Controlling cleaning of a layer on a substrate using nozzles

Provided is a method for cleaning an ion implanted resist layer or a substrate after an ashing process. A duty cycle for turning on and turning off flows of a treatment liquid using two or more nozzles is generated. The substrate is exposed to the treatment liquid comprising a first treatment chemical, the first treatment chemical with a first film thickness, temperature, total flow rate, and first composition. A portion of a surface of the substrate is concurrently irradiated with UV light while controlling the selected plurality of cleaning operating variables in order to achieve the two or more cleaning objectives. The cleaning operating variables comprise two or more of the first temperature, first composition, first film thickness, UV wavelength, UV power, first process time, first rotation speed, duty cycle, and percentage of residue removal are optimized to achieve the two or more cleaning objectives.

FIELD

The present application generally relates to semiconductor processing and specifically to a cleaning process on a substrate using a first step of immersion in a first treatment chemical and concurrently irradiating the substrate with ultra-violet (UV) light and a second step using a wet clean process using a second treatment chemical.

RELATED ART

In semiconductor processing control of generation and lifetime of active chemical species is important to optimize cleaning processes with respect to removal efficiency of desired material, process time, and selectivity to other materials present on the substrate. In aqueous and plasma chemistry, generation of radicals is a convenient way to generate highly reactive and targeted species to remove material, Radicals are generated by mixing of two or more chemicals, (e.g. sulfuric add and hydrogen peroxide to form hydroxyl radicals) or by application of energy, for example, light, heat, electrical/magnetic force, electrochemical, or mechanical energy. Ion implanted photoresist is challenging to remove because a hard crust layer forms during the implant process on the photoresist. When a certain range of doses and energies are used to implant ions on the resist, these hard crust layers have to be removed using a plasma ashing step. There are two methods known to remove ion implanted resist at levels of 1e15atoms/cm2and higher. The first method is a two-step process using oxidizing/reducing plasma ash and a 120-140° C. sulfuric and peroxide mixture (SPM) wet process to remove residual organics. The challenge with this process is oxidization of the silicon substrate leading to loss of dopant in subsequent wet cleans. The second method is an all wet removal approach using SPM chemistry.

The challenge with all wet process removal or wet benches is that the SPM has to be heated to temperatures approaching 250° C. to achieve the desired resist removal performance and at a removal rate that is practical for manufacturing. Wet benches typically operate with SPM temperatures up to 140° C. To reach SPM temperatures of 250° C., one-pass single substrate process tools are required. However, over time, the SPM loses its activity as the sulfuric add is diluted by the continuous replenishment of hydrogen peroxide that is required to retain its cleaning activity. With SPM, the best cleaning performance is achieved above 100 wt % total acid in the SPM. SPM below 80 wt % total add has very poor cleaning performance and a fresh batch of 108-96 wt % sulfuric add is often used. Methods exist to remove the excess water from the recycled SPM or using electrolyzed sulfuric add to extend the usage life of the sulfuric add. Both methods significantly increase the complexity, capital cost, and operating costs of the resist strip process. Similar considerations are also applicable to cleaning of substrates after an ashing process.

Later approaches include cleaning techniques using a two-step process with hydrogen peroxide and ultra violet (UV) light followed by a wet stripping process. One such technique is U.S. Patent Publication No. 2012/0052687, by Ra haven, et al., (Raghaven), “Use of Catalyzed Hydrogen Peroxide (CHP) Chemical System for Stripping of Implanted State-of-the-Art UV Resists” filed on Dec. 29, 2010, where a catalyzed hydrogen peroxide solution is used with UV light to disrupt the crust of implanted photoresist and subsequently removing the underlying photoresist with a sulfuric add peroxide mixture (SPM) in a wet etch process. Effectiveness of this technique is limited by the specific ranges of concentration of the catalyzed hydrogen peroxide, temperature of the treatment liquids, and speed of rotation of the substrate.

