ELECTRONIC DEVICE

A device including first and second chips, the first chip including an electronic circuit and the second chip including a capacitor having a density greater than 700 nF/mm{circumflex over ( )}2, the first and second chips being bonded to each other by molecular bonding.

This application claims priority to French application number 2213881, filed Dec. 19, 2022, the contents of which is incorporated herein by reference in its entirety.

TECHNICAL FIELD

The present disclosure generally concerns electronic devices and their manufacturing methods.

PRIOR ART

There is a need to place capacitors close to electronic circuits, to optimize the supply of power to the electronic circuits. In particular, there is a need to significantly decrease equivalent stray inductances (ESL) and equivalent stray resistances (ESR), to greatly increase the efficiency of circuits. Conventionally, the connection of the capacitors, for example, discrete, to an active chip is performed by wire connection or by metal balls having dimensions in the range from 100 μm to 1 mm. These connections themselves generate stray inductances (from 5 to 100 pH) and/or resistances (20-100 mOhms). These stray inductances or resistances are equivalent to or even exceed the stray inductances or resistances of ultra-high-performance capacitors (1 μF/mm2).

SUMMARY OF THE INVENTION

There exists a need for very narrows interconnections of ultra-high-performance capacitors, that is, having a high value and low ESR and ESL values, with active devices, for example, transistors, which are increasingly integrated and sensitive to the quality of the power and current supply. Conventional solutions of transfer of capacitive elements onto printed circuits or into packages no longer address this need, which requires a very dense integration, as close as possible to the transistors, and thus very high connection densities.

An embodiment overcomes all or part of the disadvantages of known methods of manufacturing chips comprising capacitors.

An embodiment provides a device comprising first and second chips, the first chip comprising an electronic circuit and the second chip comprising a capacitor having a density greater than 700 nF/mm{circumflex over ( )}2, the first and second chips being bonded to each other by molecular bonding.

Another embodiment provides a method comprising the forming of a first chip comprising an electronic circuit, and the forming of a second chip comprising a capacitor having a density greater than 700 nF/mm{circumflex over ( )}2, the method further comprising the bonding of the first and second chips by molecular bonding.

According to an embodiment, the first chip comprises an interconnection network and a semiconductor substrate inside and on top of which components of the electronic circuit are located.

According to an embodiment, the capacitor comprises a stack of a first insulating layer between two second conductive layers, the stack being located in a first anodized metal region.

According to an embodiment, the second chip comprises a third insulating layer having a first planar surface and a second surface, the second surface being covered with a fourth layer comprising at least the first region.

According to an embodiment, the first region is surrounded with a fourth insulating anodized metal region.

According to an embodiment, the method comprises the forming, on a support, of the third insulating layer and an of an anodizable metal layer.

According to an embodiment, the fourth layer of the second chip comprises second insulating anodized metal regions and third metal regions, the third regions being separated by second regions.

According to an embodiment, the method comprises the anodizing of the metal layer at the locations of the first and second regions.

According to an embodiment, the method comprises the bonding of the first chip to a handle and the removing of the support to expose the planar surface of the third layer.

According to an embodiment, the first and second chips are bonded by hybrid molecular bonding, the third insulating layer and the interconnection network comprising first conductive tracks located in contact with one another.

According to an embodiment, the surface of the substrate opposite to the interconnection network is covered with a fifth insulating layer and second conductive tracks, the fifth layer and the second conductive tracks being configured to be bonded to the third layer and to the first tracks by molecular bonding.

According to an embodiment, the chips are bonded by oxide-to-oxide molecular bonding, the device comprising vias extending in the first and second chips, crossing the third layer, and reaching a conductive track buried in the interconnection network.

According to an embodiment, the vias are formed after the bonding of the first and second chips.

According to an embodiment, each of the terminals of the capacitor is coupled to a third region.

DESCRIPTION OF EMBODIMENTS

For the sake of clarity, only the steps and elements that are useful for the understanding of the described embodiments have been illustrated and described in detail.

Unless specified otherwise, the expressions “about”, “approximately”, “substantially”, and “in the order of” signify plus or minus 10%, preferably of plus or minus 5%.

FIG.1schematically shows an implementation mode of a method of manufacturing a device comprising a capacitor close to an electronic circuit.

