Delay detonator device

A reliable delay detonator device is disclosed which is thermally and chemically stable and which is also insensitive to mechanical shock and electrostatic charge. The device can be made with differing time delays and can be interconnected with other detonator devices for achieving multiple delay characteristics. A modification of the device is particularly suited to high temperature use. None of the devices contain any primary explosives, the device relying upon pyrotechnic delay materials and secondary explosives.

This invention generally relates to improved delay detonator devices and, 
more particularly, to delayed detonator devices which contain only 
pyrotechnic materials and secondary explosives. 
There has been a continuing effort in designing a reliable detonator device 
that contains no primary explosives for military use as well as commercial 
applications. The absence of primary explosives greatly reduces the 
hazards that are typically associated with detonators. By incorporating 
pyrotechnic materials and secondary type explosives in such detonators, 
they are significantly less vulnerable to the possibility of detonation 
due to mechanical shock or static electrical discharge. While there has 
been considerable research and development of an all secondary explosive 
detonator devices, difficulty has been experienced in designing and 
building a device that has any significant reliability. One such reliable 
all secondary explosive nondelay detonator device is disclosed in U.S. 
Pat. No. 3,978,791, by Lemley, et al., which is assigned to the same 
assignee as the present invention. 
While the Lemley, et al. patent is directed to an instantaneous firing 
detonator device, the safety considerations that are disclosed therein are 
also applicable to a detonator device that is fired after a predetermined 
time delay. Because delay detonators that are currently used incorporate 
sensitive igniter mixes, they suffer from the same type of problems that 
are experienced with instantaneously acting detonator devices that utilize 
primary explosives, i.e., they are relatively sensitive to mechanical 
shock, heat, static electric discharge and the like. 
Accordingly, it is an object of the present invention to provide a 
detonator device that has an absence of primary explosive which has delay 
capability and which is reliable in its operation. 
Yet another object of the present invention is to provide a delay detonator 
which is adapted for use in detonation-pyrotechnic delay-detonation delay 
trains. 
Still another object of the present invention is to provide a delay 
detonator that is reliable in its operation at elevated temperatures, 
i.e., temperatures approaching 600.degree. F.

Turning now to the drawings and particularly FIGS. 1 and 2, one embodiment 
of the delay detonator device of the present invention, indicated 
generally at 10, comprises a generally cylindrically shaped body 12 having 
internal threads 14 and 16 at opposite end portions thereof, with the 
threads 14 receiving an insert portion 18 with outer threads 20 engaging 
the threads 14. When the insert portion 18 is fully inserted to the 
position as shown, the detonator device 10 has an internal chamber 22 
which communicates with a first bore 24 that has an internal diameter that 
is less than the diameter of the chamber 22. A second insert 26 may be 
positioned at the opposite end of the bore 24 and contain an acceptor 
charge 28 of secondary explosive for detonating a main charge of 
explosive. The insert 26 shown has the charge 28 in an outwardly flared 
conical configuration in line with the bore 24. The insert 26 has outer 
threads 30 for engaging the inner threads 16, and may be removed in favor 
of a fuse element which may be positioned within the bore 24 for providing 
a multiple delay train as will be hereinafter described. 
Referring again to the internal chamber 22, an impactor disk 32 is located 
adjacent the bore 24 abutting against the end of the chamber. The surface 
against which the disk abuts is in the shape of a flat annular shoulder 34 
having a radial width that is defined by the difference in the internal 
diameters of the chamber and the bore 24. A charge of secondary explosive 
36 is positioned adjacent the impactor disk 32 and another charge 38 of a 
pyrotechnic delay mixture is positioned adjacent the donor secondary 
explosive charge. A bridge wire 40 that is connected at opposite ends to 
conductors 42 provides the means for initiating the detonator device and 
may operate in accordance with the well known technique, initiation by a 
hot wire. Layers of header insulation 44 and header backing 46 are 
positioned near the delay mixture 38 and the backing layers have apertures 
through which the conductors 42 penetrate into the delay mixture charge. 
