Biaxially oriented multilayer polyolefin film

A transparent, coextruded multilayer polyolefin film which is heat-sealable on both sides and has a base layer essentially comprising propylene polymers and outer layers essentially comprising heat-sealable olefin polymers is described. The propylene polymer of the base layer has been peroxidically degraded, its degradation factor A being in the range of about 3 to about 10. The heat-sealable olefin polymer of the outer layers is an ethylene-propylene copolymer having an ethylene content in the range of about 2 to about 8% by weight which has also been peroxidically degraded. Its degradation factor A is in the range of about 3 to 15. The film is useful as, for example, a packaging film.

BACKGROUND OF THE INVENTION 
The invention relates to a transparent, coextruded multilayer polyolefin 
film which is heat-sealable on both sides, wherein the base layer 
comprises polypropylene and the outer layers comprise heat-sealable olefin 
polymers. The invention furthermore relates to a process for the 
production of the film and to the use of the film. 
Biaxially oriented multilayer polyolefin films which are heat-sealable on 
both sides and in which the base layer comprises propylene homopolymers 
and the two heat-sealable outer layers comprise heat-sealable olefin 
polymers are described in numerous publications including EP 194,588; EP 
8,904; and U.S. Pat. No. 4,419,411. These multilayer polyolefin films have 
important properties for packaging films including broad heat-sealing 
range, good heat-sealing properties, relatively high scratch resistance, 
and low abrasion which gives good running properties on various types of 
high-speed packaging machines. 
However, the films described are in need of improvement with respect to the 
optical properties of transparency and gloss. 
SUMMARY OF THE INVENTION 
It is therefore an object of the present invention to provide a biaxially 
oriented multilayer polyolefin film which is heat-sealable on both sides 
and which has excellent optical properties, i.e., high transparency and 
gloss, in addition to the above-mentioned important properties. 
This object is achieved by providing a multilayer film, wherein 
a) the base layer of the multilayer film contains a propylene homopolymer 
which has been peroxidically degraded, its degradation factor A being in 
the range of about 3 to about 10, and 
b) the heat-sealable olefin polymer of the outer layers contains an 
ethylenepropylene copolymer having an ethylene content in the range of 
about 2 to about 8% by weight, based on the total weight of the copolymer, 
which has also been peroxidically degraded, its degradation factor A being 
in the range of about 3 to about 15. 
It is further an object of the invention to provide a method for preparing 
the multilayer film comprising the steps of: 
i) coextruding melts corresponding to the individual layers to produce a 
multilayer film, 
ii) solidifying said multilayer film by cooling, 
iii) biaxially stretching said multilayer film, and 
iv) thermofixing said multilayer film. 
There is further provided a laminate and a packaging film comprising the 
multilayer film. 
Further objects, features and advantages of the present invention will 
become apparent from the detailed description of the preferred embodiments 
that follows. 
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
The multilayer film according to the invention has very high transparency, 
very high gloss and is suitable for universal use on high-speed packaging 
machines. In particular, the film according to the invention preferably 
has a haze of less than 17%, most preferably in the range of 16 to 12%. 
Its gloss, measured at an angle of incidence of 20.degree., is preferably 
at least 110, and is most preferably in the range of 115 to 130. 
The outer layers may each optionally be corona- or flame-treated on their 
free surface. 
The thickness of the heat-sealing layers is preferably greater than 0.3 
.mu.m, most preferably in the range of 0.4 to 1.5 .mu.m. 
The base layer comprises a peroxidically degraded propylene polymer which 
predominantly comprises propylene units and preferably has a melting point 
in the range of 162.degree. to 168.degree. C. Isotactic polypropylene 
having an n-heptanesoluble content of 6% by weight or less is a preferred 
propylene polymer. In order to achieve the required good optical 
properties, the peroxidically degraded propylene homopolymer has a 
degradation factor A of 3 to 10, preferably from 4 to 8. The melt flow 
index of the starting polypropylene powder is preferably less than 1.5 
g/10 min, most preferably of 0.2 to 0.9 g/10 min (measurement in 
accordance with DIN 53 735, at a load of 21.6 N and at 230.degree. C.). 
