Method for forming semiconductor device structure

A method for forming a semiconductor device structure is provided. The method includes forming a target layer over a substrate and forming a seed layer over the target layer. The method includes forming a hard mask layer over the seed layer, and the hard mask layer includes an opening to expose a portion of the seed layer. The method includes forming a conductive layer in the opening, and the conductive layer is selectively formed on the portion of the seed layer. The method includes etching a portion of the target layer by using the conductive layer as a mask.

BACKGROUND

Semiconductor manufacturing technologies include a number of processes which involve complex physical and chemical interactions. The photolithography process is the process of transferring patterns of geometric shapes on a mask to a thin layer of photosensitive material (resist) covering the surface of a semiconductor wafer. The photolithography process is becoming a more sensitive and critical step in IC fabrication process as feature sizes shrink to ever-smaller sizes. However, there are many challenges related to the photolithography process.

Although existing photolithography process and methods of fabricating semiconductor device structure have generally been adequate for their intended purpose, they have not been entirely satisfactory in all respects.

DETAILED DESCRIPTION

Embodiments for a semiconductor device structure and method for forming the same are provided.FIGS. 1A-1Fshow cross-sectional representations of various stages of forming a semiconductor device structure100a, in accordance with some embodiments of the disclosure.

Referring toFIG. 1A, a substrate102is provided. The substrate102may be made of silicon or other semiconductor materials. In some embodiments, the substrate102is a wafer. Alternatively or additionally, the substrate102may include other elementary semiconductor materials such as germanium. In some embodiments, the substrate102is made of a compound semiconductor such as silicon carbide, gallium arsenic, indium arsenide, or indium phosphide. In some embodiments, the substrate102is made of an alloy semiconductor such as silicon germanium, silicon germanium carbide, gallium arsenic phosphide, or gallium indium phosphide. In some embodiments, the substrate102includes an epitaxial layer. For example, the substrate102has an epitaxial layer overlying a bulk semiconductor.

A target layer104is formed over the substrate102. The target layer104may be a dielectric layer, such as silicon oxide (SiOx), silicon nitride (SixNy), silicon oxynitride (SiON), dielectric material(s) with low dielectric constant (low-k), or combinations thereof. The target layer104will be patterned by the following operations. The target layer104may be a single layer or multiple layers.

The target layer104may be formed by a front-end-of-line (FEOL) process or back-end-of-line (BEOL) process. The target layer104may be formed by a deposition process, such as chemical vapor deposition process (CVD), physical vapor deposition process (PVD), spin-on coating process, sputtering process, planting process, or a combination thereof. The CVD process may be a low-pressure CVD (LPCVD) or plasma enhanced CVD (PECVD).

In some embodiments, device elements (not shown) are formed in the target layer104. The device elements include transistors (e.g., metal oxide semiconductor field effect transistors (MOSFET), complementary metal oxide semiconductor (CMOS) transistors, bipolar junction transistors (BJT), high-voltage transistors, high-frequency transistors, p-channel and/or n channel field effect transistors (PFETs/NFETs), etc.), diodes, and/or other applicable elements. Various processes are performed to form device elements, such as deposition, etching, implantation, photolithography, annealing, and/or other applicable processes. In some embodiments, device elements are formed in the substrate102in a front-end-of-line (FEOL) process.

Afterwards, a seed layer106is formed over the target layer104. The seed layer106is configured to facilitate the formation of a conductive layer120(shown inFIG. 1C). In some embodiments, the seed layer106is made of silicon (Si), titanium (Ti), titanium nitride (TiN), aluminum (Al), copper (Cu), silver (Ag), platinum (Pt), applicable materials or a combination thereof. In some embodiments, the seed layer106is formed by a deposition process, such as chemical vapor deposition process (CVD), physical vapor deposition process (PVD), electroplating, sputtering process, planting process, or a combination thereof.

Afterwards, a hard mask layer110is formed over the seed layer106. The hard mask layer110may be a single layer or multiple layers. The hard mask layer110may be made of silicon oxide, silicon nitride, silicon oxynitride, or another applicable material.

Afterwards, the hard mask layer110is patterned by a patterning process, as shown inFIG. 1B, in accordance with some embodiments of the disclosure. As a result, the patterned hard mask layer110includes openings111. In addition, a portion of the top surface of the seed layer106is exposed.

