Multi-color electrophoretic display device, image sheet, and manufacturing method thereof

A multi-color electrophoretic display (EPD) device, an image sheet, and a method of fabricating the same. The multi-color EPD device includes: a plurality of unit color pixels; and a plurality of color capsules, each comprising color capsule shell which stores a dielectric fluid and at least one type of electrophoretic particles dispersed in the dielectric fluid, the plurality of color capsules being arranged to define subpixels of each of the plurality of unit color pixels.

FIELD OF THE INVENTION

The present invention relates to a flat panel display device, and more particularly, to a multi-color electrophoretic display (EPD) device, an image sheet, and a method of fabricating the same.

BACKGROUND ART

As semiconductor fabricating technology and information communication technology have recently been developed, markets for electronic devices such as mobile phones, personal computers, visual entertainment systems, personal digital assistants (PDAs), and electronic books have expanded. Various flat panel display devices such as liquid crystal display (LCD) devices, field emission display (FED) devices, electrophoretic display (EPD) devices, and organic/inorganic electroluminescence devices are applied to such electronic devices.

Among these flat panel display devices, EPD devices are considered as next-generation display devices because they have a wide viewing angle and low power consumption, and may easily realize flexible display devices. There have been recent attempts to obtain multi-colors by applying a color filter to an EPD device. To this end, however, the color filter has to be fabricated and an additional process such as an additional process of aligning the color filter in the EPD device is required.

DISCLOSURE

Technical Problem

The present invention provides an electrophoretic display (EPD) device which may realize a multi-color display device without a color filter and may have high color saturation and high contrast.

The present invention also provides a method of fabricating the EPD device.

The present invention also provides an image sheet which may realize a multi-color display device without a color filter and may have high color saturation and high contrast.

The present invention also provides a method of fabricating the image sheet.

Technical Solution

According to an aspect of the present invention, there is provided a multi-color electrophoretic display (EPD) device including: a plurality of unit color pixels; and a plurality of color capsules that include color capsule shells each of which stores a dielectric fluid and at least one type of electrophoretic particles dispersed in the dielectric fluid, wherein the plurality of color capsules are arranged to define subpixels of each of the plurality of unit color pixels.

According to another aspect of the present invention, there is provided a method of fabricating a multi-color electrophoretic display (EPD) device including a plurality of unit color pixels, the method including: forming a plurality of color capsules that include capsule shells each of which stores a dielectric fluid and at least one type of electrophoretic particles dispersed in the dielectric fluid; and arranging the plurality of color capsules on a substrate to define subpixels of each of the unit color pixels.

According to another aspect of the present invention, there is provided an image sheet for a multi-color electrophoretic display (EPD) device, the image sheet including a plurality of color capsules that are disposed on a support substrate and include color capsule shells each of which stores a dielectric fluid and at least one type of electrophoretic particles dispersed in the dielectric fluid, wherein the plurality of color capsules are arranged to define subpixels of each of unit color pixels.

According to another aspect of the present invention, there is provided a method of fabricating an image sheet for a multi-color electrophoretic display (EPD) device, the method including: providing a support substrate; and arranging on the support substrate a plurality of color capsules that include color capsule shells each of which stores a dielectric fluid and at least one type of electrophoretic particles dispersed in the dielectric fluid to define subpixels of each of unit color pixels.

Advantageous Effects

Since a multi-color display device according to embodiments of the present invention switches light by using an electrophoretic layer including a plurality of color capsules, the multi-color display device may be realized without a color filter. Thus, the multi-color display device may have high color saturation and high contrast.

Also, an image sheet according to embodiments of the present invention may implement multi-colors without light loss due to a color filter.

BEST MODE

Hereinafter, exemplary embodiments will be described in greater detail with reference to the accompanying drawings.

Embodiments may take many different forms and should not be construed as being limited to those set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art.

In the drawings, lengths and sizes of layers and regions may be exaggerated for clarity. Like reference numerals in the drawings denote like elements. The term “and/or” used herein includes any one of listed items or a combination of two or more thereof.

It is also understood that when a layer is referred to as being “on” another layer or substrate, it can be directly on the other or substrate or intervening layers or layers formed in the intervening layers may also be present. It will be clearly understood by those skilled in the art that a structure or shape “adjacent to” another shape may have a portion overlapping the other shape or a portion below the other shape.

