Energetic fluid product and its application to the supply of combustible matter to a reaction chamber

An energetic fluid product containing finely divided solid combustible matter suspended in at least one liquid phase and capable of being made to circulate in a line for supplying a treatment chamber, and a device for the preparation and a particular application of this product. The solid particles (13) are dispersed homogeneously within a stable foam produced by mixing a gas phase with the liquid phase to which stabilizing and emulsifying products have been added, and the liquid phase consists solely of fine film (12) connecting the solid particles (13) together and confining gas bubbles (11) which occupy the spaces between the solid particles (13). The invention applies in particular to the supply of combustible matter to a combustion chamber or to a reactor for coal gasification.

FIELD OF THE INVENTION 
The invention relates to an energetic fluid product containing finely 
divided combustible matter, a device for the preparation of such a product 
and a particular application of the product to the supply of combustible 
matter to a reaction chamber. 
PRIOR ART 
Various combustion or gasification processes are known which employ a 
reaction chamber supplied with solid combustible matter such as finely 
divided coal. 
The fuel must normally be introduced into the reaction chamber in a 
continuous manner, and for this purpose it is useful to prepare it in the 
form of a fluid product capable of being conveyed in feed lines using 
simple means. It is possible, for example, to employ pneumatic conveying, 
the particles being suspended in a stream of air, but this produces an 
auto-ignition and explosion hazard. When inert gas is not available 
cheaply, it is generally preferred to disperse the particles in a liquid 
phase to produce a mixture with the consistency of a slurry and capable of 
being conveyed for example by means of a positive displacement pump. The 
coal is generally suspended in water but, in this case, the combustion 
reactions are retarded, which makes it necessary to enlarge the combustion 
chambers, and the thermal yield of the reaction is greatly reduced since a 
considerable part of the energy provided serves only to vaporize water. 
The attempt is therefore to reduce the proportion of water as much as 
possible relative to the proportion of solid matter. However, as the 
concentration of solid is increased the viscosity of the product also 
rises and more energy needs to be employed to pump the product. For a 
minimum proportion of water, the viscosity of the mixture can be lowered 
by means of chemical additives, but the latter are costly and moreover can 
be corrosive. 
It has also been proposed to make use of the particle size of the solid 
particles because it is known that a denser mixture is obtained by 
employing particles belonging to at least two size ranges. It is then 
necessary to add to the particles normally employed particles other finer, 
particles in specified proportions, but the formation of such mixtures 
with a multimodal particle size distribution is costly, and in any case 
the quantity of solid matter present cannot exceed 70 to 75%, depending on 
the nature of the solid. 
Now, the finer the particle size of the fuel, the more efficient is its 
valorization, since the time required for the reaction is a function of 
particle size. It is therefore advantageous to try to employ fuels with 
the finest particle size possible this which obviates the use of filters 
and results in reducing the content of liquid to the maximum degree 
without, however, reaching a compactness which would prevent pumping for 
the purpose of introducing the mixture into the reactor. 
The problem of the introduction of the combustible matter into a reactor is 
further complicated by the fact that the reaction yield is better when the 
reactor operates under pressure, making it necessary also to place the 
product under pressure if it is intended to introduce it into the reactor 
continuously. The difficulties in introducing a mixture containing little 
moisture are then increased. 
A consequence of these difficulties is that, until now, the fluid products 
produced for supplying a reactor with combustible matter generally 
contains a proportion of liquid which is at least 30%. Of course, the 
energetic disadvantages of the use of such a proportion of a liquid phase 
can be reduced if the latter is formed by a liquid fuel but, in this case, 
the economic benefit of the process is also reduced. 
SUMMARY OF THE INVENTION 
The invention has as its subject a new energetic fluid product in which the 
proportion by weight of liquid phase relative to that of the solid 
particles is appreciably reduced in comparison to the known product and 
which additionally makes it possible to employ very fine particles. 
