Semiconductor carbon nanotubes fabricated by hydrogen functionalization and method for fabricating the same

Semiconductor carbon nanotubes functionalized by hydrogen and a method for fabricating the same, wherein the functional hydrogenated semiconductor carbon nanotubes have chemical bonds between carbon and hydrogen atoms. The semiconductor carbon nanotube fabricating method includes heating carbon nanotubes in a vacuum, dissociating hydrogen molecules in hydrogen gas into hydrogen atoms, and exposing the carbon nanotubes to the hydrogen gas to form chemical bonds between carbon atoms of the carbon nanotubes and the hydrogen atoms. The conversion of metallic carbon nanotubes into semiconductor nanotubes and of semiconductor nanotubes having a relatively narrow energy bandgap into semiconductor nanotubes having a relative wide energy bandgap can be achieved using the method. The functional hydrogenated semiconductor carbon nanotubes may be applied and used in, for example, electronic devices, optoelectronic devices, and energy storage.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to semiconductor carbon nanotubes functionalized by hydrogen, and more particularly, to a method for fabricating the same.

2. Description of the Related Art

Carbon nanotubes are cylindrical or tubular forms of carbon having diameters ranging from a few to tens of nanometers and lengths of tens of micrometers.

FIG. 1illustrates the configuration of a conventional carbon nanotube. Carbon nanotubes may be thought of as being formed by rolling up sheets of graphite (a hexagonal lattice of carbon) into cylinders. The unique properties of carbon tubes are determined by the length, configuration and diameter of the carbon tubes as determined by the angle at which a sheet of graphite being rolled is twisted, i.e., chirality, and the diameter of the carbon nanotubes at the initial stage of rolling.

Referring toFIG. 1, vector {right arrow over (C)}hfrom an arbitrary start point A to an end point A′, which meet when the sheet is rolled up, is shown. If it is assumed that A has coordinates (0, 0) and A′ has coordinates (n, m), then vector {right arrow over (C)}hcan be expressed with unit vectors {right arrow over (a)}1and {right arrow over (a)}2as in equation (1) below.
{right arrow over (C)}h=n{right arrow over (a)}1+m{right arrow over (a)}2(1)

The diameter dtof the carbon nanotube can be calculated using equation (2) below.

Carbon nanotubes feature very high aspect ratios of 1,000 or greater and have the electrical properties of a metal or of a semiconductor depending on their diameters and configurations. Metallic carbon nanotubes are known to have high electrical conductance.

FIG. 2Aillustrates a special type of a carbon nantotube in zigzag form, which is obtained when m=0.FIG. 2Billustrates a carbon nanotube having an armchair configuration, which is obtained when n=m.

Most carbon nanotubes have chiral configurations spirally arranged along arbitrary tubular axes. Carbon nanotubes formed from a single sheet of graphite rolled up into a cylinder are called “single wall nanotubes” (SWNT), and carbon nanotubes formed from multiple sheets of graphite rolled up into cylinders inside other cylinders are called “multi-wall nanotubes” (MWNT).

Conventionally, carbon nanotubes are manufactured using arc discharging, laser ablation, chemical vapor deposition (CVD), and like processes. Such conventional techniques, however, cannot control chirality, and lead to a mixture of metallic and semiconductor carbon nanotube particles, which cannot be used to manufacture metallic nanotransistors. In addition, transistors manufactured from semiconductor carbon nanotubes do not work at an ambient temperature due to the small energy bandgap of the semiconductor carbon nanotubes.

To overcome such drawbacks, a method has been developed for converting metallic carbon nanotubes into semiconductor carbon nanotubes by separating outer walls of MWNTs to reduce the diameter of the carbon nanotubes. However, this method involves placing the metallic carbon nanotubes in contact with an electrode and applying a high current to them, which renders the overall process to be complex. In addition, the method can be applied neither directly to transistors nor to SWNTs having no extra wall to be separated out.

Another conventional method for converting semiconductor carbon nanotubes into metallic carbon nanotubes by the addition of alkali metal has been suggested. However, this method cannot be applied to convert metallic carbon nanotubes into semiconductor carbon nanotubes nor to convert narrow bandgap semiconductor carbon nanotubes into large bandgap semiconductor carbon nanotubes.

SUMMARY OF THE INVENTION

The present invention provides a semiconductor carbon nanotube that is fabricated by hydrogen functionalization.

