Heat sensitive label for packaging a dry-cell battery

A heat sensitive label for packaging a dry-cell battery includes a label substrate, a heat sensitive adhesive layer provided on one surface of the label substrate and a printing layer provided on an opposite surface of the label substrate, in which an ultraviolet ray curing ink is applied for the printing layer.

BACKGROUND OF THE INVENTION 
This invention relates to an improvement in a heat sensitive label for 
packaging a dry-cell battery. 
Referring to FIG. 4, a label 30, which has a label substrate 31 made of a 
heat shrink film, a printing layer 32 provided on one surface of the label 
substrate 31, and a pressure sensitive adhesive layer 33 provided on an 
opposite surface of the label substrate 31, is wound around a dry-cell 
battery and bonded to the same via the pressure sensitive adhesive layer 
33. Instead of a conventional metal jacket, the label of this type is 
commonly used for packaging the dry-cell battery, since it can be 
manufactured to be thinner than the metal jacket, and is therefore 
advantageous in the fact that a dry-cell battery of a larger dimension can 
be packaged, while maintaining an outer diameter of a finished product of 
the battery with the label 30 thereon. 
For packaging the dry-cell battery with the label 30 thereon, a release 
paper 34 is usually attached to an exposed surface of the pressure 
sensitive adhesive layer 33 provided on the opposite surface of the label 
substrate 31 to prevent the pressure sensitive adhesive layer 33 from 
bonding to unintentional portions. The release paper 34 is relatively 
expensive, and requires additional steps, that is, the steps of attaching 
the release paper to the pressure sensitive adhesive layer 33 and 
releasing the same therefrom. This may be troublesome and increase the 
manufacturing cost of the label 30. 
Alternatively, there has been proposed a heat sensitive label with an 
adhesive layer of a heat sensitive adhesive thereon, since the heat 
sensitive adhesive does not possess an adhesive property until the heat 
sensitive label is heated to a predetermined temperature. This arrangement 
eliminates the necessity of the release paper 34 or the like in 
transportation and storing of the label 30. 
However, when activating the heat sensitive adhesive of this type by heat, 
a printing ink of the printing layer 32 may be damaged by the heat, and 
consequently deteriorate the appearance of the label 30. 
In addition, when the label substrate 31 of the heat shrinking film is 
heated to an excessively high temperature for activating the adhesive, the 
label substrate 31 may be shrinked and subsequently deformed and/or 
wrinkled. 
It is an object of the present invention to provide a heat sensitive label 
for snugly and securely packaging the dry-cell battery in an inexpensive 
manner. 
SUMMARY OF THE INVENTION 
In accordance with the present invention, a heat sensitive label for 
packaging a dry-cell battery includes a label substrate, a heat sensitive 
adhesive layer provided on one surface of the label substrate, and a 
printing layer provided on an opposite surface of the label substrate, in 
which an ultraviolet ray curing ink is applied for the printing layer. 
Further, a heat sensitive label of the present invention includes a label 
substrate, and a heat sensitive adhesive layer provided on one surface of 
the label substrate. The label substrate is made of a synthetic resin film 
having a heat shrinking property, a heat shrinkage percentage of 3 percent 
or less at 70.degree. C., and is activated to possess an adhesive property 
at 70.degree. C. or less. 
In accordance with the above arrangements, since the label substrate is 
provided on its one surface with the heat sensitive adhesive, the release 
paper can be omitted. In addition, since the printing layer is provided by 
applying the ultraviolet ray curing ink which has excellent hardness and 
thermal resistance as compared with a printing ink of a commonly used 
type, it is unlikely that the printing layer is damaged by the heat during 
activation of the heat sensitive adhesive. 
In case that an ultraviolet ray curing varnish is applied on an exposed 
surface of the printing layer, the printing layer is more effectively 
protected against the heat. Accordingly, the heat sensitive adhesive can 
be heated to a high temperature for the activation thereof without any 
damage, the label can be bonded to the dry-cell battery in a short period 
of time. 
Further, in case that the label substrate is made of a heat shrink film, 
and the heat sensitive adhesive with such a property that it is activated 
at a temperature lower than that at which the label substrate is shrinked 
is employed for the heat sensitive adhesive layer, it is possible that the 
heat sensitive adhesive layer is activated, while the label substrate is 
prevented from shrinking. 
In the present invention, a heat shrinking temperature of the label 
substrate refers to a temperature at which the label substrate is shrunk 
via heat by 1% or more (heat shrinkage percentage).