The number of the openings111is not limited two (shown inFIG. 1B) and it is dependent on the actual application. The patterning process includes a photolithography process and an etching process. The photolithography process includes photoresist coating (e.g., spin-on coating), soft baking, mask aligning, exposure, post-exposure baking, developing the photoresist, rinsing and drying (e.g., hard baking). The etching process may be a wet etching process or a dry etching process.

Afterwards, a conductive layer120is selectively formed in the openings111, as shown inFIG. 1C, in accordance with some embodiments of the disclosure. The conductive layer120is only formed over the seed layer106, but is not formed over the hard mask layer110. In other words, the conductive layer120is directly formed on the exposed surface of the seed layer106and in direct contact with the seed layer106.

The conductive layer120is formed by a selective deposition process. In some embodiments, the selective deposition process includes a selective chemical vapor deposition (CVD) process, an epitaxy process or a plating process. The advantage of the selective deposition process is that the conductive layer120is self-aligned formed on the seed layer106, because the metal materials are attracted by the seed layer106.

A second advantage of the selective deposition process is that no extra removing process is needed to remove excess metal materials. If the conductive layer120is formed by another deposition process, other than the selective deposition process, some metal materials may form over the hard mask layer110. The excess metal materials should be removed by an additional removal operation, such as chemical mechanical polishing (CMP) process or no etching back process. In contrast to the normal deposition process, the conductive layer120is self-aligned and selectively formed on the seed layer106. No excess metal materials are on the pattered hard mask layer110, and therefore no additional removal operation is needed to remove the excess conductive layer. More specifically, in some embodiments, no chemical mechanical polishing (CMP) process or no etching back process is performed to remove the excess conductive layer. Since the removal operation (such as CMP process) is omitted, the fabrication process and cost are reduced.

In addition, if the conductive layer120is formed by another deposition process, other than the selective deposition process, some voids are formed in the conductive layer120. The voids may degrade the performance of the conductive layer. Another advantage of the selective deposition process is that the conductive layer120is uniformly grown on the seed layer106, the voids may be reduced. Therefore, the shape of the conductive layer120is better.

In some embodiments, the conductive layer120is made of metal or metal compound. The metal includes tungsten (W), aluminum (Al), copper (Cu), titanium (Ti), cobalt (Co), or applicable material. The metal compound includes metal silicide, metal nitride, metal oxide. In some embodiments, a selective chemical vapor deposition (CVD) process is performed to form the conductive layer120over the exposed surface of the seed layer106. During the selective CVD process, an organometallic gas is introduced into a CVD chamber, the organometallic gas is thermally decomposed to form metal vapor and organic vapor. The metal vapor is spontaneously deposited and formed over the seed layer106, and therefore the conductive layer120is selectively grown on the seed layer106.

In some embodiments, the conductive layer120is made of high-melting point metal, such as tungsten (W). For example, the seed layer106is made of silicon (Si). A tungsten hexa-fluoride (WF6) and is used as a precursor gas and the hydrogen (H2) gas is used as a reduction gas during the selective CVD process, and. At the beginning, the chemical reaction is as following: WF6+Si→W+SiFx (g). In addition, another chemical reaction is occurred through adsorbed H2on existed W surface: WF6+H2→W+6HF (g). Therefore, tungsten (W) layer keeps growing only on the seed layer106(made of conductive material), and is hardly deposited on the hard mask layer110(made of insulating material). The SiFx and HF are volatile and do not form on the seed layer106. In some other embodiments, the conductive layer120is made of copper (Cu). For example, a Cu (hfac) TMVS (hfac: Hexafluoroacetylacetonate, TMVS: Trimethylvinylsilane) compound is used as a precursor. Cu (hfac) TMVS is in the liquid state at an ordinary temperature and an atmospheric pressure, and the CVD chamber is heated to vaporizes Cu(hfac) TMVS.

In some other embodiments, an electroless plating process is performed to form the conductive layer120over the exposed surface of the seed layer106. In some embodiments, a platinum (Pt) layer is formed as a seed layer106, and a copper conductive layer120is formed over the platinum seed layer106by electroless plating process. The copper conductive layer120is formed by using a copper containing solution, and the copper containing solution includes CuSO4.5H2O.

In some embodiments, a pre-clean process is performed on the exposed surface of the seed layer106to clean the exposed surface.

