Olefin polymerization catalyst subjected to preliminary polymerization treatment

An olefin polymerization catalyst component subjected to successive preliminary polymerization treatment using each of a straight chain alpha-olefin having 2 to 5 carbon atoms and 3-methyl-1-butene; an olefin polymerization catalyst using the olefin polymerization catalyst component; a process for polymerizing olefin(s) which comprises polymerizing or copolymerizing olefin(s) in the presence of the olefin polymerization catalyst; and a film and an injection-molded article of polypropylene which is prepared by the process are also provided.

This invention relates to an olefin polymerization catalyst, a catalyst 
component thereof, and a process for polymerizing olefins using the 
catalyst, and a film or injection-molded article from the obtained 
polyolefin. More specifically, this invention relates to an olefin 
polymerization catalyst capable of giving in a high yield a polyolefin 
which is excellent in a see-through property and transparency in a form of 
a molded article, and at the same time has good properties, a catalyst 
component thereof and a process for preparing such a polyolefin by 
polymerizing olefin(s) in the presence of the catalyst, and a film or 
injection-molded article from the polyolefin. 
Many proposals have already been made on the production of a solid titanium 
catalyst component containing as indispensable ingredients, magnesium, 
titanium, halogen and an electron donor, and it is known that by using 
such a solid titanium catalyst component in the polymerization of an 
alpha-olefin having at least 3 carbon atoms, a polymer having high 
stereoregularity can be prepared in high yield. 
Further, it is known in preparation of a propylene series polymer using an 
olefin polymerization catalyst component consisting of such a solid 
titanium catalyst component as above-mentioned and an organoaluminum 
compound catalyst component that a propylene series polymer having an 
excellent see-through property can be obtained by preliminarily 
polymerizing 3-methyl-1-butene on the olefin polymerization catalyst 
component. It is conjectured that when 3-methyl-1-butene is preliminarily 
polymerized on the olefin polymerization catalyst component, 
poly(3-methyl-1-butene) acts as a polymer-nucleating agent in the 
propylene series polymer to miniaturize the spherulite size of 
polypropylene and thus the see-through property of the obtained propylene 
series polymer is enhanced. 
However, there has been a problem that when propylene or propylene and 
another alpha-olefin are subjected to main polymerization after 
3-methyl-1-butene is preliminarily polymerized using such an olefin 
polymerization catalyst component as above-mentioned, a part of particles 
of the obtained propylene series polymer is sometimes destroyed and 
finally powdery polymer is formed by this destruction. 
Further, there has been a problem that a propylene series polymer obtained 
as above-mentioned has a small apparent bulk density due to the ununiform 
particle size. 
An object of the invention is to provide an olefin polymerization catalyst 
giving a polyolefin which is excellent in a see-through property and has 
good particle properties. 
Another object of the invention is to provide as an ingredient of the above 
catalyst of the invention a catalyst component which contains Mg, Ti, 
halogen and Al, and is subjected to successive preliminary polymerization 
using 3-methyl-1-butene and a straight chain alpha-olefin having 2 to 5 
carbon atoms. 
Still another object of the invention is to provide a process of preparing 
the above catalyst component of the invention. 
A still further object of the invention is to provide a process of 
preparing in a high yield a polyolefin having an excellent see-through 
property and transparency in molded articles such as film and 
injection-molded article, and having good particle properties and moreover 
a large apparent density by polymerizing or copolymerizing olefin(s) in 
the presence of the above catalyst of the invention. 
A still further object of the invention is to provide a film and an 
injection-molded article from the polyolefin having an excellent 
see-through property and transparency and good particle properties. 
Still other objects and advantages of the invention will be clarified from 
the following description. 
According to the invention, the above objects and advantages can be 
attained by an olefin polymerization catalyst subjected to preliminary 
polymerization treatment, which is formed by subjecting an olefin 
polymerization catalyst component (X), which is formed from 
(A) a solid titanium catalyst component containing magnesium, titanium, 
halogen and an electron donor as essential ingredients, 
(B) an organoaluminum compound catalyst component, and when desired, 
(C) an electron donor, to successive preliminary polymerization treatment 
using each of a straight chain alpha-olefin having 2 to 5 carbon atoms and 
3-methyl-1-butene, and contains a polymerization unit of the straight 
chain alpha-olefin having 2 to 5 carbon atoms of 0.1 to 300 g and a 
polymerization unit of 3-methyl-1-butene of 0.1 to 100 g, per g of the 
solid part of the polymerization catalyst component (X), respectively. 
According to the invention, the above olefin polymerization catalyst 
component can be formed either by 
(1) first preliminarily polymerizing a straight chain alpha-olefin having 2 
to 5 carbon atoms in an amount of 0.1 to 300 g per g of the solid part of 
the polymerization catalyst component (X), using the olefin catalyst 
component (X) and then preliminarily polymerizing thereon 
3-methyl-1-butene in an amount of 0.1 to 100 g per g of the solid part of 
the polymerization catalyst component (X), or by 
(2) first preliminarily polymerizing 3-methyl-1-butene in an amount of 0.1 
to 100 g per g of the solid part of the polymerization catalyst component 
(X), using the solid part of the polymerization catalyst component (X) and 
then preliminarily polymerizing thereon a straight chain alpha-olefin 
having 2 to 5 carbon atoms in an amount of 0.1 to 300 g per g of the solid 
part of the polymerization catalyst component (X). 
It should be understood in the invention that the term "polymerization" is 
sometimes used in a sense including copolymerization besides 
homopolymerization, and the term "polymer" is sometimes used in a sense 
including copolymer besides homopolymer. 
An olefin polymerization catalyst component in the invention can be formed 
by subjecting an olefin polymerization catalyst component (X), which is 
formed from 
(A) a solid titanium catalyst component containing magnesium, titanium, 
halogen and an electron donor as essential ingredients, 
(B) an organoaluminum compound catalyst component, and when desired, 
(C) an electron donor, to the successive preliminary polymerization 
treatment of the above (1) or (2) using a straight chain alpha-olefin 
having 2 to 5 carbon atoms and 3-methyl-1-butene. 
The olefin polymerization catalyst component of the invention contains the 
polymerization unit of the straight chain alpha-olefin having 2 to 5 
carbon atoms in an amount of 0.1 to 300 g, preferably 0.1 to 100 g, more 
preferably 1 to 50 g, per g of the solid part of the polymerization 
catalyst component (X), and contains the polymerization unit of 
3-methyl-1-butene in an amount of 0.1 to 100 g, preferably 1 to 50 g, more 
preferably 2 to 50 g, per g of the solid part of the polymerization 
catalyst component (X). 
The olefin polymerization catalyst of the invention is formed from (I) the 
above olefin polymerization catalyst component of the invention 
(hereinafter referred also to as preliminary polymerization catalyst 
component), (II) an organoaluminum compound when desired, and (III) an 
electron donor when desired. 
Respective components composing the above preliminary polymerization 
catalyst component and olefin polymerization catalyst are described below. 
As already described, the preliminary polymerization catalyst component can 
be prepared by preliminary polymerizing a certain olefin using an olefin 
polymerization catalyst component (X) which is formed from a solid 
titanium catalyst component (A), an organoaluminum compound catalyst 
component (B) and, when desired, an electron donor (C). 
The solid titanium catalyst component (A) used in the invention is a 
catalyst component of high activity which contains magnesium, titanium, 
halogen and an electron donor as indispensable ingredients. 
Such a solid titanium catalyst component (A) can be prepared by making a 
magnesium compound, a titanium compound and an electron donor, 
respectively as mentioned below into contact. 
As such titanium compounds may be mentioned, for example, tetravalent 
titanium compounds represented by Ti(OR).sub.g X.sub.4-g wherein R 
represents a hydrocarbon group, X represents a halogen atom, and 
0.ltoreq.g.ltoreq.4. Specific examples of the titanium compound include 
titanium tetrahalides such as TiCl.sub.4, TiBr.sub.4 and TiI.sub.4 ; 
alkoxytitanium trihalides such as Ti(OCH.sub.3)Cl.sub.3, Ti(OC.sub.2 
H.sub.5)Cl.sub.3, Ti(On--C.sub.4 H.sub.()Cl.sub.3, Ti(OC.sub.2 
H.sub.5)Br.sub.3 and Ti(O iso--C.sub.4 H.sub.9)Br.sub.3 ; dialkoxytitanium 
dihalides such as Ti(OCH.sub.3).sub.2 Cl.sub.2, Ti(OC.sub.2 H.sub.5).sub.2 
Cl.sub.2, Ti(O n--C.sub.4 H.sub.9).sub.2 Cl.sub.2 and Ti(OC.sub.2 
H.sub.5).sub.2 Br.sub.2 ; trialkoxytitanium monohalides such as 
Ti(OCH.sub.3).sub.3 Cl, Ti(OC.sub.2 H.sub.5).sub.3 Cl, Ti(O n--C.sub.4 
H.sub.9).sub.3 Cl and Ti(OC.sub.2 H.sub.5).sub.3 Br; and 
tetraalkoxytitanium such as Ti(OCH3)4, Ti(OC.sub.2 H.sub.5).sub.4, Ti(O 
n--C.sub.4 H.sub.9).sub.4, Ti(O iso--C.sub.4 H.sub.9).sub.4 and Ti(O 
2-ethylhexyl).sub.4. 
Among these are preferably used the halogen-containing titanium compounds, 
particularly titanium tetrahalide, more particularly titanium 
tetrachloride. These titanium compounds may be used singly or in a 
combination of two or more. They may be used as dilutions in hydrocarbon 
compounds or halogenated hydrocarbons. 
As the magnesium compounds, any of the magnesium compounds having 
reducibility and magnesium compounds having no reducibility can be used. 
The magnesium compounds used in the preparation of the solid titanium 
catalyst component may be, for example, a magnesium compound having 
reducibility and a magnesium having no reducibility. 
