FILTERING MATERIAL FOR FILTER AND PRODUCTION PROCESS THEREFOR

A first papermaking raw material for an upper layer and a second papermaking raw material for a lower layer are subjected to papermaking so as to form a filtering material with a continuous density gradient from the upper layer to the lower layer. Each of the papermaking raw materials contains natural fibers such as pulp and chemical fibers such as PET. The content of the chemical fibers in the first papermaking raw material is higher than the content of the chemical fibers in the second papermaking raw material. The diameter of the chemical fibers in the first papermaking raw material is larger than the diameter of the chemical fibers in the second papermaking raw material. The thus-obtained filtering material is able to collect a wide size range of particles and is made less susceptible to clogging and longer in life.

FIELD OF THE INVENTION

The present invention relates to a filtering material for a filter usable in an air cleaner of an automotive internal combustion engine etc. and, more particularly, to an improvement of a filtering material produced by a wet papermaking process using natural fibers such as pulp or linter and chemical fibers such as polyester or rayon.

BACKGROUND ART

As a filtering material in e.g. an air cleaner of an automotive internal combustion engine, it is common to use a filter paper predominantly of natural fibers such as pulp or linter by folding the filter paper a plurality of times and accommodating the folded filter paper within a case. This filter paper is generally of single-layer structure. On the other hand, there has been put into practical use a composite filtering material of two-layer structure including, as schematically shown inFIG. 10, a lower layer21of a relatively high-density filter paper and an upper layer22of a relatively low-density nonwoven fabric or filter paper laminated on an upstream side of the lower layer21for improvement in filter life. It is noted that, inFIG. 10, the density or pore size of the respective layers are expressed by the size of holes.

In such a two-layer filtering material, large dust particles are collected by the upper layer22in the two-layer filtering material. The two-layer filtering material is thus less susceptible to clogging and longer in life than the single-layer filtering material. There is however a problem that the two-layer filtering material is likely to cause clogging at the interface between the two layers21and22as schematically shown inFIG. 11.

In view of the problem, Patent Document 1 proposes a process of producing a composite filter paper by feeding papermaking raw materials for upper and lower layers on a wire part of a papermaking machine in such a manner as to partially mix these papermaking raw materials and thereby create a continuous density gradient between the upper and lower layers.

It is disclosed in Patent Document 1 that linter fibers and rayon fibers are mixed at different mixing ratios and used as the papermaking raw materials for the upper and lower layers. However, the two-layer filtering material cannot always attain good performance only by the use of the same fibers at different mixing ratios. Although it is particularly required that the air cleaner of the automotive internal combustion engine combines dust collection performance against relatively large dust particles (as tested by e.g. particles of 7 μm) with carbon collection performance against very small carbon particles (e.g. soot of about 0.5 μm), the above conventional two-layer filtering material cannot attain good carbon collection performance.

PRIOR ART DOCUMENTS

Patent Documents

Patent Document 1: Japanese Patent Publication No. S53-17687

SUMMARY OF THE INVENTION

It is accordingly an object of the present invention to provide a filtering material capable of achieving both of collection efficiency and lift expectancy at high levels by the use of the production process of Patent Document 1.

There is provided according to the present invention a filtering material for a filter, comprising: first and second papermaking raw materials for forming upper and lower layers, respectively, so as to show a continuous density gradient from the upper layer to the lower layer, wherein each of the first and second papermaking raw materials contains natural fibers and chemical fibers; wherein the content of the chemical fibers in the first papermaking raw material is higher than the content of the chemical fibers in the second papermaking raw material; wherein the diameter of the chemical fibers in the first papermaking raw material is greater than the diameter of the chemical fibers in the second papermaking raw material; and wherein the filtering material has a basis weight of 60 to 250 g/m2.

There is also provided according to the present invention a process of producing a filtering material for a filter, comprising: preparing first and second papermaking raw materials, each of which contains natural fibers and chemical fibers wherein the content of the chemical fibers in the first papermaking raw material is higher than the content of the chemical fibers in the second papermaking raw material and wherein the diameter of the chemical fibers in the first papermaking raw material is greater than the diameter of the chemical fibers in the second papermaking raw material; and subjecting the first and second papermaking raw materials to papermaking, thereby forming the filtering material with an upper layer predominantly of the first papermaking raw material and a lower layer predominantly of the second papermaking raw material within a basis weight range of the filtering material from 60 to 250 g/m2by continuously changing a mixing ratio of the first and second papermaking raw materials from the upper layer to the lower layer.