The conductive layer120has a first height H1which is measured from the top surface of the seed layer106to the top surface of the conductive layer120. The pattered hard mask layer110has a second height H2which is measured from the top surface of the seed layer106to the top surface of the pattered hard mask layer110. In some embodiments, the first height H1is smaller than or equal to the second height H2. In some embodiments, the top surface of the conductive layer120is level with or lower than a top surface of the patterned hard mask layer110.

Afterwards, the pattered hard mask layer110is removed by a first etching process to expose a portion of the seed layer106, as shown inFIG. 1D, in accordance with some embodiments of the disclosure. Because the conductive layer120has a highly etching selectivity in relation to the hard mask layer110, the conductive layer120is not removed during the first etching process. In other words, the conductive layer120has a lower etching rate in relation to that of the hard mask layer110.

The first etching process may be a dry etching process, a wet etching process or a combination thereof. In some embodiments, the first etching process is a dry etching process, the dry etching process includes an oxygen-containing gas, a fluorine-containing gas (e.g. CF4, SF6, CH2F2, CHF3and/or C2F6), a chlorine-containing gas (e.g. Cl2, CHCl3, CCl4, and/or BCl3), a bromine-containing gas (e.g. HBr and/or CHBr3), another applicable gas, or a combination thereof. In some embodiments, the first etching process is a wet etching process, and the wet etching process includes an aqueous alkaline solution, an amine-solvent mixture, or an organic solvent.

Afterwards, the exposed portion of the seed layer106and a portion of the target layer104are removed by using the conductive layer120as a mask, as shown inFIG. 1E, in accordance with some embodiments of the disclosure. In some embodiments, the exposed portion of the seed layer106is removed by a second etching process, and the portion of the target layer104is removed by a third etching process. The second etching process and the third etching process independently includes a dry etching process, a wet etching process or a combinations thereof.

The etching rate of the target layer104is faster than that of the conductive layer120. As a result, the desirable pattern dimensions of the target layer104are well preserved. The pattern dimensions may be, for example, the distance of line end to line end, a critical dimension (CD) of the semiconductor device structure. Therefore, the embodiments of the disclosure provide a better performance in pattern transfer.

Afterwards, the conductive layer120and the seed layer106underlying the conductive layer120are removed, as shown inFIG. 1F, in accordance with some embodiments of the disclosure. As a result, the target layer104is patterned to have a desirable pattern. The conductive layer120and the seed layer106underlying the conductive layer120are removed by a multiple etching process.

FIGS. 2A-2Gshow cross-sectional representations of various stages of forming a semiconductor device structure100b, in accordance with some embodiments of the disclosure. The semiconductor device structure100bis similar to, or the same as, the semiconductor device structure100ashown inFIG. 1F, except that a gate structure210is formed in the target layer104. Processes and materials used to form the semiconductor device structure100bmay be similar to, or the same as, those used to form the semiconductor device structure100aand are not repeated herein.

As shown inFIG. 2A, the target layer104is formed over the substrate102, and the gate structure210is formed in the target layer104. In some embodiments, the target layer104is a dielectric layer, such as an inter-layer dielectric (ILD) layer. Afterwards, the seed layer106and the hard mask layer110are sequentially formed over the target layer104. The gate structure210includes a gate dielectric layer204and a gate electrode layer206over the gate dielectric layer204. The spacers212are formed on opposite sidewalls of the gate structure210. The source/drain (S/D) structures214are formed in the substrate102and adjacent to the gate structure210.

An isolation structure208, such as shallow trench isolation (STI) feature or local oxidation of silicon (LOCOS) feature is formed in the substrate102. The isolation structure208may define and isolate various device elements.

Afterwards, the hard mask layer110is patterned to expose a portion of the seed layer106, as shown inFIG. 2B, in accordance with some embodiments of the disclosure. Therefore, the openings111are formed in the patterned hard mask layer110.

Afterwards, the conductive layer120is formed in the openings111, as shown inFIG. 2C, in accordance with some embodiments of the disclosure. The conductive layer120is formed over the seed layer106. More specifically, the conductive layer120is formed directly on the exposed seed layer106. In some embodiments, the top surface of the conductive layer120is leveled with or lower than the top surface of the patterned hard mask layer110.

