SEMICONDUCTOR DEVICE

A semiconductor device includes a semiconductor substrate, a first layer formed on the semiconductor substrate and including a semiconductor element and a first insulating film, a second layer formed above the first layer and including a channel including an oxide semiconductor and a second insulating film, and a third layer formed above the second layer, and including an electrode formed on the channel and a third insulating film having a film density less than at least one of a film density of the first insulating film or a film density of the second insulating film.

CROSS-REFERENCE TO RELATED APPLICATION

This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2022-128693, filed Aug. 12, 2022, the entire contents of which are incorporated herein by reference.

FIELD

BACKGROUND

The development of utilizing an oxide semiconductor as the channel of a semiconductor device has been proposed. For example, there is a dynamic random access memory (DRAM) in which an oxide semiconductor transistor is applied to a switching transistor of a memory cell.

DETAILED DESCRIPTION

Embodiments provide a semiconductor device capable of reducing a supply of oxygen to a semiconductor not requiring oxygen supply, while supplying oxygen to a semiconductor requiring oxygen supply.

In general, according to one embodiment, a semiconductor device includes a semiconductor substrate, a first layer formed on the semiconductor substrate and including a semiconductor element and a first insulating film, a second layer formed above the first layer and including a channel including an oxide semiconductor and a second insulating film, and a third layer formed above the second layer, and including an electrode formed on the channel and a third insulating film having a film density less than at least one of a film density of the first insulating film or a film density of the second insulating film.

Hereinafter, embodiments will be described with reference to the drawings. In the following description, the same or similar components may be denoted by the same reference numerals and description thereof may be omitted.

In the description, the terms “upper” and “lower” may be used for convenience of explanation, but these describe relative locations in the drawings and do not define absolute positional relationships. For example, “above” or “below” in the present embodiment may be different from “above” or “below” in the vertical direction. In addition, in the description, part of the configuration of a semiconductor device may be expressed without distinction as a “layer” or a “film”.

First Embodiment

A semiconductor memory device according to the present embodiment relates to a dynamic random access memory (DRAM) and includes a memory cell array including a plurality of memory cells. Each memory cell includes a field effect transistor (FET) and a capacitor. The memory cells are located in rows and columns to form the memory cell array. However, the plurality of memory cells may be located not only in rows and columns but also vertically. The field effect transistor in the memory cell includes a gate connected to a corresponding word line, one of a source and a drain connected to one electrode of the capacitor, and the other of the source and the drain connected to a corresponding bit line. One electrode of the capacitor may be connected to one electrode of the field effect transistor as described above so as to be able to supply charges. The other electrode of the capacitor may be connected to a power supply line that supplies a predetermined voltage. The memory cell is configured to be able to store data by storing charges in the capacitor from the bit line by the field effect transistor switched by the word line. A semiconductor memory device1according to the present embodiment will be described as an example of the semiconductor device.

Configuration of Semiconductor Memory Device1

FIG.1is a schematic cross-sectional view showing a configuration example of the semiconductor memory device1according to the present embodiment. As shown inFIG.1, the semiconductor memory device1includes a semiconductor substrate10, a semiconductor element11, an insulating layer12, a capacitor structure21, a lower capacitor electrode23, an insulating layer32, a lower electrode41, an oxide semiconductor layer42, a gate oxide film43, a word line44, an upper electrode45, an insulating layer46, a bit line51, and an insulating layer60. A metal layer serving as a landing pad may be formed between the upper electrode45and the bit line51to facilitate mutual connection.

For example, the semiconductor substrate10is a substrate including single crystal silicon and the like.

The semiconductor element11is a metal-oxide-semiconductor field effect transistor (MOSFET) or the like formed on the semiconductor substrate10, but may be another semiconductor element. For example, unlike a field effect transistor40(FIG.1), the semiconductor element11may have a channel using silicon. For example, the semiconductor element11forms a semiconductor integrated circuit including CMOS for controlling the memory cell array.

The insulating layer12(an example of a “first insulating film”) is an insulator formed in a layer shape on the semiconductor substrate10. The insulating layer12is formed in the same layer as the semiconductor element11to electrically insulate the semiconductor element11and wiring (conductors, and the like) connected thereto. For example, the insulating layer12is a silicon oxide film (SiO2) including silicon and oxygen.

The capacitor20and the insulating layer32(an example of a “fourth insulating film”) are formed in a layer (an example of a “fourth layer”) above the layer (an example of a “first layer”) in which the semiconductor element11and the insulating layer12are formed.