Broadly stated, the operation of the detonator device results in the 
acceptor charge 28 being detonated when the bridge wire 40 is energized to 
ignite the delay mixture charge 38 which, due to its slow burning 
characteristic, undergoes a time delay before it initiates deflagration of 
the donor secondary explosive charge 36. The deflagration of the donor 
charge 36 produces a high pressure within the chamber that causes the 
interior central portion of the impactor disk 32 (coextensive within 
inside diameter of the bore 24) to be sheared from the disk and be 
accelerated down the bore with sufficient velocity to detonate the 
acceptor explosive 28. 
The reliability in the operation of the detonator device is partially 
attributable to the proper confinement of the secondary explosive charge 
36 so that complete deflagration occurs. If the secondary explosive charge 
is not completely deflagrated, the ultimate pressure that is produced in 
the chamber will vary from device to device with the result that 
insufficient pressure may not be generated. If the pressure is 
insufficient, the central portion may be sheared from the impactor disk 
but may not acquire the necessary travelling speed when it impacts with 
the secondary explosive and may be insufficient to cause detonation 
thereof. Thus, the donor explosive must be chosen so that it will be 
self-sustaining after ignition and undergo complete deflagration so that 
the requisite pressures are produced. 
In keeping with the present invention, the donor secondary explosive charge 
36, as well as the acceptor secondary explosive charge 28, are preferably 
made of RDX, PBXN-5, PETN, HMX or other secondary explosives which will 
sustain complete deflagration. The preferred secondary explosive is RDX 
explosive, type B, class C, military standard MIL-R-398C having a particle 
size of about 100 microns, and pressed to about 12,500 p.s.i. pressure to 
achieve a density of about 1.65 to about 1.67 and preferably about 1.65 
grams/cc. Its chemical composition is 1, 3, 5-trinitro-1, 3, 
5-triazacyclohexane and is made by the acetic anhydride process. 
The PBXN-5 explosive made in accordance with military standard MIL-E-81111 
and having a particle size of 20 microns per military standard RR-S-366 is 
pressed to a density of about 1.67 grams/cc. PBXN-5 consists of about 4.5% 
to about 5.5% by weight of the copolymer vinylidene fluoride and 
hexafluoropropylene, with the remainder being HMX explosive, which is 1, 
3, 5, 7-tetranitro-1, 3, 5, 7-tetrazacyclo-octane. While both the RDX and 
PBXN-5 explosives may be used for the donor explosive, the RDX explosive 
is preferred, and, the PBXN-5 is preferred for the acceptor secondary 
explosive charge 28. 
In accordance with an important aspect of the present invention, when the 
RDX explosive is used as the donor explosive charge 36, its complete 
deflagration is reliably assured when it is tightly confined. Thus, the 
chamber 22 should be completely filled as shown in FIG. 1. Since the 
header materials 44 and 46 are solid and do not appreciably relieve any 
high pressure when the charges within the chamber are activated, it should 
be appreciated that confinement of the donor explosive will be maintained 
if the delay mixture 38 burns without any appreciable pressure change. It 
is important that the delay mixture charge 38 undergo burning without 
significantly increasing the pressure within the chamber and, accordingly, 
a non-gassing delay mixture is preferred. In this regard, a pyrotechnic 
mixture that is non-gassing and has burn speed characteristics that are 
suitable for the particular application of use have been found quite 
acceptable. Pyrotechnic delay mixtures can be formulated with differing 
burn rates so that the ultimate time delay that is experienced can be 
tailored to various applications. In this regard, delay mixtures that are 
suitable for the charge 38 are preferably series I through V mixtures made 
in accordance with military standard MIL-T-23132A (A.S.) dated June 16, 
1972. More specifically, one such mixture, designated "W-1" is formulated 
from 30% tungsten powder having a particle size of from 5 to 10 microns, 
56% barium chromate, 9% potassium perchlorate and 5% diatomaceous earth. 