In some embodiments, the conductive layer120is formed by a selective deposition process, such as selective CVD process or selective electroless plating process. In some embodiments, the conductive layer120is deposited only on a selected surface of the seed layer106by the selective CVD process, but is not formed over the hard mask layer110.

Since the conductive layer120is not formed over the hard mask layer110, no additional removal operation is needed to remove the excess of the conductive layer120. Therefore, no CMP process or etching-back process is performed between the etching operation for removing the hard mask layer110and the deposition operation for forming the conductive layer120. Therefore, the fabrication process is easy, and time and cost of the fabrication method are reduced.

Afterwards, the patterned hard mask layer110is removed, as shown inFIG. 2D, in accordance with some embodiments of the disclosure. The conductive layer120has a high etching selectivity in relation to the hard mask layer110, and therefore, the hard mask layer110is removed but the conductive layer120is left.

The performance of pattern transferring is affected by the well preserved profile of the conductive layer. Because the conductive layer120has a high etching selectivity, the profile of the conductive layer120is well preserved. The underlying layers (such as target layer104) below the conductive layer120are well protected. Therefore, the profile of the conductive layer120is well transferred to the underlying layer (such as target layer104).

Afterwards, a portion of the seed layer106and a portion of the target layer104are removed, as shown inFIG. 2E, in accordance with some embodiments of the disclosure. The portion of the seed layer106and the portion of the target layer104are removed by using the conductive layer120as a mask. Therefore, the target layer104is patterned to form a trench215.

Afterwards, the conductive layer120and the seed layer106are removed, as shown inFIG. 2F, in accordance with some embodiments of the disclosure. The top surface of the S/D structure214is exposed by the trench215.

Afterwards, a conductive material is filled into the trench215and over the target layer104, as shown inFIG. 2G, in accordance with some embodiments of the disclosure. Afterwards, a polishing process is performed to remove the conductive material out of the trench215. Therefore, a contact structure220is formed and is electrically connected to the S/D structure214.

FIGS. 3A-3Gshow cross-sectional representations of various stages of forming a semiconductor device structure100c, in accordance with some embodiments of the disclosure. The semiconductor device structure100cis similar to, or the same as, the semiconductor device structure100bshown inFIG. 2G, except that an interconnect structure360(shown inFIG. 3G) is formed over the gate structure. Processes and materials used to form semiconductor device structure100cmay be similar to, or the same as, those used to form the semiconductor device structure100band are not repeated herein.

Referring toFIG. 3A, a first dielectric layer302is formed over the substrate102. The gate structure210including the gate dielectric layer204and the gate electrode layer206is formed in the first dielectric layer302. The isolation structure208is formed in the substrate102to isolate two adjacent gate structures210. The spacers212are formed on the opposite sidewalls of the gate structure210. The S/D structures214are formed in the substrate102and adjacent to the spacers212.

A first conductive layer218is formed in the first dielectric layer302and over the gate structure110. In some embodiments, the first conductive layer218is made of copper (Cu), copper alloy, aluminum (Al), aluminum alloy, tungsten (W), tungsten alloy, titanium (Ti), titanium alloy, tantalum (Ta) or tantalum alloy. In some embodiments, first conductive layer218is formed by a plating method.

A second dielectric layer304is formed over the first dielectric layer302. The second dielectric layer304is made of silicon oxide (SiOx), silicon nitride (SixNy), silicon oxynitride (SiON), or dielectric material(s) with low dielectric constant (low-k). In some embodiments, the second dielectric layer304is made of an extreme low-k (ELK) dielectric material with a dielectric constant (k) less than about 2.5. In some embodiments, ELK dielectric materials include carbon doped silicon oxide, amorphous fluorinated carbon, parylene, bis-benzocyclobutenes (BCB), polytetrafluoroethylene (PTFE) (Teflon), or silicon oxycarbide polymers (SiOC). In some embodiments, ELK dielectric materials include a porous version of an existing dielectric material, such as hydrogen silsesquioxane (HSQ), porous methyl silsesquioxane (MSQ), porous polyarylether (PAE), porous SiLK, or porous silicon oxide (SiO2).

A second conductive layer306is formed in the second dielectric layer304. The second conductive layer306is electrically connected to the first conductive layer218. In some embodiments, the second conductive layer306is made of copper (Cu), copper alloy, aluminum (Al), aluminum alloy, tungsten (W), tungsten alloy, titanium (Ti), titanium alloy, tantalum (Ta) or tantalum alloy.