The magnesium compound having reducibility may be, for example, a magnesium 
compound having a magnesium-carbon bond or a magnesium-hydrogen bond. 
Specific examples of the magnesium compound having reducibility include 
dimethyl magnesium, diethyl magnesium, dipropyl magnesium, dibutyl 
magnesium, diamyl magnesium, dihexyl magnesium, didecyl magnesium, decyl 
butyl magnesium, ethyl magnesium chloride, propyl magnesium chloride, 
butyl magnesium chloride, hexyl magnesium chloride, amyl magnesium 
chloride, butyl ethoxy magnesium, ethyl butyl magnesium and butyl 
magnesium halides. These magnesium compounds may be used as such or as a 
complex with an organoaluminum compound to be later described. These 
magnsium compound may be liquid or solid. 
Specific examples of the magnsium compound having no reducibility include 
magensium halides such as magnesium chloride, magnesium bromide, magnesium 
iodide and magnesium fluoride; alkoxy magnesium halides such as methoxy 
magnesium chloride, ethoxy magnesium chloride, isopropoxy magnesium 
chloride, butoxy magnesium chloride and octoxy magnesium chloride; aryloxy 
magnesium halides such as phenoxy magnesium chloride and methylphenoxy 
magnesium chloride; alkoxy magnesiums such as ethoxy magnesium, isopropoxy 
magnesium, butoxy magnesium, n-octoxy magnesium and 2-ethylhexoxy 
magnesium; aryloxy magnesiums such as phenoxy magnesium and 
dimethylphenoxy magnesium; and carboxylic acid salts of magnesium such as 
magnesium laurate and magnesium stearate. 
The magnesium compound having no reducibility may be derived from the 
magnesium compound having reducibility. This derivation may be effected, 
for example, by contacting the magnesium compound having reducibility with 
such a compound as a polysiloxane compound, a halogen-containing silane 
compound, a halogen-containing aluminum compound, an ester or an alcohol. 
Further, such a magnesium compound as above-mentioned may be used as a 
complex compound or double compound with another metal, or a mixture with 
another metal compound, or a mixture of these compounds. 
In the present invention, the magnesium compounds having no reducibility 
are preferred, and halogen-containing magnesium compounds are especially 
preferred. Above all, magnesium chloride, alkoxy magnesium chlorides and 
aryloxy magnesium chlorides are particularly advantageously used. 
Further, as the electron donor, polycarboxylic acid esters may preferably 
be used, and specifically compounds having the skeletons represented by 
the following formulae are mentioned: 
##STR1## 
wherein R.sup.1 represents a substituted or unsubstituted hydrocarbon 
group, and R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom or a 
substituted or unsubstituted hydrocarbon group, R.sup.3 and R.sup.4 
represent a hydrogen atom or a substituted or unsubstituted hydrocarbon 
group, represents a single bond or a double bond, at least one of 
R.sup.3 and R.sup.4 is preferably a substituted or unsubstituted 
hydrocarbon group, and R.sup.3 and R.sup.4 may be linked to each other to 
form a cyclic structure. 
Examples of the substituted hydrocarbon groups for R.sup.1 through R.sup.5 
are hydrocarbon groups having substituents containing hetero atoms such as 
N, O and S, for example, --C--O--C--, --COOR, --COOH, --OH, --SO.sub.3 H, 
--C--N--C--and --NH.sub.2. 
Among them are preferred diesters of dicarboxylic acids wherein at least 
one of R.sup.1 and R.sup.2 is an alkyl group having at least two carbon 
atoms. 
Specific examples of polycarboxylic acid esters include aliphatic 
polycarboxylic acid esters such as diethyl succinate, dibutyl succinate, 
diethyl methylsuccinate, diisobutyl alpha-methylglutarate, dibutyl 
malonate, diethyl methylmalonate, diethyl ethylmalonate, diethyl 
isopropylmalonate, diethyl butylmalonate, diethyl phenylmalonate, diethyl 
diethylmalonate, diethyl allylmalonate, diethyl diisobutylmalonate, 
diethyl di-n-butylmalonate, dimethyl maleate, monooctyl maleate, 
diisooctyl maleate, diisobutyl maleate, diisobutyl butylmaleate, diethyl 
butylmaleate, diisopropyl beta-methylglutarate, diallyl ethylsuccinate, 
di-2-ethylhexyl fumarate, diethyl itaconate, diisobutyl itaconate, 
diisooctyl citraconate and dimethyl citraconate; alicyclic polycarboxylic 
acid esters such as diethyl 1,2-cyclohexanecarboxylate, diisobutyl 
1,2-cyclohexanecarboxylate, diethyl tetrahydrophthalate and nadic acid 
diethyl ester; aromatic polycarboxylic acid esters such as monoethyl 
phthalate, dimethyl phthalate, methylethyl phthalate, monoisobutyl 
phthalate, n-butyl phthalate, diethyl phthalate, ethylisobutyl phthalate, 
ethyl-n-butyl phthalate, di-n-propyl phthalate, diisopropyl phthalate, 
di-n-butyl phthalate, diisobutyl phthalate, di-n-heptyl phthlate, 
di-2-ethylhexyl phthalate, didecyl phthalate, benzylbutyl phthalate, 
diphenyl phthalate, diethyl naphthlenedicarboxylate, dibutyl 
naphthlenedicarboxylate, triethyl trimellitate and dibutyl trimellitate; 
and heterocyclic polycarboxylic acid esters such as 3,4-furanedicarboxylic 
acid esters. 
Other examples of polycarboxylic acid esters include esters of long-chain 
dicarboxylic acids such as diethyl adipate, diisobutyl adipate, 
diisopropyl sebacate, di-n-butyl sebacate, di-n-octyl sebacate and 
di-2-ethylhexyl sebacate. 
Among these polycarboxylic acid esters, compounds having the skeletons 
given by the above general formulae are preferred. More preferred are 
esters formed between phthalic acid, maleic acid or substituted malonic 
acid and alcohols having at least 2 carbon atoms, diesters formed between 
phthalic acid and alcohols having at least 2 carbon atoms are especially 
preferred. 
These polycarboxylic acid esters may not always be in the form of 
polycarboxylic acid esters at the starting stage, and may optionally be 
formed in the preparation stage of the solid titanium catalyst components 
(A) from compounds capable of being converted into these polycarboxylic 
acid esters. 
As electron donors other than polycarboxylic acids which can be used in 
preparation of solid titanium catalysts (A) are usable hereinafter 
described alcohols, amines, amides, ethers, ketones, nitriles, phosphines, 
stibines, arsins, phosphoryl amides, esters, thioethers, thioesters, acid 
anhydrides, acid halides, aldehydes, alcoholates, organosilicon compounds 
such as alkoxy(or aryloxy)silanes, organic acids, amides and salts of 
metals of groups I to IV of the periodic table, etc. 
In the present invention, the solid titanium catalyst component (A) may be 
produced by contacting the above magnesium compound (or metallic 
magnesium), the electron donor and the titanium compound. Known methods 
used to prepare a highly active titanium catalyst component from a 
magnesium compound, a titanium compound and an electron donor may be 
adopted in preparation of the solid titanium catalyst component (A). The 
above compounds may be contacted in the presence of another reaction agent 
such as silicon, phosphorus or aluminum. 
(1) A method wherein either a magnesium compound and a titanium compound, 
or a titanium compound and a complex compound of a magnesium compound with 
an electron donor are reacted in a liquid phase. This reaction may be 
carried out in the presence of a pulverizing agent or the like. Compounds 
which are solid may be pulverized before the reaction. Further, each 
ingredient may preliminarily be treated before the reaction with an 
electron donor and/or a reaction acid such as an organoaluminum compound 
or halogen-containing silicon compound. The above electron donor is used 
at least once in this method. 
(2) A method wherein a liquid magnesium compound having no reducibility and 
a liquid titanium compound are reacted in the presence of the electron 
donor to deposit a solid titanium composite. 
(3) A method wherein the reaction product obtained in (2) is further 
reacted with the titanium compound. 
(4) A method wherein the reaction product obtained in (1) or (2) is further 
reacted with the electron donor and the titanium compound. 
(5) A method wherein the magnesium compound or a complex of the magnesium 
compound and the electron donor is pulverized magnesium compound and the 
electron donor is pulverized in the presence of the titanium compound, and 
the resulting solid product is treated with a halogen, a halogen compound 
or an aromatic hydrocarbon. In this method, the magnesium compound or the 
complex of it with the electron donor may also be pulverized in the 
presence of a pulverizing agent, etc. Alternatively, the magnesium 
compound or the complex of the magnesium compound and the electron donor 
is pulverized in the presence of the titanium compound, preliminarily 
treated with a reaction aid and thereafter, treated with halogen, etc. The 
reaction aid may be an organoaluminum compound or a halogen-containing 
silicon compound. The electron donor is at least once used in this method. 
(6) A method wherein the product obtained in (1) to (4) is treated with a 
halogen, a halogen compound or an aromatic hydrocarbon. 
(7) A method wherein a product obtained by contacting a metal oxide, 
dihydrocarbyl magnesium and a halogen-containing alcohol is contacted with 
the electron donor and the titanium compound. 
(8) A method wherein a magnesium compound such as a magnesium salt of an 
organic acid, an alkoxy magnesium or an aryloxy magnesium is reacted with 
the electron donor, the titanium compound and/or a halogen-containing 
hydrocarbon. 
(9) A method wherein the catalyst component in a hydrocarbon solution at 
least containing the magnesium compound, and an alkoxy titanium and/or an 
electron donor such as an alcohol or ether is reacted with the titanium 
compound and/or a halogen-containing compound such as a halogen-containing 
silicon compound, in any one of steps of this method such an electron 
donor as above-mentioned represented by phthalic diesters being made to 
coexist. 