Another technique is contained in U.S. application Ser. No. 13/670,381, by Brown, I J, “METHOD OF STRIPPING PHOTORESIST ON A SINGLE SUBSTRATE SYSTEM”, filed on Nov. 6, 2012 (Brown). Brown introduced operating variables consisting of UV wavelength, UV power, first rotation speed, first flow rate, second process time, second rotation speed, percentage of residue removal, and dispense temperature. The additional operating variables provide some flexibility to control the cleaning process, but some issues develop as the process is used in a manufacturing environment. Some of the issues include: a) rotation of bigger size substrates require new and stronger motors and associated housing, b) time constraints involved in starting up and stopping rotation of substrate increases with increasing size and speed, c) time needed to perform the softening of the residue is a function of at least two or more operating variables such as thickness of the first chemical film, rotation speed of the substrate, and exposure time to the UV light, concentration of the first chemical, and intensity of the UV light. The position of the nozzle relative to the substrate and flow rate of the first chemical also affects the cleaning of the substrate. In order to make single substrate cleaning of substrates economically feasible, these issues and operating challenges must be addressed when the cleaning process is implemented in production volume environment.

There is a need for a cleaning method and system that makes single substrate process to competitive in terms of cost of ownership and higher reliability in addition to expanding the process window for the stripping an ion implanted resist or cleaning or performing a post-ash cleaning. The key operating variables need to identified and ranges of the key operating variables need to be determined in order to develop a process sequence that addresses the issues and operating challenges and achieve the two or more cleaning objectives for a production single substrate cleaning method and system.

SUMMARY

Provided is a method for cleaning an ion implanted resist layer or a substrate after an ashing process. A duty cycle for turning on and turning off flows of a treatment liquid in two or more nozzles is generated. The substrate is exposed to the treatment liquid comprising a first treatment chemical, the first treatment chemical with a first film thickness, temperature, total flow rate, and first composition. A portion of a surface of the substrate is concurrently irradiated with UV light while controlling the selected plurality of cleaning operating variables in order to achieve the two or more cleaning objectives. The cleaning operating variables comprise two or more of the first temperature, first composition, first film thickness, UV wavelength, UV power, first process time, first rotation speed, duty cycle, and percentage of residue removal. The two or more cleaning operating variables are optimized to achieve the two or more cleaning objectives which can comprise (1) highest cleaning completion rate and (2) minimum film thickness of the treatment liquid.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

FIG. 1Adepicts an exemplary prior art architectural diagram100of the profile of a structure with a crust108fused to the surface, points124, of a structure104in the substrate128and profile of an adjoining structure116without crust fused to the surface, points120. The high dose ions112used in a previous process can cause development of the crust108that makes cleaning difficult. Formation of the crust108can be at the surface, points124, of structure104in substrate128or near the edge bead region (not shown) of the substrate128. Resist strip performance depends on the ion implant dose and energy. Effectiveness of a resist strip performance is correlated to the extent of removal percentage of the resist, speed of the process, and cost of ownership, which shall be discussed below.FIG. 1Bdepicts exemplary prior art graphs150of relative strip rate as a function of temperature of the resist compared to the temperature of the carbonized layer, such as the crust108inFIG. 1A. The relative strip rate graph154for the resist has a greater up-slope as the temperature goes from 100° C. to 350° C. ending at 1.00 relative strip rate compared to the relative strip rate graph158of the carbonized layer at less than 0.20 relative strip rate at 340° C. Furthermore, the energy used in stripping the resist was much less, Ea=0.17 ev, compared to the energy used in stripping the carbonized layer, Ea=2.60 ev, with the carbonized layer having a much lower relative strip rate.

FIG. 2depicts an exemplary prior art architectural diagram200of a single substrate implementation of the first step of a UV peroxide process for stripping an ion implant resist layer. A dispense nozzle208is used to dispense hydrogen peroxide solution212onto a rotating substrate220where the substrate220has an ion implant resist layer216and the substrate220was immersed in the hydrogen peroxide solution212. The UV lamp204directs the irradiation concurrently on the hydrogen peroxide solution212. The second step comprises the use of a sulfuric peroxide mixture (SPM) to further remove the rest of the resist layer216not removed in the first step. Current art cleaning techniques generally use 254 nm UV lamps, the hydrogen peroxide solution212at 1 to 30 wt % at 25 to 60° C., and the SPM with a ratio of 2:1 sulfuric acid to hydrogen peroxide. The highest resist strip performance for current art was obtained with 5 wt % hydrogen peroxide solution in the first step and total of 15 minutes to complete the first and second steps.