A first etch stop layer308is formed over the second dielectric layer304. The first etch stop layer308may be a single layer or multiple layers. The first etch stop layer308is made of silicon oxide (SiOx), silicon carbide (SiC), silicon nitride (SixNy), silicon carbonitride (SiCN), silicon oxycarbide (SiOC), silicon oxycarbon nitride (SiOCN), or another applicable material. In some embodiments, the first etch stop layer308has a bi-layer structure which includes a silicon oxide (SiOx) layer formed on a SiC layer, and silicon oxide layer is formed from tetraethyl orthosilicate (TEOS). The SiC layer is used as a glue layer to improve adhesion between the underlying layer and silicon oxide layer.

The third dielectric layer314is formed on first etch stop layer308. The third dielectric layer314may be a single layer or multiple layers. The third dielectric layer314is made of silicon oxide (SiOx), silicon nitride (SixNy), silicon oxynitride (SiON), or dielectric material(s) with low dielectric constant (low-k).

A second etch stop layer318and a hard mask layer320are sequentially formed on the third dielectric layer314. The hard mask layer320is then patterned to form the patterned hard mask layer320.

Afterwards, a fourth dielectric layer324is formed over the second etch stop layer318and the hard mask layer320, as shown inFIG. 3B, in accordance with some embodiments of the disclosure. Next, the seed layer106is formed over the fourth dielectric layer324, and the hard mask layer110is formed over the seed layer106. The hard mask layer110is patterned to form the opening (not shown) and then the conductive layer120is formed in opening. As mentioned above, the conductive layer120is selectively formed on the seed layer106.

Afterwards, the hard mask layer110is removed, as shown inFIG. 3C, in accordance with some embodiments of the disclosure. Due to the conductive layer120has a high etching selectivity in relation to the hard mask layer110, the conductive layer120is left while the hard mask layer110is removed.

Afterwards, the seed layer106, the fourth dielectric layer324, the second etch stop layer318and the third dielectric layer314are sequentially removed, as shown inFIG. 3D, in accordance with some embodiments of the disclosure. Therefore, a first hole335aand a second hole335bare formed in the third dielectric layer314. In some embodiments, the seed layer106, the fourth dielectric layer324, the second etch stop layer318and the third dielectric layer314are sequentially removed by a multiple etching processes.

Afterwards, the conductive layer120, the seed layer106and the fourth dielectric layer324are sequentially removed, as shown inFIG. 3E, in accordance with some embodiments of the disclosure.

Afterwards, a portion of the second etch stop layer318and a portion of the third dielectric layer314are sequentially removed by using the hard mask layer320as a mask, as shown inFIG. 3F, in accordance with some embodiments of the disclosure. As a result, a first trench-via structure345aand a second trench-via structure345bare formed in the third dielectric layer314to use as dual damascene cavities.

Afterwards, the a diffusion barrier layer350is formed in first trench-via structure345aand the second trench-via structure345b, and a third conductive structure352is formed on the diffusion barrier layer350, as shown inFIG. 3G, in accordance with some embodiments of the disclosure. An interconnect structure360is formed over the first dielectric layer302. The interconnect structure360is formed by the second dielectric layer304, the second conductive layer306, the third dielectric layer314and the third conductive structure352.

The diffusion barrier layer350may be made of titanium (Ti), titanium nitride (TiN), tantalum (Ta), tantalum nitride (TaN), or aluminum nitride (AlN). In some embodiments, the third conductive structure352is made of copper, and the diffusion barrier layer350includes TaN/Ta bi-layer.

FIGS. 4A-4Hshow cross-sectional representations of various stages of forming a semiconductor device structure100d, in accordance with some embodiments of the disclosure. The semiconductor device structure100dis similar to, or the same as, the semiconductor device structure100ashown inFIG. 1F, except that a 3D fin structure410(shown inFIG. 4F) is extended from above the substrate102. Processes and materials used to form semiconductor device structure100dmay be similar to, or the same as, those used to form the semiconductor device structure100aand are not repeated herein.

Referring toFIG. 4A, the substrate102is provided, and the seed layer106is formed over the substrate102. In some embodiments, the substrate102is a silicon wafer.