Among the methods (1) to (9) cited above for the preparation of the solid 
titanium catalyst component (A), the method in which the liquid titanium 
halide is used at the time of catalyst preparation, and the method in 
which the halogenated hydrocarbon is used after, or during, the use of the 
titanium compound are preferred. 
The amounts of the ingredients used in preparing the solid titanium 
catalyst component (A) may vary depending upon the method of preparation. 
For example, about 0.01 to 5 moles, preferably 0.05 to 2 moles, of the 
electron donor and about 0.01 to 500 moles, preferably about 0.05 to 300 
moles, of the titanium compound are used per mole of the magnesium 
compound. 
The solid titanium catalyst component (A) so obtained contains magnesium, 
titanium, halogen and the electron donor as essential ingredients. 
In the solid titanium catalyst component (A), the atomic ratio of 
halogen/titanium is about 4 to 200, preferably about 5 to 100; the 
electron donor/titanium mole ratio is about 0.1 to 10, preferably about 
0.2 to 6; and the magnesium/titanium atomic ratio is about 1 to 100, 
preferably about 2 to 50. 
The resulting solid titanium catalyst component (A) contains a magnesium 
halide of a smaller crystal size than commercial magnesium halides and 
usually has a specific surface area of at least about 50 m.sup.2 /g, 
preferably about 60 to 1,000 m.sup.2 /g, more preferably about 100 to 800 
m.sup.2 /g. Since, the above ingredients are unified to form an integral 
structure of the solid titanium catalyst component (A), the composition of 
the solid titanium catalyst component (A) does not substantially change by 
washing with hexane. 
The solid titanium catalyst component (A) may be used alone. If desired, it 
can be used after being diluted with an inorganic or organic compound such 
as a silicon compound, an aluminum compound or a polyolefin. When such a 
diluent is used, the catalyst component (A) show high catalystic activity 
even when it has a lower specific surface than that described above. 
Methods of preparing the highly active catalyst component, which can be 
used in this invention, are described in Japanese Laid-Open Patent 
Publications Nos. 108385/1975, 126590/1975, 20297/1976, 28189/1976, 
64586/1976, 92885/1976, 136625/1976, 87489/1977, 100596/1977, 147688/1977, 
104593/1977, 2580/1978, 40093/1978, 40094/1978, 43094/1978, 135102/1980, 
135103/1980, 152710/1980, 811/1981, 11908/1981, 18606/1981, 83006/1983, 
138705/1977, 138706/1983, 138707/1983, 138708/1983, 138709/1983, 
138710/1983, 138715/1983, 23404/1985, 21109/1986, 37802/1986 and 
37803/1986. 
Compounds having at least one aluminum-carbon bond in the molecule can be 
used as the organoaluminum compound as catalyst component (B). Examples 
are compounds of the following general formulae (i) and (ii). 
(i) Organoaluminum compounds of the general formula 
EQU R.sub.m.sup.7 Al(OR.sup.8).sub.n H.sub.p X.sub.q.sup.1 
In the general formula, R.sup.7 and R.sup.8 may be identical or different, 
and each represents a hydrocarbon group usually having 1 to 15 carbon 
atoms, preferably 1 to 4 carbon atoms; X.sup.1 represents a halogen atom, 
0&lt;m.ltoreq.3, 0.ltoreq.n&lt;3, 0.ltoreq.p&lt;3, 0.ltoreq.q&lt;3, and m+n+p+q=3. 
(ii) Complex alkylated compounds between aluminum and a metal of Group I 
represented by the general formula 
EQU M.sup.1 AIR.sub.4.sup.7 
wherein M.sup.1 represents Li, Na or K, and R.sup.7 is as defined above. 
Examples of the organoaluminum compounds of general formula (i) are as 
follows: Compounds of the general formula 
EQU R.sub.m.sup.7 Al(OR.sup.8).sub.3-m 
wherein R.sup.7, R.sup.8 and m are as defined, and m is preferably a number 
represented by 1.5.ltoreq.m.ltoreq.3. Compounds of the general formula 
EQU F.sub.m.sup.7 AlX.sub.3-m 
wherein R.sup.7, X and m are as defined and m is preferably a number 
represented by 0&lt;m&lt;3. Compounds of the general formula 
R.sub.m.sup.7 AlH.sub.3-m 
wherein R.sup.7 and m are as defined above, and m is preferably a number 
represented by 2.ltoreq.m&lt;3. Compounds represented by the general formula 
EQU F.sub.m.sup.7 Al(OR.sup.8).sub.n X.sub.1 
wherein R.sup.7, R.sup.8, m, n and q are as defined above. 
Specific examples of the organoaluminum compounds belonging to (i) include 
trialkyl aluminums such as triethyl aluminum and tributyl aluminum; 
trialkenyl aluminums such as triisoprenyl aluminum; dialkyl aluminum 
alkoxides such as diethyl aluminum ethoxide and dibutyl aluminum butoxide; 
alkyl aluminum sesquialkoxides such as ethyl aluminum sesquiethoxide and 
butyl aluminum sesquibutoxide; partially alkoxylated alkyl aluminums 
having an average composition represented by R.sub.2.5.sup.7 
Al(OR.sup.8).sub.0.5 ; dialkyl aluminum halides such as diethyl aluminum 
chloride, dibutyl aluminum chloride and diethyl aluminum bromide; alkyl 
aluminum sesquihalides such as ethyl aluminum sesquichloride, butyl 
aluminum sesquichloride and ethyl aluminum sesquibromide; partially 
halogenated alkyl aluminums, for example alkyl aluminum dihalides such as 
ethyl aluminum dichloride, propyl aluminum dichloride and butyl aluminum 
dibromide; dialkyl aluminum hydrides such as diethyl aluminum hydride and 
dibutyl aluminum hydride; other partially hydrogenated alkyl aluminum, for 
example alkyl aluminum dihyrides such as ethyl aluminum dihydride and 
propyl aluminum dihydride; and partially alkoxylated and halogenated alkyl 
aluminums such as ethyl aluminum ethoxychloride, butyl aluminum 
butoxychloride and ethyl aluminum ethoxybromide. 
Organoaluminum compounds similar to (i) in which two or more aluminum atoms 
are bonded via an oxygen or nitrogen atom. Examples are (C.sub.2 
H.sub.5).sub.2 AlOAl (C.sub.2 H.sub.5).sub.2, (C.sub.4 H.sub.9).sub.2 
AlOAl(C.sub.4 H.sub.9).sub.2, 
##STR2## 
and methylaluminoxane. 
Examples of the compounds belonging to (ii) are LiAl(C.sub.2 H.sub.5).sub.4 
and LiAl(C.sub.7 H.sub.15).sub.4. 
Among these, the trialkyl aluminums and the alkyl aluminums resulting from 
bonding of the two or more of the above aluminum compounds are preferred. 
In preparation of the olefin polymerization catalyst component in the 
invention, an electron donor (C) may be used if desired. Examples of such 
electron donors (C) include oxygen-containing electron donors such as 
alcohols, phenols, ketones, aldehydes, carboxylic acids, esters of organic 
or inorganic acids, ethers, acid amides, acid anhydrides and 
alkoxysilanes; nitrogen-containing electron donors such as ammonia, 
amines, nitriles and isocyanates; the above polycarboxylic acid esters; 
etc. 
Specific examples of electron donors (C) include alcohols having 1 to 18 
carbon atoms such as methanol, ethanol, propanol, pentanol, hexanol, 
octanol, dodecanol, octadecyl, alcohol, oleoyl alcohol, benzyl alcohol, 
phenylethyl alcohol, cumyl alcohol, isopropyl alcohol and isopropylbenzyl 
alcohol; phenols having 6 to 20 carbon atoms and optionally having a lower 
alkyl group such as phenol, cresol, xylenol, ethylphenol, propylphenol, 
nonylphenol, cumylphenol and naphthol; ketones having 3 to 15 carbon atoms 
such as acetone, methyl ethyl ketone, methyl isobutyl ketone, 
acetophenone, benzophenone and benzoquinone; aldehydes having 2 to 15 
carbon atoms such as acetaldehyde, propionaldehyde, octylaldehyde, 
benzaldehyde, tolualdehyde and naphthaldehyde; organic acid esters having 
2 to 30 carbon atoms such as methyl formate, methyl acetate, ethyl 
acetate, vinyl acetate, propyl acetate, octyl acetate, cyclohexyl acetate, 
ethyl propionate, methyl butyrate, ethyl valerate, methyl chloroacetate, 
ethyl dichloroacetate, methyl methacrylate, ethyl crotonate, ethyl 
cyclohexanecarboxylate, methyl benzoate, ethyl benzoate, propyl benzoate, 
butyl benzoate, octyl benzoate, cyclohexyl benzoate, phenyl benzoate, 
benzyl benzoate, methyl toluylate, ethyl toluylate, amyl toluylate, ethyl 
ethylbenzoate, methyl anisurate, n-butyl maleate, diisobutyl 
methylmalonate, di-n-hexyl cyclohexanecarboxylate, diethyl nadate, 
diisopropyl tetrahydrophthalate, diethyl phthalate, diisobutyl phthalate, 
di-n-butyl phthalate, di-2-ethylhexyl phthalate, gamma-butyrolactone, 
deltavalerolactone, coumarin, phthalide and ethylene carbonate; acid 
halides having 2 to 15 carbon atoms such as acetyl chloride, benzoyl 
chloride, toluyl chloride and anisuryl chloride; ethers and diethers 
having 2 to 20 carbon atoms such as methyl ether, ethyl ether, isopropyl 
ether, butyl ether, amyl ether, tetrahydrofuran, anisole, diphenyl ether 
and epoxy-p-menthane; acid amides such as acetamide, benzamide and 
toluamide; amines such as methylamine, ethylamine, diethylamine, 
tributylamine, piperidine, tribenzylamine, aniline, pyridine, picoline and 
tetramethylenediamine; nitriles such as acetonitrile, benzonitrile and 
tolunitrile; acid anhydrides such as acetic anhydride, phthalic anhydride 
and benzoic anhydride; etc. 
