Perlite boards and method for making same

Perlite board made from expanded perlite and a binder having the property of permanent tackiness in the dry state. The board may be made by expanding the perlite, adding a tacky resin emulsion to the perlite, drying the mixture and forming it into a board-like product.

FIELD OF THE INVENTION 
The present invention relates to perlite boards and, more particularly, to 
relatively thick perlite boards formed of expanded perlite and a tacky 
binder. 
BACKGROUND OF THE INVENTION 
Perlite ore is a naturally occurring volcanic mineral consisting primarily 
of silica, alumina and a small amount of water. Exposure of perlite ore to 
temperatures in the range of 1700 to 2100.degree. F. softens the mineral 
and causes the water to expand to form a light cellular mineral particle. 
Due to the low density and low thermal conductivity of expanded perlite, 
it has found utility as a thermal insulator. Expanded perlite has been 
used in its particulate form, for example, as loose-fill insulation. A 
co-pending application, Ser. No. 875,632, filed Feb. 6, 1978, now U.S. 
Pat. No. 4,212,755, discloses a loose-fill insulation of expanded perlite 
particles coated with a material rendering the particles slightly tacky. 
It is also known to use expanded perlite as a component of an insulating 
board. Conventional perlite board is made from an aqueous slurry of 
fibers, sizing and expanded perlite, that is formed into a board by a 
Fourdrinier process and subsequently dried. Because the mixture of fiber 
and expanded perlite is an efficient thermal insulator, it requires a 
great amount of energy to remove the water component of the slurry from 
the core of a thick, conventionally formed perlite board. Therefore, it 
has been necessary to laminate two relatively thin perlite boards to get a 
product thickness greater than about 1 1/4 inch. The lamination of such 
boards significantly increases the cost of production and renders the 
product susceptible to potential problems with delamination of the layers. 
The present invention overcomes this difficulty of the prior art by 
producing thick, expanded perlite without resorting to either an energy 
inefficient Fourdrinier process or lamination of thin boards. In addition, 
the product may be formulated in such a manner that it is flexible. 
SUMMARY OF THE INVENTION 
The invention is directed to perlite boards comprised of particles o 
expanded perlite and a binder having the property of permanent tackiness 
in the dry state. Preferably, the binder is an organic polyacrylic rsin 
compound. The preferred composition comprises from about 65 percent to 
about 95 percent by weight particles of expanded perlite and from about 5 
percent to about 35 percent by weight binder, expressed as a solid. 
Optionally, fibers, water-repellents and other additives may be added to 
the product. 
The invention is further directed to a method for producing expanded 
perlite boards of a thickness greater than about 1 inch comprising the 
steps of: adding a tacky resin emulsion to expanded perlite to form a 
composition; drying the composition; and fabricating the dried composition 
into boards. Optionally, the process further includes the steps of mixing 
both a glass fiber and a dilute asphalt emulsion with the expanded perlite 
and drying the mixture of asphalt emulsion and expanded perlite prior to 
adding the tacky emulsion. 
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
In accordance with the present invention, and as embodied herein, there are 
provided perlite boards having a thickness greater than about 1 inch 
comprised of expanded perlite and a permanently tack binder. The boards 
are particularly useful as insulation boards because, aside from the fact 
they provide effective thermal insulation, they are flexible and 
resilient. For example, the boards may be shaped at the job site to 
conform to the shape of large radius tanks and held in place by mechanical 
means. Other uses will be apparent to those skilled in the art. 
The binder, which may be organic or inorganic, is especially selected for 
the property of permanent tackiness in the dry state. Preferably, a 
self-crosslinking permanently tacky polymer, such as an acrylic polymer is 
used. Examples of organic materials useful as binders include such polymer 
resin types as styrene-butadiene, vinylidene chloride-butadiene, 
carboxylated vinyl acetate-ethylene, isobutylene, vinyl ethers, vinyl 
chlorides, vinyl propionate, natural rubber, polyisoprene, poly-amid, 
epoxy and combinations thereof. 
Union Carbide UCAR Latex 152 is a specific example of a polyacrylate resin 
useful in the practice of the invention. Bondmaster K800 by National 
Adhesives is another example of a compound adhesive that meets the 
tackiness requirement of this disclosure. The total binder, expressed as 
solids, comprises from about 5 to about 35 percent by weight of the board. 
The perlite, comprising 65-95 percent by weight of the board, consists in 
its expanded form of particles, milled or unmilled, ranging in size from 
less than 0.1 mm to about 3 mm. Commercial sources for such perlite are 
readily available. Bulk density may range from about one pound per cubic 
foot (pcf) to about ten pounds pcf. Optionally, the perlite may be 
previously treated to contain about 3 percent by weight emulsified asphalt 
solids. Methods for so treating perlite are well-known in the art. 
Optionally, reinforcing fibers, waterproofing materials, and fire 
retardants may form part of the composition. If bituminous or waxy 
water-repellent materials are used, they comprise from about 1.0% to about 
10% of the perlite by weight. These materials may be applied to the 
perlite from molten states or as emulsions by methods described in U.S. 
Pat. Nos. 2,626,872 and 2,634,208 to Miscall et al. If silicone emulsions 
are used, the silicone comprises from about 0.01% to about 2% of the 
perlite by weight. The silicon emulsions may be applied directly to the 
perlite as it exits the expander by means well-known in the art, or it may 
be added to and applied together with the tacky binder. 
If used, fine fibers comprise from about 1% to about 15% by weight of the 
board. Typically, hammermilled waste newsprint, with fibers from less than 
about 0.5 to about 5 mm in length are used. Glass fiber, mineral wool, and 
other such materials may also be used. Additionally, fibers, such as 
reclaimed nylon tire cord, are capable of use. To prevent balling up of 
the fibers, they are preferably mixed with the perlite by utilizing air as 
the mixing fluid. The binder may be sprayed onto the perlite 
simultaneously with the air mixing of perlite and fibers or after the 
mixing thereof. 
A compatible fire retardant, such as diammonium phosphate, may also be 
used. If so, it may be dissolved in the binder liquid and sprayed 
simulataneously onto the perlite. 
The basic method of producing the composition of the invention comprises 
the steps of expanding the perlite and mixing the expanded perlite with an 
aqueous, dispersion or emulsion of an organic or inorganic binder, which 
has the property of permanent tackiness in the dry state. Mixing of the 
perlite and the binder may be accomplished by spraying the binder onto the 
perlite. Although the binder may be sprayed onto the perlite in a 
solvent-based form, the emulsion form is preferred for safety reasons. 
Mixing may occur over a temperature range running from room temperature 
upward to any temperature below the decomposition point of the tacky resin 
binder. Other co-binders, wellknown in the art, may be added along with 
the tacky binder to impart desired properties.