The capacitor20of the present embodiment is a three-dimensional capacitor such as a so-called pillar capacitor, cylinder capacitor, or the like. The capacitor20includes the capacitor structure21and the lower capacitor electrode23and is configured to be able to store charge between the lower electrode41and the lower capacitor electrode23. The capacitor structure21is a known structure including a dielectric capable of storing a charge and serving as a capacitor.

The field effect transistor40and the insulating layer46(an example of a “second insulating film”) having the oxide semiconductor layer42as a channel are formed in a layer (an example of a “second layer”) above the layer (an example of the “fourth layer”) in which the capacitor20and the insulating layer32are formed. In the present embodiment, the lower electrode41, the oxide semiconductor layer42, the gate oxide film43, the word line44and the upper electrode45form the field effect transistor40. The field effect transistor40is formed above the capacitor20. The field effect transistor40is a component of the memory cell.FIG.1shows four field effect transistors40paired with four capacitors20. The number of field effect transistors40may be freely changed according to the number of capacitors20.

The lower electrode41is provided on the capacitor structure21and electrically connected to the capacitor structure21. For example, the lower electrode41includes metal oxide such as indium tin oxide (ITO) and the like.

The oxide semiconductor layer42is formed in a through via hole formed between the lower electrode41and the upper electrode45and extends vertically in a columnar shape. For example, the oxide semiconductor layer42is an oxide including indium (In), gallium (Ga), and zinc (Zn). The oxide semiconductor layer42forms the channel of the field effect transistor40.

The gate oxide film43is provided between the oxide semiconductor layer42and the word line44so as to cover a periphery of the oxide semiconductor layer42. The gate oxide film43is an insulator, such as a silicon oxide film (SiO2) including silicon (Si) and oxygen (O).

The word line44is a word line in the memory cell and also forms the gate electrode of the field effect transistor40. For example, the word line44is a conductor including at least one material selected from the group consisting of tungsten (W), titanium (Ti), titanium nitride (TiN), molybdenum (Mo), cobalt (Co), and ruthenium (Ru), and typically includes tungsten.

The upper electrode45is provided on the oxide semiconductor layer42. For example, the upper electrode45is a conductor including conductive oxide, and includes metal oxide such as indium tin oxide (ITO) and the like.

The upper electrode45serves as one of a source electrode or a drain electrode of the field effect transistor40, and the lower electrode41serves as the other of the source electrode or the drain electrode of the field effect transistor40.

In the field effect transistor40configured as described above, a voltage is applied to the word line44serving as the gate electrode to generate a predetermined voltage difference between the word line44and the source or drain electrode, so that an electric field is generated in the channel region of the oxide semiconductor layer42. Therefore, carriers (electrons or holes) flow between the source electrode and the drain electrode. It can also be said that the word line44serving as the gate electrode is a control electrode for generating an electric field in the oxide semiconductor layer42serving as a channel.

The bit line51is formed on the upper electrode45. For example, the bit line51includes a conductor such as tungsten (W) or the like. A landing pad structure may be formed between the bit line51and the upper electrode45to facilitate connection. For example, the landing pad may include tungsten (W), ruthenium (Ru), molybdenum (Mo), or a stacked structure of a plurality of metals including these. In addition, a barrier metal may be formed between the bit line or landing pad and the upper electrode. For example, the barrier metal includes a conductor such as tantalum (Ta), tantalum nitride (TaN), or the like.

The insulating layer32is an insulator that electrically insulates between the capacitors20in the layer in which the capacitors20are formed. For example, the insulating layer32is a silicon oxide film (SiO2) including silicon and oxygen.

The insulating layer46is an insulator provided in the layer in which the oxide semiconductor layer42and the like are formed. For example, the insulating layer46is a silicon oxide film (SiO2) including silicon and oxygen.

The insulating layer60(an example of a “third insulating film”) formed in a layer above the insulating layer46is an insulator formed in a layer (an example of a “third layer”) including the upper electrode45and the bit line51formed on the upper electrode45. The insulating layer60electrically insulates the upper electrode45and the bit line51from the adjacent upper electrode45and bit line51. For example, the insulating layer60is a silicon oxide film (SiO2) including silicon and oxygen.

As described above, the semiconductor memory device1according to the present embodiment includes two types of transistors, including a first transistor (the semiconductor element11) and a second transistor (the field effect transistor40) having an oxide semiconductor channel (a channel including oxygen atoms). For example, the first transistor is an N-type semiconductor element having a channel formed by adding an element such as phosphorus (P) and the like to silicon or the like, or a P-type semiconductor element having a channel formed by adding an element such as boron (B) and the like to silicon or the like. The second transistor is an N-type or P-type semiconductor element having a compound semiconductor channel including oxygen atoms and other elements as a channel. While it is necessary to supply oxygen in the manufacturing process to the second transistor having an oxide semiconductor as a channel in order to adjust the threshold voltage of the semiconductor, it is also preferable that supply of excess amount of oxygen is prevented, because supply of oxygen to the first transistor (the semiconductor element11) results in changes in the characteristics of the semiconductor element11and the unstable threshold voltage.