In the present invention, both of the natural fibers such as pulp or linter and the chemical fibers such as polyester or rayon are contained in the first papermaking raw material. Similarly, both of the natural fibers and the chemical fibers are contained in the second papermaking raw material in the present invention. However, the natural fibers of the first papermaking raw material and the natural fibers of the second papermaking raw material are not necessarily of the same kind; and the chemical fibers of the first papermaking raw material and the chemical fibers of the second papermaking raw material are not necessarily of the same kind.

FIG. 1is a schematic view showing a process of producing the filtering material of the present invention by papermaking. There is no particular difference between the production process of the present invention and the production process of Patent Document 1. The first and second papermaking raw materials1and2are subjected to papermaking in a papermaking machine by feeding these papermaking raw materials1and2from respective separate head boxes (not shown) to a wire part of the papermaking machine. Herein, the wire part of the papermaking machine is constituted by a wire transfer drum3and a wire4. In the downstream side of a mixing ratio control plate5of the papermaking machine, the first and second papermaking raw materials1and2are placed on the wire4in a state of being partially mixed together without a clear interface defined therebetween. There is thus obtained the filtering material in which the mixing ratio of the first and second papermaking raw materials1and2is continuously changed from the upper layer to the lower layer. It is noted that, in the present invention, the terms “upper layer” and “lower layer” respectively refer to upstream- and downstream-side layers relative to the flow of a fluid to be filtered (in the case where the filtering material is used in the air cleaner, the flow of air to be filtered) and do not limit that the upper and lower layers must be situated on upper and lower sides during the papermaking process.

FIG. 2is a schematic view of the filtering material of the present invention. It is noted that, inFIG. 2, the density or pore size of the respective layers are expressed by the size of holes as in the case ofFIGS. 10 and 11. In the filtering material of the present invention, the density and pore size are gradually changed so that there exists no interface between the two layers. The filtering material of the present invention is thus basically unlikely to cause interface clogging.

Due to the fact that the chemical fibers are straight in comparison to the natural fibers such as pulp, the filtering material decreases in density by pore generation when the chemical fibers are contained in a large amount. Even in the case of the same kind of chemical fibers, such a density decrease effect is more pronounced when the chemical fibers are large in diameter. For these reasons, the papermaking process ofFIG. 1is performed in the present invention in such a manner that the mixing ratio of the first and second papermaking raw material is gradually changed so as to not only create a continuous density gradient between the upper and lower layers but also allow a larger amount of the large-diameter chemical fibers to exist in the upper layer and allow a larger amount of the small-diameter chemical fibers to exist in the lower layer. By such a configuration, it is possible to achieve collection efficiency and life expectancy (time elapsed until clogging) at high levels for both of dust collection performance against relatively large dust particles (as tested by e.g. particles of 7 μm) and carbon collection performance against very small carbon particles (e.g. soot of about 0.5 μm).

It is a preferred embodiment of the present invention that: the content of the chemical fibers in the first papermaking raw material is 10 to 80% (in terms of wt %; the same applies to the following); the diameter of the chemical fibers in the first papermaking raw material is 10 to 30 μm; the content of the chemical fibers in the second papermaking raw material is 60% or lower; and the diameter of the chemical fibers in the second papermaking raw material is 3 to 20 μm.

If the content of the chemical fibers in the upper layer is too low, the upper layer becomes low in porosity and cannot obtain a sufficient density decrease effect. If the content of the chemical fibers in the upper layer is too high, the upper layer becomes high in porosity and allows a flow of dust particles therethrough so that the function of the upper layer cannot be performed properly. The content of the chemical fibers in the upper layer is thus preferably in the range of 10 to 80%. On the other hand, it is necessary to contain a large amount of the natural fibers in the lower layer in order that the lower layer becomes higher in density than the upper layer to create a density gradient and in order that the filtering material can be easily pleated in the subsequent process step for use as e.g. an air cleaner element. The content of the chemical fibers in the lower layer is thus preferably in the range of 60% or lower. As mentioned above, the larger the diameter of the chemical fibers, the greater the effect of securing the pores and decreasing the density of the filtering material. Thus, the diameter of the chemical fibers in the upper layer is preferably in the range of 10 to 30 μm; and the diameter of the chemical diameter in the lower layer is preferably in the range of 3 to 20 μm.

