Melt blowing process

Thermoplastic materials are converted directly into thermally bonded, coherent fibrous products by melt blowing techniques. The fibrous product is in the form of a rod having a relatively dense, rigid skin in which the fiber portions are oriented primarily in a longitudinal direction with respect to the axis of the product, and a less dense core where the fiber portions are oriented primarily in a transverse direction with respect to the axis of the product. The products are made by melt blowing fibers and intercepting them by a fiber collecting and forming device which permits a relatively heavy build-up of fiber mass in the central portion and a relatively light build-up of fibers in a lip portion surrounding the central portion. As fibers are continuously deposited on the collecting and forming device, the product thus formed is withdrawn at a rate synchronized with collection of fibers such that the aforesaid build-up is maintained, and such that the lip portion is folded back over the central portion by the collecting and forming device to form the rod as described.

BACKGROUND OF THE INVENTION 
1. Field of the Invention 
This invention relates to a process for producing a fibrous product by melt 
blowing thermoplastic material, and to the fibrous product produced 
thereby. 
2. Description of the Prior Art 
Various processes for producing melt-blown products from thermoplastic 
materials are known in the art. For example, U.S. Pat. Nos. 3,755,527 and 
3,959,421 relate to processes for producing melt-blown continuous mats or 
webs on drums. U.S. Pat. No. 3,313,665 relates to forming filaments into 
articles by a process which includes treating the filaments with gas under 
pressure and orienting the filaments in a transverse direction of the 
article and then bonding the filaments by application of hot vaporized 
liquid. U.S. Pat. No. 3,023,075 discloses a method and apparatus for 
shaping fibrous rods into a desired cross section. U.S. Pat. No. 3,110,642 
relates to a method of producing a fibrous product from melt blown 
thermoplastic fibers by application of a stream of inert gas or stream 
propelled substantially at right angles to a melt or solution issuing from 
the supply container at a velocity and under a pressure sufficient to 
attenuate the melt or solution into the form of fibers. U.S. Pat. No. 
3,595,245 relates to a tow of entangled continuous fibers of polypropylene 
formed by melt-blowing techniques. 
SUMMARY OF THE INVENTION 
In the present invention, thermoplastic materials are converted directly 
into thermally bonded, coherent fibrous products by melt blowing 
techniques. The fibrous product is in the form of a rod having a 
relatively dense, rigid skin in which the fiber portions are oriented 
primarily in a longitudinal direction with respect to the axis of the 
product, and a less dense core in which the fiber portions are oriented 
primarily in a transverse direction with respect to the axis of the 
product. Thus, the general orientation of fibers is randomly parabolic. 
The products are made by melt blowing fibers and intercepting them by a 
fiber collecting and forming device which permits a relatively heavy 
build-up of fiber mass in the central portion and a relatively light 
build-up of fibers in a lip portion surrounding the central portion. As 
fibers are continuously deposited on the collecting and forming device, 
the product thus formed is withdrawn at a rate synchronized with 
collection of fibers such that the aforesaid build-up is maintained, and 
such that the lip portion is folded back over the central portion by the 
collecting and forming device to form the rod as described.

DETAILED DESCRIPTION OF THE INVENTION 
Basically, the method of formation involves extruding a molten 
thermoplastic material through a nozzle into a fine stream and attenuating 
the stream by a converging flow of high velocity gas (usually air), which 
breaks the stream into discontinuous fibers of small diameter. In general, 
the resulting fibers have an average diameter of less than about 10 
microns with very few, if any, of the fibers exceeding 20 microns in 
diameter. Usually, the average diameter of the fibers is within the range 
of about 1-15 microns. The fibers are discontinuous, they generally have a 
length of about 10 mm. 
Referring to the drawings, FIG. 1 is a schematic view of apparatus for 
carrying out the process of this invention. Molten thermoplastic material 
enters extruder 10 and is forced therethrough in the direction of the 
arrow. Material exists from nozzle 12 and is immediately contacted by gas 
at the nozzle tip being forced under pressure in the direction indicated 
by arrows. A plurality of nozzles suitably arranged may be used if 
desired. The gas may be heated, and serves to attenuate the extruded 
thermoplastic material into a plurality of fibers 14 and direct them to a 
combination collecting and forming device 16. The fibers form a mass at 
the throat 50 of the collecting and forming device, and once build-up of 
the fibrous mass occurs at this point, the leading portion thereof, which 
has now assumed the shape of a self-supporting rod 18 may be manually 
pulled from the exit end and fed into feed rolls 20 and 22. The speed of 
rolls 20 and 22 is synchronized with the rate of fiber extrusion such that 
the build-up of fiber mass on the collecting and forming device 16 is 
substantially continuous and of a predetermined magnitude as will be 
explained hereinafter in greater detail. 