Meanwhile, the inventors of the present application found that less oxygen permeates through the insulating film as the film density of the insulating film increases. For example, for the insulating films formed at the temperatures of 300° C. and 400° C., respectively, the insulating film formed at 300° C. has a lower film density than that of the insulating film formed at 400° C. It was confirmed that sufficient oxygen is supplied to the oxide semiconductor located under the insulating film that is formed at 300° C., and a semiconductor having a desired threshold voltage is formed, while insufficient oxygen is supplied to the oxide semiconductor located under the insulating film that is formed at 400° C., and the oxide semiconductor does not have a desired threshold voltage.

Therefore, in the semiconductor memory device1according to the present embodiment, a configuration is adopted in which a film density of the insulating layer32is higher than a film density of the insulating layer60. In other words, in the semiconductor memory device1, a configuration is adopted in which the film density of the insulating layer60in the third layer is less than at least one of a film density of the insulating layer12in the first layer and the film density of the insulating layer32in the second layer. Furthermore, in the present embodiment, a configuration is adopted in which the film density of the insulating layer12in the first layer, the film density of the insulating layer32in the second layer, and a film density of the insulating layer46in the fourth layer are the same as each other. That is, a configuration is adopted in which the film densities of the insulating layer12, the insulating layer32, and the insulating layer46are equal to each other, and the film density of the insulating layer60is lower than these film densities.

By adopting the configuration described above, in the semiconductor memory device1, it is possible to promote the supply of oxygen to the oxide semiconductor layer42located under the insulating layer60having a relatively low film density, while reducing the supply of oxygen to the semiconductor element11located under the insulating layer32having a relatively high film density. Therefore, it is possible to stabilize both the threshold voltage of the first type transistor having an oxide semiconductor as a channel, and the threshold voltage of the second type transistor not having an oxide semiconductor as a channel.

Method for Manufacturing Semiconductor Memory Device1

Hereinbelow, a method for manufacturing the semiconductor memory device1will be described mainly with reference to the characteristics of the present embodiment. A known method for manufacturing a semiconductor device can be adopted for the processes other than the processes described below, and the description thereof will be omitted.

In the method for manufacturing the semiconductor memory device1according to the present embodiment, first, the semiconductor element11is formed on the semiconductor substrate10using a known method, and then the insulating layer12forms the first layer.

Then, the insulating layer32is formed, and then patterning, etching, film formation, and the like are repeatedly performed on the insulating layer32to form the capacitor20, thereby forming the fourth layer on the first layer. When forming the insulating layer32, for example, tetraethoxysilane (TEOS) is used as a material, and an insulating layer of silicon oxide (SiO2) is formed by a plasma CVD (PECVD) method using plasma at a predetermined temperature.

Then, the insulating layer46and the word lines44are formed in the same manner, and then etching, film formation, and the like are repeatedly performed on the insulating layer46and the word lines44to form the oxide semiconductor layer42, thereby forming the second layer on the fourth layer.

Then, the upper electrode45and the bit line51are formed. Then, the insulating layer60forms the third layer on the second layer. When forming the insulating layer60, TEOS is used as a material, and an insulating layer of silicon oxide (SiO2) is formed by a plasma CVD method using plasma at a temperature lower than when the insulating layer32is formed. Accordingly, the film density of the insulating layer60can be made lower than the film density of the insulating layer32.

Furthermore, the present embodiment provides a configuration in which the insulating layer12in the first layer, the insulating layer32in the second layer, and the insulating layer46in the fourth layer are formed at approximately the same temperature, and the insulating layer60in the third layer is formed at a temperature higher than the film forming temperature of the insulating layer12in the first layer and the like, such that the film density of the insulating layer12in the first layer, the film density of the insulating layer32in the second layer, and the film density of the insulating layer46in the fourth layer are substantially the same as each other, and the film density of the insulating layer60in the third layer is higher than the film density of the insulating layer12in the first layer and the like.

In a process that follows the formation of the insulating layer60, oxygen annealing is performed by heating to supply oxygen to the oxide semiconductor layer42. As a result, oxygen is supplied to the oxide semiconductor layer42from the surface of the insulating layer60via the insulating layer60and the upper electrode45.

