Asbestos contamination control method and formulas used therein

A method and material for protection from airborne asbestos and other particular contamination is disclosed that is useful for protecting the environment and individuals working therein as occurs at a job site when friable or cementitious asbestos containing coatings are being removed from existing structures. The method includes application of a combined wetting and encapsulation formula which bonds the asbestos fibers to materials in the formula so as to convert friable asbestos to non-friable asbestos and a hardening procedure and formula which places the bonded non-friable asbestos in a hardened mass so that it may be safely disposed of.

BACKGROUND OF THE INVENTION 
1. Technical Field 
This invention relates to a method of asbestos contamination control and 
the formulas used therein and the use of the method on friable or 
cementitious asbestos containing coatings or articles that are being 
removed from a building being renovated or demolished. 
2. Description of the Prior Art 
U.S. Pat. No. 3,972,972 discloses a process for producing a board of 
cement-like material reinforced by fibrous material, such as asbestos, 
wherein the fibrous material is airborne during the formation of the 
material. 
U.S. Pat. No. 4,271,115 discloses a method of producing a prewet dust-free 
form of asbestos short fibers by agglomerating the asbestos fibers with a 
relatively small amount of hydrophilic liquids such as water and a 
polymeric material such as ethylene glycol. The asbestos agglomerate is 
designed for use in connection with non-polar materials such as solvents, 
oils, rubber, polyethylene, and polyesters. 
U.S. Pat. No. 4,489,109 discloses a process for the production of a 
vulcanized latex protective coating bonded to the surface of an 
asbestos-cement article to prevent the subsequent release of asbestos 
fibers from the same. 
U.S. Pat. No. 4,604,111 discloses a negative air pressure method and 
apparatus for the protection of a job site from airborne asbestos fibers 
in a specified enclosure defining the job site. 
The present invention differs from the known prior art in avoiding the 
release of friable asbestos into the environment by an initial step of 
wetting the asbestos containing material and simultaneously encapsulating 
the asbestos fibers in the material thus preventing the release of friable 
asbestos into the environment whereas the prior art relates to utilizing 
friable asbestos in a product where the friable asbestos is airborne 
during some or all of the stated process or in the case of U.S. Pat. No. 
4,604,111, friable asbestos in the environment is airborne and is 
theoretically circulated through filters in communication with an exhaust 
means. 
The United States Environmental Protection Agency has established 
regulations setting certain standards for the handling of friable asbestos 
in various work environments including demolition. The demolition of 
structures containing friable asbestos is controlled by these regulations 
and requires very expensive handling and disposal techniques. The disposal 
techniques for friable asbestos are particularly burdensome and expensive 
including wetting, double bagging, and disposal in only certain licensed 
disposal sites which are often a great distance from a demolition site. 
SUMMARY OF THE INVENTION 
The present invention is directed to a method of converting friable 
asbestos in insulating coatings and coverings to non-friable asbestos and 
is particularly useful in protecting the environment from contamination 
with friable asbestos when asbestos containing insulating coatings, 
coverings and similar forms are being removed and/or the structures in 
which they are located demolished. The method of the present invention 
comprises converting friable asbestos to non-friable asbestos by wetting 
and encapsulating the asbestos and/or asbestos containing material with 
water containing propylene glycol, vinyl acetate/ethylene copolymer and 
preferably a dye to indicate satuation and depth of penetration of the 
wetting liquid in the material which can then be safely removed and 
following such removal further encapsulating the asbestos with an 
additional treatment of the same material. 
The removed material including the encapsulated asbestos is then mixed with 
a hardening formula of water, Portland cement, and a small amount of 
propylene glycol so as to form a pourable mixture that will harden and 
form a mass completely and safely containing the non-friable asbestos. The 
propylene glycol acts to bond the larger molecules of the water, vinyl 
acetate/ethylene copolymer and Portland cement to the asbestos fibers to a 
much greater extent than has heretofore been believed possible.