The fluid product according to the invention consists of a stable foam 
produced by mixing a gaseous phase with the liquid phase to which 
stabilizing and emulsifying products have been added and in which the 
solid particles are homogeneously dispersed, the liquid phase consisting 
solely of fine films connecting the solid particles together and confining 
the gas bubbles which occupy the spaces between the solid particles. 
In such a product according to the invention, the solid particles can have 
any particle size distribution and the proportion by weight of solid phase 
can reach at least 70%. 
According to a characteristic of the invention, the gaseous phase can be an 
inert gas, a combustive gas or a fuel gas. 
Another subject of the invention is a device for preparing a fluid product 
according to the invention comprising a means for preparing a stable foam 
by incorporating a gaseous phase in a liquid phase to which emulsifying 
and stabilizing products have been added, and a means for dispersing the 
particles of combustible matter homogeneously within the foam thus 
prepared. 
In a particularly advantageous embodiment the means for dispersing the 
solid particles homogeneously in the foam incorporate a double-screw mixer 
comprising, inside an elongated cylindrical sleeve, an agitator in the 
shape of a helical ribbon driven in rotation around the axis in a 
direction which determines the advance from upstream to downstream and 
over the periphery of the sleeve of the foam introduced through an orifice 
located at the upstream end, the helical ribbon surrounding an axial free 
space the upstream part of which is entered by a screw feeder for the 
introduction of a specified flow of solid particles. 
In a particular application, the invention also relates to a process for 
introducing into a reaction chamber solid combustible matter which is 
finely powdered and dispersed homogeneously in a stable foam, in which the 
liquid phase consists solely of the films connecting the solid particles 
together and confining gas bubbles which occupy the spaces between the 
particles, the said foam being then made to move in a duct for supplying 
the reaction chamber. 
To prepare the fluid product according to the invention, the foam is 
preferably first produced by vigorous agitation of the liquid phase in the 
presence of the gaseous phase, and the solid particles are then dispersed 
in the foam thus prepared, the latter being capable of being stored in 
anticipation of subsequent use. 
According to an advantageous characteristic, before being introduced into 
the chamber, the fluid product can be subjected to a pressure rise 
resulting in an increase in the proportion of solid matter per unit 
volume, up to a pressure below the limiting pressure starting from which 
the volume of the compressed product remains constant.

DETAILED DESCRIPTION 
FIG. 1 shows diagrammatically a sample of the product 1 which consists of a 
foam made of bubbles 11 confined by liquid films 12 in the shape of a 
meniscus, within which foam solid particles 13 are homogeneously 
dispersed, joined together by the liquid films 12. The solid particles 13 
are shown in symbolized by spheres in the drawing as spheres, but of 
course, they may be of any shape. The average size of the particles is of 
the order of 50 microns but can even go down under 20 microns. The gas 
bubbles 11 can be of the order of a millimeter in size but can microns, 
may be even smaller than 20 microns. The gas bubbles making it possible to 
increase the proportion of solid particles incorporated in the foam. 
It can be seen that, in such a product, the liquid phase consists solely of 
the films 12 connecting the particles 13 and that, consequently, the 
weight proportion of the liquid in the product can be greatly reduced. 
However, given that the particles are separated from each other by the 
bubbles, the mixture is pumpable and can be conveyed within ducts by any 
known means, and behaves as a compressible fluid. 
FIG. 3 shows by way of example a diagram of the preparation of such a 
product. The liquid phase, for example water, is introduced into a vat 2 
in which it is mixed vigorously with a thickener product 21, which is 
introduced by a metering device and which enables a kind of gel 20 to be 
produced. The latter is then conveyed to a second vat 23 in which water is 
also introduced through an entry 24 and an emulsifier product of the 
surfactant type through a line 25. The whole is mixed vigorously until all 
the liquid phase has been emulsified with the gas present in the 
enclosure. 