FIG. 2 is a detail view in cross section showing a suitable nozzle 12 for 
simultaneously extruding thermoplastic material and directing air at the 
material as it is extruded into fibers. Such nozzles are well known in the 
art, but a brief, general description of a suitable nozzle follows. Nozzle 
12 is fitted onto a suitable extrusion device (not shown) wherein molten 
thermoplastic material is forced under pressure in the direction of the 
arrow leading to the center chamber 24. Molten thermoplastic material is 
continuously forced through passage 24 and exits from opening 26. 
Pressurized gas (e.g., air) enters passages 28 into the circular manifold 
30, through circular passage 32 and exits from the circular opening 34 
where it is directed at an angle towards the extruded material. The gas so 
directed serves to attenuate the extruded material into a plurality of 
fibers 14 and direct them to the forming and collecting device 16. 
FIG. 3 illustrates one embodiment of the invention in which fibers 14 from 
nozzle 12 are deposited on collecting and forming device 16, which will 
herein sometimes be referred to as a collector. Fibers 14 will be 
deposited randomly on the collector generally as shown, with the largest 
mass formed in the center thereof. Due at least partially to the 
turbulence created by the air from nozzle 12, some fibers will also be 
deposited on the inclined wall 40 of collector 16. The fibers are in 
somewhat of a thermoplastic condition when they are deposited on the 
collector 16, such that they will adhere or thermally bond to each other. 
According to the process of this invention, the fibers are deposited on 
collector 16 such that the accumulated mass will assume the general shape 
shown in FIG. 3, i.e., the greatest build up in the center 42, with the 
mass of fibers decreasing as the radius of the flared collector 14 
increases, to thereby form a peripheral lip 44 of fibers around the 
collector 14. Once the mass of fibers builds up to this point, the fiber 
rod formed thereby is gradually withdrawn in the direction of the arrow 
(FIG. 1) at a speed such as to substantially maintain the shape shown in 
FIG. 3. As the rod 18 is withdrawn, lip 44 is continuously folded back 
over the central fiber build-up 42 to result in a relatively dense, rigid 
skin 46. 
Rod 18 may be withdrawn by conventional means, such as by a pair of pull 
rolls 20 and 22. The rod may be started by temporarily blocking the exit 
of the collector until the rod begins to form and then withdrawing the rod 
by a hook and threading it through the pull rolls. It is important that 
the speed of withdrawal of the rod be synchronized with the rate of build 
up the fiber mass so as to maintain the build up on the inclined wall of 
collector 16. This may be accomplished either by adjusting the rate of 
fiber extrusion or by the speed of the pull rolls 20 and 22. 
The collector may conveniently be funnel-shaped as illustrated, trumpet 
shaped, or the like. The collector is provided with a throat section 50 
which offers resistance to the lip 44 of fiber mass, to fold lip 44 back 
over the central portion 42 as the rod is withdrawn. The collector is 
conveniently provided with openings 52 to allow the escape of gas from 
nozzle 12 without causing undue turbulence within the collector 16. 
FIG. 4 illustrates the rod-like fibrous product 18 formed by the process. 
As shown, the individual fibers assume a generally parabolic shape in the 
rod as the lip 44 is folded back over the central portion 42. The fibers 
in the lip portion 44, being deposited while still in a thermoplastic 
state, thermally bond together. As they are compressed while passing 
through throat 50, a relatively dense skin 46 having suitable porosity and 
integrity and uniform composition is formed around the inner fibers while 
generally maintaining their generally parabolic shape. The fibers are 
oriented such that portions in the skin are primarily longitudinally 
oriented while portion in the core are primarily transversely oriented. 
The fibrous product has adequate rigidity and resiliency for use in 
filters, ink pen reservoirs, etc. 
Other apparatus for carrying out the invention is illustrated in FIGS. 5, 6 
and 7 wherein continuous belts 60 and 62 are used as the collector and 
take-away for the rod. As shown in the drawings, belts 60 and 62 travel 
over forming rolls 64 and 66 which are shaped such that in combination 
they form a cylindrical opening at their nip. Belts 60 and 62 follow the 
contour of the rolls and continuously form a collector and forming device 
in essentially the same manner as the rigid, stationary collector 
illustrated in FIG. 3. In this case, the take-away speed will be governed 
by the speed of the belts 60 and 62. 