The starting polypropylene powder is degraded to achieve a preferred melt 
flow index of the granules of 2 to 5.5 g/10 min (measurement in accordance 
with DIN 53 735, at a load of 21.6 N and at 230.degree. C.) during 
extrusion by addition of organic peroxides. Preferred peroxides include 
dialkyl peroxides, such as 2,5-dimethyl-2,5-di(t-butylperoxy)hexane or 
di-tbutyl peroxide. 
The degradation factor A of the propylene homopolymer is defined as 
##EQU1## 
where S.sub.G(PP) =melt flow index of the degraded PP granules and 
S.sub.P(PP) =melt flow index of the starting PP powder, each melt flow 
index being measured in accordance with DIN 53 735 at a load of 21.6 N and 
at 230.degree. C. 
The heat-sealable olefin polymer of the outer layer contains a 
peroxidically degraded ethylenepropylene copolymer which preferably has an 
ethylene content of 3 to 7% by weight and hence a propylene content of 
93-97% based on the total weight of the copolymer. In order to achieve the 
required good optical properties, the peroxidically degraded copolymer has 
a degradation factor A of 3 to 15, preferably of 6 to 10. The melt flow 
index of the C.sub.2 /C.sub.3 starting powder is preferably less than 3.0 
g/10 min (measured in accordance with DIN 53 735, at a load of 21.6 N and 
at 230.degree. C.). The starting C.sub.2 /C.sub.3 powder is degraded to a 
preferred melt flow index of the granules of 5.5 to 15 g/10 min before 
extrusion by adding organic peroxides. Preferably the melt flow index of 
the copolymer is greater than that of the polypropylene of the base layer. 
The degradation factor A of the ethylenepropylene copolymer is defined as 
##EQU2## 
where S.sub.G(cop.) =melt flow index of degraded ethylenepropylene 
copolymer granules and 
S.sub.P(cop.) =melt flow index of the starting ethylenepropylene copolymer 
powder, 
the melt flow index being measured in accordance with DIN 53 735 at a load 
of 21.6 N and at 230.degree. C. 
Peroxidic degradation and peroxidically degraded or CR ("controlled 
rheology") polypropylene homopolymers as such, are known in the literature 
(cf. Plastverarbeiter, Volume 38, 1987, No. 4; Polymer Engineering and 
Science, March 1989, Vol. 29, No. 6; plastverarbeiter, Vol. 36, 1985, No. 
11). Peroxidically degraded propylene homopolymers of this type are used, 
in particular, in injection molding and in the production of fibers. 
Peroxidically degraded C.sub.2 /C.sub.3 copolymers having a C.sub.2 
content of from 1 to 2.5% by weight are in some cases also employed for 
unstretched office films (organisation sector). However, there is no 
mention of the magnitude of the degradation factor for these products. 
The ethylene content of the copolymer is determined using .sup.13 C NMR 
spectroscopy. The measurements were carried out using a Bruker HX-270 
(Germany) nuclear magnetic resonance spectrometer fitted with a Bruker 
Aspect 2000 computer. To carry out the measurement, the ethylene-propylene 
copolymer to be characterized is dissolved in a solvent mixture comprising 
65% by volume of hexachlorobenzene and 35% by volume of 
1,1dideuterotetrachloroethane, giving a 10% by weight solution. As 
reference standard, octamethyltetrasiloxane (CMTS) is added. The 67.9 MHz 
.sup.13 C nuclear magnetic resonance spectrum is measured at 130.degree. 
C. The spectra are evaluated by the method described in J. C. Randall, 
Polymer Sequence Distribution (Academic Press, New York, 1977). 
The olefin polymer of the heat-sealable layers has a lower melting point 
than the propylene polymer of the base layer. The melting point of the 
olefin polymer is preferably in the range of 80.degree. to 160.degree. C., 
most preferably of 100.degree. to 140.degree. C. 
Surprisingly, it was found that the combination of said parameters for the 
propylene homopolymer of the base layer and for the ethylene-propylene 
copolymer of the outer layers and the outer layer thicknesses of the film 
must be kept within narrow limits in order to simultaneously optimize all 
the properties mentioned previously. 
