An X-ray microscope utilizing X-rays radiating from a laser-irradiated target so as to form an X-ray image of a specimen placed in a sample cell, the X-ray microscope includes a target for radiating X-rays when the same is irradiated with a laser beam, a sample cell for housing a specimen, the sample cell provided near the surface of target placed opposite to where the target is irradiated with the laser beam, and a detector for forming an X-ray image of the specimen by X-ray penetration, wherein the target, the sample cell and the detector are unified in a unit. The unit is placed at a place where the laser beam is irradiated to the target. A spacer is provided between the target and the sample cell, wherein the size of the spacer is determined depending on a distance between the specimen and the target. With this construction, this facilitates the fabrication of the unit. The unit is placed in the miniature vacuum chamber which comprises a division for housing the unit, and a space provided toward the target. And the vacuum chamber housing the unit is placed in an X-ray microscope.

FIELD OF THE INVENTION 
The present invention relates generally to an X-ray microscope, and more 
particularly to an X-ray microscope utilizing X-rays radiating from a 
laser-irradiated target. 
BACKGROUND OF THE INVENTION 
An X-ray microscope is known in the art which examines a specimen through 
an X-ray image obtained from X-rays radiating from a laser-irradiated 
target such as metal. 
There are at least two types of X-ray microscopes known in the art, which 
will be described with reference to FIGS. 8 and 9. One type is shown in 
FIG. 8, where X-rays are radiated from a target in a direction in which a 
laser beam is irradiated to the target, and the other is an embodiment 
where X-rays are radiated from a target in an opposite direction from 
where a laser beam is irradiated. 
More specifically, in the embodiment of FIG. 8, a specimen 81 is placed 
facing a source of a laser beam 83 with respect to a target 82, and X-rays 
84 radiated from the target 82 are irradiated on the specimen 81. The 
X-rays penetrating the specimen 81 are detected by a detector such as a 
photoresist layer formed on a substrate 86, and form an X-ray image 
through which the specimen 81 is examined. The specimen 81 is placed on 
the photoresist layer 85, and above the substrate 86 a window 87 is 
provided through which the X-rays pass the specimen 81 and on to the 
photoresist layer 85. In this way the substrate 86, the photoresist layer 
85, and the X-ray window 87 constitute a sample cell 88. 
In the embodiment shown in FIG. 9, the specimen 81 is also placed in a 
sample cell 88 having a similar structure as shown in FIG. 8 but the 
sample cell 88 is placed on an opposite side from where a target 91 is 
irradiated with the laser beam 83. With this arrangement, the part of the 
X-rays which penetrate the target 91 are irradiated to the specimen 81 and 
forms an X-ray image on the photoresist layer 85. 
In general, X-ray microscopes require that the wavelength of the X-ray is 
determined in accordance with the kind of the specimen and the purpose of 
a particular test. To this end, the specific material of the target is 
selected so as to obtain X-rays having a desired wavelength. Furthermore, 
as shown FIG. 9, in order to prevent X-rays from radiating from other 
substances than the target, such as an air, the target 91 and the sample 
cell 88 or the like are placed within a vacuum chamber 92. In addition, 
the X-ray microscope shown in FIG. 8 can be placed with the target 82 and 
the sample cell 88 or the like within a vacuum chamber (not shown). 
These X-ray microscopes described above have the following disadvantages: 
The X-ray microscope shown in FIG. 8 tend to emit inadequately intense 
X-rays to be irradiated to a specimen. This embodiment also requires that 
the sample cell 88 be located at such a distance from the target 82 as to 
stand in the optical path of the laser beam; for example, the sample cell 
88 must be placed at a distance of at least 1 cm from the target 82. In 
general, X-rays radiated from a spot of not greater than 100 .mu.m in 
diameter becomes less intense in reverse proportion to d.sup.2 (distance) 
when the laser beam is focused on the surface of the target. According to 
this general principle, the embodiment of FIG. 8 has difficulty in 
achieving sufficiently intense X-rays for examining a specimen. 
