{"categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "images": [{"id": 0, "width": 1352, "height": 1112, "file_name": "jacs.5b05415-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [193.4, 728.31, 53.65, 40.74], "category_id": 3}, {"id": 1, "bbox": [85.79, 587.69, 234.44, 128.27], "category_id": 1}, {"id": 2, "bbox": [1090.17, 45.32, 234.45, 171.31], "category_id": 1}, {"id": 3, "bbox": [863.47, 46.76, 171.31, 158.4], "category_id": 1}, {"id": 4, "bbox": [641.07, 61.11, 187.09, 149.78], "category_id": 1}, {"id": 5, "bbox": [22.65, 82.63, 234.45, 128.26], "category_id": 1}, {"id": 6, "bbox": [981.12, 998.06, 55.09, 42.14], "category_id": 3}, {"id": 7, "bbox": [174.75, 980.84, 53.65, 42.17], "category_id": 3}, {"id": 8, "bbox": [1174.83, 223.24, 53.65, 42.18], "category_id": 3}, {"id": 9, "bbox": [950.99, 223.24, 56.53, 42.18], "category_id": 3}, {"id": 10, "bbox": [744.38, 227.55, 52.22, 42.17], "category_id": 3}, {"id": 11, "bbox": [131.7, 213.2, 50.78, 40.74], "category_id": 3}, {"id": 12, "bbox": [877.82, 824.44, 233.01, 172.75], "category_id": 1}, {"id": 13, "bbox": [68.57, 844.53, 231.57, 129.7], "category_id": 1}, {"id": 14, "bbox": [877.82, 563.3, 255.96, 179.92], "category_id": 1}, {"id": 15, "bbox": [981.12, 738.35, 55.09, 40.74], "category_id": 3}], "reactions": [{"reactants": [13], "conditions": [8, 7], "products": [12, 11, 10]}, {"reactants": [9], "conditions": [6, 5], "products": [23]}, {"reactants": [22], "conditions": [4, 3], "products": [21]}], "corefs": [[5, 11], [4, 10], [3, 9], [2, 8], [1, 0], [14, 15], [13, 7], [12, 6]], "caption": "Figure 2. Fe/O2 as compatible conditions with gold catalysis.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 570, 375, 585], "ImageBB": [82, 283, 420, 561]}, "diagram_type": "multiple"}, {"id": 1, "width": 1312, "height": 1020, "file_name": "ja9535975-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [815.94, 8.49, 421.84, 140.19], "category_id": 1}, {"id": 1, "bbox": [92.06, 4.54, 299.45, 144.14], "category_id": 1}, {"id": 2, "bbox": [1021.25, 170.37, 44.12, 37.54], "category_id": 3}, {"id": 3, "bbox": [289.48, 171.69, 42.8, 37.54], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [2, 0], "products": [1]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Comparison of Reaction Conditions for the Photopromoted Pauson-Khand Reaction ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 70, 693, 95], "ImageBB": [434, 100, 762, 355]}, "diagram_type": "single"}, {"id": 2, "width": 1352, "height": 1080, "file_name": "ja905415r-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [990.35, 31.45, 279.31, 258.41], "category_id": 1}, {"id": 1, "bbox": [710.24, 4.97, 254.23, 291.86], "category_id": 1}, {"id": 2, "bbox": [76.18, 59.32, 336.45, 234.72], "category_id": 1}, {"id": 3, "bbox": [1178.47, 265.56, 56.35, 42.41], "category_id": 3}, {"id": 4, "bbox": [306.11, 266.96, 54.96, 41.01], "category_id": 3}, {"id": 5, "bbox": [863.53, 271.14, 53.56, 42.41], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 7], "products": [2, 1]}], "corefs": [[2, 4], [1, 5], [0, 3]], "caption": "Table 5. Comparison of the enantioselectivities of 2a and 3a, isolated from the reaction of 1a using different Au catalysts.a ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 365, 81], "ImageBB": [58, 89, 396, 359]}, "diagram_type": "single"}, {"id": 3, "width": 1352, "height": 1096, "file_name": "ja905415r-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.3, 6.42, 304.6, 238.17], "category_id": 1}, {"id": 1, "bbox": [201.72, 286.43, 405.04, 188.67], "category_id": 3}, {"id": 2, "bbox": [884.77, 3.59, 260.8, 255.14], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [5, 2], "products": [6]}], "corefs": [[0, 1]], "caption": "Table 4. Enantioselective Au(I)-Catalyzed Allenediene [4C+2C] Cycloadditions with (S,S,S)-I and (R,R,R)-Ka ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 376, 81], "ImageBB": [58, 90, 396, 364]}, "diagram_type": "single"}, {"id": 4, "width": 1348, "height": 1132, "file_name": "ja9039289-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [743.53, 253.63, 35.59, 42.9], "category_id": 3}, {"id": 1, "bbox": [636.9, 142.62, 254.69, 108.63], "category_id": 1}, {"id": 2, "bbox": [21.97, 139.7, 206.49, 107.16], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [9, 4], "products": [5, 6, 0]}], "corefs": [[1, 0]], "caption": "Table 3. Fluoride Effect on Ni- and Co-Catalyzed Biaryl Cross-Coupling in the Presence of Phosphine Ligands ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 57, 703, 81], "ImageBB": [425, 89, 762, 372]}, "diagram_type": "single"}, {"id": 5, "width": 1348, "height": 408, "file_name": "ja407179c-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1056.81, 267.38, 91.53, 35.57], "category_id": 3}, {"id": 1, "bbox": [966.43, 46.16, 336.85, 209.45], "category_id": 1}, {"id": 2, "bbox": [235.62, 84.03, 303.28, 110.46], "category_id": 1}, {"id": 3, "bbox": [44.52, 4.84, 150.92, 249.05], "category_id": 1}, {"id": 4, "bbox": [68.63, 267.38, 41.59, 33.85], "category_id": 3}], "reactions": [{"reactants": [7, 6], "conditions": [3, 2], "products": [5]}], "corefs": [[3, 4], [1, 0]], "caption": "Table 2. Dynamic Kinetic Resolution in the Au(I)-Catalyzed Vinylogous [3 + 2] Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 419, 233]}, "diagram_type": "single"}, {"id": 6, "width": 2820, "height": 1784, "file_name": "ja406383h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1346.2, 183.12, 30.46, 33.08], "category_id": 3}, {"id": 1, "bbox": [562.19, 205.12, 88.68, 38.22], "category_id": 3}, {"id": 2, "bbox": [1525.21, 185.35, 27.08, 30.84], "category_id": 3}, {"id": 3, "bbox": [1719.53, 185.1, 27.08, 31.34], "category_id": 3}, {"id": 4, "bbox": [1931.91, 185.35, 25.82, 31.09], "category_id": 3}, {"id": 5, "bbox": [2080.59, 177.33, 200.34, 37.6], "category_id": 3}, {"id": 6, "bbox": [2320.16, 176.7, 230.6, 38.55], "category_id": 3}, {"id": 7, "bbox": [272.39, 207.71, 44.7, 35.63], "category_id": 3}, {"id": 8, "bbox": [2348.38, 35.45, 110.76, 114.22], "category_id": 1}, {"id": 9, "bbox": [2111.38, 35.02, 132.85, 114.21], "category_id": 1}, {"id": 10, "bbox": [1643.02, 28.95, 159.71, 122.88], "category_id": 1}, {"id": 11, "bbox": [1860.52, 53.21, 151.48, 98.62], "category_id": 1}, {"id": 12, "bbox": [1461.48, 33.72, 144.54, 130.68], "category_id": 1}, {"id": 13, "bbox": [1297.7, 87.44, 115.52, 34.93], "category_id": 1}, {"id": 14, "bbox": [957.15, 4.69, 261.96, 227.3], "category_id": 1}, {"id": 15, "bbox": [546.84, 70.54, 112.92, 102.96], "category_id": 1}, {"id": 16, "bbox": [232.14, 7.02, 261.33, 180.85], "category_id": 1}], "reactions": [{"reactants": [18, 17], "conditions": [9, 8], "products": [16]}], "corefs": [[16, 7], [15, 1], [13, 0], [12, 2], [10, 3], [11, 4], [9, 5], [8, 6]], "caption": "Table 1. Optimization of Direct C\u2212H Amidation of Benzamidea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 446, 110], "ImageBB": [82, 116, 787, 562]}, "diagram_type": "single"}, {"id": 7, "width": 1352, "height": 428, "file_name": "ja3066978-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [829.38, 21.2, 204.02, 163.45], "category_id": 1}, {"id": 1, "bbox": [1079.75, 26.38, 204.02, 132.37], "category_id": 1}, {"id": 2, "bbox": [466.77, 5.66, 284.32, 178.12], "category_id": 1}, {"id": 3, "bbox": [1210.98, 203.37, 27.9, 34.8], "category_id": 3}, {"id": 4, "bbox": [60.14, 12.57, 285.17, 146.18], "category_id": 1}, {"id": 5, "bbox": [229.35, 203.37, 22.72, 35.67], "category_id": 3}, {"id": 6, "bbox": [640.31, 200.78, 27.9, 35.67], "category_id": 3}, {"id": 7, "bbox": [964.06, 210.27, 25.31, 34.81], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [], "products": [2, 0, 1]}], "corefs": [[4, 5], [2, 6], [0, 7], [1, 3]], "caption": "Table 1. Hydrogenation of 6-Chloroquinoline to 6-Chloro- 1,2,3,4-tetrahydroquinoline under Various Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 782, 125], "ImageBB": [449, 131, 787, 238]}, "diagram_type": "single"}, {"id": 8, "width": 1764, "height": 2364, "file_name": "ja2070522-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [977.96, 586.23, 424.88, 437.73], "category_id": 1}, {"id": 1, "bbox": [207.93, 583.37, 404.87, 440.63], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [2]}], "corefs": [], "caption": "Figure 1. Knoevenagel condensation using benzaldehyde with active methylene compounds. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 503, 784, 531], "ImageBB": [418, 536, 859, 1127]}, "diagram_type": "single"}, {"id": 9, "width": 1412, "height": 2660, "file_name": "ja075824w-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1026.15, 119.39, 289.47, 299.87], "category_id": 1}, {"id": 1, "bbox": [28.65, 119.4, 220.2, 299.86], "category_id": 1}], "reactions": [{"reactants": [2, 0], "conditions": [4, 3], "products": [1]}], "corefs": [], "caption": "Figure 3. Effect of auxiliary base on the DMAP-catalyzed acetylation, isobutyrylation, and pivaloylation of l-menthol with acid anhydride. The reaction of l-menthol (5 mmol) was conducted with (RCO)2O (5.5 mmol) under solvent-free conditions or in heptane (5 mL): red squares, 1 (0.1 mol %) and i-Pr2NEt (1.1 equiv); green circles, 1 (0.1 mol %) without i-Pr2- NEt; blue triangles, i-Pr2NEt (1.1 equiv) without 1. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 704, 409, 779], "ImageBB": [74, 35, 427, 700]}, "diagram_type": "single"}, {"id": 10, "width": 1348, "height": 1920, "file_name": "ja053650h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [951.35, 63.27, 339.46, 218.43], "category_id": 1}, {"id": 1, "bbox": [57.68, 7.41, 316.18, 220.76], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 3], "products": [1]}], "corefs": [], "caption": "Table 2. Intramolecular Carbonylation of 2-(2-Iodophenoxy)aniline (3, R1 ) R2 ) H, X ) I) with Different Palladium-Complexed Dendrimersa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 772, 100], "ImageBB": [439, 102, 776, 582]}, "diagram_type": "single"}, {"id": 11, "width": 1328, "height": 1268, "file_name": "op9802071-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [584.0, 84.0, 339.0, 208.0], "category_id": 1}, {"id": 1, "bbox": [1125.0, 337.0, 86.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [716.0, 328.0, 80.0, 62.0], "category_id": 3}, {"id": 3, "bbox": [719.0, 703.0, 81.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [705.0, 891.0, 415.0, 235.0], "category_id": 1}, {"id": 5, "bbox": [828.0, 1154.0, 261.0, 114.0], "category_id": 3}, {"id": 6, "bbox": [1003.1, 79.3, 321.6, 220.0], "category_id": 1}, {"id": 7, "bbox": [1125.0, 711.0, 93.4, 56.8], "category_id": 3}, {"id": 8, "bbox": [999.8, 457.0, 326.2, 222.7], "category_id": 1}, {"id": 9, "bbox": [584.0, 454.2, 337.4, 211.8], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [4], "products": [0, 8, 13, 12]}, {"reactants": [9], "conditions": [11], "products": [6]}], "corefs": [[0, 2], [6, 1], [9, 3], [8, 7], [4, 5]], "caption": "Table 1. Reduction of 3 with borohydrides", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 382, 310, 396], "ImageBB": [74, 52, 406, 369]}, "diagram_type": "multiple"}, {"id": 12, "width": 1000, "height": 1388, "file_name": "op900008a-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 973.0, 226.0, 152.0], "category_id": 1}, {"id": 1, "bbox": [531.0, 742.0, 428.0, 118.0], "category_id": 1}, {"id": 2, "bbox": [516.0, 1350.0, 43.0, 30.0], "category_id": 3}, {"id": 3, "bbox": [0.0, 731.0, 322.0, 122.8], "category_id": 1}, {"id": 4, "bbox": [117.0, 1100.0, 44.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [688.0, 975.0, 304.0, 149.0], "category_id": 1}, {"id": 6, "bbox": [512.0, 1109.0, 43.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [321.0, 1214.0, 311.0, 150.0], "category_id": 1}, {"id": 8, "bbox": [0.0, 0.0, 995.0, 530.0], "category_id": 1}, {"id": 9, "bbox": [322.0, 968.0, 304.0, 155.3], "category_id": 1}, {"id": 10, "bbox": [798.0, 240.0, 33.0, 35.0], "category_id": 3}, {"id": 11, "bbox": [875.0, 1099.0, 40.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2], "products": [4]}, {"reactants": [4], "conditions": [10], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [14]}, {"reactants": [3], "conditions": [1], "products": [14]}, {"reactants": [9], "conditions": [6], "products": [12]}], "corefs": [[8, 10], [0, 4], [9, 6], [5, 11], [7, 2]], "caption": "Figure 2", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 183, 109, 197], "ImageBB": [108, 47, 358, 394]}, "diagram_type": "tree"}, {"id": 13, "width": 1352, "height": 536, "file_name": "op8002097-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 481.0, 57.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [1148.0, 79.0, 199.0, 406.0], "category_id": 1}, {"id": 2, "bbox": [430.0, 102.0, 200.0, 390.0], "category_id": 1}, {"id": 3, "bbox": [909.0, 91.0, 203.0, 390.0], "category_id": 1}, {"id": 4, "bbox": [9.0, 91.2, 201.0, 412.8], "category_id": 1}, {"id": 5, "bbox": [431.0, 494.0, 40.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [3, 0], "products": [6, 2]}], "corefs": [[4, 0], [2, 5]], "caption": "Table 2. Results of enzymatic screening for ester formation (organic media) ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 191, 386, 218], "ImageBB": [58, 45, 396, 179]}, "diagram_type": "single"}, {"id": 14, "width": 1196, "height": 404, "file_name": "op7001886-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.1, 336.0, 279.4, 65.2], "category_id": 3}, {"id": 1, "bbox": [1019.0, 341.0, 55.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [914.0, 0.0, 279.0, 330.0], "category_id": 1}, {"id": 3, "bbox": [665.5, 64.9, 228.7, 194.7], "category_id": 1}, {"id": 4, "bbox": [7.0, 65.1, 501.0, 291.9], "category_id": 1}, {"id": 5, "bbox": [726.0, 336.0, 44.2, 60.8], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [], "products": [3, 2]}], "corefs": [[4, 0], [3, 5], [2, 1]], "caption": "Figure 2", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 541, 476, 555], "ImageBB": [444, 437, 743, 538]}, "diagram_type": "single"}, {"id": 15, "width": 2816, "height": 1412, "file_name": "op700160a-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [861.0, 1329.0, 56.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [1388.0, 1326.0, 59.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [610.0, 266.0, 44.0, 53.0], "category_id": 3}, {"id": 3, "bbox": [953.0, 263.0, 44.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [352.0, 1320.0, 47.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [2333.99, 1088.73, 317.41, 238.67], "category_id": 1}, {"id": 6, "bbox": [1791.2, 0.0, 196.4, 254.5], "category_id": 1}, {"id": 7, "bbox": [2052.2, 2.0, 190.2, 255.0], "category_id": 1}, {"id": 8, "bbox": [656.7, 1051.0, 430.3, 278.0], "category_id": 1}, {"id": 9, "bbox": [157.7, 1051.0, 428.3, 279.8], "category_id": 1}, {"id": 10, "bbox": [1832.0, 260.0, 100.4, 59.4], "category_id": 3}, {"id": 11, "bbox": [2076.63, 263.0, 95.0, 53.0], "category_id": 3}, {"id": 12, "bbox": [573.9, 71.4, 120.4, 138.2], "category_id": 1}, {"id": 13, "bbox": [2480.37, 1327.25, 44.0, 47.0], "category_id": 3}, {"id": 14, "bbox": [1960.75, 1325.63, 59.0, 50.0], "category_id": 3}, {"id": 15, "bbox": [1699.74, 1054.75, 566.86, 278.25], "category_id": 1}, {"id": 16, "bbox": [816.5, 56.6, 314.1, 171.9], "category_id": 1}, {"id": 17, "bbox": [1157.74, 1052.26, 485.66, 305.24], "category_id": 1}], "reactions": [{"reactants": [16, 20], "conditions": [4, 13], "products": [9, 10]}], "corefs": [[12, 2], [16, 3], [6, 10], [7, 11], [9, 4], [8, 0], [17, 1], [15, 14], [5, 13]], "caption": "Table 4. Direct synthesis of (\u2013)-1 utilizing chiral ligands and catalysts", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 441, 60], "ImageBB": [58, 74, 762, 427]}, "diagram_type": "single"}, {"id": 16, "width": 2816, "height": 1176, "file_name": "op700060e-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1799.5, 12.6, 279.9, 199.2], "category_id": 1}, {"id": 1, "bbox": [734.4, 36.5, 217.7, 161.3], "category_id": 1}, {"id": 2, "bbox": [1213.7, 28.7, 293.8, 171.9], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [4]}, {"reactants": [4], "conditions": [5, 6], "products": [2]}], "corefs": [], "caption": "Table 3. Tandem SNAr/oxidation evaluation with alternative pyridine and aromatic substrates (HPLC purity data is reported for isolated solids) ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 746, 73], "ImageBB": [58, 88, 762, 382]}, "diagram_type": "single"}, {"id": 17, "width": 1356, "height": 208, "file_name": "op700060e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [542.0, 6.0, 334.0, 145.3], "category_id": 1}, {"id": 1, "bbox": [1162.2, 4.0, 190.8, 152.7], "category_id": 1}, {"id": 2, "bbox": [645.0, 132.0, 43.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [3.0, 0.0, 195.0, 151.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [0, 3], "products": [1]}], "corefs": [[0, 2]], "caption": "Figure 1. Approaches to 2-benzenethiopyridine, 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 311, 702, 325], "ImageBB": [424, 256, 763, 308]}, "diagram_type": "single"}, {"id": 18, "width": 1356, "height": 392, "file_name": "op5002462-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [89.7, 140.7, 329.3, 196.2], "category_id": 1}, {"id": 1, "bbox": [826.1, 130.6, 444.8, 209.3], "category_id": 1}, {"id": 2, "bbox": [458.4, 36.4, 310.1, 175.5], "category_id": 1}, {"id": 3, "bbox": [1043.0, 351.0, 47.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [231.0, 347.0, 49.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [[0, 4], [1, 3]], "caption": "Figure 1. Kharasch\u2212Sosnovsky oxidation of valencene.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 834, 711, 848], "ImageBB": [448, 727, 787, 825]}, "diagram_type": "single"}, {"id": 19, "width": 1352, "height": 1248, "file_name": "op500234a-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [147.0, 1150.0, 290.0, 98.0], "category_id": 1}, {"id": 1, "bbox": [134.0, 997.0, 300.0, 102.0], "category_id": 1}, {"id": 2, "bbox": [968.1, 992.0, 281.9, 256.0], "category_id": 1}, {"id": 3, "bbox": [555.0, 1036.0, 290.0, 73.0], "category_id": 1}], "reactions": [{"reactants": [1, 0], "conditions": [3], "products": [2]}], "corefs": [], "caption": "Figure 4. Real-time in situ Raman analysis of the addition cyclization involving group 7 (C\ue0c8C). ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 513, 417, 541], "ImageBB": [82, 192, 420, 504]}, "diagram_type": "single"}, {"id": 20, "width": 1352, "height": 2624, "file_name": "op500224x-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [505.0, 1956.0, 230.0, 127.0], "category_id": 3}, {"id": 1, "bbox": [456.0, 62.2, 186.0, 187.6], "category_id": 1}, {"id": 2, "bbox": [0.0, 3.0, 295.3, 313.0], "category_id": 1}, {"id": 3, "bbox": [997.7, 25.9, 346.7, 268.1], "category_id": 1}, {"id": 4, "bbox": [1045.0, 709.0, 223.0, 121.0], "category_id": 3}, {"id": 5, "bbox": [741.0, 712.0, 230.0, 109.0], "category_id": 3}, {"id": 6, "bbox": [415.0, 703.0, 237.0, 127.0], "category_id": 3}, {"id": 7, "bbox": [66.0, 709.0, 234.0, 112.0], "category_id": 3}, {"id": 8, "bbox": [85.0, 2352.0, 208.0, 115.0], "category_id": 3}, {"id": 9, "bbox": [514.0, 2355.0, 198.0, 118.0], "category_id": 3}, {"id": 10, "bbox": [910.0, 2358.0, 224.0, 109.0], "category_id": 3}, {"id": 11, "bbox": [898.0, 869.0, 421.0, 272.0], "category_id": 1}, {"id": 12, "bbox": [6.0, 1265.0, 415.0, 313.0], "category_id": 1}, {"id": 13, "bbox": [450.0, 1265.0, 422.0, 304.0], "category_id": 1}, {"id": 14, "bbox": [894.0, 1262.0, 425.0, 316.0], "category_id": 1}, {"id": 15, "bbox": [846.0, 1688.0, 429.0, 267.0], "category_id": 1}, {"id": 16, "bbox": [418.0, 1690.0, 406.0, 266.0], "category_id": 1}, {"id": 17, "bbox": [3.0, 1687.0, 390.0, 275.0], "category_id": 1}, {"id": 18, "bbox": [3.0, 2090.0, 374.0, 271.0], "category_id": 1}, {"id": 19, "bbox": [412.0, 2087.0, 377.0, 262.0], "category_id": 1}, {"id": 20, "bbox": [824.0, 2074.0, 425.0, 281.0], "category_id": 1}, {"id": 21, "bbox": [1125.0, 319.0, 134.0, 58.0], "category_id": 3}, {"id": 22, "bbox": [511.0, 313.0, 134.0, 64.0], "category_id": 3}, {"id": 23, "bbox": [95.0, 322.0, 109.0, 64.0], "category_id": 3}, {"id": 24, "bbox": [102.0, 1141.0, 265.0, 108.0], "category_id": 3}, {"id": 25, "bbox": [543.0, 1147.0, 297.0, 102.0], "category_id": 3}, {"id": 26, "bbox": [987.0, 1141.0, 284.0, 111.0], "category_id": 3}, {"id": 27, "bbox": [978.0, 1562.0, 265.0, 121.0], "category_id": 3}, {"id": 28, "bbox": [539.0, 1559.0, 256.0, 119.0], "category_id": 3}, {"id": 29, "bbox": [85.0, 1566.0, 237.0, 118.0], "category_id": 3}, {"id": 30, "bbox": [69.0, 1959.0, 240.0, 131.0], "category_id": 3}, {"id": 31, "bbox": [936.0, 1962.0, 217.0, 115.0], "category_id": 3}, {"id": 32, "bbox": [709.0, 428.0, 294.0, 284.0], "category_id": 1}, {"id": 33, "bbox": [0.0, 850.0, 473.0, 300.0], "category_id": 1}, {"id": 34, "bbox": [1009.0, 431.0, 307.0, 268.0], "category_id": 1}, {"id": 35, "bbox": [479.0, 853.0, 399.0, 307.0], "category_id": 1}, {"id": 36, "bbox": [370.0, 418.0, 333.0, 285.0], "category_id": 1}, {"id": 37, "bbox": [6.0, 409.0, 361.0, 306.0], "category_id": 1}], "reactions": [{"reactants": [2, 1], "conditions": [23, 4], "products": [3]}], "corefs": [[2, 23], [1, 22], [3, 21], [37, 7], [36, 6], [32, 5], [34, 4], [33, 24], [35, 25], [11, 26], [12, 29], [13, 28], [14, 27], [17, 30], [16, 0], [15, 31], [18, 8], [19, 9], [20, 10]], "caption": "Table 8. Diels\u2212Alder cycloaddition of 1,2-dihydropyridines", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 416, 110], "ImageBB": [82, 116, 420, 772]}, "diagram_type": "single"}, {"id": 21, "width": 1320, "height": 1012, "file_name": "op0600106-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [818.0, 970.0, 46.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [112.0, 730.0, 45.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [652.0, 518.0, 336.0, 438.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 393.0, 246.0, 312.0], "category_id": 1}, {"id": 4, "bbox": [1190.0, 420.0, 45.0, 46.0], "category_id": 3}, {"id": 5, "bbox": [266.42, 500.83, 237.94, 51.41], "category_id": 1}, {"id": 6, "bbox": [777.56, 345.14, 63.15, 49.94], "category_id": 3}, {"id": 7, "bbox": [1075.3, 69.0, 241.8, 317.0], "category_id": 1}, {"id": 8, "bbox": [537.9, 6.0, 370.9, 488.0], "category_id": 1}, {"id": 9, "bbox": [267.0, 447.0, 236.0, 43.2], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [12, 7, 10], "products": [11, 4]}, {"reactants": [11], "conditions": [2, 3], "products": [9]}], "corefs": [[3, 1], [8, 6], [7, 4], [2, 0]], "caption": "Figure 2. Example of synthesis of cyclic sulfamide 13.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 309, 375, 323], "ImageBB": [73, 53, 403, 306]}, "diagram_type": "tree"}, {"id": 22, "width": 1344, "height": 2476, "file_name": "op049899l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [733.0, 741.0, 56.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [1181.0, 748.0, 55.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [276.0, 309.0, 63.0, 59.0], "category_id": 3}, {"id": 3, "bbox": [622.0, 202.0, 62.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [811.0, 149.0, 349.0, 263.0], "category_id": 1}, {"id": 5, "bbox": [563.0, 99.0, 172.0, 74.0], "category_id": 1}, {"id": 6, "bbox": [88.0, 467.0, 341.0, 282.0], "category_id": 1}, {"id": 7, "bbox": [501.0, 458.0, 316.0, 348.0], "category_id": 1}, {"id": 8, "bbox": [914.0, 436.0, 326.0, 342.0], "category_id": 1}, {"id": 9, "bbox": [193.3, 3.0, 268.7, 317.0], "category_id": 1}, {"id": 10, "bbox": [312.0, 739.0, 58.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [10, 6], "conditions": [0, 5], "products": [7, 8, 9]}], "corefs": [[9, 2], [5, 3], [6, 10], [7, 0], [8, 1]], "caption": "Table 2. Optimization of the coupling of 5a and 18", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 355, 67], "ImageBB": [74, 75, 410, 694]}, "diagram_type": "multiple"}, {"id": 23, "width": 1348, "height": 884, "file_name": "op049899l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1053.0, 841.0, 48.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [327.0, 818.0, 47.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [832.0, 597.0, 410.0, 210.0], "category_id": 1}, {"id": 3, "bbox": [643.0, 576.0, 153.0, 128.0], "category_id": 1}, {"id": 4, "bbox": [111.0, 590.0, 428.0, 204.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4, 6], "products": [3]}], "corefs": [[4, 1], [2, 0]], "caption": "Table 1. DOE results for alkylation of 6 to give 17 (% yield)", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 773, 67], "ImageBB": [439, 70, 776, 291]}, "diagram_type": "single"}, {"id": 24, "width": 1316, "height": 1416, "file_name": "op034198u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [706.5, 83.0, 593.0, 360.0], "category_id": 1}, {"id": 1, "bbox": [32.2, 1056.0, 590.6, 350.0], "category_id": 1}, {"id": 2, "bbox": [744.0, 941.0, 59.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [17.0, 79.0, 363.0, 361.0], "category_id": 1}, {"id": 4, "bbox": [963.0, 400.0, 38.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [191.0, 402.0, 42.0, 54.0], "category_id": 3}, {"id": 6, "bbox": [467.0, 472.0, 614.0, 468.0], "category_id": 1}, {"id": 7, "bbox": [282.0, 1370.0, 46.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [10, 9], "products": [0]}, {"reactants": [0], "conditions": [3], "products": [8]}, {"reactants": [8], "conditions": [2, 12], "products": [1]}], "corefs": [[3, 5], [0, 4], [6, 2], [1, 7]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 128, 129, 142], "ImageBB": [74, 152, 403, 506]}, "diagram_type": "multiple"}, {"id": 25, "width": 1128, "height": 468, "file_name": "op0340661-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [383.7, 408.37, 52.74, 51.89], "category_id": 3}, {"id": 1, "bbox": [614.0, 0.0, 358.0, 237.0], "category_id": 1}, {"id": 2, "bbox": [104.67, 179.53, 42.54, 49.34], "category_id": 3}, {"id": 3, "bbox": [706.95, 181.23, 40.84, 47.64], "category_id": 3}, {"id": 4, "bbox": [4.0, 21.0, 307.0, 209.0], "category_id": 1}, {"id": 5, "bbox": [302.0, 250.0, 443.3, 214.0], "category_id": 1}, {"id": 6, "bbox": [685.0, 232.6, 441.0, 233.4], "category_id": 1}, {"id": 7, "bbox": [769.05, 407.51, 51.9, 46.79], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [1, 7, 8]}], "corefs": [[4, 2], [1, 3], [5, 0], [6, 7]], "caption": "Table 1. Alkylation of 9 with ethylbromoacetate in the presence of K2CO3 in DMF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 767, 740, 796], "ImageBB": [467, 638, 749, 755]}, "diagram_type": "multiple"}, {"id": 26, "width": 1352, "height": 1128, "file_name": "op034064g-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [668.0, 473.1, 233.5, 296.4], "category_id": 1}, {"id": 1, "bbox": [354.0, 472.0, 293.0, 154.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 8, 6], "products": [3]}, {"reactants": [3], "conditions": [5, 1], "products": [9]}], "corefs": [], "caption": "Table 5. Coupling temperature effect on selectivity", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 354, 67], "ImageBB": [74, 70, 412, 352]}, "diagram_type": "single"}, {"id": 27, "width": 1348, "height": 784, "file_name": "op0256183-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 6.0, 382.0, 135.7], "category_id": 1}, {"id": 1, "bbox": [969.0, 2.0, 377.0, 139.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 2], "products": [3]}], "corefs": [], "caption": "Table 5. Effects of reducing the substrate-to-catalyst ratio", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 656, 759, 670], "ImageBB": [439, 677, 776, 873]}, "diagram_type": "single"}, {"id": 28, "width": 1356, "height": 812, "file_name": "op0256183-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 29.0, 360.0, 140.0], "category_id": 1}, {"id": 1, "bbox": [974.0, 26.1, 370.0, 139.4], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 2], "products": [4]}], "corefs": [], "caption": "Table 3. Effect of substrate concentration and addition of triethylamine ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 326, 391, 354], "ImageBB": [73, 358, 412, 561]}, "diagram_type": "single"}, {"id": 29, "width": 1100, "height": 1936, "file_name": "op000111i-Figure-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 3.0, 372.9, 223.6], "category_id": 1}, {"id": 1, "bbox": [804.0, 249.0, 153.0, 345.5], "category_id": 1}, {"id": 2, "bbox": [718.0, 214.5, 62.0, 58.5], "category_id": 3}, {"id": 3, "bbox": [725.5, 1870.99, 60.0, 65.01], "category_id": 3}, {"id": 4, "bbox": [718.0, 1128.0, 67.0, 72.5], "category_id": 3}, {"id": 5, "bbox": [638.0, 0.0, 360.0, 222.0], "category_id": 1}, {"id": 6, "bbox": [605.5, 566.5, 379.5, 547.5], "category_id": 1}, {"id": 7, "bbox": [30.51, 569.0, 375.0, 486.0], "category_id": 1}, {"id": 8, "bbox": [125.88, 224.43, 57.39, 57.38], "category_id": 3}, {"id": 9, "bbox": [232.0, 1138.0, 57.0, 66.0], "category_id": 3}, {"id": 10, "bbox": [530.0, 1271.0, 570.0, 541.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [2, 11], "products": [9]}, {"reactants": [9], "conditions": [5], "products": [10]}, {"reactants": [10], "conditions": [14, 4], "products": [15]}], "corefs": [[0, 8], [5, 2], [6, 4], [7, 9], [10, 3]], "caption": "Figure 6. Oxazaborolidine bound to a polystyrene.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 541, 358, 555], "ImageBB": [105, 54, 380, 538]}, "diagram_type": "tree"}, {"id": 30, "width": 2640, "height": 1760, "file_name": "op000111i-Figure-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1700.95, 1229.2, 61.24, 81.64], "category_id": 3}, {"id": 1, "bbox": [1459.0, 701.0, 728.0, 757.0], "category_id": 1}, {"id": 2, "bbox": [1027.1, 517.7, 304.3, 289.8], "category_id": 1}, {"id": 3, "bbox": [345.4, 517.0, 306.4, 292.7], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [2], "products": [6]}], "corefs": [[1, 0]], "caption": "Figure 11. Continuous reduction of tetralone, applying polystyrene-bound oxazaborolidine as catalyst.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 1013, 638, 1027], "ImageBB": [97, 564, 757, 1004]}, "diagram_type": "single"}, {"id": 31, "width": 1348, "height": 1128, "file_name": "ol9005079-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [567.0, 181.0, 60.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [153.0, 181.0, 65.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1048.0, 179.0, 76.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [860.0, 0.0, 379.0, 199.0], "category_id": 1}, {"id": 4, "bbox": [116.0, 16.0, 199.5, 163.0], "category_id": 1}, {"id": 5, "bbox": [396.3, 0.0, 259.7, 200.0], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [1, 0], "products": [6]}], "corefs": [[4, 1], [5, 0], [3, 2]], "caption": "Table 1. Optimization of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 688, 88], "ImageBB": [425, 97, 762, 379]}, "diagram_type": "single"}, {"id": 32, "width": 1348, "height": 1180, "file_name": "ol802141g-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1019.0, 236.2, 221.0, 83.6], "category_id": 1}, {"id": 1, "bbox": [489.4, 145.6, 238.6, 248.3], "category_id": 1}, {"id": 2, "bbox": [820.6, 178.2, 179.4, 221.2], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [4, 2]}], "corefs": [], "caption": "Figure 2. UV spectra of 9e (solid line, ca. 1 \u00d7 10-4 M in 20% aqueous methanol) and its 300 nm photolysis (dashed lines, every 5 min). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 856, 761, 886], "ImageBB": [425, 557, 762, 852]}, "diagram_type": "single"}, {"id": 33, "width": 1352, "height": 800, "file_name": "ol802005n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.3, 3.9, 262.7, 201.0], "category_id": 1}, {"id": 1, "bbox": [657.6, 1.9, 265.0, 185.8], "category_id": 1}, {"id": 2, "bbox": [5.2, 4.6, 223.9, 181.7], "category_id": 1}, {"id": 3, "bbox": [86.0, 222.0, 42.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [778.0, 220.0, 42.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [1168.0, 218.0, 39.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [4, 8], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}], "corefs": [[2, 3], [1, 4], [0, 5]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 730, 296, 743], "ImageBB": [58, 753, 396, 953]}, "diagram_type": "single"}, {"id": 34, "width": 1352, "height": 612, "file_name": "ol801498u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [49.0, 5.0, 261.0, 146.9], "category_id": 1}, {"id": 1, "bbox": [938.0, 7.0, 362.0, 142.0], "category_id": 1}, {"id": 2, "bbox": [398.0, 9.0, 146.0, 142.0], "category_id": 1}, {"id": 3, "bbox": [203.73, 148.04, 44.89, 56.98], "category_id": 3}], "reactions": [{"reactants": [0, 4], "conditions": [1, 3], "products": [2]}], "corefs": [[0, 3]], "caption": "Table 1. Comparison of the Direct Crossed-Claisen Coupling of Various Thioesters and Oxoester 8 with 5 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 141, 390, 168], "ImageBB": [58, 177, 396, 330]}, "diagram_type": "single"}, {"id": 35, "width": 1348, "height": 552, "file_name": "ol800527p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [919.33, 317.91, 52.17, 46.37], "category_id": 3}, {"id": 1, "bbox": [231.28, 154.7, 51.6, 42.7], "category_id": 3}, {"id": 2, "bbox": [99.5, 1.4, 180.0, 194.2], "category_id": 1}, {"id": 3, "bbox": [307.4, 18.8, 582.2, 397.1], "category_id": 1}, {"id": 4, "bbox": [943.4, 84.5, 379.6, 328.5], "category_id": 1}, {"id": 5, "bbox": [456.28, 329.42, 68.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [4, 0], "products": [5, 6]}], "corefs": [[2, 1], [3, 5], [4, 0]], "caption": "Table 2. Optimization of the Pictet-Spengler Reaction", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 713, 711, 726], "ImageBB": [425, 736, 762, 874]}, "diagram_type": "single"}, {"id": 36, "width": 1344, "height": 872, "file_name": "ol800288b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [71.0, 20.0, 249.0, 67.0], "category_id": 1}, {"id": 1, "bbox": [809.0, 1.0, 464.0, 92.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 4, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Aziridination of 1-Hexene Catalyzed by Various Copper-carbene Complexesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 426, 379, 454], "ImageBB": [74, 459, 410, 677]}, "diagram_type": "single"}, {"id": 37, "width": 1348, "height": 1388, "file_name": "ol401042b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [562.0, 578.0, 69.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [530.0, 254.0, 73.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [133.0, 576.0, 62.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [1030.0, 250.0, 75.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [905.0, 0.0, 410.0, 289.0], "category_id": 1}, {"id": 5, "bbox": [165.0, 246.0, 69.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [496.3, 29.9, 140.5, 220.6], "category_id": 1}, {"id": 7, "bbox": [16.0, 368.5, 387.4, 240.2], "category_id": 1}, {"id": 8, "bbox": [20.9, 40.5, 390.1, 211.5], "category_id": 1}, {"id": 9, "bbox": [517.6, 372.0, 312.8, 250.4], "category_id": 1}, {"id": 10, "bbox": [911.21, 528.0, 412.0, 119.0], "category_id": 3}, {"id": 11, "bbox": [954.9, 374.3, 249.9, 149.8], "category_id": 1}], "reactions": [{"reactants": [9, 7], "conditions": [], "products": [5]}], "corefs": [[8, 5], [6, 1], [4, 3], [7, 2], [9, 0], [11, 10]], "caption": "Table 1. Screening of Organocatalysts and Optimization of the Reaction Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 346, 404, 373], "ImageBB": [71, 384, 408, 731]}, "diagram_type": "single"}, {"id": 38, "width": 2808, "height": 1024, "file_name": "ol303482k-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1845.0, 432.0, 53.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [1688.0, 679.0, 691.0, 264.0], "category_id": 1}, {"id": 2, "bbox": [2123.0, 265.0, 268.0, 141.0], "category_id": 1}, {"id": 3, "bbox": [16.0, 162.0, 1310.0, 806.0], "category_id": 1}, {"id": 4, "bbox": [2235.0, 408.0, 51.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [2068.0, 824.0, 175.0, 98.0], "category_id": 3}, {"id": 6, "bbox": [1625.0, 212.6, 462.0, 260.4], "category_id": 1}], "reactions": [{"reactants": [9, 3], "conditions": [0, 5], "products": [2]}], "corefs": [[6, 0], [2, 4], [1, 5]], "caption": "Figure 2. X-ray crystal structure of imide 15d.", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 314, 315, 327], "ImageBB": [71, 59, 773, 315]}, "diagram_type": "tree"}, {"id": 39, "width": 1344, "height": 1628, "file_name": "ol303154k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [330.0, 69.0, 109.2, 203.0], "category_id": 1}, {"id": 1, "bbox": [365.0, 308.0, 32.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [512.0, 313.0, 31.0, 31.0], "category_id": 3}, {"id": 3, "bbox": [1106.0, 351.0, 48.0, 31.0], "category_id": 3}, {"id": 4, "bbox": [27.9, 71.0, 267.6, 200.6], "category_id": 1}, {"id": 5, "bbox": [104.0, 284.0, 163.0, 70.0], "category_id": 3}, {"id": 6, "bbox": [471.0, 62.0, 199.0, 230.0], "category_id": 1}, {"id": 7, "bbox": [951.0, 2.0, 369.0, 347.8], "category_id": 1}], "reactions": [{"reactants": [7, 0, 9], "conditions": [6, 5], "products": [10]}], "corefs": [[4, 5], [0, 1], [6, 2], [7, 3]], "caption": "Table 3. Substrate Scope of Anilines and R-Alkyl o-Hydroxystyrenesa ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 333, 115], "ImageBB": [71, 126, 407, 533]}, "diagram_type": "single"}, {"id": 40, "width": 1348, "height": 1728, "file_name": "ol303154k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [355.0, 328.0, 45.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [1120.0, 330.0, 32.0, 34.0], "category_id": 3}, {"id": 2, "bbox": [510.0, 328.0, 45.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [146.0, 330.0, 26.0, 28.0], "category_id": 3}, {"id": 4, "bbox": [318.0, 87.0, 112.0, 220.1], "category_id": 1}, {"id": 5, "bbox": [908.1, 2.0, 415.9, 321.0], "category_id": 1}, {"id": 6, "bbox": [25.7, 107.1, 262.8, 195.2], "category_id": 1}, {"id": 7, "bbox": [456.0, 91.0, 173.0, 166.7], "category_id": 1}], "reactions": [{"reactants": [8, 6, 10], "conditions": [9, 1], "products": [7]}], "corefs": [[6, 3], [4, 0], [7, 2], [5, 1]], "caption": "Table 2. Substrate Scope of Isatinsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 627, 101], "ImageBB": [436, 112, 773, 544]}, "diagram_type": "single"}, {"id": 41, "width": 1300, "height": 1376, "file_name": "ol302668y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.55, 312.0, 71.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [323.3, 144.7, 320.2, 107.1], "category_id": 1}, {"id": 2, "bbox": [948.6, 0.0, 341.4, 406.0], "category_id": 1}, {"id": 3, "bbox": [478.0, 317.0, 35.0, 40.0], "category_id": 3}, {"id": 4, "bbox": [1027.0, 305.0, 38.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 142.1, 279.0, 100.5], "category_id": 1}], "reactions": [{"reactants": [9, 3], "conditions": [7, 2], "products": [4]}], "corefs": [[5, 0], [1, 3], [2, 4]], "caption": "Table 3. Click Reaction of 2b with Various Acetylenes 3 and Fluorescence Properties of Various 5-Methyl-1,3a,6a-triaza- pentalenes in Dichloromethane ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 392, 128], "ImageBB": [77, 139, 402, 483]}, "diagram_type": "single"}, {"id": 42, "width": 1344, "height": 1004, "file_name": "ol3023903-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [589.0, 669.0, 242.0, 30.0], "category_id": 3}, {"id": 1, "bbox": [980.0, 723.0, 338.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [129.0, 916.0, 236.0, 37.0], "category_id": 3}, {"id": 3, "bbox": [338.0, 164.0, 217.0, 179.0], "category_id": 1}, {"id": 4, "bbox": [507.0, 963.0, 336.0, 36.0], "category_id": 3}, {"id": 5, "bbox": [1001.0, 940.0, 229.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [967.0, 410.0, 295.0, 295.0], "category_id": 1}, {"id": 7, "bbox": [384.72, 341.51, 31.05, 36.23], "category_id": 3}, {"id": 8, "bbox": [873.78, 338.92, 40.11, 33.64], "category_id": 3}, {"id": 9, "bbox": [458.3, 743.6, 406.7, 216.8], "category_id": 1}, {"id": 10, "bbox": [839.8, 213.1, 110.6, 125.9], "category_id": 1}, {"id": 11, "bbox": [600.4, 172.1, 150.3, 88.9], "category_id": 1}, {"id": 12, "bbox": [89.0, 723.2, 322.1, 192.8], "category_id": 1}, {"id": 13, "bbox": [983.6, 778.9, 296.1, 146.6], "category_id": 1}, {"id": 14, "bbox": [134.0, 616.0, 272.0, 33.0], "category_id": 3}, {"id": 15, "bbox": [568.6, 428.9, 270.9, 227.8], "category_id": 1}, {"id": 16, "bbox": [81.6, 478.0, 431.4, 142.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [12, 0], "products": [11]}], "corefs": [[3, 7], [10, 8], [16, 14], [15, 0], [6, 1], [12, 2], [9, 4], [13, 5]], "caption": "Figure 4. Scope of the radical olefination for vinyl fluorides. Reaction conditions: olefin (2 equiv), xanthate (1 equiv), lauroyl peroxide was added in 30 mol % portions (with respect to the xanthate) every hour (5 7 h). For 10c, the reaction was run in refluxing DCE. ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 322, 771, 391], "ImageBB": [437, 58, 773, 309]}, "diagram_type": "single"}, {"id": 43, "width": 1352, "height": 1832, "file_name": "ol3023903-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [863.0, 215.8, 134.6, 131.2], "category_id": 1}, {"id": 1, "bbox": [625.0, 396.7, 326.9, 204.3], "category_id": 1}, {"id": 2, "bbox": [1028.4, 443.4, 280.2, 233.6], "category_id": 1}, {"id": 3, "bbox": [0.0, 1094.7, 515.0, 279.3], "category_id": 1}, {"id": 4, "bbox": [27.6, 452.8, 546.8, 229.3], "category_id": 1}, {"id": 5, "bbox": [375.1, 156.7, 187.5, 191.2], "category_id": 1}, {"id": 6, "bbox": [521.0, 681.8, 454.0, 301.1], "category_id": 1}, {"id": 7, "bbox": [22.0, 760.9, 466.0, 225.1], "category_id": 1}, {"id": 8, "bbox": [973.0, 801.4, 365.6, 255.6], "category_id": 1}, {"id": 9, "bbox": [912.1, 1148.0, 351.9, 211.0], "category_id": 1}, {"id": 10, "bbox": [588.0, 1257.2, 268.6, 217.8], "category_id": 1}, {"id": 11, "bbox": [1033.0, 1058.0, 241.0, 40.0], "category_id": 3}, {"id": 12, "bbox": [123.0, 1298.0, 148.0, 79.0], "category_id": 3}, {"id": 13, "bbox": [1032.0, 687.0, 283.0, 39.0], "category_id": 3}, {"id": 14, "bbox": [238.0, 663.0, 278.0, 42.0], "category_id": 3}, {"id": 15, "bbox": [664.0, 904.0, 118.0, 83.0], "category_id": 3}, {"id": 16, "bbox": [88.0, 984.0, 310.0, 45.0], "category_id": 3}, {"id": 17, "bbox": [971.0, 1313.0, 154.0, 68.0], "category_id": 3}, {"id": 18, "bbox": [731.0, 1434.0, 123.0, 76.0], "category_id": 3}, {"id": 19, "bbox": [477.0, 1137.0, 132.0, 76.0], "category_id": 3}, {"id": 20, "bbox": [721.0, 554.0, 146.0, 79.0], "category_id": 3}, {"id": 21, "bbox": [907.0, 351.0, 37.0, 31.0], "category_id": 3}, {"id": 22, "bbox": [607.0, 172.0, 166.0, 92.0], "category_id": 1}, {"id": 23, "bbox": [451.0, 1003.0, 395.0, 225.0], "category_id": 1}, {"id": 24, "bbox": [401.0, 353.0, 27.0, 26.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [23, 11], "products": [0]}], "corefs": [[5, 24], [0, 21], [4, 14], [1, 20], [2, 13], [7, 16], [6, 15], [8, 11], [3, 12], [23, 19], [10, 18], [9, 17]], "caption": "Figure 3. Scope of the radical olefination process via strategy B.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 530, 405, 543], "ImageBB": [71, 59, 409, 517]}, "diagram_type": "single"}, {"id": 44, "width": 2808, "height": 968, "file_name": "ol300387f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.0, 226.0, 54.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [1417.21, 229.59, 161.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [1130.6, 17.0, 205.4, 213.6], "category_id": 1}, {"id": 3, "bbox": [1192.6, 238.0, 117.4, 44.0], "category_id": 3}, {"id": 4, "bbox": [1727.38, 235.17, 54.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [1967.79, 231.38, 117.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [1373.0, 26.0, 202.1, 202.8], "category_id": 1}, {"id": 7, "bbox": [460.9, 17.0, 177.8, 211.7], "category_id": 1}, {"id": 8, "bbox": [1912.4, 15.2, 178.2, 212.0], "category_id": 1}, {"id": 9, "bbox": [1638.1, 13.2, 228.8, 215.3], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [12, 9], "products": [3, 8, 13, 11]}], "corefs": [[7, 0], [2, 3], [6, 1], [9, 4], [8, 5]], "caption": "Table 2. Rhodium-Catalyzed Addition of AlMe3 to 5-Substituted Cyclohex-2-enones", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 522, 102], "ImageBB": [71, 112, 773, 354]}, "diagram_type": "single"}, {"id": 45, "width": 1348, "height": 1448, "file_name": "ol202499g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [45.5, 12.6, 193.9, 141.6], "category_id": 1}, {"id": 1, "bbox": [456.0, 175.0, 64.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [113.0, 171.0, 38.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [1133.0, 191.0, 47.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [296.0, 0.0, 300.0, 184.0], "category_id": 1}, {"id": 5, "bbox": [960.0, 1.0, 342.0, 190.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [0, 1], "products": [9]}], "corefs": [[0, 2], [4, 1], [5, 3]], "caption": "Table 1. Direct Allylic Alkylation of O-Protected Cyanohydrins with MBH Adducts 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 405, 114], "ImageBB": [71, 126, 408, 488]}, "diagram_type": "single"}, {"id": 46, "width": 1348, "height": 1452, "file_name": "ol202395s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [148.7, 366.9, 65.6, 67.4], "category_id": 3}, {"id": 1, "bbox": [475.11, 371.0, 64.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [1084.0, 368.0, 62.4, 55.0], "category_id": 3}, {"id": 3, "bbox": [381.7, 1.2, 283.3, 277.2], "category_id": 1}, {"id": 4, "bbox": [17.7, 3.0, 349.3, 277.0], "category_id": 1}, {"id": 5, "bbox": [962.0, 21.0, 386.0, 350.0], "category_id": 1}], "reactions": [{"reactants": [4, 3], "conditions": [5, 6], "products": [7]}], "corefs": [[4, 0], [3, 1], [5, 2]], "caption": "Table 1. Reaction of P-Alkenyl-\u03bb5-phosphazenes and Aryne Precursors in the Presence of CsFa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 756, 115], "ImageBB": [436, 126, 773, 489]}, "diagram_type": "single"}, {"id": 47, "width": 1352, "height": 1784, "file_name": "ol102784c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [38.0, 231.8, 240.6, 107.0], "category_id": 1}, {"id": 1, "bbox": [381.0, 367.0, 53.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [189.0, 6.0, 152.0, 127.0], "category_id": 1}, {"id": 3, "bbox": [669.0, 133.0, 643.0, 252.0], "category_id": 1}, {"id": 4, "bbox": [873.0, 0.0, 290.0, 133.0], "category_id": 1}, {"id": 5, "bbox": [963.0, 367.0, 52.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [585.0, 367.0, 50.0, 39.0], "category_id": 3}, {"id": 7, "bbox": [146.0, 364.0, 47.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [536.09, 217.62, 217.5, 119.1], "category_id": 1}, {"id": 9, "bbox": [284.94, 194.31, 240.8, 147.59], "category_id": 1}], "reactions": [{"reactants": [5, 4], "conditions": [2, 3], "products": [7]}], "corefs": [[0, 7], [9, 1], [8, 6], [3, 5]], "caption": "Table 1. Optimization of Reaction Conditions in the Copper-Catalyzed Coupling of Iodobenzene and Potassium Thiocyanatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 342, 362, 383], "ImageBB": [58, 392, 396, 838]}, "diagram_type": "single"}, {"id": 48, "width": 1356, "height": 2980, "file_name": "ol100734t-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [760.4, 582.3, 327.6, 285.7], "category_id": 1}, {"id": 1, "bbox": [116.4, 211.4, 326.6, 287.3], "category_id": 1}, {"id": 2, "bbox": [149.3, 479.7, 125.7, 43.4], "category_id": 3}, {"id": 3, "bbox": [617.0, 209.0, 334.0, 294.0], "category_id": 1}, {"id": 4, "bbox": [318.0, 584.0, 333.0, 284.0], "category_id": 1}, {"id": 5, "bbox": [699.0, 481.0, 46.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [304.0, 856.0, 33.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [734.0, 867.0, 36.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [7], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5, 1]}], "corefs": [[1, 2], [3, 5], [4, 6], [0, 7]], "caption": "Figure 1. (a) VCD spectra of (S,S)-imidazoline 1 at different reaction times during racemization in DMSO solution at 60 \u00b0C. (b) Relationship of ln (ee %) versus time at different temperatures. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 797, 760, 839], "ImageBB": [424, 46, 763, 791]}, "diagram_type": "multiple"}, {"id": 49, "width": 1352, "height": 1680, "file_name": "op500224x-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.0, 698.0, 171.0, 91.0], "category_id": 3}, {"id": 1, "bbox": [123.0, 1165.0, 197.0, 99.0], "category_id": 3}, {"id": 2, "bbox": [548.0, 1170.0, 174.0, 90.0], "category_id": 3}, {"id": 3, "bbox": [234.0, 1591.0, 174.0, 89.0], "category_id": 3}, {"id": 4, "bbox": [972.0, 1173.0, 168.0, 86.0], "category_id": 3}, {"id": 5, "bbox": [543.0, 704.0, 191.0, 81.0], "category_id": 3}, {"id": 6, "bbox": [869.0, 1593.0, 175.0, 87.0], "category_id": 3}, {"id": 7, "bbox": [140.0, 703.0, 167.0, 82.0], "category_id": 3}, {"id": 8, "bbox": [642.0, 306.0, 91.0, 56.0], "category_id": 3}, {"id": 9, "bbox": [1166.0, 302.0, 80.0, 64.0], "category_id": 3}, {"id": 10, "bbox": [109.0, 306.0, 60.0, 60.0], "category_id": 3}, {"id": 11, "bbox": [9.0, 1277.0, 613.0, 302.0], "category_id": 1}, {"id": 12, "bbox": [661.0, 1275.0, 649.0, 302.0], "category_id": 1}, {"id": 13, "bbox": [1050.0, 7.0, 302.0, 295.0], "category_id": 1}, {"id": 14, "bbox": [5.0, 860.0, 463.0, 292.0], "category_id": 1}, {"id": 15, "bbox": [402.0, 848.0, 454.0, 313.0], "category_id": 1}, {"id": 16, "bbox": [459.0, 386.0, 369.0, 318.0], "category_id": 1}, {"id": 17, "bbox": [864.0, 390.0, 473.0, 302.0], "category_id": 1}, {"id": 18, "bbox": [817.0, 801.0, 528.0, 398.0], "category_id": 1}, {"id": 19, "bbox": [537.0, 3.0, 306.0, 302.0], "category_id": 1}, {"id": 20, "bbox": [0.0, 6.0, 269.0, 295.0], "category_id": 1}, {"id": 21, "bbox": [34.0, 382.0, 405.0, 318.0], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [18, 24], "products": [21]}, {"reactants": [21], "conditions": [8, 23], "products": [14]}], "corefs": [[20, 10], [19, 8], [13, 9], [21, 7], [16, 5], [17, 0], [14, 1], [15, 2], [18, 4], [11, 3], [12, 6]], "caption": "Table 7. Thermodynamic protonation with carbon nucleophile addition products ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 734, 125], "ImageBB": [448, 131, 786, 551]}, "diagram_type": "single"}, {"id": 50, "width": 1704, "height": 1296, "file_name": "op500102h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [495.0, 227.0, 105.9, 47.0], "category_id": 3}, {"id": 1, "bbox": [1248.2, 12.0, 289.1, 210.0], "category_id": 1}, {"id": 2, "bbox": [378.8, 4.0, 319.3, 212.7], "category_id": 1}, {"id": 3, "bbox": [1361.0, 230.0, 94.2, 45.4], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [5, 6], "products": [2]}], "corefs": [[2, 0], [1, 3]], "caption": "Table 3. Decarboxylation of 3,5-bis(\ufb02uoroalkyl)pyrazoles 5", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 781, 414, 796], "ImageBB": [10, 803, 436, 1127]}, "diagram_type": "single"}, {"id": 51, "width": 1352, "height": 1516, "file_name": "op400278d-Table-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [739.0, 239.0, 199.0, 53.0], "category_id": 1}, {"id": 1, "bbox": [287.3, 227.0, 174.5, 66.0], "category_id": 1}, {"id": 2, "bbox": [10.1, 630.3, 434.9, 217.7], "category_id": 1}, {"id": 3, "bbox": [896.4, 0.0, 221.6, 323.8], "category_id": 1}, {"id": 4, "bbox": [47.0, 235.03, 121.0, 49.0], "category_id": 1}, {"id": 5, "bbox": [1131.1, 0.0, 200.6, 281.8], "category_id": 1}, {"id": 6, "bbox": [6.1, 1106.4, 458.6, 224.1], "category_id": 1}, {"id": 7, "bbox": [492.0, 1099.0, 391.9, 231.6], "category_id": 1}, {"id": 8, "bbox": [887.0, 625.1, 453.0, 226.7], "category_id": 1}, {"id": 9, "bbox": [457.0, 631.0, 391.0, 212.8], "category_id": 1}, {"id": 10, "bbox": [208.0, 1326.0, 61.0, 43.0], "category_id": 3}, {"id": 11, "bbox": [686.0, 1330.0, 60.0, 39.0], "category_id": 3}, {"id": 12, "bbox": [1109.0, 1331.0, 58.0, 36.0], "category_id": 3}, {"id": 13, "bbox": [1009.0, 867.0, 56.0, 48.0], "category_id": 3}, {"id": 14, "bbox": [577.0, 872.0, 59.0, 46.0], "category_id": 3}, {"id": 15, "bbox": [123.0, 859.0, 57.0, 43.0], "category_id": 3}, {"id": 16, "bbox": [1211.0, 328.0, 47.0, 43.0], "category_id": 3}, {"id": 17, "bbox": [977.0, 330.0, 49.0, 37.0], "category_id": 3}, {"id": 18, "bbox": [842.0, 1055.0, 504.0, 321.0], "category_id": 1}], "reactions": [{"reactants": [4, 1], "conditions": [6], "products": [0, 3, 5]}], "corefs": [[3, 17], [5, 16], [2, 15], [9, 14], [8, 13], [6, 10], [7, 11], [18, 12]], "caption": "Table 11. Aryl aminations with sensitive functional groups in the presence of optimized alkoxide base 92 ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 510]}, "diagram_type": "single"}, {"id": 52, "width": 2820, "height": 2056, "file_name": "op400242j-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1477.0, 281.0, 45.0, 34.0], "category_id": 3}, {"id": 1, "bbox": [476.0, 789.0, 646.0, 395.0], "category_id": 1}, {"id": 2, "bbox": [699.0, 1170.0, 276.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [1340.0, 651.0, 254.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [439.0, 651.0, 28.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [536.0, 269.0, 26.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [2274.0, 524.0, 25.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [1251.0, 34.0, 406.0, 263.0], "category_id": 1}, {"id": 8, "bbox": [1885.0, 139.0, 644.0, 395.0], "category_id": 1}, {"id": 9, "bbox": [1307.0, 422.0, 353.0, 235.0], "category_id": 1}, {"id": 10, "bbox": [285.0, 408.0, 349.0, 237.0], "category_id": 1}, {"id": 11, "bbox": [288.0, 38.0, 408.0, 261.0], "category_id": 1}], "reactions": [{"reactants": [18], "conditions": [15, 21, 16], "products": [10]}, {"reactants": [17], "conditions": [19, 20, 9], "products": [12]}, {"reactants": [10, 12], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [7, 8, 13, 14], "products": [1]}], "corefs": [[11, 5], [7, 0], [8, 6], [10, 4], [9, 3], [1, 2]], "caption": "Figure 4. FTIR spectroscopy of DIPEA-catalyzed and DIPEA-free chlorinations.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 640, 471, 654], "ImageBB": [82, 116, 787, 630]}, "diagram_type": "tree"}, {"id": 53, "width": 1348, "height": 1024, "file_name": "op300031r-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [506.0, 3.0, 537.3, 397.0], "category_id": 1}, {"id": 1, "bbox": [71.9, 80.1, 361.6, 311.7], "category_id": 1}, {"id": 2, "bbox": [714.0, 347.0, 234.8, 51.0], "category_id": 3}, {"id": 3, "bbox": [228.0, 342.0, 243.3, 53.1], "category_id": 3}, {"id": 4, "bbox": [851.88, 876.0, 73.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [663.0, 408.0, 618.4, 517.3], "category_id": 1}], "reactions": [{"reactants": [1, 0], "conditions": [8, 7], "products": [5]}], "corefs": [[1, 3], [0, 2], [5, 4]], "caption": "Table 2. Suzuki Coupling Screening", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 653, 110], "ImageBB": [449, 116, 786, 372]}, "diagram_type": "multiple"}, {"id": 54, "width": 1348, "height": 640, "file_name": "op200234j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [26.0, 1.0, 322.0, 241.0], "category_id": 1}, {"id": 1, "bbox": [1040.0, 4.0, 267.0, 148.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [], "caption": "Table 2. Hydrogenation of methyl (R)-lactate", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 718, 339, 733], "ImageBB": [82, 739, 419, 899]}, "diagram_type": "single"}, {"id": 55, "width": 2808, "height": 428, "file_name": "op2001047-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1598.7, 8.5, 253.2, 133.9], "category_id": 1}, {"id": 1, "bbox": [957.7, 8.1, 248.8, 134.3], "category_id": 1}, {"id": 2, "bbox": [1676.0, 171.0, 108.5, 57.0], "category_id": 3}, {"id": 3, "bbox": [1044.0, 177.0, 96.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [6, 1], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 7. Optimized reaction conditions for the \ufb02ow hydrogenation of 4-aryl-3-buten-2-ones 1a ca", "pdf": {"Page": 8, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 617, 109], "ImageBB": [71, 117, 773, 224]}, "diagram_type": "single"}, {"id": 56, "width": 2808, "height": 416, "file_name": "op2001047-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [723.0, 55.0, 283.0, 174.0], "category_id": 1}, {"id": 1, "bbox": [1911.0, 221.0, 73.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [874.0, 229.0, 73.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [1659.0, 5.0, 428.0, 210.0], "category_id": 1}, {"id": 4, "bbox": [1064.0, 72.0, 171.0, 126.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [1, 6], "products": [7]}], "corefs": [[0, 2], [3, 1]], "caption": "Table 1. Optimization of the Mizoroki Heck reaction of 4-iodoanisole (3b) and methyl vinyl ketone (MVK) under microwave batch and continuous \ufb02ow conditionsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 770, 123], "ImageBB": [71, 133, 773, 237]}, "diagram_type": "single"}, {"id": 57, "width": 1356, "height": 1568, "file_name": "op200005e-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1023.0, 670.0, 59.2, 45.8], "category_id": 3}, {"id": 1, "bbox": [853.2, 266.0, 62.9, 43.2], "category_id": 3}, {"id": 2, "bbox": [371.5, 17.0, 221.5, 140.0], "category_id": 1}, {"id": 3, "bbox": [395.5, 800.0, 683.3, 213.0], "category_id": 1}, {"id": 4, "bbox": [139.6, 804.4, 111.7, 103.3], "category_id": 1}, {"id": 5, "bbox": [0.0, 1219.0, 687.6, 210.7], "category_id": 1}, {"id": 6, "bbox": [637.2, 35.5, 494.7, 206.9], "category_id": 1}, {"id": 7, "bbox": [123.0, 280.0, 54.0, 49.9], "category_id": 3}, {"id": 8, "bbox": [5.0, 35.5, 311.4, 212.8], "category_id": 1}, {"id": 9, "bbox": [0.0, 459.9, 187.6, 156.1], "category_id": 1}, {"id": 10, "bbox": [763.6, 430.3, 592.4, 210.7], "category_id": 1}, {"id": 11, "bbox": [498.0, 1023.0, 52.7, 44.6], "category_id": 3}], "reactions": [{"reactants": [21], "conditions": [12, 4], "products": [16]}, {"reactants": [22, 17], "conditions": [3, 20], "products": [23]}, {"reactants": [23], "conditions": [14, 7, 1], "products": [13]}, {"reactants": [13], "conditions": [18, 2], "products": [15]}], "corefs": [[8, 7], [6, 1], [10, 0], [3, 11]], "caption": "Figure 4. Second generation scale-up synthesis of 1 3 HCl 3 H2O.", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 691, 378, 710], "ImageBB": [71, 285, 410, 677]}, "diagram_type": "multiple"}, {"id": 58, "width": 1356, "height": 464, "file_name": "op100267p-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1077.11, 307.98, 70.8, 53.8], "category_id": 3}, {"id": 1, "bbox": [138.96, 305.84, 46.6, 56.5], "category_id": 3}, {"id": 2, "bbox": [906.4, 0.0, 431.2, 270.7], "category_id": 1}, {"id": 3, "bbox": [2.0, 41.7, 366.8, 224.9], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [4, 5], "products": [2]}], "corefs": [[3, 1], [2, 0]], "caption": "Figure 1. Three-step telescoped synthesis of electron-de\ufb01cient amide- substituted arylboronic acids. ", "pdf": {"Page": 1, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 453, 771, 481], "ImageBB": [436, 323, 775, 439]}, "diagram_type": "single"}, {"id": 59, "width": 1356, "height": 780, "file_name": "op100202j-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.3, 358.1, 450.3, 80.8], "category_id": 1}, {"id": 1, "bbox": [685.1, 28.0, 662.6, 239.0], "category_id": 1}, {"id": 2, "bbox": [825.8, 234.6, 253.2, 234.9], "category_id": 1}, {"id": 3, "bbox": [93.5, 3.0, 255.8, 236.2], "category_id": 1}, {"id": 4, "bbox": [481.0, 425.5, 875.0, 354.5], "category_id": 1}], "reactions": [{"reactants": [3, 0], "conditions": [5], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [4]}], "corefs": [], "caption": "Table 3. Some typical values of absorption bands in the IR spectra of 6-isopropylisocytosine and 6-phenylisocytosine ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 286, 751, 313], "ImageBB": [424, 79, 763, 274]}, "diagram_type": "tree"}, {"id": 60, "width": 2816, "height": 948, "file_name": "op100072y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2038.63, 248.75, 68.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [664.88, 244.0, 57.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [1337.24, 0.75, 536.36, 216.35], "category_id": 1}, {"id": 3, "bbox": [1556.88, 244.75, 54.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1908.6, 3.0, 457.4, 214.3], "category_id": 1}, {"id": 5, "bbox": [454.1, 6.0, 525.9, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [7, 6], "products": [2, 4]}], "corefs": [[5, 1], [2, 3], [4, 0]], "caption": "Table 1. Hydrogenolysis vs dechlorination selectivity varying solvent or inorganic additives", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 358, 558, 372], "ImageBB": [58, 372, 762, 609]}, "diagram_type": "single"}, {"id": 61, "width": 1348, "height": 668, "file_name": "ol0619157-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [95.3, 5.0, 293.6, 149.9], "category_id": 1}, {"id": 1, "bbox": [964.8, 6.9, 289.2, 148.0], "category_id": 1}, {"id": 2, "bbox": [215.0, 170.0, 38.1, 57.0], "category_id": 3}, {"id": 3, "bbox": [1087.9, 170.0, 49.1, 52.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [4, 5], "products": [1]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 2. Catalytic Asymmetric Conjugate Reduction of Enones", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 440, 775, 453], "ImageBB": [439, 457, 776, 624]}, "diagram_type": "single"}, {"id": 62, "width": 1352, "height": 1092, "file_name": "ol061289d-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [898.0, 458.0, 43.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [669.81, 136.0, 458.49, 312.07], "category_id": 1}, {"id": 2, "bbox": [213.0, 210.07, 387.0, 171.0], "category_id": 1}, {"id": 3, "bbox": [362.0, 458.0, 50.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [], "products": [5]}], "corefs": [[2, 3], [1, 0]], "caption": "Figure 2. HPLC chromatographs for the reaction of 4 with bromoacetylated Val-OMe. HPLC conditions: Kromasil C18, 0-65% B in A over 30 min, A ) H2O + 0.1% TFA, B ) CH3CN + 0.08% TFA. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 337, 775, 392], "ImageBB": [439, 52, 777, 325]}, "diagram_type": "single"}, {"id": 63, "width": 1344, "height": 1160, "file_name": "ol060664z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1076.0, 223.0, 46.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [86.0, 225.0, 42.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [957.0, 7.1, 317.1, 248.7], "category_id": 1}, {"id": 3, "bbox": [71.3, 1.6, 270.4, 274.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 3], "products": [5]}], "corefs": [[3, 1], [2, 0]], "caption": "Table 2. Formation of Pyrroles 3 from 1 and Amines 2a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 372, 89], "ImageBB": [74, 98, 410, 388]}, "diagram_type": "single"}, {"id": 64, "width": 1352, "height": 2216, "file_name": "ol060473w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [118.0, 57.0, 184.0, 138.4], "category_id": 1}, {"id": 1, "bbox": [924.8, 0.0, 355.5, 255.1], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Direct Amidation of Quinoline and Isoquinoline N-Oxides with Various Amides ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 193, 743, 221], "ImageBB": [439, 222, 777, 776]}, "diagram_type": "single"}, {"id": 65, "width": 1352, "height": 1076, "file_name": "ol0604623-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [357.0, 55.0, 264.0, 165.0], "category_id": 1}, {"id": 1, "bbox": [554.0, 226.0, 80.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [1025.0, 209.0, 85.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [911.0, 2.0, 344.0, 264.0], "category_id": 1}, {"id": 4, "bbox": [92.0, 22.0, 366.0, 212.0], "category_id": 1}, {"id": 5, "bbox": [284.0, 231.0, 61.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [9, 5, 0], "conditions": [6, 7], "products": [4]}], "corefs": [[4, 5], [0, 1], [3, 2]], "caption": "Table 2. Formation of Functionalized Pyrazoline by Reaction of PPh3-DIAD Zwitterion with 6 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 262, 399, 290], "ImageBB": [73, 295, 411, 564]}, "diagram_type": "single"}, {"id": 66, "width": 1344, "height": 1424, "file_name": "ol051920v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [148.0, 14.0, 182.0, 172.0], "category_id": 1}, {"id": 1, "bbox": [384.0, 56.0, 158.0, 140.0], "category_id": 1}, {"id": 2, "bbox": [951.0, 1.0, 249.0, 182.0], "category_id": 1}, {"id": 3, "bbox": [1054.0, 195.0, 49.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [418.0, 206.0, 51.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [175.0, 197.0, 51.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [2, 3], "conditions": [8, 0], "products": [4]}], "corefs": [[0, 5], [1, 4], [2, 3]], "caption": "Table 1. Reactions of Salicylaldehyde 1a (0.5 mmol) with 3-Methylpenta-3,4-dien-2-one 2a (2.0 mmol) in the Presence of Various Lewis Bases and Solvents ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 402, 120], "ImageBB": [74, 125, 410, 481]}, "diagram_type": "single"}, {"id": 67, "width": 1344, "height": 1964, "file_name": "ol051488h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [267.0, 764.0, 455.0, 247.0], "category_id": 3}, {"id": 1, "bbox": [49.0, 0.0, 195.0, 224.0], "category_id": 1}, {"id": 2, "bbox": [260.0, 1.0, 220.6, 168.7], "category_id": 1}, {"id": 3, "bbox": [870.0, 0.0, 410.0, 225.0], "category_id": 1}, {"id": 4, "bbox": [849.0, 291.0, 454.0, 168.0], "category_id": 1}, {"id": 5, "bbox": [58.0, 519.0, 122.0, 172.0], "category_id": 1}, {"id": 6, "bbox": [269.0, 496.0, 284.0, 273.0], "category_id": 1}, {"id": 7, "bbox": [617.0, 504.0, 285.0, 191.0], "category_id": 1}, {"id": 8, "bbox": [948.0, 511.0, 292.0, 224.0], "category_id": 1}, {"id": 9, "bbox": [143.0, 210.0, 59.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [328.0, 209.0, 76.0, 56.0], "category_id": 3}, {"id": 11, "bbox": [1053.0, 206.0, 63.0, 63.0], "category_id": 3}, {"id": 12, "bbox": [664.0, 696.0, 64.0, 59.0], "category_id": 3}, {"id": 13, "bbox": [998.0, 696.0, 68.0, 61.0], "category_id": 3}, {"id": 14, "bbox": [104.0, 701.0, 68.0, 57.0], "category_id": 3}, {"id": 15, "bbox": [1064.0, 446.0, 37.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [3, 5], "conditions": [4, 2], "products": [6, 7]}], "corefs": [[1, 9], [2, 10], [3, 11], [4, 15], [5, 14], [6, 0], [7, 12], [8, 13]], "caption": "Table 1. Asymmetric Conjugate Addition of Isovaleraldehyde 3a to Vinyl Sulfones 1-2 Catalyzed by Various Amines 4a-g ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 410, 401, 438], "ImageBB": [74, 443, 410, 934]}, "diagram_type": "single"}, {"id": 68, "width": 1344, "height": 868, "file_name": "jo025987x-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.0, 274.0, 244.0, 106.0], "category_id": 3}, {"id": 1, "bbox": [1039.0, 274.0, 86.0, 52.9], "category_id": 3}, {"id": 2, "bbox": [874.0, 1.0, 252.0, 353.0], "category_id": 1}, {"id": 3, "bbox": [203.0, 7.0, 193.0, 367.0], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [4, 7], "products": [2]}], "corefs": [[3, 0], [2, 1]], "caption": "Figure 2. d No separation by chiral HPLC.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [100, 315, 321, 328], "ImageBB": [74, 99, 410, 316]}, "diagram_type": "single"}, {"id": 69, "width": 1344, "height": 484, "file_name": "jo0109321-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1080.0, 17.0, 225.0, 222.0], "category_id": 1}, {"id": 1, "bbox": [712.0, 21.0, 343.0, 174.0], "category_id": 1}, {"id": 2, "bbox": [28.0, 3.0, 243.0, 173.0], "category_id": 1}, {"id": 3, "bbox": [865.0, 197.0, 31.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [1154.0, 209.0, 32.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [3, 1, 2], "products": [5, 4]}], "corefs": [[1, 3], [0, 4]], "caption": "Table 7. Hydroboration of 3,3-Dimethyl-1-butene with                 BH3-THF in THFa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [82, 716, 401, 742], "ImageBB": [74, 750, 410, 871]}, "diagram_type": "single"}, {"id": 70, "width": 1368, "height": 1880, "file_name": "jo0014414-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [382.7, 1222.6, 232.3, 237.8], "category_id": 1}, {"id": 1, "bbox": [783.5, 1224.0, 229.5, 243.0], "category_id": 1}, {"id": 2, "bbox": [389.0, 1536.2, 221.7, 270.9], "category_id": 1}, {"id": 3, "bbox": [764.0, 249.0, 604.0, 504.1], "category_id": 1}, {"id": 4, "bbox": [527.6, 371.6, 202.0, 295.9], "category_id": 1}, {"id": 5, "bbox": [107.2, 394.7, 272.6, 208.4], "category_id": 1}, {"id": 6, "bbox": [974.2, 871.2, 324.8, 263.1], "category_id": 1}, {"id": 7, "bbox": [803.9, 1540.5, 202.2, 292.9], "category_id": 1}, {"id": 8, "bbox": [458.6, 867.7, 272.4, 266.9], "category_id": 1}, {"id": 9, "bbox": [562.06, 1148.0, 58.4, 55.3], "category_id": 3}, {"id": 10, "bbox": [888.3, 1827.5, 63.7, 52.5], "category_id": 3}, {"id": 11, "bbox": [478.0, 1829.0, 76.0, 40.0], "category_id": 3}, {"id": 12, "bbox": [210.0, 648.0, 69.0, 83.0], "category_id": 3}, {"id": 13, "bbox": [583.0, 681.0, 65.0, 61.0], "category_id": 3}, {"id": 14, "bbox": [1129.0, 684.0, 69.0, 69.0], "category_id": 3}, {"id": 15, "bbox": [1082.0, 1148.0, 69.0, 50.0], "category_id": 3}, {"id": 16, "bbox": [467.0, 1474.0, 65.0, 65.0], "category_id": 3}, {"id": 17, "bbox": [876.0, 1474.0, 61.0, 61.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [3]}, {"reactants": [13], "conditions": [24, 9], "products": [8]}, {"reactants": [8], "conditions": [23, 10], "products": [6]}, {"reactants": [6], "conditions": [11, 12], "products": [0]}, {"reactants": [0], "conditions": [21, 20], "products": [1]}, {"reactants": [1], "conditions": [22, 14], "products": [2]}, {"reactants": [2], "conditions": [15, 16], "products": [7]}], "corefs": [[5, 12], [4, 13], [3, 14], [8, 9], [6, 15], [0, 16], [1, 17], [2, 11], [7, 10]], "caption": "Table 1. Stereo- and Regioselectivities in the Reduction                    of Hajos Dione (1) ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 518, 772, 543], "ImageBB": [424, 35, 766, 505]}, "diagram_type": "multiple"}, {"id": 71, "width": 1336, "height": 1152, "file_name": "jo000694u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [959.4, 82.7, 376.6, 423.3], "category_id": 1}, {"id": 1, "bbox": [15.69, 667.69, 380.91, 444.0], "category_id": 1}, {"id": 2, "bbox": [534.0, 95.69, 385.0, 420.0], "category_id": 1}, {"id": 3, "bbox": [683.0, 512.0, 47.0, 36.3], "category_id": 3}, {"id": 4, "bbox": [1091.0, 503.7, 59.3, 43.3], "category_id": 3}, {"id": 5, "bbox": [4.0, 106.0, 313.4, 407.7], "category_id": 1}, {"id": 6, "bbox": [150.0, 1104.0, 47.0, 43.0], "category_id": 3}, {"id": 7, "bbox": [131.0, 507.0, 48.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [6], "products": [2, 0]}, {"reactants": [5], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [], "products": [2]}], "corefs": [[5, 7], [2, 3], [0, 4], [1, 6]], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 148, 131, 161], "ImageBB": [75, 171, 409, 459]}, "diagram_type": "graph"}, {"id": 72, "width": 1692, "height": 1828, "file_name": "jo000081h-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [859.38, 13.3, 289.19, 130.0], "category_id": 1}, {"id": 1, "bbox": [306.5, 348.0, 1058.9, 141.5], "category_id": 1}, {"id": 2, "bbox": [477.5, 0.7, 166.7, 138.2], "category_id": 1}, {"id": 3, "bbox": [8.0, 1076.0, 403.0, 301.1], "category_id": 1}, {"id": 4, "bbox": [561.0, 1082.0, 401.0, 286.1], "category_id": 1}, {"id": 5, "bbox": [57.0, 1571.5, 340.0, 256.5], "category_id": 1}, {"id": 6, "bbox": [1081.0, 1076.0, 418.0, 294.0], "category_id": 1}, {"id": 7, "bbox": [509.0, 1503.0, 455.0, 325.0], "category_id": 1}, {"id": 8, "bbox": [1398.0, 391.0, 72.0, 61.0], "category_id": 3}, {"id": 9, "bbox": [1211.0, 1580.9, 338.0, 247.1], "category_id": 1}, {"id": 10, "bbox": [1038.0, 578.0, 457.0, 426.4], "category_id": 1}, {"id": 11, "bbox": [543.0, 592.0, 432.8, 412.0], "category_id": 1}, {"id": 12, "bbox": [10.0, 603.7, 439.3, 390.4], "category_id": 1}], "reactions": [{"reactants": [16], "conditions": [19], "products": [4]}, {"reactants": [4], "conditions": [10], "products": [5]}, {"reactants": [5], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [15], "products": [8]}, {"reactants": [8], "conditions": [20, 1], "products": [14]}], "corefs": [[1, 8]], "caption": "Figure 4. Proposed terpenoid biosynthetic pathway, based upon 13C acetate labeling studies, for the production of the mangicol carbon skeleton. ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 535, 775, 562], "ImageBB": [214, 65, 637, 522]}, "diagram_type": "tree"}, {"id": 73, "width": 1348, "height": 1276, "file_name": "acs.orglett.5b01842-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [859.0, 5.0, 299.0, 146.7], "category_id": 1}, {"id": 1, "bbox": [416.9, 22.0, 228.1, 62.0], "category_id": 1}, {"id": 2, "bbox": [191.4, 5.0, 168.3, 126.6], "category_id": 1}, {"id": 3, "bbox": [494.0, 130.0, 33.0, 31.0], "category_id": 3}, {"id": 4, "bbox": [263.0, 134.0, 28.0, 31.0], "category_id": 3}, {"id": 5, "bbox": [1001.0, 146.0, 32.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [2], "products": [0]}], "corefs": [[2, 4], [1, 3], [0, 5]], "caption": "Table 1. Reductive Amination of Phenol: Reaction Condition Optimization ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 523, 417, 553], "ImageBB": [82, 560, 419, 879]}, "diagram_type": "single"}, {"id": 74, "width": 1352, "height": 1368, "file_name": "acs.orglett.5b01077-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1012.0, 237.0, 87.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [220.0, 237.0, 49.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [390.0, 21.0, 182.0, 206.0], "category_id": 1}, {"id": 3, "bbox": [868.0, 0.0, 410.0, 249.0], "category_id": 1}, {"id": 4, "bbox": [456.0, 229.0, 95.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [76.0, 16.0, 250.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [7, 3], "conditions": [5, 2], "products": [4]}], "corefs": [[5, 1], [2, 4], [3, 0]], "caption": "Table 2. Nitrone Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 586, 111], "ImageBB": [448, 116, 786, 458]}, "diagram_type": "single"}, {"id": 75, "width": 1348, "height": 1140, "file_name": "acs.orglett.5b00776-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [754.6, 0.0, 535.4, 395.0], "category_id": 1}, {"id": 1, "bbox": [301.0, 324.9, 290.0, 310.1], "category_id": 1}, {"id": 2, "bbox": [44.0, 312.9, 270.0, 311.1], "category_id": 1}, {"id": 3, "bbox": [1120.0, 336.0, 73.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [718.0, 523.0, 587.0, 326.0], "category_id": 1}, {"id": 5, "bbox": [1122.0, 820.0, 71.0, 59.0], "category_id": 3}, {"id": 6, "bbox": [202.0, 635.0, 69.0, 56.0], "category_id": 3}, {"id": 7, "bbox": [438.0, 639.0, 73.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [7], "products": [0, 4]}], "corefs": [[2, 6], [1, 7], [0, 3], [4, 5]], "caption": "Table 1. C versus N Selectivity in Reaction of AH 1a with DD 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 152, 410, 186], "ImageBB": [82, 193, 419, 478]}, "diagram_type": "single"}, {"id": 76, "width": 1356, "height": 348, "file_name": "acs.oprd.6b00180-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1038.0, 38.4, 314.9, 204.8], "category_id": 1}, {"id": 1, "bbox": [7.0, 65.6, 253.0, 137.4], "category_id": 1}, {"id": 2, "bbox": [327.2, 65.3, 301.8, 123.5], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [6, 7], "products": [3]}], "corefs": [], "caption": "Figure 3. Suzuki reaction of 4-bromoanisole with 3-aminophenylbor- onic acid using Pd(OAc)2/K3PO4/H2O in the absence of added ligand. ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 746, 784, 788], "ImageBB": [448, 650, 787, 737]}, "diagram_type": "single"}, {"id": 77, "width": 3396, "height": 2004, "file_name": "acs.oprd.5b00312-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1136.4, 387.5, 397.8, 243.7], "category_id": 1}, {"id": 1, "bbox": [1755.0, 421.2, 389.5, 155.5], "category_id": 1}, {"id": 2, "bbox": [1941.35, 800.27, 288.95, 194.93], "category_id": 1}, {"id": 3, "bbox": [1837.0, 311.0, 300.0, 62.0], "category_id": 3}, {"id": 4, "bbox": [1222.0, 304.0, 271.0, 66.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5], "products": [1]}], "corefs": [[0, 4], [1, 3]], "caption": "Figure 1. (A\u2212C) UHPLC/UV chromatograms at 254 nm for (A) unreacted compound 3, (B) the HCl control, and (C) the TiCl3/HCl-treated sample. (D, E) High-resolution mass spectra of (D) compound 3 and (E) reduced quinoxaline compound 3a. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 537, 784, 565], "ImageBB": [10, 22, 859, 523]}, "diagram_type": "single"}, {"id": 78, "width": 1356, "height": 808, "file_name": "acs.oprd.5b00282-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [961.0, 45.0, 277.0, 326.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 98.0, 276.0, 272.0], "category_id": 1}], "reactions": [{"reactants": [1, 3, 5], "conditions": [2], "products": [0, 8, 6]}, {"reactants": [0, 8, 6], "conditions": [], "products": [1, 3, 5]}, {"reactants": [9], "conditions": [10], "products": [11]}, {"reactants": [11], "conditions": [], "products": [12]}], "corefs": [], "caption": "Figure 1. Bio-oxidation/hydroxylation reaction of \u03b1-isophorone to 4- hydroxy-\u03b1-isophorone. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 820, 784, 851], "ImageBB": [448, 612, 787, 814]}, "diagram_type": "graph"}, {"id": 79, "width": 1172, "height": 816, "file_name": "ol501514b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 20.0, 271.0, 144.0], "category_id": 1}, {"id": 1, "bbox": [344.0, 40.0, 244.0, 126.0], "category_id": 1}, {"id": 2, "bbox": [894.0, 5.0, 274.0, 181.0], "category_id": 1}, {"id": 3, "bbox": [974.0, 167.0, 60.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [444.0, 166.0, 42.0, 33.0], "category_id": 3}, {"id": 5, "bbox": [126.0, 165.0, 44.0, 34.0], "category_id": 3}], "reactions": [{"reactants": [1, 2], "conditions": [7, 8], "products": [3]}], "corefs": [[0, 5], [1, 4], [2, 3]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 345, 110], "ImageBB": [104, 116, 397, 320]}, "diagram_type": "single"}, {"id": 80, "width": 1332, "height": 1824, "file_name": "ol501422k-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [53.1, 716.7, 349.9, 137.3], "category_id": 1}, {"id": 1, "bbox": [438.0, 1010.0, 419.0, 144.0], "category_id": 1}, {"id": 2, "bbox": [414.0, 705.0, 443.0, 153.0], "category_id": 1}, {"id": 3, "bbox": [1140.0, 191.0, 110.0, 75.0], "category_id": 3}, {"id": 4, "bbox": [150.0, 202.0, 97.0, 76.0], "category_id": 3}, {"id": 5, "bbox": [558.0, 1766.0, 49.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [1026.0, 1774.0, 44.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [982.0, 1603.0, 347.0, 146.0], "category_id": 1}, {"id": 8, "bbox": [494.0, 1607.0, 356.0, 183.0], "category_id": 1}, {"id": 9, "bbox": [105.0, 882.0, 139.5, 44.2], "category_id": 3}, {"id": 10, "bbox": [551.0, 1491.0, 138.2, 41.0], "category_id": 3}, {"id": 11, "bbox": [54.0, 1597.0, 353.0, 141.0], "category_id": 1}, {"id": 12, "bbox": [1042.0, 1487.0, 121.8, 43.2], "category_id": 3}, {"id": 13, "bbox": [106.0, 1170.0, 137.0, 41.8], "category_id": 3}, {"id": 14, "bbox": [551.0, 1175.0, 137.2, 42.0], "category_id": 3}, {"id": 15, "bbox": [1042.0, 1175.0, 128.2, 42.4], "category_id": 3}, {"id": 16, "bbox": [44.0, 7.0, 331.3, 149.0], "category_id": 1}, {"id": 17, "bbox": [102.0, 1489.0, 143.4, 35.4], "category_id": 3}, {"id": 18, "bbox": [894.0, 1318.0, 438.0, 144.0], "category_id": 1}, {"id": 19, "bbox": [434.0, 1321.0, 423.0, 141.0], "category_id": 1}, {"id": 20, "bbox": [555.0, 890.0, 135.0, 41.4], "category_id": 3}, {"id": 21, "bbox": [109.0, 1773.0, 35.0, 46.0], "category_id": 3}, {"id": 22, "bbox": [419.74, 13.11, 135.01, 121.77], "category_id": 1}, {"id": 23, "bbox": [908.0, 4.0, 359.0, 149.0], "category_id": 1}, {"id": 24, "bbox": [10.0, 1318.0, 397.0, 142.0], "category_id": 1}, {"id": 25, "bbox": [914.0, 1006.0, 417.0, 146.0], "category_id": 1}, {"id": 26, "bbox": [3.0, 1011.0, 401.0, 141.0], "category_id": 1}], "reactions": [{"reactants": [18, 24], "conditions": [29, 26], "products": [25]}], "corefs": [[16, 4], [23, 3], [0, 9], [2, 20], [26, 13], [1, 14], [25, 15], [24, 17], [19, 10], [18, 12], [11, 21], [8, 5], [7, 6]], "caption": "Table 4. Nucleophilc Addition of Alkylazaarenes to tert-Butyl Nitritea ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 424, 417, 458], "ImageBB": [84, 464, 417, 920]}, "diagram_type": "single"}, {"id": 81, "width": 1352, "height": 680, "file_name": "ol403122a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [606.0, 49.6, 645.4, 201.9], "category_id": 1}, {"id": 1, "bbox": [96.6, 48.8, 502.4, 200.2], "category_id": 1}, {"id": 2, "bbox": [129.0, 356.0, 430.0, 239.0], "category_id": 1}, {"id": 3, "bbox": [709.0, 322.0, 459.0, 271.0], "category_id": 1}], "reactions": [], "corefs": [], "caption": "Figure 1. Representative biologically active sulfones.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 765, 336, 779], "ImageBB": [82, 586, 420, 756]}, "diagram_type": "single"}, {"id": 82, "width": 1476, "height": 2912, "file_name": "ol4025293-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [145.7, 1079.4, 482.2, 453.7], "category_id": 1}, {"id": 1, "bbox": [316.0, 267.0, 145.3, 269.0], "category_id": 1}, {"id": 2, "bbox": [915.0, 1586.2, 407.7, 467.0], "category_id": 1}, {"id": 3, "bbox": [282.1, 1583.7, 330.4, 458.9], "category_id": 1}, {"id": 4, "bbox": [721.9, 1080.0, 435.0, 449.0], "category_id": 1}, {"id": 5, "bbox": [645.3, 649.7, 333.5, 374.3], "category_id": 1}, {"id": 6, "bbox": [970.5, 689.5, 373.0, 147.1], "category_id": 1}, {"id": 7, "bbox": [226.7, 650.0, 346.0, 373.1], "category_id": 1}, {"id": 8, "bbox": [505.0, 269.3, 223.3, 117.7], "category_id": 1}, {"id": 9, "bbox": [380.0, 590.0, 33.0, 39.0], "category_id": 3}, {"id": 10, "bbox": [1025.0, 2061.0, 150.0, 54.0], "category_id": 3}, {"id": 11, "bbox": [406.0, 2068.0, 33.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [378.0, 1545.0, 24.0, 24.0], "category_id": 3}, {"id": 13, "bbox": [919.0, 1536.0, 44.0, 38.0], "category_id": 3}, {"id": 14, "bbox": [426.0, 1034.0, 41.0, 31.0], "category_id": 3}, {"id": 15, "bbox": [859.0, 1036.0, 41.0, 26.0], "category_id": 3}, {"id": 16, "bbox": [831.0, 595.0, 37.0, 56.0], "category_id": 3}, {"id": 17, "bbox": [682.0, 206.0, 329.0, 387.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [9, 27], "products": [28]}, {"reactants": [28], "conditions": [26, 25], "products": [7]}, {"reactants": [7], "conditions": [23, 24], "products": [5]}, {"reactants": [5], "conditions": [6, 8], "products": [0]}, {"reactants": [0], "conditions": [12, 11], "products": [4]}, {"reactants": [4], "conditions": [14, 13], "products": [3]}, {"reactants": [3], "conditions": [15], "products": [2]}], "corefs": [[1, 9], [17, 16], [7, 14], [5, 15], [0, 12], [4, 13], [3, 11], [2, 10]], "caption": "Figure 1. Fluorescence spectra of probe 1 (5 \u03bcM, \u03bbex = 440 nm) in the presence of various metal ions (Li\u00fe, Zn2\u00fe, Ba2\u00fe, Mn2\u00fe, Hg2\u00fe, K\u00fe, Na\u00fe, Ca2\u00fe, Sr2\u00fe, Mg2\u00fe, Fe2\u00fe, Fe3\u00fe, and Cu2\u00fe) (A), and different concentrations of Cu2\u00fe ions (0 2500 \u03bcM) (B) in HEPES buffer (10 mM, pH 7.4). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 797, 771, 869], "ImageBB": [404, 59, 773, 787]}, "diagram_type": "multiple"}, {"id": 83, "width": 1348, "height": 1636, "file_name": "ol401881n-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [834.3, 0.0, 367.9, 239.1], "category_id": 1}, {"id": 1, "bbox": [147.5, 40.3, 389.9, 207.9], "category_id": 1}, {"id": 2, "bbox": [954.3, 237.0, 44.7, 52.6], "category_id": 3}, {"id": 3, "bbox": [291.0, 247.0, 46.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 1], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 2. DABCO-Catalyzed Anion Relay Leading to Functionalized 2,3-Dihydrofuransa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 354, 114], "ImageBB": [71, 126, 408, 535]}, "diagram_type": "single"}, {"id": 84, "width": 1352, "height": 1152, "file_name": "ol0480731-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1036.0, 68.0, 248.6, 202.0], "category_id": 1}, {"id": 1, "bbox": [597.7, 75.0, 158.0, 133.0], "category_id": 1}, {"id": 2, "bbox": [58.0, 0.0, 445.0, 302.0], "category_id": 1}, {"id": 3, "bbox": [96.0, 254.0, 135.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [2, 6], "products": [0]}], "corefs": [[2, 3]], "caption": "Table 1. Syn-Selective Aldehyde Crotylation with (R,R)-2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 547, 380, 560], "ImageBB": [73, 561, 411, 849]}, "diagram_type": "single"}, {"id": 85, "width": 1348, "height": 1100, "file_name": "ol0349920-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [620.94, 356.85, 191.69, 87.0], "category_id": 1}, {"id": 1, "bbox": [113.0, 159.0, 316.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [442.0, 7.0, 439.0, 298.0], "category_id": 1}, {"id": 3, "bbox": [896.0, 200.0, 339.0, 206.0], "category_id": 1}, {"id": 4, "bbox": [837.0, 249.0, 36.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 5, 4, 0, 3], "products": [7]}], "corefs": [[2, 4]], "caption": "Table 1. Enantioselective Deuteride Reduction of Various Aldimines or Their Equivalents Derived from p-Phenylbenzaldehydea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 747, 120], "ImageBB": [439, 125, 776, 400]}, "diagram_type": "single"}, {"id": 86, "width": 1348, "height": 1088, "file_name": "ol034469l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [932.0, 18.0, 228.0, 189.0], "category_id": 1}, {"id": 1, "bbox": [193.0, 63.0, 378.0, 143.0], "category_id": 1}, {"id": 2, "bbox": [1018.0, 201.0, 75.0, 55.0], "category_id": 3}, {"id": 3, "bbox": [346.0, 201.0, 72.0, 60.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 0], "products": [1]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Screen of Solvents and Br\u00f8nsted Acids", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 314, 698, 327], "ImageBB": [439, 331, 776, 603]}, "diagram_type": "single"}, {"id": 87, "width": 1348, "height": 904, "file_name": "ol026156g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [407.5, 2.4, 326.7, 295.0], "category_id": 1}, {"id": 1, "bbox": [1132.0, 356.0, 61.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [55.5, 86.0, 274.8, 131.5], "category_id": 1}, {"id": 3, "bbox": [517.3, 354.6, 88.7, 46.4], "category_id": 3}, {"id": 4, "bbox": [1018.9, 9.7, 284.1, 282.3], "category_id": 1}], "reactions": [{"reactants": [3, 0], "conditions": [7, 5], "products": [8]}], "corefs": [[0, 3], [4, 1]], "caption": "Table 1. Effects of R-Amino Acids in 2 on Catalytic Asymmetric Coupling of 2-Naphthol in CCl4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 478, 721, 510], "ImageBB": [439, 520, 776, 746]}, "diagram_type": "single"}, {"id": 88, "width": 1348, "height": 1112, "file_name": "ol0157003-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [960.18, 0.0, 310.05, 217.56], "category_id": 1}, {"id": 1, "bbox": [645.66, 0.0, 304.09, 217.56], "category_id": 1}, {"id": 2, "bbox": [1088.38, 225.01, 59.62, 49.19], "category_id": 3}, {"id": 3, "bbox": [77.74, 4.4, 378.62, 211.67], "category_id": 1}, {"id": 4, "bbox": [775.35, 225.01, 55.15, 47.7], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [7], "products": [1, 0]}], "corefs": [[1, 4], [0, 2]], "caption": "Table 1. Rearrangements of Syn Acetals 6s-10sa", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 246, 705, 260], "ImageBB": [439, 264, 776, 542]}, "diagram_type": "single"}, {"id": 89, "width": 1348, "height": 604, "file_name": "jo990938e-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [707.56, 148.53, 95.56, 40.67], "category_id": 3}, {"id": 1, "bbox": [985.09, 148.53, 96.57, 42.7], "category_id": 3}, {"id": 2, "bbox": [228.0, 148.0, 187.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [628.0, 1.0, 257.0, 193.0], "category_id": 1}, {"id": 4, "bbox": [184.0, 21.0, 273.0, 125.0], "category_id": 1}, {"id": 5, "bbox": [905.0, 4.0, 260.0, 192.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [9, 8, 7], "products": [3, 10]}], "corefs": [[4, 2], [3, 0], [5, 1]], "caption": "Table 4. Additions of Allenylmetal Reagents Prepared          from Allenyl Iodide 6 to Aldehyde 3a ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [447, 64, 767, 89], "ImageBB": [439, 98, 776, 249]}, "diagram_type": "single"}, {"id": 90, "width": 1348, "height": 1044, "file_name": "jo990528q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [212.0, 2.0, 237.2, 144.0], "category_id": 1}, {"id": 1, "bbox": [810.0, 362.2, 354.0, 190.2], "category_id": 1}, {"id": 2, "bbox": [293.6, 136.4, 26.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [914.4, 532.0, 102.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [493.2, 344.0, 244.8, 109.8], "category_id": 1}, {"id": 5, "bbox": [212.8, 390.2, 180.2, 145.2], "category_id": 1}, {"id": 6, "bbox": [696.0, 351.0, 89.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [282.0, 537.0, 37.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [4, 6], "products": [1]}], "corefs": [[0, 2], [5, 7], [4, 6], [1, 3]], "caption": "Table 1. Reaction of 2 with r,\u03b2-Unsaturated thioester                         3a-e ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 353, 765, 380], "ImageBB": [439, 390, 776, 651]}, "diagram_type": "tree"}, {"id": 91, "width": 1340, "height": 1760, "file_name": "jo982004g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [810.55, 559.45, 470.01, 199.24], "category_id": 1}, {"id": 1, "bbox": [524.0, 818.7, 419.0, 287.3], "category_id": 1}, {"id": 2, "bbox": [369.3, 774.0, 53.2, 46.4], "category_id": 3}, {"id": 3, "bbox": [713.28, 1100.64, 43.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [168.1, 1508.0, 523.3, 209.6], "category_id": 1}, {"id": 5, "bbox": [475.0, 244.6, 358.7, 130.4], "category_id": 1}, {"id": 6, "bbox": [741.9, 1500.4, 507.6, 212.4], "category_id": 1}, {"id": 7, "bbox": [234.7, 610.2, 362.5, 112.7], "category_id": 1}, {"id": 8, "bbox": [962.5, 1368.29, 44.82, 51.9], "category_id": 3}, {"id": 9, "bbox": [358.53, 1712.74, 49.55, 47.26], "category_id": 3}, {"id": 10, "bbox": [924.75, 1710.38, 49.55, 47.19], "category_id": 3}, {"id": 11, "bbox": [1003.0, 780.0, 44.0, 49.0], "category_id": 3}, {"id": 12, "bbox": [565.0, 393.0, 308.0, 147.0], "category_id": 3}, {"id": 13, "bbox": [784.0, 1272.0, 541.1, 104.8], "category_id": 1}], "reactions": [{"reactants": [22, 11], "conditions": [2, 3], "products": [0]}, {"reactants": [0], "conditions": [21], "products": [4]}, {"reactants": [15, 1], "conditions": [16, 10], "products": [23]}, {"reactants": [23], "conditions": [17], "products": [7, 9]}], "corefs": [[5, 12], [7, 2], [0, 11], [1, 3], [13, 8], [4, 9], [6, 10]], "caption": "Table 1. Diastereomeric Ratio (dr) of Adducts Shown in                       Scheme 2 ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 486, 772, 511], "ImageBB": [426, 35, 761, 475]}, "diagram_type": "tree"}, {"id": 92, "width": 1384, "height": 1620, "file_name": "jo961824v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1081.0, 1516.0, 27.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [88.0, 308.0, 285.0, 214.0], "category_id": 1}, {"id": 2, "bbox": [573.0, 244.0, 232.0, 427.0], "category_id": 1}, {"id": 3, "bbox": [94.0, 892.0, 470.0, 552.0], "category_id": 1}, {"id": 4, "bbox": [878.0, 895.0, 469.0, 555.0], "category_id": 1}, {"id": 5, "bbox": [610.0, 694.0, 436.0, 149.0], "category_id": 3}, {"id": 6, "bbox": [128.0, 723.0, 417.9, 93.7], "category_id": 3}, {"id": 7, "bbox": [219.0, 1476.3, 396.3, 141.7], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [3, 2], "products": [5]}, {"reactants": [5], "conditions": [8, 7], "products": [6]}], "corefs": [[1, 6], [2, 5], [3, 7], [4, 0]], "caption": " Table 1. BF3-Promoted Addition Reaction of 1,2-Naphthoquinones with 1,1-Diarylethylenesa ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [469, 437, 743, 462], "ImageBB": [424, 20, 770, 425]}, "diagram_type": "multiple"}, {"id": 93, "width": 1156, "height": 1316, "file_name": "jo961365y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [711.0, 1253.0, 66.0, 57.0], "category_id": 3}, {"id": 1, "bbox": [355.0, 190.0, 205.0, 92.0], "category_id": 1}, {"id": 2, "bbox": [155.0, 1264.0, 68.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [692.0, 727.0, 116.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [170.0, 726.0, 116.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [461.0, 287.0, 26.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [590.0, 539.0, 305.0, 183.0], "category_id": 1}, {"id": 7, "bbox": [42.6, 1076.0, 377.4, 186.0], "category_id": 1}, {"id": 8, "bbox": [86.3, 554.9, 305.7, 165.1], "category_id": 1}, {"id": 9, "bbox": [549.0, 1079.0, 395.0, 183.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [12, 10], "products": [15]}, {"reactants": [1], "conditions": [12, 11], "products": [13]}, {"reactants": [15], "conditions": [9, 8], "products": [14]}, {"reactants": [13], "conditions": [7, 6], "products": [16]}], "corefs": [[1, 5], [8, 4], [6, 3], [7, 2], [9, 0]], "caption": "Table 1. Comparison of the % of Enantiomeric Excess of    (R)- and (S)-6 in Asymmetric Dihydroxylation of 5 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 361, 772, 386], "ImageBB": [486, 20, 775, 349]}, "diagram_type": "tree"}, {"id": 94, "width": 1348, "height": 868, "file_name": "jo951899j-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [319.0, 291.0, 96.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [971.0, 283.0, 97.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [134.0, 51.0, 421.0, 209.0], "category_id": 1}, {"id": 3, "bbox": [819.0, 52.0, 395.0, 209.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [1, 6], "products": [5]}], "corefs": [[2, 0], [3, 1]], "caption": "Table 6. Removal of the MEE Ester Protecting Group       from \u03b2-Glycosidic Conjugates with Papain ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [438, 277, 755, 302], "ImageBB": [429, 311, 766, 528]}, "diagram_type": "single"}, {"id": 95, "width": 1348, "height": 1084, "file_name": "jo951899j-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [873.0, 347.0, 140.6, 46.7], "category_id": 3}, {"id": 1, "bbox": [264.37, 426.95, 251.8, 207.3], "category_id": 3}, {"id": 2, "bbox": [772.3, 34.8, 429.7, 292.8], "category_id": 1}, {"id": 3, "bbox": [146.8, 152.2, 396.1, 237.6], "category_id": 1}, {"id": 4, "bbox": [175.0, 373.0, 85.4, 50.0], "category_id": 3}], "reactions": [{"reactants": [7, 5], "conditions": [3, 8], "products": [4]}], "corefs": [[3, 4], [3, 1], [2, 0]], "caption": "Table 4. Synthesis of the Saccharide Amino Acid                Conjugates 11a-f ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [85, 594, 375, 619], "ImageBB": [63, 628, 400, 899]}, "diagram_type": "single"}, {"id": 96, "width": 1348, "height": 348, "file_name": "jo501785d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1057.0, 200.0, 74.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [338.0, 55.0, 303.0, 126.0], "category_id": 1}, {"id": 2, "bbox": [950.0, 9.0, 345.0, 216.0], "category_id": 1}, {"id": 3, "bbox": [172.0, 203.0, 52.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [463.0, 203.0, 51.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [55.0, 49.0, 246.0, 178.0], "category_id": 1}], "reactions": [{"reactants": [7, 1], "conditions": [4, 3], "products": [2]}], "corefs": [[5, 3], [1, 4], [2, 0]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 371, 110], "ImageBB": [82, 116, 419, 203]}, "diagram_type": "single"}, {"id": 97, "width": 1348, "height": 288, "file_name": "jo501006u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [602.85, 55.01, 246.01, 51.84], "category_id": 1}, {"id": 1, "bbox": [1125.1, 95.3, 136.4, 51.5], "category_id": 1}, {"id": 2, "bbox": [340.3, 86.0, 203.4, 52.3], "category_id": 1}, {"id": 3, "bbox": [81.0, 79.0, 107.0, 64.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [4, 2, 3, 6], "products": [5]}], "corefs": [], "caption": "Table 1. Coupling Reaction of Alkyl (Pseudo)halides with n- BuMgCl Using Phenylpropyne as an Additivea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 353, 417, 387], "ImageBB": [82, 394, 419, 466]}, "diagram_type": "single"}, {"id": 98, "width": 1416, "height": 916, "file_name": "jo501006u-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [114.0, 113.0, 179.5, 63.0], "category_id": 1}, {"id": 1, "bbox": [1138.0, 122.0, 219.0, 53.0], "category_id": 1}, {"id": 2, "bbox": [583.03, 93.13, 255.26, 43.87], "category_id": 1}, {"id": 3, "bbox": [372.98, 113.07, 203.41, 63.81], "category_id": 1}], "reactions": [{"reactants": [0, 6], "conditions": [3, 5, 2, 1], "products": [4]}], "corefs": [], "caption": "Figure 4. Time-courses of the cross coupling reaction of n-NonCl with n-BuMgCl with 5 mol % of CuCl2 and 300 mol % (\u25c6), 100 mol % (\u25a0), 50 mol % (\u25b2), 10 mol % (\u25cf), or 5 mol % (\u25c7) of phenylpropyne. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 613, 784, 669], "ImageBB": [433, 375, 787, 604]}, "diagram_type": "single"}, {"id": 99, "width": 3396, "height": 1416, "file_name": "jo4027148-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2290.5, 434.6, 183.4, 116.0], "category_id": 1}, {"id": 1, "bbox": [1105.0, 381.0, 622.0, 369.6], "category_id": 1}, {"id": 2, "bbox": [1846.2, 388.0, 265.8, 346.0], "category_id": 1}, {"id": 3, "bbox": [751.0, 416.2, 315.0, 117.8], "category_id": 1}, {"id": 4, "bbox": [1019.7, 963.84, 190.1, 113.6], "category_id": 1}, {"id": 5, "bbox": [2611.0, 1293.0, 53.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [2627.0, 388.0, 429.0, 370.0], "category_id": 1}, {"id": 7, "bbox": [412.0, 378.0, 297.0, 384.0], "category_id": 1}, {"id": 8, "bbox": [1421.0, 924.0, 277.0, 338.0], "category_id": 1}, {"id": 9, "bbox": [531.0, 923.0, 280.0, 349.0], "category_id": 1}, {"id": 10, "bbox": [1871.0, 923.0, 409.0, 356.0], "category_id": 1}, {"id": 11, "bbox": [2426.0, 924.0, 422.0, 351.0], "category_id": 1}, {"id": 12, "bbox": [1957.0, 784.0, 50.0, 49.0], "category_id": 3}, {"id": 13, "bbox": [1388.0, 785.0, 56.0, 48.0], "category_id": 3}, {"id": 14, "bbox": [2044.0, 1293.0, 53.0, 37.0], "category_id": 3}, {"id": 15, "bbox": [1529.0, 1293.0, 49.0, 44.0], "category_id": 3}, {"id": 16, "bbox": [2811.0, 789.0, 49.0, 35.0], "category_id": 3}, {"id": 17, "bbox": [640.0, 1293.0, 61.0, 47.0], "category_id": 3}, {"id": 18, "bbox": [539.0, 789.0, 56.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [18, 3, 24, 25], "products": [1]}, {"reactants": [2], "conditions": [19, 0, 23, 12], "products": [6]}, {"reactants": [9], "conditions": [17, 4, 26], "products": [8, 10, 11]}], "corefs": [[7, 18], [1, 13], [2, 12], [6, 16], [9, 17], [8, 15], [10, 14], [11, 5]], "caption": "Figure 5. (A) Daugulis\u2019 methylene C\u2212H arylation. (B) Statistical arylation of 28 with 1 equiv of iodobenzene.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 386, 620, 400], "ImageBB": [10, 22, 859, 376]}, "diagram_type": "multiple"}, {"id": 100, "width": 1348, "height": 404, "file_name": "jo4014707-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1034.0, 13.0, 186.0, 202.0], "category_id": 1}, {"id": 1, "bbox": [134.3, 13.0, 110.3, 187.0], "category_id": 1}, {"id": 2, "bbox": [179.0, 213.0, 29.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [1060.0, 217.0, 102.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [2, 7], "conditions": [0, 8], "products": [1]}], "corefs": [[1, 2], [0, 3]], "caption": "Table 2. Asymmetric 1,4-Addition at Low Temperaturea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 640, 400, 661], "ImageBB": [82, 667, 419, 768]}, "diagram_type": "single"}, {"id": 101, "width": 1348, "height": 1872, "file_name": "jo4014707-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [469.5, 837.0, 253.5, 185.2], "category_id": 1}, {"id": 1, "bbox": [65.0, 396.7, 360.5, 316.3], "category_id": 1}, {"id": 2, "bbox": [547.0, 745.0, 280.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [1051.0, 656.0, 126.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [112.0, 15.0, 124.0, 194.0], "category_id": 1}, {"id": 5, "bbox": [953.0, 468.0, 330.0, 180.0], "category_id": 1}, {"id": 6, "bbox": [463.32, 1031.44, 258.46, 203.26], "category_id": 1}, {"id": 7, "bbox": [483.0, 405.0, 405.0, 313.0], "category_id": 1}, {"id": 8, "bbox": [63.0, 859.0, 367.0, 310.0], "category_id": 1}, {"id": 9, "bbox": [161.0, 227.0, 36.0, 45.0], "category_id": 3}, {"id": 10, "bbox": [1067.0, 19.0, 199.0, 208.0], "category_id": 1}, {"id": 11, "bbox": [1097.0, 232.0, 104.0, 44.0], "category_id": 3}, {"id": 12, "bbox": [152.0, 745.0, 195.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [7, 21], "conditions": [16, 15, 14, 13, 12], "products": [20]}], "corefs": [[4, 9], [10, 11], [1, 12], [7, 2], [5, 3]], "caption": "Table 1. Asymmetric 1,4-Addition of 2a to 1 at 0 \u00b0Ca", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 386, 111], "ImageBB": [82, 116, 419, 584]}, "diagram_type": "single"}, {"id": 102, "width": 2820, "height": 1424, "file_name": "jo401195c-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [552.0, 306.0, 89.0, 41.1], "category_id": 3}, {"id": 1, "bbox": [779.0, 530.5, 206.0, 149.5], "category_id": 1}, {"id": 2, "bbox": [461.0, 583.0, 263.0, 72.0], "category_id": 1}, {"id": 3, "bbox": [1987.0, 67.0, 318.0, 215.0], "category_id": 1}, {"id": 4, "bbox": [2119.0, 720.0, 52.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [1771.0, 718.0, 57.0, 50.0], "category_id": 3}, {"id": 6, "bbox": [846.0, 305.0, 63.0, 44.0], "category_id": 3}, {"id": 7, "bbox": [1743.0, 313.0, 39.0, 41.0], "category_id": 3}, {"id": 8, "bbox": [2122.0, 312.0, 52.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [1655.0, 33.0, 254.0, 262.0], "category_id": 1}, {"id": 10, "bbox": [2012.0, 537.0, 270.0, 152.0], "category_id": 1}, {"id": 11, "bbox": [1636.0, 518.0, 325.0, 139.0], "category_id": 1}, {"id": 12, "bbox": [854.0, 713.0, 53.0, 42.0], "category_id": 3}, {"id": 13, "bbox": [566.0, 712.0, 61.0, 46.0], "category_id": 3}, {"id": 14, "bbox": [487.0, 135.0, 218.0, 163.0], "category_id": 1}, {"id": 15, "bbox": [748.0, 132.0, 255.0, 150.0], "category_id": 1}], "reactions": [{"reactants": [20, 21, 4, 2], "conditions": [16, 0], "products": [13, 6, 15, 14]}], "corefs": [[14, 0], [15, 6], [9, 7], [3, 8], [2, 13], [1, 12], [11, 5], [10, 4]], "caption": "Table 6. Concurrent and Competitive Acetylation of trans-Diol (\u00b1)-1 and meso-Diol 28 with Catalyst 12b and DMAP", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 474, 746, 494], "ImageBB": [82, 116, 787, 472]}, "diagram_type": "single"}, {"id": 103, "width": 2820, "height": 2776, "file_name": "jo400755q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [964.1, 944.0, 408.3, 412.7], "category_id": 1}, {"id": 1, "bbox": [1417.28, 408.0, 398.6, 418.0], "category_id": 1}, {"id": 2, "bbox": [481.0, 937.0, 491.0, 469.0], "category_id": 1}, {"id": 3, "bbox": [1378.7, 947.0, 437.3, 422.0], "category_id": 1}, {"id": 4, "bbox": [1805.6, 940.0, 474.4, 419.0], "category_id": 1}, {"id": 5, "bbox": [529.0, 1525.2, 415.6, 446.6], "category_id": 1}, {"id": 6, "bbox": [983.44, 1532.6, 415.0, 419.0], "category_id": 1}, {"id": 7, "bbox": [1421.28, 1528.2, 398.0, 423.8], "category_id": 1}, {"id": 8, "bbox": [1880.7, 1532.2, 414.9, 416.8], "category_id": 1}, {"id": 9, "bbox": [502.0, 2101.0, 316.0, 432.0], "category_id": 1}, {"id": 10, "bbox": [947.3, 2109.2, 307.1, 428.2], "category_id": 1}, {"id": 11, "bbox": [1368.2, 2105.9, 334.0, 440.1], "category_id": 1}, {"id": 12, "bbox": [1829.0, 2101.4, 465.4, 323.9], "category_id": 1}, {"id": 13, "bbox": [520.0, 408.0, 427.6, 394.0], "category_id": 1}, {"id": 14, "bbox": [726.0, 0.0, 338.9, 318.3], "category_id": 1}, {"id": 15, "bbox": [1391.0, 3.0, 334.3, 313.0], "category_id": 1}, {"id": 16, "bbox": [1377.0, 2562.28, 247.0, 54.0], "category_id": 3}, {"id": 17, "bbox": [1825.56, 2549.72, 243.0, 71.0], "category_id": 3}, {"id": 18, "bbox": [824.2, 286.0, 112.2, 43.6], "category_id": 3}, {"id": 19, "bbox": [1485.5, 279.0, 98.3, 50.3], "category_id": 3}, {"id": 20, "bbox": [1063.0, 1420.0, 250.0, 57.0], "category_id": 3}, {"id": 21, "bbox": [976.0, 401.0, 411.0, 402.0], "category_id": 1}, {"id": 22, "bbox": [1854.0, 394.0, 391.0, 422.0], "category_id": 1}, {"id": 23, "bbox": [773.0, 826.0, 81.0, 71.0], "category_id": 3}, {"id": 24, "bbox": [1209.0, 826.0, 74.0, 64.0], "category_id": 3}, {"id": 25, "bbox": [1553.0, 836.0, 247.0, 67.0], "category_id": 3}, {"id": 26, "bbox": [1958.0, 836.0, 260.0, 64.0], "category_id": 3}, {"id": 27, "bbox": [604.0, 1416.0, 270.0, 68.0], "category_id": 3}, {"id": 28, "bbox": [1654.0, 1413.0, 81.0, 67.0], "category_id": 3}, {"id": 29, "bbox": [2093.0, 1420.0, 71.0, 60.0], "category_id": 3}, {"id": 30, "bbox": [607.0, 2017.0, 260.0, 54.0], "category_id": 3}, {"id": 31, "bbox": [1239.0, 2010.0, 67.0, 57.0], "category_id": 3}, {"id": 32, "bbox": [1648.0, 2010.0, 70.0, 54.0], "category_id": 3}, {"id": 33, "bbox": [1968.0, 2017.0, 230.0, 60.0], "category_id": 3}, {"id": 34, "bbox": [496.0, 2553.0, 243.0, 74.0], "category_id": 3}, {"id": 35, "bbox": [945.0, 2563.0, 243.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [14], "conditions": [16, 25], "products": [15]}], "corefs": [[14, 18], [15, 19], [13, 23], [21, 24], [1, 25], [22, 26], [2, 27], [0, 20], [3, 28], [4, 29], [5, 30], [6, 31], [7, 32], [8, 33], [9, 34], [10, 35], [11, 16], [12, 17]], "caption": "Table 2. Ortho-Bromination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 529, 111], "ImageBB": [82, 116, 787, 810]}, "diagram_type": "single"}, {"id": 104, "width": 1348, "height": 400, "file_name": "jo4004426-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [291.0, 32.0, 181.8, 268.0], "category_id": 1}, {"id": 1, "bbox": [49.0, 36.0, 128.0, 265.0], "category_id": 1}, {"id": 2, "bbox": [169.0, 238.0, 30.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [460.0, 238.0, 32.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [959.0, 6.0, 336.0, 291.0], "category_id": 1}, {"id": 5, "bbox": [1129.0, 234.0, 31.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [7, 0], "products": [5]}], "corefs": [[1, 2], [0, 3], [4, 5]], "caption": "Table 1. Optimization Studies with a Homogeneous Metal Source ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 412, 125], "ImageBB": [82, 131, 419, 231]}, "diagram_type": "single"}, {"id": 105, "width": 1352, "height": 260, "file_name": "jo302439t-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [503.6, 49.2, 346.9, 86.0], "category_id": 1}, {"id": 1, "bbox": [1078.9, 45.4, 270.1, 173.6], "category_id": 1}, {"id": 2, "bbox": [0.0, 39.0, 281.0, 177.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [5]}], "corefs": [], "caption": "Figure 4. Compound 5 at 0.4 M concentration in THF-d8 solution. 13   C NMR line shapes for C2 and C3 (left) observed at di\ufb00erent temperatures, K, and (right) calculated to \ufb01t with \ufb01rst-order rate constants. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 566, 417, 623], "ImageBB": [82, 626, 420, 691]}, "diagram_type": "single"}, {"id": 106, "width": 1352, "height": 512, "file_name": "jo302288z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [31.0, 242.0, 416.0, 133.0], "category_id": 1}, {"id": 1, "bbox": [159.0, 6.0, 166.0, 183.0], "category_id": 1}, {"id": 2, "bbox": [799.0, 57.0, 370.0, 302.0], "category_id": 1}, {"id": 3, "bbox": [216.0, 376.0, 52.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [5, 6], "products": [3]}], "corefs": [[0, 3]], "caption": "Table 3. Michael Reactions of 1a with 2 by Catalyst 3f under Solvent-Free Conditions for 2 ha ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 629, 417, 659], "ImageBB": [82, 494, 420, 622]}, "diagram_type": "single"}, {"id": 107, "width": 1352, "height": 1120, "file_name": "jo201996w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [378.1, 22.0, 205.9, 163.0], "category_id": 1}, {"id": 1, "bbox": [1136.0, 236.0, 32.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [103.0, 238.0, 39.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [347.0, 234.0, 264.0, 148.0], "category_id": 3}, {"id": 4, "bbox": [957.8, 5.0, 370.2, 212.0], "category_id": 1}, {"id": 5, "bbox": [33.9, 27.0, 221.1, 161.0], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [1, 2], "products": [6]}], "corefs": [[5, 2], [0, 3], [4, 1]], "caption": "Table 1. Synthesis of 2,2\u2032-Dinitrogen-Substituted Azo- benzenes 3 ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 235, 405, 266], "ImageBB": [69, 272, 407, 552]}, "diagram_type": "single"}, {"id": 108, "width": 1344, "height": 1168, "file_name": "jo2008675-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [416.0, 224.0, 32.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [92.0, 211.0, 97.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [334.0, 82.0, 233.0, 117.0], "category_id": 1}, {"id": 3, "bbox": [973.0, 37.0, 368.0, 177.0], "category_id": 1}, {"id": 4, "bbox": [3.0, 2.0, 241.0, 204.0], "category_id": 1}, {"id": 5, "bbox": [1142.0, 216.0, 102.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [4, 2], "conditions": [7, 6], "products": [3]}], "corefs": [[4, 1], [2, 0], [3, 5]], "caption": "Table 3. Synthesis of Di\ufb00erently Substituted 2, 3-Dihydrobenzofuransa ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 698, 122], "ImageBB": [437, 133, 773, 425]}, "diagram_type": "single"}, {"id": 109, "width": 1356, "height": 992, "file_name": "jo2003264-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [306.0, 102.0, 135.0, 47.0], "category_id": 1}, {"id": 1, "bbox": [354.0, 166.0, 31.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [86.0, 163.0, 45.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 102.0, 213.0, 47.0], "category_id": 1}, {"id": 4, "bbox": [707.0, 327.0, 53.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [1111.0, 329.0, 53.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [554.28, 198.83, 294.0, 128.0], "category_id": 1}, {"id": 7, "bbox": [941.0, 198.83, 415.0, 127.0], "category_id": 1}], "reactions": [{"reactants": [3, 0], "conditions": [10, 4], "products": [7, 8]}], "corefs": [[3, 2], [0, 1], [6, 4], [7, 5]], "caption": "Table 2. E\ufb00ects of Additives in the Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of 1a with 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 759, 122], "ImageBB": [436, 133, 775, 381]}, "diagram_type": "multiple"}, {"id": 110, "width": 1352, "height": 680, "file_name": "ol701624y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [267.0, 278.0, 78.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [106.0, 44.0, 365.0, 212.0], "category_id": 1}, {"id": 2, "bbox": [883.0, 3.0, 364.0, 279.0], "category_id": 1}, {"id": 3, "bbox": [907.0, 281.0, 73.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 5, 1], "products": [3]}], "corefs": [[1, 0], [2, 3]], "caption": "Table 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 486, 89], "ImageBB": [439, 93, 777, 263]}, "diagram_type": "single"}, {"id": 111, "width": 1356, "height": 940, "file_name": "acs.joc.5b00632-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [786.0, 43.0, 434.0, 187.0], "category_id": 1}, {"id": 1, "bbox": [136.0, 43.0, 345.0, 188.0], "category_id": 1}, {"id": 2, "bbox": [162.0, 351.0, 418.0, 233.0], "category_id": 1}, {"id": 3, "bbox": [794.0, 344.0, 417.0, 197.0], "category_id": 1}, {"id": 4, "bbox": [166.0, 681.0, 332.0, 246.0], "category_id": 1}, {"id": 5, "bbox": [662.0, 690.0, 330.0, 246.0], "category_id": 1}, {"id": 6, "bbox": [860.2, 550.0, 347.8, 46.0], "category_id": 3}, {"id": 7, "bbox": [172.0, 243.0, 269.0, 92.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [4], "conditions": [8], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [0], "products": [6]}, {"reactants": [6], "conditions": [], "products": [9]}], "corefs": [[1, 7], [3, 6]], "caption": "Figure 2. Proposed clopidogrel bioactivation pathway.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 869, 712, 883], "ImageBB": [448, 625, 787, 860]}, "diagram_type": "tree"}, {"id": 112, "width": 1352, "height": 668, "file_name": "jacs.5b05415-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1148.82, 231.42, 51.21, 39.13], "category_id": 3}, {"id": 1, "bbox": [889.81, 231.42, 52.08, 39.13], "category_id": 3}, {"id": 2, "bbox": [163.74, 213.29, 49.48, 37.4], "category_id": 3}, {"id": 3, "bbox": [1061.62, 48.4, 226.47, 176.39], "category_id": 1}, {"id": 4, "bbox": [833.7, 46.67, 163.44, 161.72], "category_id": 1}, {"id": 5, "bbox": [61.0, 420.5, 300.72, 180.71], "category_id": 1}, {"id": 6, "bbox": [77.4, 76.02, 228.2, 125.46], "category_id": 1}, {"id": 7, "bbox": [161.15, 606.98, 52.94, 40.85], "category_id": 3}], "reactions": [{"reactants": [14], "conditions": [1, 0], "products": [12, 11]}, {"reactants": [14], "conditions": [9, 15], "products": [13]}, {"reactants": [13], "conditions": [18, 20, 17], "products": [3, 2]}], "corefs": [[6, 2], [4, 1], [3, 0], [5, 7]], "caption": "Figure 4. Mechanistic investigation.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 414, 254, 428], "ImageBB": [82, 237, 420, 404]}, "diagram_type": "tree"}, {"id": 113, "width": 1348, "height": 1228, "file_name": "ja905415r-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [256.84, 313.25, 54.29, 44.78], "category_id": 3}, {"id": 1, "bbox": [1099.8, 313.25, 59.05, 44.78], "category_id": 3}, {"id": 2, "bbox": [969.87, 2.68, 263.45, 304.65], "category_id": 1}, {"id": 3, "bbox": [107.9, 61.31, 350.59, 244.43], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [0, 1], "products": [4]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 3. Asymmetric Au(I)-Catalyzed [4C+2C] Cycloadditions and Development of an Efficient Enantioselective Chiral Gold Catalysta ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 57, 758, 81], "ImageBB": [425, 90, 762, 397]}, "diagram_type": "single"}, {"id": 114, "width": 1348, "height": 720, "file_name": "ja9039289-Table-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1025.0, 173.54, 30.8, 36.38], "category_id": 3}, {"id": 1, "bbox": [802.96, 53.79, 474.88, 108.84], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [4, 3], "products": [2]}], "corefs": [[1, 0]], "caption": "Table 10. Reaction of Cobalt and Nickel Salts with p-TolMgBr in the Presence of IPr \u00b7 HCl ", "pdf": {"Page": 9, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 245, 747, 269], "ImageBB": [425, 277, 762, 457]}, "diagram_type": "single"}, {"id": 115, "width": 1356, "height": 1208, "file_name": "ja406383h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1101.35, 93.32, 176.08, 236.63], "category_id": 1}, {"id": 1, "bbox": [194.59, 396.07, 213.93, 106.46], "category_id": 1}, {"id": 2, "bbox": [324.78, 61.53, 176.08, 215.47], "category_id": 1}, {"id": 3, "bbox": [896.99, 751.81, 406.18, 374.4], "category_id": 1}, {"id": 4, "bbox": [56.83, 82.72, 226.05, 168.52], "category_id": 1}, {"id": 5, "bbox": [545.79, 106.94, 215.44, 191.22], "category_id": 1}, {"id": 6, "bbox": [68.95, 891.08, 328.97, 238.15], "category_id": 1}, {"id": 7, "bbox": [454.96, 374.88, 212.42, 167.0], "category_id": 1}, {"id": 8, "bbox": [974.19, 356.72, 256.31, 177.59], "category_id": 1}, {"id": 9, "bbox": [127.98, 644.33, 377.42, 168.52], "category_id": 1}, {"id": 10, "bbox": [518.54, 677.64, 142.78, 121.59], "category_id": 1}, {"id": 11, "bbox": [884.88, 93.32, 194.25, 236.63], "category_id": 1}, {"id": 12, "bbox": [417.12, 889.57, 453.1, 236.63], "category_id": 1}], "reactions": [{"reactants": [15, 16], "conditions": [6, 7], "products": [11, 24, 5]}], "corefs": [], "caption": "Figure 1. (a) Potential utilities of the amidated products obtained in this study. (b) Synthesis of benzanilides bearing peptides using the present Ir-catalyzed C\u2212H amidation. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 533, 784, 575], "ImageBB": [448, 222, 787, 524]}, "diagram_type": "multiple"}, {"id": 116, "width": 1344, "height": 1332, "file_name": "ja208286b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [207.66, 355.22, 27.04, 33.71], "category_id": 3}, {"id": 1, "bbox": [968.8, 71.46, 270.74, 504.42], "category_id": 1}, {"id": 2, "bbox": [484.74, 3.02, 305.79, 195.63], "category_id": 1}, {"id": 3, "bbox": [105.84, 71.46, 255.72, 275.74], "category_id": 1}, {"id": 4, "bbox": [695.06, 156.58, 48.74, 37.06], "category_id": 3}, {"id": 5, "bbox": [1167.44, 355.22, 48.73, 38.72], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 0], "products": [3]}], "corefs": [[3, 0], [2, 4], [1, 5]], "caption": "Table 1. Optimization Studies for the Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridine (1)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 404, 122], "ImageBB": [71, 133, 407, 466]}, "diagram_type": "single"}, {"id": 117, "width": 1412, "height": 3028, "file_name": "ja208286b-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [188.6, 2073.83, 90.24, 43.48], "category_id": 3}, {"id": 1, "bbox": [718.96, 1854.09, 44.36, 33.77], "category_id": 3}, {"id": 2, "bbox": [780.74, 1495.81, 27.59, 32.89], "category_id": 3}, {"id": 3, "bbox": [1062.25, 1164.0, 47.89, 35.53], "category_id": 3}, {"id": 4, "bbox": [99.7, 449.9, 375.6, 370.53], "category_id": 1}, {"id": 5, "bbox": [513.96, 307.59, 300.63, 192.61], "category_id": 1}, {"id": 6, "bbox": [909.17, 336.81, 267.59, 495.09], "category_id": 1}, {"id": 7, "bbox": [136.54, 1001.42, 252.34, 273.95], "category_id": 1}, {"id": 8, "bbox": [489.81, 837.5, 300.63, 193.88], "category_id": 1}, {"id": 9, "bbox": [900.27, 881.97, 266.32, 493.79], "category_id": 1}, {"id": 10, "bbox": [483.46, 1277.18, 374.33, 370.52], "category_id": 1}, {"id": 11, "bbox": [80.63, 1768.97, 305.71, 272.67], "category_id": 1}, {"id": 12, "bbox": [508.88, 1701.62, 301.9, 192.61], "category_id": 1}, {"id": 13, "bbox": [906.62, 1762.61, 304.45, 495.06], "category_id": 1}, {"id": 14, "bbox": [416.28, 698.05, 27.62, 33.77], "category_id": 3}, {"id": 15, "bbox": [1094.02, 695.4, 47.0, 36.42], "category_id": 3}, {"id": 16, "bbox": [812.51, 406.83, 44.36, 33.77], "category_id": 3}, {"id": 17, "bbox": [339.5, 1183.41, 23.18, 34.65], "category_id": 3}, {"id": 18, "bbox": [788.68, 931.91, 46.12, 34.65], "category_id": 3}, {"id": 19, "bbox": [1131.08, 2055.3, 111.43, 40.83], "category_id": 3}], "reactions": [{"reactants": [10], "conditions": [11, 20, 21], "products": [12]}, {"reactants": [13], "conditions": [14, 6, 5, 16], "products": [15]}, {"reactants": [17], "conditions": [18, 1], "products": [19, 27]}], "corefs": [[4, 14], [5, 16], [6, 15], [7, 17], [8, 18], [9, 3], [10, 2], [11, 0], [12, 1], [13, 19]], "caption": "Figure 1. Single-crystal X-ray structure of the novel meta product 3a. Ellipsoids are represented at 30% probability. ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 279, 771, 307], "ImageBB": [420, 307, 773, 1064]}, "diagram_type": "multiple"}, {"id": 118, "width": 1344, "height": 1668, "file_name": "ja206047h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [348.08, 100.39, 165.04, 102.33], "category_id": 1}, {"id": 1, "bbox": [1073.39, 108.75, 257.01, 156.68], "category_id": 1}, {"id": 2, "bbox": [15.74, 92.03, 261.19, 165.04], "category_id": 1}, {"id": 3, "bbox": [189.23, 271.8, 45.89, 34.7], "category_id": 3}, {"id": 4, "bbox": [686.7, 4.24, 198.48, 171.31], "category_id": 1}, {"id": 5, "bbox": [1187.86, 272.45, 43.3, 33.5], "category_id": 3}, {"id": 6, "bbox": [477.68, 271.79, 29.12, 33.41], "category_id": 3}], "reactions": [{"reactants": [4, 0], "conditions": [7, 6], "products": [1]}], "corefs": [[2, 3], [0, 6], [1, 5]], "caption": "Table 1. Optimization of Catalytic Enantioselective Arylation", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 396, 108], "ImageBB": [71, 117, 407, 534]}, "diagram_type": "single"}, {"id": 119, "width": 2816, "height": 1156, "file_name": "ja1048847-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1568.01, 245.3, 32.09, 37.41], "category_id": 3}, {"id": 1, "bbox": [1457.02, 25.87, 301.43, 178.26], "category_id": 1}, {"id": 2, "bbox": [695.53, 241.77, 203.75, 85.18], "category_id": 3}, {"id": 3, "bbox": [1813.79, 4.63, 322.68, 216.49], "category_id": 1}, {"id": 4, "bbox": [675.5, 2.51, 324.8, 218.61], "category_id": 1}, {"id": 5, "bbox": [1888.33, 231.16, 51.56, 49.78], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [7, 6], "products": [2, 4]}], "corefs": [[4, 2], [1, 0], [3, 5]], "caption": "Table 1. Synthesis of Cyclobutarenes: Study of C(sp3)-H Arylation Parameters", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 56, 455, 69], "ImageBB": [58, 78, 762, 367]}, "diagram_type": "single"}, {"id": 120, "width": 2128, "height": 1584, "file_name": "ja0516864-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [630.45, 475.0, 22.55, 33.27], "category_id": 3}, {"id": 1, "bbox": [439.22, 1536.16, 27.94, 35.35], "category_id": 3}, {"id": 2, "bbox": [1619.3, 1475.0, 172.49, 98.37], "category_id": 3}, {"id": 3, "bbox": [1109.87, 1475.03, 305.83, 102.04], "category_id": 3}, {"id": 4, "bbox": [828.27, 1536.16, 26.09, 33.5], "category_id": 3}, {"id": 5, "bbox": [4.22, 101.67, 392.88, 116.87], "category_id": 1}, {"id": 6, "bbox": [98.71, 272.11, 233.59, 96.49], "category_id": 1}, {"id": 7, "bbox": [495.17, 94.26, 389.23, 324.36], "category_id": 1}, {"id": 8, "bbox": [1197.3, 88.7, 389.22, 326.21], "category_id": 1}, {"id": 9, "bbox": [1710.5, 7.19, 320.65, 444.78], "category_id": 1}, {"id": 10, "bbox": [1365.75, 474.1, 21.66, 33.27], "category_id": 3}, {"id": 11, "bbox": [1869.65, 475.0, 17.19, 33.27], "category_id": 3}, {"id": 12, "bbox": [287.31, 1089.68, 313.24, 416.99], "category_id": 1}, {"id": 13, "bbox": [674.5, 1085.97, 315.1, 413.29], "category_id": 1}, {"id": 14, "bbox": [1089.49, 1119.32, 291.01, 268.78], "category_id": 1}, {"id": 15, "bbox": [1491.52, 1130.44, 389.18, 159.47], "category_id": 1}, {"id": 16, "bbox": [1982.83, 331.4, 139.1, 37.2], "category_id": 1}], "reactions": [{"reactants": [6, 7], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [11, 12], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10]}], "corefs": [[7, 0], [8, 10], [9, 11], [12, 1], [13, 4], [14, 3], [15, 2]], "caption": "Table 1. Selected Experimental NMR Spectroscopic Data of Aryl-Substituted Vinyl Cations. NMR Chemical Shifts \u03b4 versus TMS, Coupling Constants 1J (Hz) in Bracketsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 487, 766, 511], "ImageBB": [159, 80, 691, 476]}, "diagram_type": "single"}, {"id": 121, "width": 1344, "height": 1056, "file_name": "ja0289088-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [252.53, 22.24, 174.72, 127.75], "category_id": 1}, {"id": 1, "bbox": [266.7, 472.18, 22.44, 34.7], "category_id": 3}, {"id": 2, "bbox": [595.09, 484.44, 27.88, 34.71], "category_id": 3}, {"id": 3, "bbox": [984.78, 481.72, 26.53, 34.7], "category_id": 3}, {"id": 4, "bbox": [922.11, 278.69, 221.37, 158.7], "category_id": 1}, {"id": 5, "bbox": [929.76, 23.75, 176.23, 126.24], "category_id": 1}, {"id": 6, "bbox": [551.48, 284.15, 225.47, 157.33], "category_id": 1}, {"id": 7, "bbox": [198.58, 285.51, 218.65, 158.69], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [10, 0], "products": [6]}], "corefs": [[7, 1], [6, 2], [4, 3]], "caption": "Table 1. Asymmetric Epoxidation of 1-Phenylcyclohexene Using Chiral Amines as Catalyst ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 398, 88], "ImageBB": [74, 96, 410, 360]}, "diagram_type": "single"}, {"id": 122, "width": 1220, "height": 1384, "file_name": "op970113b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 647.1, 287.3], "category_id": 1}, {"id": 1, "bbox": [0.0, 435.1, 584.4, 312.6], "category_id": 1}, {"id": 2, "bbox": [16.1, 957.5, 588.7, 300.8], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [7, 1], "products": [4]}], "corefs": [], "caption": "Table 1. Scale-up of benzoyl migration method and comparison to original Sharpless methoda,b ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 427, 361, 455], "ImageBB": [112, 69, 417, 415]}, "diagram_type": "multiple"}, {"id": 123, "width": 2816, "height": 2116, "file_name": "op700249f-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [591.0, 354.9, 258.0, 87.1], "category_id": 3}, {"id": 1, "bbox": [1967.0, 358.0, 115.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [1626.0, 30.0, 743.0, 309.0], "category_id": 1}, {"id": 3, "bbox": [1163.0, 3.0, 266.0, 147.0], "category_id": 1}, {"id": 4, "bbox": [464.0, 71.0, 627.0, 258.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0], "products": [4]}], "corefs": [[4, 0], [2, 1]], "caption": "Figure 3. Reaction profile of triazole-linked glycosidic amino acid 45 with glycinamide. identity of the impurities could not be established, although it    concomitant decreas was clear that enzymatic hydrolysis of the starting material was    by HPLC resulting  not an issue. Since glycinamide was added to the reaction           2). Next, a slightly  mixture in excess, formation of a tripeptide (NTGA-Gly-Gly-         involving addition of NH2) might be one of the possibilities.                             to methyl ester 45 in ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 841, 536, 940], "ImageBB": [58, 308, 762, 837]}, "diagram_type": "single"}, {"id": 124, "width": 1352, "height": 1204, "file_name": "op7001694-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [983.0, 226.23, 52.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [795.0, 3.0, 399.5, 197.0], "category_id": 1}, {"id": 2, "bbox": [151.0, 45.0, 265.0, 160.0], "category_id": 1}, {"id": 3, "bbox": [259.0, 227.0, 47.9, 56.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1, 7], "products": [3]}], "corefs": [[2, 3], [1, 0]], "caption": "Table 1. Solvent effect on the decarboxylative Blaise reaction of 4a ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 259, 347, 286], "ImageBB": [58, 301, 396, 602]}, "diagram_type": "single"}, {"id": 125, "width": 2816, "height": 1752, "file_name": "op700160a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [379.9, 1370.4, 322.1, 304.8], "category_id": 1}, {"id": 1, "bbox": [911.0, 258.3, 61.3, 54.4], "category_id": 3}, {"id": 2, "bbox": [635.0, 259.0, 46.4, 51.0], "category_id": 3}, {"id": 3, "bbox": [772.3, 24.1, 317.7, 180.8], "category_id": 1}, {"id": 4, "bbox": [1468.8, 1402.2, 368.9, 249.1], "category_id": 1}, {"id": 5, "bbox": [2094.1, 1392.1, 393.5, 266.0], "category_id": 1}, {"id": 6, "bbox": [950.2, 1388.8, 307.5, 273.8], "category_id": 1}, {"id": 7, "bbox": [1969.4, 0.0, 238.5, 232.6], "category_id": 1}, {"id": 8, "bbox": [2037.36, 258.35, 105.68, 63.41], "category_id": 3}, {"id": 9, "bbox": [1727.35, 258.35, 96.29, 61.06], "category_id": 3}, {"id": 10, "bbox": [607.1, 46.8, 116.2, 135.1], "category_id": 1}, {"id": 11, "bbox": [1660.3, 3.0, 238.2, 231.8], "category_id": 1}], "reactions": [{"reactants": [18, 6], "conditions": [14, 16], "products": [19, 13]}], "corefs": [[10, 2], [3, 1], [11, 9], [7, 8]], "caption": "Table 2. Chiral lanthanide camphorate catalysts in bisfuran alcohol formationa", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 493, 59], "ImageBB": [58, 74, 762, 512]}, "diagram_type": "single"}, {"id": 126, "width": 1352, "height": 1088, "file_name": "op500334b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1117.0, 1041.0, 40.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [811.0, 4.0, 510.0, 290.0], "category_id": 1}, {"id": 2, "bbox": [1.0, 736.0, 489.0, 315.0], "category_id": 1}, {"id": 3, "bbox": [98.0, 243.0, 47.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [921.0, 228.0, 45.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [198.0, 1036.0, 43.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [661.0, 1043.0, 51.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [34.5, 0.0, 349.5, 285.4], "category_id": 1}, {"id": 8, "bbox": [550.0, 736.0, 367.0, 305.2], "category_id": 1}, {"id": 9, "bbox": [1012.0, 743.3, 335.0, 297.7], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [8, 12], "products": [2]}], "corefs": [[7, 3], [1, 4], [2, 5], [8, 6], [9, 0]], "caption": "Table 2. Optimization of the copper catalyst and main impurities ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 463, 757, 493], "ImageBB": [448, 499, 786, 771]}, "diagram_type": "single"}, {"id": 127, "width": 1348, "height": 516, "file_name": "op500334b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [763.0, 5.0, 477.0, 277.0], "category_id": 1}, {"id": 1, "bbox": [108.0, 2.0, 313.0, 280.0], "category_id": 1}, {"id": 2, "bbox": [891.0, 251.0, 123.0, 73.0], "category_id": 3}, {"id": 3, "bbox": [157.0, 261.0, 125.0, 70.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Optimization of the Hurtley reaction of 6a, 6b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 463, 396, 478], "ImageBB": [82, 484, 419, 613]}, "diagram_type": "single"}, {"id": 128, "width": 1240, "height": 380, "file_name": "op060249m-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 200.0, 180.0, 129.0], "category_id": 1}, {"id": 1, "bbox": [465.0, 199.0, 326.0, 181.0], "category_id": 1}, {"id": 2, "bbox": [192.0, 3.0, 327.0, 171.0], "category_id": 1}, {"id": 3, "bbox": [828.0, 279.48, 182.93, 39.66], "category_id": 3}, {"id": 4, "bbox": [830.0, 236.0, 188.4, 38.9], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 4, 3], "products": [5]}, {"reactants": [8], "conditions": [1], "products": [7]}], "corefs": [[1, 4], [1, 3]], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 308, 495, 322], "ImageBB": [453, 209, 763, 304]}, "diagram_type": "single"}, {"id": 129, "width": 1300, "height": 660, "file_name": "op0602270-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 5.9, 342.2, 219.1], "category_id": 1}, {"id": 1, "bbox": [936.6, 2.0, 344.8, 224.3], "category_id": 1}, {"id": 2, "bbox": [1064.1, 597.9, 118.9, 51.1], "category_id": 3}, {"id": 3, "bbox": [127.88, 226.96, 88.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [1068.94, 242.02, 126.0, 55.0], "category_id": 3}, {"id": 5, "bbox": [276.06, 600.02, 79.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [961.0, 352.0, 339.0, 223.0], "category_id": 1}, {"id": 7, "bbox": [15.0, 344.0, 233.0, 316.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [7, 8], "products": [1]}, {"reactants": [11], "conditions": [2, 3], "products": [10]}], "corefs": [[0, 3], [1, 4], [7, 5], [6, 2]], "caption": "Table 1. Hydrogenation of E-7 and Z-7 with different 4,5-dihydro-3H-dinaphtho[2,1-c;1\u2032,2\u2032-e]phosphepines (6a-6i) ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 403, 81], "ImageBB": [80, 89, 405, 254]}, "diagram_type": "multiple"}, {"id": 130, "width": 1356, "height": 812, "file_name": "op060175e-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 183.0, 472.0, 344.0], "category_id": 1}, {"id": 1, "bbox": [600.0, 0.0, 481.0, 345.0], "category_id": 1}, {"id": 2, "bbox": [670.0, 428.0, 479.0, 354.0], "category_id": 1}, {"id": 3, "bbox": [192.0, 527.0, 87.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [3], "products": [8, 5]}, {"reactants": [2], "conditions": [4], "products": [9, 6]}], "corefs": [[0, 3]], "caption": "Figure 2. Resolution of 1a and 4 with both antipodes of DPTTA. a: Yields were calculated relative to the theoretical amount, which is half of the starting racemate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 544, 409, 586], "ImageBB": [73, 338, 412, 541]}, "diagram_type": "tree"}, {"id": 131, "width": 1016, "height": 772, "file_name": "op0601316-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [720.0, 462.3, 38.8, 58.4], "category_id": 1}, {"id": 1, "bbox": [837.3, 442.1, 125.2, 99.5], "category_id": 1}, {"id": 2, "bbox": [610.7, 442.0, 84.1, 96.7], "category_id": 1}, {"id": 3, "bbox": [693.1, 249.0, 66.5, 112.0], "category_id": 1}, {"id": 4, "bbox": [839.1, 115.4, 139.9, 156.3], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [2, 0], "conditions": [], "products": [1]}], "corefs": [], "caption": "Figure 5. Rate of HPP and benzoin formation as a function of benzaldehyde concentration. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 250, 409, 278], "ImageBB": [115, 54, 369, 247]}, "diagram_type": "tree"}, {"id": 132, "width": 1344, "height": 1024, "file_name": "op0501242-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [788.0, 6.0, 379.9, 284.0], "category_id": 1}, {"id": 1, "bbox": [176.5, 26.4, 253.9, 209.9], "category_id": 1}, {"id": 2, "bbox": [247.49, 285.75, 56.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [452.2, 29.9, 212.8, 255.2], "category_id": 1}, {"id": 4, "bbox": [956.63, 289.37, 49.1, 40.9], "category_id": 3}, {"id": 5, "bbox": [534.75, 286.0, 59.98, 41.45], "category_id": 3}], "reactions": [{"reactants": [4, 6], "conditions": [0, 1], "products": [3]}], "corefs": [[1, 2], [3, 5], [0, 4]], "caption": "Table 1. Base and solvent screen for the coupling of 2-chloro-4-iodoaniline (1a) with 2,3,4-trifluorobenzoic acid (2a) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 366, 95], "ImageBB": [74, 99, 410, 355]}, "diagram_type": "single"}, {"id": 133, "width": 784, "height": 428, "file_name": "op049889k-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [388.0, 6.0, 302.0, 231.0], "category_id": 1}, {"id": 1, "bbox": [479.0, 250.0, 42.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [578.0, 180.0, 206.0, 177.0], "category_id": 1}, {"id": 3, "bbox": [679.0, 375.0, 37.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [4], "products": [0, 2]}], "corefs": [[0, 1], [2, 3]], "caption": "Figure 3. [3+2] Cycloaddition strategy.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 370, 297, 384], "ImageBB": [144, 258, 340, 365]}, "diagram_type": "single"}, {"id": 134, "width": 2808, "height": 1408, "file_name": "op030202q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [878.3, 3.2, 235.2, 298.7], "category_id": 1}, {"id": 1, "bbox": [1693.5, 11.0, 231.6, 297.5], "category_id": 1}, {"id": 2, "bbox": [983.0, 317.0, 35.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [1800.0, 331.0, 36.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 0], "products": [2]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 1. Aromatic ring hydrogenation of phenyl lactic acid: catalyst screening", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 244, 506, 258], "ImageBB": [74, 263, 776, 615]}, "diagram_type": "single"}, {"id": 135, "width": 1084, "height": 1884, "file_name": "op020019h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [321.0, 6.0, 683.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [356.0, 551.0, 608.0, 193.0], "category_id": 1}, {"id": 2, "bbox": [298.0, 987.0, 623.0, 320.0], "category_id": 1}, {"id": 3, "bbox": [804.0, 1419.0, 191.0, 152.0], "category_id": 1}, {"id": 4, "bbox": [479.0, 1612.0, 353.0, 185.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3], "products": [4]}, {"reactants": [4], "conditions": [0], "products": [5]}, {"reactants": [5], "conditions": [6], "products": [7, 8]}], "corefs": [], "caption": "Figure 1. Periodate-coupled chromogenic assay principle for esterase/lipase activity. C2-CLIPS-O (2-hydroxy-4-(p-nitrophe- noxy)butylacetate (1)), C3-CLIPS-O (2-hydroxy-4-(p-nitrophe- noxy)butylpropionate (2)), C10-CLIPS-O (2-hydroxy-4-(p- nitrophenoxy)butyldecanoate (3)) and C16-CLIPS-O 2-hydroxy- 4-(p-nitrophenoxy)butylpalmitate (4)). ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 529, 775, 612], "ImageBB": [473, 54, 744, 525]}, "diagram_type": "single"}, {"id": 136, "width": 1344, "height": 1132, "file_name": "op0155211-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [979.0, 398.4, 170.0, 226.6], "category_id": 1}, {"id": 1, "bbox": [19.0, 176.54, 169.0, 147.0], "category_id": 1}, {"id": 2, "bbox": [907.0, 166.6, 250.4, 147.9], "category_id": 1}, {"id": 3, "bbox": [95.0, 458.4, 258.4, 158.6], "category_id": 1}, {"id": 4, "bbox": [376.92, 168.29, 136.0, 148.0], "category_id": 1}, {"id": 5, "bbox": [925.2, 841.0, 355.9, 198.6], "category_id": 1}, {"id": 6, "bbox": [506.0, 1083.0, 53.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [166.0, 1074.0, 62.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [435.0, 822.0, 186.0, 211.0], "category_id": 1}, {"id": 9, "bbox": [5.0, 801.0, 282.0, 227.0], "category_id": 1}, {"id": 10, "bbox": [1060.0, 319.0, 56.0, 52.0], "category_id": 3}, {"id": 11, "bbox": [247.0, 633.0, 58.0, 51.0], "category_id": 3}, {"id": 12, "bbox": [1185.5, 224.62, 81.69, 52.51], "category_id": 1}, {"id": 13, "bbox": [354.01, 530.96, 78.77, 56.89], "category_id": 1}, {"id": 14, "bbox": [1268.65, 897.11, 75.35, 58.35], "category_id": 1}, {"id": 15, "bbox": [1058.0, 639.0, 61.0, 44.0], "category_id": 3}, {"id": 16, "bbox": [1058.0, 1078.0, 62.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [5, 11], "products": [2, 18]}, {"reactants": [3, 19], "conditions": [12, 13], "products": [0]}, {"reactants": [10, 9], "conditions": [14, 15], "products": [6, 20]}], "corefs": [[2, 10], [3, 11], [0, 15], [9, 7], [8, 6], [5, 16]], "caption": "Figure 2. Process of kinetic data extraction.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 528, 687, 542], "ImageBB": [440, 551, 776, 834]}, "diagram_type": "tree"}, {"id": 137, "width": 1348, "height": 916, "file_name": "op000095p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [950.0, 0.0, 232.0, 343.0], "category_id": 1}, {"id": 1, "bbox": [621.4, 7.0, 239.9, 335.0], "category_id": 1}, {"id": 2, "bbox": [169.0, 1.0, 263.0, 343.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [3, 2]}], "corefs": [], "caption": "Table 2. Results from Oxidation of Benzylic Alcohols with the Modified Alkaline Nitrobenzene Method ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 496, 761, 524], "ImageBB": [439, 534, 776, 763]}, "diagram_type": "single"}, {"id": 138, "width": 1300, "height": 472, "file_name": "op000070q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [393.36, 29.24, 192.54, 115.06], "category_id": 1}, {"id": 1, "bbox": [1039.09, 2.36, 255.11, 170.84], "category_id": 1}, {"id": 2, "bbox": [507.9, 322.6, 147.6, 147.7], "category_id": 1}, {"id": 3, "bbox": [5.49, 4.85, 238.21, 150.75], "category_id": 1}], "reactions": [{"reactants": [5, 2], "conditions": [1, 0], "products": [3]}], "corefs": [], "caption": "Table 3. Analysis of N-BOC amino acid resins", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 202, 696, 216], "ImageBB": [446, 73, 771, 191]}, "diagram_type": "single"}, {"id": 139, "width": 1352, "height": 1056, "file_name": "ol990836a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1025.0, 28.0, 222.0, 190.0], "category_id": 1}, {"id": 1, "bbox": [802.9, 37.0, 198.1, 186.9], "category_id": 1}, {"id": 2, "bbox": [834.92, 210.2, 52.0, 47.6], "category_id": 3}, {"id": 3, "bbox": [1065.0, 210.8, 54.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [145.1, 54.0, 120.8, 128.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [4, 1], "products": [3, 0]}], "corefs": [[1, 2], [0, 3]], "caption": "Table 1. Rates of Catalysis for the Oxidation of Bromide by Hydrogen Peroxide in the Presence of Phenylseleno-Containing Molecules As Determined by the Rate of Bromination of Cyclohexene ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 178, 401, 237], "ImageBB": [73, 238, 411, 502]}, "diagram_type": "single"}, {"id": 140, "width": 1260, "height": 1236, "file_name": "ol802556f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [141.0, 564.0, 241.0, 82.0], "category_id": 1}, {"id": 1, "bbox": [1029.0, 26.0, 206.0, 93.0], "category_id": 1}, {"id": 2, "bbox": [24.0, 2.0, 277.0, 133.0], "category_id": 1}, {"id": 3, "bbox": [146.0, 319.0, 202.0, 85.0], "category_id": 1}, {"id": 4, "bbox": [144.0, 442.0, 216.0, 83.0], "category_id": 1}, {"id": 5, "bbox": [136.0, 677.0, 232.0, 114.0], "category_id": 1}, {"id": 6, "bbox": [107.0, 837.0, 286.0, 115.0], "category_id": 1}, {"id": 7, "bbox": [176.0, 974.0, 150.0, 149.0], "category_id": 1}, {"id": 8, "bbox": [126.0, 1147.0, 245.0, 83.0], "category_id": 1}, {"id": 9, "bbox": [157.0, 126.0, 26.0, 35.0], "category_id": 3}, {"id": 10, "bbox": [412.0, 124.0, 33.0, 38.0], "category_id": 3}, {"id": 11, "bbox": [1108.0, 130.0, 29.0, 33.0], "category_id": 3}, {"id": 12, "bbox": [371.0, 50.0, 114.0, 39.0], "category_id": 1}], "reactions": [{"reactants": [2, 15], "conditions": [10, 11], "products": [1]}], "corefs": [[2, 9], [12, 10], [1, 11]], "caption": "Table 1. Scope of the Electrophilea", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 610, 88], "ImageBB": [436, 97, 751, 406]}, "diagram_type": "single"}, {"id": 141, "width": 1348, "height": 1584, "file_name": "ol802073q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [313.1, 47.3, 368.9, 110.7], "category_id": 1}, {"id": 1, "bbox": [1039.0, 170.0, 39.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [435.0, 166.0, 46.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [67.0, 32.0, 162.0, 146.0], "category_id": 1}, {"id": 4, "bbox": [1035.0, 1.0, 243.0, 210.0], "category_id": 1}, {"id": 5, "bbox": [117.0, 167.0, 39.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [7, 0, 3], "conditions": [2, 6], "products": [8]}], "corefs": [[3, 5], [0, 2], [4, 1]], "caption": "Table 2. Reactions of Carbonyl Compounds with Indium and 1-Bromopent-4-en-2-ynea ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 743, 102], "ImageBB": [425, 111, 762, 507]}, "diagram_type": "single"}, {"id": 142, "width": 1344, "height": 760, "file_name": "ol400025a-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [301.0, 259.06, 67.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [920.04, 260.04, 67.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [837.6, 11.8, 294.5, 239.3], "category_id": 1}, {"id": 3, "bbox": [218.5, 3.9, 294.6, 241.2], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [6, 4], "products": [2]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 4. Study on the Cascade Reaction Pathwaya", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 339, 101], "ImageBB": [71, 112, 407, 302]}, "diagram_type": "single"}, {"id": 143, "width": 1348, "height": 948, "file_name": "ol302997q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [110.0, 287.0, 51.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [27.8, 81.1, 267.5, 203.6], "category_id": 1}, {"id": 2, "bbox": [346.6, 76.9, 218.8, 165.3], "category_id": 1}, {"id": 3, "bbox": [1012.9, 2.2, 309.4, 247.2], "category_id": 1}, {"id": 4, "bbox": [475.0, 286.0, 54.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [1176.0, 287.0, 63.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [3, 5], "conditions": [2, 4, 1], "products": [6]}], "corefs": [[1, 0], [2, 4], [3, 5]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 479, 707, 495], "ImageBB": [436, 506, 773, 743]}, "diagram_type": "single"}, {"id": 144, "width": 1324, "height": 924, "file_name": "ol3023177-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [891.0, 2.0, 259.0, 185.0], "category_id": 1}, {"id": 1, "bbox": [496.0, 46.0, 185.0, 105.0], "category_id": 1}, {"id": 2, "bbox": [156.0, 39.0, 241.0, 108.0], "category_id": 1}, {"id": 3, "bbox": [1140.0, 129.0, 29.0, 38.0], "category_id": 3}, {"id": 4, "bbox": [610.0, 136.0, 53.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [271.0, 143.0, 34.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [], "products": [0]}], "corefs": [[2, 5], [1, 4], [0, 3]], "caption": "Table 3. Scope of H-Bonding Directed Hydroaminationa", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 374, 101], "ImageBB": [74, 112, 405, 343]}, "diagram_type": "single"}, {"id": 145, "width": 1348, "height": 1108, "file_name": "ol3023177-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [281.0, 145.0, 60.1, 53.6], "category_id": 3}, {"id": 1, "bbox": [1012.3, 153.9, 60.4, 45.7], "category_id": 3}, {"id": 2, "bbox": [584.4, 147.3, 69.0, 44.8], "category_id": 3}, {"id": 3, "bbox": [878.4, 4.0, 279.3, 146.1], "category_id": 1}, {"id": 4, "bbox": [529.4, 44.9, 182.6, 99.0], "category_id": 1}, {"id": 5, "bbox": [194.0, 28.9, 239.1, 103.2], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [], "products": [4]}], "corefs": [[5, 0], [4, 2], [3, 1]], "caption": "Table 1. Optimization of Reaction of 1a with 2aa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 387, 698, 403], "ImageBB": [436, 414, 773, 691]}, "diagram_type": "single"}, {"id": 146, "width": 1344, "height": 748, "file_name": "ol300387f-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.0, 232.0, 47.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [853.0, 229.0, 109.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1099.0, 231.0, 45.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [121.0, 18.0, 160.0, 192.2], "category_id": 1}, {"id": 4, "bbox": [809.0, 18.0, 170.0, 193.0], "category_id": 1}, {"id": 5, "bbox": [1022.0, 20.0, 203.0, 191.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [6, 8], "products": [5, 7]}], "corefs": [[3, 0], [4, 1], [5, 2]], "caption": "Table 3. Kinetic Resolution of 1e Followed by 1,4-Addition of Remaining (S)-1e ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 770, 403, 797], "ImageBB": [71, 808, 407, 995]}, "diagram_type": "single"}, {"id": 147, "width": 1348, "height": 740, "file_name": "ol202499g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [399.0, 15.0, 201.0, 154.0], "category_id": 1}, {"id": 1, "bbox": [980.0, 3.0, 343.0, 180.0], "category_id": 1}, {"id": 2, "bbox": [1130.0, 198.0, 24.0, 32.0], "category_id": 3}, {"id": 3, "bbox": [460.0, 193.0, 42.0, 31.0], "category_id": 3}, {"id": 4, "bbox": [155.0, 195.0, 23.0, 29.0], "category_id": 3}, {"id": 5, "bbox": [26.0, 11.0, 247.0, 175.0], "category_id": 1}], "reactions": [{"reactants": [9, 1], "conditions": [3, 4], "products": [2]}], "corefs": [[5, 4], [0, 3], [1, 2]], "caption": "Table 2. Direct Allylic Alkylation of O-Protected Allylic Cya- nohydrin 1 with MBH Adducts 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 765, 114], "ImageBB": [436, 126, 773, 311]}, "diagram_type": "single"}, {"id": 148, "width": 1348, "height": 1832, "file_name": "ol201201a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [309.0, 66.3, 255.6, 196.7], "category_id": 1}, {"id": 1, "bbox": [1100.0, 260.0, 83.0, 50.1], "category_id": 3}, {"id": 2, "bbox": [423.0, 260.0, 45.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 7.0, 187.0, 241.0], "category_id": 1}, {"id": 4, "bbox": [951.0, 11.0, 382.0, 256.0], "category_id": 1}, {"id": 5, "bbox": [47.0, 265.0, 59.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [5, 0], "conditions": [4, 1], "products": [6]}], "corefs": [[3, 5], [0, 2], [4, 1]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 185, 688, 201], "ImageBB": [436, 211, 773, 669]}, "diagram_type": "single"}, {"id": 149, "width": 1344, "height": 1316, "file_name": "ol200849k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [111.0, 287.2, 454.0, 251.3], "category_id": 1}, {"id": 1, "bbox": [703.9, 281.0, 506.8, 255.5], "category_id": 1}, {"id": 2, "bbox": [1070.33, 14.0, 273.67, 231.5], "category_id": 1}, {"id": 3, "bbox": [68.3, 205.8, 49.4, 56.4], "category_id": 3}, {"id": 4, "bbox": [365.3, 202.1, 51.4, 52.8], "category_id": 3}, {"id": 5, "bbox": [1151.9, 205.9, 43.5, 49.0], "category_id": 3}, {"id": 6, "bbox": [954.2, 497.9, 45.5, 50.0], "category_id": 3}, {"id": 7, "bbox": [280.0, 75.8, 242.0, 68.1], "category_id": 1}, {"id": 8, "bbox": [304.1, 506.3, 41.8, 45.8], "category_id": 3}, {"id": 9, "bbox": [5.0, 33.0, 199.0, 170.4], "category_id": 1}], "reactions": [{"reactants": [13, 10], "conditions": [4, 12, 5], "products": [3]}], "corefs": [[9, 3], [7, 4], [2, 5], [0, 8], [1, 6]], "caption": "Table 1. CDC between Various Nitrones 1 and Alkynes 2 Using a Stoichiometric Amount of Oxidant 3 ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 164, 405, 191], "ImageBB": [71, 202, 407, 531]}, "diagram_type": "single"}, {"id": 150, "width": 1352, "height": 3592, "file_name": "ol200038n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [201.0, 2994.0, 911.0, 598.0], "category_id": 1}, {"id": 1, "bbox": [996.0, 845.0, 40.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [589.0, 1854.0, 58.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [652.0, 1531.0, 64.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [1081.0, 1536.0, 64.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [417.0, 1573.0, 381.0, 342.0], "category_id": 1}, {"id": 6, "bbox": [858.0, 581.0, 321.0, 293.0], "category_id": 1}, {"id": 7, "bbox": [480.63, 603.52, 304.37, 83.28], "category_id": 1}, {"id": 8, "bbox": [696.0, 883.0, 599.0, 264.0], "category_id": 3}, {"id": 9, "bbox": [914.0, 1228.6, 346.6, 322.3], "category_id": 1}, {"id": 10, "bbox": [494.2, 1225.7, 339.2, 326.8], "category_id": 1}], "reactions": [{"reactants": [15], "conditions": [17, 16, 23, 14], "products": [13]}, {"reactants": [28], "conditions": [8, 29, 0], "products": [27, 26]}, {"reactants": [27], "conditions": [], "products": [26]}, {"reactants": [26], "conditions": [], "products": [27]}, {"reactants": [26], "conditions": [24, 22, 9], "products": [7]}, {"reactants": [7], "conditions": [20, 10], "products": [5]}], "corefs": [[6, 1], [6, 8], [10, 3], [9, 4], [5, 2]], "caption": "Figure 2. Single-crystal X-ray structure of 9a. Hydrogen atoms are omitted for clarity except polar N-H bonds. Selected bond lengths (A\u030a): C5-O1 1.224(3), C12-O2 1.200(3), N1-C1 1.368(3), N1-C4 1.340(3). ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 966, 771, 1021], "ImageBB": [436, 55, 774, 953]}, "diagram_type": "multiple"}, {"id": 151, "width": 1368, "height": 1372, "file_name": "ol1030487-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [257.0, 318.0, 217.0, 135.0], "category_id": 1}, {"id": 1, "bbox": [559.0, 320.2, 105.0, 127.8], "category_id": 1}, {"id": 2, "bbox": [326.0, 455.0, 42.0, 46.2], "category_id": 3}, {"id": 3, "bbox": [1033.0, 0.0, 318.0, 195.0], "category_id": 1}, {"id": 4, "bbox": [353.1, 34.4, 210.9, 65.6], "category_id": 1}, {"id": 5, "bbox": [0.0, 30.0, 295.0, 186.3], "category_id": 1}, {"id": 6, "bbox": [531.36, 77.27, 45.98, 42.3], "category_id": 3}, {"id": 7, "bbox": [1124.0, 214.0, 103.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [593.0, 455.0, 26.0, 37.0], "category_id": 3}, {"id": 9, "bbox": [144.0, 214.0, 95.0, 37.0], "category_id": 3}, {"id": 10, "bbox": [730.0, 217.0, 100.0, 38.0], "category_id": 3}, {"id": 11, "bbox": [649.0, 2.0, 308.0, 201.0], "category_id": 1}, {"id": 12, "bbox": [799.0, 457.0, 46.0, 42.0], "category_id": 3}, {"id": 13, "bbox": [737.0, 328.0, 205.0, 125.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 1], "products": [13, 4]}], "corefs": [[5, 9], [4, 6], [11, 10], [3, 7], [0, 2], [1, 8], [13, 12]], "caption": "Table 1. Screening of Catalyst, Solvent, and Reaction Condi- tions for the Synthesis of Pentasubstituted Cyclopentanecar- baldehydesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 553, 762, 594], "ImageBB": [436, 593, 778, 936]}, "diagram_type": "single"}, {"id": 152, "width": 1348, "height": 388, "file_name": "ol102784c-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1077.0, 222.0, 44.0, 33.0], "category_id": 3}, {"id": 1, "bbox": [78.0, 162.0, 41.0, 33.0], "category_id": 3}, {"id": 2, "bbox": [263.0, 161.0, 44.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [764.0, 136.0, 45.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [1077.0, 74.0, 38.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [920.2, 145.0, 363.6, 105.9], "category_id": 1}, {"id": 6, "bbox": [673.1, 52.0, 285.8, 106.8], "category_id": 1}, {"id": 7, "bbox": [171.1, 48.3, 185.9, 106.7], "category_id": 1}, {"id": 8, "bbox": [992.1, 3.0, 209.9, 95.0], "category_id": 1}, {"id": 9, "bbox": [59.3, 45.4, 117.7, 102.6], "category_id": 1}], "reactions": [{"reactants": [12, 8], "conditions": [9, 10], "products": [7, 11, 6]}], "corefs": [[9, 1], [7, 2], [6, 3], [8, 4], [5, 0]], "caption": "Table 4. Cross-Coupling of Aryl Iodides Catalyzed by Cua", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 731, 88], "ImageBB": [425, 97, 762, 194]}, "diagram_type": "single"}, {"id": 153, "width": 1348, "height": 992, "file_name": "ol1022036-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [216.0, 161.0, 178.8, 52.0], "category_id": 1}, {"id": 1, "bbox": [30.0, 89.6, 146.0, 121.1], "category_id": 1}, {"id": 2, "bbox": [1061.6, 108.6, 257.4, 150.4], "category_id": 1}, {"id": 3, "bbox": [818.0, 2.0, 118.0, 41.7], "category_id": 1}], "reactions": [{"reactants": [4, 3, 1, 9, 10], "conditions": [6, 8], "products": [5]}], "corefs": [], "caption": "Table 3. One-Pot, Three-Step Synthesis of 1-Substituted 4-Acyl-1H-1,2,3-triazoles 7a-e ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 717, 102], "ImageBB": [425, 111, 762, 359]}, "diagram_type": "tree"}, {"id": 154, "width": 2816, "height": 2140, "file_name": "ol100073y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [514.0, 306.0, 32.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [1080.0, 0.0, 438.0, 304.0], "category_id": 1}, {"id": 2, "bbox": [1989.0, 1.0, 444.0, 300.0], "category_id": 1}, {"id": 3, "bbox": [382.0, 15.0, 232.0, 215.0], "category_id": 1}, {"id": 4, "bbox": [1536.0, 1.3, 440.0, 297.7], "category_id": 1}, {"id": 5, "bbox": [1610.0, 309.0, 323.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [879.1, 269.9, 222.9, 139.1], "category_id": 3}, {"id": 7, "bbox": [1154.0, 308.0, 321.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [2084.0, 309.0, 318.0, 56.0], "category_id": 3}, {"id": 9, "bbox": [675.5, 115.0, 330.5, 246.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0, 12], "products": [3, 7, 4]}], "corefs": [[3, 0], [9, 6], [1, 7], [4, 5], [2, 8]], "caption": "Table 1. Optimization of the Addition Reaction of N-Sulfinyl Imidate 1 across Aldimines 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 531, 88], "ImageBB": [58, 97, 762, 632]}, "diagram_type": "single"}, {"id": 155, "width": 1356, "height": 1156, "file_name": "op5001463-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 1096.0, 41.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [794.0, 9.0, 343.0, 145.0], "category_id": 1}, {"id": 2, "bbox": [924.0, 592.0, 57.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [192.99, 602.86, 34.09, 43.39], "category_id": 3}, {"id": 4, "bbox": [318.1, 179.0, 40.5, 42.2], "category_id": 3}, {"id": 5, "bbox": [906.0, 156.0, 38.4, 39.2], "category_id": 3}, {"id": 6, "bbox": [424.3, 1095.9, 46.0, 54.0], "category_id": 3}, {"id": 7, "bbox": [220.0, 1099.0, 47.1, 49.3], "category_id": 3}, {"id": 8, "bbox": [501.0, 597.5, 50.2, 44.5], "category_id": 3}, {"id": 9, "bbox": [831.1, 712.89, 330.2, 356.51], "category_id": 1}, {"id": 10, "bbox": [477.8, 711.69, 348.6, 441.71], "category_id": 1}, {"id": 11, "bbox": [192.8, 720.8, 311.7, 302.4], "category_id": 1}, {"id": 12, "bbox": [217.95, 383.05, 152.35, 255.05], "category_id": 1}, {"id": 13, "bbox": [398.2, 238.5, 339.9, 338.9], "category_id": 1}, {"id": 14, "bbox": [831.0, 258.2, 327.5, 313.8], "category_id": 1}, {"id": 15, "bbox": [207.1, 1.3, 339.2, 179.2], "category_id": 1}], "reactions": [{"reactants": [15], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [12], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}], "corefs": [[15, 4], [1, 5], [12, 3], [13, 8], [14, 2], [11, 7], [10, 6], [9, 0]], "caption": "Figure 2. Impurities.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 414, 551, 428], "ImageBB": [448, 116, 787, 405]}, "diagram_type": "multiple"}, {"id": 156, "width": 3396, "height": 1640, "file_name": "op400292m-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2115.2, 945.2, 181.0, 238.2], "category_id": 1}, {"id": 1, "bbox": [1978.25, 328.24, 110.25, 191.96], "category_id": 1}, {"id": 2, "bbox": [1474.1, 990.3, 290.9, 160.3], "category_id": 1}, {"id": 3, "bbox": [835.1, 915.9, 400.1, 176.2], "category_id": 1}, {"id": 4, "bbox": [826.2, 1451.56, 98.4, 126.1], "category_id": 1}, {"id": 5, "bbox": [2186.0, 282.24, 183.1, 148.36], "category_id": 1}, {"id": 6, "bbox": [2117.0, 1454.8, 194.0, 185.2], "category_id": 1}, {"id": 7, "bbox": [1082.71, 1298.07, 188.09, 143.73], "category_id": 1}, {"id": 8, "bbox": [1969.6, 1344.6, 98.7, 156.6], "category_id": 1}, {"id": 9, "bbox": [1766.7, 481.6, 185.0, 283.5], "category_id": 1}, {"id": 10, "bbox": [958.2, 294.2, 139.1, 143.4], "category_id": 1}, {"id": 11, "bbox": [1162.4, 525.0, 261.0, 223.1], "category_id": 1}, {"id": 12, "bbox": [1105.7, 289.0, 219.4, 216.4], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [26], "products": [24]}, {"reactants": [24], "conditions": [25], "products": [5]}, {"reactants": [12], "conditions": [3, 8], "products": [19]}, {"reactants": [19], "conditions": [21], "products": [5]}, {"reactants": [6], "conditions": [4], "products": [5]}, {"reactants": [15], "conditions": [27], "products": [0]}, {"reactants": [0], "conditions": [28, 18], "products": [5]}, {"reactants": [7], "conditions": [16], "products": [14]}, {"reactants": [14], "conditions": [], "products": [5]}, {"reactants": [13], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [23], "products": [5]}], "corefs": [], "caption": "Figure 2. Various approaches available to obtain the C2-symmetric diamines 1 or 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 442, 489, 457], "ImageBB": [10, 22, 859, 432]}, "diagram_type": "tree"}, {"id": 157, "width": 1352, "height": 1772, "file_name": "op400278d-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [34.14, 840.0, 388.0, 111.0], "category_id": 3}, {"id": 1, "bbox": [544.0, 844.0, 364.0, 105.0], "category_id": 3}, {"id": 2, "bbox": [150.8, 1123.0, 427.3, 383.1], "category_id": 1}, {"id": 3, "bbox": [1045.5, 530.8, 306.5, 320.2], "category_id": 1}, {"id": 4, "bbox": [534.4, 438.5, 406.6, 385.7], "category_id": 1}, {"id": 5, "bbox": [7.0, 425.5, 435.7, 394.0], "category_id": 1}, {"id": 6, "bbox": [866.0, 0.0, 450.0, 305.0], "category_id": 1}, {"id": 7, "bbox": [50.4, 51.4, 171.3, 198.6], "category_id": 1}, {"id": 8, "bbox": [143.0, 1529.0, 417.9, 109.9], "category_id": 3}, {"id": 9, "bbox": [1102.0, 874.2, 177.0, 43.8], "category_id": 3}, {"id": 10, "bbox": [812.75, 1532.37, 468.0, 207.0], "category_id": 3}, {"id": 11, "bbox": [824.6, 1121.4, 443.4, 427.6], "category_id": 1}, {"id": 12, "bbox": [307.91, 47.58, 171.03, 201.9], "category_id": 1}], "reactions": [{"reactants": [10, 16], "conditions": [2], "products": [9]}], "corefs": [[5, 0], [4, 1], [3, 9], [2, 8], [11, 10]], "caption": "Table 7. Formation of symmetric triarylamines with Pd- PEPPSI-IPentCl (84) in the presence of excess aryl chloride and aniline derivatives ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 94, 416, 139], "ImageBB": [82, 146, 420, 589]}, "diagram_type": "single"}, {"id": 158, "width": 1356, "height": 1112, "file_name": "op400278d-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [652.0, 592.0, 61.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [1100.0, 589.0, 58.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [187.0, 587.0, 65.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [369.0, 947.0, 56.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [958.0, 946.0, 61.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [46.0, 26.0, 185.0, 216.0], "category_id": 1}, {"id": 6, "bbox": [309.0, 22.0, 181.0, 218.0], "category_id": 1}, {"id": 7, "bbox": [899.0, 63.0, 454.0, 196.0], "category_id": 1}, {"id": 8, "bbox": [15.0, 358.0, 475.0, 244.0], "category_id": 1}, {"id": 9, "bbox": [458.0, 354.0, 458.0, 262.0], "category_id": 1}, {"id": 10, "bbox": [927.0, 342.0, 429.0, 250.0], "category_id": 1}, {"id": 11, "bbox": [183.0, 729.0, 554.0, 253.0], "category_id": 1}, {"id": 12, "bbox": [765.0, 734.0, 468.0, 255.0], "category_id": 1}], "reactions": [{"reactants": [14, 15], "conditions": [1, 13], "products": [16]}], "corefs": [[8, 2], [9, 0], [10, 1], [11, 3], [12, 4]], "caption": "Table 5. Comparative study of Pd-PEPPSI-IPr (2) and Pd- PEPPSI-IPent (1) in aryl aminations with electron-de\ufb01cient anilines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 94, 784, 139], "ImageBB": [448, 146, 787, 424]}, "diagram_type": "single"}, {"id": 159, "width": 1352, "height": 868, "file_name": "op400278d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [922.16, 98.78, 322.84, 153.32], "category_id": 1}, {"id": 1, "bbox": [242.8, 363.33, 257.4, 272.87], "category_id": 1}, {"id": 2, "bbox": [519.8, 365.69, 266.9, 270.11], "category_id": 1}, {"id": 3, "bbox": [750.0, 334.0, 296.0, 337.2], "category_id": 1}, {"id": 4, "bbox": [258.0, 700.0, 227.0, 133.0], "category_id": 3}, {"id": 5, "bbox": [9.0, 700.0, 197.1, 131.5], "category_id": 3}, {"id": 6, "bbox": [1065.0, 357.0, 261.0, 289.0], "category_id": 1}, {"id": 7, "bbox": [13.35, 372.3, 243.85, 254.52], "category_id": 1}, {"id": 8, "bbox": [60.7, 31.2, 171.3, 198.8], "category_id": 1}, {"id": 9, "bbox": [528.0, 700.5, 227.5, 131.2], "category_id": 3}, {"id": 10, "bbox": [802.1, 698.1, 224.2, 132.9], "category_id": 3}, {"id": 11, "bbox": [1087.1, 695.1, 225.9, 135.8], "category_id": 3}], "reactions": [{"reactants": [13, 11], "conditions": [4, 10], "products": [0]}], "corefs": [[7, 5], [1, 4], [2, 9], [3, 10], [6, 11]], "caption": "Table 4. Comparative study of Pd-PEPPSI-IPr (2) and Pd- PEPPSI-IPent (1) in aryl aminations with dialkylamines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 555, 413, 586], "ImageBB": [82, 591, 420, 808]}, "diagram_type": "single"}, {"id": 160, "width": 1348, "height": 444, "file_name": "op400278d-Table-c13.png", "license": 0, "bboxes": [{"id": 0, "bbox": [35.2, 39.2, 190.7, 192.5], "category_id": 1}, {"id": 1, "bbox": [329.1, 76.2, 214.9, 152.8], "category_id": 1}, {"id": 2, "bbox": [1021.0, 5.0, 324.0, 248.0], "category_id": 1}, {"id": 3, "bbox": [69.0, 249.0, 75.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [374.0, 243.0, 60.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [1194.0, 250.0, 56.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [2, 3], "conditions": [1, 0], "products": [4]}], "corefs": [[0, 3], [1, 4], [2, 5]], "caption": "Table 13. Direct comparison between Pd-PEPPSI-IPr* (100) and IPent (1, 33) PEPPSI sca\ufb00olds under identical reaction conditions ", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 279, 417, 324], "ImageBB": [82, 330, 419, 441]}, "diagram_type": "single"}, {"id": 161, "width": 2820, "height": 2032, "file_name": "op300363s-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2154.0, 260.0, 71.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [1771.0, 263.0, 67.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [1400.0, 260.0, 52.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [1757.0, 873.1, 603.8, 476.5], "category_id": 1}, {"id": 4, "bbox": [518.72, 262.72, 59.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [947.17, 261.45, 75.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [2054.0, 29.0, 330.0, 275.1], "category_id": 1}, {"id": 7, "bbox": [1637.9, 7.0, 312.2, 302.6], "category_id": 1}, {"id": 8, "bbox": [1248.1, 0.0, 303.9, 304.1], "category_id": 1}, {"id": 9, "bbox": [862.2, 15.4, 298.4, 228.3], "category_id": 1}, {"id": 10, "bbox": [439.3, 38.5, 268.3, 202.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [], "products": [7]}, {"reactants": [8], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10]}, {"reactants": [7], "conditions": [], "products": [6]}], "corefs": [[10, 4], [9, 5], [8, 2], [7, 1], [6, 0]], "caption": "Figure 5. 1H NMR analysis of a sample containing dienylimine 9a after extraction of the reaction mixture with sat. NaHCO3/EtOAc. Conditions: 1 mmol 2-ethylphenylhydrazine hydrochloride 1a, 1 equiv DHF, 1.5 mL MeOH/H2O 2:1; 20% H2SO4; 5 min reaction temperature at 130 \u00b0C. ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 631, 784, 662], "ImageBB": [82, 116, 787, 624]}, "diagram_type": "single"}, {"id": 162, "width": 1352, "height": 896, "file_name": "op3002883-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [229.0, 200.0, 51.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [792.0, 1.0, 560.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [985.0, 217.0, 49.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 50.0, 488.0, 141.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2, 1], "products": [3]}], "corefs": [[3, 0], [1, 2]], "caption": "Table 1. Ligand and Solvent Optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 321, 339], "ImageBB": [82, 346, 420, 570]}, "diagram_type": "single"}, {"id": 163, "width": 1348, "height": 588, "file_name": "op300235t-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [460.53, 41.89, 68.11, 59.98], "category_id": 3}, {"id": 1, "bbox": [448.5, 54.0, 300.0, 166.5], "category_id": 1}, {"id": 2, "bbox": [966.0, 446.0, 50.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [81.0, 29.0, 299.0, 384.0], "category_id": 1}, {"id": 4, "bbox": [810.0, 3.0, 456.0, 439.0], "category_id": 1}, {"id": 5, "bbox": [220.0, 444.0, 35.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [1], "products": [4]}], "corefs": [[3, 5], [1, 0], [4, 2]], "caption": "Table 1. Optimization of base and temperature for benzimidazole additiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 736, 171], "ImageBB": [449, 178, 786, 325]}, "diagram_type": "single"}, {"id": 164, "width": 2820, "height": 760, "file_name": "op200351g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [237.0, 25.0, 605.0, 337.0], "category_id": 1}, {"id": 1, "bbox": [2219.0, 271.0, 73.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [1422.0, 266.0, 85.0, 66.0], "category_id": 3}, {"id": 3, "bbox": [495.0, 271.0, 66.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [1971.0, 66.0, 632.0, 235.0], "category_id": 1}, {"id": 5, "bbox": [1141.0, 63.0, 619.0, 244.7], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [8, 9], "products": [10]}, {"reactants": [10], "conditions": [7, 1], "products": [6]}], "corefs": [[0, 3], [5, 2], [4, 1]], "caption": "Table 2. PFR cyclization results for ketoamide (11) cyclization and deprotection", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 656, 537, 671], "ImageBB": [82, 677, 787, 867]}, "diagram_type": "single"}, {"id": 165, "width": 2820, "height": 1248, "file_name": "op200334x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1235.0, 483.0, 93.0, 91.0], "category_id": 3}, {"id": 1, "bbox": [1717.0, 488.0, 98.0, 82.0], "category_id": 3}, {"id": 2, "bbox": [2322.0, 481.0, 102.0, 75.0], "category_id": 3}, {"id": 3, "bbox": [1425.0, 0.0, 578.5, 624.1], "category_id": 1}, {"id": 4, "bbox": [732.5, 74.2, 200.5, 157.6], "category_id": 1}, {"id": 5, "bbox": [2024.4, 76.0, 569.0, 544.9], "category_id": 1}, {"id": 6, "bbox": [1037.1, 82.5, 465.0, 539.6], "category_id": 1}, {"id": 7, "bbox": [228.4, 85.0, 454.8, 395.7], "category_id": 1}, {"id": 8, "bbox": [303.0, 402.6, 62.0, 74.8], "category_id": 3}], "reactions": [{"reactants": [11], "conditions": [8, 4], "products": [10, 6, 9]}], "corefs": [[7, 8], [6, 0], [3, 1], [5, 2]], "caption": "Table 1. Catalyst and ligand screening for the cross coupling to 13", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 460, 110], "ImageBB": [82, 116, 787, 428]}, "diagram_type": "single"}, {"id": 166, "width": 1344, "height": 620, "file_name": "op200052z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [749.0, 50.4, 473.9, 227.6], "category_id": 1}, {"id": 1, "bbox": [974.0, 327.1, 44.9, 46.9], "category_id": 3}, {"id": 2, "bbox": [180.01, 328.97, 44.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [23.2, 64.4, 401.8, 236.6], "category_id": 1}, {"id": 4, "bbox": [438.0, 3.0, 273.0, 176.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 6], "products": [0, 3]}], "corefs": [[3, 2], [0, 1]], "caption": "Table 2. Results of di\ufb02uoromethylation of 5", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 444, 317, 459], "ImageBB": [71, 469, 407, 624]}, "diagram_type": "single"}, {"id": 167, "width": 1356, "height": 796, "file_name": "op200038y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [658.0, 219.0, 43.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [929.0, 219.0, 46.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 56.0, 245.0, 125.0], "category_id": 1}, {"id": 3, "bbox": [513.0, 8.0, 298.0, 199.0], "category_id": 1}, {"id": 4, "bbox": [1099.0, 54.7, 253.0, 122.4], "category_id": 1}, {"id": 5, "bbox": [90.0, 217.0, 49.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [823.0, 57.5, 239.0, 122.5], "category_id": 1}, {"id": 7, "bbox": [1133.0, 210.0, 206.0, 91.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4], "products": [3, 7]}], "corefs": [[2, 5], [3, 0], [6, 1], [4, 7]], "caption": "Table 2. Selective hydrolysis of diester 3c with various bases", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 247, 405, 262], "ImageBB": [71, 272, 410, 471]}, "diagram_type": "single"}, {"id": 168, "width": 1356, "height": 1104, "file_name": "op200038y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1107.0, 247.0, 229.0, 98.0], "category_id": 3}, {"id": 1, "bbox": [303.4, 68.0, 182.6, 134.5], "category_id": 1}, {"id": 2, "bbox": [745.0, 248.0, 231.0, 101.0], "category_id": 3}, {"id": 3, "bbox": [290.0, 248.0, 214.0, 93.0], "category_id": 3}, {"id": 4, "bbox": [1120.0, 0.0, 234.0, 243.0], "category_id": 1}, {"id": 5, "bbox": [678.0, 15.0, 320.0, 192.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 54.0, 264.0, 189.0], "category_id": 1}, {"id": 7, "bbox": [100.0, 250.0, 44.0, 57.0], "category_id": 3}], "reactions": [{"reactants": [8, 1], "conditions": [9, 3], "products": [7, 6]}], "corefs": [[6, 7], [1, 3], [5, 2], [4, 0]], "caption": "Table 1. Base and solvent e\ufb00ects in cyclopropanation", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 263, 734, 278], "ImageBB": [436, 288, 775, 564]}, "diagram_type": "single"}, {"id": 169, "width": 1352, "height": 732, "file_name": "op100205s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [971.0, 3.0, 377.0, 273.0], "category_id": 1}, {"id": 1, "bbox": [596.0, 11.0, 341.0, 275.0], "category_id": 1}, {"id": 2, "bbox": [2.0, 8.0, 339.0, 278.0], "category_id": 1}, {"id": 3, "bbox": [863.0, 252.0, 66.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [1241.0, 252.0, 66.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [263.0, 250.0, 48.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [7], "products": [1, 0]}], "corefs": [[2, 5], [1, 3], [0, 4]], "caption": "Table 3. Screen of conditions for pyridine N-methylation of 9b ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 386, 73], "ImageBB": [58, 88, 396, 271]}, "diagram_type": "single"}, {"id": 170, "width": 2232, "height": 1432, "file_name": "op100113j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [717.0, 411.0, 501.0, 294.0], "category_id": 1}, {"id": 1, "bbox": [963.0, 0.0, 399.0, 306.0], "category_id": 1}, {"id": 2, "bbox": [1650.0, 18.0, 381.0, 303.0], "category_id": 1}, {"id": 3, "bbox": [1524.0, 414.0, 522.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 417.0, 510.0, 297.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 819.0, 396.0, 321.0], "category_id": 1}, {"id": 6, "bbox": [417.0, 834.0, 546.0, 213.0], "category_id": 1}, {"id": 7, "bbox": [157.0, 298.0, 30.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [136.0, 693.0, 35.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [493.0, 297.0, 38.0, 39.0], "category_id": 3}, {"id": 10, "bbox": [1071.0, 298.0, 34.0, 41.0], "category_id": 3}, {"id": 11, "bbox": [865.0, 697.0, 39.0, 41.0], "category_id": 3}, {"id": 12, "bbox": [1775.0, 288.0, 33.0, 44.0], "category_id": 3}, {"id": 13, "bbox": [147.0, 1131.0, 34.0, 42.0], "category_id": 3}, {"id": 14, "bbox": [685.0, 1020.0, 38.0, 45.0], "category_id": 3}, {"id": 15, "bbox": [1646.0, 688.0, 32.0, 39.0], "category_id": 3}, {"id": 16, "bbox": [1103.0, 840.4, 665.1, 295.2], "category_id": 1}, {"id": 17, "bbox": [440.3, 56.5, 241.8, 217.0], "category_id": 1}, {"id": 18, "bbox": [39.0, 45.0, 252.5, 229.1], "category_id": 1}], "reactions": [{"reactants": [26, 25], "conditions": [8], "products": [1]}, {"reactants": [1], "conditions": [9], "products": [2]}, {"reactants": [2], "conditions": [12], "products": [4]}, {"reactants": [4], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [10], "products": [3]}, {"reactants": [3], "conditions": [13], "products": [5]}, {"reactants": [5], "conditions": [6, 14], "products": [24]}], "corefs": [[18, 7], [17, 9], [1, 10], [2, 12], [4, 8], [0, 11], [3, 15], [5, 13], [6, 14]], "caption": "Table 1. Comparison of original and modified reaction conditions and pilot-plant performance", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 434, 577, 448], "ImageBB": [131, 65, 689, 423]}, "diagram_type": "multiple"}, {"id": 171, "width": 1344, "height": 1088, "file_name": "ol0616236-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [905.0, 231.8, 356.8, 92.4], "category_id": 3}, {"id": 1, "bbox": [646.0, 0.0, 146.0, 134.6], "category_id": 1}, {"id": 2, "bbox": [926.9, 16.2, 270.8, 178.2], "category_id": 1}, {"id": 3, "bbox": [83.9, 25.2, 399.5, 237.0], "category_id": 1}, {"id": 4, "bbox": [325.0, 226.0, 50.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [2, 4], "products": [3]}], "corefs": [[3, 4], [2, 0]], "caption": "Table 2. Condensations of 2b and 2c with Aldehydes", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 580, 359, 593], "ImageBB": [74, 602, 410, 874]}, "diagram_type": "single"}, {"id": 172, "width": 1344, "height": 1060, "file_name": "ol0610183-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [35.0, 2.2, 243.3, 305.8], "category_id": 1}, {"id": 1, "bbox": [511.6, 15.0, 246.4, 299.0], "category_id": 1}, {"id": 2, "bbox": [1182.58, 343.74, 34.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [1071.58, 35.0, 240.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [627.0, 341.0, 27.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [141.0, 339.0, 36.0, 35.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 7], "products": [1]}, {"reactants": [1], "conditions": [8, 9], "products": [3]}], "corefs": [[0, 5], [1, 4], [3, 2]], "caption": "Table 1. Substitution of 1 with Aromatic Compounds", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 624, 359, 637], "ImageBB": [74, 642, 410, 907]}, "diagram_type": "single"}, {"id": 173, "width": 1356, "height": 1040, "file_name": "ol053021c-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [795.0, 450.0, 217.0, 204.0], "category_id": 1}, {"id": 1, "bbox": [923.0, 45.0, 291.0, 213.0], "category_id": 1}, {"id": 2, "bbox": [715.0, 648.0, 380.0, 192.0], "category_id": 1}, {"id": 3, "bbox": [234.0, 859.0, 346.0, 122.0], "category_id": 1}, {"id": 4, "bbox": [113.18, 45.97, 293.0, 138.0], "category_id": 1}, {"id": 5, "bbox": [677.0, 838.0, 455.0, 202.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 7], "products": [2]}], "corefs": [], "caption": "Table 3. Direct Arylation of Imidazo[1,2-a]pyridinesa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 359, 89], "ImageBB": [73, 98, 412, 358]}, "diagram_type": "single"}, {"id": 174, "width": 1352, "height": 960, "file_name": "ol052245s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [623.0, 382.0, 361.0, 190.0], "category_id": 1}, {"id": 1, "bbox": [277.0, 323.0, 94.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [221.2, 384.9, 306.3, 183.4], "category_id": 1}, {"id": 3, "bbox": [29.7, 184.7, 386.0, 131.3], "category_id": 1}, {"id": 4, "bbox": [727.86, 567.0, 94.0, 38.0], "category_id": 3}, {"id": 5, "bbox": [457.0, 565.0, 94.1, 45.0], "category_id": 3}, {"id": 6, "bbox": [1089.0, 567.0, 217.0, 41.9], "category_id": 3}, {"id": 7, "bbox": [1008.0, 386.0, 327.0, 185.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 0], "products": [6, 1, 12]}], "corefs": [[3, 1], [2, 5], [0, 4], [7, 6]], "caption": "Table 1. Platinum-Catalyzed Hydrosilylation of Para- and Ortho-Substituted Alkynes 1a,b with Triethylsilanea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 296, 746, 324], "ImageBB": [439, 51, 777, 291]}, "diagram_type": "multiple"}, {"id": 175, "width": 1344, "height": 636, "file_name": "jo0109321-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [741.0, 141.0, 33.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [735.0, 365.0, 36.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [697.1, 3.0, 345.7, 131.9], "category_id": 1}, {"id": 3, "bbox": [964.1, 92.3, 267.4, 130.7], "category_id": 1}, {"id": 4, "bbox": [694.2, 158.0, 261.6, 197.9], "category_id": 1}, {"id": 5, "bbox": [1006.0, 235.1, 43.0, 44.8], "category_id": 3}, {"id": 6, "bbox": [109.1, 101.1, 263.9, 141.8], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [3, 10, 2], "products": [6, 8, 7]}], "corefs": [[2, 0], [4, 1], [3, 5]], "caption": "Table 6. Hydroboration of Allylbenzene with BH3-THF                       in THF ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [77, 479, 404, 506], "ImageBB": [74, 515, 410, 674]}, "diagram_type": "single"}, {"id": 176, "width": 1348, "height": 348, "file_name": "acs.orglett.6b00326-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1080.0, 210.0, 70.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [978.0, 6.0, 201.0, 191.0], "category_id": 1}, {"id": 2, "bbox": [257.0, 203.0, 51.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [203.6, 43.0, 189.4, 149.0], "category_id": 1}, {"id": 4, "bbox": [481.0, 49.0, 160.0, 142.9], "category_id": 1}, {"id": 5, "bbox": [541.0, 205.0, 52.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [6, 7], "conditions": [5, 8], "products": [3]}], "corefs": [[3, 2], [4, 5], [1, 0]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 135, 366, 156], "ImageBB": [82, 162, 419, 249]}, "diagram_type": "single"}, {"id": 177, "width": 1352, "height": 1152, "file_name": "acs.orglett.5b02709-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [250.0, 1029.0, 402.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [5.0, 0.0, 344.0, 233.0], "category_id": 1}, {"id": 2, "bbox": [214.0, 188.0, 49.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [711.0, 180.0, 55.0, 49.0], "category_id": 3}, {"id": 4, "bbox": [998.0, 3.0, 338.0, 231.0], "category_id": 1}, {"id": 5, "bbox": [810.0, 711.0, 351.0, 282.3], "category_id": 1}, {"id": 6, "bbox": [253.0, 735.0, 341.0, 250.6], "category_id": 1}, {"id": 7, "bbox": [1197.0, 186.6, 53.0, 49.4], "category_id": 3}, {"id": 8, "bbox": [784.0, 1027.7, 427.0, 39.3], "category_id": 3}, {"id": 9, "bbox": [486.0, 1.0, 353.0, 222.9], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [13]}, {"reactants": [13], "conditions": [10, 1], "products": [7]}], "corefs": [[1, 2], [9, 3], [4, 7], [6, 0], [5, 8]], "caption": "Table 1. Oxidation of the Phenylsul\ufb01de and Its Elimination", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 110], "ImageBB": [82, 116, 420, 404]}, "diagram_type": "single"}, {"id": 178, "width": 1348, "height": 920, "file_name": "acs.orglett.5b01692-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [547.0, 591.0, 232.0, 97.0], "category_id": 3}, {"id": 1, "bbox": [26.0, 353.7, 346.0, 217.3], "category_id": 1}, {"id": 2, "bbox": [951.3, 385.3, 360.7, 269.7], "category_id": 1}, {"id": 3, "bbox": [521.7, 371.3, 292.3, 198.7], "category_id": 1}, {"id": 4, "bbox": [1057.0, 6.67, 269.34, 269.0], "category_id": 1}, {"id": 5, "bbox": [397.7, 36.7, 248.97, 236.31], "category_id": 1}, {"id": 6, "bbox": [34.01, 66.01, 280.99, 178.69], "category_id": 1}, {"id": 7, "bbox": [515.32, 284.0, 60.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [121.99, 279.66, 67.0, 53.0], "category_id": 3}, {"id": 9, "bbox": [32.0, 597.0, 322.0, 233.0], "category_id": 3}, {"id": 10, "bbox": [1096.0, 599.0, 38.0, 47.0], "category_id": 3}, {"id": 11, "bbox": [1158.0, 281.0, 83.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [7, 6], "conditions": [2, 13], "products": [5]}], "corefs": [[6, 8], [5, 7], [4, 11], [1, 9], [3, 0], [2, 10]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 362, 366, 383], "ImageBB": [82, 389, 419, 619]}, "diagram_type": "single"}, {"id": 179, "width": 1348, "height": 356, "file_name": "acs.orglett.5b01044-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [74.0, 0.0, 305.0, 210.0], "category_id": 1}, {"id": 1, "bbox": [508.0, 208.9, 50.0, 41.1], "category_id": 3}, {"id": 2, "bbox": [987.9, 211.0, 124.1, 43.0], "category_id": 3}, {"id": 3, "bbox": [433.2, 17.1, 206.8, 191.9], "category_id": 1}, {"id": 4, "bbox": [205.9, 208.9, 52.1, 40.1], "category_id": 3}, {"id": 5, "bbox": [837.9, 16.1, 434.7, 193.9], "category_id": 1}], "reactions": [{"reactants": [3, 6], "conditions": [0, 2], "products": [8]}], "corefs": [[0, 4], [3, 1], [5, 2]], "caption": "Table 1. Enantioselective Addition of o-tBu-Phenol to Ethyl(p-tolyl)ketene Catalyzed by (S)-1a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 90, 746, 125], "ImageBB": [449, 131, 786, 220]}, "diagram_type": "single"}, {"id": 180, "width": 2816, "height": 708, "file_name": "acs.oprd.6b00011-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1545.6, 169.1, 522.4, 393.9], "category_id": 1}, {"id": 1, "bbox": [1090.1, 0.0, 394.5, 258.5], "category_id": 1}, {"id": 2, "bbox": [1622.0, 569.0, 295.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [1270.0, 278.0, 34.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [935.0, 551.0, 63.0, 67.0], "category_id": 3}, {"id": 5, "bbox": [744.0, 188.2, 355.4, 346.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [3, 2, 1], "products": [0]}], "corefs": [[5, 4], [1, 3], [0, 2]], "caption": "Table 4. Pd Catalyst Screen for the Stage 2 Suzuki Cross-Coupling Reaction", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 513, 110], "ImageBB": [82, 116, 786, 293]}, "diagram_type": "single"}, {"id": 181, "width": 3396, "height": 1556, "file_name": "acs.oprd.5b00170-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [773.0, 287.0, 254.0, 120.0], "category_id": 1}, {"id": 1, "bbox": [815.0, 1510.0, 55.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [1501.0, 1510.0, 59.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [2344.0, 1510.0, 34.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [1518.0, 1096.0, 27.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [2344.0, 1090.0, 34.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [2340.0, 755.0, 38.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [1513.0, 759.0, 40.0, 42.0], "category_id": 3}, {"id": 8, "bbox": [1505.0, 423.0, 56.0, 44.0], "category_id": 3}, {"id": 9, "bbox": [808.0, 423.0, 66.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [1401.0, 289.0, 318.0, 122.0], "category_id": 1}, {"id": 11, "bbox": [2099.0, 1298.0, 523.0, 196.0], "category_id": 1}, {"id": 12, "bbox": [1402.0, 1333.0, 315.0, 122.0], "category_id": 1}, {"id": 13, "bbox": [773.0, 1333.0, 253.0, 121.0], "category_id": 1}, {"id": 14, "bbox": [2104.0, 936.0, 517.0, 164.0], "category_id": 1}, {"id": 15, "bbox": [1401.0, 942.0, 327.0, 153.0], "category_id": 1}, {"id": 16, "bbox": [2102.0, 588.0, 519.0, 178.0], "category_id": 1}, {"id": 17, "bbox": [1404.0, 624.0, 298.0, 123.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [18], "products": [25]}, {"reactants": [14], "conditions": [22], "products": [1]}, {"reactants": [14], "conditions": [2], "products": [29]}, {"reactants": [29], "conditions": [19], "products": [27]}, {"reactants": [27], "conditions": [16], "products": [24]}, {"reactants": [24], "conditions": [15], "products": [25]}, {"reactants": [29], "conditions": [21, 18], "products": [25]}, {"reactants": [27], "conditions": [17, 18], "products": [25]}, {"reactants": [29, 27], "conditions": [20], "products": [28]}, {"reactants": [28], "conditions": [13], "products": [26]}, {"reactants": [26], "conditions": [12], "products": [23]}, {"reactants": [23], "conditions": [0], "products": [24]}], "corefs": [[0, 9], [10, 8], [13, 1], [17, 7], [15, 4], [12, 2], [16, 6], [14, 5], [11, 3]], "caption": "Figure 1. Mechanistic pathways for the reduction of 1-iodo-4-nitrobenzene.1e", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 418, 457, 435], "ImageBB": [10, 22, 859, 411]}, "diagram_type": "graph"}, {"id": 182, "width": 1752, "height": 4044, "file_name": "ol501514b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1213.0, 3252.0, 39.0, 50.0], "category_id": 3}, {"id": 1, "bbox": [709.0, 3263.0, 37.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [310.0, 3261.0, 73.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [445.03, 33.05, 290.97, 150.35], "category_id": 1}, {"id": 4, "bbox": [834.0, 3031.0, 36.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [864.0, 2768.0, 40.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [501.0, 2770.0, 35.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [402.0, 2342.0, 256.0, 170.0], "category_id": 1}, {"id": 8, "bbox": [1211.0, 164.0, 41.0, 45.0], "category_id": 3}, {"id": 9, "bbox": [599.0, 164.0, 43.0, 51.0], "category_id": 3}, {"id": 10, "bbox": [229.0, 161.0, 41.0, 59.0], "category_id": 3}, {"id": 11, "bbox": [379.0, 3034.0, 41.0, 49.0], "category_id": 3}, {"id": 12, "bbox": [130.57, 18.95, 247.93, 153.0], "category_id": 1}, {"id": 13, "bbox": [1093.0, 3081.0, 289.0, 229.0], "category_id": 1}, {"id": 14, "bbox": [589.0, 3087.0, 272.0, 225.0], "category_id": 1}, {"id": 15, "bbox": [203.0, 3070.0, 285.0, 242.0], "category_id": 1}, {"id": 16, "bbox": [229.0, 2830.0, 313.0, 240.0], "category_id": 1}, {"id": 17, "bbox": [737.0, 2843.0, 270.0, 221.0], "category_id": 1}, {"id": 18, "bbox": [366.0, 2566.0, 294.0, 232.0], "category_id": 1}, {"id": 19, "bbox": [1144.0, 0.0, 291.5, 199.0], "category_id": 1}, {"id": 20, "bbox": [1104.0, 2305.0, 259.0, 255.0], "category_id": 1}, {"id": 21, "bbox": [761.0, 2373.0, 236.0, 125.0], "category_id": 1}, {"id": 22, "bbox": [748.0, 2543.0, 300.0, 231.0], "category_id": 1}, {"id": 23, "bbox": [512.0, 2465.0, 36.0, 50.0], "category_id": 3}, {"id": 24, "bbox": [859.0, 2470.0, 47.0, 43.0], "category_id": 3}, {"id": 25, "bbox": [1226.0, 2504.0, 34.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [14, 4], "conditions": [12, 22], "products": [21]}, {"reactants": [32], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [32]}, {"reactants": [8], "conditions": [26], "products": [24]}, {"reactants": [24], "conditions": [27], "products": [23]}, {"reactants": [24], "conditions": [], "products": [25]}, {"reactants": [25], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [], "products": [25]}, {"reactants": [20], "conditions": [], "products": [19]}, {"reactants": [19], "conditions": [], "products": [20]}, {"reactants": [19], "conditions": [], "products": [15]}, {"reactants": [23], "conditions": [28], "products": [15]}, {"reactants": [19], "conditions": [30, 31], "products": [18]}, {"reactants": [15], "conditions": [29], "products": [16]}, {"reactants": [16], "conditions": [], "products": [17]}], "corefs": [[12, 10], [3, 9], [19, 8], [7, 23], [21, 24], [20, 25], [18, 6], [22, 5], [16, 11], [17, 4], [15, 2], [14, 1], [13, 0]], "caption": "Table 2. Reaction Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 591, 110], "ImageBB": [421, 116, 859, 1127]}, "diagram_type": "graph"}, {"id": 183, "width": 1348, "height": 388, "file_name": "ol5012407-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [921.0, 28.0, 293.0, 215.0], "category_id": 1}, {"id": 1, "bbox": [260.0, 246.0, 47.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [140.0, 5.0, 293.0, 227.0], "category_id": 1}, {"id": 3, "bbox": [1038.0, 246.0, 56.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [6, 2], "products": [0]}], "corefs": [[2, 1], [0, 3]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 349, 110], "ImageBB": [82, 116, 419, 213]}, "diagram_type": "single"}, {"id": 184, "width": 1356, "height": 1212, "file_name": "ol501085y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1042.8, 0.0, 308.5, 241.0], "category_id": 1}, {"id": 1, "bbox": [6.2, 2.6, 260.3, 234.8], "category_id": 1}, {"id": 2, "bbox": [46.0, 229.0, 204.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [5, 7], "conditions": [2, 1], "products": [3]}], "corefs": [[1, 2]], "caption": "Table 2. Reaction Optimization for PyBidine-NiCl2- Catalyzed Asymmetric Nitro-Mannich Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 251, 742, 281], "ImageBB": [448, 287, 787, 590]}, "diagram_type": "single"}, {"id": 185, "width": 1348, "height": 420, "file_name": "ol500444z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [984.0, 275.0, 81.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [842.9, 93.6, 346.1, 156.7], "category_id": 1}, {"id": 2, "bbox": [462.3, 2.7, 275.8, 158.7], "category_id": 1}, {"id": 3, "bbox": [164.33, 109.25, 218.37, 142.45], "category_id": 1}, {"id": 4, "bbox": [220.0, 259.0, 78.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [2, 5], "products": [1]}], "corefs": [[3, 4], [1, 0]], "caption": "Table 1. Synthesis of Quinoxalinesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 212, 285, 233], "ImageBB": [82, 239, 419, 344]}, "diagram_type": "single"}, {"id": 186, "width": 1344, "height": 632, "file_name": "ol402981z-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1017.0, 230.0, 308.0, 248.6], "category_id": 1}, {"id": 1, "bbox": [490.8, 212.7, 336.0, 267.4], "category_id": 1}, {"id": 2, "bbox": [26.3, 291.9, 263.0, 157.7], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [7, 8], "products": [2]}, {"reactants": [2], "conditions": [0, 5], "products": [1]}], "corefs": [], "caption": "Figure 1. Concept behind enantioselective halonium ion-initiated Wagner Meerwein transposition of allylic alcohols. Hal = F, Cl, Br, or I. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 568, 405, 612], "ImageBB": [71, 400, 407, 558]}, "diagram_type": "single"}, {"id": 187, "width": 1352, "height": 1588, "file_name": "ol4017244-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [197.0, 631.0, 137.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [957.0, 177.0, 359.0, 195.0], "category_id": 1}, {"id": 2, "bbox": [45.0, 227.0, 333.0, 143.0], "category_id": 1}, {"id": 3, "bbox": [1083.0, 1535.0, 127.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [623.0, 1540.0, 136.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [198.0, 1528.0, 144.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [1083.0, 1235.0, 142.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [617.0, 1235.0, 160.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [195.0, 1225.0, 157.0, 48.0], "category_id": 3}, {"id": 9, "bbox": [1080.0, 934.0, 132.0, 40.0], "category_id": 3}, {"id": 10, "bbox": [620.0, 937.0, 137.0, 42.0], "category_id": 3}, {"id": 11, "bbox": [498.0, 1341.0, 372.0, 174.0], "category_id": 1}, {"id": 12, "bbox": [41.0, 439.0, 374.0, 193.0], "category_id": 1}, {"id": 13, "bbox": [1089.0, 383.0, 34.0, 37.0], "category_id": 3}, {"id": 14, "bbox": [969.0, 1342.0, 346.0, 174.0], "category_id": 1}, {"id": 15, "bbox": [182.0, 385.0, 29.0, 40.0], "category_id": 3}, {"id": 16, "bbox": [195.0, 927.0, 139.0, 43.0], "category_id": 3}, {"id": 17, "bbox": [1083.0, 632.0, 137.0, 48.0], "category_id": 3}, {"id": 18, "bbox": [620.0, 636.0, 140.0, 43.0], "category_id": 3}, {"id": 19, "bbox": [931.0, 1041.0, 381.0, 188.0], "category_id": 1}, {"id": 20, "bbox": [544.0, 1041.0, 322.0, 175.0], "category_id": 1}, {"id": 21, "bbox": [69.0, 1040.0, 348.0, 189.0], "category_id": 1}, {"id": 22, "bbox": [947.0, 738.0, 365.0, 196.0], "category_id": 1}, {"id": 23, "bbox": [554.0, 951.0, 5.0, 9.0], "category_id": 1}, {"id": 24, "bbox": [502.0, 742.0, 365.0, 235.0], "category_id": 1}, {"id": 25, "bbox": [139.0, 1342.0, 278.0, 170.0], "category_id": 1}, {"id": 26, "bbox": [65.0, 739.0, 350.0, 188.0], "category_id": 1}, {"id": 27, "bbox": [964.0, 439.0, 349.0, 187.0], "category_id": 1}, {"id": 28, "bbox": [511.0, 440.0, 353.0, 186.0], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [3], "products": [1]}], "corefs": [[2, 15], [1, 13], [12, 0], [28, 18], [27, 17], [26, 16], [24, 10], [22, 9], [21, 8], [20, 7], [19, 6], [25, 5], [11, 4], [14, 3]], "caption": "Figure 1. Scope of aryl diazonium salts. Reaction conditions: All reactions were performed with 1 (0.2 mmol) and 2a (3 equiv), in 0.4 mL of H2O and 1.0 mL of acetone at 0 \u00b0C, in Ar, for 20 min; isolated yields of 3. aThe reaction was performed with 5 equiv of 2a. ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 709, 405, 764], "ImageBB": [71, 300, 409, 697]}, "diagram_type": "single"}, {"id": 188, "width": 1344, "height": 1004, "file_name": "ol4013926-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [22.6, 367.5, 432.4, 377.0], "category_id": 1}, {"id": 1, "bbox": [478.9, 368.2, 437.8, 378.9], "category_id": 1}, {"id": 2, "bbox": [972.3, 366.0, 335.0, 415.2], "category_id": 1}, {"id": 3, "bbox": [474.0, 745.0, 312.0, 99.0], "category_id": 3}, {"id": 4, "bbox": [188.0, 747.0, 103.0, 61.0], "category_id": 3}], "reactions": [], "corefs": [[0, 4], [1, 3]], "caption": "Figure 1. Bifunctional quaternary phophonium salts and a possible working model. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 581, 405, 608], "ImageBB": [71, 317, 407, 568]}, "diagram_type": "tree"}, {"id": 189, "width": 1352, "height": 892, "file_name": "ol401042b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [145.0, 323.0, 60.0, 25.0], "category_id": 3}, {"id": 1, "bbox": [26.9, 5.6, 301.1, 316.7], "category_id": 1}, {"id": 2, "bbox": [426.15, 175.7, 192.9, 107.0], "category_id": 1}, {"id": 3, "bbox": [925.0, 64.4, 396.0, 251.6], "category_id": 1}, {"id": 4, "bbox": [1057.0, 318.0, 128.0, 36.6], "category_id": 3}], "reactions": [{"reactants": [4, 6], "conditions": [3, 2], "products": [7]}], "corefs": [[1, 0], [3, 4]], "caption": "Table 3. Scope of Substrate for Organocatalytic Annulationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 483, 394, 499], "ImageBB": [71, 510, 409, 733]}, "diagram_type": "single"}, {"id": 190, "width": 1384, "height": 624, "file_name": "ol050791f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.7, 15.3, 144.8, 197.0], "category_id": 1}, {"id": 1, "bbox": [1152.0, 212.0, 45.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [157.0, 217.0, 73.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [1067.5, 0.0, 315.5, 226.5], "category_id": 1}, {"id": 4, "bbox": [76.4, 26.4, 247.0, 174.1], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [2, 1], "products": [6]}], "corefs": [[4, 2], [3, 1]], "caption": "Table 2. Preparation of Fluorinated \u03b3-Amino Alcohols 2 from Aldimines 1 and Other Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 403, 105], "ImageBB": [74, 109, 420, 265]}, "diagram_type": "single"}, {"id": 191, "width": 1352, "height": 848, "file_name": "ol047761h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [970.0, 49.0, 235.0, 139.0], "category_id": 1}, {"id": 1, "bbox": [124.0, 0.0, 269.0, 216.0], "category_id": 1}, {"id": 2, "bbox": [1189.0, 179.0, 33.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [333.0, 177.0, 28.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [2, 6], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Lactonization Study of Bn2N-R-Me-Ser", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 196, 699, 210], "ImageBB": [439, 218, 777, 430]}, "diagram_type": "single"}, {"id": 192, "width": 1344, "height": 1084, "file_name": "ol035127i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [743.0, 0.0, 315.0, 294.0], "category_id": 1}, {"id": 1, "bbox": [12.0, 32.0, 410.0, 257.0], "category_id": 1}, {"id": 2, "bbox": [1063.0, 0.0, 267.0, 311.0], "category_id": 1}, {"id": 3, "bbox": [1171.0, 289.0, 72.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [164.0, 297.0, 61.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [981.0, 296.0, 70.0, 53.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [0, 2]}], "corefs": [[1, 4], [0, 5], [2, 3]], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 147, 339, 160], "ImageBB": [74, 171, 410, 442]}, "diagram_type": "single"}, {"id": 193, "width": 1348, "height": 800, "file_name": "ol016212y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [916.9, 2.1, 313.0, 241.7], "category_id": 1}, {"id": 1, "bbox": [96.4, 7.3, 265.2, 236.5], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [4, 2], "products": [0]}], "corefs": [], "caption": "Table 2. Comparison of the Fiber-Supported Amino Alcohol P3 with 3 and 5 as Catalysts in the Addition of Et2Zn to PhCHO ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 276, 761, 320], "ImageBB": [439, 322, 776, 522]}, "diagram_type": "single"}, {"id": 194, "width": 1352, "height": 1084, "file_name": "ol0157003-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [144.3, 194.7, 306.6, 172.5], "category_id": 1}, {"id": 1, "bbox": [1044.0, 382.0, 33.0, 41.3], "category_id": 3}, {"id": 2, "bbox": [106.2, 522.8, 376.7, 213.0], "category_id": 1}, {"id": 3, "bbox": [871.0, 516.0, 372.9, 222.2], "category_id": 1}, {"id": 4, "bbox": [273.91, 381.81, 31.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [913.0, 196.0, 319.0, 175.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [10], "products": [2]}, {"reactants": [9], "conditions": [8], "products": [3]}], "corefs": [[0, 4], [5, 1]], "caption": "Figure 1. Acetal substrates.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 553, 222, 566], "ImageBB": [73, 269, 411, 540]}, "diagram_type": "tree"}, {"id": 195, "width": 1340, "height": 924, "file_name": "ol010283f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [893.28, 22.19, 443.0, 274.0], "category_id": 1}, {"id": 1, "bbox": [1091.0, 275.81, 83.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [239.0, 279.0, 86.0, 58.0], "category_id": 3}, {"id": 3, "bbox": [0.0, 0.0, 548.0, 274.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 3], "products": [0]}], "corefs": [[3, 2], [0, 1]], "caption": "Table 2. Effect of Ruthenium Porphyrin Catalysts on Cyclization of (-)-Menthyl-\u03b3-benzyloxy-R-diazo-\u03b2-ketoesterd ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 702, 757, 730], "ImageBB": [440, 733, 775, 964]}, "diagram_type": "single"}, {"id": 196, "width": 1348, "height": 716, "file_name": "jo990938e-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [729.0, 195.0, 119.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [243.0, 195.0, 89.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [1010.0, 196.0, 122.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [152.0, 14.0, 297.0, 171.0], "category_id": 1}, {"id": 4, "bbox": [662.0, 19.0, 262.0, 173.0], "category_id": 1}, {"id": 5, "bbox": [937.0, 14.0, 263.0, 182.0], "category_id": 1}, {"id": 6, "bbox": [515.3, 2.0, 118.2, 114.9], "category_id": 1}, {"id": 7, "bbox": [587.6, 49.92, 38.63, 40.67], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [3, 9, 7], "products": [5, 8]}], "corefs": [[3, 1], [6, 7], [4, 0], [5, 2]], "caption": " Table 7. Additions of Transient Chiral Allenylindium Reagents from Mesylate ent-1 to Representative Achiral                       Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [444, 64, 770, 101], "ImageBB": [439, 110, 776, 289]}, "diagram_type": "single"}, {"id": 197, "width": 1344, "height": 712, "file_name": "jo990938e-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.97, 49.86, 34.46, 40.54], "category_id": 3}, {"id": 1, "bbox": [665.0, 187.0, 92.0, 33.0], "category_id": 3}, {"id": 2, "bbox": [1011.0, 189.0, 93.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [148.0, 18.0, 248.0, 161.0], "category_id": 1}, {"id": 4, "bbox": [445.0, 5.0, 120.0, 113.0], "category_id": 1}, {"id": 5, "bbox": [601.0, 22.0, 249.0, 161.0], "category_id": 1}, {"id": 6, "bbox": [940.0, 21.0, 251.0, 161.0], "category_id": 1}, {"id": 7, "bbox": [238.0, 190.0, 27.0, 34.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [9, 5, 10], "products": [6, 7]}], "corefs": [[3, 7], [4, 0], [5, 1], [6, 2]], "caption": "Table 6. Additions of Transient Chiral Allenylindium  Reagents from Mesylate 7 to Representative Achiral                      Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [83, 64, 398, 101], "ImageBB": [74, 110, 410, 288]}, "diagram_type": "single"}, {"id": 198, "width": 2028, "height": 1676, "file_name": "jo951894m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [933.0, 1235.0, 58.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [1862.0, 1285.0, 68.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [179.0, 1227.0, 58.0, 77.0], "category_id": 3}, {"id": 3, "bbox": [960.0, 693.0, 52.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [474.0, 1620.0, 71.0, 56.0], "category_id": 3}, {"id": 5, "bbox": [1636.0, 1620.0, 72.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [94.0, 699.0, 44.0, 63.0], "category_id": 3}, {"id": 7, "bbox": [94.0, 275.0, 52.0, 69.0], "category_id": 3}, {"id": 8, "bbox": [894.0, 283.0, 58.0, 61.0], "category_id": 3}, {"id": 9, "bbox": [1845.0, 729.0, 41.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [1787.0, 368.0, 61.0, 55.0], "category_id": 3}, {"id": 11, "bbox": [295.16, 215.62, 220.17, 143.79], "category_id": 1}, {"id": 12, "bbox": [732.0, 115.0, 341.0, 162.0], "category_id": 1}, {"id": 13, "bbox": [850.0, 396.0, 253.0, 294.0], "category_id": 1}, {"id": 14, "bbox": [1683.0, 407.0, 297.0, 308.0], "category_id": 1}, {"id": 15, "bbox": [839.0, 913.0, 286.0, 297.0], "category_id": 1}, {"id": 16, "bbox": [1353.0, 1252.0, 462.0, 401.0], "category_id": 1}, {"id": 17, "bbox": [52.5, 924.0, 286.5, 286.0], "category_id": 1}, {"id": 18, "bbox": [277.0, 1309.0, 429.8, 295.0], "category_id": 1}, {"id": 19, "bbox": [988.0, 743.0, 777.0, 147.8], "category_id": 3}, {"id": 20, "bbox": [3.0, 107.0, 185.2, 129.4], "category_id": 1}, {"id": 21, "bbox": [1668.9, 85.0, 322.9, 272.2], "category_id": 1}, {"id": 22, "bbox": [1021.0, 271.8, 280.0, 116.2], "category_id": 3}, {"id": 23, "bbox": [17.0, 393.0, 223.7, 295.3], "category_id": 1}, {"id": 24, "bbox": [1735.0, 960.0, 290.8, 298.0], "category_id": 1}], "reactions": [{"reactants": [31], "conditions": [20, 19], "products": [23]}, {"reactants": [23], "conditions": [8], "products": [32]}, {"reactants": [32], "conditions": [], "products": [24]}, {"reactants": [24], "conditions": [9], "products": [34]}, {"reactants": [24], "conditions": [7], "products": [25]}, {"reactants": [24], "conditions": [22], "products": [26]}, {"reactants": [26], "conditions": [10], "products": [28]}, {"reactants": [26], "conditions": [6], "products": [35]}, {"reactants": [26], "conditions": [4], "products": [29]}, {"reactants": [26], "conditions": [5], "products": [27]}], "corefs": [[20, 7], [12, 8], [12, 22], [21, 10], [13, 3], [23, 6], [14, 9], [15, 0], [17, 2], [18, 4], [24, 1], [16, 5], [15, 19]], "caption": "Table 1. Reactions of 1,4-Di- and 1,4,5-Trisubstituted-2-[(benzotriazol-1-yl)alkyl]pyrroles 7, 10, 15, 17, and 19", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [99, 486, 729, 498], "ImageBB": [161, 54, 668, 473]}, "diagram_type": "tree"}, {"id": 199, "width": 1352, "height": 2364, "file_name": "jo501910q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.54, 735.13, 129.92, 72.89], "category_id": 3}, {"id": 1, "bbox": [551.0, 1827.0, 408.0, 307.0], "category_id": 1}, {"id": 2, "bbox": [745.59, 224.94, 120.42, 60.21], "category_id": 3}, {"id": 3, "bbox": [311.45, 215.43, 129.93, 57.04], "category_id": 3}, {"id": 4, "bbox": [573.0, 1276.8, 333.2, 365.4], "category_id": 1}, {"id": 5, "bbox": [65.0, 1307.3, 377.7, 306.2], "category_id": 1}, {"id": 6, "bbox": [873.7, 856.2, 338.8, 310.0], "category_id": 1}, {"id": 7, "bbox": [431.5, 858.5, 347.0, 307.5], "category_id": 1}, {"id": 8, "bbox": [81.0, 1615.5, 636.8, 197.5], "category_id": 3}, {"id": 9, "bbox": [108.5, 852.5, 278.1, 311.9], "category_id": 1}, {"id": 10, "bbox": [398.0, 426.6, 387.9, 382.4], "category_id": 1}, {"id": 11, "bbox": [915.0, 1627.0, 404.0, 95.0], "category_id": 3}, {"id": 12, "bbox": [977.0, 2130.0, 229.0, 69.0], "category_id": 3}, {"id": 13, "bbox": [500.0, 1583.0, 199.1, 57.8], "category_id": 3}, {"id": 14, "bbox": [96.2, 1160.18, 340.1, 159.12], "category_id": 3}, {"id": 15, "bbox": [469.34, 1158.34, 343.0, 117.0], "category_id": 3}, {"id": 16, "bbox": [822.32, 1156.83, 383.88, 110.47], "category_id": 3}, {"id": 17, "bbox": [660.0, 2145.14, 233.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [138.2, 2205.5, 739.6, 120.7], "category_id": 3}, {"id": 19, "bbox": [959.49, 1805.2, 331.01, 322.46], "category_id": 1}, {"id": 20, "bbox": [255.4, 65.0, 338.6, 159.6], "category_id": 1}, {"id": 21, "bbox": [634.35, 3.83, 301.25, 229.47], "category_id": 1}, {"id": 22, "bbox": [138.4, 1813.8, 411.6, 386.8], "category_id": 1}, {"id": 23, "bbox": [949.5, 1315.7, 333.1, 308.1], "category_id": 1}], "reactions": [{"reactants": [20, 21], "conditions": [22], "products": [10]}], "corefs": [[20, 3], [21, 2], [10, 0], [9, 14], [7, 15], [6, 16], [5, 8], [4, 13], [23, 11], [22, 18], [1, 17], [19, 12]], "caption": "Table 2. Synthesis of Various Substituted 5,6- Dihydrophenanthridines ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 340, 263], "ImageBB": [82, 269, 420, 860]}, "diagram_type": "tree"}, {"id": 200, "width": 1352, "height": 544, "file_name": "jo501736w-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [945.0, 482.0, 51.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [422.0, 499.0, 58.0, 38.0], "category_id": 3}, {"id": 2, "bbox": [1137.9, 233.0, 48.1, 44.0], "category_id": 3}, {"id": 3, "bbox": [251.4, 241.1, 367.5, 236.7], "category_id": 1}, {"id": 4, "bbox": [1003.3, 95.0, 348.7, 144.0], "category_id": 1}, {"id": 5, "bbox": [329.3, 96.1, 134.2, 140.7], "category_id": 1}, {"id": 6, "bbox": [775.2, 311.1, 350.4, 169.0], "category_id": 1}, {"id": 7, "bbox": [1.0, 93.3, 240.9, 135.6], "category_id": 1}], "reactions": [{"reactants": [9, 6], "conditions": [8, 0], "products": [5]}, {"reactants": [9, 6], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [9, 6]}, {"reactants": [4], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [4]}, {"reactants": [7], "conditions": [], "products": [5]}], "corefs": [[3, 1], [6, 0], [4, 2]], "caption": "Figure 2. Proposed direct electrochemical amination for the formation of 2-aminobenzoxazoles. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 435, 417, 463], "ImageBB": [82, 290, 420, 426]}, "diagram_type": "graph"}, {"id": 201, "width": 1348, "height": 288, "file_name": "jo501006u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [643.51, 49.92, 160.62, 56.93], "category_id": 1}, {"id": 1, "bbox": [1121.0, 95.0, 144.0, 53.0], "category_id": 1}, {"id": 2, "bbox": [329.0, 83.0, 221.0, 60.1], "category_id": 1}, {"id": 3, "bbox": [82.0, 83.0, 97.0, 60.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [6, 2, 3, 5], "products": [4]}], "corefs": [], "caption": "Table 2. Coupling Reaction of Alkyl (Pseudo)halides with n- BuMgCl Using 1,3-Butadiene as an Additivea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 473, 784, 507], "ImageBB": [449, 514, 786, 586]}, "diagram_type": "single"}, {"id": 202, "width": 1348, "height": 496, "file_name": "jo4014707-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.0, 295.0, 144.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [65.5, 44.0, 185.5, 233.0], "category_id": 1}, {"id": 2, "bbox": [1022.3, 47.0, 262.7, 229.0], "category_id": 1}, {"id": 3, "bbox": [112.0, 301.0, 63.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [2, 7], "products": [3]}], "corefs": [[1, 3], [2, 0]], "caption": "Table 3. Asymmetric 1,4-Addition of 2a to N-Me-maleimide (6a)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 417, 125], "ImageBB": [82, 131, 419, 255]}, "diagram_type": "single"}, {"id": 203, "width": 1912, "height": 2060, "file_name": "jo400755q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [104.0, 1435.0, 254.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [1409.0, 915.0, 274.0, 71.0], "category_id": 3}, {"id": 2, "bbox": [943.0, 913.0, 253.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [531.0, 915.0, 248.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [112.0, 911.0, 242.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [276.0, 10.0, 340.0, 310.0], "category_id": 1}, {"id": 6, "bbox": [924.0, 6.0, 336.0, 302.0], "category_id": 1}, {"id": 7, "bbox": [1081.0, 300.0, 73.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [299.0, 292.0, 183.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [1565.0, 1433.0, 77.0, 52.0], "category_id": 3}, {"id": 10, "bbox": [559.0, 1433.0, 265.0, 65.0], "category_id": 3}, {"id": 11, "bbox": [112.2, 1505.0, 312.0, 440.8], "category_id": 1}, {"id": 12, "bbox": [1262.3, 1585.5, 478.2, 321.7], "category_id": 1}, {"id": 13, "bbox": [863.0, 995.0, 408.7, 419.0], "category_id": 1}, {"id": 14, "bbox": [675.4, 1512.5, 341.4, 440.0], "category_id": 1}, {"id": 15, "bbox": [464.2, 977.3, 403.0, 442.7], "category_id": 1}, {"id": 16, "bbox": [1323.0, 1004.0, 411.1, 407.2], "category_id": 1}, {"id": 17, "bbox": [672.0, 1947.0, 254.4, 69.0], "category_id": 3}, {"id": 18, "bbox": [443.5, 447.6, 391.5, 421.4], "category_id": 1}, {"id": 19, "bbox": [110.1, 423.8, 306.2, 364.2], "category_id": 1}, {"id": 20, "bbox": [17.8, 995.8, 400.5, 410.0], "category_id": 1}, {"id": 21, "bbox": [1269.0, 449.0, 476.7, 454.5], "category_id": 1}, {"id": 22, "bbox": [887.0, 447.0, 373.0, 418.0], "category_id": 1}, {"id": 23, "bbox": [1258.0, 1947.0, 250.0, 72.5], "category_id": 3}, {"id": 24, "bbox": [1118.48, 1419.48, 54.2, 69.5], "category_id": 3}, {"id": 25, "bbox": [117.0, 1953.24, 248.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [9, 13], "products": [6]}], "corefs": [[5, 8], [6, 7], [19, 4], [18, 3], [22, 2], [21, 1], [20, 0], [15, 10], [13, 24], [16, 9], [11, 25], [14, 17], [12, 23]], "caption": "Table 3. Ortho-Chlorination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 530, 111], "ImageBB": [195, 116, 673, 631]}, "diagram_type": "single"}, {"id": 204, "width": 1348, "height": 408, "file_name": "jo4004426-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [285.4, 28.0, 179.8, 279.0], "category_id": 1}, {"id": 1, "bbox": [963.0, 3.0, 352.9, 301.9], "category_id": 1}, {"id": 2, "bbox": [32.1, 16.0, 132.2, 296.0], "category_id": 1}, {"id": 3, "bbox": [451.0, 236.0, 34.0, 52.0], "category_id": 3}, {"id": 4, "bbox": [1124.0, 229.0, 45.0, 63.0], "category_id": 3}, {"id": 5, "bbox": [149.0, 239.0, 42.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [4, 0], "products": [2]}], "corefs": [[2, 5], [0, 3], [1, 4]], "caption": "Table 2. Optimization Studies with Heterogeneous Copper Catalysts ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 205, 415, 235], "ImageBB": [82, 242, 419, 344]}, "diagram_type": "single"}, {"id": 205, "width": 1236, "height": 2336, "file_name": "jo300771f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [861.0, 1079.3, 309.0, 344.7], "category_id": 1}, {"id": 1, "bbox": [79.0, 744.0, 295.0, 248.0], "category_id": 1}, {"id": 2, "bbox": [471.0, 375.0, 304.0, 233.0], "category_id": 1}, {"id": 3, "bbox": [368.8, 688.0, 454.2, 341.0], "category_id": 1}, {"id": 4, "bbox": [815.5, 683.4, 393.7, 320.6], "category_id": 1}, {"id": 5, "bbox": [77.3, 1143.0, 301.7, 262.0], "category_id": 1}, {"id": 6, "bbox": [446.4, 1115.9, 372.6, 296.1], "category_id": 1}, {"id": 7, "bbox": [868.0, 21.5, 358.0, 233.5], "category_id": 1}, {"id": 8, "bbox": [14.0, 2.0, 362.1, 242.0], "category_id": 1}, {"id": 9, "bbox": [79.0, 1525.7, 299.6, 300.9], "category_id": 1}, {"id": 10, "bbox": [830.6, 1555.5, 362.3, 253.6], "category_id": 1}, {"id": 11, "bbox": [63.0, 1934.2, 618.0, 334.8], "category_id": 1}, {"id": 12, "bbox": [80.9, 380.3, 300.3, 219.7], "category_id": 1}, {"id": 13, "bbox": [859.7, 380.3, 310.3, 219.7], "category_id": 1}, {"id": 14, "bbox": [606.0, 1945.0, 615.0, 321.0], "category_id": 1}, {"id": 15, "bbox": [138.0, 1851.0, 166.8, 58.8], "category_id": 3}, {"id": 16, "bbox": [924.0, 1014.92, 167.0, 51.0], "category_id": 3}, {"id": 17, "bbox": [529.0, 1020.0, 190.3, 46.9], "category_id": 3}, {"id": 18, "bbox": [143.0, 1014.0, 183.5, 53.0], "category_id": 3}, {"id": 19, "bbox": [139.0, 621.0, 175.2, 42.0], "category_id": 3}, {"id": 20, "bbox": [545.0, 1428.0, 169.7, 52.7], "category_id": 3}, {"id": 21, "bbox": [477.3, 1511.3, 312.2, 348.2], "category_id": 1}, {"id": 22, "bbox": [545.11, 613.0, 164.0, 57.0], "category_id": 3}, {"id": 23, "bbox": [931.0, 613.0, 182.1, 52.0], "category_id": 3}, {"id": 24, "bbox": [928.73, 1851.85, 164.27, 57.35], "category_id": 3}, {"id": 25, "bbox": [925.0, 1426.0, 175.4, 52.8], "category_id": 3}, {"id": 26, "bbox": [547.0, 1856.1, 167.8, 51.8], "category_id": 3}, {"id": 27, "bbox": [285.0, 2282.0, 186.8, 49.0], "category_id": 3}, {"id": 28, "bbox": [823.0, 2277.0, 170.9, 50.9], "category_id": 3}, {"id": 29, "bbox": [1032.0, 276.0, 30.0, 43.0], "category_id": 3}, {"id": 30, "bbox": [172.0, 273.0, 37.0, 41.0], "category_id": 3}, {"id": 31, "bbox": [141.78, 1422.6, 172.66, 56.9], "category_id": 3}], "reactions": [{"reactants": [8, 32], "conditions": [25, 26], "products": [7]}], "corefs": [[8, 30], [7, 29], [12, 19], [2, 22], [13, 23], [1, 18], [3, 17], [4, 16], [5, 31], [6, 20], [0, 25], [9, 15], [21, 26], [10, 24], [11, 27], [14, 28]], "caption": "Table 2. Substrate Scopea,b", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 239, 109], "ImageBB": [96, 116, 405, 700]}, "diagram_type": "single"}, {"id": 206, "width": 1352, "height": 3144, "file_name": "jo201489z-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [827.0, 603.0, 441.0, 408.0], "category_id": 1}, {"id": 1, "bbox": [736.0, 477.0, 66.0, 31.0], "category_id": 3}, {"id": 2, "bbox": [734.0, 942.0, 59.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [1128.0, 1501.0, 71.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [586.0, 1487.0, 95.0, 65.0], "category_id": 3}, {"id": 5, "bbox": [608.0, 2037.0, 82.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [1130.0, 2021.0, 83.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [543.0, 85.0, 442.0, 399.0], "category_id": 1}, {"id": 8, "bbox": [316.0, 599.0, 445.0, 406.0], "category_id": 1}, {"id": 9, "bbox": [293.0, 1163.0, 438.0, 385.0], "category_id": 1}, {"id": 10, "bbox": [807.0, 1156.0, 435.0, 402.0], "category_id": 1}, {"id": 11, "bbox": [817.0, 1677.0, 418.0, 402.0], "category_id": 1}, {"id": 12, "bbox": [300.0, 1670.0, 421.0, 416.0], "category_id": 1}, {"id": 13, "bbox": [145.0, 2267.0, 540.0, 550.0], "category_id": 1}, {"id": 14, "bbox": [636.0, 2231.0, 566.0, 570.0], "category_id": 1}, {"id": 15, "bbox": [277.0, 2811.0, 388.0, 319.0], "category_id": 1}, {"id": 16, "bbox": [748.0, 2794.0, 401.0, 333.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [3], "products": [12, 0]}, {"reactants": [12], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [16]}, {"reactants": [0], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [15]}, {"reactants": [16], "conditions": [2], "products": [8]}], "corefs": [[7, 1], [8, 2], [0, 2], [9, 4], [10, 3], [12, 5], [11, 6]], "caption": "Figure 2. DFT calculated structures IIB (left) and IIIA (right), shown above the expansions of the key bipyrrolic fragments. ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 875, 405, 903], "ImageBB": [69, 81, 407, 867]}, "diagram_type": "tree"}, {"id": 207, "width": 1356, "height": 908, "file_name": "jo2001534-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1014.0, 7.0, 337.0, 333.0], "category_id": 1}, {"id": 1, "bbox": [491.0, 21.0, 335.0, 301.0], "category_id": 1}, {"id": 2, "bbox": [1.0, 25.0, 339.0, 293.0], "category_id": 1}, {"id": 3, "bbox": [1141.0, 341.0, 86.0, 38.0], "category_id": 3}, {"id": 4, "bbox": [614.0, 340.0, 71.0, 38.0], "category_id": 3}, {"id": 5, "bbox": [135.0, 343.0, 71.0, 34.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0], "products": [2]}, {"reactants": [2], "conditions": [8], "products": [1]}], "corefs": [[2, 5], [1, 4], [0, 3]], "caption": "Table 5. Yields and Substitution Patterns for Compounds 10a-e ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 672, 392, 702], "ImageBB": [71, 709, 410, 936]}, "diagram_type": "single"}, {"id": 208, "width": 1348, "height": 560, "file_name": "ol5029892-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [173.06, 131.92, 35.29, 44.76], "category_id": 3}, {"id": 1, "bbox": [1060.54, 129.33, 43.9, 47.35], "category_id": 3}, {"id": 2, "bbox": [965.0, 364.0, 383.0, 52.5], "category_id": 3}, {"id": 3, "bbox": [405.0, 357.0, 192.0, 60.1], "category_id": 3}, {"id": 4, "bbox": [649.0, 368.0, 297.0, 51.4], "category_id": 3}, {"id": 5, "bbox": [119.9, 67.9, 145.8, 59.7], "category_id": 1}, {"id": 6, "bbox": [365.0, 249.0, 272.5, 68.4], "category_id": 1}, {"id": 7, "bbox": [989.5, 4.0, 185.5, 124.8], "category_id": 1}, {"id": 8, "bbox": [115.0, 368.7, 105.5, 38.3], "category_id": 3}, {"id": 9, "bbox": [1021.2, 207.3, 251.7, 148.7], "category_id": 1}, {"id": 10, "bbox": [673.4, 228.1, 246.3, 105.6], "category_id": 1}, {"id": 11, "bbox": [9.7, 186.5, 319.5, 191.7], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [15, 9], "products": [10]}], "corefs": [[5, 0], [7, 1], [11, 8], [6, 3], [10, 4], [9, 2]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 268, 110], "ImageBB": [82, 116, 419, 256]}, "diagram_type": "single"}, {"id": 209, "width": 2820, "height": 824, "file_name": "acs.oprd.5b00070-Figure-c2.png", "license": 0, "bboxes": [], "reactions": [{"reactants": [16, 3], "conditions": [18, 11], "products": [4, 5, 17]}, {"reactants": [16, 3], "conditions": [10, 12], "products": [2, 15]}, {"reactants": [2, 15], "conditions": [19, 9], "products": [14, 0, 7]}, {"reactants": [4, 5, 17, 14, 0, 7], "conditions": [13], "products": [8]}], "corefs": [], "caption": "Figure 2. Investigation of two potential process routes for the synthesis of rif S.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 558, 471, 572], "ImageBB": [82, 343, 787, 549]}, "diagram_type": "graph"}, {"id": 210, "width": 1316, "height": 820, "file_name": "acs.joc.5b02382-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [541.0, 360.0, 258.0, 99.0], "category_id": 3}, {"id": 1, "bbox": [483.5, 203.0, 403.7, 147.7], "category_id": 1}, {"id": 2, "bbox": [7.0, 244.2, 443.9, 114.5], "category_id": 1}, {"id": 3, "bbox": [865.8, 465.4, 405.7, 105.5], "category_id": 1}, {"id": 4, "bbox": [479.9, 465.1, 381.7, 105.0], "category_id": 1}, {"id": 5, "bbox": [907.9, 212.5, 399.8, 144.5], "category_id": 1}, {"id": 6, "bbox": [878.0, 29.5, 338.4, 124.5], "category_id": 1}, {"id": 7, "bbox": [281.3, 0.0, 304.7, 150.5], "category_id": 1}, {"id": 8, "bbox": [38.9, 10.6, 196.1, 141.1], "category_id": 1}, {"id": 9, "bbox": [876.3, 639.0, 346.8, 124.2], "category_id": 1}, {"id": 10, "bbox": [434.5, 638.4, 320.2, 122.6], "category_id": 1}, {"id": 11, "bbox": [74.0, 375.0, 281.0, 356.5], "category_id": 3}, {"id": 12, "bbox": [1002.0, 588.0, 119.0, 50.0], "category_id": 3}, {"id": 13, "bbox": [542.0, 768.0, 151.0, 46.0], "category_id": 3}, {"id": 14, "bbox": [981.0, 138.0, 35.0, 29.0], "category_id": 3}, {"id": 15, "bbox": [408.0, 127.0, 52.0, 42.0], "category_id": 3}, {"id": 16, "bbox": [111.0, 127.0, 36.0, 35.0], "category_id": 3}, {"id": 17, "bbox": [539.0, 582.0, 140.0, 48.0], "category_id": 3}, {"id": 18, "bbox": [989.0, 374.0, 147.0, 54.0], "category_id": 3}, {"id": 19, "bbox": [1002.0, 771.0, 130.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [9, 8], "conditions": [5], "products": [7]}], "corefs": [[8, 16], [7, 15], [6, 14], [2, 11], [1, 0], [4, 17], [10, 13], [5, 18], [3, 12], [9, 19]], "caption": "Table 2. Substrate Scope of the Propargylic Amidesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 274, 748, 295], "ImageBB": [453, 300, 782, 505]}, "diagram_type": "single"}, {"id": 211, "width": 1352, "height": 1828, "file_name": "acs.joc.5b02057-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [988.0, 1456.0, 316.0, 262.0], "category_id": 1}, {"id": 1, "bbox": [679.0, 1458.0, 285.0, 283.0], "category_id": 1}, {"id": 2, "bbox": [378.0, 1452.0, 281.0, 293.0], "category_id": 1}, {"id": 3, "bbox": [4.0, 1469.0, 330.0, 267.0], "category_id": 1}, {"id": 4, "bbox": [1024.0, 1070.0, 271.0, 317.0], "category_id": 1}, {"id": 5, "bbox": [685.0, 1064.0, 281.0, 325.0], "category_id": 1}, {"id": 6, "bbox": [360.0, 1059.0, 303.0, 328.0], "category_id": 1}, {"id": 7, "bbox": [15.0, 1064.0, 316.0, 320.0], "category_id": 1}, {"id": 8, "bbox": [1024.0, 654.0, 280.0, 316.0], "category_id": 1}, {"id": 9, "bbox": [690.0, 659.0, 296.0, 305.0], "category_id": 1}, {"id": 10, "bbox": [376.0, 654.0, 283.0, 321.0], "category_id": 1}, {"id": 11, "bbox": [6.0, 650.0, 290.0, 305.0], "category_id": 1}, {"id": 12, "bbox": [1028.0, 302.0, 260.0, 294.0], "category_id": 1}, {"id": 13, "bbox": [674.0, 291.0, 301.0, 290.0], "category_id": 1}, {"id": 14, "bbox": [369.0, 400.0, 274.0, 190.0], "category_id": 1}, {"id": 15, "bbox": [13.0, 398.0, 285.0, 192.0], "category_id": 1}, {"id": 16, "bbox": [1030.0, 0.0, 319.0, 207.0], "category_id": 1}, {"id": 17, "bbox": [340.0, 66.0, 236.0, 141.0], "category_id": 1}, {"id": 18, "bbox": [0.0, 69.0, 289.0, 120.0], "category_id": 1}, {"id": 19, "bbox": [1150.0, 218.0, 61.0, 40.0], "category_id": 3}, {"id": 20, "bbox": [409.0, 215.0, 76.0, 47.0], "category_id": 3}, {"id": 21, "bbox": [78.0, 211.0, 71.0, 53.0], "category_id": 3}, {"id": 22, "bbox": [716.0, 1741.0, 196.0, 53.0], "category_id": 3}, {"id": 23, "bbox": [391.0, 1747.0, 210.0, 49.0], "category_id": 3}, {"id": 24, "bbox": [42.0, 1750.0, 185.0, 40.0], "category_id": 3}, {"id": 25, "bbox": [1055.0, 1391.0, 209.0, 51.0], "category_id": 3}, {"id": 26, "bbox": [710.0, 1398.0, 213.0, 42.0], "category_id": 3}, {"id": 27, "bbox": [398.0, 1393.0, 234.0, 38.0], "category_id": 3}, {"id": 28, "bbox": [49.0, 1391.0, 187.0, 45.0], "category_id": 3}, {"id": 29, "bbox": [1057.0, 970.0, 203.0, 56.0], "category_id": 3}, {"id": 30, "bbox": [716.0, 977.0, 203.0, 53.0], "category_id": 3}, {"id": 31, "bbox": [407.0, 984.0, 196.0, 46.0], "category_id": 3}, {"id": 32, "bbox": [46.0, 981.0, 174.0, 45.0], "category_id": 3}, {"id": 33, "bbox": [1070.0, 594.0, 178.0, 47.0], "category_id": 3}, {"id": 34, "bbox": [721.0, 587.0, 191.0, 56.0], "category_id": 3}, {"id": 35, "bbox": [398.0, 592.0, 200.0, 49.0], "category_id": 3}, {"id": 36, "bbox": [33.0, 598.0, 220.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [19, 18], "conditions": [0, 39], "products": [17]}], "corefs": [[18, 21], [17, 20], [16, 19], [15, 36], [14, 35], [13, 34], [12, 33], [11, 32], [10, 31], [9, 30], [8, 29], [7, 28], [6, 27], [5, 26], [4, 25], [3, 24], [2, 23], [1, 22], [0, 22]], "caption": "Table 2. Reaction Scope of Ynamides 1 with Vinyl Azide 2ba", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 380, 417, 401], "ImageBB": [82, 407, 420, 864]}, "diagram_type": "single"}, {"id": 212, "width": 1352, "height": 1388, "file_name": "acs.joc.5b02057-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 10.0, 302.0, 170.6], "category_id": 1}, {"id": 1, "bbox": [1019.0, 0.0, 333.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [1132.0, 194.0, 56.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [447.0, 191.0, 57.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [120.0, 190.0, 56.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [383.0, 70.6, 212.4, 127.4], "category_id": 1}], "reactions": [{"reactants": [0, 9], "conditions": [4, 2], "products": [3]}], "corefs": [[0, 4], [5, 3], [1, 2]], "caption": "Table 1. E\ufb00ect of Reaction Parameters on the Gold- Catalyzed Reaction of 1b and 2ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 433, 745, 463], "ImageBB": [448, 470, 786, 817]}, "diagram_type": "single"}, {"id": 213, "width": 3396, "height": 1776, "file_name": "jacs.6b00143-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2390.35, 60.38, 146.74, 112.34], "category_id": 1}, {"id": 1, "bbox": [1262.95, 198.63, 49.38, 36.4], "category_id": 3}, {"id": 2, "bbox": [878.06, 201.87, 81.18, 34.45], "category_id": 3}, {"id": 3, "bbox": [2443.58, 201.87, 28.61, 35.1], "category_id": 3}, {"id": 4, "bbox": [1908.11, 9.1, 357.68, 188.28], "category_id": 1}, {"id": 5, "bbox": [1127.7, 41.51, 272.44, 171.58], "category_id": 1}, {"id": 6, "bbox": [848.15, 59.84, 146.35, 109.71], "category_id": 1}, {"id": 7, "bbox": [2043.11, 201.87, 27.96, 35.1], "category_id": 3}], "reactions": [{"reactants": [8, 7], "conditions": [5, 9], "products": [6, 0]}], "corefs": [[6, 2], [5, 1], [4, 7], [0, 3]], "caption": "Table 2. Substrate Scope for Kinetic Resolutions of Sulfoximines and a Sulfondiimide with Enal 2ba", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 656, 648, 677], "ImageBB": [10, 683, 859, 1127]}, "diagram_type": "single"}, {"id": 214, "width": 1356, "height": 788, "file_name": "jacs.5b12989-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [678.07, 211.47, 38.6, 31.49], "category_id": 3}, {"id": 1, "bbox": [590.63, 12.18, 182.98, 174.86], "category_id": 1}, {"id": 2, "bbox": [205.27, 17.27, 187.05, 170.78], "category_id": 1}, {"id": 3, "bbox": [965.82, 12.18, 180.98, 174.86], "category_id": 1}, {"id": 4, "bbox": [285.59, 211.47, 35.56, 31.49], "category_id": 3}, {"id": 5, "bbox": [1054.28, 211.47, 49.78, 31.49], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [7, 6], "products": [2]}, {"reactants": [2], "conditions": [4, 8], "products": [5]}], "corefs": [[2, 4], [1, 0], [3, 5]], "caption": "Table 1. Boron Reagent Variation", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 799, 636, 814], "ImageBB": [448, 820, 787, 1017]}, "diagram_type": "single"}, {"id": 215, "width": 1344, "height": 800, "file_name": "ja9810742-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [806.23, 2.1, 277.62, 183.68], "category_id": 1}, {"id": 1, "bbox": [364.43, 10.36, 235.29, 171.29], "category_id": 1}, {"id": 2, "bbox": [935.26, 184.81, 37.1, 37.1], "category_id": 3}, {"id": 3, "bbox": [467.65, 185.84, 37.1, 40.2], "category_id": 3}], "reactions": [{"reactants": [6, 3], "conditions": [1, 0], "products": [2]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 3. Allylation of 3-Phenylpropanal 1a with Homoallylic Alcohols 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 544, 385, 569], "ImageBB": [74, 570, 410, 770]}, "diagram_type": "single"}, {"id": 216, "width": 1352, "height": 972, "file_name": "ja806060a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [717.89, 6.77, 255.35, 188.87], "category_id": 1}, {"id": 1, "bbox": [38.12, 13.04, 144.98, 168.8], "category_id": 1}, {"id": 2, "bbox": [222.49, 13.04, 227.75, 111.11], "category_id": 1}, {"id": 3, "bbox": [1000.05, 8.22, 306.93, 181.75], "category_id": 1}, {"id": 4, "bbox": [89.43, 211.3, 29.82, 38.38], "category_id": 3}, {"id": 5, "bbox": [321.61, 211.3, 79.03, 35.17], "category_id": 3}, {"id": 6, "bbox": [782.75, 211.3, 76.89, 35.17], "category_id": 3}, {"id": 7, "bbox": [1157.22, 211.3, 26.61, 35.17], "category_id": 3}], "reactions": [{"reactants": [2, 3], "conditions": [1, 5], "products": [0, 4]}], "corefs": [[1, 4], [2, 5], [0, 6], [3, 7]], "caption": "Table 1. [3 + 2] Annulation Reactions of Ethyl 2,3-Butadienoate 6 with the Unsaturated Esters 7a,b and Enones 7c-k Promoted by Phosphine 5c ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 54, 389, 92], "ImageBB": [58, 101, 396, 344]}, "diagram_type": "single"}, {"id": 217, "width": 1348, "height": 1012, "file_name": "ja5017206-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [63.44, 216.08, 139.06, 46.4], "category_id": 3}, {"id": 1, "bbox": [908.29, 217.39, 246.19, 45.09], "category_id": 3}, {"id": 2, "bbox": [225.4, 546.45, 161.26, 45.09], "category_id": 3}, {"id": 3, "bbox": [212.3, 824.59, 187.42, 43.79], "category_id": 3}, {"id": 4, "bbox": [772.49, 824.59, 187.42, 43.79], "category_id": 3}, {"id": 5, "bbox": [784.24, 546.45, 166.53, 45.09], "category_id": 3}, {"id": 6, "bbox": [13.81, 5.85, 251.39, 200.45], "category_id": 1}, {"id": 7, "bbox": [903.59, 6.16, 274.41, 200.61], "category_id": 1}, {"id": 8, "bbox": [178.35, 346.67, 256.63, 191.34], "category_id": 1}, {"id": 9, "bbox": [598.82, 346.67, 539.99, 191.34], "category_id": 1}, {"id": 10, "bbox": [179.65, 622.19, 251.41, 191.34], "category_id": 1}, {"id": 11, "bbox": [596.2, 622.19, 543.91, 192.65], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [13, 15, 14, 16], "products": [7, 8]}], "corefs": [[6, 0], [7, 1], [8, 2], [9, 5], [10, 3], [11, 4]], "caption": "Table 3. APF Rearrangement of Racemic (Z)-1 Catalyzed by (R)-3a as Reference for Crossover Experimentsa ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [449, 131, 786, 384]}, "diagram_type": "single"}, {"id": 218, "width": 1348, "height": 760, "file_name": "ja063878k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [71.2, 5.43, 130.09, 152.46], "category_id": 1}, {"id": 1, "bbox": [257.24, 14.58, 210.4, 150.42], "category_id": 1}, {"id": 2, "bbox": [391.43, 139.62, 20.3, 27.42], "category_id": 3}, {"id": 3, "bbox": [137.28, 139.62, 38.6, 28.43], "category_id": 3}, {"id": 4, "bbox": [896.68, 5.43, 309.01, 153.47], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [0, 1], "products": [7]}], "corefs": [[0, 3], [1, 2]], "caption": "Table 1. Preliminary Screen of Vinylsilane Alkenylation", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 250, 718, 262], "ImageBB": [439, 264, 776, 454]}, "diagram_type": "single"}, {"id": 219, "width": 2064, "height": 1688, "file_name": "ja054378e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1582.37, 112.48, 474.64, 499.2], "category_id": 1}, {"id": 1, "bbox": [1304.11, 789.73, 711.98, 834.75], "category_id": 1}, {"id": 2, "bbox": [661.65, 441.9, 22.46, 32.69], "category_id": 3}, {"id": 3, "bbox": [205.38, 568.76, 26.55, 32.69], "category_id": 3}, {"id": 4, "bbox": [56.01, 1509.94, 24.51, 32.66], "category_id": 3}, {"id": 5, "bbox": [1351.17, 1647.03, 22.46, 34.74], "category_id": 3}, {"id": 6, "bbox": [1017.66, 630.14, 24.51, 34.73], "category_id": 3}, {"id": 7, "bbox": [1629.43, 630.1, 24.51, 32.7], "category_id": 3}, {"id": 8, "bbox": [1703.09, 718.12, 149.32, 194.33], "category_id": 1}, {"id": 9, "bbox": [962.42, 6.09, 591.26, 613.77], "category_id": 1}, {"id": 10, "bbox": [6.91, 943.18, 478.73, 552.39], "category_id": 1}, {"id": 11, "bbox": [66.24, 709.93, 149.32, 196.38], "category_id": 1}, {"id": 12, "bbox": [555.25, 341.64, 351.88, 89.98], "category_id": 1}, {"id": 13, "bbox": [152.18, 290.49, 186.14, 265.94], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [3, 16], "products": [13]}, {"reactants": [13], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [12, 4], "products": [1]}, {"reactants": [17], "conditions": [15, 2], "products": [14]}], "corefs": [[13, 3], [12, 2], [9, 6], [0, 7], [1, 5], [10, 4]], "caption": "Figure 1. Schematic for the synthesis of N-isopropyl-N-[4-(thien-3-ylethynyl) phenyl] amine and N-isopropyl-N-(4-{[4-(thien-3-ylethynyl) phenyl] ethynyl} phenyl) amine. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 490, 775, 515], "ImageBB": [167, 64, 683, 486]}, "diagram_type": "tree"}, {"id": 220, "width": 1348, "height": 732, "file_name": "ja053368a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [202.2, 4.6, 362.78, 113.7], "category_id": 1}], "reactions": [{"reactants": [2, 0], "conditions": [3, 4], "products": [1]}], "corefs": [], "caption": "Table 3. DA Reaction of Dienes with R-(p-Methoxybenzoyloxy)acroleina ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 628, 88], "ImageBB": [439, 92, 776, 275]}, "diagram_type": "single"}, {"id": 221, "width": 1348, "height": 884, "file_name": "ja0289088-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [522.13, 7.34, 218.09, 169.49], "category_id": 1}, {"id": 1, "bbox": [255.38, 187.24, 177.76, 128.14], "category_id": 1}, {"id": 2, "bbox": [631.72, 127.27, 64.08, 48.53], "category_id": 1}, {"id": 3, "bbox": [916.05, 186.21, 177.77, 128.14], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 6, 5, 3, 2], "products": [7]}], "corefs": [], "caption": "Table 3. Variation of the Amount of Water", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 654, 76], "ImageBB": [439, 84, 776, 305]}, "diagram_type": "single"}, {"id": 222, "width": 1348, "height": 632, "file_name": "ja026703t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [232.99, 11.3, 158.67, 124.09], "category_id": 1}, {"id": 1, "bbox": [965.48, 8.25, 158.72, 125.1], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 4], "products": [2]}], "corefs": [], "caption": "Table 3. Transfer Hydrogenation Catalyzed by C-6 and C-8a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 63, 745, 76], "ImageBB": [439, 82, 776, 240]}, "diagram_type": "single"}, {"id": 223, "width": 1340, "height": 816, "file_name": "ja001164i-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [498.83, 483.84, 360.24, 253.71], "category_id": 1}, {"id": 1, "bbox": [963.61, 97.5, 330.97, 253.71], "category_id": 1}, {"id": 2, "bbox": [489.46, 97.5, 359.08, 253.71], "category_id": 1}, {"id": 3, "bbox": [599.51, 769.5, 34.78, 28.93], "category_id": 3}, {"id": 4, "bbox": [600.68, 384.33, 40.64, 30.1], "category_id": 3}], "reactions": [{"reactants": [10], "conditions": [9, 12, 6], "products": [3, 2]}, {"reactants": [8], "conditions": [13, 11, 5], "products": [1]}], "corefs": [[2, 4], [0, 3]], "caption": "Table 8. Comparison of the Reactivities of LBAs in the Protonation of 3a to 4aa ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 298, 721, 323], "ImageBB": [439, 82, 775, 286]}, "diagram_type": "multiple"}, {"id": 224, "width": 1344, "height": 632, "file_name": "ja001164i-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1136.1, 203.92, 22.29, 32.43], "category_id": 3}, {"id": 1, "bbox": [175.52, 202.91, 23.28, 33.45], "category_id": 3}, {"id": 2, "bbox": [1026.55, 6.13, 220.09, 173.42], "category_id": 1}, {"id": 3, "bbox": [97.42, 5.11, 300.22, 173.43], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [0, 7, 6], "products": [4]}], "corefs": [[3, 1], [2, 0]], "caption": "Table 4. Enantioselective Protonation of 5f-i by (R)-1\u201aSnCl4a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 385, 78], "ImageBB": [74, 86, 410, 244]}, "diagram_type": "single"}, {"id": 225, "width": 1196, "height": 1184, "file_name": "op9802071-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 891.0, 246.0, 207.3], "category_id": 1}, {"id": 1, "bbox": [464.0, 165.4, 377.0, 332.6], "category_id": 1}, {"id": 2, "bbox": [660.0, 898.0, 349.0, 205.6], "category_id": 1}, {"id": 3, "bbox": [694.0, 585.0, 65.9, 47.8], "category_id": 3}, {"id": 4, "bbox": [72.0, 94.0, 342.0, 442.0], "category_id": 1}, {"id": 5, "bbox": [266.0, 588.0, 59.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [60.0, 1114.0, 99.0, 50.0], "category_id": 3}, {"id": 7, "bbox": [831.0, 1139.0, 47.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3], "products": [2]}], "corefs": [[4, 5], [1, 3], [0, 6], [2, 7]], "caption": "Figure 1.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 432, 129, 446], "ImageBB": [128, 269, 427, 565]}, "diagram_type": "single"}, {"id": 226, "width": 1344, "height": 732, "file_name": "op980039c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1102.0, 679.0, 37.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [234.0, 4.0, 328.0, 272.0], "category_id": 1}, {"id": 2, "bbox": [2.0, 27.0, 132.0, 216.0], "category_id": 1}, {"id": 3, "bbox": [955.0, 359.0, 385.0, 261.0], "category_id": 1}, {"id": 4, "bbox": [399.0, 289.0, 65.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [44.0, 292.0, 40.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [0, 1], "products": [5]}], "corefs": [[2, 5], [1, 4], [3, 0]], "caption": "Table 1. 1.3-Dipolar cycloaddition of the N-imine (4) with the alkyne (5b) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 267, 396, 295], "ImageBB": [75, 72, 411, 255]}, "diagram_type": "single"}, {"id": 227, "width": 948, "height": 1028, "file_name": "op9600419-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [196.0, 981.0, 35.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [513.0, 348.0, 35.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [591.0, 608.0, 357.0, 337.0], "category_id": 1}, {"id": 3, "bbox": [126.0, 0.0, 688.0, 341.0], "category_id": 1}, {"id": 4, "bbox": [2.0, 604.0, 454.0, 356.0], "category_id": 1}, {"id": 5, "bbox": [801.0, 960.0, 36.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [], "products": [4, 2]}], "corefs": [[3, 1], [4, 0], [2, 5]], "caption": "Figure 1. Retrosynthetic analysis.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 312, 264, 326], "ImageBB": [123, 52, 360, 309]}, "diagram_type": "tree"}, {"id": 228, "width": 2392, "height": 620, "file_name": "op8001799-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [541.2, 302.0, 325.8, 281.6], "category_id": 1}, {"id": 1, "bbox": [0.0, 0.0, 436.3, 250.0], "category_id": 1}, {"id": 2, "bbox": [818.8, 40.0, 494.1, 470.9], "category_id": 1}, {"id": 3, "bbox": [125.8, 400.0, 232.6, 136.8], "category_id": 1}, {"id": 4, "bbox": [222.0, 240.0, 40.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [692.0, 577.0, 46.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [212.0, 560.0, 41.0, 48.0], "category_id": 3}, {"id": 7, "bbox": [1739.0, 522.0, 55.0, 55.0], "category_id": 3}, {"id": 8, "bbox": [1068.0, 515.0, 50.0, 50.0], "category_id": 3}, {"id": 9, "bbox": [1506.3, 74.2, 497.7, 440.8], "category_id": 1}], "reactions": [{"reactants": [2, 5], "conditions": [1, 4, 0], "products": [3]}, {"reactants": [3], "conditions": [13], "products": [14]}, {"reactants": [14], "conditions": [11, 12], "products": [15]}], "corefs": [[1, 4], [3, 6], [0, 5], [2, 8], [9, 7]], "caption": "Figure 1. Synthesis of 1 via asymmetric [3 + 2] cycloaddition and selective ester reduction.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 203, 559, 219], "ImageBB": [111, 48, 709, 203]}, "diagram_type": "single"}, {"id": 229, "width": 1356, "height": 816, "file_name": "op7001886-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [41.41, 275.34, 55.69, 44.46], "category_id": 3}, {"id": 1, "bbox": [1242.4, 276.0, 57.2, 41.9], "category_id": 3}, {"id": 2, "bbox": [2.0, 23.0, 255.4, 212.7], "category_id": 1}, {"id": 3, "bbox": [950.75, 275.62, 58.4, 41.57], "category_id": 3}, {"id": 4, "bbox": [1070.62, 1.25, 280.0, 264.0], "category_id": 1}, {"id": 5, "bbox": [771.16, 1.53, 286.0, 271.0], "category_id": 1}, {"id": 6, "bbox": [480.38, 2.72, 300.0, 269.0], "category_id": 1}, {"id": 7, "bbox": [554.75, 277.09, 65.7, 40.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [9, 8, 7]}], "corefs": [[2, 0], [6, 7], [5, 3], [4, 1]], "caption": "Table 1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 441, 471, 455], "ImageBB": [424, 456, 763, 660]}, "diagram_type": "single"}, {"id": 230, "width": 1348, "height": 476, "file_name": "op500334b-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [97.0, 242.0, 38.0, 30.0], "category_id": 3}, {"id": 1, "bbox": [24.0, 7.0, 349.0, 271.0], "category_id": 1}, {"id": 2, "bbox": [809.0, 15.0, 501.0, 273.0], "category_id": 1}, {"id": 3, "bbox": [920.0, 226.0, 36.0, 33.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [1, 4, 5], "products": [3]}], "corefs": [[1, 0], [2, 3]], "caption": "Table 4. Optimization of the base and copper catalyst of the Hurtley reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [449, 131, 786, 250]}, "diagram_type": "single"}, {"id": 231, "width": 1352, "height": 704, "file_name": "op5002462-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [93.0, 38.8, 352.0, 288.2], "category_id": 1}, {"id": 1, "bbox": [894.0, 101.0, 365.0, 236.0], "category_id": 1}, {"id": 2, "bbox": [831.6, 450.0, 350.4, 235.0], "category_id": 1}, {"id": 3, "bbox": [362.2, 449.0, 333.8, 194.0], "category_id": 1}, {"id": 4, "bbox": [414.0, 642.0, 157.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [894.0, 651.0, 157.0, 49.0], "category_id": 3}, {"id": 6, "bbox": [959.0, 303.0, 161.0, 57.0], "category_id": 3}, {"id": 7, "bbox": [230.0, 313.0, 35.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [1, 9], "products": [2, 4, 3]}], "corefs": [[0, 7], [1, 6], [3, 4], [2, 5]], "caption": "Figure 2. Allylic oxidation of valencene with SeO2 and TBHP.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 688, 379, 703], "ImageBB": [82, 502, 420, 678]}, "diagram_type": "multiple"}, {"id": 232, "width": 1396, "height": 1296, "file_name": "op010232y-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 10.0, 405.3, 221.6], "category_id": 1}, {"id": 1, "bbox": [243.0, 269.0, 54.0, 62.0], "category_id": 3}, {"id": 2, "bbox": [936.0, 229.0, 49.0, 61.0], "category_id": 3}, {"id": 3, "bbox": [629.0, 0.0, 472.6, 235.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 7], "products": [6]}], "corefs": [[0, 1], [3, 2]], "caption": "Figure 2. Effect of pH on reaction rate.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 401, 664, 415], "ImageBB": [424, 73, 773, 397]}, "diagram_type": "multiple"}, {"id": 233, "width": 1228, "height": 1168, "file_name": "op0102013-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [705.0, 341.0, 198.0, 34.0], "category_id": 3}, {"id": 1, "bbox": [708.0, 297.0, 121.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [553.0, 372.0, 489.0, 323.0], "category_id": 1}, {"id": 3, "bbox": [132.0, 288.0, 73.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [140.09, 1082.0, 48.9, 46.5], "category_id": 3}, {"id": 5, "bbox": [563.0, 0.0, 492.0, 323.9], "category_id": 1}, {"id": 6, "bbox": [21.5, 3.0, 446.5, 305.0], "category_id": 1}, {"id": 7, "bbox": [172.0, 682.1, 39.0, 47.4], "category_id": 3}, {"id": 8, "bbox": [780.0, 777.0, 445.0, 320.0], "category_id": 1}, {"id": 9, "bbox": [383.0, 777.0, 451.0, 318.4], "category_id": 1}, {"id": 10, "bbox": [0.0, 773.0, 446.0, 314.0], "category_id": 1}, {"id": 11, "bbox": [16.56, 366.5, 495.44, 326.5], "category_id": 1}, {"id": 12, "bbox": [686.5, 675.0, 45.5, 47.0], "category_id": 3}, {"id": 13, "bbox": [541.0, 1087.4, 172.4, 77.6], "category_id": 3}, {"id": 14, "bbox": [917.02, 1090.9, 197.38, 68.07], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [14, 15], "products": [5]}, {"reactants": [5], "conditions": [19, 18], "products": [11]}, {"reactants": [11], "conditions": [17], "products": [2]}, {"reactants": [2], "conditions": [12, 13], "products": [16]}], "corefs": [[6, 3], [5, 1], [5, 0], [11, 7], [2, 12], [10, 4], [9, 13], [8, 14]], "caption": "Figure 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 715, 495, 729], "ImageBB": [455, 419, 762, 711]}, "diagram_type": "single"}, {"id": 234, "width": 1348, "height": 712, "file_name": "op000111i-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1178.0, 343.0, 38.0, 60.0], "category_id": 3}, {"id": 1, "bbox": [327.33, 343.67, 45.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [655.08, 218.67, 39.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [850.66, 36.27, 495.34, 300.73], "category_id": 1}, {"id": 4, "bbox": [524.76, 0.0, 313.84, 232.0], "category_id": 1}, {"id": 5, "bbox": [198.6, 542.9, 740.3, 166.3], "category_id": 1}, {"id": 6, "bbox": [3.0, 15.0, 522.0, 304.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5], "products": [4]}], "corefs": [[6, 1], [4, 2], [3, 0]], "caption": "Figure 5. Oxazaborolidine bound to a polysiloxane.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 441, 728, 455], "ImageBB": [440, 260, 777, 438]}, "diagram_type": "single"}, {"id": 235, "width": 1352, "height": 1136, "file_name": "ol901760a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [450.0, 928.3, 121.1, 47.7], "category_id": 1}, {"id": 1, "bbox": [1022.0, 742.0, 89.0, 66.0], "category_id": 1}, {"id": 2, "bbox": [912.1, 490.1, 153.0, 244.0], "category_id": 1}, {"id": 3, "bbox": [781.54, 553.46, 112.0, 56.0], "category_id": 1}, {"id": 4, "bbox": [243.2, 492.6, 221.7, 270.2], "category_id": 1}, {"id": 5, "bbox": [855.5, 117.5, 263.5, 306.3], "category_id": 1}, {"id": 6, "bbox": [566.7, 855.1, 162.4, 276.5], "category_id": 1}, {"id": 7, "bbox": [289.8, 856.4, 150.2, 273.7], "category_id": 1}, {"id": 8, "bbox": [912.2, 845.3, 151.2, 290.7], "category_id": 1}, {"id": 9, "bbox": [236.0, 492.0, 45.0, 45.0], "category_id": 3}, {"id": 10, "bbox": [232.0, 124.0, 51.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [607.2, 493.0, 158.6, 244.9], "category_id": 1}, {"id": 12, "bbox": [284.0, 118.8, 268.1, 295.2], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [16, 15], "products": [6]}, {"reactants": [5], "conditions": [11], "products": [14]}, {"reactants": [14], "conditions": [4], "products": [3]}, {"reactants": [3], "conditions": [10, 1], "products": [9]}, {"reactants": [9], "conditions": [2], "products": [7]}, {"reactants": [7], "conditions": [0], "products": [8]}], "corefs": [[12, 10], [4, 9]], "caption": "Figure 1. Preliminary studies by Hayford and co-workers. (A) Preparation of indolizines from (Z)-2-pyridine- and quinoline- silylated vinylacetylenes (numbering relative to the indolizine structure). (B) Proposed mechanism for the formation of indolizines from enynylpyridines. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 458, 393, 528], "ImageBB": [58, 167, 396, 451]}, "diagram_type": "tree"}, {"id": 236, "width": 1348, "height": 380, "file_name": "ol9005079-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [526.0, 204.0, 56.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [104.0, 204.0, 31.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [1134.0, 199.0, 35.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [348.0, 21.0, 266.0, 203.0], "category_id": 1}, {"id": 4, "bbox": [30.0, 41.0, 238.0, 166.0], "category_id": 1}, {"id": 5, "bbox": [927.0, 18.0, 395.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [0, 4], "products": [8]}], "corefs": [[4, 1], [3, 0], [5, 2]], "caption": "Table 3. Proving the Scope of Indoles in the tBuTMG-Catalyzed Alkylation Process with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 176, 670, 203], "ImageBB": [425, 212, 762, 307]}, "diagram_type": "single"}, {"id": 237, "width": 1348, "height": 1020, "file_name": "ol8013717-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [19.72, 0.69, 321.08, 239.0], "category_id": 1}, {"id": 1, "bbox": [1145.0, 247.4, 65.0, 46.9], "category_id": 3}, {"id": 2, "bbox": [989.3, 0.0, 337.9, 240.9], "category_id": 1}, {"id": 3, "bbox": [105.5, 245.3, 207.0, 58.7], "category_id": 3}], "reactions": [{"reactants": [0, 5], "conditions": [3, 6], "products": [2]}], "corefs": [[0, 3], [2, 1]], "caption": "Table 1. Cu-Mediated Cross-Coupling of 1 and 2aa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 693, 88], "ImageBB": [425, 97, 762, 352]}, "diagram_type": "single"}, {"id": 238, "width": 1348, "height": 836, "file_name": "ol8006259-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [884.0, 340.0, 353.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [876.0, 143.0, 452.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [465.0, 0.0, 526.7, 386.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [6], "products": [3]}, {"reactants": [2], "conditions": [5], "products": [1]}], "corefs": [[2, 1], [2, 0]], "caption": "Table 2. Synthesis of R-(N-Glycosyltriazolyl)-\u03b2-lactam Hybrids 15-18 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 731, 755, 761], "ImageBB": [425, 770, 762, 979]}, "diagram_type": "tree"}, {"id": 239, "width": 1348, "height": 1008, "file_name": "ol800527p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [997.0, 144.0, 333.0, 238.0], "category_id": 1}, {"id": 1, "bbox": [765.0, 316.0, 54.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [159.0, 321.0, 51.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [14.0, 145.0, 335.0, 162.3], "category_id": 1}, {"id": 4, "bbox": [503.85, 140.27, 58.46, 54.56], "category_id": 3}, {"id": 5, "bbox": [1073.0, 311.0, 54.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [312.0, 3.0, 338.0, 203.0], "category_id": 1}, {"id": 7, "bbox": [625.0, 92.0, 330.0, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [9, 1, 2], "products": [10, 0]}], "corefs": [[3, 2], [6, 4], [7, 1], [0, 5]], "caption": "Table 1. Regioselectivity of the Introduction of a Cyanomethyl Group ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 345, 752, 372], "ImageBB": [425, 381, 762, 633]}, "diagram_type": "single"}, {"id": 240, "width": 1344, "height": 788, "file_name": "ol400025a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [734.0, 514.1, 486.0, 238.9], "category_id": 1}, {"id": 1, "bbox": [126.1, 509.1, 248.9, 205.9], "category_id": 1}, {"id": 2, "bbox": [485.0, 166.1, 332.0, 241.9], "category_id": 1}, {"id": 3, "bbox": [123.0, 166.0, 339.9, 236.8], "category_id": 1}, {"id": 4, "bbox": [863.0, 206.1, 237.0, 153.8], "category_id": 1}, {"id": 5, "bbox": [421.0, 508.0, 296.0, 218.0], "category_id": 1}, {"id": 6, "bbox": [964.0, 752.0, 24.0, 27.0], "category_id": 3}, {"id": 7, "bbox": [556.0, 746.0, 35.0, 30.0], "category_id": 3}, {"id": 8, "bbox": [176.6, 415.97, 258.4, 60.5], "category_id": 3}, {"id": 9, "bbox": [515.4, 417.0, 261.6, 59.5], "category_id": 3}, {"id": 10, "bbox": [128.2, 723.0, 280.8, 58.5], "category_id": 3}, {"id": 11, "bbox": [861.4, 411.0, 252.6, 60.5], "category_id": 3}], "reactions": [], "corefs": [[3, 8], [2, 9], [4, 11], [1, 10], [5, 7], [0, 6]], "caption": "Figure 1. Squaramide catalysts.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 269, 604, 282], "ImageBB": [437, 59, 773, 256]}, "diagram_type": "multiple"}, {"id": 241, "width": 1344, "height": 1608, "file_name": "ol303154k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [372.0, 279.0, 49.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [332.0, 598.0, 53.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [25.2, 350.3, 226.5, 217.6], "category_id": 1}, {"id": 3, "bbox": [909.0, 273.5, 417.7, 349.5], "category_id": 1}, {"id": 4, "bbox": [459.2, 357.7, 183.7, 172.0], "category_id": 1}, {"id": 5, "bbox": [296.4, 0.0, 334.5, 281.9], "category_id": 1}, {"id": 6, "bbox": [302.2, 344.1, 124.7, 235.8], "category_id": 1}, {"id": 7, "bbox": [504.0, 598.0, 54.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [1101.0, 605.0, 95.0, 50.0], "category_id": 3}, {"id": 9, "bbox": [132.0, 602.0, 52.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [649.0, 64.0, 391.0, 231.8], "category_id": 3}], "reactions": [{"reactants": [2, 6, 4], "conditions": [9, 10], "products": [3]}], "corefs": [[5, 0], [5, 10], [2, 9], [6, 1], [4, 7], [3, 8]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 322, 101], "ImageBB": [71, 112, 407, 514]}, "diagram_type": "single"}, {"id": 242, "width": 1356, "height": 1580, "file_name": "ol302400p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1239.0, 207.0, 48.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [206.0, 61.0, 184.0, 67.0], "category_id": 1}, {"id": 2, "bbox": [675.0, 26.0, 365.0, 169.0], "category_id": 1}, {"id": 3, "bbox": [1066.0, 77.0, 290.0, 117.0], "category_id": 1}, {"id": 4, "bbox": [294.0, 209.0, 50.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [26.0, 207.0, 44.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [796.0, 205.0, 37.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [3.0, 0.0, 186.0, 153.0], "category_id": 1}], "reactions": [{"reactants": [10, 1], "conditions": [6, 5], "products": [2, 3]}], "corefs": [[7, 5], [1, 4], [2, 6], [3, 0]], "caption": "Table 1. Reaction Condition Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 450, 669, 466], "ImageBB": [436, 477, 775, 872]}, "diagram_type": "single"}, {"id": 243, "width": 1344, "height": 2100, "file_name": "ol301863j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [247.0, 1363.0, 550.0, 190.0], "category_id": 1}, {"id": 1, "bbox": [805.0, 1342.0, 510.0, 223.0], "category_id": 1}, {"id": 2, "bbox": [244.0, 1155.0, 499.0, 176.0], "category_id": 1}, {"id": 3, "bbox": [821.0, 904.0, 494.0, 191.0], "category_id": 1}, {"id": 4, "bbox": [463.0, 2017.0, 32.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [199.0, 175.0, 63.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [983.0, 173.0, 99.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [452.0, 1764.0, 60.0, 41.0], "category_id": 3}, {"id": 8, "bbox": [37.0, 9.0, 448.0, 194.0], "category_id": 1}, {"id": 9, "bbox": [842.0, 0.0, 462.0, 215.0], "category_id": 1}, {"id": 10, "bbox": [198.0, 472.0, 543.0, 212.0], "category_id": 1}, {"id": 11, "bbox": [453.0, 646.0, 28.0, 39.0], "category_id": 3}, {"id": 12, "bbox": [764.0, 407.0, 504.0, 220.0], "category_id": 1}, {"id": 13, "bbox": [764.0, 643.0, 551.0, 191.0], "category_id": 1}, {"id": 14, "bbox": [240.0, 879.0, 463.0, 249.0], "category_id": 1}, {"id": 15, "bbox": [455.0, 1081.0, 52.0, 37.0], "category_id": 3}, {"id": 16, "bbox": [457.0, 1295.0, 53.0, 42.0], "category_id": 3}, {"id": 17, "bbox": [457.0, 1539.0, 51.0, 36.0], "category_id": 3}, {"id": 18, "bbox": [1002.0, 1545.0, 143.0, 46.0], "category_id": 3}, {"id": 19, "bbox": [996.0, 2017.0, 155.0, 53.0], "category_id": 3}, {"id": 20, "bbox": [836.0, 1816.0, 489.0, 220.0], "category_id": 1}, {"id": 21, "bbox": [256.0, 1824.0, 499.0, 217.0], "category_id": 1}, {"id": 22, "bbox": [243.0, 1604.0, 525.0, 212.0], "category_id": 1}, {"id": 23, "bbox": [1002.0, 1076.0, 146.0, 49.6], "category_id": 3}, {"id": 24, "bbox": [985.0, 599.0, 158.3, 43.5], "category_id": 3}, {"id": 25, "bbox": [980.0, 810.0, 167.9, 48.0], "category_id": 3}], "reactions": [{"reactants": [10], "conditions": [9, 7], "products": [12]}], "corefs": [[8, 5], [9, 6], [10, 11], [12, 24], [13, 25], [14, 15], [3, 23], [2, 16], [0, 17], [1, 18], [22, 7], [21, 4], [20, 19]], "caption": "Table 1. Stereoselective Reduction of Oxime Disaccharides 4 7", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 405, 100], "ImageBB": [71, 112, 407, 637]}, "diagram_type": "single"}, {"id": 244, "width": 1348, "height": 2060, "file_name": "ol300353w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [140.0, 1811.0, 65.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [436.0, 1603.0, 68.0, 52.0], "category_id": 3}, {"id": 2, "bbox": [893.0, 1804.0, 68.0, 61.0], "category_id": 3}, {"id": 3, "bbox": [410.9, 1447.0, 253.1, 219.0], "category_id": 1}, {"id": 4, "bbox": [775.0, 1544.0, 542.0, 253.0], "category_id": 1}, {"id": 5, "bbox": [802.0, 7.0, 412.0, 221.0], "category_id": 1}, {"id": 6, "bbox": [137.0, 5.0, 306.0, 231.0], "category_id": 1}, {"id": 7, "bbox": [260.0, 246.0, 73.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [36.0, 1530.0, 314.0, 260.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [11, 0], "products": [7]}, {"reactants": [12], "conditions": [4, 6], "products": [5]}], "corefs": [[6, 7], [8, 0], [3, 1], [4, 2]], "caption": "Table 1. Conversion of Aldehydes to Syn-Aldol Products", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 522, 741, 535], "ImageBB": [436, 547, 773, 1062]}, "diagram_type": "multiple"}, {"id": 245, "width": 2808, "height": 888, "file_name": "ol200288w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1706.0, 2.0, 389.0, 166.0], "category_id": 1}, {"id": 1, "bbox": [1175.0, 61.0, 186.0, 75.6], "category_id": 1}, {"id": 2, "bbox": [809.9, 6.4, 215.7, 178.1], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [5, 0], "products": [2]}], "corefs": [], "caption": "Table 1. Subset of Selected Products that are Synthesized by NRPS325", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 447, 100], "ImageBB": [71, 112, 773, 334]}, "diagram_type": "single"}, {"id": 246, "width": 1344, "height": 1348, "file_name": "ol1030487-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [391.6, 365.2, 106.4, 95.99], "category_id": 1}, {"id": 1, "bbox": [538.0, 385.0, 267.0, 154.0], "category_id": 1}, {"id": 2, "bbox": [1032.0, 411.0, 256.0, 164.0], "category_id": 1}, {"id": 3, "bbox": [1258.0, 185.0, 43.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [101.0, 22.0, 240.5, 200.2], "category_id": 1}, {"id": 5, "bbox": [79.0, 361.0, 39.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [213.0, 579.0, 41.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [658.0, 549.0, 41.0, 34.0], "category_id": 3}, {"id": 8, "bbox": [1213.0, 553.0, 40.0, 34.0], "category_id": 3}, {"id": 9, "bbox": [130.0, 192.0, 33.0, 27.0], "category_id": 3}, {"id": 10, "bbox": [738.0, 231.0, 23.0, 36.0], "category_id": 3}, {"id": 11, "bbox": [729.0, 79.0, 39.0, 32.0], "category_id": 3}, {"id": 12, "bbox": [578.0, 181.0, 201.0, 47.0], "category_id": 1}, {"id": 13, "bbox": [1229.0, 354.0, 46.0, 38.0], "category_id": 3}, {"id": 14, "bbox": [1148.0, 299.5, 195.0, 57.9], "category_id": 1}, {"id": 15, "bbox": [3.6, 300.6, 188.4, 62.4], "category_id": 1}, {"id": 16, "bbox": [707.5, 984.9, 324.9, 357.7], "category_id": 1}, {"id": 17, "bbox": [843.0, 373.0, 103.0, 91.0], "category_id": 1}, {"id": 18, "bbox": [1029.19, 20.4, 281.0, 196.8], "category_id": 1}, {"id": 19, "bbox": [80.0, 395.2, 258.5, 162.6], "category_id": 1}, {"id": 20, "bbox": [576.0, 21.7, 186.7, 62.3], "category_id": 1}, {"id": 21, "bbox": [307.7, 932.7, 372.1, 399.7], "category_id": 1}], "reactions": [{"reactants": [25, 16], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [0, 10], "products": [23]}, {"reactants": [23], "conditions": [19, 15], "products": [5]}, {"reactants": [1], "conditions": [21, 12], "products": [2]}, {"reactants": [2], "conditions": [24, 18], "products": [22]}], "corefs": [[20, 11], [12, 10], [1, 7], [19, 6], [15, 5], [4, 9], [18, 3], [14, 13], [2, 8]], "caption": "Figure 1. Stereo plots of the X-ray crystal structures of (\u00fe)-9: C, gray; N, blue; O, red. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 994, 405, 1021], "ImageBB": [71, 644, 407, 981]}, "diagram_type": "tree"}, {"id": 247, "width": 1348, "height": 816, "file_name": "ol102738b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [868.3, 4.2, 336.9, 185.3], "category_id": 1}, {"id": 1, "bbox": [525.6, 159.0, 52.4, 47.0], "category_id": 3}, {"id": 2, "bbox": [141.4, 9.9, 258.6, 156.1], "category_id": 1}, {"id": 3, "bbox": [413.3, 30.6, 266.9, 121.8], "category_id": 1}, {"id": 4, "bbox": [208.2, 156.1, 43.8, 49.9], "category_id": 3}, {"id": 5, "bbox": [1006.0, 148.0, 46.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [2, 3], "conditions": [4, 5], "products": [0]}], "corefs": [[2, 4], [3, 1], [0, 5]], "caption": "Table 3. PBu3-Catalyzed [3 \u00fe 2] Cyclization of 1 and 2a", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 325, 732, 343], "ImageBB": [436, 353, 773, 557]}, "diagram_type": "single"}, {"id": 248, "width": 1704, "height": 1952, "file_name": "op500224x-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [168.0, 310.0, 67.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [700.0, 308.0, 73.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [1238.0, 310.0, 74.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [726.0, 805.0, 491.0, 291.0], "category_id": 1}, {"id": 4, "bbox": [910.0, 405.0, 480.0, 302.0], "category_id": 1}, {"id": 5, "bbox": [68.0, 403.0, 398.0, 304.0], "category_id": 1}, {"id": 6, "bbox": [44.0, 0.0, 292.0, 301.0], "category_id": 1}, {"id": 7, "bbox": [496.0, 401.0, 375.0, 306.0], "category_id": 1}, {"id": 8, "bbox": [274.0, 1107.0, 170.0, 89.0], "category_id": 3}, {"id": 9, "bbox": [966.0, 1522.0, 169.0, 89.0], "category_id": 3}, {"id": 10, "bbox": [247.0, 712.0, 184.0, 86.0], "category_id": 3}, {"id": 11, "bbox": [587.0, 708.0, 199.0, 95.0], "category_id": 3}, {"id": 12, "bbox": [1061.0, 708.0, 188.0, 95.0], "category_id": 3}, {"id": 13, "bbox": [899.0, 1105.0, 173.0, 87.0], "category_id": 3}, {"id": 14, "bbox": [291.0, 1529.0, 171.0, 84.0], "category_id": 3}, {"id": 15, "bbox": [111.2, 835.0, 501.8, 285.0], "category_id": 1}, {"id": 16, "bbox": [76.7, 1209.0, 582.3, 306.3], "category_id": 1}, {"id": 17, "bbox": [584.7, 0.0, 286.3, 306.7], "category_id": 1}, {"id": 18, "bbox": [1107.0, 0.0, 305.0, 305.8], "category_id": 1}, {"id": 19, "bbox": [777.5, 1198.0, 545.5, 326.0], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [3, 4], "products": [20]}, {"reactants": [20], "conditions": [5, 22], "products": [21]}], "corefs": [[6, 0], [17, 1], [18, 2], [5, 10], [7, 11], [4, 12], [15, 8], [3, 13], [16, 14], [19, 9]], "caption": "Table 3. Kinetic protonation and carbon nucleophile addition products ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 603, 747, 633], "ImageBB": [433, 639, 859, 1127]}, "diagram_type": "single"}, {"id": 249, "width": 1352, "height": 468, "file_name": "op500102h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [49.0, 326.0, 55.0, 47.9], "category_id": 3}, {"id": 1, "bbox": [1062.0, 114.4, 287.0, 208.6], "category_id": 1}, {"id": 2, "bbox": [1.0, 166.3, 228.0, 130.5], "category_id": 1}, {"id": 3, "bbox": [494.2, 146.2, 214.8, 183.8], "category_id": 1}, {"id": 4, "bbox": [770.41, 4.98, 265.39, 115.92], "category_id": 1}, {"id": 5, "bbox": [552.0, 326.0, 52.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [1188.0, 325.0, 35.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 6], "products": [3]}, {"reactants": [3], "conditions": [4, 8, 9], "products": [1]}], "corefs": [[2, 0], [3, 5], [1, 6]], "caption": "Table 1. Reaction of activated TFEDMA with \u03b2-keto esters and hydrazines ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 367, 783, 401], "ImageBB": [448, 407, 786, 524]}, "diagram_type": "single"}, {"id": 250, "width": 1352, "height": 1564, "file_name": "op400278d-Table-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [204.0, 1148.0, 95.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [446.0, 1404.0, 94.0, 65.0], "category_id": 3}, {"id": 2, "bbox": [993.0, 966.0, 107.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [1040.0, 1408.8, 84.9, 62.2], "category_id": 3}, {"id": 4, "bbox": [207.5, 499.7, 84.4, 49.4], "category_id": 3}, {"id": 5, "bbox": [1105.0, 559.3, 85.6, 75.7], "category_id": 3}, {"id": 6, "bbox": [195.0, 829.0, 104.0, 62.0], "category_id": 3}, {"id": 7, "bbox": [29.1, 980.1, 440.7, 246.2], "category_id": 1}, {"id": 8, "bbox": [37.4, 663.9, 471.2, 244.8], "category_id": 1}, {"id": 9, "bbox": [689.0, 304.5, 627.6, 440.6], "category_id": 1}, {"id": 10, "bbox": [24.3, 333.0, 543.0, 242.1], "category_id": 1}, {"id": 11, "bbox": [920.9, 37.2, 416.7, 189.3], "category_id": 1}, {"id": 12, "bbox": [314.2, 3.6, 170.8, 200.3], "category_id": 1}, {"id": 13, "bbox": [48.2, 6.5, 174.1, 194.0], "category_id": 1}, {"id": 14, "bbox": [203.5, 1236.7, 552.4, 253.7], "category_id": 1}, {"id": 15, "bbox": [759.6, 1203.9, 557.5, 310.3], "category_id": 1}, {"id": 16, "bbox": [504.0, 759.5, 806.1, 277.1], "category_id": 1}], "reactions": [{"reactants": [22, 21], "conditions": [12, 27], "products": [20]}], "corefs": [[10, 4], [9, 5], [8, 6], [16, 2], [7, 0], [14, 1], [15, 3]], "caption": "Table 10. Examining the substrate scope of room temperature aryl aminations catalyzed by Pd-PEPPSI- IPentCl-o-picoline (35) ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 492, 384, 539], "ImageBB": [82, 544, 420, 935]}, "diagram_type": "single"}, {"id": 251, "width": 1704, "height": 896, "file_name": "op400055z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [106.0, 3.0, 340.0, 218.0], "category_id": 1}, {"id": 1, "bbox": [963.0, 0.0, 356.0, 221.0], "category_id": 1}, {"id": 2, "bbox": [303.0, 210.0, 68.0, 64.0], "category_id": 3}, {"id": 3, "bbox": [1188.0, 179.0, 64.0, 57.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 2. Asymmetric hydrogenation of 7b with high TONs", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 875, 782, 890], "ImageBB": [433, 903, 859, 1127]}, "diagram_type": "single"}, {"id": 252, "width": 2820, "height": 808, "file_name": "op300171m-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1193.5, 77.5, 484.8, 683.7], "category_id": 1}, {"id": 1, "bbox": [937.0, 351.0, 38.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [677.5, 166.0, 509.5, 170.0], "category_id": 1}, {"id": 3, "bbox": [325.8, 323.3, 408.8, 244.9], "category_id": 1}, {"id": 4, "bbox": [537.0, 627.0, 40.0, 65.0], "category_id": 3}, {"id": 5, "bbox": [1305.0, 627.0, 48.0, 72.0], "category_id": 3}, {"id": 6, "bbox": [1835.6, 2.1, 475.6, 653.9], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 8], "products": [0]}, {"reactants": [0], "conditions": [2, 9], "products": [7]}], "corefs": [[3, 4], [2, 1], [0, 5]], "caption": "Table 3. Reaction Condition Optimization of Ammonolysis in the Synthesis of Vilazodone", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 636, 592, 651], "ImageBB": [82, 427, 787, 629]}, "diagram_type": "single"}, {"id": 253, "width": 3396, "height": 1160, "file_name": "op300101d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1447.0, 238.0, 29.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [1930.0, 239.0, 24.0, 32.0], "category_id": 3}, {"id": 2, "bbox": [1390.0, 9.0, 138.0, 186.0], "category_id": 1}, {"id": 3, "bbox": [1884.0, 18.0, 114.0, 190.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [5]}], "corefs": [[2, 0], [3, 1]], "caption": "Table 2. Familiarization runs using cyclohexanone oxime 4 as model substratea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 810, 530, 831], "ImageBB": [10, 837, 859, 1127]}, "diagram_type": "single"}, {"id": 254, "width": 3396, "height": 2324, "file_name": "op300087r-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [840.55, 1412.75, 32.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [838.0, 820.0, 40.2, 44.5], "category_id": 3}, {"id": 2, "bbox": [594.0, 1023.0, 589.1, 389.0], "category_id": 1}, {"id": 3, "bbox": [2203.54, 1038.88, 590.0, 341.0], "category_id": 1}, {"id": 4, "bbox": [2211.0, 448.0, 578.8, 341.3], "category_id": 1}, {"id": 5, "bbox": [609.0, 451.0, 568.4, 377.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [13, 12], "products": [6]}, {"reactants": [4], "conditions": [10, 9], "products": [5]}], "corefs": [[5, 1], [2, 0]], "caption": "Figure 3. Optical micrographs of bosutinib monohydrate isolated from: A) water, and B) MIBK/water.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 612, 584, 626], "ImageBB": [10, 22, 859, 603]}, "diagram_type": "multiple"}, {"id": 255, "width": 1352, "height": 1436, "file_name": "op200312m-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [807.15, 555.15, 68.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [208.3, 554.85, 53.0, 63.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 251.4, 508.1, 308.4], "category_id": 1}, {"id": 3, "bbox": [660.0, 238.2, 484.1, 291.8], "category_id": 1}, {"id": 4, "bbox": [227.0, 1085.0, 54.0, 65.0], "category_id": 3}, {"id": 5, "bbox": [644.0, 768.0, 494.0, 296.0], "category_id": 1}, {"id": 6, "bbox": [31.0, 766.0, 509.0, 316.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [16], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [5], "conditions": [17, 18], "products": [22]}, {"reactants": [22], "conditions": [15], "products": [0]}, {"reactants": [0], "conditions": [14, 11], "products": [3]}, {"reactants": [3], "conditions": [13, 12], "products": [2]}, {"reactants": [6], "conditions": [19, 7], "products": [21]}, {"reactants": [21], "conditions": [20], "products": [8]}], "corefs": [[2, 1], [3, 0], [6, 4]], "caption": "Table 5. Optimizing formic acida", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 767, 271, 788], "ImageBB": [82, 408, 420, 767]}, "diagram_type": "tree"}, {"id": 256, "width": 2820, "height": 784, "file_name": "op200312m-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1532.0, 304.0, 40.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [734.5, 0.0, 414.5, 295.0], "category_id": 1}, {"id": 2, "bbox": [1364.5, 58.1, 397.4, 194.9], "category_id": 1}, {"id": 3, "bbox": [903.0, 305.0, 39.5, 43.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [9, 2], "products": [4, 8, 6, 5]}], "corefs": [[1, 3], [2, 0]], "caption": "Table 3. Levels of the five factors in the 25\u20111 fractional factorial design", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 479, 109], "ImageBB": [82, 116, 787, 312]}, "diagram_type": "single"}, {"id": 257, "width": 1344, "height": 1492, "file_name": "op200174k-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.0, 510.0, 323.0, 264.0], "category_id": 1}, {"id": 1, "bbox": [806.0, 880.0, 504.0, 485.0], "category_id": 1}, {"id": 2, "bbox": [24.0, 850.0, 400.0, 524.0], "category_id": 1}, {"id": 3, "bbox": [1014.0, 738.0, 70.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [948.0, 1392.0, 41.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [115.0, 1392.0, 65.0, 59.0], "category_id": 3}, {"id": 6, "bbox": [243.0, 740.0, 41.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [826.0, 510.0, 389.0, 270.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [5, 4], "products": [12]}, {"reactants": [6, 13], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 6], [7, 3], [2, 5], [1, 4]], "caption": "Table 6. Low-Catalyst Scale-Up Runs", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 646, 107], "ImageBB": [437, 111, 773, 484]}, "diagram_type": "multiple"}, {"id": 258, "width": 1356, "height": 556, "file_name": "op2001047-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 8.0, 332.8, 206.8], "category_id": 1}, {"id": 1, "bbox": [412.4, 50.9, 232.4, 119.4], "category_id": 1}, {"id": 2, "bbox": [931.5, 3.0, 423.5, 211.5], "category_id": 1}, {"id": 3, "bbox": [538.0, 241.0, 39.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1188.0, 239.0, 58.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [180.0, 237.0, 65.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [0, 1], "conditions": [3, 5], "products": [2]}], "corefs": [[0, 5], [1, 3], [2, 4]], "caption": "Table 2. Reaction optimization for the Wittig reaction of p-anisaldehyde (4b) and (acetylmethylene)triphenylphospho- rane (5) under microwave batch conditionsa ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 770, 137], "ImageBB": [436, 148, 775, 287]}, "diagram_type": "single"}, {"id": 259, "width": 1344, "height": 952, "file_name": "op200011x-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [314.0, 235.0, 34.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [981.0, 236.0, 42.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [495.0, 100.0, 37.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [877.5, 82.0, 254.5, 205.8], "category_id": 1}, {"id": 4, "bbox": [543.4, 3.0, 235.6, 127.0], "category_id": 1}, {"id": 5, "bbox": [225.0, 85.4, 225.8, 168.4], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [7, 4], "products": [6]}], "corefs": [[5, 0], [4, 2], [3, 1]], "caption": "Table 3", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 115, 107], "ImageBB": [71, 133, 407, 371]}, "diagram_type": "single"}, {"id": 260, "width": 1896, "height": 396, "file_name": "op100108j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [910.81, 342.44, 54.34, 53.56], "category_id": 3}, {"id": 1, "bbox": [1617.17, 341.01, 51.47, 51.48], "category_id": 3}, {"id": 2, "bbox": [241.64, 339.58, 47.18, 52.91], "category_id": 3}, {"id": 3, "bbox": [653.4, 9.0, 565.3, 361.3], "category_id": 1}, {"id": 4, "bbox": [1333.3, 2.0, 560.1, 362.5], "category_id": 1}, {"id": 5, "bbox": [2.6, 35.9, 541.9, 328.6], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [3, 4]}], "corefs": [[5, 2], [3, 0], [4, 1]], "caption": "Figure 1. Structures of (+)-catechin (1) and its B-ring fission lactone products, 2 and 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 148, 540, 162], "ImageBB": [173, 46, 647, 145]}, "diagram_type": "single"}, {"id": 261, "width": 1348, "height": 2308, "file_name": "ol060246u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [203.0, 237.0, 34.0, 33.0], "category_id": 3}, {"id": 1, "bbox": [50.0, 0.0, 234.0, 270.0], "category_id": 1}, {"id": 2, "bbox": [909.0, 245.0, 29.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [1260.0, 234.0, 34.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [1053.7, 24.7, 251.3, 271.3], "category_id": 1}, {"id": 5, "bbox": [710.5, 12.4, 348.5, 279.8], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2], "products": [7, 6]}], "corefs": [[1, 0], [5, 2], [4, 3]], "caption": "Table 1. Effect of Base, Solvent, Temperature, and Reactant Ratio on the Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 760, 104], "ImageBB": [439, 113, 776, 690]}, "diagram_type": "single"}, {"id": 262, "width": 1348, "height": 1244, "file_name": "ol0600584-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [786.0, 15.0, 220.3, 135.0], "category_id": 1}, {"id": 1, "bbox": [345.0, 16.0, 208.0, 133.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1, 4], "products": [0]}], "corefs": [], "caption": "Table 1. Enantioselective Borane Reduction of Acetophenonea", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 500, 770, 514], "ImageBB": [439, 523, 776, 834]}, "diagram_type": "single"}, {"id": 263, "width": 1412, "height": 1724, "file_name": "jo0007837-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [243.5, 1323.5, 219.0, 166.5], "category_id": 1}, {"id": 1, "bbox": [516.0, 731.0, 59.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [107.0, 1506.0, 524.5, 218.0], "category_id": 3}, {"id": 3, "bbox": [1069.0, 1352.5, 179.5, 139.4], "category_id": 1}, {"id": 4, "bbox": [463.5, 197.5, 390.0, 513.0], "category_id": 1}, {"id": 5, "bbox": [998.66, 202.71, 145.12, 310.27], "category_id": 1}, {"id": 6, "bbox": [743.43, 200.21, 147.63, 235.21], "category_id": 1}, {"id": 7, "bbox": [1136.28, 1498.84, 50.04, 52.55], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [0, 5], "products": [4]}], "corefs": [[4, 1], [0, 2], [3, 7]], "caption": " Table 1. Enantioselective Reduction of Oxime Ether with BH3\u201aTHF Catalyzed by Polymer-Supported Chiral                       Catalysta ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [81, 477, 401, 514], "ImageBB": [74, 35, 427, 466]}, "diagram_type": "multiple"}, {"id": 264, "width": 1348, "height": 380, "file_name": "acs.orglett.6b00233-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [358.0, 239.0, 74.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [1077.1, 213.0, 73.9, 50.0], "category_id": 3}, {"id": 2, "bbox": [912.2, 13.1, 398.7, 223.9], "category_id": 1}, {"id": 3, "bbox": [36.1, 4.0, 399.7, 230.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [2]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 1. Study of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 506, 302, 527], "ImageBB": [82, 533, 419, 628]}, "diagram_type": "single"}, {"id": 265, "width": 1348, "height": 360, "file_name": "acs.orglett.5b03589-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [708.57, 202.92, 29.49, 39.65], "category_id": 3}, {"id": 1, "bbox": [1115.21, 211.05, 46.76, 41.68], "category_id": 3}, {"id": 2, "bbox": [554.0, 72.1, 245.0, 146.5], "category_id": 1}, {"id": 3, "bbox": [198.25, 62.12, 31.51, 36.6], "category_id": 3}, {"id": 4, "bbox": [144.37, 145.48, 210.43, 114.88], "category_id": 1}, {"id": 5, "bbox": [252.12, 174.96, 32.53, 36.6], "category_id": 3}, {"id": 6, "bbox": [141.0, 6.0, 205.9, 117.7], "category_id": 1}, {"id": 7, "bbox": [1020.1, 58.1, 187.9, 147.2], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [5], "products": [2]}, {"reactants": [2], "conditions": [6], "products": [9]}], "corefs": [[6, 3], [4, 5], [2, 0], [7, 1]], "caption": "Table 1. Coupling and Dehydration Reagent Investigations", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 187, 409, 202], "ImageBB": [82, 208, 419, 298]}, "diagram_type": "single"}, {"id": 266, "width": 1348, "height": 496, "file_name": "acs.orglett.5b03104-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [60.0, 220.3, 284.9, 143.4], "category_id": 1}, {"id": 1, "bbox": [924.1, 199.3, 359.6, 187.2], "category_id": 1}, {"id": 2, "bbox": [629.28, 175.27, 52.86, 45.75], "category_id": 3}, {"id": 3, "bbox": [590.4, 0.0, 309.3, 229.0], "category_id": 1}, {"id": 4, "bbox": [382.0, 243.0, 179.0, 104.0], "category_id": 1}], "reactions": [{"reactants": [2, 7], "conditions": [6, 0, 1], "products": [3]}], "corefs": [[3, 2]], "caption": "Table 1. Selected Entries of Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 744, 110], "ImageBB": [449, 116, 786, 240]}, "diagram_type": "single"}, {"id": 267, "width": 1352, "height": 2396, "file_name": "acs.orglett.5b02003-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [858.0, 2043.0, 323.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [521.0, 2339.0, 361.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [1114.0, 633.0, 31.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [464.0, 631.0, 64.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [191.0, 631.0, 39.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [27.0, 1093.0, 356.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [514.0, 1732.0, 361.0, 56.0], "category_id": 3}, {"id": 7, "bbox": [27.0, 1727.0, 348.0, 62.0], "category_id": 3}, {"id": 8, "bbox": [29.0, 2339.0, 342.0, 49.0], "category_id": 3}, {"id": 9, "bbox": [519.0, 1090.0, 346.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [974.0, 1088.0, 356.0, 60.0], "category_id": 3}, {"id": 11, "bbox": [175.0, 1402.0, 346.0, 54.0], "category_id": 3}, {"id": 12, "bbox": [179.0, 2043.0, 315.0, 65.0], "category_id": 3}, {"id": 13, "bbox": [983.0, 2337.0, 353.0, 55.0], "category_id": 3}, {"id": 14, "bbox": [849.0, 1413.0, 349.0, 49.0], "category_id": 3}, {"id": 15, "bbox": [995.0, 1730.0, 337.0, 57.0], "category_id": 3}, {"id": 16, "bbox": [385.0, 481.0, 233.0, 159.1], "category_id": 1}, {"id": 17, "bbox": [925.0, 449.0, 353.0, 226.1], "category_id": 1}, {"id": 18, "bbox": [121.0, 1792.0, 433.0, 264.0], "category_id": 1}, {"id": 19, "bbox": [29.0, 437.0, 344.0, 210.2], "category_id": 1}, {"id": 20, "bbox": [930.0, 804.0, 411.0, 268.0], "category_id": 1}, {"id": 21, "bbox": [775.0, 1787.0, 441.0, 247.0], "category_id": 1}, {"id": 22, "bbox": [7.0, 2081.0, 441.0, 272.0], "category_id": 1}, {"id": 23, "bbox": [903.0, 2096.0, 448.0, 257.0], "category_id": 1}, {"id": 24, "bbox": [11.0, 1457.0, 420.0, 268.0], "category_id": 1}, {"id": 25, "bbox": [468.0, 1460.0, 418.0, 260.0], "category_id": 1}, {"id": 26, "bbox": [912.0, 1460.0, 420.0, 262.0], "category_id": 1}, {"id": 27, "bbox": [465.0, 2106.0, 427.0, 237.0], "category_id": 1}, {"id": 28, "bbox": [8.0, 772.0, 349.0, 312.0], "category_id": 1}, {"id": 29, "bbox": [472.0, 804.0, 395.0, 263.0], "category_id": 1}, {"id": 30, "bbox": [958.0, 255.0, 365.0, 182.0], "category_id": 1}, {"id": 31, "bbox": [1017.0, 24.0, 308.0, 194.0], "category_id": 1}, {"id": 32, "bbox": [17.0, 7.0, 223.0, 180.0], "category_id": 1}, {"id": 33, "bbox": [20.0, 236.0, 272.0, 155.0], "category_id": 1}, {"id": 34, "bbox": [327.0, 235.0, 153.0, 170.0], "category_id": 1}, {"id": 35, "bbox": [317.0, 41.0, 149.0, 176.0], "category_id": 1}, {"id": 36, "bbox": [588.0, 240.0, 360.0, 209.0], "category_id": 1}, {"id": 37, "bbox": [759.0, 1143.0, 466.0, 268.0], "category_id": 1}, {"id": 38, "bbox": [110.0, 1152.0, 448.0, 255.0], "category_id": 1}, {"id": 39, "bbox": [671.0, 9.0, 291.0, 240.0], "category_id": 1}], "reactions": [{"reactants": [38, 41], "conditions": [32, 31], "products": [45, 37]}, {"reactants": [39, 40], "conditions": [30, 29], "products": [42, 36]}, {"reactants": [21, 18], "conditions": [9, 12], "products": [19]}], "corefs": [[19, 4], [16, 3], [17, 2], [28, 5], [29, 9], [20, 10], [38, 11], [37, 14], [24, 7], [25, 6], [26, 15], [18, 12], [21, 0], [22, 8], [27, 1], [23, 13]], "caption": "Table 3. Scope of Phthalazinium Dicyanomethanidesa,b", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 396, 110], "ImageBB": [82, 116, 420, 715]}, "diagram_type": "multiple"}, {"id": 268, "width": 1352, "height": 776, "file_name": "acs.orglett.5b01754-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1192.0, 218.0, 77.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [339.0, 210.0, 74.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [943.7, 6.6, 318.5, 262.9], "category_id": 1}, {"id": 3, "bbox": [85.3, 3.9, 322.8, 263.5], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 4], "products": [5]}], "corefs": [[3, 1], [2, 0]], "caption": "Table 3. Proposed Direct Interconversion of BINOL and H8-BINOL-Based Chiral Br\u00f8nsted Acid ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 387, 771, 417], "ImageBB": [448, 424, 786, 618]}, "diagram_type": "single"}, {"id": 269, "width": 1348, "height": 376, "file_name": "acs.orglett.5b01385-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1063.0, 212.0, 62.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [129.5, 70.3, 135.4, 115.5], "category_id": 1}, {"id": 2, "bbox": [369.2, 55.0, 96.7, 158.0], "category_id": 1}, {"id": 3, "bbox": [969.3, 50.1, 254.5, 159.9], "category_id": 1}], "reactions": [{"reactants": [5, 7], "conditions": [6, 2], "products": [8]}], "corefs": [[3, 0]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 738, 110], "ImageBB": [449, 116, 786, 210]}, "diagram_type": "single"}, {"id": 270, "width": 1348, "height": 364, "file_name": "acs.orglett.5b01044-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1019.0, 27.0, 244.0, 200.0], "category_id": 1}, {"id": 1, "bbox": [713.0, 25.0, 244.0, 204.0], "category_id": 1}, {"id": 2, "bbox": [84.0, 27.0, 242.0, 202.0], "category_id": 1}, {"id": 3, "bbox": [182.0, 213.0, 121.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [799.0, 208.0, 123.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [1099.0, 208.0, 122.0, 60.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [2, 1]}], "corefs": [[2, 3], [1, 4], [0, 5]], "caption": "Table 2. Enantioselective Acetylation of rac-15 Catalyzed by (S)-1a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 595, 782, 629], "ImageBB": [449, 635, 786, 726]}, "diagram_type": "single"}, {"id": 271, "width": 1348, "height": 1064, "file_name": "acs.orglett.5b00805-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [501.09, 253.91, 54.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [957.2, 3.0, 316.3, 238.2], "category_id": 1}, {"id": 2, "bbox": [133.3, 35.1, 219.9, 207.6], "category_id": 1}, {"id": 3, "bbox": [461.4, 391.3, 299.5, 305.7], "category_id": 1}, {"id": 4, "bbox": [906.3, 366.5, 432.7, 334.5], "category_id": 1}, {"id": 5, "bbox": [16.4, 388.1, 247.6, 306.9], "category_id": 1}, {"id": 6, "bbox": [420.82, 69.5, 166.78, 109.64], "category_id": 1}, {"id": 7, "bbox": [1048.0, 245.0, 61.0, 55.0], "category_id": 3}, {"id": 8, "bbox": [23.0, 701.0, 323.0, 90.0], "category_id": 3}, {"id": 9, "bbox": [50.0, 237.0, 397.0, 135.0], "category_id": 3}, {"id": 10, "bbox": [1101.0, 701.0, 212.0, 84.0], "category_id": 3}, {"id": 11, "bbox": [429.0, 695.0, 514.0, 275.0], "category_id": 3}], "reactions": [{"reactants": [2, 7], "conditions": [6, 8], "products": [1]}], "corefs": [[2, 9], [6, 0], [1, 7], [5, 8], [3, 11], [4, 10]], "caption": "Table 1. Enantioselective Addition of Cumene Hydroperoxide 2a to Ketimines 1a\u2212c Derived from Isatins Using Various Chiral Organocatalysts 3,4a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 174, 414, 219], "ImageBB": [82, 226, 419, 492]}, "diagram_type": "single"}, {"id": 272, "width": 1352, "height": 508, "file_name": "acs.oprd.6b00180-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1211.0, 200.0, 44.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [993.0, 1.9, 359.0, 218.1], "category_id": 1}, {"id": 2, "bbox": [381.3, 74.7, 246.7, 134.3], "category_id": 1}, {"id": 3, "bbox": [161.28, 196.04, 33.62, 47.16], "category_id": 3}, {"id": 4, "bbox": [1.0, 59.7, 287.9, 152.7], "category_id": 1}], "reactions": [{"reactants": [7, 5], "conditions": [0, 3], "products": [4]}], "corefs": [[4, 3], [1, 0]], "caption": "Table 4. E\ufb00ect of the Amount of Aryl Bromide on the Heterogeneous Pd(OAc)2 Catalyzed Suzuki Reaction of 4- Bromoanisole (1) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 411, 278], "ImageBB": [82, 285, 420, 412]}, "diagram_type": "single"}, {"id": 273, "width": 1352, "height": 1340, "file_name": "acs.oprd.6b00128-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.0, 19.0, 322.1, 283.0], "category_id": 1}, {"id": 1, "bbox": [894.0, 5.0, 380.0, 345.0], "category_id": 1}, {"id": 2, "bbox": [442.49, 55.76, 188.6, 229.92], "category_id": 1}], "reactions": [{"reactants": [0, 3], "conditions": [2, 4], "products": [1]}], "corefs": [], "caption": "Table 1. Suzuki Coupling Conditions for Biaryl Synthesisa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 413, 110], "ImageBB": [82, 116, 420, 451]}, "diagram_type": "single"}, {"id": 274, "width": 1352, "height": 372, "file_name": "acs.oprd.6b00126-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1122.1, 10.0, 229.9, 189.0], "category_id": 1}, {"id": 1, "bbox": [784.2, 11.0, 252.8, 191.0], "category_id": 1}, {"id": 2, "bbox": [4.0, 5.1, 317.8, 194.9], "category_id": 1}, {"id": 3, "bbox": [116.0, 213.0, 29.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1237.0, 213.0, 29.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [899.0, 211.0, 35.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [11, 10, 9, 8, 7], "products": [1, 0]}], "corefs": [[2, 3], [1, 5], [0, 4]], "caption": "Table 1. Reevaluation of Previously Reported Reaction Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 217, 392, 247], "ImageBB": [82, 253, 420, 346]}, "diagram_type": "single"}, {"id": 275, "width": 3396, "height": 2056, "file_name": "acs.oprd.5b00312-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1973.0, 315.0, 281.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [1215.0, 319.0, 262.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [1185.5, 413.2, 198.7, 181.5], "category_id": 1}, {"id": 3, "bbox": [1946.8, 410.5, 201.3, 184.0], "category_id": 1}, {"id": 4, "bbox": [1571.9, 411.1, 219.2, 182.9], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [7], "products": [12, 11]}], "corefs": [[2, 1], [3, 0]], "caption": "Figure 2. (A\u2212C) UHPLC/UV chromatograms at 254 nm for (A) unreacted compound 6, (B) the HCl control, and (C) the TiCl3/HCl-treated sample. (D\u2212F) MS-selected-ion chromatograms for (D, E) compound 6 with the target mass of m/z 253 and (F) compound 6a with the target mass m/z 223. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 548, 784, 590], "ImageBB": [10, 22, 859, 536]}, "diagram_type": "single"}, {"id": 276, "width": 1352, "height": 364, "file_name": "acs.oprd.5b00303-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1150.1, 29.1, 201.9, 182.9], "category_id": 1}, {"id": 1, "bbox": [679.9, 2.0, 220.2, 182.5], "category_id": 1}, {"id": 2, "bbox": [254.3, 70.0, 170.7, 150.9], "category_id": 1}, {"id": 3, "bbox": [6.0, 85.0, 205.0, 100.7], "category_id": 1}], "reactions": [{"reactants": [10, 9], "conditions": [5, 4], "products": [8]}, {"reactants": [8], "conditions": [6], "products": [7]}], "corefs": [], "caption": "Table 1. Preparation of N-Vinylisobutyramidea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 203, 714, 225], "ImageBB": [448, 230, 786, 321]}, "diagram_type": "single"}, {"id": 277, "width": 1352, "height": 744, "file_name": "acs.oprd.5b00278-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.0, 281.0, 286.0, 237.0], "category_id": 1}, {"id": 1, "bbox": [1044.0, 274.0, 294.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [520.0, 277.0, 291.0, 246.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [7], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [5]}, {"reactants": [10], "conditions": [6, 12], "products": [9]}, {"reactants": [9, 0], "conditions": [4], "products": [5, 1]}, {"reactants": [5, 2], "conditions": [3], "products": [9, 11]}], "corefs": [], "caption": "Figure 2. Catalytic cycle of GOase including the reduction to the semioxidized inactive form. The active site is simpli\ufb01ed to only shown the copper-Tyr272 coordination. Adapted with permission from ref 8. Copyright 2003 American Chemical Society. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 785, 417, 840], "ImageBB": [82, 589, 420, 775]}, "diagram_type": "graph"}, {"id": 278, "width": 1348, "height": 1584, "file_name": "ol502681y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1008.0, 344.25, 283.3, 269.75], "category_id": 1}, {"id": 1, "bbox": [242.45, 728.16, 265.35, 300.64], "category_id": 1}, {"id": 2, "bbox": [699.96, 1021.96, 375.0, 108.0], "category_id": 3}, {"id": 3, "bbox": [132.0, 53.0, 267.0, 153.8], "category_id": 1}, {"id": 4, "bbox": [60.8, 328.2, 569.3, 283.2], "category_id": 1}, {"id": 5, "bbox": [230.0, 1109.0, 298.5, 272.9], "category_id": 1}, {"id": 6, "bbox": [803.92, 644.9, 48.0, 42.06], "category_id": 3}, {"id": 7, "bbox": [246.0, 1393.04, 288.0, 93.0], "category_id": 3}, {"id": 8, "bbox": [856.0, 1441.0, 40.0, 40.2], "category_id": 3}, {"id": 9, "bbox": [1148.92, 642.94, 48.2, 44.1], "category_id": 3}, {"id": 10, "bbox": [684.29, 333.83, 343.51, 272.17], "category_id": 1}, {"id": 11, "bbox": [608.63, 722.25, 557.37, 276.55], "category_id": 1}, {"id": 12, "bbox": [720.0, 1152.0, 321.0, 272.0], "category_id": 1}, {"id": 13, "bbox": [919.0, 129.0, 298.0, 83.0], "category_id": 1}, {"id": 14, "bbox": [167.0, 640.0, 353.2, 54.6], "category_id": 3}, {"id": 15, "bbox": [357.0, 1051.0, 46.0, 28.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [0, 2], "products": [15]}], "corefs": [[4, 14], [10, 6], [0, 9], [1, 15], [11, 2], [5, 7], [12, 8]], "caption": "Table 1. Hydrogenation Activity of Various Ru Complexesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 417, 110], "ImageBB": [82, 116, 419, 512]}, "diagram_type": "single"}, {"id": 279, "width": 1348, "height": 280, "file_name": "ol501019y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [755.2, 43.3, 406.0, 120.6], "category_id": 1}, {"id": 1, "bbox": [186.7, 44.5, 179.9, 120.3], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [1, 2], "products": [3]}], "corefs": [], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 450, 716, 471], "ImageBB": [449, 477, 786, 547]}, "diagram_type": "single"}, {"id": 280, "width": 1352, "height": 440, "file_name": "ol500618w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.6, 49.4, 270.5, 136.7], "category_id": 1}, {"id": 1, "bbox": [1065.7, 49.3, 282.8, 140.0], "category_id": 1}, {"id": 2, "bbox": [439.4, 61.5, 151.8, 112.4], "category_id": 1}, {"id": 3, "bbox": [501.0, 204.0, 38.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1184.0, 203.0, 53.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [116.0, 206.0, 55.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [0, 2], "conditions": [4, 8], "products": [1]}], "corefs": [[0, 5], [2, 3], [1, 4]], "caption": "Table 1. Screening Conditions for the Palladium-Catalyzed Cyanation of Alkenyl Bromide 1a ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 435, 782, 465], "ImageBB": [448, 472, 786, 582]}, "diagram_type": "single"}, {"id": 281, "width": 1348, "height": 964, "file_name": "ol5000692-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.1, 5.5, 282.9, 189.8], "category_id": 1}, {"id": 1, "bbox": [294.2, 196.0, 110.8, 56.5], "category_id": 3}, {"id": 2, "bbox": [945.7, 200.5, 114.6, 53.3], "category_id": 3}, {"id": 3, "bbox": [784.0, 0.0, 363.0, 188.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 4], "products": [5]}], "corefs": [[0, 1], [3, 2]], "caption": "Table 2. Cyclization of 2 to 3 Catalyzed by 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 737, 345, 758], "ImageBB": [82, 764, 419, 1005]}, "diagram_type": "single"}, {"id": 282, "width": 1348, "height": 328, "file_name": "ol403122a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [503.2, 75.4, 249.3, 121.5], "category_id": 1}, {"id": 1, "bbox": [788.6, 7.2, 216.1, 120.8], "category_id": 1}, {"id": 2, "bbox": [1001.9, 60.6, 292.1, 133.1], "category_id": 1}, {"id": 3, "bbox": [1121.53, 184.28, 54.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2, 1], "products": [3]}, {"reactants": [3], "conditions": [4, 6], "products": [5]}], "corefs": [[2, 3]], "caption": "Table 1. Initial Screening and Optimization of Conditions for S-Alkylation of DABSO-Generated Magnesium Sul\ufb01natesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 411, 140], "ImageBB": [82, 146, 419, 228]}, "diagram_type": "single"}, {"id": 283, "width": 1348, "height": 1564, "file_name": "ol402138y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1132.0, 242.0, 55.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [189.0, 236.0, 54.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [995.1, 0.0, 290.9, 242.4], "category_id": 1}, {"id": 3, "bbox": [68.1, 21.0, 316.8, 224.9], "category_id": 1}], "reactions": [{"reactants": [7, 4], "conditions": [5, 0], "products": [6]}], "corefs": [[3, 1], [2, 0]], "caption": "Table 1. Reaction Condition Screeninga", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 313, 649, 329], "ImageBB": [436, 339, 773, 730]}, "diagram_type": "single"}, {"id": 284, "width": 1348, "height": 1368, "file_name": "ol4017244-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [901.8, 5.0, 401.8, 212.2], "category_id": 1}, {"id": 1, "bbox": [51.7, 43.8, 375.1, 165.6], "category_id": 1}, {"id": 2, "bbox": [1055.2, 215.7, 78.6, 57.0], "category_id": 3}, {"id": 3, "bbox": [176.37, 216.41, 74.48, 51.29], "category_id": 3}], "reactions": [{"reactants": [2, 7], "conditions": [0], "products": [1]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Optimization of the Reaction Conditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 702, 101], "ImageBB": [436, 112, 773, 454]}, "diagram_type": "single"}, {"id": 285, "width": 1344, "height": 1304, "file_name": "ol4017244-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.0, 751.0, 397.0, 205.0], "category_id": 1}, {"id": 1, "bbox": [49.0, 751.0, 355.0, 195.0], "category_id": 1}, {"id": 2, "bbox": [748.0, 1029.0, 433.0, 216.0], "category_id": 1}, {"id": 3, "bbox": [127.0, 1051.0, 548.0, 202.0], "category_id": 1}, {"id": 4, "bbox": [506.0, 438.0, 390.0, 206.0], "category_id": 1}, {"id": 5, "bbox": [945.0, 747.0, 374.0, 195.0], "category_id": 1}, {"id": 6, "bbox": [25.0, 438.0, 416.0, 215.0], "category_id": 1}, {"id": 7, "bbox": [954.0, 171.0, 368.0, 215.0], "category_id": 1}, {"id": 8, "bbox": [611.0, 661.0, 151.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [197.0, 391.0, 16.0, 31.0], "category_id": 3}, {"id": 10, "bbox": [1116.0, 387.0, 24.0, 33.0], "category_id": 3}, {"id": 11, "bbox": [165.0, 657.0, 149.0, 40.0], "category_id": 3}, {"id": 12, "bbox": [1004.0, 662.0, 129.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [175.0, 952.0, 142.0, 41.0], "category_id": 3}, {"id": 14, "bbox": [616.0, 956.0, 147.0, 43.0], "category_id": 3}, {"id": 15, "bbox": [1006.0, 957.0, 141.0, 44.0], "category_id": 3}, {"id": 16, "bbox": [290.0, 1256.0, 145.0, 42.0], "category_id": 3}, {"id": 17, "bbox": [970.0, 1254.0, 123.0, 38.0], "category_id": 3}, {"id": 18, "bbox": [916.3, 451.0, 373.7, 196.0], "category_id": 1}, {"id": 19, "bbox": [26.0, 229.0, 369.6, 161.0], "category_id": 1}], "reactions": [{"reactants": [22, 13], "conditions": [21], "products": [7]}], "corefs": [[19, 9], [7, 10], [6, 11], [4, 8], [18, 12], [1, 13], [0, 14], [5, 15], [3, 16], [2, 17]], "caption": "Figure 2. Scope of isocyanides. Reaction conditions: All reac- tions were performed with 1 (0.2 mmol) and 2 (3 equiv), in 0.4 mL of H2O and 1.0 mL of acetone at 0 \u00b0C, in Ar, for 20 min; isolated yields of 3. a The reaction was performed with 5 equiv of 2. b The reaction was performed with 3 equiv of 1, and 2 (0.2 mmol, 1 equiv). ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 398, 771, 481], "ImageBB": [437, 59, 773, 385]}, "diagram_type": "single"}, {"id": 286, "width": 1352, "height": 1136, "file_name": "ol0480731-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 1.0, 476.0, 311.0], "category_id": 1}, {"id": 1, "bbox": [1025.0, 77.0, 256.0, 212.0], "category_id": 1}, {"id": 2, "bbox": [601.0, 81.91, 153.0, 139.0], "category_id": 1}, {"id": 3, "bbox": [99.0, 257.0, 146.0, 57.0], "category_id": 3}], "reactions": [{"reactants": [0, 6], "conditions": [1, 2], "products": [4]}], "corefs": [[0, 3]], "caption": "Table 2. Anti-Selective Aldehyde Crotylation with (R,R)-3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 226, 749, 239], "ImageBB": [439, 245, 777, 529]}, "diagram_type": "single"}, {"id": 287, "width": 1344, "height": 1300, "file_name": "ol034469l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [990.0, 209.0, 93.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [206.3, 71.0, 327.7, 136.1], "category_id": 1}, {"id": 2, "bbox": [930.9, 25.3, 204.6, 176.9], "category_id": 1}, {"id": 3, "bbox": [333.0, 202.0, 73.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[1, 3], [2, 0]], "caption": "Table 2. Intramolecular Reductive Dimerization Scope", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 364, 89], "ImageBB": [74, 93, 410, 418]}, "diagram_type": "single"}, {"id": 288, "width": 1352, "height": 1012, "file_name": "ol027494k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [50.1, 3.0, 290.9, 244.5], "category_id": 1}, {"id": 1, "bbox": [856.2, 8.0, 441.8, 284.2], "category_id": 1}, {"id": 2, "bbox": [1014.0, 303.0, 52.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [118.0, 271.0, 47.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [4, 3], "products": [2]}], "corefs": [[0, 3], [1, 2]], "caption": "Table 3. Diastereoselective Alkenylation Reaction of Oxazolidinone Derivatives with Alkenylselenonium Salts 1 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 343, 744, 371], "ImageBB": [439, 375, 777, 628]}, "diagram_type": "single"}, {"id": 289, "width": 1348, "height": 644, "file_name": "ol016212y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [101.2, 5.0, 266.6, 230.8], "category_id": 1}, {"id": 1, "bbox": [920.0, 6.0, 313.8, 237.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [2, 3], "products": [5]}], "corefs": [], "caption": "Table 4. Titanium-Mediated Addition of Et2Zn to PhCHO Using P2 and 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 748, 104], "ImageBB": [439, 107, 776, 268]}, "diagram_type": "single"}, {"id": 290, "width": 1344, "height": 884, "file_name": "ol016212y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.9, 3.6, 317.8, 237.0], "category_id": 1}, {"id": 1, "bbox": [100.0, 0.0, 266.0, 233.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 3], "products": [4]}], "corefs": [], "caption": "Table 1. Comparison of the Fiber-Supported Titanium TADDOLate Derived from P1 with P1B and 4 in the Addition of Et2Zn to PhCHO ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 180, 399, 224], "ImageBB": [74, 226, 410, 447]}, "diagram_type": "single"}, {"id": 291, "width": 1348, "height": 572, "file_name": "ol015948s-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [920.0, 34.2, 220.0, 106.6], "category_id": 1}, {"id": 1, "bbox": [210.4, 49.3, 226.5, 75.2], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 1], "products": [0]}], "corefs": [], "caption": "Table 4. Reduction of N-Benzylidineaniline with Phenylsilane", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 334, 768, 347], "ImageBB": [439, 355, 776, 498]}, "diagram_type": "single"}, {"id": 292, "width": 1344, "height": 1276, "file_name": "ol0157003-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1090.0, 229.0, 58.0, 45.6], "category_id": 3}, {"id": 1, "bbox": [76.6, 5.0, 377.4, 213.4], "category_id": 1}, {"id": 2, "bbox": [952.0, 0.0, 324.0, 222.0], "category_id": 1}, {"id": 3, "bbox": [773.0, 229.0, 66.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [640.0, 2.0, 314.0, 221.6], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1], "products": [7, 4]}], "corefs": [[4, 3], [2, 0]], "caption": "Table 2. Rearrangements of Anti Acetals 6a-10aa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 361, 344, 375], "ImageBB": [74, 380, 410, 699]}, "diagram_type": "single"}, {"id": 293, "width": 1352, "height": 2476, "file_name": "ol006041h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [22.0, 800.0, 568.0, 218.0], "category_id": 1}, {"id": 1, "bbox": [836.0, 1039.0, 243.0, 71.0], "category_id": 3}, {"id": 2, "bbox": [771.0, 169.0, 537.0, 191.0], "category_id": 1}, {"id": 3, "bbox": [688.0, 1832.0, 546.0, 220.0], "category_id": 1}, {"id": 4, "bbox": [709.0, 1497.0, 497.0, 247.0], "category_id": 1}, {"id": 5, "bbox": [51.0, 1513.0, 510.0, 244.0], "category_id": 1}, {"id": 6, "bbox": [22.0, 1082.0, 573.0, 331.0], "category_id": 1}, {"id": 7, "bbox": [667.0, 1151.0, 573.0, 177.0], "category_id": 1}, {"id": 8, "bbox": [607.0, 777.0, 702.0, 249.0], "category_id": 1}, {"id": 9, "bbox": [595.0, 473.0, 726.0, 216.0], "category_id": 1}, {"id": 10, "bbox": [34.0, 475.0, 554.0, 225.0], "category_id": 1}, {"id": 11, "bbox": [804.0, 2402.0, 324.0, 74.0], "category_id": 3}, {"id": 12, "bbox": [138.0, 2391.0, 354.0, 85.0], "category_id": 3}, {"id": 13, "bbox": [807.0, 2073.0, 349.0, 75.0], "category_id": 3}, {"id": 14, "bbox": [147.0, 2069.0, 337.0, 77.0], "category_id": 3}, {"id": 15, "bbox": [832.0, 1742.0, 258.0, 79.0], "category_id": 3}, {"id": 16, "bbox": [189.0, 1750.0, 239.0, 73.0], "category_id": 3}, {"id": 17, "bbox": [840.0, 1336.0, 231.0, 73.0], "category_id": 3}, {"id": 18, "bbox": [193.0, 1424.0, 233.0, 73.0], "category_id": 3}, {"id": 19, "bbox": [836.0, 311.0, 277.0, 64.0], "category_id": 3}, {"id": 20, "bbox": [3.0, 175.0, 404.0, 161.0], "category_id": 1}, {"id": 21, "bbox": [191.0, 1028.0, 227.0, 81.0], "category_id": 3}, {"id": 22, "bbox": [842.0, 693.0, 233.0, 75.0], "category_id": 3}, {"id": 23, "bbox": [195.0, 693.0, 233.0, 73.0], "category_id": 3}, {"id": 24, "bbox": [218.0, 321.0, 56.0, 56.0], "category_id": 3}, {"id": 25, "bbox": [672.0, 2202.0, 565.0, 200.0], "category_id": 1}, {"id": 26, "bbox": [36.0, 1844.0, 556.0, 210.0], "category_id": 1}, {"id": 27, "bbox": [45.0, 2153.0, 535.0, 256.0], "category_id": 1}], "reactions": [{"reactants": [20], "conditions": [25, 24], "products": [2]}], "corefs": [[20, 24], [2, 19], [10, 23], [9, 22], [0, 21], [8, 1], [6, 18], [7, 17], [5, 16], [4, 15], [26, 14], [3, 13], [27, 12], [25, 11]], "caption": "Figure 1. Glycosyl-1-phosphates derived from dehydrative gly- cosylation.21 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 684, 775, 711], "ImageBB": [439, 51, 777, 670]}, "diagram_type": "single"}, {"id": 294, "width": 1320, "height": 1316, "file_name": "jo991700t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [797.2, 729.1, 326.3, 250.7], "category_id": 1}, {"id": 1, "bbox": [91.1, 751.2, 291.3, 230.2], "category_id": 1}, {"id": 2, "bbox": [113.6, 199.1, 314.8, 250.1], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [5], "products": [2]}], "corefs": [], "caption": "Table 3. Hydrogen Transfer Reduction of Acetophenone                Using Ligands 16-22ba ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [75, 376, 408, 401], "ImageBB": [74, 35, 404, 364]}, "diagram_type": "tree"}, {"id": 295, "width": 1344, "height": 544, "file_name": "jo990938e-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [183.12, 25.04, 294.0, 129.0], "category_id": 1}, {"id": 1, "bbox": [299.0, 170.0, 33.0, 34.0], "category_id": 3}, {"id": 2, "bbox": [906.0, 13.0, 260.0, 174.9], "category_id": 1}, {"id": 3, "bbox": [632.0, 5.0, 256.0, 178.0], "category_id": 1}, {"id": 4, "bbox": [696.0, 167.0, 104.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [978.0, 169.0, 93.0, 37.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [0, 5], "products": [6, 4]}], "corefs": [[0, 1], [3, 4], [2, 5]], "caption": "Table 3. Additions of Allenylindium Reagent Prepared        from Allenyl Iodide 6 to Aldehydes 3a-d ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [79, 64, 403, 89], "ImageBB": [74, 98, 410, 234]}, "diagram_type": "single"}, {"id": 296, "width": 1344, "height": 820, "file_name": "jo9902998-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [247.0, 8.0, 153.0, 233.0], "category_id": 1}, {"id": 1, "bbox": [954.0, 3.0, 146.0, 237.0], "category_id": 1}, {"id": 2, "bbox": [1014.0, 268.0, 27.0, 32.0], "category_id": 3}, {"id": 3, "bbox": [310.0, 266.0, 29.0, 34.0], "category_id": 3}], "reactions": [{"reactants": [1, 7], "conditions": [8, 5], "products": [2]}], "corefs": [[0, 3], [1, 2]], "caption": "Table 2. Pd-Catalyzed Allylic Alkylation of 7a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [106, 63, 375, 76], "ImageBB": [74, 81, 410, 286]}, "diagram_type": "single"}, {"id": 297, "width": 1412, "height": 1688, "file_name": "jo9716338-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [235.0, 1048.0, 128.0, 64.0], "category_id": 3}, {"id": 1, "bbox": [982.0, 1051.0, 83.0, 55.0], "category_id": 3}, {"id": 2, "bbox": [976.0, 1627.0, 96.0, 55.0], "category_id": 3}, {"id": 3, "bbox": [261.0, 1624.0, 86.0, 64.0], "category_id": 3}, {"id": 4, "bbox": [234.9, 1404.3, 291.4, 185.4], "category_id": 1}, {"id": 5, "bbox": [225.1, 243.0, 295.2, 195.9], "category_id": 1}, {"id": 6, "bbox": [232.1, 820.9, 294.6, 193.7], "category_id": 1}, {"id": 7, "bbox": [251.0, 473.0, 83.9, 64.0], "category_id": 3}, {"id": 8, "bbox": [951.4, 793.9, 299.8, 238.3], "category_id": 1}, {"id": 9, "bbox": [953.5, 1374.2, 290.1, 229.3], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [6], "products": [12]}, {"reactants": [12], "conditions": [2], "products": [14]}, {"reactants": [12], "conditions": [5, 10], "products": [7]}, {"reactants": [14], "conditions": [9, 8], "products": [15]}], "corefs": [[5, 7], [6, 0], [8, 1], [4, 3], [9, 2]], "caption": "Table 1. Kinetic Data for the Reaction of Bromide 4  with (TMS)3SiH in Toluene or Benzene at Various                   Temperaturesa ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 469, 761, 506], "ImageBB": [424, 35, 777, 457]}, "diagram_type": "tree"}, {"id": 298, "width": 1356, "height": 812, "file_name": "jo961049j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [912.0, 66.0, 397.0, 333.0], "category_id": 1}, {"id": 1, "bbox": [40.0, 6.0, 453.0, 402.0], "category_id": 1}, {"id": 2, "bbox": [202.0, 405.0, 129.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [1025.0, 405.0, 131.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [6, 7, 0, 8], "products": [2]}], "corefs": [[1, 2], [0, 3]], "caption": "Table 2. Tandem Enyne Allene-Radical Cyclization of                 Substrates 84-88 ", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [79, 49, 402, 74], "ImageBB": [73, 76, 412, 279]}, "diagram_type": "single"}, {"id": 299, "width": 1348, "height": 1156, "file_name": "jo9602433-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [963.0, 700.0, 60.0, 65.0], "category_id": 3}, {"id": 1, "bbox": [326.0, 702.0, 36.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [630.9, 261.8, 664.4, 415.8], "category_id": 1}, {"id": 3, "bbox": [16.0, 192.2, 550.3, 507.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [10, 9]}], "corefs": [[3, 1], [2, 0]], "caption": "Table 3. Treatment of (E)-4 with BTMBr3 or Br2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [89, 261, 372, 274], "ImageBB": [63, 280, 400, 569]}, "diagram_type": "multiple"}, {"id": 300, "width": 1352, "height": 2216, "file_name": "jo501910q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [478.0, 1558.0, 373.1, 129.1], "category_id": 3}, {"id": 1, "bbox": [918.0, 1138.0, 326.1, 525.2], "category_id": 1}, {"id": 2, "bbox": [157.8, 526.9, 213.2, 158.2], "category_id": 3}, {"id": 3, "bbox": [132.0, 1461.0, 258.0, 206.0], "category_id": 3}, {"id": 4, "bbox": [870.9, 594.9, 340.2, 105.2], "category_id": 3}, {"id": 5, "bbox": [237.0, 948.0, 222.0, 198.0], "category_id": 3}, {"id": 6, "bbox": [696.0, 1043.4, 330.8, 104.1], "category_id": 3}, {"id": 7, "bbox": [490.9, 603.9, 325.2, 104.2], "category_id": 3}, {"id": 8, "bbox": [884.9, 2104.9, 192.2, 68.3], "category_id": 3}, {"id": 9, "bbox": [622.86, 2116.9, 202.3, 64.3], "category_id": 3}, {"id": 10, "bbox": [197.0, 2014.0, 116.0, 157.1], "category_id": 3}, {"id": 11, "bbox": [1061.9, 1670.0, 187.2, 66.1], "category_id": 3}, {"id": 12, "bbox": [131.6, 296.6, 315.4, 220.5], "category_id": 1}, {"id": 13, "bbox": [256.5, 788.9, 321.6, 186.2], "category_id": 1}, {"id": 14, "bbox": [840.1, 162.9, 351.0, 427.2], "category_id": 1}, {"id": 15, "bbox": [436.9, 1259.9, 417.1, 308.3], "category_id": 1}, {"id": 16, "bbox": [35.9, 1318.9, 436.2, 170.3], "category_id": 1}, {"id": 17, "bbox": [172.8, 1844.9, 313.2, 225.3], "category_id": 1}, {"id": 18, "bbox": [467.8, 264.7, 290.4, 331.4], "category_id": 1}, {"id": 19, "bbox": [530.8, 1777.9, 295.5, 338.4], "category_id": 1}, {"id": 20, "bbox": [904.8, 1738.9, 351.5, 426.4], "category_id": 1}, {"id": 21, "bbox": [680.0, 706.0, 466.0, 399.0], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [14, 22], "products": [19]}], "corefs": [[12, 2], [18, 7], [14, 4], [13, 5], [21, 6], [16, 3], [15, 0], [1, 11], [17, 10], [19, 9], [20, 8]], "caption": "Table 3. Regioselective Synthesis of N-Sulfonyl 6,7-Dihydro- 5H-dibenzo[c,e]azepines ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 417, 125], "ImageBB": [82, 131, 420, 685]}, "diagram_type": "single"}, {"id": 301, "width": 1348, "height": 376, "file_name": "jo501216h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [23.0, 8.0, 264.0, 167.0], "category_id": 1}, {"id": 1, "bbox": [802.0, 33.0, 265.0, 138.0], "category_id": 1}, {"id": 2, "bbox": [43.0, 193.0, 98.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [841.0, 192.0, 102.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 2. 1-Iodo-4-nitrobenzene-Catalyzed Synthesis of Benzoxazoles with Oxonea ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 388, 125], "ImageBB": [82, 131, 419, 225]}, "diagram_type": "single"}, {"id": 302, "width": 2820, "height": 996, "file_name": "jo501006u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [605.0, 165.0, 142.0, 65.0], "category_id": 1}, {"id": 1, "bbox": [920.0, 160.0, 298.0, 73.0], "category_id": 1}, {"id": 2, "bbox": [1256.83, 117.35, 359.41, 70.18], "category_id": 1}, {"id": 3, "bbox": [2122.0, 172.0, 197.0, 74.0], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [0, 4, 1, 5], "products": [6]}], "corefs": [], "caption": "Figure 1. Time-course of reaction of RBr and n-BuMgCl (a) with 500 mol ppm of CuCl2 (R = PhCH(Me)CH2: 1m) and (b) 25 mol ppm of CuCl2 (R = n-Non). With alkyne R-n-Bu: \u25cf (solid line), R-H: \u25cb (dashed line), without alkyne R-n-Bu: \u25a0 (solid line), R-H: \u25a1 (dashed line). ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1032, 784, 1060], "ImageBB": [82, 763, 787, 1012]}, "diagram_type": "single"}, {"id": 303, "width": 1348, "height": 1236, "file_name": "jo4026034-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [916.0, 4.0, 324.0, 224.0], "category_id": 1}, {"id": 1, "bbox": [1065.0, 237.0, 57.0, 61.0], "category_id": 3}, {"id": 2, "bbox": [559.0, 178.0, 54.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [113.6, 6.0, 289.4, 272.7], "category_id": 1}, {"id": 4, "bbox": [461.2, 49.0, 271.8, 125.0], "category_id": 1}], "reactions": [{"reactants": [5, 6], "conditions": [4], "products": [0]}], "corefs": [[4, 2], [0, 1]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 647, 343, 662], "ImageBB": [82, 668, 419, 977]}, "diagram_type": "single"}, {"id": 304, "width": 1340, "height": 2404, "file_name": "jo4007046-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [712.0, 765.0, 435.0, 126.0], "category_id": 1}, {"id": 1, "bbox": [160.0, 765.0, 379.0, 123.0], "category_id": 1}, {"id": 2, "bbox": [933.0, 477.0, 379.0, 108.0], "category_id": 1}, {"id": 3, "bbox": [459.0, 480.0, 399.0, 123.0], "category_id": 1}, {"id": 4, "bbox": [24.0, 462.0, 397.0, 144.0], "category_id": 1}, {"id": 5, "bbox": [1118.0, 193.0, 93.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [978.0, 2.0, 154.0, 350.0], "category_id": 1}, {"id": 7, "bbox": [436.0, 15.0, 128.0, 291.0], "category_id": 1}, {"id": 8, "bbox": [988.0, 1496.0, 221.0, 430.0], "category_id": 1}, {"id": 9, "bbox": [780.0, 1966.0, 226.0, 435.0], "category_id": 1}, {"id": 10, "bbox": [411.0, 1966.0, 216.0, 432.0], "category_id": 1}, {"id": 11, "bbox": [173.0, 1316.0, 65.0, 49.0], "category_id": 3}, {"id": 12, "bbox": [871.0, 1376.0, 107.0, 48.0], "category_id": 3}, {"id": 13, "bbox": [210.0, 1113.0, 126.0, 287.0], "category_id": 1}, {"id": 14, "bbox": [818.0, 1097.0, 356.0, 326.0], "category_id": 1}, {"id": 15, "bbox": [544.0, 636.0, 281.0, 65.0], "category_id": 3}, {"id": 16, "bbox": [175.0, 1486.0, 226.1, 436.4], "category_id": 1}, {"id": 17, "bbox": [557.0, 1863.0, 178.6, 58.0], "category_id": 3}, {"id": 18, "bbox": [125.0, 1870.0, 157.7, 51.5], "category_id": 3}, {"id": 19, "bbox": [286.0, 2284.51, 173.6, 48.0], "category_id": 3}, {"id": 20, "bbox": [1048.0, 2271.51, 178.1, 47.5], "category_id": 3}, {"id": 21, "bbox": [948.0, 1865.0, 150.7, 57.5], "category_id": 3}, {"id": 22, "bbox": [711.2, 67.0, 251.8, 91.0], "category_id": 1}, {"id": 23, "bbox": [267.0, 916.0, 134.7, 46.0], "category_id": 3}, {"id": 24, "bbox": [1024.0, 638.0, 160.0, 53.0], "category_id": 3}, {"id": 25, "bbox": [867.0, 924.0, 159.2, 48.5], "category_id": 3}, {"id": 26, "bbox": [77.0, 646.0, 301.0, 53.0], "category_id": 3}, {"id": 27, "bbox": [487.7, 1179.0, 323.1, 73.0], "category_id": 1}, {"id": 28, "bbox": [582.0, 1496.0, 228.0, 427.7], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [18, 26, 6], "products": [7]}, {"reactants": [15], "conditions": [19, 32, 14], "products": [16]}], "corefs": [[6, 5], [4, 26], [3, 15], [2, 24], [1, 23], [0, 25], [13, 11], [14, 12], [16, 18], [28, 17], [8, 21], [10, 19], [9, 20]], "caption": "Table 2. Synthesis of (a) Allylbenzenes 6\u221210 and (b) \u03b3- Benzyl Lactones 11\u221215a ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 400, 125], "ImageBB": [83, 131, 418, 732]}, "diagram_type": "multiple"}, {"id": 305, "width": 1352, "height": 968, "file_name": "jo4007046-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1106.0, 738.0, 33.6, 30.0], "category_id": 3}, {"id": 1, "bbox": [1217.8, 524.5, 92.9, 254.5], "category_id": 1}, {"id": 2, "bbox": [1072.0, 520.3, 97.8, 203.7], "category_id": 1}, {"id": 3, "bbox": [922.5, 519.0, 87.5, 200.6], "category_id": 1}, {"id": 4, "bbox": [668.0, 559.0, 241.9, 57.0], "category_id": 1}, {"id": 5, "bbox": [545.0, 523.8, 91.6, 196.5], "category_id": 1}, {"id": 6, "bbox": [635.0, 687.0, 20.0, 29.0], "category_id": 3}, {"id": 7, "bbox": [1310.0, 665.0, 19.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [946.0, 735.0, 37.0, 30.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 9], "products": [3, 2, 1]}], "corefs": [[5, 6], [3, 8], [2, 0], [1, 7]], "caption": "Figure 3. Ratio between the yield of 4-allyltoluene (6) and that of the other photoproducts (toluene 1a and 4-methylanisole 1b) from the irradiation of 4-chlorotoluene (1) in MeOH in the presence of an increasing amount of allyltrimethylsilane (ATMS). ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1004, 417, 1059], "ImageBB": [82, 743, 420, 985]}, "diagram_type": "single"}, {"id": 306, "width": 2820, "height": 1940, "file_name": "jo2020856-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [829.0, 264.0, 67.2, 61.6], "category_id": 3}, {"id": 1, "bbox": [1695.0, 50.0, 389.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [743.8, 66.6, 258.6, 205.6], "category_id": 1}, {"id": 3, "bbox": [1316.2, 0.4, 352.6, 197.6], "category_id": 1}, {"id": 4, "bbox": [1751.0, 261.0, 132.6, 55.4], "category_id": 3}], "reactions": [{"reactants": [6, 3], "conditions": [7, 1, 9], "products": [5]}], "corefs": [[2, 0], [1, 4]], "caption": "Table 3. Scope of the Reaction with Different Aromatic and Heteroaromatic Aldehydes", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 574, 110], "ImageBB": [82, 116, 787, 601]}, "diagram_type": "single"}, {"id": 307, "width": 3396, "height": 1140, "file_name": "jo201975b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1920.0, 236.0, 150.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [1864.0, 0.0, 251.0, 236.0], "category_id": 1}, {"id": 2, "bbox": [1351.0, 231.0, 154.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [1257.0, 22.0, 326.0, 198.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [0, 4], "products": [3]}], "corefs": [[3, 2], [1, 0]], "caption": "Table 1. Stereoselective Synthesis of cis-2,6-Disubstituted Morpholines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 820, 479, 836], "ImageBB": [10, 842, 859, 1127]}, "diagram_type": "single"}, {"id": 308, "width": 1344, "height": 1004, "file_name": "jo201478d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [101.0, 27.0, 297.0, 177.0], "category_id": 1}, {"id": 1, "bbox": [210.0, 187.0, 49.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [531.0, 187.0, 51.0, 37.0], "category_id": 3}, {"id": 3, "bbox": [1029.0, 187.0, 52.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [873.0, 31.0, 373.0, 151.0], "category_id": 1}, {"id": 5, "bbox": [427.0, 27.0, 211.0, 132.0], "category_id": 1}], "reactions": [{"reactants": [0, 7], "conditions": [1, 2], "products": [6]}], "corefs": [[0, 1], [5, 2], [4, 3]], "caption": "Table 1. Comparison of Catalyst Loading on Tandem Reac- tion of (Z)-\u03b4-Hydroxyalkenylsilane 1a and Phenylacetaldehyde ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 137], "ImageBB": [71, 148, 407, 399]}, "diagram_type": "single"}, {"id": 309, "width": 1356, "height": 856, "file_name": "jo200480h-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [600.0, 147.0, 361.0, 355.0], "category_id": 1}, {"id": 1, "bbox": [4.6, 19.3, 241.4, 147.7], "category_id": 1}, {"id": 2, "bbox": [401.9, 152.4, 125.5, 46.6], "category_id": 3}, {"id": 3, "bbox": [630.0, 505.0, 193.1, 47.9], "category_id": 3}, {"id": 4, "bbox": [39.0, 502.0, 191.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [271.0, 41.0, 443.9, 107.0], "category_id": 1}, {"id": 6, "bbox": [17.0, 205.0, 417.0, 295.0], "category_id": 1}, {"id": 7, "bbox": [47.0, 161.0, 39.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [1, 5], "conditions": [7, 8], "products": [6, 0]}], "corefs": [[1, 7], [5, 2], [6, 4], [0, 3]], "caption": "Table 4. Heteroannulation Reaction between 4-Acetamido- 3-iodopyridine (1) and Unsymmetrical Diarylacetylenes 24 27 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 427, 767, 472], "ImageBB": [436, 483, 775, 697]}, "diagram_type": "multiple"}, {"id": 310, "width": 1356, "height": 1020, "file_name": "jo200480h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.88, 128.53, 138.1, 46.48], "category_id": 3}, {"id": 1, "bbox": [274.7, 31.0, 537.6, 110.9], "category_id": 1}, {"id": 2, "bbox": [50.4, 366.0, 177.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [4.7, 140.6, 302.5, 213.9], "category_id": 1}, {"id": 4, "bbox": [859.0, 3.0, 497.0, 370.0], "category_id": 1}, {"id": 5, "bbox": [960.0, 372.0, 153.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1, 6, 3], "products": [5]}], "corefs": [[3, 2], [1, 0], [4, 5]], "caption": "Table 3. Heteroannulation Reaction between 4-Acetamido- 3-iodopyridines 1, 4, and 6 and Symmetrical Diarylacetylenes 16 18 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 771, 137], "ImageBB": [436, 148, 775, 403]}, "diagram_type": "single"}, {"id": 311, "width": 1356, "height": 640, "file_name": "jo2003264-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [306.0, 90.0, 134.8, 48.2], "category_id": 1}, {"id": 1, "bbox": [351.6, 151.13, 36.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [83.27, 152.27, 50.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [707.0, 318.0, 46.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1112.0, 315.0, 46.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [1.0, 87.0, 210.0, 56.0], "category_id": 1}, {"id": 6, "bbox": [555.0, 187.0, 286.0, 131.0], "category_id": 1}, {"id": 7, "bbox": [945.0, 186.0, 409.0, 129.0], "category_id": 1}], "reactions": [{"reactants": [7, 1], "conditions": [8, 0], "products": [9, 10]}], "corefs": [[5, 2], [0, 1], [6, 3], [7, 4]], "caption": "Table 1. Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of 1a with 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 398, 122], "ImageBB": [71, 133, 410, 293]}, "diagram_type": "multiple"}, {"id": 312, "width": 1344, "height": 936, "file_name": "jo0524728-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [922.0, 837.0, 232.0, 99.0], "category_id": 3}, {"id": 1, "bbox": [875.5, 477.1, 312.4, 329.7], "category_id": 1}, {"id": 2, "bbox": [32.3, 460.8, 307.8, 369.7], "category_id": 1}, {"id": 3, "bbox": [0.0, 0.0, 310.0, 378.0], "category_id": 1}, {"id": 4, "bbox": [447.2, 477.9, 307.7, 326.7], "category_id": 1}, {"id": 5, "bbox": [126.0, 384.0, 74.0, 49.0], "category_id": 3}, {"id": 6, "bbox": [157.0, 843.0, 78.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [507.0, 833.0, 232.0, 103.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [9, 5], "products": [2, 4, 1]}], "corefs": [[3, 5], [2, 6], [4, 7], [1, 0]], "caption": "Table 1 it can be seen that the highest yields of products were obtained upon photolysis at 350 nm, while irradiation at 300 and 254 nm resulted mostly in recovery of the starting material. This observation can be rationalized by absorption of light (at 300 and 254 nm) by photoproducts which revert to the starting material by a photochemical reaction. After prolonged irradia- tion, a photostationary state is reached, determined by the ratio of absorption coefficients, and rates of interconversions, of products and the starting material. Thus, after irradiation of 8 at 350 nm where the products are formed with maximal efficiency, subsequent irradiation (of the same solution) at 300 or 254 nm gives back the starting material and hence a lower observed yield of photoproducts (Table 1). ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 347, 775, 544], "ImageBB": [440, 555, 776, 789]}, "diagram_type": "multiple"}, {"id": 313, "width": 1348, "height": 404, "file_name": "ol503404p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [752.0, 0.0, 273.0, 308.8], "category_id": 1}, {"id": 1, "bbox": [49.0, 96.9, 262.6, 166.4], "category_id": 1}, {"id": 2, "bbox": [422.7, 75.2, 59.0, 181.8], "category_id": 1}, {"id": 3, "bbox": [1031.0, 45.7, 265.9, 215.9], "category_id": 1}, {"id": 4, "bbox": [189.0, 250.0, 50.0, 46.0], "category_id": 3}, {"id": 5, "bbox": [825.0, 248.0, 67.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [423.0, 253.0, 55.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [1171.0, 233.0, 36.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [1, 2], "conditions": [10, 4], "products": [0, 3]}], "corefs": [[1, 4], [2, 6], [0, 5], [3, 7]], "caption": "Table 1. Reaction Optimization for the Synthesis of 7aaa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 764, 110], "ImageBB": [449, 116, 786, 217]}, "diagram_type": "single"}, {"id": 314, "width": 1356, "height": 796, "file_name": "ol5029892-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1142.03, 249.92, 66.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [159.0, 245.0, 64.9, 51.9], "category_id": 3}, {"id": 2, "bbox": [404.3, 109.0, 233.8, 107.9], "category_id": 1}, {"id": 3, "bbox": [1105.1, 5.1, 145.7, 227.9], "category_id": 1}, {"id": 4, "bbox": [494.0, 248.9, 57.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [105.2, 104.4, 171.8, 126.4], "category_id": 1}, {"id": 6, "bbox": [726.2, 181.0, 287.8, 137.9], "category_id": 1}], "reactions": [{"reactants": [7, 3], "conditions": [1, 8], "products": [5]}], "corefs": [[5, 1], [2, 4], [3, 0]], "caption": "Table 3. Reactivity of Benzylic Grignard Reagent with O- Benzoyl-N-hydroxypiperidine ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 773, 125], "ImageBB": [448, 131, 787, 330]}, "diagram_type": "single"}, {"id": 315, "width": 1348, "height": 568, "file_name": "acs.joc.6b00116-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [968.0, 272.0, 330.0, 125.1], "category_id": 1}, {"id": 1, "bbox": [48.9, 47.0, 274.1, 149.0], "category_id": 1}, {"id": 2, "bbox": [92.0, 218.0, 198.4, 106.0], "category_id": 3}, {"id": 3, "bbox": [521.0, 255.0, 417.3, 172.4], "category_id": 1}, {"id": 4, "bbox": [704.0, 432.0, 28.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [1120.0, 432.0, 25.0, 35.0], "category_id": 3}], "reactions": [{"reactants": [3, 7], "conditions": [0], "products": [5, 1]}], "corefs": [[1, 2], [3, 4], [0, 5]], "caption": "Table 1. TpRh(C2H4)2/P(2-furyl)3-Catalyzed Reaction of Terminal Alkynes with Hydrazinesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 403, 125], "ImageBB": [82, 131, 419, 273]}, "diagram_type": "multiple"}, {"id": 316, "width": 1348, "height": 340, "file_name": "jacs.6b01306-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [62.6, 118.47, 347.18, 103.57], "category_id": 1}, {"id": 1, "bbox": [936.3, 118.47, 348.04, 102.71], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 1], "products": [3]}], "corefs": [], "caption": "Table 1. Asymmetric Hydrogenation of Dimethyl Itaconate with Mixtures of BTA Ligand, [Rh(cod)2]BArF, and Ester BTA: Screening of Various Comonomersa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 373, 415, 418], "ImageBB": [82, 425, 419, 510]}, "diagram_type": "single"}, {"id": 317, "width": 1352, "height": 1088, "file_name": "jacs.5b05415-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [105.44, 270.39, 52.54, 44.12], "category_id": 3}, {"id": 1, "bbox": [732.97, 531.51, 155.02, 46.92], "category_id": 3}, {"id": 2, "bbox": [243.02, 1042.52, 66.57, 41.28], "category_id": 3}, {"id": 3, "bbox": [160.19, 865.63, 232.23, 213.99], "category_id": 1}, {"id": 4, "bbox": [745.6, 344.8, 232.24, 213.98], "category_id": 1}, {"id": 5, "bbox": [1082.53, 96.31, 230.83, 166.25], "category_id": 1}, {"id": 6, "bbox": [745.6, 96.31, 233.64, 167.66], "category_id": 1}, {"id": 7, "bbox": [11.38, 611.53, 239.25, 166.26], "category_id": 1}, {"id": 8, "bbox": [11.38, 365.85, 240.66, 166.26], "category_id": 1}, {"id": 9, "bbox": [11.38, 114.56, 239.25, 128.35], "category_id": 1}, {"id": 10, "bbox": [101.22, 781.4, 58.16, 42.71], "category_id": 3}, {"id": 11, "bbox": [101.22, 531.51, 56.78, 44.12], "category_id": 3}, {"id": 12, "bbox": [1114.82, 268.99, 164.85, 44.11], "category_id": 3}, {"id": 13, "bbox": [716.12, 268.99, 289.79, 44.11], "category_id": 3}], "reactions": [{"reactants": [17], "conditions": [10, 9], "products": [14, 13]}, {"reactants": [16], "conditions": [8, 7], "products": [12]}, {"reactants": [15], "conditions": [6, 3], "products": [22]}, {"reactants": [11], "conditions": [0, 2], "products": [23]}], "corefs": [[9, 0], [6, 13], [5, 12], [8, 11], [4, 1], [7, 10], [3, 2]], "caption": "Figure 5. Challenges in gold-catalyzed cyclization.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1046, 321, 1060], "ImageBB": [82, 754, 420, 1026]}, "diagram_type": "multiple"}, {"id": 318, "width": 1344, "height": 624, "file_name": "ja9810742-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [942.06, 132.75, 30.33, 37.18], "category_id": 3}, {"id": 1, "bbox": [839.93, 11.74, 251.75, 118.72], "category_id": 1}], "reactions": [{"reactants": [1, 7], "conditions": [4, 3], "products": [5]}], "corefs": [[1, 0]], "caption": "Table 2. Allylation of Aldehydes 1 with 2,3-Dimethyl-4-penten-2-ol 2ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 262, 283, 287], "ImageBB": [74, 288, 410, 444]}, "diagram_type": "single"}, {"id": 319, "width": 1156, "height": 448, "file_name": "ja953272o-Figure-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.16, 124.19, 302.44, 241.17], "category_id": 1}, {"id": 1, "bbox": [615.9, 122.71, 348.21, 243.39], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1], "products": [4]}, {"reactants": [4], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 9. An equilibrium between agostic and anagostic conformers.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 143, 764, 156], "ImageBB": [476, 27, 765, 139]}, "diagram_type": "single"}, {"id": 320, "width": 1356, "height": 1484, "file_name": "ja408733f-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [995.09, 6.16, 333.33, 263.57], "category_id": 1}, {"id": 1, "bbox": [463.22, 6.16, 334.58, 263.57], "category_id": 1}, {"id": 2, "bbox": [23.53, 4.91, 265.44, 404.95], "category_id": 1}, {"id": 3, "bbox": [158.24, 805.8, 1037.9, 670.95], "category_id": 1}, {"id": 4, "bbox": [461.98, 470.76, 332.7, 259.21], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [6], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [4]}, {"reactants": [2], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [8], "products": [7]}, {"reactants": [7], "conditions": [9], "products": [3]}], "corefs": [], "caption": "Figure 1. Molecular structure of [\u03ba4-Tptm]ZnF.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 733, 679, 749], "ImageBB": [448, 355, 787, 726]}, "diagram_type": "tree"}, {"id": 321, "width": 1356, "height": 1136, "file_name": "ja2014746-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [269.68, 430.42, 20.43, 28.16], "category_id": 3}, {"id": 1, "bbox": [37.04, 5.39, 527.1, 139.56], "category_id": 1}, {"id": 2, "bbox": [6.0, 631.97, 640.29, 481.94], "category_id": 1}, {"id": 3, "bbox": [668.32, 622.33, 680.23, 506.73], "category_id": 1}, {"id": 4, "bbox": [22.25, 240.57, 518.23, 160.27], "category_id": 1}, {"id": 5, "bbox": [821.0, 5.39, 501.96, 135.12], "category_id": 1}, {"id": 6, "bbox": [806.21, 234.66, 504.91, 163.23], "category_id": 1}, {"id": 7, "bbox": [288.5, 148.86, 16.79, 30.11], "category_id": 3}, {"id": 8, "bbox": [1047.81, 429.83, 20.43, 26.37], "category_id": 3}, {"id": 9, "bbox": [1066.24, 151.03, 20.43, 27.56], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [8]}, {"reactants": [7], "conditions": [6, 10], "products": [9]}], "corefs": [[1, 7], [5, 9], [4, 0], [6, 8]], "caption": "Figure 1. (Left) ORTEP drawing of 2 (50% probability level). One of the tert-butyl groups on Si3 is disordered, and the minor contribution (occupancy factor 0.299) and hydrogen atoms are omitted for clarity. # indicates the following symmetry transformation:  x,  y \u00fe 1,  z. Selected bond lengths (\u00c5) and angles (deg): Si1 Si2 = 2.3675(6), Si1 Si3 = 2.3737(6), Si1 C1 = 1.8174(14), C1 C2 = 1.423(2), C1 C3# = 1.422(2), C2 C3 = 1.3700(19). Si2 Si1 Si3 = 122.86(2), Si2 Si1 C1 = 117.52(5), Si3 Si1 C1 = 119.58(5), Si1 C1 C2 = 120.66(11), Si1 C1 C3# = 124.39(11), C2 C1 C3# = 114.94(12), C1 C2 C3 = 122.78(13), C2 C3 C1# = 122.29(13). (Right) ORTEP drawing of 4 (50% probability level). Hydrogen atoms are omitted for clarity. # indicates the following symmetry transformation:  x \u00fe 1/2,  y \u00fe 1/2, z. Selected bond lengths (\u00c5) and angles (deg): Si1 Si2 = 2.3554(14), Si1 Si3 = 2.3524(14), Si1 C2 = 1.9108(19), C1 C2 = 1.387(3), C1 C2# = 1.387(3), C2 C3 = 1.395(5), C3 C4 = 1.386(4), C4 C3# = 1.386(4). Si2 Si1 Si3 = 122.21(5), Si2 Si1 C2 = 117.15(5), Si3 Si1 C2 = 119.29(5), C2 C1 C2# = 123.2(4), Si1 C2 C1 = 120.8(3), Si1 C2 C3 = 121.73(17), C1 C2 C3 = 117.5(2), C2 C3 C4 = 121.0(3), C3 C4 C3# = 119.7(4). ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 430, 405, 707], "ImageBB": [71, 133, 410, 417]}, "diagram_type": "multiple"}, {"id": 322, "width": 2428, "height": 636, "file_name": "ja106807u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1843.79, 4.66, 578.78, 467.09], "category_id": 1}, {"id": 1, "bbox": [1034.45, 110.86, 580.62, 263.84], "category_id": 1}, {"id": 2, "bbox": [287.38, 110.86, 516.53, 267.51], "category_id": 1}, {"id": 3, "bbox": [324.0, 440.45, 186.94, 99.05], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [1]}], "corefs": [[2, 3]], "caption": "Table 1. Absorption and Emission Properties of B, G, and R in Solution and in Organogels (Deoxygenated): Lowest Energy Absorption Wavelength, \u03bbabs, Extinction Coefficient, \u03b5, Emission Wavelength, \u03bbem, and Quantum Yield, \u03a6em, Decay Time, \u03c4, and Radiative Constant, kr ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 249, 748, 274], "ImageBB": [71, 73, 678, 232]}, "diagram_type": "single"}, {"id": 323, "width": 1348, "height": 736, "file_name": "ja063878k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.28, 145.42, 21.31, 30.46], "category_id": 3}, {"id": 1, "bbox": [302.99, 10.21, 229.71, 165.67], "category_id": 1}, {"id": 2, "bbox": [70.19, 4.11, 143.3, 169.74], "category_id": 1}, {"id": 3, "bbox": [853.98, 15.29, 320.19, 168.72], "category_id": 1}, {"id": 4, "bbox": [142.37, 146.43, 81.29, 36.57], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [2, 1], "products": [6]}], "corefs": [[2, 4], [1, 0]], "caption": "Table 2. Alkenylation with 2-Substituted Vinylsilanes", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 514, 705, 526], "ImageBB": [439, 528, 776, 712]}, "diagram_type": "single"}, {"id": 324, "width": 1344, "height": 1248, "file_name": "ja053650h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.34, 53.93, 312.11, 201.68], "category_id": 1}, {"id": 1, "bbox": [149.69, 7.04, 289.42, 204.7], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [0]}], "corefs": [], "caption": "Table 1. Intramolecular Carbonylation of 2-(2-Iodophenoxy)aniline (3, R1 ) R2 ) H, X ) I) with G1-Pd under Different Reaction Conditionsa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 406, 100], "ImageBB": [74, 102, 410, 414]}, "diagram_type": "single"}, {"id": 325, "width": 1348, "height": 852, "file_name": "ja026640e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [180.02, 9.01, 350.38, 257.47], "category_id": 1}, {"id": 1, "bbox": [867.0, 282.82, 65.56, 32.56], "category_id": 3}, {"id": 2, "bbox": [325.48, 279.15, 16.67, 32.56], "category_id": 3}, {"id": 3, "bbox": [766.76, 12.67, 404.17, 255.04], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4], "products": [5]}], "corefs": [[0, 2], [3, 1]], "caption": "Table 1. Product Studies for the Ene Reaction of ArNO, PTAD and 1O2 with the Optically Active Tiglic Amides 1a,b ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 323, 757, 348], "ImageBB": [439, 352, 776, 565]}, "diagram_type": "single"}, {"id": 326, "width": 1348, "height": 700, "file_name": "ja001164i-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [289.96, 220.37, 23.36, 32.52], "category_id": 3}, {"id": 1, "bbox": [1113.0, 223.42, 23.36, 30.49], "category_id": 3}, {"id": 2, "bbox": [181.1, 5.71, 170.88, 189.19], "category_id": 1}, {"id": 3, "bbox": [1014.32, 7.74, 160.7, 186.14], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 6], "products": [4]}], "corefs": [[2, 0], [3, 1]], "caption": "Table 3. Enantioselective Protonation of Silyl Enol Ethers 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 745, 78], "ImageBB": [439, 86, 776, 261]}, "diagram_type": "single"}, {"id": 327, "width": 1188, "height": 1476, "file_name": "op990099y-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [272.3, 1017.6, 574.5, 458.4], "category_id": 1}, {"id": 1, "bbox": [41.0, 593.0, 1023.0, 220.9], "category_id": 1}, {"id": 2, "bbox": [9.0, 0.0, 567.0, 197.2], "category_id": 1}, {"id": 3, "bbox": [753.0, 2.0, 435.0, 188.9], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [5], "products": [4, 3]}], "corefs": [], "caption": "Figure 1. Reaction scheme for the reaction between diphenyl oxide with benzyl chloride over sulphated zirconia catalyst. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 428, 775, 456], "ImageBB": [460, 55, 757, 424]}, "diagram_type": "tree"}, {"id": 328, "width": 1012, "height": 1472, "file_name": "op990044w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [831.0, 1019.4, 42.8, 48.6], "category_id": 3}, {"id": 1, "bbox": [709.0, 932.7, 122.0, 196.3], "category_id": 1}, {"id": 2, "bbox": [241.5, 379.6, 123.5, 190.9], "category_id": 1}, {"id": 3, "bbox": [609.1, 628.8, 402.9, 191.5], "category_id": 1}, {"id": 4, "bbox": [650.0, 81.2, 289.2, 226.5], "category_id": 1}, {"id": 5, "bbox": [75.8, 78.5, 288.7, 226.8], "category_id": 1}, {"id": 6, "bbox": [757.0, 272.0, 69.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [171.0, 271.0, 66.0, 55.0], "category_id": 3}, {"id": 8, "bbox": [369.0, 464.0, 34.0, 58.0], "category_id": 3}, {"id": 9, "bbox": [410.0, 1419.0, 54.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [293.0, 1149.0, 328.0, 235.0], "category_id": 1}, {"id": 11, "bbox": [777.0, 828.0, 77.0, 60.0], "category_id": 3}, {"id": 12, "bbox": [172.0, 846.0, 51.0, 50.0], "category_id": 3}, {"id": 13, "bbox": [55.0, 610.0, 330.0, 212.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2], "products": [16]}, {"reactants": [16], "conditions": [6], "products": [11]}, {"reactants": [4], "conditions": [14], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [11]}], "corefs": [[5, 7], [4, 6], [2, 8], [13, 12], [3, 11], [1, 0], [10, 9]], "caption": "Table 1. Horner-Emmons reaction of aldehyde (5b) and triethyl phosphonoacetatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 454, 753, 482], "ImageBB": [482, 74, 735, 442]}, "diagram_type": "tree"}, {"id": 329, "width": 1280, "height": 232, "file_name": "op980075b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 5.0, 148.0, 159.0], "category_id": 1}, {"id": 1, "bbox": [743.8, 22.8, 205.4, 135.1], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [1], "products": [5, 0]}], "corefs": [], "caption": "Table 1. Epoxidation of 1-decene (experiments 1-8) and methyl 10-undecenoate (experiments 9-12) with procedure A ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 334, 763, 376], "ImageBB": [448, 264, 768, 322]}, "diagram_type": "single"}, {"id": 330, "width": 1348, "height": 904, "file_name": "op970105v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [267.0, 0.0, 438.0, 389.0], "category_id": 1}, {"id": 1, "bbox": [834.0, 1.0, 489.0, 430.0], "category_id": 1}, {"id": 2, "bbox": [430.0, 381.0, 61.0, 59.0], "category_id": 3}, {"id": 3, "bbox": [1043.0, 387.0, 67.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [6], "products": [5, 2]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 485, 64], "ImageBB": [438, 65, 775, 291]}, "diagram_type": "single"}, {"id": 331, "width": 1344, "height": 1040, "file_name": "op970105v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [478.0, 40.0, 364.0, 371.0], "category_id": 1}, {"id": 1, "bbox": [498.66, 410.64, 413.0, 100.0], "category_id": 3}, {"id": 2, "bbox": [838.0, 90.0, 368.0, 304.6], "category_id": 1}, {"id": 3, "bbox": [31.0, 416.0, 424.3, 104.3], "category_id": 3}, {"id": 4, "bbox": [918.64, 410.64, 411.0, 98.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 1.0, 347.0, 409.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2], "products": [0, 3]}], "corefs": [[5, 3], [0, 1], [2, 4]], "caption": "Table 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 50, 119, 64], "ImageBB": [73, 63, 409, 323]}, "diagram_type": "single"}, {"id": 332, "width": 1412, "height": 1248, "file_name": "op9001824-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 1009.7, 421.4, 180.3], "category_id": 1}, {"id": 1, "bbox": [931.2, 1013.0, 422.8, 188.6], "category_id": 1}, {"id": 2, "bbox": [843.8, 370.0, 445.7, 375.7], "category_id": 1}, {"id": 3, "bbox": [1120.5, 147.5, 291.5, 162.5], "category_id": 1}, {"id": 4, "bbox": [1304.0, 310.0, 51.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [1071.0, 757.0, 52.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [667.0, 588.0, 23.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [186.0, 1198.0, 47.0, 48.0], "category_id": 3}, {"id": 8, "bbox": [649.0, 1183.0, 52.0, 40.0], "category_id": 3}, {"id": 9, "bbox": [480.8, 937.3, 390.4, 262.5], "category_id": 1}, {"id": 10, "bbox": [652.6, 304.78, 40.2, 42.0], "category_id": 3}, {"id": 11, "bbox": [485.5, 140.9, 376.0, 167.7], "category_id": 1}, {"id": 12, "bbox": [1112.78, 1206.39, 59.22, 34.0], "category_id": 3}, {"id": 13, "bbox": [486.0, 410.5, 377.7, 179.5], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [14], "products": [2]}], "corefs": [[11, 10], [3, 4], [13, 6], [2, 5], [0, 7], [9, 8], [1, 12]], "caption": "Figure 1", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 360, 109, 374], "ImageBB": [58, 45, 411, 357]}, "diagram_type": "multiple"}, {"id": 333, "width": 1188, "height": 1220, "file_name": "op8002486-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 663.0, 401.0, 141.1], "category_id": 1}, {"id": 1, "bbox": [3.0, 987.0, 409.0, 140.0], "category_id": 1}, {"id": 2, "bbox": [167.93, 1168.14, 69.17, 50.31], "category_id": 3}, {"id": 3, "bbox": [171.07, 826.98, 64.46, 55.02], "category_id": 3}, {"id": 4, "bbox": [171.07, 510.97, 64.46, 56.6], "category_id": 3}, {"id": 5, "bbox": [175.79, 166.67, 58.17, 51.88], "category_id": 3}, {"id": 6, "bbox": [702.0, 993.0, 426.0, 147.0], "category_id": 1}, {"id": 7, "bbox": [704.0, 663.0, 402.0, 138.0], "category_id": 1}, {"id": 8, "bbox": [704.0, 347.0, 444.0, 174.0], "category_id": 1}, {"id": 9, "bbox": [2.0, 339.0, 462.0, 163.0], "category_id": 1}, {"id": 10, "bbox": [701.0, 12.0, 375.0, 169.0], "category_id": 1}, {"id": 11, "bbox": [2.0, 4.0, 370.0, 164.0], "category_id": 1}], "reactions": [{"reactants": [18], "conditions": [12], "products": [17]}, {"reactants": [17], "conditions": [], "products": [18]}, {"reactants": [17], "conditions": [10], "products": [15]}, {"reactants": [15], "conditions": [], "products": [17]}, {"reactants": [16], "conditions": [9], "products": [15]}, {"reactants": [15], "conditions": [], "products": [16]}, {"reactants": [0], "conditions": [24], "products": [14]}, {"reactants": [14], "conditions": [], "products": [0]}, {"reactants": [14], "conditions": [22], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}, {"reactants": [13], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [21], "products": [13]}], "corefs": [[11, 5], [9, 4], [0, 3], [1, 2]], "caption": "Table 1. Predicted reaction times for cyanate conversion to reach >95% with KOCN addition times of 0.25 h, 0.5 h, and 1 h (20 \u00b0C, 2 mol % excess of 15) ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 382, 760, 424], "ImageBB": [445, 65, 742, 370]}, "diagram_type": "tree"}, {"id": 334, "width": 2816, "height": 832, "file_name": "op700160a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1798.0, 274.0, 61.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [1153.0, 268.0, 172.0, 66.0], "category_id": 3}, {"id": 2, "bbox": [1729.0, 3.0, 211.0, 256.0], "category_id": 1}, {"id": 3, "bbox": [911.0, 274.0, 133.0, 51.0], "category_id": 3}, {"id": 4, "bbox": [878.0, 0.0, 202.0, 265.0], "category_id": 1}, {"id": 5, "bbox": [1140.0, 0.0, 194.0, 259.0], "category_id": 1}], "reactions": [{"reactants": [6, 7], "conditions": [0], "products": [3]}], "corefs": [[4, 3], [5, 1], [2, 0]], "caption": "Table 1. Screening of oxidation conditions for conversion of bisfuran alcohol, 1, to ketone, 9", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 564, 60], "ImageBB": [58, 74, 762, 282]}, "diagram_type": "single"}, {"id": 335, "width": 1356, "height": 1184, "file_name": "op7000172-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.0, 406.0, 567.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [663.0, 281.0, 57.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [168.0, 295.0, 66.0, 53.0], "category_id": 3}, {"id": 3, "bbox": [211.0, 703.0, 72.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [679.0, 1082.0, 51.0, 68.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 46.0, 369.0, 243.0], "category_id": 1}, {"id": 6, "bbox": [671.05, 419.29, 250.89, 56.71], "category_id": 1}, {"id": 7, "bbox": [1032.59, 352.35, 72.0, 52.0], "category_id": 3}, {"id": 8, "bbox": [670.9, 606.0, 457.1, 119.0], "category_id": 1}, {"id": 9, "bbox": [908.0, 224.2, 329.0, 146.8], "category_id": 1}, {"id": 10, "bbox": [505.3, 59.8, 342.7, 217.8], "category_id": 1}, {"id": 11, "bbox": [855.94, 694.24, 51.0, 53.0], "category_id": 3}, {"id": 12, "bbox": [262.6, 811.7, 566.4, 366.3], "category_id": 1}, {"id": 13, "bbox": [896.9, 7.0, 332.1, 136.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [4, 5], "products": [16]}, {"reactants": [16], "conditions": [19, 6, 15], "products": [0]}, {"reactants": [0], "conditions": [12, 2, 14, 3], "products": [18]}], "corefs": [[5, 2], [10, 1], [9, 7], [0, 3], [8, 11], [12, 4]], "caption": "Table 2. Palladium content of coupling products 17, 21, 31, and 34 before and after scavenging ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 393, 400, 421], "ImageBB": [73, 85, 412, 381]}, "diagram_type": "multiple"}, {"id": 336, "width": 1352, "height": 1452, "file_name": "op500224x-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [410.0, 803.0, 392.0, 303.0], "category_id": 1}, {"id": 1, "bbox": [4.0, 1167.0, 392.0, 285.0], "category_id": 1}, {"id": 2, "bbox": [989.0, 1083.0, 163.0, 70.0], "category_id": 3}, {"id": 3, "bbox": [572.0, 1095.6, 174.0, 85.4], "category_id": 3}, {"id": 4, "bbox": [225.0, 1086.0, 162.0, 84.5], "category_id": 3}, {"id": 5, "bbox": [45.0, 824.0, 417.0, 271.0], "category_id": 1}, {"id": 6, "bbox": [739.0, 779.0, 582.0, 361.0], "category_id": 1}, {"id": 7, "bbox": [338.0, 1179.0, 396.0, 273.0], "category_id": 1}, {"id": 8, "bbox": [696.0, 1181.0, 319.0, 271.0], "category_id": 1}, {"id": 9, "bbox": [944.0, 1203.0, 408.0, 249.0], "category_id": 1}, {"id": 10, "bbox": [969.0, 347.0, 102.0, 61.0], "category_id": 3}, {"id": 11, "bbox": [710.0, 350.0, 85.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [114.0, 356.0, 61.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [112.0, 722.0, 88.0, 61.0], "category_id": 3}, {"id": 14, "bbox": [1118.0, 727.0, 101.0, 63.0], "category_id": 3}, {"id": 15, "bbox": [613.0, 727.0, 88.0, 65.0], "category_id": 3}, {"id": 16, "bbox": [207.0, 0.0, 76.0, 56.0], "category_id": 3}, {"id": 17, "bbox": [22.0, 0.0, 279.0, 169.0], "category_id": 1}, {"id": 18, "bbox": [1.0, 94.0, 273.0, 256.0], "category_id": 1}, {"id": 19, "bbox": [597.0, 33.0, 313.0, 314.0], "category_id": 1}, {"id": 20, "bbox": [969.0, 60.0, 81.0, 274.0], "category_id": 1}, {"id": 21, "bbox": [26.0, 406.0, 289.0, 303.0], "category_id": 1}, {"id": 22, "bbox": [335.0, 566.0, 124.0, 59.0], "category_id": 1}, {"id": 23, "bbox": [500.0, 429.0, 309.0, 264.0], "category_id": 1}, {"id": 24, "bbox": [983.0, 426.0, 349.0, 312.0], "category_id": 1}], "reactions": [{"reactants": [22, 23], "conditions": [19, 20], "products": [24]}, {"reactants": [24, 25], "conditions": [17, 18], "products": [29]}, {"reactants": [26], "conditions": [27], "products": [28]}], "corefs": [[17, 16], [18, 12], [19, 11], [20, 10], [21, 13], [23, 15], [24, 14], [5, 4], [0, 3], [6, 2]], "caption": "Table 9. Tropane synthesis via azomethine ylides", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 727, 110], "ImageBB": [448, 116, 786, 479]}, "diagram_type": "multiple"}, {"id": 337, "width": 1272, "height": 700, "file_name": "op0602270-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [956.0, 352.0, 311.0, 215.0], "category_id": 1}, {"id": 1, "bbox": [941.0, 7.0, 310.0, 217.0], "category_id": 1}, {"id": 2, "bbox": [3.0, 9.0, 312.0, 218.0], "category_id": 1}, {"id": 3, "bbox": [13.0, 349.0, 230.0, 310.0], "category_id": 1}, {"id": 4, "bbox": [998.0, 246.0, 260.0, 90.0], "category_id": 3}, {"id": 5, "bbox": [287.0, 602.0, 216.0, 88.0], "category_id": 3}, {"id": 6, "bbox": [995.0, 606.0, 261.0, 89.0], "category_id": 3}, {"id": 7, "bbox": [95.0, 248.0, 218.0, 83.