The present invention also provides a method for converting a metallic carbon nanotube into a semiconductor carbon nanotube, and for converting a narrow energy bandgap semiconductor carbon nanotube into a wide energy bandgap semiconductor carbon nanotube.

According to a feature of a preferred embodiment of the present invention, there is provided a semiconductor carbon nanotube having chemical bonds between carbon and hydrogen atoms. It is preferred that the chemical bonds between carbon and hydrogen atoms are sp3hybrid bonds.

According to another feature of another preferred embodiment of the present invention, there is provided a method for fabricating a semiconductor carbon nanotube, the method comprising heating a carbon nanotube in a vacuum, dissociating hydrogen molecules in hydrogen gas into hydrogen atoms, and exposing the carbon nanotube to the hydrogen atoms in the hydrogen gas to form chemical bonds between carbon atoms of the carbon nanotube and hydrogen atoms.

In accordance with an aspect of the present invention, heating of the carbon nanotube in a vacuum may be performed at a temperature of 100° C. or greater for 2 hours or longer.

In accordance with another aspect of the present invention, dissociation of hydrogen molecules into hydrogen atoms may be performed by heating the hydrogen molecules at a temperature of 1500° C. or greater. The dissociation of the hydrogen molecules into the hydrogen atoms may be accomplished by applying an RF or DC bias voltage or using arc discharging.

According to another feature of an embodiment of the present invention, when forming the chemical bonds between the carbon atoms and hydrogen atoms, the energy bandgap of the carbon nanotube may be controlled by varying the length of time the carbon nanotube is exposed to the hydrogen gas containing hydrogen atoms. Alternatively, the energy bandgap of the carbon nanotube may be controlled by varying the level of pressure under which the carbon nanotube is exposed to the hydrogen gas containing hydrogen atoms. The chemical bonds between the carbon and hydrogen atoms in the carbon nanotube fabricated according to an embodiment of the present inventive method may be sp3hybrid bonds.

According to the present invention, metallic carbon nanotubes can be converted into semiconductor carbon nanotubes, and narrow energy bandgap semiconductor carbon nanotubes can be converted into wide energy bandgap semiconductor carbon nanotubes by hydrogenation. The functional hydrogenated semiconductor carbon nanotubes have a wide range of applications, including use in electronic devices such as transistors, electro-optic devices, energy storage devices, and other electronic devices.

DETAILED DESCRIPTION OF THE INVENTION

Korean Patent Application No. 2002-24476, filed on May 3, 2002, and entitled “Semiconductor Carbon Nanotubes Fabricated by Hydrogen Functionalization and Method for Fabricating the Same,” is incorporated by reference herein in its entirety.

Embodiments of carbon nanotubes with hydrogen and a method for fabricating the same according to the present invention will now be described with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. The invention may, however, be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.

FIG. 3illustrates a carbon nanotube according to an embodiment of the present invention. Referring toFIG. 3, a carbon nanotube21according to an embodiment of the present invention has C—H chemical bonds formed by binding hydrogen atoms to dangling bonds on the surface of the carbon nanotube.

The carbon nanotube21can be manufactured using, for example, arc discharge, laser vaporization, plasma enhanced chemical vapor deposition (PECVD), thermal chemical vapor deposition, vapor phase growth, and the like.

Carbon nanotubes according to the present invention have chemical bonds between their carbon atoms and hydrogen atoms, in which sp3hybrid bonding is promoted while sp2hybrid bonding is suppressed to take energy away from the Fermi level electrons, thereby imparting semiconductor properties to the carbon nanotubes.

Carbon atoms, whose atomic number is 6, have an electron configuration of 1s22s22p2in the ground state. However, the electron configuration of carbon is converted when covalently bonded to another atom. In other words, after one of the electrons in the 2s orbital is promoted to the 2p orbital, the 2s orbital and the 2p orbital are combined to give sp hybrid orbitals.

An sp hybrid orbital is formed from one s orbital and one p orbital with electrons, three sp2hybrid orbitals are formed from one s orbital and two p orbitals with electrons, and four sp3hybrid orbitals are formed from one s orbital and three p orbitals with electrons.

The electron configuration of carbon atoms enabling them to form a crystalline structure on their own includes sp3and sp2configurations. The sp3configuration with four hybrid orbitals permits carbon atoms to form four strong σ bonds. The sp2configuration with three hybrid orbitals permits carbon atoms to form three σ bonds in a plane, which are weaker than those in the sp3configuration. The sp2configuration also permits the electrons in the p orbitals to form weak π bonds.