Meanwhile, the insulating layer32has a higher film density than the insulating layer60and has a lower oxygen permeability, and accordingly, the supply of oxygen to the layer under the insulating layer32is reduced. Therefore, oxygen is not supplied more than necessary to the semiconductor element11located under the insulating layer32, and the characteristics can be maintained.

Modifications

The semiconductor memory device1according to the present embodiment is not limited to the configuration described above, and may have the following configurations, for example.

First Modification

According to the embodiment, the film densities of the insulating layers12,32, and46are equal to each other, and the film density of the insulating layer60is set to be less than these film densities, but it is also possible that the film densities of the insulating layers12and46are freely set. In this case, it is still possible to supply oxygen to the oxide semiconductor layer42located immediately under the insulating layer60having a low film density, and reduce the supply of oxygen to the semiconductor element11located under the insulating layer32having a high film density.

Second Modification

The semiconductor memory device1may be configured such that the film density of the insulating layer60is relatively low, and the film density of the insulating layers46or12is higher than the film density of the insulating layer60. At this time, the film density of the insulating layer32may be freely set. In this case, it is still possible to supply oxygen to the oxide semiconductor layer42located immediately under the insulating layer60. In addition, in this configuration, since the film density of the insulating layers46or12located between the semiconductor element11and the oxide semiconductor layer42is high, the supply of oxygen to the semiconductor element11located thereunder is reduced.

Third Modification

According to the embodiment, the insulating layers12,32,46, and60all have substantially the same configuration including silicon and oxygen, and the film density is adjusted by changing the temperature of the plasma used for plasma CVD, but embodiments are not limited thereto. That is, as long as the relationship between the film densities of the embodiment and the modification can be ensured, different materials may be used, or the temperature of plasma CVD for forming the insulating layer may be identically set or freely changed, or the process for forming the insulating layer may be other than plasma CVD. For example, silicon nitride (SiN), aluminum oxide (Al2O3), or other materials having a high dielectric constant may be used as the material of the insulating layer having a high film density.

Meanwhile, when silicon nitride (SiN), aluminum oxide (Al2O3), or the like is used as the material of the insulating layer having a high film density for reducing permeation of oxygen, permeation of hydrogen may be reduced and sufficient hydrogen may not be supplied to the semiconductor element11in a hydrogen annealing process in which hydrogen is supplied to the semiconductor element11for the purpose of improving characteristics. Therefore, it is preferable to use a material such as silicon oxide (SiO2) or the like having hydrogen permeability as the material of the insulating layer having a high film density.

Fourth Modification

In the semiconductor memory device1, when a material having hydrogen permeability such as silicon oxide (SiO2) or the like is used as the material of the insulating layer60, in the hydrogen annealing process, hydrogen is supplied to the oxide semiconductor layer42, and the characteristics of the oxide semiconductor layer42may change. In order to reduce such a change in the characteristics of the oxide semiconductor layer42as described above, a hydrogen barrier film for blocking permeation (or diffusion) of hydrogen may protect the periphery of the oxide semiconductor layer42. For example, the hydrogen barrier film in this case may be provided in a box shape that accommodates at least part of the oxide semiconductor layer42therein so as to cover the periphery of the oxide semiconductor layer42.

The embodiment and modifications of the semiconductor memory device1are described above. As can be seen from the embodiment and modifications, the semiconductor memory device1described in the present embodiment and modifications includes the semiconductor substrate10, the first layer including the semiconductor element11and the insulating layer12, and the second layer formed above the first layer and including the oxide semiconductor layer42and the insulating layer46. The oxide semiconductor layer42forms a channel. The upper electrode45is formed on the channel. The third layer formed above the second layer includes the upper electrode45and the insulating layer60. The insulating layer60in the third layer herein has a lower film density than either the insulating layer12or the insulating layer46. That is, either the insulating layer12in the first layer or the insulating layer46in the second layer has a higher film density than the insulating layer60in the third layer.

With such a configuration, it is possible to supply sufficient oxygen to the oxide semiconductor layer42located under the insulating layer60having a relatively lower film density, and reduce the supply of oxygen to the semiconductor element11formed under the insulating layer32having a relatively higher film density. As a result, the characteristics of the semiconductor element11can be maintained as desired while the oxide semiconductor layer42has a desired threshold voltage.

In addition, an insulating layer (for example, the insulating layer32) may be provided in the fourth layer between the first layer and the second layer, and the film density of the insulating layer60in the third layer may be lower than at least one of the insulating layers located in the first, second, and fourth layers. In other words, any one of the insulating layers (for example, the insulating layers12,46, and32) located in the first, second, and fourth layers may have a higher film density than the insulating layer60in the third layer which is the uppermost layer of these four layers. It is also possible to achieve the object described above by adopting these configurations.