The method comprises a step10during which a first chip is formed. The first chip comprises an electronic circuit. The first chip for example comprises transistors. The first chip preferably comprises a semiconductor substrate, inside and on top of which are formed transistors, and an interconnection network. The interconnection network for example comprises insulating layers and a network of conductive tracks and of conductive vias. The first chip comprises a planar surface adapted to molecular bonding.

The method comprises a step12during which a second chip is formed. The second chip comprises at least one metal-insulator-metal capacitor, that is, a capacitor comprising a stack of an insulating layer and of two metal layers, the insulating layer being located between the metal layers. The capacitor stack is located on a metal layer comprising at least one anodized region. Said region of the metal layer comprises a plurality of cavities, or nanopores, the stack forming the capacitor extending over the walls and the bottom of the cavities and over the portions of the layer between the cavities.

Preferably, the second chip comprises no other active electronic components than capacitors, and possibly resistors. For example, the second chip comprises no transistor. For example, the second chip comprises no semiconductor substrate.

The second chip comprises a planar surface, adapted to molecular bonding.

Steps10and12may be carried out independently, for example successively or in parallel.

The method further comprises a step14during which the first and second chips are bonded to each other by molecular bonding. More specifically, the planar surfaces of the first and second chips are bonded to each other by molecular bonding.

FIG.2shows an embodiment of a device16comprising a capacitor18, and possibly resistors, not shown, close to an electronic circuit. Device16is obtained by a method such as that described in relation withFIG.1.

Device16comprises a chip20. Chip20, like the first chip ofFIG.1, comprises a semiconductor substrate22. Electronic components, such as transistors, are located inside and on top of substrate22. Chip20further comprises an interconnection network24. Interconnection network24comprises insulating layers26, the separations of the different layers not being shown inFIG.2. Interconnection network24further comprises conductive vias28and conductive tracks30. Network24comprises metal tracks32flush with a surface34of network24. Surface34is the surface most distant from substrate22, in other words the surface opposite to the surface of network24in contact with substrate22. Tracks32are adapted to a hybrid molecular bonding step.

Vias28and tracks30,32enable to form electric connections between electronic components of chip20and other components of chip20or components external to the chip, for example capacitor18.

Device16also comprises a chip36. Chip36corresponds to the second chip ofFIG.1. Chip36comprises a capacitor18, and optionally resistors. Although a single capacitor18is shown inFIG.2, chip36may comprise a plurality of capacitors18.

Chip36comprises an insulating layer38. Layer38has, for example, a thickness in the range from 10 nm to 1 μm. Insulating layer38comprises a surface40. Chip36further comprises metal tracks42in layer38. Metal tracks42are flush with surface40of layer38. Preferably, tracks42run through track38. In other words, tracks42preferably have the same thickness as layer38. Surface40of layer38is bonded by hybrid molecular bonding to surface34of chip20. Thus, each track42is preferably located in such a way as to be in contact with a track32. Connections between chip20and chip36are thus formed via tracks32and42.

Chip36further comprises elements43made of insulating material, for example of the same material as layer38. Elements43are located on layer38, more precisely on the surface opposite to surface40. Elements43preferably do not cover, even partially, tracks42. Elements43cover certain portions of layer38. Elements43do not fully cover layer38. Elements43for example have a thickness in the range from 300 nm to 3 μm.

Chip36comprises a layer44. Layer44is located on layer38, on tracks42, and on elements43. More precisely, layer44covers the surface opposite to surface40of layer38. Layer44for example has a thickness lower than 20 μm, for example, substantially equal to 10 μm.

Layer44comprises regions46. Regions46are conductive regions. Regions46are made of an anodizable conductive material, preferably of metal. Regions46are for example made of aluminum or of tantalum. Each track42is preferably covered, preferably in contact, with a region46.

Regions46extend, at least in certain portions of layer44, along the entire height of layer44. Regions46thus extend from the upper surface of layer20to the upper surface of layer44. Each region46enables to continue the electric link of the track42having region46in contact therewith.

Regions46are for example surrounded with regions48of layer44. Regions48are insulating regions. Regions48are made of the material of regions46, for example of aluminum, which has been anodized, for example to obtain alumina. Regions48are thus porous regions. In other words, regions48comprise a plurality of cavities, or nanopores, not shown, extending, for example, along the entire height of region48.