If the degradation factor of the propylene homopolymer is less than 3, the 
optical properties are impaired giving significant increase in film haze 
and reduction in surface gloss. If the degradation factor is greater than 
10, problems occur in stretching, resulting in an extremely adverse effect 
on the running reliability during film production. At a degradation factor 
of greater than 10, the propylene homopolymer can only be stretched in a 
very narrow temperature range or not at all. 
The ethylene content of the copolymer is important for the heat-sealing 
properties. If the ethylene content is less than 2%, the film can only be 
heat-sealed at significantly higher temperatures or not at all. If the 
film is to be printed or metallized, the ethylene content of the copolymer 
is of particular importance for the ability to be surface treated by 
electrical corona discharge or flame and for the long-term stability of 
the adhesion properties. If the ethylene content is less than 2% by 
weight, the ability of the film to be corona treated is poor and the decay 
behavior of the treatment intensity is unfavorable. 
If the degradation factor of the C.sub.2 /C.sub.3 copolymer is less than 3, 
the optical properties are impaired resulting in increase in film haze and 
reduction in surface gloss. If the degradation factor is greater than 15, 
problems occur during stretching. 
If the melt flow index of the C.sub.2 /C.sub.3 powder is greater than 3 
g/10 min (21.6 N/230.degree.), the preferred degradation factor of 6 to 10 
causes the melt flow index of the C.sub.2 /C.sub.3 granules to be 
excessively high. An excessive viscosity difference between the 
polypropylene base material and the copolymer outer layer causes undesired 
flow impairment in the melt. 
If the thickness of the outer layers is less than 0.4 .mu.m, in particular 
less than 0.3 .mu.m, the heat-sealing properties and the ability of the 
film to be corona treated are impaired. In addition, the long-term 
behavior of the pretreatment intensity is unfavorable. 
In order to further improve certain properties of the polyolefin film 
according to the invention, both the base layer and the two outer layers 
may contain appropriate additives in an effective amount. These additives 
include antistatic agents, antiblocking agents, lubricants, stabilizers 
and/or low-molecular-weight resins, which are compatible with the polymers 
of the base layer and/or the heat-sealing layers. 
Preferred antistatics include alkali metal alkanesulfonates, 
polyether-modified, i.e., ethoxylated and/or propoxylated, 
polydiorganosiloxanes such as polydialkylsiloxanes, 
polyalkylphenylsiloxanes and the like, and/or essentially straight-chain 
and saturated, aliphatic, tertiary amines which contain an aliphatic 
radical having 10 to 20 carbon atoms and are substituted by .omega. 
hydroxy(C.sub.1 -C.sub.4)alkyl groups, of which N,N-bis(2hydroxyethyl) 
alkylamines containing (C.sub.10 -C.sub.20)-,preferably (C.sub.12 
-C.sub.18)-alkyl groups are particularly suitable. The effective amount of 
antistatic is generally in the range of 0.05 to 3% by weight, based on the 
weight of the layer containing the antistatic agent. 
Suitable antiblocking agents include inorganic additives, such as silicon 
dioxide, calcium carbonate, magnesium silicate, aluminum silicate, calcium 
phosphate, and the like, nonionogenic surfactants, anionic surfactants 
and/or incompatible organic polymers, such as polyamides, polyesters, 
polycarbonates, and the like. The effective amount of the antiblocking 
agent is generally in the range of 0.1 to 2% by weight, based on the 
weight of the layer containing the antiblocking agents. 
Suitable lubricants include higher aliphatic acid amides, waxes, metal 
soaps and polydiorganosiloxanes, preferably polydialkylsiloxanes. The 
effective amount is generally from 0.1 to 2.5% by weight, based on the 
weight of the layer containing the lubricant. 
Stabilizers which can be employed include the conventional stabilizing 
compounds for polymers of ethylene, propylene and other .alpha.-olefins. 
The effective amount is generally from 0.1 to 2% by weight, based on the 
weight of the layer containing the stabilizers. 