Carbon nanotubes according to the present invention are synthesized by forming C—H chemical bonds through the addition of hydrogen into carbon nanotubes having the sp3and sp2electron configurations, in which π or π* bonds near the Fermi level in the sp2hybrid orbitals are cleaved, so that less sp2bonds and more sp3bonds are present in the structure of the carbon nanotubes. The hydrogen and carbon atoms form a strong C—H bond with an atomic binding energy of −2.65 eV. The C—C bonds in the carbon nanotubes have a bond length of about 1.54 Å, which is almost equal to that of diamond. The C—C bond remains resistant to external environmental variations or strong electrical current and thus prevents decomposition of the carbon nanotubes.

The carbon nanotubes that are functionalized by hydrogen according to an embodiment of the present invention have semiconductor properties that are essential in their application to nanotransistors. Nanotransistors can be manufactured using the functional hydrogenated carbon nanotubes with an improved yield of almost 100%. Also, the nanotransistors remain operable at high temperature due to the stable C—H chemical bonds.

FIG. 4illustrates the configuration of an intermolecular junction device3manufactured using carbon nanotubes, according to an embodiment of the present invention.

In general, intermolecular junction devices3are molecular diode devices manufactured by kinking carbon nanotubes, with one metallic kinked end and the other a semiconductor end. The intermolecular junction device3shown inFIG. 4has a heterogeneous structure of two kinds of carbon nanotubes, wherein carbon nanotubes functionalized by hydrogen according to the present invention may be used for at least one of the carbon nanotubes. The two carbon nanotubes are bound together with different chiral angles at binding sites5and7.

Heterogeneous carbon nanotubes having different energy bandgaps, which can thus be used for diodes, can be manufactured by the hydrogenation of a portion of carbon nanotubes. There is no known method for arbitrarily controlling chiral angles to manufacture such a device as shown inFIG. 4. However, carbon nanotubes having properties required for such a device can be manufactured by partial hydrogenation of arbitrary carbon nanotubes.

FIG. 5illustrates a sectional view of a field emitter device using carbon nanotubes according to an embodiment of the present invention. Referring toFIG. 5, a field emitter device according to an embodiment of the present invention includes a source electrode12formed as a stripe on a substrate11, a thin film12aformed on the source electrode12with tips15of carbon nanotubes functionalized by hydrogen, a gate dielectric layer13formed to surround the tips15, and a gate electrode14formed on the gate dielectric layer13with an opening14aabove the tips15for electron emission. A drain electrode (not shown) is formed on the gate electrode14as a stripe perpendicular to the source electrode13.

It is preferable that an electron emitter source for the field emitter be manufactured by controlling the electronic energy bandgap of carbon nanotubes for uniform resistance, and be applied uniformly over the entire area of the field emitter for uniform electron emission.

FIG. 6illustrates a perspective view of a nanotransistor using carbon nanotubes according to an embodiment of the present invention. Referring toFIG. 6, a nanotransistor using carbon nanotubes according to an embodiment of the present invention includes a substrate21, an insulating layer23formed on the substrate21, a source region25and a drain region27formed on the insulating layer23with a separation distance therebetween, and a carbon nanotube unit31connecting the source region25and the drain region27as an electron channel.

The carbon nanotube unit31in the nanotransistor is formed of a semiconductor carbon nanotube fabricated by hydrogen functionalization according to the present invention. The energy bandgap of the carbon nanotube unit31can be controlled within a desired range by varying the duration for which and pressure under which source carbon nanotubes are exposed to hydrogen gas during hydrogenation.

The semiconductor carbon nanotubes according to the embodiment of the present invention can be applied to memory devices, sensors, and other like devices as well as nanotransistors.

InFIG. 6, although the nanotransistor is described as having the source region25and the drain region27on the substrate21, the source region25and the drain region27may also be located in the substrate21. In this case, the carbon nanotube unit31is located in or on the substrate21to connect the source region25and the drain region27.

In general, the substrate21is a silicon substrate, and the insulating layer23on the silicon substrate21is formed of silicon oxide. The source region25and the drain region27may be formed of metal such as titanium, gold, etc. The nanotransistor as described above may be formed using known semiconductor manufacturing processes such as photolithography, etching, oxidation, and thin film deposition.