Second Embodiment

Next, a second embodiment will be described. A semiconductor memory device2according to the second embodiment relates to a shape of the oxide semiconductor layer42forming a channel and formed in a through via hole, and a manufacturing method thereof. It is noted that components having the same or similar functions and configurations as those of the first embodiment will be denoted by the same or similar reference numerals, descriptions thereof will be omitted or simplified, and differences from the first embodiment will be mainly described. Details will be given below with reference to the drawings.

Configuration of Semiconductor Memory Device2

The semiconductor memory device2according to the second embodiment has the same configuration as the semiconductor memory device1according to the first embodiment except for the shape of the oxide semiconductor layer42corresponding to the channel of the field effect transistor40and the gate oxide film43. That is, as shown inFIG.2, the semiconductor memory device2according to the second embodiment includes the semiconductor substrate10, the semiconductor element11, the insulating layer12, the capacitor structure21, the lower capacitor electrode23, the insulating layer32, the lower electrode41, the oxide semiconductor layer42a, the gate oxide film43a, the word line44, the upper electrode45, the insulating layer46, the bit line51, and the insulating layer60.

As in the first embodiment, the oxide semiconductor layer42acorresponding to the channel of the field effect transistor40is provided in the through via hole penetrating the insulating layer46and the word line44. Therefore, the oxide semiconductor layer42ais surrounded by the insulating layer46and the word line44.

Hereinafter, differences between the shapes of the through via hole and the oxide semiconductor (FIGS.3and4) according to a configuration of the field effect transistor of a comparative example for the second embodiment, and the shape of the oxide semiconductor layer42a(FIG.5) according to the second embodiment will be described with reference to the drawings.

Since the oxide semiconductor layer is provided in the through via hole formed by etching for vertically connecting the source and the drain of the field effect transistor, the through via hole has a tapered shape progressively narrowing in a diameter downward according to the aspect ratio. While a diameter of the through via hole may vary depending on the semiconductor process rule, for example, the diameter is 20 nm at the boundary with the upper electrode which is the uppermost portion. Therefore, the through via hole in the tapered shape may not have a sufficient diameter at the lowermost portion connected to the lower electrode. In this case, the oxide semiconductor layer formed in the through via hole also does not have a sufficient diameter at the connection portion with the lower electrode.

FIG.3shows, as a comparative example, a field effect transistor40X in which a lower end of the through via hole in contact with a lower electrode41X is too narrow, and so the lower end of the through via hole is blocked by a gate oxide film43X and an oxide semiconductor layer42X is not in contact with the lower electrode41X. In the field effect transistor40X in such a state, the upper electrode (not shown) located on the oxide semiconductor layer42A and the lower electrode41X are not properly connected, resulting in malfunction.

FIG.4shows, as a comparative example, a field effect transistor40Y in which the lower end of the through via hole in contact with a lower electrode41Y is narrowed and the area of an oxide semiconductor layer42Y in contact with the lower electrode41Y is extremely reduced. In the field effect transistor40Y in such a state, the lower electrode41Y may deteriorate due to etching ions. In addition, the electrical resistance of the oxide semiconductor layer42Y in the vicinity of the lower electrode41Y is extremely high, which may adversely affect the characteristics of the field effect transistor40Y and cause malfunction in operation.

In order to avoid the problems described above, a field effect transistor40aof the semiconductor memory device2according to the present embodiment is configured as follows.FIG.5shows a configuration example of the field effect transistor40aaccording to the present embodiment. As shown inFIG.5, the field effect transistor40ahas an upper insulating layer46a(an example of the “second insulating film”) on the upper side and a lower insulating layer46b(an example of the “first insulating film”) on the lower side with the word line44(an example of a “control electrode”) interposed therebetween.

The upper insulating layer46aand the lower insulating layer46bare insulators, respectively. The upper insulating layer46ahas parameters of a film density Dt, a dielectric constant εrt, a Young's modulus Et, and an etching rate Rt. The lower insulating layer46bhas parameters of a film density Db, a dielectric constant εrb, a Young's modulus Eb, and an etching rate Rb. Since the lower insulating layer46bhas a higher etching rate than the upper insulating layer46a, that is, Rb>Rt, the lower insulating layer46bis processed faster than the upper insulating layer46aduring etching. The etching rate of the word lines44is the same as the etching rate of the upper insulating layer46a.

