Storage-stable solution of a copper phthalocyanine reactive dyestuff

A new storage-stable solution of the reactive dyestuff of the formula ##STR1## wherein CuPc=the radical of a Cu phthalocyanine dyestuff, PA0 m=1, 2 or 3, PA0 n=1, 2 or 3, PA0 m+n=3 to 4 and PA0 M.sup..sym. =H.sup..sym., an alkali metal cation or an ammonium ion, is provided. The storage-stable solution according to the invention is characterized in that it contains 10-35% by weight of reactive dyestuff (1), 10-30% by weight of solubilizing agent, 0-10% by weight of anionic dispersing agent, 0-7% by weight of inorganic salts, such as Na.sub.2 SO.sub.4, Li.sub.2 SO.sub.4 and the like, and 0.1-3% by weight of buffer (pH 4-7), the remainder to make up to 100% by weight being water.

The present invention relates to a storage-stable solution of the reactive 
dyestuff of the formula 
##STR2## 
wherein 
CuPc=the radical of a Cu phthalocyanine dyestuff, 
m=1, 2 or 3, 
n=1, 2 or 3, 
m+n=3 to 4 and 
M.sym.=H.sym., an alkali metal cation or an ammonium ion. 
In formula (1), M.sym. preferably represents Na.sym. or Li.sym.. 
The storage-stable solution according to the invention is characterised in 
that it contains 10-35% by weight of reactive dyestuff (1), 10-30% by 
weight of solubilising agent, 0-10% by weight of anionic dispersing agent, 
0-7% by weight of inorganic salts, such as Na.sub.2 SO.sub.4, Li.sub.2 
SO.sub.4 and the like, and 0.1-3% by weight of buffer (pH 4-7), the 
remainder to make up to 100% by weight being water. 
The storage-stable solution preferably contains 15-30% by weight of 
reactive dyestuff (1), 15-25% by weight of solubilising agent, 0-5% by 
weight of anionic dispersing agent, 0-4% weight of inorganic salts and 
0.1-1% weight of buffer (pH 4-7), the remainder to make up to 100% by 
weight being water. 
In particular, salts of the dyestuff which, in the form of the free acid, 
has the following formula are used: 
##STR3## 
Stable solutions of reactive dyestuffs are already known. In British Pat. 
No. A 1,060,063, stable solutions of reactive dyestuffs are described, 
which are characterised in that they contain at least 10% of 
.epsilon.-caprolactam as a solubilising agent. No buffer additive has been 
mentioned either in the examples or in the patent claim. However, many 
2,4,6-trifluoro-5-chloropyrimidine dyestuffs (cold-dyeing dyes) are not 
stable to hydrolysis over a prolonged period at elevated temperature (4 
weeks at 50.degree. C.) or over a period of years at 25.degree. C. in this 
form without the addition of a buffer. 
For this reason, 1-6% by weight of buffer substances which are not capable 
of a chemical reaction with the reactive group which reduces the 
tinctorial strength are added to aqueous reactive dyestuff formulations in 
German Pat. No. A 2,529,658. In the examples mentioned therein, however, 
no 2,4,6-trifluoro-5-chloropyrimidine reactive dyestuff (cold-dyeing dye) 
liquid formulations are mentioned in respect of their reactivity. 
According to the prior art, reactive liquid formulations with dyestuffs 
containing the 2,6-difluoro-5-chloro-pyrimidin-4-yl radical are more 
stable to hydrolysis at pH 7 than at pH 4-5. For this reason, buffer 
mixtures for the pH range from 6.5 to 8 were also used in German Pat. No. 
A 3,207,534. 
Highly surprisingly, it has now been found that liquid formulations 
according to the invention, for example buffered to pH 4.5, are extremely 
stable towards hydrolysis over a prolonged period. 
Preferred possible solubilising agents are: lower aliphatic or cyclic 
amides, such as .epsilon.-caprolactam, N-alkylpyrrolidones, 
N-vinylpyrrolidones and polymers thereof and/or aliphatic sulphoxides 
and/or sulphur-containing compounds, such as dimethyl sulphone and diethyl 
sulphone, and/or hydrotropic compounds, such as thiourea, urea and the 
associated derivatives, N,N'-dimethylurea, .epsilon.-caprolactam and 
dimethyl sulphone being particularly preferred. 
Examples of possible anionic dispersing agents are: condensation products 
of an aromatic sulphonic acid and formaldehyde (such as, for example, 
naphthalene-sulphonic acid, ditolylether-sulphonic acid or 
terphenyl-sulphonic acid with formaldehyde). 
Examples of possible buffers are: buffer systems which buffer in the pH 
range from 4 to 7 and are not capable of reaction with the reactive group 
which reduces the tinctorial strength, for example a boric acid/LiOH 
mixture, a boric acid/NaOH mixture, an NaH.sub.2 PO.sub.4 /Na.sub.2 
HPO.sub.4 mixture, a citric acid/citrate mixture and mixtures of the 
systems mentioned. 
Preferred possible inorganic salts are: Na.sub.2 SO.sub.4, Li.sub.2 
SO.sub.4, NaCl and LiCl. The fewer inorganic salts the liquid formulation 
according to the invention contains, the higher the dyestuff content with 
which it can be formulated. 
Those dyestuffs which have as low as possible a content of inorganic salts 
(usually resulting from the synthesis) are advantageously used in the 
preparation of the liquid formulation according to the invention. Such 
formulations of low salt content can be obtained in various ways: 
1. The reactive dyestuff is isolated from the synthesis liquor and filtered 
off with suction to the maximum possible dry content. The press-cake can 
then be washed with a little neutral or weakly acid water and subsequently 
dissolved in the solubilising agent described, and stabilised with buffer. 
If the storage-stable solutions according to the invention contain only 10 
to 20% by weight of dyestuff, the rinsing may possibly be dispensed. 
2. However, German Pat. No. A 2,948,282 describes another process. The 
dilute salt-containing reaction liquor or a dilute aqueous solution of the 
dyestuff is subjected to pressure permeation, demineralised and 
concentrated. 
3. The liquid grade according to the invention can furthermore also be 
prepared by the process described in German Pat. No. A 3,207,534.