The semiconductor carbon nanotubes fabricated by hydrogen functionalization according to an embodiment of the present invention can be applied as probe tips for scanning probe microscopy (SPM), as well as the nanodevices illustrated inFIGS. 4 and 6, and further for nanobalances using the resonance of nanotubes, electro-optic devices using the optical properties of carbon nanotubes, various electronic devices, memory devices, chemical sensors using field effect transistors (FETs), and the like.

In addition, the H of the C—H bond on the carbon nanotube wall may be replaced by another substitutent in order for the carbon nanotubes to be used for biochips or biosensors. Alternatively, the carbon nanotubes may be dispersed in a solution to increase their electronegativity and surface area for use as energy devices such as surface capacitors.

FIG. 7illustrates a flowchart showing a method for manufacturing hydrogenated carbon nanotubes according to an embodiment of the present invention.FIG. 8illustrates an apparatus for conducting carbon nanotube hydrogenation.

Initially, a substrate45with carbon nanotube powder or individual carbon nanotubes thereon is heated in a vacuum container43at 10−6torr or less and above 100° C. for 2 hours or longer, to remove gas adsorbed on the walls of the carbon nanotubes (step101). With a tungsten filament49disposed near the top entrance of the vacuum container, which is heated to a temperature of 1500° C. or greater by an electric current, a RF or DC bias voltage is applied to hydrogen gas in molecular form supplied through an inlet47, or an arc discharge is induced to dissociate the molecular hydrogen gas into hydrogen atoms (step103). The dissociated hydrogen atoms contact and are adsorbed into the walls of the carbon nanotubes to form C—H chemical bonds (step105). At this time, the temperature of the substrate45is maintained at 100° C. or less.

The duration for which the carbon nanotubes are exposed to the hydrogen gas is controlled within a range of from 1 hour to 20 hours, and the pressure of the hydrogen gas in the vacuum container is controlled within a range from 10−6torr to 10−3torr, such that metallic carbon nanotubes are converted into semiconductor nanotubes or narrow energy bandgap semiconductor carbon nanotubes are converted into wide energy bandgap semiconductor carbon nanotubes.

FIG. 9Ais a scanning electron microscopic (SEM) image showing the hydrogenation of carbon nanotubes to form C—H bonds in the manufacture of semiconductor carbon nanotubes by hydrogenation according to an embodiment of the present invention. Initially, the carbon nanotubes are bound to the silicon substrate by metal using electron-beam lithography, wherein half of a carbon nanotube is buried in a silicon oxide (SiO2) layer having a thickness of 100 nm while the other half is exposed to the hydrogen gas, as shown inFIG. 9A. Next, a vacuum atmosphere is created by degassing at 300° C. for 6 hours, and the carbon nanotubes are hydrogenated by being exposed to the hydrogen gas at a temperature of 100° C. and a pressure of 10−5torr for several hours.

Hydrogen atoms in the hydrogen gas permeate into the carbon nanotubes exposed on the surface of the silicon oxide layer to bind to carbon atoms, so that functional hydrogenated carbon nanotubes are formed. In the photograph ofFIG. 9A, the atoms of the carbon nanotube are carbon atoms, and the smaller atoms on the external wall of the carbon nanotube are hydrogen atoms.

FIG. 9B-2is a graph of current versus voltage for pristine samples (denoted as “MS”) and semiconducting samples (denoted as “SS”) having an energy bandgap of 0.8 eV before hydrogenation, andFIG. 9B-1is a graph of current versus voltage for the MS and SS after hydrogenation.

As is apparent from the insert ofFIG. 9B-2, the pristine samples have metallic properties at room temperature, and the MS and SS have resistances of 155 kΩ and 10 MΩ, respectively. However, as is apparent fromFIG. 9B-1, the MS and SS are converted, by hydrogenation, into semiconductor carbon nanotubes with a wide energy bandgap, with a rectifying effect at an ambient temperature that is greater in the SS than in the MS. The anisotropy, which can be defined as α=|I(Vd=2V)/I(Vd=−2V)|, is 5 and 10 for the respective MS and SS samples, i.e., the rectifying effect is more prominent in the SS sample.

FIG. 9C-2is a graph illustrating a curve for the pristine MS sample showing differential conductance (dI/dV) at 5.6K with respect to drain voltage before hydrogenation, andFIG. 9C-1is a graph illustrating a curve for the MS showing differential conductance (dI/dV) at 4.2K with respect to drain voltage after hydrogenation. As shown inFIG. 9C-2, the MS before hydrogenation has a value (dI/dV) of differential conductance at a zero-drain voltage, i.e., in a zero bias region, at 5.6K, which indicates that the MS has conductance and is nearly metallic. The graph ofFIG. 9Cillustrates that the MS becomes semiconductive with a widened energy bandgap of about 1. 88 eV after hydrogenation and that the conductance of the MS linearly increases beyond the energy bandgap region.