The low-molecular-weight resins recommended as an additive include a 
natural or synthetic resin having a softening point of 60.degree. to 
180.degree. C., preferably 80.degree. to 150.degree. C. (determined in 
accordance with ASTM E-28). Of the numerous low-molecular-weight resins, 
hydrocarbon resins such as petroleum resins, styrene resins, 
cyclopentadiene resins, or terpene resins (these resins are described in 
Ullmanns Enzyklopadie der Techn. Chemie, [Ullmann's Encyclopedia of 
Industrial Chemistry], 4th Edition, Volume 2, pages 539 to 553) are 
preferred. Preferably the low-molecular-weight resin has a number average 
molecular weight of 200 to 1000. The preferred amount of 
low-molecular-weight resin is 3 to 15% by weight, most preferably 5 to 10% 
by weight, based on the weight of the layer containing the resin. 
The thickness of the multilayer polyolefin film according to the invention 
may vary within broad limits and depends, in particular, on the intended 
use. Its overall thickness is preferably from 10 to 50 .mu.m, most 
preferably from 20 to 40 .mu.m. The heat-sealing layers are preferably 
each thicker than 0.3 .mu.m, most preferably 0.4 to 1.5 .mu.m thick. The 
thickness of the base layer preferably makes up from 50 to 90% of the 
total film thickness. 
In the multilayer film according to the invention, the outer layers may 
have the same or different compositions. The multilayer film is produced 
by any known process, preferably by the known coextrusion process. Within 
the confines of this process, the melts corresponding to the individual 
layers of the film are coextruded through a flat-film die, the resultant 
film is solidified by cooling, the film is biaxially stretched (oriented), 
the biaxially stretched film is thermofixed, and the surface layer 
intended for corona treatment is corona treated. The biaxial stretching 
(orientation) may be carried out simultaneously or consecutively. 
Consecutive biaxial stretching, in which the film is first stretched 
longitudinally (in the machine direction) and then transversely 
(perpendicular to the machine direction), is preferred. The film is 
preferably stretched from 4 to 7:1 in the longitudinal direction and from 
8 to 10:1 in the transverse direction. The longitudinal stretching is 
preferably carried out at a film temperature of 120.degree. to 140.degree. 
C., and the transverse stretching is preferably carried out at 160.degree. 
to 175.degree. C. The longitudinal stretching is expediently carried out 
using two rollers running at different speeds corresponding to the 
intended stretching ratio, and the transverse stretching is expediently 
carried out using an appropriate tenter frame. The biaxial stretching of 
the film is followed by thermofixing (heat treatment) thereof. In this 
step, the film is preferably kept at a temperature of 150.degree. to 
160.degree. C. for from 0.5 to 10 seconds. 
If it is desired that the multilayer polyolefin film should be printable or 
metallizable, the film is corona treated. The electrical corona treatment 
is preferably carried out at an alternating voltage of 10,000 V and 10,000 
Hz, on one or both sides as desired. The film produced in this way is 
wound up in a conventional manner using a wind-up unit and has, 
immediately after production, a surface tension on the treated side of 
preferably of 36 to 42 mN/m, most preferably of 38 to 40 mN/m. 
The multilayer polyolefin film according to the invention is particularly 
suitable as a packaging film on high-speed packaging machines. This is 
because it has all the important properties required of polyolefin films 
with respect to high-speed machines. It has, in particular, the ability to 
be heat-sealed on both sides, high scratch resistance, good running 
properties, very good optical properties, in particular high gloss and low 
haze, and good printability. 
Since the multilayer polyolefin film according to the invention also has 
good immediate and long-term printability properties after the corona 
treatment, it is also suitable for the production of laminates with paper, 
with board, with metals with metallized plastic films and with 
unmetallized plastic films, and as a base film for aqueous barrier coating 
systems, for example, systems based on aqueous dispersions of 
polyvinylidene chloride or ethylene-vinyl alcohol copolymers. It can also 
be printed with aqueous printing inks, for example with two-component 
reactive dyes, with excellent results. 
If the corona treatment is omitted, the multilayer polyolefin film 
according to the invention is particularly suitable as a cigarette 
packaging film since it has extremely low haze and very good gloss in 
addition to the important properties required with respect to high-speed 
packaging machines. 
The invention is described in greater detail below with reference to 
working examples. 