The foam 10 thus produced is directed to a third vat 4 into which the solid 
particles 13 are poured by means of a metering hopper 44. The whole is 
vigorously stirred to disperse the solid particles homogeneously within 
the product 1 which is then in the form shown diagrammatically in FIG. 1. 
The thickener 21 introduced into the vat 2 makes it possible to stabilize 
the emulsion by suppressing spontaneous ruptures of the liquid films 
providing the partitioning of the foam, and thus ensures that the solid 
particles are kept in suspension. It is possible to employ hygroscopic 
non-volatile soluble products such as carboxymethylcellulose or, for 
example, glycerol, dodecane or polyvinylalcohol. 
The emulsifier product 25 is a surfactant which makes it possible to 
emulsify the gas in water. It is possible to employ an alkylarylsulfonate 
or another known foaming agent, for example a saponified fatty acid, an 
amine, quaternary ammonium, alkylpolyethoxyetherphosphate and the like. 
As an example, a product has been produced in which the liquid phase 
prepared before the addition of the gas contained 1% of surfactant and 
0.2% of stabilizer. 
Given that the separation of the solid particles which ensures the fluidity 
of the product is produced by the presence of gas bubbles of negligible 
weight, it is possible in fact to incorporate in the product a very 
considerable proportion by weight of solid phase without the need to 
combine particles of different particle sizes. 
Thus it has been possible to prepare a fluid product containing 75% by 
weight of powdered coal, 80% of whose particles had a diameter below 80 
microns. 
It should be noted, moreover, that the presence of air in the form of gas 
bubbles in the mixer is not dangerous, even in a considerable proportion, 
because the coal particles are coated with the liquid films confining the 
bubbles, and because the latter reduce the danger of oxidation of the 
particles which might produce a rise in temperature. 
To employ the foam, it can be circulated by means of a pump 27 in a closed 
circuit 28 from which the foam needed is withdrawn by the metering pumps 
29. It is also possible to place the circuit 28 under pressure and to 
replace the metering pumps by simple inlet valves making it possible, for 
example, to feed the burners of a reaction chamber 6. 
In fact, according to an advantageous characteristic, the fluid product 
consisting of the stabilized foam can be subjected to a pressure rise 
which determines a reduction in the size of the bubbles and brings the 
particles closer together and consequently produces an increase in the 
density of the product. 
When the product is at atmospheric pressure, the coal particles dispersed 
randomly in the foam are practically out of contact with each other. The 
mixture is then easily pumpable. 
When the pressure P applied to the product is increased, the particles come 
closer together, the bubbles being reduced in diameter. However, the 
product remains pumpable so long as the particles remain sufficiently 
separated from each other. 
There is therefore a limiting pressure P starting at which, as shown in 
FIG. 2, the coal particles are arranged according to a close packing. In 
this case, the mixture is no longer pumpable, the friction between the 
particles resisting their motions. 
It follows that the pressure increase applied to the liquid product must 
remain below the limit starting from which the specific volume of the 
product is no longer reduced when the pressure is increased. 
This limit depends on the concentration of solid particles and can be 
determined either empirically, by a series of tests, or by calculation. 
It is known, for example, that a close packing of a unimodal particle size 
distribution incorporating 80% of particles of a size below 80 microns 
corresponds to a porosity of approximately 0.4. This means that, in a 
close packing, the volume occupied by the solid particles is 60% of the 
total. 
Moreover, it has been determined experimentally that, at a proportion of 
solid particles of 75% by weight, a kilogram of product occupies a volume 
of approximately two liters. By comparing the gas to a perfect gas and 
applying Mariotte's law, it is therefore possible, using these data and 
starting from atmospheric pressure, to determine the limiting pressure 
rise beyond which the volume occupied by a specified mass of product no 
longer varies. For example, in the case of a product based on coal, air 
and water and containing 75% by weight of coal, the limiting pressure is 
of the order of 9 bars. Care will therefore be taken, in respect of the 
use circuit 27, 28 and 29, not to reach this pressure, at which a complete 
blockage of the lines would be produced. 