FIG. 3depicts an exemplary architectural diagram300of the two-step UV-peroxide (UVP) and sulfuric peroxide mixture (SPM) processes in an exemplary embodiment of the present invention. In Step 1 (first step), a substrate320having a resist layer is positioned in a processing chamber (not shown), the substrate rotating at a first rotation speed of 300 to 12,000 rpm, and is immersed in 10 wt % H2O2316, from one or more nozzles312. The immersed substrate320is concurrently irradiated with one or more UV lamps308where the UV light304generated is 254 nm. In Step 2 (second step), a nozzle338is used to dispense SPM334having a ratio of about 20:1 of sulfuric acid to hydrogen peroxide where the SPM334is dispensed onto the substrate320at about 150° C., and the substrate320is in a second rotation speed of from 300 to 1,000 rpm. The SPM334can optionally be recirculated with a recycle subsystem338where new hydrogen peroxide can be introduced to maintain a target ratio of the sulfuric acid to hydrogen peroxide, at point344.

FIG. 4Adepicts an exemplary top-view400of an area of a substrate prior to cleaning whileFIG. 4Bdepicts an exemplary side-view450of a portion of substrate prior to cleaning.FIG. 4Ashows the residue enclosed in the white dotted line404in between the lines and spaces of a grating for cleaning. InFIG. 4B, the side view shows a layer of substrate material466above the photoresist462and in another portion of the substrate a polymer film454is shown. In between the polymer film454and the layer of substrate material466and the resist462, residues are also visible in the enclosed area of the white dotted area458. The object of the cleaning system is to clean the substrate of residue and photoresist462.

FIG. 5Adepicts another exemplary top-view500of an area of a substrate before cleaning which shows the residue as a white line in the areas enclosed in the white dotted line whileFIG. 5Bis another exemplary top view550of a cleaned substrate which does not show any presence of residue. As mentioned above, the invention is configured to perform the two-step cleaning operation where the operating variables are concurrently optimized to identify the key operating variables and ranges of the key operating variables for a semiconductor application.

FIG. 6Adepicts another exemplary top-view600of an area of a substrate before cleaning whileFIG. 6Bis another exemplary top-view640of a partially cleaned substrate; andFIG. 6Cis yet another exemplary top-view680of a 100% cleaned substrate. InFIG. 6A, the residue can be seen as white, segmented lines604in a substrate608comprising lines and spaces of a structure on the substrate608prior to a cleaning process.FIG. 6Bdepicts substrate648with some leftover residue, such as inside the white dotted ovals, in the substrate after the first step of cleaning with a first chemical and concurrent exposure to UV light.FIG. 6Cdepicts an exemplary top view680of a substrate684after both the first step of cleaning with a first chemical and concurrent exposure to UV light and the second step of the cleaning process using a second chemical.

FIG. 7is an exemplary schematic700of the difference in absorbance of UV light as a function of the liquid film thickness of the treatment liquid, (H2O2) above the substrate724. The graph700shows a pictorial708of the absorbance of UV light by the treatment liquid, hydrogen peroxide (H2O2), at top of and at a lower base (BL) level closer to the bottom of the treatment liquid film near the surface of the substrate722. The absorbance of UV light by H2O2 is equal to:
A=ε|c
where ε molar absorptivity=f(λUV)(L/mol cm),

I=liquid film thickness (cm)=f(ω,Q,r), and

Minimizing, I,716, allows more UV light to reach the substrate surface726, The absorbance of UV light at the substrate surface726is equal to:
A=εIBLc

I=mass transport boundary layer thickness (cm)=f(ω,Q,r), and

The peroxide dispense708at about the center730of the substrate722rotating at a rotation speed, ω, expressed in rad/s; Q is the flow rate of the treatment liquid at L/min, λUVis the wavelength of UV source, r is the radial distance where the UV light is hitting the substrate surface726. As mentioned above, minimizing the liquid film thickness causes a higher intensity of UV energy712to reach the substrate surface726, generating more hydroxyl radicals, thus increasing the cleaning effect of the first step of cleaning to increase cleaning efficacy and to prepare the hardened crust of residues at the substrate surface726for the second step of cleaning with a second chemical.