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
Referring to FIG. 1, a label substrate 1 is made of a heat shrink film of 
polyethylene terephthalate. The label substrate 1 has a heat shrinkage 
percentage of 3% or less at 70.degree. C. in the circumferential direction 
when it is positioned on a dry-cell battery having a cylindrical body, a 
planar top surface 16a and bottom surface 16b, as shown in FIG. 3B. More 
preferably, the heat shrinkage at 70.degree. C. is 1 percent or less, and 
the heat shrinkage percentage of 10% or more at 130.degree. C. in the 
circumferential direction, and more preferably 20% or more. 
When the heat shrinkage percentage is less than 10 percent at 130.degree. 
C., it is difficult to bring edge portions of the label extending from the 
top and bottom surfaces 16a, 16b of the dry-cell battery 16 into tight 
contact with the surfaces 16a and 16b via the heat shrinking property of 
the label, after the label is wrapped around the dry-cell battery 16. 
Therefore, the label having such a heat shrinkage percentage is not 
preferable for this purpose. 
The label substrate 1 has a thickness of 20 to 100 .mu.m, and more 
preferably 30 to 60 .mu.m. 
A heat sensitive adhesive 2 is provided on one surface of the label 
substrate 1 via an aluminium metallized layer 6. Example of a hot melt 
adhesive include a heat fusing synthetic resin which is made of 
ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, 
ethylene-methacrylic acid copolymer, ionomer or a low density 
polyethylene, or one made of a mixture of these materials. A tackifier, 
for example, a terpene resin and a petroleum resin, a plasticizer of a 
varying type, and an addition agent, for example, a stabilizer may 
optionally be added to the heat sensitive adhesive layer 2 of the above 
composition. 
The heat sensitive adhesive of the heat sensitive adhesive layer 2 is 
activated to possess the adhesive property at 70.degree. C. or less, and 
more preferably at 65.degree. C. or less. 
The aluminium metallized layer 6 is formed on the one surface of the label 
substrate 1 by means of vacuum evaporation of aluminium, and has a 
thickness of 0.01 to 0.1 .mu.m. 
An anchor coat layer may be provided between the label substrate 1 and the 
aluminium metallized layer 6, and/or between the aluminium metallized 
layer 6 and the heat sensitive adhesive layer 2 to improve the adhesive 
property of these layers. 
The label substrate is provided on its opposite surface with a printing 
layer 3 by printing an ultraviolet ray curing ink. The printing layer 3 
displays a trade name, ornamental design and the like thereon. The 
ultraviolet ray curing ink has an excellent thermal resistance as compared 
with an ink of a solvent dry type which is conventionally used. As a 
material of the ultraviolet ray curing ink, oligomer, for example, epoxy 
acrylate, urethane acrylate and polyester acrylate, and polyester monomer, 
which selectively contains an ultraviolet ray initiator, a coloring agent, 
for example, a pigment, a dispersing agent and an addition agent, may be 
employed. Specifically, materials which are commercially available under 
the marks BESTCURE (Toka shikiso Kagaku K.K.), UVACE (Kuboi Ink K.K.) and 
CP-UV (Matsui Kagaku K.K.) are suitable for the ultraviolet ray curing 
ink. 
The anchor coat layer may be provided between the label substrate 1 and the 
printing layer 3 to possess the adhesive property for the same reason as 
above. 
An ultraviolet ray curing varnish layer 5 of a transparent type is applied 
on an exposed surface of the printing layer 3 to protect the printing 
layer 3 and obtain a glossy appearance. 
To manufacture the heat sensitive label 10 of the above arrangement, the 
aluminium metallized layer 6 with a thickness of about 0.05 .mu.m is 
formed on one surface of a lengthy film of polyethylene terephthalate with 
a thickness of about 50 .mu.m. This polyethylene terephthalate film has a 
shrinkage percentage of 0.1% in the longitudinal direction thereof and 0% 
in the lateral direction thereof at 70.degree. C., and 25% in the 
longitudinal direction and 4% in the lateral direction at 130.degree. C. 
An anchor coat agent is then applied on the surface, on which the aluminium 
metallized layer 6 has been formed. The heat fusing synthetic resin using 
ethylene-vinyl acetate copolymer as a main component, is then coated on 
the anchor coat agent by means of a melting and extruding method to form 
the heat sensitive adhesive layer 2 with a thickness of 20 .mu.m. 