The films of the examples and comparative examples are each biaxially 
oriented by use of a longitudinal stretching ratio of 5:1 and transverse 
stretching ratio of 10:1. The films are transparent polyolefin films 
having a base layer comprising an isotactic polypropylene having an 
n-heptane-soluble content of 4.5% by weight and a melting point of 
165.degree. C. as the principal component. The base layer is approximately 
19 .mu.m thick, and the two heat-sealing layers covering the base layer 
are each 0.8 .mu.m thick. Films having the layer sequence A-B-A are 
produced, where A is the outer layer and B the base layer. The three-layer 
polyolefin films have been produced by the known coextrusion process. 
All the layers contain 0.12% by weight of pentaerythrityl 
tetrakis-3-(3,5-di-tertiary-butyl-4-hydroxyphenyl)propionate (Irganox 
1010.RTM.) for stabilization and 0.06% by weight of calcium stearate for 
neutralization of acidic catalyst residues. The base layer also contains 
0.15% by weight of N,N-bis(2-hydroxyethyl)-(C.sub.10 -C.sub.20)alkylamine 
(Armostat 300.RTM.) as antistatic.

EXAMPLE 1 
The isotactic propylene homopolymer of the base layer is degraded from a 
starting polypropylene powder having a melt flow index S.sub.P(PP) of 0.7 
g/10 min (determined in accordance with DIN 53 735 at a load of 21.6 N and 
at 230.degree. C.) by addition of di-t-butyl peroxide to give a melt flow 
index of the granules So.sub.G(PP) of 3.5 g/10 min (DIN 53 735 at a load 
of 21.6 N and at 230.degree. C.), giving a degradation factor A of 5. 
The random ethylene-propylene copolymer of the heat-sealing layers is 
degraded from a melt flow index of a starting powder S.sub.P(cop.) of 0.7 
g/10 min (DIN 53 735 at a load of 21.6 N and at 230.degree. C.) by 
addition of di-t-butyl peroxide to a melt flow index of the granules of 
5.6 g/10 min (DIN 53 735 at a load of 21.6 N and at 230.degree. C.), 
giving a degradation factor A of 8. The peroxidically degraded 
ethylene-propylene copolymer has an ethylene content of 4.0% by weight and 
is blended with 0.8% by weight of polydimethylsiloxane having a viscosity 
of 30,000 mm.sup.2 /s at 25.degree. C. and 0.3% by weight of silicon 
dioxide having a mean particle diameter of 2 .mu.m. 
EXAMPLE 2 
The isotactic propylene homopolymer of the base layer is degraded from a 
starting polypropylene powder having a melt flow index S.sub.P(PP) of 0.5 
g/10 min (determined in accordance with DIN 53 735 at a load of 21.6 N and 
at 230.degree. C.) by addition of di-t-butyl peroxide to give a melt flow 
index of the granules S.sub.G(PP) of 3.5 g/10 min (DIN 53 735 at a load of 
21.6 N and at 230.degree. C.), giving a degradation factor A of 7. 
The random ethylene-propylene copolymer of the heat-sealing layers is 
degraded from a melt flow index of a starting powder S.sub.P(cop.) of 0.6 
g/10 min (DIN 53 735 at a load of 21.6 N and at 230.degree. C.) by 
addition of di-t-butyl peroxide to a melt flow index of the granules 
S.sub.G(cop.) of 6.0 g/10 min (DIN 53 735 at a load of 21.6 N and at 
230.degree. C.), giving a degradation factor A of 10. The peroxidically 
degraded ethylenepropylene copolymer has an ethylene content of 4.0% by 
weight and is blended with 0.8% by weight of polydimethylsiloxane having a 
viscosity of 30,000 mm.sup.2 /s at 25.degree. C. and 0.3% by weight of 
silicon dioxide having a mean particle diameter of 2 .mu.m. 