FIG. 8is an exemplary graph800of the hydroxyl radical generation curve as a function of the concentration in weight percent of the hydrogen peroxide, H2O2. The graph816shows that the OH radical generation in atoms/cm2starts at a rate of 1.7 E+09 atoms/cm2at about 1 wt % H2O2, point804and rises to a maximum of 2.6+09 atoms/cm2, point808, at about 4.8% goes down to about 1.5 E+09 atoms/cm2at about 9.0 wt %, point812, and descends dose to a straight line onward toward the end of the scale at 20 wt %, point820. The desired concentration of hydroxyl radical atoms needs to be optimized in conjunction with the selected two or more cleaning variables for the cleaning process.

FIG. 9is an exemplary diagram900for a cleaning system902where the UV source904is located above a diffusion plate924, the diffusion plate924configured to block 185 nm wavelength light to irradiate the substrate932during the pre-treatment process and protect the UV source904and associated equipment during the subsequent wet clean process. The process gas912can comprise oxygen and/or nitrogen. Alternatively, the process gas can comprise oxygen and/or nitrogen and/or ozone. In another embodiment, fan filter unit (FFU) air or CDA920can be introduced into the process chamber916as the process gas during the pre-treatment process. During the wet clean process, the treatment liquid944is delivered into the process chamber916by delivery device936onto the substrate932, where the treatment liquid944and the process gas912or920are removed through exhaust units940,928. The system hardware for the substrate cleaning system is simplified because there is no requirement for an external oxygen or ozone containing oxygen gas feed into the UV chamber. Processing with standard air has demonstrated the ability to generate sufficient ozone and oxygen atoms for the pre-treatment process to work. Feeding oxygen or ozone carrying gas lines increases tool cost because of the associated hardware design safety requirements. The inventor found out that significantly shorter UV exposure times can be realized by the combined pre-treatment process using UV and a process gas followed by a wet clean process. Further, the inventor was also able to shorten the wet clean process time. Moreover, the generation of in-situ process gas also reduces the number of UV sources employed in the design of the substrate cleaning system. For example, all UV hardware inFIG. 9is contributing directly to the cleaning of the substrate, ultimately to the generation of atomic oxygen.

Referring toFIG. 9, an embodiment of the invention includes an indirect source of ozone generated either by vacuum UV (VUV) sources (<200 nm), corona discharge or UV source with wavelengths below 200 nm fed into the substrate processing chamber while under irradiation with 254 nm only radiation. The absorption of the radiation by the ozone initiates the formation of oxygen atoms at the substrate surface that enable the damage-free cleaning of substrates. Alternatively, in another embodiment, the substrate is irradiated with ozone emitting UV where an 185 nm absorbing filter is placed between the substrate with geometry that prevents direct and indirect illumination with 185 nm but allows a diffusion path for ozone to reach the substrate surface. Mass transport of the process gas can be enhanced by flowing the oxygen filled atmosphere through the <200 nm wavelength absorbing gas diffusion plate.