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1, 7], "products": [3]}, {"reactants": [5], "conditions": [0, 6], "products": [2]}], "corefs": [[2, 7], [1, 4], [3, 5], [0, 6]], "caption": "Table 2. Influence of ester group on conversion and enantioselectivity ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 726, 81], "ImageBB": [449, 89, 767, 264]}, "diagram_type": "multiple"}, {"id": 338, "width": 1344, "height": 380, "file_name": "op060155c-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [357.1, 126.0, 162.9, 193.8], "category_id": 1}, {"id": 1, "bbox": [773.0, 124.1, 215.9, 199.9], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Figure 2. Lithium exchange in MeTHF.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 338, 299, 352], "ImageBB": [74, 238, 410, 333]}, "diagram_type": "single"}, {"id": 339, "width": 1356, "height": 1932, "file_name": "op060114g-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [591.0, 68.0, 281.0, 431.0], "category_id": 1}, {"id": 1, "bbox": [61.0, 376.0, 47.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [39.0, 793.0, 273.0, 423.0], "category_id": 1}, {"id": 3, "bbox": [1077.0, 775.0, 276.0, 426.0], "category_id": 1}, {"id": 4, "bbox": [1042.0, 78.0, 277.0, 413.0], "category_id": 1}, {"id": 5, "bbox": [34.0, 113.0, 264.0, 232.0], "category_id": 1}, {"id": 6, "bbox": [4.0, 1881.0, 200.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [910.0, 1867.0, 294.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [12.0, 1205.0, 166.0, 56.0], "category_id": 3}, {"id": 9, "bbox": [965.4, 1451.0, 283.6, 412.0], "category_id": 1}, {"id": 10, "bbox": [1000.0, 487.0, 202.0, 61.0], "category_id": 3}, {"id": 11, "bbox": [41.0, 1449.0, 273.2, 415.8], "category_id": 1}, {"id": 12, "bbox": [569.0, 491.0, 164.0, 53.0], "category_id": 3}, {"id": 13, "bbox": [1070.0, 1197.0, 165.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [15], "conditions": [11, 10], "products": [0, 14]}, {"reactants": [0], "conditions": [9, 3], "products": [13]}, {"reactants": [13], "conditions": [6, 7], "products": [12]}, {"reactants": [12], "conditions": [5], "products": [21]}, {"reactants": [21], "conditions": [8, 1], "products": [19]}], "corefs": [[5, 1], [0, 12], [4, 10], [3, 13], [2, 8], [11, 6], [9, 7]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 332, 129, 346], "ImageBB": [73, 356, 412, 839]}, "diagram_type": "tree"}, {"id": 340, "width": 1356, "height": 1156, "file_name": "op049889k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [995.0, 0.0, 360.0, 334.0], "category_id": 1}, {"id": 1, "bbox": [608.1, 18.8, 366.9, 328.2], "category_id": 1}, {"id": 2, "bbox": [174.4, 178.8, 363.1, 152.8], "category_id": 1}, {"id": 3, "bbox": [340.0, 321.0, 57.3, 58.4], "category_id": 3}, {"id": 4, "bbox": [716.8, 334.0, 87.2, 54.1], "category_id": 3}, {"id": 5, "bbox": [1177.4, 350.1, 86.9, 55.8], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2], "products": [1, 0]}], "corefs": [[2, 3], [1, 4], [0, 5]], "caption": "Table 1. Cycloaddition optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 273, 67], "ImageBB": [73, 71, 412, 361]}, "diagram_type": "single"}, {"id": 341, "width": 1344, "height": 756, "file_name": "op034181b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [813.0, 7.0, 326.0, 202.0], "category_id": 1}, {"id": 1, "bbox": [284.0, 200.0, 55.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [901.05, 199.0, 45.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [199.0, 1.0, 305.8, 191.8], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 4], "products": [0]}], "corefs": [[3, 1], [0, 2]], "caption": "Table 2. Esterification of 2,4,6-trimethylbenzoic acid", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 367, 67], "ImageBB": [74, 70, 410, 259]}, "diagram_type": "single"}, {"id": 342, "width": 1800, "height": 632, "file_name": "op0340816-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [254.8, 558.4, 43.3, 52.3], "category_id": 3}, {"id": 1, "bbox": [1197.79, 0.57, 303.31, 214.83], "category_id": 1}, {"id": 2, "bbox": [523.1, 15.0, 341.9, 212.1], "category_id": 1}, {"id": 3, "bbox": [4.0, 6.0, 265.2, 192.6], "category_id": 1}, {"id": 4, "bbox": [1271.0, 231.0, 67.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [836.5, 340.8, 307.2, 214.6], "category_id": 1}, {"id": 6, "bbox": [165.1, 321.1, 335.4, 219.9], "category_id": 1}, {"id": 7, "bbox": [920.1, 574.2, 47.6, 47.5], "category_id": 3}, {"id": 8, "bbox": [639.08, 238.57, 54.22, 58.93], "category_id": 3}, {"id": 9, "bbox": [1435.5, 344.4, 237.6, 194.2], "category_id": 1}, {"id": 10, "bbox": [1524.43, 583.12, 48.0, 46.6], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [5, 4], "products": [2]}, {"reactants": [2], "conditions": [8, 7], "products": [1]}, {"reactants": [1], "conditions": [18, 19], "products": [13]}, {"reactants": [13], "conditions": [9], "products": [12]}, {"reactants": [12], "conditions": [11, 10], "products": [16]}], "corefs": [[2, 8], [1, 4], [6, 0], [5, 7], [9, 10]], "caption": "Figure 1. Commercial preparation of 1-chloro-2,6-difluorobenzene.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 215, 447, 229], "ImageBB": [200, 54, 650, 212]}, "diagram_type": "multiple"}, {"id": 343, "width": 2808, "height": 1068, "file_name": "op030202q-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1715.3, 8.0, 237.3, 283.0], "category_id": 1}, {"id": 1, "bbox": [521.3, 7.4, 227.5, 291.6], "category_id": 1}, {"id": 2, "bbox": [966.0, 5.0, 304.1, 294.8], "category_id": 1}, {"id": 3, "bbox": [989.0, 363.0, 207.0, 59.0], "category_id": 3}, {"id": 4, "bbox": [1796.0, 299.0, 132.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [602.0, 316.0, 87.0, 61.0], "category_id": 3}, {"id": 6, "bbox": [972.0, 313.0, 219.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [1, 10], "products": [4]}, {"reactants": [4], "conditions": [5, 3], "products": [0, 11]}], "corefs": [[1, 5], [2, 6], [2, 3], [0, 4]], "caption": "Table 4. Resolution of racemic PLA by diastereomeric salt formation: optimization", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 460, 533, 474], "ImageBB": [74, 479, 776, 746]}, "diagram_type": "single"}, {"id": 344, "width": 2808, "height": 1784, "file_name": "op030202q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [882.2, 0.0, 224.8, 305.2], "category_id": 1}, {"id": 1, "bbox": [1697.8, 11.5, 229.9, 298.5], "category_id": 1}, {"id": 2, "bbox": [955.0, 366.0, 58.0, 70.0], "category_id": 3}, {"id": 3, "bbox": [1780.0, 363.0, 68.0, 70.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 0], "products": [2]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 2. Aromatic ring hydrogenation of phenyl alanine: catalyst screening", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 490, 67], "ImageBB": [74, 83, 776, 529]}, "diagram_type": "single"}, {"id": 345, "width": 1348, "height": 668, "file_name": "ol8019605-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [462.0, 224.0, 283.0, 218.0], "category_id": 1}, {"id": 1, "bbox": [805.0, 227.0, 128.0, 267.0], "category_id": 1}, {"id": 2, "bbox": [883.0, 0.0, 211.0, 191.0], "category_id": 1}, {"id": 3, "bbox": [247.0, 1.0, 219.0, 193.0], "category_id": 1}, {"id": 4, "bbox": [853.0, 511.0, 36.0, 38.0], "category_id": 3}, {"id": 5, "bbox": [583.0, 508.0, 34.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [0, 2], "products": [4]}], "corefs": [[0, 5], [1, 4]], "caption": "Table 1. Borylation of Sterically Hindered m-Terphenylsa", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 367, 724, 382], "ImageBB": [425, 392, 762, 559]}, "diagram_type": "single"}, {"id": 346, "width": 1348, "height": 272, "file_name": "ol801791g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [29.8, 9.3, 196.7, 149.2], "category_id": 1}, {"id": 1, "bbox": [709.7, 8.4, 180.9, 152.7], "category_id": 1}, {"id": 2, "bbox": [454.7, 8.7, 224.4, 151.9], "category_id": 1}, {"id": 3, "bbox": [772.0, 196.0, 44.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [931.8, 0.9, 389.2, 191.1], "category_id": 1}, {"id": 5, "bbox": [65.86, 195.03, 105.44, 38.77], "category_id": 3}, {"id": 6, "bbox": [527.6, 196.0, 49.4, 38.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 0], "products": [3, 2, 7]}], "corefs": [[0, 5], [2, 6], [1, 3]], "caption": "Table 2. Dynamic Kinetic Resolution of 6a (trans) + 12 (cis)a", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 71, 752, 88], "ImageBB": [425, 97, 762, 165]}, "diagram_type": "single"}, {"id": 347, "width": 1352, "height": 864, "file_name": "ol801788t-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [285.0, 312.0, 51.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [639.11, 317.51, 65.5, 45.1], "category_id": 3}, {"id": 2, "bbox": [61.7, 108.9, 394.9, 197.9], "category_id": 1}, {"id": 3, "bbox": [532.6, 109.8, 280.3, 204.7], "category_id": 1}, {"id": 4, "bbox": [1039.0, 678.0, 43.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [828.5, 397.3, 416.4, 287.9], "category_id": 1}, {"id": 6, "bbox": [408.1, 491.8, 241.1, 151.2], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [10, 1], "products": [8]}], "corefs": [[2, 0], [3, 1], [5, 4]], "caption": "Table 1. Palladium-Catalyzed Disilylation of o-Quinodimethanes with 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 291, 102], "ImageBB": [58, 111, 396, 327]}, "diagram_type": "multiple"}, {"id": 348, "width": 1352, "height": 932, "file_name": "ol801035c-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 541.0, 227.0, 178.0], "category_id": 1}, {"id": 1, "bbox": [909.0, 706.0, 309.0, 177.0], "category_id": 1}, {"id": 2, "bbox": [247.0, 742.0, 33.0, 37.0], "category_id": 3}, {"id": 3, "bbox": [827.0, 742.0, 29.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1225.0, 744.0, 26.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [1139.0, 863.0, 35.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [1052.0, 541.0, 219.0, 178.0], "category_id": 1}, {"id": 7, "bbox": [679.0, 541.0, 294.0, 176.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [9, 8, 1]}], "corefs": [[0, 2], [7, 3], [6, 4], [1, 5]], "caption": "Figure 1. 4-Thiazolylcarboxylic esters are units of the heterocyclic core in the d series of thiopeptide antibiotics exemplified by sulfomycinamte and micrococcinate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 285, 394, 327], "ImageBB": [425, 132, 763, 365]}, "diagram_type": "single"}, {"id": 349, "width": 1348, "height": 644, "file_name": "ol801034x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [74.2, 70.0, 301.4, 221.1], "category_id": 1}, {"id": 1, "bbox": [322.2, 31.9, 266.7, 220.1], "category_id": 1}, {"id": 2, "bbox": [946.0, 0.0, 329.0, 267.0], "category_id": 1}, {"id": 3, "bbox": [460.0, 277.0, 49.0, 62.0], "category_id": 3}, {"id": 4, "bbox": [1087.0, 285.0, 45.0, 56.0], "category_id": 3}, {"id": 5, "bbox": [116.0, 277.0, 40.0, 53.0], "category_id": 3}], "reactions": [{"reactants": [0, 1], "conditions": [2, 8], "products": [3]}], "corefs": [[0, 5], [1, 3], [2, 4]], "caption": "Table 1. Reation of 1 with Isatin to Generate Compound 5a", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 243, 736, 258], "ImageBB": [425, 267, 762, 428]}, "diagram_type": "single"}, {"id": 350, "width": 1348, "height": 948, "file_name": "ol800288b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [887.0, 10.0, 303.0, 91.0], "category_id": 1}, {"id": 1, "bbox": [161.0, 39.0, 265.0, 64.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 4], "products": [1]}], "corefs": [], "caption": "Table 1. Aziridination of 1-Hexene Catalyzed by IPrCuCla", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 475, 752, 489], "ImageBB": [439, 494, 776, 731]}, "diagram_type": "single"}, {"id": 351, "width": 1344, "height": 1024, "file_name": "ol400110c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1016.0, 325.0, 70.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [318.0, 330.72, 63.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [156.2, 4.0, 335.5, 324.0], "category_id": 1}, {"id": 3, "bbox": [876.0, 21.0, 312.9, 289.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [3, 2], "products": [6]}], "corefs": [[2, 1], [3, 0]], "caption": "Table 1. Optimization Studies", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 237, 231, 250], "ImageBB": [71, 261, 407, 517]}, "diagram_type": "single"}, {"id": 352, "width": 1476, "height": 1984, "file_name": "ol303482k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [450.0, 871.0, 248.0, 230.0], "category_id": 1}, {"id": 1, "bbox": [456.0, 408.0, 234.0, 225.0], "category_id": 1}, {"id": 2, "bbox": [605.0, 50.0, 172.0, 185.0], "category_id": 1}, {"id": 3, "bbox": [170.0, 2.0, 380.0, 274.0], "category_id": 1}, {"id": 4, "bbox": [341.0, 247.0, 65.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [668.0, 221.0, 44.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [1110.0, 235.0, 59.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [909.0, 0.0, 536.0, 276.0], "category_id": 1}, {"id": 8, "bbox": [548.0, 635.0, 77.0, 53.0], "category_id": 3}, {"id": 9, "bbox": [538.0, 1102.0, 85.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [542.0, 1366.0, 79.0, 45.0], "category_id": 3}, {"id": 11, "bbox": [499.0, 1658.0, 87.0, 65.0], "category_id": 3}, {"id": 12, "bbox": [434.0, 1406.0, 288.0, 358.0], "category_id": 1}, {"id": 13, "bbox": [393.0, 1146.0, 370.0, 220.0], "category_id": 1}], "reactions": [{"reactants": [3, 2], "conditions": [4], "products": [8]}], "corefs": [[3, 4], [2, 5], [7, 6], [1, 8], [0, 9], [13, 10], [12, 11]], "caption": "Table 1. Alkylation of Bromide 12 with a Chiral Propionate 7", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 539, 765, 552], "ImageBB": [404, 564, 773, 1060]}, "diagram_type": "single"}, {"id": 353, "width": 1344, "height": 1400, "file_name": "ol303154k-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [919.8, 1050.8, 332.0, 224.6], "category_id": 1}, {"id": 1, "bbox": [579.4, 92.2, 273.6, 205.0], "category_id": 1}, {"id": 2, "bbox": [586.0, 343.8, 301.6, 202.6], "category_id": 1}, {"id": 3, "bbox": [343.0, 575.8, 136.0, 145.2], "category_id": 1}, {"id": 4, "bbox": [26.4, 261.6, 168.0, 163.2], "category_id": 1}, {"id": 5, "bbox": [224.2, 102.6, 262.2, 122.6], "category_id": 1}, {"id": 6, "bbox": [515.4, 1054.6, 397.6, 263.4], "category_id": 1}, {"id": 7, "bbox": [233.0, 427.0, 307.0, 125.0], "category_id": 1}, {"id": 8, "bbox": [95.0, 939.0, 381.0, 394.0], "category_id": 1}, {"id": 9, "bbox": [338.25, 3.58, 124.48, 37.89], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [6, 0], "products": [2]}, {"reactants": [5], "conditions": [19, 17], "products": [3]}], "corefs": [], "caption": "Figure 1. Bioactive spiro-tetrahydroquinolines.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 492, 321, 505], "ImageBB": [71, 130, 407, 480]}, "diagram_type": "tree"}, {"id": 354, "width": 1344, "height": 952, "file_name": "ol3023903-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [667.0, 189.8, 208.5, 97.7], "category_id": 1}, {"id": 1, "bbox": [65.6, 425.5, 132.6, 110.4], "category_id": 1}, {"id": 2, "bbox": [674.9, 426.0, 151.0, 115.0], "category_id": 1}, {"id": 3, "bbox": [665.0, 662.9, 205.3, 122.1], "category_id": 1}, {"id": 4, "bbox": [685.5, 820.3, 178.8, 115.9], "category_id": 1}, {"id": 5, "bbox": [48.4, 190.7, 172.9, 102.3], "category_id": 1}, {"id": 6, "bbox": [85.0, 692.0, 230.0, 212.0], "category_id": 1}], "reactions": [{"reactants": [11, 13], "conditions": [19, 18], "products": [2]}, {"reactants": [3, 10], "conditions": [17, 16], "products": [4]}, {"reactants": [22, 12], "conditions": [0, 15], "products": [5, 6]}], "corefs": [], "caption": "Figure 1. Synthetic approaches for the construction of C(sp2) CF3 bonds. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 932, 405, 962], "ImageBB": [71, 683, 407, 921]}, "diagram_type": "tree"}, {"id": 355, "width": 1472, "height": 3684, "file_name": "ol301535j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [876.0, 467.0, 224.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [862.0, 736.0, 253.0, 252.0], "category_id": 1}, {"id": 2, "bbox": [837.0, 1041.0, 299.0, 252.0], "category_id": 1}, {"id": 3, "bbox": [848.0, 1349.0, 266.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [872.0, 1658.0, 233.0, 256.0], "category_id": 1}, {"id": 5, "bbox": [834.0, 1937.0, 313.0, 252.0], "category_id": 1}, {"id": 6, "bbox": [847.0, 2213.0, 271.0, 256.0], "category_id": 1}, {"id": 7, "bbox": [859.0, 2526.0, 280.0, 241.0], "category_id": 1}, {"id": 8, "bbox": [880.0, 2755.0, 61.0, 40.0], "category_id": 3}, {"id": 9, "bbox": [901.0, 2453.0, 52.0, 37.0], "category_id": 3}, {"id": 10, "bbox": [875.0, 2168.0, 46.0, 47.0], "category_id": 3}, {"id": 11, "bbox": [921.0, 1896.0, 51.0, 41.0], "category_id": 3}, {"id": 12, "bbox": [900.0, 1616.0, 52.0, 42.0], "category_id": 3}, {"id": 13, "bbox": [879.0, 1282.0, 49.0, 35.0], "category_id": 3}, {"id": 14, "bbox": [903.0, 970.0, 51.0, 39.0], "category_id": 3}, {"id": 15, "bbox": [918.0, 701.0, 55.0, 35.0], "category_id": 3}, {"id": 16, "bbox": [943.0, 233.0, 80.0, 32.0], "category_id": 3}, {"id": 17, "bbox": [540.0, 229.0, 36.0, 38.0], "category_id": 3}, {"id": 18, "bbox": [487.0, 18.0, 218.0, 213.0], "category_id": 1}, {"id": 19, "bbox": [903.0, 4.0, 205.0, 245.0], "category_id": 1}], "reactions": [{"reactants": [25], "conditions": [29, 30], "products": [28]}], "corefs": [[18, 17], [19, 16], [0, 15], [1, 14], [2, 13], [3, 12], [4, 11], [5, 10], [6, 9], [7, 8]], "caption": "Table 1. Tandem Reactions Initiated by an Epoxide Ring Opening Using NaN3, Followed by 7-endo-trig Intramolecular Oxa-Michael Addition ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 770, 128], "ImageBB": [405, 139, 773, 1060]}, "diagram_type": "single"}, {"id": 356, "width": 1344, "height": 540, "file_name": "ol202499g-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [512.2, 278.1, 167.5, 156.8], "category_id": 1}, {"id": 1, "bbox": [1227.43, 421.54, 37.5, 44.59], "category_id": 3}, {"id": 2, "bbox": [769.1, 412.0, 183.9, 120.0], "category_id": 1}, {"id": 3, "bbox": [27.0, 289.0, 86.0, 120.0], "category_id": 1}, {"id": 4, "bbox": [578.0, 448.0, 16.0, 31.0], "category_id": 3}, {"id": 5, "bbox": [1034.1, 283.3, 257.6, 176.6], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [1], "products": [0]}, {"reactants": [0, 3], "conditions": [1], "products": [7]}], "corefs": [[0, 4], [5, 1]], "caption": "Figure 1. Strategy of tandem cyanation allylic alkylation reaction. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 328, 405, 355], "ImageBB": [71, 180, 407, 315]}, "diagram_type": "tree"}, {"id": 357, "width": 1348, "height": 1328, "file_name": "ol2017998-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [171.0, 226.0, 129.0, 59.0], "category_id": 3}, {"id": 1, "bbox": [1153.0, 231.0, 67.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [914.9, 3.0, 386.1, 287.0], "category_id": 1}, {"id": 3, "bbox": [55.2, 0.0, 345.8, 235.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 4, 0], "products": [6]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 2. Optimization of Cross-Coupling Reaction Using Trialkylphosphonium Tetrafluoroborate Saltsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 323, 742, 350], "ImageBB": [436, 362, 773, 694]}, "diagram_type": "single"}, {"id": 358, "width": 1348, "height": 808, "file_name": "ol2017998-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1141.0, 258.0, 65.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [879.0, 256.0, 66.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [219.0, 201.0, 43.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [747.1, 52.9, 309.0, 155.8], "category_id": 1}, {"id": 4, "bbox": [1073.3, 2.2, 217.7, 183.3], "category_id": 1}, {"id": 5, "bbox": [60.1, 29.8, 396.1, 189.6], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [10, 1], "products": [8, 9]}], "corefs": [[5, 2], [3, 1], [4, 0]], "caption": "Table 1. Effect of Silanolate Nontransferable Group and Olefin Geometrya ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 154, 771, 181], "ImageBB": [436, 192, 773, 394]}, "diagram_type": "single"}, {"id": 359, "width": 1348, "height": 3576, "file_name": "ol200038n-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [463.0, 420.0, 330.0, 77.0], "category_id": 1}, {"id": 1, "bbox": [623.0, 1633.0, 146.4, 40.0], "category_id": 3}, {"id": 2, "bbox": [760.0, 1683.0, 407.0, 281.0], "category_id": 1}, {"id": 3, "bbox": [81.0, 1690.0, 628.0, 292.0], "category_id": 1}, {"id": 4, "bbox": [886.0, 1332.0, 411.0, 278.0], "category_id": 1}, {"id": 5, "bbox": [482.0, 1328.0, 399.0, 275.0], "category_id": 1}, {"id": 6, "bbox": [49.0, 1256.0, 430.0, 420.0], "category_id": 1}, {"id": 7, "bbox": [699.0, 964.0, 412.0, 275.0], "category_id": 1}, {"id": 8, "bbox": [211.0, 962.0, 412.0, 282.0], "category_id": 1}, {"id": 9, "bbox": [827.0, 900.0, 35.0, 35.0], "category_id": 3}, {"id": 10, "bbox": [607.0, 637.0, 393.0, 263.0], "category_id": 1}, {"id": 11, "bbox": [800.0, 420.0, 51.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [1070.0, 642.0, 35.0, 50.0], "category_id": 3}, {"id": 13, "bbox": [882.0, 344.0, 372.0, 322.0], "category_id": 1}, {"id": 14, "bbox": [940.0, 1967.0, 147.8, 51.0], "category_id": 3}, {"id": 15, "bbox": [1034.79, 1633.59, 143.6, 40.0], "category_id": 3}, {"id": 16, "bbox": [276.0, 2962.0, 802.0, 608.0], "category_id": 1}, {"id": 17, "bbox": [845.0, 1254.0, 151.6, 44.0], "category_id": 3}, {"id": 18, "bbox": [274.0, 1632.0, 144.2, 40.0], "category_id": 3}, {"id": 19, "bbox": [489.0, 1964.0, 139.9, 55.0], "category_id": 3}, {"id": 20, "bbox": [419.0, 1256.0, 148.6, 44.0], "category_id": 3}], "reactions": [{"reactants": [24], "conditions": [19, 18, 2, 1], "products": [17]}, {"reactants": [17], "conditions": [0, 3], "products": [14]}], "corefs": [[0, 11], [13, 12], [10, 9], [8, 20], [7, 17], [6, 18], [5, 1], [4, 15], [3, 19], [2, 14]], "caption": "Figure 1. Single-crystal X-ray structure of 2a. Hydrogen atoms are omitted for clarity except polar N-H bonds. Selected bond lengths (A\u030a): N1-C1 1.390(2), N1-C6 1.363(2), N2-N3 1.350(2), N2-C4 1.372(2), N3-C5 1.327(2), N4-N2 1.438(2). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 966, 771, 1021], "ImageBB": [436, 59, 773, 953]}, "diagram_type": "multiple"}, {"id": 360, "width": 1348, "height": 1220, "file_name": "ol102738b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [178.64, 180.73, 65.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [396.3, 21.9, 255.1, 124.6], "category_id": 1}, {"id": 2, "bbox": [142.3, 19.5, 207.7, 157.2], "category_id": 1}, {"id": 3, "bbox": [485.63, 170.0, 72.0, 51.0], "category_id": 3}, {"id": 4, "bbox": [871.0, 0.0, 339.0, 232.0], "category_id": 1}, {"id": 5, "bbox": [911.0, 178.0, 68.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [0, 6], "products": [7]}], "corefs": [[2, 0], [1, 3], [4, 5]], "caption": "Table 1. Optimization of Conditions on the Model Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 762, 101], "ImageBB": [436, 112, 773, 417]}, "diagram_type": "single"}, {"id": 361, "width": 1352, "height": 2052, "file_name": "op500224x-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [989.0, 358.0, 41.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [872.0, 23.0, 281.0, 312.0], "category_id": 1}, {"id": 2, "bbox": [145.0, 15.0, 239.0, 178.0], "category_id": 1}, {"id": 3, "bbox": [181.0, 357.0, 28.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1160.0, 720.0, 62.0, 54.0], "category_id": 3}, {"id": 5, "bbox": [55.0, 1232.0, 303.0, 288.0], "category_id": 1}, {"id": 6, "bbox": [399.0, 1215.0, 387.0, 294.0], "category_id": 1}, {"id": 7, "bbox": [829.0, 1217.0, 423.0, 299.0], "category_id": 1}, {"id": 8, "bbox": [16.0, 1658.0, 314.0, 252.0], "category_id": 1}, {"id": 9, "bbox": [386.0, 1641.0, 395.0, 303.0], "category_id": 1}, {"id": 10, "bbox": [850.0, 1645.0, 447.0, 407.0], "category_id": 1}, {"id": 11, "bbox": [268.0, 11.0, 42.0, 48.0], "category_id": 3}, {"id": 12, "bbox": [455.0, 718.0, 64.0, 47.0], "category_id": 3}, {"id": 13, "bbox": [48.0, 96.0, 319.0, 254.0], "category_id": 1}, {"id": 14, "bbox": [339.0, 397.0, 298.0, 320.0], "category_id": 1}, {"id": 15, "bbox": [1039.0, 383.0, 299.0, 308.0], "category_id": 1}, {"id": 16, "bbox": [29.0, 815.0, 303.0, 299.0], "category_id": 1}, {"id": 17, "bbox": [418.0, 813.0, 378.0, 316.0], "category_id": 1}, {"id": 18, "bbox": [884.0, 821.0, 424.0, 278.0], "category_id": 1}, {"id": 19, "bbox": [448.0, 1938.0, 284.0, 90.0], "category_id": 3}, {"id": 20, "bbox": [59.0, 1533.0, 286.0, 93.0], "category_id": 3}, {"id": 21, "bbox": [513.0, 1525.0, 172.0, 87.1], "category_id": 3}, {"id": 22, "bbox": [968.0, 1525.0, 174.0, 86.0], "category_id": 3}, {"id": 23, "bbox": [878.0, 1944.0, 176.0, 93.1], "category_id": 3}, {"id": 24, "bbox": [40.0, 1120.0, 286.0, 95.0], "category_id": 3}, {"id": 25, "bbox": [536.0, 1120.0, 157.0, 75.0], "category_id": 3}, {"id": 26, "bbox": [949.0, 1120.0, 290.0, 97.0], "category_id": 3}, {"id": 27, "bbox": [0.0, 1929.0, 330.0, 123.0], "category_id": 3}], "reactions": [{"reactants": [3, 19], "conditions": [0, 10], "products": [2]}, {"reactants": [2], "conditions": [9, 8], "products": [20]}, {"reactants": [20], "conditions": [7, 6], "products": [21]}], "corefs": [[2, 11], [13, 3], [1, 0], [14, 12], [15, 4], [16, 24], [17, 25], [18, 26], [5, 20], [6, 21], [7, 22], [8, 27], [9, 19], [10, 23]], "caption": "Table 6. Thermodynamic protonation and reduction tetrahydropyridine products ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 378, 125], "ImageBB": [82, 131, 420, 644]}, "diagram_type": "multiple"}, {"id": 362, "width": 1352, "height": 488, "file_name": "op5001226-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [38.1, 0.0, 524.9, 424.0], "category_id": 1}, {"id": 1, "bbox": [794.0, 46.0, 513.0, 378.5], "category_id": 1}, {"id": 2, "bbox": [268.0, 398.0, 48.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [1025.0, 398.0, 34.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3], "products": [1]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 1. Screening of Ag(I) catalyst and N\u2212F reagent of decarboxylative \ufb02uorination of 10a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 639, 402, 670], "ImageBB": [82, 510, 420, 632]}, "diagram_type": "single"}, {"id": 363, "width": 1704, "height": 1124, "file_name": "op400278d-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [65.1, 18.1, 217.7, 175.9], "category_id": 1}, {"id": 1, "bbox": [981.0, 0.0, 427.0, 221.0], "category_id": 1}, {"id": 2, "bbox": [603.0, 764.0, 298.0, 76.0], "category_id": 3}, {"id": 3, "bbox": [180.0, 762.0, 265.0, 82.0], "category_id": 3}, {"id": 4, "bbox": [83.0, 199.0, 197.0, 92.0], "category_id": 3}, {"id": 5, "bbox": [332.0, 203.0, 189.0, 90.0], "category_id": 3}, {"id": 6, "bbox": [1176.0, 203.0, 68.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [532.45, 311.04, 429.55, 413.96], "category_id": 1}, {"id": 8, "bbox": [82.5, 308.5, 429.5, 432.0], "category_id": 1}, {"id": 9, "bbox": [1113.97, 760.0, 161.0, 59.0], "category_id": 3}, {"id": 10, "bbox": [979.47, 313.07, 430.93, 407.43], "category_id": 1}, {"id": 11, "bbox": [309.51, 12.09, 248.61, 191.35], "category_id": 1}], "reactions": [{"reactants": [0, 13], "conditions": [2, 1], "products": [3]}], "corefs": [[0, 4], [11, 5], [1, 6], [8, 3], [7, 2], [10, 9]], "caption": "Table 9. Pyridine optimization of the IPentCl-Pd-based pre- catalysts in room temperature aryl aminations ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 797, 782, 830], "ImageBB": [433, 846, 859, 1127]}, "diagram_type": "single"}, {"id": 364, "width": 1352, "height": 976, "file_name": "op400278d-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [381.0, 237.0, 247.8, 51.2], "category_id": 3}, {"id": 1, "bbox": [196.0, 830.2, 357.6, 103.5], "category_id": 3}, {"id": 2, "bbox": [924.0, 787.0, 150.7, 44.8], "category_id": 3}, {"id": 3, "bbox": [719.0, 461.0, 531.0, 316.0], "category_id": 1}, {"id": 4, "bbox": [21.0, 34.0, 171.0, 194.0], "category_id": 1}, {"id": 5, "bbox": [214.0, 17.0, 525.0, 216.0], "category_id": 1}, {"id": 6, "bbox": [812.0, 0.0, 537.0, 312.0], "category_id": 1}, {"id": 7, "bbox": [107.0, 433.0, 533.0, 386.0], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [3], "products": [9]}], "corefs": [[5, 0], [7, 1], [3, 2]], "caption": "Table 8. Formation of asymmetric triarylamines with Pd- PEPPSI-IPentCl (84) using a diarylamine precursor ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 596, 404, 627], "ImageBB": [82, 633, 420, 877]}, "diagram_type": "single"}, {"id": 365, "width": 2820, "height": 1632, "file_name": "op400269b-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1853.0, 1268.0, 119.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [1538.0, 441.0, 820.0, 551.0], "category_id": 1}, {"id": 2, "bbox": [552.0, 520.0, 753.0, 407.0], "category_id": 1}, {"id": 3, "bbox": [463.0, 988.0, 869.0, 336.0], "category_id": 1}, {"id": 4, "bbox": [1466.0, 964.0, 855.0, 360.0], "category_id": 1}, {"id": 5, "bbox": [1106.0, 1351.0, 445.0, 277.0], "category_id": 1}, {"id": 6, "bbox": [1934.0, 340.0, 135.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [1010.0, 337.0, 48.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [495.0, 337.0, 108.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [1286.0, 1589.0, 55.0, 32.0], "category_id": 3}, {"id": 10, "bbox": [882.0, 1269.0, 46.0, 46.0], "category_id": 3}, {"id": 11, "bbox": [881.0, 870.0, 49.0, 40.0], "category_id": 3}, {"id": 12, "bbox": [1870.0, 870.0, 54.0, 58.0], "category_id": 3}, {"id": 13, "bbox": [1534.0, 3.0, 772.0, 286.9], "category_id": 1}, {"id": 14, "bbox": [769.75, 17.38, 511.25, 254.72], "category_id": 1}, {"id": 15, "bbox": [361.0, 7.3, 366.0, 269.7], "category_id": 1}], "reactions": [{"reactants": [19, 18], "conditions": [8, 9], "products": [17, 6]}], "corefs": [[15, 8], [14, 7], [13, 6], [2, 11], [1, 12], [3, 10], [4, 0], [5, 9]], "caption": "Figure 2. Impurities derived from CDMT-mediated coupling of 2 and 4.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 533, 437, 547], "ImageBB": [82, 116, 787, 524]}, "diagram_type": "single"}, {"id": 366, "width": 2820, "height": 2272, "file_name": "op300341n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.2, 79.1, 199.6, 128.7], "category_id": 1}, {"id": 1, "bbox": [976.4, 96.1, 855.0, 269.7], "category_id": 1}, {"id": 2, "bbox": [2296.4, 293.1, 148.4, 202.8], "category_id": 1}, {"id": 3, "bbox": [2097.6, 0.0, 713.3, 191.2], "category_id": 1}, {"id": 4, "bbox": [14.2, 120.0, 750.8, 205.7], "category_id": 1}, {"id": 5, "bbox": [1461.0, 377.0, 67.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [2461.0, 431.0, 62.0, 48.0], "category_id": 3}, {"id": 7, "bbox": [364.0, 364.0, 63.0, 81.0], "category_id": 3}, {"id": 8, "bbox": [2540.0, 128.0, 44.0, 64.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [0], "products": [1]}, {"reactants": [1], "conditions": [], "products": [6, 5]}], "corefs": [[4, 7], [1, 5], [3, 8], [2, 6]], "caption": "Figure 2. Distillation phase diagrams for chloroacetonitrile, TFA, and 2-butanol.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 693, 471, 707], "ImageBB": [82, 116, 787, 684]}, "diagram_type": "single"}, {"id": 367, "width": 1352, "height": 1340, "file_name": "op300331b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1088.0, 654.0, 59.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [44.0, 0.0, 412.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [53.0, 367.0, 513.0, 241.0], "category_id": 1}, {"id": 3, "bbox": [679.0, 657.0, 64.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [517.0, 376.0, 482.0, 241.0], "category_id": 1}, {"id": 5, "bbox": [966.0, 367.0, 336.0, 244.0], "category_id": 1}, {"id": 6, "bbox": [157.0, 272.0, 55.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [215.0, 657.0, 61.0, 50.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [2, 7, 8]}], "corefs": [[1, 6], [2, 7], [4, 3], [5, 0]], "caption": "Table 2. Screening of reaction conditions for carbonylation of 17 ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 589, 417, 619], "ImageBB": [82, 626, 420, 961]}, "diagram_type": "multiple"}, {"id": 368, "width": 1348, "height": 568, "file_name": "op300235t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [204.0, 395.0, 59.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [1161.0, 392.0, 61.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [46.0, 9.0, 309.0, 391.0], "category_id": 1}, {"id": 3, "bbox": [457.2, 9.0, 339.4, 391.0], "category_id": 1}, {"id": 4, "bbox": [640.0, 395.0, 60.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [951.0, 14.0, 348.0, 381.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "corefs": [[2, 0], [3, 4], [5, 1]], "caption": "Table 3. Halogenation via organometallationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 564, 341, 585], "ImageBB": [82, 591, 419, 733]}, "diagram_type": "single"}, {"id": 369, "width": 1348, "height": 592, "file_name": "op300235t-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [438.0, 444.0, 58.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [985.0, 445.0, 51.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [799.0, 5.0, 524.6, 440.0], "category_id": 1}, {"id": 3, "bbox": [237.2, 0.0, 504.6, 441.9], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [5, 4]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 2. Investigations into electrophilic halogenationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 393, 110], "ImageBB": [82, 116, 419, 264]}, "diagram_type": "single"}, {"id": 370, "width": 3396, "height": 1076, "file_name": "op300216x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [839.0, 835.0, 255.0, 177.0], "category_id": 1}, {"id": 1, "bbox": [1919.0, 827.0, 319.0, 188.0], "category_id": 1}, {"id": 2, "bbox": [1362.0, 829.0, 302.0, 247.0], "category_id": 1}, {"id": 3, "bbox": [2044.9, 408.4, 294.2, 166.8], "category_id": 1}, {"id": 4, "bbox": [1097.0, 822.0, 212.0, 90.0], "category_id": 1}, {"id": 5, "bbox": [2378.0, 887.0, 99.0, 77.0], "category_id": 1}, {"id": 6, "bbox": [1102.0, 403.0, 201.0, 74.0], "category_id": 1}, {"id": 7, "bbox": [1344.1, 408.7, 201.7, 159.6], "category_id": 1}, {"id": 8, "bbox": [854.0, 413.6, 232.3, 162.4], "category_id": 1}, {"id": 9, "bbox": [1589.0, 450.0, 206.0, 88.0], "category_id": 1}, {"id": 10, "bbox": [2439.0, 457.0, 99.0, 73.0], "category_id": 1}, {"id": 11, "bbox": [976.0, 697.0, 68.0, 77.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6], "products": [7, 9]}, {"reactants": [7, 9], "conditions": [], "products": [3, 10]}, {"reactants": [3, 10], "conditions": [], "products": [7, 9]}, {"reactants": [7, 9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}, {"reactants": [0], "conditions": [4], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}, {"reactants": [2], "conditions": [], "products": [1, 5]}, {"reactants": [1, 5], "conditions": [], "products": [2]}], "corefs": [], "caption": "Figure 1. Potential reaction pathways associated with the formation of the sulfonate ester MMS.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 300, 551, 314], "ImageBB": [10, 22, 859, 291]}, "diagram_type": "tree"}, {"id": 371, "width": 2820, "height": 316, "file_name": "op3001355-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1028.0, 0.0, 313.0, 199.0], "category_id": 1}, {"id": 1, "bbox": [402.75, 221.87, 39.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [2286.0, 227.0, 31.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [1911.0, 227.0, 52.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1158.0, 226.0, 38.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [1513.0, 227.0, 51.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [2225.63, 14.0, 237.27, 190.1], "category_id": 1}, {"id": 7, "bbox": [1456.8, 6.3, 230.5, 198.2], "category_id": 1}, {"id": 8, "bbox": [1773.0, 0.0, 317.4, 212.6], "category_id": 1}, {"id": 9, "bbox": [355.0, 0.0, 229.4, 193.5], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [7, 6], "products": [0, 9, 10, 8]}], "corefs": [[9, 1], [0, 4], [7, 5], [8, 3], [6, 2]], "caption": "Table 2. Reaction conditions and the results for selective bromination of compound 7 to 8", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 463, 596, 478], "ImageBB": [82, 377, 787, 456]}, "diagram_type": "single"}, {"id": 372, "width": 1348, "height": 440, "file_name": "op300031r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 4.0, 274.0, 290.0], "category_id": 1}, {"id": 1, "bbox": [653.0, 8.0, 300.0, 279.0], "category_id": 1}, {"id": 2, "bbox": [972.0, 9.0, 305.0, 281.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 7], "products": [3, 6]}], "corefs": [], "caption": "Table 1. Screening of MeMgBr Addition to Cyclobutanone Substrates ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 782, 125], "ImageBB": [449, 131, 786, 241]}, "diagram_type": "single"}, {"id": 373, "width": 1344, "height": 988, "file_name": "op200174k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [29.3, 66.6, 213.7, 341.8], "category_id": 1}, {"id": 1, "bbox": [258.0, 87.6, 203.8, 315.1], "category_id": 1}, {"id": 2, "bbox": [105.0, 449.0, 70.0, 60.0], "category_id": 3}, {"id": 3, "bbox": [377.0, 454.0, 45.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [903.0, 546.0, 75.0, 55.0], "category_id": 3}, {"id": 5, "bbox": [823.0, 0.0, 299.0, 514.0], "category_id": 1}], "reactions": [{"reactants": [0, 1], "conditions": [2, 4, 10], "products": [11, 9]}], "corefs": [[0, 2], [1, 3], [5, 4]], "caption": "Table 1. Summary of Ir-Catalyzed Reactions (5% Catalyst) in Sealed Reaction Vesselsa ", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 122], "ImageBB": [71, 133, 407, 380]}, "diagram_type": "single"}, {"id": 374, "width": 1356, "height": 1940, "file_name": "ol0703579-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1001.0, 220.0, 60.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [416.0, 214.0, 45.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [148.0, 223.0, 48.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [879.0, 6.0, 360.2, 266.8], "category_id": 1}, {"id": 4, "bbox": [348.2, 85.6, 201.8, 184.2], "category_id": 1}, {"id": 5, "bbox": [43.0, 2.6, 293.0, 208.8], "category_id": 1}], "reactions": [{"reactants": [10, 9], "conditions": [2, 7], "products": [8]}], "corefs": [[5, 2], [4, 1], [3, 0]], "caption": "Table 1. Optimized Catalytic Asymmetric Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 724, 89], "ImageBB": [439, 93, 777, 578]}, "diagram_type": "single"}, {"id": 375, "width": 1348, "height": 992, "file_name": "ol051901l-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1119.0, 265.0, 41.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [149.0, 263.0, 68.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [32.0, 22.0, 340.0, 250.0], "category_id": 1}, {"id": 3, "bbox": [975.9, 3.0, 333.1, 294.0], "category_id": 1}], "reactions": [{"reactants": [3, 7], "conditions": [2, 6], "products": [8]}], "corefs": [[2, 1], [3, 0]], "caption": "Table 3. Reaction of Amidine 3a with Acetal 9a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 75, 698, 89], "ImageBB": [439, 98, 776, 346]}, "diagram_type": "single"}, {"id": 376, "width": 1348, "height": 536, "file_name": "jo0109321-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [711.0, 52.0, 302.0, 144.0], "category_id": 1}, {"id": 1, "bbox": [1055.0, 211.0, 34.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [1010.0, 0.0, 223.0, 199.8], "category_id": 1}, {"id": 3, "bbox": [127.2, 71.0, 214.8, 132.9], "category_id": 1}, {"id": 4, "bbox": [758.1, 203.0, 34.8, 40.9], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [9, 5, 8], "products": [1, 4]}], "corefs": [[0, 4], [2, 1]], "caption": "Table 8. Hydroboration of Styrene with BH3-THF in                       THF ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [450, 62, 763, 89], "ImageBB": [439, 99, 776, 233]}, "diagram_type": "single"}, {"id": 377, "width": 1352, "height": 708, "file_name": "jo0109321-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [5.1, 76.4, 526.9, 78.6], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 5, 7], "products": [2, 3, 6]}], "corefs": [], "caption": "Table 2. Effect of Catalyst on the Hydroboration of          1-Octene with BH3-THF in THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [455, 296, 758, 322], "ImageBB": [439, 330, 777, 507]}, "diagram_type": "single"}, {"id": 378, "width": 1348, "height": 392, "file_name": "acs.orglett.6b00233-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [210.9, 248.0, 50.1, 45.0], "category_id": 3}, {"id": 1, "bbox": [965.0, 10.0, 373.0, 212.8], "category_id": 1}, {"id": 2, "bbox": [14.0, 4.0, 370.0, 227.0], "category_id": 1}, {"id": 3, "bbox": [1181.0, 254.0, 27.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [1, 8, 2, 5], "products": [3]}], "corefs": [[2, 0], [1, 3]], "caption": "Table 3. Reaction with Carbon Nucleophilesa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 548, 336, 569], "ImageBB": [82, 575, 419, 673]}, "diagram_type": "single"}, {"id": 379, "width": 1352, "height": 676, "file_name": "acs.orglett.5b02680-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [470.0, 336.0, 424.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [864.0, 9.0, 399.0, 251.0], "category_id": 1}, {"id": 2, "bbox": [91.0, 29.0, 435.0, 230.0], "category_id": 1}, {"id": 3, "bbox": [629.0, 583.0, 78.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [278.0, 234.0, 77.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [951.0, 233.0, 76.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [5, 0], "products": [2]}, {"reactants": [3], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [6], "products": [2]}], "corefs": [[2, 4], [0, 3], [1, 5]], "caption": "Table 2. Substituents and Yields for DBNs 5a\u2212d", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 716, 347, 731], "ImageBB": [82, 544, 420, 713]}, "diagram_type": "graph"}, {"id": 380, "width": 1348, "height": 440, "file_name": "acs.orglett.5b02279-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [298.0, 88.6, 341.0, 182.4], "category_id": 1}, {"id": 1, "bbox": [1160.0, 288.05, 36.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [10.1, 40.3, 253.9, 271.7], "category_id": 1}, {"id": 3, "bbox": [385.0, 289.0, 37.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [90.0, 298.0, 48.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [915.0, 1.0, 431.0, 319.0], "category_id": 1}], "reactions": [{"reactants": [2, 0], "conditions": [3, 8], "products": [7]}], "corefs": [[2, 4], [0, 3], [5, 1]], "caption": "Table 2. Scope of 2-(Chloromethyl)phenyl-carbamates 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 406, 110], "ImageBB": [82, 116, 419, 226]}, "diagram_type": "single"}, {"id": 381, "width": 1352, "height": 828, "file_name": "acs.orglett.5b01754-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [69.0, 16.0, 329.0, 266.0], "category_id": 1}, {"id": 1, "bbox": [1210.0, 222.0, 69.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [948.0, 5.0, 336.0, 269.0], "category_id": 1}, {"id": 3, "bbox": [312.0, 219.0, 78.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [5]}], "corefs": [[0, 3], [2, 1]], "caption": "Table 1. Proposed Direct Interconversion of BINOL and H8-BINOL-Based Chiral Br\u00f8nsted Acids ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 759, 404, 789], "ImageBB": [82, 796, 420, 1003]}, "diagram_type": "single"}, {"id": 382, "width": 1348, "height": 332, "file_name": "acs.orglett.5b00663-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.0, 4.0, 316.0, 152.0], "category_id": 1}, {"id": 1, "bbox": [297.0, 151.0, 48.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [960.0, 149.0, 40.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [199.0, 54.0, 281.0, 103.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "corefs": [[3, 1], [0, 2]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 366, 109], "ImageBB": [82, 116, 419, 199]}, "diagram_type": "single"}, {"id": 383, "width": 1352, "height": 432, "file_name": "acs.oprd.6b00180-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [135.94, 209.94, 38.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [1215.0, 210.2, 45.0, 50.8], "category_id": 3}, {"id": 2, "bbox": [362.2, 78.3, 246.8, 133.7], "category_id": 1}, {"id": 3, "bbox": [0.0, 61.3, 267.0, 157.7], "category_id": 1}, {"id": 4, "bbox": [1014.4, 7.1, 335.6, 218.9], "category_id": 1}], "reactions": [{"reactants": [5, 3], "conditions": [2, 4], "products": [6]}], "corefs": [[3, 0], [4, 1]], "caption": "Table 7. E\ufb00ect of Palladium Catalysts on the 100 mL Scale Suzuki Reaction of 4-Bromoaniline (2) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 327, 417, 372], "ImageBB": [82, 378, 420, 486]}, "diagram_type": "single"}, {"id": 384, "width": 2816, "height": 740, "file_name": "acs.oprd.6b00128-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1567.9, 0.0, 391.1, 368.9], "category_id": 1}, {"id": 1, "bbox": [976.0, 48.0, 193.5, 262.5], "category_id": 1}, {"id": 2, "bbox": [555.2, 6.9, 382.6, 285.1], "category_id": 1}, {"id": 3, "bbox": [739.4, 234.8, 50.6, 50.4], "category_id": 3}], "reactions": [{"reactants": [6, 5], "conditions": [4, 2], "products": [1]}], "corefs": [[2, 3]], "caption": "Table 2. PdCl2(dppf) Facilitates Coupling Reactions on a Small Scalea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 807, 481, 829], "ImageBB": [82, 834, 786, 1019]}, "diagram_type": "single"}, {"id": 385, "width": 1356, "height": 416, "file_name": "acs.oprd.6b00095-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1064.0, 38.0, 205.0, 306.0], "category_id": 1}, {"id": 1, "bbox": [361.3, 39.5, 209.7, 311.5], "category_id": 1}, {"id": 2, "bbox": [4.0, 42.0, 213.0, 308.0], "category_id": 1}, {"id": 3, "bbox": [706.0, 51.0, 207.0, 308.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 1. Catalytic oxidation of glucose to glucaric acid.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 612, 715, 626], "ImageBB": [448, 499, 787, 603]}, "diagram_type": "single"}, {"id": 386, "width": 1352, "height": 516, "file_name": "ol502423k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1024.32, 241.27, 312.08, 51.0], "category_id": 3}, {"id": 1, "bbox": [623.59, 245.14, 250.91, 47.16], "category_id": 3}, {"id": 2, "bbox": [614.36, 5.32, 290.04, 211.68], "category_id": 1}, {"id": 3, "bbox": [1022.45, 3.86, 315.55, 213.14], "category_id": 1}, {"id": 4, "bbox": [248.55, 247.27, 98.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [253.0, 42.1, 102.8, 165.6], "category_id": 1}, {"id": 6, "bbox": [76.32, 245.27, 93.0, 43.0], "category_id": 3}, {"id": 7, "bbox": [10.9, 26.0, 212.1, 209.0], "category_id": 1}], "reactions": [{"reactants": [10, 8], "conditions": [0, 3], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [5]}], "corefs": [[7, 6], [5, 4], [2, 1], [3, 0]], "caption": "Table 1. Preparation of 2-Aminoindoles 4a", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 466, 692, 487], "ImageBB": [449, 493, 787, 622]}, "diagram_type": "single"}, {"id": 387, "width": 1336, "height": 1824, "file_name": "ol501422k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [886.4, 27.4, 391.5, 151.5], "category_id": 1}, {"id": 1, "bbox": [451.84, 44.73, 103.43, 126.93], "category_id": 1}, {"id": 2, "bbox": [2.4, 1014.2, 395.1, 143.3], "category_id": 1}, {"id": 3, "bbox": [868.7, 711.4, 465.0, 154.5], "category_id": 1}, {"id": 4, "bbox": [419.0, 712.1, 436.7, 146.5], "category_id": 1}, {"id": 5, "bbox": [511.3, 1607.2, 348.6, 189.4], "category_id": 1}, {"id": 6, "bbox": [151.7, 225.7, 105.5, 59.6], "category_id": 3}, {"id": 7, "bbox": [64.5, 36.8, 326.1, 144.6], "category_id": 1}, {"id": 8, "bbox": [1045.0, 1174.0, 140.4, 58.9], "category_id": 3}, {"id": 9, "bbox": [53.8, 722.1, 344.5, 134.8], "category_id": 1}, {"id": 10, "bbox": [97.0, 877.0, 166.0, 66.9], "category_id": 3}, {"id": 11, "bbox": [550.0, 881.7, 159.0, 66.2], "category_id": 3}, {"id": 12, "bbox": [54.0, 1593.1, 344.3, 147.1], "category_id": 1}, {"id": 13, "bbox": [897.7, 1324.5, 438.3, 150.3], "category_id": 1}, {"id": 14, "bbox": [435.1, 1325.1, 420.3, 149.8], "category_id": 1}, {"id": 15, "bbox": [6.4, 1326.4, 395.1, 148.2], "category_id": 1}, {"id": 16, "bbox": [916.8, 1010.8, 419.2, 149.5], "category_id": 1}, {"id": 17, "bbox": [439.8, 1011.8, 417.1, 150.4], "category_id": 1}, {"id": 18, "bbox": [1166.4, 213.97, 70.52, 63.46], "category_id": 3}, {"id": 19, "bbox": [475.0, 237.0, 71.0, 50.0], "category_id": 3}, {"id": 20, "bbox": [97.0, 1486.0, 159.0, 66.0], "category_id": 3}, {"id": 21, "bbox": [553.0, 1177.0, 149.0, 59.0], "category_id": 3}, {"id": 22, "bbox": [101.0, 1174.0, 140.0, 53.0], "category_id": 3}, {"id": 23, "bbox": [1042.0, 883.0, 153.0, 63.0], "category_id": 3}, {"id": 24, "bbox": [546.0, 1493.0, 163.0, 62.0], "category_id": 3}, {"id": 25, "bbox": [1042.0, 1493.0, 150.0, 59.0], "category_id": 3}, {"id": 26, "bbox": [92.0, 1761.0, 149.0, 60.0], "category_id": 3}, {"id": 27, "bbox": [553.0, 1771.0, 152.0, 53.0], "category_id": 3}], "reactions": [{"reactants": [10, 3], "conditions": [13, 2, 1], "products": [0]}], "corefs": [[7, 6], [1, 19], [0, 18], [9, 10], [4, 11], [3, 23], [2, 22], [17, 21], [16, 8], [15, 20], [14, 24], [13, 25], [12, 26], [5, 27]], "caption": "Table 2. E\ufb00ect of Substituents on the Azaarene Moietya", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 759, 110], "ImageBB": [450, 116, 784, 572]}, "diagram_type": "single"}, {"id": 388, "width": 1352, "height": 1632, "file_name": "ol501085y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [269.0, 1548.0, 340.0, 80.0], "category_id": 3}, {"id": 1, "bbox": [708.0, 1542.0, 371.0, 90.0], "category_id": 3}, {"id": 2, "bbox": [1046.9, 3.0, 303.0, 227.5], "category_id": 1}, {"id": 3, "bbox": [664.72, 1312.21, 465.48, 219.79], "category_id": 1}, {"id": 4, "bbox": [222.9, 1295.59, 402.6, 249.31], "category_id": 1}, {"id": 5, "bbox": [25.49, 216.41, 212.61, 55.59], "category_id": 3}, {"id": 6, "bbox": [0.0, 0.0, 257.1, 230.0], "category_id": 1}], "reactions": [{"reactants": [11, 9], "conditions": [10, 3], "products": [4]}], "corefs": [[6, 5], [4, 0], [3, 1]], "caption": "Table 1. Exploration of E\ufb03cient Asymmetric Nitro-Mannich Catalysis for Isatin-Derived N-Boc Ketimine (1a) ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 365, 417, 397], "ImageBB": [82, 402, 420, 810]}, "diagram_type": "single"}, {"id": 389, "width": 1356, "height": 1428, "file_name": "ol5007604-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [818.28, 12.16, 341.92, 540.54], "category_id": 1}, {"id": 1, "bbox": [307.0, 561.0, 46.8, 49.4], "category_id": 3}, {"id": 2, "bbox": [1003.48, 559.84, 54.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [593.44, 139.83, 200.58, 46.0], "category_id": 1}, {"id": 4, "bbox": [203.0, 5.0, 286.0, 535.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 2, 3], "products": [0]}], "corefs": [[4, 1], [0, 2]], "caption": "Table 1. [2 + 1 + 2 + 1] Cycloaddition on Strained Precursor", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 110], "ImageBB": [448, 116, 787, 473]}, "diagram_type": "single"}, {"id": 390, "width": 1348, "height": 2160, "file_name": "ol402981z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1149.0, 758.0, 46.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [564.0, 759.0, 36.0, 31.0], "category_id": 3}, {"id": 2, "bbox": [854.0, 762.0, 44.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [1020.0, 435.0, 306.0, 324.0], "category_id": 1}, {"id": 4, "bbox": [738.0, 420.0, 282.0, 335.0], "category_id": 1}, {"id": 5, "bbox": [443.0, 405.0, 311.0, 379.0], "category_id": 1}, {"id": 6, "bbox": [875.0, 2.0, 334.0, 407.0], "category_id": 1}, {"id": 7, "bbox": [611.0, 128.0, 188.0, 151.0], "category_id": 1}, {"id": 8, "bbox": [183.0, 115.0, 217.0, 167.0], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [12, 11], "products": [8]}], "corefs": [[5, 1], [4, 2], [3, 0]], "caption": "Table 1. Optimization of the Reaction Conditionsa,f", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 713, 101], "ImageBB": [436, 112, 773, 652]}, "diagram_type": "single"}, {"id": 391, "width": 1348, "height": 1100, "file_name": "ol402871f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1003.0, 140.0, 61.0, 29.0], "category_id": 3}, {"id": 1, "bbox": [546.0, 137.0, 50.0, 34.0], "category_id": 3}, {"id": 2, "bbox": [295.0, 140.0, 42.0, 28.0], "category_id": 3}, {"id": 3, "bbox": [480.0, 20.0, 166.0, 111.0], "category_id": 1}, {"id": 4, "bbox": [195.3, 0.0, 250.8, 151.0], "category_id": 1}, {"id": 5, "bbox": [856.0, 29.0, 299.7, 106.2], "category_id": 1}], "reactions": [{"reactants": [6, 3], "conditions": [5, 4], "products": [8]}], "corefs": [[4, 2], [3, 1], [5, 0]], "caption": "Table 1. Investigation of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 707, 101], "ImageBB": [436, 112, 773, 387]}, "diagram_type": "single"}, {"id": 392, "width": 2816, "height": 1016, "file_name": "ol0348957-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1747.0, 66.9, 217.0, 161.7], "category_id": 1}, {"id": 1, "bbox": [850.5, 65.0, 208.3, 156.0], "category_id": 1}, {"id": 2, "bbox": [1519.4, 7.0, 193.0, 130.6], "category_id": 1}, {"id": 3, "bbox": [1239.6, 38.7, 226.9, 183.6], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [1]}], "corefs": [], "caption": "Table 4. Key Experiments from CNRS Group Using 1 Equiv of Synthetic Aliphatic Fluoroketones", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 777, 591, 790], "ImageBB": [73, 799, 777, 1053]}, "diagram_type": "single"}, {"id": 393, "width": 1352, "height": 396, "file_name": "ol034469l-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1033.0, 159.1, 190.0, 218.0], "category_id": 1}, {"id": 1, "bbox": [133.0, 139.0, 185.0, 257.0], "category_id": 1}, {"id": 2, "bbox": [524.4, 200.1, 288.6, 136.4], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 2. Model for diastereoselectivity.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 868, 654, 881], "ImageBB": [439, 757, 777, 856]}, "diagram_type": "single"}, {"id": 394, "width": 1344, "height": 968, "file_name": "ol015948s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [117.1, 39.4, 147.6, 311.8], "category_id": 1}, {"id": 1, "bbox": [1007.1, 6.0, 220.9, 379.2], "category_id": 1}, {"id": 2, "bbox": [381.1, 109.2, 139.9, 169.7], "category_id": 1}], "reactions": [{"reactants": [3, 5], "conditions": [0, 2], "products": [4]}], "corefs": [], "caption": "Table 3. Direct Reductive Amination Using Alkylaminesa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 195, 381, 209], "ImageBB": [74, 220, 410, 462]}, "diagram_type": "single"}, {"id": 395, "width": 1348, "height": 1100, "file_name": "ol006129v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1059.0, 212.0, 59.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [885.0, 1.0, 407.0, 221.0], "category_id": 1}, {"id": 2, "bbox": [64.0, 21.0, 409.0, 181.0], "category_id": 1}, {"id": 3, "bbox": [227.0, 212.0, 53.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [0, 3], "products": [4]}], "corefs": [[2, 3], [1, 0]], "caption": "Table 1. Oxygen Atom Transfer from Oxidoiodane 2 to Unsaturated Diketone 3aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 268, 737, 296], "ImageBB": [439, 306, 776, 581]}, "diagram_type": "single"}, {"id": 396, "width": 1352, "height": 656, "file_name": "jo990938e-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [127.0, 13.0, 286.0, 222.0], "category_id": 1}, {"id": 1, "bbox": [1035.92, 183.22, 115.22, 48.94], "category_id": 3}, {"id": 2, "bbox": [735.14, 182.2, 120.31, 40.79], "category_id": 3}, {"id": 3, "bbox": [547.53, 46.6, 38.74, 43.84], "category_id": 3}, {"id": 4, "bbox": [471.7, 1.0, 130.3, 113.1], "category_id": 1}, {"id": 5, "bbox": [917.8, 16.0, 305.1, 207.7], "category_id": 1}, {"id": 6, "bbox": [633.0, 13.0, 297.0, 213.8], "category_id": 1}, {"id": 7, "bbox": [266.0, 185.0, 47.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [10, 7, 2], "products": [9, 8]}], "corefs": [[0, 7], [4, 3], [6, 2], [5, 1]], "caption": "Table 8. Additions of Transient Chiral Allenylindium Reagents from Mesylate 11 to Representative Achiral                      Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 356, 764, 393], "ImageBB": [439, 403, 777, 567]}, "diagram_type": "single"}, {"id": 397, "width": 1344, "height": 748, "file_name": "jo990938e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [572.0, 178.0, 327.0, 177.9], "category_id": 1}, {"id": 1, "bbox": [657.01, 370.92, 134.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [1035.2, 373.0, 59.7, 37.0], "category_id": 3}, {"id": 3, "bbox": [775.1, 6.0, 373.7, 130.0], "category_id": 1}, {"id": 4, "bbox": [836.1, 129.0, 384.9, 233.1], "category_id": 1}, {"id": 5, "bbox": [138.4, 0.0, 242.6, 142.9], "category_id": 1}, {"id": 6, "bbox": [300.4, 181.0, 324.5, 174.0], "category_id": 1}, {"id": 7, "bbox": [357.0, 369.0, 150.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [196.0, 101.0, 38.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [938.0, 108.0, 42.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [3, 11], "products": [7]}, {"reactants": [7], "conditions": [2, 4], "products": [10, 0, 8]}], "corefs": [[5, 8], [3, 9], [6, 7], [0, 1], [4, 2]], "caption": "Table 1. Addition of Allenylmetal Reagents Prepared         from Allenylstannane 2 to Aldehyde 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [84, 64, 399, 89], "ImageBB": [74, 99, 410, 286]}, "diagram_type": "multiple"}, {"id": 398, "width": 1344, "height": 1112, "file_name": "jo961049j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [19.0, 18.0, 277.0, 444.0], "category_id": 1}, {"id": 1, "bbox": [526.0, 20.0, 257.0, 388.0], "category_id": 1}, {"id": 2, "bbox": [993.0, 2.0, 333.0, 414.0], "category_id": 1}, {"id": 3, "bbox": [64.0, 475.0, 198.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [595.0, 473.0, 125.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [1122.0, 479.0, 125.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [6]}], "corefs": [[0, 3], [1, 4], [2, 5]], "caption": "Table 1. Tandem Enyne Allene-Radical Cyclization of                 Substrates 62-67 ", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [79, 49, 402, 74], "ImageBB": [73, 76, 409, 354]}, "diagram_type": "single"}, {"id": 399, "width": 1348, "height": 1072, "file_name": "jo9602433-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [308.0, 646.0, 69.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [734.3, 275.1, 491.6, 370.3], "category_id": 1}, {"id": 2, "bbox": [960.0, 656.0, 66.7, 52.5], "category_id": 3}, {"id": 3, "bbox": [93.2, 259.0, 478.8, 372.4], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [8, 9, 10], "products": [5, 3]}], "corefs": [[3, 0], [1, 2]], "caption": "Table 2. Treatment of (Z)-3 with BTMABr3 or Br2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [451, 670, 742, 683], "ImageBB": [429, 391, 766, 659]}, "diagram_type": "multiple"}, {"id": 400, "width": 1348, "height": 804, "file_name": "jo951899j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.0, 318.0, 184.7, 73.5], "category_id": 3}, {"id": 1, "bbox": [446.0, 313.0, 199.9, 81.1], "category_id": 3}, {"id": 2, "bbox": [1016.6, 0.0, 327.4, 176.8], "category_id": 1}, {"id": 3, "bbox": [482.0, 5.8, 328.0, 169.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 8.0, 289.4, 167.1], "category_id": 1}, {"id": 5, "bbox": [128.0, 207.0, 81.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [665.0, 209.0, 79.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [1150.0, 212.0, 73.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [8, 13], "products": [5]}, {"reactants": [5], "conditions": [3, 2], "products": [4]}], "corefs": [[4, 5], [3, 6], [2, 7], [4, 0], [3, 1]], "caption": "Table 1. Synthesis of N-Protected Serine and Threonine                       MEE Esters ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [430, 370, 763, 395], "ImageBB": [429, 404, 766, 605]}, "diagram_type": "single"}, {"id": 401, "width": 1148, "height": 244, "file_name": "jo800904u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [110.0, 204.0, 57.0, 34.0], "category_id": 3}, {"id": 1, "bbox": [2.0, 5.0, 212.0, 183.0], "category_id": 1}, {"id": 2, "bbox": [855.0, 201.0, 37.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [752.9, 18.7, 273.2, 206.7], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3, 2], "products": [5]}], "corefs": [[1, 0], [3, 2]], "caption": "Figure 1 shows the 1H and 13C NMR spectra of germanium", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [438, 993, 760, 1008], "ImageBB": [450, 922, 737, 983]}, "diagram_type": "single"}, {"id": 402, "width": 1348, "height": 1684, "file_name": "jo502752u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [228.0, 137.0, 39.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [891.0, 1.0, 293.0, 141.0], "category_id": 1}, {"id": 2, "bbox": [168.0, 3.0, 277.0, 135.0], "category_id": 1}, {"id": 3, "bbox": [944.0, 133.0, 42.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [2, 1], "products": [4]}], "corefs": [[2, 0], [1, 3]], "caption": "Table 1. Hydration of Benzonitrilea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 285, 110], "ImageBB": [82, 116, 419, 537]}, "diagram_type": "single"}, {"id": 403, "width": 1352, "height": 1008, "file_name": "jo5026145-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [738.0, 322.0, 89.4, 52.9], "category_id": 3}, {"id": 1, "bbox": [1152.54, 319.3, 84.0, 55.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 23.9, 307.2, 288.0], "category_id": 1}, {"id": 3, "bbox": [591.0, 21.2, 334.5, 296.8], "category_id": 1}, {"id": 4, "bbox": [1062.3, 1.0, 282.7, 286.7], "category_id": 1}, {"id": 5, "bbox": [103.0, 318.0, 71.2, 55.6], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [2, 0], "products": [5, 6]}], "corefs": [[2, 5], [3, 0], [4, 1]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 250, 343, 265], "ImageBB": [82, 271, 420, 523]}, "diagram_type": "single"}, {"id": 404, "width": 1352, "height": 496, "file_name": "jo501913z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 34.0, 184.0, 212.0], "category_id": 1}, {"id": 1, "bbox": [360.0, 0.0, 140.0, 247.0], "category_id": 1}, {"id": 2, "bbox": [918.0, 16.0, 432.0, 216.0], "category_id": 1}, {"id": 3, "bbox": [1105.0, 298.0, 60.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [389.0, 299.0, 62.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [34.0, 299.0, 55.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [1, 2], "conditions": [6, 4, 9], "products": [3]}], "corefs": [[0, 5], [1, 4], [2, 3]], "caption": "Table 3. Claisen\u2212Schmidt Condensation of Acetophenone and Benzaldehyde ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 411, 202], "ImageBB": [82, 208, 420, 332]}, "diagram_type": "single"}, {"id": 405, "width": 2820, "height": 3068, "file_name": "jo501180a-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1238.0, 1067.0, 333.0, 135.0], "category_id": 1}, {"id": 1, "bbox": [1000.0, 1682.0, 668.0, 510.0], "category_id": 1}, {"id": 2, "bbox": [1021.0, 2240.0, 592.0, 552.0], "category_id": 1}, {"id": 3, "bbox": [1586.0, 804.0, 844.0, 810.0], "category_id": 1}, {"id": 4, "bbox": [1896.0, 1396.0, 65.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [388.0, 225.0, 841.0, 353.0], "category_id": 1}, {"id": 6, "bbox": [1594.0, 2.0, 828.0, 802.0], "category_id": 1}, {"id": 7, "bbox": [1248.0, 2043.0, 71.0, 57.0], "category_id": 3}, {"id": 8, "bbox": [1261.0, 2614.0, 63.0, 63.0], "category_id": 3}, {"id": 9, "bbox": [1911.0, 568.0, 50.0, 63.0], "category_id": 3}, {"id": 10, "bbox": [1251.0, 246.0, 322.0, 133.0], "category_id": 1}, {"id": 11, "bbox": [786.0, 1402.0, 41.0, 57.0], "category_id": 3}, {"id": 12, "bbox": [386.0, 1033.0, 836.0, 350.0], "category_id": 1}, {"id": 13, "bbox": [793.0, 599.0, 45.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [15, 2, 1, 13], "products": [10]}, {"reactants": [17], "conditions": [3, 0, 9], "products": [6]}], "corefs": [[5, 13], [6, 9], [12, 11], [3, 4], [1, 7], [2, 8]], "caption": "Figure 3. 1H NMR spectra (aliphatic region) of compounds 10 and 9 in CDCl3.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 890, 476, 907], "ImageBB": [82, 116, 787, 883]}, "diagram_type": "multiple"}, {"id": 406, "width": 3396, "height": 1248, "file_name": "jo501006u-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1061.0, 382.0, 302.0, 85.0], "category_id": 1}, {"id": 1, "bbox": [2422.0, 376.88, 247.0, 85.0], "category_id": 1}, {"id": 2, "bbox": [2011.0, 377.12, 316.0, 91.0], "category_id": 1}, {"id": 3, "bbox": [732.0, 385.0, 262.0, 82.0], "category_id": 1}], "reactions": [{"reactants": [3, 0], "conditions": [5, 4], "products": [2, 1]}], "corefs": [], "caption": "Figure 2. Time-courses of coupling product (a) and reduced product (b) in the reaction of n-NonBr with n-BuMgCl with 25 mol ppm of CuCl2 and 100 mol % (\u25c6), 50 mol % (\u25a0), 25 mol % (\u25b2), 5 mol % (\u25cf), or 0 mol % (\u25c7) of phenylpropyne. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 343, 784, 371], "ImageBB": [10, 22, 859, 334]}, "diagram_type": "single"}, {"id": 407, "width": 2740, "height": 588, "file_name": "jo4027148-Figure-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1322.0, 22.0, 328.0, 206.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 67.0, 496.0, 429.0], "category_id": 1}, {"id": 2, "bbox": [2630.0, 389.0, 48.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [1833.0, 490.0, 65.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1038.0, 538.0, 56.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [117.0, 523.0, 255.0, 64.0], "category_id": 3}, {"id": 6, "bbox": [1686.0, 76.0, 373.0, 373.0], "category_id": 1}, {"id": 7, "bbox": [2510.3, 173.3, 229.7, 184.6], "category_id": 1}, {"id": 8, "bbox": [786.7, 41.0, 513.3, 466.0], "category_id": 1}, {"id": 9, "bbox": [2164.8, 10.0, 243.2, 224.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [0, 2], "products": [8]}, {"reactants": [8], "conditions": [11, 3], "products": [9]}], "corefs": [[1, 5], [8, 4], [6, 3], [7, 2]], "caption": "Figure 6. Retrosynthesis of dictazole A (5) employing C\u2212H arylation and an Ugi reaction.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 702, 525, 716], "ImageBB": [92, 546, 777, 693]}, "diagram_type": "single"}, {"id": 408, "width": 1348, "height": 500, "file_name": "jo4014707-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1034.0, 28.0, 257.0, 253.0], "category_id": 1}, {"id": 1, "bbox": [115.0, 307.0, 36.9, 41.0], "category_id": 3}, {"id": 2, "bbox": [60.05, 38.0, 166.0, 244.0], "category_id": 1}, {"id": 3, "bbox": [1111.0, 304.0, 96.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [3, 7], "conditions": [8, 5], "products": [0]}], "corefs": [[2, 1], [0, 3]], "caption": "Table 4. Asymmetric 1,4-Addition of Arylboronic Acids (2) to N-R-maleimide (6)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 126], "ImageBB": [449, 131, 786, 256]}, "diagram_type": "single"}, {"id": 409, "width": 2820, "height": 1680, "file_name": "jo400755q-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [580.0, 1014.0, 391.0, 427.0], "category_id": 1}, {"id": 1, "bbox": [727.0, 0.0, 330.0, 317.0], "category_id": 1}, {"id": 2, "bbox": [1873.0, 401.0, 412.0, 447.0], "category_id": 1}, {"id": 3, "bbox": [1441.0, 427.5, 417.0, 420.5], "category_id": 1}, {"id": 4, "bbox": [1384.0, 0.0, 332.2, 311.7], "category_id": 1}, {"id": 5, "bbox": [542.3, 420.3, 355.4, 417.7], "category_id": 1}, {"id": 6, "bbox": [920.3, 416.0, 484.2, 458.0], "category_id": 1}, {"id": 7, "bbox": [1799.0, 1030.8, 481.7, 315.7], "category_id": 1}, {"id": 8, "bbox": [1221.3, 992.0, 298.7, 437.5], "category_id": 1}, {"id": 9, "bbox": [770.0, 304.0, 194.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [1507.0, 304.0, 95.0, 53.0], "category_id": 3}, {"id": 11, "bbox": [1976.0, 867.0, 277.0, 73.0], "category_id": 3}, {"id": 12, "bbox": [1531.0, 863.0, 256.0, 68.0], "category_id": 3}, {"id": 13, "bbox": [1054.0, 874.0, 259.0, 60.0], "category_id": 3}, {"id": 14, "bbox": [603.0, 871.0, 255.0, 60.0], "category_id": 3}, {"id": 15, "bbox": [663.0, 1448.0, 254.0, 70.0], "category_id": 3}, {"id": 16, "bbox": [1223.0, 1450.0, 242.0, 66.0], "category_id": 3}, {"id": 17, "bbox": [1802.0, 1443.0, 263.0, 69.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [8]}], "corefs": [[1, 9], [4, 10], [5, 14], [6, 13], [3, 12], [2, 11], [0, 15], [8, 16], [7, 17]], "caption": "Table 4. Ortho-Iodination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 517, 111], "ImageBB": [82, 116, 787, 536]}, "diagram_type": "single"}, {"id": 410, "width": 1348, "height": 476, "file_name": "jo400501k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [544.0, 41.3, 199.0, 138.7], "category_id": 1}, {"id": 1, "bbox": [272.0, 105.3, 253.0, 169.5], "category_id": 1}, {"id": 2, "bbox": [772.0, 5.0, 302.8, 372.1], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Preparation of Chiral Diaminesa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 317, 110], "ImageBB": [82, 116, 419, 235]}, "diagram_type": "single"}, {"id": 411, "width": 2820, "height": 1336, "file_name": "jo202324f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1698.0, 15.0, 252.0, 149.0], "category_id": 1}, {"id": 1, "bbox": [856.0, 0.0, 351.0, 173.0], "category_id": 1}, {"id": 2, "bbox": [1189.0, 929.0, 286.0, 292.0], "category_id": 1}, {"id": 3, "bbox": [1824.0, 931.0, 269.0, 301.0], "category_id": 1}, {"id": 4, "bbox": [1662.0, 278.0, 495.0, 484.0], "category_id": 1}, {"id": 5, "bbox": [787.0, 938.0, 251.0, 294.0], "category_id": 1}, {"id": 6, "bbox": [1324.0, 45.0, 57.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [1790.0, 34.0, 48.0, 48.0], "category_id": 3}, {"id": 8, "bbox": [1267.0, 1180.0, 50.0, 36.0], "category_id": 3}, {"id": 9, "bbox": [1209.6, 2.0, 443.9, 390.4], "category_id": 1}, {"id": 10, "bbox": [658.5, 372.1, 535.5, 387.9], "category_id": 1}], "reactions": [{"reactants": [23], "conditions": [1, 10, 11], "products": [24]}, {"reactants": [23], "conditions": [0, 25, 22], "products": [7]}, {"reactants": [24], "conditions": [3], "products": [18]}, {"reactants": [7], "conditions": [16], "products": [6]}, {"reactants": [6], "conditions": [15, 14], "products": [5]}], "corefs": [[9, 6], [0, 7], [2, 8]], "caption": "Table 1. Condition Optimization for the Enantioselective Cascade [4 + 1] Annulation/Rearrangement Reactiona", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 450, 718, 471], "ImageBB": [82, 116, 787, 450]}, "diagram_type": "tree"}, {"id": 412, "width": 2808, "height": 852, "file_name": "jo201056f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1666.66, 235.34, 108.0, 55.06], "category_id": 3}, {"id": 1, "bbox": [883.13, 305.22, 105.88, 59.3], "category_id": 3}, {"id": 2, "bbox": [1664.54, 622.87, 103.77, 59.29], "category_id": 3}, {"id": 3, "bbox": [1589.2, 384.2, 461.2, 328.2], "category_id": 1}, {"id": 4, "bbox": [1583.7, 6.0, 465.5, 319.8], "category_id": 1}, {"id": 5, "bbox": [807.9, 57.8, 462.7, 332.0], "category_id": 1}], "reactions": [{"reactants": [8, 10], "conditions": [9], "products": [4, 7, 6]}], "corefs": [[5, 1], [4, 0], [3, 2]], "caption": "Table 2. Yields of BBE-Catalyzed Oxidative Kinetic Resolution via C C Bond Formation", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 650, 568, 665], "ImageBB": [71, 675, 773, 888]}, "diagram_type": "tree"}, {"id": 413, "width": 2072, "height": 636, "file_name": "jo200882k-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [32.0, 392.0, 290.0, 181.0], "category_id": 1}, {"id": 1, "bbox": [159.0, 266.0, 40.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [1219.0, 263.0, 61.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [719.0, 57.0, 286.0, 223.0], "category_id": 1}, {"id": 4, "bbox": [36.0, 45.0, 288.0, 231.0], "category_id": 1}, {"id": 5, "bbox": [1102.0, 52.0, 298.0, 234.0], "category_id": 1}, {"id": 6, "bbox": [1782.0, 42.0, 290.0, 243.0], "category_id": 1}, {"id": 7, "bbox": [1789.0, 390.0, 283.0, 181.0], "category_id": 1}, {"id": 8, "bbox": [1109.0, 390.0, 287.0, 180.0], "category_id": 1}, {"id": 9, "bbox": [728.0, 398.0, 287.0, 160.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [15], "products": [4]}, {"reactants": [4], "conditions": [14], "products": [5]}, {"reactants": [21], "conditions": [17], "products": [22]}, {"reactants": [22], "conditions": [16], "products": [21]}, {"reactants": [1], "conditions": [13], "products": [25]}, {"reactants": [25], "conditions": [12], "products": [1]}, {"reactants": [24], "conditions": [11], "products": [23]}, {"reactants": [23], "conditions": [10], "products": [24]}], "corefs": [[4, 1], [5, 2]], "caption": "Figure 5. Calculated equilibrium constants (Khyd) of the hydration of (a) cis-DHMP 5, (b) trans-DHMP 10, (c) (2R,4S)-DHMF, and (d) (2S,4S)- DHMF. ", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 497, 770, 525], "ImageBB": [163, 324, 681, 483]}, "diagram_type": "multiple"}, {"id": 414, "width": 1344, "height": 496, "file_name": "jo200666z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [994.2, 4.0, 335.8, 310.0], "category_id": 1}, {"id": 1, "bbox": [1062.0, 267.0, 45.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [16.0, 6.0, 320.0, 200.0], "category_id": 1}, {"id": 3, "bbox": [393.0, 123.0, 219.0, 89.0], "category_id": 1}, {"id": 4, "bbox": [138.0, 265.0, 51.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [443.0, 269.0, 48.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [4, 5], "conditions": [6, 2], "products": [0]}], "corefs": [[2, 4], [3, 5], [0, 1]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 87, 700, 108], "ImageBB": [437, 117, 773, 241]}, "diagram_type": "single"}, {"id": 415, "width": 1356, "height": 464, "file_name": "jo200480h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [46.0, 279.0, 47.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [1088.0, 277.0, 39.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [998.0, 2.0, 354.0, 296.0], "category_id": 1}, {"id": 3, "bbox": [2.0, 130.0, 243.0, 147.0], "category_id": 1}, {"id": 4, "bbox": [261.0, 139.0, 383.0, 122.0], "category_id": 1}, {"id": 5, "bbox": [430.0, 273.0, 51.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [6, 7], "conditions": [3, 4], "products": [2]}], "corefs": [[3, 0], [4, 5], [2, 1]], "caption": "Table 1. Optimization of the Heteroannulation Reaction between 4-Acetamido-3-iodopyridine (1) and Diphenylace- tylene (2) ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 764, 137], "ImageBB": [436, 148, 775, 264]}, "diagram_type": "single"}, {"id": 416, "width": 1356, "height": 1376, "file_name": "jo2001534-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [146.0, 415.0, 211.0, 120.0], "category_id": 3}, {"id": 1, "bbox": [562.0, 228.0, 218.0, 112.0], "category_id": 3}, {"id": 2, "bbox": [1000.0, 424.9, 198.2, 101.2], "category_id": 3}, {"id": 3, "bbox": [38.1, 803.5, 192.5, 96.0], "category_id": 3}, {"id": 4, "bbox": [1088.0, 600.1, 264.5, 174.0], "category_id": 1}, {"id": 5, "bbox": [513.1, 606.8, 334.1, 231.4], "category_id": 1}, {"id": 6, "bbox": [582.7, 854.2, 178.1, 101.7], "category_id": 3}, {"id": 7, "bbox": [1129.6, 799.9, 188.6, 100.5], "category_id": 3}, {"id": 8, "bbox": [957.3, 234.8, 279.7, 188.0], "category_id": 1}, {"id": 9, "bbox": [551.5, 1.8, 237.6, 207.1], "category_id": 1}, {"id": 10, "bbox": [5.3, 594.8, 257.5, 183.0], "category_id": 1}, {"id": 11, "bbox": [125.7, 208.5, 256.3, 203.5], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [12], "products": [16]}, {"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [7], "conditions": [13], "products": [17]}, {"reactants": [7], "conditions": [5], "products": [15]}, {"reactants": [7], "conditions": [11], "products": [14]}], "corefs": [[5, 6], [10, 3], [4, 7], [11, 0], [9, 1], [8, 2]], "caption": "Table 6. Comparison of 5-Exo-Trig, 5-Endo-Trig, 6-Exo-Trig, 6-Endo-Trig, and 7-Endo-Trig Ring-Forming Reactions of Anion 1a- and 1d-. (Activation Barriers (Erel TS) and Reaction Energies (Erel Cycle) with Regard to the Global Minimum Structures of the Open-Chain Form (Erel = 0.0 kcal/mol)): SCS-MP2/6-311\u00feG(d,p)//B3LYP/6-31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 366, 771, 487], "ImageBB": [436, 498, 775, 842]}, "diagram_type": "tree"}, {"id": 417, "width": 1352, "height": 640, "file_name": "ol701624y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [71.0, 0.0, 390.0, 129.0], "category_id": 1}, {"id": 1, "bbox": [870.0, 0.0, 409.0, 219.0], "category_id": 1}, {"id": 2, "bbox": [208.0, 154.0, 82.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [1068.0, 233.0, 88.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [2]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 449, 120, 462], "ImageBB": [73, 466, 411, 626]}, "diagram_type": "single"}, {"id": 418, "width": 1348, "height": 564, "file_name": "ol503587n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [275.0, 179.0, 42.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [234.0, 376.0, 37.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [614.0, 192.0, 27.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [151.4, 102.3, 214.6, 113.8], "category_id": 1}, {"id": 4, "bbox": [125.58, 258.84, 188.12, 128.26], "category_id": 1}, {"id": 5, "bbox": [913.0, 136.0, 321.0, 182.7], "category_id": 1}, {"id": 6, "bbox": [1046.0, 301.0, 24.8, 38.1], "category_id": 3}, {"id": 7, "bbox": [505.7, 3.4, 235.3, 209.0], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [8, 9], "products": [6]}], "corefs": [[3, 0], [4, 1], [7, 2], [5, 6]], "caption": "Table 1. Coupling of Aniline and Benzyl Alcohol Using Catalyst 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 396, 125], "ImageBB": [82, 131, 419, 272]}, "diagram_type": "single"}, {"id": 419, "width": 1356, "height": 616, "file_name": "acs.oprd.5b00148-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [953.2, 40.1, 297.4, 205.5], "category_id": 1}, {"id": 1, "bbox": [102.2, 48.2, 301.6, 209.96], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1, 4], "products": [0]}], "corefs": [], "caption": "Figure 2. Stereospeci\ufb01c cross-coupling reactions of benzylic ethers and esters. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 785, 784, 813], "ImageBB": [448, 622, 787, 776]}, "diagram_type": "single"}, {"id": 420, "width": 3396, "height": 1176, "file_name": "acs.oprd.5b00070-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2345.0, 904.0, 265.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [1513.0, 890.0, 285.0, 64.0], "category_id": 3}, {"id": 2, "bbox": [766.0, 897.0, 278.0, 57.0], "category_id": 3}, {"id": 3, "bbox": [639.0, 444.0, 558.0, 452.0], "category_id": 1}, {"id": 4, "bbox": [1389.0, 444.0, 517.0, 438.0], "category_id": 1}, {"id": 5, "bbox": [2188.0, 477.0, 527.0, 398.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [8], "products": [4]}, {"reactants": [4], "conditions": [6], "products": [5]}, {"reactants": [3], "conditions": [9, 10], "products": [5]}], "corefs": [[3, 2], [4, 1], [5, 0]], "caption": "Figure 1. Comparison of the industrially used two-step process (red) and the presented new one-step process (green).", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 325, 660, 339], "ImageBB": [10, 22, 859, 316]}, "diagram_type": "graph"}, {"id": 421, "width": 1348, "height": 448, "file_name": "acs.joc.6b01001-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1090.0, 305.0, 58.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [222.0, 305.0, 58.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [95.3, 126.2, 317.7, 77.8], "category_id": 1}, {"id": 3, "bbox": [982.2, 79.1, 269.4, 169.8], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 2], "products": [6]}], "corefs": [[2, 1], [3, 0]], "caption": "Table 1. Optimization of Reaction Parameters for the Sultone Formationa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 375, 392, 405], "ImageBB": [82, 412, 419, 524]}, "diagram_type": "single"}, {"id": 422, "width": 1352, "height": 420, "file_name": "acs.joc.5b00685-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [993.3, 239.0, 229.7, 33.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 0.0, 437.7, 218.0], "category_id": 1}, {"id": 2, "bbox": [39.8, 239.0, 358.2, 34.2], "category_id": 3}, {"id": 3, "bbox": [860.0, 2.0, 492.0, 243.0], "category_id": 1}, {"id": 4, "bbox": [606.0, 1.0, 215.0, 86.5], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [5, 7, 4, 3], "products": [6]}], "corefs": [[1, 2], [3, 0]], "caption": "Table 2. Optimization of the Rapid Conversion of Thiamine to Fursultiamine by Disul\ufb01de Formation ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 416, 784, 446], "ImageBB": [448, 453, 786, 558]}, "diagram_type": "single"}, {"id": 423, "width": 1348, "height": 524, "file_name": "ja9612413-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [851.09, 5.62, 220.64, 116.48], "category_id": 1}, {"id": 1, "bbox": [265.75, 44.35, 400.54, 66.56], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Table 2. Substituent Group Effects on the Turnover Frequencies for Primary Aminoalkyne Hydroamination/Cyclizationa ", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 761, 75], "ImageBB": [438, 84, 775, 214]}, "diagram_type": "single"}, {"id": 424, "width": 1168, "height": 824, "file_name": "ja960062i-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [51.41, 500.95, 333.73, 110.45], "category_id": 1}, {"id": 1, "bbox": [451.19, 429.71, 655.88, 385.82], "category_id": 1}, {"id": 2, "bbox": [653.2, 5.48, 507.03, 351.8], "category_id": 1}, {"id": 3, "bbox": [5.7, 15.05, 334.78, 341.17], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [5, 1], "products": [3]}, {"reactants": [3], "conditions": [0], "products": [2]}], "corefs": [], "caption": "Figure 4. Scheme of synthesis of oligonucleotide-CHEVP conjugate by the diamine method. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 260, 408, 286], "ImageBB": [95, 50, 387, 256]}, "diagram_type": "multiple"}, {"id": 425, "width": 1352, "height": 344, "file_name": "ja5017206-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1071.65, 43.58, 242.62, 173.29], "category_id": 1}, {"id": 1, "bbox": [528.2, 44.6, 237.53, 169.21], "category_id": 1}, {"id": 2, "bbox": [23.49, 44.6, 233.45, 170.23], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [7, 4], "products": [2]}, {"reactants": [2], "conditions": [0, 8], "products": [1]}], "corefs": [], "caption": "Figure 1. Catalytic sequence for providing optically active \u03b2-amino aldehydes having an alkyl substituent at the \u03b2-position. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 439, 417, 471], "ImageBB": [82, 347, 420, 433]}, "diagram_type": "single"}, {"id": 426, "width": 1232, "height": 560, "file_name": "ja410533y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [299.94, 197.65, 140.44, 131.14], "category_id": 1}, {"id": 1, "bbox": [49.08, 197.65, 145.08, 120.92], "category_id": 1}, {"id": 2, "bbox": [49.08, 4.39, 145.08, 121.86], "category_id": 1}, {"id": 3, "bbox": [325.03, 342.59, 41.95, 32.66], "category_id": 3}, {"id": 4, "bbox": [1001.42, 341.66, 39.16, 32.66], "category_id": 3}, {"id": 5, "bbox": [21.21, 138.18, 201.76, 37.31], "category_id": 3}, {"id": 6, "bbox": [24.92, 325.86, 195.26, 36.38], "category_id": 3}, {"id": 7, "bbox": [3.56, 515.4, 237.99, 37.31], "category_id": 3}, {"id": 8, "bbox": [909.44, 161.41, 198.97, 132.08], "category_id": 1}, {"id": 9, "bbox": [61.16, 386.26, 123.71, 119.99], "category_id": 1}], "reactions": [{"reactants": [2, 0], "conditions": [6, 7], "products": [12]}, {"reactants": [1, 0], "conditions": [6, 7], "products": [12]}, {"reactants": [13, 0], "conditions": [6, 7], "products": [12]}], "corefs": [[2, 5], [1, 6], [9, 7], [0, 3], [8, 4]], "caption": "Table 3. Redox Level-Independent Formation of Lactone 3fa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 417, 110], "ImageBB": [97, 116, 405, 256]}, "diagram_type": "single"}, {"id": 427, "width": 1348, "height": 372, "file_name": "ja408031s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [188.28, 218.4, 72.58, 42.46], "category_id": 3}, {"id": 1, "bbox": [46.25, 131.46, 358.36, 63.98], "category_id": 1}, {"id": 2, "bbox": [1004.31, 227.87, 28.68, 40.74], "category_id": 3}, {"id": 3, "bbox": [770.17, 80.68, 531.39, 112.18], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [4], "products": [5]}], "corefs": [[1, 0], [3, 2]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 343, 110], "ImageBB": [82, 116, 419, 209]}, "diagram_type": "single"}, {"id": 428, "width": 1352, "height": 1188, "file_name": "ja307151x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [896.7, 271.76, 351.59, 42.22], "category_id": 3}, {"id": 1, "bbox": [103.15, 1014.26, 198.46, 40.68], "category_id": 3}, {"id": 2, "bbox": [970.95, 1014.26, 299.0, 42.22], "category_id": 3}, {"id": 3, "bbox": [359.94, 1103.98, 563.51, 79.35], "category_id": 3}, {"id": 4, "bbox": [579.59, 607.44, 264.97, 40.67], "category_id": 3}, {"id": 5, "bbox": [214.53, 271.76, 170.61, 42.22], "category_id": 3}, {"id": 6, "bbox": [78.4, 5.7, 453.69, 234.03], "category_id": 1}, {"id": 7, "bbox": [854.94, 8.79, 424.29, 249.5], "category_id": 1}, {"id": 8, "bbox": [513.08, 353.75, 398.0, 234.03], "category_id": 1}, {"id": 9, "bbox": [8.79, 757.48, 394.91, 235.58], "category_id": 1}, {"id": 10, "bbox": [448.11, 760.58, 401.09, 334.57], "category_id": 1}, {"id": 11, "bbox": [893.61, 755.94, 430.48, 235.57], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [14, 15], "products": [9]}, {"reactants": [8], "conditions": [0], "products": [10]}, {"reactants": [10], "conditions": [7], "products": [12]}, {"reactants": [10], "conditions": [16], "products": [13]}], "corefs": [[6, 5], [7, 0], [8, 4], [9, 1], [10, 3], [11, 2]], "caption": "Figure 1. Formations of monodictyphenone (2) and related xanthones 3\u22126 proceed by a deoxygenation reaction and BV oxidation.2\u22125,7 Chrysophanol (7) has been shown to be a precursor of 4\u22126.4c,d,5d,7 Each deoxygenation site is highlighted by a circle. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 640, 784, 695], "ImageBB": [448, 333, 786, 630]}, "diagram_type": "tree"}, {"id": 429, "width": 1348, "height": 800, "file_name": "ja0547477-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [471.74, 6.1, 706.46, 280.6], "category_id": 1}, {"id": 1, "bbox": [738.09, 275.54, 44.69, 32.5], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4], "products": [0]}], "corefs": [[0, 1]], "caption": "Table 1. Conditions for the Cyclization of Sulfoxide 15 to Tetracycle 42 ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 727, 88], "ImageBB": [439, 88, 776, 288]}, "diagram_type": "single"}, {"id": 430, "width": 1344, "height": 784, "file_name": "ja053368a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1023.23, 33.49, 264.72, 152.62], "category_id": 1}, {"id": 1, "bbox": [212.31, 54.5, 261.22, 107.09], "category_id": 1}, {"id": 2, "bbox": [54.7, 66.8, 105.31, 114.06], "category_id": 1}], "reactions": [{"reactants": [4, 2], "conditions": [5, 0], "products": [1]}], "corefs": [], "caption": "Table 2. DA Reaction of 2,3-Dimethylbutadiene with R-Acyloxyacroleina ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 338, 86], "ImageBB": [74, 85, 410, 281]}, "diagram_type": "single"}, {"id": 431, "width": 1356, "height": 2000, "file_name": "ja030125e-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [30.9, 1799.42, 205.6, 52.28], "category_id": 3}, {"id": 1, "bbox": [219.76, 1876.24, 213.33, 119.03], "category_id": 1}, {"id": 2, "bbox": [30.67, 1902.91, 152.72, 58.18], "category_id": 3}, {"id": 3, "bbox": [37.42, 1097.53, 58.18, 43.87], "category_id": 3}, {"id": 4, "bbox": [7.01, 1242.56, 1283.87, 479.19], "category_id": 1}, {"id": 5, "bbox": [95.89, 617.77, 1227.74, 453.69], "category_id": 1}, {"id": 6, "bbox": [35.08, 5.1, 1311.92, 455.83], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [4], "products": [7]}, {"reactants": [7], "conditions": [0], "products": [6]}], "corefs": [[5, 3], [4, 0], [4, 2]], "caption": "Figure 4. Synthetic scheme for polyamide-acridine conjugates: (i) 4:1 piperidine-DMF, 25 \u00b0C (30 min); (ii) Boc2O, DIEA, NMP, 55 \u00b0C (30 min); (iii) 2,2\u2032-(ethylenedioxy)-bis(ethylamine), 55 \u00b0C (18 h); (iv) 9-chloroacridine or N-(2-(dimethylamino)ethyl)-9-chloroacridine-4-carboxamide, phenol, DIEA, 100 \u00b0C (1 h); (v) 80% TFA/DCM, 0.4 M PhSH, 25 \u00b0C (15 min). ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 568, 409, 631], "ImageBB": [73, 64, 412, 564]}, "diagram_type": "tree"}, {"id": 432, "width": 1344, "height": 504, "file_name": "ja001164i-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [99.45, 76.02, 301.23, 161.25], "category_id": 1}, {"id": 1, "bbox": [1025.54, 76.02, 222.11, 160.23], "category_id": 1}, {"id": 2, "bbox": [230.3, 260.63, 45.61, 33.44], "category_id": 3}, {"id": 3, "bbox": [1052.93, 259.61, 170.38, 41.56], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 1, 2], "products": [4]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 6. Chiral LBA-catalyzed Enantioselective Protonation of 5aa", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 408, 78], "ImageBB": [74, 86, 410, 212]}, "diagram_type": "single"}, {"id": 433, "width": 1348, "height": 800, "file_name": "ja001164i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [150.24, 10.55, 161.65, 188.06], "category_id": 1}, {"id": 1, "bbox": [1135.14, 214.97, 24.96, 33.03], "category_id": 3}, {"id": 2, "bbox": [251.36, 217.27, 24.95, 34.14], "category_id": 3}, {"id": 3, "bbox": [1016.81, 7.11, 180.02, 188.05], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 5], "products": [6]}], "corefs": [[0, 2], [3, 1]], "caption": "Table 1. Enantioselective Protonation of 3a-f by (R)-1\u201aSnCl4a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 753, 78], "ImageBB": [439, 86, 776, 286]}, "diagram_type": "single"}, {"id": 434, "width": 1336, "height": 1540, "file_name": "op980184q-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.9, 1303.9, 521.1, 188.1], "category_id": 1}, {"id": 1, "bbox": [815.0, 1001.0, 512.0, 177.1], "category_id": 1}, {"id": 2, "bbox": [16.0, 1001.0, 499.0, 171.1], "category_id": 1}, {"id": 3, "bbox": [32.8, 523.9, 515.2, 176.2], "category_id": 1}, {"id": 4, "bbox": [188.0, 1500.0, 50.1, 40.0], "category_id": 3}, {"id": 5, "bbox": [199.0, 1203.0, 45.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [559.7, 85.0, 306.3, 154.0], "category_id": 1}, {"id": 7, "bbox": [1070.0, 833.03, 51.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [239.0, 734.93, 47.0, 56.1], "category_id": 3}, {"id": 9, "bbox": [747.9, 1311.9, 562.1, 175.1], "category_id": 1}, {"id": 10, "bbox": [14.9, 75.9, 216.1, 161.2], "category_id": 1}, {"id": 11, "bbox": [669.9, 253.0, 43.1, 57.1], "category_id": 3}, {"id": 12, "bbox": [57.95, 256.03, 57.0, 48.0], "category_id": 3}, {"id": 13, "bbox": [982.0, 1194.0, 54.0, 47.0], "category_id": 3}, {"id": 14, "bbox": [1021.0, 1489.0, 46.0, 51.0], "category_id": 3}, {"id": 15, "bbox": [804.0, 661.0, 532.0, 179.0], "category_id": 1}, {"id": 16, "bbox": [812.0, 421.0, 524.0, 161.0], "category_id": 1}, {"id": 17, "bbox": [997.0, 309.0, 36.0, 48.0], "category_id": 3}, {"id": 18, "bbox": [878.0, 200.0, 300.0, 119.0], "category_id": 1}, {"id": 19, "bbox": [1058.92, 563.58, 43.66, 43.66], "category_id": 3}], "reactions": [{"reactants": [12], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [5, 22], "products": [4]}, {"reactants": [4], "conditions": [18, 23], "products": [20, 19]}, {"reactants": [3], "conditions": [15], "products": [2]}], "corefs": [[10, 12], [6, 11], [18, 17], [3, 8], [16, 19], [15, 7], [2, 5], [1, 13], [0, 4], [9, 14]], "caption": "Figure 1. Compound 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 309, 576, 323], "ImageBB": [440, 333, 774, 718]}, "diagram_type": "multiple"}, {"id": 435, "width": 1356, "height": 712, "file_name": "op900056s-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.2, 625.5, 272.8, 86.5], "category_id": 3}, {"id": 1, "bbox": [9.4, 3.0, 341.2, 173.1], "category_id": 1}, {"id": 2, "bbox": [3.0, 214.0, 419.5, 89.0], "category_id": 3}, {"id": 3, "bbox": [432.5, 310.9, 414.9, 292.8], "category_id": 1}, {"id": 4, "bbox": [800.1, 1.2, 345.9, 174.5], "category_id": 1}, {"id": 5, "bbox": [774.5, 206.0, 581.5, 98.0], "category_id": 3}, {"id": 6, "bbox": [398.17, 76.12, 59.64, 55.97], "category_id": 1}], "reactions": [{"reactants": [1, 8], "conditions": [6, 4], "products": [5]}], "corefs": [[1, 2], [4, 5], [3, 0]], "caption": "Figure 1. DMI hydrogenation catalysed by Ru-BINAP.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 229, 728, 243], "ImageBB": [424, 47, 763, 225]}, "diagram_type": "single"}, {"id": 436, "width": 1412, "height": 1452, "file_name": "op800091p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 913.0, 447.0, 177.0], "category_id": 1}, {"id": 1, "bbox": [1026.0, 1195.0, 327.0, 175.0], "category_id": 1}, {"id": 2, "bbox": [139.0, 1127.0, 66.0, 37.0], "category_id": 3}, {"id": 3, "bbox": [486.0, 1411.0, 50.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [1176.0, 1409.0, 48.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [339.1, 1191.3, 340.8, 182.5], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [7]}, {"reactants": [7], "conditions": [9], "products": [1]}], "corefs": [[0, 2], [5, 3], [1, 4]], "caption": "Table 2. Overall comparison of productivities", "pdf": {"Page": 12, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 311, 60], "ImageBB": [58, 61, 411, 424]}, "diagram_type": "multiple"}, {"id": 437, "width": 1352, "height": 1616, "file_name": "op8000756-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [323.0, 278.0, 40.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [1033.0, 694.0, 56.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [822.0, 341.0, 530.0, 342.0], "category_id": 1}, {"id": 3, "bbox": [108.0, 437.0, 309.0, 294.0], "category_id": 1}, {"id": 4, "bbox": [4.0, 5.0, 635.0, 338.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [0], "products": [2, 5]}], "corefs": [[4, 0], [2, 1]], "caption": "Table 1. SNAr approaches to 1", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 229, 60], "ImageBB": [58, 74, 396, 478]}, "diagram_type": "single"}, {"id": 438, "width": 1312, "height": 636, "file_name": "op700292s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.9, 82.9, 154.5, 546.2], "category_id": 1}, {"id": 1, "bbox": [773.8, 77.9, 382.3, 557.1], "category_id": 1}, {"id": 2, "bbox": [264.9, 226.9, 85.5, 284.1], "category_id": 1}], "reactions": [{"reactants": [0, 3], "conditions": [5, 4], "products": [2, 1]}], "corefs": [], "caption": "Table 2. Chemical yields of 3,6-diphenyl-4-n-butylpyridazine under various experimental conditions ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 216, 759, 243], "ImageBB": [425, 45, 753, 204]}, "diagram_type": "single"}, {"id": 439, "width": 1352, "height": 1560, "file_name": "op700274v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [240.2, 19.0, 278.8, 251.3], "category_id": 1}, {"id": 1, "bbox": [841.8, 19.0, 271.2, 202.9], "category_id": 1}, {"id": 2, "bbox": [937.0, 227.0, 64.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [345.0, 230.0, 54.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [[0, 3], [1, 2]], "caption": "Table 1. N-Detosylationa of N-tosyl-7-azaindole (1a)", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 343, 59], "ImageBB": [58, 60, 396, 450]}, "diagram_type": "single"}, {"id": 440, "width": 1140, "height": 664, "file_name": "op7001485-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [790.0, 343.0, 344.0, 263.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 132.0, 346.0, 270.0], "category_id": 1}, {"id": 2, "bbox": [376.0, 56.0, 400.0, 181.0], "category_id": 1}, {"id": 3, "bbox": [774.0, 5.0, 357.0, 263.0], "category_id": 1}, {"id": 4, "bbox": [423.0, 417.0, 254.0, 170.0], "category_id": 1}, {"id": 5, "bbox": [380.0, 373.0, 53.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [370.0, 258.0, 52.0, 39.0], "category_id": 3}, {"id": 7, "bbox": [1021.0, 267.0, 48.0, 33.0], "category_id": 3}, {"id": 8, "bbox": [153.0, 459.0, 27.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [1035.0, 616.0, 50.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [2, 10, 11, 4], "products": [3, 0]}], "corefs": [[1, 8], [2, 6], [4, 5], [3, 7], [0, 9]], "caption": "Figure 1. Fluorination of steroid with DAST or Deoxofluor. Rings A, B, and C represent the rest of the steroid molecule that remains unchanged in the reaction. ", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 357, 760, 398], "ImageBB": [451, 188, 736, 354]}, "diagram_type": "single"}, {"id": 441, "width": 1336, "height": 880, "file_name": "op0602270-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 232.0, 559.0, 181.7], "category_id": 3}, {"id": 1, "bbox": [734.0, 225.72, 602.0, 189.18], "category_id": 3}, {"id": 2, "bbox": [826.0, 778.0, 455.0, 88.0], "category_id": 3}, {"id": 3, "bbox": [31.0, 785.0, 403.0, 88.6], "category_id": 3}, {"id": 4, "bbox": [13.0, 481.0, 249.0, 300.0], "category_id": 1}, {"id": 5, "bbox": [869.0, 488.0, 337.0, 218.0], "category_id": 1}, {"id": 6, "bbox": [4.0, 1.0, 340.0, 216.0], "category_id": 1}, {"id": 7, "bbox": [863.0, 0.0, 355.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [6, 7], "products": [11]}, {"reactants": [8], "conditions": [4, 5], "products": [9]}], "corefs": [[6, 0], [7, 1], [4, 3], [5, 2]], "caption": "Table 3. Influence of \u03b23-substitution on conversion and enantioselectivity ", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 377, 81], "ImageBB": [75, 89, 409, 309]}, "diagram_type": "multiple"}, {"id": 442, "width": 1288, "height": 1288, "file_name": "op0602270-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [75.0, 229.0, 217.8, 56.0], "category_id": 3}, {"id": 1, "bbox": [933.4, 7.0, 354.6, 217.1], "category_id": 1}, {"id": 2, "bbox": [3.0, 4.5, 348.7, 230.5], "category_id": 1}, {"id": 3, "bbox": [1079.0, 225.0, 70.0, 62.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1, 0], "products": [3]}], "corefs": [[2, 0], [1, 3]], "caption": "Figure 4. Dependency of hydrogen consumption versus reac- tion time. Reactions were carried out under isobaric conditions (1.0 bar) at 25 \u00b0C. [Rh(cod)2]BF4 (0.0072 mmol) and 0.015 mmol ligand 6a were stirred for 10 min under hydrogen atmosphere in 10.0 mL of methanol. Afterwards the substrate (0.72 mmol) was added in 1.0 mL of methanol. The conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 378, 409, 489], "ImageBB": [81, 53, 403, 375]}, "diagram_type": "single"}, {"id": 443, "width": 1316, "height": 1224, "file_name": "op0602270-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [928.0, 9.0, 386.0, 237.8], "category_id": 1}, {"id": 1, "bbox": [78.0, 257.0, 217.8, 60.8], "category_id": 3}, {"id": 2, "bbox": [1082.0, 255.0, 81.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 11.0, 378.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 4], "products": [0]}], "corefs": [[3, 1], [0, 2]], "caption": "Figure 2. Dependency of enantioselectivity versus temperature. Reactions were carried out at corresponding temperature for 1-24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of 2-propanol. Conver- sions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 362, 775, 446], "ImageBB": [444, 53, 773, 359]}, "diagram_type": "single"}, {"id": 444, "width": 824, "height": 128, "file_name": "op060155c-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [613.0, 6.0, 211.0, 122.0], "category_id": 1}, {"id": 1, "bbox": [2.0, 1.0, 222.0, 124.0], "category_id": 1}, {"id": 2, "bbox": [317.0, 0.0, 214.0, 123.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 1. MeTHF production process.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 88, 290, 102], "ImageBB": [139, 53, 345, 85]}, "diagram_type": "single"}, {"id": 445, "width": 1344, "height": 976, "file_name": "op0501242-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [415.2, 0.0, 212.8, 259.1], "category_id": 1}, {"id": 1, "bbox": [103.2, 3.0, 253.8, 190.0], "category_id": 1}, {"id": 2, "bbox": [854.0, 3.0, 392.0, 257.0], "category_id": 1}, {"id": 3, "bbox": [190.0, 298.0, 30.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [509.0, 298.0, 29.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [1038.0, 299.0, 98.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [1, 0], "conditions": [2, 3], "products": [4]}], "corefs": [[1, 3], [0, 4], [2, 5]], "caption": "Table 2. Coupling reactions of primary anilines with 2-fluorobenzoic acids in THF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 444, 364, 472], "ImageBB": [74, 476, 410, 720]}, "diagram_type": "single"}, {"id": 446, "width": 1348, "height": 924, "file_name": "op034181b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1140.9, 234.12, 47.07, 54.49], "category_id": 3}, {"id": 1, "bbox": [285.02, 262.6, 45.83, 56.98], "category_id": 3}, {"id": 2, "bbox": [141.0, 108.0, 334.0, 161.9], "category_id": 1}, {"id": 3, "bbox": [876.0, 0.0, 335.0, 413.0], "category_id": 1}, {"id": 4, "bbox": [527.0, 43.0, 327.0, 156.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 1, 5], "products": [6]}], "corefs": [[2, 1], [3, 0]], "caption": "Table 1. Nucleophilic aromatic substitution of 4-fluoro-3-nitroaniline with phenethylamine ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 697, 81], "ImageBB": [439, 84, 776, 315]}, "diagram_type": "single"}, {"id": 447, "width": 1120, "height": 728, "file_name": "op0340964-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.0, 605.5, 188.0, 117.5], "category_id": 3}, {"id": 1, "bbox": [832.0, 606.5, 187.0, 117.5], "category_id": 3}, {"id": 2, "bbox": [851.6, 332.7, 268.4, 222.7], "category_id": 1}, {"id": 3, "bbox": [4.9, 210.9, 247.2, 171.5], "category_id": 1}, {"id": 4, "bbox": [849.9, 0.0, 264.1, 227.6], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 5], "products": [6, 2]}], "corefs": [[3, 0], [2, 1]], "caption": "Figure 2. Enzymatic and uncatalyzed hydrocyanation of benzaldehyde and 2-chlorobenzaldehyde. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 436, 409, 464], "ImageBB": [102, 251, 382, 433]}, "diagram_type": "tree"}, {"id": 448, "width": 884, "height": 800, "file_name": "op034064g-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [394.1, 6.0, 484.9, 149.4], "category_id": 1}, {"id": 1, "bbox": [138.78, 154.0, 53.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [62.22, 486.86, 51.0, 53.0], "category_id": 3}, {"id": 3, "bbox": [0.0, 570.1, 573.7, 192.9], "category_id": 1}, {"id": 4, "bbox": [1.0, 331.1, 196.8, 142.8], "category_id": 1}, {"id": 5, "bbox": [212.0, 752.0, 62.2, 48.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 15.4, 302.1, 145.9], "category_id": 1}], "reactions": [{"reactants": [9, 2], "conditions": [7, 1, 0], "products": [6]}], "corefs": [[6, 1], [4, 2], [3, 5]], "caption": "Table 4. Alkylation of resorcinol monobenzoate", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 294, 702, 308], "ImageBB": [424, 81, 645, 281]}, "diagram_type": "tree"}, {"id": 449, "width": 1332, "height": 956, "file_name": "op020010f-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.4, 702.0, 697.0, 254.0], "category_id": 1}, {"id": 1, "bbox": [2.5, 2.5, 638.5, 235.0], "category_id": 1}, {"id": 2, "bbox": [0.0, 325.6, 609.4, 255.4], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [7], "products": [4]}, {"reactants": [4], "conditions": [1], "products": [2]}], "corefs": [], "caption": "Figure 1. Biosynthetic pathway from penicillin N to deacetoxycephalosporin C and deacetylcephalosporin C. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 478, 775, 506], "ImageBB": [442, 233, 775, 472]}, "diagram_type": "tree"}, {"id": 450, "width": 1184, "height": 468, "file_name": "op000111i-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [55.7, 236.1, 179.1, 132.7], "category_id": 1}, {"id": 1, "bbox": [58.0, 5.5, 181.5, 131.9], "category_id": 1}, {"id": 2, "bbox": [762.5, 225.0, 184.8, 138.5], "category_id": 1}, {"id": 3, "bbox": [748.9, 7.0, 176.4, 129.3], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [8, 1], "products": [4]}, {"reactants": [0], "conditions": [6], "products": [3]}], "corefs": [], "caption": "Figure 3. Catalysed and uncatalyzed reduction of prochiral ketones by borane. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 174, 409, 202], "ImageBB": [94, 54, 390, 171]}, "diagram_type": "multiple"}, {"id": 451, "width": 1344, "height": 772, "file_name": "op000095p-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [328.0, 8.0, 232.0, 336.0], "category_id": 1}, {"id": 1, "bbox": [788.0, 2.0, 230.0, 343.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2], "products": [1]}], "corefs": [], "caption": "Table 3. Results from Oxidation of Benzaldehydes with the Modified Alkaline Nitrobenzene Method ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 400, 81], "ImageBB": [74, 89, 410, 282]}, "diagram_type": "single"}, {"id": 452, "width": 1352, "height": 1404, "file_name": "ol9913542-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [464.0, 589.0, 85.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [40.0, 594.0, 69.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [1013.0, 1139.0, 160.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [476.0, 1134.0, 84.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [45.0, 1185.0, 65.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [40.0, 901.0, 67.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [1009.0, 859.0, 154.0, 63.0], "category_id": 3}, {"id": 7, "bbox": [478.0, 852.0, 90.0, 58.0], "category_id": 3}, {"id": 8, "bbox": [1016.0, 558.0, 113.0, 60.0], "category_id": 3}, {"id": 9, "bbox": [1007.0, 297.0, 120.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [466.0, 285.0, 78.0, 56.0], "category_id": 3}, {"id": 11, "bbox": [38.0, 331.0, 65.0, 58.0], "category_id": 3}, {"id": 12, "bbox": [541.9, 84.6, 314.0, 282.4], "category_id": 1}, {"id": 13, "bbox": [977.0, 413.2, 340.5, 198.9], "category_id": 1}, {"id": 14, "bbox": [543.6, 370.0, 325.4, 281.5], "category_id": 1}, {"id": 15, "bbox": [6.4, 92.5, 318.5, 273.8], "category_id": 1}, {"id": 16, "bbox": [9.4, 382.0, 336.6, 262.6], "category_id": 1}, {"id": 17, "bbox": [9.4, 657.0, 328.6, 269.0], "category_id": 1}, {"id": 18, "bbox": [457.4, 686.9, 513.8, 212.1], "category_id": 1}, {"id": 19, "bbox": [974.4, 718.0, 367.8, 188.2], "category_id": 1}, {"id": 20, "bbox": [973.0, 997.7, 374.8, 184.6], "category_id": 1}, {"id": 21, "bbox": [455.7, 963.0, 517.1, 215.5], "category_id": 1}, {"id": 22, "bbox": [8.0, 937.0, 323.0, 273.4], "category_id": 1}, {"id": 23, "bbox": [975.9, 131.1, 339.3, 197.4], "category_id": 1}], "reactions": [{"reactants": [32], "conditions": [23, 22], "products": [29]}, {"reactants": [29], "conditions": [0, 28], "products": [41]}, {"reactants": [33], "conditions": [3, 4], "products": [31]}, {"reactants": [31], "conditions": [1, 2], "products": [30]}, {"reactants": [34], "conditions": [5, 6], "products": [35]}, {"reactants": [35], "conditions": [8, 7], "products": [36]}, {"reactants": [39], "conditions": [10, 11], "products": [38]}, {"reactants": [38], "conditions": [9, 12], "products": [37]}], "corefs": [[15, 11], [12, 10], [23, 9], [16, 1], [14, 0], [13, 8], [17, 5], [18, 7], [19, 6], [22, 4], [21, 3], [20, 2]], "caption": "Table 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 593, 483, 606], "ImageBB": [439, 609, 777, 960]}, "diagram_type": "multiple"}, {"id": 453, "width": 1148, "height": 920, "file_name": "ol9909583-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [821.6, 607.1, 160.5, 148.6], "category_id": 1}, {"id": 1, "bbox": [389.0, 144.9, 197.8, 248.0], "category_id": 1}, {"id": 2, "bbox": [0.0, 148.8, 161.6, 221.3], "category_id": 1}, {"id": 3, "bbox": [788.1, 210.3, 310.4, 200.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 561.3, 166.8, 64.5], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [1]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [2], "conditions": [], "products": [4]}], "corefs": [], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 254, 491, 267], "ImageBB": [490, 51, 777, 281]}, "diagram_type": "tree"}, {"id": 454, "width": 1352, "height": 2396, "file_name": "ol802674r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.0, 821.0, 37.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [863.0, 520.0, 32.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [355.0, 482.0, 64.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [228.0, 258.0, 268.0, 214.0], "category_id": 1}, {"id": 4, "bbox": [640.0, 264.0, 477.0, 282.0], "category_id": 1}, {"id": 5, "bbox": [661.0, 566.0, 463.0, 294.0], "category_id": 1}, {"id": 6, "bbox": [221.0, 589.0, 298.0, 224.0], "category_id": 1}, {"id": 7, "bbox": [637.0, 862.0, 469.0, 267.0], "category_id": 1}, {"id": 8, "bbox": [201.0, 894.0, 311.0, 157.0], "category_id": 1}, {"id": 9, "bbox": [619.0, 1197.0, 494.0, 242.0], "category_id": 1}, {"id": 10, "bbox": [201.0, 1184.0, 308.0, 228.0], "category_id": 1}, {"id": 11, "bbox": [592.0, 1460.0, 536.0, 307.0], "category_id": 1}, {"id": 12, "bbox": [210.0, 1507.0, 311.0, 254.0], "category_id": 1}, {"id": 13, "bbox": [830.0, 1765.0, 54.0, 38.0], "category_id": 3}, {"id": 14, "bbox": [339.0, 1773.0, 35.0, 47.0], "category_id": 3}, {"id": 15, "bbox": [846.0, 1452.0, 48.0, 43.0], "category_id": 3}, {"id": 16, "bbox": [345.0, 1418.0, 36.0, 39.0], "category_id": 3}, {"id": 17, "bbox": [885.0, 1124.0, 53.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [353.0, 1061.0, 39.0, 38.0], "category_id": 3}, {"id": 19, "bbox": [876.0, 828.0, 34.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [7, 8], "products": [6]}, {"reactants": [12], "conditions": [10, 9], "products": [11]}, {"reactants": [16], "conditions": [14, 13], "products": [15]}, {"reactants": [20], "conditions": [18, 17], "products": [19]}, {"reactants": [24], "conditions": [22, 21], "products": [23]}], "corefs": [[3, 2], [4, 1], [6, 0], [5, 19], [8, 18], [7, 17], [10, 16], [9, 15], [12, 14], [11, 13]], "caption": "Table 1. Compounds Obtained by Variation of the Carbonyl Component ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 653, 738, 680], "ImageBB": [425, 46, 763, 645]}, "diagram_type": "multiple"}, {"id": 455, "width": 1352, "height": 1064, "file_name": "ol802141g-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [451.0, 127.0, 339.0, 231.0], "category_id": 1}, {"id": 1, "bbox": [1105.0, 168.0, 189.0, 171.0], "category_id": 1}, {"id": 2, "bbox": [875.0, 141.0, 206.0, 217.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [4, 1]}], "corefs": [], "caption": "Figure 1. UV spectra of 6b (solid line, ca. 1 \u00d7 10-4 M in 20% aqueous methanol) and its 300 nm photolysis (dashed lines, every 4 min). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 317, 393, 361], "ImageBB": [58, 47, 396, 313]}, "diagram_type": "single"}, {"id": 456, "width": 1344, "height": 1288, "file_name": "ol702044z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [170.0, 0.0, 282.0, 243.0], "category_id": 1}, {"id": 1, "bbox": [1025.0, 250.0, 43.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [886.0, 30.0, 286.0, 212.0], "category_id": 1}, {"id": 3, "bbox": [242.0, 247.0, 50.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 2], "products": [4]}], "corefs": [[0, 3], [2, 1]], "caption": "Table 1. Reaction Development for the Conversion 1 f 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 298, 387, 314], "ImageBB": [74, 317, 410, 639]}, "diagram_type": "single"}, {"id": 457, "width": 1348, "height": 1000, "file_name": "ol401042b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.0, 191.6, 156.4, 70.6], "category_id": 1}, {"id": 1, "bbox": [907.0, 74.6, 417.7, 215.1], "category_id": 1}, {"id": 2, "bbox": [27.1, 1.0, 329.8, 309.2], "category_id": 1}, {"id": 3, "bbox": [480.0, 282.0, 77.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [1076.0, 276.0, 86.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [158.0, 279.0, 65.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [5, 0], "conditions": [2, 4], "products": [3]}], "corefs": [[2, 5], [0, 3], [1, 4]], "caption": "Table 2. Scope of Aldehydes for Organocatalytic Annulationa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 579, 766, 595], "ImageBB": [436, 606, 773, 856]}, "diagram_type": "single"}, {"id": 458, "width": 1344, "height": 1196, "file_name": "ol400025a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [418.0, 251.0, 54.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [1004.0, 248.0, 67.5, 45.9], "category_id": 3}, {"id": 2, "bbox": [352.1, 48.0, 299.4, 182.3], "category_id": 1}, {"id": 3, "bbox": [924.8, 1.5, 299.1, 241.4], "category_id": 1}, {"id": 4, "bbox": [181.0, 246.6, 59.0, 50.4], "category_id": 3}, {"id": 5, "bbox": [126.3, 104.3, 205.2, 126.9], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [0, 6], "products": [5]}], "corefs": [[5, 4], [2, 0], [3, 1]], "caption": "Table 2. Screening of Squaramide Catalytsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 544, 303, 560], "ImageBB": [71, 571, 407, 870]}, "diagram_type": "single"}, {"id": 459, "width": 1344, "height": 1048, "file_name": "ol400025a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [705.8, 8.1, 247.4, 198.8], "category_id": 1}, {"id": 1, "bbox": [329.1, 44.2, 244.8, 147.3], "category_id": 1}, {"id": 2, "bbox": [128.2, 93.9, 165.1, 101.6], "category_id": 1}, {"id": 3, "bbox": [976.5, 1.4, 245.1, 196.8], "category_id": 1}, {"id": 4, "bbox": [171.0, 214.0, 37.0, 26.0], "category_id": 3}, {"id": 5, "bbox": [1044.0, 204.0, 56.0, 27.0], "category_id": 3}, {"id": 6, "bbox": [775.0, 213.0, 54.0, 27.0], "category_id": 3}, {"id": 7, "bbox": [384.0, 214.0, 36.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [8, 9], "products": [0, 3]}], "corefs": [[2, 4], [1, 7], [0, 6], [3, 5]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 322, 101], "ImageBB": [71, 112, 407, 374]}, "diagram_type": "single"}, {"id": 460, "width": 1344, "height": 608, "file_name": "ol303452r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [780.6, 4.0, 537.4, 307.1], "category_id": 1}, {"id": 1, "bbox": [26.7, 120.2, 532.6, 189.7], "category_id": 1}, {"id": 2, "bbox": [966.0, 338.0, 57.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [174.0, 332.0, 129.0, 59.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Influence of Reaction Conditions on the Synthesis of the N-(Cyanomethyl)ureas 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 287, 765, 314], "ImageBB": [437, 127, 773, 279]}, "diagram_type": "single"}, {"id": 461, "width": 1344, "height": 1948, "file_name": "ol301114z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [508.0, 345.0, 61.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [398.0, 701.0, 141.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [120.0, 695.0, 61.0, 57.0], "category_id": 3}, {"id": 3, "bbox": [1022.0, 699.0, 57.0, 57.0], "category_id": 3}, {"id": 4, "bbox": [1094.0, 320.0, 59.0, 67.0], "category_id": 3}, {"id": 5, "bbox": [820.0, 334.0, 59.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [139.0, 345.0, 43.