An etching rate R indicates, in relative or absolute value, the amount of material removed from the element to be etched per unit time. The etching rate R and a film density D, a dielectric constant εr, and a Young's modulus E have a relationship in which the etching rate R is decreased as each of the film density D, the dielectric constant εr, and the Young's modulus E is increased. Therefore, when the etching rate Rb is higher than the etching rate Rt, at least one of: the film density Db<Dt; the dielectric constant εrb<εrt; or the Young's modulus Eb<Et is established. However, in the present embodiment, as long as the etching rate satisfies the relationship of Rb>Rt, the high-low relationship of the film density D, the relative dielectric constant εr, and the Young's modulus E is not essentially required.

In addition, the etching rate may vary depending on the etching method adopted or the material to be removed by etching, and the etching rate as used herein indicates the amount of material removed from the element to be etched per unit time in relative or absolute value, when considering the etching method adopted or the material removed by etching.

As described above, when the etching rate Rb of the lower insulating layer46bis greater than the etching rate Rt of the upper insulating layer46a, the lower insulating layer46bis removed more than the upper insulating layer46awhile the etching for forming the through via holes is performed. Therefore, the formed through via hole has a shape that is partially widened on the lower insulating layer46bside as indicated by the boundaries between the gate oxide film43aand the upper insulating layer46a, the word line44, and the lower insulating layer46bshown inFIG.5. More specifically, as shown inFIG.5, a maximum diameter C1of the through via hole under the boundary between the lower insulating layer46band the word line44is greater than a diameter C2of the through via hole at the boundary between the lower insulating layer46band the word line44. It is noted that the diameter of the through via hole is obtained in a cross section in a plane perpendicular to a stacking direction.

When the gate oxide film43aand the oxide semiconductor layer42aare formed in the through via hole formed in the shape described above in the processes after the etching for forming the through via hole, the gate oxide film43aand the oxide semiconductor layer42ahas shapes as shown inFIG.5. That is, the oxide semiconductor layer42adoes not have a simple tapered shape, but has a shape in which the diameter is at least partially increased at a location corresponding to the lower insulating layer46b. More specifically, the maximum diameter of the oxide semiconductor layer42aunder the boundary between the lower insulating layer46band the word line44is greater than the diameter at the boundary between the lower insulating layer46band the word line44.

For example, the upper insulating layer46aincludes a silicon oxide film (SiO2) formed by a CVD method using tetraethoxysilane (TEOS), a silicon nitride film (P—SiN) formed by the plasma CVD method, a silicon oxide film (ALD SiO) formed by atomic layer deposition method, or the like.

For example, the lower insulating layer46bincludes a silicon oxide film (SiO2) formed by the CVD method using tetraethoxysilane (TEOS), a carbon-added silicon nitride film (SiOC), a partially stabilized zirconia (PSZ), or the like.

The upper insulating layer46ais preferably formed using NH3-containing gas in the initial step in order to ensure adhesion with the word line44in contact with the lower layer. Meanwhile, the lower insulating layer46bis preferably formed without using NH3-containing gas in the initial step in order to ensure adhesion with the lower electrode41in contact with the lower layer.

Method for Manufacturing Semiconductor Memory Device2

Next, the characteristics of the method for manufacturing the semiconductor memory device2according to the present embodiment will be described. A known method for manufacturing a semiconductor device can be adopted for the processes other than the processes described below.

FIG.6is a diagram showing the vicinity of the field effect transistor40ain the semiconductor memory device2after completing the manufacturing process up to the layer including the lower electrode41and the insulating layer32inFIG.2.

From the state shown inFIG.6described above, the lower insulating layer46b, the word line44, and the upper insulating layer46aare formed in order.FIG.7shows the semiconductor memory device2in which the lower insulating layer46b, the word line44, and the upper insulating layer46aare formed.

For example, as already described, the lower insulating layer46bincludes the silicon oxide film (SiO2) formed by the CVD method using tetraethoxysilane (TEOS), the carbon-added silicon nitride film (SiOC), the partially stabilized zirconia (PSZ), or the like.

The word line44is formed by forming an insulating layer in a layer above the lower insulating layer46bby a known method, removing part of the insulating layer by etching, and then forming a film of a conductor such as tungsten or the like.

As already described, the upper insulating layer46aincludes the silicon oxide film (SiO2) formed by the CVD method using tetraethoxysilane (TEOS), the silicon nitride film (P—SiN) formed by the plasma CVD method, the silicon oxide film (ALD SiO) formed by atomic layer deposition method, or the like.

It is noted that while a method for manufacturing the upper insulating layer46aand the lower insulating layer46bdifferent from the example described above may be adopted, the adopted manufacturing method has to ensure that at least the lower insulating layer46bhas a higher etching rate than the upper insulating layer46a.