FIG. 10is an exemplary architectural diagram1000of a stack of dedicated spin chambers1012embodiment and an all-in-one spin chamber1022embodiment of the present invention. The dedicated spin chambers1012can be one or more stacks of UV-peroxide (UVP) chambers1008where the substrate (not shown) is loaded, immersed in the hydrogen peroxide solution and concurrently irradiated with one or more UV light devices for a first process time at a first rotation speed of the substrate. Other oxidizers in addition to hydrogen peroxide can also be used. The substrates (not shown) are unloaded from the UVP chambers1008and loaded onto the recycle SPM (rSPM) processing chamber1004where the resist is treated with SPM for a second process time at a second rotation speed of the substrate. In another embodiment, the all-in-one spin chambers1022can be one or more stacks of processing chambers each further comprising a UVP chamber1014and an rSPM chamber1018. In an embodiment, the UVP chamber1014and the rSPM chamber1018can be a single processing chamber having one of more nozzles for dispensing the hydrogen peroxide solution and/or the SPM. Alternatively, different nozzles can be used for dispensing the hydrogen peroxide solution and the SPM. In other embodiments, acids other than sulfuric acid and oxidizers other than hydrogen peroxide can also be used.

FIG. 11is an exemplary method flowchart1100of an embodiment of the present invention. In operation1104, a substrate is provided in a cleaning system comprising a processing chamber and a treatment liquid delivery system. The substrate cleaning may be a post-etch stripping of an ion implanted resist or cleaning or performing a post-etch cleaning. Moreover, the substrate cleaning process include means for performing a standard clean1(SC1), a standard clean2(SC2), water cleaning, or solvent cleaning and/or wherein the substrate cleaning process performed includes a treatment liquid comprising hydrofluoric acid (HF), diluted HF, or buffered HF; or the substrate cleaning process includes a treatment liquid comprising deionized water, isopropyl alcohol, deionized water and ozone, rinsing fluids, sulfuric acid peroxide mixture (SPM), sulfuric acid peroxide and ozone mixture (SOM), phosphoric acid, or phosphoric acid and steam mixture. In an embodiment, treatment liquid is a sulfuric acid peroxide mixture (SPM) or sulfuric acid peroxide and ozone mixture (SOM), the substrate cleaning process is photoresist stripping. All the above cleaning process chemistries are known to people in the art.

The flow rate of the SPM can be 2 liters per minute or less, the selected two or more dispense devices can comprise 5 nozzles, including a central nozzle and 4 additional nozzles, arranged in a line pattern, and the substrate can be from 200 to 450 mm. The selected two or more dispense devices can have varying sizes of dispense width. In one embodiment, the selected two or more dispense devices are positioned above the substrate according to a selected pattern, the selected pattern including a height from the substrate surface to the dispense device and distance between a central dispense device and each additional dispense device of the selected two or more dispense devices. In another embodiment, the selected two or more dispense devices can comprise a central nozzle and one or more additional nozzles located at selected distances from the central nozzle towards an edge of the substrate, the central nozzle configured with a flow rate lower than any of the one or more additional nozzles. The dispense width of a nozzle requires sufficient size to allow a continuous dispense of the treatment liquid at the selected flow rate of the dispense device when continuous flow is desired. In yet another embodiment, spray nozzles can also be used. Nitrogen or air can be mixed with the treatment liquid to use in a spray nozzle to spread out and thin the peroxide film across the substrate to increase generation of hydroxyl radicals.

For example, the first delivery device nozzles can be configured to support a treatment liquid flow rate in a range from 15 to 500 mL/min, 15 mL/min, or less than 15 mL/min. In still another embodiment, selection and placement, the selected two or more dispense devices comprising of nozzles can be connected to a single supply line and the duty cycle requires sequential turning on and turning off from a central nozzle towards a nozzle closest to the edge of the substrate and from the nozzle closest to the edge of the substrate towards the central nozzle. In yet another embodiment, each dispense device of the selected two or more dispense devices can be independently connected to a supply line and can be turned on and turned off independently; and/or wherein the selected two or more dispense devices are disposed in a line pattern, a cross pattern, a 3-ray star pattern configuration; and/or wherein the selected two or more dispense devices can be turned on and turned off independently.

In operation1108, two or more cleaning objectives are selected. The two or more cleaning objectives can comprise least two of: (1) target first process time, (2) target first rotation speed, (3) a target total process time, (4) target liquid film thickness of the first chemical, for example, the hydrogen peroxide in an SPM combination, and the like. The thinner film of the first chemical can provide improved performance because more UV is absorbed by the first chemical. In an UV-peroxide embodiment, two hydroxyl radicals are generated when UV is absorbed. The hydroxyl radicals react with the ion implanted crust and enable easier removal in the subsequent SPM step. In an embodiment, the cleaning objectives can be the target first rotation speed of 2000 rpm or less, 20 wt % hydrogen peroxide, and target first process time of 3 minutes or less.