A trade name, varying ornamental design, etc., are printed on the opposite 
surface of the polyethylene terephthalate film by means of a relief 
duplicator, using the ultraviolet ray curing ink to form the printing 
layer 3. The ultraviolet ray curing varnish of a transparent type is then 
applied on the printing layer 3 to form the varnish layer 5. The 
ultraviolet ray curing ink of the printing layer 3 is cured by radiating 
ultraviolet rays via an ultraviolet lamp whenever each color thereof is 
applied, and the ultraviolet ray curing varnish is cured via the 
ultraviolet lamp whenever it has been applied on the printing layer 3. 
Thus, a plurality of the heat sensitive labels are formed, and are 
separated from each other by cutting predetermined portions of the lengthy 
film 11 to form a plurality of the individual heat sensitive labels 10, 
each having the above arrangement. At this time, the heat sensitive label 
10 is formed so that opposite longitudinal edges of the film 11 extend in 
the circumferential direction of the dry-cell battery 16 when positioned 
thereon. 
The operational steps of packaging the dry-cell battery 16 with the heat 
sensitive label 10 will be described hereinbelow. 
Referring to FIG. 2, the lengthy film 11 with the printing layer 3, the 
varnish layer 5, the aluminium metallized layer 6 and the heat sensitive 
adhesive layer 2 thereon is drawn from a roll, and transported via 
transporting rollers 12 to a cutting station, where the lengthy film 11 is 
cut via a cutter 13a mounted on a cutting roller 13 into the individual 
heat sensitive labels 10. 
The heat sensitive labels 10 are successively sucked by a rotary drum 14 
which moves in the direction of arrow A, so each of the heat sensitive 
adhesive layers 2 lies on a circumferential surface of the rotary drum 14 
as it faces outwardly. 
The heat sensitive labels 10 on the rotating drum 14 are transported to a 
heating mechanism 15, where the outermost surface of each heat sensitive 
label 10, that is, the heat sensitive adhesive layer 2 is heated by a 
heater 15a in such a manner as to be activated to possess the adhesive 
property. At this time, the heat sensitive adhesive layer 2 is heated to a 
temperature of 65.degree. to 70.degree. C., which temperature enables the 
adhesive 2 to be activated. It is preferable that the heat sensitive 
adhesive layer 2 is heated to such a temperature that the adhesive thereof 
can possess the adhesive property, while the label substrate 1 does not 
shrink or slightly shrinks. The heat sensitive adhesive layer 2 may be 
heated by heating the rotary drum 14. 
On the other hand, the dry-cell batteries 16 to be packaged are 
successively fed to a transporting drum 21 via a conveyor 20, held by 
respective holding parts 21a of the transporting drum 21, transported to a 
place near a feeding drum 29, held by respective holding members 29a 
formed in a circumferential surface of the feeding drum 29, transported 
along a path between a guiding member 30 and the feeding drum 29, and 
supplied to a place near the rotary drum 14. 
At the time the heat sensitive label 10 with the activated heat sensitive 
adhesive layer 2 thereon is transported via the rotary drum 14 to a place 
near the dry-cell battery 16, the dry-cell battery 16 held by the holding 
member 29a is brought into contact with the outwardly facing surface of 
the heat sensitive label 10 via rotation of the feeding drum 29, and is 
rotated in the direction of arrow B via rotation of the rotary drum 14 so 
that the heat sensitive label 10 on the rotary drum 14 is wound around the 
cylindrical body of the dry-cell battery 16, as the heat sensitive label 
10 abuts against and is bonded to the surface of the dry-cell battery 16 
via the activated heat sensitive adhesive layer 2. Overlapped edges of the 
heat sensitive label 10 are bonded to one another via the surfaces of the 
heat sensitive adhesive layer 2 and the printing layer 3, as illustrated 
in FIG. 3A. 
The dry-cell batteries 16 each having the heat sensitive label 10 thereon 
are then transported to a transporting drum 31 via the feeding drum 29, 
held by respective holding members 31a of the transporting drum 31, and 
mounted onto an endless belt member 32, which is rotated in the direction 
of the arrow so that the dry-cell batteries 16 are successively introduced 
into a position under a heating belt member 18 of a heating unit 33. The 
heating belt member 18 is heated to a temperature of about 130.degree. C. 
by the heating unit 33, and positioned in such a manner as to press the 
cylindrical body of the dry-cell battery 16, as it is rotated to move the 
dry-cell batteries 16 forwardly, which movement enables the dry-cell 
batteries 16 to be rotated, and the entire surface of each heat sensitive 
label 10 to be heated and pressed by the heating belt member 18. In this 
regard, reapplication of the heat enables the heat sensitive adhesive 
layer 2 to be activated again and more securely bonded to the dry-cell 
battery 16 and the printing layer 3 of the overlapped edge of the heat 
sensitive label 10. 