Then, a through via hole47is formed by etching to penetrate the upper insulating layer46a, the word lines44, and the lower insulating layer46b.FIG.8shows the semiconductor memory device2in which the through via hole is formed. Since the lower insulating layer46bhas a higher etching rate than the upper insulating layer46a, as shown inFIG.8, in the through via hole47, the maximum diameter C1of the through via hole47under the boundary between the lower insulating layer46band the word line44is greater than the diameter C2of the through via hole47at the boundary between the lower insulating layer46band the word line44.

Then, after forming the gate oxide film43aas shown inFIG.9by a known method, unnecessary gate oxide film43ais removed by etching as shown inFIG.10.

Then, the oxide semiconductor layer42ais formed in the through via hole47in which the gate oxide film43ais formed. Thus, the field effect transistor40aof the semiconductor memory device2as shown inFIG.11is obtained. From this state, the semiconductor memory device2as shown inFIG.2is manufactured by forming the upper electrode45and the like on the upper layer.

The manufacturing process described above is merely an example, and a similar configuration may be manufactured by another semiconductor manufacturing process. For example, the etching in each process may employ either dry etching or wet etching as needed.

Modifications

For example, the field effect transistor in the semiconductor memory device2according to the present embodiment is not limited to the configuration described above, and may have the following configurations.

First Modification

In field effect transistors40band40caccording to a first modification, the through via holes, gate oxide films43band43c, and oxide semiconductor layers42band42care formed in the shapes shown inFIGS.12and13, respectively. In this modification, the relationship between the etching rates of the upper insulating layer46aand the lower insulating layer46bis the same as in the second embodiment. For example, by employing the known process conditions different from those of the second embodiment, it is possible to form the through via holes as indicated by the outer edge of the gate oxide film43bor43cshown inFIGS.12and13. After forming the through via holes, the gate oxide films43band43cand the oxide semiconductor layers42band42ccan be formed, respectively by the same method as in the second embodiment.

Second Modification

As shown inFIG.14, in a field effect transistor40daccording to a second modification, the lower insulating layer46bin the second embodiment includes a plurality of insulating layers such as a first lower insulating layer46d(an example of a “first film”) and a second lower insulating layer46e(an example of a “second film”). The first lower insulating layer46dis located above the second lower insulating layer46e. In this case, for example, the upper insulating layer46aand the first lower insulating layer46dhave the same etching rate, and the etching rate of the second lower insulating layer46eis higher than the etching rate of the first lower insulating layer46d. At this time, for example, the upper insulating layer46aand the first lower insulating layer46dinclude a material having the same film density, dielectric constant, or Young's modulus, and the second lower insulating layer46eincludes a material having a lower film density, dielectric constant, or Young's modulus than the first lower insulating layer46d.

With such a configuration, as shown inFIG.14, since the second lower insulating layer46eis easier to process by etching than the first lower insulating layer46d, a through via hole is formed as indicated by the outer edge of the gate oxide film43dinFIG.14. That is, the maximum diameter of the through via hole under the boundary between the first lower insulating layer46dand the second lower insulating layer46eis greater than the diameter of the through via hole at the boundary between the first lower insulating layer46dand the second lower insulating layer46e. After forming the through via hole, the gate oxide film43dand the oxide semiconductor layer42dare formed by the same method as in the second embodiment.

Third Modification

In a field effect transistor40eaccording to the third modification shown inFIG.15, as in the second modification ofFIG.14, the lower insulating layer46bin the second embodiment includes a third lower insulating layer46fand a fourth lower insulating layer46g, which are a plurality of insulating layers, but these insulating layers have the different high-low relationship of etching rates.

In a third modification, the etching rate increases in the order of the upper insulating layer46a, the third lower insulating layer46f, and the fourth lower insulating layer46g. At this time, for example, each layer of the upper insulating layer46a, the third lower insulating layer46f, and the fourth lower insulating layer46gincludes a material such that any one of the film density, the dielectric constant, or the Young's modulus decreases in the order of the upper insulating layer46a, the third lower insulating layer46f, and the fourth lower insulating layer46g.

With such a configuration, the removal of material by etching progresses more easily in the third lower insulating layer46fthan in the upper insulating layer46a, and also the removal of material by etching progresses more easily in the fourth lower insulating layer46gthan in the third lower insulating layer46f. Therefore, a through via hole is formed as indicated by the outer edge of gate oxide film43einFIG.15. After forming the through via hole, the gate oxide film43eand the oxide semiconductor layer42eare formed by the same method as in the second embodiment.