In operation1112, two or more cleaning operating variables to be optimized for achieving the two or more cleaning objectives are selected. In operation1116, a surface of the substrate is exposed to the treatment liquid comprising a first treatment chemical, the first treatment chemical with a first film thickness, a first temperature, the first total flow rate, and a first composition, and concurrently irradiating a portion of a surface of the substrate with UV light, the UV light having a wavelength and having a UV power, the irradiating operationally configured to be completed in a first process time, the irradiating performed while the substrate is in a first rotation speed. Corresponding cleaning operating variables for the second step involving the second process chemical can also be selected. For example in one embodiment, the second process chemical can be SPM at 170° C., the second process time at 60 seconds or less, and a mixing ratio of 20 parts sulfuric acid to 1 part 25° C. hydrogen peroxide. In one embodiment, additives can be used to control the pH of the first chemical, for example, hydrogen peroxide, to extend or reduce the lifetime of the generated hydroxyl radical. For low pH, hydrochloric acid can be used but other acids such as hydrofluoric acid (HF) or nitric acid HNO3could be used. For high pH, tetramethyl ammonium hydroxide (TMAH) or ammonium hydroxide (NH4OH) can be used to increase the pH to 10 or higher.

In operation1120, the substrate is exposed to a second treatment liquid, the second treatment chemical having a second temperature, a second flow rate, a second composition, a second process time, and a second rotation speed. In operation1124, the selected plurality of cleaning operating variables are controlled in order to achieve the two or more cleaning objectives. In operation1128, the first and second treatment chemicals are optionally recycled so as to reduce treatment liquid usage. In operation1132, if the two or more cleaning objectives are not met, one or more of cleaning operating variables are adjusted in order to meet the two or more cleaning objectives.

FIG. 12is an exemplary flowchart1200of adjusting one or more treatment operating variables to meet the two or more objectives of the present invention. In operation1204, measurements are obtained for calculating a value of the two or more cleaning objectives. As will be discussed below, optical metrology devices, such as reflectometer or interferometer used to obtain a film thickness of the treatment liquid above a surface of the substrate and/or process metrology devices are used to obtain other measurements. In operation1208, the calculated value is obtained of the two or more cleaning objectives with the selected two or more cleaning objectives. In operation1212, if the two or more cleaning objectives are not met, the two or more cleaning operating variables are adjusted and operations1204to1212are iterated until the two or more cleaning objectives are met. The inventors found that increasing the speed of rotation of the substrate up to over 6,000 rpm significantly improved the cleaning performance with the subsequent wet cleaning step in an SPM application. As the rotation speed increases and the size of the substrates were increased, some operating issues materialized. As the rotation was reduced, the film thickness of the treatment liquid was kept low by using spray nozzles and/or use of pH additives. Cycling the on and off cycle and placement of the nozzles also provided improvements and can produce unwanted particles in the flow. Adjustment of the flow rates of the central and additional nozzles also provided incremental changes. The inventors concluded that concurrent optimization of selected cleaning operating variables is needed to identify the key operating variables and ranges of these key operating variables needed to be determined in order to develop a process sequence that is configured to achieve the two or more cleaning objectives selected for a semiconductor application.

FIG. 13is an exemplary architectural diagram1300of a cleaning system1304depicting use of a controller1390for optimizing the operating variables of the cleaning system1304towards meeting the one or more pre-treatment objectives. The controller1390includes storage and memory configured to store and access recipes for cleaning processes including photoresist stripping, post etch cleaning, film etching involving oxide, nitride or metal, particle removal, metal removal, organic material removal, or photoresist developing. In addition, the controller includes storage to store and access the two or more cleaning objectives, wherein the two or more cleaning objectives further include a process completion percentage and cost per unit throughput or a process completion percentage and cost of ownership per unit of throughput or a total cleaning time.