DESCRIPTION OF THE PREFERRED EMBODIMENT 
As used throughout this specification, the term friable asbestos means any 
material containing asbestos that by hand pressure can crumble, pulverize, 
or be reduced to powder-like fibers which can be airborne. The term 
asbestos means any of the asbestiform varities of chrysotile, crocidolite, 
cummingtonite-grunerite, anthophoyllite, and actinolite-tremolite. The 
herein disclosed method and formulas for converting friable asbestos to 
non-friable asbestos have many advantages in both eliminating a potential 
health hazard and in greatly reducing the cost and difficulties of 
disposing of friable asbestos in accordance with the National Emission 
Standards for Hazardous Air Pollutants (49 Federal Register, page 13658 et 
seq.). The wetting and encapsulation formula may comprise for example 
93.88% by volume water, 0.015% by volume propylene glycol, 6.09% by volume 
vinyl acetate/ethylene copolymer, 0.0003% by volume F,D and C Blue No. 1, 
and 0.0007% by volume F,D and C Yellow No. 5 to obtain the color green in 
the formula. The final hardening formula may comprise 75.46% by volume, 
water, 0.011% by volume propylene glycol, and 24.53% by volume Portland 
cement. Vinyl acetate/ethylene copolymer may be substituted for the 
Portland cement. The color dyes above referred to may be added to the 
hardening formula if desired. The quantity of asbestos fibers in different 
articles varies and an improved formula of the wetting and encapsulation 
formula can be obtained by increasing the vinyl acetate/ethylene copolymer 
to 11.49% by volume with a similar increase of the propylene glycol and 
reducing the water content to 88.50% by volume. The hardening or 
solidifying formula may comprise from about 67.42% by volume to about 
75.46% by volume water, from about 0.011% to about 0.02% by volume 
propylene glycol, and from about 24.53% to about 29.50% by volume Portland 
cement and an equal amount of vinyl acetate/ethylene copolymer may be 
substituted for the Portland cement. The wetting and encapsulation formula 
may comprise from about 60% by volume to about 99% by volume water, from 
about 0.011% to about 0.02% by volume propylene glycol, and from about 
6.9% to about 7.81% by volume vinyl acetate/ethylene copolymer. The vinyl 
acetate/ethylene copolymer is a water soluble, dry white powder 
commerically available as AIRFLEX RP 226, a product of Air Products and 
Chemicals, Inc. of Allentown, Pa. 
A still further improved wetting and encapsulation formula can be obtained 
by additionally increasing the content of vinyl acetate/ethylene copolymer 
to 17.4% by volume with a similar increase of the propylene glycol and 
reducing the water content to 82.6% by volume. 
Flame retardants may and should be added to above formulas and may comprise 
75 to 150 grams of ammonium polyphosphate for each gallon of the wetting 
and encapsulation formula or alternately from 12 to 20 ounces of liquid 
sodium silicate grade 40 added to each gallon of the wetting and 
encapsulation formula. 
Those skilled in the art will observe that the application of the above 
formulas in the hereindisclosed method may be quickly performed and that 
the materials used in the formulas are relatively inexpensive as the 
asbestos and/or asbestos containing material to be removed is simply 
sprayed or otherwise wet with the wetting and encapsulation formula above 
described so that the asbestos and/or asbestos containing material is 
sufficiently saturated and/or penetrated as may be visibly determined by 
the color thereof. The asbestos material is then removed and further 
encapsulated by mixing by mixing with the hardening formula including the 
Portland cement so as to completely enclose and bond the asbestos 
containing material rendering it safe for disposal as all of the asbestos 
and the particles of other materials, such as binders, are advantageously 
bonded in a solid mass by the hardening formula hereinbefore given. 
It will thus be seen that the asbestos and/or asbestos containing material, 
such as insulation, may be quickly and safely removed from an article or 
structure without enclosing the area or otherwise attempting to control 
air quality in the removal area. 
It will also be observed that there can be no air contamination as no 
friable asbestos is present in the material being removed. 