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [750.6, 67.0, 213.4, 183.4], "category_id": 1}, {"id": 8, "bbox": [1003.5, 426.6, 321.0, 331.3], "category_id": 1}, {"id": 9, "bbox": [399.1, 534.1, 160.4, 111.9], "category_id": 1}, {"id": 10, "bbox": [25.1, 477.0, 258.8, 195.5], "category_id": 1}, {"id": 11, "bbox": [1000.1, 54.6, 264.9, 186.8], "category_id": 1}, {"id": 12, "bbox": [25.5, 3.0, 312.5, 311.4], "category_id": 1}, {"id": 13, "bbox": [374.0, 3.0, 316.0, 310.0], "category_id": 1}], "reactions": [{"reactants": [13, 12], "conditions": [10, 2], "products": [11]}], "corefs": [[12, 6], [13, 0], [7, 5], [11, 4], [10, 2], [9, 1], [8, 3]], "caption": "Table 1. Optimization of the Reaction Conditions for the [4 \u00fe 2] Annulation ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 405, 115], "ImageBB": [71, 126, 407, 613]}, "diagram_type": "single"}, {"id": 462, "width": 1340, "height": 860, "file_name": "ol300387f-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [129.0, 5.0, 164.0, 197.2], "category_id": 1}, {"id": 1, "bbox": [478.0, 6.0, 230.0, 200.1], "category_id": 1}, {"id": 2, "bbox": [522.0, 216.0, 128.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [803.0, 214.0, 83.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [218.97, 210.55, 33.25, 39.89], "category_id": 3}, {"id": 5, "bbox": [736.0, 5.0, 231.0, 200.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [8, 7], "products": [2, 9]}], "corefs": [[0, 4], [1, 2], [5, 3]], "caption": "Table 4. 1,4-Addition of ArZnCl and PhB(OH)2 to Enones 1e,f", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 548, 405, 563], "ImageBB": [72, 573, 407, 788]}, "diagram_type": "single"}, {"id": 463, "width": 1348, "height": 988, "file_name": "ol203001w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [252.0, 340.0, 52.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [1055.0, 330.0, 44.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [110.2, 0.0, 341.5, 360.1], "category_id": 1}, {"id": 3, "bbox": [898.6, 28.9, 336.5, 305.7], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2, 3], "products": [6]}], "corefs": [[2, 0], [3, 1]], "caption": "Table 2. Copper-Catalyzed Reactions of 1b fa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 320, 101], "ImageBB": [71, 112, 408, 359]}, "diagram_type": "single"}, {"id": 464, "width": 1356, "height": 1192, "file_name": "ol202027k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [653.0, 220.0, 24.0, 31.0], "category_id": 3}, {"id": 1, "bbox": [1195.0, 184.0, 20.0, 26.0], "category_id": 3}, {"id": 2, "bbox": [1.0, 72.0, 258.0, 146.0], "category_id": 1}, {"id": 3, "bbox": [329.0, 55.0, 105.0, 30.0], "category_id": 1}, {"id": 4, "bbox": [311.0, 183.0, 123.0, 35.0], "category_id": 1}, {"id": 5, "bbox": [1057.6, 20.8, 285.6, 197.6], "category_id": 1}, {"id": 6, "bbox": [595.0, 4.0, 152.0, 212.0], "category_id": 1}, {"id": 7, "bbox": [814.0, 14.0, 176.0, 184.0], "category_id": 1}, {"id": 8, "bbox": [192.0, 223.0, 40.0, 32.0], "category_id": 3}, {"id": 9, "bbox": [881.0, 225.0, 22.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [2], "products": [7, 8]}, {"reactants": [3, 5], "conditions": [2], "products": [7, 8]}], "corefs": [[2, 8], [6, 0], [7, 9], [5, 1]], "caption": "Table 2. Regioselectivity of the Nitroso Diels Alder Reaction of 1,2-Dihydropyridine 1b ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [436, 126, 775, 424]}, "diagram_type": "single"}, {"id": 465, "width": 1120, "height": 720, "file_name": "ol102784c-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.0, 518.0, 238.0, 99.0], "category_id": 1}, {"id": 1, "bbox": [158.0, 417.0, 259.0, 93.0], "category_id": 1}, {"id": 2, "bbox": [185.0, 309.0, 216.0, 100.0], "category_id": 1}, {"id": 3, "bbox": [239.61, 24.1, 139.95, 123.54], "category_id": 1}, {"id": 4, "bbox": [796.0, 23.5, 321.0, 137.5], "category_id": 1}, {"id": 5, "bbox": [3.0, 17.7, 199.4, 142.13], "category_id": 1}, {"id": 6, "bbox": [506.0, 623.0, 363.0, 89.0], "category_id": 1}, {"id": 7, "bbox": [496.0, 509.0, 376.0, 110.0], "category_id": 1}, {"id": 8, "bbox": [475.0, 408.0, 409.0, 97.0], "category_id": 1}, {"id": 9, "bbox": [521.0, 311.0, 311.0, 91.0], "category_id": 1}, {"id": 10, "bbox": [180.0, 618.0, 233.0, 94.0], "category_id": 1}], "reactions": [{"reactants": [7, 3], "conditions": [8, 5], "products": [6]}], "corefs": [], "caption": "Table 5. Copper-Catalyzed Cross-Coupling Reaction of Different Aryl Iodidesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 493, 713, 520], "ImageBB": [453, 529, 733, 709]}, "diagram_type": "single"}, {"id": 466, "width": 1352, "height": 868, "file_name": "op500224x-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [547.0, 514.0, 276.0, 282.0], "category_id": 1}, {"id": 1, "bbox": [104.0, 595.0, 37.0, 52.0], "category_id": 3}, {"id": 2, "bbox": [637.0, 814.0, 56.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [1163.0, 815.0, 47.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [1169.0, 344.0, 46.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [653.0, 347.0, 38.0, 49.0], "category_id": 3}, {"id": 6, "bbox": [1053.0, 514.9, 293.3, 287.1], "category_id": 1}, {"id": 7, "bbox": [555.29, 44.98, 272.71, 281.12], "category_id": 1}, {"id": 8, "bbox": [1061.8, 47.6, 290.2, 280.4], "category_id": 1}, {"id": 9, "bbox": [0.0, 301.0, 267.3, 281.5], "category_id": 1}], "reactions": [{"reactants": [13], "conditions": [9, 8], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [12]}, {"reactants": [13], "conditions": [15, 7], "products": [1]}, {"reactants": [1], "conditions": [14], "products": [10]}], "corefs": [[9, 1], [7, 5], [8, 4], [0, 2], [6, 3]], "caption": "Figure 3. Piperidines generated via kinetic and thermodynamic iminiums. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 984, 417, 1012], "ImageBB": [82, 758, 420, 975]}, "diagram_type": "tree"}, {"id": 467, "width": 1352, "height": 1536, "file_name": "op400278d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.6, 306.8, 435.9, 373.1], "category_id": 1}, {"id": 1, "bbox": [1004.0, 1.4, 278.0, 222.7], "category_id": 1}, {"id": 2, "bbox": [310.3, 52.4, 187.3, 131.7], "category_id": 1}, {"id": 3, "bbox": [22.6, 19.0, 172.8, 171.3], "category_id": 1}, {"id": 4, "bbox": [45.96, 208.0, 65.89, 51.48], "category_id": 3}, {"id": 5, "bbox": [1145.46, 212.12, 67.94, 45.3], "category_id": 3}, {"id": 6, "bbox": [912.5, 312.9, 435.4, 365.9], "category_id": 1}, {"id": 7, "bbox": [260.06, 206.94, 243.74, 53.26], "category_id": 3}, {"id": 8, "bbox": [909.7, 888.9, 434.1, 417.2], "category_id": 1}, {"id": 9, "bbox": [458.3, 923.9, 437.1, 386.1], "category_id": 1}, {"id": 10, "bbox": [2.0, 891.2, 442.0, 418.8], "category_id": 1}, {"id": 11, "bbox": [464.1, 311.8, 434.2, 367.0], "category_id": 1}, {"id": 12, "bbox": [560.5, 723.6, 226.4, 119.1], "category_id": 3}, {"id": 13, "bbox": [20.0, 724.0, 421.0, 158.0], "category_id": 3}, {"id": 14, "bbox": [926.0, 714.0, 426.0, 142.0], "category_id": 3}, {"id": 15, "bbox": [113.0, 1330.1, 229.0, 130.9], "category_id": 3}, {"id": 16, "bbox": [1026.2, 1335.4, 205.8, 124.1], "category_id": 3}, {"id": 17, "bbox": [457.0, 1329.4, 440.0, 173.7], "category_id": 3}], "reactions": [{"reactants": [3, 2], "conditions": [8, 7], "products": [1]}], "corefs": [[3, 4], [2, 7], [1, 5], [0, 13], [11, 12], [6, 14], [10, 15], [9, 17], [8, 16]], "caption": "Table 2. Optimization of NHC and pyridine ligand sterics in aryl sul\ufb01nations ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 515]}, "diagram_type": "single"}, {"id": 468, "width": 1352, "height": 832, "file_name": "op400278d-Table-c12.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.0, 467.0, 393.0, 204.0], "category_id": 1}, {"id": 1, "bbox": [413.0, 493.0, 446.0, 173.0], "category_id": 1}, {"id": 2, "bbox": [866.0, 491.0, 486.0, 182.0], "category_id": 1}, {"id": 3, "bbox": [223.0, 685.0, 66.0, 38.0], "category_id": 3}, {"id": 4, "bbox": [1095.0, 683.0, 45.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [640.0, 683.0, 47.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [66.0, 0.0, 136.0, 251.0], "category_id": 1}, {"id": 7, "bbox": [884.0, 97.0, 451.0, 182.0], "category_id": 1}, {"id": 8, "bbox": [301.27, 61.0, 152.0, 181.0], "category_id": 1}], "reactions": [{"reactants": [15, 17], "conditions": [14, 13], "products": [16]}], "corefs": [[0, 3], [1, 5], [2, 4]], "caption": "Table 12. Published comparison of Pd-PEPPSI-IPr (2) with Pd-PEPPSI-IPr*OMe (101) under di\ufb00erent reaction conditions ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 480, 784, 525], "ImageBB": [448, 532, 786, 740]}, "diagram_type": "single"}, {"id": 469, "width": 1352, "height": 800, "file_name": "op400055z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 0.0, 326.0, 227.0], "category_id": 1}, {"id": 1, "bbox": [388.0, 118.0, 538.0, 337.0], "category_id": 1}, {"id": 2, "bbox": [901.0, 388.0, 40.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [1164.0, 235.0, 108.0, 62.0], "category_id": 3}, {"id": 4, "bbox": [81.0, 227.0, 115.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [1026.0, 1.0, 323.0, 227.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [7]}], "corefs": [[0, 4], [1, 2], [5, 3]], "caption": "Table 1. Asymmetric hydrogenation of enamides using 9 as catalysta ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 404, 417, 434], "ImageBB": [82, 440, 420, 640]}, "diagram_type": "single"}, {"id": 470, "width": 1352, "height": 1104, "file_name": "op300205j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [950.0, 0.0, 180.7, 157.3], "category_id": 1}, {"id": 1, "bbox": [588.9, 0.0, 187.1, 164.2], "category_id": 1}, {"id": 2, "bbox": [205.0, 3.0, 213.0, 159.2], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [4], "products": [0]}], "corefs": [], "caption": "Figure 1. (1) Reaction of 2-bromopyridine with n-BuLi followed by trapping with MeOH using the \ufb02ow microreactor system with the in- line mixer. (2) Reaction of 2-bromopyridine with n-BuLi followed by trapping with MeOH using the \ufb02ow microreactor system without the in-line mixer. (3) Reaction of 2-bromopyridine with n-BuLi followed by trapping with MeOH using a conventional macro batch system. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 431, 417, 514], "ImageBB": [82, 146, 420, 422]}, "diagram_type": "single"}, {"id": 471, "width": 2820, "height": 1168, "file_name": "op200351g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1868.0, 121.0, 667.0, 328.6], "category_id": 1}, {"id": 1, "bbox": [822.0, 39.0, 254.0, 391.0], "category_id": 1}, {"id": 2, "bbox": [1354.0, 16.0, 268.0, 406.0], "category_id": 1}, {"id": 3, "bbox": [343.0, 14.1, 243.5, 394.9], "category_id": 1}, {"id": 4, "bbox": [1382.0, 424.0, 195.0, 105.0], "category_id": 3}, {"id": 5, "bbox": [337.0, 428.0, 180.0, 95.0], "category_id": 3}, {"id": 6, "bbox": [856.0, 431.0, 186.0, 93.0], "category_id": 3}, {"id": 7, "bbox": [2072.0, 416.0, 186.0, 116.0], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [10, 4], "products": [5]}, {"reactants": [5], "conditions": [11, 2], "products": [6]}, {"reactants": [6], "conditions": [3, 1], "products": [0]}], "corefs": [[3, 5], [1, 6], [2, 4], [0, 7]], "caption": "Table 1. Scale-up results for the synthesis of ketoamides 11 and 1", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 455, 110], "ImageBB": [82, 116, 787, 408]}, "diagram_type": "single"}, {"id": 472, "width": 1344, "height": 968, "file_name": "op100335q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [986.0, 599.0, 176.0, 271.0], "category_id": 1}, {"id": 1, "bbox": [559.0, 578.0, 262.0, 276.0], "category_id": 1}, {"id": 2, "bbox": [90.0, 573.0, 200.0, 311.0], "category_id": 1}, {"id": 3, "bbox": [71.0, 191.0, 337.0, 302.0], "category_id": 1}, {"id": 4, "bbox": [370.0, 245.0, 238.0, 94.0], "category_id": 1}, {"id": 5, "bbox": [622.0, 187.0, 345.0, 289.0], "category_id": 1}, {"id": 6, "bbox": [1040.0, 231.0, 233.0, 92.0], "category_id": 1}, {"id": 7, "bbox": [1142.0, 286.0, 61.0, 60.0], "category_id": 3}, {"id": 8, "bbox": [1043.0, 792.0, 57.0, 59.0], "category_id": 3}, {"id": 9, "bbox": [125.0, 860.0, 52.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [476.0, 304.0, 65.0, 42.0], "category_id": 3}, {"id": 11, "bbox": [806.0, 458.0, 52.0, 41.0], "category_id": 3}, {"id": 12, "bbox": [260.0, 458.0, 56.0, 53.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [14], "products": [13]}, {"reactants": [5], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}], "corefs": [[3, 12], [4, 10], [5, 11], [6, 7], [2, 9], [0, 8]], "caption": "Table 1. E\ufb00ect of acid on the formation of imidazoles 14 and 20a ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 401, 405, 431], "ImageBB": [71, 133, 407, 375]}, "diagram_type": "tree"}, {"id": 473, "width": 1344, "height": 608, "file_name": "ol0619157-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [83.1, 1.0, 320.9, 147.9], "category_id": 1}, {"id": 1, "bbox": [940.0, 5.0, 344.0, 146.9], "category_id": 1}, {"id": 2, "bbox": [219.0, 172.0, 65.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [1036.0, 171.0, 131.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 544, 339, 557], "ImageBB": [74, 562, 410, 714]}, "diagram_type": "single"}, {"id": 474, "width": 1348, "height": 1012, "file_name": "ol051920v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [464.0, 208.0, 54.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [211.0, 190.0, 25.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [1004.0, 185.0, 30.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [932.0, 0.0, 286.0, 182.0], "category_id": 1}, {"id": 4, "bbox": [143.0, 5.0, 227.0, 178.0], "category_id": 1}, {"id": 5, "bbox": [416.0, 50.0, 184.0, 153.0], "category_id": 1}], "reactions": [{"reactants": [6, 8], "conditions": [1, 0], "products": [5]}], "corefs": [[4, 1], [5, 0], [3, 2]], "caption": "Table 2. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with 3-Methylpenta-3,4-dien-2-one 2a (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at Room Temperature ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 768, 120], "ImageBB": [439, 125, 776, 378]}, "diagram_type": "single"}, {"id": 475, "width": 1352, "height": 1116, "file_name": "ol051901l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.5, 1.0, 265.0, 220.5], "category_id": 1}, {"id": 1, "bbox": [71.0, 52.5, 269.0, 163.5], "category_id": 1}, {"id": 2, "bbox": [188.0, 225.0, 38.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [1037.0, 240.0, 205.0, 93.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [3], "products": [0]}, {"reactants": [2, 7], "conditions": [3], "products": [0]}], "corefs": [[1, 2], [0, 3]], "caption": "Table 2. Cyclization of Amidine 3 with Acetal 5 or 7a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 210, 364, 224], "ImageBB": [73, 233, 411, 512]}, "diagram_type": "single"}, {"id": 476, "width": 1352, "height": 848, "file_name": "ol051365x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [473.0, 726.0, 385.0, 122.0], "category_id": 3}, {"id": 1, "bbox": [333.0, 480.0, 602.0, 227.0], "category_id": 1}, {"id": 2, "bbox": [767.0, 141.4, 306.0, 203.6], "category_id": 1}, {"id": 3, "bbox": [285.0, 143.2, 323.8, 209.8], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [7]}], "corefs": [[1, 0]], "caption": "Figure 1. Twisted \u03c0-electron system chromophores.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 887, 713, 900], "ImageBB": [439, 668, 777, 880]}, "diagram_type": "single"}, {"id": 477, "width": 1352, "height": 1056, "file_name": "ol051342i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [39.0, 0.0, 402.0, 221.0], "category_id": 1}, {"id": 1, "bbox": [186.0, 230.0, 58.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [1056.0, 232.0, 47.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [919.0, 1.0, 402.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 0], "products": [6]}], "corefs": [[0, 1], [3, 2]], "caption": "Table 1. Pictet-Spengler Reaction of Thioortho Esters with N-Tosyltryptamines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 460, 758, 488], "ImageBB": [439, 496, 777, 760]}, "diagram_type": "single"}, {"id": 478, "width": 2808, "height": 1160, "file_name": "jo0157425-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [493.0, 407.0, 140.0, 62.0], "category_id": 3}, {"id": 1, "bbox": [1319.0, 446.0, 67.0, 65.0], "category_id": 3}, {"id": 2, "bbox": [1744.0, 448.0, 96.0, 60.0], "category_id": 3}, {"id": 3, "bbox": [2193.0, 446.0, 91.0, 73.0], "category_id": 3}, {"id": 4, "bbox": [387.0, 57.0, 376.0, 308.0], "category_id": 1}, {"id": 5, "bbox": [1147.0, 83.0, 379.0, 295.0], "category_id": 1}, {"id": 6, "bbox": [1591.0, 77.0, 387.0, 312.0], "category_id": 1}, {"id": 7, "bbox": [2040.0, 103.0, 392.0, 307.0], "category_id": 1}, {"id": 8, "bbox": [1029.25, 142.8, 44.47, 52.94], "category_id": 3}, {"id": 9, "bbox": [914.9, 2.0, 117.7, 193.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [10, 11], "products": [6, 7, 8]}], "corefs": [[4, 0], [9, 8], [5, 1], [6, 2], [7, 3]], "caption": "Table 1. Reaction of Enolates of Mandelic Acid Acetal 7 with 2-Cyclopenten-1-one (5)", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [175, 64, 674, 76], "ImageBB": [74, 87, 776, 377]}, "diagram_type": "single"}, {"id": 479, "width": 1332, "height": 1096, "file_name": "jo011082s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [192.0, 559.0, 283.0, 129.9], "category_id": 1}, {"id": 1, "bbox": [392.0, 193.0, 177.0, 128.0], "category_id": 1}, {"id": 2, "bbox": [635.0, 81.0, 283.0, 212.5], "category_id": 1}, {"id": 3, "bbox": [0.0, 95.5, 358.0, 205.5], "category_id": 1}, {"id": 4, "bbox": [25.0, 288.8, 312.0, 183.2], "category_id": 3}, {"id": 5, "bbox": [172.0, 981.0, 49.0, 50.0], "category_id": 3}, {"id": 6, "bbox": [1151.0, 281.0, 48.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [762.0, 295.0, 46.0, 60.0], "category_id": 3}, {"id": 8, "bbox": [611.0, 971.0, 104.0, 60.0], "category_id": 3}, {"id": 9, "bbox": [1049.0, 968.0, 171.0, 61.0], "category_id": 3}, {"id": 10, "bbox": [1077.0, 97.0, 252.0, 195.0], "category_id": 1}, {"id": 11, "bbox": [975.0, 724.0, 279.0, 240.0], "category_id": 1}, {"id": 12, "bbox": [526.0, 724.0, 275.0, 233.0], "category_id": 1}, {"id": 13, "bbox": [42.0, 738.0, 302.0, 243.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [6, 8, 1], "products": [2]}, {"reactants": [2], "conditions": [9], "products": [18]}, {"reactants": [3], "conditions": [5, 4, 0], "products": [21]}, {"reactants": [21], "conditions": [12], "products": [20, 19]}], "corefs": [[3, 4], [2, 7], [10, 6], [13, 5], [12, 8], [11, 9]], "caption": "Table 1. 3,4,6-Trisubstituted 3,4-Dihydropyran-2-ones 6                          and 7 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 348, 403, 373], "ImageBB": [76, 63, 409, 337]}, "diagram_type": "tree"}, {"id": 480, "width": 1348, "height": 620, "file_name": "jo0109321-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [74.0, 48.0, 260.0, 106.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 2, 1], "products": [7, 6, 5]}], "corefs": [], "caption": "Table 3. RhCl3\u201anH2O-Promoted Hydroboration of     Isomeric Octenes with BH3-THF in THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [461, 514, 752, 542], "ImageBB": [439, 552, 776, 707]}, "diagram_type": "single"}, {"id": 481, "width": 1352, "height": 1148, "file_name": "acs.orglett.6b00661-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [660.0, 552.0, 586.0, 446.0], "category_id": 1}, {"id": 1, "bbox": [105.0, 114.0, 384.0, 319.0], "category_id": 1}, {"id": 2, "bbox": [1047.0, 117.0, 203.0, 313.0], "category_id": 1}, {"id": 3, "bbox": [148.7, 551.0, 515.3, 439.0], "category_id": 1}, {"id": 4, "bbox": [733.0, 865.2, 392.5, 115.6], "category_id": 3}, {"id": 5, "bbox": [125.0, 856.0, 905.0, 292.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[3, 5], [0, 4]], "caption": "Figure 1. Gold(I)-catalyzed 6-exo-dig cyclization reaction and structures of gardnerine (1), hydroxygardnerine (2), hydroxygardnu- tine (3), and (E)-16-epi-normacusine B (4). ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 852, 417, 894], "ImageBB": [82, 556, 420, 843]}, "diagram_type": "multiple"}, {"id": 482, "width": 1348, "height": 408, "file_name": "acs.orglett.5b03590-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1085.0, 226.0, 50.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [803.0, 68.0, 162.0, 91.0], "category_id": 1}, {"id": 2, "bbox": [117.1, 12.1, 220.9, 203.9], "category_id": 1}, {"id": 3, "bbox": [630.0, 227.9, 50.0, 36.1], "category_id": 3}, {"id": 4, "bbox": [988.1, 6.0, 246.9, 220.0], "category_id": 1}, {"id": 5, "bbox": [344.0, 104.1, 164.9, 56.9], "category_id": 1}, {"id": 6, "bbox": [222.0, 226.0, 56.1, 41.1], "category_id": 3}, {"id": 7, "bbox": [534.2, 18.1, 249.8, 202.8], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [8, 3], "products": [5]}, {"reactants": [10], "conditions": [4, 0], "products": [7]}], "corefs": [[2, 6], [7, 3], [4, 0]], "caption": "Table 1. Cascades Forming Triazinonesa or Pyridazinones:b Optimization Using \u03b1-Ketocarbazone 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 398, 416, 435], "ImageBB": [82, 440, 419, 542]}, "diagram_type": "single"}, {"id": 483, "width": 1348, "height": 436, "file_name": "acs.orglett.5b02279-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [991.0, 0.0, 350.0, 300.0], "category_id": 1}, {"id": 1, "bbox": [355.0, 7.0, 242.0, 249.0], "category_id": 1}, {"id": 2, "bbox": [6.0, 18.0, 339.0, 237.0], "category_id": 1}, {"id": 3, "bbox": [1116.0, 276.0, 34.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [600.0, 53.0, 222.0, 134.0], "category_id": 1}, {"id": 5, "bbox": [585.0, 204.0, 420.0, 140.0], "category_id": 3}, {"id": 6, "bbox": [411.07, 248.0, 58.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [195.95, 197.98, 46.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [1, 7], "conditions": [5, 4], "products": [0]}], "corefs": [[2, 7], [1, 6], [4, 5], [0, 3]], "caption": "Table 1. Screening Conditions of [4 + 3] Cycloadditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 196, 405, 217], "ImageBB": [82, 223, 419, 332]}, "diagram_type": "single"}, {"id": 484, "width": 1356, "height": 1132, "file_name": "acs.orglett.5b00740-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.0, 370.0, 200.0, 72.0], "category_id": 3}, {"id": 1, "bbox": [969.0, 507.0, 335.0, 75.0], "category_id": 3}, {"id": 2, "bbox": [525.0, 253.0, 364.0, 85.0], "category_id": 3}, {"id": 3, "bbox": [383.0, 6.0, 681.0, 272.0], "category_id": 1}, {"id": 4, "bbox": [17.0, 222.0, 377.0, 290.0], "category_id": 1}, {"id": 5, "bbox": [660.0, 366.0, 678.0, 281.0], "category_id": 1}, {"id": 6, "bbox": [241.0, 571.0, 37.0, 61.0], "category_id": 3}, {"id": 7, "bbox": [22.0, 520.0, 534.0, 96.4], "category_id": 1}], "reactions": [{"reactants": [10, 5], "conditions": [9], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [6]}], "corefs": [[7, 6], [4, 0], [3, 2], [5, 1]], "caption": "Figure 1. TEM images of Oxime-MSNPs: (a) 150,000\u00d7 magni\ufb01ca- tion; (b,c) 500,000\u00d7 magni\ufb01cation of nanoparticles at two di\ufb00erent locations on the dried nanoparticle aggregate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 409, 784, 451], "ImageBB": [448, 116, 787, 399]}, "diagram_type": "tree"}, {"id": 485, "width": 1356, "height": 476, "file_name": "acs.oprd.6b00180-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1227.96, 208.04, 32.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [365.2, 78.6, 246.78, 132.6], "category_id": 1}, {"id": 2, "bbox": [5.0, 64.5, 261.98, 150.61], "category_id": 1}, {"id": 3, "bbox": [1012.0, 7.2, 340.0, 217.8], "category_id": 1}, {"id": 4, "bbox": [131.95, 207.0, 35.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [5, 6], "products": [3]}], "corefs": [[2, 4], [3, 0]], "caption": "Table 5. Screening Conditions for 100\u2212750 mL Scale Pd(OAc)2 Catalyzed Suzuki Reaction of 4-Bromoaniline (2) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 140], "ImageBB": [448, 146, 787, 265]}, "diagram_type": "single"}, {"id": 486, "width": 1352, "height": 644, "file_name": "acs.oprd.5b00418-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.0, 124.5, 112.7, 258.3], "category_id": 1}, {"id": 1, "bbox": [1090.1, 480.8, 45.6, 47.2], "category_id": 3}, {"id": 2, "bbox": [793.4, 3.0, 121.6, 437.7], "category_id": 1}, {"id": 3, "bbox": [197.1, 482.0, 52.3, 53.9], "category_id": 3}, {"id": 4, "bbox": [1060.6, 2.9, 135.4, 459.1], "category_id": 1}, {"id": 5, "bbox": [819.0, 478.94, 48.08, 52.86], "category_id": 3}, {"id": 6, "bbox": [24.96, 480.98, 45.5, 54.9], "category_id": 3}, {"id": 7, "bbox": [171.0, 124.0, 179.0, 284.0], "category_id": 1}], "reactions": [{"reactants": [0, 9], "conditions": [7, 10], "products": [3, 5]}], "corefs": [[0, 6], [7, 3], [2, 5], [4, 1]], "caption": "Table 1. Performance of the Complexes in Batchwise Suzuki Cross-Coupling of 5 and 6 (Laboratory Equipment and Conditions)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 283, 417, 328], "ImageBB": [82, 116, 420, 277]}, "diagram_type": "single"}, {"id": 487, "width": 1348, "height": 788, "file_name": "acs.oprd.5b00379-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [526.71, 647.43, 30.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [67.6, 0.0, 923.4, 621.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [2]}], "corefs": [[1, 0]], "caption": "Table 3. Optimization of the C18 Puri\ufb01cation Procedure", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 579, 403, 594], "ImageBB": [82, 601, 419, 798]}, "diagram_type": "single"}, {"id": 488, "width": 2820, "height": 920, "file_name": "acs.oprd.5b00339-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1225.9, 426.7, 352.3, 137.4], "category_id": 1}, {"id": 1, "bbox": [367.8, 0.0, 929.3, 238.0], "category_id": 1}, {"id": 2, "bbox": [798.62, 271.62, 68.0, 81.0], "category_id": 3}, {"id": 3, "bbox": [797.75, 826.87, 51.4, 48.5], "category_id": 3}, {"id": 4, "bbox": [1977.0, 826.0, 58.6, 58.3], "category_id": 3}, {"id": 5, "bbox": [1967.24, 272.49, 65.0, 81.0], "category_id": 3}, {"id": 6, "bbox": [370.3, 390.9, 857.7, 416.1], "category_id": 1}, {"id": 7, "bbox": [1560.0, 517.4, 902.9, 290.3], "category_id": 1}, {"id": 8, "bbox": [1518.0, 0.0, 961.0, 247.0], "category_id": 1}, {"id": 9, "bbox": [1384.43, 563.1, 48.92, 51.05], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [1], "products": [7]}], "corefs": [[1, 2], [8, 5], [7, 4], [0, 9], [6, 3]], "caption": "Table 1. Asymmetric Hydrogenation of Ketone 4 with Optimizing Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 346, 581, 367], "ImageBB": [82, 116, 787, 346]}, "diagram_type": "tree"}, {"id": 489, "width": 2820, "height": 1132, "file_name": "acs.oprd.5b00312-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [506.0, 572.0, 106.0, 33.0], "category_id": 1}, {"id": 1, "bbox": [327.0, 764.2, 349.6, 259.8], "category_id": 1}, {"id": 2, "bbox": [325.9, 678.0, 259.1, 44.0], "category_id": 3}, {"id": 3, "bbox": [318.0, 168.4, 347.6, 256.6], "category_id": 1}, {"id": 4, "bbox": [323.7, 61.0, 241.3, 40.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1], "products": [2]}], "corefs": [[3, 4], [1, 2]], "caption": "Figure 3. (A) UHPLC/UV chromatogram at 254 nm for the TiCl3 treated sample and (B, C) high-resolution mass spectra of (B) compound 7 and (C)the reduced aniline compound 7a. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 886, 784, 914], "ImageBB": [82, 593, 787, 876]}, "diagram_type": "tree"}, {"id": 490, "width": 1480, "height": 2100, "file_name": "ol501424f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [331.5, 214.86, 38.97, 49.85], "category_id": 3}, {"id": 1, "bbox": [646.89, 214.86, 43.51, 49.85], "category_id": 3}, {"id": 2, "bbox": [1195.2, 224.83, 41.69, 48.04], "category_id": 3}, {"id": 3, "bbox": [719.1, 249.2, 395.6, 252.4], "category_id": 1}, {"id": 4, "bbox": [1071.56, 4.56, 305.0, 215.0], "category_id": 1}, {"id": 5, "bbox": [520.0, 50.0, 275.0, 132.0], "category_id": 1}, {"id": 6, "bbox": [235.0, 67.0, 245.0, 141.0], "category_id": 1}], "reactions": [{"reactants": [8, 6], "conditions": [5, 7], "products": [4]}], "corefs": [[6, 0], [5, 1], [4, 2]], "caption": "Table 1. Substrate Scope of NHC-Catalyzed aza-DA Reactiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 737, 125], "ImageBB": [416, 131, 786, 656]}, "diagram_type": "single"}, {"id": 491, "width": 1348, "height": 1044, "file_name": "ol501165h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [924.0, 553.1, 353.3, 359.6], "category_id": 1}, {"id": 1, "bbox": [847.0, 452.0, 247.0, 81.0], "category_id": 3}, {"id": 2, "bbox": [64.0, 815.0, 312.0, 127.0], "category_id": 3}, {"id": 3, "bbox": [502.0, 848.0, 276.0, 96.0], "category_id": 3}, {"id": 4, "bbox": [220.0, 550.0, 265.0, 360.0], "category_id": 1}, {"id": 5, "bbox": [940.0, 793.0, 103.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [302.2, 34.0, 196.8, 56.0], "category_id": 1}, {"id": 7, "bbox": [558.0, 428.69, 88.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [162.0, 442.69, 228.0, 91.0], "category_id": 3}, {"id": 9, "bbox": [218.0, 237.1, 286.7, 236.9], "category_id": 1}, {"id": 10, "bbox": [553.0, 230.1, 280.0, 243.9], "category_id": 1}, {"id": 11, "bbox": [874.9, 207.4, 330.4, 296.0], "category_id": 1}, {"id": 12, "bbox": [546.8, 550.0, 300.2, 313.0], "category_id": 1}], "reactions": [{"reactants": [0, 10], "conditions": [3, 11], "products": [2]}], "corefs": [[9, 8], [10, 7], [11, 1], [4, 2], [12, 3], [0, 5]], "caption": "Table 2. Cyclocarbopalladation/Suzuki\u2212Miyaura Coupling", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 411, 110], "ImageBB": [82, 116, 419, 377]}, "diagram_type": "single"}, {"id": 492, "width": 1352, "height": 384, "file_name": "ol500618w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [475.08, 195.0, 38.12, 40.9], "category_id": 3}, {"id": 1, "bbox": [1168.94, 188.32, 63.46, 54.78], "category_id": 3}, {"id": 2, "bbox": [3.37, 35.45, 281.33, 140.65], "category_id": 1}, {"id": 3, "bbox": [413.5, 48.2, 157.3, 113.9], "category_id": 1}, {"id": 4, "bbox": [1052.86, 36.59, 295.64, 140.51], "category_id": 1}, {"id": 5, "bbox": [116.5, 194.04, 55.7, 43.46], "category_id": 3}], "reactions": [{"reactants": [5, 6], "conditions": [10, 0], "products": [7]}], "corefs": [[2, 5], [3, 0], [4, 1]], "caption": "Table 2. Optimization of the Reaction Conditions for the Cyanation Reaction of Alkenyl Bromide 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 407, 125], "ImageBB": [82, 131, 420, 227]}, "diagram_type": "single"}, {"id": 493, "width": 1356, "height": 2340, "file_name": "ol500121z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [996.0, 294.0, 233.0, 100.0], "category_id": 1}, {"id": 1, "bbox": [204.0, 211.0, 91.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [489.0, 163.0, 76.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [1080.0, 192.0, 26.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1086.0, 428.0, 26.0, 32.0], "category_id": 3}, {"id": 5, "bbox": [1014.0, 0.0, 195.0, 179.0], "category_id": 1}, {"id": 6, "bbox": [481.0, 99.0, 92.0, 38.0], "category_id": 1}, {"id": 7, "bbox": [136.0, 85.0, 253.0, 107.0], "category_id": 1}, {"id": 8, "bbox": [611.0, 255.0, 353.0, 289.0], "category_id": 3}, {"id": 9, "bbox": [120.0, 260.0, 596.0, 665.0], "category_id": 3}], "reactions": [{"reactants": [10, 9], "conditions": [7, 6], "products": [8, 0]}], "corefs": [[7, 1], [7, 9], [6, 2], [6, 8], [5, 3], [0, 4]], "caption": "Table 2. [Pd(cod)(C3H5)]BF4/bpy-Catalyzed Double Alkylation of 1 with 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 748, 125], "ImageBB": [448, 131, 787, 716]}, "diagram_type": "single"}, {"id": 494, "width": 1348, "height": 772, "file_name": "ol402047d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1002.02, 296.0, 35.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [882.0, 269.0, 33.0, 34.0], "category_id": 3}, {"id": 2, "bbox": [713.0, 75.0, 33.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [852.0, 12.0, 97.0, 251.0], "category_id": 1}, {"id": 4, "bbox": [605.0, 15.0, 200.0, 75.1], "category_id": 1}, {"id": 5, "bbox": [983.0, 0.0, 87.1, 299.0], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [4, 3, 9, 5, 8], "products": [7, 11, 10]}], "corefs": [[4, 2], [3, 1], [5, 0]], "caption": "Table 4. Recyclability of Polymer Using the Same Nucleophile", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 770, 100], "ImageBB": [436, 112, 773, 305]}, "diagram_type": "single"}, {"id": 495, "width": 1348, "height": 1260, "file_name": "ol402047d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.0, 108.0, 96.1, 248.0], "category_id": 1}, {"id": 1, "bbox": [229.0, 0.0, 257.0, 250.0], "category_id": 1}, {"id": 2, "bbox": [1008.0, 392.0, 31.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [864.0, 359.0, 35.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [983.0, 105.0, 93.0, 290.0], "category_id": 1}, {"id": 5, "bbox": [619.0, 113.0, 211.0, 86.0], "category_id": 1}, {"id": 6, "bbox": [738.0, 182.0, 32.0, 31.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2, 1, 8, 11, 6, 13], "products": [0, 10, 4]}], "corefs": [[5, 6], [0, 3], [4, 2]], "caption": "Table 2. Structure Activity Study of Siloxane Polymers in CCRa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 771, 101], "ImageBB": [436, 112, 773, 427]}, "diagram_type": "single"}, {"id": 496, "width": 1344, "height": 976, "file_name": "ol402047d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [848.0, 277.0, 32.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [987.0, 306.0, 28.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [958.0, 6.0, 99.0, 305.0], "category_id": 1}, {"id": 3, "bbox": [685.0, 78.0, 31.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [560.0, 24.1, 207.5, 77.9], "category_id": 1}, {"id": 5, "bbox": [820.0, 12.0, 93.7, 259.7], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [1, 2, 11, 10, 8], "products": [12, 6, 4]}], "corefs": [[4, 3], [5, 0], [2, 1]], "caption": "Table 1. Optimization of CCR Employing PSTAa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 336, 101], "ImageBB": [71, 112, 407, 356]}, "diagram_type": "single"}, {"id": 497, "width": 1348, "height": 1644, "file_name": "ol401881n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [936.0, 177.0, 66.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [318.0, 177.0, 66.0, 52.0], "category_id": 3}, {"id": 2, "bbox": [130.8, 2.0, 424.2, 153.4], "category_id": 1}, {"id": 3, "bbox": [818.9, 4.2, 401.7, 173.7], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [5, 0], "products": [6]}], "corefs": [[2, 1], [3, 0]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 376, 707, 392], "ImageBB": [436, 403, 773, 814]}, "diagram_type": "single"}, {"id": 498, "width": 1344, "height": 1892, "file_name": "ol401812h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [161.19, 25.63, 311.71, 147.97], "category_id": 1}, {"id": 1, "bbox": [264.0, 216.0, 193.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [875.2, 6.3, 308.3, 172.0], "category_id": 1}, {"id": 3, "bbox": [502.0, 0.0, 302.5, 87.0], "category_id": 1}, {"id": 4, "bbox": [1020.0, 216.1, 56.0, 58.9], "category_id": 3}, {"id": 5, "bbox": [503.74, 104.69, 333.66, 146.01], "category_id": 1}, {"id": 6, "bbox": [373.0, 320.8, 404.1, 316.2], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 6], "products": [3]}], "corefs": [[0, 1], [2, 4]], "caption": "Table 1. Screening of Reaction Conditions", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 298, 100], "ImageBB": [71, 112, 407, 585]}, "diagram_type": "single"}, {"id": 499, "width": 1344, "height": 1568, "file_name": "ol401571r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [178.0, 250.0, 56.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [76.0, 0.0, 300.0, 224.0], "category_id": 1}, {"id": 2, "bbox": [970.0, 3.0, 300.0, 247.0], "category_id": 1}, {"id": 3, "bbox": [1073.0, 248.0, 62.0, 50.0], "category_id": 3}], "reactions": [{"reactants": [2, 6], "conditions": [4, 7], "products": [3]}], "corefs": [[1, 0], [2, 3]], "caption": "Table 1. Examination of Metal Salts and Condition Optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 343, 405, 356], "ImageBB": [71, 367, 407, 759]}, "diagram_type": "single"}, {"id": 500, "width": 1348, "height": 1156, "file_name": "ol401443a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [61.0, 91.0, 205.0, 168.0], "category_id": 1}, {"id": 1, "bbox": [691.0, 0.0, 250.0, 294.0], "category_id": 1}, {"id": 2, "bbox": [137.0, 263.0, 75.0, 55.0], "category_id": 3}, {"id": 3, "bbox": [766.0, 291.0, 76.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [1014.0, 280.0, 50.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [933.6, 0.0, 354.4, 280.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 7], "products": [1, 8]}], "corefs": [[0, 2], [1, 3], [5, 4]], "caption": "Table 1. Catalyst Screening", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 583, 100], "ImageBB": [436, 112, 773, 401]}, "diagram_type": "single"}, {"id": 501, "width": 2808, "height": 1788, "file_name": "ol401179k-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1483.0, 1170.0, 77.0, 57.0], "category_id": 3}, {"id": 1, "bbox": [1120.0, 1304.0, 63.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [1741.0, 1735.0, 95.0, 53.0], "category_id": 3}, {"id": 3, "bbox": [1118.4, 981.53, 69.12, 53.0], "category_id": 3}, {"id": 4, "bbox": [2165.0, 1023.0, 79.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [2202.0, 1319.0, 87.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [196.39, 1138.7, 69.8, 53.8], "category_id": 3}, {"id": 7, "bbox": [1125.0, 1680.0, 61.0, 56.5], "category_id": 3}, {"id": 8, "bbox": [114.0, 298.2, 319.2, 181.6], "category_id": 1}, {"id": 9, "bbox": [1020.4, 295.9, 372.8, 238.9], "category_id": 1}, {"id": 10, "bbox": [1594.0, 270.0, 370.2, 253.0], "category_id": 1}, {"id": 11, "bbox": [48.4, 973.2, 397.2, 180.1], "category_id": 1}, {"id": 12, "bbox": [2557.0, 1159.0, 92.0, 53.4], "category_id": 3}, {"id": 13, "bbox": [188.0, 491.39, 192.0, 89.6], "category_id": 3}, {"id": 14, "bbox": [881.0, 775.4, 463.0, 259.1], "category_id": 1}, {"id": 15, "bbox": [1110.91, 529.48, 206.29, 96.32], "category_id": 3}, {"id": 16, "bbox": [1727.22, 579.91, 100.28, 57.19], "category_id": 3}, {"id": 17, "bbox": [1593.7, 1424.6, 373.3, 250.9], "category_id": 1}, {"id": 18, "bbox": [1013.3, 1443.8, 378.1, 244.7], "category_id": 1}, {"id": 19, "bbox": [2357.3, 907.5, 432.8, 268.0], "category_id": 1}, {"id": 20, "bbox": [1976.5, 1076.3, 449.0, 258.1], "category_id": 1}, {"id": 21, "bbox": [1269.3, 912.5, 431.4, 262.9], "category_id": 1}, {"id": 22, "bbox": [1966.0, 773.7, 461.9, 255.8], "category_id": 1}, {"id": 23, "bbox": [887.1, 1075.8, 456.6, 257.2], "category_id": 1}, {"id": 24, "bbox": [1394.0, 420.0, 175.5, 68.4], "category_id": 1}], "reactions": [{"reactants": [16], "conditions": [14], "products": [17]}, {"reactants": [17], "conditions": [22, 41], "products": [18]}, {"reactants": [19], "conditions": [40], "products": [23, 38, 34]}, {"reactants": [23, 38, 34], "conditions": [5, 7], "products": [37, 32, 31]}, {"reactants": [19], "conditions": [39], "products": [28]}, {"reactants": [28], "conditions": [24, 29], "products": [27]}], "corefs": [[8, 13], [9, 15], [10, 16], [11, 6], [14, 3], [23, 1], [21, 0], [22, 4], [20, 5], [19, 12], [18, 7], [17, 2]], "caption": "Figure 1. Strategy for synthetic diversification of monoterpene indole alkaloids using Pd-catalyzed Suzuki Miyaura coupling reaction. Alkaloid analogs with chlorine and bromine at the 7-position of the indole ring were obtained by culturing transgenic tryptophan decarboxylase-suppressed hairy root cultures in the presence of 7-chlorotryptamine 1a or 7-bromotryptamine 1b (a). Alkaloid analogs with chlorine at the 6-position of the indole ring were obtained by culturing hairy root cultures that express a mutant strictosidine synthase enzyme (V214M) in the presence of 6-chlorotryptamine 1c (b). Alkaloid analogs with chlorine at the 7-position of the indole ring could also be obtained from hairy root cultures that express prokaryotic halogenases, RebH and RebF (c). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 519, 770, 602], "ImageBB": [71, 59, 773, 506]}, "diagram_type": "multiple"}, {"id": 502, "width": 1352, "height": 860, "file_name": "ol0362663-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [28.6, 6.2, 260.4, 195.8], "category_id": 1}, {"id": 1, "bbox": [631.5, 8.1, 249.7, 194.0], "category_id": 1}, {"id": 2, "bbox": [1157.7, 11.9, 169.8, 146.5], "category_id": 1}, {"id": 3, "bbox": [889.2, 9.9, 224.8, 192.5], "category_id": 1}, {"id": 4, "bbox": [748.0, 210.0, 45.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [1264.0, 210.0, 42.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [1008.0, 209.0, 43.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [169.0, 207.0, 43.0, 56.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5], "products": [1, 3, 2]}], "corefs": [[0, 7], [1, 4], [3, 6], [2, 5]], "caption": "Table 1. Influence of Reoxidant on Product Distribution", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 541, 373, 554], "ImageBB": [73, 564, 411, 779]}, "diagram_type": "single"}, {"id": 503, "width": 1352, "height": 948, "file_name": "ol027494k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [54.0, 6.4, 198.5, 135.6], "category_id": 1}, {"id": 1, "bbox": [112.0, 186.0, 61.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [880.0, 300.0, 60.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [772.0, 0.0, 365.0, 280.0], "category_id": 1}, {"id": 4, "bbox": [1171.0, 91.0, 129.0, 61.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 2], "products": [6, 7]}], "corefs": [[0, 1], [3, 2]], "caption": "Table 1. Alkenylation Reaction of Enolate with Alkenylselenonium Salt 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 328, 104], "ImageBB": [73, 108, 411, 345]}, "diagram_type": "single"}, {"id": 504, "width": 1348, "height": 1000, "file_name": "ol026509b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [727.0, 190.0, 38.3, 46.0], "category_id": 3}, {"id": 1, "bbox": [116.7, 4.0, 240.0, 145.0], "category_id": 1}, {"id": 2, "bbox": [1125.0, 197.0, 41.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [252.0, 193.0, 37.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [998.0, 7.0, 239.0, 148.0], "category_id": 1}, {"id": 5, "bbox": [596.0, 1.0, 241.0, 147.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [6, 5]}], "corefs": [[1, 3], [5, 0], [4, 2]], "caption": "Table 1. Lithiation of Azabicycle 4 and Electrophile Additions to Provide Methylene 6 and Bridgehead 8 E-Substituted Productsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 406, 120], "ImageBB": [74, 130, 411, 380]}, "diagram_type": "single"}, {"id": 505, "width": 1348, "height": 684, "file_name": "jo990938e-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [340.0, 166.0, 31.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [840.0, 165.0, 124.0, 40.0], "category_id": 1}, {"id": 2, "bbox": [780.0, 7.0, 330.9, 171.5], "category_id": 1}, {"id": 3, "bbox": [243.2, 27.0, 294.8, 136.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [3]}], "corefs": [[3, 0]], "caption": "Table 2. Additions of Allenylmetal Reagents Prepared          from Allenyl Iodide 6 to Aldehyde 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [447, 64, 767, 89], "ImageBB": [439, 98, 776, 269]}, "diagram_type": "single"}, {"id": 506, "width": 1348, "height": 976, "file_name": "jo9902998-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [899.2, 58.9, 297.2, 137.6], "category_id": 1}, {"id": 1, "bbox": [159.1, 55.7, 293.2, 135.0], "category_id": 1}, {"id": 2, "bbox": [1054.23, 203.96, 65.9, 56.5], "category_id": 3}, {"id": 3, "bbox": [288.0, 205.0, 78.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [5, 2], "conditions": [1, 8], "products": [3]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Pd-Catalyzed Allylic Alkylation of 5a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [472, 63, 741, 76], "ImageBB": [439, 82, 776, 326]}, "diagram_type": "single"}, {"id": 507, "width": 1344, "height": 1672, "file_name": "jo962200s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [512.0, 1082.0, 76.0, 64.8], "category_id": 3}, {"id": 1, "bbox": [707.0, 1274.0, 384.9, 398.0], "category_id": 1}, {"id": 2, "bbox": [237.25, 1010.72, 47.07, 56.03], "category_id": 3}, {"id": 3, "bbox": [143.3, 721.7, 296.1, 266.0], "category_id": 1}, {"id": 4, "bbox": [777.0, 712.0, 415.0, 422.0], "category_id": 1}, {"id": 5, "bbox": [130.0, 1265.0, 345.0, 275.0], "category_id": 1}, {"id": 6, "bbox": [380.75, 822.66, 198.99, 315.47], "category_id": 1}, {"id": 7, "bbox": [237.0, 1549.0, 86.0, 68.0], "category_id": 3}], "reactions": [{"reactants": [7, 13], "conditions": [10], "products": [8]}, {"reactants": [7], "conditions": [1], "products": [9]}, {"reactants": [9], "conditions": [], "products": [7]}, {"reactants": [9], "conditions": [6, 4], "products": [2]}, {"reactants": [2], "conditions": [], "products": [5]}], "corefs": [[3, 2], [6, 0], [5, 7]], "caption": "Table 1. Reaction of 6-Amino-1,3-dimethyl-5-    thioformyluracil (1) with Enamines 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [108, 49, 373, 74], "ImageBB": [73, 76, 409, 494]}, "diagram_type": "graph"}, {"id": 508, "width": 1288, "height": 1696, "file_name": "jo961049j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1100.0, 1029.0, 33.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [236.0, 1027.0, 32.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1086.0, 1647.0, 36.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [227.0, 1645.0, 38.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [914.8, 1217.0, 336.8, 368.5], "category_id": 1}, {"id": 5, "bbox": [865.5, 697.6, 417.5, 286.9], "category_id": 1}, {"id": 6, "bbox": [933.7, 188.1, 335.8, 258.6], "category_id": 1}, {"id": 7, "bbox": [88.0, 114.8, 317.6, 399.8], "category_id": 1}, {"id": 8, "bbox": [1086.91, 490.36, 73.99, 73.04], "category_id": 3}, {"id": 9, "bbox": [240.35, 492.18, 45.2, 59.6], "category_id": 3}, {"id": 10, "bbox": [73.5, 1162.3, 315.4, 488.2], "category_id": 1}, {"id": 11, "bbox": [59.5, 630.2, 384.0, 399.3], "category_id": 1}], "reactions": [{"reactants": [13], "conditions": [1, 8], "products": [12]}, {"reactants": [17], "conditions": [9, 10], "products": [11]}, {"reactants": [16], "conditions": [0, 2], "products": [7]}], "corefs": [[7, 9], [6, 8], [11, 1], [5, 0], [10, 3], [4, 2]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 456, 130, 469], "ImageBB": [73, 20, 395, 444]}, "diagram_type": "multiple"}, {"id": 509, "width": 1156, "height": 640, "file_name": "jo9519672-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [423.0, 586.0, 59.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [939.0, 586.0, 59.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [990.0, 298.0, 64.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [246.0, 285.0, 54.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [883.4, 346.3, 268.7, 213.1], "category_id": 1}, {"id": 5, "bbox": [7.0, 88.3, 612.0, 185.9], "category_id": 1}, {"id": 6, "bbox": [774.6, 96.5, 378.4, 179.2], "category_id": 1}, {"id": 7, "bbox": [194.5, 385.1, 417.5, 193.9], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [4]}], "corefs": [[5, 3], [6, 2], [7, 0], [4, 1]], "caption": "Figure 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [63, 417, 120, 430], "ImageBB": [87, 440, 376, 600]}, "diagram_type": "multiple"}, {"id": 510, "width": 1348, "height": 800, "file_name": "jo951899j-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.0, 97.7, 377.0, 311.3], "category_id": 1}, {"id": 1, "bbox": [851.4, 94.2, 345.3, 308.8], "category_id": 1}, {"id": 2, "bbox": [360.07, 455.15, 87.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [1061.0, 454.0, 108.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 7], "products": [1]}], "corefs": [[0, 2], [1, 3]], "caption": "Table 5. Removal of the MEE Ester Protecting Group", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [438, 55, 755, 67], "ImageBB": [429, 66, 766, 266]}, "diagram_type": "single"}, {"id": 511, "width": 1352, "height": 912, "file_name": "jo501006u-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [235.0, 135.0, 204.0, 75.0], "category_id": 1}, {"id": 1, "bbox": [454.72, 107.52, 249.39, 52.57], "category_id": 1}, {"id": 2, "bbox": [9.0, 135.0, 172.0, 73.0], "category_id": 1}, {"id": 3, "bbox": [938.0, 151.0, 230.6, 45.0], "category_id": 1}], "reactions": [{"reactants": [7, 2], "conditions": [0, 4, 6, 1], "products": [8, 5]}], "corefs": [], "caption": "Figure 3. Plots of the yields of the cross-coupling product (\u25a0, left axis) and nonane (\u25c6, right axis) against the amount of phenylpropyne used at 3 h reaction time. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 749, 417, 793], "ImageBB": [82, 514, 420, 742]}, "diagram_type": "single"}, {"id": 512, "width": 1352, "height": 352, "file_name": "jo500412w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1187.0, 214.0, 74.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [137.1, 212.1, 56.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [1043.3, 6.1, 308.7, 196.7], "category_id": 1}, {"id": 3, "bbox": [706.1, 4.1, 303.9, 199.7], "category_id": 1}, {"id": 4, "bbox": [6.0, 15.3, 297.0, 195.7], "category_id": 1}, {"id": 5, "bbox": [852.1, 211.2, 62.5, 34.7], "category_id": 3}], "reactions": [{"reactants": [6, 8], "conditions": [2, 9], "products": [5, 4]}], "corefs": [[4, 1], [3, 5], [2, 0]], "caption": "Table 1. Condition Optimizations for Amidation Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 303, 417, 324], "ImageBB": [82, 330, 420, 418]}, "diagram_type": "single"}, {"id": 513, "width": 2820, "height": 1184, "file_name": "jo402399n-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1649.0, 414.0, 493.0, 346.7], "category_id": 1}, {"id": 1, "bbox": [487.0, 2.0, 383.5, 321.5], "category_id": 1}, {"id": 2, "bbox": [490.0, 410.8, 460.9, 348.2], "category_id": 1}, {"id": 3, "bbox": [1738.0, 822.0, 496.0, 323.5], "category_id": 1}, {"id": 4, "bbox": [645.0, 1049.0, 50.0, 63.0], "category_id": 3}, {"id": 5, "bbox": [1915.0, 1049.0, 92.0, 69.0], "category_id": 3}, {"id": 6, "bbox": [1781.0, 667.0, 73.0, 72.0], "category_id": 3}, {"id": 7, "bbox": [1820.0, 305.0, 85.0, 64.0], "category_id": 3}, {"id": 8, "bbox": [597.0, 657.0, 82.0, 73.0], "category_id": 3}, {"id": 9, "bbox": [584.0, 253.0, 55.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [492.0, 817.0, 464.0, 335.0], "category_id": 1}, {"id": 11, "bbox": [1668.0, 5.0, 413.0, 319.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [17, 14], "products": [19]}, {"reactants": [3], "conditions": [16, 13], "products": [1]}, {"reactants": [18], "conditions": [15, 0], "products": [5]}], "corefs": [[1, 9], [11, 7], [2, 8], [0, 6], [10, 4], [3, 5]], "caption": "Table 4. Solvent-Free Regioselective Allylation Catalyzed by Bu2SnOa", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 412, 476, 434], "ImageBB": [82, 116, 787, 412]}, "diagram_type": "multiple"}, {"id": 514, "width": 1352, "height": 416, "file_name": "jo401608v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [85.0, 225.0, 60.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 26.0, 272.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [317.0, 106.0, 266.0, 66.0], "category_id": 1}, {"id": 3, "bbox": [1047.0, 1.0, 305.0, 274.0], "category_id": 1}, {"id": 4, "bbox": [1108.0, 225.0, 56.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [432.0, 224.0, 49.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [1, 2], "conditions": [4, 8], "products": [3]}], "corefs": [[1, 0], [2, 5], [3, 4]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 268, 110], "ImageBB": [82, 116, 420, 220]}, "diagram_type": "single"}, {"id": 515, "width": 1348, "height": 532, "file_name": "jo400755q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [282.07, 385.0, 62.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [992.05, 386.0, 74.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [881.3, 13.9, 308.7, 355.1], "category_id": 1}, {"id": 3, "bbox": [162.2, 2.0, 271.3, 357.8], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [4]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 554, 371, 575], "ImageBB": [82, 581, 419, 714]}, "diagram_type": "single"}, {"id": 516, "width": 1260, "height": 1896, "file_name": "jo4004426-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [798.0, 943.0, 401.1, 307.0], "category_id": 1}, {"id": 1, "bbox": [830.6, 631.0, 376.7, 293.0], "category_id": 1}, {"id": 2, "bbox": [95.2, 298.0, 347.8, 303.7], "category_id": 1}, {"id": 3, "bbox": [556.6, 324.8, 266.4, 281.9], "category_id": 1}, {"id": 4, "bbox": [848.0, 321.0, 374.0, 285.4], "category_id": 1}, {"id": 5, "bbox": [946.0, 8.0, 314.0, 277.4], "category_id": 1}, {"id": 6, "bbox": [228.0, 5.0, 185.3, 276.5], "category_id": 1}, {"id": 7, "bbox": [0.0, 22.0, 164.5, 192.1], "category_id": 1}, {"id": 8, "bbox": [84.2, 1259.0, 366.8, 304.0], "category_id": 1}, {"id": 9, "bbox": [116.0, 1591.0, 324.0, 299.0], "category_id": 1}, {"id": 10, "bbox": [460.0, 1284.0, 366.4, 279.0], "category_id": 1}, {"id": 11, "bbox": [52.0, 865.0, 290.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [60.0, 1845.0, 171.0, 51.0], "category_id": 3}, {"id": 13, "bbox": [435.0, 1845.0, 181.0, 51.0], "category_id": 3}, {"id": 14, "bbox": [823.0, 1837.0, 151.0, 59.0], "category_id": 3}, {"id": 15, "bbox": [826.0, 1502.0, 276.0, 61.0], "category_id": 3}, {"id": 16, "bbox": [74.0, 1507.0, 151.0, 67.0], "category_id": 3}, {"id": 17, "bbox": [451.0, 1513.0, 160.0, 59.0], "category_id": 3}, {"id": 18, "bbox": [809.0, 1197.0, 156.0, 53.0], "category_id": 3}, {"id": 19, "bbox": [440.0, 1181.0, 176.0, 67.0], "category_id": 3}, {"id": 20, "bbox": [55.0, 1192.0, 181.0, 61.0], "category_id": 3}, {"id": 21, "bbox": [823.0, 871.0, 170.0, 44.0], "category_id": 3}, {"id": 22, "bbox": [451.0, 868.0, 162.0, 59.0], "category_id": 3}, {"id": 23, "bbox": [94.0, 622.0, 349.0, 299.0], "category_id": 1}, {"id": 24, "bbox": [513.0, 617.0, 310.0, 304.0], "category_id": 1}, {"id": 25, "bbox": [476.0, 941.0, 355.0, 312.0], "category_id": 1}, {"id": 26, "bbox": [778.0, 1262.0, 433.0, 301.0], "category_id": 1}, {"id": 27, "bbox": [837.0, 1569.0, 377.0, 318.0], "category_id": 1}, {"id": 28, "bbox": [443.0, 1586.0, 391.0, 304.0], "category_id": 1}, {"id": 29, "bbox": [393.0, 220.0, 30.0, 39.0], "category_id": 3}, {"id": 30, "bbox": [1046.0, 226.0, 92.0, 47.0], "category_id": 3}, {"id": 31, "bbox": [72.0, 544.0, 296.0, 70.0], "category_id": 3}, {"id": 32, "bbox": [460.0, 541.0, 282.0, 62.0], "category_id": 3}, {"id": 33, "bbox": [828.0, 552.0, 171.0, 56.0], "category_id": 3}, {"id": 34, "bbox": [88.0, 943.0, 366.5, 299.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [29, 30], "products": [5]}], "corefs": [[6, 29], [5, 30], [2, 31], [3, 32], [4, 33], [23, 11], [24, 22], [1, 21], [34, 20], [25, 19], [0, 18], [8, 16], [10, 17], [26, 15], [9, 12], [28, 13], [27, 14]], "caption": "Table 3. Scope of the Reaction", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 625, 110], "ImageBB": [460, 116, 775, 590]}, "diagram_type": "single"}, {"id": 517, "width": 1348, "height": 996, "file_name": "jo302142v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [731.0, 0.0, 582.3, 268.0], "category_id": 1}, {"id": 1, "bbox": [734.0, 279.0, 577.0, 269.7], "category_id": 1}, {"id": 2, "bbox": [24.0, 189.0, 352.0, 258.3], "category_id": 1}, {"id": 3, "bbox": [408.0, 187.0, 212.0, 244.3], "category_id": 1}, {"id": 4, "bbox": [862.0, 500.0, 91.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [856.0, 231.0, 95.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [439.0, 442.0, 159.0, 58.0], "category_id": 3}, {"id": 7, "bbox": [170.0, 409.0, 65.0, 47.7], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [], "products": [1, 2]}], "corefs": [[2, 7], [3, 6], [0, 5], [1, 4]], "caption": "Table 1. Aldol Reactions of the (c-Hex)2B Enolate of 1a (R = MOM, Et3Si) with (\u00b1)-5a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 127], "ImageBB": [82, 131, 419, 380]}, "diagram_type": "tree"}, {"id": 518, "width": 1196, "height": 900, "file_name": "jo201478d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [23.0, 700.0, 143.0, 134.0], "category_id": 1}, {"id": 1, "bbox": [438.0, 834.0, 55.0, 39.0], "category_id": 3}, {"id": 2, "bbox": [1003.0, 171.0, 33.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [0.0, 436.0, 172.0, 127.0], "category_id": 1}, {"id": 4, "bbox": [831.0, 1.0, 365.0, 218.0], "category_id": 1}, {"id": 5, "bbox": [440.0, 567.0, 52.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [87.0, 835.0, 53.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [373.0, 52.0, 197.0, 130.0], "category_id": 1}, {"id": 8, "bbox": [445.0, 171.0, 31.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [2.0, 24.0, 357.0, 183.0], "category_id": 1}, {"id": 10, "bbox": [87.0, 567.0, 55.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [309.0, 408.0, 351.0, 152.0], "category_id": 1}, {"id": 12, "bbox": [152.0, 173.0, 54.0, 39.0], "category_id": 3}, {"id": 13, "bbox": [309.0, 686.0, 314.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [11, 9], "conditions": [1, 14], "products": [6]}], "corefs": [[9, 12], [7, 8], [4, 2], [3, 10], [11, 5], [0, 6], [13, 1]], "caption": "Table 2. Epoxide Rearrangement Followed by Addition and ISMS Using the Unprotected \u03b4-Hydroxyalkenylsilanes ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 770, 123], "ImageBB": [455, 133, 754, 358]}, "diagram_type": "single"}, {"id": 519, "width": 1344, "height": 912, "file_name": "jo201478d-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [612.0, 259.8, 223.0, 191.0], "category_id": 1}, {"id": 1, "bbox": [975.14, 432.84, 87.36, 38.39], "category_id": 3}, {"id": 2, "bbox": [457.0, 187.0, 36.2, 39.1], "category_id": 3}, {"id": 3, "bbox": [922.6, 291.7, 222.8, 156.5], "category_id": 1}, {"id": 4, "bbox": [644.3, 0.0, 251.1, 200.4], "category_id": 1}, {"id": 5, "bbox": [261.0, 188.0, 37.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [504.0, 667.0, 340.0, 245.0], "category_id": 1}, {"id": 7, "bbox": [200.1, 7.9, 152.7, 175.7], "category_id": 1}, {"id": 8, "bbox": [390.8, 23.4, 143.2, 141.9], "category_id": 1}, {"id": 9, "bbox": [743.0, 210.1, 43.9, 44.3], "category_id": 3}], "reactions": [{"reactants": [9, 10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4, 6]}], "corefs": [[7, 5], [8, 2], [4, 9], [3, 1]], "caption": "Figure 1. Proposed steric hindrance limiting the transformation of trans-stilbene oxide to the desired DHP product. ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 374, 405, 402], "ImageBB": [71, 133, 407, 361]}, "diagram_type": "multiple"}, {"id": 520, "width": 1356, "height": 1176, "file_name": "jo2008675-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1162.0, 204.0, 106.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 8.0, 226.0, 190.0], "category_id": 1}, {"id": 2, "bbox": [261.0, 187.0, 446.4, 146.1], "category_id": 3}, {"id": 3, "bbox": [356.3, 29.6, 195.3, 161.0], "category_id": 1}, {"id": 4, "bbox": [1029.6, 23.9, 326.4, 172.1], "category_id": 1}, {"id": 5, "bbox": [68.0, 202.0, 66.8, 48.0], "category_id": 3}], "reactions": [{"reactants": [1, 6], "conditions": [3, 4], "products": [7]}], "corefs": [[1, 5], [3, 2], [4, 0]], "caption": "Table 4. Domino Reaction of 2-Hydroxyaryl-r,\u03b2-unsatu- rated Ketones 2, 2-Hydroxyarylimines 4, 2-Hydroxyarylni- troalkenes 3, and Salicylic Aldehydes 1 to 1,3-Dicarbonyl Compounds (8a and 8b)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 519, 758, 580], "ImageBB": [436, 589, 775, 883]}, "diagram_type": "single"}, {"id": 521, "width": 1352, "height": 620, "file_name": "ol7019636-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 0.0, 261.0, 140.0], "category_id": 1}, {"id": 1, "bbox": [241.0, 0.0, 265.0, 142.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1], "products": [0]}], "corefs": [], "caption": "Table 3. Preparation of Some Diazeniumdiolate Prodrug Forms ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 373, 104], "ImageBB": [73, 108, 411, 263]}, "diagram_type": "single"}, {"id": 522, "width": 1348, "height": 416, "file_name": "ol503708v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [713.7, 43.3, 204.3, 271.3], "category_id": 1}, {"id": 1, "bbox": [1075.0, 265.9, 52.7, 38.1], "category_id": 3}, {"id": 2, "bbox": [977.6, 38.6, 205.1, 273.7], "category_id": 1}, {"id": 3, "bbox": [164.4, 3.0, 235.6, 245.1], "category_id": 1}, {"id": 4, "bbox": [807.46, 265.68, 52.51, 45.62], "category_id": 3}, {"id": 5, "bbox": [243.0, 258.0, 27.0, 34.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [7, 8], "products": [0, 2]}], "corefs": [[3, 5], [0, 4], [2, 1]], "caption": "Table 1. Azide Rearrangement Optimization", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 332, 187], "ImageBB": [82, 193, 419, 297]}, "diagram_type": "single"}, {"id": 523, "width": 1348, "height": 344, "file_name": "ol502998n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [445.0, 204.0, 36.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [121.0, 32.0, 214.0, 132.0], "category_id": 1}, {"id": 2, "bbox": [977.0, 4.0, 251.0, 238.0], "category_id": 1}, {"id": 3, "bbox": [203.0, 205.0, 36.0, 31.0], "category_id": 3}, {"id": 4, "bbox": [1029.0, 204.0, 36.0, 31.0], "category_id": 3}, {"id": 5, "bbox": [452.0, 38.0, 40.0, 151.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [1, 4], "products": [3]}], "corefs": [[1, 3], [5, 0], [2, 4]], "caption": "Table 1. Condition Investigation Using Pyrazolidin-3-one as an Oxidative DGa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 449, 416, 479], "ImageBB": [82, 486, 419, 572]}, "diagram_type": "single"}, {"id": 524, "width": 1348, "height": 376, "file_name": "acs.joc.5b01366-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [188.0, 203.0, 68.0, 66.0], "category_id": 3}, {"id": 1, "bbox": [1128.0, 224.0, 71.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [987.3, 1.0, 295.6, 236.0], "category_id": 1}, {"id": 3, "bbox": [61.0, 3.0, 377.0, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1], "products": [4]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 371, 110], "ImageBB": [82, 116, 419, 210]}, "diagram_type": "single"}, {"id": 525, "width": 1052, "height": 1008, "file_name": "op990044w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [98.0, 931.0, 254.0, 74.0], "category_id": 3, "id": 0}, {"bbox": [344.0, 5.2, 463.7, 316.4], "category_id": 1, "id": 1}, {"bbox": [2.6, 527.6, 576.0, 339.5], "category_id": 1, "id": 2}, {"bbox": [593.8, 493.9, 456.7, 368.0], "category_id": 1, "id": 3}, {"bbox": [435.0, 380.0, 249.0, 74.0], "category_id": 3, "id": 4}, {"bbox": [655.0, 927.0, 358.0, 81.0], "category_id": 3, "id": 5}], "caption": "Figure 1. Structure of adenosine A1 receptor antagonists.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 555, 760, 570], "ImageBB": [476, 300, 739, 552]}, "corefs": [[1, 4], [2, 0], [3, 5]]}, {"id": 526, "width": 976, "height": 1680, "file_name": "op980043o-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [314.5, 0.0, 170.0, 147.1], "category_id": 1, "id": 0}, {"bbox": [366.5, 744.83, 47.0, 59.0], "category_id": 3, "id": 1}, {"bbox": [273.8, 381.8, 217.2, 159.2], "category_id": 1, "id": 2}, {"bbox": [325.3, 1030.5, 202.7, 157.2], "category_id": 1, "id": 3}, {"bbox": [292.5, 576.0, 208.5, 161.0], "category_id": 1, "id": 4}, {"bbox": [1.0, 405.0, 211.0, 100.0], "category_id": 3, "id": 5}], "caption": "Table 1. Conditions and results for the synthesis of 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 518, 736, 532], "ImageBB": [486, 86, 730, 506]}, "corefs": [[2, 5], [4, 1]]}, {"id": 527, "width": 1108, "height": 892, "file_name": "op900265h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [807.0, 846.0, 38.0, 46.0], "category_id": 3, "id": 0}, {"bbox": [611.0, 4.0, 497.0, 369.0], "category_id": 1, "id": 1}, {"bbox": [3.0, 473.0, 582.0, 363.0], "category_id": 1, "id": 2}, {"bbox": [236.0, 398.0, 36.0, 45.0], "category_id": 3, "id": 3}, {"bbox": [3.0, 3.0, 580.0, 370.0], "category_id": 1, "id": 4}, {"bbox": [234.0, 844.0, 35.0, 45.0], "category_id": 3, "id": 5}, {"bbox": [805.0, 395.0, 41.0, 47.0], "category_id": 3, "id": 6}, {"bbox": [606.4, 472.0, 498.6, 367.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Byproducts on oxidation of 1 using a catalytic amount of H2WO4 or Na2WO4 and H2O2. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 273, 393, 301], "ImageBB": [88, 47, 365, 270]}, "corefs": [[4, 3], [1, 6], [2, 5], [7, 0]]}, {"id": 528, "width": 1248, "height": 2136, "file_name": "op800067v-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1.0, 6.0, 1242.0, 807.0], "category_id": 1, "id": 0}, {"bbox": [589.0, 751.0, 230.0, 68.0], "category_id": 3, "id": 1}, {"bbox": [493.0, 1598.0, 270.0, 59.0], "category_id": 3, "id": 2}, {"bbox": [661.0, 2073.0, 213.0, 63.0], "category_id": 3, "id": 3}, {"bbox": [305.0, 1810.0, 744.7, 235.0], "category_id": 1, "id": 4}, {"bbox": [20.0, 804.0, 1163.9, 825.0], "category_id": 1, "id": 5}], "caption": "Figure 3. Structures of impurities A-C.", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 1009, 649, 1023], "ImageBB": [437, 471, 749, 1005]}, "corefs": [[0, 1], [5, 2], [4, 3]]}, {"id": 529, "width": 1296, "height": 964, "file_name": "op050182n-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [609.46, 312.58, 86.04, 49.02], "category_id": 3, "id": 0}, {"bbox": [295.8, 313.4, 87.3, 47.1], "category_id": 3, "id": 1}, {"bbox": [157.1, 1.3, 243.5, 292.5], "category_id": 1, "id": 2}, {"bbox": [531.6, 79.2, 313.6, 213.2], "category_id": 1, "id": 3}, {"bbox": [908.4, 80.6, 315.4, 212.1], "category_id": 1, "id": 4}, {"bbox": [6.1, 418.6, 422.2, 467.9], "category_id": 1, "id": 5}, {"bbox": [990.9, 914.0, 83.1, 50.0], "category_id": 3, "id": 6}, {"bbox": [534.0, 912.6, 90.0, 51.4], "category_id": 3, "id": 7}, {"bbox": [239.0, 910.0, 91.2, 54.0], "category_id": 3, "id": 8}, {"bbox": [991.0, 320.0, 91.1, 43.0], "category_id": 3, "id": 9}, {"bbox": [427.0, 408.0, 421.2, 485.5], "category_id": 1, "id": 10}, {"bbox": [872.8, 398.6, 423.2, 491.4], "category_id": 1, "id": 11}], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 297, 129, 311], "ImageBB": [80, 53, 404, 294]}, "corefs": [[2, 1], [3, 0], [4, 9], [5, 8], [10, 7], [11, 6]]}, {"id": 530, "width": 1072, "height": 540, "file_name": "op010073i-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [690.41, 453.02, 159.89, 82.29], "category_id": 3, "id": 0}, {"bbox": [137.09, 315.08, 33.7, 38.4], "category_id": 3, "id": 1}, {"bbox": [3.0, 114.0, 296.0, 162.0], "category_id": 1, "id": 2}, {"bbox": [476.0, 6.0, 592.0, 417.0], "category_id": 1, "id": 3}], "caption": "Figure 1. Structures of nelfinavir 2 and its key intermidiate 1. 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X-ray structure of 12.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 904, 622, 918], "ImageBB": [424, 56, 771, 900]}, "corefs": [[12, 7], [4, 8], [0, 9], [6, 10]]}, {"id": 532, "width": 1344, "height": 416, "file_name": "ol3023177-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [282.2, 161.8, 277.5, 241.3], "category_id": 1, "id": 0}], "caption": "Figure 2. Proposed transition state model for the H-bonding directed Cope-type hydroamination. 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X-ray Structure of 30.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 816, 606, 829], "ImageBB": [437, 463, 773, 803]}, "corefs": [[4, 0]]}, {"id": 536, "width": 1352, "height": 348, "file_name": "ol071386m-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [667.0, 306.0, 29.0, 39.0], "category_id": 3, "id": 0}, {"bbox": [487.02, 135.2, 381.0, 178.0], "category_id": 1, "id": 1}], "caption": "Figure 2. 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Natural products and biologically active compounds containing the pyrrole structure. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 793, 417, 821], "ImageBB": [82, 587, 420, 784]}, "corefs": [[2, 0], [1, 3]]}, {"id": 545, "width": 1352, "height": 640, "file_name": "acs.orglett.5b03104-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [496.0, 312.0, 399.0, 259.0], "category_id": 1, "id": 0}, {"bbox": [12.0, 288.0, 477.0, 311.0], "category_id": 1, "id": 1}, {"bbox": [570.0, 53.2, 255.0, 165.9], "category_id": 1, "id": 2}, {"bbox": [15.0, 44.04, 473.0, 182.0], "category_id": 1, "id": 3}, {"bbox": [926.2, 106.3, 362.8, 453.7], "category_id": 1, "id": 4}], "caption": "Figure 1. Examples of organophosphorus compounds and their potential applications. 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Orthogonally functionalized monomer units.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 417, 725, 430], "ImageBB": [439, 138, 777, 405]}, "corefs": [[5, 2], [3, 0], [1, 4]]}, {"id": 549, "width": 1352, "height": 1444, "file_name": "ol0167661-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1136.2, 1129.9, 90.4, 151.4], "category_id": 1, "id": 0}, {"bbox": [803.5, 196.9, 535.0, 525.4], "category_id": 1, "id": 1}, {"bbox": [812.0, 838.0, 513.5, 91.0], "category_id": 3, "id": 2}, {"bbox": [14.0, 133.0, 656.1, 651.0], "category_id": 1, "id": 3}, {"bbox": [17.0, 890.0, 670.3, 263.0], "category_id": 3, "id": 4}, {"bbox": [768.6, 1013.5, 193.1, 379.8], "category_id": 1, "id": 5}, {"bbox": [874.0, 1404.0, 31.0, 36.0], "category_id": 3, "id": 6}, {"bbox": [286.0, 787.0, 55.0, 30.0], "category_id": 3, "id": 7}, {"bbox": [1047.0, 773.0, 27.0, 33.0], "category_id": 3, "id": 8}, {"bbox": [1172.0, 1304.0, 50.0, 35.0], "category_id": 3, "id": 9}], "caption": "Figure 1. Compounds 1-6.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 425, 223, 438], "ImageBB": [73, 52, 411, 413]}, "corefs": [[3, 7], [3, 4], [1, 8], [1, 2], [5, 6], [0, 9]]}, {"id": 550, "width": 1304, "height": 1504, "file_name": "jo9911286-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [135.0, 111.0, 771.0, 598.0], "category_id": 1, "id": 0}, {"bbox": [445.0, 495.0, 77.0, 60.0], "category_id": 3, "id": 1}], "caption": "Figure 2. HPLC chromatogram of DBU-catalyzed reaction of bis-anhydrides 22. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 424, 409, 450], "ImageBB": [74, 35, 400, 411]}, "corefs": [[0, 1]]}, {"id": 551, "width": 2112, "height": 560, "file_name": "jo990209z-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 4.0, 720.0, 556.0], "category_id": 1, "id": 0}, {"bbox": [1161.0, 2.0, 949.0, 558.0], "category_id": 1, "id": 1}], "caption": "Figure 3. Proposed conformational dynamics for deep cavitands 6 and 7.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 218, 484, 231], "ImageBB": [162, 65, 690, 205]}, "corefs": []}, {"id": 552, "width": 1404, "height": 1228, "file_name": "jo961901m-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [140.0, 199.0, 1030.0, 1029.0], "category_id": 1, "id": 0}], "caption": "Table 1. Estimated Stability Constants of Iron(III)              Complexes of 3HOPYna ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [457, 343, 756, 369], "ImageBB": [424, 20, 775, 327]}, "corefs": []}, {"id": 553, "width": 1352, "height": 876, "file_name": "jo201975b-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1037.0, 133.8, 204.0, 212.2], "category_id": 1, "id": 0}, {"bbox": [20.0, 42.0, 351.0, 304.0], "category_id": 1, "id": 1}, {"bbox": [696.0, 481.0, 603.0, 276.0], "category_id": 1, "id": 2}, {"bbox": [55.0, 483.0, 575.0, 325.0], "category_id": 1, "id": 3}, {"bbox": [371.0, 96.0, 648.0, 252.0], "category_id": 1, "id": 4}], "caption": "Figure 1. Bioactive compounds bearing a morpholine moiety.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 912, 382, 927], "ImageBB": [82, 685, 420, 904]}, "corefs": []}, {"id": 554, "width": 2820, "height": 744, "file_name": "ol5029139-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2133.0, 133.0, 129.0, 110.0], "category_id": 1, "id": 0}, {"bbox": [2480.0, 251.0, 42.0, 43.0], "category_id": 3, "id": 1}, {"bbox": [2147.0, 243.0, 58.0, 41.0], "category_id": 3, "id": 2}, {"bbox": [2355.0, 461.0, 56.0, 48.0], "category_id": 3, "id": 3}, {"bbox": [1715.0, 463.0, 42.0, 42.0], "category_id": 3, "id": 4}, {"bbox": [2392.0, 121.0, 276.0, 120.0], "category_id": 1, "id": 5}, {"bbox": [2256.0, 320.0, 311.0, 141.0], "category_id": 1, "id": 6}, {"bbox": [1614.0, 314.0, 317.0, 151.0], "category_id": 1, "id": 7}, {"bbox": [4.0, 44.0, 1350.0, 661.0], "category_id": 1, "id": 8}], "caption": "Figure 1. Molecular structure (50% ellipsoid probability) of 8n in the solid state. Oxygen atoms are shown in red, nitrogen atoms in blue, and chlorine atoms in green.20 ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 316, 417, 358], "ImageBB": [82, 131, 787, 317]}, "corefs": [[0, 2], [5, 1], [6, 3], [7, 4]]}, {"id": 555, "width": 1352, "height": 1208, "file_name": "acs.joc.5b00301-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [259.71, 980.71, 267.83, 180.59], "category_id": 1, "id": 0}, {"bbox": [68.99, 323.97, 265.8, 253.63], "category_id": 1, "id": 1}, {"bbox": [620.2, 4.06, 173.14, 207.64], "category_id": 1, "id": 2}, {"bbox": [606.0, 546.49, 206.28, 176.53], "category_id": 1, "id": 3}, {"bbox": [1138.95, 393.64, 138.65, 181.94], "category_id": 1, "id": 4}, {"bbox": [930.64, 1010.47, 181.94, 133.24], "category_id": 1, "id": 5}], "caption": "Scheme 2. Approaches to Chemoselective Intermolecular Cross-Benzoin Reactions ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 647, 399, 677], "ImageBB": [82, 683, 420, 985]}, "diagram_type": "tree", "corefs": []}, {"id": 556, "width": 1352, "height": 780, "file_name": "acs.joc.5b02382-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 294.9, 214.4, 100.78], "category_id": 1, "id": 0}, {"bbox": [726.39, 248.23, 121.06, 138.77], "category_id": 1, "id": 1}, {"bbox": [461.94, 588.44, 319.91, 106.19], "category_id": 1, "id": 2}, {"bbox": [401.74, 449.79, 201.55, 96.72], "category_id": 1, "id": 3}, {"bbox": [1170.74, 251.61, 181.26, 131.22], "category_id": 1, "id": 4}, {"bbox": [498.46, 537.72, 43.29, 33.14], "category_id": 3, "id": 5}, {"bbox": [516.05, 399.06, 27.73, 32.47], "category_id": 3, "id": 6}, {"bbox": [771.03, 389.59, 42.6, 37.2], "category_id": 3, "id": 7}, {"bbox": [597.88, 703.43, 25.03, 31.11], "category_id": 3, "id": 8}, {"bbox": [522.81, 4.06, 169.08, 94.69], "category_id": 1, "id": 9}, {"bbox": [417.98, 286.11, 186.67, 109.57], "category_id": 1, "id": 10}], "caption": "Scheme 1. Transition-Metal-Catalyzed Cyclization/ Functionalization of Propargylic Amides To Synthesize Oxazoles ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 743, 393, 788], "ImageBB": [82, 795, 420, 990]}, "diagram_type": "tree", "corefs": [[1, 7], [10, 6], [3, 5], [2, 8]]}, {"id": 557, "width": 1356, "height": 1400, "file_name": "acs.oprd.5b00303-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [371.22, 1116.36, 167.39, 132.36], "category_id": 1, "id": 0}, {"bbox": [69.34, 467.13, 220.63, 187.7], "category_id": 1, "id": 1}, {"bbox": [619.86, 1162.58, 244.44, 161.78], "category_id": 1, "id": 2}, {"bbox": [470.67, 336.87, 219.93, 126.06], "category_id": 1, "id": 3}, {"bbox": [462.27, 684.24, 131.68, 62.33], "category_id": 1, "id": 4}, {"bbox": [981.27, 841.82, 196.82, 201.0], "category_id": 1, "id": 5}, {"bbox": [69.34, 72.14, 220.63, 186.29], "category_id": 1, "id": 6}, {"bbox": [69.34, 834.12, 307.48, 240.92], "category_id": 1, "id": 7}, {"bbox": [981.27, 476.94, 218.53, 196.8], "category_id": 1, "id": 8}, {"bbox": [470.67, 134.47, 217.83, 57.43], "category_id": 1, "id": 9}, {"bbox": [423.75, 839.02, 293.47, 193.3], "category_id": 1, "id": 10}, {"bbox": [981.27, 76.34, 216.43, 197.5], "category_id": 1, "id": 11}, {"bbox": [69.34, 1211.61, 238.14, 114.85], "category_id": 1, "id": 12}, {"bbox": [1140.96, 1155.58, 197.52, 203.1], "category_id": 1, "id": 13}, {"bbox": [462.27, 518.96, 175.8, 76.34], "category_id": 1, "id": 14}], "caption": "Scheme 1. Synthetic Routes to N-Vinylalkylamide", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 407, 729, 427], "ImageBB": [448, 432, 787, 782]}, "diagram_type": "multiple", "corefs": []}, {"id": 558, "width": 1704, "height": 1680, "file_name": "acs.orglett.5b02743-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1196.81, 682.91, 381.88, 243.84], "category_id": 1, "id": 0}, {"bbox": [366.54, 1064.01, 197.77, 186.71], "category_id": 1, "id": 1}, {"bbox": [1309.33, 307.78, 311.98, 215.7], "category_id": 1, "id": 2}, {"bbox": [1277.79, 1040.99, 211.4, 150.05], "category_id": 1, "id": 3}, {"bbox": [366.54, 728.1, 206.29, 150.05], "category_id": 1, "id": 4}, {"bbox": [640.17, 1207.24, 154.29, 85.26], "category_id": 1, "id": 5}, {"bbox": [366.54, 18.76, 177.31, 146.64], "category_id": 1, "id": 6}, {"bbox": [790.2, 1191.04, 183.27, 121.07], "category_id": 1, "id": 7}, {"bbox": [1195.95, 17.9, 190.95, 145.79], "category_id": 1, "id": 8}, {"bbox": [976.03, 1173.14, 191.79, 157.73], "category_id": 1, "id": 9}, {"bbox": [741.61, 598.51, 287.27, 187.56], "category_id": 1, "id": 10}, {"bbox": [366.54, 301.81, 441.56, 225.93], "category_id": 1, "id": 11}], "caption": "Scheme 1. Recent New Protocols for Synthetizing Compounds Containing a Sul\ufb01nyl Group ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 671, 364, 701], "ImageBB": [10, 707, 436, 1127]}, "diagram_type": "multiple", "corefs": []}, {"id": 559, "width": 1356, "height": 1596, "file_name": "ja060064v-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [255.39, 1369.25, 318.43, 182.84], "category_id": 1, "id": 0}, {"bbox": [192.34, 159.68, 54.27, 47.9], "category_id": 3, "id": 1}, {"bbox": [79.01, 30.34, 227.45, 93.41], "category_id": 1, "id": 2}, {"bbox": [231.44, 860.67, 201.12, 149.3], "category_id": 1, "id": 3}, {"bbox": [977.65, 1223.95, 57.46, 44.71], "category_id": 3, "id": 4}, {"bbox": [790.9, 1044.31, 472.46, 168.46], "category_id": 1, "id": 5}, {"bbox": [760.57, 1328.54, 177.18, 219.56], "category_id": 1, "id": 6}, {"bbox": [418.99, 1568.85, 60.66, 27.15], "category_id": 3, "id": 7}, {"bbox": [786.11, 503.79, 567.44, 179.64], "category_id": 1, "id": 8}, {"bbox": [840.38, 1569.65, 58.26, 26.35], "category_id": 3, "id": 9}, {"bbox": [0.0, 1048.3, 498.8, 164.47], "category_id": 1, "id": 10}, {"bbox": [76.62, 496.6, 347.16, 158.09], "category_id": 1, "id": 11}, {"bbox": [192.34, 1223.95, 54.27, 46.3], "category_id": 3, "id": 12}, {"bbox": [940.57, 199.28, 306.55, 44.07], "category_id": 3, "id": 13}, {"bbox": [980.8, 758.74, 151.36, 34.49], "category_id": 3, "id": 14}, {"bbox": [195.26, 724.26, 51.73, 36.4], "category_id": 3, "id": 15}, {"bbox": [940.94, 157.28, 333.16, 41.52], "category_id": 3, "id": 16}, {"bbox": [981.0, 725.6, 194.7, 34.2], "category_id": 3, "id": 17}, {"bbox": [841.18, 3.19, 284.91, 117.37], "category_id": 1, "id": 18}], "caption": "Scheme 1. Second Generation Synthesis of Hydroxydecanoic Acid Building Block (15)a ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 387, 88], "ImageBB": [73, 92, 412, 491]}, "diagram_type": "tree", "corefs": [[2, 1], [18, 16], [18, 13], [8, 17], [8, 14], [11, 15], [10, 12], [5, 4], [0, 7], [6, 9]]}, {"id": 560, "width": 1344, "height": 560, "file_name": "ja9810742-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [607.79, 20.86, 254.14, 149.84], "category_id": 1, "id": 0}, {"bbox": [630.65, 178.3, 231.28, 41.72], "category_id": 3, "id": 1}, {"bbox": [8.74, 6.06, 190.27, 158.11], "category_id": 1, "id": 2}, {"bbox": [494.84, 507.99, 32.94, 37.01], "category_id": 3, "id": 3}, {"bbox": [24.2, 349.2, 264.9, 158.12], "category_id": 1, "id": 4}, {"bbox": [76.65, 176.28, 55.8, 39.03], "category_id": 3, "id": 5}, {"bbox": [119.0, 509.34, 30.26, 36.33], "category_id": 3, "id": 6}, {"bbox": [991.02, 345.17, 350.29, 156.1], "category_id": 1, "id": 7}, {"bbox": [353.65, 393.61, 308.6, 53.83], "category_id": 1, "id": 8}, {"bbox": [1056.91, 509.34, 197.67, 44.41], "category_id": 3, "id": 9}, {"bbox": [714.02, 368.72, 106.23, 108.32], "category_id": 1, "id": 10}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 156, 495, 170], "ImageBB": [440, 174, 776, 314]}, "diagram_type": "tree", "corefs": [[2, 5], [0, 1], [4, 6], [8, 3], [7, 9]]}, {"id": 561, "width": 1048, "height": 1648, "file_name": "jo010904i-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [361.78, 277.83, 37.09, 41.22], "category_id": 3, "id": 0}, {"bbox": [561.22, 1003.31, 101.36, 39.57], "category_id": 3, "id": 1}, {"bbox": [229.1, 1241.56, 696.37, 193.74], "category_id": 1, "id": 2}, {"bbox": [184.6, 3.3, 426.89, 258.04], "category_id": 1, "id": 3}, {"bbox": [689.78, 1046.18, 267.83, 150.87], "category_id": 1, "id": 4}, {"bbox": [824.93, 275.35, 50.27, 45.35], "category_id": 3, "id": 5}, {"bbox": [668.35, 66.78, 379.65, 179.72], "category_id": 1, "id": 6}, {"bbox": [365.08, 401.49, 558.74, 184.67], "category_id": 1, "id": 7}, {"bbox": [361.78, 793.08, 565.34, 198.69], "category_id": 1, "id": 8}, {"bbox": [561.22, 596.05, 101.36, 40.4], "category_id": 3, "id": 9}, {"bbox": [561.22, 1452.61, 228.27, 89.04], "category_id": 3, "id": 10}], "caption": "Scheme 1a", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 451, 641, 465], "ImageBB": [453, 471, 715, 883]}, "diagram_type": "tree", "corefs": [[3, 0], [6, 5], [7, 9], [8, 1], [2, 10]]}, {"id": 562, "width": 1356, "height": 796, "file_name": "jo200480h-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [20.35, 58.37, 291.01, 250.47], "category_id": 1, "id": 0}, {"bbox": [1047.36, 422.2, 269.3, 251.82], "category_id": 1, "id": 1}, {"bbox": [18.32, 696.42, 68.51, 54.98], "category_id": 3, "id": 2}, {"bbox": [0.0, 458.17, 221.14, 264.72], "category_id": 1, "id": 3}, {"bbox": [15.3, 0.0, 60.67, 54.98], "category_id": 3, "id": 4}, {"bbox": [241.9, 509.4, 110.1, 44.7], "category_id": 1, "id": 5}, {"bbox": [841.14, 212.46, 142.45, 52.26], "category_id": 1, "id": 6}, {"bbox": [1203.37, 696.42, 57.66, 52.27], "category_id": 3, "id": 7}, {"bbox": [1045.32, 61.77, 271.34, 253.86], "category_id": 1, "id": 8}, {"bbox": [525.03, 249.11, 314.75, 250.47], "category_id": 1, "id": 9}, {"bbox": [1203.37, 6.11, 61.73, 50.23], "category_id": 3, "id": 10}, {"bbox": [242.32, 561.08, 109.42, 42.95], "category_id": 1, "id": 11}, {"bbox": [242.32, 615.28, 109.42, 43.97], "category_id": 1, "id": 12}, {"bbox": [814.99, 599.94, 206.57, 48.06], "category_id": 1, "id": 13}], "caption": "Scheme 1. Recent Methods for 5-Azaindole Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 370, 107], "ImageBB": [71, 117, 410, 316]}, "diagram_type": "tree", "corefs": [[0, 4], [8, 10], [1, 7], [3, 2]]}, {"id": 563, "width": 2820, "height": 1056, "file_name": "jo202324f-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1365.56, 52.21, 242.64, 255.43], "category_id": 1, "id": 0}, {"bbox": [1668.86, 397.95, 475.41, 272.36], "category_id": 1, "id": 1}, {"bbox": [905.67, 424.76, 466.95, 221.56], "category_id": 1, "id": 2}, {"bbox": [1904.45, 46.57, 272.27, 245.54], "category_id": 1, "id": 3}, {"bbox": [640.46, 128.42, 217.25, 141.11], "category_id": 1, "id": 4}, {"bbox": [914.14, 681.6, 521.96, 306.22], "category_id": 1, "id": 5}, {"bbox": [868.99, 142.53, 251.11, 135.47], "category_id": 1, "id": 6}, {"bbox": [1668.86, 683.01, 476.82, 330.21], "category_id": 1, "id": 7}, {"bbox": [640.46, 500.97, 217.25, 139.7], "category_id": 1, "id": 8}], "caption": "Scheme 1. Our Previous Works on the Cascade Reactions of Stable Sulfur Ylides with Nitroolefins", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 638, 110], "ImageBB": [82, 116, 787, 380]}, "diagram_type": "multiple", "corefs": []}, {"id": 564, "width": 1356, "height": 808, "file_name": "jo300771f-Scheme-c12.png", "license": 0, "bboxes": [{"bbox": [562.41, 1.6, 195.32, 46.02], "category_id": 1, "id": 0}, {"bbox": [214.71, 343.15, 160.56, 45.0], "category_id": 1, "id": 1}, {"bbox": [665.69, 720.5, 201.46, 38.86], "category_id": 3, "id": 2}, {"bbox": [666.13, 668.41, 233.37, 46.89], "category_id": 3, "id": 3}, {"bbox": [286.26, 251.08, 59.69, 46.82], "category_id": 3, "id": 4}, {"bbox": [1015.47, 249.04, 63.77, 49.54], "category_id": 3, "id": 5}, {"bbox": [879.81, 34.61, 337.81, 202.22], "category_id": 1, "id": 6}, {"bbox": [530.46, 352.87, 284.23, 293.15], "category_id": 1, "id": 7}, {"bbox": [246.92, 48.86, 187.22, 177.79], "category_id": 1, "id": 8}], "caption": "Scheme 12. Preparation of 12b", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 415, 625, 430], "ImageBB": [448, 436, 787, 638]}, "diagram_type": "multiple", "corefs": [[8, 4], [6, 5], [7, 3], [7, 2]]}, {"id": 565, "width": 1704, "height": 1256, "file_name": "jo502578x-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [397.23, 0.0, 291.53, 158.48], "category_id": 1, "id": 0}, {"bbox": [904.42, 568.3, 292.39, 147.4], "category_id": 1, "id": 1}, {"bbox": [797.87, 11.08, 139.8, 138.02], "category_id": 1, "id": 2}, {"bbox": [395.53, 823.06, 293.23, 159.33], "category_id": 1, "id": 3}, {"bbox": [667.45, 562.34, 138.09, 135.47], "category_id": 1, "id": 4}, {"bbox": [277.04, 547.0, 291.53, 132.92], "category_id": 1, "id": 5}, {"bbox": [667.45, 301.62, 138.95, 109.06], "category_id": 1, "id": 6}, {"bbox": [904.42, 284.58, 292.39, 143.99], "category_id": 1, "id": 7}, {"bbox": [278.74, 263.28, 288.12, 157.62], "category_id": 1, "id": 8}, {"bbox": [797.87, 832.43, 139.8, 140.59], "category_id": 1, "id": 9}], "caption": "Scheme 2. Postulated Mechanism of the NHC-Catalyzed H/ D Exchange Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 766, 784, 796], "ImageBB": [433, 813, 859, 1127]}, "diagram_type": "tree", "corefs": []}, {"id": 566, "width": 1352, "height": 1584, "file_name": "jo961323+-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [690.03, 992.87, 68.13, 47.55], "category_id": 3, "id": 0}, {"bbox": [690.03, 1500.8, 71.3, 46.75], "category_id": 3, "id": 1}, {"bbox": [128.34, 1058.64, 342.25, 462.76], "category_id": 1, "id": 2}, {"bbox": [6.62, 1.86, 287.18, 568.57], "category_id": 1, "id": 3}, {"bbox": [965.0, 3.77, 374.61, 433.55], "category_id": 1, "id": 4}, {"bbox": [42.75, 564.73, 346.08, 437.35], "category_id": 1, "id": 5}, {"bbox": [476.3, 570.43, 346.09, 433.56], "category_id": 1, "id": 6}, {"bbox": [995.43, 566.63, 336.58, 454.47], "category_id": 1, "id": 7}, {"bbox": [1014.45, 1068.64, 273.82, 418.34], "category_id": 1, "id": 8}, {"bbox": [61.76, 435.42, 72.26, 53.24], "category_id": 3, "id": 9}, {"bbox": [668.36, 433.52, 66.56, 53.24], "category_id": 3, "id": 10}, {"bbox": [1157.06, 431.62, 79.87, 53.24], "category_id": 3, "id": 11}, {"bbox": [250.02, 990.68, 74.16, 51.34], "category_id": 3, "id": 12}, {"bbox": [1132.34, 992.58, 76.06, 47.54], "category_id": 3, "id": 13}, {"bbox": [217.69, 1502.2, 79.87, 55.14], "category_id": 3, "id": 14}, {"bbox": [1065.79, 1500.29, 163.53, 55.15], "category_id": 3, "id": 15}, {"bbox": [480.88, 7.13, 379.48, 438.2], "category_id": 1, "id": 16}, {"bbox": [535.55, 1058.64, 282.03, 382.73], "category_id": 1, "id": 17}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 275, 63], "ImageBB": [73, 70, 411, 466]}, "diagram_type": "tree", "corefs": [[3, 9], [16, 10], [4, 11], [5, 12], [6, 0], [7, 13], [2, 14], [17, 1], [8, 15]]}, {"id": 567, "width": 1776, "height": 1476, "file_name": "jo980755c-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [837.8, 57.74, 318.3, 76.39], "category_id": 1, "id": 0}, {"bbox": [0.0, 71.95, 359.82, 81.73], "category_id": 1, "id": 1}, {"bbox": [1163.86, 1153.91, 242.55, 73.73], "category_id": 1, "id": 2}, {"bbox": [771.04, 1290.03, 223.26, 49.61], "category_id": 3, "id": 3}, {"bbox": [419.35, 1278.28, 270.08, 56.85], "category_id": 3, "id": 4}, {"bbox": [422.9, 59.5, 190.13, 87.1], "category_id": 1, "id": 5}, {"bbox": [762.29, 533.87, 541.06, 192.77], "category_id": 1, "id": 6}, {"bbox": [455.77, 1103.28, 204.34, 154.57], "category_id": 1, "id": 7}, {"bbox": [747.18, 1115.72, 221.22, 150.12], "category_id": 1, "id": 8}, {"bbox": [1253.6, 0.0, 89.73, 183.88], "category_id": 1, "id": 9}], "caption": "Scheme 5. Proposed Mechanism for the Oxidation of Aromatic Alkenes by Oxoruthenium(IV)", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [114, 64, 734, 78], "ImageBB": [203, 83, 647, 452]}, "diagram_type": "tree", "corefs": [[7, 4], [8, 3]]}, {"id": 568, "width": 2080, "height": 648, "file_name": "jo9816515-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [0.0, 4.16, 288.22, 352.98], "category_id": 1, "id": 0}, {"bbox": [559.8, 79.13, 390.19, 305.08], "category_id": 1, "id": 1}, {"bbox": [1801.14, 394.62, 139.43, 55.19], "category_id": 3, "id": 2}, {"bbox": [74.92, 399.83, 126.94, 58.31], "category_id": 3, "id": 3}, {"bbox": [1204.92, 397.75, 129.03, 57.26], "category_id": 3, "id": 4}, {"bbox": [675.3, 394.62, 135.27, 54.15], "category_id": 3, "id": 5}, {"bbox": [1697.09, 78.09, 382.91, 306.12], "category_id": 1, "id": 6}, {"bbox": [1056.13, 57.27, 388.11, 296.75], "category_id": 1, "id": 7}], "caption": "Scheme 10", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [387, 531, 458, 545], "ImageBB": [165, 551, 685, 713]}, "diagram_type": "single", "corefs": [[0, 3], [1, 5], [7, 4], [6, 2]]}, {"id": 569, "width": 1356, "height": 812, "file_name": "ol0513995-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [0.0, 58.35, 259.13, 115.35], "category_id": 1, "id": 0}, {"bbox": [845.89, 0.0, 263.87, 175.06], "category_id": 1, "id": 1}, {"bbox": [1010.05, 183.88, 40.02, 52.93], "category_id": 3, "id": 2}, {"bbox": [124.81, 481.08, 192.65, 215.77], "category_id": 1, "id": 3}, {"bbox": [214.36, 707.03, 42.05, 46.82], "category_id": 3, "id": 4}, {"bbox": [845.21, 479.04, 266.59, 219.17], "category_id": 1, "id": 5}, {"bbox": [113.96, 187.27, 31.88, 43.43], "category_id": 3, "id": 6}, {"bbox": [1010.05, 705.67, 40.02, 48.18], "category_id": 3, "id": 7}], "caption": "Scheme 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 547, 265, 560], "ImageBB": [73, 565, 412, 768]}, "diagram_type": "tree", "corefs": [[0, 6], [1, 2], [3, 4], [5, 7]]}, {"id": 570, "width": 1352, "height": 1224, "file_name": "ol052474e-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [780.49, 692.45, 313.15, 261.03], "category_id": 1, "id": 0}, {"bbox": [326.67, 2.7, 117.01, 192.05], "category_id": 1, "id": 1}, {"bbox": [803.49, 363.13, 267.15, 211.66], "category_id": 1, "id": 2}, {"bbox": [744.65, 956.18, 388.22, 100.76], "category_id": 3, "id": 3}, {"bbox": [325.32, 362.46, 120.39, 214.36], "category_id": 1, "id": 4}, {"bbox": [803.49, 2.7, 267.15, 192.05], "category_id": 1, "id": 5}, {"bbox": [744.65, 193.4, 388.22, 148.77], "category_id": 3, "id": 6}, {"bbox": [225.9, 695.84, 299.2, 125.77], "category_id": 1, "id": 7}, {"bbox": [744.65, 577.5, 386.19, 100.08], "category_id": 3, "id": 8}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 555, 265, 568], "ImageBB": [73, 573, 411, 879]}, "diagram_type": "multiple", "corefs": [[5, 6], [2, 8], [0, 3]]}, {"id": 571, "width": 1352, "height": 960, "file_name": "ol060123+-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [77.78, 781.44, 213.72, 73.01], "category_id": 1, "id": 0}, {"bbox": [698.66, 526.59, 55.46, 46.65], "category_id": 3, "id": 1}, {"bbox": [906.97, 761.84, 263.77, 127.08], "category_id": 1, "id": 2}, {"bbox": [906.97, 371.79, 370.63, 127.76], "category_id": 1, "id": 3}, {"bbox": [80.2, 395.28, 153.27, 86.43], "category_id": 1, "id": 4}, {"bbox": [411.89, 360.98, 280.68, 138.57], "category_id": 1, "id": 5}], "caption": "Scheme 2. Possible Reaction Mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [497, 575, 717, 588], "ImageBB": [439, 593, 777, 833]}, "diagram_type": "graph", "corefs": [[5, 1]]}, {"id": 572, "width": 1352, "height": 1228, "file_name": "ol060531d-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [471.41, 400.31, 289.47, 288.06], "category_id": 1, "id": 0}, {"bbox": [988.81, 314.43, 46.66, 52.07], "category_id": 3, "id": 1}, {"bbox": [928.61, 0.0, 299.62, 293.47], "category_id": 1, "id": 2}, {"bbox": [971.22, 810.08, 257.01, 294.15], "category_id": 1, "id": 3}, {"bbox": [1033.44, 1123.84, 54.11, 51.39], "category_id": 3, "id": 4}, {"bbox": [431.5, 314.43, 44.64, 51.39], "category_id": 3, "id": 5}, {"bbox": [542.42, 688.37, 48.7, 48.68], "category_id": 3, "id": 6}, {"bbox": [470.73, 1117.07, 49.37, 49.37], "category_id": 3, "id": 7}, {"bbox": [1005.04, 686.34, 47.34, 50.71], "category_id": 3, "id": 8}, {"bbox": [938.08, 398.95, 290.15, 291.44], "category_id": 1, "id": 9}, {"bbox": [367.93, 810.08, 291.5, 292.12], "category_id": 1, "id": 10}, {"bbox": [131.21, 0.0, 509.96, 352.97], "category_id": 1, "id": 11}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 153, 631, 166], "ImageBB": [439, 171, 777, 478]}, "diagram_type": "multiple", "corefs": [[11, 5], [2, 1], [0, 6], [9, 8], [10, 7], [3, 4]]}, {"id": 573, "width": 1352, "height": 616, "file_name": "ol071386m-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [752.76, 138.73, 119.72, 62.93], "category_id": 3, "id": 0}, {"bbox": [561.36, 353.25, 179.23, 37.89], "category_id": 3, "id": 1}, {"bbox": [725.71, 341.74, 265.8, 215.76], "category_id": 1, "id": 2}, {"bbox": [6.76, 181.36, 117.69, 98.8], "category_id": 1, "id": 3}, {"bbox": [754.12, 451.37, 43.28, 33.84], "category_id": 3, "id": 4}, {"bbox": [1233.64, 451.37, 110.24, 37.9], "category_id": 3, "id": 5}, {"bbox": [869.09, 525.14, 27.73, 29.77], "category_id": 3, "id": 6}, {"bbox": [561.36, 137.37, 129.18, 60.23], "category_id": 3, "id": 7}, {"bbox": [1086.88, 305.2, 246.18, 219.26], "category_id": 1, "id": 8}, {"bbox": [134.59, 228.05, 93.34, 144.15], "category_id": 1, "id": 9}, {"bbox": [353.72, 190.16, 214.4, 120.45], "category_id": 1, "id": 10}, {"bbox": [723.68, 2.71, 206.96, 119.78], "category_id": 1, "id": 11}], "caption": "Scheme 6. Proposed Reaction Pathways for 6a and 10", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [461, 162, 754, 175], "ImageBB": [439, 180, 777, 334]}, "diagram_type": "tree", "corefs": [[10, 7], [10, 1], [11, 0], [2, 4], [2, 6], [8, 5]]}, {"id": 574, "width": 1356, "height": 648, "file_name": "ol3023903-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [6.11, 385.3, 290.32, 169.59], "category_id": 1, "id": 0}, {"bbox": [527.75, 37.31, 438.88, 225.89], "category_id": 1, "id": 1}, {"bbox": [0.0, 2.71, 341.2, 304.58], "category_id": 1, "id": 2}, {"bbox": [572.52, 297.12, 312.71, 291.69], "category_id": 1, "id": 3}, {"bbox": [718.36, 267.27, 40.7, 33.92], "category_id": 3, "id": 4}, {"bbox": [195.36, 267.95, 42.06, 33.24], "category_id": 3, "id": 5}, {"bbox": [106.5, 563.03, 29.85, 33.92], "category_id": 3, "id": 6}, {"bbox": [353.41, 330.36, 156.02, 108.53], "category_id": 1, "id": 7}, {"bbox": [718.36, 563.03, 41.38, 35.27], "category_id": 3, "id": 8}, {"bbox": [353.41, 101.75, 143.13, 46.13], "category_id": 1, "id": 9}, {"bbox": [1017.51, 128.89, 196.72, 201.47], "category_id": 1, "id": 10}], "caption": "Scheme 5. Combination of the Xanthate Addition with the Allylation Reaction ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 446, 750, 473], "ImageBB": [436, 484, 775, 646]}, "diagram_type": "tree", "corefs": [[2, 5], [1, 4], [0, 6], [3, 8]]}, {"id": 575, "width": 1344, "height": 1680, "file_name": "ol303482k-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [124.43, 534.51, 398.51, 257.17], "category_id": 1, "id": 0}, {"bbox": [298.46, 758.9, 57.17, 52.95], "category_id": 3, "id": 1}, {"bbox": [892.86, 0.0, 313.6, 254.65], "category_id": 1, "id": 2}, {"bbox": [893.7, 525.26, 312.76, 271.46], "category_id": 1, "id": 3}, {"bbox": [186.64, 239.52, 259.79, 48.74], "category_id": 3, "id": 4}, {"bbox": [913.04, 236.16, 227.84, 52.1], "category_id": 3, "id": 5}, {"bbox": [152.17, 1160.62, 325.37, 261.37], "category_id": 1, "id": 6}, {"bbox": [152.17, 20.17, 343.86, 212.63], "category_id": 1, "id": 7}, {"bbox": [1039.15, 759.74, 41.2, 47.9], "category_id": 3, "id": 8}, {"bbox": [295.1, 1393.42, 55.49, 47.9], "category_id": 3, "id": 9}, {"bbox": [1045.88, 1386.69, 61.37, 47.91], "category_id": 3, "id": 10}, {"bbox": [893.7, 1166.5, 328.73, 252.97], "category_id": 1, "id": 11}], "caption": "Scheme 2. Synthesis of the Bromide 12", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 643, 102], "ImageBB": [437, 111, 773, 531]}, "diagram_type": "tree", "corefs": [[7, 4], [2, 5], [3, 8], [0, 1], [6, 9], [11, 10]]}, {"id": 576, "width": 2820, "height": 916, "file_name": "ol502425f-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1801.47, 315.99, 56.43, 50.78], "category_id": 3, "id": 0}, {"bbox": [1145.49, 83.23, 383.71, 290.6], "category_id": 1, "id": 1}, {"bbox": [2353.06, 435.9, 458.48, 416.14], "category_id": 1, "id": 2}, {"bbox": [218.66, 811.13, 49.37, 46.56], "category_id": 3, "id": 3}, {"bbox": [576.98, 499.38, 435.91, 338.56], "category_id": 1, "id": 4}, {"bbox": [1736.58, 12.7, 465.53, 344.2], "category_id": 1, "id": 5}, {"bbox": [2482.84, 792.8, 52.2, 52.19], "category_id": 3, "id": 6}, {"bbox": [1509.45, 117.09, 217.25, 98.74], "category_id": 1, "id": 7}, {"bbox": [12.8, 134.7, 179.06, 103.0], "category_id": 1, "id": 8}, {"bbox": [1716.9, 436.7, 432.1, 400.5], "category_id": 1, "id": 9}, {"bbox": [1854.43, 786.62, 44.67, 48.91], "category_id": 3, "id": 10}, {"bbox": [1156.78, 499.38, 444.37, 338.56], "category_id": 1, "id": 11}, {"bbox": [355.5, 88.87, 235.59, 176.34], "category_id": 1, "id": 12}, {"bbox": [2355.88, 12.7, 464.12, 409.09], "category_id": 1, "id": 13}, {"bbox": [1261.17, 371.01, 146.71, 46.55], "category_id": 3, "id": 14}, {"bbox": [620.71, 88.87, 256.75, 179.16], "category_id": 1, "id": 15}, {"bbox": [26.8, 479.63, 438.73, 362.54], "category_id": 1, "id": 16}], "caption": "Scheme 1. Plausible Biogenetic Pathway for 1 and 2 (Red, Newly Formed Rings)", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 530, 110], "ImageBB": [82, 116, 787, 345]}, "diagram_type": "tree", "corefs": [[1, 14], [5, 0], [16, 3], [9, 10], [2, 6]]}, {"id": 577, "width": 1348, "height": 888, "file_name": "ol802669r-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [56.64, 462.3, 294.02, 330.83], "category_id": 1, "id": 0}, {"bbox": [1098.5, 711.52, 39.11, 43.17], "category_id": 3, "id": 1}, {"bbox": [463.94, 496.38, 333.13, 333.84], "category_id": 1, "id": 2}, {"bbox": [574.54, 678.47, 37.76, 46.54], "category_id": 3, "id": 3}, {"bbox": [191.51, 772.22, 33.72, 43.16], "category_id": 3, "id": 4}, {"bbox": [364.82, 254.26, 42.48, 42.49], "category_id": 3, "id": 5}, {"bbox": [956.88, 468.73, 334.48, 335.19], "category_id": 1, "id": 6}, {"bbox": [975.09, 0.0, 293.34, 306.86], "category_id": 1, "id": 7}, {"bbox": [159.82, 20.91, 422.13, 246.84], "category_id": 1, "id": 8}, {"bbox": [1080.29, 223.24, 37.76, 49.9], "category_id": 3, "id": 9}], "caption": "Scheme 3. Reaction with Diaminoacetal 5", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [483, 74, 702, 89], "ImageBB": [425, 96, 762, 318]}, "diagram_type": "graph", "corefs": [[8, 5], [7, 9], [0, 4], [2, 3], [6, 1]]}, {"id": 578, "width": 1224, "height": 1020, "file_name": "op010052o-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 116.32, 199.61, 361.21], "category_id": 1, "id": 0}, {"bbox": [56.94, 478.75, 37.36, 45.31], "category_id": 3, "id": 1}, {"bbox": [720.07, 576.09, 503.93, 377.13], "category_id": 1, "id": 2}, {"bbox": [443.92, 90.61, 504.54, 375.9], "category_id": 1, "id": 3}, {"bbox": [309.83, 254.07, 44.7, 48.36], "category_id": 3, "id": 4}, {"bbox": [792.32, 476.91, 41.03, 43.47], "category_id": 3, "id": 5}, {"bbox": [303.09, 966.69, 43.48, 47.14], "category_id": 3, "id": 6}, {"bbox": [947.85, 965.46, 39.8, 46.53], "category_id": 3, "id": 7}, {"bbox": [20.21, 580.99, 505.15, 372.84], "category_id": 1, "id": 8}, {"bbox": [263.9, 2.45, 149.41, 247.95], "category_id": 1, "id": 9}], "caption": "Scheme 1. Reported synthesis of 6", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 269, 639, 283], "ImageBB": [455, 288, 761, 543]}, "diagram_type": "multiple", "corefs": [[9, 4], [0, 1], [3, 5], [8, 6], [2, 7]]}, {"id": 579, "width": 1248, "height": 888, "file_name": "op0100706-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [547.52, 0.0, 415.79, 194.88], "category_id": 1, "id": 0}, {"bbox": [14.98, 648.99, 494.46, 148.04], "category_id": 1, "id": 1}, {"bbox": [0.0, 255.47, 417.66, 206.13], "category_id": 1, "id": 2}, {"bbox": [596.22, 255.47, 466.98, 206.13], "category_id": 1, "id": 3}, {"bbox": [596.22, 647.12, 367.09, 231.73], "category_id": 1, "id": 4}, {"bbox": [329.81, 782.45, 29.85, 31.98], "category_id": 3, "id": 5}, {"bbox": [181.05, 428.5, 41.83, 43.09], "category_id": 3, "id": 6}, {"bbox": [752.3, 416.63, 43.7, 47.47], "category_id": 3, "id": 7}, {"bbox": [736.69, 838.88, 45.57, 44.35], "category_id": 3, "id": 8}], "caption": "Scheme 2. Outline of cephalosporin C biosynthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 572, 362, 586], "ImageBB": [86, 591, 398, 813]}, "diagram_type": "tree", "corefs": [[2, 6], [3, 7], [1, 5], [4, 8]]}, {"id": 580, "width": 1112, "height": 612, "file_name": "op025619v-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [497.87, 261.87, 189.69, 244.09], "category_id": 1, "id": 0}, {"bbox": [429.45, 5.0, 222.51, 172.36], "category_id": 1, "id": 1}, {"bbox": [1007.42, 563.78, 44.5, 45.04], "category_id": 3, "id": 2}, {"bbox": [0.0, 50.6, 225.29, 128.99], "category_id": 1, "id": 3}, {"bbox": [881.14, 246.31, 230.86, 272.99], "category_id": 1, "id": 4}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 216, 501, 230], "ImageBB": [469, 235, 747, 388]}, "diagram_type": "multiple", "corefs": [[4, 2]]}, {"id": 581, "width": 968, "height": 2124, "file_name": "op049953y-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [86.0, 1466.29, 882.0, 310.26], "category_id": 1, "id": 0}, {"bbox": [0.0, 1887.06, 968.0, 160.44], "category_id": 1, "id": 1}, {"bbox": [561.62, 578.02, 49.9, 49.94], "category_id": 3, "id": 2}, {"bbox": [313.19, 464.33, 587.11, 158.31], "category_id": 1, "id": 3}, {"bbox": [457.58, 2079.37, 57.33, 44.63], "category_id": 3, "id": 4}, {"bbox": [86.0, 0.0, 475.62, 272.01], "category_id": 1, "id": 5}, {"bbox": [86.0, 807.52, 882.0, 313.45], "category_id": 1, "id": 6}, {"bbox": [248.43, 285.82, 45.65, 49.94], "category_id": 3, "id": 7}, {"bbox": [274.97, 1807.37, 35.04, 45.68], "category_id": 3, "id": 8}], "caption": "Scheme 2. Initial route to 1 via the amide intermediate derived from 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 752, 81], "ImageBB": [487, 85, 729, 616]}, "diagram_type": "tree", "corefs": [[5, 7], [3, 2], [0, 8], [1, 4]]}, {"id": 582, "width": 2032, "height": 2812, "file_name": "op050151s-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [367.24, 938.27, 73.17, 59.08], "category_id": 3, "id": 0}, {"bbox": [160.41, 1291.35, 769.66, 409.35], "category_id": 1, "id": 1}, {"bbox": [748.56, 2088.95, 97.09, 59.09], "category_id": 3, "id": 2}, {"bbox": [1317.01, 1745.72, 671.18, 399.5], "category_id": 1, "id": 3}, {"bbox": [1526.67, 2730.41, 56.28, 52.05], "category_id": 3, "id": 4}, {"bbox": [1317.01, 631.61, 593.79, 413.57], "category_id": 1, "id": 5}, {"bbox": [614.89, 419.2, 80.2, 54.86], "category_id": 3, "id": 6}, {"bbox": [975.1, 198.35, 46.43, 56.26], "category_id": 3, "id": 7}, {"bbox": [98.49, 2384.36, 765.45, 406.54], "category_id": 1, "id": 8}, {"bbox": [443.23, 270.09, 461.51, 163.17], "category_id": 1, "id": 9}, {"bbox": [747.15, 1676.79, 98.5, 61.9], "category_id": 3, "id": 10}, {"bbox": [1550.59, 1014.23, 64.72, 57.68], "category_id": 3, "id": 11}, {"bbox": [160.41, 1685.23, 757.0, 405.13], "category_id": 1, "id": 12}, {"bbox": [1934.72, 2081.92, 97.28, 63.3], "category_id": 3, "id": 13}, {"bbox": [98.49, 606.29, 711.98, 403.72], "category_id": 1, "id": 14}, {"bbox": [367.24, 2720.56, 73.17, 61.9], "category_id": 3, "id": 15}, {"bbox": [1380.63, 1309.74, 638.02, 391.59], "category_id": 1, "id": 16}, {"bbox": [1934.72, 1645.84, 97.28, 66.12], "category_id": 3, "id": 17}, {"bbox": [1317.01, 2408.28, 658.51, 403.72], "category_id": 1, "id": 18}, {"bbox": [1246.66, 244.77, 189.96, 151.92], "category_id": 1, "id": 19}, {"bbox": [811.88, 0.0, 358.8, 272.9], "category_id": 1, "id": 20}, {"bbox": [1317.01, 402.32, 70.36, 50.64], "category_id": 3, "id": 21}], "caption": "Scheme 3. Efficient three-step prodrug synthesis using n-Bu3GeH as a highly stereoselective debromination reagenta", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 717, 68], "ImageBB": [171, 71, 679, 774]}, "diagram_type": "tree", "corefs": [[20, 7], [19, 21], [9, 6], [14, 0], [5, 11], [16, 17], [1, 10], [12, 2], [3, 13], [8, 15], [18, 4]]}, {"id": 583, "width": 1184, "height": 588, "file_name": "op050182n-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [183.02, 209.67, 40.28, 43.24], "category_id": 3, "id": 0}, {"bbox": [763.47, 197.83, 40.28, 47.38], "category_id": 3, "id": 1}, {"bbox": [738.59, 286.67, 432.97, 216.78], "category_id": 1, "id": 2}, {"bbox": [14.22, 280.75, 435.93, 307.25], "category_id": 1, "id": 3}, {"bbox": [174.73, 496.93, 39.09, 47.39], "category_id": 3, "id": 4}, {"bbox": [543.73, 2.37, 434.15, 213.22], "category_id": 1, "id": 5}, {"bbox": [0.0, 2.37, 336.42, 215.0], "category_id": 1, "id": 6}, {"bbox": [999.2, 501.67, 40.28, 46.2], "category_id": 3, "id": 7}], "caption": "Scheme 2. Synthesis of 5 using diastereoselective reduction of 7 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 254, 406, 282], "ImageBB": [94, 286, 390, 433]}, "diagram_type": "multiple", "corefs": [[6, 0], [5, 1], [3, 4], [2, 7]]}, {"id": 584, "width": 2136, "height": 320, "file_name": "op060099f-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [1318.57, 249.66, 98.31, 66.15], "category_id": 3, "id": 0}, {"bbox": [1807.96, 3.2, 328.04, 243.26], "category_id": 1, "id": 1}, {"bbox": [1860.32, 257.13, 255.38, 62.87], "category_id": 3, "id": 2}, {"bbox": [0.0, 4.27, 329.11, 242.19], "category_id": 1, "id": 3}, {"bbox": [1197.83, 13.87, 329.11, 213.39], "category_id": 1, "id": 4}, {"bbox": [589.83, 4.27, 330.18, 242.19], "category_id": 1, "id": 5}], "caption": "Scheme 5. Oxidation of 2,3-substituted indoles as reported by Hino et al.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 464, 483, 478], "ImageBB": [158, 482, 692, 562]}, "diagram_type": "single", "corefs": [[4, 0], [1, 2]]}, {"id": 585, "width": 2820, "height": 512, "file_name": "op200351g-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [2003.2, 420.42, 53.61, 47.97], "category_id": 3, "id": 0}, {"bbox": [1821.22, 208.8, 371.02, 173.53], "category_id": 1, "id": 1}, {"bbox": [550.18, 417.6, 43.73, 50.79], "category_id": 3, "id": 2}, {"bbox": [1532.03, 14.11, 273.67, 363.99], "category_id": 1, "id": 3}, {"bbox": [1654.76, 416.19, 66.3, 55.02], "category_id": 3, "id": 4}, {"bbox": [479.64, 29.63, 253.93, 331.54], "category_id": 1, "id": 5}, {"bbox": [1063.67, 417.6, 60.66, 50.79], "category_id": 3, "id": 6}, {"bbox": [969.15, 25.39, 259.57, 335.78], "category_id": 1, "id": 7}], "caption": "Scheme 4. Synthesis of ketoamide 11 via azide/Staudinger sequence", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 735, 466, 750], "ImageBB": [82, 756, 787, 884]}, "diagram_type": "single", "corefs": [[5, 2], [7, 6], [3, 4], [1, 0]]}, {"id": 586, "width": 1356, "height": 816, "file_name": "op300059b-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [246.24, 211.68, 168.9, 160.12], "category_id": 1, "id": 0}, {"bbox": [32.56, 459.33, 37.31, 40.71], "category_id": 3, "id": 1}, {"bbox": [423.96, 323.63, 33.92, 44.1], "category_id": 3, "id": 2}, {"bbox": [1187.09, 696.79, 34.6, 40.03], "category_id": 3, "id": 3}, {"bbox": [4.07, 324.99, 172.98, 126.2], "category_id": 1, "id": 4}, {"bbox": [1122.65, 176.4, 233.35, 150.62], "category_id": 1, "id": 5}, {"bbox": [417.25, 529.98, 229.24, 177.71], "category_id": 1, "id": 6}, {"bbox": [747.53, 464.08, 37.99, 42.06], "category_id": 3, "id": 7}, {"bbox": [1126.72, 533.28, 223.17, 171.65], "category_id": 1, "id": 8}, {"bbox": [1183.7, 328.38, 34.6, 41.39], "category_id": 3, "id": 9}, {"bbox": [518.25, 731.39, 33.92, 40.71], "category_id": 3, "id": 10}, {"bbox": [569.13, 274.78, 337.13, 180.48], "category_id": 1, "id": 11}], "caption": "Scheme 2. Reaction mechanism for the formation of 2 and 8", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 689, 784, 704], "ImageBB": [448, 710, 787, 914]}, "diagram_type": "graph", "corefs": [[4, 1], [0, 2], [11, 7], [5, 9], [8, 3], [6, 10]]}, {"id": 587, "width": 2820, "height": 916, "file_name": "op400242j-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [571.34, 330.1, 57.83, 47.96], "category_id": 3, "id": 0}, {"bbox": [1877.65, 323.04, 59.25, 49.38], "category_id": 3, "id": 1}, {"bbox": [842.19, 60.66, 407.69, 269.44], "category_id": 1, "id": 2}, {"bbox": [658.8, 483.86, 641.87, 371.01], "category_id": 1, "id": 3}, {"bbox": [1090.48, 334.33, 53.6, 46.55], "category_id": 3, "id": 4}, {"bbox": [428.85, 94.51, 339.98, 222.89], "category_id": 1, "id": 5}, {"bbox": [1862.13, 829.47, 36.68, 43.73], "category_id": 3, "id": 6}, {"bbox": [1496.76, 0.0, 639.05, 366.77], "category_id": 1, "id": 7}, {"bbox": [1496.76, 455.65, 643.28, 402.04], "category_id": 1, "id": 8}], "caption": "Scheme 9. Formation of the 22 in the coupling process and conversion to 5", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 512, 110], "ImageBB": [82, 116, 787, 345]}, "diagram_type": "multiple", "corefs": [[5, 0], [2, 4], [7, 1], [8, 6]]}, {"id": 588, "width": 1352, "height": 472, "file_name": "op5003165-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [459.91, 2.71, 206.28, 206.44], "category_id": 1, "id": 0}, {"bbox": [75.75, 223.37, 46.67, 43.32], "category_id": 3, "id": 1}, {"bbox": [18.26, 18.28, 209.67, 182.07], "category_id": 1, "id": 2}, {"bbox": [911.03, 227.43, 41.25, 37.23], "category_id": 3, "id": 3}, {"bbox": [863.01, 6.09, 206.28, 207.8], "category_id": 1, "id": 4}, {"bbox": [1166.68, 226.08, 44.64, 38.58], "category_id": 3, "id": 5}, {"bbox": [1123.4, 6.09, 209.66, 207.8], "category_id": 1, "id": 6}, {"bbox": [493.73, 228.11, 41.25, 35.19], "category_id": 3, "id": 7}], "caption": "Scheme 4. Synthesis of intermediate lactam (11)", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 433, 357, 448], "ImageBB": [82, 455, 420, 573]}, "diagram_type": "graph", "corefs": [[2, 1], [0, 7], [4, 3], [6, 5]]}, {"id": 589, "width": 1348, "height": 440, "file_name": "op700253t-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 178.74, 186.79, 37.77], "category_id": 3, "id": 0}, {"bbox": [872.59, 250.91, 132.85, 109.27], "category_id": 1, "id": 1}, {"bbox": [564.42, 250.91, 129.47, 109.27], "category_id": 1, "id": 2}, {"bbox": [839.55, 0.0, 209.04, 151.09], "category_id": 1, "id": 3}, {"bbox": [366.84, 251.59, 125.43, 108.59], "category_id": 1, "id": 4}, {"bbox": [1150.42, 0.0, 197.58, 151.09], "category_id": 1, "id": 5}, {"bbox": [1192.23, 249.56, 119.36, 110.62], "category_id": 1, "id": 6}, {"bbox": [335.82, 0.0, 194.21, 151.09], "category_id": 1, "id": 7}, {"bbox": [24.95, 0.0, 195.56, 151.09], "category_id": 1, "id": 8}, {"bbox": [64.74, 252.26, 117.33, 107.92], "category_id": 1, "id": 9}, {"bbox": [0.0, 397.95, 204.32, 39.8], "category_id": 3, "id": 10}, {"bbox": [533.4, 0.0, 203.6, 151.09], "category_id": 1, "id": 11}], "caption": "Scheme 1. Preparation of chiral secondary alcohols by chemoenzymatic deracemization ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 363, 73], "ImageBB": [58, 79, 395, 189]}, "diagram_type": "multiple", "corefs": [[8, 0], [9, 10]]}, {"id": 590, "width": 992, "height": 1352, "file_name": "op9000687-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [0.0, 327.35, 411.24, 177.87], "category_id": 1, "id": 0}, {"bbox": [772.42, 124.45, 56.14, 45.31], "category_id": 3, "id": 1}, {"bbox": [124.45, 734.5, 572.9, 202.9], "category_id": 1, "id": 2}, {"bbox": [321.96, 1304.66, 62.22, 47.34], "category_id": 3, "id": 3}, {"bbox": [319.25, 914.41, 67.64, 54.78], "category_id": 3, "id": 4}, {"bbox": [148.8, 1100.4, 547.19, 202.9], "category_id": 1, "id": 5}, {"bbox": [553.28, 313.14, 381.48, 167.74], "category_id": 1, "id": 6}, {"bbox": [100.1, 473.44, 58.17, 46.66], "category_id": 3, "id": 7}, {"bbox": [567.48, 2.71, 333.46, 117.0], "category_id": 1, "id": 8}, {"bbox": [753.49, 488.99, 60.19, 45.99], "category_id": 3, "id": 9}], "caption": "Scheme 5. First route for the synthesis of biaryl 15", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 711, 60], "ImageBB": [469, 65, 717, 403]}, "diagram_type": "tree", "corefs": [[8, 1], [6, 9], [0, 7], [2, 4], [5, 3]]}, {"id": 591, "width": 1356, "height": 1088, "file_name": "ja960062i-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [247.79, 3.66, 212.58, 219.6], "category_id": 1, "id": 0}, {"bbox": [28.79, 188.97, 184.5, 110.09], "category_id": 1, "id": 1}, {"bbox": [37.21, 625.57, 410.52, 341.74], "category_id": 1, "id": 2}, {"bbox": [48.44, 417.8, 402.1, 91.85], "category_id": 1, "id": 3}, {"bbox": [579.1, 473.95, 518.63, 107.29], "category_id": 1, "id": 4}, {"bbox": [555.24, 615.74, 761.49, 462.47], "category_id": 1, "id": 5}, {"bbox": [350.27, 261.97, 336.12, 112.9], "category_id": 1, "id": 6}, {"bbox": [850.05, 180.54, 336.12, 111.51], "category_id": 1, "id": 7}, {"bbox": [517.33, 62.62, 256.1, 100.27], "category_id": 1, "id": 8}], "caption": "Figure 2. Scheme for derivatization of phosphorylated oligonuleotides with a dihydrazide linker and subsequent coupling with CHEVP. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 749, 774, 775], "ImageBB": [437, 474, 776, 746]}, "corefs": []}, {"id": 592, "width": 656, "height": 596, "file_name": "op980215h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [6.0, 4.0, 473.0, 463.0], "category_id": 1, "id": 0}, {"bbox": [148.0, 504.0, 501.0, 86.0], "category_id": 3, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 385, 495, 399], "ImageBB": [526, 232, 690, 381]}, "corefs": [[0, 1]]}, {"id": 593, "width": 1192, "height": 1444, "file_name": "op9800055-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [320.0, 653.0, 352.0, 69.8], "category_id": 3, "id": 0}, {"bbox": [594.3, 752.4, 499.7, 504.6], "category_id": 1, "id": 1}, {"bbox": [1.9, 786.5, 539.8, 516.6], "category_id": 1, "id": 2}, {"bbox": [272.8, 0.0, 534.8, 574.4], "category_id": 1, "id": 3}, {"bbox": [619.0, 1372.9, 569.0, 71.1], "category_id": 3, "id": 4}, {"bbox": [22.0, 1367.0, 502.0, 77.0], "category_id": 3, "id": 5}], "caption": "Figure 1. Nonpeptide angiotensin II receptor antagonists.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 591, 760, 605], "ImageBB": [459, 226, 757, 587]}, "corefs": [[3, 0], [2, 5], [1, 4]]}, {"id": 594, "width": 792, "height": 1360, "file_name": "op960033s-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [85.0, 720.0, 626.5, 512.0], "category_id": 1, "id": 0}, {"bbox": [3.5, 6.0, 788.5, 515.7], "category_id": 1, "id": 1}], "caption": "Figure 1. Structures of dirithromycin, dirithromycin B, and erythromycylamine. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 544, 774, 572], "ImageBB": [508, 200, 706, 540]}, "corefs": []}, {"id": 595, "width": 1116, "height": 508, "file_name": "op900284w-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 1.0, 419.0, 477.0], "category_id": 1, "id": 0}, {"bbox": [922.0, 464.0, 45.0, 38.0], "category_id": 3, "id": 1}, {"bbox": [567.0, 464.0, 47.0, 38.0], "category_id": 3, "id": 2}, {"bbox": [198.0, 462.0, 48.0, 41.0], "category_id": 3, "id": 3}, {"bbox": [775.0, 39.0, 338.0, 400.0], "category_id": 1, "id": 4}, {"bbox": [421.0, 57.0, 345.0, 365.0], "category_id": 1, "id": 5}], "caption": "Figure 2. Structure of impurities 12-14.", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 177, 284, 191], "ImageBB": [87, 47, 366, 174]}, "corefs": [[0, 3], [5, 2], [4, 1]]}, {"id": 596, "width": 772, "height": 488, "file_name": "op900284w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [588.0, 446.0, 24.0, 33.0], "category_id": 3, "id": 0}, {"bbox": [6.0, 0.0, 383.0, 441.0], "category_id": 1, "id": 1}, {"bbox": [432.0, 58.0, 340.0, 329.0], "category_id": 1, "id": 2}, {"bbox": [185.0, 444.4, 26.3, 35.6], "category_id": 3, "id": 3}], "caption": "Figure 1. Structure of amtolmetin 1 and tolmetin 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 374, 712, 388], "ImageBB": [497, 249, 690, 371]}, "corefs": [[1, 3], [2, 0]]}, {"id": 597, "width": 512, "height": 456, "file_name": "op900265h-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 3.0, 505.0, 379.6], "category_id": 1, "id": 0}, {"bbox": [202.94, 410.24, 65.0, 42.0], "category_id": 3, "id": 1}], "caption": "Figure 7. 12-Oxolactone 10.", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 165, 224, 179], "ImageBB": [163, 47, 291, 161]}, "corefs": [[0, 1]]}, {"id": 598, "width": 1768, "height": 500, "file_name": "op9002533-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1378.9, 66.7, 389.1, 217.3], "category_id": 1, "id": 0}, {"bbox": [2.9, 438.0, 490.1, 60.0], "category_id": 3, "id": 1}, {"bbox": [14.0, 5.0, 449.0, 398.0], "category_id": 1, "id": 2}, {"bbox": [645.1, 437.0, 564.9, 59.0], "category_id": 3, "id": 3}, {"bbox": [1427.7, 441.0, 322.3, 58.0], "category_id": 3, "id": 4}, {"bbox": [603.0, 36.0, 659.0, 389.0], "category_id": 1, "id": 5}], "caption": "Figure 1. Examples of commercial APIs with tetrahydroisoquinoline cores.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 176, 470, 190], "ImageBB": [189, 47, 631, 172]}, "corefs": [[2, 1], [5, 3], [0, 4]]}, {"id": 599, "width": 1124, "height": 828, "file_name": "op900197r-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [707.2, 541.9, 416.8, 177.4], "category_id": 1, "id": 0}, {"bbox": [31.0, 0.0, 297.0, 400.0], "category_id": 1, "id": 1}, {"bbox": [101.0, 398.0, 76.0, 47.0], "category_id": 3, "id": 2}, {"bbox": [741.0, 397.0, 57.0, 43.0], "category_id": 3, "id": 3}, {"bbox": [253.0, 785.0, 58.0, 40.0], "category_id": 3, "id": 4}, {"bbox": [883.0, 782.0, 62.0, 41.0], "category_id": 3, "id": 5}, {"bbox": [4.0, 491.6, 615.8, 282.4], "category_id": 1, "id": 6}, {"bbox": [495.0, 25.0, 611.0, 331.6], "category_id": 1, "id": 7}], "caption": "Figure 2. Major impurities formed during the synthesis of ABT-279. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 258, 760, 285], "ImageBB": [453, 47, 734, 254]}, "corefs": [[1, 2], [7, 3], [6, 4], [0, 5]]}, {"id": 600, "width": 1124, "height": 460, "file_name": "op900188v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 6.0, 602.0, 386.0], "category_id": 1, "id": 0}, {"bbox": [972.0, 418.0, 32.0, 39.0], "category_id": 3, "id": 1}, {"bbox": [824.0, 77.0, 300.0, 327.0], "category_id": 1, "id": 2}, {"bbox": [143.0, 420.0, 22.0, 39.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Target 5HT4 agonist and key benzopyran intermediate.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 699, 394, 713], "ImageBB": [86, 581, 367, 696]}, "corefs": [[0, 3], [2, 1]]}, {"id": 601, "width": 444, "height": 432, "file_name": "op9001824-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [192.0, 382.0, 47.0, 50.0], "category_id": 3, "id": 0}, {"bbox": [7.0, 6.0, 431.0, 365.0], "category_id": 1, "id": 1}], "caption": "Figure 6", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 158, 476, 172], "ImageBB": [538, 46, 649, 154]}, "corefs": [[1, 0]]}, {"id": 602, "width": 696, "height": 460, "file_name": "op9001824-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [435.0, 379.0, 76.0, 54.0], "category_id": 3, "id": 0}, {"bbox": [253.9, 0.0, 442.1, 375.0], "category_id": 1, "id": 1}], "caption": "Figure 5", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 156, 109, 170], "ImageBB": [108, 46, 282, 161]}, "corefs": [[1, 0]]}, {"id": 603, "width": 888, "height": 432, "file_name": "op9001824-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 2.0, 418.0, 351.0], "category_id": 1, "id": 0}, {"bbox": [536.0, 5.0, 350.0, 348.0], "category_id": 1, "id": 1}, {"bbox": [181.0, 387.0, 56.0, 42.0], "category_id": 3, "id": 2}, {"bbox": [682.0, 388.0, 54.0, 41.0], "category_id": 3, "id": 3}], "caption": "Figure 4", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 569, 109, 583], "ImageBB": [116, 458, 338, 566]}, "corefs": [[0, 2], [1, 3]]}, {"id": 604, "width": 436, "height": 448, "file_name": "op9001824-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [199.0, 404.0, 57.0, 43.0], "category_id": 3, "id": 0}, {"bbox": [0.0, 0.0, 436.0, 372.0], "category_id": 1, "id": 1}], "caption": "Figure 3", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 433, 109, 447], "ImageBB": [172, 318, 281, 430]}, "corefs": [[1, 0]]}, {"id": 605, "width": 652, "height": 360, "file_name": "op9001824-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [300.5, 4.0, 350.5, 264.1], "category_id": 1, "id": 0}, {"bbox": [406.0, 276.0, 61.0, 44.0], "category_id": 3, "id": 1}], "caption": "Figure 2", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 469, 109, 483], "ImageBB": [108, 385, 271, 475]}, "corefs": [[0, 1]]}, {"id": 606, "width": 820, "height": 1088, "file_name": "op9000687-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [184.0, 1025.0, 53.0, 61.0], "category_id": 3, "id": 0}, {"bbox": [189.0, 253.0, 50.0, 52.0], "category_id": 3, "id": 1}, {"bbox": [3.0, 4.0, 680.0, 245.0], "category_id": 1, "id": 2}, {"bbox": [2.0, 358.4, 731.4, 379.6], "category_id": 1, "id": 3}, {"bbox": [0.0, 802.8, 820.0, 259.2], "category_id": 1, "id": 4}, {"bbox": [192.4, 697.01, 49.0, 54.19], "category_id": 3, "id": 5}], "caption": "Figure 3. Some impurities formed during the synthesis of AR- C123196. ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 322, 760, 349], "ImageBB": [491, 47, 696, 319]}, "corefs": [[2, 1], [3, 5], [4, 0]]}, {"id": 607, "width": 1196, "height": 708, "file_name": "op9000687-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [626.9, 323.0, 569.1, 341.0], "category_id": 1, "id": 0}, {"bbox": [831.0, 669.0, 42.0, 29.0], "category_id": 3, "id": 1}, {"bbox": [550.0, 208.0, 41.0, 33.0], "category_id": 3, "id": 2}, {"bbox": [0.0, 299.0, 575.0, 345.0], "category_id": 1, "id": 3}, {"bbox": [410.0, 0.0, 334.1, 210.1], "category_id": 1, "id": 4}, {"bbox": [210.0, 664.0, 43.0, 30.0], "category_id": 3, "id": 5}], "caption": "Figure 2. Impurities in biaryl 15.", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 227, 610, 241], "ImageBB": [444, 47, 743, 224]}, "corefs": [[4, 2], [3, 5], [0, 1]]}, {"id": 608, "width": 1064, "height": 924, "file_name": "op9000687-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [314.0, 556.0, 61.0, 48.0], "category_id": 3, "id": 0}, {"bbox": [430.0, 874.0, 61.0, 48.0], "category_id": 3, "id": 1}, {"bbox": [173.7, 1.2, 806.2, 250.7], "category_id": 1, "id": 2}, {"bbox": [137.7, 354.9, 764.0, 217.2], "category_id": 1, "id": 3}, {"bbox": [430.0, 178.0, 46.0, 42.0], "category_id": 3, "id": 4}, {"bbox": [0.0, 644.0, 1059.2, 270.5], "category_id": 1, "id": 5}], "caption": "Figure 1. Product mixture arising from reaction between carbonate 12 and biaryl 8. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 281, 393, 308], "ImageBB": [94, 47, 360, 278]}, "corefs": [[2, 4], [3, 0], [5, 1]]}, {"id": 609, "width": 908, "height": 212, "file_name": "op8002932-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [165.0, 171.0, 40.0, 34.0], "category_id": 3, "id": 0}, {"bbox": [498.0, 1.0, 407.0, 134.0], "category_id": 1, "id": 1}, {"bbox": [679.0, 172.0, 46.0, 33.0], "category_id": 3, "id": 2}, {"bbox": [3.0, 3.0, 411.0, 131.0], "category_id": 1, "id": 3}], "caption": "Figure 2. 2-(S)-2-Hydroxyglutaric acid, dibenzyl ester, the major impurity present in crude 9. 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Structure of byproduct 10 formed during catalytic asymmetric hydrogenation of ketone 5. 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Intermediates and byproduct of the improved procedure.", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 171, 428, 185], "ImageBB": [187, 47, 632, 168]}, "corefs": [[0, 3], [2, 4], [1, 5]]}, {"id": 613, "width": 1172, "height": 1680, "file_name": "op800057d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [267.0, 1204.0, 458.0, 371.0], "category_id": 1, "id": 0}, {"bbox": [177.0, 582.0, 461.0, 506.0], "category_id": 1, "id": 1}, {"bbox": [956.0, 72.0, 213.0, 180.0], "category_id": 1, "id": 2}, {"bbox": [0.0, 0.0, 452.0, 297.0], "category_id": 1, "id": 3}, {"bbox": [478.0, 72.0, 224.0, 132.0], "category_id": 1, "id": 4}, {"bbox": [178.0, 360.0, 25.0, 34.0], "category_id": 3, "id": 5}, {"bbox": [375.0, 1133.0, 27.0, 36.0], "category_id": 3, "id": 6}, {"bbox": [465.0, 1580.0, 27.0, 39.0], "category_id": 3, "id": 7}], "caption": "Figure 1. Design of in-line reactor.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 471, 619, 485], "ImageBB": [447, 47, 740, 467]}, "corefs": [[3, 5], [1, 6], [0, 7]]}, {"id": 614, "width": 1248, "height": 628, "file_name": "op700249f-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [771.6, 1.0, 333.8, 283.4], "category_id": 1, "id": 0}, {"bbox": [115.9, 6.0, 340.5, 280.2], "category_id": 1, "id": 1}], "caption": "Figure 4. Nomenclature of the triazole-linked glycosidic amino acids. 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General structure of SEGRA compounds.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 887, 333, 901], "ImageBB": [82, 738, 420, 877]}, "corefs": []}, {"id": 619, "width": 1352, "height": 532, "file_name": "op5003165-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [657.0, 484.0, 39.0, 48.0], "category_id": 3, "id": 0}, {"bbox": [282.0, 31.0, 781.0, 416.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Structure of amide (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 565, 246, 579], "ImageBB": [82, 422, 420, 555]}, "corefs": [[1, 0]]}, {"id": 620, "width": 1356, "height": 368, "file_name": "op500250b-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [439.0, 317.0, 64.0, 51.0], "category_id": 3, "id": 0}, {"bbox": [246.8, 41.6, 422.0, 254.6], "category_id": 1, "id": 1}, {"bbox": [941.0, 320.1, 71.9, 45.9], "category_id": 3, "id": 2}, {"bbox": [760.5, 82.4, 351.5, 226.4], "category_id": 1, "id": 3}], "caption": "Figure 2. Side products of the [3 + 2] cycloaddition.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 1046, 709, 1060], "ImageBB": [448, 934, 787, 1026]}, "corefs": [[1, 0], [3, 2]]}, {"id": 621, "width": 892, "height": 492, "file_name": "op100010n-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [436.8, 260.0, 450.5, 204.0], "category_id": 3, "id": 0}, {"bbox": [0.0, 0.0, 595.0, 485.7], "category_id": 1, "id": 1}], "caption": "Figure 1. Structure of target compound 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 360, 660, 374], "ImageBB": [482, 234, 705, 357]}, "corefs": [[1, 0]]}, {"id": 622, "width": 1232, "height": 408, "file_name": "op060249m-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [879.0, 82.0, 347.0, 266.0], "category_id": 1, "id": 0}, {"bbox": [455.0, 1.0, 373.0, 330.0], "category_id": 1, "id": 1}, {"bbox": [5.0, 75.0, 362.0, 274.0], "category_id": 1, "id": 2}, {"bbox": [170.0, 367.0, 26.0, 34.0], "category_id": 3, "id": 3}, {"bbox": [636.0, 352.0, 28.0, 38.0], "category_id": 3, "id": 4}, {"bbox": [1043.0, 349.0, 31.0, 40.0], "category_id": 3, "id": 5}], "caption": "Figure 2. Major impurities formed in the reaction of (S)- propylene oxide with TEPA anions. 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Potential by-products in the conversion 4 f 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 191, 756, 207], "ImageBB": [439, 53, 777, 188]}, "corefs": [[0, 4], [5, 3], [1, 2]]}, {"id": 624, "width": 1356, "height": 1068, "file_name": "op0602425-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [177.0, 1020.0, 92.0, 44.9], "category_id": 3, "id": 0}, {"bbox": [471.7, 6.3, 406.6, 406.7], "category_id": 1, "id": 1}, {"bbox": [944.0, 13.0, 407.0, 398.9], "category_id": 1, "id": 2}, {"bbox": [448.0, 591.0, 429.6, 406.5], "category_id": 1, "id": 3}, {"bbox": [0.0, 595.0, 427.9, 405.3], "category_id": 1, "id": 4}, {"bbox": [969.2, 593.0, 380.4, 402.6], "category_id": 1, "id": 5}, {"bbox": [11.5, 1.4, 402.9, 403.4], "category_id": 1, "id": 6}, {"bbox": [155.0, 434.0, 93.0, 42.0], "category_id": 3, "id": 7}, {"bbox": [622.0, 1018.0, 92.0, 50.0], "category_id": 3, "id": 8}, {"bbox": [1110.0, 1029.0, 89.0, 39.0], "category_id": 3, "id": 9}, {"bbox": [620.0, 436.0, 89.0, 38.0], "category_id": 3, "id": 10}, {"bbox": [1127.0, 432.0, 92.0, 44.0], "category_id": 3, "id": 11}], "caption": "Figure 2. by-products isolated from the mother liquor of batch 35. 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Solubility of reacting species in MTBE phase at 22 \u00b0C ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 782, 409, 811], "ImageBB": [74, 816, 410, 1051]}, "corefs": [[0, 4], [2, 3]]}, {"id": 627, "width": 872, "height": 1108, "file_name": "op060204l-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [205.0, 735.0, 471.0, 58.0], "category_id": 3, "id": 0}, {"bbox": [86.0, 831.4, 700.0, 222.6], "category_id": 1, "id": 1}, {"bbox": [130.9, 370.5, 615.1, 91.5], "category_id": 3, "id": 2}, {"bbox": [0.0, 467.0, 872.0, 268.0], "category_id": 1, "id": 3}, {"bbox": [204.0, 1055.0, 471.0, 51.0], "category_id": 3, "id": 4}, {"bbox": [0.0, 1.0, 872.0, 370.0], "category_id": 1, "id": 5}], "caption": "Figure 1. Representative nodulisporic acid congeners.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 511, 740, 525], "ImageBB": [499, 231, 717, 508]}, "corefs": [[5, 2], [3, 0], [1, 4]]}, {"id": 628, "width": 2420, "height": 816, "file_name": "op0601464-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1582.0, 3.0, 416.0, 351.0], "category_id": 1, "id": 0}, {"bbox": [638.0, 0.0, 635.0, 293.0], "category_id": 1, "id": 1}, {"bbox": [951.0, 440.0, 696.0, 372.0], "category_id": 1, "id": 2}, {"bbox": [1915.0, 201.0, 505.0, 118.0], "category_id": 1, "id": 3}], "caption": "Figure 5. Monohydrochloride reverses the crucial N-H-O hydrogen bond in starting material and product: from acceptor to donor. 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Postulated intramolecular hydrogen bond in 4.", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 160, 391, 174], "ImageBB": [156, 53, 427, 157]}, "corefs": []}, {"id": 630, "width": 1356, "height": 804, "file_name": "op060114g-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [187.23, 252.0, 60.0, 49.7], "category_id": 3, "id": 0}, {"bbox": [946.3, 53.6, 405.0, 164.8], "category_id": 1, "id": 1}, {"bbox": [39.86, 523.93, 456.64, 110.17], "category_id": 1, "id": 2}, {"bbox": [4.3, 4.0, 417.6, 208.4], "category_id": 1, "id": 3}, {"bbox": [105.5, 673.08, 226.9, 60.12], "category_id": 3, "id": 4}, {"bbox": [1086.0, 263.7, 185.0, 64.0], "category_id": 3, "id": 5}, {"bbox": [444.1, 21.52, 107.78, 56.04], "category_id": 1, "id": 6}, {"bbox": [612.23, 241.38, 208.01, 90.53], "category_id": 1, "id": 7}], "caption": "Figure 2.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 257, 129, 271], "ImageBB": [73, 53, 412, 254]}, "corefs": [[3, 0], [1, 5], [2, 4]]}, {"id": 631, "width": 1344, "height": 604, "file_name": "op060099f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [215.0, 502.0, 241.4, 102.0], "category_id": 3, "id": 0}, {"bbox": [799.3, 2.0, 543.7, 482.0], "category_id": 1, "id": 1}, {"bbox": [955.1, 512.1, 240.3, 91.9], "category_id": 3, "id": 2}, {"bbox": [144.0, 304.0, 73.0, 95.0], "category_id": 3, "id": 3}, {"bbox": [0.0, 4.0, 741.0, 473.0], "category_id": 1, "id": 4}, {"bbox": [943.0, 310.0, 96.0, 91.0], "category_id": 3, "id": 5}], "caption": "Figure 1. Structures of PDE-V inhibitors R301249 and R290629. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 522, 775, 550], "ImageBB": [440, 367, 776, 518]}, "corefs": [[4, 3], [4, 0], [1, 5], [1, 2]]}, {"id": 632, "width": 1356, "height": 756, "file_name": "op050151s-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [750.2, 377.6, 598.8, 378.4], "category_id": 1, "id": 0}, {"bbox": [288.0, 0.0, 396.0, 284.0], "category_id": 1, "id": 1}, {"bbox": [478.0, 319.0, 52.0, 52.0], "category_id": 3, "id": 2}, {"bbox": [937.0, 697.0, 67.0, 59.0], "category_id": 3, "id": 3}, {"bbox": [259.0, 695.0, 66.0, 61.0], "category_id": 3, "id": 4}, {"bbox": [6.0, 381.0, 687.0, 375.0], "category_id": 1, "id": 5}], "caption": "Table 1. Comparison of various hydrides related to Bu3GeH used for conversiona of 14a/14b mixtures into 7 ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 271, 406, 299], "ImageBB": [73, 71, 412, 260]}, "corefs": [[1, 2], [5, 4], [0, 3]]}, {"id": 633, "width": 504, "height": 684, "file_name": "op050102f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [37.75, 578.08, 459.85, 103.52], "category_id": 3, "id": 0}, {"bbox": [0.0, 1.0, 485.0, 568.0], "category_id": 1, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 422, 495, 436], "ImageBB": [545, 247, 671, 418]}, "corefs": [[1, 0]]}, {"id": 634, "width": 1032, "height": 780, "file_name": "op050077d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [416.0, 413.0, 146.0, 254.0], "category_id": 1, "id": 0}, {"bbox": [767.0, 1.0, 143.0, 261.0], "category_id": 1, "id": 1}, {"bbox": [64.0, 3.0, 160.0, 259.0], "category_id": 1, "id": 2}], "caption": "Figure 1. 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Key benzothiazolone amine hydrochloride interme- diate. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 452, 775, 480], "ImageBB": [548, 381, 668, 449]}, "corefs": [[0, 1]]}, {"id": 637, "width": 872, "height": 304, "file_name": "op049953y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [416.68, 201.04, 18.62, 36.26], "category_id": 3, "id": 0}, {"bbox": [1.0, 8.0, 865.0, 290.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Sibenadet Hydrochloride.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 356, 641, 370], "ImageBB": [499, 277, 717, 353]}, "corefs": [[1, 0]]}, {"id": 638, "width": 1352, "height": 952, "file_name": "op049889k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [4.0, 0.0, 629.1, 244.6], "category_id": 1, "id": 0}, {"bbox": [23.7, 539.3, 661.0, 341.8], "category_id": 1, "id": 1}, {"bbox": [767.7, 6.0, 557.3, 334.1], "category_id": 1, "id": 2}, {"bbox": [203.0, 314.0, 259.0, 99.1], "category_id": 3, "id": 3}, {"bbox": [885.24, 399.41, 148.03, 111.03], "category_id": 1, "id": 4}, {"bbox": [866.1, 574.24, 241.19, 148.04], "category_id": 1, "id": 5}], "caption": "Figure 1. BPH antagonists.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 497, 596, 511], "ImageBB": [439, 255, 777, 493]}, "corefs": [[0, 3]]}, {"id": 639, "width": 1128, "height": 964, "file_name": "op049867y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [404.0, 396.0, 211.0, 70.0], "category_id": 3, "id": 0}, {"bbox": [410.0, 901.0, 233.0, 63.0], "category_id": 3, "id": 1}, {"bbox": [0.0, 0.0, 1057.0, 331.0], "category_id": 1, "id": 2}, {"bbox": [0.0, 494.0, 1125.0, 349.9], "category_id": 1, "id": 3}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 498, 495, 512], "ImageBB": [467, 254, 749, 495]}, "corefs": [[2, 0], [3, 1]]}, {"id": 640, "width": 1352, "height": 1608, "file_name": "op049800a-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [337.0, 317.0, 20.0, 30.0], "category_id": 3, "id": 0}, {"bbox": [1007.0, 317.0, 45.0, 30.0], "category_id": 3, "id": 1}, {"bbox": [1029.0, 795.0, 21.0, 31.0], "category_id": 3, "id": 2}, {"bbox": [1024.0, 1166.0, 21.0, 30.0], "category_id": 3, "id": 3}, {"bbox": [358.0, 1185.0, 24.0, 32.0], "category_id": 3, "id": 4}, {"bbox": [594.0, 1282.0, 403.0, 259.0], "category_id": 1, "id": 5}, {"bbox": [805.0, 888.0, 463.0, 188.0], "category_id": 1, "id": 6}, {"bbox": [143.0, 961.0, 417.0, 191.0], "category_id": 1, "id": 7}, {"bbox": [815.0, 408.0, 441.0, 192.0], "category_id": 1, "id": 8}, {"bbox": [6.0, 361.0, 705.0, 350.0], "category_id": 1, "id": 9}, {"bbox": [722.0, 11.0, 625.0, 268.0], "category_id": 1, "id": 10}, {"bbox": [156.0, 64.0, 391.0, 187.0], "category_id": 1, "id": 11}], "caption": "Figure 3. Isolated reaction products.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 884, 647, 898], "ImageBB": [439, 479, 777, 881]}, "corefs": [[11, 0], [10, 1], [8, 2], [7, 4], [6, 3]]}, {"id": 641, "width": 1088, "height": 432, "file_name": "op049800a-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [185.0, 54.0, 898.0, 360.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Key aldol bond-forming reactions used in the Novartis synthetic route to (+)-discodermolide. 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YM087 (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 393, 564, 407], "ImageBB": [531, 254, 685, 390]}, "corefs": [[0, 1]]}, {"id": 646, "width": 1344, "height": 916, "file_name": "op0340661-Table-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [512.0, 6.0, 330.0, 250.0], "category_id": 1, "id": 0}], "caption": "Table 4. 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Aldose reductase inhibitors.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 453, 654, 467], "ImageBB": [490, 255, 726, 448]}, "corefs": [[2, 0], [4, 5], [1, 3]]}, {"id": 648, "width": 1412, "height": 1020, "file_name": "op030202q-Table-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1042.0, 303.0, 54.0, 52.0], "category_id": 3, "id": 0}, {"bbox": [922.0, 3.0, 255.0, 294.0], "category_id": 1, "id": 1}, {"bbox": [987.0, 299.0, 51.0, 56.0], "category_id": 3, "id": 2}], "caption": "Table 7. Evaluation of different sulfonates", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 307, 67], "ImageBB": [74, 75, 427, 330]}, "corefs": [[1, 2], [1, 0]]}, {"id": 649, "width": 1412, "height": 1492, "file_name": "op030202q-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [910.0, 316.0, 69.0, 53.0], "category_id": 3, "id": 0}, {"bbox": [820.5, 6.0, 233.5, 291.0], "category_id": 1, "id": 1}, {"bbox": [1275.1, 3.0, 136.9, 294.0], "category_id": 1, "id": 2}, {"bbox": [1354.0, 313.0, 58.0, 53.0], "category_id": 3, "id": 3}], "caption": "Table 3. Resolution of racemic PLA: base screening", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 363, 67], "ImageBB": [74, 75, 427, 448]}, "corefs": [[1, 0], [2, 3]]}, {"id": 650, "width": 2100, "height": 1440, "file_name": "op0256183-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1332.4, 791.1, 309.3, 290.8], "category_id": 1, "id": 0}, {"bbox": [655.5, 722.7, 319.2, 436.9], "category_id": 1, "id": 1}, {"bbox": [1497.7, 0.0, 307.8, 394.1], "category_id": 1, "id": 2}, {"bbox": [745.0, 10.0, 493.0, 361.7], "category_id": 1, "id": 3}, {"bbox": [13.0, 5.0, 467.3, 373.6], "category_id": 1, "id": 4}, {"bbox": [117.9, 731.8, 229.1, 405.1], "category_id": 1, "id": 5}], "caption": "Figure 1. Diphosphines screened for the asymmetric hydrogenation of 2-methylenesuccinamic acid.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 419, 621, 433], "ImageBB": [163, 55, 688, 415]}, "corefs": []}, {"id": 651, "width": 1340, "height": 1424, "file_name": "op025538z-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [587.0, 4.0, 180.0, 241.0], "category_id": 1, "id": 0}, {"bbox": [355.0, 351.0, 200.0, 169.0], "category_id": 1, "id": 1}, {"bbox": [520.0, 1064.0, 280.0, 306.0], "category_id": 1, "id": 2}, {"bbox": [881.0, 609.0, 292.0, 348.0], "category_id": 1, "id": 3}, {"bbox": [188.0, 618.0, 218.0, 349.0], "category_id": 1, "id": 4}], "caption": "Table 1. Control reaction", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 473, 582, 487], "ImageBB": [440, 103, 775, 459]}, "corefs": []}, {"id": 652, "width": 432, "height": 468, "file_name": "op025516c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [154.0, 406.0, 35.0, 50.0], "category_id": 3, "id": 0}, {"bbox": [6.0, 7.0, 416.0, 351.0], "category_id": 1, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 173, 495, 187], "ImageBB": [554, 53, 662, 170]}, "corefs": [[1, 0]]}, {"id": 653, "width": 1060, "height": 692, "file_name": "op020211j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [585.7, 2.0, 474.3, 560.0], "category_id": 1, "id": 0}, {"bbox": [0.0, 85.0, 446.0, 324.0], "category_id": 1, "id": 1}, {"bbox": [82.0, 418.1, 229.0, 58.8], "category_id": 3, "id": 2}, {"bbox": [723.0, 581.0, 337.0, 111.0], "category_id": 3, "id": 3}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 388, 495, 402], "ImageBB": [475, 211, 740, 384]}, "corefs": [[1, 2], [0, 3]]}, {"id": 654, "width": 560, "height": 368, "file_name": "op020090n-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [254.0, 324.0, 33.0, 44.0], "category_id": 3, "id": 0}, {"bbox": [3.0, 10.0, 556.0, 300.0], "category_id": 1, "id": 1}], "caption": "Figure 7. N3-Cyanoethylthymidine. 16 h. The cooled products were concentrated under vacuum; a solution of the residue in CHCl3 (200 mL) was washed with water (2 \u00d7 100 mL), dried (Na2SO4), and the CHCl3 was evaporated. The residual oil was purified by chroma- tography on silica gel, and concentration of the fractions eluted with CHCl3-MeOH (49:1 v/v) gave the title com- pound (6) (3.5 g, 6 mmol, 30%) as a colorless glass17 (Figure 7). ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 561, 409, 711], "ImageBB": [172, 466, 312, 558]}, "corefs": [[1, 0]]}, {"id": 655, "width": 760, "height": 524, "file_name": "op020090n-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [140.67, 477.75, 49.0, 46.25], "category_id": 3, "id": 0}, {"bbox": [599.0, 474.0, 60.0, 49.0], "category_id": 3, "id": 1}, {"bbox": [530.0, 19.0, 230.0, 437.0], "category_id": 1, "id": 2}, {"bbox": [11.0, 8.0, 327.0, 428.0], "category_id": 1, "id": 3}], "caption": "Figure 4. Cyclic adducts of bases.", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 379, 266, 393], "ImageBB": [147, 245, 337, 376]}, "corefs": [[3, 0], [2, 1]]}, {"id": 656, "width": 1248, "height": 920, "file_name": "op0200165-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [13.0, 23.0, 515.0, 147.0], "category_id": 1, "id": 0}, {"bbox": [490.0, 644.0, 411.0, 266.0], "category_id": 1, "id": 1}, {"bbox": [584.0, 6.0, 649.0, 208.0], "category_id": 1, "id": 2}, {"bbox": [494.0, 361.0, 441.0, 171.0], "category_id": 1, "id": 3}, {"bbox": [953.0, 301.0, 282.0, 272.0], "category_id": 1, "id": 4}, {"bbox": [917.0, 688.0, 316.0, 213.0], "category_id": 1, "id": 5}, {"bbox": [4.0, 242.0, 467.0, 338.0], "category_id": 1, "id": 6}, {"bbox": [7.0, 716.0, 470.0, 196.0], "category_id": 1, "id": 7}], "caption": "Figure 2. Examples of substrates successfully synthesized using CALB as catalyst.19 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 287, 775, 315], "ImageBB": [453, 53, 765, 283]}, "corefs": []}, {"id": 657, "width": 1284, "height": 968, "file_name": "op0200165-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [908.0, 17.0, 370.0, 301.0], "category_id": 1, "id": 0}, {"bbox": [449.0, 70.0, 280.0, 180.0], "category_id": 1, "id": 1}, {"bbox": [0.0, 2.0, 203.0, 302.0], "category_id": 1, "id": 2}, {"bbox": [1102.3, 619.0, 27.7, 47.5], "category_id": 3, "id": 3}, {"bbox": [521.0, 271.0, 34.0, 45.0], "category_id": 3, "id": 4}, {"bbox": [77.0, 279.0, 35.0, 43.0], "category_id": 3, "id": 5}, {"bbox": [278.0, 755.0, 995.0, 131.0], "category_id": 1, "id": 6}, {"bbox": [32.0, 774.0, 184.0, 142.0], "category_id": 1, "id": 7}, {"bbox": [96.0, 389.0, 547.0, 269.0], "category_id": 1, "id": 8}, {"bbox": [849.0, 414.0, 384.0, 205.0], "category_id": 1, "id": 9}, {"bbox": [123.0, 919.0, 31.0, 45.0], "category_id": 3, "id": 10}, {"bbox": [754.0, 910.0, 34.0, 44.0], "category_id": 3, "id": 11}, {"bbox": [1091.0, 269.0, 36.0, 42.0], "category_id": 3, "id": 12}, {"bbox": [217.82, 623.73, 36.17, 46.16], "category_id": 3, "id": 13}], "caption": "Figure 1. Examples of unique substrates accepted by CALA.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 298, 409, 312], "ImageBB": [82, 53, 403, 295]}, "corefs": [[2, 5], [1, 4], [0, 12], [8, 13], [9, 3], [7, 10], [6, 11]]}, {"id": 658, "width": 1304, "height": 2552, "file_name": "op010224h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [760.0, 1203.0, 528.0, 476.0], "category_id": 1, "id": 0}, {"bbox": [235.0, 1209.0, 453.0, 460.0], "category_id": 1, "id": 1}, {"bbox": [204.82, 368.27, 286.12, 141.41], "category_id": 1, "id": 2}, {"bbox": [758.0, 1963.0, 544.0, 526.0], "category_id": 1, "id": 3}, {"bbox": [1008.0, 2495.0, 57.0, 57.0], "category_id": 3, "id": 4}, {"bbox": [980.0, 1674.0, 52.0, 60.0], "category_id": 3, "id": 5}, {"bbox": [423.0, 1682.0, 45.0, 49.0], "category_id": 3, "id": 6}, {"bbox": [744.0, 997.0, 61.0, 59.0], "category_id": 3, "id": 7}, {"bbox": [154.0, 993.0, 61.0, 69.0], "category_id": 3, "id": 8}, {"bbox": [1016.6, 1802.6, 284.1, 145.1], "category_id": 1, "id": 9}, {"bbox": [0.0, 528.0, 439.8, 457.0], "category_id": 1, "id": 10}, {"bbox": [535.7, 521.9, 538.3, 457.1], "category_id": 1, "id": 11}], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 697, 129, 711], "ImageBB": [80, 55, 406, 693]}, "corefs": [[10, 8], [11, 7], [1, 6], [0, 5], [3, 4]]}, {"id": 659, "width": 1324, "height": 700, "file_name": "op0102013-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [844.3, 7.2, 479.7, 269.8], "category_id": 1, "id": 0}, {"bbox": [80.41, 661.0, 265.0, 31.0], "category_id": 3, "id": 1}, {"bbox": [860.26, 388.6, 371.34, 263.6], "category_id": 1, "id": 2}, {"bbox": [440.5, 217.6, 366.5, 263.9], "category_id": 1, "id": 3}, {"bbox": [569.0, 466.0, 152.0, 66.0], "category_id": 3, "id": 4}, {"bbox": [947.0, 657.0, 265.0, 40.0], "category_id": 3, "id": 5}, {"bbox": [74.0, 272.0, 260.0, 45.0], "category_id": 3, "id": 6}, {"bbox": [5.0, 5.0, 367.0, 265.0], "category_id": 1, "id": 7}, {"bbox": [0.0, 394.0, 378.0, 264.0], "category_id": 1, "id": 8}, {"bbox": [959.0, 269.0, 222.0, 35.0], "category_id": 3, "id": 9}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 375, 495, 389], "ImageBB": [443, 195, 774, 370]}, "corefs": [[7, 6], [3, 4], [0, 9], [8, 1], [2, 5]]}, {"id": 660, "width": 844, "height": 376, "file_name": "op010097p-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [658.4, 121.2, 179.0, 110.7], "category_id": 3, "id": 0}, {"bbox": [4.0, 3.0, 577.0, 373.0], "category_id": 1, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 309, 495, 323], "ImageBB": [503, 210, 714, 304]}, "corefs": [[1, 0]]}, {"id": 661, "width": 1028, "height": 1236, "file_name": "op010068e-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [462.0, 538.0, 195.0, 45.0], "category_id": 3, "id": 0}, {"bbox": [205.0, 6.0, 777.0, 493.0], "category_id": 1, "id": 1}, {"bbox": [760.0, 665.0, 268.0, 328.0], "category_id": 1, "id": 2}, {"bbox": [0.0, 631.0, 525.0, 500.0], "category_id": 1, "id": 3}, {"bbox": [938.0, 1044.0, 36.0, 54.0], "category_id": 3, "id": 4}, {"bbox": [227.0, 1187.0, 203.0, 42.0], "category_id": 3, "id": 5}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 530, 495, 544], "ImageBB": [480, 217, 737, 526]}, "corefs": [[1, 0], [3, 5], [2, 4]]}, {"id": 662, "width": 880, "height": 672, "file_name": "op010026q-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [340.0, 8.0, 540.0, 486.0], "category_id": 1, "id": 0}], "caption": "Table 2. Optimized Percent yields for the synthesis of DHPs by route B ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 253, 771, 281], "ImageBB": [424, 73, 644, 241]}, "corefs": []}, {"id": 663, "width": 1412, "height": 1272, "file_name": "op0000879-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1302.9, 205.0, 107.1, 208.0], "category_id": 1, "id": 0}, {"bbox": [378.3, 81.0, 376.7, 404.0], "category_id": 1, "id": 1}, {"bbox": [728.0, 919.0, 571.0, 346.0], "category_id": 1, "id": 2}, {"bbox": [563.0, 509.0, 106.0, 63.0], "category_id": 3, "id": 3}], "caption": "Table 2. Evaluation of Various Metalation Procedures", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 384, 373, 398], "ImageBB": [74, 52, 427, 370]}, "corefs": [[1, 3]]}, {"id": 664, "width": 932, "height": 400, "file_name": "op000086g-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2.0, 6.0, 752.0, 290.0], "category_id": 1, "id": 0}, {"bbox": [323.0, 349.0, 32.0, 45.0], "category_id": 3, "id": 1}], "caption": "Figure 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 406, 129, 420], "ImageBB": [194, 301, 427, 401]}, "corefs": [[0, 1]]}, {"id": 665, "width": 1344, "height": 1948, "file_name": "op0000428-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [309.0, 1864.0, 73.0, 57.0], "category_id": 3, "id": 0}, {"bbox": [193.0, 678.0, 344.0, 604.0], "category_id": 1, "id": 1}, {"bbox": [640.1, 794.0, 281.9, 198.4], "category_id": 1, "id": 2}, {"bbox": [328.16, 1267.77, 65.27, 55.23], "category_id": 3, "id": 3}, {"bbox": [198.1, 1353.5, 542.9, 592.5], "category_id": 1, "id": 4}, {"bbox": [814.1, 1488.0, 333.4, 259.5], "category_id": 1, "id": 5}], "caption": "Table 2. Resolution examples with various molar ratios of (+)-DTTA over (()-MAC ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 393, 81], "ImageBB": [74, 84, 410, 571]}, "corefs": [[1, 3], [4, 0]]}, {"id": 666, "width": 1352, "height": 592, "file_name": "ol9913542-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [163.0, 136.9, 444.7, 408.1], "category_id": 1, "id": 0}, {"bbox": [329.0, 548.0, 44.0, 36.0], "category_id": 3, "id": 1}, {"bbox": [872.0, 548.0, 52.0, 34.0], "category_id": 3, "id": 2}, {"bbox": [654.5, 176.2, 534.0, 347.7], "category_id": 1, "id": 3}], "caption": "Figure 1. Transition states leading to cis- and trans-vinylcyclo- propanes. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 335, 409, 362], "ImageBB": [73, 174, 411, 322]}, "corefs": [[0, 1], [3, 2]]}, {"id": 667, "width": 1352, "height": 2276, "file_name": "ol991134o-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 1569.0, 272.0, 81.0], "category_id": 3, "id": 0}, {"bbox": [0.0, 792.0, 267.0, 81.0], "category_id": 3, "id": 1}, {"bbox": [234.0, 1667.9, 1103.3, 608.1], "category_id": 1, "id": 2}, {"bbox": [230.2, 933.6, 1115.9, 461.5], "category_id": 1, "id": 3}], "caption": "Figure 1. Crystal structures of carbamates (S)-10 and (S)-11, achieved from starting material (R)-8. O: red. N: blue. S: yellow. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 633, 775, 660], "ImageBB": [439, 52, 777, 620]}, "corefs": [[3, 1], [2, 0]]}, {"id": 668, "width": 1352, "height": 696, "file_name": "ol990688o-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [888.7, 137.0, 418.3, 405.4], "category_id": 1, "id": 0}, {"bbox": [44.9, 142.4, 438.1, 393.6], "category_id": 1, "id": 1}, {"bbox": [284.0, 644.0, 52.0, 45.0], "category_id": 3, "id": 2}], "caption": "Figure 1. 1,2-Asymmetric induction.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 289, 635, 302], "ImageBB": [439, 103, 777, 277]}, "corefs": [[1, 2]]}, {"id": 669, "width": 1352, "height": 644, "file_name": "ol9905250-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [703.6, 163.5, 346.3, 191.4], "category_id": 1, "id": 0}, {"bbox": [799.2, 372.0, 246.8, 176.5], "category_id": 1, "id": 1}, {"bbox": [301.9, 159.0, 338.1, 400.0], "category_id": 1, "id": 2}], "caption": "Figure 2. Proposed conformations of fluorinated inhibitors bound to CA. In conformation I, an electrostatic interaction is involved between fluorines of the inhibitor and hydrogens of Phe131. In conformation II, the molecular quadrupoles of the fluorinated inhibitor and Phe131 are expected to interact favorably. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 226, 775, 295], "ImageBB": [439, 52, 777, 213]}, "corefs": []}, {"id": 670, "width": 1356, "height": 712, "file_name": "ol901760a-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [723.0, 396.7, 280.0, 155.3], "category_id": 1, "id": 0}, {"bbox": [2.0, 386.1, 338.0, 197.4], "category_id": 1, "id": 1}, {"bbox": [892.6, 151.0, 279.4, 149.0], "category_id": 1, "id": 2}, {"bbox": [546.0, 115.6, 331.0, 185.4], "category_id": 1, "id": 3}, {"bbox": [360.0, 355.0, 330.0, 145.0], "category_id": 1, "id": 4}, {"bbox": [1083.0, 441.0, 271.0, 201.0], "category_id": 1, "id": 5}, {"bbox": [206.0, 178.0, 314.0, 187.0], "category_id": 1, "id": 6}], "caption": "Figure 3. Free energy profile (kcal/mol, 298 K) for the nucleophilic pathway from enynylpiridines E-1a, E-1b, and E-1c to the corre- sponding indolizines. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 536, 760, 578], "ImageBB": [424, 351, 763, 529]}, "corefs": []}, {"id": 671, "width": 1352, "height": 584, "file_name": "ol900636w-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [855.1, 479.72, 75.4, 64.1], "category_id": 3, "id": 0}, {"bbox": [711.4, 118.0, 600.0, 439.4], "category_id": 1, "id": 1}, {"bbox": [152.4, 482.0, 68.6, 64.0], "category_id": 3, "id": 2}, {"bbox": [35.6, 188.2, 644.2, 389.8], "category_id": 1, "id": 3}], "caption": "Figure 2. Structures of 7 (A) and 8 (B) optimized at the B3LYP/ 6-31G(d) level of calculation. Methyl hydrogen atoms have been omitted for clarity. ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 200, 393, 242], "ImageBB": [58, 47, 396, 193]}, "corefs": [[3, 2], [1, 0]]}, {"id": 672, "width": 1348, "height": 796, "file_name": "ol8027253-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [347.0, 112.0, 496.0, 496.0], "category_id": 1, "id": 0}, {"bbox": [450.0, 734.0, 326.0, 62.0], "category_id": 1, "id": 1}], "caption": "Figure 2. Structures of previous bryopyran analogues.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 253, 705, 268], "ImageBB": [425, 47, 762, 246]}, "corefs": []}, {"id": 673, "width": 1416, "height": 592, "file_name": "ol802297h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [501.0, 491.0, 483.0, 98.0], "category_id": 3, "id": 0}, {"bbox": [588.0, 219.0, 329.0, 248.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Proposed structures for tagetitoxin.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 726, 659, 741], "ImageBB": [408, 571, 762, 719]}, "corefs": [[1, 0]]}, {"id": 674, "width": 1416, "height": 864, "file_name": "ol801791g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [841.7, 575.3, 302.2, 220.5], "category_id": 1, "id": 0}, {"bbox": [342.1, 575.8, 364.2, 220.1], "category_id": 1, "id": 1}, {"bbox": [814.0, 214.0, 337.0, 283.7], "category_id": 1, "id": 2}, {"bbox": [338.9, 216.9, 370.1, 284.5], "category_id": 1, "id": 3}], "caption": "Figure 1. Relevant carbocyclic nucleosides.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 863, 652, 878], "ImageBB": [408, 641, 762, 857]}, "corefs": []}, {"id": 675, "width": 1348, "height": 624, "file_name": "ol801498u-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [763.47, 155.91, 162.63, 138.79], "category_id": 1, "id": 0}, {"bbox": [949.61, 322.3, 164.69, 135.3], "category_id": 1, "id": 1}, {"bbox": [613.28, 133.75, 133.72, 135.05], "category_id": 1, "id": 2}, {"bbox": [300.9, 365.5, 142.5, 136.6], "category_id": 1, "id": 3}, {"bbox": [461.2, 339.7, 149.5, 134.9], "category_id": 1, "id": 4}], "caption": "Figure 1. Qualitative relationship between Br\u00f8nsted acidity, Lewis basicity, and soft enolization. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 467, 761, 495], "ImageBB": [425, 304, 762, 460]}, "corefs": []}, {"id": 676, "width": 1348, "height": 692, "file_name": "ol800946x-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [655.0, 113.0, 574.0, 574.0], "category_id": 1, "id": 0}, {"bbox": [267.0, 578.0, 37.0, 49.0], "category_id": 3, "id": 1}, {"bbox": [115.0, 154.3, 356.0, 394.7], "category_id": 1, "id": 2}], "caption": "Figure 2. Structure of 4 in the crystal.28 The ellipsoids are drawn at the 50% probability level, and the hydrogen atoms are drawn with an arbitrary radius. For the enantiomer shown, the Flack x parameter refined to 0.03(4).29 ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 226, 760, 283], "ImageBB": [425, 47, 762, 220]}, "corefs": [[2, 1]]}, {"id": 677, "width": 2816, "height": 1064, "file_name": "ol800946x-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1769.8, 136.0, 370.2, 374.0], "category_id": 1, "id": 0}, {"bbox": [550.0, 674.2, 830.0, 258.8], "category_id": 1, "id": 1}, {"bbox": [1784.0, 610.0, 365.8, 402.0], "category_id": 1, "id": 2}, {"bbox": [1629.0, 1014.0, 685.0, 50.0], "category_id": 3, "id": 3}, {"bbox": [1745.0, 552.0, 467.0, 53.0], "category_id": 3, "id": 4}, {"bbox": [779.0, 559.0, 381.0, 51.0], "category_id": 3, "id": 5}, {"bbox": [823.0, 1009.0, 291.0, 51.0], "category_id": 3, "id": 6}, {"bbox": [504.0, 116.0, 922.0, 427.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Metabolites of the Streptomyces family 1-3 and target structure 4.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 321, 456, 336], "ImageBB": [58, 48, 762, 314]}, "corefs": [[7, 5], [0, 4], [1, 6], [2, 3]]}, {"id": 678, "width": 1352, "height": 1052, "file_name": "ol8005198-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [198.0, 118.0, 922.0, 192.0], "category_id": 1, "id": 0}, {"bbox": [692.0, 713.0, 413.0, 198.0], "category_id": 1, "id": 1}, {"bbox": [905.07, 623.63, 51.51, 43.38], "category_id": 3, "id": 2}, {"bbox": [255.0, 710.0, 308.0, 192.0], "category_id": 1, "id": 3}, {"bbox": [320.3, 394.0, 330.7, 242.8], "category_id": 1, "id": 4}, {"bbox": [757.2, 435.0, 382.8, 192.0], "category_id": 1, "id": 5}, {"bbox": [284.17, 638.54, 371.46, 56.94], "category_id": 3, "id": 6}, {"bbox": [271.3, 287.2, 751.7, 95.8], "category_id": 3, "id": 7}, {"bbox": [465.1, 926.0, 641.9, 53.0], "category_id": 3, "id": 8}, {"bbox": [465.2, 995.0, 637.8, 50.0], "category_id": 3, "id": 9}], "caption": "Figure 1. Structures of small bacteriocin (1) and acyl homoserine lactones from Gram-negative bacteria. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 317, 393, 345], "ImageBB": [58, 47, 396, 310]}, "corefs": [[0, 7], [4, 6], [5, 2], [3, 8], [1, 9]]}, {"id": 679, "width": 1352, "height": 544, "file_name": "ol800418m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [479.6, 483.0, 388.4, 56.0], "category_id": 3, "id": 0}, {"bbox": [340.0, 120.0, 676.0, 337.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Chemical structure of lancifodilactone G.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 802, 324, 817], "ImageBB": [58, 660, 396, 796]}, "corefs": [[1, 0]]}, {"id": 680, "width": 1352, "height": 564, "file_name": "ol8001706-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [151.7, 137.7, 390.8, 362.6], "category_id": 1, "id": 0}, {"bbox": [702.6, 136.5, 497.8, 358.7], "category_id": 1, "id": 1}, {"bbox": [265.07, 513.94, 74.2, 49.2], "category_id": 3, "id": 2}, {"bbox": [833.35, 512.84, 119.2, 50.3], "category_id": 3, "id": 3}], "caption": "Figure 3. Chiral ligand L5 and the complex of Ti/L4.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 205, 358, 218], "ImageBB": [73, 52, 411, 193]}, "corefs": [[0, 2], [1, 3]]}, {"id": 681, "width": 1352, "height": 508, "file_name": "ol8001706-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [883.0, 229.0, 463.0, 186.0], "category_id": 3, "id": 0}, {"bbox": [7.0, 209.0, 318.0, 184.0], "category_id": 1, "id": 1}, {"bbox": [452.0, 142.0, 328.0, 362.0], "category_id": 1, "id": 2}, {"bbox": [83.0, 417.0, 131.0, 45.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Structure of diene 1 and chiral ligands L1-L4.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 190, 742, 203], "ImageBB": [439, 51, 777, 178]}, "corefs": [[1, 3], [2, 0]]}, {"id": 682, "width": 1356, "height": 668, "file_name": "ol702142j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1005.0, 291.0, 183.0, 96.0], "category_id": 3, "id": 0}, {"bbox": [278.0, 299.0, 162.0, 90.0], "category_id": 3, "id": 1}, {"bbox": [311.0, 613.0, 48.0, 55.0], "category_id": 3, "id": 2}, {"bbox": [1022.0, 618.0, 40.0, 50.0], "category_id": 3, "id": 3}, {"bbox": [2.0, 136.0, 722.0, 149.0], "category_id": 1, "id": 4}, {"bbox": [748.0, 142.0, 608.0, 129.0], "category_id": 1, "id": 5}, {"bbox": [740.0, 416.0, 607.0, 189.0], "category_id": 1, "id": 6}, {"bbox": [36.0, 465.2, 650.0, 130.8], "category_id": 1, "id": 7}], "caption": "Figure 1. Axle molecules.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 352, 215, 365], "ImageBB": [73, 173, 412, 340]}, "corefs": [[4, 1], [5, 0], [7, 2], [6, 3]]}, {"id": 683, "width": 1344, "height": 780, "file_name": "ol401042b-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [338.02, 693.02, 75.0, 67.0], "category_id": 3, "id": 0}, {"bbox": [68.1, 354.1, 606.8, 327.7], "category_id": 1, "id": 1}, {"bbox": [708.0, 161.1, 597.0, 600.9], "category_id": 1, "id": 2}], "caption": "Figure 1. X-ray crystallographic analysis of cyclohexa-1,3-diene 4i.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 267, 405, 280], "ImageBB": [71, 59, 407, 254]}, "corefs": [[1, 0]]}, {"id": 684, "width": 1344, "height": 984, "file_name": "ol303375x-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [331.3, 163.2, 974.5, 397.7], "category_id": 1, "id": 0}, {"bbox": [40.9, 165.7, 269.7, 662.7], "category_id": 1, "id": 1}, {"bbox": [330.93, 575.31, 980.67, 403.59], "category_id": 1, "id": 2}, {"bbox": [34.5, 828.5, 330.5, 155.5], "category_id": 3, "id": 3}, {"bbox": [897.7, 890.22, 251.07, 59.6], "category_id": 3, "id": 4}, {"bbox": [898.97, 474.3, 251.07, 59.6], "category_id": 3, "id": 5}], "caption": "Figure 1. QPP core 1 and previously described tetraalkoxy and tetraalkylthio-substituted QPP derivatives 2. QPP derivatives 3 and 4 are new liquid crystalline derivatives reported here. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 615, 405, 656], "ImageBB": [71, 356, 407, 602]}, "corefs": [[1, 3], [0, 5], [2, 4]]}, {"id": 685, "width": 1344, "height": 364, "file_name": "ol302863r-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [314.0, 163.0, 318.0, 156.0], "category_id": 1, "id": 0}, {"bbox": [401.57, 327.57, 138.0, 33.0], "category_id": 3, "id": 1}, {"bbox": [713.0, 165.0, 312.0, 159.0], "category_id": 1, "id": 2}, {"bbox": [798.29, 327.42, 137.81, 34.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Structures of the hydrophobic tags (HO-TAGa, HO- TAGb) used in this work. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 346, 771, 373], "ImageBB": [437, 242, 773, 333]}, "corefs": [[0, 1], [2, 3]]}, {"id": 686, "width": 1356, "height": 1204, "file_name": "ol301535j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [35.0, 198.8, 333.3, 189.2], "category_id": 1, "id": 0}, {"bbox": [835.9, 467.0, 465.1, 340.0], "category_id": 1, "id": 1}, {"bbox": [826.1, 162.0, 464.0, 231.3], "category_id": 1, "id": 2}, {"bbox": [5.0, 485.0, 617.1, 251.0], "category_id": 1, "id": 3}, {"bbox": [7.2, 839.0, 715.8, 259.8], "category_id": 1, "id": 4}, {"bbox": [763.7, 858.0, 586.3, 245.0], "category_id": 1, "id": 5}], "caption": "Figure 1. Biologically active sultams.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 372, 267, 385], "ImageBB": [71, 59, 410, 360]}, "corefs": []}, {"id": 687, "width": 1348, "height": 2296, "file_name": "ol300808c-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [694.0, 502.0, 638.0, 330.4], "category_id": 1, "id": 0}, {"bbox": [29.0, 483.0, 631.0, 354.5], "category_id": 1, "id": 1}, {"bbox": [460.0, 295.0, 373.1, 103.2], "category_id": 1, "id": 2}, {"bbox": [369.0, 828.0, 35.0, 37.0], "category_id": 3, "id": 3}, {"bbox": [415.0, 831.0, 34.0, 31.0], "category_id": 3, "id": 4}, {"bbox": [1021.0, 832.0, 36.0, 29.0], "category_id": 3, "id": 5}, {"bbox": [1067.0, 832.0, 33.0, 28.0], "category_id": 3, "id": 6}, {"bbox": [9.0, 0.0, 611.0, 263.0], "category_id": 1, "id": 7}, {"bbox": [677.0, 0.0, 671.0, 260.0], "category_id": 1, "id": 8}], "caption": "Table 2. Solid-Phase CM of Peptoids Containing Arbitrary Sequences on Different Resinsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 752, 114], "ImageBB": [436, 126, 773, 700]}, "corefs": [[1, 3], [1, 4], [0, 5], [0, 6]]}, {"id": 688, "width": 1352, "height": 2276, "file_name": "ol300353w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [709.0, 1899.7, 475.0, 262.3], "category_id": 1, "id": 0}, {"bbox": [148.0, 1401.5, 463.0, 234.5], "category_id": 1, "id": 1}, {"bbox": [146.0, 1848.0, 467.0, 301.0], "category_id": 1, "id": 2}, {"bbox": [705.0, 1389.0, 475.0, 259.0], "category_id": 1, "id": 3}], "caption": "Figure 1. Proposed transition state for Kobayashi\u2019s syn-selective aldol reaction. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 640, 771, 667], "ImageBB": [436, 58, 774, 627]}, "corefs": []}, {"id": 689, "width": 1344, "height": 828, "file_name": "ol203272k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [785.08, 184.57, 41.62, 48.01], "category_id": 3, "id": 0}, {"bbox": [27.5, 187.77, 42.69, 43.75], "category_id": 3, "id": 1}, {"bbox": [780.6, 168.0, 539.4, 516.0], "category_id": 1, "id": 2}, {"bbox": [64.1, 163.9, 540.9, 516.1], "category_id": 1, "id": 3}], "caption": "Figure 1. The Ser-Pro dipeptide motif forms a unique turn structure, referred to here as the SP turn. In the SP turn, two distinct patterns of hydrogen bonding are possible. The left panel shows an SP turn with the 6 \u00fe 10 hydrogen-bonding pattern and the corresponding diagnostic NOEs (NOE-6 and NOE-10). The right panel shows an SP turn with a 9 \u00fe 10 hydrogen-bonding pattern and the corresponding diagnostic NOEs (NOE-9 and NOE-10). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 358, 405, 468], "ImageBB": [71, 138, 407, 345]}, "corefs": [[3, 1], [2, 0]]}, {"id": 690, "width": 1344, "height": 660, "file_name": "ol202880y-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [340.5, 162.3, 664.5, 497.7], "category_id": 1, "id": 0}], "caption": "Figure 2. Concerted transition state of DMDO attack at the re- face mediates cyclization to the syn-cis product. ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 237, 405, 264], "ImageBB": [71, 59, 407, 224]}, "corefs": []}, {"id": 691, "width": 1344, "height": 860, "file_name": "ol202395s-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [222.7, 798.8, 150.4, 60.0], "category_id": 3, "id": 0}, {"bbox": [804.9, 361.1, 464.8, 317.6], "category_id": 1, "id": 1}, {"bbox": [66.0, 328.6, 503.5, 338.6], "category_id": 1, "id": 2}], "caption": "Figure 2. Electronic and steric factors in the reaction of P-vinyl- \u03bb5-phosphazenes and 3-methoxybenzyne. ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 784, 771, 813], "ImageBB": [437, 556, 773, 771]}, "corefs": [[2, 0]]}, {"id": 692, "width": 1344, "height": 488, "file_name": "ol202395s-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [518.0, 160.0, 310.0, 328.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Schematic representation of 1,4-additions to P-alkenyl- \u03bb5-phosphazenes. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 436, 405, 465], "ImageBB": [71, 302, 407, 424]}, "corefs": []}, {"id": 693, "width": 1412, "height": 1340, "file_name": "ol202381m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1002.0, 310.0, 372.4, 411.8], "category_id": 1, "id": 0}, {"bbox": [139.3, 888.8, 338.7, 364.4], "category_id": 1, "id": 1}, {"bbox": [469.0, 891.8, 439.6, 359.2], "category_id": 1, "id": 2}, {"bbox": [933.0, 888.8, 406.0, 359.2], "category_id": 1, "id": 3}, {"bbox": [533.2, 314.8, 378.4, 417.8], "category_id": 1, "id": 4}, {"bbox": [108.2, 319.0, 371.8, 358.0], "category_id": 1, "id": 5}, {"bbox": [481.6, 737.3, 465.4, 100.7], "category_id": 3, "id": 6}, {"bbox": [896.0, 1243.0, 473.0, 95.3], "category_id": 3, "id": 7}, {"bbox": [177.6, 1250.11, 229.3, 43.6], "category_id": 3, "id": 8}, {"bbox": [1026.0, 732.0, 304.0, 64.0], "category_id": 3, "id": 9}, {"bbox": [506.22, 1246.0, 333.0, 48.0], "category_id": 3, "id": 10}, {"bbox": [116.0, 732.0, 310.0, 64.0], "category_id": 3, "id": 11}], "caption": "Figure 1. Known alkaloids of the bohemamine type.", "pdf": {"Page": 1, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 829, 715, 842], "ImageBB": [420, 481, 773, 816]}, "corefs": [[5, 11], [4, 6], [0, 9], [1, 8], [2, 10], [3, 7]]}, {"id": 694, "width": 1344, "height": 600, "file_name": "ol201915j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [838.0, 179.0, 340.0, 42.0], "category_id": 1, "id": 0}, {"bbox": [23.0, 168.0, 617.0, 432.0], "category_id": 1, "id": 1}, {"bbox": [758.0, 396.0, 445.9, 133.0], "category_id": 1, "id": 2}], "caption": "Figure 1. [2]pseudorotaxanes PS1 and PS2 and binding data obtained by 1H NMR experiments at 233 K. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 222, 405, 249], "ImageBB": [71, 59, 407, 209]}, "corefs": []}, {"id": 695, "width": 1344, "height": 356, "file_name": "ol2017438-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [73.0, 6.0, 220.0, 132.0], "category_id": 1, "id": 0}, {"bbox": [761.0, 3.0, 527.0, 220.0], "category_id": 3, "id": 1}, {"bbox": [293.0, 1.0, 467.0, 181.0], "category_id": 3, "id": 2}], "caption": "Table 1. Optimization Employing Proline-Based Amine Saltsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 86, 766, 102], "ImageBB": [437, 113, 773, 202]}, "corefs": [[0, 2], [0, 1]]}, {"id": 696, "width": 1344, "height": 484, "file_name": "ol200717n-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [328.0, 163.0, 670.0, 321.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of fluvirucin B1 (the 3,6-dideoxy-3-amino-L- talose residue is highlighted in red). ", "pdf": {"Page": 1, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 940, 771, 967], "ImageBB": [437, 806, 773, 927]}, "corefs": []}, {"id": 697, "width": 2808, "height": 488, "file_name": "ol200296j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2194.0, 348.0, 24.0, 39.0], "category_id": 3, "id": 0}, {"bbox": [884.0, 194.0, 241.0, 203.0], "category_id": 1, "id": 1}, {"bbox": [229.0, 188.0, 563.0, 300.0], "category_id": 1, "id": 2}, {"bbox": [2086.0, 116.0, 246.0, 206.0], "category_id": 1, "id": 3}, {"bbox": [992.0, 430.0, 27.0, 35.0], "category_id": 3, "id": 4}], "caption": "Figure 1. Limit structures in D-A approach.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 445, 310, 458], "ImageBB": [71, 310, 773, 432]}, "corefs": [[1, 4], [3, 0]]}, {"id": 698, "width": 1344, "height": 1152, "file_name": "ol102975t-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [860.7, 696.2, 457.0, 345.3], "category_id": 1, "id": 0}, {"bbox": [218.0, 760.7, 263.0, 241.3], "category_id": 1, "id": 1}, {"bbox": [842.1, 161.4, 464.8, 347.3], "category_id": 1, "id": 2}, {"bbox": [43.1, 180.4, 457.9, 350.3], "category_id": 1, "id": 3}, {"bbox": [548.4, 914.23, 103.47, 210.02], "category_id": 1, "id": 4}], "caption": "Figure 1. Proposed detection mechanism of RHP.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 359, 336, 372], "ImageBB": [71, 59, 407, 347]}, "corefs": []}, {"id": 699, "width": 1348, "height": 1192, "file_name": "ol1017933-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [332.0, 603.0, 770.0, 589.0], "category_id": 1, "id": 0}, {"bbox": [169.0, 126.0, 437.1, 420.7], "category_id": 1, "id": 1}, {"bbox": [78.4, 563.8, 90.8, 88.0], "category_id": 3, "id": 2}, {"bbox": [77.2, 103.0, 89.8, 88.4], "category_id": 3, "id": 3}, {"bbox": [806.0, 118.0, 457.6, 430.0], "category_id": 1, "id": 4}], "caption": "Figure 4. (a) Resonance structures of 2. (b) The total spin-density distribution of 2 calculated by the DFT UMPW1PW91/6-31G(d). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 909, 760, 937], "ImageBB": [425, 605, 762, 903]}, "corefs": [[1, 3], [0, 2]]}, {"id": 700, "width": 2816, "height": 1044, "file_name": "ol1014703-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [916.85, 976.0, 63.45, 68.0], "category_id": 3, "id": 0}, {"bbox": [1923.72, 978.11, 62.18, 65.89], "category_id": 3, "id": 1}, {"bbox": [390.0, 110.0, 1070.0, 828.0], "category_id": 1, "id": 2}, {"bbox": [1471.0, 115.0, 1096.0, 828.0], "category_id": 1, "id": 3}], "caption": "Figure 4. ORTEP representation of lucknolides A and B (1 and 2). Ellipsoids with 50% probability.", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 315, 576, 330], "ImageBB": [58, 48, 762, 309]}, "corefs": [[2, 0], [3, 1]]}, {"id": 701, "width": 1352, "height": 716, "file_name": "ol1014703-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1074.0, 603.0, 73.0, 61.0], "category_id": 3, "id": 0}, {"bbox": [674.0, 605.0, 67.0, 62.0], "category_id": 3, "id": 1}, {"bbox": [73.0, 200.0, 418.0, 339.0], "category_id": 1, "id": 2}, {"bbox": [506.0, 184.0, 344.0, 354.0], "category_id": 1, "id": 3}, {"bbox": [882.0, 118.0, 393.0, 425.0], "category_id": 1, "id": 4}, {"bbox": [182.0, 610.0, 205.6, 102.9], "category_id": 3, "id": 5}], "caption": "Figure 1. Structure of lucknolide A (1) and lucknolide B (2). Bold bonds in substructure 1a indicate 1H-1H COSY correlations; partial structure 1b was derived from 1H-1H COSY and HMBC correla- tions. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 669, 393, 725], "ImageBB": [58, 484, 396, 663]}, "corefs": [[2, 5], [3, 1], [4, 0]]}, {"id": 702, "width": 1352, "height": 1052, "file_name": "ol101168w-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [484.8, 128.8, 338.1, 171.5], "category_id": 1, "id": 0}, {"bbox": [647.7, 1005.2, 104.3, 37.75], "category_id": 3, "id": 1}, {"bbox": [196.3, 1001.6, 88.7, 43.4], "category_id": 3, "id": 2}, {"bbox": [211.3, 658.0, 67.2, 50.0], "category_id": 3, "id": 3}, {"bbox": [650.2, 656.0, 88.8, 49.0], "category_id": 3, "id": 4}, {"bbox": [1068.0, 656.0, 92.5, 49.0], "category_id": 3, "id": 5}, {"bbox": [490.7, 743.3, 326.9, 234.8], "category_id": 1, "id": 6}, {"bbox": [104.8, 740.7, 267.6, 237.5], "category_id": 1, "id": 7}, {"bbox": [905.5, 118.5, 404.6, 182.1], "category_id": 1, "id": 8}, {"bbox": [106.2, 409.7, 325.1, 233.4], "category_id": 1, "id": 9}, {"bbox": [977.4, 414.7, 266.7, 230.5], "category_id": 1, "id": 10}, {"bbox": [554.0, 414.8, 266.7, 232.0], "category_id": 1, "id": 11}, {"bbox": [39.1, 126.1, 338.3, 185.7], "category_id": 1, "id": 12}, {"bbox": [630.0, 318.0, 102.0, 50.0], "category_id": 3, "id": 13}, {"bbox": [195.0, 319.0, 90.0, 47.0], "category_id": 3, "id": 14}, {"bbox": [914.9, 744.9, 390.0, 239.6], "category_id": 1, "id": 15}, {"bbox": [1073.28, 1009.49, 91.72, 41.1], "category_id": 3, "id": 16}, {"bbox": [1062.0, 316.0, 89.6, 44.6], "category_id": 3, "id": 17}], "caption": "Figure 2. Compounds used in this work.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 889, 270, 904], "ImageBB": [58, 619, 396, 882]}, "corefs": [[12, 14], [0, 13], [8, 17], [9, 3], [11, 4], [10, 5], [7, 2], [6, 1], [15, 16]]}, {"id": 703, "width": 1352, "height": 696, "file_name": "ol101168w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [655.1, 128.0, 264.8, 226.0], "category_id": 1, "id": 0}, {"bbox": [192.0, 115.0, 259.0, 238.0], "category_id": 1, "id": 1}, {"bbox": [1016.55, 131.83, 263.06, 226.36], "category_id": 1, "id": 2}, {"bbox": [182.1, 479.0, 127.9, 62.9], "category_id": 1, "id": 3}, {"bbox": [520.0, 473.0, 132.0, 63.9], "category_id": 1, "id": 4}, {"bbox": [183.2, 584.1, 121.7, 61.8], "category_id": 1, "id": 5}, {"bbox": [522.0, 581.0, 125.8, 66.0], "category_id": 1, "id": 6}], "caption": "Figure 1. Redox reactions of anthraquinone (a) and ferrocene (b); cartoon of a single-layer electrochromic device (c). ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 398, 393, 426], "ImageBB": [58, 217, 396, 391]}, "corefs": []}, {"id": 704, "width": 2816, "height": 496, "file_name": "ol1009703-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1085.0, 0.0, 443.0, 271.9], "category_id": 1, "id": 0}, {"bbox": [1564.0, 4.0, 415.0, 263.9], "category_id": 1, "id": 1}, {"bbox": [1993.0, 12.0, 484.0, 243.0], "category_id": 1, "id": 2}, {"bbox": [1732.0, 238.0, 49.0, 42.0], "category_id": 3, "id": 3}, {"bbox": [540.0, 234.0, 55.0, 44.0], "category_id": 3, "id": 4}, {"bbox": [1249.0, 234.0, 50.0, 40.0], "category_id": 3, "id": 5}, {"bbox": [2189.0, 243.0, 48.0, 42.0], "category_id": 3, "id": 6}, {"bbox": [363.5, 0.0, 489.5, 236.0], "category_id": 1, "id": 7}], "caption": "Table 1. Optimization of Domino Carbopalladation-Carbonylation for Amide 7a", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 73, 472, 88], "ImageBB": [58, 97, 762, 221]}, "corefs": [[7, 4], [0, 5], [1, 3], [2, 6]]}, {"id": 705, "width": 1348, "height": 360, "file_name": "ol1009703-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [627.0, 314.0, 62.0, 46.0], "category_id": 3, "id": 0}, {"bbox": [468.0, 114.0, 413.0, 227.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Byproduct observed with DMAP as base.", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 395, 693, 410], "ImageBB": [425, 298, 762, 388]}, "corefs": [[1, 0]]}, {"id": 706, "width": 1356, "height": 3188, "file_name": "ol100734t-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [5.0, 1896.0, 523.0, 578.0], "category_id": 1, "id": 0}, {"bbox": [10.0, 2462.0, 96.0, 75.0], "category_id": 3, "id": 1}, {"bbox": [643.0, 2812.0, 61.0, 54.0], "category_id": 3, "id": 2}, {"bbox": [8.0, 2634.0, 587.0, 554.0], "category_id": 1, "id": 3}, {"bbox": [570.0, 2652.0, 185.0, 172.0], "category_id": 1, "id": 4}, {"bbox": [762.0, 2644.0, 594.0, 412.7], "category_id": 1, "id": 5}, {"bbox": [568.4, 1989.5, 166.7, 187.4], "category_id": 1, "id": 6}, {"bbox": [587.0, 1973.3, 766.0, 397.7], "category_id": 1, "id": 7}], "caption": "Figure 3. (a) Calculated lowest energy conformation of intermediate 2. (b) Calculated lowest energy conformation of intermediate 3. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 853, 761, 881], "ImageBB": [424, 46, 763, 843]}, "corefs": [[0, 1], [4, 2]]}, {"id": 707, "width": 1348, "height": 564, "file_name": "ol100073y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [435.07, 469.08, 52.9, 50.8], "category_id": 3, "id": 0}, {"bbox": [245.2, 115.0, 393.8, 351.9], "category_id": 1, "id": 1}, {"bbox": [942.02, 465.1, 50.0, 53.8], "category_id": 3, "id": 2}, {"bbox": [723.3, 121.0, 419.9, 347.9], "category_id": 1, "id": 3}], "caption": "Figure 1. Proposed transition state model.", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 528, 644, 543], "ImageBB": [425, 380, 762, 521]}, "corefs": [[1, 0], [3, 2]]}, {"id": 708, "width": 1408, "height": 1096, "file_name": "op500208j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [155.0, 542.0, 449.0, 358.0], "category_id": 1, "id": 0}, {"bbox": [895.1, 443.6, 288.9, 557.4], "category_id": 1, "id": 1}], "caption": "Figure 1. Examples for biologically active molecules containing a piperidine core. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 535, 784, 563], "ImageBB": [433, 252, 785, 526]}, "corefs": []}, {"id": 709, "width": 1352, "height": 244, "file_name": "op500155f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [508.0, 39.0, 333.0, 201.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Isonicotinyloxycarbonyl group.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 675, 280, 689], "ImageBB": [82, 605, 420, 666]}, "corefs": []}, {"id": 710, "width": 1352, "height": 484, "file_name": "op5001463-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [477.0, 41.0, 397.0, 443.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of AZD8329.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 649, 244, 663], "ImageBB": [82, 518, 420, 639]}, "corefs": []}, {"id": 711, "width": 1352, "height": 1048, "file_name": "op500063g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [741.0, 280.0, 450.0, 165.0], "category_id": 1, "id": 0}, {"bbox": [728.4, 968.2, 48.2, 41.8], "category_id": 3, "id": 1}, {"bbox": [98.0, 558.0, 463.0, 149.0], "category_id": 1, "id": 2}, {"bbox": [655.0, 555.0, 473.0, 157.0], "category_id": 1, "id": 3}, {"bbox": [424.0, 848.0, 600.0, 173.0], "category_id": 1, "id": 4}, {"bbox": [908.0, 706.2, 52.1, 44.8], "category_id": 3, "id": 5}, {"bbox": [232.0, 31.0, 221.0, 181.0], "category_id": 1, "id": 6}, {"bbox": [710.0, 41.0, 537.0, 162.0], "category_id": 1, "id": 7}, {"bbox": [185.0, 271.0, 393.0, 171.0], "category_id": 1, "id": 8}, {"bbox": [316.6, 194.0, 38.4, 52.4], "category_id": 3, "id": 9}, {"bbox": [954.0, 196.4, 47.0, 42.6], "category_id": 3, "id": 10}, {"bbox": [339.0, 412.0, 38.9, 55.4], "category_id": 3, "id": 11}, {"bbox": [938.62, 429.62, 51.4, 45.8], "category_id": 3, "id": 12}, {"bbox": [333.0, 692.6, 61.0, 46.4], "category_id": 3, "id": 13}], "caption": "Figure 1. Antibiotics developed for the treatment of serious infections caused by Gram-positive bacteria. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1014, 417, 1042], "ImageBB": [82, 742, 420, 1004]}, "corefs": [[6, 9], [7, 10], [8, 11], [0, 12], [2, 13], [3, 5], [4, 1]]}, {"id": 712, "width": 1352, "height": 536, "file_name": "op5000094-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1040.06, 485.08, 54.8, 45.9], "category_id": 3, "id": 0}, {"bbox": [824.2, 100.8, 388.0, 345.8], "category_id": 1, "id": 1}, {"bbox": [139.6, 40.3, 391.9, 412.3], "category_id": 1, "id": 2}, {"bbox": [341.0, 487.0, 57.0, 48.0], "category_id": 3, "id": 3}], "caption": "Figure 2. Retrosynthesis of ketone 9.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 484, 260, 498], "ImageBB": [82, 341, 420, 475]}, "corefs": [[2, 3], [1, 0]]}, {"id": 713, "width": 3396, "height": 1520, "file_name": "op4003505-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1704.1, 283.5, 970.3, 656.3], "category_id": 1, "id": 0}, {"bbox": [1672.0, 1153.2, 206.0, 213.8], "category_id": 1, "id": 1}, {"bbox": [1125.0, 1080.2, 477.0, 331.8], "category_id": 1, "id": 2}, {"bbox": [858.2, 396.0, 585.8, 348.2], "category_id": 1, "id": 3}, {"bbox": [2207.0, 1173.7, 124.0, 182.5], "category_id": 1, "id": 4}, {"bbox": [1953.0, 1161.9, 179.0, 210.1], "category_id": 1, "id": 5}], "caption": "Figure 1. Structures of ATT and paclitaxel and overview of the taxane carbon numbering scheme.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 411, 559, 425], "ImageBB": [10, 22, 859, 402]}, "corefs": []}, {"id": 714, "width": 1356, "height": 2312, "file_name": "op400278d-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [271.0, 82.0, 179.0, 179.0], "category_id": 1, "id": 0}, {"bbox": [32.0, 114.0, 157.0, 187.0], "category_id": 1, "id": 1}, {"bbox": [893.0, 76.0, 237.0, 134.0], "category_id": 1, "id": 2}, {"bbox": [843.0, 214.0, 172.0, 130.0], "category_id": 1, "id": 3}, {"bbox": [1063.0, 232.0, 163.0, 120.0], "category_id": 1, "id": 4}, {"bbox": [1114.0, 145.0, 223.0, 72.0], "category_id": 1, "id": 5}, {"bbox": [189.0, 299.0, 263.0, 45.0], "category_id": 1, "id": 6}, {"bbox": [993.0, 1433.0, 324.0, 306.0], "category_id": 1, "id": 7}, {"bbox": [523.0, 1532.0, 328.0, 278.0], "category_id": 1, "id": 8}, {"bbox": [18.0, 1490.0, 366.0, 301.0], "category_id": 1, "id": 9}, {"bbox": [809.0, 704.0, 249.0, 248.0], "category_id": 1, "id": 10}, {"bbox": [793.0, 1914.0, 201.0, 226.0], "category_id": 1, "id": 11}, {"bbox": [388.0, 1928.0, 299.0, 196.0], "category_id": 1, "id": 12}, {"bbox": [3.0, 2016.0, 337.0, 168.0], "category_id": 1, "id": 13}, {"bbox": [9.0, 1182.0, 358.0, 216.0], "category_id": 1, "id": 14}, {"bbox": [441.0, 1272.0, 267.0, 190.0], "category_id": 1, "id": 15}, {"bbox": [760.0, 1117.0, 318.0, 209.0], "category_id": 1, "id": 16}, {"bbox": [1103.0, 999.0, 252.0, 171.0], "category_id": 1, "id": 17}, {"bbox": [381.0, 1041.0, 377.0, 132.0], "category_id": 1, "id": 18}, {"bbox": [9.0, 787.0, 332.0, 337.0], "category_id": 1, "id": 19}, {"bbox": [412.0, 725.0, 296.0, 195.0], "category_id": 1, "id": 20}, {"bbox": [1022.0, 1939.0, 322.0, 207.0], "category_id": 1, "id": 21}, {"bbox": [1146.0, 436.0, 179.0, 377.0], "category_id": 1, "id": 22}, {"bbox": [788.0, 417.0, 313.0, 169.0], "category_id": 1, "id": 23}, {"bbox": [431.0, 423.0, 285.0, 176.0], "category_id": 1, "id": 24}, {"bbox": [14.0, 511.0, 334.0, 185.0], "category_id": 1, "id": 25}, {"bbox": [144.0, 698.0, 33.0, 38.0], "category_id": 3, "id": 26}, {"bbox": [552.0, 599.0, 39.0, 36.0], "category_id": 3, "id": 27}, {"bbox": [930.0, 591.0, 34.0, 39.0], "category_id": 3, "id": 28}, {"bbox": [1225.0, 827.0, 40.0, 47.0], "category_id": 3, "id": 29}, {"bbox": [933.0, 953.0, 48.0, 39.0], "category_id": 3, "id": 30}, {"bbox": [553.0, 907.0, 35.0, 49.0], "category_id": 3, "id": 31}, {"bbox": [109.0, 1026.0, 40.0, 39.0], "category_id": 3, "id": 32}, {"bbox": [554.0, 1166.0, 41.0, 42.0], "category_id": 3, "id": 33}, {"bbox": [173.0, 1389.0, 51.0, 37.0], "category_id": 3, "id": 34}, {"bbox": [872.0, 1337.0, 53.0, 43.0], "category_id": 3, "id": 35}, {"bbox": [1213.0, 1183.0, 50.0, 39.0], "category_id": 3, "id": 36}, {"bbox": [1002.0, 1849.0, 53.0, 50.0], "category_id": 3, "id": 37}, {"bbox": [1007.0, 1819.0, 52.0, 39.0], "category_id": 3, "id": 38}, {"bbox": [670.0, 1785.0, 54.0, 38.0], "category_id": 3, "id": 39}, {"bbox": [202.0, 1782.0, 46.0, 35.0], "category_id": 3, "id": 40}, {"bbox": [163.0, 2188.0, 53.0, 52.0], "category_id": 3, "id": 41}, {"bbox": [343.0, 2229.0, 57.0, 34.0], "category_id": 3, "id": 42}, {"bbox": [344.0, 2176.0, 56.0, 48.0], "category_id": 3, "id": 43}, {"bbox": [865.0, 2160.0, 67.0, 37.0], "category_id": 3, "id": 44}, {"bbox": [1150.0, 2158.0, 62.0, 43.0], "category_id": 3, "id": 45}], "caption": "Table 1. Low-temperature aryl sul\ufb01nations with aryl-, alkyl-, and silylthiols using Pd-PEPPSI-IPent (1) ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 285, 784, 316], "ImageBB": [448, 321, 787, 899]}, "corefs": [[25, 26], [24, 27], [23, 28], [22, 29], [19, 32], [20, 31], [10, 30], [17, 36], [16, 35], [18, 33], [14, 34], [9, 40], [8, 39], [7, 37], [7, 38], [13, 41], [12, 43], [12, 42], [11, 44], [21, 45]]}, {"id": 715, "width": 2820, "height": 584, "file_name": "op400278d-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [950.0, 75.3, 504.5, 218.6], "category_id": 1, "id": 0}, {"bbox": [1459.1, 71.9, 403.5, 220.0], "category_id": 1, "id": 1}, {"bbox": [1873.7, 41.1, 394.3, 252.9], "category_id": 1, "id": 2}, {"bbox": [545.5, 79.5, 400.1, 200.9], "category_id": 1, "id": 3}], "caption": "Figure 4. Proposed ranking of reactivity of selected Pd\u2212NHC catalysts in C\u2212N and C\u2212S cross-coupling.", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1046, 595, 1060], "ImageBB": [82, 880, 787, 1026]}, "corefs": []}, {"id": 716, "width": 1352, "height": 604, "file_name": "op400278d-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [12.34, 500.35, 612.06, 100.65], "category_id": 3, "id": 0}, {"bbox": [672.0, 27.0, 677.0, 459.0], "category_id": 1, "id": 1}, {"bbox": [861.0, 502.0, 386.8, 51.1], "category_id": 3, "id": 2}, {"bbox": [0.0, 33.0, 577.0, 403.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Pd\u2212NHC precatalysts reported by Nolan and co-workers.", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 815, 413, 829], "ImageBB": [82, 655, 420, 806]}, "corefs": [[3, 0], [1, 2]]}, {"id": 717, "width": 3396, "height": 892, "file_name": "op400278d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1925.0, 306.9, 616.0, 452.7], "category_id": 1, "id": 0}, {"bbox": [851.0, 292.0, 520.0, 472.0], "category_id": 1, "id": 1}, {"bbox": [1388.0, 311.0, 515.0, 449.8], "category_id": 1, "id": 2}, {"bbox": [1090.0, 803.0, 28.0, 40.0], "category_id": 3, "id": 3}, {"bbox": [1621.0, 804.0, 32.0, 39.0], "category_id": 3, "id": 4}, {"bbox": [2213.0, 803.0, 30.0, 45.0], "category_id": 3, "id": 5}], "caption": "Figure 1. Structures of Pd-PEPPSI-IPent, Pd-PEPPSI-IPr and Pd-PEPPSI-IMes.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 254, 469, 268], "ImageBB": [10, 22, 859, 245]}, "corefs": [[1, 3], [2, 4], [0, 5]]}, {"id": 718, "width": 3396, "height": 1772, "file_name": "op400269b-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [581.0, 301.0, 271.0, 269.1], "category_id": 1, "id": 0}, {"bbox": [1248.8, 288.2, 224.5, 280.7], "category_id": 1, "id": 1}, {"bbox": [1899.0, 280.0, 221.1, 277.0], "category_id": 1, "id": 2}, {"bbox": [910.0, 290.2, 224.4, 279.6], "category_id": 1, "id": 3}, {"bbox": [1572.3, 278.0, 236.7, 283.3], "category_id": 1, "id": 4}, {"bbox": [1917.0, 582.0, 95.0, 58.0], "category_id": 3, "id": 5}, {"bbox": [1276.0, 598.0, 66.0, 50.0], "category_id": 3, "id": 6}, {"bbox": [940.0, 598.0, 52.0, 42.0], "category_id": 3, "id": 7}, {"bbox": [614.0, 606.0, 50.0, 26.0], "category_id": 3, "id": 8}, {"bbox": [1610.0, 582.0, 99.0, 53.0], "category_id": 3, "id": 9}], "caption": "Figure 1. Monitoring of intermediates I, II/III, and of 11a and 12a during the hydrogenation of 11a by LC\u2212MS. (a) 3% Pt/2.5% V (Degussa CF 1082 RV/W) (b) 10% Pd/C (Engelhard ESCAT 163). Reaction in EtOH, H2 (1 bar), 10% w/w catalyst loading. [LC\u2212MS conditions: Eclipse Plus C18, 1.8 \u03bcm, 2.1 mm \u00d7 50 mm, 1 mL/min, 50 \u00b0C, eluent A: water, 0.04% TFA, eluent B: acetonitrile, 0.006% TFA, gradient: 2 min 95% B, 2.8 min 95% B, 3.0 min 5% B.] ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 475, 784, 530], "ImageBB": [10, 22, 859, 465]}, "corefs": [[0, 8], [3, 7], [1, 6], [4, 9], [2, 5]]}, {"id": 719, "width": 1416, "height": 1268, "file_name": "op4002164-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [940.5, 128.49, 315.1, 167.51], "category_id": 1, "id": 0}, {"bbox": [118.9, 674.3, 409.7, 349.3], "category_id": 1, "id": 1}, {"bbox": [810.0, 1053.0, 70.8, 69.7], "category_id": 3, "id": 2}, {"bbox": [1276.0, 1061.0, 89.0, 64.5], "category_id": 3, "id": 3}, {"bbox": [1041.0, 358.0, 72.6, 67.5], "category_id": 3, "id": 4}, {"bbox": [639.0, 368.0, 77.0, 58.0], "category_id": 3, "id": 5}, {"bbox": [689.1, 682.5, 320.8, 362.5], "category_id": 1, "id": 6}, {"bbox": [507.9, 0.8, 355.1, 304.3], "category_id": 1, "id": 7}, {"bbox": [0.0, 1050.0, 569.3, 177.3], "category_id": 3, "id": 8}, {"bbox": [1331.0, 356.0, 85.0, 124.3], "category_id": 3, "id": 9}, {"bbox": [0.0, 358.0, 496.8, 283.0], "category_id": 3, "id": 10}, {"bbox": [1304.0, 142.0, 112.0, 89.0], "category_id": 1, "id": 11}, {"bbox": [2.0, 1.0, 357.0, 312.0], "category_id": 1, "id": 12}, {"bbox": [1193.0, 668.0, 223.0, 370.0], "category_id": 1, "id": 13}], "caption": "Table 1. Rh- or Ir-catalyzed hydrogenation of (E)-7\u00b7HNCy2a", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 437, 417, 459], "ImageBB": [82, 119, 436, 436]}, "corefs": [[12, 10], [7, 5], [0, 4], [11, 9], [1, 8], [6, 2], [13, 3]]}, {"id": 720, "width": 1352, "height": 728, "file_name": "op400137m-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [291.0, 43.0, 772.0, 600.0], "category_id": 1, "id": 0}, {"bbox": [634.0, 689.0, 45.0, 37.0], "category_id": 3, "id": 1}], "caption": "Figure 2. Impurity derived from 18.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 259, 338], "ImageBB": [82, 133, 420, 315]}, "corefs": [[0, 1]]}, {"id": 721, "width": 1356, "height": 664, "file_name": "op400055z-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [207.3, 288.0, 271.7, 44.0], "category_id": 3, "id": 0}, {"bbox": [939.3, 271.04, 241.7, 43.0], "category_id": 3, "id": 1}, {"bbox": [963.8, 605.07, 184.24, 46.0], "category_id": 3, "id": 2}, {"bbox": [212.9, 614.1, 234.1, 46.9], "category_id": 3, "id": 3}, {"bbox": [81.0, 394.0, 465.0, 206.0], "category_id": 1, "id": 4}, {"bbox": [809.0, 392.0, 467.0, 196.0], "category_id": 1, "id": 5}, {"bbox": [98.0, 69.0, 470.0, 207.0], "category_id": 1, "id": 6}, {"bbox": [808.0, 51.0, 466.0, 208.0], "category_id": 1, "id": 7}], "caption": "Figure 1. BIBOP ligands.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 599, 574, 613], "ImageBB": [448, 423, 787, 589]}, "corefs": [[6, 0], [7, 1], [4, 3], [5, 2]]}, {"id": 722, "width": 1352, "height": 436, "file_name": "op400039d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [321.0, 42.0, 705.0, 354.0], "category_id": 1, "id": 0}, {"bbox": [670.0, 393.0, 49.0, 34.0], "category_id": 3, "id": 1}], "caption": "Figure 1. Impurity generated by reaction of the lithio reagent of 10 with 21. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 605, 417, 633], "ImageBB": [82, 487, 420, 596]}, "corefs": [[0, 1]]}, {"id": 723, "width": 1416, "height": 1540, "file_name": "op4000219-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [848.0, 0.0, 360.0, 359.8], "category_id": 1, "id": 0}, {"bbox": [571.7, 1481.0, 324.3, 59.0], "category_id": 3, "id": 1}, {"bbox": [418.0, 22.0, 366.0, 295.0], "category_id": 1, "id": 2}, {"bbox": [965.0, 377.0, 63.0, 52.0], "category_id": 3, "id": 3}, {"bbox": [227.0, 1097.0, 892.0, 377.0], "category_id": 1, "id": 4}], "caption": "Figure 2. Structure of eravacycline.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 510, 254, 524], "ImageBB": [82, 116, 436, 501]}, "corefs": [[0, 3], [4, 1]]}, {"id": 724, "width": 3396, "height": 832, "file_name": "op400013e-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [759.0, 277.0, 560.0, 482.0], "category_id": 1, "id": 0}, {"bbox": [1509.0, 366.0, 295.0, 250.0], "category_id": 1, "id": 1}, {"bbox": [2168.0, 380.0, 315.0, 247.0], "category_id": 1, "id": 2}, {"bbox": [909.0, 771.3, 308.8, 60.7], "category_id": 3, "id": 3}, {"bbox": [1659.2, 710.3, 46.8, 58.7], "category_id": 3, "id": 4}, {"bbox": [2321.3, 717.3, 40.7, 51.7], "category_id": 3, "id": 5}], "caption": "Figure 1. Structure of \u03b3-secretase inhibitor 6 and (R)-5,5,5-tri\ufb02uoronorvaline 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 236, 468, 254], "ImageBB": [10, 22, 859, 230]}, "corefs": [[0, 3], [1, 4], [2, 5]]}, {"id": 725, "width": 1352, "height": 828, "file_name": "op300363s-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 41.0, 395.0, 309.0], "category_id": 1, "id": 0}, {"bbox": [493.0, 39.0, 371.0, 313.0], "category_id": 1, "id": 1}, {"bbox": [934.0, 39.0, 415.0, 311.0], "category_id": 1, "id": 2}, {"bbox": [189.0, 439.0, 433.0, 387.0], "category_id": 1, "id": 3}, {"bbox": [909.0, 526.0, 374.0, 202.0], "category_id": 1, "id": 4}], "caption": "Figure 1. Selected pharmaceutically important indoles derived from tryptophol analogues. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 886, 417, 914], "ImageBB": [82, 669, 420, 876]}, "corefs": []}, {"id": 726, "width": 1352, "height": 312, "file_name": "op300306c-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [476.0, 266.0, 52.0, 41.0], "category_id": 3, "id": 0}, {"bbox": [1038.08, 262.0, 60.0, 50.0], "category_id": 3, "id": 1}, {"bbox": [169.3, 63.3, 724.4, 168.5], "category_id": 1, "id": 2}, {"bbox": [909.8, 33.12, 270.0, 214.0], "category_id": 1, "id": 3}], "caption": "Figure 2. Byproducts from the Negishi coupling step.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 251, 344, 265], "ImageBB": [82, 164, 420, 242]}, "corefs": [[2, 0], [3, 1]]}, {"id": 727, "width": 1352, "height": 376, "file_name": "op300306c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [795.0, 127.0, 387.0, 228.6], "category_id": 1, "id": 0}, {"bbox": [977.0, 335.0, 46.0, 35.0], "category_id": 3, "id": 1}, {"bbox": [169.0, 43.0, 617.0, 279.0], "category_id": 1, "id": 2}, {"bbox": [387.0, 333.0, 45.0, 41.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Dimerization product 51 and over-hydrolysis product 52.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 554, 410, 568], "ImageBB": [82, 451, 420, 545]}, "corefs": [[2, 3], [0, 1]]}, {"id": 728, "width": 912, "height": 360, "file_name": "op3002883-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 44.0, 570.0, 184.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Impurity 16.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 877, 193, 891], "ImageBB": [192, 811, 420, 901]}, "corefs": []}, {"id": 729, "width": 1352, "height": 316, "file_name": "op3002883-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [344.0, 40.0, 645.0, 210.0], "category_id": 1, "id": 0}, {"bbox": [686.0, 278.0, 35.0, 34.0], "category_id": 3, "id": 1}], "caption": "Figure 1. Structure of API 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 637, 225, 651], "ImageBB": [82, 549, 420, 628]}, "corefs": [[0, 1]]}, {"id": 730, "width": 1352, "height": 516, "file_name": "op300252n-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [820.0, 70.0, 457.0, 322.0], "category_id": 1, "id": 0}, {"bbox": [57.0, 32.0, 665.0, 386.0], "category_id": 1, "id": 1}, {"bbox": [890.0, 422.9, 275.0, 90.1], "category_id": 3, "id": 2}, {"bbox": [291.0, 439.0, 242.0, 48.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Structures of BMS-690514 and pyrrolotriazine core 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 635, 393, 649], "ImageBB": [82, 497, 420, 626]}, "corefs": [[1, 3], [0, 2]]}, {"id": 731, "width": 1352, "height": 1360, "file_name": "op300209p-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [151.1, 733.2, 430.6, 565.0], "category_id": 1, "id": 0}, {"bbox": [615.0, 768.5, 510.2, 550.5], "category_id": 1, "id": 1}, {"bbox": [812.6, 33.9, 539.4, 526.8], "category_id": 1, "id": 2}, {"bbox": [460.8, 96.7, 397.9, 408.7], "category_id": 1, "id": 3}, {"bbox": [0.0, 196.6, 453.8, 313.3], "category_id": 1, "id": 4}, {"bbox": [76.0, 571.0, 288.8, 65.4], "category_id": 3, "id": 5}, {"bbox": [984.0, 573.0, 291.0, 63.5], "category_id": 3, "id": 6}, {"bbox": [184.0, 1310.0, 242.0, 47.0], "category_id": 3, "id": 7}, {"bbox": [802.0, 1298.0, 253.0, 62.0], "category_id": 3, "id": 8}, {"bbox": [526.82, 568.47, 263.0, 66.6], "category_id": 3, "id": 9}], "caption": "Figure 1. Compounds with a pyrazole moiety.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1028, 309, 1042], "ImageBB": [82, 678, 420, 1018]}, "corefs": [[4, 5], [3, 9], [2, 6], [0, 7], [1, 8]]}, {"id": 732, "width": 1416, "height": 1804, "file_name": "op300205j-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [764.0, 275.0, 215.9, 145.0], "category_id": 1, "id": 0}, {"bbox": [710.0, 1312.0, 322.2, 201.0], "category_id": 1, "id": 1}, {"bbox": [767.0, 761.0, 215.9, 172.0], "category_id": 1, "id": 2}], "caption": "Table 1. Br/Li exchange reaction of heteroaromatic compounds with n-BuLi followed by reaction with electrophiles at 10 \u00b0C using the \ufb02ow microreactor system ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 784, 126], "ImageBB": [10, 131, 859, 1127]}, "corefs": []}, {"id": 733, "width": 1352, "height": 536, "file_name": "op300179u-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [898.2, 37.1, 453.8, 424.9], "category_id": 1, "id": 0}, {"bbox": [374.9, 45.3, 452.1, 425.7], "category_id": 1, "id": 1}, {"bbox": [547.0, 488.0, 63.7, 43.9], "category_id": 3, "id": 2}, {"bbox": [135.98, 471.04, 55.0, 51.8], "category_id": 3, "id": 3}, {"bbox": [5.1, 211.4, 323.1, 236.6], "category_id": 1, "id": 4}, {"bbox": [1105.0, 493.0, 53.0, 43.0], "category_id": 3, "id": 5}], "caption": "Figure 1. Structures of impurities 9, 10, and 11.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1046, 318, 1060], "ImageBB": [82, 892, 420, 1026]}, "corefs": [[4, 3], [1, 2], [0, 5]]}, {"id": 734, "width": 1352, "height": 616, "file_name": "op3001355-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [678.0, 44.0, 631.0, 435.0], "category_id": 1, "id": 0}, {"bbox": [38.0, 41.0, 522.0, 413.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Examples of C- and O-glycosides as SGLT2 inhibitors that have entered clinical development. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 895, 417, 923], "ImageBB": [82, 732, 420, 886]}, "corefs": []}, {"id": 735, "width": 1352, "height": 520, "file_name": "op300130p-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [651.0, 416.0, 44.0, 49.0], "category_id": 3, "id": 0}, {"bbox": [426.4, 40.3, 496.1, 344.7], "category_id": 1, "id": 1}], "caption": "Figure 1. Sulopenem.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 792, 189, 806], "ImageBB": [82, 653, 420, 783]}, "corefs": [[1, 0]]}, {"id": 736, "width": 1352, "height": 376, "file_name": "op300059b-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [997.6, 43.2, 348.4, 269.8], "category_id": 1, "id": 0}, {"bbox": [491.5, 112.4, 350.4, 187.4], "category_id": 1, "id": 1}, {"bbox": [3.0, 120.4, 349.9, 175.5], "category_id": 1, "id": 2}], "caption": "Figure 1. Byproducts detected in the cyclopropanation.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 653, 352, 667], "ImageBB": [82, 549, 420, 643]}, "corefs": []}, {"id": 737, "width": 1352, "height": 792, "file_name": "op200351g-Figure-c8.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [552.0, 477.0, 31.0, 36.0], "category_id": 3, "id": 0}, {"bbox": [848.0, 155.0, 33.0, 39.0], "category_id": 3, "id": 1}, {"bbox": [1177.0, 219.0, 28.0, 40.0], "category_id": 3, "id": 2}, {"bbox": [1065.0, 68.0, 282.0, 166.0], "category_id": 1, "id": 3}, {"bbox": [703.0, 40.0, 283.0, 172.0], "category_id": 1, "id": 4}, {"bbox": [620.0, 306.0, 53.0, 45.0], "category_id": 3, "id": 5}, {"bbox": [452.0, 165.0, 277.0, 158.0], "category_id": 1, "id": 6}, {"bbox": [389.0, 333.0, 242.0, 165.0], "category_id": 1, "id": 7}], "caption": "Figure 8. HPLC traces for cyclization temperature screen at Vreactor/ Qfeed = 15 min: 100 to 190 \u00b0C. ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 739, 417, 768], "ImageBB": [82, 532, 420, 730]}, "corefs": [[7, 0], [6, 5], [4, 1], [3, 2]]}, {"id": 738, "width": 3396, "height": 1324, "file_name": "op200331s-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2589.0, 673.0, 198.0, 227.0], "category_id": 1, "id": 0}, {"bbox": [2855.0, 674.0, 198.0, 187.0], "category_id": 1, "id": 1}, {"bbox": [2594.0, 1023.0, 198.0, 229.0], "category_id": 1, "id": 2}, {"bbox": [2853.0, 1027.0, 210.0, 220.0], "category_id": 1, "id": 3}, {"bbox": [1836.0, 681.0, 109.0, 164.0], "category_id": 1, "id": 4}, {"bbox": [2024.0, 675.0, 201.0, 187.0], "category_id": 1, "id": 5}, {"bbox": [2344.0, 680.0, 155.0, 222.0], "category_id": 1, "id": 6}, {"bbox": [1794.0, 1017.0, 190.0, 232.0], "category_id": 1, "id": 7}, {"bbox": [2028.0, 1026.0, 205.0, 223.0], "category_id": 1, "id": 8}, {"bbox": [2304.0, 1023.0, 198.0, 228.0], "category_id": 1, "id": 9}], "caption": "Figure 6. Flow reactor for generation and use of HOF\u00b7MeCN.", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 356, 388, 370], "ImageBB": [10, 22, 859, 353]}, "corefs": []}, {"id": 739, "width": 1352, "height": 376, "file_name": "op2003216-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [551.1, 39.2, 242.9, 277.7], "category_id": 1, "id": 0}, {"bbox": [636.0, 325.0, 36.0, 49.0], "category_id": 3, "id": 1}], "caption": "Figure 1. Structure of 1-bromoacetyl-3,3-dinitroazetidine (3).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 740, 380, 754], "ImageBB": [82, 637, 420, 731]}, "corefs": [[0, 1]]}, {"id": 740, "width": 1352, "height": 412, "file_name": "op200313v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [702.92, 293.96, 107.0, 54.0], "category_id": 3, "id": 0}, {"bbox": [896.0, 295.9, 127.0, 49.0], "category_id": 3, "id": 1}, {"bbox": [235.4, 38.2, 878.4, 224.3], "category_id": 1, "id": 2}, {"bbox": [441.31, 291.9, 119.79, 48.0], "category_id": 3, "id": 3}], "caption": "Figure 1. ALK inhibitor CEP-28122.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 891, 262, 905], "ImageBB": [82, 778, 420, 881]}, "corefs": [[2, 3], [2, 0], [2, 1]]}, {"id": 741, "width": 1356, "height": 940, "file_name": "op200278q-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [267.0, 355.0, 161.0, 73.0], "category_id": 1, "id": 0}, {"bbox": [261.0, 740.0, 204.0, 61.0], "category_id": 1, "id": 1}, {"bbox": [67.0, 738.0, 171.0, 65.0], "category_id": 1, "id": 2}, {"bbox": [264.0, 652.0, 126.0, 85.0], "category_id": 1, "id": 3}, {"bbox": [61.0, 649.0, 141.0, 88.0], "category_id": 1, "id": 4}, {"bbox": [260.0, 531.0, 165.0, 124.0], "category_id": 1, "id": 5}, {"bbox": [55.0, 527.0, 162.0, 122.0], "category_id": 1, "id": 6}, {"bbox": [269.0, 437.0, 193.0, 69.0], "category_id": 1, "id": 7}, {"bbox": [264.0, 844.0, 150.0, 78.0], "category_id": 1, "id": 8}, {"bbox": [64.0, 843.0, 140.0, 86.0], "category_id": 1, "id": 9}, {"bbox": [260.0, 149.0, 207.0, 83.0], "category_id": 1, "id": 10}, {"bbox": [64.0, 249.0, 182.0, 80.0], "category_id": 1, "id": 11}, {"bbox": [265.0, 252.0, 190.0, 74.0], "category_id": 1, "id": 12}, {"bbox": [76.0, 356.0, 129.0, 77.0], "category_id": 1, "id": 13}, {"bbox": [72.0, 442.0, 170.0, 63.0], "category_id": 1, "id": 14}, {"bbox": [57.0, 152.0, 194.0, 78.0], "category_id": 1, "id": 15}], "caption": "Table 3. Suzuki Miyaura coupling reactions run in Mini- Block mediated by SiliaCat S-Pd ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 519, 392, 549], "ImageBB": [71, 559, 410, 794]}, "corefs": []}, {"id": 742, "width": 1412, "height": 424, "file_name": "op200251c-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [317.0, 329.0, 30.0, 37.0], "category_id": 3, "id": 0}, {"bbox": [865.0, 327.0, 24.0, 42.0], "category_id": 3, "id": 1}, {"bbox": [1196.0, 164.0, 28.0, 42.0], "category_id": 3, "id": 2}, {"bbox": [1093.0, 4.0, 319.0, 163.0], "category_id": 1, "id": 3}, {"bbox": [703.0, 110.0, 383.0, 183.0], "category_id": 1, "id": 4}, {"bbox": [143.0, 119.0, 360.0, 159.0], "category_id": 1, "id": 5}], "caption": "Table 1. Screening of solvents in the reductive cyclizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 245, 398, 266], "ImageBB": [71, 117, 424, 223]}, "corefs": [[5, 0], [4, 1], [3, 2]]}, {"id": 743, "width": 1352, "height": 404, "file_name": "op200234j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [261.0, 33.0, 438.0, 298.0], "category_id": 1, "id": 0}, {"bbox": [713.0, 50.0, 377.0, 341.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Ru-MACHO.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 826, 198, 840], "ImageBB": [82, 716, 420, 817]}, "corefs": []}, {"id": 744, "width": 832, "height": 720, "file_name": "op200217q-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [478.7, 405.0, 353.3, 315.0], "category_id": 1, "id": 0}, {"bbox": [19.6, 404.5, 357.1, 312.6], "category_id": 1, "id": 1}, {"bbox": [224.4, 4.9, 350.9, 382.4], "category_id": 1, "id": 2}], "caption": "Figure 1. Retarder performance testing was carried out on the above three 7-substituted quinone methides. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 961, 784, 989], "ImageBB": [513, 772, 721, 952]}, "corefs": []}, {"id": 745, "width": 1344, "height": 308, "file_name": "op200176f-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [720.0, 263.0, 57.0, 45.0], "category_id": 3, "id": 0}, {"bbox": [380.0, 105.0, 591.0, 203.0], "category_id": 1, "id": 1}], "caption": "Figure 3. Carboxylic acid formed during dehydration.", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 695, 329, 709], "ImageBB": [71, 604, 407, 681]}, "corefs": [[1, 0]]}, {"id": 746, "width": 532, "height": 316, "file_name": "op200176f-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 7.0, 520.0, 304.0], "category_id": 1, "id": 0}, {"bbox": [124.0, 257.0, 52.0, 39.0], "category_id": 3, "id": 1}], "caption": "Figure 2. N-Oxide impurity.", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 589, 209, 603], "ImageBB": [173, 502, 306, 581]}, "corefs": [[0, 1]]}, {"id": 747, "width": 2804, "height": 1340, "file_name": "op200112g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1939.0, 1265.0, 65.0, 57.0], "category_id": 3, "id": 0}, {"bbox": [1374.0, 863.0, 48.0, 51.0], "category_id": 3, "id": 1}, {"bbox": [1956.0, 865.0, 55.0, 58.0], "category_id": 3, "id": 2}, {"bbox": [749.0, 887.0, 48.0, 50.0], "category_id": 3, "id": 3}, {"bbox": [780.0, 1270.0, 48.0, 55.0], "category_id": 3, "id": 4}, {"bbox": [1276.0, 1265.0, 52.0, 67.0], "category_id": 3, "id": 5}, {"bbox": [780.0, 461.0, 59.0, 79.0], "category_id": 3, "id": 6}, {"bbox": [1355.0, 466.0, 60.0, 57.0], "category_id": 3, "id": 7}, {"bbox": [2009.0, 466.0, 35.0, 63.0], "category_id": 3, "id": 8}, {"bbox": [1123.6, 621.0, 549.6, 313.3], "category_id": 1, "id": 9}, {"bbox": [545.0, 136.6, 499.5, 420.4], "category_id": 1, "id": 10}, {"bbox": [1741.4, 1009.1, 525.1, 330.9], "category_id": 1, "id": 11}, {"bbox": [1091.1, 1073.3, 673.7, 256.1], "category_id": 1, "id": 12}, {"bbox": [545.7, 1015.3, 485.5, 324.7], "category_id": 1, "id": 13}, {"bbox": [614.8, 659.3, 345.7, 258.2], "category_id": 1, "id": 14}, {"bbox": [1665.2, 213.6, 608.0, 348.4], "category_id": 1, "id": 15}, {"bbox": [1682.2, 614.9, 582.9, 330.0], "category_id": 1, "id": 16}, {"bbox": [1071.3, 207.1, 562.1, 352.6], "category_id": 1, "id": 17}], "caption": "Figure 1. Selected structures. The glyceollins, such as GLY I 1, GLY II 2, and GLY III 3, are phytoalexins produced by the soybean in response to speci\ufb01c stress conditions. Structure 4 depicts the typical pterocarpan ring system and speci\ufb01cally denotes the \u201c6a\u201d position. Structures 5 and 6 are respectively (+) pisatin and (+) variabilin; these compounds are 6a-hydroxypterocarpan natural products which have been previously synthesized by other investigators. All of the GLYs are derived from the phytochemical intermediate glycinol 7. Structure 8 is an appropriately substituted iso\ufb02av-3-ene system that serves as a key intermediate for both of our former total syntheses and for the present scale-up synthesis of GLY I. Structure 12 is lespedezol A1 which we previously prepared and used as a model system to explore alternative synthetic entries toward GLY I (see text for details). ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 402, 770, 485], "ImageBB": [71, 56, 772, 391]}, "corefs": [[10, 6], [17, 7], [15, 8], [14, 3], [9, 1], [16, 2], [13, 4], [12, 5], [11, 0]]}, {"id": 748, "width": 2000, "height": 1540, "file_name": "op1002177-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1539.5, 429.5, 460.5, 472.6], "category_id": 1, "id": 0}, {"bbox": [705.6, 441.0, 649.4, 365.4], "category_id": 1, "id": 1}, {"bbox": [665.5, 2.1, 398.0, 357.9], "category_id": 1, "id": 2}, {"bbox": [2.1, 315.7, 388.2, 219.7], "category_id": 1, "id": 3}, {"bbox": [724.4, 1065.7, 450.2, 337.2], "category_id": 1, "id": 4}, {"bbox": [1380.9, 164.5, 196.3, 207.2], "category_id": 1, "id": 5}, {"bbox": [399.35, 673.08, 231.2, 76.38], "category_id": 1, "id": 6}, {"bbox": [916.0, 821.0, 68.0, 61.0], "category_id": 3, "id": 7}, {"bbox": [858.0, 312.0, 33.0, 64.0], "category_id": 3, "id": 8}, {"bbox": [900.0, 1427.0, 55.0, 61.0], "category_id": 3, "id": 9}, {"bbox": [1723.0, 837.0, 39.0, 61.0], "category_id": 3, "id": 10}], "caption": "Figure 3. Plausible reaction mechanism for both syntheses catalysed by TiO2-ZrO2.", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 1006, 522, 1023], "ImageBB": [160, 620, 660, 1005]}, "corefs": [[2, 8], [0, 10], [1, 7], [4, 9]]}, {"id": 749, "width": 1016, "height": 996, "file_name": "op1002177-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [358.0, 4.0, 213.0, 150.0], "category_id": 1, "id": 0}, {"bbox": [56.0, 375.9, 716.0, 480.1], "category_id": 1, "id": 1}, {"bbox": [742.8, 91.0, 200.2, 208.0], "category_id": 1, "id": 2}, {"bbox": [769.6, 355.0, 198.4, 205.0], "category_id": 1, "id": 3}, {"bbox": [115.0, 107.1, 181.0, 186.9], "category_id": 1, "id": 4}], "caption": "Figure 2. Exact catalyst surface sites for the activation of epoxide and generation of nucleophile. ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 300, 393, 327], "ImageBB": [100, 47, 354, 296]}, "corefs": []}, {"id": 750, "width": 752, "height": 780, "file_name": "op100210s-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 1.0, 446.0, 520.5], "category_id": 1, "id": 0}, {"bbox": [68.59, 557.29, 43.91, 60.65], "category_id": 3, "id": 1}], "caption": "Figure 1. GSK2137305 (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 1000, 576, 1014], "ImageBB": [575, 843, 763, 1038]}, "corefs": [[0, 1]]}, {"id": 751, "width": 1352, "height": 676, "file_name": "op100113j-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1.0, 214.4, 589.0, 285.6], "category_id": 1, "id": 0}, {"bbox": [97.0, 613.0, 230.0, 48.0], "category_id": 3, "id": 1}, {"bbox": [785.0, 623.0, 243.0, 49.0], "category_id": 3, "id": 2}, {"bbox": [668.5, 1.0, 683.5, 612.0], "category_id": 1, "id": 3}], "caption": "Figure 6. Proposed API degradation products.", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 219, 316, 233], "ImageBB": [58, 47, 396, 216]}, "corefs": [[0, 1], [3, 2]]}, {"id": 752, "width": 488, "height": 320, "file_name": "op100113j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 0.0, 485.0, 184.0], "category_id": 1, "id": 0}, {"bbox": [170.0, 189.0, 226.0, 126.8], "category_id": 3, "id": 1}], "caption": "Figure 1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 1009, 109, 1023], "ImageBB": [166, 925, 288, 1005]}, "corefs": [[0, 1]]}, {"id": 753, "width": 544, "height": 428, "file_name": "op100103v-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [222.3, 381.9, 60.8, 43.8], "category_id": 3, "id": 0}, {"bbox": [2.0, 1.0, 533.0, 392.0], "category_id": 1, "id": 1}], "caption": "Figure 3. tert-Butyl 6-[2-methoxyethenyl]-4H-imidazo[5, 1-c][1,4]benzoxazine-3-carboxylate 29, major side product of stage two. ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 156, 393, 197], "ImageBB": [159, 46, 295, 153]}, "corefs": [[1, 0]]}, {"id": 754, "width": 1352, "height": 1488, "file_name": "ol070970s-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [759.0, 122.0, 463.0, 304.0], "category_id": 1, "id": 0}, {"bbox": [110.0, 505.0, 393.0, 897.0], "category_id": 1, "id": 1}, {"bbox": [100.0, 216.0, 477.0, 151.0], "category_id": 1, "id": 2}, {"bbox": [764.0, 547.0, 447.0, 844.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Electrostatic potential surfaces of two model compounds, paraquat (left) and N,N\u2032-dimethylpyromellitic diimide (right). Blue represents positive electrostatic potential and red stands for negative electrostatic potential. The surfaces were optimized with the MMFF94x force field. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 435, 409, 504], "ImageBB": [73, 51, 411, 423]}, "corefs": []}, {"id": 755, "width": 1352, "height": 1220, "file_name": "ol070970s-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [36.0, 760.0, 593.7, 458.4], "category_id": 1, "id": 0}, {"bbox": [11.9, 150.2, 624.3, 501.8], "category_id": 1, "id": 1}, {"bbox": [692.0, 180.7, 652.0, 422.9], "category_id": 1, "id": 2}, {"bbox": [725.9, 761.6, 568.2, 427.0], "category_id": 1, "id": 3}, {"bbox": [33.26, 158.69, 60.51, 60.51], "category_id": 3, "id": 4}, {"bbox": [38.16, 750.7, 53.97, 52.33], "category_id": 3, "id": 5}], "caption": "Figure 1. Stick representation of X-ray structures and structural formula of (a) [2]catenane 62+ and (b) [2]catenane 52+. Hydrogen atoms and counterions are omitted for clarity. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 623, 409, 664], "ImageBB": [73, 305, 411, 610]}, "corefs": [[1, 4], [0, 5]]}, {"id": 756, "width": 1352, "height": 632, "file_name": "ol0703579-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [710.0, 196.0, 380.0, 323.0], "category_id": 1, "id": 0}, {"bbox": [398.0, 573.0, 160.0, 54.0], "category_id": 3, "id": 1}, {"bbox": [261.0, 139.0, 363.0, 434.0], "category_id": 1, "id": 2}, {"bbox": [806.0, 573.0, 162.0, 59.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Two hindered chiral phosphoric acid catalysts.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 610, 371, 623], "ImageBB": [73, 440, 411, 598]}, "corefs": [[2, 1], [0, 3]]}, {"id": 757, "width": 1352, "height": 956, "file_name": "ol061715v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [361.0, 143.0, 631.0, 813.0], "category_id": 1, "id": 0}], "caption": "Figure 1. X-ray crystal structure of 11b.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 1001, 655, 1014], "ImageBB": [439, 750, 777, 989]}, "corefs": []}, {"id": 758, "width": 1356, "height": 740, "file_name": "ol0616236-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [184.0, 14.0, 284.9, 157.0], "category_id": 1, "id": 0}, {"bbox": [784.0, 15.0, 265.0, 117.0], "category_id": 1, "id": 1}, {"bbox": [1083.0, 12.0, 267.0, 111.0], "category_id": 1, "id": 2}], "caption": "Table 3. Comparison of Stereoselectivity of Reactions of Fluorinated (2) and Unfluorinated (1b)a BT-Sulfones ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 398, 377, 426], "ImageBB": [73, 427, 412, 612]}, "corefs": []}, {"id": 759, "width": 1352, "height": 776, "file_name": "ol061289d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [284.0, 142.0, 361.0, 287.0], "category_id": 1, "id": 0}, {"bbox": [405.6, 450.0, 109.4, 74.0], "category_id": 3, "id": 1}, {"bbox": [689.0, 138.0, 378.0, 283.0], "category_id": 1, "id": 2}, {"bbox": [872.0, 467.0, 28.0, 35.0], "category_id": 3, "id": 3}], "caption": "Figure 1. N-Alkylaminooxy amino acids used for model peptides.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 258, 409, 271], "ImageBB": [73, 52, 411, 246]}, "corefs": [[0, 1], [2, 3]]}, {"id": 760, "width": 1352, "height": 676, "file_name": "ol0600584-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [434.0, 142.0, 484.0, 534.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Presumed transition state for borane reduction.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 360, 738, 373], "ImageBB": [439, 179, 777, 348]}, "corefs": []}, {"id": 761, "width": 1352, "height": 668, "file_name": "ol0521782-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [20.39, 229.0, 572.0, 346.67], "category_id": 1, "id": 0}, {"bbox": [354.82, 195.36, 284.47, 161.09], "category_id": 3, "id": 1}], "caption": "Figure 4. Structure and absorption spectra of sensors 1 (black line), 2 (blue line), 3 (orange line), and 4 (pink line) in CH2Cl2 (50 \u00b5M). Inset shows solutions. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 231, 409, 272], "ImageBB": [73, 52, 411, 219]}, "corefs": [[0, 1]]}, {"id": 762, "width": 1352, "height": 480, "file_name": "ol0521782-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 137.7, 436.0, 266.2], "category_id": 1, "id": 0}, {"bbox": [110.0, 412.0, 63.0, 51.0], "category_id": 3, "id": 1}, {"bbox": [560.0, 412.0, 42.0, 48.0], "category_id": 3, "id": 2}, {"bbox": [992.0, 410.0, 62.0, 46.0], "category_id": 3, "id": 3}, {"bbox": [889.0, 138.4, 456.9, 261.4], "category_id": 1, "id": 4}, {"bbox": [446.0, 138.5, 434.0, 264.4], "category_id": 1, "id": 5}], "caption": "Figure 1. Structures of sensors 2-4 designed for tuning of anion affinity, selectivity, and also a degree of color response. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 184, 409, 211], "ImageBB": [73, 52, 411, 172]}, "corefs": [[0, 1], [5, 2], [4, 3]]}, {"id": 763, "width": 704, "height": 864, "file_name": "jo0497306-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [61.0, 420.0, 53.0, 42.0], "category_id": 3, "id": 0}, {"bbox": [237.2, 235.0, 228.8, 185.0], "category_id": 1, "id": 1}, {"bbox": [0.0, 628.0, 177.0, 202.8], "category_id": 1, "id": 2}, {"bbox": [73.0, 828.0, 52.0, 36.0], "category_id": 3, "id": 3}, {"bbox": [175.8, 645.4, 292.2, 186.6], "category_id": 1, "id": 4}, {"bbox": [390.0, 420.2, 60.0, 41.8], "category_id": 3, "id": 5}, {"bbox": [0.0, 220.0, 168.4, 194.0], "category_id": 1, "id": 6}, {"bbox": [400.0, 828.0, 57.0, 34.0], "category_id": 3, "id": 7}], "caption": "Table 1 allows a comparison", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [603, 260, 775, 274], "ImageBB": [600, 34, 776, 250]}, "corefs": [[6, 0], [1, 5], [2, 3], [4, 7]]}, {"id": 764, "width": 1236, "height": 708, "file_name": "jo025690z-Table-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [892.0, 424.0, 344.0, 236.0], "category_id": 1, "id": 0}, {"bbox": [438.0, 420.0, 383.0, 171.0], "category_id": 1, "id": 1}, {"bbox": [0.0, 388.0, 367.0, 213.0], "category_id": 1, "id": 2}, {"bbox": [601.0, 653.0, 44.0, 43.0], "category_id": 3, "id": 3}, {"bbox": [1030.0, 661.0, 58.0, 43.0], "category_id": 3, "id": 4}, {"bbox": [204.0, 195.0, 31.0, 39.0], "category_id": 3, "id": 5}, {"bbox": [527.0, 72.0, 146.0, 58.0], "category_id": 1, "id": 6}, {"bbox": [25.0, 7.0, 378.0, 143.0], "category_id": 1, "id": 7}, {"bbox": [143.0, 659.05, 39.0, 43.0], "category_id": 3, "id": 8}, {"bbox": [587.0, 195.0, 36.9, 39.0], "category_id": 3, "id": 9}], "caption": " Table 4.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [697, 431, 747, 445], "ImageBB": [440, 462, 749, 639]}, "corefs": [[7, 5], [6, 9], [2, 8], [1, 3], [0, 4]]}, {"id": 765, "width": 1280, "height": 1164, "file_name": "jo016363e-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [423.67, 1.66, 435.87, 234.83], "category_id": 1, "id": 0}, {"bbox": [616.27, 266.9, 57.44, 59.13], "category_id": 3, "id": 1}], "caption": "Figure 5. Experimental 1H NMR (300 MHz in hexachloro- acetone) signals of the N-methyl group of the amide moiety of 4 as a function of temperature (left). On the right is shown the computer simulation with the reported rate constants. ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 835, 409, 888], "ImageBB": [82, 532, 402, 823]}, "corefs": [[0, 1]]}, {"id": 766, "width": 1412, "height": 1816, "file_name": "jo016363e-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [372.0, 411.2, 457.0, 253.8], "category_id": 1, "id": 0}], "caption": "Figure 2. Experimental 13C NMR (100.6 MHz in CD2Cl2) signals (left) of the tert-butyl methyl group of 1 as a function of temperature. On the right is shown the computer simulation with the reported rate constants. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 542, 409, 595], "ImageBB": [74, 78, 427, 532]}, "corefs": []}, {"id": 767, "width": 1408, "height": 948, "file_name": "jo0157425-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [171.0, 467.0, 268.0, 45.0], "category_id": 3, "id": 0}, {"bbox": [154.0, 177.0, 341.0, 227.0], "category_id": 1, "id": 1}], "caption": "Table 3. Effect of Additives to the Difluorination          Reaction of 17 with Deoxofluor ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [462, 395, 752, 420], "ImageBB": [424, 35, 776, 272]}, "corefs": [[1, 0]]}, {"id": 768, "width": 1244, "height": 760, "file_name": "jo010904i-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [190.0, 658.0, 215.8, 97.2], "category_id": 3, "id": 0}, {"bbox": [861.79, 665.0, 39.0, 40.0], "category_id": 3, "id": 1}, {"bbox": [0.0, 3.0, 646.0, 639.0], "category_id": 1, "id": 2}, {"bbox": [695.0, 2.0, 549.0, 656.0], "category_id": 1, "id": 3}], "caption": "Figure 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 258, 131, 271], "ImageBB": [87, 65, 398, 255]}, "corefs": [[2, 0], [3, 1]]}, {"id": 769, "width": 2812, "height": 1884, "file_name": "jo001700p-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [557.0, 111.0, 1722.0, 609.0], "category_id": 1, "id": 0}], "caption": "Figure 2. 400 MHz 1H NMR spectrum of 1.18C6 in CDCl3 at 300 K.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 518, 459, 532], "ImageBB": [74, 35, 777, 506]}, "corefs": []}, {"id": 770, "width": 1412, "height": 752, "file_name": "jo001700p-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [73.7, 184.8, 1335.3, 414.2], "category_id": 1, "id": 0}], "caption": "Figure 1. The general structure of our crown-ether-based multiporphyrin systems. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 235, 775, 261], "ImageBB": [424, 35, 777, 223]}, "corefs": []}, {"id": 771, "width": 1376, "height": 2472, "file_name": "jo0014156-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1075.45, 2353.42, 53.81, 57.38], "category_id": 3, "id": 0}, {"bbox": [434.67, 2336.2, 35.87, 50.23], "category_id": 3, "id": 1}, {"bbox": [100.0, 2021.0, 399.0, 384.0], "category_id": 1, "id": 2}, {"bbox": [142.0, 2408.0, 345.0, 64.0], "category_id": 3, "id": 3}, {"bbox": [817.0, 2042.0, 364.0, 369.0], "category_id": 1, "id": 4}, {"bbox": [142.0, 1486.0, 357.0, 366.0], "category_id": 1, "id": 5}, {"bbox": [803.0, 1440.0, 387.0, 370.0], "category_id": 1, "id": 6}, {"bbox": [607.0, 1819.0, 769.0, 171.0], "category_id": 3, "id": 7}, {"bbox": [142.0, 1879.0, 303.0, 54.0], "category_id": 3, "id": 8}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 665, 497, 678], "ImageBB": [424, 35, 768, 653]}, "corefs": [[5, 8], [6, 7], [2, 1], [2, 3], [4, 0]]}, {"id": 772, "width": 1352, "height": 904, "file_name": "acs.orglett.6b01181-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [91.7, 45.8, 368.3, 351.2], "category_id": 1, "id": 0}, {"bbox": [504.4, 55.0, 374.6, 285.1], "category_id": 1, "id": 1}, {"bbox": [934.0, 47.0, 327.0, 347.0], "category_id": 1, "id": 2}, {"bbox": [89.1, 475.0, 480.9, 370.0], "category_id": 1, "id": 3}, {"bbox": [593.0, 502.0, 657.0, 307.0], "category_id": 1, "id": 4}], "caption": "Figure 1. Examples of biologically active indolizine derivatives.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 871, 386, 885], "ImageBB": [82, 636, 420, 862]}, "corefs": []}, {"id": 773, "width": 1352, "height": 624, "file_name": "acs.orglett.5b02680-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [456.0, 5.0, 440.0, 221.0], "category_id": 1, "id": 0}, {"bbox": [638.0, 206.0, 88.0, 39.0], "category_id": 3, "id": 1}], "caption": "Table 1. Substituents and Yields for Alkyne/Nitrile Oxide 1,3- Dipolar Cycloadditions Yielding Isoxazoles 3a\u2212d ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 287]}, "corefs": [[0, 1]]}, {"id": 774, "width": 1352, "height": 456, "file_name": "acs.orglett.5b01754-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [454.1, 341.0, 41.8, 30.0], "category_id": 3, "id": 0}, {"bbox": [1088.0, 53.1, 258.9, 297.0], "category_id": 1, "id": 1}, {"bbox": [751.0, 48.1, 318.0, 291.0], "category_id": 1, "id": 2}, {"bbox": [364.3, 65.1, 326.7, 272.9], "category_id": 1, "id": 3}, {"bbox": [28.3, 53.2, 318.7, 274.6], "category_id": 1, "id": 4}, {"bbox": [105.96, 337.9, 37.0, 33.1], "category_id": 3, "id": 5}, {"bbox": [853.0, 338.0, 30.0, 32.0], "category_id": 3, "id": 6}, {"bbox": [1163.0, 338.0, 38.0, 33.0], "category_id": 3, "id": 7}], "caption": "Figure 1. Examples of BINOL and H8-BINOL-based chiral Br\u00f8nsted acids. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 803, 417, 831], "ImageBB": [82, 679, 420, 793]}, "corefs": [[4, 5], [3, 0], [2, 6], [1, 7]]}, {"id": 775, "width": 1352, "height": 516, "file_name": "acs.orglett.5b00805-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [735.2, 152.0, 584.8, 194.9], "category_id": 1, "id": 0}, {"bbox": [26.0, 46.0, 635.0, 387.1], "category_id": 1, "id": 1}], "caption": "Figure 1. Natural compounds having an \u03b1-amino peroxide structure.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 853, 416, 871], "ImageBB": [82, 718, 420, 847]}, "corefs": []}, {"id": 776, "width": 1352, "height": 688, "file_name": "acs.oprd.6b00037-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [194.1, 42.9, 945.9, 254.2], "category_id": 1, "id": 0}, {"bbox": [201.9, 348.0, 453.1, 248.0], "category_id": 1, "id": 1}, {"bbox": [907.1, 351.0, 247.9, 255.0], "category_id": 1, "id": 2}, {"bbox": [910.5, 637.0, 241.5, 46.0], "category_id": 3, "id": 3}, {"bbox": [217.1, 631.8, 390.9, 44.2], "category_id": 3, "id": 4}, {"bbox": [580.6, 288.7, 315.4, 45.3], "category_id": 3, "id": 5}], "caption": "Figure 1. Chemical structure of vitamins K.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 815, 296, 829], "ImageBB": [82, 634, 420, 806]}, "corefs": [[0, 5], [1, 4], [2, 3]]}, {"id": 777, "width": 1348, "height": 904, "file_name": "acs.oprd.6b00011-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [381.0, 366.0, 26.0, 33.0], "category_id": 3, "id": 0}, {"bbox": [1057.0, 364.0, 31.0, 36.0], "category_id": 3, "id": 1}, {"bbox": [137.0, 28.0, 375.0, 314.0], "category_id": 1, "id": 2}, {"bbox": [861.0, 0.0, 355.0, 338.0], "category_id": 1, "id": 3}], "caption": "Table 3. PTC Alkylation of 5: Reagent Stoichiometry Study", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 742, 417, 757], "ImageBB": [82, 763, 419, 989]}, "corefs": [[2, 0], [3, 1]]}, {"id": 778, "width": 1352, "height": 416, "file_name": "acs.oprd.5b00371-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [499.0, 40.0, 354.0, 375.0], "category_id": 1, "id": 0}, {"bbox": [718.0, 351.0, 25.0, 37.0], "category_id": 3, "id": 1}], "caption": "Figure 1. Picoxystrobin (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 546, 220, 560], "ImageBB": [82, 432, 420, 536]}, "corefs": [[0, 1]]}, {"id": 779, "width": 2820, "height": 1240, "file_name": "acs.oprd.5b00312-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1185.0, 222.1, 370.4, 159.1], "category_id": 1, "id": 0}, {"bbox": [468.2, 0.0, 437.5, 393.0], "category_id": 1, "id": 1}, {"bbox": [1348.0, 446.0, 71.0, 60.0], "category_id": 3, "id": 2}, {"bbox": [678.0, 446.0, 51.6, 53.0], "category_id": 3, "id": 3}, {"bbox": [2107.8, 1032.0, 67.0, 55.2], "category_id": 3, "id": 4}, {"bbox": [1819.4, 617.9, 534.6, 384.1], "category_id": 1, "id": 5}, {"bbox": [1329.0, 665.9, 355.0, 301.1], "category_id": 1, "id": 6}, {"bbox": [2065.0, 452.0, 60.0, 49.0], "category_id": 3, "id": 7}, {"bbox": [1501.0, 1021.0, 68.0, 65.0], "category_id": 3, "id": 8}, {"bbox": [1048.0, 1032.0, 39.0, 60.0], "category_id": 3, "id": 9}, {"bbox": [572.0, 1040.0, 68.0, 52.0], "category_id": 3, "id": 10}, {"bbox": [1830.0, 138.0, 524.0, 303.4], "category_id": 1, "id": 11}, {"bbox": [552.8, 678.0, 171.4, 286.0], "category_id": 1, "id": 12}, {"bbox": [858.0, 664.0, 376.0, 322.0], "category_id": 1, "id": 13}], "caption": "Table 1. Summary of the Completion of Reduction by Titanium(III) Chloride in 50% Aqueous Acetonitrile", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 432, 689, 447], "ImageBB": [82, 116, 787, 426]}, "corefs": [[1, 3], [0, 2], [11, 7], [12, 10], [13, 9], [6, 8], [5, 4]]}, {"id": 780, "width": 1352, "height": 476, "file_name": "acs.oprd.5b00303-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [221.0, 42.0, 257.0, 250.0], "category_id": 1, "id": 0}, {"bbox": [809.0, 43.0, 250.0, 249.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Chemical structures of the repeat units of poly(N- vinylisobutyramide) (PNVIBA) and poly(N-isopropylacrylamide) (PNIPAM). ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 812, 417, 854], "ImageBB": [82, 684, 420, 803]}, "corefs": []}, {"id": 781, "width": 1356, "height": 380, "file_name": "acs.oprd.5b00273-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [442.6, 40.0, 470.4, 335.9], "category_id": 1, "id": 0}], "caption": "Figure 2. Structure of metallacyclic complex isolated and characterized by Leconte et al.36 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 466, 784, 494], "ImageBB": [448, 362, 787, 457]}, "corefs": []}, {"id": 782, "width": 1352, "height": 1104, "file_name": "acs.oprd.5b00251-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [9.0, 13.0, 1343.0, 1091.0], "category_id": 1, "id": 0}], "caption": "Figure 1. A schematic representation of a fully substituted sucrose ester of fatty acid from soybean oil. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1014, 417, 1042], "ImageBB": [82, 728, 420, 1004]}, "corefs": []}, {"id": 783, "width": 1352, "height": 400, "file_name": "acs.oprd.5b00192-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [391.0, 359.0, 46.0, 36.0], "category_id": 3, "id": 0}, {"bbox": [232.0, 45.0, 371.0, 276.0], "category_id": 1, "id": 1}, {"bbox": [733.0, 52.0, 373.0, 348.0], "category_id": 1, "id": 2}, {"bbox": [879.0, 356.0, 51.0, 41.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Oxazolidine intermediates (55:45 ratio of isomers at the ketal carbon). ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 760, 417, 788], "ImageBB": [82, 650, 420, 750]}, "corefs": [[1, 0], [2, 3]]}, {"id": 784, "width": 2424, "height": 1676, "file_name": "acs.oprd.5b00170-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [364.0, 415.0, 71.0, 44.0], "category_id": 3, "id": 0}, {"bbox": [232.0, 1246.0, 415.0, 295.0], "category_id": 1, "id": 1}, {"bbox": [223.0, 833.0, 432.0, 259.0], "category_id": 1, "id": 2}, {"bbox": [256.0, 275.0, 328.0, 137.0], "category_id": 1, "id": 3}, {"bbox": [391.0, 715.0, 94.0, 58.5], "category_id": 3, "id": 4}, {"bbox": [399.0, 1554.0, 83.0, 72.0], "category_id": 3, "id": 5}, {"bbox": [408.0, 1098.0, 63.0, 68.0], "category_id": 3, "id": 6}, {"bbox": [229.0, 469.87, 423.0, 234.0], "category_id": 1, "id": 7}], "caption": "Table 1. Data on Hydrogenation of 4-Iodoaniline 4a and Isolation of Halogenated Anilines 4b\u22124d by Extraction and Crystallization ", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 742, 125], "ImageBB": [131, 131, 737, 550]}, "corefs": [[3, 0], [7, 4], [2, 6], [1, 5]]}, {"id": 785, "width": 1352, "height": 340, "file_name": "ol5028392-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [885.0, 288.0, 46.0, 46.0], "category_id": 3, "id": 0}, {"bbox": [207.2, 286.0, 236.8, 48.0], "category_id": 3, "id": 1}, {"bbox": [677.0, 42.3, 587.2, 245.7], "category_id": 1, "id": 2}, {"bbox": [85.0, 42.8, 574.0, 292.2], "category_id": 1, "id": 3}], "caption": "Figure 1. Structure of arterolane (1) and arterolane-inspired trioxolane\u2212drug conjugate 2. Free drug is released from 2 in the presence of ferrous iron. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 758, 417, 800], "ImageBB": [82, 664, 420, 749]}, "corefs": [[3, 1], [2, 0]]}, {"id": 786, "width": 1356, "height": 364, "file_name": "ol5020043-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [729.07, 46.91, 302.2, 313.46], "category_id": 1, "id": 0}, {"bbox": [325.6, 42.5, 393.8, 321.5], "category_id": 1, "id": 1}], "caption": "Figure 2. Crystal structure of 33.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 307, 612, 321], "ImageBB": [448, 206, 787, 297]}, "corefs": []}, {"id": 787, "width": 1352, "height": 632, "file_name": "ol5020043-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [419.0, 438.0, 196.0, 88.4], "category_id": 3, "id": 0}, {"bbox": [809.0, 440.0, 51.4, 47.7], "category_id": 3, "id": 1}, {"bbox": [43.4, 47.0, 278.7, 383.4], "category_id": 1, "id": 2}, {"bbox": [325.45, 45.81, 331.85, 382.99], "category_id": 1, "id": 3}, {"bbox": [649.4, 54.86, 335.1, 382.24], "category_id": 1, "id": 4}, {"bbox": [977.45, 67.76, 314.15, 378.14], "category_id": 1, "id": 5}, {"bbox": [170.59, 434.91, 58.11, 50.89], "category_id": 3, "id": 6}, {"bbox": [930.0, 432.0, 394.0, 150.0], "category_id": 3, "id": 7}], "caption": "Figure 1. Representative members of the welwitindolinone alkaloids.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 792, 416, 806], "ImageBB": [82, 625, 420, 783]}, "corefs": [[2, 6], [3, 0], [4, 1], [5, 7]]}, {"id": 788, "width": 1084, "height": 1068, "file_name": "ol501165h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [252.9, 320.5, 360.1, 95.5], "category_id": 3, "id": 0}, {"bbox": [0.0, 106.64, 236.4, 218.66], "category_id": 1, "id": 1}, {"bbox": [225.4, 43.5, 379.8, 293.2], "category_id": 1, "id": 2}], "caption": "Figure 1. Starting sul\ufb01des 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 985, 589, 999], "ImageBB": [588, 860, 859, 1127]}, "corefs": [[2, 0]]}, {"id": 789, "width": 1352, "height": 484, "file_name": "ol501085y-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [827.9, 86.3, 336.6, 287.4], "category_id": 1, "id": 0}, {"bbox": [886.63, 393.06, 147.63, 56.98], "category_id": 3, "id": 1}, {"bbox": [180.0, 47.0, 519.0, 434.0], "category_id": 1, "id": 2}], "caption": "Figure 2. X-ray structure of (R)-2m.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 835, 261, 849], "ImageBB": [82, 705, 420, 826]}, "corefs": [[0, 1]]}, {"id": 790, "width": 1352, "height": 888, "file_name": "ol5007604-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [987.0, 415.0, 49.0, 32.0], "category_id": 3, "id": 0}, {"bbox": [993.0, 693.0, 37.0, 39.0], "category_id": 3, "id": 1}, {"bbox": [987.0, 557.0, 41.0, 41.0], "category_id": 3, "id": 2}, {"bbox": [1047.0, 626.0, 266.8, 169.3], "category_id": 1, "id": 3}, {"bbox": [1047.6, 481.0, 266.2, 168.0], "category_id": 1, "id": 4}, {"bbox": [1047.9, 50.7, 265.7, 148.9], "category_id": 1, "id": 5}, {"bbox": [985.0, 129.0, 43.0, 37.0], "category_id": 3, "id": 6}, {"bbox": [1048.0, 196.28, 264.6, 174.42], "category_id": 1, "id": 7}, {"bbox": [1047.7, 339.4, 264.7, 150.3], "category_id": 1, "id": 8}, {"bbox": [985.0, 271.0, 46.0, 36.0], "category_id": 3, "id": 9}], "caption": "Figure 4. UV\u2212vis absorption (solid line) and \ufb02uorescence spectra (dashed lines) of [2 + 1 + 2 + 1] cycloaddition products (normalized spectra, measured in chloroform). ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1015, 417, 1060], "ImageBB": [82, 777, 420, 999]}, "corefs": [[5, 6], [7, 9], [8, 0], [4, 2], [3, 1]]}, {"id": 791, "width": 1352, "height": 1068, "file_name": "ol500618w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [690.8, 570.9, 509.6, 388.7], "category_id": 1, "id": 0}, {"bbox": [166.5, 638.1, 451.9, 249.6], "category_id": 1, "id": 1}, {"bbox": [713.1, 43.8, 466.6, 330.1], "category_id": 1, "id": 2}, {"bbox": [140.3, 38.0, 506.4, 345.2], "category_id": 1, "id": 3}], "caption": "Figure 1. Representative examples of clinically important alkenyl- nitrile containing pharmaceuticals. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1014, 417, 1042], "ImageBB": [82, 737, 420, 1004]}, "corefs": []}, {"id": 792, "width": 1344, "height": 692, "file_name": "ol402074u-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [697.0, 279.0, 546.0, 388.0], "category_id": 1, "id": 0}, {"bbox": [109.1, 282.1, 562.9, 404.9], "category_id": 1, "id": 1}, {"bbox": [696.97, 217.57, 80.26, 61.53], "category_id": 3, "id": 2}, {"bbox": [108.42, 217.57, 65.98, 64.2], "category_id": 3, "id": 3}], "caption": "Figure 5. Fragments A and B in crystal structure of receptor 4 in anti and syn conformation. The atomic displacement param- eters are at 50% probability level. Hydrogen atoms have been omitted for clarity. ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 578, 405, 633], "ImageBB": [71, 393, 407, 566]}, "corefs": [[1, 3], [0, 2]]}, {"id": 793, "width": 1344, "height": 1012, "file_name": "ol401443a-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [91.9, 637.0, 506.1, 308.6], "category_id": 1, "id": 0}, {"bbox": [62.3, 159.0, 741.8, 457.0], "category_id": 1, "id": 1}, {"bbox": [748.69, 707.3, 244.71, 217.1], "category_id": 1, "id": 2}, {"bbox": [693.0, 179.0, 613.0, 472.0], "category_id": 1, "id": 3}], "caption": "Figure 1. Natural products and biologically active molecules containing R-nitrogen substituted peroxides. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 325, 405, 354], "ImageBB": [71, 59, 407, 312]}, "corefs": []}, {"id": 794, "width": 1344, "height": 976, "file_name": "ol4013926-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [323.0, 277.0, 700.0, 689.0], "category_id": 1, "id": 0}], "caption": "Figure 2. X-ray crystal structure of 4a.", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 949, 276, 962], "ImageBB": [71, 692, 407, 936]}, "corefs": []}, {"id": 795, "width": 1352, "height": 588, "file_name": "ol0508779-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [48.3, 160.1, 475.8, 293.4], "category_id": 1, "id": 0}, {"bbox": [735.7, 140.9, 519.0, 336.1], "category_id": 1, "id": 1}, {"bbox": [745.0, 486.0, 558.0, 93.9], "category_id": 3, "id": 2}, {"bbox": [152.0, 485.0, 316.0, 60.0], "category_id": 3, "id": 3}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 990, 491, 1003], "ImageBB": [439, 831, 777, 978]}, "corefs": [[0, 3], [1, 2]]}, {"id": 796, "width": 2816, "height": 1696, "file_name": "ol050648m-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1112.0, 123.0, 238.0, 177.0], "category_id": 1, "id": 0}, {"bbox": [1420.0, 161.5, 699.0, 225.0], "category_id": 1, "id": 1}], "caption": "Figure 3. Aliphatic regions of 1H NMR spectra of mycapolyols A (1, top) and F (6, bottom). Red dashed boxes indicate methylene signals in the polyol portion, while blue boxes indicate those of the alkyl chains. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 487, 775, 515], "ImageBB": [73, 52, 777, 476]}, "corefs": []}, {"id": 797, "width": 2816, "height": 1008, "file_name": "ol050648m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [793.0, 947.0, 39.0, 45.0], "category_id": 3, "id": 0}, {"bbox": [1360.0, 947.0, 35.0, 47.0], "category_id": 3, "id": 1}, {"bbox": [1892.0, 947.0, 39.0, 45.0], "category_id": 3, "id": 2}, {"bbox": [558.0, 134.0, 1706.0, 747.0], "category_id": 1, "id": 3}], "caption": "Figure 1. Partial structures and selected HMBC correlations of mycapolyol B (2).", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 316, 501, 329], "ImageBB": [73, 52, 777, 304]}, "corefs": [[3, 0], [3, 1], [3, 2]]}, {"id": 798, "width": 1352, "height": 804, "file_name": "ol050133v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [878.0, 206.8, 346.8, 333.9], "category_id": 1, "id": 0}, {"bbox": [477.7, 159.9, 324.4, 462.1], "category_id": 1, "id": 1}, {"bbox": [97.9, 150.3, 313.2, 558.5], "category_id": 1, "id": 2}, {"bbox": [223.0, 760.0, 41.0, 44.0], "category_id": 3, "id": 3}, {"bbox": [597.0, 751.0, 53.0, 53.0], "category_id": 3, "id": 4}, {"bbox": [1035.0, 758.0, 41.0, 46.0], "category_id": 3, "id": 5}], "caption": "Figure 1. (a) Putative transition state for RNA hydrolysis. (b) Structure of the vanadate-uridine complex bound in the active site of RNase A as determined by X-ray crystallography. (c) Janda\u2019s technetium- and rhenium-based TSAs for RNA hydrolysis. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 948, 775, 1003], "ImageBB": [439, 735, 777, 936]}, "corefs": [[2, 3], [1, 4], [0, 5]]}, {"id": 799, "width": 1352, "height": 344, "file_name": "ol049640n-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [222.0, 139.0, 320.0, 199.0], "category_id": 1, "id": 0}, {"bbox": [843.0, 142.0, 286.0, 201.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Proposed Aza-Diels-Alder Reaction of R,\u03b2-Unsaturated Oximes. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 199, 409, 229], "ImageBB": [73, 104, 411, 190]}, "corefs": []}, {"id": 800, "width": 1352, "height": 2184, "file_name": "ol048273c-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [105.0, 246.0, 212.0, 132.0], "category_id": 1, "id": 0}, {"bbox": [117.0, 1505.0, 157.0, 50.0], "category_id": 3, "id": 1}, {"bbox": [1014.0, 1110.0, 175.0, 43.0], "category_id": 3, "id": 2}, {"bbox": [804.0, 1108.0, 77.0, 42.0], "category_id": 3, "id": 3}, {"bbox": [471.0, 1108.0, 179.0, 52.0], "category_id": 3, "id": 4}, {"bbox": [167.0, 1110.0, 193.0, 39.0], "category_id": 3, "id": 5}, {"bbox": [814.0, 442.0, 171.0, 53.0], "category_id": 3, "id": 6}, {"bbox": [1106.0, 442.0, 64.0, 44.0], "category_id": 3, "id": 7}, {"bbox": [907.0, 768.0, 218.0, 51.0], "category_id": 3, "id": 8}, {"bbox": [682.0, 764.0, 56.0, 38.0], "category_id": 3, "id": 9}, {"bbox": [385.0, 761.0, 154.0, 48.0], "category_id": 3, "id": 10}, {"bbox": [108.0, 757.0, 218.0, 52.0], "category_id": 3, "id": 11}, {"bbox": [120.0, 517.0, 201.0, 186.0], "category_id": 1, "id": 12}, {"bbox": [402.0, 452.0, 58.0, 37.0], "category_id": 3, "id": 13}, {"bbox": [123.0, 876.0, 295.0, 188.0], "category_id": 1, "id": 14}, {"bbox": [466.0, 867.0, 178.0, 204.0], "category_id": 1, "id": 15}, {"bbox": [725.0, 860.0, 221.0, 195.0], "category_id": 1, "id": 16}, {"bbox": [1003.0, 869.0, 220.0, 195.0], "category_id": 1, "id": 17}, {"bbox": [322.0, 248.0, 210.0, 127.0], "category_id": 1, "id": 18}, {"bbox": [567.0, 446.0, 165.0, 53.0], "category_id": 3, "id": 19}, {"bbox": [129.0, 441.0, 160.0, 55.0], "category_id": 3, "id": 20}, {"bbox": [362.0, 524.0, 209.0, 181.0], "category_id": 1, "id": 21}, {"bbox": [1021.0, 215.0, 240.0, 183.0], "category_id": 1, "id": 22}, {"bbox": [790.0, 225.0, 227.0, 169.0], "category_id": 1, "id": 23}, {"bbox": [604.0, 521.0, 210.0, 188.0], "category_id": 1, "id": 24}, {"bbox": [93.0, 1934.0, 191.0, 152.0], "category_id": 1, "id": 25}, {"bbox": [381.0, 1275.0, 242.0, 148.0], "category_id": 1, "id": 26}, {"bbox": [106.0, 2129.0, 165.0, 55.0], "category_id": 3, "id": 27}, {"bbox": [422.0, 2133.0, 165.0, 51.0], "category_id": 3, "id": 28}, {"bbox": [138.0, 1759.0, 148.0, 49.0], "category_id": 3, "id": 29}, {"bbox": [857.0, 504.0, 318.0, 235.0], "category_id": 1, "id": 30}, {"bbox": [446.0, 1760.0, 157.0, 47.0], "category_id": 3, "id": 31}, {"bbox": [818.0, 1762.0, 146.0, 45.0], "category_id": 3, "id": 32}, {"bbox": [789.0, 1500.0, 164.0, 48.0], "category_id": 3, "id": 33}, {"bbox": [429.0, 1502.0, 158.0, 51.0], "category_id": 3, "id": 34}, {"bbox": [534.0, 218.0, 243.0, 194.0], "category_id": 1, "id": 35}, {"bbox": [399.0, 1566.14, 261.0, 115.0], "category_id": 1, "id": 36}, {"bbox": [92.93, 1564.15, 245.0, 119.0], "category_id": 1, "id": 37}, {"bbox": [699.01, 1557.8, 391.0, 132.8], "category_id": 1, "id": 38}, {"bbox": [122.7, 1283.7, 157.3, 128.3], "category_id": 1, "id": 39}, {"bbox": [748.0, 1207.0, 246.0, 282.9], "category_id": 1, "id": 40}, {"bbox": [405.7, 1929.0, 188.3, 153.0], "category_id": 1, "id": 41}], "caption": "Figure 2. Building blocks used for the biaryl medium-ring library with yields in parentheses. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 610, 408, 637], "ImageBB": [73, 52, 411, 598]}, "corefs": [[0, 20], [18, 13], [35, 19], [23, 6], [22, 7], [12, 11], [21, 10], [24, 9], [30, 8], [14, 5], [15, 4], [16, 3], [17, 2], [39, 1], [26, 34], [40, 33], [37, 29], [36, 31], [38, 32], [25, 27], [41, 28]]}, {"id": 801, "width": 1352, "height": 552, "file_name": "ol036510q-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [74.0, 144.5, 531.0, 285.5], "category_id": 1, "id": 0}, {"bbox": [1003.0, 515.0, 39.0, 32.0], "category_id": 3, "id": 1}, {"bbox": [757.0, 137.0, 525.0, 354.0], "category_id": 1, "id": 2}, {"bbox": [321.0, 433.0, 23.0, 28.0], "category_id": 3, "id": 3}], "caption": "Figure 2. Ligands synthesized.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 412, 605, 425], "ImageBB": [439, 262, 777, 400]}, "corefs": [[0, 3], [2, 1]]}, {"id": 802, "width": 1148, "height": 872, "file_name": "ol036510q-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [109.0, 489.0, 670.0, 168.3], "category_id": 1, "id": 0}, {"bbox": [0.0, 140.0, 461.0, 215.8], "category_id": 1, "id": 1}, {"bbox": [480.0, 134.0, 481.0, 220.6], "category_id": 1, "id": 2}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 990, 491, 1003], "ImageBB": [490, 799, 777, 1017]}, "corefs": []}, {"id": 803, "width": 1352, "height": 504, "file_name": "ol035711r-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [209.1, 133.0, 320.7, 236.7], "category_id": 1, "id": 0}, {"bbox": [813.3, 175.0, 328.7, 188.0], "category_id": 1, "id": 1}], "caption": "Figure 5. Steric interactions and Kt/c values at 298 K.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 190, 722, 204], "ImageBB": [439, 52, 777, 178]}, "corefs": []}, {"id": 804, "width": 1352, "height": 892, "file_name": "ol035711r-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [470.0, 146.1, 302.0, 329.9], "category_id": 1, "id": 0}, {"bbox": [918.0, 183.5, 395.0, 292.5], "category_id": 1, "id": 1}, {"bbox": [1051.0, 502.0, 138.0, 50.0], "category_id": 3, "id": 2}, {"bbox": [107.0, 506.0, 97.0, 53.0], "category_id": 3, "id": 3}, {"bbox": [67.0, 519.0, 515.0, 373.0], "category_id": 1, "id": 4}, {"bbox": [53.0, 561.0, 58.0, 59.0], "category_id": 3, "id": 5}, {"bbox": [53.0, 143.0, 59.0, 57.0], "category_id": 3, "id": 6}, {"bbox": [49.0, 146.0, 289.0, 339.0], "category_id": 1, "id": 7}], "caption": "Figure 4. Intramolecular forces: (a) hydrogen bonding and (b) n f \u03c0* interaction (looking down the CR-N bond). ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 287, 409, 316], "ImageBB": [73, 52, 411, 275]}, "corefs": [[7, 6], [7, 3], [1, 2], [4, 5]]}, {"id": 805, "width": 1356, "height": 696, "file_name": "ol035711r-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [172.0, 330.0, 34.0, 58.0], "category_id": 3, "id": 0}, {"bbox": [643.0, 331.0, 61.0, 54.0], "category_id": 3, "id": 1}, {"bbox": [123.7, 386.9, 491.3, 307.1], "category_id": 1, "id": 2}, {"bbox": [548.7, 146.0, 353.3, 182.1], "category_id": 1, "id": 3}, {"bbox": [1081.0, 333.0, 79.0, 49.0], "category_id": 3, "id": 4}, {"bbox": [1002.5, 143.0, 349.4, 186.04], "category_id": 1, "id": 5}, {"bbox": [61.0, 146.3, 344.7, 182.5], "category_id": 1, "id": 6}], "caption": "Figure 1. Electron distribution in prolylamides.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 868, 323, 881], "ImageBB": [73, 681, 412, 855]}, "corefs": [[6, 0], [3, 1], [5, 4]]}, {"id": 806, "width": 1352, "height": 488, "file_name": "ol030073y-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [935.0, 448.0, 41.0, 33.0], "category_id": 3, "id": 0}, {"bbox": [320.0, 430.9, 43.1, 35.1], "category_id": 3, "id": 1}, {"bbox": [80.0, 167.0, 509.0, 221.0], "category_id": 1, "id": 2}, {"bbox": [676.0, 162.0, 548.0, 219.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Selected NOESY for 16 and 17.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 1001, 298, 1014], "ImageBB": [73, 871, 411, 993]}, "corefs": [[2, 1], [3, 0]]}, {"id": 807, "width": 1352, "height": 600, "file_name": "ol026156g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [764.0, 146.1, 355.8, 317.8], "category_id": 1, "id": 0}, {"bbox": [301.7, 494.1, 276.3, 103.9], "category_id": 3, "id": 1}, {"bbox": [230.2, 180.1, 411.4, 255.6], "category_id": 1, "id": 2}, {"bbox": [900.0, 517.0, 92.0, 44.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Vanadyl complexes derived from 2-hydroxy-1-naph- thaldehyde or (+)-ketopinic acid with R-amino acids. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 466, 409, 493], "ImageBB": [73, 303, 411, 453]}, "corefs": [[2, 1], [0, 3]]}, {"id": 808, "width": 1352, "height": 568, "file_name": "ol020041v-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [150.0, 139.0, 405.0, 278.0], "category_id": 1, "id": 0}, {"bbox": [806.0, 147.0, 395.0, 275.0], "category_id": 1, "id": 1}, {"bbox": [329.0, 431.0, 35.0, 60.0], "category_id": 3, "id": 2}, {"bbox": [966.0, 432.0, 99.0, 61.0], "category_id": 3, "id": 3}], "caption": "Figure 4. \u03c0-Spin density distribution of 1 and 4\u20222- calculated by a local spin density functional theory using Gaussian 94 with the UBLYP/6-31G*//UBLYP/6-31G* method. Vacant and filled circles denote negative and positive \u03c0-spin densities, respectively.11 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 198, 775, 256], "ImageBB": [439, 51, 777, 193]}, "corefs": [[0, 2], [1, 3]]}, {"id": 809, "width": 1352, "height": 704, "file_name": "ol016867z-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1039.0, 428.0, 173.0, 148.0], "category_id": 1, "id": 0}, {"bbox": [328.0, 130.0, 590.0, 487.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Schematic representation of the concepts underlying the design of a continually rotating motor (see text). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 241, 409, 268], "ImageBB": [73, 52, 411, 228]}, "corefs": []}, {"id": 810, "width": 1352, "height": 3720, "file_name": "ol016466j-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [655.0, 3121.0, 417.5, 42.2], "category_id": 3, "id": 0}, {"bbox": [727.0, 2304.0, 417.0, 160.0], "category_id": 3, "id": 1}, {"bbox": [654.98, 3177.7, 397.82, 49.7], "category_id": 3, "id": 2}, {"bbox": [181.0, 2700.0, 990.0, 366.0], "category_id": 1, "id": 3}, {"bbox": [581.0, 2035.0, 654.0, 275.0], "category_id": 1, "id": 4}, {"bbox": [121.0, 2035.0, 378.0, 265.0], "category_id": 1, "id": 5}], "caption": "Table 1. Glycosylation Reaction of GalpR(1f4)Glcp\u03b2-O-(DOX)(PEGM) 4 with a Number of Retaining and Inverting Glycosyltransferases ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 739, 120], "ImageBB": [439, 121, 777, 1051]}, "corefs": [[4, 1], [3, 0], [3, 2]]}, {"id": 811, "width": 1148, "height": 564, "file_name": "ol0163169-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [222.0, 246.0, 25.3, 41.6], "category_id": 3, "id": 0}, {"bbox": [676.0, 241.4, 35.3, 40.6], "category_id": 3, "id": 1}, {"bbox": [579.0, 153.6, 230.0, 85.8], "category_id": 1, "id": 2}, {"bbox": [140.0, 148.0, 186.0, 98.4], "category_id": 1, "id": 3}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 745, 491, 758], "ImageBB": [490, 631, 777, 772]}, "corefs": [[3, 0], [2, 1]]}, {"id": 812, "width": 1352, "height": 772, "file_name": "ol0101638-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [292.2, 145.0, 765.8, 620.6], "category_id": 1, "id": 0}], "caption": "Figure 1. Proposed binding model of GHK-AN with Cu2+.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 913, 384, 927], "ImageBB": [73, 709, 411, 902]}, "corefs": []}, {"id": 813, "width": 1352, "height": 1368, "file_name": "ol006614q-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [474.0, 1189.0, 406.0, 179.0], "category_id": 3, "id": 0}, {"bbox": [660.0, 394.0, 35.0, 43.0], "category_id": 3, "id": 1}, {"bbox": [662.0, 660.0, 30.0, 41.0], "category_id": 3, "id": 2}, {"bbox": [660.0, 907.0, 31.0, 37.0], "category_id": 3, "id": 3}, {"bbox": [396.0, 145.0, 571.0, 257.0], "category_id": 1, "id": 4}, {"bbox": [436.0, 981.5, 478.0, 196.5], "category_id": 1, "id": 5}, {"bbox": [341.0, 428.7, 673.0, 238.0], "category_id": 1, "id": 6}, {"bbox": [369.7, 693.0, 610.3, 216.8], "category_id": 1, "id": 7}], "caption": "Figure 1. \u03b2-Amino acid derivatives used to determine ee values.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 899, 775, 912], "ImageBB": [439, 544, 777, 886]}, "corefs": [[4, 1], [6, 2], [7, 3], [5, 0]]}, {"id": 814, "width": 1352, "height": 548, "file_name": "ol006192k-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [58.5, 141.2, 336.9, 380.6], "category_id": 1, "id": 0}, {"bbox": [517.2, 144.1, 322.8, 380.5], "category_id": 1, "id": 1}, {"bbox": [1041.98, 504.96, 48.0, 40.0], "category_id": 3, "id": 2}, {"bbox": [593.0, 501.94, 48.0, 43.0], "category_id": 3, "id": 3}, {"bbox": [128.06, 497.98, 55.0, 46.0], "category_id": 3, "id": 4}, {"bbox": [966.2, 145.4, 326.5, 381.2], "category_id": 1, "id": 5}], "caption": "Figure 4. Revised structures for the pseudopterosin G-J aglycon 15 and helioporin E (16) and the reported structure for pseudopterox- azole 18. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 866, 775, 907], "ImageBB": [439, 716, 777, 853]}, "corefs": [[0, 4], [1, 3], [5, 2]]}, {"id": 815, "width": 1352, "height": 1044, "file_name": "ol006192k-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [4.6, 246.0, 601.2, 607.0], "category_id": 1, "id": 0}, {"bbox": [649.0, 170.8, 671.0, 854.8], "category_id": 1, "id": 1}, {"bbox": [767.0, 982.0, 86.0, 60.0], "category_id": 3, "id": 2}, {"bbox": [107.0, 782.0, 55.0, 46.0], "category_id": 3, "id": 3}], "caption": "Figure 3. X-ray crystal structure of p-bromobenzoate 17.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 493, 739, 506], "ImageBB": [439, 216, 777, 477]}, "corefs": [[0, 3], [1, 2]]}, {"id": 816, "width": 1352, "height": 548, "file_name": "ol006192k-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [875.0, 506.0, 46.0, 31.0], "category_id": 3, "id": 0}, {"bbox": [301.0, 502.0, 52.0, 39.0], "category_id": 3, "id": 1}, {"bbox": [793.0, 143.0, 328.0, 378.0], "category_id": 1, "id": 2}, {"bbox": [231.4, 143.0, 331.5, 377.2], "category_id": 1, "id": 3}], "caption": "Figure 2. Originally reported structures for the pseudopterosin G-J aglycon 10 and helioporin E (11). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 987, 775, 1014], "ImageBB": [439, 837, 777, 974]}, "corefs": [[3, 1], [2, 0]]}, {"id": 817, "width": 1352, "height": 1072, "file_name": "ol0002368-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [376.0, 1019.0, 38.0, 48.0], "category_id": 3, "id": 0}, {"bbox": [1009.0, 1024.0, 39.0, 45.0], "category_id": 3, "id": 1}, {"bbox": [308.75, 524.38, 54.6, 60.0], "category_id": 3, "id": 2}, {"bbox": [76.1, 639.6, 567.7, 358.8], "category_id": 1, "id": 3}, {"bbox": [960.06, 536.23, 56.3, 53.9], "category_id": 3, "id": 4}, {"bbox": [90.1, 174.2, 527.8, 325.7], "category_id": 1, "id": 5}, {"bbox": [740.0, 136.2, 531.3, 377.7], "category_id": 1, "id": 6}, {"bbox": [761.1, 695.0, 518.4, 257.8], "category_id": 1, "id": 7}], "caption": "Figure 2.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 333, 491, 346], "ImageBB": [439, 52, 777, 320]}, "corefs": [[3, 2], [6, 4], [3, 0], [7, 1]]}, {"id": 818, "width": 1300, "height": 1404, "file_name": "jo991700t-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [189.5, 1049.0, 186.7, 119.7], "category_id": 1, "id": 0}, {"bbox": [652.3, 678.0, 275.1, 189.0], "category_id": 1, "id": 1}, {"bbox": [587.7, 119.5, 222.5, 165.1], "category_id": 1, "id": 2}, {"bbox": [429.5, 367.1, 273.7, 185.8], "category_id": 1, "id": 3}, {"bbox": [653.6, 1023.4, 284.6, 270.0], "category_id": 1, "id": 4}, {"bbox": [147.1, 615.1, 290.1, 273.8], "category_id": 1, "id": 5}, {"bbox": [190.73, 1283.63, 182.56, 116.69], "category_id": 1, "id": 6}], "caption": "Figure 2. Two mechanistic pathways for hydrogen transfer reactions. ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 397, 409, 423], "ImageBB": [74, 35, 399, 386]}, "corefs": []}, {"id": 819, "width": 1252, "height": 1540, "file_name": "jo991681n-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [52.0, 259.0, 576.4, 512.0], "category_id": 1, "id": 0}], "caption": "Figure 2. 1H NMR spectra of free macrolide 1b (bottom) and a mixture of free macrolide 1b and its Ba2+ complex (top). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 462, 409, 489], "ImageBB": [86, 65, 399, 450]}, "corefs": []}, {"id": 820, "width": 2808, "height": 1840, "file_name": "jo990209z-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1836.0, 91.0, 756.0, 595.0], "category_id": 1, "id": 0}, {"bbox": [1858.0, 1108.0, 738.0, 648.0], "category_id": 1, "id": 1}, {"bbox": [1182.0, 1556.0, 375.0, 179.0], "category_id": 1, "id": 2}, {"bbox": [0.0, 843.0, 1030.0, 354.0], "category_id": 1, "id": 3}, {"bbox": [1366.0, 1753.0, 56.0, 38.0], "category_id": 3, "id": 4}, {"bbox": [483.0, 1226.0, 36.0, 45.0], "category_id": 3, "id": 5}, {"bbox": [2248.0, 1796.0, 26.0, 40.0], "category_id": 3, "id": 6}], "caption": "Figure 1. Resorcinarenes 2 and first generation cavitands 1 and 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 271, 452, 284], "ImageBB": [75, 294, 777, 754]}, "corefs": [[3, 5], [2, 4], [1, 6]]}, {"id": 821, "width": 1392, "height": 1032, "file_name": "jo982024i-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [460.0, 535.0, 238.0, 47.0], "category_id": 3, "id": 0}, {"bbox": [1138.0, 528.0, 254.0, 54.0], "category_id": 3, "id": 1}, {"bbox": [153.0, 968.0, 237.0, 60.0], "category_id": 3, "id": 2}, {"bbox": [628.0, 970.0, 208.0, 52.0], "category_id": 3, "id": 3}, {"bbox": [982.0, 975.0, 361.0, 55.0], "category_id": 3, "id": 4}, {"bbox": [741.0, 531.0, 357.9, 48.0], "category_id": 3, "id": 5}, {"bbox": [108.0, 524.0, 249.0, 61.0], "category_id": 3, "id": 6}, {"bbox": [744.7, 187.0, 311.2, 313.9], "category_id": 1, "id": 7}, {"bbox": [413.0, 187.0, 303.7, 313.9], "category_id": 1, "id": 8}, {"bbox": [1001.0, 635.5, 312.6, 308.2], "category_id": 1, "id": 9}, {"bbox": [556.0, 634.8, 312.5, 308.5], "category_id": 1, "id": 10}, {"bbox": [141.0, 672.3, 312.3, 267.7], "category_id": 1, "id": 11}, {"bbox": [1079.8, 185.3, 312.2, 317.8], "category_id": 1, "id": 12}, {"bbox": [88.0, 188.4, 308.0, 311.8], "category_id": 1, "id": 13}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 562, 497, 575], "ImageBB": [424, 293, 772, 551]}, "corefs": [[13, 6], [8, 0], [7, 5], [12, 1], [11, 2], [10, 3], [9, 4]]}, {"id": 822, "width": 1188, "height": 468, "file_name": "jo982004g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 0.0, 1188.0, 68.0], "category_id": 3, "id": 0}, {"bbox": [408.5, 102.6, 420.4, 360.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Preferential transitional structure for Michael addition. ring bound to the chiral center.13 Starting from this premise, we performed conjugate additions with donors bearing a naphthyl instead of a phenyl group at the chiral center with the hope that the bulkier aromatic group would improve the proximity effect. Indeed, enhancement of dr (93:7) was determined in the obtained high-yield products (entries 5-7). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 352, 775, 465], "ImageBB": [453, 224, 750, 341]}, "corefs": [[1, 0]]}, {"id": 823, "width": 624, "height": 308, "file_name": "jo981396o-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 0.0, 623.0, 308.0], "category_id": 1, "id": 0}], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 545, 131, 558], "ImageBB": [164, 456, 320, 533]}, "corefs": []}, {"id": 824, "width": 776, "height": 412, "file_name": "jo981359x-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [492.4, 23.3, 199.8, 333.8], "category_id": 1, "id": 0}, {"bbox": [104.0, 361.0, 103.0, 50.0], "category_id": 3, "id": 1}, {"bbox": [549.0, 361.0, 109.0, 48.0], "category_id": 3, "id": 2}, {"bbox": [41.0, 22.0, 220.0, 339.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Endo-activated complexes of the Diels-Alder reactions of 1 and 4 with 2. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 709, 775, 735], "ImageBB": [511, 592, 705, 695]}, "corefs": [[3, 1], [0, 2]]}, {"id": 825, "width": 1172, "height": 584, "file_name": "jo980755c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [69.0, 124.0, 621.0, 288.0], "category_id": 1, "id": 0}], "caption": "Figure 1. (+)-PPz* ) (+)-2,6-bis[(4S,7R)-7,8,8-trimethyl- 4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 181, 775, 210], "ImageBB": [483, 35, 776, 181]}, "corefs": []}, {"id": 826, "width": 1336, "height": 1484, "file_name": "jo980181b-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [685.0, 125.0, 557.0, 662.0], "category_id": 1, "id": 0}, {"bbox": [619.0, 794.0, 697.0, 622.0], "category_id": 1, "id": 1}, {"bbox": [4.0, 233.0, 392.0, 302.0], "category_id": 1, "id": 2}, {"bbox": [887.0, 539.0, 101.0, 44.0], "category_id": 3, "id": 3}, {"bbox": [26.0, 914.0, 360.0, 307.0], "category_id": 1, "id": 4}, {"bbox": [860.0, 1435.0, 105.0, 48.0], "category_id": 3, "id": 5}], "caption": "Figure 5. Transiton states of Z-sulfonyl trienes calculated by MOPAC PM3. ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 419, 775, 445], "ImageBB": [443, 35, 777, 406]}, "corefs": [[0, 3], [1, 5]]}, {"id": 827, "width": 1072, "height": 572, "file_name": "jo980058k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 131.0, 782.0, 441.0], "category_id": 1, "id": 0}], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 192, 497, 205], "ImageBB": [509, 35, 777, 178]}, "corefs": []}, {"id": 828, "width": 1088, "height": 736, "file_name": "jo970671o-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2.0, 0.0, 1085.0, 736.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Oscillamide Y (* unknown stereochemistry).", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 658, 747, 671], "ImageBB": [471, 462, 743, 646]}, "corefs": []}, {"id": 829, "width": 2808, "height": 1200, "file_name": "jo962055i-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1148.9, 5.0, 509.4, 298.0], "category_id": 1, "id": 0}], "caption": "Table 3. Physical Properties and DNA Binding Properties and Cytotoxicity of Representative Examples of the Newly                                               Described Products ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [80, 49, 766, 74], "ImageBB": [73, 80, 775, 380]}, "corefs": []}, {"id": 830, "width": 2068, "height": 2096, "file_name": "jo961901m-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [57.0, 31.0, 125.0, 83.0], "category_id": 3, "id": 0}, {"bbox": [17.0, 1171.0, 130.0, 96.0], "category_id": 3, "id": 1}, {"bbox": [254.0, 1099.0, 483.0, 409.0], "category_id": 1, "id": 2}, {"bbox": [190.0, 199.0, 523.0, 470.0], "category_id": 1, "id": 3}], "caption": "          1H Figure 3.    NMR spectra of (a) Ga(3opy5) complex and (b) free ligand (3HOPY5) in CD3OD. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 585, 592, 599], "ImageBB": [165, 50, 682, 574]}, "corefs": [[3, 0], [2, 1]]}, {"id": 831, "width": 1340, "height": 2916, "file_name": "jo961901m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [962.6, 290.7, 377.4, 267.3], "category_id": 1, "id": 0}, {"bbox": [168.5, 84.1, 637.0, 264.9], "category_id": 1, "id": 1}, {"bbox": [153.7, 747.0, 714.3, 356.0], "category_id": 1, "id": 2}, {"bbox": [1111.0, 531.0, 43.0, 49.0], "category_id": 3, "id": 3}, {"bbox": [319.0, 1078.0, 48.0, 67.0], "category_id": 3, "id": 4}, {"bbox": [352.51, 359.71, 139.67, 186.22], "category_id": 3, "id": 5}], "caption": "Figure 1. Spectral change of Fe(3opy5) in aqueous solution under various pH conditions. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 788, 408, 814], "ImageBB": [92, 48, 427, 777]}, "corefs": [[1, 5], [0, 3], [2, 4]]}, {"id": 832, "width": 1340, "height": 2344, "file_name": "jo9521209-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [931.1, 1421.0, 390.2, 373.4], "category_id": 1, "id": 0}, {"bbox": [908.6, 1925.0, 414.4, 361.0], "category_id": 1, "id": 1}, {"bbox": [29.0, 932.4, 396.4, 377.2], "category_id": 1, "id": 2}, {"bbox": [25.7, 494.1, 498.0, 329.5], "category_id": 1, "id": 3}, {"bbox": [817.1, 495.0, 515.9, 342.0], "category_id": 1, "id": 4}, {"bbox": [0.0, 1919.9, 609.6, 315.1], "category_id": 1, "id": 5}, {"bbox": [3.1, 1473.4, 575.0, 320.7], "category_id": 1, "id": 6}, {"bbox": [913.3, 123.0, 409.7, 316.0], "category_id": 1, "id": 7}, {"bbox": [28.3, 106.0, 378.1, 314.0], "category_id": 1, "id": 8}, {"bbox": [906.7, 936.0, 416.0, 382.7], "category_id": 1, "id": 9}, {"bbox": [1018.0, 848.0, 96.0, 51.0], "category_id": 3, "id": 10}, {"bbox": [168.0, 431.0, 75.0, 47.0], "category_id": 3, "id": 11}, {"bbox": [1026.0, 428.0, 79.0, 44.0], "category_id": 3, "id": 12}, {"bbox": [157.0, 844.0, 105.0, 68.0], "category_id": 3, "id": 13}, {"bbox": [164.0, 2289.0, 126.0, 52.0], "category_id": 3, "id": 14}, {"bbox": [1008.0, 2289.0, 153.0, 48.0], "category_id": 3, "id": 15}, {"bbox": [1016.0, 1811.0, 129.0, 63.0], "category_id": 3, "id": 16}, {"bbox": [172.0, 1333.0, 106.0, 58.0], "category_id": 3, "id": 17}, {"bbox": [168.0, 1815.0, 116.0, 55.0], "category_id": 3, "id": 18}, {"bbox": [1018.0, 1330.0, 112.0, 54.0], "category_id": 3, "id": 19}], "caption": "Figure 2.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 625, 486, 638], "ImageBB": [432, 26, 767, 612]}, "corefs": [[8, 11], [7, 12], [3, 13], [4, 10], [2, 17], [9, 19], [6, 18], [0, 16], [5, 14], [1, 15]]}, {"id": 833, "width": 1204, "height": 836, "file_name": "jo8022318-Table-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [10.0, 9.0, 546.0, 336.9], "category_id": 1, "id": 0}, {"bbox": [312.36, 309.76, 63.0, 44.0], "category_id": 3, "id": 1}, {"bbox": [965.0, 311.0, 61.0, 43.0], "category_id": 3, "id": 2}, {"bbox": [19.0, 426.0, 548.0, 357.0], "category_id": 1, "id": 3}, {"bbox": [639.0, 2.0, 558.0, 438.0], "category_id": 1, "id": 4}, {"bbox": [231.0, 778.0, 63.0, 56.0], "category_id": 3, "id": 5}], "caption": "Table 4.", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 705, 471, 719], "ImageBB": [443, 737, 744, 946]}, "corefs": [[0, 1], [4, 2], [3, 5]]}, {"id": 834, "width": 1028, "height": 1156, "file_name": "jo5026145-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [366.0, 120.0, 342.0, 179.0], "category_id": 1, "id": 0}, {"bbox": [210.0, 319.0, 51.0, 47.0], "category_id": 3, "id": 1}, {"bbox": [612.0, 292.0, 72.0, 48.0], "category_id": 3, "id": 2}, {"bbox": [610.0, 604.0, 76.0, 45.0], "category_id": 3, "id": 3}, {"bbox": [601.0, 871.0, 68.0, 48.0], "category_id": 3, "id": 4}, {"bbox": [222.0, 904.0, 41.0, 52.0], "category_id": 3, "id": 5}, {"bbox": [1.0, 131.0, 284.0, 266.0], "category_id": 1, "id": 6}, {"bbox": [361.0, 381.0, 323.0, 216.0], "category_id": 1, "id": 7}, {"bbox": [10.0, 710.0, 262.0, 205.0], "category_id": 1, "id": 8}, {"bbox": [419.0, 690.0, 236.0, 195.0], "category_id": 1, "id": 9}, {"bbox": [411.0, 939.0, 249.0, 209.0], "category_id": 1, "id": 10}], "caption": "Table 3. Arylation on the C-5 Position of 1,4-Disubstituted 1,2,3-Triazole ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [122, 131, 379, 420]}, "corefs": [[6, 1], [0, 2], [7, 3], [8, 5], [9, 4]]}, {"id": 835, "width": 1352, "height": 260, "file_name": "jo502408z-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [406.0, 37.0, 536.0, 223.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Alanine Schi\ufb00 base.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 742, 223, 756], "ImageBB": [82, 668, 420, 733]}, "corefs": []}, {"id": 836, "width": 1348, "height": 1796, "file_name": "jo501910q-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [730.0, 190.0, 501.0, 153.0], "category_id": 3, "id": 0}, {"bbox": [79.0, 237.0, 548.0, 193.0], "category_id": 3, "id": 1}, {"bbox": [87.0, 635.4, 282.0, 311.6], "category_id": 1, "id": 2}, {"bbox": [163.7, 2.4, 353.9, 231.6], "category_id": 1, "id": 3}, {"bbox": [878.37, 1221.41, 386.13, 245.0], "category_id": 1, "id": 4}, {"bbox": [454.0, 1162.0, 411.2, 474.8], "category_id": 1, "id": 5}, {"bbox": [85.0, 1192.0, 402.7, 392.7], "category_id": 1, "id": 6}, {"bbox": [753.0, 642.3, 506.1, 368.0], "category_id": 1, "id": 7}, {"bbox": [702.9, 13.0, 315.5, 170.0], "category_id": 1, "id": 8}, {"bbox": [394.0, 583.0, 357.0, 489.0], "category_id": 1, "id": 9}, {"bbox": [1020.0, 1486.0, 75.0, 60.0], "category_id": 3, "id": 10}, {"bbox": [646.0, 1601.0, 75.0, 60.0], "category_id": 3, "id": 11}, {"bbox": [250.0, 1579.0, 67.0, 49.0], "category_id": 3, "id": 12}, {"bbox": [992.0, 957.0, 53.0, 43.0], "category_id": 3, "id": 13}, {"bbox": [117.0, 947.0, 217.0, 108.0], "category_id": 3, "id": 14}, {"bbox": [324.0, 1075.0, 526.0, 106.6], "category_id": 3, "id": 15}], "caption": "Table 1. Optimization Studya", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 617, 110], "ImageBB": [449, 116, 786, 565]}, "corefs": [[3, 1], [8, 0], [2, 14], [9, 15], [7, 13], [6, 12], [5, 11], [4, 10]]}, {"id": 837, "width": 1352, "height": 736, "file_name": "jo501910q-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [54.0, 632.0, 566.0, 40.0], "category_id": 3, "id": 0}, {"bbox": [54.0, 287.0, 356.0, 49.9], "category_id": 3, "id": 1}, {"bbox": [54.0, 678.0, 671.0, 50.9], "category_id": 3, "id": 2}, {"bbox": [56.3, 38.1, 276.3, 248.9], "category_id": 1, "id": 3}, {"bbox": [425.3, 59.3, 866.4, 502.4], "category_id": 1, "id": 4}, {"bbox": [61.5, 346.0, 270.7, 282.0], "category_id": 1, "id": 5}, {"bbox": [665.2, 467.1, 539.5, 71.8], "category_id": 3, "id": 6}], "caption": "Figure 1. Dihydrophenanthridine and its structurally related compounds. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 884, 417, 912], "ImageBB": [82, 691, 420, 875]}, "corefs": [[3, 1], [5, 0], [5, 2], [4, 6]]}, {"id": 838, "width": 1356, "height": 484, "file_name": "jo501736w-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [77.0, 40.0, 265.0, 132.9], "category_id": 1, "id": 0}, {"bbox": [1074.0, 229.2, 135.0, 234.8], "category_id": 1, "id": 1}, {"bbox": [1040.9, 64.0, 239.1, 112.1], "category_id": 1, "id": 2}, {"bbox": [437.0, 40.3, 269.0, 129.7], "category_id": 1, "id": 3}, {"bbox": [728.0, 234.2, 243.0, 240.8], "category_id": 1, "id": 4}, {"bbox": [429.0, 257.3, 208.0, 168.7], "category_id": 1, "id": 5}, {"bbox": [760.0, 77.0, 217.0, 70.0], "category_id": 1, "id": 6}, {"bbox": [97.0, 268.0, 209.0, 169.0], "category_id": 1, "id": 7}], "caption": "Figure 3. Molecular structures of amine partners that failed to react under the optimized reaction conditions. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 309, 784, 337], "ImageBB": [448, 179, 787, 300]}, "corefs": []}, {"id": 839, "width": 1356, "height": 732, "file_name": "jo501014e-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [955.0, 678.0, 194.0, 51.1], "category_id": 3, "id": 0}, {"bbox": [136.6, 44.2, 276.1, 254.8], "category_id": 1, "id": 1}, {"bbox": [563.0, 671.0, 192.0, 59.0], "category_id": 3, "id": 2}, {"bbox": [185.0, 673.0, 184.0, 58.0], "category_id": 3, "id": 3}, {"bbox": [179.0, 309.0, 184.0, 56.0], "category_id": 3, "id": 4}, {"bbox": [871.3, 39.3, 323.6, 264.7], "category_id": 1, "id": 5}, {"bbox": [92.5, 415.2, 369.5, 256.8], "category_id": 1, "id": 6}, {"bbox": [460.0, 411.4, 401.2, 258.6], "category_id": 1, "id": 7}, {"bbox": [844.9, 409.6, 413.7, 268.4], "category_id": 1, "id": 8}, {"bbox": [496.2, 38.2, 303.8, 267.8], "category_id": 1, "id": 9}, {"bbox": [554.0, 309.0, 184.0, 57.9], "category_id": 3, "id": 10}, {"bbox": [932.0, 309.0, 200.0, 55.8], "category_id": 3, "id": 11}], "caption": "Figure 2. Sulfones obtained by oxidation of the corresponding thia- 2H-indazoles. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 1032, 784, 1060], "ImageBB": [448, 829, 787, 1012]}, "corefs": [[1, 4], [9, 10], [5, 11], [6, 3], [7, 2], [8, 0]]}, {"id": 840, "width": 1352, "height": 404, "file_name": "jo5007575-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [718.0, 36.0, 299.0, 294.0], "category_id": 1, "id": 0}, {"bbox": [331.5, 120.0, 293.5, 210.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Structures of N-heterocyclic carbenes (NHC) and imidazolium 2-carboxylates (NHC\u2212CO2). ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1014, 417, 1043], "ImageBB": [82, 903, 420, 1004]}, "corefs": []}, {"id": 841, "width": 1352, "height": 1176, "file_name": "jo500480r-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [967.1, 101.1, 325.1, 241.7], "category_id": 1, "id": 0}, {"bbox": [304.5, 18.6, 369.4, 305.2], "category_id": 1, "id": 1}], "caption": "Table 3. Absorption Maxima of Monotriazines 3\u22125", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 320, 366, 335], "ImageBB": [82, 341, 420, 635]}, "corefs": []}, {"id": 842, "width": 3396, "height": 3908, "file_name": "jo402763m-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [590.0, 2575.0, 125.0, 53.0], "category_id": 3, "id": 0}, {"bbox": [1513.0, 1258.0, 89.0, 53.0], "category_id": 3, "id": 1}, {"bbox": [599.0, 1251.0, 103.0, 63.0], "category_id": 3, "id": 2}, {"bbox": [2693.0, 829.0, 182.0, 63.0], "category_id": 3, "id": 3}, {"bbox": [2232.0, 833.0, 85.0, 49.0], "category_id": 3, "id": 4}, {"bbox": [1500.0, 813.0, 95.0, 72.0], "category_id": 3, "id": 5}, {"bbox": [1526.0, 3518.0, 181.0, 56.0], "category_id": 3, "id": 6}, {"bbox": [2205.0, 3518.0, 198.0, 60.0], "category_id": 3, "id": 7}, {"bbox": [2697.0, 3518.0, 217.0, 53.0], "category_id": 3, "id": 8}, {"bbox": [2548.0, 3222.0, 370.0, 237.0], "category_id": 1, "id": 9}, {"bbox": [2027.0, 3212.0, 406.0, 260.0], "category_id": 1, "id": 10}, {"bbox": [1322.0, 3225.0, 438.0, 241.0], "category_id": 1, "id": 11}, {"bbox": [425.0, 2216.0, 405.0, 313.0], "category_id": 1, "id": 12}, {"bbox": [2040.0, 2295.0, 403.0, 280.0], "category_id": 1, "id": 13}, {"bbox": [2558.0, 2302.0, 360.0, 247.0], "category_id": 1, "id": 14}, {"bbox": [2558.0, 1766.0, 381.0, 363.0], "category_id": 1, "id": 15}, {"bbox": [2035.0, 1812.0, 470.0, 323.0], "category_id": 1, "id": 16}, {"bbox": [1344.0, 1824.0, 458.0, 292.0], "category_id": 1, "id": 17}, {"bbox": [449.0, 1781.0, 378.0, 311.0], "category_id": 1, "id": 18}, {"bbox": [434.0, 1348.0, 396.0, 292.0], "category_id": 1, "id": 19}, {"bbox": [1344.0, 1428.0, 378.0, 243.0], "category_id": 1, "id": 20}, {"bbox": [2035.0, 1437.0, 375.0, 246.0], "category_id": 1, "id": 21}, {"bbox": [2552.0, 1425.0, 353.0, 246.0], "category_id": 1, "id": 22}, {"bbox": [2665.0, 884.0, 292.0, 344.0], "category_id": 1, "id": 23}, {"bbox": [2130.0, 933.0, 351.0, 304.0], "category_id": 1, "id": 24}, {"bbox": [1454.0, 936.0, 338.0, 286.0], "category_id": 1, "id": 25}, {"bbox": [569.0, 893.0, 280.0, 311.0], "category_id": 1, "id": 26}, {"bbox": [2672.0, 546.0, 242.0, 236.0], "category_id": 1, "id": 27}, {"bbox": [2152.0, 525.0, 266.0, 278.0], "category_id": 1, "id": 28}, {"bbox": [1456.0, 528.0, 275.0, 257.0], "category_id": 1, "id": 29}, {"bbox": [566.0, 456.0, 263.0, 308.0], "category_id": 1, "id": 30}, {"bbox": [603.0, 836.0, 85.0, 43.0], "category_id": 3, "id": 31}, {"bbox": [497.0, 8.0, 334.0, 290.0], "category_id": 1, "id": 32}, {"bbox": [1397.0, 89.0, 347.0, 228.0], "category_id": 1, "id": 33}, {"bbox": [2588.0, 78.0, 294.0, 238.0], "category_id": 1, "id": 34}, {"bbox": [2081.0, 76.0, 340.0, 264.0], "category_id": 1, "id": 35}, {"bbox": [1345.0, 2282.0, 405.0, 277.0], "category_id": 1, "id": 36}, {"bbox": [2683.0, 1258.0, 205.0, 56.0], "category_id": 3, "id": 37}, {"bbox": [606.0, 1697.0, 89.0, 46.0], "category_id": 3, "id": 38}, {"bbox": [1516.0, 1683.0, 73.0, 60.0], "category_id": 3, "id": 39}, {"bbox": [2228.0, 1690.0, 96.0, 59.0], "category_id": 3, "id": 40}, {"bbox": [2693.0, 1700.0, 178.0, 56.0], "category_id": 3, "id": 41}, {"bbox": [606.0, 2147.0, 96.0, 59.0], "category_id": 3, "id": 42}, {"bbox": [1510.0, 2143.0, 95.0, 56.0], "category_id": 3, "id": 43}, {"bbox": [2225.0, 2147.0, 96.0, 52.0], "category_id": 3, "id": 44}, {"bbox": [2680.0, 2140.0, 198.0, 73.0], "category_id": 3, "id": 45}, {"bbox": [2703.0, 2582.0, 86.0, 56.0], "category_id": 3, "id": 46}, {"bbox": [1533.0, 2575.0, 89.0, 53.0], "category_id": 3, "id": 47}, {"bbox": [2205.0, 2569.0, 99.0, 59.0], "category_id": 3, "id": 48}, {"bbox": [2502.0, 335.0, 406.0, 115.0], "category_id": 3, "id": 49}, {"bbox": [2136.0, 341.0, 195.0, 56.0], "category_id": 3, "id": 50}, {"bbox": [1486.0, 331.0, 162.0, 70.0], "category_id": 3, "id": 51}, {"bbox": [550.0, 341.0, 168.0, 56.0], "category_id": 3, "id": 52}, {"bbox": [2222.0, 1248.0, 99.0, 56.0], "category_id": 3, "id": 53}], "caption": "Table 3. Pd-Catalyzed Chemoselective Intramolecular Heck Coupling of Tertiary Alcohols 4 to the Region-Isomeric Mixture of Indenols 13 and Indenenes 14 ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 784, 125], "ImageBB": [10, 150, 859, 1127]}, "corefs": [[32, 52], [33, 51], [35, 50], [34, 49], [30, 31], [29, 5], [28, 4], [27, 3], [26, 2], [25, 1], [24, 53], [23, 37], [19, 38], [20, 39], [21, 40], [22, 41], [18, 42], [17, 43], [16, 44], [15, 45], [12, 0], [36, 47], [13, 48], [14, 46], [11, 6], [10, 7], [9, 8]]}, {"id": 843, "width": 1416, "height": 2308, "file_name": "jo402749d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [845.0, 1170.0, 301.0, 298.0], "category_id": 1, "id": 0}, {"bbox": [1196.0, 1170.0, 201.0, 272.0], "category_id": 1, "id": 1}, {"bbox": [307.0, 495.0, 4.0, 3.0], "category_id": 1, "id": 2}, {"bbox": [1042.0, 696.0, 374.0, 373.0], "category_id": 1, "id": 3}, {"bbox": [375.0, 1184.0, 201.0, 212.0], "category_id": 1, "id": 4}, {"bbox": [604.0, 1173.0, 233.0, 223.0], "category_id": 1, "id": 5}, {"bbox": [465.0, 1582.0, 530.0, 521.0], "category_id": 1, "id": 6}, {"bbox": [263.2, 774.7, 704.5, 238.9], "category_id": 1, "id": 7}, {"bbox": [372.0, 327.9, 494.9, 350.1], "category_id": 1, "id": 8}, {"bbox": [1118.5, 0.0, 297.5, 466.0], "category_id": 1, "id": 9}], "caption": "Figure 1. Kealiinine and kealiiquinone alkaloids and analogues.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 868, 388, 882], "ImageBB": [82, 282, 436, 859]}, "corefs": []}, {"id": 844, "width": 3396, "height": 2196, "file_name": "jo4027148-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1478.0, 1067.0, 506.0, 437.0], "category_id": 1, "id": 0}, {"bbox": [2294.0, 1646.0, 531.0, 480.0], "category_id": 1, "id": 1}, {"bbox": [2250.0, 1092.0, 615.0, 368.0], "category_id": 1, "id": 2}, {"bbox": [368.0, 364.0, 582.0, 269.0], "category_id": 1, "id": 3}, {"bbox": [1380.0, 1598.0, 629.0, 565.0], "category_id": 1, "id": 4}, {"bbox": [2337.0, 269.0, 663.0, 463.0], "category_id": 1, "id": 5}, {"bbox": [2552.9, 738.0, 239.1, 51.0], "category_id": 3, "id": 6}, {"bbox": [550.8, 1779.6, 583.2, 212.7], "category_id": 1, "id": 7}, {"bbox": [636.9, 1114.2, 408.1, 327.8], "category_id": 1, "id": 8}, {"bbox": [1323.6, 319.4, 667.4, 393.6], "category_id": 1, "id": 9}, {"bbox": [2404.6, 1497.0, 299.4, 64.0], "category_id": 3, "id": 10}, {"bbox": [729.39, 2141.0, 216.8, 55.0], "category_id": 3, "id": 11}, {"bbox": [1566.3, 2141.0, 283.7, 55.0], "category_id": 3, "id": 12}, {"bbox": [694.3, 1502.0, 299.7, 45.0], "category_id": 3, "id": 13}, {"bbox": [1587.63, 1504.81, 251.0, 44.0], "category_id": 3, "id": 14}, {"bbox": [2418.6, 2142.0, 279.4, 54.0], "category_id": 3, "id": 15}, {"bbox": [550.3, 737.0, 252.7, 56.0], "category_id": 3, "id": 16}, {"bbox": [1538.0, 733.0, 220.0, 53.0], "category_id": 3, "id": 17}], "caption": "Figure 4. Biosynthetic relationships between various dimeric natural products.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 581, 461, 595], "ImageBB": [10, 22, 859, 571]}, "corefs": [[3, 16], [9, 17], [5, 6], [8, 13], [0, 14], [2, 10], [7, 11], [4, 12], [1, 15]]}, {"id": 845, "width": 2820, "height": 680, "file_name": "jo4027148-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2178.0, 38.0, 228.0, 194.0], "category_id": 1, "id": 0}, {"bbox": [118.0, 275.0, 144.0, 175.0], "category_id": 1, "id": 1}, {"bbox": [1009.0, 170.0, 182.0, 169.0], "category_id": 1, "id": 2}, {"bbox": [835.0, 393.0, 108.0, 171.0], "category_id": 1, "id": 3}, {"bbox": [1580.0, 38.0, 196.0, 207.0], "category_id": 1, "id": 4}, {"bbox": [1573.0, 266.0, 205.0, 207.0], "category_id": 1, "id": 5}, {"bbox": [1582.0, 489.0, 192.0, 189.0], "category_id": 1, "id": 6}, {"bbox": [1883.0, 36.0, 213.0, 205.0], "category_id": 1, "id": 7}, {"bbox": [2509.0, 45.0, 208.0, 191.0], "category_id": 1, "id": 8}, {"bbox": [2482.0, 268.0, 232.0, 207.0], "category_id": 1, "id": 9}, {"bbox": [2180.0, 259.0, 219.0, 198.0], "category_id": 1, "id": 10}, {"bbox": [1039.8, 393.6, 122.2, 168.3], "category_id": 1, "id": 11}, {"bbox": [822.0, 166.0, 144.4, 174.1], "category_id": 1, "id": 12}, {"bbox": [309.4, 275.0, 180.5, 174.1], "category_id": 1, "id": 13}, {"bbox": [2196.0, 480.0, 197.0, 200.0], "category_id": 1, "id": 14}, {"bbox": [1876.0, 494.0, 215.0, 186.0], "category_id": 1, "id": 15}, {"bbox": [1867.0, 273.0, 222.0, 196.0], "category_id": 1, "id": 16}], "caption": "Figure 2. Potential products of a hypothetical photochemical [2 + 2] heterodimerzation reaction.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 610, 555, 624], "ImageBB": [82, 430, 787, 600]}, "corefs": []}, {"id": 846, "width": 1356, "height": 880, "file_name": "jo401737t-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [371.5, 103.3, 876.7, 79.0], "category_id": 1, "id": 0}, {"bbox": [215.4, 263.0, 1022.2, 147.2], "category_id": 1, "id": 1}, {"bbox": [427.8, 489.0, 807.7, 389.8], "category_id": 1, "id": 2}], "caption": "Figure 6. Structure of commercially available surfactants.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 669, 725, 683], "ImageBB": [448, 439, 787, 659]}, "corefs": []}, {"id": 847, "width": 1348, "height": 520, "file_name": "jo401195c-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [380.0, 363.0, 528.0, 61.0], "category_id": 3, "id": 0}, {"bbox": [341.8, 6.0, 667.3, 338.8], "category_id": 1, "id": 1}], "caption": "Table 3. Screening of the KR of (\u00b1)-1 with Peptide Catalysts 18\u221221 and 12c: Investigation of the Role of the C-Terminal Amino Acid ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 140], "ImageBB": [82, 146, 419, 276]}, "corefs": [[1, 0]]}, {"id": 848, "width": 1352, "height": 452, "file_name": "jo401195c-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [765.5, 87.8, 208.1, 164.9], "category_id": 1, "id": 0}, {"bbox": [397.4, 84.8, 229.3, 142.5], "category_id": 1, "id": 1}, {"bbox": [1121.0, 264.0, 131.0, 62.0], "category_id": 3, "id": 2}, {"bbox": [792.0, 275.0, 130.0, 56.0], "category_id": 3, "id": 3}, {"bbox": [415.0, 270.0, 130.0, 62.0], "category_id": 3, "id": 4}, {"bbox": [79.0, 261.0, 128.0, 73.0], "category_id": 3, "id": 5}, {"bbox": [44.5, 41.2, 221.1, 210.7], "category_id": 1, "id": 6}, {"bbox": [1082.2, 134.1, 222.4, 91.7], "category_id": 1, "id": 7}], "caption": "Figure 6. Testing the KR of the racemic monoalcohols 24\u221227 with catalyst 12b. ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 727, 417, 755], "ImageBB": [82, 605, 420, 718]}, "corefs": [[6, 5], [1, 4], [0, 3], [7, 2]]}, {"id": 849, "width": 2820, "height": 2312, "file_name": "jo401195c-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1433.0, 1680.64, 836.0, 63.0], "category_id": 3, "id": 0}, {"bbox": [334.0, 1810.0, 1047.0, 434.0], "category_id": 1, "id": 1}, {"bbox": [340.0, 1257.0, 1031.0, 416.0], "category_id": 1, "id": 2}, {"bbox": [1445.0, 1817.0, 1026.0, 410.0], "category_id": 1, "id": 3}, {"bbox": [1439.0, 1226.0, 1027.0, 434.0], "category_id": 1, "id": 4}, {"bbox": [341.0, 662.0, 1030.0, 438.0], "category_id": 1, "id": 5}, {"bbox": [1435.0, 669.0, 1027.0, 428.0], "category_id": 1, "id": 6}, {"bbox": [1437.0, 92.0, 1039.0, 399.0], "category_id": 1, "id": 7}, {"bbox": [336.0, 55.0, 1040.0, 439.0], "category_id": 1, "id": 8}, {"bbox": [1415.0, 2258.0, 847.0, 54.0], "category_id": 3, "id": 9}, {"bbox": [389.0, 1678.0, 842.0, 72.0], "category_id": 3, "id": 10}, {"bbox": [436.0, 1114.0, 957.0, 63.0], "category_id": 3, "id": 11}, {"bbox": [1517.0, 1120.93, 850.0, 66.0], "category_id": 3, "id": 12}, {"bbox": [1439.0, 523.29, 1062.0, 54.0], "category_id": 3, "id": 13}, {"bbox": [400.64, 510.93, 873.0, 65.0], "category_id": 3, "id": 14}, {"bbox": [403.0, 2249.0, 842.0, 63.0], "category_id": 3, "id": 15}], "caption": "Figure 4. Variation of peptide catalysts. Structural changes of the peptides compared to 12a and 12b are drawn in red.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1046, 661, 1060], "ImageBB": [82, 448, 787, 1026]}, "corefs": [[8, 14], [7, 13], [5, 11], [6, 12], [2, 10], [4, 0], [1, 15], [3, 9]]}, {"id": 850, "width": 1356, "height": 584, "file_name": "jo401158d-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [734.0, 243.0, 332.0, 290.0], "category_id": 1, "id": 0}, {"bbox": [296.0, 249.0, 280.0, 292.0], "category_id": 1, "id": 1}, {"bbox": [426.0, 541.0, 28.0, 38.0], "category_id": 3, "id": 2}, {"bbox": [780.0, 257.0, 33.0, 36.0], "category_id": 3, "id": 3}, {"bbox": [928.0, 543.0, 32.0, 36.0], "category_id": 3, "id": 4}, {"bbox": [634.0, 46.0, 287.0, 210.0], "category_id": 1, "id": 5}], "caption": "Figure 2. Chirons for polyalicyclic synthesis.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 840, 666, 854], "ImageBB": [448, 685, 787, 831]}, "corefs": [[5, 3], [1, 2], [0, 4]]}, {"id": 851, "width": 1336, "height": 1952, "file_name": "jo4007046-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [478.1, 13.0, 204.3, 159.5], "category_id": 1, "id": 0}, {"bbox": [403.1, 1055.6, 232.7, 357.2], "category_id": 1, "id": 1}, {"bbox": [40.3, 1058.6, 231.1, 356.5], "category_id": 1, "id": 2}, {"bbox": [215.0, 1894.0, 180.0, 58.0], "category_id": 3, "id": 3}, {"bbox": [732.9, 1051.2, 233.6, 354.1], "category_id": 1, "id": 4}, {"bbox": [730.9, 3.0, 262.1, 385.1], "category_id": 1, "id": 5}, {"bbox": [155.7, 42.9, 131.6, 297.9], "category_id": 1, "id": 6}, {"bbox": [999.0, 286.0, 142.8, 73.2], "category_id": 3, "id": 7}, {"bbox": [105.0, 264.0, 84.4, 61.8], "category_id": 3, "id": 8}, {"bbox": [401.1, 1419.2, 175.1, 68.7], "category_id": 3, "id": 9}, {"bbox": [775.9, 1412.9, 168.6, 65.4], "category_id": 3, "id": 10}, {"bbox": [1112.0, 1408.0, 166.6, 65.2], "category_id": 3, "id": 11}, {"bbox": [636.0, 1889.2, 175.2, 55.0], "category_id": 3, "id": 12}, {"bbox": [971.4, 1886.2, 176.0, 60.6], "category_id": 3, "id": 13}, {"bbox": [1067.5, 1050.1, 231.4, 352.2], "category_id": 1, "id": 14}, {"bbox": [177.7, 1532.8, 230.8, 351.2], "category_id": 1, "id": 15}, {"bbox": [595.3, 1525.2, 233.4, 353.5], "category_id": 1, "id": 16}, {"bbox": [971.3, 1532.7, 227.8, 348.7], "category_id": 1, "id": 17}, {"bbox": [845.2, 558.5, 229.8, 355.8], "category_id": 1, "id": 18}, {"bbox": [500.1, 564.8, 230.6, 353.9], "category_id": 1, "id": 19}, {"bbox": [112.6, 565.3, 232.2, 356.4], "category_id": 1, "id": 20}, {"bbox": [96.0, 950.0, 302.0, 78.0], "category_id": 3, "id": 21}], "caption": "Table 3. Synthesis of 3-Arylacetals and 3-Arylketals 16\u221225a", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 784, 110], "ImageBB": [450, 116, 784, 604]}, "corefs": [[6, 8], [5, 7], [20, 21], [1, 9], [4, 10], [14, 11], [15, 3], [16, 12], [17, 13]]}, {"id": 852, "width": 3396, "height": 1372, "file_name": "jo3026753-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1390.0, 640.0, 431.0, 115.0], "category_id": 3, "id": 0}, {"bbox": [1258.0, 1257.0, 706.0, 115.0], "category_id": 3, "id": 1}, {"bbox": [821.0, 1257.0, 369.0, 71.0], "category_id": 3, "id": 2}, {"bbox": [2059.0, 633.0, 488.0, 116.0], "category_id": 3, "id": 3}, {"bbox": [2171.0, 1260.0, 255.9, 67.8], "category_id": 3, "id": 4}, {"bbox": [800.0, 640.5, 414.0, 104.5], "category_id": 3, "id": 5}, {"bbox": [790.0, 272.6, 410.7, 363.9], "category_id": 1, "id": 6}, {"bbox": [746.0, 776.0, 513.6, 474.0], "category_id": 1, "id": 7}, {"bbox": [1948.4, 795.3, 704.4, 442.1], "category_id": 1, "id": 8}, {"bbox": [1400.3, 284.5, 421.2, 349.2], "category_id": 1, "id": 9}, {"bbox": [1413.8, 830.5, 392.8, 368.5], "category_id": 1, "id": 10}, {"bbox": [2076.0, 275.6, 438.2, 358.3], "category_id": 1, "id": 11}], "caption": "Figure 1. Morphine alkaloids and medicinally useful semisynthetic derivatives.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 374, 461, 388], "ImageBB": [10, 22, 859, 365]}, "corefs": [[6, 5], [9, 0], [11, 3], [7, 2], [10, 1], [8, 4]]}, {"id": 853, "width": 1352, "height": 560, "file_name": "jo3010342-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [406.0, 40.0, 539.0, 520.0], "category_id": 1, "id": 0}], "caption": "Figure 3. Perpendicular displacements of each atom of 3a out of the mean oxaporphyrin core plane in units of pm. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1032, 417, 1060], "ImageBB": [82, 872, 420, 1012]}, "corefs": []}, {"id": 854, "width": 1352, "height": 436, "file_name": "jo2020856-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [116.3, 38.4, 531.7, 346.6], "category_id": 1, "id": 0}, {"bbox": [663.0, 36.3, 566.0, 340.7], "category_id": 1, "id": 1}, {"bbox": [796.0, 388.1, 56.0, 43.9], "category_id": 3, "id": 2}, {"bbox": [245.0, 392.0, 41.0, 37.0], "category_id": 3, "id": 3}], "caption": "Figure 2. Important (a) COSY (dark lines) and (b) HMBC cross correlation (curved arrows) in synthesized glycoconjugates. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 588, 417, 616], "ImageBB": [82, 470, 420, 579]}, "corefs": [[0, 3], [1, 2]]}, {"id": 855, "width": 1352, "height": 708, "file_name": "jo2020856-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [557.6, 398.2, 394.7, 267.8], "category_id": 1, "id": 0}, {"bbox": [222.1, 54.3, 492.1, 249.2], "category_id": 1, "id": 1}, {"bbox": [798.4, 41.2, 333.7, 283.7], "category_id": 1, "id": 2}], "caption": "Figure 1. Biologically active quinazolinone and quinazolinone based natural product. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 868, 417, 896], "ImageBB": [82, 681, 420, 858]}, "corefs": []}, {"id": 856, "width": 892, "height": 1088, "file_name": "jo201996w-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [291.0, 2.0, 320.0, 271.0], "category_id": 1, "id": 0}, {"bbox": [359.0, 293.0, 199.0, 159.0], "category_id": 3, "id": 1}], "caption": "Figure 2. Absorption spectra of a representative ortho-amino-, nitro-, acetamido-, and hydrogen-substituted bis-azobenzenes (4b, 4d, 4g, and 4h, respectively) in chloroform. ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 362, 405, 404], "ImageBB": [127, 82, 350, 354]}, "corefs": [[0, 1]]}, {"id": 857, "width": 2508, "height": 2228, "file_name": "jo201996w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [343.0, 14.0, 332.0, 204.0], "category_id": 1, "id": 0}, {"bbox": [1742.0, 251.0, 56.3, 35.8], "category_id": 3, "id": 1}, {"bbox": [396.0, 219.0, 218.9, 122.4], "category_id": 3, "id": 2}, {"bbox": [1771.0, 1412.7, 56.3, 37.6], "category_id": 3, "id": 3}, {"bbox": [485.0, 1369.7, 63.8, 49.8], "category_id": 3, "id": 4}, {"bbox": [1609.0, 0.0, 342.0, 213.0], "category_id": 1, "id": 5}, {"bbox": [1590.0, 1132.0, 408.0, 261.0], "category_id": 1, "id": 6}, {"bbox": [343.0, 1132.0, 337.0, 219.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Absorption spectra (a) and photoisomerization of representative ortho-amino-, nitro-, and acetamido-substituted monoazobenzenes (3b, 3d, and 3i, respectively; b\u2212d) in chloroform. ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 648, 772, 676], "ImageBB": [108, 82, 735, 639]}, "corefs": [[0, 2], [5, 1], [7, 4], [6, 3]]}, {"id": 858, "width": 828, "height": 368, "file_name": "jo200882k-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [416.4, 94.0, 282.6, 221.0], "category_id": 1, "id": 0}, {"bbox": [59.4, 95.7, 279.5, 220.9], "category_id": 1, "id": 1}, {"bbox": [137.0, 324.0, 121.0, 44.0], "category_id": 3, "id": 2}, {"bbox": [485.0, 325.0, 140.0, 43.0], "category_id": 3, "id": 3}], "caption": "Figure 2. Strategies for the development of modulators of AI-2- based QS. ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 463, 405, 491], "ImageBB": [136, 357, 343, 449]}, "corefs": [[1, 2], [0, 3]]}, {"id": 859, "width": 1344, "height": 384, "file_name": "jo200882k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [278.4, 196.2, 309.2, 181.8], "category_id": 1, "id": 0}, {"bbox": [723.2, 198.2, 285.1, 179.8], "category_id": 1, "id": 1}], "caption": "Figure 1. Equilibrium of DPD.", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 237, 221, 251], "ImageBB": [71, 252, 407, 348]}, "corefs": []}, {"id": 860, "width": 2808, "height": 1360, "file_name": "jo200877k-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2046.0, 1057.0, 32.0, 43.0], "category_id": 3, "id": 0}, {"bbox": [1959.4, 906.4, 310.9, 150.1], "category_id": 1, "id": 1}], "caption": "Figure 7. Laser \ufb02ash photolysis of 1 with a 266 nm laser collected between (A) 0.19 and 1.3 \u03bcs (red trace) and between (B) 18 and 39 \u03bcs (black trace) after the laser pulse. The inset shows the transients of 1 with a 266 nm excitation in N2-saturated acetonitrile collected between 0.19 and 1.3 \u03bcs (red trace) and between 1.6 and 5.3 \u03bcs (blue trace), and in O2-saturated acetonitrile collected between 0.74 and 3.3 \u03bcs (green trace). (C) Calculated electronic transition for 2 using CASPT2 (gas phase) and TD-DFT (acetonitrile) calculations. ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 848, 770, 907], "ImageBB": [71, 497, 773, 837]}, "corefs": [[1, 0]]}, {"id": 861, "width": 784, "height": 568, "file_name": "jo0497306-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [581.0, 252.0, 202.0, 158.3], "category_id": 3, "id": 0}, {"bbox": [6.0, 252.0, 238.0, 307.0], "category_id": 3, "id": 1}, {"bbox": [329.0, 253.0, 200.0, 154.9], "category_id": 3, "id": 2}, {"bbox": [603.8, 5.0, 109.4, 189.5], "category_id": 1, "id": 3}, {"bbox": [6.0, 53.6, 163.7, 127.2], "category_id": 1, "id": 4}, {"bbox": [395.2, 34.6, 110.5, 159.6], "category_id": 1, "id": 5}], "caption": "Table 2 reveals that while the parent", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [171, 625, 408, 639], "ImageBB": [144, 472, 340, 614]}, "corefs": [[4, 1], [5, 2], [3, 0]]}, {"id": 862, "width": 1344, "height": 812, "file_name": "ol7019636-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [738.0, 0.0, 380.0, 239.0], "category_id": 1, "id": 0}, {"bbox": [222.0, 239.0, 342.0, 90.5], "category_id": 3, "id": 1}, {"bbox": [734.0, 230.0, 337.0, 99.0], "category_id": 3, "id": 2}, {"bbox": [290.6, 38.0, 318.4, 154.0], "category_id": 1, "id": 3}], "caption": "Table 2. Kinetic Parameters for Diazeniumdiolate Anion Decompositiona ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 382, 375, 410], "ImageBB": [74, 414, 410, 617]}, "corefs": [[3, 1], [0, 2]]}, {"id": 863, "width": 1352, "height": 624, "file_name": "ol701624y-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [774.2, 145.0, 404.8, 354.0], "category_id": 1, "id": 0}, {"bbox": [168.0, 140.0, 413.0, 360.8], "category_id": 1, "id": 1}], "caption": "Figure 2. NOE observed with the ortho proton in the Tol group.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 784, 775, 797], "ImageBB": [439, 616, 777, 772]}, "corefs": []}, {"id": 864, "width": 1148, "height": 736, "file_name": "ol701624y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [28.0, 135.6, 893.0, 373.4], "category_id": 1, "id": 0}, {"bbox": [281.93, 533.8, 249.0, 48.0], "category_id": 3, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 815, 125, 828], "ImageBB": [124, 658, 411, 842]}, "corefs": [[0, 1]]}, {"id": 865, "width": 1352, "height": 840, "file_name": "ol701540y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [461.0, 375.0, 440.0, 417.0], "category_id": 1, "id": 0}, {"bbox": [913.0, 438.0, 62.0, 51.0], "category_id": 3, "id": 1}, {"bbox": [623.0, 794.0, 60.0, 46.0], "category_id": 3, "id": 2}, {"bbox": [396.0, 450.0, 55.5, 38.7], "category_id": 3, "id": 3}, {"bbox": [789.7, 174.4, 275.0, 274.8], "category_id": 1, "id": 4}, {"bbox": [284.5, 143.2, 291.9, 317.0], "category_id": 1, "id": 5}], "caption": "Figure 1. Fragment structures and key COSY (-) and HMBC (f) corrections of compound 1. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 987, 775, 1014], "ImageBB": [439, 765, 777, 975]}, "corefs": [[5, 3], [0, 2], [4, 1]]}, {"id": 866, "width": 1352, "height": 920, "file_name": "ol7014434-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [34.0, 296.0, 522.0, 622.0], "category_id": 1, "id": 0}, {"bbox": [685.0, 136.0, 667.0, 776.0], "category_id": 1, "id": 1}], "caption": "Figure 1. ORTEP view of compound 3 (left) and 14 (right).", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 413, 756, 426], "ImageBB": [439, 171, 777, 401]}, "corefs": []}, {"id": 867, "width": 1352, "height": 304, "file_name": "ol503587n-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [414.5, 45.4, 295.5, 210.6], "category_id": 1, "id": 0}, {"bbox": [825.5, 45.5, 333.9, 254.0], "category_id": 1, "id": 1}, {"bbox": [44.3, 52.3, 238.7, 211.7], "category_id": 1, "id": 2}, {"bbox": [522.0, 257.0, 48.0, 41.0], "category_id": 3, "id": 3}, {"bbox": [153.0, 263.0, 44.0, 39.0], "category_id": 3, "id": 4}], "caption": "Figure 5. Activated and hydride derivatives of 1 and likely mechanism of hydride transfer. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 413, 417, 441], "ImageBB": [82, 328, 420, 404]}, "corefs": [[2, 4], [0, 3]]}, {"id": 868, "width": 1356, "height": 304, "file_name": "ol503587n-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [949.3, 50.6, 304.2, 180.5], "category_id": 1, "id": 0}, {"bbox": [106.9, 52.0, 317.3, 180.0], "category_id": 1, "id": 1}, {"bbox": [494.3, 45.8, 360.1, 196.2], "category_id": 1, "id": 2}], "caption": "Figure 4. Substrates which worked poorly and were not isolated.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 755, 765, 769], "ImageBB": [448, 670, 787, 746]}, "corefs": []}, {"id": 869, "width": 1356, "height": 2144, "file_name": "ol502842f-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [66.4, 46.1, 232.4, 240.4], "category_id": 1, "id": 0}, {"bbox": [1003.0, 52.47, 244.7, 247.7], "category_id": 1, "id": 1}, {"bbox": [164.0, 249.0, 31.0, 39.0], "category_id": 3, "id": 2}, {"bbox": [1120.0, 249.0, 47.0, 56.0], "category_id": 3, "id": 3}, {"bbox": [663.5, 1235.5, 327.2, 262.4], "category_id": 1, "id": 4}, {"bbox": [64.9, 1241.1, 322.8, 269.4], "category_id": 1, "id": 5}, {"bbox": [61.8, 889.0, 329.3, 280.5], "category_id": 1, "id": 6}, {"bbox": [107.1, 532.0, 301.9, 256.0], "category_id": 1, "id": 7}, {"bbox": [716.8, 558.0, 321.2, 257.8], "category_id": 1, "id": 8}, {"bbox": [244.8, 1652.8, 869.6, 414.7], "category_id": 1, "id": 9}, {"bbox": [666.3, 897.0, 335.7, 264.2], "category_id": 1, "id": 10}, {"bbox": [1025.0, 1077.0, 262.0, 141.0], "category_id": 3, "id": 11}, {"bbox": [1025.0, 540.0, 258.9, 153.0], "category_id": 3, "id": 12}, {"bbox": [1029.0, 921.0, 256.8, 149.0], "category_id": 3, "id": 13}, {"bbox": [424.0, 1254.0, 242.0, 145.0], "category_id": 3, "id": 14}, {"bbox": [416.0, 1407.0, 254.0, 160.0], "category_id": 3, "id": 15}, {"bbox": [1025.0, 1246.0, 255.0, 149.0], "category_id": 3, "id": 16}, {"bbox": [1025.0, 1411.0, 251.0, 137.0], "category_id": 3, "id": 17}, {"bbox": [76.0, 293.0, 594.1, 193.0], "category_id": 3, "id": 18}, {"bbox": [420.0, 517.0, 258.0, 157.0], "category_id": 3, "id": 19}, {"bbox": [424.0, 1073.0, 254.0, 130.0], "category_id": 3, "id": 20}, {"bbox": [420.0, 897.0, 250.0, 149.0], "category_id": 3, "id": 21}, {"bbox": [1033.0, 721.0, 254.0, 156.0], "category_id": 3, "id": 22}, {"bbox": [420.0, 685.0, 246.0, 145.0], "category_id": 3, "id": 23}, {"bbox": [354.8, 143.71, 102.22, 52.5], "category_id": 1, "id": 24}, {"bbox": [357.56, 199.0, 234.84, 57.99], "category_id": 1, "id": 25}], "caption": "Figure 2. X-ray crystal structure of compound 5a.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 802, 687, 816], "ImageBB": [448, 257, 787, 793]}, "corefs": [[0, 2], [0, 18], [1, 3], [7, 19], [7, 23], [8, 12], [8, 22], [6, 21], [6, 20], [10, 13], [10, 11], [5, 14], [5, 15], [4, 16], [4, 17]]}, {"id": 870, "width": 1352, "height": 532, "file_name": "acs.oprd.5b00148-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [747.1, 57.0, 516.9, 266.0], "category_id": 1, "id": 0}, {"bbox": [313.0, 344.0, 35.0, 35.0], "category_id": 3, "id": 1}, {"bbox": [104.0, 37.0, 460.0, 293.0], "category_id": 1, "id": 2}, {"bbox": [969.0, 342.0, 26.0, 35.0], "category_id": 3, "id": 3}], "caption": "Figure 1. Tubulin-binding compounds.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 855, 272, 869], "ImageBB": [82, 712, 420, 845]}, "corefs": [[2, 1], [0, 3]]}, {"id": 871, "width": 1352, "height": 256, "file_name": "acs.oprd.5b00144-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [430.0, 30.0, 362.0, 226.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Lorcaserin (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 579, 203, 593], "ImageBB": [82, 506, 420, 570]}, "corefs": []}, {"id": 872, "width": 1356, "height": 584, "file_name": "acs.oprd.5b00137-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [400.0, 41.0, 560.0, 541.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Chemical structure of valsartan: (S)-N-(1-carboxy-2-methyl- prop-1-yl)-N-pentanoyl-N-[2\u2032-(1H-tetrazol-5-yl)biphenyl-4-ylmethyl]- amine. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 567, 784, 609], "ImageBB": [448, 412, 787, 558]}, "corefs": []}, {"id": 873, "width": 1352, "height": 340, "file_name": "acs.oprd.5b00027-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [397.0, 293.0, 41.0, 45.0], "category_id": 3, "id": 0}, {"bbox": [1081.0, 293.0, 56.0, 47.0], "category_id": 3, "id": 1}, {"bbox": [1.0, 36.0, 865.0, 274.0], "category_id": 1, "id": 2}, {"bbox": [896.3, 90.5, 451.7, 204.6], "category_id": 1, "id": 3}], "caption": "Figure 1. Brexpiprazole (1) and intermediate 18.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 596, 322, 610], "ImageBB": [82, 502, 420, 587]}, "corefs": [[2, 0], [3, 1]]}, {"id": 874, "width": 1356, "height": 496, "file_name": "acs.oprd.5b00023-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [538.0, 322.0, 490.0, 174.0], "category_id": 1, "id": 0}, {"bbox": [1094.0, 260.0, 34.0, 44.0], "category_id": 3, "id": 1}, {"bbox": [405.0, 34.0, 719.0, 272.0], "category_id": 1, "id": 2}, {"bbox": [1045.0, 449.0, 56.0, 47.0], "category_id": 3, "id": 3}], "caption": "Figure 6. Possible interaction of 1 and 10.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 341, 658, 355], "ImageBB": [448, 207, 787, 331]}, "corefs": [[2, 1], [0, 3]]}, {"id": 875, "width": 1352, "height": 1172, "file_name": "acs.joc.5b02057-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1026.0, 0.0, 326.0, 267.0], "category_id": 1, "id": 0}, {"bbox": [109.1, 233.5, 61.4, 44.5], "category_id": 3, "id": 1}, {"bbox": [1183.0, 232.0, 38.0, 43.4], "category_id": 3, "id": 2}, {"bbox": [950.0, 750.0, 279.0, 289.0], "category_id": 1, "id": 3}, {"bbox": [1.0, 29.0, 308.0, 179.0], "category_id": 1, "id": 4}, {"bbox": [419.0, 235.0, 59.0, 44.0], "category_id": 3, "id": 5}, {"bbox": [1058.0, 310.0, 291.0, 356.0], "category_id": 1, "id": 6}, {"bbox": [775.0, 320.0, 262.0, 361.0], "category_id": 1, "id": 7}, {"bbox": [425.0, 315.0, 304.0, 348.0], "category_id": 1, "id": 8}, {"bbox": [40.0, 314.0, 301.0, 354.0], "category_id": 1, "id": 9}, {"bbox": [492.0, 685.0, 206.0, 64.0], "category_id": 3, "id": 10}, {"bbox": [1137.0, 685.0, 215.0, 57.0], "category_id": 3, "id": 11}, {"bbox": [366.0, 79.3, 170.0, 146.8], "category_id": 1, "id": 12}, {"bbox": [41.6, 752.0, 277.9, 357.0], "category_id": 1, "id": 13}, {"bbox": [526.3, 752.0, 277.6, 328.0], "category_id": 1, "id": 14}, {"bbox": [85.0, 689.0, 221.0, 61.0], "category_id": 3, "id": 15}, {"bbox": [591.0, 1096.0, 205.0, 66.0], "category_id": 3, "id": 16}, {"bbox": [89.0, 1109.0, 217.0, 51.0], "category_id": 3, "id": 17}, {"bbox": [806.0, 686.0, 193.0, 62.0], "category_id": 3, "id": 18}, {"bbox": [1024.0, 1102.0, 219.0, 60.0], "category_id": 3, "id": 19}], "caption": "Table 3. Reaction Scope of Vinyl Azides 2 with Ynamides 1ba ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 248, 776, 278], "ImageBB": [448, 285, 786, 578]}, "corefs": [[4, 1], [12, 5], [0, 2], [9, 15], [8, 10], [7, 18], [6, 11], [13, 17], [14, 16], [3, 19]]}, {"id": 876, "width": 3396, "height": 1268, "file_name": "acs.joc.5b00763-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [931.0, 811.0, 793.0, 313.4], "category_id": 1, "id": 0}, {"bbox": [2098.0, 272.0, 447.0, 420.0], "category_id": 1, "id": 1}, {"bbox": [850.9, 374.8, 542.1, 290.3], "category_id": 1, "id": 2}, {"bbox": [1699.2, 843.0, 765.2, 331.2], "category_id": 1, "id": 3}, {"bbox": [1474.0, 324.0, 598.0, 386.3], "category_id": 1, "id": 4}], "caption": "Figure 1. Selected examples for bioactive C2-amidated indoles and pyrroles.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 348, 452, 362], "ImageBB": [10, 22, 859, 339]}, "corefs": []}, {"id": 877, "width": 1228, "height": 1264, "file_name": "acs.joc.5b00632-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [226.0, 829.0, 78.0, 67.0], "category_id": 3, "id": 0}, {"bbox": [222.0, 530.0, 85.0, 57.0], "category_id": 3, "id": 1}, {"bbox": [231.0, 1126.0, 71.0, 59.0], "category_id": 3, "id": 2}, {"bbox": [231.0, 206.0, 66.0, 58.0], "category_id": 3, "id": 3}, {"bbox": [637.7, 991.3, 463.1, 206.2], "category_id": 1, "id": 4}, {"bbox": [634.0, 700.0, 466.1, 210.0], "category_id": 1, "id": 5}, {"bbox": [681.3, 388.0, 376.2, 211.0], "category_id": 1, "id": 6}, {"bbox": [674.0, 71.0, 377.0, 208.3], "category_id": 1, "id": 7}], "caption": "Table 1. Active Clopidogrel Metabolite Stereochemical Assignment ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 447, 391, 477], "ImageBB": [97, 484, 404, 800]}, "corefs": [[7, 3], [6, 1], [5, 0], [4, 2]]}, {"id": 878, "width": 3396, "height": 2132, "file_name": "acs.joc.5b00632-Scheme-c12.png", "license": 0, "bboxes": [{"bbox": [859.7, 168.16, 74.67, 53.44], "category_id": 3, "id": 0}, {"bbox": [2255.1, 0.0, 356.03, 178.35], "category_id": 1, "id": 1}, {"bbox": [1330.2, 1623.82, 426.41, 207.22], "category_id": 1, "id": 2}, {"bbox": [1449.6, 1.82, 350.87, 181.83], "category_id": 1, "id": 3}, {"bbox": [1080.8, 480.74, 396.97, 202.32], "category_id": 1, "id": 4}, {"bbox": [1349.71, 644.65, 66.59, 51.22], "category_id": 3, "id": 5}, {"bbox": [2002.94, 1058.2, 69.66, 47.56], "category_id": 3, "id": 6}, {"bbox": [2002.94, 1532.09, 73.05, 47.56], "category_id": 3, "id": 7}, {"bbox": [2189.82, 762.65, 300.69, 210.62], "category_id": 1, "id": 8}, {"bbox": [960.43, 759.9, 302.21, 207.44], "category_id": 1, "id": 9}, {"bbox": [1247.27, 862.34, 478.92, 197.2], "category_id": 1, "id": 10}, {"bbox": [789.96, 1623.82, 382.25, 207.22], "category_id": 1, "id": 11}, {"bbox": [650.66, 1318.08, 455.29, 207.22], "category_id": 1, "id": 12}, {"bbox": [1775.3, 854.37, 366.95, 207.23], "category_id": 1, "id": 13}, {"bbox": [1547.65, 460.31, 321.08, 253.08], "category_id": 1, "id": 14}, {"bbox": [2482.02, 164.76, 62.86, 56.05], "category_id": 3, "id": 15}, {"bbox": [939.46, 1810.66, 66.26, 54.35], "category_id": 3, "id": 16}, {"bbox": [789.96, 1058.2, 69.66, 56.05], "category_id": 3, "id": 17}, {"bbox": [1676.76, 171.55, 62.86, 50.96], "category_id": 3, "id": 18}, {"bbox": [735.6, 0.0, 244.64, 183.44], "category_id": 1, "id": 19}, {"bbox": [1411.74, 1795.37, 83.25, 56.05], "category_id": 3, "id": 20}, {"bbox": [840.93, 1503.22, 61.16, 56.05], "category_id": 3, "id": 21}, {"bbox": [2592.44, 1564.37, 76.45, 56.05], "category_id": 3, "id": 22}, {"bbox": [2383.49, 1350.35, 385.63, 210.62], "category_id": 1, "id": 23}, {"bbox": [1248.0, 1324.87, 488.22, 207.22], "category_id": 1, "id": 24}, {"bbox": [1494.99, 1058.2, 71.35, 52.65], "category_id": 3, "id": 25}, {"bbox": [567.42, 901.93, 385.63, 154.57], "category_id": 1, "id": 26}, {"bbox": [1885.72, 470.5, 366.95, 224.21], "category_id": 1, "id": 27}, {"bbox": [1783.79, 1324.87, 389.04, 215.72], "category_id": 1, "id": 28}, {"bbox": [2482.02, 859.47, 344.87, 200.43], "category_id": 1, "id": 29}, {"bbox": [2189.82, 762.65, 300.69, 212.32], "category_id": 1, "id": 30}, {"bbox": [2650.21, 1056.5, 76.44, 54.35], "category_id": 3, "id": 31}], "caption": "Scheme 12. Stereocontrolled Preparation of Clopidogrel Metabolite Thioacetate Intermediates", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 562, 613, 577], "ImageBB": [10, 594, 859, 1127]}, "diagram_type": "tree", "corefs": [[19, 0], [3, 18], [1, 15], [4, 5], [29, 31], [13, 6], [10, 25], [26, 17], [12, 21], [28, 7], [23, 22], [11, 16], [2, 20]]}, {"id": 879, "width": 2820, "height": 928, "file_name": "acs.joc.5b00685-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1026.99, 831.67, 452.84, 56.39], "category_id": 3, "id": 0}, {"bbox": [1709.77, 73.3, 534.66, 262.19], "category_id": 1, "id": 1}, {"bbox": [670.09, 556.8, 270.85, 102.9], "category_id": 1, "id": 2}, {"bbox": [1190.64, 339.72, 153.76, 56.38], "category_id": 3, "id": 3}, {"bbox": [623.53, 342.54, 59.25, 47.92], "category_id": 3, "id": 4}, {"bbox": [1471.37, 80.35, 191.85, 102.9], "category_id": 1, "id": 5}, {"bbox": [507.85, 125.46, 304.72, 201.57], "category_id": 1, "id": 6}, {"bbox": [983.26, 534.24, 605.19, 298.84], "category_id": 1, "id": 7}, {"bbox": [1139.85, 118.41, 300.48, 197.34], "category_id": 1, "id": 8}], "caption": "Scheme 1. Strategy for Synthesis of 11C-Labeled Thiamine [11C]-1 (vitamin B1) and Fursultiamine [11C]-2 (a prodrug of vitamin B1) ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 784, 126], "ImageBB": [82, 131, 787, 363]}, "diagram_type": "multiple", "corefs": [[6, 4], [8, 3], [7, 0]]}, {"id": 880, "width": 2820, "height": 676, "file_name": "acs.joc.5b01547-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [643.28, 229.62, 57.84, 53.53], "category_id": 3, "id": 0}, {"bbox": [1965.11, 5.63, 320.23, 190.17], "category_id": 1, "id": 1}, {"bbox": [2122.4, 239.21, 91.45, 72.31], "category_id": 1, "id": 2}, {"bbox": [529.01, 8.45, 344.22, 188.77], "category_id": 1, "id": 3}, {"bbox": [1423.4, 228.21, 62.07, 49.3], "category_id": 3, "id": 4}, {"bbox": [1323.24, 12.68, 324.46, 184.54], "category_id": 1, "id": 5}, {"bbox": [1262.58, 580.38, 153.77, 52.12], "category_id": 3, "id": 6}, {"bbox": [1602.56, 259.2, 335.75, 211.3], "category_id": 1, "id": 7}, {"bbox": [1086.24, 349.35, 438.73, 219.76], "category_id": 1, "id": 8}, {"bbox": [1965.11, 397.25, 313.18, 184.54], "category_id": 1, "id": 9}], "caption": "Scheme 2. Formation of 4 with Excess Sodium Trichloroacetate", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 442, 110], "ImageBB": [82, 116, 787, 285]}, "diagram_type": "tree", "corefs": [[3, 0], [5, 4], [8, 6]]}, {"id": 881, "width": 1352, "height": 1248, "file_name": "acs.joc.5b01703-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [406.48, 774.7, 443.0, 332.2], "category_id": 1, "id": 0}, {"bbox": [160.29, 1088.64, 48.02, 44.65], "category_id": 3, "id": 1}, {"bbox": [721.65, 342.36, 509.29, 96.07], "category_id": 3, "id": 2}, {"bbox": [231.31, 322.73, 31.79, 45.34], "category_id": 3, "id": 3}, {"bbox": [160.29, 506.09, 204.26, 176.59], "category_id": 1, "id": 4}, {"bbox": [156.23, 692.15, 206.29, 48.72], "category_id": 3, "id": 5}, {"bbox": [14.88, 783.49, 382.13, 347.77], "category_id": 1, "id": 6}, {"bbox": [881.94, 767.93, 441.65, 365.36], "category_id": 1, "id": 7}, {"bbox": [973.25, 1149.53, 248.22, 48.04], "category_id": 3, "id": 8}, {"bbox": [1091.61, 396.48, 260.39, 200.27], "category_id": 1, "id": 9}, {"bbox": [827.84, 8.8, 367.25, 325.44], "category_id": 1, "id": 10}, {"bbox": [567.45, 1075.1, 51.4, 46.69], "category_id": 3, "id": 11}, {"bbox": [491.7, 2.03, 204.25, 138.02], "category_id": 1, "id": 12}, {"bbox": [0.0, 18.27, 428.8, 334.91], "category_id": 1, "id": 13}], "caption": "Scheme 1. First Generation Synthesis of Naamidine A and Analogues ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 357, 412, 387], "ImageBB": [82, 394, 420, 706]}, "diagram_type": "tree", "corefs": [[13, 3], [10, 2], [4, 5], [6, 1], [0, 11], [7, 8]]}, {"id": 882, "width": 1356, "height": 1248, "file_name": "acs.joc.5b02057-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 417.8, 259.13, 250.95], "category_id": 1, "id": 0}, {"bbox": [0.0, 80.03, 223.85, 235.35], "category_id": 1, "id": 1}, {"bbox": [717.0, 86.14, 163.48, 212.29], "category_id": 1, "id": 2}, {"bbox": [438.21, 785.41, 181.79, 124.12], "category_id": 1, "id": 3}, {"bbox": [1095.52, 425.26, 260.48, 193.3], "category_id": 1, "id": 4}, {"bbox": [14.92, 760.31, 213.68, 191.95], "category_id": 1, "id": 5}, {"bbox": [987.66, 97.67, 189.26, 212.97], "category_id": 1, "id": 6}, {"bbox": [335.78, 89.53, 241.49, 211.61], "category_id": 1, "id": 7}, {"bbox": [363.59, 419.83, 256.41, 218.4], "category_id": 1, "id": 8}, {"bbox": [704.79, 1077.73, 188.58, 114.63], "category_id": 1, "id": 9}, {"bbox": [743.46, 419.83, 259.13, 191.95], "category_id": 1, "id": 10}, {"bbox": [438.21, 1094.01, 175.01, 108.52], "category_id": 1, "id": 11}, {"bbox": [704.79, 798.97, 191.97, 118.02], "category_id": 1, "id": 12}], "caption": "Scheme 1. Gold-Catalyzed Reactions of Organic Azides with Alkynes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 535, 784, 565], "ImageBB": [448, 572, 787, 884]}, "diagram_type": "graph", "corefs": []}, {"id": 883, "width": 1356, "height": 396, "file_name": "acs.joc.5b02237-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [671.56, 8.82, 285.58, 286.47], "category_id": 1, "id": 0}, {"bbox": [166.19, 4.07, 287.62, 263.39], "category_id": 1, "id": 1}, {"bbox": [789.59, 306.15, 57.66, 46.84], "category_id": 3, "id": 2}, {"bbox": [287.62, 306.15, 50.87, 43.45], "category_id": 3, "id": 3}], "caption": "Scheme 7. Proposed Mechanism of the Photorearrangement", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 563, 784, 578], "ImageBB": [448, 584, 787, 683]}, "diagram_type": "single", "corefs": [[1, 3], [0, 2]]}, {"id": 884, "width": 1352, "height": 1008, "file_name": "acs.joc.5b02382-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [100.1, 412.5, 65.6, 48.69], "category_id": 3, "id": 0}, {"bbox": [292.18, 757.37, 264.45, 111.58], "category_id": 1, "id": 1}, {"bbox": [406.48, 411.82, 60.19, 48.01], "category_id": 3, "id": 2}, {"bbox": [909.0, 6.09, 358.46, 116.31], "category_id": 1, "id": 3}, {"bbox": [42.61, 259.67, 147.44, 152.83], "category_id": 1, "id": 4}, {"bbox": [401.07, 862.86, 35.84, 42.61], "category_id": 3, "id": 5}, {"bbox": [1038.86, 871.65, 58.16, 39.9], "category_id": 3, "id": 6}, {"bbox": [0.0, 48.69, 214.4, 114.28], "category_id": 1, "id": 7}, {"bbox": [388.89, 111.58, 36.53, 39.89], "category_id": 3, "id": 8}, {"bbox": [100.1, 449.69, 472.08, 244.12], "category_id": 1, "id": 9}, {"bbox": [77.78, 891.27, 53.43, 40.57], "category_id": 3, "id": 10}, {"bbox": [601.94, 452.39, 281.36, 242.77], "category_id": 1, "id": 11}, {"bbox": [894.8, 454.42, 290.14, 240.06], "category_id": 1, "id": 12}, {"bbox": [325.32, 284.69, 212.37, 108.87], "category_id": 1, "id": 13}, {"bbox": [77.78, 140.65, 39.23, 37.2], "category_id": 3, "id": 14}, {"bbox": [12.85, 797.27, 213.05, 117.66], "category_id": 1, "id": 15}, {"bbox": [912.38, 754.67, 366.58, 120.37], "category_id": 1, "id": 16}, {"bbox": [1034.8, 121.04, 50.05, 37.2], "category_id": 3, "id": 17}, {"bbox": [284.06, 12.17, 259.72, 102.79], "category_id": 1, "id": 18}], "caption": "Scheme 2. Unexpected Zn(OTf)2-catalyzed cycloisomerization/allylic alkylation cascade to synthesize oxazoles ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 406, 140], "ImageBB": [82, 146, 420, 398]}, "diagram_type": "graph", "corefs": [[7, 14], [18, 8], [3, 17], [4, 0], [13, 2], [15, 10], [1, 5], [16, 6]]}, {"id": 885, "width": 1352, "height": 1264, "file_name": "acs.joc.6b01262-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 611.53, 238.75, 171.82], "category_id": 1, "id": 0}, {"bbox": [310.44, 654.14, 170.44, 126.5], "category_id": 1, "id": 1}, {"bbox": [16.23, 117.03, 233.34, 165.06], "category_id": 1, "id": 2}, {"bbox": [826.49, 627.08, 306.38, 171.83], "category_id": 1, "id": 3}, {"bbox": [16.23, 1001.17, 294.89, 161.68], "category_id": 1, "id": 4}, {"bbox": [787.26, 987.64, 305.03, 171.15], "category_id": 1, "id": 5}, {"bbox": [856.24, 347.7, 304.36, 168.44], "category_id": 1, "id": 6}, {"bbox": [938.76, 97.41, 305.7, 169.79], "category_id": 1, "id": 7}, {"bbox": [16.23, 375.44, 228.6, 168.44], "category_id": 1, "id": 8}], "caption": "Scheme 1. Di\ufb00erent Approaches to Primary \u03b1-Ketoamides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 367, 411, 387], "ImageBB": [82, 392, 420, 708]}, "diagram_type": "multiple", "corefs": []}, {"id": 886, "width": 3396, "height": 1036, "file_name": "acs.oprd.5b00027-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [2296.84, 711.21, 73.05, 54.31], "category_id": 3, "id": 0}, {"bbox": [852.82, 476.97, 490.97, 224.05], "category_id": 1, "id": 1}, {"bbox": [2004.64, 432.4, 550.43, 268.62], "category_id": 1, "id": 2}, {"bbox": [927.57, 290.25, 71.35, 54.32], "category_id": 3, "id": 3}, {"bbox": [1211.28, 22.07, 458.69, 247.82], "category_id": 1, "id": 4}, {"bbox": [1505.18, 290.25, 66.26, 50.93], "category_id": 3, "id": 5}, {"bbox": [2002.94, 0.0, 552.13, 268.19], "category_id": 1, "id": 6}, {"bbox": [2288.3, 290.25, 52.71, 50.93], "category_id": 3, "id": 7}, {"bbox": [840.93, 42.43, 253.13, 218.97], "category_id": 1, "id": 8}, {"bbox": [1088.96, 714.6, 57.76, 50.92], "category_id": 3, "id": 9}], "caption": "Scheme 2. Improved synthetic route for 4-(1-piperazinyl)benzo[b]thiophene dihydrochloride (18)", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 836, 634, 851], "ImageBB": [10, 868, 859, 1127]}, "diagram_type": "graph", "corefs": [[8, 3], [4, 5], [6, 7], [1, 9], [2, 0]]}, {"id": 887, "width": 1416, "height": 632, "file_name": "acs.oprd.5b00209-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [1103.62, 534.77, 59.5, 50.29], "category_id": 3, "id": 0}, {"bbox": [609.18, 247.2, 51.01, 49.58], "category_id": 3, "id": 1}, {"bbox": [955.57, 366.19, 398.09, 148.04], "category_id": 1, "id": 2}, {"bbox": [424.3, 60.91, 294.68, 161.5], "category_id": 1, "id": 3}], "caption": "Scheme 10. Current Sulfamoylation Process", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 330, 110], "ImageBB": [82, 116, 436, 274]}, "diagram_type": "multiple", "corefs": [[3, 1], [2, 0]]}, {"id": 888, "width": 2820, "height": 1260, "file_name": "acs.oprd.5b00209-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [2065.27, 38.06, 362.55, 131.11], "category_id": 1, "id": 0}, {"bbox": [2254.31, 631.57, 84.64, 66.26], "category_id": 3, "id": 1}, {"bbox": [1747.86, 642.85, 77.59, 62.02], "category_id": 3, "id": 2}, {"bbox": [2086.43, 473.68, 420.39, 128.28], "category_id": 1, "id": 3}, {"bbox": [732.16, 446.89, 397.81, 184.68], "category_id": 1, "id": 4}, {"bbox": [933.57, 256.86, 274.35, 44.66], "category_id": 3, "id": 5}, {"bbox": [1892.71, 254.73, 340.28, 59.55], "category_id": 3, "id": 6}, {"bbox": [1709.77, 824.7, 393.59, 208.65], "category_id": 1, "id": 7}, {"bbox": [1582.81, 441.25, 421.8, 193.14], "category_id": 1, "id": 8}, {"bbox": [933.9, 190.3, 336.0, 64.2], "category_id": 3, "id": 9}, {"bbox": [897.21, 649.89, 83.23, 63.44], "category_id": 3, "id": 10}, {"bbox": [1052.39, 43.7, 393.58, 125.47], "category_id": 1, "id": 11}, {"bbox": [1880.47, 1046.03, 53.61, 52.16], "category_id": 3, "id": 12}, {"bbox": [310.36, 0.0, 187.62, 208.64], "category_id": 1, "id": 13}, {"bbox": [732.16, 851.49, 411.92, 190.31], "category_id": 1, "id": 14}, {"bbox": [640.46, 1151.76, 271.14, 62.04], "category_id": 3, "id": 15}, {"bbox": [1891.76, 190.3, 352.67, 55.3], "category_id": 3, "id": 16}, {"bbox": [378.9, 243.9, 54.1, 57.7], "category_id": 3, "id": 17}, {"bbox": [644.69, 1097.5, 318.51, 56.0], "category_id": 3, "id": 18}], "caption": "Scheme 3. Synthesis of Amino Diol 4 though Sharpless Epoxidation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 465, 110], "ImageBB": [82, 116, 787, 431]}, "diagram_type": "multiple", "corefs": [[13, 17], [11, 9], [11, 5], [0, 16], [0, 6], [4, 10], [8, 2], [3, 1], [14, 18], [14, 15], [7, 12]]}, {"id": 889, "width": 2820, "height": 772, "file_name": "acs.oprd.5b00209-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1721.06, 678.4, 125.55, 52.19], "category_id": 3, "id": 0}, {"bbox": [602.37, 307.47, 64.89, 49.36], "category_id": 3, "id": 1}, {"bbox": [1967.93, 76.16, 424.63, 187.58], "category_id": 1, "id": 2}, {"bbox": [730.75, 471.07, 479.64, 196.05], "category_id": 1, "id": 3}, {"bbox": [918.37, 681.22, 63.48, 49.37], "category_id": 3, "id": 4}, {"bbox": [1388.13, 307.47, 66.31, 46.54], "category_id": 3, "id": 5}, {"bbox": [1227.31, 67.7, 389.36, 210.15], "category_id": 1, "id": 6}, {"bbox": [427.44, 80.39, 420.39, 184.76], "category_id": 1, "id": 7}, {"bbox": [2154.15, 306.06, 55.01, 49.36], "category_id": 3, "id": 8}, {"bbox": [1548.95, 483.77, 475.41, 166.42], "category_id": 1, "id": 9}], "caption": "Scheme 4. Current Manufacturing Process of Amino-Diol Intermediate 4-HBr", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 438, 522, 453], "ImageBB": [82, 459, 787, 652]}, "diagram_type": "multiple", "corefs": [[7, 1], [6, 5], [2, 8], [3, 4], [9, 0]]}, {"id": 890, "width": 1416, "height": 1540, "file_name": "acs.oprd.6b00011-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1104.43, 1103.96, 311.57, 356.69], "category_id": 1, "id": 0}, {"bbox": [425.14, 1064.67, 392.79, 429.11], "category_id": 1, "id": 1}, {"bbox": [1335.49, 1449.09, 41.59, 47.0], "category_id": 3, "id": 2}, {"bbox": [970.42, 0.0, 319.63, 341.28], "category_id": 1, "id": 3}, {"bbox": [652.34, 1449.09, 36.2, 43.92], "category_id": 3, "id": 4}, {"bbox": [969.65, 812.76, 53.91, 55.46], "category_id": 3, "id": 5}, {"bbox": [469.81, 62.4, 267.25, 235.74], "category_id": 1, "id": 6}, {"bbox": [566.85, 318.94, 33.12, 40.06], "category_id": 3, "id": 7}, {"bbox": [744.76, 413.7, 396.64, 452.98], "category_id": 1, "id": 8}, {"bbox": [1121.38, 317.4, 41.59, 43.91], "category_id": 3, "id": 9}, {"bbox": [789.43, 28.5, 125.54, 142.53], "category_id": 1, "id": 10}], "caption": "Scheme 1. Discovery Chemistry Synthesis of GDC-0084", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 398, 110], "ImageBB": [82, 124, 436, 509]}, "diagram_type": "multiple", "corefs": [[6, 7], [3, 9], [8, 5], [1, 4], [0, 2]]}, {"id": 891, "width": 1356, "height": 616, "file_name": "acs.orglett.5b00663-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [341.88, 410.09, 162.02, 50.84], "category_id": 1, "id": 0}, {"bbox": [613.54, 208.27, 261.79, 128.85], "category_id": 1, "id": 1}, {"bbox": [589.48, 14.91, 266.58, 130.83], "category_id": 1, "id": 2}, {"bbox": [904.9, 205.38, 169.59, 133.54], "category_id": 1, "id": 3}, {"bbox": [980.2, 338.24, 33.24, 33.21], "category_id": 3, "id": 4}, {"bbox": [157.37, 530.75, 39.35, 31.18], "category_id": 3, "id": 5}, {"bbox": [652.56, 336.89, 104.47, 38.63], "category_id": 3, "id": 6}, {"bbox": [77.33, 437.21, 235.38, 84.72], "category_id": 1, "id": 7}, {"bbox": [890.66, 68.46, 167.55, 56.26], "category_id": 1, "id": 8}, {"bbox": [674.95, 140.31, 45.45, 31.18], "category_id": 3, "id": 9}, {"bbox": [636.28, 399.25, 259.13, 128.11], "category_id": 1, "id": 10}, {"bbox": [674.95, 530.07, 99.71, 32.53], "category_id": 3, "id": 11}, {"bbox": [379.19, 199.96, 139.74, 84.05], "category_id": 1, "id": 12}, {"bbox": [951.71, 414.84, 200.79, 98.28], "category_id": 1, "id": 13}, {"bbox": [341.88, 4.07, 198.08, 93.54], "category_id": 1, "id": 14}, {"bbox": [75.97, 47.45, 236.74, 86.76], "category_id": 1, "id": 15}, {"bbox": [75.97, 240.63, 236.07, 86.77], "category_id": 1, "id": 16}, {"bbox": [157.37, 335.53, 40.71, 31.86], "category_id": 3, "id": 17}, {"bbox": [157.37, 137.6, 38.67, 31.86], "category_id": 3, "id": 18}], "caption": "Scheme 2. Investigations of the Role of Ester", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 699, 110], "ImageBB": [448, 116, 787, 270]}, "diagram_type": "multiple", "corefs": [[15, 18], [2, 9], [16, 17], [1, 6], [3, 4], [7, 5], [10, 11]]}, {"id": 892, "width": 1356, "height": 1304, "file_name": "acs.orglett.5b00776-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [328.99, 312.69, 45.45, 56.97], "category_id": 3, "id": 0}, {"bbox": [586.76, 308.62, 56.31, 59.01], "category_id": 3, "id": 1}, {"bbox": [609.83, 1209.37, 64.44, 50.87], "category_id": 3, "id": 2}, {"bbox": [951.71, 595.53, 385.97, 383.9], "category_id": 1, "id": 3}, {"bbox": [476.19, 425.28, 297.12, 271.99], "category_id": 1, "id": 4}, {"bbox": [499.26, 871.59, 294.4, 337.78], "category_id": 1, "id": 5}, {"bbox": [46.13, 843.78, 269.3, 361.52], "category_id": 1, "id": 6}, {"bbox": [1177.6, 314.72, 49.52, 54.26], "category_id": 3, "id": 7}, {"bbox": [819.43, 315.4, 63.77, 54.26], "category_id": 3, "id": 8}, {"bbox": [136.35, 1199.19, 50.87, 48.84], "category_id": 3, "id": 9}, {"bbox": [951.71, 0.0, 381.23, 312.01], "category_id": 1, "id": 10}, {"bbox": [770.29, 9.33, 164.37, 299.0], "category_id": 1, "id": 11}, {"bbox": [550.13, 14.92, 140.67, 231.58], "category_id": 1, "id": 12}, {"bbox": [22.39, 18.31, 124.81, 234.01], "category_id": 1, "id": 13}, {"bbox": [48.16, 440.2, 290.33, 264.53], "category_id": 1, "id": 14}, {"bbox": [608.47, 707.44, 60.37, 61.73], "category_id": 3, "id": 15}, {"bbox": [1207.1, 435.2, 62.7, 66.4], "category_id": 1, "id": 16}, {"bbox": [63.09, 308.62, 61.05, 61.04], "category_id": 3, "id": 17}, {"bbox": [1178.95, 986.89, 48.17, 54.26], "category_id": 3, "id": 18}, {"bbox": [299.15, 25.1, 147.88, 235.36], "category_id": 1, "id": 19}, {"bbox": [136.35, 707.44, 54.94, 56.98], "category_id": 3, "id": 20}], "caption": "Scheme 5. Plausible Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 630, 110], "ImageBB": [448, 116, 787, 442]}, "diagram_type": "tree", "corefs": [[13, 17], [19, 0], [12, 1], [11, 8], [10, 7], [14, 20], [4, 15], [3, 18], [6, 9], [5, 2]]}, {"id": 893, "width": 1352, "height": 500, "file_name": "acs.orglett.5b01044-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [85.89, 61.54, 190.73, 136.62], "category_id": 1, "id": 0}, {"bbox": [733.15, 4.06, 199.52, 256.32], "category_id": 1, "id": 1}, {"bbox": [498.46, 236.71, 309.76, 217.09], "category_id": 1, "id": 2}, {"bbox": [1064.56, 29.08, 202.9, 204.92], "category_id": 1, "id": 3}, {"bbox": [420.68, 2.71, 190.73, 256.99], "category_id": 1, "id": 4}, {"bbox": [653.34, 399.02, 211.7, 47.34], "category_id": 3, "id": 5}], "caption": "Scheme 1. Reported Fu\u2019s Original Synthesis of Planar-Chiral Ferrocene-Fused 4-Dialkylaminopyridines 1 ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 787, 417, 817], "ImageBB": [82, 823, 420, 948]}, "diagram_type": "multiple", "corefs": [[2, 5]]}, {"id": 894, "width": 1352, "height": 1408, "file_name": "acs.orglett.5b01044-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [902.97, 717.03, 331.74, 285.26], "category_id": 1, "id": 0}, {"bbox": [198.62, 950.88, 238.78, 90.86], "category_id": 3, "id": 1}, {"bbox": [607.85, 953.69, 243.7, 87.34], "category_id": 3, "id": 2}, {"bbox": [674.06, 640.96, 55.64, 39.04], "category_id": 3, "id": 3}, {"bbox": [488.11, 1044.55, 374.01, 312.74], "category_id": 1, "id": 4}, {"bbox": [185.24, 291.6, 214.83, 84.52], "category_id": 3, "id": 5}, {"bbox": [962.13, 111.99, 299.35, 226.8], "category_id": 1, "id": 6}, {"bbox": [197.92, 1310.8, 238.07, 50.71], "category_id": 3, "id": 7}, {"bbox": [1067.08, 643.07, 47.89, 38.74], "category_id": 3, "id": 8}, {"bbox": [185.24, 645.19, 100.02, 42.26], "category_id": 3, "id": 9}, {"bbox": [900.85, 1125.55, 360.63, 231.74], "category_id": 1, "id": 10}, {"bbox": [490.93, 737.46, 319.77, 266.24], "category_id": 1, "id": 11}, {"bbox": [612.07, 1313.62, 220.46, 51.41], "category_id": 3, "id": 12}, {"bbox": [534.6, 460.65, 295.12, 221.16], "category_id": 1, "id": 13}, {"bbox": [89.45, 111.99, 269.06, 226.8], "category_id": 1, "id": 14}, {"bbox": [926.21, 460.65, 296.53, 223.98], "category_id": 1, "id": 15}, {"bbox": [1012.14, 953.69, 245.82, 86.64], "category_id": 3, "id": 16}, {"bbox": [1086.1, 293.71, 86.63, 45.79], "category_id": 3, "id": 17}, {"bbox": [87.34, 1129.08, 324.7, 229.62], "category_id": 1, "id": 18}, {"bbox": [88.04, 460.65, 284.56, 221.16], "category_id": 1, "id": 19}, {"bbox": [87.34, 778.31, 326.11, 225.39], "category_id": 1, "id": 20}, {"bbox": [1012.84, 1310.1, 238.78, 53.53], "category_id": 3, "id": 21}, {"bbox": [525.44, 116.22, 260.61, 222.57], "category_id": 1, "id": 22}, {"bbox": [638.8, 289.08, 141.99, 43.95], "category_id": 3, "id": 23}], "caption": "Scheme 5. Conversion of Pyridones 2 to Pyridine Derivatives", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 110], "ImageBB": [82, 116, 420, 468]}, "diagram_type": "graph", "corefs": [[14, 5], [22, 23], [6, 17], [19, 9], [13, 3], [15, 8], [20, 1], [11, 2], [0, 16], [18, 7], [4, 12], [10, 21]]}, {"id": 895, "width": 1356, "height": 1092, "file_name": "acs.orglett.5b01309-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [209.61, 1009.14, 37.31, 38.68], "category_id": 3, "id": 0}, {"bbox": [959.17, 416.69, 392.76, 242.27], "category_id": 1, "id": 1}, {"bbox": [495.87, 259.24, 43.41, 46.15], "category_id": 3, "id": 2}, {"bbox": [754.99, 29.18, 395.47, 233.45], "category_id": 1, "id": 3}, {"bbox": [707.51, 662.35, 73.26, 42.76], "category_id": 3, "id": 4}, {"bbox": [871.67, 274.85, 202.82, 40.04], "category_id": 3, "id": 5}, {"bbox": [510.79, 394.97, 389.37, 241.6], "category_id": 1, "id": 6}, {"bbox": [1117.22, 682.71, 78.01, 38.01], "category_id": 3, "id": 7}, {"bbox": [175.69, 272.14, 94.29, 44.11], "category_id": 3, "id": 8}, {"bbox": [5.51, 56.37, 381.47, 208.44], "category_id": 1, "id": 9}, {"bbox": [105.14, 634.53, 71.23, 37.32], "category_id": 3, "id": 10}, {"bbox": [439.56, 50.9, 194.69, 168.3], "category_id": 1, "id": 11}, {"bbox": [12.89, 407.86, 391.4, 265.35], "category_id": 1, "id": 12}, {"bbox": [47.48, 785.87, 373.77, 218.52], "category_id": 1, "id": 13}], "caption": "Scheme 6. Zwitterion Formation in \u03b2-Lactam Formation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 170, 768, 190], "ImageBB": [448, 196, 787, 469]}, "diagram_type": "tree", "corefs": [[9, 8], [11, 2], [3, 5], [1, 7], [6, 4], [12, 10], [13, 0]]}, {"id": 896, "width": 1356, "height": 1492, "file_name": "acs.orglett.5b01692-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [16.43, 1192.7, 333.01, 188.84], "category_id": 1, "id": 0}, {"bbox": [1027.43, 276.16, 266.56, 247.79], "category_id": 1, "id": 1}, {"bbox": [817.61, 11.94, 123.95, 164.95], "category_id": 1, "id": 2}, {"bbox": [369.61, 765.78, 182.49, 254.72], "category_id": 1, "id": 3}, {"bbox": [516.7, 325.42, 380.06, 178.38], "category_id": 1, "id": 4}, {"bbox": [487.58, 29.11, 220.27, 115.69], "category_id": 1, "id": 5}, {"bbox": [992.33, 744.13, 246.41, 258.25], "category_id": 1, "id": 6}, {"bbox": [53.76, 338.85, 342.73, 170.92], "category_id": 1, "id": 7}, {"bbox": [935.59, 1194.94, 330.77, 204.51], "category_id": 1, "id": 8}, {"bbox": [34.92, 814.95, 207.77, 111.05], "category_id": 1, "id": 9}], "caption": "Scheme 1. Strategies for NHC-Catalyzed Reactions of Enals with Nitroalkenes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 462, 780, 492], "ImageBB": [448, 498, 787, 871]}, "diagram_type": "graph", "corefs": []}, {"id": 897, "width": 1356, "height": 652, "file_name": "acs.orglett.5b01872-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [274.73, 77.7, 414.77, 213.28], "category_id": 1, "id": 0}, {"bbox": [917.79, 38.66, 419.89, 249.61], "category_id": 1, "id": 1}, {"bbox": [525.71, 220.44, 51.56, 46.8], "category_id": 3, "id": 2}, {"bbox": [381.9, 352.7, 254.38, 141.09], "category_id": 1, "id": 3}, {"bbox": [1170.14, 221.12, 48.84, 46.12], "category_id": 3, "id": 4}, {"bbox": [507.4, 478.19, 40.7, 40.69], "category_id": 3, "id": 5}, {"bbox": [246.92, 475.47, 59.01, 48.16], "category_id": 3, "id": 6}, {"bbox": [79.37, 341.17, 272.01, 169.57], "category_id": 1, "id": 7}, {"bbox": [733.28, 6.1, 189.94, 56.3], "category_id": 1, "id": 8}], "caption": "Scheme 3. Synthesis of the Divinyl Intermediate", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 722, 110], "ImageBB": [448, 116, 787, 279]}, "diagram_type": "tree", "corefs": [[0, 2], [1, 4], [7, 6], [3, 5]]}, {"id": 898, "width": 1356, "height": 1100, "file_name": "acs.orglett.5b01872-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [847.25, 452.6, 442.95, 219.17], "category_id": 1, "id": 0}, {"bbox": [375.8, 187.96, 40.7, 46.82], "category_id": 3, "id": 1}, {"bbox": [120.07, 422.06, 441.59, 248.35], "category_id": 1, "id": 2}, {"bbox": [492.47, 727.41, 252.35, 243.6], "category_id": 1, "id": 3}, {"bbox": [847.25, 35.28, 423.28, 217.14], "category_id": 1, "id": 4}, {"bbox": [1098.91, 190.67, 53.59, 45.47], "category_id": 3, "id": 5}, {"bbox": [375.8, 607.98, 50.88, 44.79], "category_id": 3, "id": 6}, {"bbox": [1098.91, 606.63, 54.94, 48.85], "category_id": 3, "id": 7}, {"bbox": [122.1, 4.07, 419.89, 248.35], "category_id": 1, "id": 8}], "caption": "Scheme 4. Construction of Naphthopyrazine by RCM", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 500, 753, 515], "ImageBB": [448, 521, 787, 796]}, "diagram_type": "tree", "corefs": [[8, 1], [4, 5], [2, 6], [0, 7]]}, {"id": 899, "width": 1356, "height": 572, "file_name": "acs.orglett.5b02279-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [487.73, 477.8, 210.28, 48.19], "category_id": 3, "id": 0}, {"bbox": [487.73, 312.88, 262.51, 149.99], "category_id": 1, "id": 1}, {"bbox": [487.73, 194.11, 232.67, 52.94], "category_id": 3, "id": 2}, {"bbox": [480.94, 6.79, 276.09, 175.1], "category_id": 1, "id": 3}, {"bbox": [912.37, 409.93, 345.95, 51.59], "category_id": 3, "id": 4}, {"bbox": [43.41, 295.23, 288.98, 158.82], "category_id": 1, "id": 5}, {"bbox": [41.38, 0.0, 271.33, 183.25], "category_id": 1, "id": 6}, {"bbox": [912.37, 132.35, 401.57, 270.8], "category_id": 1, "id": 7}], "caption": "Scheme 1. Proposed [4 + 3] Cycloadditions of in situ Generated Allylic Ylides and Aza-o-quinone Methides ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 599, 754, 629], "ImageBB": [448, 636, 787, 779]}, "diagram_type": "tree", "corefs": [[3, 2], [7, 4], [1, 0]]}, {"id": 900, "width": 1352, "height": 788, "file_name": "acs.orglett.5b02709-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [672.96, 89.27, 343.58, 231.28], "category_id": 1, "id": 0}, {"bbox": [1092.29, 672.89, 162.32, 61.54], "category_id": 1, "id": 1}, {"bbox": [4.06, 511.26, 371.98, 223.17], "category_id": 1, "id": 2}, {"bbox": [1137.6, 502.47, 154.88, 147.43], "category_id": 1, "id": 3}, {"bbox": [309.76, 607.97, 163.68, 123.08], "category_id": 1, "id": 4}, {"bbox": [709.48, 504.5, 156.23, 235.34], "category_id": 1, "id": 5}, {"bbox": [25.7, 0.0, 564.07, 461.89], "category_id": 1, "id": 6}, {"bbox": [879.24, 273.89, 39.23, 48.02], "category_id": 3, "id": 7}, {"bbox": [193.43, 695.89, 38.55, 39.22], "category_id": 3, "id": 8}, {"bbox": [1123.4, 600.53, 40.58, 45.99], "category_id": 3, "id": 9}, {"bbox": [838.66, 701.3, 33.82, 41.25], "category_id": 3, "id": 10}, {"bbox": [329.38, 403.74, 205.6, 45.98], "category_id": 3, "id": 11}], "caption": "Scheme 1. Retrosynthetic Analysis", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 276, 110], "ImageBB": [82, 116, 420, 313]}, "diagram_type": "multiple", "corefs": [[6, 11], [0, 7], [3, 9], [5, 10], [2, 8]]}, {"id": 901, "width": 1352, "height": 700, "file_name": "acs.orglett.6b00233-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [728.42, 38.56, 344.93, 199.57], "category_id": 1, "id": 0}, {"bbox": [766.97, 583.82, 36.52, 40.59], "category_id": 3, "id": 1}, {"bbox": [585.71, 388.31, 327.35, 186.71], "category_id": 1, "id": 2}, {"bbox": [10.82, 24.35, 329.38, 198.89], "category_id": 1, "id": 3}, {"bbox": [194.11, 251.66, 33.82, 38.56], "category_id": 3, "id": 4}, {"bbox": [183.96, 598.02, 35.85, 41.95], "category_id": 3, "id": 5}, {"bbox": [4.06, 390.34, 330.73, 188.74], "category_id": 1, "id": 6}, {"bbox": [931.99, 263.83, 24.35, 39.24], "category_id": 3, "id": 7}], "caption": "Scheme 2. Strategy for Fused Tetrahydroisoquinolines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 383, 110], "ImageBB": [82, 116, 420, 291]}, "diagram_type": "multiple", "corefs": [[3, 4], [0, 7], [6, 5], [2, 1]]}, {"id": 902, "width": 1356, "height": 932, "file_name": "acs.orglett.6b00233-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1021.58, 187.94, 305.93, 48.17], "category_id": 3, "id": 0}, {"bbox": [661.38, 495.97, 44.09, 40.71], "category_id": 3, "id": 1}, {"bbox": [548.1, 316.85, 301.86, 185.23], "category_id": 1, "id": 2}, {"bbox": [14.92, 345.35, 314.07, 135.69], "category_id": 1, "id": 3}, {"bbox": [1035.15, 302.6, 300.5, 213.72], "category_id": 1, "id": 4}, {"bbox": [390.05, 249.0, 102.42, 98.38], "category_id": 1, "id": 5}, {"bbox": [993.77, 2.71, 320.17, 168.95], "category_id": 1, "id": 6}, {"bbox": [991.05, 627.6, 303.22, 204.22], "category_id": 1, "id": 7}, {"bbox": [1130.79, 533.29, 122.78, 43.42], "category_id": 3, "id": 8}, {"bbox": [1105.69, 846.07, 123.46, 44.1], "category_id": 3, "id": 9}], "caption": "Scheme 3. Concise Synthesis Crispine A and Analogues", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 757, 156], "ImageBB": [448, 162, 787, 395]}, "diagram_type": "tree", "corefs": [[2, 1], [6, 0], [4, 8], [7, 9]]}, {"id": 903, "width": 1352, "height": 1392, "file_name": "acs.orglett.6b00661-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [469.92, 497.89, 390.68, 55.31], "category_id": 3, "id": 0}, {"bbox": [970.48, 471.43, 349.49, 428.95], "category_id": 1, "id": 1}, {"bbox": [472.01, 395.53, 388.47, 98.18], "category_id": 1, "id": 2}, {"bbox": [735.87, 16.71, 191.45, 293.16], "category_id": 1, "id": 3}, {"bbox": [36.9, 15.32, 216.51, 296.64], "category_id": 1, "id": 4}, {"bbox": [103.04, 306.39, 77.97, 63.37], "category_id": 3, "id": 5}, {"bbox": [470.5, 554.72, 394.37, 51.81], "category_id": 3, "id": 6}, {"bbox": [749.57, 1224.82, 304.13, 50.13], "category_id": 3, "id": 7}, {"bbox": [886.6, 825.44, 317.5, 45.11], "category_id": 3, "id": 8}, {"bbox": [886.6, 776.97, 262.35, 46.79], "category_id": 3, "id": 9}, {"bbox": [405.18, 926.14, 460.87, 425.47], "category_id": 1, "id": 10}, {"bbox": [806.18, 308.48, 66.14, 57.1], "category_id": 3, "id": 11}, {"bbox": [36.9, 497.19, 344.61, 251.38], "category_id": 1, "id": 12}, {"bbox": [747.7, 1183.1, 373.0, 43.6], "category_id": 3, "id": 13}, {"bbox": [886.9, 729.2, 308.0, 48.9], "category_id": 3, "id": 14}, {"bbox": [108.1, 775.0, 213.3, 45.2], "category_id": 3, "id": 15}, {"bbox": [134.62, 822.09, 168.77, 48.46], "category_id": 3, "id": 16}], "caption": "Scheme 2. Synthesis of Alkynyl Silyl Enol Ethers 10 and 19", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 470, 417, 485], "ImageBB": [82, 491, 420, 839]}, "diagram_type": "multiple", "corefs": [[4, 5], [3, 11], [2, 0], [2, 6], [12, 15], [12, 16], [1, 14], [1, 9], [1, 8], [10, 13], [10, 7]]}, {"id": 904, "width": 1352, "height": 2036, "file_name": "acs.orglett.6b00661-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [4.07, 16.3, 351.46, 422.68], "category_id": 1, "id": 0}, {"bbox": [120.21, 1329.15, 460.45, 67.23], "category_id": 3, "id": 1}, {"bbox": [1016.67, 736.38, 77.43, 61.11], "category_id": 3, "id": 2}, {"bbox": [116.13, 1849.61, 462.5, 70.28], "category_id": 3, "id": 3}, {"bbox": [122.25, 1048.05, 576.59, 428.79], "category_id": 1, "id": 4}, {"bbox": [122.25, 1564.43, 578.62, 437.96], "category_id": 1, "id": 5}, {"bbox": [775.24, 435.92, 575.57, 445.09], "category_id": 1, "id": 6}, {"bbox": [1013.62, 143.61, 77.42, 63.15], "category_id": 3, "id": 7}, {"bbox": [239.4, 736.38, 92.7, 61.11], "category_id": 3, "id": 8}, {"bbox": [911.75, 1329.15, 302.55, 71.3], "category_id": 3, "id": 9}, {"bbox": [613.26, 287.22, 81.5, 71.3], "category_id": 3, "id": 10}, {"bbox": [775.24, 1048.05, 572.51, 365.64], "category_id": 1, "id": 11}, {"bbox": [0.0, 456.29, 590.85, 424.72], "category_id": 1, "id": 12}, {"bbox": [538.9, 16.3, 340.25, 423.7], "category_id": 1, "id": 13}, {"bbox": [871.0, 0.0, 405.44, 208.79], "category_id": 1, "id": 14}, {"bbox": [83.53, 282.13, 82.52, 81.48], "category_id": 3, "id": 15}], "caption": "Scheme 5. Synthesis of Gardnerine (1), Hydroxygardnerine (2), and Hydroxygardnutine (3) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 640]}, "diagram_type": "tree", "corefs": [[0, 15], [13, 10], [14, 7], [12, 8], [6, 2], [4, 1], [11, 9], [5, 3]]}, {"id": 905, "width": 1704, "height": 1188, "file_name": "acs.orglett.6b01059-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [503.97, 566.15, 139.77, 108.39], "category_id": 1, "id": 0}, {"bbox": [1163.56, 737.62, 41.77, 44.35], "category_id": 3, "id": 1}, {"bbox": [981.14, 470.71, 329.04, 240.48], "category_id": 1, "id": 2}, {"bbox": [811.51, 239.62, 58.82, 45.2], "category_id": 3, "id": 3}, {"bbox": [705.81, 648.08, 315.4, 240.48], "category_id": 1, "id": 4}, {"bbox": [561.75, 661.73, 44.33, 47.75], "category_id": 3, "id": 5}, {"bbox": [519.13, 166.28, 190.94, 115.13], "category_id": 1, "id": 6}, {"bbox": [768.04, 871.5, 47.73, 47.76], "category_id": 3, "id": 7}, {"bbox": [685.35, 3.41, 283.86, 241.33], "category_id": 1, "id": 8}, {"bbox": [575.39, 263.5, 57.96, 43.49], "category_id": 3, "id": 9}, {"bbox": [981.14, 169.7, 394.68, 240.47], "category_id": 1, "id": 10}], "caption": "Scheme 3. Proposed Mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 797, 633, 812], "ImageBB": [433, 830, 859, 1127]}, "diagram_type": "graph", "corefs": [[8, 3], [6, 9], [0, 5], [4, 7], [2, 1]]}, {"id": 906, "width": 1356, "height": 1180, "file_name": "acs.orglett.6b01181-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [845.89, 4.07, 165.51, 263.19], "category_id": 1, "id": 0}, {"bbox": [439.56, 649.16, 49.52, 41.38], "category_id": 3, "id": 1}, {"bbox": [14.92, 257.09, 291.01, 230.63], "category_id": 1, "id": 2}, {"bbox": [374.44, 820.78, 287.62, 282.86], "category_id": 1, "id": 3}, {"bbox": [404.97, 237.42, 52.91, 48.84], "category_id": 3, "id": 4}, {"bbox": [1140.97, 4.07, 200.78, 218.42], "category_id": 1, "id": 5}, {"bbox": [656.63, 1085.4, 238.77, 48.4], "category_id": 1, "id": 6}, {"bbox": [158.73, 4.07, 362.91, 286.93], "category_id": 1, "id": 7}, {"bbox": [1174.21, 212.32, 63.76, 51.55], "category_id": 3, "id": 8}, {"bbox": [978.17, 431.42, 341.2, 263.19], "category_id": 1, "id": 9}, {"bbox": [904.67, 1090.81, 52.42, 41.08], "category_id": 3, "id": 10}, {"bbox": [1056.25, 1056.81, 41.08, 42.5], "category_id": 3, "id": 11}, {"bbox": [112.6, 477.54, 85.48, 48.84], "category_id": 3, "id": 12}, {"bbox": [193.33, 431.42, 320.17, 268.62], "category_id": 1, "id": 13}, {"bbox": [997.84, 648.48, 40.7, 50.88], "category_id": 3, "id": 14}, {"bbox": [875.06, 195.36, 38.66, 44.77], "category_id": 3, "id": 15}, {"bbox": [872.09, 841.5, 236.57, 259.23], "category_id": 1, "id": 16}], "caption": "Scheme 4. Proposed Reaction Pathway", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 217, 669, 232], "ImageBB": [448, 239, 787, 534]}, "diagram_type": "graph", "corefs": [[7, 4], [0, 15], [5, 8], [9, 14], [16, 11], [6, 10], [13, 1], [2, 12]]}, {"id": 907, "width": 1348, "height": 1320, "file_name": "ja011003u-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1001.39, 897.76, 59.34, 49.24], "category_id": 3, "id": 0}, {"bbox": [267.71, 1264.01, 57.99, 47.89], "category_id": 3, "id": 1}, {"bbox": [215.11, 362.21, 185.45, 47.88], "category_id": 3, "id": 2}, {"bbox": [759.3, 503.18, 584.65, 366.92], "category_id": 1, "id": 3}, {"bbox": [0.0, 6.74, 587.35, 295.44], "category_id": 1, "id": 4}, {"bbox": [54.62, 823.56, 545.54, 396.61], "category_id": 1, "id": 5}], "caption": "Scheme 1. Schematic Representation of the Potential Interconversion from Neutral [Hg(arene)2(AlCl4)2] (cf, 1 and 3) to Cationic [Hg(arene)2(AlCl4)2]+ (cf., 5) via an Asymmetrical Complex (cf, 7) ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 65, 770, 120], "ImageBB": [440, 125, 777, 455]}, "diagram_type": "tree", "corefs": [[4, 2], [3, 0], [5, 1]]}, {"id": 908, "width": 1284, "height": 616, "file_name": "ja012253d-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [91.21, 340.81, 371.9, 204.74], "category_id": 1, "id": 0}, {"bbox": [711.05, 327.97, 308.31, 283.69], "category_id": 1, "id": 1}, {"bbox": [404.02, 23.11, 204.9, 188.69], "category_id": 1, "id": 2}, {"bbox": [818.0, 5.81, 222.0, 166.19], "category_id": 1, "id": 3}, {"bbox": [1114.51, 4.42, 164.61, 137.5], "category_id": 1, "id": 4}, {"bbox": [11.56, 37.87, 155.44, 158.53], "category_id": 1, "id": 5}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 146, 125, 158], "ImageBB": [82, 158, 403, 312]}, "diagram_type": "tree", "corefs": []}, {"id": 909, "width": 1020, "height": 400, "file_name": "ja012253d-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [783.24, 4.59, 230.64, 168.81], "category_id": 1, "id": 0}, {"bbox": [113.28, 194.82, 279.11, 199.92], "category_id": 1, "id": 1}, {"bbox": [394.94, 3.06, 237.27, 203.49], "category_id": 1, "id": 2}, {"bbox": [0.0, 4.59, 239.31, 165.75], "category_id": 1, "id": 3}, {"bbox": [520.97, 206.55, 234.21, 182.58], "category_id": 1, "id": 4}], "caption": "Scheme 7", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 145, 125, 157], "ImageBB": [115, 157, 370, 257]}, "diagram_type": "tree", "corefs": []}, {"id": 910, "width": 1304, "height": 1964, "file_name": "ja0161958-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [925.56, 1900.14, 162.12, 57.97], "category_id": 3, "id": 0}, {"bbox": [0.0, 1395.14, 631.78, 498.12], "category_id": 1, "id": 1}, {"bbox": [239.74, 336.99, 62.88, 47.16], "category_id": 3, "id": 2}, {"bbox": [925.56, 336.99, 62.88, 50.11], "category_id": 3, "id": 3}, {"bbox": [65.83, 0.0, 455.9, 310.47], "category_id": 1, "id": 4}, {"bbox": [239.74, 992.32, 63.87, 51.09], "category_id": 3, "id": 5}, {"bbox": [930.47, 990.35, 59.93, 50.11], "category_id": 3, "id": 6}, {"bbox": [743.79, 0.0, 458.84, 307.52], "category_id": 1, "id": 7}, {"bbox": [660.27, 1398.09, 639.63, 483.38], "category_id": 1, "id": 8}, {"bbox": [65.83, 468.65, 460.81, 500.09], "category_id": 1, "id": 9}, {"bbox": [207.32, 1910.95, 169.98, 53.05], "category_id": 3, "id": 10}, {"bbox": [739.86, 465.7, 458.84, 498.12], "category_id": 1, "id": 11}], "caption": "Scheme 1. Synthesis of the Biomimetic Supramolecular