The X-ray microscope shown in FIG. 9 can obtain more intense X-rays than 
that of FIG. 8 because the specimen 81 is placed opposite to where the 
laser beam is irradiated to the target 91, and can therefore be located 
near the target 91. However, it is necessary to adjust the distance 
between the specimen 81 and the target 91 based upon the constituent 
substance of the target. The intensity of X-rays radiating from the target 
91 depends on the constituent substance of the target 91, which 
necessitates frequent adjustment of the distance between the target 91 and 
the specimen 81 in accordance with the intensity of X-rays radiated from 
the target 91, so as to irradiate to the specimen 81 with a required X-ray 
intensity of a disired wavelength. This adjustment is usually effected by 
changing the position of the specimen 81; more specifically, by adjusting 
the support of the sample cell 88 because the target 91 is previously 
placed at a focal point of the laser beam. 
The embodiments of FIGS. 8 and 9 requires that the target, the sample cell, 
and peripheral devices such as supporters and the driving device, are all 
placed in a relatively large vacuum vessel so as to prevent X-rays from 
radiating from other components than the target. This configuration 
requires enlarging the size of the X-ray microscope. 
SUMMARY OF THE INVENTION 
Accordingly, the present invention is intended to solve the problems 
pointed out about with known X-ray microscopes. It is an object of the 
present invention to provide an X-ray microscope allowing a specimen to be 
placed as near the target as possible so as to expose it to sufficiently 
intense X-rays, and to facilitate the efficient adjustment of a distance 
between the target and the specimen. 
Another object of the present invention is to provide an X-ray microscope 
of such a compact size as to eliminate the need to use a large vacuum 
chamber, thereby reducing the size of an X-ray microscope. 
In order to achieve these objects, according to the present invention there 
is provided an X-ray microscope utilizing X-rays radiating from a 
laser-irradiated target so as to form an X-ray image of a specimen placed 
in a sample cell. A target is provided for radiating X-rays when it is 
irradiated with a laser beam, and a sample cell is provided for housing a 
specimen therein. The sample cell is provided near the surface of the 
target placed opposite to where the target is irradiated with the laser 
beam, and a detector is provided for forming an X-ray image with the 
X-rays penetrating the specimen. The elements are unified in a unit. 
In a preferred embodiment, the unit includes a substrate, a photoresist 
layer formed on the substrate as the detector, a first space for housing 
the specimen, with the first space provided adjacent to the photoresist 
layer. An X-ray window is opposite the photoresist layer through the first 
space, and a second space is provided on the opposite side of the first 
space through the X-ray window. The target is positioned opposite the 
X-ray window with the second space being interposed therebetween. 
In a further preferred embodiment, the second space is airtight and filled 
with an excellent X-ray transmissible gas, such as He gas. 
In a still further preferred embodiment the second space is formed by 
providing a spacer between the target and the X-ray window, wherein the 
size of the spacer is determined depending on a desired distance between 
the specimen and the target. 
In another embodiment the second space is formed by providing a first 
spacer and a second spacer between the target and the X-ray window, 
wherein the size of the first spacer is determined depending on a distance 
between the specimen and the target, and the second spacer is formed 
integral with the X-ray window. 
In another embodiment, a miniature vacuum chamber is included which 
includes a division for housing the unit and a space provided toward the 
target, the miniature vacuum chamber housing the unit being placed at a 
place where the laser beam is irradiated to the target. 
In another embodiment the vacuum chamber housing the unit is placed in an 
X-ray microscope, such that the surface of the target is positioned at the 
focal point of the laser beam, thereby ensuring that the vacuum chamber 
for housing the unit is placed at a predetermined position in X-ray 
microscope. The specimen is then exposed to the X-rays radiating from the 
target. 
In yet another embodiment a movable framework is provided to enable a 
plurality units to be mounted and to shift each unit to a place where the 
target is irradiated with a laser beam, thereby ensuring that a plurality 
of specimens are continuously exposed to X-rays and examined for a 
relatively short period of time. 
According to the present invention, the target, the sample cell and the 
detector are unified or integrated into an appropriate configuration for 
being housed in an X-ray microscope. The target is selected in accordance 
with the constituent substance of the specimen so as to emit X-rays having 
a wavelength suited to the nature of the specimen and the purpose of 
observation. The laser beam is irradiated to the target with the specimen 
housed within the sample cell. The X-rays radiated from the bottom surface 
of the target penetrates the specimen and the penetrated X-rays are 
detected by the detector. 