Spatially relative terms, such as “below”, “above”, “upper”, “lower” “horizontal”, or “vertical”, may be used herein for ease of description to describe one element, layer, or region's relationship to another element(s), layer(s), or region(s) as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures.

Exemplary embodiments are described herein with reference to drawings that are schematic illustrations of exemplary embodiments (and intermediate structures). As such, variations from the shapes of the illustrations as a result, for example, of fabricating techniques and/or tolerances, may be expected. Thus, exemplary embodiments should not be construed as limited to the particular shapes of regions illustrated herein but may be to include deviations in shapes that result, for example, from fabricating.

Structure and Operation of Multi-Color EPD Device

FIG. 1is a cross-sectional view illustrating an electrophoretic display (EPD) device100which is a multi-color EPD device, according to an embodiment of the present invention.

Referring toFIG. 1, the EPD device100includes a first substrate (which may be a lower substrate10) and a second substrate (which may be an upper substrate20) that faces the lower substrate10. At least one of the lower substrate10and the upper substrate20, for example, the upper substrate20, may be transparent, and the remaining substrate, that is, the lower substrate10, may not be transparent. Alternatively, both the lower substrate10and the upper substrate20may be transparent.

Each of the lower substrate10and the upper substrate20may be a glass substrate, or may be formed of an inorganic material having a single crystalline structure or a polycrystalline structure. Each of the lower substrate10and the upper substrate20may be flexible. In this case, each of the lower substrate10and the upper substrate20may be formed of a resin-based material. For example, the resin-based material may be, but is not limited to, any one of a cellulose-based resin; a polyester resin such as polyethylene terephthalate (PET) or polyethylene naphthalate (PEN); a polyethylene resin; a polyvinyl chloride resin; polycarbonate (PC); polyether sulfone (PES); polyether etherketone (PEEK); and polyphenylene sulfide (PPS), or a combination thereof.

Electrodes facing to each other may be respectively formed on the lower substrate10and the upper substrate20to generate an electric field perpendicular to main surfaces of the lower substrate10and the upper substrate20. For example, as shown inFIG. 1, when a unit color pixel of the EPD device100includes first through third subpixels, one or a plurality of pixel electrodes30R,30G, and30B may be formed on the lower substrate10respectively for the first through third subpixels. Also, a common electrode30cfacing the pixel electrodes30R,30G, and30B may be disposed on the upper substrate20. Each of the first, second, and third subpixels may be a subpixel of any one color of red, green, blue, magenta, cyan, and yellow for the purpose of providing color display.

Although three subpixels constitute one unit color pixel inFIG. 1, the present embodiment is not limited thereto. For example, a unit color pixel may include two subpixels, or four or more subpixels including additional subpixels for displaying black and/or white in order to improve color rendition as will be described below.

Each of the pixel electrodes30R,30G, and30B may have a pattern suitable for a passive or active matrix addressing scheme.FIG. 1exemplarily illustrates an electrode structure that may be driven by using an active matrix addressing scheme, and the pixel electrodes30R,30G, and30B may be driven by using an appropriate switching element50, for example, a metal-oxide semiconductor (MOS) thin film transistor. The switch element50may include a semiconductor layer50A having a channel region and source/drain regions, a gate electrode50G, and a gate insulating film50I disposed between the semiconductor layer50A and the gate electrode50G.

The switch element50and each of the pixel electrodes30R,30G, and30B may be electrically connected to each other through a drain electrode50D, and a source electrode50S may be electrically connected to a data line (not shown). When the gate electrode50G and the source electrode50S are arranged in an array of a plurality of rows and a plurality of columns, an active matrix suitable for obtaining multi-colors is realized. Alternatively, as is well known in the art, a simple electrode structure for a static drive method using segments may be within the scope of the present invention. If necessary, a driving member may be formed on the upper substrate20, and the common electrode30cmay be controlled as an individual electrode by being connected to the driving member.

At least one of the electrodes30R,30G,30B, and30cmay be a transparent electrode. For example, inFIG. 1, the common electrode30cof the upper electrode20that provides a visual surface to an observer1is a transparent electrode. Also, in order to implement a transmissive display device, the pixel electrodes30R,30G, and30B may also be transparent electrodes. Each of the transparent electrodes may be formed of, but is not limited to, any one of a transparent metal oxide such as indium-tin-oxide (ITO), fluorinated tin oxide (FTO), indium oxide (IO), or tin oxide (SnO2), a transparent conductive resin such as polyacetylene, and a conductive resin including fine conductive metal particles, or a combination thereof. Electrically insulating protective films70aand70bfor protecting the electrodes30R,30G,30B, and30cmay be formed on the electrodes30R,30G,30B, and30c.