The basis weight of the filtering material is highly correlated with the paper strength (material strength) and thickness of the filtering material as shown inFIG. 3. If the basis weight of the filtering material is less than 60 g/m2, the filtering material cannot attain a sufficient strength required for use as a filter such as air cleaner element. The basis weight of the filtering material is thus preferably 60 g/m2or more. The filtering material attains a high strength, but exceeds a given thickness and cannot secure a sufficient required filtration area (i.e. becomes too bulky) for installation as a pleated filter (air cleaner element etc.) in a case, if the basis weight of the filtering material is more than 250 g/m2. In addition, the filtering material becomes high in airflow resistance due too large thickness. The basis weight of the filtering material is thus preferably 250 g/m2or less.

It is preferable in the present invention that the first and second papermaking raw materials are contained at a basis weight ratio of 2:8 to 6:4.

In the case where the filtering material has a density gravity as in the present invention, the basis weigh ratio of the upper and lower layers is highly correlated with the filtration performance (expressed as dust holding capacity: DHC in the figure) and rigidity of the filtering material as shown inFIG. 5. As the proportion of the upstream-side low-density layer becomes increased, the filtering material improves in life with respect to dust collection performance. However, it is likely that the filtering material will deteriorate in rigidity and cause deterioration in filter performance (life and collection efficiency) due to adhesion of the filtering material if the proportion of the downstream-side high-density layer becomes too low. Thus, the basis weight ratio of the first and second papermaking raw materials is preferably in the range of 2:8 to 6:4 in view of the filtration performance and rigidity.

It is also preferable that the filtering material has a thickness of 0.4 to 1.5 mm. As shown inFIG. 6, the thickness of the filtering material is highly correlated with the filtration area and airflow resistance of the filtering material. The smaller the thickness of the filtering material, the larger the filtration area and the lower the airflow resistance in the same type of filter. The thickness of the filtering material is thus preferably smaller than or equal to 1.5 mm. In view of the strength, however, the thickness of the filtering material needs to be at least 0.4 mm.

Further, it is preferable that the filtering material has a density of 0.1 to 0.5 g/cm3. The density of the filtering material is highly correlated with the filtration performance of the filtering material as shown inFIG. 7. The lower the density of the filtering material, the longer the life of the filtering material until the occurrence of clogging. However, the lower the density of the filtering material, the lower the collection efficiency of the filtering material. The density of the filtering material is thus preferably in the range of 0.1 to 0.5 g/cm3in view of the balance between the life and collection efficiency.

As mentioned above, it is possible according to the present invention to provide the filtering material capable of filtering out a wide size range of particles, from fine particles like exhaust carbon particles to relatively large coarse dust particles, while securing a long life until the occurrence of clogging.

DESCRIPTION OF THE EMBODIMENTS

Hereinafter, specific embodiments of the present invention will be described in detail below. The following explanation will be given of the use of the filtering material in an air cleaner element of an automotive internal combustion engine by way of example.

As indicated in TABLE 1, a blend of 40% mercerized pulp as chemical fibers and 60% PET (polyethylene terephthalate) fibers of 18 μm diameter as natural fibers was prepared as a first paper raw material for an upper layer; and a blend of 35% mercerized pulp and 60% non-mercerized normal pulp as chemical fibers and 5% PET fibers of 9 um diameter as chemical fibers was prepared as a second papermaking raw material for a lower layer. It is herein noted that: the mercerized pulp, which has a curl by alkaline treatment, is more bulky and lower in density than the normal pulp; whereas the normal pulp is higher in strength than the mercerized pulp.

The above-mentioned wet papermaking process ofFIG. 1was performed on these first and second papermaking raw materials, thereby forming a filtering material with a continuous density gradient. At this time, the feed amounts of the first and second papermaking raw materials were adjusted in such a manner that: the overall basis weight of the filtering material was 120 g/m2; and the basis weigh ratio of the first and second papermaking raw materials was 4:6. The thus-obtained filtering material had a thickness of 0.95 mm (without calendaring treatment), a pore size of 75 μm and an overall density of 0.13 g/cm3.

As also indicated in TABLE 1, a blend of 80% mercerized pulp as natural fibers and 20% PET fibers of 12 μm diameter as chemical fibers was prepared as a first papermaking raw material for an upper layer; and a blend of 20% mercerized pulp and 65% non-mercerized normal pulp as chemical fibers and 15% PET fibers of 9 μm diameter as chemical fibers was prepared as a second papermaking raw material for a lower layer.