Under the arrangement of the present invention, the specimen is placed in 
an opposite direction to that in which a laser beam is irradiated to the 
target. This ensures that the specimen is exposed to intense X-rays, as in 
the arrangement shown in FIG. 9. In addition, once a suitable unit is 
selected, the specimen is placed at a fixed position from the target, so 
that it is not necessary to adjust the distance between the specimen and 
the target within the X-ray microscope. 
The distance between the specimen and the target is selected by determining 
the size of the spacer inserted between the target and the X-ray window. 
Since the unit is placed in the miniature vacuum chamber which comprises a 
housing division for housing the unit, and a space provided toward the 
target, the specimen is prevented from being exposed to X-rays radiated 
from any other impure substances than the target. In general, an area 
which X-rays can be radiated from other substances (such as an air) than 
the target in the case where the laser beam is focused on the target is 
the vicinity of the focal point of laser beam; more specifically the 
vicinity of the target surface irradiated with laser beam. Therefore, the 
vacuum chamber of the present invention is provided with a sufficient 
capacity for accommodating the unit and for allowing a space adjacent 
thereto to be provided toward the target, so that the specimen is 
protected from exposure to X-rays radiation from any substances other than 
the target.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 
Referring to FIGS. 1 and 2, a first embodiment of the X-ray microscope of 
the present invention will be described. 
FIG. 1 is a partial sectional view showing a unit in which a target 17, a 
sample cell 20 and a detector 12 are integrated in a unit 1, and FIG. 2 is 
a vertical cross-section showing the unit 1. 
In addition to the target 17, the unit 1 includes a substrate 11, a 
photoresist layer (detector) 12 formed on the surface of the substrate 11, 
a first spacer 13 provided on the photoresist layer 12, and an X-ray 
window 14 placed on the first spacer 13. A second spacer 15 is placed on 
the X-ray window 14, and a third spacer 16 placed on the second spacer 15. 
The first spacer 13 maintains a first space 18 between the photoresist 
layer 12 and the X-ray window 14. A specimen 19 is placed in the first 
space 18. The substrate 11 and the first space 18 therefore constitute a 
sample cell 20 for housing the specimen 19, and the X-ray window 14 
functions as a cover closing the open end of the sample cell 20. The first 
space 18 may be maintained at an atmospheric pressure, and before the 
specimen 19 is placed in the space 18, the unit 1 is divided into two 
parts from the border between the first spacer 13 and the X-ray window 14. 
These two parts include a sample cell 20 and a target 21 including the 
window 14, the spacers 15, 16, and the target 17. 
The specimen 19 is placed on the photoresist layer 12 before the unit 1 is 
assembled. Then the first spacer 13 and the X-ray window 14 are joined 
into an entity as shown in FIG. 1. Finally, the assembled unit 1 is placed 
in an X-ray microscope. 
The second spacer 15 and the third spacer 16 define a second space 22 
between the X-ray window 14 and the target 17, and the second space 22 is 
sealed airtight against the atmosphere with an X-ray transmissible gas, 
such as He gas, confined at a pressure of a few Torrs. The X-ray 
transmissible gas disperses fine particles (debris) occurring when a laser 
beam 40 is irradiated to the target 17, thereby preventing the fine 
particles from adhering to the X-ray window 14 and the specimen 19. 
The substrate 11 is preferably made of silicon to a thickness of 0.5 mm or 
so, and the photoresist layer 12 formed thereon is made of a material, 
such as PMMA, which permits recording of an X-ray image. The first spacer 
13 can be made of metal such as aluminum or stainless steel to a thickness 
of 5 .mu.m to 50 .mu.m. 
The X-ray window 14, designed to select a wavelength of X-ray which is 
irradiated to the specimen 19 or to prevent debris scattering from the 
target 17 from adhering to the specimen 19, can be made of SiN or 
polyimide resin film or the like. The X-ray window 14 can be made in one 
piece with the second spacer 15 as shown in dotted lines in FIG. 1; more 
specifically, the substrate of Si is doped with nitrogen to form an SiN 
layer on one side thereof and the other side is etched. The second spacer 
15 can be as thick as approximately 0.5 mm, to minimize the impact of 
debris upon the X-ray window 14 by providing a space between the target 17 
and the X-ray window 14. 