A plurality of color capsules40R,40G, and40B which may be collectively denoted by40and constitute the first through third subpixels are disposed between the lower substrate10and the upper substrate20. The color capsules40R,40G,40B may be arranged as a single layer. Although the color capsules40have spherical shapes inFIG. 1, the color capsules40may each have a fan-like cross-sectional shape which has a surface whose projection area increases closer to the upper substrate20and decreases closer to the lower substrate10. Alternatively, the color capsules40may each have a rectangular parallelepiped cross-sectional shape.

Each of the plurality of color capsules40stores therein a dielectric fluid41and electrophoretic particles42having at least one color and dispersed in the dielectric fluid41. The dielectric fluid41and the electrophoretic particles42are encapsulated in a capsule shell43. The capsule shell43may be formed by, but is not limited thereto, an encapsulation reaction such as a chemical process such as emulsion polymerization, interfacial polymerization, or in-situ polymerization, a physical process such as co-extrusion or phase separation, or a simple/complex coacervation.

Materials of the capsule shell43formed by using the simple coacervation may include, but are not limited to, a cellulose-based derivative such as gelatin, polyvinyl alcohol, polyvinyl acetate, or carboxymethyl cellulose. Materials of the capsule shell43formed by using the complex coacervation may include, but are not limited to, gelatin, acacia, caragenan, carboxymethyl cellulose, hydrolyzed styrene anhydride copolymer, agar, casein, albumin, and cellulose phthalate. Materials of the capsule shell43formed by using the phase separation may include, but are not limited to, polystyrene, polymethyl methacrylate (PMMA), polyethyl methacrylate, polybutyle methacrylate, ethyl cellulose, and polyvinyl pyridine. Materials of the capsule shell43formed by using the insitu polymerization may include, but are not limited to, polyhydroxyamide, melamine, urea, soluble oligomers, and vinyl monomers such as styrene and methyl methacrylate (MMA). Also, materials of the capsule shell43formed by using the interfacial polymerization may include, but are not limited to, sebacoyl, adipoyl, diamine, polyamine, alcohol, and isocyanate.

Materials of the capsule shell43formed by using the emulsion polymerization may include, but are not limited to, styrene, vinyl acetate, acrylic acid, butyl acrylate, t-butyl acrylate, methyl methacrylate, and methacrylate. Alternatively, the capsule shell43may be formed of water-soluble polymers, water-dispersed polymers, oil-soluble polymers, a thermosetting resin, a thermoplastic resin, or an ultraviolet (UV) or radiation curable resin.

A color of the color capsule shell43may be produced by using dyes, pigments, or a combination of dyes and pigments of a corresponding color included in the capsule shell43. Alternatively, after a transparent capsule shell is formed, a color of the capsule shell43may be produced. Alternatively, a color of the color capsule shell43may be produced by additionally forming on the capsule shell43a coating layer of a corresponding color. A process of producing a color of the color capsule shell43will be explained below.

The capsule shells43of the plurality of color capsules40may have colors corresponding to the first, second, and third subpixels. For example, in order to obtain multi-colors by using a red/green/blue (RGB) color system, the first through third subpixels may be a red pixel, a green pixel, and a blue pixel, respectively. In this case, the capsule shells43of the color capsules40R of the first subpixel are red. Likewise, the capsule shells43of the color capsules40G of the second subpixel and the color capsules40B of the third subpixel may be green and blue, respectively.

Alternatively, the EPD device100may obtain multi-colors by using a cyan/magenta/yellow (CMY) color system. In this case, the capsule shells43of the color capsules40of the first through third subpixels may be cyan, magenta, and yellow, respectively.

The dielectric fluid41encapsulated in the capsule shell43is a fluid having high resistance. The dielectric fluid41may be a single fluid or a mixture of two or more fluids. The dielectric fluid41may be prepared such that a specific gravity of the dielectric fluid41is substantially equal to a specific gravity of the electrophoretic particles42dispersed in the dielectric fluid41.

