanic action in this cell 
continues. The rate of its current is thus controlled primarily by 
resistors 124 and 125. These resistors effectively form a voltage divider 
with the emitter voltage of transistor 123 then serving as the base 
signal, across a resistor 127, to the base of a transistor 133 which thus 
sets an effective base signal as long as transistor 123 is conducting. 
Once cell C11 is fully dissipated it becomes an effective short to ground 
(its effective internal resistance being negligible relative the other 
circuit components) and the VCE of transistor 123 then falls to zero. At 
this point the base signal to transistor 133 also falls to zero and all 
substantial conduction through this transistor then ceases. 
Transistor 133 is connected at its collector, across corresponding 
resistors 141 and 142 to cells C12 and C13 (and by similar example to the 
remaining cells along the zinc electrode 28-1). These cells, in turn, 
complete their circuits to the graphite electrodes 39-2 and 39-3 which 
return to the common ground through temperature responsive reed switches 
250 and 350. It is these reed switches that set the temperature at which 
the graphite electrodes 39-1 through 39-5 are brought into operation. 
(Electrode 39-1 through 39-5 indicates, by suffix number, the electrode 39 
in the corresponding groove 30-1 through 30-5). 
In a similar manner a transistor 223 fed by a base resistor 222 from 
battery 110 develops an emitter follower signal at an emitter resistor 
225. This emitter signal connects, in turn, to cell C11 and is thus 
floated at its potential. This same floating potential is concurrently 
applied to the end of an emitter resistor 237 at a transistor 233 switched 
by a base signal from the emitter of transistor 223. The collector of 
transistor 223 is fed, across resistor 228, from cell C21 while the 
emitter of transistor 233 is tied to cell C11. 
Accordingly, as long as cells C11 and C21 are at the same potential no 
conduction will occur through transistor 233. Once cell C11 dissipates an 
effective conduction path is established to render conduction through 
cells C22 and C23 across their resistors 241 and 242 and transistor 233. 
This sequence of floating the conduction thus sets a stepping ladder for a 
time sequence in which the various vertical zinc strips are brought in. 
Once two adjacent cells in the lowermost rank are dissipated no further 
action will occur along this zinc strip. Accordingly, a visual display of 
eroded zinc apertures is devised which advances at the rate set by the 
consumption of the lowermost rank. 
Of course the 9.times.5 cell matrix, defined by the crossings of grooves 
20-1 through 20-9 and 30-1 through 30-5, as described above, is exemplary 
only. Larger matrices are contemplated and may conveniently be effected in 
accordance with the example above. Moreover, the progressively increasing 
zinc section allows for selective circuit emphasis (as determined by the 
resistor network) on those aperture ranks in the higher, more critical 
temperature region. These same larger zinc sections are associated with 
larger openings 35 which thus render perception of significant temperature 
levels more effective. To further enhance this perception the exterior of 
the covering 501 may be scribed, color coded, or otherwise marked to suit 
the application. 
In a further alternative shown in FIG. 7 an integrated switch bank 1050 may 
be devised in which a curled common contact 1051 expands or uncurls with 
temperature. A plurality of contact tabs 1250, 1350, 1450 and 1550 extend 
to varying separations above contact 1051 and are thus contacted at 
selected temperature levels. These contacts may be substituted for and may 
effect the function of reed switches 250 and 350 as described above. 
Obviously many modifications and changes may be made to the foregoing 
description without departing from the spirit of the invention. It is 
therefore intended that the scope of the invention be determined solely on 
the claims appended hereto.