A modification of the wetting and encapsulation formulas hereinbefore given 
may be employed wherein Portland cement is substituted for the vinyl 
acetate/ethylene copolymer of the earlier examples. One such generally 
satisfactory mixture comprises water 75.46% by volume, Portland cement 
24.53% by volume and propylene glycol 0.011% by volume in which mixture 
the amount of water may be varied depending upon a desired consistency. 
The propylene glycol bonds the larger molecules of the Portland cement to 
the smaller molecules of the asbestos fibers. 
The hardening formula with the Portland cement may be used by mixing the 
wetted and encapsulated asbestos containing material in a ratio of 7 parts 
by volume to one part by volume of the Portland cement containing 
hardening formula. The ratio may change depending on the asbestos 
containing material composition from 2 to 14 parts by volume to 1 part of 
the Portland cement containing hardening formula. The resulting mix which 
contains no friable asbestos will harden into a solidified mass which may 
be safely and easily disposed of in any landfill or the like. 
It will occur to those skilled in the art that when the resulting mass has 
dried and hardened, the same may be sprayed with the wetting and 
encapsulating formula hereinbefore disclosed if desired to additionally 
coat and seal the mass before final disposal. 
A further modification of the wetting and encapsulating formulas may 
comprise water 67.72% by volume, Portland cement 29.34% by volume, vinyl 
acetate/ethylene copolymer 2.93% by volume, and propylene glycol 0.0062% 
by volume. 
A still further modification may comprise water 95.83% by volume, vinyl 
acetate/ethylene copolymer 4.15% by volume, and propylene glycol 0.0152% 
by volume. 
It will occur to those skilled in the art that the several formulas 
hereinbefore set forth may be adapted for use in lower temperature or 
winter removal operations to prevent freezing by increasing the percentage 
ratio of propylene glycol to that of water, propylene glycol is 
1,2-propanediol sometimes known as 1,2-dihydroxypropane. 
Numerous tests of the wetting and encapsulation material formulas 
hereinbefore given have been made with test samples formulated as follows. 
One wetting and encapsulation formula sample comprises 38 ounces of water 
and 0.187 grams of propylene glycol with the addition of saturation and 
penetration indicating dye comprising 0.013 grams of F,D, and C Blue No. 1 
and 0.027 grams of F,D, and C Yellow No. 5 to obtain the color green. The 
wetting and encapsulation formula sprayed or similarly applied on asbestos 
containing material penetrates the same rapidly and to a depth of four 
inches in approximately one hour's time. The degree of penetration and/or 
saturation is visible due to the color occasioned by the dye in the 
formula. Removing the treated asbestos containing material such as 
insulation from an object is facilitated by the freeing of the bonding 
agents by the wetting and encapsulation formula and disclose no friable 
asbestos or other material capable of being airborne. The wetting and 
encapsulation (bonding) softening action is maintained for a number of 
hours (from 6 to 12 hours) and may be repeated in the event the time 
element is extended and some drying of the asbestos containing material 
occurs before removal. The bonding of the removed asbestos containing 
material with the hardening formulas hereinbefore given insures the 
stability of the removed material and the continued absence of friable 
asbestos. 
It has been found that an acceptable modified wetting and encapsulation 
formula can be formed by subsituting an acrylic polymer such as 
commercially available from Rohm and Haas Company of Philadelphia, Pa. 
19105, as RHOPLEX MC 76 Emulsion (an aqueous acrylic emulsion) for the 
vinyl acetate/ethylene copolymer of the formulas hereinbefore disclosed 
and adding Portland cement. For example, the wetting and encapsulation 
formula may comprise substantially 67.65% by volume water, 0.00076% by 
volume propylene glycol, 7.81% by volume acrylic polymer, and 24.53% by 
volume Portland cement, and 0.00038% by volume F,D, and C Blue No. 1 and 
0.00076% by volume F,D, and C Yellow No. 5 to obtain the color green. The 
acrylic polymer is an emulsion of 47% acrylic polymer solids and water.