EXAMPLE 3 
The propylene homopolymer of the base layer and the random 
ethylene-propylene copolymer of the heat-sealing layers are peroxidically 
degraded as in Example 1. However, the three-layer film produced now has 
an A-B-C structure (A and C =heat-sealing layers, B =base layer), the 
peroxidically degraded ethylene-propylene copolymer of layer A containing 
1.6% by weight of polydimethylsiloxane having a viscosity of 30,000 
mm.sup.2 /s at 25.degree. C. and 0.3% by weight of silicon dioxide having 
a mean particle diameter of 2 .mu.m. The peroxidically degraded copolymer 
of layer C contains 0.3% by weight of silicon dioxide having a mean 
particle diameter of 2 .mu.m and no polydimethylsiloxane. Layer C is 
corona-treated, the surface tension of this side being 40 mN/m immediately 
after production. 
EXAMPLE 4 
The propylene homopolymer of the base layer and the random 
ethylene-propylene copolymer of the heat-sealing layers are peroxidically 
degraded as in Example 2. The three-layer film produced has, as in Example 
3, an A-B-C structure (A and C heat-sealing layers, B =base layer), the 
peroxidically degraded ethylene-propylene copolymer of layer A containing 
2.4% by weight of polydimethylsiloxane having a viscosity of 30,000 
mm.sup.2 /s at 25.degree. C. and 0.3% by weight of silicon dioxide having 
a mean particle diameter of 2 .mu.m. The peroxidically degraded copolymer 
of layer C contains 0.3% by weight of silicon dioxide having a mean 
particle diameter of 2 .mu.m and no polydimethylsiloxane. As in Example 3, 
layer C is corona treated, the surface tension of this side being 40 mN/m 
immediately after production. 
EXAMPLE 5 
The propylene homopolymer of the base layer and of the random 
ethylene-propylene copolymer of the heat-sealing layers are peroxidically 
degraded as in Example 2. However, the peroxidically degraded copolymer 
has an ethylene content of 6.0% by weight. Layers A and C are formulated 
as in Example 3, layer C being corona treated as in Example 3. 
COMATIVE EXAMPLE 1 
A three-layer film is produced as in Example 2. The isotactic propylene 
homopolymer likewise has a melt flow index of the granules of 3.5 g/10 min 
(DIN 53 735 at a load of 21.6 N and at 230.degree. C.), but has not been 
peroxidically degraded. 
The random ethylene-propylene copolymer of the outer layers is 
peroxidically degraded as in Example 2 and is blended with additives as in 
Example 2. 
COMATIVE EXAMPLE 2 
A three-layer film is produced as in Example 2. The polypropylene polymer 
of the base layer likewise has a melt flow index of the granules of 3.5 
g/10 min (DIN 53 735 at a load of 21.6 N and at 230.degree. C.), but has 
not been peroxidically degraded. 
The random ethylene-propylene copolymer is formulated as in Example 2 and 
has, as in Example 2, a melt flow index of the granules of 6.0 g/10 min 
(DIN 53 735 at a load of 21.6 N and at 230.degree. C.). However, the 
random ethylene-propylene copolymer of the outer layers has not been 
peroxidically degraded. 
COMATIVE EXAMPLE 3 
A three-layer film having an A-B-C structure is produced as in Example 5. 
Neither the propylene homopolymer of the base layer nor the random 
ethylene-propylene copolymer of the heat-sealing layers has been 
peroxidically degraded. 
COMATIVE EXAMPLE 4 
A three-layer film having an A-B-C structure is produced in accordance with 
Example 1 of European Patent 194,588. 
COMATIVE EXAMPLE 5 
A three-layer film is produced in accordance with Example 4 of U.S. Pat. 
No. 4,419,411. 
The following measurement methods were used to characterize the raw 
materials and films: 
Ethylene content: As described above. 
Melt flow index: DIN 53 735 at 230.degree. C. and a load of 21.6 N 
Haze: The haze of the film is measured in accordance with ASTM-D 1003-52, 
using a 1.degree. slit diaphragm instead of a 4.degree. pinhole diaphragm, 
and the haze is indicated in percent for four film layers one on top of 
the other. The four layers were selected since the optimum measurement 
range is thereby utilized. The haze evaluation was carried out with: 
______________________________________ 
.ltoreq.17% = very good (++) 
.gtoreq.17% to 20% = 
good (+) 
.gtoreq.20% to 25% = 
moderate (.+-.) 
.gtoreq.25% = poor (-) 
______________________________________ 
Gloss: The gloss is determined in accordance with DIN 67 530. The reflector 
value is measured as an optical characteristic of the surface of a film. 