As the electron donor (C) are also usable organosilicon compounds 
represented by the following general formula (Ia) 
EQU R.sub.r.sup.9 Si(OR.sup.10).sub.4-r (Ia) 
wherein R.sup.9 and R.sup.10 are hydrocarbon groups and 0&lt;r&lt;4. 
Specific examples of the organosilicon compounds of the general formula 
(Ia) include trimethylmethoxysilane, trimethylethoxysilane, 
dimethyldimethoxysilane, dimethyldiethoxysilane, 
diisopropyldimethoxysilane, t-butylmethyldimethoxysilane, 
t-butylmethyldiethoxysilane, t-amylmethyldiethoxysilane, 
diphenyldimethoxysilane, phenylmethyldimethoxysilane, 
diphenyldiethoxysilane, bis-o-tolyldimethoxysilane, 
bis-m-tolyldimethoxysilane, bis-p-tolyldimethoxysilane, 
bis-p-tolyldiethoxysilane, bisethylphenyldimethoxysilane, 
dicyclohexyldimethoxysilane, cyclohexylmethyldimethoxysilane, 
cyclohexylmethyldiethoxysilane, ethyltrimethoxysilane, 
ethyltriethoxysilane, vinyltrimethoxysilane, methyltrimethoxysilane, 
n-propyltriethoxysilane, decyltrimethoxysilane, decyltriethoxysilane, 
phenyltrimethoxysilane, gamma-chloropropyltrimethoxysilane, 
methyltoluethoxysilane, ethyltriethoxysilane, vinyltriethoxysilane, 
t-butyltriethoxysilane, n-butyltriethoxysilane, isobutyltrimethoxysilane, 
phenyltriethoxysilane, gamma-aminopropyltriethoxysilane, 
chlorotriethoxysilane, ethyltriisopropoxysilane, vinyltributoxysilane, 
cyclohexyltrimethoxysilane, cyclohexyltriethoxysilane, 
2-norbornanetrimethoxysilane, 2-norbornanetriethoxysilane, 
2-norbornanemethyldimethoxysilane, ethyl silicate, butyl silicate, 
trimethylphenoxysilane, methyltriallyloxysilane, 
vinyltris(beta-methoxyethoxy)silane, vinyltriacetoxysilane, 
dimethyltetraethoxydisiloxane, etc. 
Among them are preferred trimethylmethoxysilane, ethyltriethoxysilane, 
n-propyltriethoxysilane, t-butyltriethoxysilane, vinyltriethoxysilane, 
phenyltriethoxysilane, vinyltributoxysilane, diphenyldimethoxysilane, 
phenylmethyldimethoxysilane, bis-p-tolyldimethoxysilane, 
p-tolylmethyldimethoxysilane, dicyclohexyldimethoxysilane, 
cyclohexylmethyldimethoxysilane, 2-norbornanetriethoxysilane, 
2-norbornanemethyldimethoxysilane and diphenyldiethoxysilane. 
Further, as electron donor (C) are also usable organosilicon compounds 
represented by the following general formula (IIa) 
SiR.sup.11 R.sub.s.sup.12 (OR.sup.13).sub.3-s (IIa) 
wherein R.sup.11 is a cyclopentyl group or a cyclopentyl group having an 
alkyl group, R.sup.12 is a group selected from the group consisting of an 
alkyl group, a cyclopentyl group and a cyclopentyl group having an alkyl 
group, R.sup.13 is a hydrocarbon group, and s is a number of 
0.ltoreq.s&lt;s2. 
As above defined, R.sup.11 in the above formula (IIa) is a cyclopentyl 
group or a cyclopentyl group having an alkyl group, and examples of 
R.sup.11 include, for example, a cyclopentyl group and alkyl-substituted 
cyclopentyl groups such as 2-methylcyclopentyl, 3-methylcyclopentyl, 
2-ethylcyclopentyl and 2,3-dimethylcyclopentyl groups. 
Further, R.sup.12 in the formula (IIa) is an alkyl group, a cyclopentyl 
group or a cyclopentyl group having an alkyl group, and examples of 
R.sup.12 include, for example, alkyl groups such as methyl, ethyl, propyl, 
isopropyl, butyl and hexyl groups, and cyclopentyl group and 
alkylsubstituted cyclopentyl groups as exemplified as R.sup.11. 
Further, R.sup.13 in the formula (IIa) is a hydrocarbon group, and examples 
of R.sup.13 include, for example, hydrocarbon groups such as alkyl, 
cycloalkyl, aryl and aralkyl groups. 
It is preferred to use among them organosilicon compounds wherein R.sup.11 
is a cyclopentyl group, R.sup.12 is an alkyl or cyclopentyl group, and 
R.sup.13 is an alkyl group, especially a methyl or ethyl group. 
Specific examples of the organosilicon compound include trialkoxysilanes 
such as cyclopentyltrimethoxysilane, 2-methylcyclopentyltrimethoxysilane, 
2,3-dimethylcyclopentyltrimethoxysilane and cyclopentyltriethoxysilane; 
dialkoxysilanes such as dicyclopentyldiethoxysilane, 
bis(2-methylcyclopentyl)dimethoxysilane, 
bis-(2,3-dimethylcyclopentyl)dimethoxysilane and 
dicyclopentyldiethoxysilane; monoalkoxysilanes such as 
tricyclopentylmethoxysilane, tricyclopentylethoxysilane, 
dicyclopentylmethylmethoxysilane, dicyclopentylethylmethoxysilane, 
dicyclopentylmethylethoxysilane, cyclopentyldimethylmethoxysilane, 
cyclopentyldiethylmethoxysilane and cyclopentyldimethylethoxysilane, etc. 
As the electron donor (C), the above organic carboxylic acid esters and the 
organosilicon compounds are preferred, and the organosilicon compounds are 
particularly preferred. 
The preliminary polymerization catalyst component (I) of the invention is 
prepared by subjecting the olefin polymerization catalyst component (X) 
formed from the above solid titanium catalyst component (A), the 
organoaluminum compound catalyst component (B) and when desired the 
electron donor (C) to successive preliminary polymerization treatment 
using a straight chain alpha-olefin having 2 to 5 carbon atoms and 
3-methyl-1-butene. As already mentioned, the preliminary polymerization 
treatment is carried out either by first using the straight chain 
alpha-olefin having 2 to 5 carbon atoms and then 3-methyl-1-butene or by 
first using 3-methyl-1-butene and then the straight chain alpha-olefin 
having 2 to 5 carbon atoms. 
In either preliminary polymerization treatment, the straight chain 
alpha-olefin having 2 to 5 carbon atoms is used in an amount of 0.1 to 300 
g, preferably 1 to 100 g, particularly preferably 1 to 50 g, per g of the 
solid part of the polymerization catalyst component (X), and 
3-methyl-1-butene is used in an amount of 0.1 to 100 g, preferably 1 to 50 
g, particularly preferably 2 to 50 g, per g of the solid part of the 
polymerization catalyst component (X). 
Specific examples of the straight chain alpha-olefin having 2 to 5 carbon 
atoms include ethylene, propylene, n-butene-1 and n-pentene-1. 
In the preliminary polymerization, the catalyst can be used in a 
concentration rather higher than the catalyst concentration in the main 
polymerization system. 
It is desirable to arrange the concentration of the solid titanium catalyst 
component (A) in the preliminary polymerization in a range of usually 
about 0.01 to 200 millimoles, preferably about 0.1 to 100 millimoles, 
particularly preferably 1 to 50 millimoles, in terms of titanium atom per 
liter of the later-described inactive hydrocarbon solvent. 
The amount of the organoaluminum catalyst component (B) may be an amount 
such that 0.1 to 500 g, preferably 0.3 to 300 g, of the polymer is formed 
per g of the solid titanium catalyst component (A). It is desirable that 
the amount is an amount of usually about 0.1 to 500 moles, preferably 
about 1 to 100 moles, per mole of the titanium atom in the solid titanium 
catalyst component (A). 
The electron donor (C) is used according to necessity, and it is preferred 
to use it in an amount of 0.1 to 100 moles, preferably 1 to 50 moles, 
particularly preferably 1 to 10 moles, per mole of the titanium atom in 
the solid titanium catalyst component (A). 
The preliminary polymerization is preferably carried out under a mild 
condition with addition of the olefin and the above catalyst components to 
an inert hydrocarbon medium. 
Examples of the inert hydrocarbon medium to be used include aliphatic 
hydrocarbons such as propane, butane, pentane, hexane, heptane, octane, 
decane, dodecane and kerosene; alicyclic hydrocarbons such as 
cyclopentane, cyclohexane and methylcyclopentane; aromatic hydrocarbons 
such as benzene, toluene and xylene; and halogenated hydrocarbons such as 
ethylene chloride and chlorobenzene; and their mixtures; etc. Aliphatic 
hydrocarbons are particularly preferably used among these inert 
hydrocarbon medium. It is also possible to use the monomer itself as a 
solvent or to preliminary polymerize the monomer in a state substantially 
free of a solvent. 
The reaction temperature for the preliminary polymerization may be one at 
which the resulting preliminary polymer does not substantially dissolve in 
the inert hydrocarbon medium. Desirably, it is usually about -20.degree. 
to +100.degree. C., preferably about -20.degree. to +80.degree. C., more 
preferably 0.degree. to +40.degree. C. 
A molecular weight-controlling agent such as hydrogen may be used in the 
preliminary polymerization. Desirably, the molecular weight-controlling 
agent is used in such an amount that the polymer obtained by the 
preliminary polymerization has an intrinsic viscosity [.eta.], measured in 
decalin at 135.degree. C., of at least about 0.2 dl/g, preferably about 
0.5 to 10 dl/g. 