The dielectric fluid41may be a non-aqueous solution or a non-polar liquid. For example, the dielectric fluid41may be a hydrocarbon-containing solution such as decahydronaphthalene (DECALIN), 5-ethylidene-2-norbornene, fatty acid ester, or paraffin oil, an aromatic hydrocarbon-containing solution such as toluene, xylene, phenylxylyethane, dodecylbenzene, or alkylnaphthalene, or a halogenated solution such as perfluorodecalin, perfluorotoluene, perfluoroxylene, dichlorobenzotrifluoride, 3,4,5-trichlorobenzotrifluoride, chloropentafluro-benzene, dichlorononane, pentachlorobenzene, or tetrachloroethylene. In addition to the electrophoretic particles42, any of various functional additives such as a charge-controlling agent, a cationic or anionic ion surfactant, a metallic soap, a resin material, a metal-based binder, and a stabilizing agent may be added to the dielectric fluid41.

The electrophoretic particles42dispersed in the dielectric fluid41may be positively or negatively charged, and may be formed of solid pigments, dyed particles, or a combination of at least one of the solid pigments and the dyed particles and polymers. For example, the combination of the pigments and the polymers may be obtained by, but is not limited to, coating the pigments on polymer particles or mixing the pigments and the polymers in an appropriate ratio.

The electrophoretic particles42may be light-absorbing electrophoretic particles as shown inFIG. 1. For example, the light-absorbing electrophoretic particles may be black electrophoretic particles such as aniline black, carbon black, or titanium black particles.

Alternatively, the EPD device100may have a rib structure60that defines subpixels. In this case, the color capsules40R,40G, and40B having different colors may be separated from one another by the rib structure60. Alternatively, the rib structure60may be omitted.

Unlike inFIG. 1, the rib structure60may be further formed to define a unit color pixel. When the capsules40are disposed as a single layer, a height of the rib structure60may be substantially equal to a diameter of each of the capsules40. A color of the rib structure60may be, but is not limited to, white, or black to function as a black matrix.

The color capsules40R,40G, and40B of the first through third subpixels may be bonded to the lower substrate20by using an adhesive member80such as an adhesive layer or a binder. Alternatively, the color capsules40R,40G, and40B may be respectively bonded to the first through third subpixels through self-assembly by coating a predetermined receptor compound on each of the first through third subpixels and forming a functional group which may specifically bind to the receptor compound on a surface of the capsule shell43, which will be explained in detail with reference toFIGS. 5 through 7.

The EPD device100may further include a reflective film91that is disposed between the color capsules40and the lower substrate10. Accordingly, when the EPD device100is a reflective display device, the display quality of the EPD device100may be improved. Also, in this case, the EPD device100may further include a front illumination member92that includes a light source92asuch as a light-emitting diode (LED) and a light guide plate92b. Alternatively, when the EPD device100is a transmissive display device, a light source may be further disposed adjacent to the lower substrate10.

A method of driving the EPD device100ofFIG. 1will now be explained. For convenience of explanation, it is assumed that the electrophoretic particles42are black electrophoretic particles which are positively charged, the first through third subpixels constituting the unit color pixel are respectively red, green, and blue subpixels, and the EPD device100is a reflective display device.

When a scan signal is received through the gate electrode50G and a data signal is received through the source electrode50S, a predetermined electric field may be formed between the pixel electrodes30R,30G, and30B and the common electrode30c. For example, a positive potential may be applied to the pixel electrode30R of the first subpixel, a negative potential may be applied to the pixel electrodes30G and30B of the second and third subpixels, and a ground potential may be applied to the common electrode30c. In this case, an electric field directed from the lower substrate10toward the upper substrate20is formed in the first subpixel, and an electric field from the upper substrate20toward the lower substrate10is formed in the second and third subpixels.FIG. 1illustrates a distribution of the black electrophoretic particles42due to the electric fields.

In the red subpixel (that is, in the first subpixel), light i1incident through the light guide plate92bis absorbed by the black electrophoretic particles42. As a result, light reflected by the red subpixel is turned off. However, light i2and light i3incident through the light guide plate92bare respectively reflected as reflected light r2and reflected light r3by the green subpixel (that is, the second subpixel) and the blue subpixel (the third subpixel), and the reflected light r2and the reflected light r3are turned on. In this case, an observer1may observe a color obtained by mixing the reflected light r2which is green light and the reflected light r3which is blue light. Although only the first subpixel which is the red subpixel is turned off inFIG. 1, it will be understood by one of ordinary skill in the art that 8-bit multi-colors may be obtained by turning on/off the first through third subpixels, and when a plurality of pixel electrodes are provided in one subpixel, gradation may be achieved.