The thickness of the third spacer 16 is selected in accordance with the 
constituent substance of the target 17, so that the distance between the 
target 17 and the specimen 19 can be adjusted depending upon the kind of 
the target 17 such as metal or any other material. The thickness is 
selected to be in a range of 1 to 2 mm. 
The target 17 is made of a material which can emit X-rays in response to 
the laser beam irradiated thereto, and the target is selected in 
accordance with the wavelength of X-ray that is suitable for the specimen 
19. The constituent substance can be selected from metal or plastic such 
as Al, Au, Mo, Ta or "Kapton" (trademark), and the thickness of it can 
fall in a range of 1 .mu.m to 100 .mu.m. 
The unit 1 is placed in a vacuum chamber 30 as shown in FIG. 3, and then 
the vacuum chamber 30 is placed at a position in an X-ray microscope where 
the laser beam 40 is irradiated to the target 17. 
The vacuum chamber 30 is box-shaped, and has a body 31 made of metal such 
as Al and stainless steel, and a transparent laser transmissible lid 32 
closing the open end of the body 31. The internal space of the chamber 30 
includes a main space 33 for housing the unit 1 and a subordinate space 34 
between the main space 33 and the transparent lid 32, and the inside of 
the vacuum chamber 30 is evacuated. The unit 1 is placed in the vacuum 
chamber 30 with the target 17 facing the transparent lid 32. In this state 
the subordinate space 34 adjacent to the target 17 is evacuated, the 
target 17 is irradiated with a laser beam 40. 
According to the embodiment shown in FIG. 4, the laser beam 40 can be 
focused on the surface of the target 17 by placing the vacuum chamber 30 
housing the unit 1 at a predetermined position by considering a relative 
relationship among the optical system 41 for focusing the laser beam 40, 
the dimension of the vacuum chamber 30, and the position thereof. 
The unit 1 can be miniaturized to such an extent that its side dimension is 
10 to 20 mm, and the vacuum chamber 30 is sized to such an extent that the 
main space 33 of the vacuum chamber 30 can house the unit 1 and the 
subordinate space 34 is smaller than the main space 33. 
Referring to FIGS. 5A-1 to 5C, a typical manner of fabricating the unit 1 
and a process of exposing a specimen to X-rays will be described, such 
that the sample cell 20 and the target 21 are separately fabricated. 
More specifically, as shown in FIG. 5A-1, the Si substrate 51 is doped with 
nitrogen on one side to form an SiN layer, and is etched on the other 
side. In this way the X-ray window 14 of the SiN layer and the second 
spacer 15 on the periphery thereof are formed as one piece. Then, as shown 
in FIGS. 5A-2 and 5A-3, the third spacer 16 is formed on the second spacer 
5 and the target 17 is joined to the third spacer 16. In this way the 
target division 21 including an airtight space 22 is fabricated. Because 
of the possibility of selecting the wavelength of X-ray to be irradiated 
to the specimen in accordance with the kind of the specimen and the object 
of the observation, several kinds of targets 17 are prepared so as to meet 
required wavelengths. The strength of X-rays irradiated and the quantity 
of fine particles dispersed from the target 17 toward the X-ray window 14 
differ depending upon the kind of the material of the target 17. The 
thickness of the third spacer 16 can therefore be determined in accordance 
with the kind of the target 17. As a result, it is possible to equalize 
the conditions of the X-rays irradiated to the specimen 19 and the 
influence of the fine particles. When the target division 21 is 
fabricated, the second space 22 is filled with He gas, etc. at a pressure 
of a few Torrs. 
As shown in FIG. 5B-1, the specimen division 20 is fabricated by applying a 
photoresist such as PMMA to the surface of the Si substrate 11 to form a 
photoresist layer 12, and by joining the second spacer 13 to the 
photoresist layer 12. 
The specimen 19 is placed on the photoresist layer 12 as shown in FIG. 
5B-2. Then the target division 21, which has one of the targets 17 
selected depending upon the constituent substance of specimen 19, is 
placed on the specimen division 20 as shown FIG. 5C and the first spacer 
13 is finally joined to the X-ray window 14. In this way the unit 1 is 
assembled. The joint is effected by use of cyanoacrylate-based adhesive. 