The heat sensitive label 10 with the ultraviolet ray curing ink and the 
ultraviolet ray curing varnish applied thereon is unlikely to be damaged 
by the heat effected by the heating belt member 18. 
Referring to FIG. 3B, the heat sensitive label 10 is dimensioned in such a 
manner as to slightly project from the top and bottom planar surfaces 16a, 
16b of the dry-cell battery 16 in a wrapping state. The dry-cell battery 
16 is heated within the heating unit 33 so that the projecting portions of 
the heat sensitive label 10 are shrinked and bonded to the respective 
surfaces of the dry-cell battery 16, as illustrated in FIG. 3C. 
In accordance with the above steps of bonding the heat sensitive label 10, 
the dry-cell battery 16 is subjected to the heat in an extremely short 
period of time, and therefore is unlikely to be heated to a high 
temperature. Thus, the heat sensitive label 10 can maintain its quality. 
As being apparent from the above embodiment, in the case the heat sensitive 
label 10 is activated at a relatively low temperature, that is, 70.degree. 
C. or less, it is not necessary to form the printing layer 3 by applying 
the ultraviolet ray curing ink. Instead, an ink of a common type may be 
used to form the printing layer 3. It is to be noted, however, that the 
ultraviolet ray curing ink enables the heat sensitive label 10 to be more 
effectively and securely bonded to the dry-cell battery 16, since the heat 
sensitive label 10 can be subjected to pressure and a high temperature 
effected by the heating belt member 18, after the heat sensitive label 10 
has been bonded to the dry-cell battery 16. 
Although a single layer of the polyethylene terephthalate film is employed 
as a material of the label substrate 1 in this embodiment, materials 
possessing a heat shrinking property, for example, polyethylene, polyvinyl 
chloride and polypropylene may be used for the label substrate 1. However, 
it is to be noted that a film of polyester including polyethylene 
terephthalate has an excellent mechanical strength and rigidity, and may 
not generate poisonous gases in burning, and is therefore suitable for the 
label substrate 1. 
The label substrate 1 may be made of a film other than the heat shrink 
film. However, the heat shrink film enables the label substrate 1 to be 
easily and tightly attached to the dry-cell battery 16 via its heat 
shrinking property, and is therefore suitable for the label substrate 1. 
It is not essential to form the ultraviolet ray curing varnish on the 
printing layer 3, and form the aluminium metallized layer 6 on the 
opposite surface of the label substrate 1. 
In this embodiment, the adhesive of the heat sensitive adhesive layer 2 is 
activated to possess the adhesive property when heated to a temperature of 
70.degree. C. or less, and more preferably 65.degree. C. or less. It is 
not essential that the adhesive is activated within such ranges. However, 
in case that the adhesive of the type, which is activated at an extremely 
high temperature, is used, the heat shrink film of the type, which does 
not shrink at such extremely high temperature, may be required as a 
material of the label substrate 1. In addtion, the application of high 
temperature may deteriorate the dry-cell battery. On the other hand, in 
case that the adhesive is activated at a relatively low temperature, some 
problems will be caused in storing the heat sensitive label. Therefore, it 
is preferable to employ the adhesive having the activation temperature of 
the above ranges. 
In the above embodiment, the heat sensitive label 10 is heated and pressed 
by the heating belt member 18 to be more securely bonded to the dry-cell 
battery 16, after it is positioned on the dry-cell battery 16. 
Alternatively, the bonding state between the dry-cell battery 16 and the 
heat sensitive label 10 may be secured by clamping and rotating the 
cylindrical body of the dry-cell battery 16 with hot plates or the like, 
while applying a pressure. Varying application methods of the heat 
sensitive label 10 may be employed. 
This specification is by no means intended to restrict the present 
invention to the preferred embodiments set forth therein. Various 
modifications to the heat sensitive label, as described herein, may be 
made by those skilled in the art without departing from the spirit and 
scope of the present invention as defined in the appended claims.