Pulsed corona reactor system for abatement of pollution by hazardous agents

Hazardous gases within a fluent mixture such as polluted air, are treated exposure to corona discharge within reaction zones of a plurality of reactor modules to effect chemical breakdown for pollution abatement purposes. Electrical pulse energy delivered to the reaction zones to effect corona discharge therein, is monitored to optimize pollution abatement by suppression of thermal arcing within the reaction zones.

This invention relates in general to the treatment of hazardous fluent 
substances which have an adverse affect on the environment. 
BACKGROUND OF THE INVENTION 
Conventional methods of treating hazardous gases to abate environmental 
pollution typically utilized thermal techniques for generating conditions 
within a reactor under which breakdown of pollutant molecules was achieved 
by heating the neutral gas background to a very high temperature. Such 
thermal techniques were highly inefficient for relatively low pollutant 
concentrations and required excessively high electrical power to not only 
effect chemical breakdown but to cool the resultant effluent emerging from 
the reactor. 
Other methods for breakdown of hazardous gases, generally known in the art, 
involve the use of non-thermal plasmas within the reactor. Dielectric 
barrier types of non-thermal plasma reactors are disclosed for example in 
U.S. Pat. Nos. 4,956,152, 4,966,666 and 5,061,462 to Keough et al., 
Waltonen and Suzuki, respectively. Use of a pulsed corona discharge type 
of reactor on the other hand, is disclosed for example in U.S. Pat. No. 
4,695,358 to Mizuno et al. Such non-thermal plasma systems are extremely 
inefficient electrically because of rotating spark gaps, constant voltage 
resistive charging and use of elements to form the desired high-voltage 
pulses. 
It is therefor an important object of the present invention to provide a 
more efficient system for the abatement of adverse affects on the 
environment of effluents such as nitrogen oxide, sulfur oxide, volatile 
organic compounds, chlorofluorocarbons and other hazardous gases. 
Other and more particular objects of the invention are to collectively 
protect personnel exposed to airborne chemical and biological agents in a 
more effective manner. 
Still other objects of the invention involve the treatment of hazardous 
agents for pollution abatement purposes, including the introduction of 
active radicals into aqueous media of a wastewater treatment system. 
Pursuant to the foregoing objects, it is an additional object of the 
invention to more efficiently effect breakdown of hazardous substances 
into less hazardous by-products which can be easily removed by 
conventional scrubbers or filters. 
SUMMARY OF THE INVENTION 
In accordance with the present invention, discharge conditions within a 
pulsed corona reactor are controlled to optimize the efficiency of 
chemical breakdown of pollutants. Electrical efficiency is maximized by 
charging a capacitor from a constant current supply of power, by 
resonantly transfering energy to the reactor using hydrogen spark gap 
switching and by suppressing thermal arcing via disabling the power supply 
after the current monitor detects a streamer discharge. The foregoing 
operational aspects of the invention are performed within an integrated 
geometrical arrangement of apparatus which virtually eliminates 
electromagnetic interference with surrounding equipment and allows 
adjustment of discharge conditions within the chamber of the pulsed corona 
reactor in order to select optimizing pulse parameters and scaling to 
accommodate different flow rates of inflowing hazardous gases.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS 
Referring now to the drawing in detail, FIG. 1 is a schematic diagram of a 
pulsed corona reactor system in accordance with one embodiment of the 
invention, generally referred to by reference numeral 10. The system 
diagrammed in FIG. 1 includes a 3-phase electrical voltage source 12 
monitored through unit 13 and connected to a power supply 14 through which 
a capacitive energy storage network 16 is charged to a high voltage. The 
energy storage network 16 is connected by a fast closing spark-gap type 
switching assembly 18 to a pulsed corona reactor 20, shown by electrical 
equivalent diagramming in FIG. 1. A voltage pulse is accordingly received 
by the reactor 20 through a switch closing gap of switching assembly 18 
from the capacitive storage network 16. The power supply 14, which charges 
the capacitive storage network 16, is of a commercially available 
constant-current type such as a Maxwell Model CCDS 85ON-1-208 capable of 
being remotely controlled. 
With continued reference to FIG. 1, control over the power supply 14 is 
exercised externally thereof through a remote control interface 22 to 
which an electrical diagnostic monitor 24 is connected. The diagnostic 
monitor is operatively coupled by current and voltage probes as diagrammed 
to the output of the switching assembly 18 for fast current detection of 
each switching event in order to provide a corresponding disabling signal 
to the remote control interface 22. The power supply 14 is thereby 
disabled from the capacitive storage network 16 between charge commands. 