FIG. 9D-2is a graph illustrating a curve for the pristine SS sample showing differential conductance (dI/dV) at 5.6K with respect to drain voltage before hydrogenation, andFIG. 9D-1is a graph illustrating a curve for the SS sample showing differential conductance at 4.2K with respect to drain voltage after hydrogenation. As shown inFIG. 9D-2, the SS before hydrogenation has semiconductor properties with an energy bandgap of about 0.8 eV. The graph illustrated inFIG. 9D-1shows that the SS after hydrogenation has improved semiconductor properties with a widened energy bandgap of about 4.4 eV.

FIGS. 10A through 10Dillustrate the conversion of metallic carbon nanotubes into semiconducting carbon nanotubes by hydrogenation according to the present invention, in which changes in configuration and energy bandgap before and after hydrogenation are shown.FIG. 10Ashows the configuration of a (5,5) armchair metallic sample,FIG. 10Bshows the configuration of a (5,5)h semiconducting sample hydrogenated from the (5,5) armchair metallic sample,FIG. 10Cshows the energy level of the (5,5) metallic sample shown inFIG. 10A, andFIG. 10Dshows the energy level of the (5,5)h semiconducting sample shown inFIG. 10B. The (5,5) metallic sample was converted into the semiconducting sample shown inFIG. 10Bhaving an energy bandgap of 1.63 eV after hydrogenation.

FIGS. 11A through 11Dillustrate the conversion of a (9,0) zigzag semiconducting sample having a narrow energy bandgap into a (9,0)h semiconducting sample having a wide energy bandgap by hydrogenation according to the present invention, in which changes in configuration and energy bandgap before and after hydrogenation are shown.FIG. 11Ashows the configuration of a (9,0) semiconducting sample,FIG. 11Bshows the configuration of a (9,0)h semiconducting sample,FIG. 11Cshows the energy level of the (9,0) semiconducting sample shown inFIG. 11Ahaving a zero energy bandgap, andFIG. 11Dshows the energy level of the (9,0)h semiconductor carbon nanotube shown inFIG. 11Bhaving a relatively wide energy bandgap. The energy bandgap of the (9,0) semiconductor carbon nanotube, which has zero energy bandgap, was widened to 2.63 eV in the (9,0)h semiconducting sample after hydrogenation.

FIGS. 12A and 13Aillustrate configurations of intermolecular junctions between general carbon nanotubes and hydrogenated carbon nanotubes according to an embodiment of the present invention. The length of C—CH bonds is 1.48 Å. However, the length of all other bonds from the second layer at the interface layer on both sides is closer to the length of individual tubes. Carbon atoms of the metallic carbon nanotube located at the hydrogenated carbon nanotube side accept extra charges from the adsorbed hydrogen atoms of the hydrogenated carbon nanotube, rather than from carbon atoms at the metallic CNT side, so that more charges accumulate at the interface layer closer to the metallic carbon nanotube than the semiconductor hydrogenated carbon nanotube. Accordingly, a small degree of band-bending is highly likely to occur in the MS junction, whereas the degree of band-bending in the SS junction is negligible.

FIGS. 12B and 13Bare diagrams showing the height and energy bandgap of a M-S Schottky junction barrier formed by connecting the MS and the SS, and the height and energy bandgap of an S-S Schottky junction barrier formed by connecting two SSs, respectively.

In general, the height of a Shottky junction barrier is mainly determined by the charges in a neutral condition, and the migration of charges relies on the difference in electronegativity between a metal and a semiconductor. Most semiconductors do not simply comply with the Shottky model, and thus it is desirable to refer to a junction band diagram to understand the properties of semiconductors.FIGS. 12B and 13Bare junction band diagrams for the M-S and S-S junctions, respectively, where the junction barrier height is equal to the energy band offset.

Referring toFIG. 12B, the energy bandgap between a valence band (VB) and a conduction band (CB) in a semiconductor carbon nanotube region reaches 1.88 eV, and there is a relatively low energy barrier between the metallic carbon nanotube (MS) and the SS.

Referring toFIG. 13B, which is for the case where a semiconductor carbon nanotube (SS) having a relatively wide energy bandgap of 4.4 eV is connected with a semiconductor carbon nanotube (SS) having a narrow energy bandgap of 0.8 eV, apparently, the energy bandgap becomes wide with an energy barrier of 3.6 eV between the two SSs.