Regions48are located on elements43. Preferably, each element43is at least partially, for example predominantly, covered with a region48. Preferably, each region48covers an element43. Elements43and regions48enable to form a lateral insulation in layer44.

Layer44further comprises one or a plurality of regions50, having capacitors18located therein. Each region50for example comprises a single capacitor18. In the example ofFIG.2, layer44comprises a single capacitor18, and a single region50. Capacitor18is a high-density capacitor, that is, a capacitor having a density greater than 700 nF/mm{circumflex over ( )}2, for example greater than 1 μF/mm{circumflex over ( )}2.

Region50extends in front of a portion of layer38not covered with elements43. Thus, region50does not face, even partially, an element43. Region50extends from the upper surface of layer44, that is, the surface most distant from layer38. Region50is thus flush with the upper face of layer44. Region50for example does not extend all the way to layer38. Preferably, the height of region50is substantially equal to the height of the portions of regions46located in contact with elements43. Thus, region50is separated from layer38, for example, by a distance substantially equal to the height of regions43. Preferably, region50is separated from layer38by a conductive portion52, for example a layer of aluminum or of an alloy comprising aluminum covered with a tungsten layer forming a stop layer for the anodization of region50.

Region50is, like regions48, made of the material of regions46, for example of aluminum, which has been anodized, for example to obtain alumina. Region50thus comprises a plurality of cavities, not shown, for example extending along the entire height of region50. The density of cavities in region50is for example greater than 40 cavities/μm{circumflex over ( )}2.

Capacitor18is a metal-insulator-metal or MIM capacitor. Capacitor18comprises a stack of layers, not shown inFIG.1, of an insulating layer located between two conductive layers, preferably made of metal. The stack of layers of capacitor18is conformally located on the porous structure of region50.

A lower layer of the stack of capacitor18, that is, one of the conductive layers, preferably a metal layer, extends conformally over the porous structure, and in particular in the cavities of region50. The lower layer of a capacitor18covers, preferably entirely, the upper surface of region50, the side walls of the cavities, and the bottom of the cavities. The lower layer of a capacitor18is thus in contact with portion52.

An intermediate layer of the stack of capacitor18, that is, the insulating layer, extends conformally over the lower layer. The intermediate layer extends inside of the cavities. The intermediate layer preferably fully covers the lower layer.

An upper layer of the stack of a capacitor18, that is, the other conductive layer, for example made of metal, extends conformally over the intermediate layer. The upper layer extends in the cavities. The upper layer for example fills the cavities. The upper layer preferably fully covers the intermediate layer. The upper layer for example comprises a planar upper face extending over the upper surface of the porous structure.

The layer44for example comprises one or a plurality of insulating regions54delimiting region50. Region50is surrounded with regions54. Region50is thus laterally insulated from the rest of layer44. Region50is preferably directly in lateral contact with regions54. Thus, region50is preferably not separated from regions54by other regions of layer44. In particular, region50is preferably not separated from regions54by regions of the material of region46which has not been anodized and which is not porous.

Regions54are insulating regions. Regions54are made of the material of layer44, for example of aluminum which has been anodized, for example of alumina. Regions54are thus porous regions. In other words, regions54comprise a plurality of cavities, not shown, extending, for example, along the entire height of region54. Preferably, the height of regions54is substantially equal to the height of the region50. Regions54extend from the upper surface of layer44, that is, the surface most distant from layer38. Regions54are thus flush with the upper surface of layer44. Regions54for example do not extend all the way to layer38. Regions54are preferably separated from layer38by conductive portion52.

Chip36further comprises insulating portions56. Insulating portions56partially cover the upper surface of layer44. Chip36further comprises a conductive track58located on the upper surface of layer44and of certain portions56. In particular, track58extends over the upper surface of region50, and more precisely over the upper layer of the stack of capacitor18. Preferably, track58fully covers the upper surface of the upper layer of the stack. Track58allows the connection between an electrode of capacitor18and external elements.

The portion52of a region46, in contact with the bottom layer of the capacitor, allows the connection between another electrode of the capacitor and elements external to the chip. The region46comprising portion52extends, for example, around regions50and54. The region46comprising portion52is in contact with a track42.

Track58is electrically coupled to, preferably in contact with, a region46. For example, said region46is separated from capacitor18by a region48, at least a portion of region46in contact with the lower layer of the stack, and a region54. The regions46having track58extending in front of them are covered with portions56. Thus, track58is entirely separated from the regions46having track58extending in front of them by one or a plurality of insulating portions56.