This pressure may be found to be too low for feeding a gasification 
reactor. Nevertheless, it has been calculated for a product prepared at 
atmospheric pressure and at ambient temperature. Now, it can be shown that 
when the product is prepared at an absolute pressure above atmospheric 
pressure, for example 5 bars, the limiting pressure can reach 45 bars. 
Furthermore, the limiting pressure is also a function of the relationship 
between the temperature of use and the temperature of preparation. Thus, 
in the case where the product is prepared at 20.degree. C., the limiting 
pressure can be increased by 10% if, at the time of use, the temperature 
is increased to 50.degree. C., provided of course that the foam remains 
stable at such a temperature. 
FIG. 4 shows, by way of example, a plant for the preparation under pressure 
of a fluid product based on coal, air and water. 
The aqueous solution prepared, as in the case of FIG. 3, by mixing water 
with a thickener and then an emulsifier, is delivered by a pump 31 to a 
device 3 for preparing the foam, consisting of a pipe in the middle of 
which is placed a venturi 30. Air is blown into the venturi by a 
compressor 32 and is thus incorporated in the aqueous solution to form a 
foam which is directed to the mixer 4. The latter, which can incorporate 
several components in line, consists essentially of a stirrer in the shape 
of a helical ribbon 41 driven in rotation around its axis by a motor 42 
inside a cylindrical sleeve 4 equipped with an opening 43 for the entry of 
the foam placed at the upstream end in the direction of movement of the 
product resulting from the rotation of the helical ribbon 41. The latter, 
moreover, encloses a free axial space into which enters a screw feeder of 
a known type, comprising a hopper 44 provided at its base with a screw 
driven in rotation around its axis and which projects into a tube 45 
opening out into the free space determined by the helical ribbon 41 in the 
axis of the sleeve 4. 
As a result, the foam prepared in the device 3 and entering the sleeve 4 
through the orifice 43 is driven downstream along the inner periphery of 
the sleeve by the rotation of the ribbon 41 and picks up the finely 
divided coal which is poured into the hopper 44 and which therefore is 
incorporated within the foam at a flow rate determined by the rotation of 
the screw. It is possible in this way to obtain a perfectly homogeneous 
dispersion of solid particles within the foam. 
Such a mixture can operate at a low pressure below the limiting pressure, 
for example of three to six bars, and supply in this way a main vessel 5 
maintained at the desired pressure. 
The product prepared in this way can therefore be stored in advance in a 
vessel maintained under a low pressure. 
If the product is to be injected into the reactor under a higher pressure, 
it is advantageous to pass through a buffer vessel 51 which is under a 
pressure above the pressure of use, for example ten bars. The buffer 
vessel 51 is supplied from the main vessel 5 by a positive displacement 
pump fitted with a device for forced feeding. In fact, the high proportion 
of gas present in the product stored in the vessel 5 could give rise to 
irregular and random delivery. The forced feeding device could consist 
very simply of an Archimedean screw placed in the bottom of the storage 
vessel 5 and feeding a positive displacement pump 52. 
After the buffer vessel 51 it is possible to introduce the fluid product 
directly into the reactor 6 by means of a feed line 61 fitted with a 
throttle valve 62 ensuring the let-down of the product down to the 
required pressure. 
If the buffer vessel 51 is at a pressure above the pressure of use, the 
release of the compressed gas present in the bubbles at the time of the 
injection into the reactor promotes the spraying of the fluid product and 
disperses the coal particles very efficiently in the reactor enclosure. In 
view of the fineness of the particles which can be reached by virtue of 
the process according to the invention, a real atomization of the 
combustible matter is produced in the reactor. 