The means for collecting the fibers and forming the relatively heavy build 
up of fibrous mass in the throat section with decreasing mass as the 
radius of the flared section increases will vary in degree of flare over a 
wide range, so long as the aforesaid central fibrous mass and lip is 
developed. For example, the collector may be trumpet shaped wherein the 
flare is variable. In the use of continuous belts as described for FIGS. 
5, 6 and 7, the flare is dependent upon the diameter of rolls 64 and 66 
and the contour (illustrated at c) of the surface thereof. In the funnel 
design illustrated in FIG. 3, the wall 40 must be inclined with respect to 
the body 41 of the device, i.e., the angle between surface 40 and 41 is 
between 90.degree. and 180.degree.. Preferably this angle is no greater 
than about 170.degree.. Most desirably, this angle is between about 
110.degree. and 150.degree.. Those skilled in the art will be able to 
design other shapes, such as trumpet or rolls (as illustrated in FIGS. 5, 
6 and 7) using this angular range as a guideline. For example, where a 
trumpet or pair of rolls is used, for a 7.9 mm diameter rod, the effective 
circular portion may have a radius of about 3.9 mm to about 4.00 mm, in 
which case rolls 64 and 66 would have an appropriate contour relative 
thereto. 
In a typical example of suitable apparatus, a funnel shaped collector is 
designed to be a total of 95 mm in length, 7.9 mm, inside diameter, with 
the flared section occupying 10 mm of axial length. Angle between surface 
40 and 41 is 124.degree.. The collector is 38 mm in diameter at its open 
end, and is perforated with 1/16 inch openings, 64 openings per square 
inch. To form fibrous rods with such a collector according to this 
invention, the following operating parameters are found using 2.6 grams 
polymer per minute: 
______________________________________ 
Rate 
Extrusion Speed, 
Fiber Diameter, 
Rod Take-Away, 
Meters/Min. Microns Meters/Min. 
______________________________________ 
11,000 15 0.705 
24,000 10 0.705 
37,500 8 0.705 
______________________________________ 
In operating the melt-blowing process to produce fibers having diameters 
between about 1-6 microns, smooth molten flow of the thermoplastic 
material and smooth attenuation of the fibers is required. This is 
achieved through the selection and control of the appropriate combination 
of nozzle tip temperature, thermoplastic material flow rate, and 
thermoplastic material molecular weight to give an apparent viscosity in 
the die holes of from about 10 to about 800 poise, preferably within the 
range of from about 50 to about 300 poise. For a particular material, by 
measuring the pressure upstream of the nozzle holes and by measuring the 
flow rate, the apparent viscosity is calculated from the geometry of the 
nozzle by methods well known in polymer technology. The viscosity can 
usually be adjusted into the operable range by varying the nozzle tip 
temperature. 
Herein, polyester resin is used to illustrate the present invention. Other 
thermoplastic resins suitable for such use include other polyolefins, e.g. 
polyethylene; polyamides, e.g., poly(hezamethylene adipamide), 
poly(.alpha.-caproamide) and poly(hexamethylene sebacamide); polyvinyls 
such as polystyrene; and other polymers such as 
polytrifluorochloroethylene. 
To be melt blown into fibers, polyethylene terephthalate, it has been 
found, must be thermally treated at temperatures in excess of 280.degree. 
C., up to about 330.degree. C. and preferably, within the range of from 
about 300.degree. to about 315.degree. C. The degree of thermal treatment 
necessary varies with the melt index of the particular material employed 
and with the rates used in the melt blowing process. The thermal treatment 
may be carried out in the extruder alone or partially in the extruder and 
partially in the nozzle. 
The flow rate, the rate at which the material is forced through the opening 
in the nozzle, is dependent upon the specific design of the nozzle and 
extruder. However, suitable flow rates are from about 0.07 to about 0.5 or 
more gm./min./opening. The polymer flow rate may be controlled by the 
speed of the extruder. The gas flow rates are also limited by the design 
of the nozzle. Suitable products are obtained at air rates from about 0.8 
to about 10 lbs./hr. 