FIGS.3to8illustrate steps, preferably successive, of an implementation mode of the method ofFIG.1. More precisely,FIGS.3to8illustrate steps, preferably successive, of an implementation mode of a method of manufacturing the device ofFIG.2.

FIG.3shows a step of an embodiment of the method ofFIG.1. More precisely,FIG.3shows a step of manufacturing of chip36.

During this step, layer38is formed on a support60, more precisely on an upper surface of support60. Layer38is made of an insulating material, for example of silicon oxide. Layer38preferably covers, during its forming, the entire upper surface of support60.

Support60is, for example, a semiconductor substrate. Support60is for example made of a material selectively etchable over the materials of layer38and of tracks42. The upper surface of support60is preferably planar.

The step ofFIG.3further comprises the forming of tracks42in layer38. For example, cavities crossing layer38, that is, reaching support60, are formed in layer38at the locations of tracks42and are filled with the material of tracks42.

The step ofFIG.3also includes the forming of elements43. Elements43are made of an insulating material, preferably of the same material as layer38. For example, elements43are formed on the upper surface of layer38.

The step ofFIG.3further comprises the forming of a layer62made of an anodizable conductive material, preferably of metal. Layer62is for example made of aluminum or of tantalum. Layer62is made of the material of regions46.

Preferably, layer62preferably comprises no cavities during its deposition. Preferably, the lower and upper surfaces of layer62, that is, the layer closest to layer38and the layer most distant from layer38, are planar and parallel. Layer62is for example made of aluminum.

FIG.4shows another step of an implementation mode of the method ofFIG.1.

During this step, a mask64is formed on the upper surface of layer62. Mask64is for example made of the same material as portions56. Mask64comprises openings in front of the locations of regions48,50, and54.

The step ofFIG.4further comprises the forming of nanopores at the locations of regions48,50, and54. More precisely, the step inFIG.4for example comprises the forming of nanopores to form regions48and a region68corresponding to the locations of regions50and54. For clarity, the nanopores are not shown.

To form nanopores in regions48and68, the portions of layer62corresponding to regions48and68are submitted to an anode oxidation process, enabling to form a nanostructured insulating layer.

Anodizing, or anodic oxidation, is a wet electrolytic process. The principle is based on the application of an imposed potential difference between two conductive electrodes immersed in an electrolytic solution, which may for example be acidic. In the example of the method ofFIGS.3to8, one of the conductive electrodes, for example the anode, is layer62. The application of a potential to an electrode induces a growth of alumina on its surface if the electrode is made of aluminum. The dissolving of the aluminum electrode in the acid bath causes the appearing of nanopores or of cavities in the electrode surface.

The nanopores for example advantageously have a diameter in the order of 80 nm and are spaced apart by 50 nm. The nanopore density is for example 40 cavities/μm2. Further, the anodization process used enables to obtain nanopores emerging onto layer62. In other words, nanopores can be considered as nano-cylinders, having a side emerging onto layer52.

The nanopore forming method is carried out in such a way that the nanopores reach elements43in regions48and do not reach layer38in region68. Thus, portion52is formed under region68.

FIG.5shows another step of an implementation mode of the method ofFIG.1.

The method ofFIG.5comprises the forming of the stack of layers of capacitor18. More specifically, capacitor18comprises a stack of a lower metal layer, of an insulating layer, and of an upper metal layer conformally formed in region50, as described in relation withFIG.2.

Thus, the lower layer of the stack of capacitor18extends conformally over the nanopore structure, and in particular inside of the nanopores of region50. The lower layer of capacitor18covers in region50, preferably fully, the upper surface of layer44, the side walls of the nanopores, and the bottom of the nanopores. The lower layer of capacitor18is thus flush with the upper surface of portion52. The lower layer of the capacitor18is thus electrically coupled, preferably in contact, with a region46via the portion52located under capacitor18.

The intermediate layer of the stack of capacitor18extends conformally over the lower layer. The intermediate layer extends inside of the nanopores. The intermediate layer preferably fully covers the lower layer.