Other Modifications

In the field effect transistor of the semiconductor memory device2shown in the second embodiment and the modifications, the description is made based on the assumption that the cross section of the through via hole is circular, but the cross section of the through via hole does not necessarily have to be circular, and may be rectangular, elongated, or any other shape. In this case, the diameter of the through via hole described in the embodiment and modifications can be considered in place of the cross-sectional area in the plane perpendicular to the stacking direction. That is, for example, in the embodiment, the cross-sectional area of the through via hole under the boundary between the lower insulating layer46band the word line44is greater than the cross-sectional area of the through via hole at the boundary between the lower insulating layer46band the word line44.

As described above, the field effect transistor of the semiconductor memory device2according to the second embodiment and each modification includes a first insulating film (the lower insulating layer46b, and the like), a control electrode (the word line44) formed on the first insulating film, and a channel (the oxide semiconductor layer42a, and the like). The channel is surrounded by the first insulating film and the control electrode, and includes an oxide semiconductor formed in a through via hole having a first area in a cross section in a plane perpendicular to the stacking direction at a boundary between the first insulating film and the control electrode, and having a second area greater than the first area in a cross section in a plane perpendicular to the stacking direction under the boundary. With such a configuration, it is possible to reduce the occurrence of poor connection between the upper electrode45and the lower electrode41. In addition, it is possible to reduce a decrease in on-current when the field effect transistor40aor the like is turned on, which occurs due to the excessively narrowing lower end portion of the tapered channel and increasing resistance.

In addition, the field effect transistor of the semiconductor memory device2according to the second embodiment and each modification further includes the second insulating film (the upper insulating layer46a). In this case, the through via hole is surrounded by the first insulating film, the control electrode, and the second insulating film. In addition, an etching rate of the first insulating film is higher than an etching rate of the second insulating film. With such a configuration, the first insulating film is etched faster than the second insulating film, and the through via holes and channels described above can be formed.

Instead of the etching rate relationship as described above, the first insulating film may have at least one of the film density, the dielectric constant, and the Young's modulus lower than that of the second insulating film. As a result, the etching rate relationship described above can be obtained, and the through via holes and channels having the configurations described above can be formed.

Further, it is preferable that the etching rate of the first insulating film is higher than the etching rate of the control electrode. According to such a configuration, since the first insulating layer is etched faster than the control electrode, it is easier to form the through via holes and channels as described above.

It is noted that instead of the etching rate relationship between the first insulating film and the control electrode as described above, the first insulating film may have at least one of the film density, the dielectric constant, and the Young's modulus lower than that of the control electrode. As a result, the etching rate relationship described above can be obtained, and the through via holes and channels having the configurations described above can be formed.

In addition, as shown in the second and third modifications described above, the first insulating film may include a first film (the first lower insulating layer46dor the third lower insulating layer46f) and a second film (the second lower insulating layer46eor the fourth lower insulating layer46g) formed under the first film.

In this case, at least one of the etching rate of the first layer and the etching rate of the second layer may be higher than the etching rate of the second insulating film. According to such a configuration, the first layer or the second layer having an etching rate higher than the etching rate of the second insulating film is etched faster than the second insulating film. As a result, it is possible to form a field effect transistor having the configuration illustrated in the second or third modification, and it is possible to reduce the occurrence of poor connection between the upper electrode45and the lower electrode41and to reduce the decrease in on-current when the field effect transistor is turned on.

In addition, the following additional appendix will be disclosed with respect to the embodiments described above.

APPENDIX

A semiconductor device includinga semiconductor substrate,a first semiconductor element provided on the semiconductor substrate and having a channel including an element other than oxygen atoms,a first insulating film that insulates the first semiconductor element,a second semiconductor element provided above the first semiconductor element and spaced apart from the semiconductor substrate and having a channel including an element including oxygen atoms,a second insulating film that insulates the second semiconductor element,a fourth insulating film provided between the first insulating film and the second insulating film, anda third insulating film provided above the second semiconductor element and spaced apart from the semiconductor substrate, and having a film density less than at least one of the film densities of the first, second, and fourth insulating films.

The first and second embodiments, and the modifications of each embodiment are described above with reference to specific examples. However, the present disclosure is not limited to these specific examples. These specific examples with appropriate design changes by those skilled in the art are also provided in the scope of the present disclosure as long as they have the features of the present disclosure. Each element provided in each specific example described above and its arrangement, conditions, shape, and the like are not limited to those illustrated and can be changed as appropriate. The combinations of the elements in each of the specific examples described above can be appropriately changed as long as there is no technical contradiction.

For example, the configuration of the present disclosure is not limited to the semiconductor memory devices1and2according to the embodiments and modifications, and may be applied to semiconductor devices other than the memory devices.

In this case, the semiconductor device may be configured without the capacitor20.

The semiconductor memory devices1and2according to the embodiments may be semiconductor devices in which a plurality of capacitors20and field effect transistors40are formed in the stacking direction.