The above-mentioned wet papermaking process ofFIG. 1was performed on these first and second papermaking raw materials, thereby forming a filtering material with a continuous density gradient. At this time, the feed amounts of the first and second papermaking raw materials were adjusted in such a manner that: the overall basis weight of the filtering material was 100 g/m2; and the basis weigh ratio of the first and second papermaking raw materials was 3:7. The thus-obtained filtering material had a thickness of 0.60 mm (without calendaring treatment), a pore size of 90 μm and an overall density of 0.17 g/cm3.

As also indicated in TABLE 1, a blend of 35% mercerized pulp and 15% non-mercerized normal pulp as natural fibers and 20% PET fibers of 18 μm diameter and 30% PET fibers of 8 μm diameter as chemical fibers was prepared as a first papermaking raw material for an upper layer; and a blend of 15% mercerized pulp and 40% non-mercerized normal pulp as natural fibers and 35% PET fibers of 8 μm diameter and 10% PET fibers of 3 μm diameter as chemical fibers was prepared as a second papermaking raw material for a lower layer.

The above-mentioned wet papermaking process ofFIG. 1was performed on these first and second papermaking raw materials, thereby forming a filtering material with a continuous density gradient. At this time, the feed amounts of the first and second papermaking raw materials were adjusted in such a manner that: the overall basis weight of the filtering material was 80 g/m2; and the basis weigh ratio of the first and second papermaking raw materials was 6:4. The thus-obtained filtering material had a thickness of 0.56 mm (without calendaring treatment), a pore size of 60 μm and an overall density of 0.14 g/cm3.

The papermaking raw materials and the physical properties of the filtering materials of Comparative Examples 4 to 14 are indicated in TABLES 2 to 5. Each of the filtering materials of Comparative Examples 4, 5 and 6 was of two-layer structure using two kinds of papermaking raw materials of high density and low density. In Comparative Examples 4, 5 and 6, the raw materials were subjected to papermaking so as to create a continuous density gradient by the papermaking process ofFIG. 1in the same manner as in Examples 1 to 3. Each of the filtering materials of Comparative Examples 7 to 14 was of single-layer structure using one kind of papermaking raw material.

FIG. 8is a diagram showing the results of the dust collection performance test on the filtering materials of Examples 1 to 3 and Comparative Examples 4 to 14. The dust collection performance test was conducted by using each filtering material as a sample and continuously feeding air, which contained dust of 7 μm particle diameter categorized as “fine dust”, through each filtering material sample. In this test, the amount of the dust collected by the filtering material until the filtering material reached a predetermined increase in airflow resistance was determined as dust holding capacity (DHC); and the ratio of the amount of the dust collected to the amount of the dust fed was determined as efficiency. The total performance (life and collection efficiency) of each filtering material is plotted by one point with the dust holding capacity on the horizontal axis and the efficiency on the vertical axis in the diagram. The plot points #1 to #3 represent the test results of Examples 1 to 3; the plot points #4 to #14 represent the test results of Comparative Examples 4 to 14.

FIG. 9is a diagram showing the results of the carbon collection performance test on the filtering materials of Examples 1 to 3 and Comparative Examples 4 to 14. The carbon collection performance test was conducted in the same manner as the above carbon collection performance test, except for using carbon (soot) of 0.5 μm particle diameter in place of the dust of 7 μm particle diameter and plotting carbon holding capacity (CHC) on the horizontal axis in the diagram.

InFIGS. 8 and 9, the upper right regions represent high levels of life and collection efficiency as indicated by arrows. The carbon collection performance ofFIG. 8is the performance of the filtering material against relatively large dust particles flying in the air; the carbon collection performance ofFIG. 9is the performance of the filtering material against very fine particles like exhaust carbon particles. As is apparent fromFIGS. 8 and 9, the life and collection efficiency of the filtering material were achieved at high levels with respect to both of the dust collection performance and the carbon collection performance in each of Examples 1 to 3 of the present invention. In particular, the life of the filtering material was significantly improved with respect to the carbon collection performance in Examples 1 to 3 as compared to Comparative Examples 4 to 14.

The use of the filtering material of the present invention is not limited to the air cleaner. The filtering material of the present invention can be used for an oil filter, a fuel filter or the like.