The fiber diameters of the nonwoven mats of this invention are achieved by 
adjusting the gas flow rates for a given molten material flow rate so that 
one obtains a pounds of gas/pounds of material ratio of from about 5 to 
about 50, preferably, between about 9 and about 12. Air rates of this 
magnitude serve to attenuate the molten material extruded through the die 
openings into fibers having suitable diameters. When the air rates for a 
given molten material flow rate are too low, large coarse fibers are 
formed. Then, as air flow rates are too high relative to the rate of 
polymer flow, the fibers break without being attenuated and have large 
diameters. 
An important factor in producing the products of this invention is the 
distance separating the collecting device from the openings in the nozzle. 
It is normally necessary to space the collecting device or collector at 
least about 50 mm from the nozzle openings to obtain the desired pattern 
of fiber mass deposit on the collector. Advantageously, the 
nozzle-collector-distance is no greater than about 150 mm, and preferably, 
from about 85 to about 110 mm. 
The fibrous rod produced by the process according to this invention is 
illustrated in FIG. 4. Passing the rod through the throat 50 of the 
forming and collecting device compresses the lip portion 44 into a 
relatively dense skin 46, the fibers of which are thermally bonded such as 
to cause the rod to be relatively rigid. As the lip is continuously folded 
back upon take-away of the rod, the fibers form a randomly parabolic 
pattern, such that fiber parts in the central or core portion 47 are 
generally perpendicular to the axis while the fiber parts in the skin 46 
are more or less parallel to the axis. It will be obvious that all of the 
fibers do not, of themselves, form such a parabolic shape. As the mass 
contains randomly deposited fibers, some of the individual fibers may not 
extend entirely across the rod--some fibers may even lie mostly in the 
skin of the rod. The general pattern, however, is parabolic due to the 
compression and drag forces on the lip 44 as the rod is formed. The skin 
is relatively thick, dense, and porous and may occupy about 5-50% 
(normally 15-35%) of the cross section, while the core is much less dense. 
Upon formation of rod 18, it may be conveyed to further processing 
equipment, such as a cutter for forming individual rods of predetermined 
lengths as is well known in the art. 
The fibrous rod may subsequently be converted into filters such as 
cigarette smoke filters or other gas or liquid filters. The fibrous rod 
may also be used as an ink reservoir for marking pens, wicks, etc. 
Unless otherwise specified, inherent viscosity is measured with a 0.5 
weight % solution of polymer in a mixture of 60/40 
phenol/tetrachloroethane. 
The following examples are submitted for a better understanding of the 
invention. 
EXAMPLE 1 
Poly(ethylene terephthalate) polymer having an inherent viscosity of 0.35 
is extruded in a 3/4-inch diameter screw extruder at a melt temperature of 
285.degree. C. to feed a melt-blowing spinneret comprised of a tube 
mounted concentrically in a cylindrical air passageway having a conical 
taper ending at the level of a single 0.3 mm diameter orifice in the tube. 
As the melt is extruded from the orifice, a stream of heated air 
(304.degree. C.) attenuates the melt to form melt-blown fibers. Polymer is 
extruded at a rate of 0.2 pound per hour into air flowing at a rate of 2.0 
standard cubic feet per minute (SCFM) to produce 1 to 10 micron diameter 
fibers which are collected in a funnel type collector, tube the throat of 
which is located 85 mm below the orifice level. The fibers are pulled 
through the funnel into a tube having an inside diameter equal to the 
desired outside diameter of the cigarette filter to form a rod of 
thermally-bonded fibers. Filters cut from this rod have a relatively 
thick, dense, but porous, outside wall with a less dense core of 
thermally-bonded fiber layers orientated perpendicular to the longitudinal 
axis of the filter. Based on photographs of longitudinal cross-section of 
the filters, the wall comprises 40-50% of the available area. 
Twenty-millimeter filter tips cut from the rods made according to this 
method, weighing 83 mg, remove 51% of total particulate matter (TPM) at a 
pressure drop of 3.9 to 4.3 inches of water at a volumetric flow rate of 
17.5 ml/second. 
EXAMPLE 2 
Using the method described in Example 1, poly(ethylene terephthalate) 
polymer having inherent viscosity of 0.35 is extruded at a melt 
temperature of 290.degree. C. at a rate of 0.2 pound per hour into 
322.degree. C. air flowing at 2.5 SCFM to make 1 to 10 micron diameter 
fibers which are collected in a funnel type collector, the throat of which 
is located 84 mm below the orifice. These fibrous bundles are pulled 
through the forming tube with a take-up device which pulls the 
newly-formed rod at a linear rate of 380 mm per minute. Filters cut from 
this rod have relatively dense, but porous, walls comprising 20-30% of the 
longitudinal cross-sectional area with a less dense core of 
thermally-bonded fiber layers orientated perpendicular to the longitudinal 
axis of the filter comprising the remaining area. Twenty-millimeter tips 
cut from this rod, weighing 69 mg, remove 32% TPM at a pressure drop of 
1.4 to 1.6 inches of water. 