This delay mixture is pressed to a density of about 20,000 p.s.i. and is a 
series IV delay mixture having a burn rate within the range of about 28 to 
about 33 seconds/inch and generally about 32 seconds/inch. Another slow 
burning delay mixture, designated "W-2" comprises 34% tungsten powder with 
a particle size of about 2 1/2 to 5 microns, 52% barium chromate, 9% 
potassium perchlorate and 5% diatomaceous earth. This delay mixture is a 
series III mixture and has a burn rate within the range of about 5 to 
about 28 seconds/inch and generally about 18 seconds/inch. Still another 
delay mixture, designated "W-3", is significantly faster than the above 
described mixtures and comprises about 58% tungsten powder having a 
particle size of less than 1 micron, 32% barium chromate, 5% potassium 
perchlorate and 5% diatomaceous earth. This mixture is a series I mixture 
and has a burn rate of about 0.38 seconds/inch. 
Each of these pyrotechnic delay mixtures can be used as the delay mixture 
charge 38 in the chamber 22 because they burn without appreciably 
generating gases, i.e., they are nongassing, and therefore do not 
appreciably increase the pressure within the chamber prior to initiating 
deflagration of the donor charge 36. 
In keeping with the present invention and referring to the impactor disk 
32, the pressure that is required to achieve the shearing of the central 
portion from the impactor disk is a function of the physical 
characteristics of the material from which the disk is made as well as the 
physical dimensions and configuration of the disk. With the material 
composition and physical characteristics that are contemplated for the 
disk, a pressure approaching 50,000 p.s.i. generated by the deflagration 
of the donor charge 36 is sufficient to shear the central portion from the 
disk 32 and propel it through the bore 24 with sufficient velocity to 
detonate the acceptor secondary explosive 28. 
As is fully described in the Lemley, et al. patent, the detonation of the 
acceptor secondary explosive produced by the impact or shock of the 
central portion of the impactor disk 32 is a function of the interaction 
pressure between the explosive and the central portion of the disk. 
However, pressure is not the only parameter that produces a high order 
detonation of explosive. Other parameters include the time in which the 
pressure acts as well as the distance that the pressure wave travels into 
the explosive and the effect of simultaneous impact of the acceptor 
explosive 28 and its holder, insert 26. Thus, if the area of impact is 
quite small, as might occur in the event the central portion disintegrated 
into a number of fragments, release waves would move in to relieve the 
high pressure and would thereby shorten the time in which the initial 
pressure would be applied to the explosive. If the time in which the 
pressure is applied is of insufficient duration, detonation may not be 
achieved. Each type of explosive has its own limit of combined pressure 
and initiation distance that is required to achieve a high order 
detonation and these limits are determined by the chemical composition and 
physical properties of the particular explosive that is used. 
Turning now to the impactor disk 32, it should be made from a material 
having the physical characteristics that would enable the central portion 
thereof to be sheared from the outer annular portion that is supported by 
the annular shoulder 34 and be accelerated through the bore 24 so that it 
can attain an impact velocity of at least about 1 millimeter per 
microsecond. The length of the bore 24 through which the pressure acts on 
the accelerating central portion is an important parameter in providing 
the requisite velocity upon impact for causing detonation. A bore length 
within the range of about 0.160 to about 0.425 inch has been found to be 
acceptable for devices having an outer diameter of about 0.3 inch, a 
length of about 1.1 inches. With a pressure of about 50,000 p.s.i. 
generated within the chamber 22, an impactor disk having a thickness of 
about 0.050 inch and a ratio of thickness to the diameter of the central 
portion within the range of about 0.4 to about 0.5 provides reliable 
operation in that the central portion can be sheared and accelerated as a 
unitary piece toward and impact squarely the secondary acceptor charge 28 
and its holder, insert 26. In this regard, it is also important that the 
accelerated central portion not only maintain its structure integrity, 
i.e., it does not disintegrate into small fragments, but that it travel 
down the bore without tumbling. If the central portion tumbles, it will 
permit pressure to escape between this moving portion and the bore wall 
which will result in slower ultimate speed upon impact, depending upon the 
amount of pressure loss that is experienced. By using a ratio of thickness 
to diameter within the prescribed range, the tendency for tumbling of the 
central portion during its travel down the bore is substantially 
minimized. When stronger materials such as titanium alloys are used for 
the impactor disk, the central portion may be thicker than the annular 
portion from which the central portion shears. Such stronger materials may 
require a reduced thickness to permit shearing of the central portion with 
the contemplated chamber pressures that are developed. 