The upper layer of the stack of capacitor18extends conformally over the intermediate layer. The upper layer extends inside of the nanopores. The upper layer for example fills the nanopores. The upper layer preferably fully covers the intermediate layer. The upper layer comprises, for example, a planar upper surface extending above the upper surface of the nanopore structure in region50.

The step shown inFIG.5further comprises the forming of the portions of insulating material56. Portions56are, for example, obtained from mask64, for example by etching openings at the locations where portions56are not present. Alternatively, mask64may be removed and replaced with portions56.

The step ofFIG.5also comprises the forming of track58.

FIG.6shows another step of an implementation mode of the method ofFIG.1.

During this step, a handle66is bonded to chip36. Handle66is bonded to the upper surface of chip36, that is, the surface opposite to support60.

Handle66is bonded to chip36by a layer of bonding material, for example a temporary glue layer68. Temporary glue layer68is located on the upper surface of chip36. More precisely, temporary glue layer68is formed in such a way as to cover the entire upper surface of chip36. The upper surfaces of track58, of portions56, and of layer44are covered with temporary glue layer68.

FIG.7shows another step of an implementation mode of the method ofFIG.1.

During this step, support60is removed, for example by a grinding step, for example, coarse and then fine, followed by chemical etching.

The step shown inFIG.7also comprises the forming of chip20. The forming of chip20may be carried out parallel or successively to the forming of chip36. Thus, chip20is formed independently from the forming of chip36.

The forming of chip20corresponds, for example, to the forming of an integrated circuit chip.

The forming of chip20comprises the forming of electronic components, for example of an electronic circuit, in substrate22. The forming of chip20comprises, for example, the forming of transistors in substrate22.

The forming of chip20further comprises the forming of an interconnection network24. The forming of the interconnection network comprises the forming of insulating layers26, and the forming in layers26of a network of conductive tracks30and of conductive vias28.

The forming of interconnection network24further comprises the forming, at the upper surface34of chip20, that is, the surface of the interconnection network most distant from substrate22, of tracks32flush with the upper surface of network24. The upper surface of network24is a planar surface, adapted to molecular bonding.

FIG.8shows another step of an implementation mode of the method ofFIG.1.

During this step, chips20and36are bonded to each other by hybrid molecular bonding, via planar surfaces34and40. Thus, tracks32and42are placed into contact, and the upper layer26of the stack of network24is placed into contact with the lower surface of layer38. Preferably, each track32is placed into contact with a track42.

The molecular bonding of chips20and36comprises an anneal step, for example below 450° C., for example substantially equal to 400° C.

Further, the step ofFIG.8comprises the removing of handle66and of bonding layer68. The removing of handle66and of bonding layer68may be performed before or after the anneal step, according to the composition and the thermal budget of the glue.

FIG.9shows an embodiment of another device70comprising a capacitor close to an electronic circuit resulting from another implementation mode.

The device70ofFIG.9comprises elements identical to the device16ofFIG.2, which will not be described again in detail. In particular, device70comprises:a chip20a, comprising substrate22inside and on top of which electronic components and interconnection network24are formed;chip36a, comprising insulating layer38, regions48,50,54, capacitor18, portions56, and track58.

Device70differs from the device16ofFIG.2in that, in device70, chips36aand20aare bonded to each other by oxide-to-oxide bonding and not by hybrid bonding.

Thus, chip20adiffers from the chip20ofFIG.2in that the upper surface of chip20a, that is, the upper surface of network24, that is, the surface of chip20amost distant from substrate22, is adapted to oxide-to-oxide molecular bonding. Thus, the upper insulating layer26of network24, that is, the layer26most distant from the substrate, comprises no tracks42.

Thus, during the manufacturing of chip20a, that is, before the molecular bonding step of chips20aand36a, the upper surface of chip20ais entirely formed of oxide, that is, the material of layer26.

Further, chip36adiffers from the chip36ofFIG.2in that layer38comprises no tracks42. Further, portions56for example cover all the regions46.

Thus, during the manufacturing of chip36a, that is, before the step of molecular bonding of chips20aand36a, the lower surface of chip20a, that is, the lower surface of layer38, is entirely formed of oxide, that is, the material of layer38.