The preliminary polymerization may be carried out batchwise or 
continuously. Further, batchwise and continuous methods may be used 
together. For example, it is possible to carry out batchwise the 
preliminary polymerization treatment with the 3-methyl-1-butene and then 
continuously the preliminary polymerization treatment with the straight 
chain alpha-olefin having 2 to 5 carbon atoms. 
By thus subjecting the olefin polymerization catalyst component (X) either 
to preliminary polymerization treatment using first the straight chain 
alpha-olefin having 2 to 5 carbon atoms and then 3-methyl-1-butene, or to 
preliminary polymerization treatment using first 3-methyl-1-butene and 
then the straight chain alpha-olefin having 2 to 5 carbon atoms, a polymer 
composition consisting of the polymerization unit of the straight chain 
alpha-olefin having 2 to 5 carbon atoms and that of 3-methyl-1-butene is 
formed on the olefin polymerization catalyst component (X). 
According to the invention is similarly provided an olefin polymerization 
catalyst formed from 
(I) the olefin polymerization catalyst component of the invention obtained 
by the above preliminary polymerization treatment, 
(II) when desired, an organoaluminum compound catalyst component, and 
(III) when desired, an electron donor. 
As the organoaluminum compound component (II), the same compounds as the 
organoaluminum compounds used in preparation of the preliminary 
polymerization catalyst component can be used. Further, there can 
similarly be used as the electron donor (III) the same compounds as the 
electron donors used in preparation of the preliminary polymerization 
catalyst component. 
However, this does not mean to make it indispensable to use the same 
compounds as used in preparation of the preliminary polymerization 
catalyst component as the organoaluminum compound catalyst component (II) 
and the electron donor (III), respectively. 
According to the invention, a polymerization method which comprises 
polymerizing or copolymerizing an olefin in the presence of the olefin 
polymerization catalyst of the invention is also provided. 
Examples of the olefin to be used in such main polymerization include 
olefins having 3 to 20 carbon atoms such as propylene, 1-butene, 
4-methyl-1-pentene and 1-octene. In the process of this invention, these 
olefins may be used singly or in combination. In one preferred embodiment 
of the invention, propylene or 1-butene is homopolymerized, or a mixed 
olefin containing propylene or 1-butene as a main component is 
copolymerized. When the mixed olefin is used, the content of propylene or 
1-butene as the main component is usually at least 50 mole %, preferably 
at least 70 mole %. When the copolymerization is carried out using a mixed 
olefin, it is possible to use ethylene as a comonomer. 
In the homopolymerization or copolymerization of these olefins, a 
polyunsaturated compound such as a conjugated diene or a non-conjugated 
diene may be used as a comonomer. 
In the polymerization process of this invention, the main polymerization of 
an olefin is carried out usually in the gaseous or liquid phase. 
When the main polymerization is carried out in a slurry reaction mode, the 
aforesaid inert hydrocarbon may be used as a reaction solvent. 
Alternatively, an olefin which is liquid at the reaction temperature may 
alternatively be used as the reaction solvent. 
In the polymerization process of the invention, the olefin polymerization 
catalyst component (2) obtained by the preliminary polymerization is used 
in an amount of usually about 0.001 to 0.5 millimole, preferably about 
0.005 to 0.1 millimole, calculated as Ti atom per liter of the volume of 
the polymerization zone. The organoaluminum compound catalyst component 
(II) is used in an amount such that the amount of the metal atom in the 
organoaluminum compound catalyst component is usually about 1 to 2,000 
moles, preferably about 5 to 500 moles, per mole of the titanium atom in 
the olefin polymerization catalyst component in the polymerization system. 
Further, the electron donor (III) is used in an amount of usually about 
0.001 to 10 moles, preferably about 0.01 to 2 moles, particularly 
preferably about 0.05 to 1 mole, per mole of the metal atom in the 
organoaluminum compound catalyst component (II). 
The use of hydrogen at the time of main polymerization makes it possible to 
control the molecular weight of the resulting polymer, and the polymer 
obtained has a high melt flow rate. In this case, too, the 
stereoregularity index of the resulting polymer and the activity of the 
catalyst are not decreased in the polymerization process of this 
invention. 
It is advantageous that the polymerization temperature of the olefin in the 
invention is usually about 20.degree. to 200.degree. C., preferably about 
50.degree. to 100.degree. C., and the polymerization pressure is usually 
from atmospheric pressure to 100 kg/cm.sup.2, preferably about 2 to 50 
kg/cm.sup.2. The main polymerization may be carried out batchwise, 
semi-continuously or continuously. The polymerization may also be carried 
out in two or more stages under different reaction conditions. 
The olefin polymer obtained by the process of the invention may be a 
homopolymer, a random copolymer or a block copolymer. The content of the 
3-methyl-1-butene polymerization unit in the olefin polymer is usually 10 
to 10,000 wt. ppm, preferably 100 to 3,000 wt. ppm, more preferably 100 to 
1,000 wt. ppm. 
When particularly polymerization of propylene or copolymerization of 
propylene with another alpha-olefin is carried out in the above manner 
either using the olefin polymerization catalyst component of the invention 
containing the 3-methyl-1-butene polymerization unit and the 
polymerization unit of the straight chain alpha-olefin having 2 to 5 
carbon atoms as a result of the preliminary polymerization, or using the 
olefin polymerization catalyst of the invention formed from this catalyst 
component, the organoaluminum compound (II) when desired, and the electron 
donor (III) when desired, a propylene series polymer having an excellent 
see-through property, good properties and a large apparent bulk density 
can be obtained. 
That is to say, when polymerization of propylene or copolymerization of 
propylene with another alpha-olefin is carried out using the olefin 
polymerization catalyst component prepared by the invention, the 
polymerization composition in the resulting propylene series polymer 
comprising the 3-methyl-1-butene polymerization unit and the 
polymerization unit of the straight chain alpha-olefin having 2 to 5 
carbon atoms makes the size of the spherulites of the propylene series 
polymer to be miniaturized, and as a result the resulting propylene series 
polymer is excellent in a see-through property. Further, the propylene 
series polymer obtained using the olefin polymerization catalyst 
component, wherein the 3-methyl-1-butene polymerization unit and the 
polymerization unit of the straight chain alpha-olefin having 2 to 5 
carbon atoms are contained as a result of the preliminary polymerization, 
is superior to a propylene series polymer obtained using an olefin 
polymerization catalyst component wherein only 3-methyl-1-butene is 
preliminarily polymerized in that particles of the resulting polymer are 
less destroyed, it is possible to suppress the formation of finely powdery 
polymer and moreover the resulting propylene series polymer has a higher 
apparent bulk density. 
Further, since the yield of the polymer having stereoregularity based on 
the unit amount of the olefin polymerization catalyst component (X) is 
high in the invention, it is possible to relatively reduce the catalyst 
residue, especially halogen content in the polymer. As a result, not only 
it is possible to omit a procedure of removing the catalyst in the 
polymer, but when a molded article is made using the formed olefin 
polymer, occurrence of rust on the metal mold can effectively be 
suppressed. 
According to the invention are also provided a nonstretched film of 
polypropylene which is prepared by polymerizing propylene in the presence 
of the olefin polymerization catalyst of the invention in the above manner 
and contains 3-methyl-1-butene polymerization unit in a content of 10 to 
10,000 wt. ppm, a stretched film obtained by stretching the nonstretched 
polypropylene film and an injection-molded article made of the 
polypropylene. 
These products are described below in this order. 
The nonstretched film can be prepared by molding the above polypropylene 
(hereinafter referred to as the 3-methyl-1-butene polymerization 
unit-containing composition) into a film according to the known molding 
method such as extrusion-molding or injection-molding. 
The molding temperature may be at least the temperature at which the 
3-methyl-1-butene polymerization unit-containing composition becomes a 
melted state, and it is desirable to carry out the molding by heating the 
composition to a temperature of usually 190.degree. to 300.degree. C., 
preferably 210.degree. to 280.degree. C. 
The thus molded nonstretched film of the invention has a thickness of 
usually 10 micrometers to 0.3 mm, preferably 20 micrometers to 0.2 mm. 
In a usual composition which is prepared by merely mixing 
poly(3-methylene-1-butene), polypropylene and the like and contains the 
3-methyl-1-butene polymer, poly(3-methyl-1-butene), polypropylene and the 
like are not uniformly blended to a state such that both ingredients are 
mixed in a molecular level as in the case in the above 3-methyl-1-butene 
polymerization unit-containing composition. It has been very difficult to 
prepare a nonstretched film having high transparency in use of such a 
usual composition. 
It is surmised in the invention that by use of the above 3-methyl-1-butene 
polymerization composition the spherulite size of the propylene series 
polymer is miniaturized and at the same time the crystallization speed of 
the propylene polymerization unit is accelerated whereby the transparency 
of the obtained nonstretched film is enhanced. That is to say, it is 
surmised that by use of the 3-methyl-1-butene polymerization 
unit-containing composition the nonstretched film of the invention having 
high transparency is obtained as a result of miniaturization of the 
spherulite size of the propylene series polymer and remarkable enhancement 
of crystallization speed. 
The nonstretched film of the invention has the above thickness and thus the 
films of the invention include sheet-like film. 
Since the 3-methyl-1-butene polymerization unit-containing composition 
contains the 3-methyl-1-butene polymerization unit as a polymer nucleus in 
the above amount, the crystallization speed thereof is fast. Thus, it is 
possible to shorten the molding cycle by use of this tight composition. 
The stretched film of the invention can be obtained by stretching the thus 
obtained nonstretched film to at least one direction of longitudinal 
direction and transverse direction. Thus the stretched film of this 
invention includes both uniaxially stretched film and biaxially stretched 
film. 
It is desirable that the stretching temperature of the above nonstretched 
film is usually 130.degree. to 200.degree. C., preferably 140.degree. to 
190.degree. C. When the stretched film of the invention is a biaxially 
stretched film, the stretching magnification in the above condition is 
usually 20 to 70 times, preferably 40 to 60 times, and in case of a 
uniaxially shortened film the stretching magnification in the above 
condition is usually 2 to 10 times, preferably 2 to 6 times. 