EXAMPLE 1 
300 g of reactive dyestuff with, in the form of the free acid, the formula 
(2) containing less than 10% by weight of inorganic salts, such as 
Na.sub.2 SO.sub.4 and the like, are slowly introduced into a mixture 
consisting of 480 g of water and 200 g of .epsilon.-caprolactam at 
30.degree. C., the pH value being kept at 6.5 by addition of 8 g of 
LiOH.H.sub.2 O. 
After dissolving, the formulation is stabilised at pH 5.5 with 5 g of boric 
acid and a little LiOH.H.sub.2 O. An extremely storage-stable solution 
containing about 27% by weight of pure dyestuff, 20% of 
.epsilon.-caprolactam, about 3.5% of inorganic salts, such as Na.sub.2 
SO.sub.4 and the like, 0.5% of boric acid and about 51% of water is 
obtained. 
After this concentrated solution according to the invention has been 
stirred into water, a dyeing solution for dyeing natural and regenerated 
cellulose fibres in a turquoise blue shade is obtained by adding the 
auxiliaries customary for reactive dyeing. 
EXAMPLE 2 
242 g of reactive dyestuff of the formula (2) containing less than 10% by 
weight of inorganic salts are slowly introduced into a mixture consisting 
of 545 g of water and 200 g of N,N'-dimethylurea at 30.degree. C., the pH 
value being kept at 6.5 by addition of 8 g of LiOH.H.sub.2 O. 
After dissolving, the formulation is stabilised at pH 5.5 with 5 g of boric 
acid and a little LiOH.H.sub.2 O. An extremely storage-stable solution 
consisting of: about 22% weight of pure dyestuff with, in the free acid, 
the formula (2), 20% by weight of N,N'-dimethylurea, about 3% by weight of 
inorganic salts, such as Na.sub.2 SO.sub.4 and the like, 0.5% by weight of 
boric acid/LiOH (pH=5.5) and about 54.5% by weight of water, is obtained. 
The formulation prepared is used as described in Example 1. 
EXAMPLE 3 
The procedure described in Example 2 is followed, a mixture of 160 g of 
.epsilon.-caprolactam and 50 g of dimethyl sulphone being used instead of 
200 g of N,N'-dimethylurea. The other conditions remain the same. A 
solution consisting of: about 22% by weight of pure dyestuff (2), 16% by 
weight of .epsilon.-caprolactam, 5% by weight of dimethyl sulphone, 3% by 
weight of inorganic salts, 0.5% by weight of boric acid/LiOH (pH=5.5) and 
about 53.5% by weight of water, is obtained. 
The use of this solution is as described in Example 1. 
EXAMPLE 4 
The procedure described in Example 1 is followed, 5 g of a mixture of 
sodium dihydrogen phosphate/disodium hydrogen phosphate (pH=5.5) being 
used instead of 5 g of boric acid. The other conditions remain the same. A 
solution consisting of: about 27% by weight of pure dyestuff (2), 20% by 
weight of .epsilon.-caprolactam, about 3.5% by weight of inorganic salts, 
such as Na.sub.2 SO.sub.4 and the like, about 0.5% by weight of a mixture 
of NaH.sub.2 PO.sub.4 /Na.sub.2 HPO.sub.4 (pH=5.5) and about 51% by weight 
of water, is obtained. 
The use of this solution is as described in Example 1.