FIGS. 2A and 2Bare cross-sectional views illustrating subpixels applicable to the EPD device100ofFIG. 1, according to embodiments of the present invention.

Referring toFIG. 2A, a subpixel includes a pixel electrode31and a common electrode32which face each other. Color capsules40adisposed between the pixel electrode31and the common electrode32may include the capsule shells43having predetermined colors such as red, blue, and green, or cyan, magenta, and yellow, instead of an achromatic color as described inFIG. 1. However, inFIG. 2A, reflective electrophoretic particles42bas well as light-absorbing electrophoretic particles42aare further included in the dielectric fluid41of each of the color capsules40a.

The reflective electrophoretic particles42bmay be white particles and may include, for example, titanium dioxide, antimony trioxide, zinc sulfide, zinc oxide, or calcium carbonate (CaCO3).

In an embodiment, the reflective electrophoretic particles42bmay be electrically neutral. Alternatively, the reflective electrophoretic particles42bmay have polarity opposite to polarity of the light-absorbing electrophoretic particles42b. In this case, under the same electric field, the reflective electrophoretic particles42bshow opposite mobilities to those of the light-absorbing electrophoretic particles42b.

FIG. 2Aillustrate a distribution of the light-absorbing electrophoretic particles42aand the reflective electrophoretic particles42bwhen the light-absorbing electrophoretic particles42ahave positive polarity and the reflective electrophoretic particles42bhave negative polarity and an electric field directed from the common electrode32toward the pixel electrode31is formed. In the subpixel ofFIG. 2A, incident light i is reflected as reflected light r by the reflective electrophoretic particles42bin the color capsules40aand the reflected light r is turned on, and the observer1may observe light of a wavelength range corresponding to colors of the color shells43. When polarity of the pixel electrode31and the common electrode32are reversed, the reflected light r may be turned off. InFIG. 2A, since not only the light-absorbing electrophoretic particles42aand the reflective electrophoretic particles42bhelp light to be turned on/off, the contrast of displayed information may be improved.

Referring toFIG. 2B, color capsules40bmay include a light-absorbing dielectric fluid41cin which black dyes and/or pigments are dispersed, instead of the light-absorbing electrophoretic particles42a. A subpixel ofFIG. 2Bmay further include the reflective electrophoretic particles42bto switch the reflected light r.

FIG. 2Billustrates a distribution of the reflective electrophoretic particles42bwhen the reflective electrophoretic particles42bhave negative polarity and an electric field directed from the common electrode32toward the pixel electrode31is formed. Like inFIG. 2A, contrast may be improved due to the light-absorbing dielectric fluid41cand the reflective electrophoretic particles42b.

FIGS. 3A and 3Bare top views illustrating unit color pixels200A and200B according to embodiments of the present invention.

A unit color pixel may include two or more subpixels in which a plurality of color capsules are arranged in a two-dimensional (2D) manner.FIGS. 3A and 3Billustrate that three types of color capsules40A,40B, and40C including capsule shells43a,43b, and43cof different colors are arranged in a 2D manner.

The subpixels are defined in each of the unit color pixels200A and200B divided by a virtual line VL that is indicated by a dash-dotted line. The subpixels may have the same size or different sizes in consideration of display quality such as color saturation and contrast. Also, the subpixels may be separated by the rib structure60that is disposed at a position of the virtual line VL as described above with reference toFIG. 1.

Although the subpixels have rectangular parallelepiped shapes inFIGS. 3A and 3B, the present embodiment is not limited thereto. For example, the subpixels may have spherical shapes, oval shapes, or arbitrary polygonal shapes such as triangular shapes or pentagonal shapes. Alternatively, the subpixels may have stripe or meander shapes continuously formed over an adjacent unit color pixel. Likewise, the unit color pixels200A and200B may have spherical shapes, oval shapes, polygonal shapes such as triangular shapes or pentagonal shapes, stripe shapes, or meander shapes in which the subpixels are arranged in a 2D manner,

The color capsules40A,40B, and40C arranged in each subpixel may be red color capsules, green color capsules, and blue color capsules. Alternatively, the plurality of color capsules40A,40B, and40C may be, for example, cyan color capsules, magenta color capsules, and yellow color capsules.