In accordance with ASTM-D 523-78 and ISO 2813 standards, the angle of 
incidence was set at 20.degree.. A light beam hits the planar test surface 
at the set angle of incidence and is reflected or scattered by this 
surface. The light beams hitting the photoelectronic receiver are 
indicated as a proportional electrical quantity. The measurement value is 
dimensionless and must be indicated together with the angle of incidence. 
The gloss is assessed (angle of incidence 20.degree.) with: 
______________________________________ 
.gtoreq.115 = very good (++) 
.ltoreq.115 to 110 = 
good (+) 
.ltoreq.110 to 100 = 
moderate (.+-.) 
.ltoreq.100 = poor (-) 
______________________________________ 
Scratch resistance or scratch sensitivity: The scratch resistance is 
determined in accordance with DIN 53 754. The scratch resistance is 
determined using the Taber model 503 Abraser from Teledyne Taber, using 
Calibrade R H 18 abrasive wheels at a load of 250 g. Scratch resistance or 
scratch sensitivity is taken to mean the increase in haze of the scratched 
film compared with the original film after 50 revolutions of the sample 
plate. The scratch resistance is very good (++) if the increase in haze is 
.ltoreq.22%, good (+) if the increase in haze is from 22 to 25%, moderate 
(+) if the increase in haze is 25-30%,,and poor (-) if the increase in 
haze is greater than 30%. 
Determination of the seal weld strength: Two 15 mm wide strips are placed 
one on top of the other and heat-sealed at 130.degree. C. for a sealing 
time of 0.1 s and at a sealing pressure of 1.5 N/cm.sup.2. The seal 
strength is determined by the T-peel method. 
Determination of the corona-treatment intensity: The corona treatment is 
carried out in such a manner that the treated film surface in each case 
has a treatment intensity of 40 mN/m immediately after the treatment. The 
treatment intensity is determined by the ink method (DIN 53 364). 
Determination of the printability: The corona-treated films are printed 14 
days after production (short-term assessment) and 6 months after 
production (long-term assessment). The adhesion of the ink is assessed by 
an adhesive tape test. If small amounts of ink can be detached by means of 
adhesive tape, the adhesion of the ink is moderate and if considerable ink 
detachment occurs, the adhesion is poor. 
Table 1 below summarizes the properties of the three-layer polyolefin films 
of the examples and comparative examples. 
As the results show, the three-layer polyolefin films according to the 
invention are clearly superior to those of the prior art. Only the films 
according to the invention satisfy the high demands with respect to very 
low film haze, high surface gloss, good scratch resistance, 
heat-sealability on both sides and running properties (smooth passage 
through the machine) and good printability, and are thus distinguished by 
universal use as packaging films and universal suitability on high-speed 
packaging machines 
TABLE 1 
__________________________________________________________________________ 
Gloss Heat- Passage 
(measurement 
sealability 
through 
Haze angle 20.degree.) 1st 
Scratch 
1st side/* 
the 
4-layer side/2nd side 
resistance 
2nd side 
machine 
Printability 
__________________________________________________________________________ 
Example 1 
++ ++/++ ++ ++/++ ++ (**) 
Example 2 
++ ++/++ ++ ++/++ ++ (**) 
Example 3 
++ ++/++ ++ ++/+ ++ ++ 
Example 4 
++ ++/++ ++ ++/+ ++ ++ 
Example 5 
++ ++/++ ++ ++/++ ++ ++ 
Comp. .+-. 
.+-./.+-. 
+ ++/++ ++ (**) 
Example 1 
Comp. - -/- .+-. ++/++ ++ (**) 
Example 2 
Comp. - -/- .+-. ++/++ ++ ++ 
Example 3 
Comp. - -/- .+-. ++/+ + ++ 
Example 4 
Comp. - -/- .+-. +/- + ++ 
Example 5 
__________________________________________________________________________ 
*2nd side: If corona treatment has been carried out, the second side (C 
layer) has been corona treated 
(**) These threelayer films were not corona treated 
In the table: 
++ denotes very good 
+ denotes good 
.+-. denotes moderate 
- denotes poor