The following examples, in conjunction with the general and detailed 
description above, more fully illustrate the nature and character of the 
present invention. 
EXAMPLE I 
One hundred grams of expanded perlite, previously treated to contain 3% of 
emulsified asphalt solids, were placed in a five-gallon drum fixed at an 
angle of 45.degree. above horizontal and driven by a motor to rotate at 60 
revolutions per minute. The perlite was 100% -16 +325 mesh (Tyler Sieve) 
and had a loose weight density of 4 pcf., when tested by methods commonly 
known in the art. 
Fifty grams of aqueous, emulsified, tacky, polyacrylate resin, such as 
Union Carbide UCAR Latex 152, containing 50% solids by weight was diluted 
with 50 grams water and sprayed onto the coated perlite. After the 
spraying was complete, the perlite-binder blend was removed from the drum, 
air dried and bagged loose. The dry composition contained 77.6% perlite, 
2.4% emulsified asphalt solids and 20% tacky resin adhesive solids. The 
material was dark brown in color, non-dusty and moderately water 
repellent. 
EXAMPLE II 
One hundred grams perlite such as described in Example I, but without the 
asphalt treatment, is placed in the rotating drum. Fifty grams of tacky 
polyacrylate resin binder, Union Carbide UCAR Latex 152 emulsion adhesive 
was diluted with 50 grams of water. Two grams of silicone emulsion was 
added and mixed into the binder emulsion mixture which was sprayed onto 
the perlite in the rotating drum. 
The resultant product was a low density, white, dust-free, highly water 
repellent, tacky powder, similar in properties to the product of Example 
I. When dry, the powder consisted of 79.5% weight percent perlite, 19.9% 
weight percent tacky binder and 0.6% weight percent silicone and was water 
repellent. 
The compositions of Examples I and II had the properties enabling such 
compositions to be formed into boards within the scope of the invention as 
defined herein. 
To manufacture boards from such compositions, the perlite particles are 
expanded in a conventional expander by a continuous process, collected by 
an air pick-up and conveyed pneumatically. Optionally, at any convenient 
point in the conveying system, fibers may be continuously injected into 
the system. Further downstream from the expander, at a point where the 
perlite temperature is below the decomposition temperature of asphalt, a 
dilute asphalt emulsion may optionally be sprayed-injected into the 
perlite or perlite-fiber stream. Further downstream at a point where the 
perlite-asphalt mixture has dried substantially and the temperature is low 
enough to avoid decomposition of the tacky resin binder, the tacky resin 
emulsion and, optionally, silicone emulsion, is injected into the flowing, 
pneumatically-conveyed stream of perlite and fibers by one or more spray 
nozzles. 
The heat from the expansion is sufficient to dry substantially the 
composition. The dried composition may then be deposited on the belt of a 
pressure conveyor for fabrication into a boardlike product. 
The invention in its broader aspects is not limited to the specific details 
shown and described and departures may be made from such details without 
departing from the principles of the invention and without sacrificing its 
chief advantages.