At least one type of electrophoretic particles for switching light, that is, at least one type of particles of the light-absorbing electrophoretic particles42aand the reflective electrophoretic particles42b, are dispersed in the dielectric fluid41of each of the color capsules40A,40B, and40C as described above. Also, as described above with reference toFIG. 2B, each of the color capsules40A,40B, and40/cmay include reflective electrophoretic particles and a dielectric fluid in which any one or all of light-absorbing pigments and dyes are dispersed instead of a transparent dielectric fluid.

Referring toFIG. 3B, the unit color pixel200B may further include a subpixel including transparent capsules40D including a transparent shell43d, as well as subpixels including the plurality of color capsules40A,40B, and40C. Particles in the transparent shell43dmay include reflective electrophoretic particles or light-absorbing electrophoretic particles, or both as described above. Due to a light-switching operation of the transparent capsules40D, an independent subpixel showing an achromatic color may be provided, and thus achromatic color rendition of the unit color pixel200B may be further improved.

Alternatively, particles in the transparent shell43dmay be chromatic electrophoretic particles, instead of achromatic electrophoretic particles. The subpixel including the chromatic electrophoretic particles may complement or replace the subpixels including the color capsules10A,40B, and40C.

Method of Fabricating Multi-Color EPD Device

FIG. 4is a flowchart illustrating a method of fabricating an EPD device which is a multi-color EPD device, according to an embodiment of the present invention.

Referring toFIG. 4, in operation S100, a plurality of color capsules including capsule shells having colors are formed. For example, a color of a color capsule shell may produced by dyes or pigments of a corresponding color included in the capsule shell or by a combination of the dyes and pigments.

To this end, a first phase inner fluid including a dielectric fluid in which at least one type of electrophoretic particles are dispersed is prepared. Also, a second phase encapsulated fluid in which dyes and pigments for producing a corresponding color of the capsule shell or a combination of the dyes and the pigments are dispersed is prepared. The second phase is different from the phase. Next, a predetermined encapsulation reaction is induced between the encapsulated fluid and the inner fluid, to form a plurality of color capsules in which a part of the first phase fluid and some of the at least one type of electrophoretic particles are encapsulated. The color capsules include color shells whose colors are produced by the dyes or pigments dispersed in the second phase encapsulated fluid.

Alternatively, a transparent capsule shell may be first formed, and then a color of the transparent capsule shell may be produced to have a corresponding color. For example, a first phase inner fluid including a dielectric fluid in which at least one type electrophoretic particles are dispersed is prepared. Also, a second phase encapsulated fluid in which a compound having a functional group that may react with dyes of a color is included. The second phase is different from the first phase. Next, a predetermined encapsulation reaction is induced between the encapsulated fluid and the inner fluid, to form a plurality of capsules in which a part of the inner fluid and some of the at least one type of electrophoretic particles are encapsulated. The functional group is exposed on surfaces of the capsules. Next, the dyes react with the functional group exposed on the surfaces of the capsule shells to produce colors of the capsule shells, thereby completely fabricating the plurality of color capsules.

Alternatively, a coloring coating layer having pigments of the corresponding color is formed by using drying or wet coating on outer surfaces of capsules including transparent capsule shells, thereby completely fabricating the plurality of color capsules.

Referring back toFIG. 4, once the plurality of color capsules are completed, in operation S200, the plurality of color capsules having the corresponding color are arranged to define a predetermined subpixel of a color pixel on a substrate. When subpixels of different colors are required in a unit color pixel, a process of arranging color capsules having a corresponding color for each subpixel may be repeatedly performed as will be described below.

FIGS. 5A through 5Eare cross-sectional views for explaining a method of arranging color capsules in a plurality of subpixel areas, according to an embodiment of the present invention. For convenience of explanation, although different types of subpixel areas are shown in parallel as shown inFIG. 1, the subpixel areas may have various other 2D patterns such as circular, oval, polygonal, and meander patterns as described above.

Referring toFIG. 5A, the substrate10is provided. The substrate10may be, for example, a lower substrate on which a pixel electrode (not shown) is formed, or an appropriate support substrate as shown inFIG. 8. The substrate10may include two or more subpixel areas. Also, the rib structure60for defining subpixel areas, a unit color pixel, or all of the subpixel areas and the unit color pixel may be formed on the substrate10.

The rib structure60may be, for example, a pattern whose mechanical strength is high such as a silicon oxide formed by using photolithography and etching or a patterned photoresist formed by using photolithography. When color capsules are arranged as a single layer, a height of the rib structure60may be substantially equal to a height of each of color capsules.