In order to implement application of the network charge commands thereto, 
the control interface 22 is connectable to ground through a high-voltage 
on/off control switch 26 and through switch 28 to a remote programmed 
enable unit 30. Also, the control interface 22 is connected to a pulse 
generator 32 to effect timing control through power supply 14 over the 
aforementioned voltage pulse applied to the reactor 20 from the capacitive 
storage network 16 through switching assembly 18. A fast-rising voltage 
pulse is accordingly delivered to the reactor 20 at a predetermined 
repetition rate established by a pulse rate preset 34 connected to the 
pulse generator 32. 
Referring now to the integrated apparatus arrangement depicted in FIG. 2, a 
housing 36 within which the power supply 14 is enclosed has an end plate 38 
attached to an abutting end of an aluminum housing 40 enclosing the 
capacitive storage network 16. An electrical resistance 42 (also 
diagrammed in FIG. 1) is enclosed within a polyvinylchloride insulator 
tube 44 and is electrically connected to the power supply. The resistance 
42 is made of a carbon composition to protect the power supply from 
voltage reversals according to one embodiment and extends into housing 40. 
The resistor dissipates minimal energy due to the constant current power 
supply and could be replaced with a free-wheeling diode. Copper bus strips 
46 electrically connect the resistance 42 in parallel to a plurality of 
storage capacitors forming capacitance 48 of the capacitive storage 
network 16. A connector cable 50 extends from the bus strips 46 through a 
brass feedthrough 52 interconnecting housing 40 with the high voltage 
switching assembly 18 as shown in FIG. 2. The storage capacitors of 
network 16 may be made of commercially available, high-frequency barium 
titanate (2-nF), and are independently removable from the network 16 to 
change the amount of energy to be stored. 
The high voltage switching assembly 18, interconnects the capacitive 
storage network 16 with the reactor 20 as shown in FIG. 2. The charging 
voltage at the storage network 16 is measured by a high voltage probe 54 
of a known type, such as a Tektronix Model 6015, from which charging 
voltage signals are fed to the diagnostic monitor 24 diagrammed in FIG. 1. 
Referring now to FIG. 3 in particular, the output cable 50 from the 
capacitive storage network 16 extends into the high voltage switching 
assembly 18 and is electrically connected by a screw rod 58 to spark gap 
electrode 60 threadedly mounted thereon. The other electrode 62 is 
threadedly mounted on the adjacently spaced end of an axially aligned rod 
56 electrically connected to the reactor 20 through a cable 64. The two 
electrodes 60 and 62, made from a copper tungsten alloy such as Elkonite, 
are positioned within a hydrogen-filled gas chamber 66 of the switching 
assembly within which the spark gap is established. The chamber 66 is 
enclosed by aluminum-oxide ceramic insulators 68, 70 and 72 held assembled 
together within an outer stainless steel housing 74. O-ring seals between 
the housing 74 and insulators 68, 70 and 72 maintain the gap chamber 66 
sealed while pressurized with hydrogen gas introduced through inlet 
fittings 76 projecting radially from housing 74. By means of brass spacers 
78 located on the threaded rods 56 and 58 axially between the insulators 
68, 72 and the electrodes 60 and 62, the spacing of the spark gap between 
the electrodes may be adjusted within the pressurized hydrogen-filled 
chamber 66 to achieve switching operation at a repetition rate of up to 1 
kHz and enable increased throughput rates in the reactor 20 by virtue of 
the delivery thereto of nano-second risetime pulses. Teflon spacers 71, 80 
and 82 through which rods 56 and 58 extend to the electrodes, augment the 
pressure-tight sealing of chamber 66 as well as insulate the rods 56 and 
58 while conducting high voltage current between the storage network 16 
and the reactor 20. The insulating spacers 71,80 and 82 are respectively 
retained in position within axial metal housing sections 84 and 86 of the 
switching assembly 18, which is thereby connected to the circuit housing 
40 by fitting 52 and to the reactor 20. 