EXAMPLE 3 
Filter rods are made according to the method described in Example 2 except 
the walls of the forming tube are heated to 85.degree. C. Filters cut from 
this rod have relatively dense, but porous, walls comprising 15-20% of the 
longitudinal cross-sectional area with less dense layers of 
thermally-bonded fibers orientated perpendicular to the longitudinal axis 
of the filter in the remaining area. Twenty-millimeter tips cut from this 
rod, weighing 73 mg, remove 42% TPM at a pressure drop of 1.4 to 1.8 
inches of water. 
EXAMPLE 4 
Using the method described in Example 1, poly(ethylene terephthalate) 
polymer having inherent viscosity of 0.35 is extruded at a melt 
temperature of 290.degree. C. at a rate of 0.2 pound per hour into 
314.degree. C. air flowing at a rate of 2.0 SCFM to make 1 to 10 micron 
diameter fibers which are collected in a funnel type collector, the throat 
of which is located 91 mm below the orifice. Rods are removed from the 
forming tube at a linear rate of 412 mm per minute. Filters cut from these 
rods have relatively dense, but porous, walls comprising 30-40% of the 
longitudinal cross-sectional area with a less dense core of 
thermally-bonded filter layers in which the fibers are orientated 
perpendicular to the longitudinal axis of the filter. Twenty-millimeter 
tips cut from this rod, weighing 85 mg, remove 37% TPM at a pressure drop 
of 2.3 to 2.5 inches of water. 
EXAMPLE 5 
Using the method described in Example 1, poly(ethylene terephthalate) 
polymer having inherent viscosity of 0.35 is extruded at a melt 
temperature of 309.degree. C. at a rate of 0.2 pound per hour into 
311.degree. C. air flowing at a rate of 2.0 SCFM to make 1 to 10 micron 
diameter fibers which were collected in a funnel type collector, which is 
cooled with chilled water to 28.degree. C., the throat of which is located 
105 mm below the orifice. Rods are removed from the forming tube at a 
linear rate of 705 mm per minute. Filters cut from these rods have 
relatively dense, but porous, walls comprising 20-30% of the longitudinal 
cross-sectional areas with a less dense core of thermally-bonded fiber 
layers in which the fibers were oriented perpendicular to the longitudinal 
axis of the filter. Twenty-millimeter tips cut from this rod, weighing 80 
mg, remove 51% TPM at a pressure drop of 3.1 to 3.2 inches of water. 
EXAMPLE 6 
Using the method described in Example 5, poly(ethylene terephthalate) 
polymer having inherent viscosity of 0.35 is extruded at a melt 
temperature of 287.degree. C. at a rate of 0.5 pound per hour into 
292.degree. C. air flowing at a rate of 3.0 SCFM to make 1 to 10 micron 
diameter fibers which are collected in a funnel type collector, the throat 
of which is located 90 mm below the orifice. The funnel section of this 
collector is perforated with 1/8-inch diameter holes which allow the air 
to flow from the sides of the funnel. Rods are removed from the forming 
tube at a linear rate of 1740 mm per minute. Filters cut from these rods 
have relatively thin, porous walls comprising 5-15% of the longitudinal 
cross-sectional area with a less dense core of thermally-bonded fiber 
layers in which the fibers are orientated perpendicular to the 
longitudinal axis of the filter. 
EXAMPLE 7 
Using the method described in Example 5, poly(propylene terephthalate) 
polymer having inherent viscosity of 0.35 is extruded at a melt 
temperature of 290.degree. C. at a rate of 0.4 pound per hour into 
355.degree. C. air flowing at a rate of 1.6 SCFM to make 1 to 10 micron 
diameter fibers which are collected in a funnel type collector, the throat 
of which is located about 95 mm from the orifice. These fibers are pulled 
through the forming tube manually to form a filter rod. Filters cut from 
these rods comprise layers of thermally-bonded fibers in the core and 
dense walls. 