Then, the unit 1 is placed in the vacuum chamber 30 as shown in FIG. 3, and 
the vacuum chamber 30 is evacuated to a pressure of approximately 
10.sup.-3 Torrs, and the vacuum chamber 30 is disposed at a predetermined 
position within an X-ray microscope (not shown) as shown in FIG. 4. 
As is evident from FIG. 4, the surface of the target 17 is positioned at 
the focal point of the laser beam 40 in the X-ray microscope, so that the 
target 17 irradiated with the laser beam 40 immediately radiates X-rays 
and debris. The X-rays are radiated toward both the vacuum window 32 and 
the second space 22 in the unit 1. Portion 50 of the X-rays toward the 
second space 22 is irradiated to the specimen 19 on the photoresist layer 
12 through the X-ray window 14. 
The surface of the laser-irradiated target 17 faces the evacuated 
subordinate space 34, and the second space 22 in the unit 1 is filled with 
X-rays transmissible gas such as He gas, thereby ensuring that there can 
be no other impure substance likely to radiate X-rays than the target 17. 
Thus the specimen 19 is not exposed to any other than the X-rays 50 
radiating from the target 17. 
The debris or fine particles coming out from the target 17 together with 
the X-rays are dispersed in the He gas in the second space 22, so that 
they are prevented from adhering to the X-ray window 14 and other walls. 
In this manner, the specimen 19 is exposed to the X-rays, and then the unit 
1 is taken out of the vacuum chamber 30, and the substrate 11 formed a 
photoresist layer 12 is separated from the unit 1. An X-ray image on the 
photoresist layer 12 is observed by means of an AFM or an electronic 
microscope. 
Whatever constituent substance a specimen may have, it can be observed by 
the same procedure by selecting a target division selected according to 
the constituent substance, and joining it to the sample cell 20 to 
assemble the unit 1 which is then placed in the vacuum chamber 30 to 
effect the exposure of the specimen. 
As is evident from the foregoing description, the unit 1 is replaced 
depending upon the constituent substance of the specimen. The vacuum 
chamber 30 can be repeatedly used until it deteriorates. 
A specimen is first placed in the sample cell 20, and the target division 
21 holding a target selected according to the constituent substance of the 
specimen is joined to the sample cell 20 to assemble the unit 1 which is 
then placed in the vacuum chamber 30. After the vacuum chamber 30 is 
evacuated, it is placed at a predetermined position in an X-ray 
microscope. Then, the specimen is exposed to the X-rays radiating from the 
target. The vacuum chamber 30 only needs to be slightly larger than the 
unit 1, so that the entire size of the X-ray microscope can be 
considerably reduced. 
The shape of the unit 1 is not limited to a rectangular solid one but can 
be various such as a cylindrical shape as a whole as shown in FIG. 6. In 
this case the shape of the vacuum chamber preferably corresponds to that 
of the unit 1. 
Referring to FIG. 7, another embodiment will be described: 
This embodiment is characterized in that it includes a movable framework 70 
on which a plurality of units 1 having the same shape and size are 
mounted. Each unit 1 includes a target, a sample cell and a detector, and 
the plurality of units are closely arranged in matrix on the framework 70. 
The framework 70 is movable along the X- and Y-axis so that each unit 1 is 
successively shifted to a place where the laser beam 40 is irradiated. 
Each unit 1 is fabricated in the same manner as described above, in which 
the target is selected in accordance with the constituent substance of the 
specimen to be examined. The thickness of the third spacer in the unit 1 
is varied in accordance with the constituent substance of the target, 
thereby differentiating the heights of the units. In order to make up for 
differences in the heights of the units, appropriate spacers are inserted 
between the bottoms of the units 1 and the framework 70 so that the top 
surfaces of the targets correspond to the respective focal points of the 
laser beam 40. 
In the embodiment shown in FIG. 7, the vacuum chamber may have a size which 
can cover the top surface of the framework 70. Alternatively, each unit 1 
may be contained in a vacuum chamber 30 which is identical in structure to 
that shown in FIG. 3, and the vacuum chambers 30 may be mounted on the 
movable framework 70. 
The movable framework 70 is effective to obtain X-ray images of a plurality 
of specimens.