Further, besides biaxially or uniaxially stretched film obtained by 
stretching in the above manner the prepared nonstretched film, the 
stretched film of the invention can also be obtained by the inflation 
method wherein the 3-methyl-1-butene polymerization unit-containing 
composition in a melted state is stretched while a gas such as air is 
blown therein. The stretching magnification in this case is arranged in a 
range of usually 4 to 50 times, preferably 9 to 16 times. 
The thus obtained stretched film of the invention is excellent especially 
in a see-through property. As is clearly described, it is surmised that 
this is because the 3-methyl-1-butene polymerization unit contained in 
this composition makes the spherulite size of the propylene series polymer 
to be miniaturized and at the same time makes the crystallization speed of 
polypropylene faster. 
The 3-methyl-1-butene polymerization unit-containing composition of the 
invention has fast crystallization speed, and thus allows the preparation 
cycle of the stretched film to be shortened. 
The injection-molded article of the invention can be prepared by 
injection-molding through heating the 3-methyl-1-butene polymerization 
unit-containing composition to a molding temperature of at least the 
temperature bringing about its melted state, namely to a temperature of 
usually 190.degree. to 300.degree. C. preferably 210.degree. to 
280.degree. C. 
Since the above 3-methyl-1-butene polymerization unit-containing 
composition of the invention has a remarkably fast crystallization speed 
as is above-mentioned, and as a result the composition gives the 
injection-molded article of the invention having a high transparency. 
Various stabilizers can be compounded in the above composition of the 
invention for preparation of the above nonstretched film, stretched film 
and injection-molded article of the invention. 
Compounding of a phenol type stabilizer is preferred since a film and an 
injection-molded article which are excellent in thermal resistance and 
heat stability, and transparency are obtained thereby, and compounding of 
both a phenol type stabilizer and an organophosphite stabilizer is further 
preferred since a film and an injection-molded article particularly 
excellent in thermal resistance and heat stability, and transparency are 
obtained. 
Further, when a higher fatty acid metal salt is compounded, the heat 
stability of the resin at molding is enhanced and its moldability is 
improved and at the same time troubles accompanying occurrence of rust and 
corrosion on and of the molding machine due to the halogen gas from the 
catalyst can be suppressed. Use of a phenol type stabilizer and/or an 
organophosphite stabilizer as the aforesaid stabilizer with the higher 
fatty acid metal salt at the same time is preferred because an excellent 
synergistic effect is accomplished thereby in moldability, and the 
transparency and thermal resistance of the obtained film and 
injection-molded article. 
Specific examples of the phenol type stabilizer include 
2,6-di-t-butyl-4-methylphenol, 2,6-di-t-butyl-4-ethylphenol, 
2,6-dicyclohexyl-4-methylphenol, 2,6-diisopropyl-4-ethylphenol, 
2,6-di-t-amyl-4-methylphenol, 2,6-d-t-octyl-4-n-propylphenol, 
2,6-dicyclohexyl-4-n-octylphonel, 2-isopropyl-4-methyl-6-t-butylphenol, 
2-t-butyl-2ethyl-6-t-octylphenol, 2-isobutyl-4-ethyl-5-t-hexylphenol, 
2-cyclohexyl-4-n-butyl-6-isopropylphenol, styrene-modified mixed cresol, 
dl-alpha-tocopherol, t-butylhydroquinone, 
2,2'-methylenebis(4-methyl-6-t-butylphenol), 
4,4'-butylidenebis(3-methyl-6-t-butylphenol), 
4,4'-thiobis(3-methyl-6-t-butylphenol), 
4,4'-thiobis(4-methyl-6-t-butylphenol), 
4,4'-methylenebis-(2,6-di-t-butylphenol), 
2,2'-methylenebis6-(1-methylcyclohexyl)-p-cresol], 
2,2'-ethylidenebis(4,6-di-t-butylphenol), 
2,2'-butylidenebis(2-t-butyl-4-methylphenol), 
1,1,3-tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane, triethylene 
glycol-bis[3-(3-t-butyl-5-methyl4-hydroxyphenyl)propionate), 
1,6-hexanediol-bis[3(3,5-di-t-butyl-4-hydroxyphenyl)propionate], 
2,2-thiodiethylenebis3-(3,5-di-t-butyl-4,4-hydroxyphenyl) propionate], 
N,N'-hexamethylenebis(3,5-di-t-butyl-4,4-hydroxy-hydrocinnamide), 
3,5-di-t-butyl-4-hydroxybenzylphosphonate diethyl ester, 
1,3,5-tris(2,6-dimethyl-3-hydroxy-4-t-butylbenzyl)isocyanurate, 
1,3,5-tris(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxyethyl)isocyanurae, 
tris(4-t-butyl-2,6-dimethyl-3-hydroxybenzyl)isocyanurate, 
2,4-bis(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-triazine, 
tetrakismethylene-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate]methane, 
bis(3,5-di-t-butyl-4-hydroxybenzylphosphonic acid ethyl)calcium, bis( 
3,5-di-t-butyl-4-hydroxybenzylphosphonic acid ethyl)nickel, 
bis[3,3-bis(3-t-butyl-4-hydroxyphenyl)butyric acid] glycol ester, 
N,N'-bis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyl)hydrazine, 
2,2'-oxamidobis[ethyl3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], 
bis-[2-t-butyl-4-methyl-6-(3-t-butyl-5-methyl-2-hydroxybenzyl)phenyl)terep 
hthalate, 1,3,5-trimethyl-2,4,6tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene, 
3,9bis-[1,1-dimethyl-2-(beta-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyl 
oxy)ethyl]-2,4,8,10-tetraoxaspino-[ 5,5)undecane, 
2,2-bis[4-(2-(3,5-di-t-butyl-4-hydroxyhydrocinnamoyloxy))ethoxyphenyl]prop 
ane, beta-(3,5-di-t-butyl-4-hydroxyphenyl)propionic alkyd ester, etc. 
When beta-(3,5-di-t-butyl-4-hydroxyphenyl)propionic acid alkyd ester is 
used as the phenol type stabilizer, the alkyd ester having 18 or less 
carbon atoms are particularly preferably used. 
Further, a phenol type stabilizer is preferred which has in the molecule 
the structure represented by 
##STR3## 
In the above formulae, R.sup.18 represents a hydrogen atom or an alkyd 
group having 1 to 6 carbon atoms, R.sup.14 and R.sup.15 independently 
represent alkyl groups having 1 to 6 carbon atoms, R.sup.16 represents an 
alkyl group having 1 to 6 carbon atoms or an alkoxy group having 1 to 6 
carbon atoms, and R.sup.17 represents an alkyl group having 1 to 22 carbon 
atoms or one of the following structures: 
##STR4## 
(wherein t and u are numbers of t+u=3 and u=0, 1, 2 or 3), 
##STR5## 
(wherein R.sup.21 represents: 
##STR6## 
Among them are preferred 2,6-di-tert-butyl-4-methyl-p-cresol, 
stearyl-beta-(4-hydroxy-3,5-di-tert-butylphenol) propionate, 
2,2'-ethylidenebis(3,6-d-tert-butylphenol) and 
tetrakis[methylene-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]methane 
. 
These phenol type stabilizers can be used alone or as a mixture thereof. 
Examples of the phosphite stabilizer include trioctyl phosphite, trilauryl 
phosphite, tristridecyl phosphite, trisisodecyl phosphite, phenyl 
diisooctyl phosphite, phenyl diisodecyl phosphite, phenyl 
di(tridecyl)phosphite, diphenyl isooctyl phosphite, diphenyl isodecyl 
phosphite, diphenyl tridecyl phosphite, triphenyl phosphite, 
tris(nonylphenyl)phosphite, tris-(2,4-di-t-butylphenyl)phosphite, 
tris(butoxyethyl)phosphite, 
tetratridecyl-4,4'-butylidenebis(3-methyl6-t-butylphenol)diphosphite, 
4,4'-isopropylidene-diphenol alkyl phosphite (wherein the alkyl has about 
12 to 15 carbon atoms), 
4,4'-isopropylidenebis(2-t-butylphenol)-di(nonylphenyl)phosphite, 
tetra(tridecyl)-1,1,3-tris-(2-methyl-5-t-butyl-4-hydroxyphenyl)butane 
diphosphite, 
tetra(tridecyl)-4,4'-butylidenebis(3-methyl-6-t-butylphenol)diphosphite, 
tris(3,5-di-t-butyl-4-hydroxyphenyl)phosphite, hydrogenated 
4,4'-isopropylidenediphenol polyphosphite, bis(octylphenyl) 
bis4,4'-butylidenebis(3-methyl-6-t-butylphenol)], 1,6-hexanediol 
diphosphite, 
hexatridecyl-1,1,3-tris(2-methyl-4-hydroxy-5-t-butylphenol)diphosphite, 
tris[4,4'-isopropylidenebis(2-t-butylphenol)]phosphite, 
tris(1,3-distearoyloxyisopropyl)phosphite, 
9,10-dihydro-9-phosphaphenanthrene10-oxide, 
tetrakis(2,4-di-t-butylphenyl)-4,4'-biphenylene diphosphite, etc. 
Among them, tris(2,4-di-tert-butylphenyl)phosphite, 
tris(nonylphenyl)phosphite and 
tetrakis(2,4-di-tert-butylphenyl)-4,4'-biphenylene diphosphite is 
particularly preferred. 
Further, phosphite type stabilizers of the following formulae, which are 
derived from pentaerythritol, can also be used: 
##STR7## 
In the above two formulae, R.sup.19 and R.sup.20 represent alkyl groups. 
The organophosphite stabilizers can be used alone or in combination. 