Referring toFIGS. 5B and 5C, an adhesive layer81is coated in each subpixel area of the substrate10to which color capsules are to be bonded. As shown inFIG. 5B, the adhesive layer81may be coated on all subpixels before a mask pattern M1is formed. As shown inFIG. 5C, the adhesive layer81may be selectively coated only in a subpixel area exposed by an opening h1after a mask pattern M2is formed, and may be coated to another subpixel area while being alternately performed with a step of charging the color capsules as will be described below. The adhesive layer81may be formed of, but is not limited to, any one of acrylate copolymer, ethylenevinylacetate copolymer, polycarbonate, and styrene copolymer, or a combination thereof.

A process of bonding the color capsules and the substrate10will be explained with reference toFIG. 5C. Referring back toFIG. 5C, the mask pattern M1having the opening h1through which a predetermined subpixel area, for example, a first subpixel area, in which a plurality of color capsules are to be filled is exposed is formed over the substrate10on which the adhesive layer81is coated.

Next, as shown inFIG. 5D, the color capsules40R having a predetermined color, for example, a red color, are filled in the first subpixel area exposed through the opening h1of the mask pattern M1. The color capsules40R may be filled in the first subpixel area by using a coating unit such as a doctor blade. In order to increase mobilities of the color capsules40R, an ultrasonic oscillation may be applied to the substrate10and/or the color capsules40R.

Next, the adhesive layer81and the color capsules40R are boned to each other. A process of bonding the adhesive layer81and the color capsules40R may be performed by using chemical energy such as crosslinking using UV radiation, or thermal or mechanical pressure.

Alternatively, in order to bond the capsules40R to the substrate10, a binder80(seeFIG. 8) may be used as an adhesive member. For example, the binder80and the capsules40R are dispersed in a fluid, and the fluid is coated on the substrate10by using, for example, a doctor blade and/or ultrasound waves. As a result, the fluid including the capsules40R and the binder80is filled in the first subpixel area. Next, predetermined thermal, mechanical, or chemical energy is applied to the binder80coated on the substrate10to cure the binder80, thereby bonding the capsules40and the substrate10. The binder80may include, for example, an ultraviolet curable monomer mixture, a photo-initiator, or a light amplifier.

Referring toFIG. 5E, the mask pattern M2having an opening h2through which a different subpixel area, for example, a second subpixel area, is exposed is formed on a resultant structure. Next, color capsules having a predetermined color, for example, the color capsules40G having green color shells, are filled in the second subpixel area exposed through which the opening h2of the mask pattern M2. Next, the color capsules40G and the substrate10are bonded by using a bonding member such as the adhesive layer81or a binder. Likewise, a process of forming a mask pattern and a process of filling blue color capsules are repeatedly performed for a third subpixel area, thereby completing a color pixel array including unit color pixels.

FIG. 6is a cross-sectional area for explaining a process of arranging color capsules on a plurality of subpixels, according to another embodiment of the present invention.

InFIG. 6, color capsules are disposed on a subpixel through self-assembly. To this end, different types of receptor compounds and a compound having a functional group that may perform self-assembly by specifically binding to each of the different types of receptor compounds are selected. Examples of a combination of the receptor compound and the functional group may include an isocyanate group/amine group, isocyanate group/hydroxyl group, epoxy/carboxylic acid group, acid/base, and cationic group/anionic group. Primary binding occurs due to a chemical reaction when the receptor compound and the functional group contact each other, and self-assembly is completed due to an acid/base reaction and an ion interaction.

In order to arrange color capsules through self-assembly, different types of receptor compound pattern layers82a,82b, and82cwhich may specifically bind are coated in corresponding subpixel areas on the substrate10. Next, the color capsules40R,40G, and40B including color capsule shells having functional groups43x,43y, and43zwhich specifically bind respectively to receptor compounds are coated on the substrate10. A process of coating the color capsules40R,40G, and40B may be performed by using a coating process using dry, wet, or spray coating. In order to increase mobilities of the color capsules40R,40G, and40B, an ultrasonic oscillation may be applied to a fluid including the color capsules40R,40G, and40B, or the substrate10.