A preferred material for the impactor disk 32 is either titanium or certain 
aluminum alloys, such as type 6061-T6 or 5052-H32 aluminum alloys, 
although other materials having similar mechanical properties to the above 
may be used. The mechanical, tensile and other physical properties for 
aluminum alloys are listed in the First Edition of Aluminum Standards and 
Data, April, 1968 published by the Aluminum Associates, New York, New 
York. More specifically, with respect to the 6061-T6 aluminum alloy, it 
has a composition of about 0.4 to 0.8% silicon, about 0.7% iron, about 
0.15 to about 0.40% copper, about 0.15% manganese, about 0.8 to about 1.2% 
magnesium, about 0.04 to about 0.35% chromium, about 0.25% zinc, about 
0.15% titanium and the remainder aluminum. The 6061-T6 aluminum alloy has 
a tensile strength of about 45 ksi, a Brinell hardness number of about 95, 
an ultimate shearing strength of about 27 ksi, a modulus of elasticity of 
about 10.sup.7 p.s.i. and a density of about 169 pounds per cubic foot. 
When the impactor disk 32 is fabricated from materials that are 
sustantially similar in their mechanical properties and if the thickness 
to diameter ratio of the travelling central portion is within the desired 
range, it moves through the bore in a manner quite similar to a piston 
within a cylinder. With the prescribed thickness to diameter ratio, 
tumbling is substantially prevented which thereby limits pressure loss or 
"blowby" and maximizes the reliability of the device. When the central 
portion impacts the secondary explosive as a unitary piece, pressure 
release waves cannot be produced as quickly and the impact pressure is 
therefore sustained over a longer period of time which contributes to more 
reliable detonation. 
As previously mentioned, the ignition means may be a low voltage hot wire 
technique as disclosed in the aforementioned Lemley, et al. patent which 
utilizes a low voltage current through the bridge wire 40 that is 
sufficient to initiate burning of the pyrotechnic delay mixture charge 38. 
By using the tungsten powder delay mixture composition W-3, which has a 
burning time of 0.38 seconds per inch, delays from about 8 to about 30 
milliseconds have been experienced. When using the W-1 and W-2 mixtures, 
delay periods from several milliseconds to several seconds can be 
achieved. In this regard, the burn rate of the W-1 mixture is nearly half 
that of the W-2 mixture, i.e., 32 seconds/inch versus 18 seconds/inch. 