Furthermore, in general, the possibility of employing, by virtue of the 
invention, coal of a particularly fine particle size presents a 
considerable advantage, the valorization of the fuel being the higher in 
proportion as its particle size is finer, since the time required for the 
reaction is a function of the particle size. 
It will also be noted that the three-phase composition position of the 
product, with a high proportion of gas, reduces the probability of impact 
of the particles against the walls, since the particles are held within 
the bubbles forming the foam, and as a result reduces the erosion of the 
injection devices. 
In addition, the possibility of preparing the product in advance in a 
stable, storable and directly usable form is a major advantage because it 
makes it possible to separate the plant for preparing the product from the 
users, the latter having to make provision only for the devices for 
pressurization and injection into the reactor of a prefabricated fluid 
product. 
Moreover, for the same proportion of coal, a foam according to the 
invention is transported in pipes with a smaller loss of pressure. It 
could thus be advantageous to prepare the combustible fluid product in a 
place eventually located very far from the place of utilization, for 
example near a coal-mine or to port, and to transport the prefabricated 
fluid product to a combustion installation which could be several hundreds 
miles away. 
Due to the small loss of pressure, the need of energy for transportation 
would be reduced. 
For example the losses of pressure for transporting in same pipe a fluid 
product according to the invention and a conventional coal-water mixture 
with the same proportion of coal were compared for different flows by 
weight. 
In this example, with a coal containing 80% of particles of a size below 80 
microns, the composition by weight of the foam product was: 
coal: 70% 
water: 28.5% 
surfactant: 1.5% 
stabilizer: 0.07% 
The increase in the loss of pressure caused by increasing the flow is 
small: In a pipe of diameter 25.5 mm the loss of pressure was 
respectively. In a pipe of diameter 25.5 mm the loss of pressure was 
respectively 0.12 bar/m for a flow by weight of 0.10 kg/sec and 0.20 bar/m 
for 0.25 kg/sec. 
By contrast, for a conventional coal-water mixture containing 70% by weight 
of coal, the increase in the loss of pressure caused by increasing the 
flow was significant: For the same flow of 0.10 and 0.25 Kg/sec, the 
losses of pressure were, respectively 0.20 and 1.10 bar/m. 
Due to this reduction of the loss of pressure it is thus possible to 
transport over long distances a concentrated product directly utilizable 
in a reactor without necessiting any dewatering. 
While the product has been described for the case of a coal-water-air 
mixture, it is quite obvious that different solid fuel could be employed 
with a liquid phase and a gas phase of another kind. In general, the 
proportion of liquid phase needs to be as low as possible because the use 
of water reduces the energy yield and a liquid fuel is more costly. On the 
other hand, the gas phase is generally useful in the reaction, and it 
would be possible, for example, to employ as the gas phase either a 
combustive gas or a fuel gas. 0,12 bar/m for a flow by weight 94 of 0,10 
kg/sec and 0,20 bar/m for 0,25 kg/sec. 
In return, for a classical Coal-Water mixture containing 70% by weight of 
coal, the increasing of the loss of pressure by increasing the flow was 
important: For the same flow of 0,10 and 0,25 Kg/sec, the losses of 
pressure were, respectively 0,20 and 1,10 bar/m. 
Due to this reduction of the loss of pressure, it is thus possible to 
transport on long distances a concentrated product directly utilizable in 
a reactor without necessiting any dewatering. 
The arrangements just described are given, of course, only by way of 
example and other devices could be employed, permitting a foam to be 
produced and solid particles to be incorporated therein. 
Furthermore, while the product has been described for the case of a coal 
water air mixture, it is quite obvious that different solid fuel could be 
employed with a liquid phase and a gas phase of another kind. It would be 
noted that, in general, the proportion of liquid phase needs to be as low 
as possible because the use of water reduces the energy yield and a liquid 
fuel is more costly. On the other hand, the gas phase is generally useful 
in the reaction and it would be possible, for example, to employ as the 
gas phase either a combustive gas or a fuel gas.