The color capsules40R,40G, and40B having the functional groups43x,43y, and43zmove over the substrate10and selectively bind respectively to the receptor compound pattern layers82a,82b, and82c, thereby completing a color pixel array. Due to self-assembly, a patterning process for forming a mask pattern which is repeatedly performed may be omitted, unlike inFIGS. 5A through 5E.

FIG. 7is a cross-sectional view for explaining a process of arranging color capsules on a plurality of subpixels, according to another embodiment of the present invention.

Referring toFIG. 7, a printing device300including nozzles300a,300b, and300cthrough which color capsules having different types of colors may be sprayed to desired positions is used. The printing device300sequentially moves in a direction indicated by an arrow350, and the color capsules40R,40G, and40B are continuously arranged on the substrate10. When the printing device300is used, a process of forming a mask pattern which is repeatedly performed may be omitted, like inFIG. 6.

InFIGS. 5A through 7, it will be understood that an adhesive layer, a binder, and self-assembly may be compatibly or a combination of the adhesive layer, the binder, and the self-assembly may be used. Also, the term ‘coating’ does not limit the scope of the present invention, and coating may be used to have the same meaning as printing. For example, a coating process includes any type of printing and coating processes such as patch dye coating; slot or extrusion coating; slide or cascade coating; curtain coating; roll coating; gravure coating; dip coating; spray coating; meniscus coating; spin coating; brush coating; air knife coating; silk screen printing; electrostatic printing; and thermal printing.

As described above, after corresponding color capsules are arranged in all subpixel areas, as shown inFIG. 1, the upper substrate20on which the common electrode30cis formed is fixedly attached to the lower substrate10, thereby completing a multi-color EPD device.

Image Sheet and Method of Fabricating the Same

FIG. 8is a cross-sectional view illustrating an image sheet300according to an embodiment of the present invention. Although color capsules are disposed on a lower substrate on which pixel electrodes are formed inFIGS. 5 through 7, the color capsules may be disposed on an upper substrate to obtain a resultant structure, and the resultant structure may be overturned and may be coupled to the lower substrate on which the pixel electrodes for driving the color capsules are formed, thereby obtaining an EPD device.

The image sheet300ofFIG. 8refers to a layer including color capsules which are light converting members used by being coupled to a lower substrate on which a driving element is formed. The image sheet300includes a support substrate11, and two or more types of color capsules40R,40G, and40B arranged on the support substrate11. An arrangement of the plurality of color capsules40R,40G, and40B and a process of producing a color have been described with reference toFIGS. 5B through 5E. The color capsules40R,40G, and40B may be bonded to the support substrate11by using the binder80. Alternatively, the color capsules40R,40G, and40B may be bonded to the support substrate11by using the adhesive layer81(seeFIG. 1). The color capsules40R,40G, and40B may be separated from one another by the rib structure60formed on the support substrate11.

The support substrate11may be a surface exposed to an observer, like the upper substrate10of the EPD device ofFIG. 1. In this case, the support substrate11may be formed of a transparent material as described above. Also, a transparent conductive layer12may be formed between the support substrate11and the color capsules40R,40G, and40B. The transparent conductive layer12may be used as a common electrode30c(seeFIG. 1) of the EPD device. In this case, a protective layer13for protecting the transparent conductive layer12may be further formed on the transparent conductive layer12as described above with reference toFIG. 1.

An adhesive complex layer including an adhesive layer14and a release layer15disposed on the adhesive layer14may be further formed on the color capsules40R,40G, and40B. In order to stack the image sheet300on a lower substrate on which pixel electrodes are formed, the release layer15may be removed, and the lower substrate and the image sheet300may be coupled to each other by using the adhesive layer14that is exposed. An intermediate layer having a predetermined wiring structure having a via-hole and a wiring pattern connected through the via-hole may be further disposed between the image sheet300and the lower substrate.

Although a counter electrode structure for vertically driving electrophoretic particles has been described in the above embodiments, the present invention is not limited thereto, and a well-known in-plane electrode structure may be used within the scope of the present invention. Although color capsules are used as a member that may replace a color filter, it is obvious that a color filter may be used along with the color capsules in order to improve color rendition.

INDUSTRIAL APPLICABILITY

Since a multi-color display device according to embodiments of the present invention switches light by using an electrophoretic layer including a plurality of color capsules, the multi-color display device may be realized without a color filter. Thus, the multi-color display device may have high color saturation and high contrast.

Also, an image sheet according to embodiments of the present invention may implement multi-colors without light loss due to a color filter.