With continued reference to FIG. 3, the voltage delivered to the reactor 20 
by cable 64 of the switching assembly 18 is measured through a fast 
capacitive probe 88 connected to the diagnostic monitor 24, while a 
self-integrating current probe 90 measures current by supply of a 
corresponding signal to the monitor 24 through cable 92 extending from an 
aluminum housing box 94 of the reactor to which the housing section 86 of 
the switching assembly is attached. The voltage probe 88 is mounted on 
housing section 86 to monitor voltages having rise-times in the 
sub-nanosecond range and an attenuation ratio of approximately 70000 to 1. 
The current probe 90, on the other hand, may be a Pearson Model 2877 or 
4100 capable of resolving either a 2-ns or a 10 ns rise time signal with a 
sensitivity of 1V/A. The housing of current probe 90 is maintained at 
ground potential of the box 94 and is insulated by a Teflon collar 96 from 
a high voltage header plate 98 to which the output cable 64 from the 
switching assembly 18 is electrically connected. 
The reactor 20 as shown in FIG. 3, includes a plurality of individual 
corona discharge modules 100 electrically connected in parallel to the 
switching assembly 18 by the high voltage header plate 98. An electrical 
voltage supply cable 102 accordingly extends to each module 100 and is 
connected to the header plate 98 by a nut 104. The reactor modules are 
removably mounted on an electrically grounded manifold plate 106 secured 
to and closing the housing box 94. An additional high voltage probe 108, 
such as a Tektronix 6015, may be connected to the header plate 98 as shown 
in FIG. 3 for redundant high voltage measurement purposes. Enclosure of the 
high voltage circuitry portion of the reactor in the metallic box 94 closed 
by manifold plate 106 provides shielding for any surrounding sensitive 
electronics from stray electric fields within the box 94. 
Referring now to FIGS. 4 and 5, each of the reactor modules 100 encloses a 
streamer corona discharge reaction zone 110 within a stainless steel 
electrode tube 112. Housing sections 114 and 116 of the module are secured 
by fittings 136 and 138 to the opposite ends of the tube 112 for support 
and electrical grounding thereof by the manifold plate 106. Thus, radially 
projecting formations 118 and 120 are respectively provided on the housing 
sections 114 and 116 so that housing section 114 may be clamped to the 
plate 106 by formation 118 and a brass collar nut 121 as shown in FIG. 4. 
Teflon insulator spacers 122 and 124 are positioned within the tube 112 at 
opposite ends thereof. Also, Teflon feedthrough fittings 126 and 128 are 
respectively positioned within the housing sections 14 and 116 in axial 
abutment with the spacers 122 and 124 therein. A discharge electrode wire 
130, made of stainless steel, extends axially through the center of zone 
110 between a stainless steel tensioning screw 132 and a stainless steel 
button 134 at opposite axial ends of the tube 112. The tensioning screw 
132 is threaded through fitting 126 from a brass nut 137 through which the 
cable 102 is electrically connected to wire 130 for supply of voltage 
pulses thereto. The fittings 126, 128 and spacers 122, 124 are held 
compressed against opposite ends of the tube 112 to seal zone 110 by 
tightening of the Swagelok fittings 136 and 138. 
Hazardous gas is introduced into the sealed reactor zone 110 through a 
Teflon gas inlet fitting 140 projecting radially through an opening in 
housing section 114 and threadedly mounted in spacer 126. Hazardous gas 
treated by exposure to the high energy electrons within the corona 
discharge zone 110 emerges therefrom through a central passage in spacer 
128 and gas discharge fitting 142. The spacers 122 and 124 have central 
openings 144 through which the electrode wire 130 extends and 
circumferentially spaced baffle openings 146 through which distributed gas 
flow is conducted into and out of the corona discharge zone 110 as more 
clearly seen in FIG. 5. When the voltage delivered to the reactor modules 
100 from the header plate 98 through the cables 102 exceeds a corona onset 
voltage level, multiple streamers along the length of the electrode wires 
130 within zones 110 are initiated to form the steamer corona discharge 
field within which the hazardous gas is treated. 
Operation of system 10 involves initiation of a charge cycle for the 
storage capacitance 48 of network 16, as diagrammed in FIG. 1, when (a) 
the input from remote enable 30 goes high by closing of switch. 28, (b) 
the high voltage on/off signal goes momentarily low by closing of switch 
26, and (c) the high voltage inhibit signal from pulse generator 32 to the 
remote control interface 22 goes low. The constant current power supply 14 
then charges the capacitance 48 to a high voltage level determined by a 
set signal delivered by the remote control interface 22 to the power 
supply 14. At a self-break voltage level of the switching assembly 18, set 
by the spark gap spacing between the electrodes 60 and 62 and gas pressure 
in the gap chamber 66, switch closure occurs to rapidly and resonantly 
charge capacitance 150 of reactor 20 through stray inductance 148 
associated with the switching assembly 18. Since the reactor capacitance 
150 is much smaller in size than the capacitance 48 of the storage network 
16, some voltage multiplication is to be expected. The risetime of the 
charging voltage applied to the reactor will be affected by the stray 
inductance 148 of the switching assembly 18 which is minimized by the 
coaxial geometry of the switching assembly 18 as hereinbefore described 
with respect to FIG. 3. 