Afterwards, the hard mask layer110is formed over the seed layer106. Next, the hard mask layer110is patterned to form the opening111, as shown inFIG. 4B, in accordance with some embodiments of the disclosure. The top surface of the seed layer106is exposed by the opening111.

Afterwards, the conductive layer120is formed in the opening111, as shown inFIG. 4C, in accordance with some embodiments of the disclosure. The top surface of the conductive layer120is level with or lower than the top surface of the hard mask layer110. In some embodiments, the conductive layer120is formed by a selective deposition process, such as a selective CVD process or a selective electroless plating process. The conductive layer120is selectively formed on the seed layer106, but not formed on the hard mask layer110.

Afterwards, the hard mask layer110is removed to expose a portion of the seed layer106, as shown inFIG. 4D, in accordance with some embodiments of the disclosure. The conductive layer120has a high etching selectivity in relation to the hard mask layer110. The etching rate of the hard mask layer110is higher than that of the conductive layer120.

Afterwards, a portion of the seed layer106and a portion of the substrate102are removed by using the conductive layer120as a mask, as shown inFIG. 4E, in accordance with some embodiments of the disclosure.

Afterwards, the conductive layer120and remaining seed layer106below the conductive layer120are removed, as shown inFIG. 4F, in accordance with some embodiments of the disclosure. As a result, a fin structure410is obtained. The fin structure410is extended above from the substrate102.

Afterwards, an isolation structure408is formed over the substrate102, as shown inFIG. 4G, in accordance with some embodiments of the disclosure. The bottom portion of the fin structure410is embedded in the isolation structure408.

Afterwards, a gate structure420is formed over a middle portion of the fin structure410, as shown inFIG. 4H, in accordance with some embodiments of the disclosure. The gate structure420includes a gate dielectric layer412and a gate electrode layer414. Spacers416are formed on opposite sidewalls of the gate structure420. The gate structure420traverses the fin structure410.

As mentioned above, the conductive layer120is selectively formed in the specific region, such as the exposed surface of the seed layer106. The conductive layer120is formed by selective deposition process, for example, selective CVD process or selective electroless plating process. Since the conductive layer120is self-aligned, no conductive layer is formed over the hard mask layer110. Therefore, no removal operation is performed between deposition process of the conductive layer and removing process of the hard mask layer. Furthermore, the voids may not be formed in the conductive layer120.

Embodiments for forming a semiconductor device structure and method for formation of the same are provided. A target layer is formed over a substrate, and a seed layer is formed over the target layer. A hard mask layer is formed over the seed layer and is pattered to form an opening. A conductive layer is selectively formed in the opening. The target layer is patterned by using a conductive layer as a mask. The conductive layer is selectively formed on the seed layer by a selective deposition process. The conductive layer is self-aligned, and no extra removing process is needed to remove the excess metal material. Therefore, the fabrication process and time for forming the semiconductor device structure are reduced.

In some embodiments, a method for forming a semiconductor device structure is provided. The method includes forming a target layer over a substrate and forming a seed layer over the target layer. The method includes forming a hard mask layer over the seed layer, and the hard mask layer includes an opening to expose a portion of the seed layer. The method includes forming a conductive layer in the opening, and the conductive layer is selectively formed on the portion of the seed layer. The method includes etching a portion of the target layer by using the conductive layer as a mask.

In some embodiments, a method for forming a semiconductor device structure is provided. The method includes forming a gate structure over a substrate and forming a source/drain (S/D) structure in the substrate and adjacent to the gate structure. The method includes forming a first dielectric layer over the gate structure and forming a seed layer over the dielectric layer. The method include forming a first hard mask layer over the seed layer, and the first hard mask layer has a plurality of openings. The method includes forming a conductive layer in the openings and removing the patterned first hard mask layer. The method includes removing a portion of the first dielectric layer by using the conductive layer as a mask to form a trench in the dielectric layer.

In some embodiments, a method for forming a semiconductor device structure is provided. The method includes forming a seed layer over a substrate. The method includes forming a hard mask layer over the seed layer, and the hard mask layer has an opening. The method includes forming a conductive layer in the opening, and the conductive layer is not formed over the hard mask layer. The method includes etching a portion of the substrate by using the conductive layer as a mask to form a fin structure, and the fin structure is extended above the substrate.