Examples of the higher fatty acid metal salt include alkali, alkaline earth 
and other metal salts of saturated or unsaturated carboxylic acids having 
12 to 40 carbon atoms. Further, the saturated or unsaturated carboxylic 
acids having 12 to 40 carbon atoms may have substituent(s) such as 
hydroxyl group(s). Specific examples of the saturated or unsaturated 
carboxylic acid having 12 to 40 carbon atoms include higher fatty acids 
such as stearic acid, oleic acid, lauric acid, capric acid, arachidonic 
acid, palmitic acid, behemic acid, 12-hydroxystearic acid and montanic 
acid. Further, as metals which form salts by reaction with these higher 
fatty acids alkaline earth metals such as magnesium, calcium and barium, 
alkali metals such as sodium, potassium and lithium, cadmium, zinc, lead, 
etc. can be mentioned 
Specific examples of the higher fatty acid salt include magnesium stearate, 
magnesium laurate, magnesium palmitate, calcium stearate, calcium oleate, 
calcium laurate, barium stearate, barium oleate, barium laurate, barium 
arachidonate, barium benenate, zinc stearate, zinc oleate, zinc laurate, 
lithium stearate, sodium stearate, sodium palmitate, sodium laurate, 
potassium stearate, potassium laurate, calcium 12-hydroxystearate, sodium 
montanate, calcium montanate, zinc montanate, etc. 
Among these higher fatty acid metal salts, zinc salts of saturated fatty 
acid having 12 to 35 carbon atoms are particularly preferred. 
These higher fatty acid metal salts can be used alone or in combination 
Compounding rate of the phenol type stabilizer is 0.01 to 10 wt.%, 
preferably 0.02 to 0.5 wt.%, particularly preferably 0.03 to 0.2 wt.%, 
compound rate of the organophosphite stabilizer is 0.01 to 1.0 wt.%, 
preferably 0.02 to 0.5 wt.%, particularly preferably 0.01 to 0.2 wt.%, and 
compound rate of the higher fatty acid metal salt is 0.01 to 1.0 wt.%, 
preferably 0.02 to 0.5 wt.%, particularly preferably 0.03 to 0.2 wt.%, 
based respectively on the molding raw material resin.

This invention is further detailedly described below by examples, but 
should not be limited thereto. 
EXAMPLE 1 
Preparation of a titanium catalyst component (A) 
Anhydrous magnesium chloride (7.14 kg), 37.5 liters of decane and 35.1 
liters of 2-ethylhexyl alcohol were reacted with heating at 140.degree. C. 
for 4 hours to form a uniform solution. To the solution was added 1.67 kg 
of phthalic anhydride, and the mixture was stirred at 130.degree. C. for 1 
hour with stirring to dissolve phthalic anhydride in the uniform solution. 
The resulting uniform solution was cooled to room temperature, and added 
dropwise to 200 liters of titanium tetrachloride kept at -20.degree. C. 
over 3 hours. After the addition, the temperature of the mixed solution 
was elevated to 110.degree. C. over the course of 4 hours. When the 
temperature reached 110.degree. C., 5.03 liters of diisobutyl phthalate 
was added. 
The mixture was maintained at this temperature for 2 hours with stirring. 
After the reaction for 2 hours, the solid portion was collected by hot 
filtration, and resuspended in 275 liters of titanium tetrachloride. The 
suspension was reacted with heating at 110.degree. C. for 2 hours. 
After the reaction, the solid portion was collected by hot filtration and 
washed with hexane until no free titanium compound was detected in the 
washings. 
The solid titanium catalyst component (A) synthesized by the above process 
was obtained as a hexane slurry. Part of this catalyst was dried. The 
dried matter was found by analysis to comprise 2.4 wt.% of titanium, 59 
wt.% of chlorine, 18 wt.% of magnesium and 11.6 wt.% of diisobutyl 
phthalate. 
Preliminary polymerization 
Purified hexane (100 liters), 3 moles of triethyl aluminum and 1 mole, as 
titanium atom, of the titanium catalyst component (A) were charged into a 
nitrogen-purged reactor. Propylene was supplied to the stirred suspension 
at a velocity of 2,130 Nl/hour over 1.5 hours while the temperature of the 
suspension was maintained at 15.degree. to 20.degree. C. After completion 
of propylene supply, the reaction was sealed and polymerization of the 
residual propylene was allowed to proceed for 30 minutes. 7 Moles of 
triethyl aluminum, 5 moles of trimethylmethoxysilane and 5.9 kg of 
3-methyl-1-butene were added and the mixture was mixed with stirring at 
30.degree. C. for 3 hours to preliminary polymerize 3-methyl-1-butene. 
After completion of the preliminary polymerization, the resulting polymer 
was adequately washed with purified hexane. Analysis of the polymer 
revealed that the preliminary polymerization amount of propylene was 2.8 
g/g catalyst and that of 3-methyl-1-butene was 2.4 g/g catalyst. 
Polymerization 
Homopolymerization of propylene was continuously carried out using a 
250-liter polymerization reactor. Polymerization pressure and 
polymerization temperature were controlled at 8 kg/cm.sup.2 G and 
70.degree. C., respectively. As catalyst compounds. 18 mmoles/hour of 
triethyl aluminum, 1.8 mmoles/hour of dicyclohexyldimethoxysilane and 0.24 
mmole in terms of titanium atom.hour of the preliminary polymerization 
catalyst wherein propylene and 3-methyl-1-butene had been preliminarily 
polymerized on the titanium catalyst component (A) were continuously 
supplied to the reactor. The resulting polypropylene was continuously 
discharged. 
The velocity of polypropylene formation was about 10 kg/hour in average. 
The content of poly(3-methyl-1-butene) in the polypropylene was 140 wt. 
ppm. 
Production of a biaxially stretched film 
One hundred parts by weight of the resulting polypropylene containing 
poly(3-methyl-1-butene) was mixed with 0.1 part by weight of calcium 
stearate, 0.1 part by weight of BHT (2,6-di-tertiary butylhydroxytoluene) 
and 0.1 part by weight of Irganox 1010 (an antioxidant produced by 
Ciba-Geigy; tetrakis[methylene-3-(3',5'-di-tertiary 
butylhydroxyphenyl)propionate]methane) as stabilizers in a Henschel mixer, 
and then pelletized by an extruder having a cylinder diameter of 65 mm at 
a kneading temperature of 220.degree. C. 
The resulting pellets were extruded at 280.degree. C. by a sheet extruder 
having a cylinder diameter of 90 mm, and formed into a 1.5 mm thick sheet 
by a cold roll at 30.degree. C. The sheet obtained was stretched 
longitudinally at 145.degree. C. to 5 times by a tenter-type consecutive 
biaxially stretching device, and subsequently stretched transversely to 10 
times in a tenter kept at 170.degree. C. to give a biaxially stretched 
film having a thickness of about 30 microns. 
Evaluation of the film 
The film obtained in Examples 1 and 2 and Comparative Examples 1 and 2 were 
evaluated by the following evaluation methods. 
(1) See-through property evaluated by visual observation 
Five films each having a thickness of 30 microns were stacked, and the 
light from a fluorescent lamp was viewed through the films. The 
see-through feeling was evaluated on a scale of 5 grades in which 5 is 
good and 1 is bad. 
(2) Light scattering index (LSI) 
Measured by an LSI tester made by Toyo Seiki Co., Ltd. 
(3) Haze 
Measured in accordance with ASTM D1003. 
(4) Diameter of the spherulites 
The diameter of spherulites in the cross section of the sheet before 
biaxial stretching was measured by a stereomicroscope (.times.100). 
As the spherulite size of the sheet is smaller, the biaxially stretched 
film tends to have better see-through property. Hence, the diameter of the 
spherulites see-through property. 
The results are shown in Table 1. 
EXAMPLE 2 
Preliminary polymerization 
Purified hexane (100 liters), 10 moles of triethyl aluminum, 10 moles of 
trimethylmethoxysilane, 1 mole, as titanium atom, of the titanium catalyst 
component (A) and 10 kg of 3-methyl-1-butene were charged into a 
nitrogen-purged reactor. The resulting suspension was stirred at 
20.degree. C. for 3 hours to carry out preliminary polymerization of 
3-methyl-1-butene. As a result of analysis, the preliminary polymerization 
amount of 3-methyl-1-butene was found to be 3.9 g/g catalyst. The stirring 
was stopped to sediment the solid part and the supernatant was removed. 
The solid was washed twice with hexane, the whole volume was adjusted to 
120 liters, 3 moles of triethyl aluminum was added, and then propylene was 
supplied at a velocity of 2,130 Nl/hour for 1.5 hours to carry out 
preliminary polymerization of propylene. Preliminary polymerization 
temperature was maintained at 15.degree. to 20.degree. C. After completion 
of the propylene supply, the reactor was sealed and polymerization of the 
residual propylene was allowed to proceed for 30 minutes, and the 
resulting polymer was washed twice with hexane. As a result of analysis, 
the preliminary polymerization amount in terms of propylene was found to 
be 2.7 g/g catalyst. 
Polymerization 
Polymerization of propylene was carried out in the same manner as in 
Example 1. As a result, the poly-(3-methyl-1-butene) content in the formed 
polypropylene was 220 ppm. A film was prepared and evaluated in the same 
manner as in Example 1. 
Results was shown in Table 1. 
COMATIVE EXAMPLES 1 AND 2 
Procedures of Examples 1 and 2 were repeated except that the propylene 
prepolymerization was omitted by supplying no propylene. Results are shown 
in Table 1. 
TABLE 1 
__________________________________________________________________________ 
Properties of the bi- 
axially stretched film 
Properties of PP powder 
See-through 
Apparent 
Fine powder amount 
property Spherulite 
bulk (100 micrometers 
evaluated diameter of 
Experimental 
density 
or less) by visual 
LSI 
Haze 
the sheet 
MI 
No. g/ml wt. % observation 
% % (microns) 
g/10 min. 