Turning now to another embodiment of the present invention shown in FIG. 3, 
it is particularly suited for use in applications where multiple time 
delays are desired and utilizes a detonation to pyrotechnic delay to 
detonation action, all of which occur without primary explosive. The delay 
device, indicated generally at 60, comprises a body 62 and an insert 64 
that is threadably coupled to the body by threads 66 and 68. A chamber 70 
is provided and a bore 72 is located in the body 62. An impactor disk 74 
is positioned adjacent the bore against an annular shelf 76. A donor 
explosive charge 78 and a delay mixture charge 80 are positioned within 
the chamber, substantially filling the same. The relative positions and 
operational considerations of the bore, impactor disk, donor and delay 
mixture charges shown in FIG. 3 are substantially similar to that 
previously described with respect to similar components of the detonator 
device 10. When the delay mixture is initiated and burns until it 
initiates deflagration of the donor explosive, the requisite high 
pressures are created to shear out the central portion of the impactor 
disk and accelerate it down the bore 72. However, it is apparent that an 
acceptor charge 28 is not present in the embodiment of FIG. 3, it being 
replaced with a mild detonating fuse (MDF) 82 that is inserted within the 
bore 72 so that the impact by the central portion will detonate the MDF 
fuse. Another mild detonating fuse 84 is positioned within a bore 86 of 
the insert 64. The bore 86 has a conical section 88 which terminates in a 
smaller aperture 90 that communicates the bore 86 with the chamber 70. The 
mild detonating fuses 82 and 84 are of conventional construction and may 
consist of a suitably sheathed cylinder 92, having an outer diameter of 
about 1/16 inch and containing explosive such as RDX, PETN, HMX or other 
explosive material which is protected by an outer sleeve 94 of stainless 
steel or the like having an outside diameter of about 1/8 inch. The end of 
the MDF 84 terminating near the conical portion 88 of the bore 86 has the 
protective sleeve terminating before the sheath of explosive material so 
that the explosive material comes in contact with a small charge of 
secondary explosive 96 which extends through the aperture 90 into the 
chamber 70 near a valve plate 98 which will be discussed in detail. The 
explosive 96 must be capable of sustaining deflagration through the 
aperture 90 which may be only about 0.025 in diameter. A PETN explosive or 
PETN based explosive is preferred, such as PYROCORE explosive as 
manufactured by the E.I. duPont de Nemours and Company of Wilmington, 
Delaware. PETN, pentaerythritol tetranitrate, powder is pressed to about 
20,000 p.s.i. 
During operation, the MDF 84 will ignite the charge 96 which will in turn 
burn through the aperture 90 into the chamber and ignite the delay mixture 
charge 80 which, after a suitable delay will initiate deflagration of the 
donor charge 78 which will result in the shearing of the central portion 
from the impactor disk 74 and cause it to travel down the bore 72 and 
detonate the other MDF 82 which can then detonate any explosive charge 
when properly boosted. An acceptor charge such as the acceptor charge 28 
described with respect to the detonator 10 shown in FIG. 1 can be situated 
at the end of the bore 72 in place of the MDF assembly 82 and detonated as 
previously described. The overall length of the device 60, excluding the 
MDF's 82 and 84 is preferably about 1 1/4 inches to about 11/2 inches with 
an overall diameter of about 1/2 inch, although a larger or smaller device 
is contemplated to be within the scope of the invention. 
In accordance with an important aspect of the invention embodied in FIG. 3, 
the confinement of the donor secondary explosive charge 78 should be 
maintained, as previously described with respect to the embodiment in FIG. 
1. Thus, the delay mixture 80 must be burned without appreciably changing 
the internal volume or pressure within the chamber and should accordingly 
be non-gassing as was the case with respect to the delay mixture charge 38 
of the detonator 10. To maintain the confinement within the chamber 62, 
the valve plate 98 is preferably used to close the aperture 90 which 
communicates the chamber 70 with the bore 86. The valve plate 98 is spaced 
away from the end of the chamber containing the aperture 90 by the 
presence of the charge 96. During operation, the burning of the secondary 
explosive charge 96 begins at the interface with the MDF 92 and burns to 
the right as shown in FIG. 3, through the aperture 90 and radially 
outwardly around the valve plate until it initiates burning of the delay 
mixture 80. The valve plate 98 is sized so that it covers the aperture 90 
after the charge 96 has been burned and should be capable of sustaining 
the high temperatures that result from the burning of the delay mixture 
80. Also, it should be capable of sustaining a mild shock which occurs 
from the MDF 92 and also withstand the high pressures that are generated 
by the deflagration of the donor charge 78. In this regard, a high nickel 
alloy valve plate is preferred having a thickness on the order of about 
0.025 inch. A high nickel-copper alloy such as MONEL or a high 
nickel-chromium alloy such as INCONEL may be used. Both of these alloys 
are made by the International Nickel Corporation. The shape of the valve 
plate is preferably non-circular in that it preferably has radial outward 
extensions that define an overall effective diameter that approaches the 
inside diameter of the chamber. This permits a sufficient area between the 
inner edge of the plate and the wall of the chamber so that delay charge 
can be ignited and also have the outward extensions that can meet the wall 
and maintain the plate centered over the aperture. A square shaped valve 
plate with diagonal dimensions of about 0.2 inch has been effective to 
maintain the desired centering and also permit ignition of the delay 
mixture. The use of the plate, while preferred, is not absolutely critical 
to operation of the device, but it substantially reduces pressure loss 
that is experienced through the aperture. The use of the valve plate 
increases the reliability of the device in that the possibility of 
malfunction is reduced because of loss of pressure in the chamber. It 
should also be understood that the delay charge material may be sufficient 
to close the aperture in the absence of a valve plate, but the reliability 
of the device is somewhat diminished when this is expected to occur. 