The controller1390can include computer capabilities a) to obtain metrology measurements and/or process measurements used to calculate a value for the selected one or more cleaning objectives, b) if the one or more cleaning objectives are not met, to adjust the process operating variables including adjusting the flow rate of the selected two or more dispense devices, rotation speed of the substrate, duty cycle of each of the selected two or more dispense devices until the one or more cleaning objectives are met. Moreover, the controller1390also contains logic circuitry or computer code to concurrently optimize a selected flow rate, dispense flow type, position of a dispense device, height of dispense, and duty cycle for turning on or turning off each of the selected two or more dispense devices, pattern used in positioning the selected two or more dispense devices, and rotation speed of the substrate. Operating data obtained from optimization tests are incorporated into procedures and recipes for combinations of substrate cleaning processes and cleaning operating variables are loaded into the controller1390. The cleaning system is configured to run in either online mode with metrology feedback or offline mode that does not require continuous metrology feedback, instead using the procedures and recipes.

The cleaning system1304can use two or more optical metrology devices1308. An optical emission spectroscopy (OES) device1370can be coupled to the processing chamber1310at a position to measure the optical emission from the processing region1315. In addition, another set of optical metrology devices1360can be disposed atop the processing chamber1310. Although four optical metrology devices are shown, many other alternative and different configurations of the optical metrology devices can be positioned to implement design objectives using a plurality of optical metrology devices. The four optical metrology devices can be spectroscopic reflectometric devices and/or interferometric devices. The measurements from the two or more optical metrology devices, for example, the OES device1370and the set of optical metrology devices1360, are transmitted to the metrology processor (not shown) where one or more critical dimension values are extracted. Measurements can be performed with the one or more optical metrology device OES1370and/or the set of optical metrology devices1360and one or more etch sensor devices,1364and1368.

As mentioned above, a process sensor device, for example, can be a residue sensor device1364measuring the percentage of residue remaining, or measuring a cleaning operating variable with a substantial correlation to percentage of residue removal, Another process sensor device can include a device measuring the partial pressure of oxygen or the oxygen and ozone partial pressures or the total pressure of the process gas. Selection of at least one or more process sensor devices can be done using multivariate analysis using sets of process data, metrology data (diffraction signals) and process performance data to identify these inter-relationships. The measurements from the two or more optical metrology devices, for example, the OES device1370and the set of optical metrology devices1360and the measurement from the sensor device1364and/or1368are transmitted to the metrology processor (not shown) where the operating variable values are extracted, Another process sensor device is a temperature measurement device that is used to the temperature of the treatment liquid along the radial line in order to determine the temperature gradient of the treatment liquid from the center to an edge of the substrate. The controller can compare the measured temperature gradient to the set temperature gradient for the application and adjust one or more of the cleaning operating variables to get the temperature to the accepts be range.

Still referring toFIG. 13, the cleaning system1304includes a controller1390coupled to sub-controllers in the two or more optical metrology measurement devices1309comprising a plurality of optical metrology devices1360, optical emission spectroscopy (OES) device1370, and one or more etch sensor devices,1364and1368. One or more chemical monitors1392can be coupled to the processing chamber to ensure the process gas is within the ranges set, Another sub-controller1394can be included in the motion control system1320that is coupled to the controller1390and can adjust the first and second speed of the rotation of the motion control system for a singe substrate tool. The motion control system1320is configured to handle substrates from 150 to 450 mm or greater than 150 mm. The controller1390can be connected to an intranet or via the Internet to other controllers in order to optimize the cleaning operating variables and in order to achieve the one or more pre-treatment objectives.

Although only certain embodiments of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the embodiments without materially departing from the novel teachings and advantages of this invention. For example, although one exemplary process flow is provided for cleaning of substrates, other process flows are contemplated. As also mentioned above, the cleaning method and system of the present invention can be used in an FEOL or BEOL fabrication cluster. Accordingly, all such modifications are intended to be included within the scope of this invention.