__________________________________________________________________________ 
Example 1 
0.46 0 5 1.4 
0.4 
5 2.7 
Comparative 
0.21 5.6 -- -- -- -- --* 
Example 1 
Example 2 
0.47 0 5 1.2 
0.4 
4 2.6 
Comparative 
0.24 4.8 -- -- -- -- --* 
Example 2 
__________________________________________________________________________ 
*Polymer necessary for film formation could not be obtained because of 
difficulty of polymerization. 
EXAMPLE 3 
Preliminary polymerization 
Purified hexane (100 liters), 10 moles of triethyl aluminum, 10 moles of 
trimethylmethoxysilane, 1 mole, as titanium atom, of the titanium catalyst 
component (A) and 20 kg of 3-methyl-1-butene were charged into a 
nitrogen-purged reactor. The resulting suspension was stirred at 
20.degree. C. for 5 hours to carry out preliminary polymerization of 
3-methyl-1-butene. As a result of analysis, the preliminary polymerization 
amount of the 3-methyl-1-butene polymerization was found to be 7.2 g/g 
catalyst. The stirring was stopped to sediment the solid part and the 
supernatant was removed. The solid was washed twice with hexane, the whole 
volume was adjusted to 120 liters, 3 moles of triethyl aluminum was added, 
and then propylene was supplied at a velocity of 2,130 Nl/hour for 1.5 
hours to carry out preliminary polymerization of propylene. Preliminary 
polymerization temperature was maintained at 15.degree. to 20.degree. C. 
After completion of the propylene supply, the reactor was sealed and 
polymerization of the residual propylene was allowed to proceed for 30 
minutes, and the resulting polymer was washed twice with hexane. As a 
result of analysis, the preliminary polymerization amount of the propylene 
polymerization unit was found to be 2.7 g/g catalyst. 
Polymerization 
Polymerization was obtained in an average formation velocity of about 10 
kg/hour in the same manner as in the "polymerization" of Example 1. The 
content of the 3-methyl-1-butene polymerization unit in the polypropylene 
was 410 wt. ppm and MFR was 6.4 g/10 minutes. 
EXAMPLES 4 AND 5 
Polypropylenes having a content of the 3-methyl-1-butene polymerization 
unit of 200 wt. ppm (Example 4) and 630 wt. ppm (Example 5), respectively, 
were prepared by changing the polypropylene formation rate based on the 
solid catalyst by adjustment of residence time in Example 3. 
Preparation of nonstretched film 
One hundred parts by weight of the resulting 3-methyl-1-butene polymer 
unit-containing composition was mixed with 0.1 part by weight of calcium 
stearate, 0.1 part by weight of Irganox 1010 [an antioxidant produced by 
Ciba-Geigy; tetrakis[methylene-3-(3',5'-tertiary 
butylhydroxyphenyl)propionate]methane), 0.1 part by weight of erucic amide 
as a stabilizer and 0.1 part by weight of silica (SYLOID 244.RTM.produced 
by Fuji-Davison Chemical Ltd.) in a Henschel mixer, and then pelletized by 
an extruder having a cylinder diameter of 65 mm at a kneading temperature 
of 220.degree. C. 
The resulting pellets were extruded at 240.degree. C. by a T-die film 
molding device having a cylinder diameter of 65 mm, and then cooled by a 
cold roll at 30.degree. C. to obtain a nonstretched film having a 
thickness of 25 microns. 
Characteristics of the film was measured and evaluated by the following 
evaluating method. The results are shown in Table 2. 
EXAMPLES 6 AND 7 
Propylene and ethylene were randomly copolymerized under the condition of 
70.degree. C. and 5 kg/cm.sup.2 G using the same preliminary 
polymerization catalyst as in Example 3. The ethylene contents in the 
resulting copolymer were 3.0 wt.% and 3.2 wt.%, and the contents of the 
3-methyl-1-butene polymerization unit were 410 wt. ppm and 220 wt. ppm. 
The proportions of the nonstretched film obtained in the same manner as in 
Example 4 are shown in Table 2. 
COMATIVE EXAMPLES 3 AND 4 
Only propylene was preliminarily polymerized in Examples 3 and 4 without 
preliminarily polymerizing 3-methyl-1-butene. Polymerization was carried 
out using the thus obtained preliminary polymerization catalyst. 
Method of evaluation of the films in Examples 3 to 7 and Comparative 
Examples 3 and 4 
(1) See-through property evaluated by visual observation 
Five films each having a thickness of 25 microns were stacked, and the 
light from a fluorescent lamp was viewed through the films. The 
see-through feeling was evaluated on a scale of 5 grades in which 5 is 
good and 1 is bad. 
(2) Light scattering index (LSI) and (3) Haze 
Measured in the same manner as in Example 1. 
(4) Diameter of the spherulites 
The diameter of spherulites in the cross section of the sheet was measured 
by a stereomicroscope (.times.100). 
As the spherulite size is smaller, the see-through property of the film 
tends to become better. Hence, the diameter of the spherulites was used as 
a measure for obtaining a film having good see-through property. 
(5) Young's modulus 
The Young's modulus of the film in the transverse direction was measured by 
an instron tensile tester at a pulling speed of 50 mm/min. in accordance 
with JIS K6781. 
TABLE 2 
__________________________________________________________________________ 
Content of the 3- 
Visual Spherulite 
Young's 
Experimental MFR methyl-1-butene polymer 
obser- 
LSI Haze 
size modulus 
No. Polymer g/10 min. 
unit (wt. ppm) 
vation 
(%) (%) (micron) 
(kg/cm.sup.2) 
__________________________________________________________________________ 
Example 3 
Homo (II = 98.2%) 
6.4 410 5 2.4 2.8 5 13,000 
Example 4 
Homo (II = 98.3%) 
6.3 220 4 2.8 3.0 8 12,500 
Example 5 
Homo (II = 98.3%) 
7.1 630 5 2.2 2.7 4 13,100 
Example 6 
Random (C.sub.2.sup.= = 3.0 wt. %) 
6.6 410 3 3.6 2.9 25 8,000 
Example 7 
Random (C.sub.2.sup.= = 3.2 wt. %) 
7.7 220 3 3.4 2.9 25 7,700 
Comparative 
Homo (II = 98.2%) 
6.6 0 1 5.0 2.9 35 11,000 
Example 3 
Comparative 
Random (C.sub.2.sup.= = 3.0 wt. %) 
7.3 0 1 4.8 2.9 50 7,500 
Example 4 
__________________________________________________________________________ 
EXAMPLE 8 
Polymerization 
Random polymerization of propylene and ethylene was continuously carried 
out using a 250-liter polymerization reactor. Polymerization pressure and 
polymerization temperature were controlled at 5 kg/cm.sup.2 G and 
70.degree. C., respectively. As catalyst components, 16 mmoles/hour of 
triethyl aluminum, 1.6 mmoles of dicyclohexyldimethoxysilane and 0.24 
mmole in terms of titanium atom/hour of the titanium catalyst component of 
Example 3 wherein propylene and 3-methyl-1-butene had been preliminarily 
polymerized were continuously supplied to the reactor. Amount of hydrogen 
and ethylene to be supplied was adjusted so that the hydrogen/propylene 
ratio in the gaseous phase might be about 0.07 mole/mole and the 
ethylene/propylene ratio therein might be about 0.03 mole/mole. 
The velocity of formation of the obtained polypropylene was about 6 kg/hour 
in average. 
The MHR of the obtained polypropylene was 7.0 g/10 minutes, the ethylene 
content thereof was 4.7 mole% and the content of the 3-methyl-1-butene 
polymerization unit in the polypropylene was 600 wt. ppm. 
Preparation of an injection-molded article 
One hundred parts by weight of the resulting 3-methyl-1-butene 
polymerization unit-containing composition was mixed with 0.1 part by 
weight of calcium stearate and 0.1 part by weight of Irganox 1010 (an 
antioxidant produced by Ciba-Geigy; terabis[methylene3-(3',5'-di-tertiary 
butylhydroxyphenyl)propionate]methane) as stabilizers in a Henschel mixer, 
and then pelletized by an extruder having a cylinder diameter of 65 mm at 
a kneading temperature of 200.degree. C. 
The resulting pellets were injection molded at a resin temperature of 
220.degree. C. and an injection die temperature of 50.degree. C. using an 
injection molding machine having a diameter of 30 mm to obtain a square 
plate having a thickness of 2 mm. 
Characteristics of the square plate were measured and evaluated according 
to the following evaluation method. 
The results are shown in Table 3. 
Method of evaluation of the square plate 
(1) Haze 
Measured according to ASTM D1003. 
(2) Bending initial elastic modulus 
The Young's modulus of the film in the transverse direction was measured by 
an instron tensile tester at a pulling speed of 50 mm/min. in accordance 
with JIS K6781. 
EXAMPLES 9 AND 10 
Polypropylene having a content of the 3-methyl-1-butene polymerization unit 
of 210 wt. ppm (Example 9) and 420 wt. ppm (Example 10), respectively, 
were prepared by changing the polypropylene formation rate based on the 
solid catalyst by adjustment of residence time in Example 1. 
COMATIVE EXAMPLE 5 
The procedures of Example 8 were repeated except that a preliminary 
polymerization catalyst was prepared by carrying out only the preliminary 
polymerization of propylene using 3 moles of triethyl aluminum and 1 mole 
in terms of titanium atom of the titanium catalyst component (A). 
TABLE 3 
______________________________________ 
Content 
of the 
3-methyl- Bending 
1-butene initial 
Ethylene polymer elastic 
Experimental 
MFR content unit Haze modulus 
No. g/10 min. 
(mole %) (wt. ppm) 
(%) (kg/cm.sup.2) 
______________________________________ 
Example 8 
7.0 4.7 600 36 9,400 
Example 9 
7.6 4.5 210 46 9,100 
Example 10 
7.2 4.4 420 40 9,200 
Comparative 
7.0 4.4 0 77 8,600 
Example 5 
______________________________________