Turning now to another embodiment of the invention shown in FIG. 4, a more 
economical detonating device, indicated generally at 100 is disclosed, 
which can be more easily made because of the absence of threads and 
multiple inserts and the like. The detonator device 100 has an integral 
body 102 which contains a chamber 104, an impactor disk 106, a donor 
explosive charge 108, a delay mixture charge 110 and a bridge wire 112 at 
the lower end of the delay charge 110. The impactor disk 106 abuts against 
an annular shoulder 114 and a bore 116 extends to an acceptor charge 118 
that is also held within the body 102. A sealing cap 120 may be provided 
at the outer exposed end of the acceptor charge. The opposite ends of the 
bridge wire 112 are connected to conductors 122 which extend through 
apertures within an insulating header 124 and header packing 126. A 
sealing material 128 is placed around the conductors 122 where they exit 
the body. The donor explosive 108 and the delay charge 110 are tightly 
confined by a swaging operation which can control the confinement pressure 
within the chamber and the swaging operating bends the outer wall of the 
body inwardly near the lower end as shown at 130. The operation of the 
detonator 100 is substantially similar to that described with respect to 
the detonator 10 shown in FIG. 1. 
In keeping with an important aspect of the invention as embodied in FIG. 3, 
it is particularly suited for use in high temperature applications, i.e., 
temperatures that may approach or even exceed 600.degree. F. When 
formulated for use at high temperatures, the donor charge is preferably a 
mixture of about 33% titanium hydride and about 67% potassium perchlorate 
which has been found to rapidly generate gas to produce sufficient 
pressure to shear out and accelerate the central portion of the impactor 
disk 106. Titanium hydride, as defined for the purposes of this document, 
has the formula TiH.sub.x. For this application the value x can vary from 
less than 1 to 2. The delay mixture charge 110 may be any of the 
pyrotechnic mixtures previously described, i.e., those designated as W-1, 
W-2 or W-3 mixtures, which can be ignited by the hot bridge wire 112. The 
acceptor charge 118 is preferably TACOT, which is tetranitrodibenzo-1, 3a, 
4, 6a tetraazapentalene, is manufactured by the E. I. duPont de Nemours 
and Company of Wilmington, Delaware. The thermal stability of these 
materials permit operating temperatures even exceeding 600.degree. F. for 
the delay detonator 100. 
From the foregoing detailed description, it should be apparent that various 
embodiments of significantly improved delay detonators have been described 
which exhibit many desirable attributes and advantages over prior delay 
detonator devices. The delay detonators embodying the present invention 
exhibit reliable operation with built in time delay and at least one 
embodiment can be used at elevated temperatures. The detonator devices 
avoid the use of either sensitive igniter mixes or primary explosives and 
are therefore relatively insensitive to heat, mechanical shock and static 
electricity. The ignition of the delay detonator with a mild detonating 
fuse enables multiple delays to be used with a single initiation source. 
While various embodiments of the invention have been illustrated and 
described, various modifications thereof will become apparent to those 
skilled in the art and, acccordingly, the scope of the present invention 
should be defined only by the appended claims and equivalents thereof. 
Various features of the invention are set forth in the following claims.