The M-S and S-S junctions are hole-doped, and an abrupt junction occurs in the interface region of one or two monolayers. In the M-S junction, charges may transfer from the MS sample to the SS sample, thereby inducing a sharp band-bending in the region of semiconductor carbon nanotubes. Although the migration of charges in the S-S junction is negligible, the charge transfer in the S-S junction may cause a spike.

FIGS. 14A and 14Bare graphs of current versus voltage for carbon nanotubes MS and SS before and after hydrogenation, respectively. Referring toFIG. 14A, before hydrogenation, both a pristine MS and a pristine SS having a narrow energy bandgap show a linear, proportional current-to-voltage relation which indicates that the pristine MS and SS have metallic properties and a metal-like nature, respectively.

However, after hydrogenation, the MS and the SS having the narrow energy bandgap have a rectifying effect like semiconductors having a large energy bandgap.

FIGS. 15A and 15Bshow graphs of current versus voltage before and after hydrogenation, respectively, in field effect transistors (FETs). In particular,FIG. 15Ais a graph of source-drain current Idat 5.6K with respect to gate voltage Vgin a FET having an electron channel formed using a non-hydrogenated metallic carbon nanotube (MC). As shown inFIG. 15A, the source-drain current Idis about −500 nA at a drain voltage Vdof −0.27V and about 500 nA at a drain voltage Vdof 0.27V. The source-drain current Idof the FET is constant regardless of gate voltage (Vg) variations. This means that the FET operates inappropriately as a transistor and that the MC acts merely as a metallic tube in the FET.

FIG. 15Bis a graph of source-drain current Idat 287K with respect to gate voltage Vgin a FET formed using hydrogenated multi-wall carbon nanotubes. As shown inFIG. 15B, when the drain voltage is positive, i.e., when a positive bias voltage is applied to the hydrogenated carbon nanotubes, a large current flows across the transistor. When the drain voltage is negative, current is suppressed, and a rectifying effect appears. In a range of drain voltage Vdfrom −2.4V to 2.4V, the source-drain current Idincreases as the gate voltage Vgincreases. Therefore, the FET properly and stably operates as a transistor at an ambient temperature, irrespective of temperature variations. These results provide support that an asymmetric metal-semiconductor (MS) junction has been formed between the hydrogenated carbon nanotubes and non-hydrogenated metallic carbon nanotubes in the FET.

FIG. 16Aillustrates a graph of drain current versus gate voltage at a predetermined drain voltage for the pristine SS sample before hydrogenation. Referring toFIG. 16A, the non-hydrogenated semiconductor carbon nanotubes show semiconductor properties with a gate effect at low temperature. The flow of a limited amount of current at a zero gate voltage means that the carbon nanotubes are already hole-doped, and the small anisotropy in current at drain voltages of different polarities means that the carbon nanotubes and a metal electrode are in asymmetrical contact.

FIG. 16Billustrates a graph of source-drain current versus gate voltage at a predetermined drain voltage for the SS sample after hydrogenation. Referring toFIG. 16B, after hydrogenation, the SS sample has a large energy bandgap, thereby providing an about 10 times greater rectifying effect than before hydrogenation. It can be expected from this result that an S-S junction between the narrow-bandgap and wide-bandgap semiconductor nanotubes has been formed in the SS sample by hydrogenation.

As shown inFIGS. 12B and 13B, the junction barrier height after hydrogenation is greater in the metallic carbon nanotube at 1 eV than in the semiconductor carbon nanotube at 0.35 eV.

In carbon nanotubes functionalized by hydrogen and a method for fabricating the functional hydrogenated carbon nanotubes according to the present invention, the energy bandgap of the carbon nanotubes can be easily controlled by varying the duration and temperature of hydrogenation, so that the conversion of metallic carbon nanotubes into semiconductor carbon nanotubes and of semiconductor carbon nanotubes having a relatively narrow energy bandgap into semiconductor carbon nanotubes having a relatively wide energy bandgap can be achieved. Such hydrogenated carbon nanotubes according to the present invention have a wide range of applications including, for example, use in various electronic devices, optoelectronic devices, energy storage devices, and the like, and particularly, can be used for nanotransistors workable at high temperature because the hydrogenated carbon nanotubes according to the present invention have stable C—H and C—C chemical bonds.