Device70comprises conductive vias72. Vias72extend from chip20ato chip36a. More precisely, each via72extends, for example, from a conductive track32aburied in network24. One end of each via72is, for example, in contact with the upper surface of a track32a. Each via72preferably extends all the way to the upper surface of chip36a. Preferably, each via72crosses layer38and an element43. Preferably, each via72at least partially, preferably entirely, crosses a region48. Each via72is thus separated from regions46and from the other vias72by layer38, elements43, and regions48. Vias72are connected to one another, to capacitors18, or to elements external to device70by conductive elements. In particular, a via72is coupled to track58. In other words, a portion of track58extends all the way to, and is in contact with, the upper end of a via72, that is, the end flush with the upper surface of region48, that is, the end opposite to the end located in chip20ain contact with tracks32a. A first terminal of capacitor18is thus coupled to a circuit of chip20via track58, a via72, and interconnection network24.

Another via72, comprising an end flush with the upper surface of a region48, is coupled, for example by a conductive track74extending over the upper surface of chip36a, to the region46comprising portion52, that is, the region56coupled to a second terminal of capacitor18. In other words, track74, for example a metal track, is for example in contact with the end of via72and with the upper surface of the region46comprising portion52. Track74preferably runs through the portion56extending above the region46comprising portion52. In the case where track74extends over other regions46, track74is preferably separated from the other regions46by a portion56.

Vias72are preferably formed after the molecular bonding step. Upper layer26and layer38preferably comprise no metal track, except for vias72. Thus, once chips20aand36ahave been bonded to each other, cavities are formed from the upper surface of chip36a, to reach tracks32a, and then filled with conductive material.

FIG.10shows an embodiment of a device76comprising a capacitor close to an electronic circuit resulting from another implementation mode.

The device76ofFIG.10comprises elements identical to the device16ofFIG.2, which will not be described again in detail. In particular, device76comprises:the chip36such as described in relation withFIG.2; anda chip20bcomprising interconnection network24and substrate22.

Device76differs from device16in that chip36is not bonded to the upper surface34of chip20b, that is, the upper surface34of interconnection network24, but to a lower surface78of chip20b, that is, the surface opposite to surface34of chip20b. In other words, chips20band36are bonded to each other by hybrid molecular bonding between surfaces40and78.

Chip20bcomprises, like chip20, active electronic components. Chip20bcomprises, for example, transistors80schematically shown inFIG.10. Transistors80are located inside and on top of substrate22. Thus, transistors80comprise regions in substrate22, for example source and drain regions. Transistors80comprise, for example, a control terminal located on the substrate, for example on the upper surface of the substrate, that is, in the insulating layers26of the interconnection network.

Surface78of chip20bis adapted to a hybrid molecular bonding, for example metal-oxide. Chip20bcomprises a layer82of an insulating material, for example, of silicon oxide, covering the lower surface of substrate22, that is, the surface of substrate22most distant from surface34. Chip20bcomprises tracks84in layer82. Tracks84are flush with surface78. Tracks84are located in such a way as to be in contact with tracks42, to allow the molecular bonding and the electric coupling with chip36.

Chip20bcomprises vias86extending from tracks84to the electronic components of chip20b. Vias86are, for example, insulated conductive vias, that is, vias comprising a conductive core and an insulating sheath.

Chip20bcomprises, like the chip20ofFIG.2, conductive tracks30buried in network24, conductive vias28, and tracks32flush with surface34of chip20b. Thus, chip20bis coupled by its lower surface78to capacitor18, and may be connected, via interconnection network24, to other elements external to the chip.

In other embodiments, the transistors80may be replaced with other types of transistors.

An advantage of the embodiments described in detail is that it is possible to form capacitors very close to chips comprising electronic circuits, only separated, for example, by a metallization level.

Another advantage of the described embodiments is that the manufacturing of the capacitors does not risk causing damage to the electronic circuits. In particular, the electronic circuits are not subjected to the thermal budget of the forming of the capacitor, but only to that of the bonding of the two chips.

Various embodiments and variants have been described. Those skilled in the art will understand that certain features of these various embodiments and variants may be combined, and other variants will occur to those skilled in the art. In particular, although the described steps of the method refer to chips, the steps may be implemented on a silicon wafer to simultaneously form a large number of chips. Thus, the chips may be manufactured individually and bonded to one another. According to another embodiment, a plurality of chips are simultaneously formed in semiconductor wafers. The chips are then individualized and bonded to one another.

Finally, the practical implementation of the described embodiments and variants is within the abilities of those skilled in the art based on the functional indications given hereabove.