Upon occurrence of spark-gap breakdown in switching assembly 18 to effect 
switch closure as aforementioned, current flow to the reactor 20 is 
detected by monitor 24 to effect momentary disablement of the power supply 
14 by feedback signal control from monitor 24 through interface 22 and 
electrically isolate the power supply from the reactor in order to allow 
spark gap recovery and switch opening of switching assembly 18. The 
capacitance 150 of the reactor 20, as electrically diagrammed in FIG. 1, 
is electrically connected in parallel with an impedance 152 that 
represents the variable resistance of the gas discharge. Once the streamer 
corona onset threshold is exceeded, current is conducted in the reactor and 
removal of the stored charge at the capacitance 48 of switching assembly 18 
and capacitance 150 of the reactor assembly 20 is achieved in about 150-200 
nanoseconds. The voltage at the capacitance 150 of the reactor after 
reaching the desired charge level decays to the corona onset threshold 
until another cycle occurs and the corona onset threshold is again 
attained. Since the grounded reactor impedance 152 is very large, it 
maintains the reactor capacitance 150 at typically 8-10 kV determined by 
the corona onset threshold. The power input to the entire system 10 is 
determined by monitor 13 through current and voltage probes 154 and 156, 
respectively located on a 208 Volt, 3-phase input line to the power supply 
14 from source 12. The actual energy per pulse delivered to the reactor is 
calculated through monitor 24 by integrating with respect to time the 
product of voltage and current respectively measured by probes 88 and 90 
as aforementioned, in order to determine the high "wall-plug" efficiency 
of the system. A reactor 20 provided with ten modules 100 for example, 
accommodates a gas inflow rate of 50 liters per minute in the disclosed 
arrangement. It has been determined that in such an arrangement the 
"wall-plug" efficiency is greater than 85-90% for a reactor voltage of 26 
kV and a pulse repetition frequency of 750 Hz. Such efficiency is partly 
attributable to the suppression of thermal arcing within the reactor 
module 100 during streamer discharge therein because of the feedback 
signal control excerise over the constant current power supply 14 in 
response to monitoring of current to the to the reactor by monitor 24. 
Electrical efficiency is also attributable to the use of constant current 
charging, resonant energy transfer, low-loss switching and high reactor 
center wire to ground impedance. 
An alternative reactor 20' for the system depicted in FIG. 1, is 
illustrated in FIG. 6, whereby larger inflow rates of gas may be 
accommodated. According to this embodiment, the reactor has a larger 
number of tubular reactor modules 100' through which corona discharge 
producing electrode wires 130' extend. Each module 100' has an outer 
electrode tube 112' made of perforated stainless steel. The tubes 112' are 
exposed between side walls 154 of the reactor to an inflow 156 of polluted 
air, perpendicular to the axes of the tubes and the electrode wires 130' 
extending therethrough. The high voltage pulses, as hereinbefore 
described, are applied to the wires 130' between a reactor header plate 
98', to which the wires are connected by fasteners 158, and a grounding 
plate 106' on which the tubes 112' are supported. The plates 98' and 106' 
are separated by an insulator plate 160. 
The crossed flow arrangement of electrode tubes 112' between inflow 156 and 
outflow 162 as shown in FIG. 6, ensures graceful degradation of the reactor 
since a given gas volume traverses several tubes rather than just one as in 
the case of the reactor 20 shown in FIGS. 3-5. The crossed flow arrangement 
of FIG. 6 furthermore induces turbulent mixing to homogenize pollution 
degradation characteristics of the reactor 20, the staggered tube geometry 
enhancing the probability that the polluted flow passes close to the 
field-enhanced region around the center wire. 
Obviously, other modifications and variations of the present invention may 
be possible in light of the foregoing teachings. It is therefore to be 
understood that within the scope of the appended claims the invention may 
be practiced otherwise than as specifically described.