EXAMPLE 8 
Using the method described in Example 5, polypropylene polymer having 
inherent viscosity of 0.75 (measured with a 1/2 weight % solution of 
polymer in distilled tetraline with BHT stabilizer heated to 125.degree. 
C.) is extruded at a melt temperature of 340.degree. C. at a rate of 0.2 
pound per hour into 355.degree. C. air flowing at a rate of 2.0 SCFM to 
make 1 to 10 micron diameter fibers which are collected in a funnel type 
collector, the throat of which is located from about 95 mm from the 
orifice. These fibers are pulled through the forming tube to form a filter 
rod. Relatively soft, uniform filter rods which expand to a diameter 
approximately 25% larger than the tube inside diameter upon being pulled 
from the forming area are obtained by this method. The rods are compressed 
to the diameter of a cigarette and wrapped with paper. Tips of 20 mm are 
attached to cigarettes and efficiency determined by standard techniques. 
At a rod weight of 53 mg/20 mm tip and pressure drops of 1.7 inches of 
water, 45% of the tar is removed from the cigarette smoke. 
EXAMPLE 9 
Using the method described in Example 1, poly(ethylene terephthalate) 
polymer having inherent viscosity of 0.35 is extruded at a melt 
temperature of 300.degree. C. at a rate of 0.2 pound per hour into 
320.degree. C. air flowing at a rate of 2.0 SCFM to make 1 to 10 micron 
diameter fibers which are collected in a funnel type collector, the throat 
of which having two, approximately 2 mm protrusions located on the tube 
wall. As the fibers are pulled through the tube, a filter rod having 
molded indentations is formed. Filters of this type are used to make 
vented cigarette filters which allow 20% dilution of the smoke with air. 
EXAMPLE 10 
Example 1 is repeated except a blend of 80% poly(ethylene terephthalate) 
(I.V.=0.35) and 20% poly(propylene terephthalate) (I.V.=0.37) is used in 
the melt-blown process to produce firm filter rods. The conditions for the 
melt-blown spinning are similar to those established for poly(ethylene 
terephthalte) alone. 
EXAMPLE 11 
Example 1 is repeated and firm filter rods were prepared. The rods are cut 
into 100-mm lengths and immediately conveyed to a heated molding device. 
At temperatures of 85.degree. C., molded filters with radial flow 
characteristics are produced. The filtration efficiency of these filters 
is superior to conventional molded filters which require molding 
temperatures of 125.degree. C. 
EXAMPLE 12 
Using the method described in Example 1, cellulose acetate polymer 
containing 39.8% acetyl having a textile viscosity of six seconds which is 
plasticized with 40 weight % triacetin is extruded at a melt temperature 
of 235.degree. C. and rate of 0.2 pound per hour into a stream of 
306.degree. C. air flowing at a rate of 2.5 SCFM. One to 10 micron 
diameter fibers are collected in a funnel type collector, the throat of 
which is located 130 mm below the spinneret orifice. Firm filter rods are 
collected by manually pulling the fibers through the rod formation area. 
Twenty-millimeter tips tested on cigarettes are equal in filtration 
efficiency of cigarette smoke to commercial filters at the same pressure 
drops but are 20% lighter. 
EXAMPLE 13 
The process described in Example 1 is used to produce a filter element 
useful for the filtration of oil, water, and air. Poly(ethylene 
terephthalate) is converted to melt-blown fibers. The melt-blown fibers 
are directed into a perforated metal mold four inches in diameter having a 
solid core three inches in diameter. Melt-blown fibers are directed at the 
mold to give a thermally-bonded element five inches in height. This 
radial-flow element is then positioned in a solid canister and placed in 
oil, water or air steam. Small particles of dust and metal are effectively 
filtered from the fluid. 
EXAMPLE 14 
The process described in Example 1 is used to produce a cylindrical rod. 
The rod is cut to a length of 3.5 inches and inserted in an empty marking 
pen. An ink containing xylenes, ketones, and ethyl alcohol is added to the 
reservoir. The poly(ethylene terephthalate) fibers are not adversely 
affected by the solvent. The pen is used for several weeks. The reservoir 
has an increased capacity for ink because the fine fiber size result in 
excellent capillary action. 
EXAMPLE 15 
Example 13 is repeated except polypropylene is the thermoplastic polymer 
used in the preparation of the melt-blown articles. 
The invention has been described in detail with particular reference to 
preferred embodiments thereof, but it will be understood that variations 
and modifications can be effected within the spirit and scope of the 
invention.