Calix[6]arene-Based Cuprous Systems Presenting Two Different Cavitiesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 761, 100], "ImageBB": [446, 100, 772, 591]}, "diagram_type": "tree", "corefs": [[4, 2], [7, 3], [9, 5], [11, 6], [8, 0], [1, 10]]}, {"id": 911, "width": 1136, "height": 1064, "file_name": "ja016495p-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [750.14, 2.27, 313.69, 343.68], "category_id": 1, "id": 0}, {"bbox": [732.52, 781.09, 237.54, 260.17], "category_id": 1, "id": 1}, {"bbox": [0.0, 390.26, 313.69, 226.66], "category_id": 1, "id": 2}, {"bbox": [251.75, 600.44, 38.07, 47.15], "category_id": 3, "id": 3}, {"bbox": [988.25, 702.13, 59.67, 51.12], "category_id": 3, "id": 4}, {"bbox": [930.85, 360.15, 56.83, 48.29], "category_id": 3, "id": 5}, {"bbox": [971.2, 1012.86, 58.53, 49.42], "category_id": 3, "id": 6}, {"bbox": [731.95, 545.91, 329.6, 139.74], "category_id": 1, "id": 7}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 65, 130, 79], "ImageBB": [143, 107, 427, 373]}, "diagram_type": "tree", "corefs": [[2, 3], [0, 5], [7, 4], [1, 6]]}, {"id": 912, "width": 968, "height": 1116, "file_name": "ja0176346-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [24.01, 474.54, 252.39, 178.65], "category_id": 1, "id": 0}, {"bbox": [785.65, 1056.26, 53.6, 44.11], "category_id": 3, "id": 1}, {"bbox": [0.0, 832.39, 284.78, 231.69], "category_id": 1, "id": 2}, {"bbox": [341.17, 2.23, 237.32, 187.58], "category_id": 1, "id": 3}, {"bbox": [454.53, 419.27, 52.48, 40.19], "category_id": 3, "id": 4}, {"bbox": [687.93, 525.34, 245.69, 121.15], "category_id": 1, "id": 5}, {"bbox": [357.37, 473.42, 242.9, 305.38], "category_id": 1, "id": 6}, {"bbox": [773.92, 184.23, 78.74, 44.11], "category_id": 3, "id": 7}, {"bbox": [357.37, 244.53, 242.9, 173.06], "category_id": 1, "id": 8}, {"bbox": [118.94, 648.16, 53.6, 37.97], "category_id": 3, "id": 9}, {"bbox": [441.68, 186.47, 73.15, 41.87], "category_id": 3, "id": 10}, {"bbox": [786.21, 646.49, 35.73, 39.64], "category_id": 3, "id": 11}, {"bbox": [496.96, 899.39, 96.05, 104.95], "category_id": 1, "id": 12}, {"bbox": [686.26, 844.12, 246.8, 152.97], "category_id": 1, "id": 13}, {"bbox": [454.53, 783.82, 46.34, 35.73], "category_id": 3, "id": 14}, {"bbox": [127.87, 1069.1, 54.16, 43.55], "category_id": 3, "id": 15}, {"bbox": [668.95, 0.0, 242.34, 184.23], "category_id": 1, "id": 16}, {"bbox": [357.37, 894.36, 117.82, 172.51], "category_id": 1, "id": 17}], "caption": "Scheme 3 a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 338, 132, 351], "ImageBB": [122, 351, 364, 630]}, "diagram_type": "graph", "corefs": [[3, 10], [16, 7], [8, 4], [0, 9], [6, 14], [5, 11], [13, 1], [2, 15]]}, {"id": 913, "width": 1032, "height": 696, "file_name": "ja0289088-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [84.15, 588.53, 35.11, 40.79], "category_id": 3, "id": 0}, {"bbox": [381.0, 2.07, 188.43, 139.9], "category_id": 1, "id": 1}, {"bbox": [821.37, 61.95, 185.33, 137.84], "category_id": 1, "id": 2}, {"bbox": [156.43, 192.05, 66.08, 73.31], "category_id": 1, "id": 3}, {"bbox": [31.49, 418.69, 231.41, 155.51], "category_id": 1, "id": 4}, {"bbox": [32.01, 55.76, 225.6, 171.39], "category_id": 1, "id": 5}, {"bbox": [851.83, 606.09, 30.97, 40.78], "category_id": 3, "id": 6}, {"bbox": [805.36, 406.3, 226.64, 186.88], "category_id": 1, "id": 7}], "caption": "Scheme 6", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 318, 125, 330], "ImageBB": [113, 334, 371, 508]}, "diagram_type": "tree", "corefs": [[4, 0], [7, 6]]}, {"id": 914, "width": 1220, "height": 1152, "file_name": "ja0289088-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [371.07, 3.66, 227.64, 165.35], "category_id": 1, "id": 0}, {"bbox": [64.08, 630.3, 231.31, 183.04], "category_id": 1, "id": 1}, {"bbox": [0.0, 1010.43, 192.86, 141.57], "category_id": 1, "id": 2}, {"bbox": [372.29, 280.06, 231.91, 185.44], "category_id": 1, "id": 3}, {"bbox": [347.87, 493.01, 53.1, 43.93], "category_id": 3, "id": 4}, {"bbox": [737.86, 616.87, 245.34, 181.22], "category_id": 1, "id": 5}, {"bbox": [778.75, 803.58, 59.81, 42.1], "category_id": 3, "id": 6}, {"bbox": [792.18, 1011.65, 189.8, 137.89], "category_id": 1, "id": 7}], "caption": "Scheme 9. Catalytic Cycle for Alkene Epoxidation", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 693, 76], "ImageBB": [455, 80, 760, 368]}, "diagram_type": "graph", "corefs": [[3, 4], [5, 6]]}, {"id": 915, "width": 1344, "height": 1716, "file_name": "ja030261j-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [994.09, 144.22, 349.91, 231.77], "category_id": 1, "id": 0}, {"bbox": [584.61, 166.54, 305.6, 229.2], "category_id": 1, "id": 1}, {"bbox": [802.65, 925.39, 499.62, 257.53], "category_id": 1, "id": 2}, {"bbox": [119.32, 674.73, 131.35, 54.93], "category_id": 3, "id": 3}, {"bbox": [721.96, 1421.56, 557.99, 236.93], "category_id": 1, "id": 4}, {"bbox": [845.58, 660.13, 127.9, 54.94], "category_id": 3, "id": 5}, {"bbox": [1045.59, 660.13, 133.06, 55.8], "category_id": 3, "id": 6}, {"bbox": [769.17, 426.64, 506.49, 206.02], "category_id": 1, "id": 7}, {"bbox": [20.6, 1406.97, 349.39, 272.98], "category_id": 1, "id": 8}, {"bbox": [84.99, 892.77, 310.76, 283.28], "category_id": 1, "id": 9}, {"bbox": [937.43, 1662.78, 125.33, 49.79], "category_id": 3, "id": 10}, {"bbox": [937.43, 1199.23, 125.33, 50.64], "category_id": 3, "id": 11}, {"bbox": [0.0, 428.36, 504.77, 212.03], "category_id": 1, "id": 12}], "caption": "Scheme 2. Derivation of the Pyrimidine Unit of Thiamin from Pyridoxine ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 573, 380, 597], "ImageBB": [74, 601, 410, 1030]}, "diagram_type": "tree", "corefs": [[12, 3], [7, 5], [7, 6], [2, 11], [4, 10]]}, {"id": 916, "width": 852, "height": 660, "file_name": "ja052327b-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [615.6, 20.45, 66.34, 48.57], "category_id": 1, "id": 0}, {"bbox": [290.68, 296.53, 37.08, 43.03], "category_id": 3, "id": 1}, {"bbox": [725.41, 60.5, 126.59, 102.25], "category_id": 1, "id": 2}, {"bbox": [0.0, 367.26, 118.06, 288.43], "category_id": 1, "id": 3}, {"bbox": [449.23, 316.56, 64.36, 51.97], "category_id": 1, "id": 4}, {"bbox": [183.27, 193.0, 241.66, 79.67], "category_id": 1, "id": 5}, {"bbox": [362.28, 478.88, 292.81, 83.51], "category_id": 1, "id": 6}, {"bbox": [418.12, 95.86, 34.52, 40.9], "category_id": 3, "id": 7}, {"bbox": [334.58, 4.26, 187.1, 75.84], "category_id": 1, "id": 8}], "caption": "Scheme 3. Postulated Mechanisms for the Formation of 1-Octene", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 407, 76], "ImageBB": [214, 80, 427, 245]}, "diagram_type": "tree", "corefs": [[8, 7], [5, 1]]}, {"id": 917, "width": 888, "height": 520, "file_name": "ja052327b-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [727.64, 4.0, 100.83, 148.29], "category_id": 1, "id": 0}, {"bbox": [710.76, 429.33, 33.31, 42.18], "category_id": 3, "id": 1}, {"bbox": [741.41, 407.58, 137.26, 80.36], "category_id": 1, "id": 2}, {"bbox": [375.81, 388.04, 255.43, 129.2], "category_id": 1, "id": 3}, {"bbox": [490.87, 179.81, 185.24, 96.35], "category_id": 1, "id": 4}, {"bbox": [782.72, 143.41, 105.28, 151.84], "category_id": 1, "id": 5}, {"bbox": [213.67, 150.96, 189.24, 139.41], "category_id": 1, "id": 6}, {"bbox": [2.67, 426.67, 227.44, 84.36], "category_id": 1, "id": 7}], "caption": "Scheme 4. Postulated Mechanisms for the Formation of Methylcyclopentane and Methylenecyclopentane ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 257, 358, 281], "ImageBB": [131, 285, 353, 415]}, "diagram_type": "graph", "corefs": [[2, 1]]}, {"id": 918, "width": 1088, "height": 1428, "file_name": "ja0547477-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [276.35, 565.06, 330.63, 73.58], "category_id": 1, "id": 0}, {"bbox": [0.0, 926.52, 522.71, 462.9], "category_id": 1, "id": 1}, {"bbox": [238.51, 1380.85, 57.12, 42.86], "category_id": 3, "id": 2}, {"bbox": [680.53, 2.86, 406.31, 157.16], "category_id": 1, "id": 3}, {"bbox": [432.74, 625.06, 57.13, 47.86], "category_id": 3, "id": 4}, {"bbox": [238.51, 845.08, 53.55, 43.58], "category_id": 3, "id": 5}, {"bbox": [0.0, 0.0, 291.35, 160.02], "category_id": 1, "id": 6}, {"bbox": [238.51, 501.48, 55.69, 41.43], "category_id": 3, "id": 7}, {"bbox": [818.35, 500.76, 59.27, 47.15], "category_id": 3, "id": 8}, {"bbox": [148.53, 120.01, 56.41, 45.01], "category_id": 3, "id": 9}, {"bbox": [17.14, 645.78, 496.29, 227.16], "category_id": 1, "id": 10}, {"bbox": [565.56, 925.81, 521.28, 463.61], "category_id": 1, "id": 11}, {"bbox": [611.26, 213.59, 474.87, 307.18], "category_id": 1, "id": 12}, {"bbox": [799.07, 1380.85, 56.41, 42.86], "category_id": 3, "id": 13}, {"bbox": [17.14, 272.88, 496.29, 253.6], "category_id": 1, "id": 14}, {"bbox": [861.91, 120.01, 46.41, 40.72], "category_id": 3, "id": 15}], "caption": "Scheme 2. Synthesis of Chiral Sulfoxide Cyclization Precursor 15a ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 389, 88], "ImageBB": [106, 92, 378, 449]}, "diagram_type": "tree", "corefs": [[6, 9], [3, 15], [14, 7], [12, 8], [0, 4], [10, 5], [1, 2], [11, 13]]}, {"id": 919, "width": 1352, "height": 828, "file_name": "ja064212t-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1094.99, 71.05, 234.01, 213.14], "category_id": 1, "id": 0}, {"bbox": [454.5, 758.51, 62.22, 55.49], "category_id": 3, "id": 1}, {"bbox": [734.5, 525.07, 230.63, 215.85], "category_id": 1, "id": 2}, {"bbox": [389.57, 495.98, 223.87, 242.91], "category_id": 1, "id": 3}, {"bbox": [454.5, 333.58, 60.87, 54.81], "category_id": 3, "id": 4}, {"bbox": [1094.99, 495.3, 232.66, 209.76], "category_id": 1, "id": 5}, {"bbox": [1193.06, 332.91, 58.84, 54.8], "category_id": 3, "id": 6}, {"bbox": [100.1, 757.84, 59.52, 56.16], "category_id": 3, "id": 7}, {"bbox": [1164.65, 758.51, 61.55, 55.49], "category_id": 3, "id": 8}, {"bbox": [100.1, 334.94, 58.16, 52.77], "category_id": 3, "id": 9}, {"bbox": [31.11, 495.3, 222.52, 243.59], "category_id": 1, "id": 10}, {"bbox": [734.5, 117.74, 231.99, 197.57], "category_id": 1, "id": 11}, {"bbox": [31.11, 71.72, 228.6, 244.95], "category_id": 1, "id": 12}, {"bbox": [389.57, 71.72, 231.98, 245.62], "category_id": 1, "id": 13}, {"bbox": [835.28, 334.94, 59.52, 52.1], "category_id": 3, "id": 14}, {"bbox": [805.52, 757.16, 65.6, 58.19], "category_id": 3, "id": 15}], "caption": "Scheme 2. Schematic Description of the (R) and (\u03b2) Conformers in Phospha(III)guanidines (X ) Lone Pair, Chalcogen) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 765, 88], "ImageBB": [439, 92, 777, 299]}, "diagram_type": "graph", "corefs": [[12, 9], [13, 4], [11, 14], [0, 6], [10, 7], [3, 1], [2, 15], [5, 8]]}, {"id": 920, "width": 2520, "height": 812, "file_name": "ja065718e-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1854.39, 80.59, 353.71, 143.51], "category_id": 1, "id": 0}, {"bbox": [505.51, 186.37, 63.03, 49.11], "category_id": 3, "id": 1}, {"bbox": [2419.3, 344.2, 51.32, 47.51], "category_id": 3, "id": 2}, {"bbox": [325.0, 346.1, 55.12, 47.51], "category_id": 3, "id": 3}, {"bbox": [2398.4, 712.89, 53.21, 43.71], "category_id": 3, "id": 4}, {"bbox": [1967.0, 709.09, 58.91, 49.41], "category_id": 3, "id": 5}, {"bbox": [1731.34, 427.82, 57.01, 45.61], "category_id": 3, "id": 6}, {"bbox": [191.97, 709.09, 57.02, 47.51], "category_id": 3, "id": 7}, {"bbox": [2010.71, 192.16, 55.11, 39.91], "category_id": 3, "id": 8}, {"bbox": [1355.18, 270.73, 190.35, 114.59], "category_id": 1, "id": 9}, {"bbox": [695.87, 318.59, 306.33, 146.07], "category_id": 1, "id": 10}, {"bbox": [1009.76, 270.73, 187.84, 114.59], "category_id": 1, "id": 11}, {"bbox": [2216.19, 515.02, 303.81, 239.26], "category_id": 1, "id": 12}, {"bbox": [1582.09, 318.59, 306.33, 156.14], "category_id": 1, "id": 13}, {"bbox": [847.14, 424.36, 61.77, 51.63], "category_id": 3, "id": 14}, {"bbox": [2212.41, 270.73, 262.21, 219.11], "category_id": 1, "id": 15}, {"bbox": [118.5, 273.25, 264.73, 222.89], "category_id": 1, "id": 16}, {"bbox": [526.94, 567.91, 279.86, 188.89], "category_id": 1, "id": 17}, {"bbox": [2048.52, 522.58, 185.32, 113.33], "category_id": 1, "id": 18}, {"bbox": [1776.23, 566.65, 281.12, 190.15], "category_id": 1, "id": 19}, {"bbox": [1653.95, 50.37, 177.75, 110.81], "category_id": 1, "id": 20}, {"bbox": [348.3, 74.29, 353.87, 145.41], "category_id": 1, "id": 21}, {"bbox": [3.8, 512.51, 312.62, 244.29], "category_id": 1, "id": 22}], "caption": "Scheme 1. Possible Mechanisms for Oxidative Coupling", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 359, 76], "ImageBB": [110, 80, 740, 283]}, "diagram_type": "graph", "corefs": [[21, 1], [10, 14], [16, 3], [22, 7], [0, 8], [15, 2], [12, 4], [19, 5], [13, 6]]}, {"id": 921, "width": 1356, "height": 492, "file_name": "ja076333e-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [69.87, 156.58, 153.98, 44.07], "category_id": 3, "id": 0}, {"bbox": [627.46, 2.71, 437.53, 181.67], "category_id": 1, "id": 1}, {"bbox": [0.0, 4.07, 338.49, 157.26], "category_id": 1, "id": 2}, {"bbox": [497.22, 258.94, 146.52, 96.93], "category_id": 1, "id": 3}, {"bbox": [721.07, 252.84, 634.93, 185.05], "category_id": 1, "id": 4}, {"bbox": [0.0, 252.84, 455.17, 183.7], "category_id": 1, "id": 5}, {"bbox": [155.34, 444.67, 148.56, 40.0], "category_id": 3, "id": 6}, {"bbox": [980.2, 443.32, 202.82, 43.38], "category_id": 3, "id": 7}, {"bbox": [675.63, 155.23, 176.36, 42.7], "category_id": 3, "id": 8}], "caption": "Scheme 1. Synthesis of Lys-NTA-SH", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 274, 76], "ImageBB": [73, 80, 412, 203]}, "diagram_type": "multiple", "corefs": [[2, 0], [1, 8], [4, 7], [5, 6]]}, {"id": 922, "width": 1252, "height": 420, "file_name": "ja1078199-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [917.55, 246.86, 317.54, 147.87], "category_id": 1, "id": 0}, {"bbox": [28.81, 5.64, 264.93, 146.61], "category_id": 1, "id": 1}, {"bbox": [427.15, 228.07, 355.12, 191.1], "category_id": 1, "id": 2}, {"bbox": [917.55, 6.27, 334.45, 152.25], "category_id": 1, "id": 3}, {"bbox": [429.65, 8.15, 331.32, 147.24], "category_id": 1, "id": 4}, {"bbox": [0.0, 253.75, 312.53, 151.63], "category_id": 1, "id": 5}], "caption": "Scheme 3. A Possible Pathway for the Photoreduction of CO2 with H2 to CO and H2O with a ReI(L)(CO)3(CH3CN)-MHPW12O40 Catalyst ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 266, 390, 302], "ImageBB": [70, 313, 383, 418]}, "diagram_type": "graph", "corefs": []}, {"id": 923, "width": 900, "height": 1220, "file_name": "ja107927b-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [653.88, 234.97, 93.41, 46.38], "category_id": 3, "id": 0}, {"bbox": [507.96, 0.0, 379.14, 264.87], "category_id": 1, "id": 1}, {"bbox": [699.06, 1176.06, 35.41, 43.94], "category_id": 3, "id": 2}, {"bbox": [187.43, 327.73, 103.79, 115.35], "category_id": 1, "id": 3}, {"bbox": [158.13, 734.2, 40.9, 45.77], "category_id": 3, "id": 4}, {"bbox": [533.6, 498.01, 366.32, 268.53], "category_id": 1, "id": 5}, {"bbox": [185.6, 234.36, 39.69, 49.43], "category_id": 3, "id": 6}, {"bbox": [686.23, 729.92, 45.18, 48.83], "category_id": 3, "id": 7}, {"bbox": [34.8, 7.93, 280.84, 261.21], "category_id": 1, "id": 8}, {"bbox": [536.66, 936.82, 320.52, 261.21], "category_id": 1, "id": 9}, {"bbox": [4.27, 500.45, 294.89, 264.26], "category_id": 1, "id": 10}], "caption": "Scheme 2. Reactions of 1 with Acetonitrile", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 282, 637, 294], "ImageBB": [481, 297, 706, 602]}, "diagram_type": "graph", "corefs": [[8, 6], [1, 0], [10, 4], [5, 7], [9, 2]]}, {"id": 924, "width": 1356, "height": 864, "file_name": "ja200818w-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [542.67, 0.0, 177.73, 114.01], "category_id": 1, "id": 0}, {"bbox": [0.0, 319.63, 263.87, 177.12], "category_id": 1, "id": 1}, {"bbox": [633.2, 762.76, 108.9, 53.61], "category_id": 1, "id": 2}, {"bbox": [971.38, 354.24, 380.55, 160.83], "category_id": 1, "id": 3}, {"bbox": [138.38, 517.1, 33.24, 44.79], "category_id": 3, "id": 4}, {"bbox": [1103.66, 548.32, 42.05, 47.5], "category_id": 3, "id": 5}], "caption": "Scheme 1. Formation of 2 by Two Di\ufb00erent Pathways", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 373, 107], "ImageBB": [71, 117, 410, 333]}, "diagram_type": "graph", "corefs": [[1, 4], [3, 5]]}, {"id": 925, "width": 2280, "height": 1976, "file_name": "ja2031294-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1088.1, 1538.98, 193.9, 225.89], "category_id": 1, "id": 0}, {"bbox": [2098.65, 805.43, 181.35, 261.25], "category_id": 1, "id": 1}, {"bbox": [891.93, 233.87, 296.54, 199.65], "category_id": 1, "id": 2}, {"bbox": [0.0, 726.71, 380.95, 420.97], "category_id": 1, "id": 3}, {"bbox": [1089.24, 28.52, 185.92, 222.46], "category_id": 1, "id": 4}, {"bbox": [1552.32, 836.23, 385.51, 341.11], "category_id": 1, "id": 5}, {"bbox": [891.93, 1746.62, 302.25, 201.92], "category_id": 1, "id": 6}], "caption": "Scheme 3. Three General Nucleophilic Substitution Mechanisms Considered for TcUP-Catalyzed Arsenolysis of Uridinea", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 419, 743, 440], "ImageBB": [137, 449, 707, 943]}, "diagram_type": "graph", "corefs": []}, {"id": 926, "width": 1352, "height": 1116, "file_name": "ja3058138-Scheme-c11.png", "license": 0, "bboxes": [{"bbox": [144.74, 939.03, 50.72, 41.94], "category_id": 3, "id": 0}, {"bbox": [1011.13, 564.23, 50.04, 37.88], "category_id": 3, "id": 1}, {"bbox": [1100.4, 181.31, 45.99, 35.86], "category_id": 3, "id": 2}, {"bbox": [238.75, 31.12, 299.62, 112.98], "category_id": 1, "id": 3}, {"bbox": [1166.01, 932.26, 52.08, 44.65], "category_id": 3, "id": 4}, {"bbox": [497.11, 566.26, 49.37, 35.85], "category_id": 3, "id": 5}, {"bbox": [10.15, 650.82, 219.8, 321.36], "category_id": 1, "id": 6}, {"bbox": [373.34, 274.0, 219.13, 301.05], "category_id": 1, "id": 7}, {"bbox": [877.21, 274.0, 221.84, 303.08], "category_id": 1, "id": 8}, {"bbox": [941.46, 10.15, 388.22, 180.63], "category_id": 1, "id": 9}, {"bbox": [1038.18, 640.68, 300.97, 286.85], "category_id": 1, "id": 10}, {"bbox": [10.82, 24.36, 172.47, 165.75], "category_id": 1, "id": 11}, {"bbox": [353.72, 163.04, 48.02, 39.24], "category_id": 3, "id": 12}], "caption": "Scheme 11. Synthesis of Key Aminoalcohol 11a", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 303, 352, 324], "ImageBB": [82, 330, 420, 609]}, "diagram_type": "multiple", "corefs": [[3, 12], [9, 2], [7, 5], [8, 1], [6, 0], [10, 4]]}, {"id": 927, "width": 1356, "height": 944, "file_name": "ja3058138-Scheme-c13.png", "license": 0, "bboxes": [{"bbox": [693.26, 855.37, 63.77, 44.77], "category_id": 3, "id": 0}, {"bbox": [1103.66, 315.42, 59.69, 44.77], "category_id": 3, "id": 1}, {"bbox": [512.15, 553.52, 396.82, 223.85], "category_id": 1, "id": 2}, {"bbox": [1005.98, 667.48, 304.57, 50.87], "category_id": 3, "id": 3}, {"bbox": [510.11, 0.0, 364.95, 338.49], "category_id": 1, "id": 4}, {"bbox": [191.1, 315.3, 183.7, 78.1], "category_id": 3, "id": 5}, {"bbox": [164.8, 521.64, 348.5, 341.2], "category_id": 1, "id": 6}, {"bbox": [966.63, 0.0, 354.77, 340.9], "category_id": 1, "id": 7}, {"bbox": [142.45, 0.0, 307.97, 303.89], "category_id": 1, "id": 8}, {"bbox": [1134.86, 856.05, 53.59, 44.09], "category_id": 3, "id": 9}, {"bbox": [1005.98, 750.91, 307.28, 120.74], "category_id": 1, "id": 10}, {"bbox": [994.45, 499.93, 330.35, 171.62], "category_id": 1, "id": 11}, {"bbox": [255.73, 858.77, 50.2, 41.37], "category_id": 3, "id": 12}, {"bbox": [636.28, 352.05, 63.09, 50.88], "category_id": 3, "id": 13}], "caption": "Scheme 13. Retrosynthetic Analysis of Goniomitine", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 575, 740, 590], "ImageBB": [448, 597, 787, 833]}, "diagram_type": "multiple", "corefs": [[8, 5], [4, 13], [7, 1], [6, 12], [2, 0], [11, 3], [10, 9]]}, {"id": 928, "width": 1356, "height": 1296, "file_name": "ja3058138-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [86.78, 521.16, 262.93, 284.72], "category_id": 1, "id": 0}, {"bbox": [306.15, 4.63, 171.14, 164.92], "category_id": 1, "id": 1}, {"bbox": [374.44, 1203.39, 62.41, 48.84], "category_id": 3, "id": 2}, {"bbox": [42.74, 350.71, 133.63, 113.28], "category_id": 1, "id": 3}, {"bbox": [901.51, 1203.39, 71.23, 50.2], "category_id": 3, "id": 4}, {"bbox": [896.09, 240.14, 261.83, 191.97], "category_id": 1, "id": 5}, {"bbox": [1132.15, 824.19, 79.36, 50.88], "category_id": 3, "id": 6}, {"bbox": [822.15, 4.07, 267.94, 166.2], "category_id": 1, "id": 7}, {"bbox": [248.95, 212.32, 233.35, 195.37], "category_id": 1, "id": 8}, {"bbox": [900.16, 404.97, 72.58, 46.13], "category_id": 3, "id": 9}, {"bbox": [997.84, 556.25, 291.0, 288.97], "category_id": 1, "id": 10}, {"bbox": [1178.95, 366.31, 131.6, 116.0], "category_id": 1, "id": 11}, {"bbox": [268.62, 942.23, 308.65, 252.34], "category_id": 1, "id": 12}, {"bbox": [329.67, 402.94, 63.09, 44.77], "category_id": 3, "id": 13}, {"bbox": [582.02, 1193.89, 130.24, 59.7], "category_id": 1, "id": 14}, {"bbox": [764.49, 928.66, 319.5, 269.98], "category_id": 1, "id": 15}, {"bbox": [233.02, 749.87, 60.68, 49.79], "category_id": 3, "id": 16}], "caption": "Scheme 7. Revised Catalytic Cycle", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 375, 644, 390], "ImageBB": [448, 396, 787, 720]}, "diagram_type": "graph", "corefs": [[8, 13], [5, 9], [0, 16], [10, 6], [12, 2], [15, 4]]}, {"id": 929, "width": 1352, "height": 1344, "file_name": "ja402810t-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [1002.33, 989.57, 244.84, 238.76], "category_id": 1, "id": 0}, {"bbox": [428.8, 554.64, 728.41, 380.82], "category_id": 1, "id": 1}, {"bbox": [4.06, 0.0, 625.54, 529.9], "category_id": 1, "id": 2}, {"bbox": [723.68, 0.0, 628.32, 526.24], "category_id": 1, "id": 3}, {"bbox": [85.89, 577.64, 269.86, 182.63], "category_id": 1, "id": 4}, {"bbox": [683.1, 989.57, 233.34, 238.76], "category_id": 1, "id": 5}, {"bbox": [0.0, 896.9, 495.08, 395.69], "category_id": 1, "id": 6}], "caption": "Scheme 5", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 138, 110], "ImageBB": [82, 116, 420, 452]}, "diagram_type": "multiple", "corefs": []}, {"id": 930, "width": 1356, "height": 640, "file_name": "ja407179c-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [987.66, 200.83, 48.84, 38.0], "category_id": 3, "id": 0}, {"bbox": [943.57, 504.12, 69.87, 49.53], "category_id": 3, "id": 1}, {"bbox": [489.76, 214.4, 71.23, 46.14], "category_id": 3, "id": 2}, {"bbox": [802.48, 4.07, 376.47, 201.51], "category_id": 1, "id": 3}, {"bbox": [769.24, 377.24, 254.37, 188.62], "category_id": 1, "id": 4}, {"bbox": [173.65, 2.71, 289.55, 164.89], "category_id": 1, "id": 5}, {"bbox": [318.14, 381.99, 246.24, 211.81], "category_id": 1, "id": 6}, {"bbox": [260.48, 113.99, 287.62, 121.45], "category_id": 1, "id": 7}, {"bbox": [333.74, 109.92, 46.81, 42.74], "category_id": 3, "id": 8}], "caption": "Scheme 6. Dynamic Kinetic Resolution Model", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 711, 110], "ImageBB": [448, 116, 787, 276]}, "diagram_type": "tree", "corefs": [[5, 8], [3, 0], [7, 2], [4, 1]]}, {"id": 931, "width": 1316, "height": 736, "file_name": "ja408733f-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [443.06, 469.74, 333.11, 258.55], "category_id": 1, "id": 0}, {"bbox": [3.95, 3.95, 267.28, 406.58], "category_id": 1, "id": 1}, {"bbox": [975.64, 5.92, 332.46, 263.16], "category_id": 1, "id": 2}, {"bbox": [443.06, 5.92, 335.74, 263.16], "category_id": 1, "id": 3}], "caption": "Scheme 1. 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Preliminary Mechanistic Studies", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 692, 110], "ImageBB": [448, 116, 787, 597]}, "diagram_type": "multiple", "corefs": [[11, 17], [14, 9], [2, 4], [3, 6], [0, 5], [13, 10], [12, 1], [7, 15]]}, {"id": 933, "width": 1284, "height": 404, "file_name": "ja806814c-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1018.72, 3.86, 261.43, 153.02], "category_id": 1, "id": 0}, {"bbox": [836.3, 265.54, 143.24, 134.38], "category_id": 1, "id": 1}, {"bbox": [0.0, 8.36, 168.93, 149.17], "category_id": 1, "id": 2}, {"bbox": [366.12, 12.22, 247.94, 163.95], "category_id": 1, "id": 3}, {"bbox": [836.3, 17.36, 150.95, 107.37], "category_id": 1, "id": 4}], "caption": "Scheme 2. Proposed Mechanism of Methanol Formation", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 569, 340, 581], "ImageBB": [66, 593, 387, 694]}, "diagram_type": "tree", "corefs": []}, {"id": 934, "width": 1356, "height": 608, "file_name": "ja900722q-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [400.9, 294.92, 449.06, 89.5], "category_id": 3, "id": 0}, {"bbox": [1022.26, 0.0, 333.74, 292.89], "category_id": 1, "id": 1}, {"bbox": [339.17, 0.0, 326.28, 292.21], "category_id": 1, "id": 2}, {"bbox": [1022.26, 297.64, 256.41, 89.49], "category_id": 3, "id": 3}], "caption": "Scheme 10. Synthesis of (R)-QUINAP by Dynamic Thermodynamic Resolution ", "pdf": {"Page": 11, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 588, 677, 612], "ImageBB": [424, 624, 763, 776]}, "diagram_type": "tree", "corefs": [[2, 0], [1, 3]]}, {"id": 935, "width": 1348, "height": 556, "file_name": "ja954050t-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [1066.8, 303.35, 275.13, 252.65], "category_id": 1, "id": 0}, {"bbox": [0.0, 18.88, 299.41, 256.83], "category_id": 1, "id": 1}, {"bbox": [1056.01, 2.7, 291.99, 254.81], "category_id": 1, "id": 2}, {"bbox": [124.08, 315.48, 54.62, 45.84], "category_id": 3, "id": 3}], "caption": "Scheme 7", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 56, 485, 70], "ImageBB": [429, 75, 766, 214]}, "diagram_type": "tree", "corefs": [[1, 3]]}, {"id": 936, "width": 1252, "height": 1476, "file_name": "ja9612413-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [602.35, 2.95, 458.41, 335.96], "category_id": 1, "id": 0}, {"bbox": [0.0, 1097.22, 343.25, 59.07], "category_id": 1, "id": 1}, {"bbox": [583.9, 523.5, 437.0, 353.68], "category_id": 1, "id": 2}, {"bbox": [577.25, 1138.57, 494.58, 337.43], "category_id": 1, "id": 3}, {"bbox": [86.37, 377.31, 293.79, 152.84], "category_id": 1, "id": 4}, {"bbox": [71.6, 657.15, 293.8, 190.5], "category_id": 1, "id": 5}], "caption": "Scheme 2. Simplified Catalytic Cycle for the Hydroamination/Cyclization of Aminoalkynes ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 690, 78], "ImageBB": [451, 84, 764, 453]}, "diagram_type": "graph", "corefs": []}, {"id": 937, "width": 1208, "height": 980, "file_name": "ja9612413-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [30.59, 164.3, 237.41, 249.97], "category_id": 1, "id": 0}, {"bbox": [766.86, 677.68, 301.55, 46.72], "category_id": 1, "id": 1}, {"bbox": [619.0, 102.6, 151.1, 41.9], "category_id": 1, "id": 2}, {"bbox": [0.0, 527.15, 161.95, 50.78], "category_id": 1, "id": 3}, {"bbox": [79.29, 558.82, 310.59, 251.77], "category_id": 1, "id": 4}, {"bbox": [418.78, 324.03, 295.12, 53.87], "category_id": 1, "id": 5}, {"bbox": [860.47, 761.18, 150.59, 34.11], "category_id": 1, "id": 6}, {"bbox": [928.71, 476.47, 154.11, 31.77], "category_id": 1, "id": 7}, {"bbox": [886.35, 329.41, 315.3, 40.0], "category_id": 1, "id": 8}], "caption": "Scheme 3. A Plausible Pathway for the Organolanthanide- Catalyzed Coupling Reactions of Terminal Alkynes ", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 50, 396, 78], "ImageBB": [91, 84, 393, 329]}, "diagram_type": "graph", "corefs": []}, {"id": 938, "width": 1264, "height": 560, "file_name": "ja974106e-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [235.85, 377.22, 36.68, 46.76], "category_id": 3, "id": 0}, {"bbox": [889.67, 350.05, 261.15, 121.95], "category_id": 1, "id": 1}, {"bbox": [83.47, 193.35, 238.38, 164.91], "category_id": 1, "id": 2}, {"bbox": [675.31, 243.26, 52.49, 48.03], "category_id": 3, "id": 3}, {"bbox": [515.97, 74.56, 244.71, 165.55], "category_id": 1, "id": 4}, {"bbox": [515.97, 309.61, 237.75, 167.44], "category_id": 1, "id": 5}, {"bbox": [901.05, 74.56, 183.37, 166.81], "category_id": 1, "id": 6}], "caption": "Scheme 1. These", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [314, 442, 409, 456], "ImageBB": [74, 469, 390, 609]}, "diagram_type": "tree", "corefs": [[2, 0], [4, 3]]}, {"id": 939, "width": 1268, "height": 652, "file_name": "ja974106e-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [644.47, 406.21, 255.63, 173.28], "category_id": 1, "id": 0}, {"bbox": [198.54, 409.39, 319.06, 172.64], "category_id": 1, "id": 1}, {"bbox": [487.16, 74.9, 258.8, 175.18], "category_id": 1, "id": 2}, {"bbox": [570.89, 279.27, 63.43, 47.6], "category_id": 3, "id": 3}, {"bbox": [966.7, 74.9, 301.3, 214.53], "category_id": 1, "id": 4}, {"bbox": [747.23, 601.7, 64.06, 46.34], "category_id": 3, "id": 5}, {"bbox": [1019.98, 396.69, 234.7, 178.99], "category_id": 1, "id": 6}, {"bbox": [88.17, 78.7, 279.1, 178.36], "category_id": 1, "id": 7}, {"bbox": [291.15, 602.34, 65.34, 47.6], "category_id": 3, "id": 8}, {"bbox": [1052.33, 279.27, 62.8, 44.43], "category_id": 3, "id": 9}], "caption": "Scheme 2. The catalytically active", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [577, 136, 774, 150], "ImageBB": [440, 156, 757, 319]}, "diagram_type": "multiple", "corefs": [[2, 3], [4, 9], [1, 8], [0, 5]]}, {"id": 940, "width": 960, "height": 972, "file_name": "ja980022+-Scheme-c12.png", "license": 0, "bboxes": [{"bbox": [756.82, 739.09, 69.02, 50.57], "category_id": 3, "id": 0}, {"bbox": [291.16, 237.77, 49.09, 54.46], "category_id": 3, "id": 1}, {"bbox": [113.74, 425.46, 347.54, 297.1], "category_id": 1, "id": 2}, {"bbox": [787.44, 241.66, 51.04, 52.03], "category_id": 3, "id": 3}, {"bbox": [150.68, 0.0, 331.99, 293.69], "category_id": 1, "id": 4}, {"bbox": [582.32, 441.51, 376.22, 307.3], "category_id": 1, "id": 5}, {"bbox": [361.15, 726.45, 63.68, 48.62], "category_id": 3, "id": 6}, {"bbox": [34.03, 796.47, 493.85, 175.53], "category_id": 1, "id": 7}, {"bbox": [583.78, 0.0, 374.76, 296.12], "category_id": 1, "id": 8}], "caption": "Scheme 12", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 277, 503, 291], "ImageBB": [488, 296, 728, 539]}, "diagram_type": "graph", "corefs": [[4, 1], [8, 3], [2, 6], [5, 0]]}, {"id": 941, "width": 1032, "height": 2176, "file_name": "ja983111v-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [754.59, 124.09, 277.41, 342.9], "category_id": 1, "id": 0}, {"bbox": [323.4, 2136.81, 35.93, 39.19], "category_id": 3, "id": 1}, {"bbox": [52.27, 4.35, 614.12, 446.31], "category_id": 1, "id": 2}, {"bbox": [82.75, 587.81, 700.15, 396.23], "category_id": 1, "id": 3}, {"bbox": [827.55, 485.49, 54.44, 42.45], "category_id": 3, "id": 4}, {"bbox": [0.0, 1702.48, 844.97, 473.52], "category_id": 1, "id": 5}, {"bbox": [319.04, 402.76, 33.76, 38.1], "category_id": 3, "id": 6}, {"bbox": [359.33, 1510.9, 29.4, 40.28], "category_id": 3, "id": 7}, {"bbox": [245.0, 1137.53, 547.7, 385.34], "category_id": 1, "id": 8}, {"bbox": [803.59, 719.53, 196.0, 183.96], "category_id": 1, "id": 9}], "caption": "Scheme 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 133, 78], "ImageBB": [113, 84, 371, 628]}, "diagram_type": "tree", "corefs": [[2, 6], [0, 4], [8, 7], [5, 1]]}, {"id": 942, "width": 1256, "height": 1512, "file_name": "ja991729e-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [798.96, 1182.98, 447.14, 329.02], "category_id": 1, "id": 0}, {"bbox": [1003.24, 348.69, 46.9, 51.43], "category_id": 3, "id": 1}, {"bbox": [0.0, 626.28, 477.41, 327.51], "category_id": 1, "id": 2}, {"bbox": [780.8, 636.11, 474.38, 333.57], "category_id": 1, "id": 3}, {"bbox": [1010.04, 987.07, 42.37, 49.17], "category_id": 3, "id": 4}, {"bbox": [822.41, 0.0, 391.16, 332.81], "category_id": 1, "id": 5}, {"bbox": [224.71, 969.68, 43.88, 51.43], "category_id": 3, "id": 6}], "caption": "Scheme 1a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 63, 501, 78], "ImageBB": [451, 86, 765, 464]}, "diagram_type": "tree", "corefs": [[5, 1], [3, 4], [2, 6]]}, {"id": 943, "width": 1352, "height": 1096, "file_name": "jacs.5b00936-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [110.24, 283.28, 294.89, 276.52], "category_id": 1, "id": 0}, {"bbox": [1087.55, 726.79, 188.02, 118.99], "category_id": 1, "id": 1}, {"bbox": [61.55, 101.41, 318.55, 53.41], "category_id": 1, "id": 2}, {"bbox": [94.69, 174.43, 241.45, 37.19], "category_id": 3, "id": 3}, {"bbox": [1101.75, 856.6, 165.71, 41.92], "category_id": 3, "id": 4}, {"bbox": [808.9, 278.55, 503.87, 325.87], "category_id": 1, "id": 5}, {"bbox": [484.93, 283.28, 302.33, 258.27], "category_id": 1, "id": 6}, {"bbox": [1003.01, 58.14, 279.33, 91.95], "category_id": 1, "id": 7}, {"bbox": [630.35, 519.91, 41.25, 41.24], "category_id": 3, "id": 8}, {"bbox": [73.72, 718.0, 140.48, 103.45], "category_id": 1, "id": 9}, {"bbox": [1000.98, 167.67, 258.36, 39.21], "category_id": 3, "id": 10}, {"bbox": [564.07, 38.54, 242.13, 60.56], "category_id": 1, "id": 11}, {"bbox": [952.28, 957.34, 366.58, 134.54], "category_id": 1, "id": 12}, {"bbox": [244.83, 523.29, 35.17, 38.54], "category_id": 3, "id": 13}, {"bbox": [550.54, 955.31, 320.58, 126.43], "category_id": 1, "id": 14}, {"bbox": [10.15, 957.34, 412.56, 122.37], "category_id": 1, "id": 15}], "caption": "Scheme 1. 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Preparation of 9c", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 611, 110], "ImageBB": [448, 116, 787, 319]}, "diagram_type": "multiple", "corefs": [[8, 6], [7, 4], [5, 0], [5, 3]]}, {"id": 973, "width": 1356, "height": 520, "file_name": "jo400501k-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [408.36, 0.0, 217.07, 166.25], "category_id": 1, "id": 0}, {"bbox": [1136.22, 289.07, 215.71, 188.65], "category_id": 1, "id": 1}, {"bbox": [1160.64, 2.71, 187.22, 171.01], "category_id": 1, "id": 2}, {"bbox": [4.07, 21.04, 230.64, 143.85], "category_id": 1, "id": 3}, {"bbox": [790.94, 0.0, 191.97, 181.86], "category_id": 1, "id": 4}], "caption": "Scheme 6. Mechanism of the Diamine Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 636, 721, 651], "ImageBB": [448, 657, 787, 787]}, "diagram_type": "tree", "corefs": []}, {"id": 974, "width": 1352, "height": 1076, "file_name": "jo400755q-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [75.5, 273.89, 470.98, 287.41], "category_id": 1, "id": 0}, {"bbox": [685.81, 697.9, 392.27, 288.09], "category_id": 1, "id": 1}, {"bbox": [622.23, 248.19, 504.55, 345.57], "category_id": 1, "id": 2}, {"bbox": [344.93, 2.71, 181.94, 233.31], "category_id": 1, "id": 3}, {"bbox": [101.45, 702.64, 395.66, 287.41], "category_id": 1, "id": 4}, {"bbox": [253.55, 476.63, 31.0, 46.5], "category_id": 3, "id": 5}, {"bbox": [792.2, 510.22, 36.17, 46.5], "category_id": 3, "id": 6}, {"bbox": [1123.4, 778.38, 150.82, 252.24], "category_id": 1, "id": 7}], "caption": "Scheme 3. Plausible Catalytic Cycle", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 675, 284, 690], "ImageBB": [82, 696, 420, 965]}, "diagram_type": "graph", "corefs": [[0, 5], [2, 6]]}, {"id": 975, "width": 1352, "height": 896, "file_name": "jo401608v-Scheme-c8.png", "license": 0, "bboxes": [{"bbox": [77.1, 0.0, 302.33, 293.67], "category_id": 1, "id": 0}, {"bbox": [1169.39, 566.36, 52.08, 55.48], "category_id": 3, "id": 1}, {"bbox": [167.73, 585.3, 62.22, 56.84], "category_id": 3, "id": 2}, {"bbox": [577.59, 581.24, 273.24, 274.05], "category_id": 1, "id": 3}, {"bbox": [663.49, 778.83, 54.78, 57.51], "category_id": 3, "id": 4}, {"bbox": [186.67, 757.85, 248.22, 66.99], "category_id": 1, "id": 5}, {"bbox": [97.39, 232.09, 100.1, 60.22], "category_id": 3, "id": 6}, {"bbox": [124.45, 337.65, 329.37, 303.82], "category_id": 1, "id": 7}, {"bbox": [1142.34, 150.22, 102.12, 63.6], "category_id": 3, "id": 8}, {"bbox": [124.45, 761.91, 54.78, 62.93], "category_id": 3, "id": 9}, {"bbox": [973.25, 337.65, 298.94, 241.56], "category_id": 1, "id": 10}, {"bbox": [996.92, 0.0, 275.27, 211.79], "category_id": 1, "id": 11}], "caption": "Scheme 8. Plausible Mechanism", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 683, 263, 698], "ImageBB": [82, 705, 420, 929]}, "diagram_type": "graph", "corefs": [[0, 6], [11, 8], [10, 1], [3, 4], [7, 2], [5, 9]]}, {"id": 976, "width": 1356, "height": 1564, "file_name": "jo4027148-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [800.98, 50.07, 534.24, 416.24], "category_id": 1, "id": 0}, {"bbox": [800.98, 1105.52, 531.89, 353.64], "category_id": 1, "id": 1}, {"bbox": [263.6, 1474.03, 62.58, 51.63], "category_id": 3, "id": 2}, {"bbox": [31.29, 1125.86, 531.11, 351.29], "category_id": 1, "id": 3}, {"bbox": [31.29, 548.46, 531.11, 347.38], "category_id": 1, "id": 4}, {"bbox": [1035.64, 422.49, 61.01, 47.73], "category_id": 3, "id": 5}, {"bbox": [267.51, 891.93, 57.89, 42.25], "category_id": 3, "id": 6}, {"bbox": [31.29, 50.07, 531.11, 352.08], "category_id": 1, "id": 7}, {"bbox": [263.6, 422.49, 66.49, 50.07], "category_id": 3, "id": 8}, {"bbox": [1034.85, 1474.03, 63.36, 50.07], "category_id": 3, "id": 9}, {"bbox": [554.58, 28.95, 252.65, 143.18], "category_id": 1, "id": 10}, {"bbox": [649.23, 175.26, 63.36, 48.5], "category_id": 3, "id": 11}, {"bbox": [1034.85, 891.14, 63.36, 43.04], "category_id": 3, "id": 12}, {"bbox": [800.98, 544.54, 531.89, 351.3], "category_id": 1, "id": 13}], "caption": "Scheme 10. Controlled C-3 Epimerization of 82", "pdf": {"Page": 12, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 720, 110], "ImageBB": [448, 116, 787, 507]}, "diagram_type": "graph", "corefs": [[7, 8], [10, 11], [0, 5], [4, 6], [13, 12], [3, 2], [1, 9]]}, {"id": 977, "width": 2820, "height": 1232, "file_name": "jo4027148-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [1627.95, 436.18, 74.77, 56.46], "category_id": 3, "id": 0}, {"bbox": [132.61, 149.63, 342.8, 231.5], "category_id": 1, "id": 1}, {"bbox": [1702.72, 571.69, 892.98, 602.74], "category_id": 1, "id": 2}, {"bbox": [1296.44, 200.44, 66.3, 50.82], "category_id": 3, "id": 3}, {"bbox": [2092.08, 1130.67, 156.58, 60.7], "category_id": 3, "id": 4}, {"bbox": [2382.68, 431.94, 73.36, 62.11], "category_id": 3, "id": 5}, {"bbox": [179.16, 678.97, 362.55, 381.13], "category_id": 1, "id": 6}, {"bbox": [949.4, 604.16, 469.77, 529.34], "category_id": 1, "id": 7}, {"bbox": [1093.3, 1033.28, 77.59, 70.57], "category_id": 3, "id": 8}, {"bbox": [632.0, 606.98, 213.01, 217.38], "category_id": 1, "id": 9}, {"bbox": [293.43, 391.01, 77.59, 62.11], "category_id": 3, "id": 10}, {"bbox": [787.17, 77.64, 386.54, 378.3], "category_id": 1, "id": 11}, {"bbox": [497.98, 276.67, 266.62, 151.04], "category_id": 1, "id": 12}, {"bbox": [293.43, 1043.16, 73.35, 56.46], "category_id": 3, "id": 13}, {"bbox": [2238.79, 43.76, 450.01, 440.41], "category_id": 1, "id": 14}, {"bbox": [1485.47, 4.23, 472.59, 520.88], "category_id": 1, "id": 15}, {"bbox": [924.01, 436.18, 79.0, 56.46], "category_id": 3, "id": 16}, {"bbox": [1224.49, 12.7, 205.97, 213.15], "category_id": 1, "id": 17}], "caption": "Scheme 5. Successful Deprotection of the Picolinimide Directing Group", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 267, 489, 282], "ImageBB": [82, 288, 787, 596]}, "diagram_type": "multiple", "corefs": [[1, 10], [11, 16], [17, 3], [15, 0], [14, 5], [6, 13], [7, 8], [2, 4]]}, {"id": 978, "width": 1148, "height": 1120, "file_name": "jo402749d-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [0.0, 783.62, 693.16, 222.91], "category_id": 1, "id": 0}, {"bbox": [771.27, 705.9, 376.73, 355.78], "category_id": 1, "id": 1}, {"bbox": [859.71, 0.0, 288.29, 461.9], "category_id": 1, "id": 2}, {"bbox": [103.95, 334.36, 493.31, 329.77], "category_id": 1, "id": 3}], "caption": "Scheme 2. GB Reaction of Mixed Propargyl Systems", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 261, 379, 276], "ImageBB": [149, 282, 436, 562]}, "diagram_type": "tree", "corefs": []}, {"id": 979, "width": 3396, "height": 1148, "file_name": "jo500696n-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [693.13, 531.28, 95.14, 50.93], "category_id": 3, "id": 0}, {"bbox": [1172.21, 548.26, 372.04, 276.67], "category_id": 1, "id": 1}, {"bbox": [1858.54, 548.26, 375.45, 278.37], "category_id": 1, "id": 2}, {"bbox": [1100.85, 40.74, 445.1, 220.66], "category_id": 1, "id": 3}, {"bbox": [445.1, 290.25, 530.04, 266.5], "category_id": 1, "id": 4}, {"bbox": [1810.97, 40.74, 441.7, 218.96], "category_id": 1, "id": 5}, {"bbox": [2509.2, 45.83, 438.3, 213.87], "category_id": 1, "id": 6}, {"bbox": [2568.66, 549.96, 363.55, 271.58], "category_id": 1, "id": 7}], "caption": "Scheme 2. Possible Photocyclization Pathways for 2-Styrylquinolines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 808, 468, 823], "ImageBB": [10, 840, 859, 1127]}, "diagram_type": "tree", "corefs": [[4, 0]]}, {"id": 980, "width": 2820, "height": 852, "file_name": "jo501180a-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [696.89, 748.59, 59.25, 60.62], "category_id": 3, "id": 0}, {"bbox": [589.67, 0.0, 283.56, 714.76], "category_id": 1, "id": 1}, {"bbox": [2447.57, 0.0, 372.43, 717.58], "category_id": 1, "id": 2}, {"bbox": [93.11, 631.58, 59.25, 66.26], "category_id": 3, "id": 3}, {"bbox": [1867.77, 752.82, 76.18, 62.03], "category_id": 3, "id": 4}, {"bbox": [2606.98, 752.82, 52.2, 59.21], "category_id": 3, "id": 5}, {"bbox": [1393.78, 752.82, 55.01, 59.21], "category_id": 3, "id": 6}, {"bbox": [1704.13, 0.0, 375.25, 717.58], "category_id": 1, "id": 7}, {"bbox": [1227.31, 0.0, 380.89, 717.58], "category_id": 1, "id": 8}, {"bbox": [0.0, 101.5, 249.69, 506.12], "category_id": 1, "id": 9}], "caption": "Scheme 1. Synthesis of Regioisomerically Pure 1,7-Dibromoperylene-3,4,9,10-tetracarboxy Tetrabutylester 3 from PBA 1", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 343, 760, 358], "ImageBB": [82, 364, 787, 577]}, "diagram_type": "single", "corefs": [[9, 3], [1, 0], [8, 6], [7, 4], [2, 5]]}, {"id": 981, "width": 1356, "height": 1224, "file_name": "jo501736w-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1202.02, 854.2, 51.55, 54.28], "category_id": 3, "id": 0}, {"bbox": [630.7, 50.3, 261.32, 182.1], "category_id": 1, "id": 1}, {"bbox": [944.93, 2.71, 170.94, 108.39], "category_id": 1, "id": 2}, {"bbox": [754.31, 230.68, 54.27, 50.21], "category_id": 3, "id": 3}, {"bbox": [93.61, 322.28, 396.83, 174.36], "category_id": 1, "id": 4}, {"bbox": [388.01, 926.8, 383.94, 194.72], "category_id": 1, "id": 5}, {"bbox": [223.85, 207.61, 43.42, 49.53], "category_id": 3, "id": 6}, {"bbox": [733.96, 316.85, 385.3, 196.75], "category_id": 1, "id": 7}, {"bbox": [991.05, 507.5, 50.2, 50.88], "category_id": 3, "id": 8}, {"bbox": [269.98, 515.64, 48.16, 52.24], "category_id": 3, "id": 9}, {"bbox": [972.06, 700.19, 383.94, 147.22], "category_id": 1, "id": 10}, {"bbox": [1019.54, 93.63, 48.84, 46.81], "category_id": 3, "id": 11}, {"bbox": [389.37, 668.3, 383.94, 196.75], "category_id": 1, "id": 12}, {"bbox": [97.68, 54.96, 253.7, 147.23], "category_id": 1, "id": 13}, {"bbox": [623.39, 860.98, 43.42, 46.82], "category_id": 3, "id": 14}, {"bbox": [623.39, 1129.66, 42.06, 47.49], "category_id": 3, "id": 15}], "caption": "Scheme 3. A Proposed Mechanism for the Halide-Mediated Electrochemical Synthesis of 2-Aminobenzoxazoles ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 233, 784, 263], "ImageBB": [448, 269, 787, 575]}, "diagram_type": "graph", "corefs": [[13, 6], [1, 3], [2, 11], [4, 9], [7, 8], [12, 14], [10, 0], [5, 15]]}, {"id": 982, "width": 1340, "height": 512, "file_name": "jo9519672-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [4.69, 4.02, 187.7, 217.33], "category_id": 1, "id": 0}, {"bbox": [811.11, 69.09, 327.12, 191.84], "category_id": 1, "id": 1}, {"bbox": [95.19, 311.23, 327.79, 194.53], "category_id": 1, "id": 2}, {"bbox": [355.95, 72.44, 282.21, 157.63], "category_id": 1, "id": 3}, {"bbox": [588.55, 310.56, 325.79, 191.84], "category_id": 1, "id": 4}, {"bbox": [1049.74, 319.95, 290.26, 186.48], "category_id": 1, "id": 5}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [562, 240, 631, 254], "ImageBB": [430, 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9}], "caption": "Scheme 3 a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 196, 637, 210], "ImageBB": [442, 215, 774, 429]}, "diagram_type": "multiple", "corefs": [[7, 8], [1, 3], [0, 9], [2, 6], [4, 5]]}, {"id": 1015, "width": 1352, "height": 980, "file_name": "ol0362663-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [455.18, 639.97, 307.73, 224.59], "category_id": 1, "id": 0}, {"bbox": [708.8, 111.62, 55.46, 49.39], "category_id": 3, "id": 1}, {"bbox": [524.84, 849.68, 78.45, 50.06], "category_id": 3, "id": 2}, {"bbox": [741.27, 327.42, 530.92, 304.43], "category_id": 1, "id": 3}, {"bbox": [406.48, 103.5, 40.58, 51.42], "category_id": 3, "id": 4}, {"bbox": [640.49, 0.0, 234.69, 151.54], "category_id": 1, "id": 5}, {"bbox": [83.19, 424.84, 308.41, 192.8], "category_id": 1, "id": 6}, {"bbox": [315.85, 0.0, 261.74, 151.54], "category_id": 1, "id": 7}, {"bbox": [881.94, 82.53, 137.3, 83.21], "category_id": 1, "id": 8}, {"bbox": [162.32, 604.79, 60.87, 52.77], "category_id": 3, "id": 9}], "caption": "Scheme 2. Regioselective monooxidation-A Proposal", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [95, 145, 387, 158], "ImageBB": [73, 165, 411, 410]}, "diagram_type": "graph", "corefs": [[7, 4], [5, 1], [6, 9], [0, 2]]}, {"id": 1016, "width": 1352, "height": 552, "file_name": "ol0514606-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [20.97, 0.0, 431.5, 154.95], "category_id": 1, "id": 0}, {"bbox": [93.33, 304.49, 433.54, 153.6], "category_id": 1, "id": 1}, {"bbox": [915.76, 157.66, 29.08, 38.57], "category_id": 3, "id": 2}, {"bbox": [1034.8, 438.46, 27.73, 36.54], "category_id": 3, "id": 3}, {"bbox": [280.68, 454.03, 29.08, 37.89], "category_id": 3, "id": 4}, {"bbox": [785.9, 252.39, 448.42, 182.69], "category_id": 1, "id": 5}, {"bbox": [657.4, 8.8, 432.18, 124.5], "category_id": 1, "id": 6}, {"bbox": [253.63, 163.07, 54.1, 41.95], "category_id": 3, "id": 7}], "caption": "Scheme 5", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 712, 631, 725], "ImageBB": [439, 730, 777, 868]}, "diagram_type": "multiple", "corefs": [[0, 7], [6, 2], [1, 4], [5, 3]]}, {"id": 1017, "width": 1352, "height": 488, "file_name": "ol0604623-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [432.18, 41.27, 270.54, 67.65], "category_id": 1, "id": 0}, {"bbox": [436.91, 156.96, 259.72, 161.69], "category_id": 1, "id": 1}, {"bbox": [246.86, 79.83, 177.2, 150.19], "category_id": 1, "id": 2}, {"bbox": [1074.7, 336.24, 156.24, 46.68], "category_id": 3, "id": 3}, {"bbox": [747.35, 4.06, 240.78, 219.2], "category_id": 1, "id": 4}, {"bbox": [0.0, 97.42, 234.01, 225.29], "category_id": 1, "id": 5}, {"bbox": [963.78, 110.28, 388.22, 221.22], "category_id": 1, "id": 6}, {"bbox": [503.87, 311.88, 163.0, 121.1], "category_id": 3, "id": 7}, {"bbox": [79.81, 330.83, 156.23, 47.35], "category_id": 3, "id": 8}, {"bbox": [529.57, 103.51, 36.53, 36.53], "category_id": 3, "id": 9}], "caption": "Scheme 1. Reaction of Huisgen Zwitterion with Cyclic and                  Acyclic 1,2-Diones ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [448, 811, 767, 838], "ImageBB": [439, 842, 777, 964]}, "diagram_type": "single", "corefs": [[5, 8], [0, 9], [1, 7], [6, 3]]}, {"id": 1018, "width": 1352, "height": 1312, "file_name": "ol060531d-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1125.43, 284.64, 59.51, 55.44], "category_id": 3, "id": 0}, {"bbox": [1029.39, 32.45, 194.11, 175.79], "category_id": 1, "id": 1}, {"bbox": [954.99, 1210.91, 61.55, 47.33], "category_id": 3, "id": 2}, {"bbox": [551.89, 383.35, 676.34, 298.17], "category_id": 1, "id": 3}, {"bbox": [968.52, 686.93, 48.02, 47.32], "category_id": 3, "id": 4}, {"bbox": [563.39, 290.73, 68.99, 45.3], "category_id": 3, "id": 5}, {"bbox": [551.89, 745.75, 666.2, 453.67], "category_id": 1, "id": 6}, {"bbox": [348.99, 0.0, 470.06, 300.19], "category_id": 1, "id": 7}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 278, 631, 291], "ImageBB": [439, 296, 777, 624]}, "diagram_type": "multiple", "corefs": [[7, 5], [1, 0], [3, 4], [6, 2]]}, {"id": 1019, "width": 1352, "height": 908, "file_name": "ol060868f-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [32.46, 546.63, 351.7, 250.99], "category_id": 1, "id": 0}, {"bbox": [806.2, 4.06, 506.57, 286.17], "category_id": 1, "id": 1}, {"bbox": [165.03, 796.94, 43.96, 50.74], "category_id": 3, "id": 2}, {"bbox": [32.46, 54.8, 258.37, 225.28], "category_id": 1, "id": 3}, {"bbox": [963.78, 290.23, 38.55, 52.09], "category_id": 3, "id": 4}, {"bbox": [165.03, 286.17, 43.28, 54.12], "category_id": 3, "id": 5}, {"bbox": [806.2, 508.74, 503.19, 290.91], "category_id": 1, "id": 6}, {"bbox": [963.78, 798.29, 44.64, 52.77], "category_id": 3, "id": 7}], "caption": "Scheme 1. Enantioselective Preparation of 6", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [121, 262, 362, 275], "ImageBB": [73, 279, 411, 506]}, "diagram_type": "tree", "corefs": [[3, 5], [1, 4], [6, 7], [0, 2]]}, {"id": 1020, "width": 1352, "height": 1344, "file_name": "ol060868f-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1000.3, 824.53, 79.81, 60.87], "category_id": 3, "id": 0}, {"bbox": [372.3, 1162.72, 277.66, 61.58], "category_id": 3, "id": 1}, {"bbox": [372.65, 1235.84, 271.05, 54.86], "category_id": 3, "id": 2}, {"bbox": [698.66, 570.88, 525.51, 242.82], "category_id": 1, "id": 3}, {"bbox": [131.21, 641.22, 516.05, 495.8], "category_id": 1, "id": 4}, {"bbox": [1004.36, 260.41, 85.22, 60.2], "category_id": 3, "id": 5}, {"bbox": [765.61, 2.71, 442.33, 247.56], "category_id": 1, "id": 6}], "caption": "Scheme 4. Synthesis of Nucleoside Analogues 17 and 18", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 408, 760, 421], "ImageBB": [439, 426, 777, 762]}, "diagram_type": "tree", "corefs": [[6, 5], [3, 0], [4, 1], [4, 2]]}, {"id": 1021, "width": 1352, "height": 940, "file_name": "ol0616236-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [706.77, 609.92, 438.27, 267.09], "category_id": 1, "id": 0}, {"bbox": [343.58, 4.06, 173.82, 242.07], "category_id": 1, "id": 1}, {"bbox": [213.72, 841.17, 54.79, 43.28], "category_id": 3, "id": 2}, {"bbox": [31.11, 607.21, 442.33, 265.07], "category_id": 1, "id": 3}, {"bbox": [83.19, 202.18, 173.14, 109.54], "category_id": 1, "id": 4}, {"bbox": [827.84, 332.68, 221.16, 159.58], "category_id": 1, "id": 5}, {"bbox": [918.47, 843.2, 45.31, 39.22], "category_id": 3, "id": 6}, {"bbox": [629.67, 69.65, 283.39, 241.4], "category_id": 1, "id": 7}], "caption": "Scheme 3. Synthesis and Fluorination of 1c", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [122, 157, 360, 170], "ImageBB": [73, 174, 411, 409]}, "diagram_type": "tree", "corefs": [[3, 2], [0, 6]]}, {"id": 1022, "width": 1352, "height": 3784, "file_name": "ol070339r-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [250.01, 295.3, 806.86, 461.88], "category_id": 1, "id": 0}, {"bbox": [659.12, 1162.27, 49.25, 51.11], "category_id": 3, "id": 1}, {"bbox": [659.12, 579.24, 49.25, 45.43], "category_id": 3, "id": 2}, {"bbox": [257.59, 760.96, 812.54, 520.56], "category_id": 1, "id": 3}, {"bbox": [511.39, 257.44, 49.24, 49.22], "category_id": 3, "id": 4}, {"bbox": [1045.51, 104.11, 43.56, 49.22], "category_id": 3, "id": 5}, {"bbox": [234.86, 35.97, 492.45, 291.51], "category_id": 1, "id": 6}, {"bbox": [833.37, 0.0, 280.32, 191.19], "category_id": 1, "id": 7}, {"bbox": [767.08, 586.81, 198.88, 136.3], "category_id": 1, "id": 8}, {"bbox": [971.64, 630.35, 39.77, 51.11], "category_id": 3, "id": 9}], "caption": "Scheme 1. Synthesis of 1 and the Corresponding Eu(III)                      Complex ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [457, 75, 756, 102], "ImageBB": [439, 107, 777, 1053]}, "diagram_type": "tree", "corefs": [[7, 5], [6, 4], [3, 2], [8, 9], [3, 1]]}, {"id": 1023, "width": 1352, "height": 1100, "file_name": "ol1009703-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [829.19, 2.03, 327.35, 228.97], "category_id": 1, "id": 0}, {"bbox": [351.7, 993.8, 37.19, 45.29], "category_id": 3, "id": 1}, {"bbox": [198.17, 8.79, 320.58, 217.01], "category_id": 1, "id": 2}, {"bbox": [333.43, 600.33, 46.0, 41.24], "category_id": 3, "id": 3}, {"bbox": [336.82, 190.65, 36.52, 45.29], "category_id": 3, "id": 4}, {"bbox": [971.22, 994.47, 37.2, 45.97], "category_id": 3, "id": 5}, {"bbox": [183.29, 774.08, 323.29, 208.9], "category_id": 1, "id": 6}, {"bbox": [973.25, 202.14, 35.17, 43.94], "category_id": 3, "id": 7}, {"bbox": [974.5, 602.11, 33.02, 39.62], "category_id": 3, "id": 8}, {"bbox": [165.03, 381.97, 321.26, 211.6], "category_id": 1, "id": 9}, {"bbox": [846.78, 768.67, 280.0, 230.33], "category_id": 1, "id": 10}, {"bbox": [847.45, 401.58, 285.42, 234.12], "category_id": 1, "id": 11}], "caption": "Scheme 2. Pathways Available to the Organopalladium Species            Where Alternatives Are Lettered A-E ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [62, 487, 391, 515], "ImageBB": [58, 524, 396, 799]}, "diagram_type": "graph", "corefs": [[2, 4], [0, 7], [11, 8], [9, 3], [11, 8], [6, 1], [10, 5]]}, {"id": 1024, "width": 1344, "height": 1348, "file_name": "ol1030487-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [122.06, 186.12, 53.27, 34.39], "category_id": 3, "id": 0}, {"bbox": [208.38, 575.88, 45.85, 37.77], "category_id": 3, "id": 1}, {"bbox": [0.0, 302.1, 193.54, 60.69], "category_id": 1, "id": 2}, {"bbox": [75.53, 397.86, 259.63, 160.49], "category_id": 1, "id": 3}, {"bbox": [573.21, 22.25, 187.47, 62.04], "category_id": 1, "id": 4}, {"bbox": [1157.2, 296.71, 182.75, 57.99], "category_id": 1, "id": 5}, {"bbox": [1228.01, 354.03, 45.18, 37.09], "category_id": 3, "id": 6}, {"bbox": [716.84, 79.57, 51.93, 35.74], "category_id": 3, "id": 7}, {"bbox": [397.87, 367.51, 95.76, 93.74], "category_id": 1, "id": 8}, {"bbox": [1031.77, 410.67, 256.93, 158.47], "category_id": 1, "id": 9}, {"bbox": [847.67, 373.58, 91.04, 86.32], "category_id": 1, "id": 10}, {"bbox": [716.84, 987.23, 313.58, 354.7], "category_id": 1, "id": 11}, {"bbox": [735.05, 231.3, 29.0, 32.37], "category_id": 3, "id": 12}, {"bbox": [99.81, 26.3, 241.42, 196.23], "category_id": 1, "id": 13}, {"bbox": [656.83, 550.26, 46.53, 35.74], "category_id": 3, "id": 14}, {"bbox": [1018.28, 22.25, 293.35, 191.51], "category_id": 1, "id": 15}, {"bbox": [1208.45, 546.89, 47.21, 42.48], "category_id": 3, "id": 16}, {"bbox": [1256.16, 179.71, 43.7, 37.05], "category_id": 3, "id": 17}, {"bbox": [321.0, 931.93, 353.36, 397.47], "category_id": 1, "id": 18}, {"bbox": [573.21, 175.33, 206.35, 51.92], "category_id": 1, "id": 19}, {"bbox": [545.56, 391.12, 258.28, 142.28], "category_id": 1, "id": 20}], "caption": "Scheme 1. Plan for the Dichotomous Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 621, 320, 634], "ImageBB": [71, 644, 407, 981]}, "diagram_type": "tree", "corefs": [[13, 0], [4, 7], [19, 12], [15, 17], [5, 6], [9, 16], [20, 14], [3, 1]]}, {"id": 1025, "width": 1344, "height": 1204, "file_name": "ol200717n-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [135.81, 28.91, 467.95, 322.09], "category_id": 1, "id": 0}, {"bbox": [879.42, 940.71, 163.37, 96.83], "category_id": 3, "id": 1}, {"bbox": [343.56, 714.11, 60.51, 50.43], "category_id": 3, "id": 2}, {"bbox": [766.46, 0.0, 393.32, 373.86], "category_id": 1, "id": 3}, {"bbox": [293.14, 1064.44, 160.69, 94.14], "category_id": 3, "id": 4}, {"bbox": [878.74, 375.88, 162.04, 94.81], "category_id": 3, "id": 5}, {"bbox": [175.48, 481.45, 389.28, 280.4], "category_id": 1, "id": 6}, {"bbox": [143.21, 834.47, 454.5, 223.92], "category_id": 1, "id": 7}, {"bbox": [260.19, 377.23, 226.58, 53.12], "category_id": 3, "id": 8}, {"bbox": [763.77, 663.68, 391.98, 275.69], "category_id": 1, "id": 9}], "caption": "Scheme 4. Elaboration of Triol 11", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 430, 253, 443], "ImageBB": [71, 455, 407, 756]}, "diagram_type": "tree", "corefs": [[0, 8], [3, 5], [6, 2], [9, 1], [7, 4]]}, {"id": 1026, "width": 1356, "height": 1136, "file_name": "ol202027k-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [502.65, 539.15, 270.66, 141.06], "category_id": 1, "id": 0}, {"bbox": [972.74, 879.59, 383.26, 215.66], "category_id": 1, "id": 1}, {"bbox": [326.28, 176.33, 266.59, 330.95], "category_id": 1, "id": 2}, {"bbox": [866.24, 427.25, 58.34, 54.93], "category_id": 3, "id": 3}, {"bbox": [830.29, 260.42, 250.98, 143.09], "category_id": 1, "id": 4}, {"bbox": [349.34, 547.97, 117.36, 208.87], "category_id": 1, "id": 5}, {"bbox": [1136.9, 707.34, 58.33, 61.71], "category_id": 3, "id": 6}, {"bbox": [797.73, 0.0, 126.85, 208.88], "category_id": 1, "id": 7}, {"bbox": [400.22, 875.53, 294.4, 215.66], "category_id": 1, "id": 8}, {"bbox": [553.52, 704.63, 63.77, 57.64], "category_id": 3, "id": 9}, {"bbox": [439.56, 6.1, 121.43, 145.81], "category_id": 1, "id": 10}, {"bbox": [972.06, 566.28, 383.94, 209.92], "category_id": 1, "id": 11}], "caption": "Scheme 2. Plausible Reaction Mechanism for the Copper-Cat- alyzed Soft Enolization Perkin Acyl-Mannich Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 402, 116], "ImageBB": [71, 127, 410, 411]}, "diagram_type": "tree", "corefs": [[4, 3], [0, 9], [11, 6]]}, {"id": 1027, "width": 1356, "height": 1104, "file_name": "ol202027k-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [69.87, 666.98, 204.86, 73.95], "category_id": 3, "id": 0}, {"bbox": [299.83, 0.0, 177.72, 228.66], "category_id": 1, "id": 1}, {"bbox": [894.73, 236.8, 50.87, 40.03], "category_id": 3, "id": 2}, {"bbox": [720.4, 670.37, 47.48, 41.39], "category_id": 3, "id": 3}, {"bbox": [230.64, 792.5, 259.8, 238.84], "category_id": 1, "id": 4}, {"bbox": [272.69, 1007.59, 48.16, 40.03], "category_id": 3, "id": 5}, {"bbox": [89.54, 400.32, 182.47, 251.73], "category_id": 1, "id": 6}, {"bbox": [823.5, 22.39, 257.77, 206.27], "category_id": 1, "id": 7}, {"bbox": [1102.3, 662.23, 201.47, 71.24], "category_id": 3, "id": 8}, {"bbox": [655.28, 381.32, 253.69, 268.01], "category_id": 1, "id": 9}, {"bbox": [776.7, 845.42, 447.02, 162.85], "category_id": 1, "id": 10}, {"bbox": [356.81, 202.87, 50.87, 35.97], "category_id": 3, "id": 11}, {"bbox": [934.75, 997.41, 34.6, 37.32], "category_id": 3, "id": 12}, {"bbox": [1102.3, 445.78, 249.63, 206.27], "category_id": 1, "id": 13}], "caption": "Scheme 3. Simple Elaborations of Inverse Adducts", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 341, 102], "ImageBB": [71, 113, 410, 389]}, "diagram_type": "multiple", "corefs": [[1, 11], [7, 2], [13, 8], [9, 3], [6, 0], [4, 5], [10, 12]]}, {"id": 1028, "width": 1344, "height": 680, "file_name": "ol202381m-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [24.88, 12.11, 236.66, 172.23], "category_id": 1, "id": 0}, {"bbox": [728.14, 220.0, 58.49, 43.05], "category_id": 3, "id": 1}, {"bbox": [567.45, 532.16, 289.78, 96.21], "category_id": 3, "id": 2}, {"bbox": [89.42, 530.82, 52.44, 46.42], "category_id": 3, "id": 3}, {"bbox": [602.41, 280.54, 187.58, 240.86], "category_id": 1, "id": 4}, {"bbox": [1122.8, 528.12, 55.13, 51.81], "category_id": 3, "id": 5}, {"bbox": [665.61, 12.78, 207.75, 200.49], "category_id": 1, "id": 6}, {"bbox": [1056.91, 280.54, 262.21, 251.62], "category_id": 1, "id": 7}, {"bbox": [24.2, 279.87, 342.22, 275.84], "category_id": 1, "id": 8}, {"bbox": [89.42, 219.32, 59.84, 43.73], "category_id": 3, "id": 9}, {"bbox": [949.9, 16.15, 310.73, 48.44], "category_id": 1, "id": 10}], "caption": "Scheme 2. Synthesis of Curtius Rearrangement Precursor 10", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 305, 757, 318], "ImageBB": [437, 329, 773, 499]}, "diagram_type": "multiple", "corefs": [[0, 9], [6, 1], [7, 5], [4, 2], [8, 3]]}, {"id": 1029, "width": 1344, "height": 1548, "file_name": "ol300353w-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [234.71, 790.65, 53.45, 46.46], "category_id": 3, "id": 0}, {"bbox": [941.15, 0.0, 250.98, 161.07], "category_id": 1, "id": 1}, {"bbox": [492.65, 144.04, 60.42, 45.68], "category_id": 3, "id": 2}, {"bbox": [33.31, 625.7, 453.92, 215.28], "category_id": 1, "id": 3}, {"bbox": [1018.61, 430.56, 61.2, 47.24], "category_id": 3, "id": 4}, {"bbox": [49.58, 313.63, 336.95, 164.17], "category_id": 1, "id": 5}, {"bbox": [285.83, 0.0, 371.04, 212.18], "category_id": 1, "id": 6}, {"bbox": [276.17, 971.94, 314.06, 286.18], "category_id": 1, "id": 7}, {"bbox": [680.88, 425.91, 59.65, 49.56], "category_id": 3, "id": 8}, {"bbox": [1022.49, 147.13, 67.39, 44.92], "category_id": 3, "id": 9}, {"bbox": [255.62, 424.36, 61.2, 49.56], "category_id": 3, "id": 10}, {"bbox": [684.76, 992.76, 300.54, 243.94], "category_id": 1, "id": 11}, {"bbox": [780.81, 626.48, 250.2, 159.52], "category_id": 1, "id": 12}, {"bbox": [484.91, 313.63, 340.05, 165.72], "category_id": 1, "id": 13}, {"bbox": [941.15, 282.65, 254.07, 159.53], "category_id": 1, "id": 14}, {"bbox": [1169.66, 933.91, 62.74, 48.79], "category_id": 3, "id": 15}, {"bbox": [1076.71, 763.55, 248.65, 215.28], "category_id": 1, "id": 16}, {"bbox": [876.86, 788.33, 64.29, 48.78], "category_id": 3, "id": 17}], "caption": "Scheme 6. Configurational Assignment of the Syn-Selective Aldol Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 753, 116], "ImageBB": [437, 127, 773, 514]}, "diagram_type": "multiple", "corefs": [[6, 2], [1, 9], [14, 4], [13, 8], [5, 10], [3, 0], [12, 17], [16, 15]]}, {"id": 1030, "width": 1356, "height": 1796, "file_name": "ol4005905-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [850.3, 841.85, 454.81, 244.38], "category_id": 1, "id": 0}, {"bbox": [677.0, 371.96, 394.41, 110.51], "category_id": 1, "id": 1}, {"bbox": [592.33, 67.38, 271.45, 243.48], "category_id": 1, "id": 2}, {"bbox": [1026.47, 434.85, 324.48, 362.07], "category_id": 1, "id": 3}, {"bbox": [474.58, 835.56, 306.51, 278.52], "category_id": 1, "id": 4}, {"bbox": [581.55, 778.06, 155.49, 50.31], "category_id": 3, "id": 5}, {"bbox": [17.08, 111.41, 343.35, 141.95], "category_id": 1, "id": 6}, {"bbox": [135.72, 579.5, 65.62, 53.01], "category_id": 3, "id": 7}, {"bbox": [671.7, 0.0, 201.97, 57.5], "category_id": 1, "id": 8}, {"bbox": [0.0, 374.8, 556.38, 378.1], "category_id": 1, "id": 9}, {"bbox": [1122.64, 672.04, 65.62, 53.91], "category_id": 3, "id": 10}, {"bbox": [981.53, 53.01, 280.43, 257.85], "category_id": 1, "id": 11}, {"bbox": [929.39, 777.16, 136.63, 51.21], "category_id": 3, "id": 12}], "caption": "Scheme 1. Initial Unexpected Observations", "pdf": {"Page": 1, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 549, 666, 562], "ImageBB": [436, 574, 775, 1023]}, "diagram_type": "graph", "corefs": [[9, 7], [4, 5], [0, 12], [3, 10]]}, {"id": 1031, "width": 1228, "height": 592, "file_name": "ol401042b-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [817.64, 357.31, 273.98, 179.28], "category_id": 1, "id": 0}, {"bbox": [217.46, 383.71, 385.18, 204.45], "category_id": 1, "id": 1}, {"bbox": [190.44, 0.0, 431.24, 248.65], "category_id": 1, "id": 2}, {"bbox": [729.18, 7.98, 498.82, 208.13], "category_id": 1, "id": 3}], "caption": "Scheme 3. Possible Mechanisms for the Annulation Reaction", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 762, 102], "ImageBB": [449, 112, 756, 260]}, "diagram_type": "tree", "corefs": []}, {"id": 1032, "width": 1344, "height": 580, "file_name": "ol4017244-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [26.89, 6.05, 302.55, 186.32], "category_id": 1, "id": 0}, {"bbox": [545.94, 54.48, 270.95, 135.2], "category_id": 1, "id": 1}, {"bbox": [1016.57, 2.69, 270.95, 183.63], "category_id": 1, "id": 2}, {"bbox": [543.25, 345.73, 303.22, 183.63], "category_id": 1, "id": 3}], "caption": "Scheme 1. Palladium-Catalyzed Carbonylative Couplings of Aryl Diazonium Salts ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 390, 116], "ImageBB": [71, 127, 407, 272]}, "diagram_type": "tree", "corefs": []}, {"id": 1033, "width": 1344, "height": 816, "file_name": "ol401881n-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [357.68, 106.94, 34.96, 48.43], "category_id": 3, "id": 0}, {"bbox": [39.0, 2.02, 379.19, 148.64], "category_id": 1, "id": 1}, {"bbox": [528.46, 548.84, 353.65, 193.04], "category_id": 1, "id": 2}, {"bbox": [635.36, 53.14, 135.14, 125.1], "category_id": 1, "id": 3}, {"bbox": [270.95, 275.09, 335.5, 207.84], "category_id": 1, "id": 4}, {"bbox": [954.05, 6.73, 348.27, 165.46], "category_id": 1, "id": 5}, {"bbox": [634.01, 720.36, 42.36, 46.41], "category_id": 3, "id": 6}, {"bbox": [378.53, 448.63, 30.92, 47.08], "category_id": 3, "id": 7}, {"bbox": [962.11, 468.8, 51.1, 45.74], "category_id": 3, "id": 8}, {"bbox": [810.84, 302.67, 350.96, 191.69], "category_id": 1, "id": 9}, {"bbox": [1033.38, 125.1, 45.72, 47.09], "category_id": 3, "id": 10}], "caption": "Scheme 3. Proposed Organocatalyzed Anion Relay Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 653, 771, 666], "ImageBB": [437, 678, 773, 882]}, "diagram_type": "graph", "corefs": [[1, 0], [5, 10], [4, 7], [9, 8], [2, 6]]}, {"id": 1034, "width": 1344, "height": 668, "file_name": "ol402871f-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1061.62, 234.48, 165.39, 143.11], "category_id": 1, "id": 0}, {"bbox": [103.54, 32.25, 230.61, 99.44], "category_id": 1, "id": 1}, {"bbox": [482.74, 262.03, 149.26, 98.09], "category_id": 1, "id": 2}, {"bbox": [36.3, 517.3, 266.92, 95.44], "category_id": 1, "id": 3}, {"bbox": [767.81, 260.01, 163.38, 116.23], "category_id": 1, "id": 4}, {"bbox": [998.42, 28.89, 258.85, 96.08], "category_id": 1, "id": 5}, {"bbox": [556.69, 32.25, 182.21, 101.45], "category_id": 1, "id": 6}, {"bbox": [909.0, 449.48, 264.23, 166.62], "category_id": 1, "id": 7}, {"bbox": [485.43, 474.33, 270.95, 141.77], "category_id": 1, "id": 8}], "caption": "Scheme 4. Plausible Reaction Mechanism", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 659, 102], "ImageBB": [437, 113, 773, 280]}, "diagram_type": "graph", "corefs": []}, {"id": 1035, "width": 1172, "height": 756, "file_name": "ol5028392-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [844.85, 201.06, 44.56, 49.24], "category_id": 3, "id": 0}, {"bbox": [7.62, 378.68, 589.23, 235.06], "category_id": 1, "id": 1}, {"bbox": [739.9, 12.9, 432.1, 231.54], "category_id": 1, "id": 2}, {"bbox": [205.79, 202.82, 36.94, 45.14], "category_id": 3, "id": 3}, {"bbox": [205.79, 566.85, 46.9, 45.72], "category_id": 3, "id": 4}, {"bbox": [5.28, 0.0, 586.29, 249.13], "category_id": 1, "id": 5}], "caption": "Scheme 1. Mechanism of Ferrous Iron-Promoted Drug Release from Trioxolane 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 392, 125], "ImageBB": [104, 131, 397, 320]}, "diagram_type": "tree", "corefs": [[5, 3], [2, 0], [1, 4]]}, {"id": 1036, "width": 1356, "height": 1156, "file_name": "ol502998n-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [161.44, 897.07, 248.28, 155.4], "category_id": 1, "id": 0}, {"bbox": [851.99, 42.75, 215.72, 179.14], "category_id": 1, "id": 1}, {"bbox": [851.99, 428.18, 219.11, 206.29], "category_id": 1, "id": 2}, {"bbox": [478.91, 451.93, 52.23, 171.0], "category_id": 1, "id": 3}, {"bbox": [478.91, 41.39, 56.3, 173.04], "category_id": 1, "id": 4}, {"bbox": [161.81, 344.16, 227.59, 145.72], "category_id": 1, "id": 5}, {"bbox": [476.19, 887.57, 52.91, 173.72], "category_id": 1, "id": 6}, {"bbox": [161.44, 629.04, 241.49, 152.0], "category_id": 1, "id": 7}, {"bbox": [851.99, 863.15, 286.26, 249.03], "category_id": 1, "id": 8}, {"bbox": [147.2, 61.07, 267.94, 153.36], "category_id": 1, "id": 9}, {"bbox": [158.3, 484.4, 200.8, 154.7], "category_id": 1, "id": 10}], "caption": "Scheme 1. Indole Synthesis via C\u2212H Activation and N\u2212N Cleavage ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 493, 771, 523], "ImageBB": [448, 530, 787, 819]}, "diagram_type": "multiple", "corefs": []}, {"id": 1037, "width": 1352, "height": 960, "file_name": "ol503404p-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [334.79, 623.26, 346.96, 277.16], "category_id": 1, "id": 0}, {"bbox": [332.59, 432.16, 39.18, 46.1], "category_id": 3, "id": 1}, {"bbox": [66.96, 205.5, 468.02, 294.05], "category_id": 1, "id": 2}, {"bbox": [1011.13, 840.93, 50.72, 55.43], "category_id": 3, "id": 3}, {"bbox": [952.96, 160.89, 328.02, 300.13], "category_id": 1, "id": 4}, {"bbox": [1108.52, 389.37, 58.16, 60.16], "category_id": 3, "id": 5}, {"bbox": [855.57, 580.9, 372.66, 319.52], "category_id": 1, "id": 6}, {"bbox": [429.47, 866.62, 51.41, 50.69], "category_id": 3, "id": 7}], "caption": "Scheme 4. Proposed Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 692, 263, 707], "ImageBB": [82, 713, 420, 953]}, "diagram_type": "graph", "corefs": [[2, 1], [0, 7], [6, 3], [4, 5]]}, {"id": 1038, "width": 1356, "height": 684, "file_name": "ol503708v-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [122.6, 0.0, 174.51, 232.81], "category_id": 1, "id": 0}, {"bbox": [127.53, 301.36, 327.64, 275.57], "category_id": 1, "id": 1}, {"bbox": [548.1, 377.38, 376.48, 208.37], "category_id": 1, "id": 2}, {"bbox": [759.06, 590.5, 34.6, 37.34], "category_id": 3, "id": 3}, {"bbox": [1064.31, 374.67, 207.58, 266.74], "category_id": 1, "id": 4}, {"bbox": [674.27, 245.7, 118.03, 41.41], "category_id": 3, "id": 5}, {"bbox": [976.81, 25.11, 206.89, 266.75], "category_id": 1, "id": 6}, {"bbox": [601.01, 6.11, 263.87, 245.02], "category_id": 1, "id": 7}, {"bbox": [295.08, 579.64, 35.27, 39.37], "category_id": 3, "id": 8}, {"bbox": [1103.2, 250.46, 113.06, 39.36], "category_id": 3, "id": 9}, {"bbox": [1189.7, 598.65, 29.28, 38.01], "category_id": 3, "id": 10}], "caption": "Scheme 4. (A) Enzymatic Dioxygenation of Benzyl Thiocyanate; (B) Mechanistic Proposal ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 156, 736, 186], "ImageBB": [448, 193, 787, 364]}, "diagram_type": "multiple", "corefs": [[7, 5], [6, 9], [1, 8], [2, 3], [4, 10]]}, {"id": 1039, "width": 1352, "height": 700, "file_name": "ol8001706-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [477.49, 2.71, 290.15, 202.95], "category_id": 1, "id": 0}, {"bbox": [601.94, 543.9, 39.9, 43.3], "category_id": 3, "id": 1}, {"bbox": [1126.78, 178.6, 225.22, 203.62], "category_id": 1, "id": 2}, {"bbox": [397.01, 363.96, 495.76, 207.0], "category_id": 1, "id": 3}, {"bbox": [1204.56, 402.52, 60.87, 45.32], "category_id": 3, "id": 4}, {"bbox": [620.88, 213.77, 42.61, 41.27], "category_id": 3, "id": 5}], "caption": "Scheme 1. Possible Pathways for the HDA Reaction between                Diene 1 and Benzaldehyde ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [443, 671, 772, 698], "ImageBB": [439, 702, 777, 877]}, "diagram_type": "graph", "corefs": [[0, 5], [2, 4], [3, 1]]}, {"id": 1040, "width": 1352, "height": 1472, "file_name": "ol800418m-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [260.74, 252.57, 62.61, 48.6], "category_id": 3, "id": 0}, {"bbox": [1035.61, 773.19, 52.3, 50.81], "category_id": 3, "id": 1}, {"bbox": [104.59, 1100.13, 364.6, 263.62], "category_id": 1, "id": 2}, {"bbox": [903.03, 534.6, 337.35, 234.9], "category_id": 1, "id": 3}, {"bbox": [261.48, 765.09, 55.98, 50.07], "category_id": 3, "id": 4}, {"bbox": [1072.44, 254.78, 55.25, 45.66], "category_id": 3, "id": 5}, {"bbox": [109.01, 505.88, 360.18, 261.42], "category_id": 1, "id": 6}, {"bbox": [280.63, 1365.96, 67.03, 53.02], "category_id": 3, "id": 7}, {"bbox": [868.41, 1093.51, 363.13, 270.24], "category_id": 1, "id": 8}, {"bbox": [1038.56, 1363.75, 47.14, 50.08], "category_id": 3, "id": 9}, {"bbox": [109.01, 0.0, 346.93, 245.95], "category_id": 1, "id": 10}, {"bbox": [902.3, 0.0, 340.29, 245.95], "category_id": 1, "id": 11}], "caption": "Scheme 4. Preparation of Diol 14", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [138, 74, 314, 89], "ImageBB": [58, 96, 396, 464]}, "diagram_type": "tree", "corefs": [[10, 0], [11, 5], [6, 4], [3, 1], [2, 7], [8, 9]]}, {"id": 1041, "width": 1352, "height": 1732, "file_name": "ol800527p-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [396.65, 1618.5, 368.07, 58.05], "category_id": 3, "id": 0}, {"bbox": [461.61, 700.08, 74.48, 60.65], "category_id": 3, "id": 1}, {"bbox": [19.05, 0.0, 587.19, 397.69], "category_id": 1, "id": 2}, {"bbox": [327.37, 435.82, 581.98, 403.75], "category_id": 1, "id": 3}, {"bbox": [1004.62, 1191.35, 75.35, 55.45], "category_id": 3, "id": 4}, {"bbox": [771.65, 878.56, 498.85, 312.79], "category_id": 1, "id": 5}, {"bbox": [879.91, 289.39, 73.61, 58.05], "category_id": 3, "id": 6}, {"bbox": [19.05, 875.96, 578.52, 363.91], "category_id": 1, "id": 7}, {"bbox": [158.49, 294.59, 66.68, 52.85], "category_id": 3, "id": 8}, {"bbox": [327.37, 1300.52, 478.06, 315.38], "category_id": 1, "id": 9}, {"bbox": [743.07, 0.0, 589.78, 398.56], "category_id": 1, "id": 10}, {"bbox": [200.06, 1194.81, 73.61, 53.72], "category_id": 3, "id": 11}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [199, 69, 252, 82], "ImageBB": [58, 91, 396, 524]}, "diagram_type": "multiple", "corefs": [[2, 8], [10, 6], [3, 1], [7, 11], [5, 4], [9, 0]]}, {"id": 1042, "width": 1352, "height": 864, "file_name": "ol801034x-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1038.18, 299.57, 52.75, 56.12], "category_id": 3, "id": 0}, {"bbox": [1100.4, 744.52, 46.67, 55.45], "category_id": 3, "id": 1}, {"bbox": [32.46, 54.77, 303.68, 221.13], "category_id": 1, "id": 2}, {"bbox": [144.06, 744.52, 45.99, 55.45], "category_id": 3, "id": 3}, {"bbox": [915.76, 2.7, 351.7, 280.64], "category_id": 1, "id": 4}, {"bbox": [4.06, 502.44, 353.72, 164.32], "category_id": 1, "id": 5}, {"bbox": [105.51, 290.1, 41.93, 52.07], "category_id": 3, "id": 6}, {"bbox": [504.55, 290.1, 47.34, 59.51], "category_id": 3, "id": 7}, {"bbox": [973.25, 446.99, 350.34, 260.34], "category_id": 1, "id": 8}, {"bbox": [407.16, 16.23, 220.48, 195.43], "category_id": 1, "id": 9}, {"bbox": [471.41, 511.9, 353.72, 131.87], "category_id": 1, "id": 10}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [199, 618, 252, 631], "ImageBB": [58, 639, 396, 855]}, "diagram_type": "tree", "corefs": [[2, 6], [9, 7], [4, 0], [5, 3], [8, 1]]}, {"id": 1043, "width": 1352, "height": 1012, "file_name": "ol802297h-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [984.75, 795.87, 44.64, 53.42], "category_id": 3, "id": 0}, {"bbox": [331.41, 903.39, 41.93, 48.01], "category_id": 3, "id": 1}, {"bbox": [283.39, 250.19, 31.78, 43.28], "category_id": 3, "id": 2}, {"bbox": [820.4, 0.0, 436.91, 246.13], "category_id": 1, "id": 3}, {"bbox": [769.67, 499.7, 489.0, 303.61], "category_id": 1, "id": 4}, {"bbox": [331.41, 606.54, 44.63, 45.98], "category_id": 3, "id": 5}, {"bbox": [89.28, 0.0, 440.29, 254.92], "category_id": 1, "id": 6}, {"bbox": [186.67, 456.43, 236.04, 144.02], "category_id": 1, "id": 7}, {"bbox": [161.64, 692.42, 409.19, 216.38], "category_id": 1, "id": 8}, {"bbox": [988.13, 248.16, 38.55, 48.69], "category_id": 3, "id": 9}], "caption": "Scheme 1. Retrosynthesis of Tagetitoxin", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [121, 74, 332, 89], "ImageBB": [58, 96, 396, 349]}, "diagram_type": "tree", "corefs": [[6, 2], [3, 9], [7, 5], [4, 0], [8, 1]]}, {"id": 1044, "width": 920, "height": 916, "file_name": "ol802674r-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [153.72, 227.85, 39.58, 44.19], "category_id": 3, "id": 0}, {"bbox": [0.0, 0.0, 291.79, 221.4], "category_id": 1, "id": 1}, {"bbox": [0.0, 334.64, 313.88, 224.63], "category_id": 1, "id": 2}, {"bbox": [0.0, 642.12, 304.21, 159.26], "category_id": 1, "id": 3}, {"bbox": [140.37, 563.41, 40.96, 41.89], "category_id": 3, "id": 4}, {"bbox": [669.63, 865.83, 58.91, 47.41], "category_id": 3, "id": 5}, {"bbox": [141.75, 800.0, 42.8, 46.95], "category_id": 3, "id": 6}, {"bbox": [420.65, 614.96, 458.35, 255.47], "category_id": 1, "id": 7}, {"bbox": [432.62, 0.0, 455.48, 300.12], "category_id": 1, "id": 8}, {"bbox": [444.58, 312.08, 460.02, 290.45], "category_id": 1, "id": 9}, {"bbox": [661.22, 572.92, 37.39, 39.59], "category_id": 3, "id": 10}, {"bbox": [650.22, 259.52, 36.29, 43.99], "category_id": 3, "id": 11}], "caption": "Scheme 2. Compounds Obtained by Variation of the             Bis-Secondary Aminea ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [456, 74, 729, 102], "ImageBB": [478, 110, 708, 339]}, "diagram_type": "multiple", "corefs": [[1, 0], [8, 11], [2, 4], [9, 10], [3, 6], [7, 5]]}, {"id": 1045, "width": 1352, "height": 964, "file_name": "ol901584g-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [169.08, 682.07, 144.74, 183.38], "category_id": 1, "id": 0}, {"bbox": [359.81, 327.5, 341.55, 175.26], "category_id": 1, "id": 1}, {"bbox": [389.57, 686.81, 280.0, 74.43], "category_id": 1, "id": 2}, {"bbox": [745.32, 90.67, 423.39, 181.35], "category_id": 1, "id": 3}, {"bbox": [729.09, 682.07, 450.44, 183.38], "category_id": 1, "id": 4}, {"bbox": [531.6, 464.87, 39.23, 38.57], "category_id": 3, "id": 5}, {"bbox": [359.81, 6.09, 340.88, 173.23], "category_id": 1, "id": 6}, {"bbox": [745.32, 414.12, 421.36, 182.69], "category_id": 1, "id": 7}, {"bbox": [169.08, 87.97, 144.74, 185.4], "category_id": 1, "id": 8}, {"bbox": [531.6, 140.07, 37.2, 39.25], "category_id": 3, "id": 9}, {"bbox": [169.08, 414.12, 144.74, 184.72], "category_id": 1, "id": 10}], "caption": "Scheme 1. Synthesis of ADBP, ACBP, and DABP", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [94, 480, 357, 495], "ImageBB": [58, 502, 396, 743]}, "diagram_type": "multiple", "corefs": [[6, 9], [1, 5]]}, {"id": 1046, "width": 1352, "height": 812, "file_name": "ol901760a-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [690.54, 0.0, 154.21, 249.44], "category_id": 1, "id": 0}, {"bbox": [848.8, 688.16, 35.85, 42.59], "category_id": 3, "id": 1}, {"bbox": [572.86, 672.61, 235.36, 78.42], "category_id": 3, "id": 2}, {"bbox": [777.11, 283.24, 180.79, 56.86], "category_id": 1, "id": 3}, {"bbox": [1023.3, 0.0, 135.27, 259.58], "category_id": 1, "id": 4}, {"bbox": [184.64, 0.0, 204.93, 250.12], "category_id": 1, "id": 5}, {"bbox": [748.71, 225.78, 83.86, 40.56], "category_id": 3, "id": 6}, {"bbox": [604.65, 404.92, 135.94, 256.2], "category_id": 1, "id": 7}, {"bbox": [827.84, 402.21, 198.84, 300.14], "category_id": 1, "id": 8}, {"bbox": [239.42, 249.44, 144.06, 48.0], "category_id": 3, "id": 9}, {"bbox": [1070.64, 263.64, 93.34, 42.58], "category_id": 3, "id": 10}], "caption": "Scheme 4. Base-Free Cyclization of Enynylpyridine Z-1b and        Intermediate Carbene-Trapping Experiments ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [66, 653, 386, 681], "ImageBB": [58, 689, 396, 892]}, "diagram_type": "graph", "corefs": [[5, 9], [0, 6], [4, 10], [7, 2], [8, 1]]}, {"id": 1047, "width": 1324, "height": 572, "file_name": "op010068e-Scheme-c8.png", "license": 0, "bboxes": [{"bbox": [245.06, 2.65, 332.49, 307.92], "category_id": 1, "id": 0}, {"bbox": [917.99, 305.28, 52.99, 39.07], "category_id": 3, "id": 1}, {"bbox": [400.71, 324.48, 60.27, 41.06], "category_id": 3, "id": 2}, {"bbox": [806.06, 5.96, 215.92, 292.03], "category_id": 1, "id": 3}], "caption": "Scheme 8", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 172, 135, 186], "ImageBB": [77, 192, 408, 335]}, "diagram_type": "multiple", "corefs": [[0, 2], [3, 1]]}, {"id": 1048, "width": 1332, "height": 652, "file_name": "op010068e-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [346.2, 314.08, 661.3, 254.72], "category_id": 1, "id": 0}, {"bbox": [0.0, 48.01, 516.41, 177.49], "category_id": 1, "id": 1}, {"bbox": [707.65, 598.15, 55.97, 40.01], "category_id": 3, "id": 2}, {"bbox": [1072.13, 248.73, 54.64, 44.68], "category_id": 3, "id": 3}, {"bbox": [258.54, 208.05, 58.63, 43.35], "category_id": 3, "id": 4}, {"bbox": [669.0, 2.67, 663.0, 255.39], "category_id": 1, "id": 5}], "caption": "Scheme 9", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [441, 72, 774, 235]}, "diagram_type": "single", "corefs": [[1, 4], [5, 3], [0, 2]]}, {"id": 1049, "width": 1304, "height": 1944, "file_name": "op0100706-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [15.56, 289.8, 301.52, 318.0], "category_id": 1, "id": 0}, {"bbox": [259.7, 983.18, 448.39, 235.35], "category_id": 1, "id": 1}, {"bbox": [1028.09, 465.82, 91.43, 136.15], "category_id": 1, "id": 2}, {"bbox": [1079.16, 310.43, 74.68, 130.69], "category_id": 1, "id": 3}, {"bbox": [931.8, 1007.5, 323.89, 213.94], "category_id": 1, "id": 4}, {"bbox": [0.0, 1249.64, 483.41, 192.56], "category_id": 1, "id": 5}, {"bbox": [412.4, 1319.66, 550.53, 284.94], "category_id": 1, "id": 6}, {"bbox": [557.33, 3.89, 454.23, 262.41], "category_id": 1, "id": 7}, {"bbox": [78.78, 645.73, 343.35, 284.94], "category_id": 1, "id": 8}, {"bbox": [1028.09, 1192.27, 41.83, 41.82], "category_id": 3, "id": 9}, {"bbox": [1028.09, 464.85, 91.43, 137.12], "category_id": 1, "id": 10}, {"bbox": [781.04, 706.03, 448.39, 235.34], "category_id": 1, "id": 11}, {"bbox": [622.5, 304.39, 312.22, 315.08], "category_id": 1, "id": 12}, {"bbox": [251.92, 1612.38, 596.23, 283.97], "category_id": 1, "id": 13}], "caption": "Scheme 1. Shionogi synthesis of Ceftibuten", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 299, 686, 313], "ImageBB": [446, 318, 772, 804]}, "diagram_type": "multiple", "corefs": [[4, 9]]}, {"id": 1050, "width": 1152, "height": 864, "file_name": "op010073i-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [684.05, 12.68, 156.75, 162.47], "category_id": 1, "id": 0}, {"bbox": [31.12, 629.15, 305.43, 165.93], "category_id": 1, "id": 1}, {"bbox": [96.82, 171.69, 40.91, 42.64], "category_id": 3, "id": 2}, {"bbox": [306.01, 520.83, 42.07, 45.52], "category_id": 3, "id": 3}, {"bbox": [199.4, 372.19, 282.95, 131.36], "category_id": 1, "id": 4}, {"bbox": [147.53, 816.4, 42.65, 46.09], "category_id": 3, "id": 5}, {"bbox": [723.82, 195.89, 38.03, 42.63], "category_id": 3, "id": 6}, {"bbox": [945.69, 815.82, 38.03, 44.94], "category_id": 3, "id": 7}, {"bbox": [0.0, 17.86, 264.52, 131.94], "category_id": 1, "id": 8}, {"bbox": [807.38, 614.75, 306.01, 169.38], "category_id": 1, "id": 9}], "caption": "Scheme 1. Literature synthesis of 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 417, 644, 431], "ImageBB": [464, 438, 752, 654]}, "diagram_type": "multiple", "corefs": [[8, 2], [0, 6], [4, 3], [1, 5], [9, 7]]}, {"id": 1051, "width": 1228, "height": 1432, "file_name": "op010097p-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1078.93, 277.23, 68.06, 55.88], "category_id": 3, "id": 0}, {"bbox": [606.81, 899.75, 545.91, 334.55], "category_id": 1, "id": 1}, {"bbox": [781.62, 45.85, 446.38, 305.35], "category_id": 1, "id": 2}, {"bbox": [204.9, 305.88, 53.01, 54.45], "category_id": 3, "id": 3}, {"bbox": [527.29, 473.51, 614.69, 308.75], "category_id": 1, "id": 4}, {"bbox": [148.3, 1371.83, 53.73, 60.17], "category_id": 3, "id": 5}, {"bbox": [739.35, 750.03, 71.64, 55.87], "category_id": 3, "id": 6}, {"bbox": [712.12, 1272.25, 70.21, 58.74], "category_id": 3, "id": 7}, {"bbox": [0.0, 66.62, 443.47, 305.89], "category_id": 1, "id": 8}, {"bbox": [148.3, 1107.49, 277.26, 315.91], "category_id": 1, "id": 9}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 441, 501, 455], "ImageBB": [455, 462, 762, 820]}, "diagram_type": "multiple", "corefs": [[8, 3], [2, 0], [4, 6], [1, 7], [9, 5]]}, {"id": 1052, "width": 1324, "height": 900, "file_name": "op0101106-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [504.7, 847.23, 52.32, 50.35], "category_id": 3, "id": 0}, {"bbox": [1036.55, 370.29, 49.01, 53.66], "category_id": 3, "id": 1}, {"bbox": [88.75, 370.29, 48.35, 55.64], "category_id": 3, "id": 2}, {"bbox": [947.8, 2.65, 376.2, 372.28], "category_id": 1, "id": 3}, {"bbox": [0.0, 15.9, 236.45, 311.33], "category_id": 1, "id": 4}, {"bbox": [429.85, 24.51, 419.26, 373.6], "category_id": 1, "id": 5}, {"bbox": [520.59, 385.53, 48.35, 49.02], "category_id": 3, "id": 6}, {"bbox": [423.89, 473.63, 641.8, 366.98], "category_id": 1, "id": 7}], "caption": "Scheme 1. Previous synthetic route of 4", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 253, 668, 267], "ImageBB": [443, 273, 774, 498]}, "diagram_type": "multiple", "corefs": [[4, 2], [5, 6], [3, 1], [7, 0]]}, {"id": 1053, "width": 1340, "height": 1052, "file_name": "op0155211-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [923.72, 732.2, 357.29, 230.62], "category_id": 1, "id": 0}, {"bbox": [967.29, 322.28, 180.99, 149.92], "category_id": 1, "id": 1}, {"bbox": [451.0, 733.67, 142.5, 151.53], "category_id": 1, "id": 2}, {"bbox": [91.17, 377.22, 258.07, 161.47], "category_id": 1, "id": 3}, {"bbox": [1053.1, 994.98, 65.02, 54.27], "category_id": 3, "id": 4}, {"bbox": [0.0, 720.27, 286.23, 231.16], "category_id": 1, "id": 5}, {"bbox": [242.66, 557.45, 59.66, 50.93], "category_id": 3, "id": 6}, {"bbox": [1054.44, 558.12, 59.66, 50.26], "category_id": 3, "id": 7}, {"bbox": [162.22, 994.98, 61.67, 54.27], "category_id": 3, "id": 8}, {"bbox": [904.95, 85.76, 251.38, 151.43], "category_id": 1, "id": 9}, {"bbox": [1054.44, 237.19, 58.99, 52.93], "category_id": 3, "id": 10}, {"bbox": [10.06, 96.48, 175.62, 142.72], "category_id": 1, "id": 11}, {"bbox": [373.38, 87.77, 136.07, 151.43], "category_id": 1, "id": 12}, {"bbox": [500.07, 999.0, 58.32, 50.25], "category_id": 3, "id": 13}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 553, 501, 567], "ImageBB": [441, 571, 776, 834]}, "diagram_type": "multiple", "corefs": [[9, 10], [3, 6], [1, 7], [5, 8], [2, 13], [0, 4]]}, {"id": 1054, "width": 1264, "height": 900, "file_name": "op020049k-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [849.83, 267.51, 398.99, 225.13], "category_id": 1, "id": 0}, {"bbox": [338.29, 191.62, 34.78, 46.8], "category_id": 3, "id": 1}, {"bbox": [911.8, 566.0, 352.2, 228.3], "category_id": 1, "id": 2}, {"bbox": [182.11, 5.69, 326.27, 169.49], "category_id": 1, "id": 3}, {"bbox": [1117.3, 853.74, 33.52, 40.48], "category_id": 3, "id": 4}, {"bbox": [339.55, 496.44, 45.53, 43.63], "category_id": 3, "id": 5}, {"bbox": [364.85, 849.95, 34.14, 42.37], "category_id": 3, "id": 6}, {"bbox": [153.65, 568.53, 356.63, 225.77], "category_id": 1, "id": 7}, {"bbox": [100.54, 267.51, 436.93, 225.76], "category_id": 1, "id": 8}, {"bbox": [1117.93, 497.07, 39.21, 45.53], "category_id": 3, "id": 9}], "caption": "Scheme 1. Synthesis of 2 using diazomethane", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 332, 67], "ImageBB": [85, 73, 401, 298]}, "diagram_type": "multiple", "corefs": [[3, 1], [0, 9], [8, 5], [7, 6], [2, 4]]}, {"id": 1055, "width": 2192, "height": 456, "file_name": "op020098x-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [0.0, 26.35, 404.63, 201.98], "category_id": 1, "id": 0}, {"bbox": [527.44, 47.2, 637.09, 210.77], "category_id": 1, "id": 1}, {"bbox": [1303.8, 0.0, 888.2, 245.9], "category_id": 1, "id": 2}], "caption": "Scheme 3. Oligonucleotide synthesis using I-linker solid support", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 534, 434, 548], "ImageBB": [151, 552, 699, 666]}, "diagram_type": "multiple", "corefs": []}, {"id": 1056, "width": 1340, "height": 1424, "file_name": "op025538z-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [517.32, 1064.26, 286.45, 304.89], "category_id": 1, "id": 0}, {"bbox": [350.58, 348.3, 207.36, 150.9], "category_id": 1, "id": 1}, {"bbox": [583.59, 0.0, 166.51, 247.9], "category_id": 1, "id": 2}, {"bbox": [188.12, 618.33, 218.75, 348.34], "category_id": 1, "id": 3}, {"bbox": [878.59, 608.35, 297.14, 349.77], "category_id": 1, "id": 4}], "caption": "Scheme 1. Reaction scheme of solid-liquid phase transfer catalysed C-alkylation of p-chlorophenyl acetonitrile with isopropyl bromide under alkaline conditions ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 768, 95], "ImageBB": [440, 103, 775, 459]}, "diagram_type": "tree", "corefs": []}, {"id": 1057, "width": 916, "height": 1456, "file_name": "op0255736-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [13.1, 426.09, 211.86, 190.83], "category_id": 1, "id": 0}, {"bbox": [112.85, 622.02, 45.86, 44.43], "category_id": 3, "id": 1}, {"bbox": [481.96, 6.56, 247.53, 258.56], "category_id": 1, "id": 2}, {"bbox": [625.38, 1416.67, 37.86, 34.96], "category_id": 3, "id": 3}, {"bbox": [102.65, 252.01, 35.68, 42.98], "category_id": 3, "id": 4}, {"bbox": [619.56, 929.39, 48.77, 48.8], "category_id": 3, "id": 5}, {"bbox": [11.65, 11.65, 235.88, 223.61], "category_id": 1, "id": 6}, {"bbox": [472.49, 771.34, 342.18, 186.46], "category_id": 1, "id": 7}, {"bbox": [481.96, 1189.42, 321.79, 218.51], "category_id": 1, "id": 8}, {"bbox": [472.49, 394.77, 326.89, 219.97], "category_id": 1, "id": 9}, {"bbox": [240.25, 378.75, 260.64, 162.42], "category_id": 1, "id": 10}, {"bbox": [32.76, 729.82, 325.43, 225.79], "category_id": 1, "id": 11}, {"bbox": [288.3, 31.32, 158.71, 107.07], "category_id": 1, "id": 12}], "caption": "Scheme 1. First-generation synthesis", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 306, 651, 320], "ImageBB": [494, 325, 723, 689]}, "diagram_type": "tree", "corefs": [[6, 4], [0, 1], [7, 5], [8, 3]]}, {"id": 1058, "width": 1172, "height": 1188, "file_name": "op025619v-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [829.07, 1145.21, 27.34, 35.66], "category_id": 3, "id": 0}, {"bbox": [0.0, 309.63, 480.21, 254.36], "category_id": 1, "id": 1}, {"bbox": [811.24, 575.28, 25.56, 34.47], "category_id": 3, "id": 2}, {"bbox": [205.63, 577.06, 22.59, 32.69], "category_id": 3, "id": 3}, {"bbox": [603.83, 302.5, 481.4, 253.17], "category_id": 1, "id": 4}, {"bbox": [618.09, 861.73, 480.21, 249.61], "category_id": 1, "id": 5}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [134, 156, 427, 453]}, "diagram_type": "tree", "corefs": [[1, 3], [4, 2], [5, 0]]}, {"id": 1059, "width": 1348, "height": 896, "file_name": "op034064g-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [198.93, 550.28, 63.39, 53.95], "category_id": 3, "id": 0}, {"bbox": [1086.36, 847.0, 64.73, 49.0], "category_id": 3, "id": 1}, {"bbox": [700.64, 178.71, 69.45, 54.62], "category_id": 3, "id": 2}, {"bbox": [1082.31, 175.33, 49.23, 47.21], "category_id": 3, "id": 3}, {"bbox": [1085.68, 498.35, 53.28, 50.58], "category_id": 3, "id": 4}, {"bbox": [218.49, 170.61, 54.62, 51.93], "category_id": 3, "id": 5}, {"bbox": [84.97, 16.18, 308.84, 152.41], "category_id": 1, "id": 6}, {"bbox": [573.19, 12.14, 320.98, 153.08], "category_id": 1, "id": 7}, {"bbox": [0.0, 400.57, 405.28, 168.59], "category_id": 1, "id": 8}, {"bbox": [885.94, 684.15, 456.06, 155.96], "category_id": 1, "id": 9}, {"bbox": [882.03, 369.55, 386.37, 157.95], "category_id": 1, "id": 10}, {"bbox": [948.79, 2.7, 300.08, 145.3], "category_id": 1, "id": 11}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 594, 501, 608], "ImageBB": [440, 612, 777, 836]}, "diagram_type": "graph", "corefs": [[6, 5], [7, 2], [11, 3], [10, 4], [8, 0], [9, 1]]}, {"id": 1060, "width": 1064, "height": 568, "file_name": "op0340661-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [220.89, 514.41, 36.73, 44.16], "category_id": 3, "id": 0}, {"bbox": [37.26, 244.17, 30.87, 40.96], "category_id": 3, "id": 1}, {"bbox": [6.92, 110.12, 297.0, 153.2], "category_id": 1, "id": 2}, {"bbox": [204.39, 335.67, 324.15, 226.62], "category_id": 1, "id": 3}, {"bbox": [690.35, 114.37, 370.46, 150.02], "category_id": 1, "id": 4}], "caption": "Scheme 7. pH dependence of ureide formation", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 664, 339, 678], "ImageBB": [109, 686, 375, 828]}, "diagram_type": "tree", "corefs": [[2, 1], [3, 0]]}, {"id": 1061, "width": 648, "height": 1212, "file_name": "op049953y-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [27.88, 5.46, 561.19, 148.54], "category_id": 1, "id": 0}, {"bbox": [390.9, 468.07, 64.24, 47.29], "category_id": 3, "id": 1}, {"bbox": [27.88, 677.24, 558.16, 153.4], "category_id": 1, "id": 2}, {"bbox": [31.51, 1034.96, 487.26, 160.06], "category_id": 1, "id": 3}, {"bbox": [390.9, 129.14, 43.03, 44.26], "category_id": 3, "id": 4}, {"bbox": [313.32, 1164.1, 64.24, 47.9], "category_id": 3, "id": 5}, {"bbox": [31.55, 347.72, 558.71, 146.95], "category_id": 1, "id": 6}], "caption": "Scheme 5. Initial route used to prepare vinyl sulfone 15", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 548, 390, 562], "ImageBB": [157, 566, 319, 869]}, "diagram_type": "tree", "corefs": [[0, 4], [6, 1], [3, 5]]}, {"id": 1062, "width": 1352, "height": 1684, "file_name": "op049954q-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [934.42, 946.04, 343.77, 737.96], "category_id": 1, "id": 0}, {"bbox": [581.38, 635.19, 141.55, 280.52], "category_id": 1, "id": 1}, {"bbox": [750.76, 1592.96, 56.6, 52.56], "category_id": 3, "id": 2}, {"bbox": [0.0, 0.0, 306.7, 288.95], "category_id": 1, "id": 3}, {"bbox": [1157.7, 1533.21, 49.71, 51.38], "category_id": 3, "id": 4}, {"bbox": [488.7, 0.0, 301.64, 281.37], "category_id": 1, "id": 5}, {"bbox": [112.91, 281.37, 32.86, 42.12], "category_id": 3, "id": 6}, {"bbox": [634.46, 278.84, 301.64, 102.78], "category_id": 3, "id": 7}, {"bbox": [36.23, 962.05, 285.63, 479.33], "category_id": 1, "id": 8}, {"bbox": [531.67, 957.83, 283.95, 726.17], "category_id": 1, "id": 9}, {"bbox": [341.24, 785.14, 38.76, 47.17], "category_id": 3, "id": 10}, {"bbox": [968.12, 0.0, 303.33, 288.95], "category_id": 1, "id": 11}, {"bbox": [119.65, 490.29, 405.28, 285.58], "category_id": 1, "id": 12}, {"bbox": [1073.44, 270.42, 37.92, 41.28], "category_id": 3, "id": 13}, {"bbox": [793.71, 410.26, 356.41, 476.81], "category_id": 1, "id": 14}, {"bbox": [81.73, 1513.83, 42.97, 46.33], "category_id": 3, "id": 15}, {"bbox": [407.81, 1566.06, 39.6, 49.7], "category_id": 3, "id": 16}, {"bbox": [237.61, 1267.0, 179.47, 320.96], "category_id": 1, "id": 17}, {"bbox": [988.34, 763.23, 48.03, 58.97], "category_id": 3, "id": 18}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 231, 501, 245], "ImageBB": [439, 250, 777, 671]}, "diagram_type": "multiple", "corefs": [[3, 6], [5, 7], [11, 13], [14, 18], [12, 10], [8, 15], [17, 16], [0, 4], [9, 2]]}, {"id": 1063, "width": 520, "height": 2132, "file_name": "op050087e-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [10.67, 502.34, 228.32, 301.83], "category_id": 1, "id": 0}, {"bbox": [0.0, 1702.19, 254.2, 429.81], "category_id": 1, "id": 1}, {"bbox": [20.5, 0.0, 220.9, 187.3], "category_id": 1, "id": 2}, {"bbox": [339.24, 1883.85, 38.39, 48.63], "category_id": 3, "id": 3}, {"bbox": [339.24, 616.94, 38.36, 51.16], "category_id": 3, "id": 4}, {"bbox": [10.67, 1068.67, 228.32, 299.69], "category_id": 1, "id": 5}, {"bbox": [337.15, 75.72, 46.95, 52.26], "category_id": 3, "id": 6}, {"bbox": [333.95, 1177.45, 44.81, 50.13], "category_id": 3, "id": 7}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [543, 71, 673, 604]}, "diagram_type": "tree", "corefs": [[2, 6], [0, 4], [5, 7], [1, 3]]}, {"id": 1064, "width": 832, "height": 1444, "file_name": "op050087e-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [0.0, 1141.33, 210.94, 302.67], "category_id": 1, "id": 0}, {"bbox": [317.86, 787.37, 39.73, 44.07], "category_id": 3, "id": 1}, {"bbox": [317.86, 1251.85, 39.73, 52.73], "category_id": 3, "id": 2}, {"bbox": [0.0, 664.57, 244.89, 303.39], "category_id": 1, "id": 3}, {"bbox": [0.0, 0.0, 244.89, 415.36], "category_id": 1, "id": 4}, {"bbox": [317.86, 137.25, 39.73, 46.95], "category_id": 3, "id": 5}], "caption": "Scheme 4", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [138, 71, 346, 432]}, "diagram_type": "graph", "corefs": [[4, 5], [3, 1], [0, 2]]}, {"id": 1065, "width": 736, "height": 608, "file_name": "op050182n-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [554.49, 232.36, 168.99, 154.29], "category_id": 1, "id": 0}, {"bbox": [121.13, 103.84, 34.24, 41.25], "category_id": 3, "id": 1}, {"bbox": [331.0, 562.67, 47.86, 45.33], "category_id": 3, "id": 2}, {"bbox": [61.85, 48.61, 160.53, 51.55], "category_id": 1, "id": 3}, {"bbox": [270.62, 440.0, 169.36, 150.8], "category_id": 1, "id": 4}, {"bbox": [571.42, 0.0, 164.58, 124.8], "category_id": 1, "id": 5}, {"bbox": [652.42, 121.52, 50.44, 41.98], "category_id": 3, "id": 6}, {"bbox": [57.07, 372.29, 42.34, 45.66], "category_id": 3, "id": 7}, {"bbox": [0.0, 268.45, 185.2, 131.46], "category_id": 1, "id": 8}, {"bbox": [607.5, 369.72, 51.18, 47.13], "category_id": 3, "id": 9}], "caption": "Scheme 3. New synthetic strategy for conversion of nitriles to chiral amines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 445, 406, 473], "ImageBB": [150, 477, 334, 629]}, "diagram_type": "graph", "corefs": [[3, 1], [5, 6], [0, 9], [8, 7], [4, 2]]}, {"id": 1066, "width": 1356, "height": 1532, "file_name": "op060099f-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [30.65, 563.29, 471.27, 411.55], "category_id": 1, "id": 0}, {"bbox": [233.0, 1394.05, 69.89, 45.98], "category_id": 3, "id": 1}, {"bbox": [157.09, 331.08, 50.58, 47.51], "category_id": 3, "id": 2}, {"bbox": [820.7, 36.79, 460.54, 367.09], "category_id": 1, "id": 3}, {"bbox": [919.55, 343.34, 73.57, 48.28], "category_id": 3, "id": 4}, {"bbox": [182.38, 1177.93, 351.73, 354.07], "category_id": 1, "id": 5}, {"bbox": [66.67, 134.12, 399.24, 242.94], "category_id": 1, "id": 6}, {"bbox": [887.37, 842.26, 75.09, 49.04], "category_id": 3, "id": 7}, {"bbox": [95.02, 853.75, 75.1, 55.18], "category_id": 3, "id": 8}, {"bbox": [820.7, 554.1, 475.87, 410.01], "category_id": 1, "id": 9}], "caption": "Scheme 6. Reaction scheme as applied in pilot plant", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 574, 370, 588], "ImageBB": [73, 593, 412, 976]}, "diagram_type": "tree", "corefs": [[6, 2], [3, 4], [0, 8], [9, 7], [5, 1]]}, {"id": 1067, "width": 1356, "height": 1004, "file_name": "op060118l-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [496.54, 0.0, 212.32, 192.64], "category_id": 1, "id": 0}, {"bbox": [704.79, 128.88, 37.99, 44.77], "category_id": 3, "id": 1}, {"bbox": [111.93, 389.36, 100.39, 55.62], "category_id": 3, "id": 2}, {"bbox": [463.98, 577.25, 393.44, 343.23], "category_id": 1, "id": 3}, {"bbox": [24.42, 166.19, 291.69, 248.94], "category_id": 1, "id": 4}, {"bbox": [625.43, 956.43, 60.37, 47.48], "category_id": 3, "id": 5}, {"bbox": [1042.61, 428.02, 50.19, 50.87], "category_id": 3, "id": 6}, {"bbox": [880.48, 120.06, 448.39, 339.16], "category_id": 1, "id": 7}], "caption": "Scheme 2. Eli Lilly\u2019s assemblage of 2\u201aHCl from (S)-6", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 460, 375, 474], "ImageBB": [73, 479, 412, 730]}, "diagram_type": "multiple", "corefs": [[0, 1], [7, 6], [4, 2], [3, 5]]}, {"id": 1068, "width": 1880, "height": 1576, "file_name": "op100010n-Scheme-c11.png", "license": 0, "bboxes": [{"bbox": [1249.88, 1089.5, 624.48, 419.62], "category_id": 1, "id": 0}, {"bbox": [0.0, 1053.75, 604.72, 420.56], "category_id": 1, "id": 1}, {"bbox": [1181.23, 0.0, 698.77, 421.5], "category_id": 1, "id": 2}, {"bbox": [1404.12, 461.96, 62.07, 50.8], "category_id": 3, "id": 3}, {"bbox": [732.63, 555.1, 698.77, 417.74], "category_id": 1, "id": 4}, {"bbox": [220.07, 1527.94, 54.55, 47.98], "category_id": 3, "id": 5}, {"bbox": [1490.65, 1527.94, 63.95, 47.98], "category_id": 3, "id": 6}, {"bbox": [224.77, 478.89, 45.14, 44.22], "category_id": 3, "id": 7}, {"bbox": [0.0, 40.46, 693.13, 425.26], "category_id": 1, "id": 8}], "caption": "Scheme 11. Proposed mechanism for the formation of 20, 21 and 22", "pdf": {"Page": 11, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 438, 60], "ImageBB": [175, 65, 645, 459]}, "diagram_type": "graph", "corefs": [[8, 7], [2, 3], [1, 5], [0, 6]]}, {"id": 1069, "width": 1356, "height": 2360, "file_name": "op100104z-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 0.0, 231.37, 253.83], "category_id": 1, "id": 0}, {"bbox": [734.24, 316.4, 499.33, 514.74], "category_id": 1, "id": 1}, {"bbox": [621.22, 1303.15, 36.83, 36.84], "category_id": 3, "id": 2}, {"bbox": [397.81, 10.63, 213.66, 253.82], "category_id": 1, "id": 3}, {"bbox": [238.45, 1322.26, 28.33, 36.6], "category_id": 3, "id": 4}, {"bbox": [49.58, 1050.73, 409.62, 337.64], "category_id": 1, "id": 5}, {"bbox": [766.11, 7.08, 265.6, 249.11], "category_id": 1, "id": 6}, {"bbox": [1023.45, 1369.48, 36.6, 37.78], "category_id": 3, "id": 7}, {"bbox": [238.45, 822.87, 28.33, 37.78], "category_id": 3, "id": 8}, {"bbox": [844.02, 251.47, 33.06, 33.05], "category_id": 3, "id": 9}, {"bbox": [82.63, 265.63, 31.87, 36.6], "category_id": 3, "id": 10}, {"bbox": [822.77, 891.35, 533.23, 518.27], "category_id": 1, "id": 11}, {"bbox": [47.22, 344.73, 537.1, 515.92], "category_id": 1, "id": 12}, {"bbox": [537.11, 1021.21, 259.69, 252.65], "category_id": 1, "id": 13}, {"bbox": [912.49, 783.91, 24.79, 33.06], "category_id": 3, "id": 14}, {"bbox": [478.08, 259.73, 29.51, 33.06], "category_id": 3, "id": 15}], "caption": "Scheme 1. Original synthesis of 1a", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 425, 619, 439], "ImageBB": [424, 448, 763, 1038]}, "diagram_type": "multiple", "corefs": [[0, 10], [3, 15], [6, 9], [12, 8], [1, 14], [11, 7], [5, 4], [13, 2]]}, {"id": 1070, "width": 1352, "height": 968, "file_name": "op100197g-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [669.57, 39.92, 275.27, 258.47], "category_id": 1, "id": 0}, {"bbox": [514.02, 901.93, 59.51, 66.07], "category_id": 3, "id": 1}, {"bbox": [802.14, 426.27, 54.1, 61.57], "category_id": 3, "id": 2}, {"bbox": [1000.3, 527.09, 351.7, 288.24], "category_id": 1, "id": 3}, {"bbox": [1130.84, 901.93, 50.72, 64.96], "category_id": 3, "id": 4}, {"bbox": [363.19, 527.09, 305.03, 286.88], "category_id": 1, "id": 5}, {"bbox": [0.0, 2.71, 305.03, 284.85], "category_id": 1, "id": 6}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [58, 65, 396, 307]}, "diagram_type": "multiple", "corefs": [[0, 2], [5, 1], [3, 4]]}, {"id": 1071, "width": 928, "height": 936, "file_name": "op100205s-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [569.67, 558.14, 304.93, 377.86], "category_id": 1, "id": 0}, {"bbox": [108.13, 22.48, 283.67, 370.84], "category_id": 1, "id": 1}, {"bbox": [584.18, 21.54, 280.86, 371.78], "category_id": 1, "id": 2}], "caption": "Scheme 10. LiOAc-catalyzed Hunsdiecker reaction of 17a", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 311, 747, 325], "ImageBB": [408, 65, 640, 299]}, "diagram_type": "tree", "corefs": []}, {"id": 1072, "width": 1344, "height": 772, "file_name": "op100335q-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [880.76, 284.95, 252.8, 114.25], "category_id": 3, "id": 0}, {"bbox": [28.91, 237.91, 289.78, 61.09], "category_id": 3, "id": 1}, {"bbox": [882.78, 19.8, 217.83, 210.72], "category_id": 1, "id": 2}, {"bbox": [47.06, 418.02, 328.78, 254.04], "category_id": 1, "id": 3}, {"bbox": [703.94, 81.99, 57.82, 45.7], "category_id": 3, "id": 4}, {"bbox": [606.45, 421.38, 388.61, 252.02], "category_id": 1, "id": 5}, {"bbox": [748.31, 674.74, 60.51, 51.75], "category_id": 3, "id": 6}, {"bbox": [63.2, 109.55, 163.38, 92.07], "category_id": 1, "id": 7}, {"bbox": [178.17, 671.38, 66.56, 53.77], "category_id": 3, "id": 8}, {"bbox": [429.62, 236.56, 256.84, 118.96], "category_id": 3, "id": 9}, {"bbox": [601.07, 24.87, 233.3, 88.04], "category_id": 1, "id": 10}, {"bbox": [452.48, 24.19, 207.08, 168.69], "category_id": 1, "id": 11}], "caption": "Scheme 3. Synthesis of imidazoles from acetamidic esters", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 340, 392, 355], "ImageBB": [71, 365, 407, 558]}, "diagram_type": "multiple", "corefs": [[7, 1], [11, 9], [10, 4], [2, 0], [3, 8], [5, 6]]}, {"id": 1073, "width": 1344, "height": 1160, "file_name": "op200019k-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [553.33, 16.13, 197.0, 145.83], "category_id": 1, "id": 0}, {"bbox": [996.4, 10.75, 193.64, 189.52], "category_id": 1, "id": 1}, {"bbox": [601.07, 643.15, 149.93, 77.29], "category_id": 3, "id": 2}, {"bbox": [1019.26, 430.11, 170.78, 194.89], "category_id": 1, "id": 3}, {"bbox": [564.76, 438.18, 185.57, 197.58], "category_id": 1, "id": 4}, {"bbox": [1106.67, 188.85, 46.39, 39.65], "category_id": 3, "id": 5}, {"bbox": [612.5, 1035.63, 153.96, 77.28], "category_id": 3, "id": 6}, {"bbox": [114.97, 439.52, 193.63, 195.56], "category_id": 1, "id": 7}, {"bbox": [1020.61, 643.15, 159.34, 79.3], "category_id": 3, "id": 8}, {"bbox": [613.5, 192.21, 146.5, 73.09], "category_id": 3, "id": 9}, {"bbox": [581.5, 842.08, 166.81, 190.86], "category_id": 1, "id": 10}, {"bbox": [126.3, 197.58, 152.8, 75.82], "category_id": 3, "id": 11}, {"bbox": [121.69, 74.6, 196.33, 78.63], "category_id": 1, "id": 12}, {"bbox": [224.56, 640.46, 57.15, 43.68], "category_id": 3, "id": 13}], "caption": "Scheme 9. HF and HCl addition to cyclopropanolactone 34", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 771, 107], "ImageBB": [437, 117, 773, 407]}, "diagram_type": "graph", "corefs": [[12, 11], [0, 9], [1, 5], [7, 13], [4, 2], [3, 8], [10, 6]]}, {"id": 1074, "width": 1412, "height": 956, "file_name": "op200086t-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [96.06, 808.34, 99.6, 59.3], "category_id": 3, "id": 0}, {"bbox": [1106.15, 195.55, 233.8, 61.42], "category_id": 3, "id": 1}, {"bbox": [16.95, 8.47, 261.35, 166.61], "category_id": 1, "id": 2}, {"bbox": [1123.81, 9.18, 215.44, 169.43], "category_id": 1, "id": 3}, {"bbox": [577.8, 808.34, 223.2, 89.66], "category_id": 3, "id": 4}, {"bbox": [562.26, 617.02, 268.41, 171.55], "category_id": 1, "id": 5}, {"bbox": [578.5, 0.0, 244.4, 170.14], "category_id": 1, "id": 6}, {"bbox": [0.0, 619.14, 290.31, 171.55], "category_id": 1, "id": 7}, {"bbox": [28.86, 392.55, 235.27, 49.35], "category_id": 3, "id": 8}, {"bbox": [497.1, 301.89, 389.06, 80.31], "category_id": 3, "id": 9}, {"bbox": [497.1, 397.14, 401.68, 80.34], "category_id": 3, "id": 10}, {"bbox": [497.4, 202.6, 366.6, 81.7], "category_id": 3, "id": 11}, {"bbox": [29.9, 290.9, 229.2, 53.7], "category_id": 3, "id": 12}, {"bbox": [1109.68, 292.27, 245.81, 60.01], "category_id": 3, "id": 13}, {"bbox": [1111.9, 385.9, 244.0, 58.1], "category_id": 3, "id": 14}, {"bbox": [29.6, 195.55, 224.69, 60.01], "category_id": 3, "id": 15}], "caption": "Scheme 1. Substrates and products of bioreductions", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 572, 362, 587], "ImageBB": [71, 597, 424, 836]}, "diagram_type": "multiple", "corefs": [[2, 15], [2, 12], [2, 8], [6, 11], [6, 9], [6, 10], [3, 1], [3, 13], [3, 14], [5, 4], [7, 0]]}, {"id": 1075, "width": 2808, "height": 696, "file_name": "op200086t-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [515.53, 4.22, 259.87, 187.05], "category_id": 1, "id": 0}, {"bbox": [1976.42, 8.44, 283.75, 185.64], "category_id": 1, "id": 1}, {"bbox": [2052.27, 194.08, 112.38, 60.48], "category_id": 3, "id": 2}, {"bbox": [581.55, 195.49, 112.37, 59.07], "category_id": 3, "id": 3}, {"bbox": [1224.9, 0.0, 293.58, 188.46], "category_id": 1, "id": 4}, {"bbox": [1310.59, 194.08, 110.97, 60.48], "category_id": 3, "id": 5}], "caption": "Scheme 2. Biocatalysed reduction of (E)- and (Z)-1 mediated by BY and OYE1 3", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 276, 529, 291], "ImageBB": [71, 301, 773, 475]}, "diagram_type": "graph", "corefs": [[0, 3], [4, 5], [1, 2]]}, {"id": 1076, "width": 1764, "height": 860, "file_name": "op200112g-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [577.12, 65.29, 310.62, 237.33], "category_id": 1, "id": 0}, {"bbox": [1088.93, 577.01, 362.69, 220.56], "category_id": 1, "id": 1}, {"bbox": [1535.45, 532.89, 228.55, 269.98], "category_id": 1, "id": 2}, {"bbox": [895.37, 425.37, 85.14, 49.22], "category_id": 1, "id": 3}, {"bbox": [1032.39, 99.44, 74.5, 42.57], "category_id": 1, "id": 4}, {"bbox": [1158.65, 3.53, 244.15, 243.07], "category_id": 1, "id": 5}, {"bbox": [377.68, 367.91, 307.82, 240.86], "category_id": 1, "id": 6}, {"bbox": [0.0, 61.76, 305.32, 221.45], "category_id": 1, "id": 7}], "caption": "Scheme 10. Proposed mechanism for Select\ufb02uor-assisted selective r-iodinationa", "pdf": {"Page": 9, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 208, 517, 230], "ImageBB": [202, 239, 643, 454]}, "diagram_type": "graph", "corefs": []}, {"id": 1077, "width": 2808, "height": 868, "file_name": "op200112g-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1689.86, 511.38, 592.78, 227.59], "category_id": 1, "id": 0}, {"bbox": [1022.62, 22.48, 545.03, 250.07], "category_id": 1, "id": 1}, {"bbox": [1864.04, 764.26, 259.87, 57.6], "category_id": 3, "id": 2}, {"bbox": [529.57, 591.46, 363.82, 161.56], "category_id": 1, "id": 3}, {"bbox": [1864.04, 290.81, 276.73, 53.39], "category_id": 3, "id": 4}, {"bbox": [1028.24, 502.95, 549.24, 250.07], "category_id": 1, "id": 5}, {"bbox": [1216.47, 292.22, 302.01, 56.19], "category_id": 3, "id": 6}, {"bbox": [1682.83, 0.0, 592.79, 280.98], "category_id": 1, "id": 7}, {"bbox": [522.55, 321.72, 375.05, 214.94], "category_id": 1, "id": 8}, {"bbox": [1223.5, 764.26, 282.34, 56.19], "category_id": 3, "id": 9}], "caption": "Scheme 2. Retrosynthetic approaches to the key iso\ufb02av-3-ene intermediate 8", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 497, 107], "ImageBB": [71, 117, 773, 334]}, "diagram_type": "tree", "corefs": [[1, 6], [7, 4], [5, 9], [0, 2]]}, {"id": 1078, "width": 2040, "height": 1424, "file_name": "op200112g-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [0.0, 1112.94, 667.41, 262.41], "category_id": 1, "id": 0}, {"bbox": [253.09, 255.26, 312.27, 215.44], "category_id": 1, "id": 1}, {"bbox": [811.31, 0.0, 319.42, 215.44], "category_id": 1, "id": 2}, {"bbox": [1374.63, 621.82, 665.37, 226.67], "category_id": 1, "id": 3}, {"bbox": [271.46, 0.0, 302.07, 217.48], "category_id": 1, "id": 4}, {"bbox": [632.72, 1122.13, 651.08, 250.15], "category_id": 1, "id": 5}, {"bbox": [628.63, 606.5, 642.93, 283.85], "category_id": 1, "id": 6}, {"bbox": [956.22, 1378.41, 31.63, 40.84], "category_id": 3, "id": 7}, {"bbox": [812.33, 265.47, 379.63, 219.53], "category_id": 1, "id": 8}, {"bbox": [1374.63, 138.86, 665.37, 222.59], "category_id": 1, "id": 9}, {"bbox": [0.0, 613.65, 563.32, 266.49], "category_id": 1, "id": 10}], "caption": "Scheme 4. Previous1 biomimetic route to the key iso\ufb02av-3-ene intermediate 8a", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 508, 108], "ImageBB": [167, 116, 677, 472]}, "diagram_type": "tree", "corefs": [[5, 7]]}, {"id": 1079, "width": 1344, "height": 684, "file_name": "op200176f-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [230.61, 579.9, 39.67, 43.72], "category_id": 3, "id": 0}, {"bbox": [71.27, 8.07, 329.44, 170.2], "category_id": 1, "id": 1}, {"bbox": [248.76, 182.31, 59.84, 48.44], "category_id": 3, "id": 2}, {"bbox": [471.98, 0.0, 403.4, 133.87], "category_id": 1, "id": 3}, {"bbox": [68.58, 347.8, 635.36, 219.99], "category_id": 1, "id": 4}, {"bbox": [974.89, 409.7, 57.15, 49.1], "category_id": 3, "id": 5}, {"bbox": [646.79, 198.46, 628.63, 205.85], "category_id": 1, "id": 6}], "caption": "Scheme 4. Preparation of Intermediate 9 from Dinitroaniline ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 229, 331, 259], "ImageBB": [71, 270, 407, 441]}, "diagram_type": "tree", "corefs": [[1, 2], [6, 5], [4, 0]]}, {"id": 1080, "width": 2820, "height": 780, "file_name": "op200313v-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [873.23, 297.42, 52.19, 50.74], "category_id": 3, "id": 0}, {"bbox": [634.82, 467.98, 572.74, 243.85], "category_id": 1, "id": 1}, {"bbox": [808.33, 46.52, 266.63, 238.21], "category_id": 1, "id": 2}, {"bbox": [922.6, 683.64, 57.84, 57.79], "category_id": 3, "id": 3}, {"bbox": [397.82, 14.1, 181.98, 239.62], "category_id": 1, "id": 4}, {"bbox": [1783.13, 649.81, 53.61, 59.2], "category_id": 3, "id": 5}, {"bbox": [1413.53, 46.52, 348.44, 245.26], "category_id": 1, "id": 6}, {"bbox": [1502.4, 427.1, 582.62, 243.85], "category_id": 1, "id": 7}, {"bbox": [2223.27, 291.78, 55.02, 52.15], "category_id": 3, "id": 8}, {"bbox": [1623.72, 259.36, 46.56, 53.56], "category_id": 3, "id": 9}, {"bbox": [1972.17, 67.66, 452.83, 245.26], "category_id": 1, "id": 10}], "caption": "Scheme 1. Medicinal chemistry route to A-ring fragment of CEP-28122", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 485, 110], "ImageBB": [82, 116, 787, 311]}, "diagram_type": "multiple", "corefs": [[2, 0], [6, 9], [10, 8], [1, 3], [7, 5]]}, {"id": 1081, "width": 1352, "height": 864, "file_name": "op2003216-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [0.0, 85.88, 201.55, 284.69], "category_id": 1, "id": 0}, {"bbox": [524.16, 83.85, 273.24, 334.73], "category_id": 1, "id": 1}, {"bbox": [1011.13, 449.01, 206.28, 235.33], "category_id": 1, "id": 2}, {"bbox": [964.46, 366.51, 48.69, 48.69], "category_id": 3, "id": 3}, {"bbox": [79.81, 371.92, 44.64, 48.69], "category_id": 3, "id": 4}, {"bbox": [1220.11, 365.16, 47.35, 50.04], "category_id": 3, "id": 5}, {"bbox": [1143.01, 83.85, 208.99, 275.23], "category_id": 1, "id": 6}, {"bbox": [254.98, 646.47, 115.65, 104.82], "category_id": 1, "id": 7}, {"bbox": [0.0, 577.5, 202.23, 241.41], "category_id": 1, "id": 8}, {"bbox": [888.71, 85.88, 237.39, 269.14], "category_id": 1, "id": 9}, {"bbox": [222.52, 4.06, 234.01, 132.54], "category_id": 1, "id": 10}], "caption": "Scheme 3. Postulated reaction mechanism for the bromoacetylation of 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 363, 125], "ImageBB": [82, 131, 420, 347]}, "diagram_type": "tree", "corefs": [[0, 4], [9, 3], [6, 5]]}, {"id": 1082, "width": 2820, "height": 1136, "file_name": "op200351g-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [1609.61, 505.02, 81.83, 52.19], "category_id": 3, "id": 0}, {"bbox": [792.82, 806.9, 476.81, 234.16], "category_id": 1, "id": 1}, {"bbox": [402.05, 488.09, 317.41, 153.76], "category_id": 1, "id": 2}, {"bbox": [2147.09, 1039.65, 46.56, 53.61], "category_id": 3, "id": 3}, {"bbox": [2152.74, 710.97, 74.76, 56.43], "category_id": 3, "id": 4}, {"bbox": [1485.47, 314.58, 366.79, 181.97], "category_id": 1, "id": 5}, {"bbox": [524.78, 708.15, 83.23, 59.25], "category_id": 3, "id": 6}, {"bbox": [1014.3, 450.0, 393.58, 222.88], "category_id": 1, "id": 7}, {"bbox": [1199.1, 705.33, 81.82, 64.89], "category_id": 3, "id": 8}, {"bbox": [1673.1, 798.43, 689.83, 249.69], "category_id": 1, "id": 9}, {"bbox": [811.9, 344.2, 129.04, 204.55], "category_id": 1, "id": 10}, {"bbox": [1196.28, 1034.01, 69.12, 59.25], "category_id": 3, "id": 11}, {"bbox": [1958.06, 399.22, 448.6, 331.5], "category_id": 1, "id": 12}, {"bbox": [1485.47, 0.0, 304.72, 172.1], "category_id": 1, "id": 13}], "caption": "Scheme 10. Synthesis of N-methyl ketoamide 6 from N-Boc sarcosine (20)", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 94, 504, 110], "ImageBB": [82, 116, 787, 400]}, "diagram_type": "tree", "corefs": [[2, 6], [7, 8], [5, 0], [12, 4], [1, 11], [9, 3]]}, {"id": 1083, "width": 1356, "height": 1480, "file_name": "op300031r-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [624.29, 963.96, 58.51, 47.39], "category_id": 3, "id": 0}, {"bbox": [812.4, 17.77, 449.52, 213.97], "category_id": 1, "id": 1}, {"bbox": [79.98, 45.16, 344.36, 167.33], "category_id": 1, "id": 2}, {"bbox": [331.77, 1335.63, 57.77, 52.56], "category_id": 3, "id": 3}, {"bbox": [458.41, 45.16, 268.08, 69.6], "category_id": 1, "id": 4}, {"bbox": [543.57, 557.5, 63.69, 54.79], "category_id": 3, "id": 5}, {"bbox": [859.79, 1079.46, 342.88, 311.7], "category_id": 1, "id": 6}, {"bbox": [1006.42, 233.96, 59.25, 39.24], "category_id": 3, "id": 7}, {"bbox": [887.1, 382.77, 363.71, 191.76], "category_id": 1, "id": 8}, {"bbox": [133.3, 1069.83, 339.18, 338.35], "category_id": 1, "id": 9}, {"bbox": [430.27, 759.62, 437.67, 222.85], "category_id": 1, "id": 10}, {"bbox": [228.09, 228.03, 45.18, 48.13], "category_id": 3, "id": 11}, {"bbox": [1037.53, 558.24, 62.95, 51.08], "category_id": 3, "id": 12}, {"bbox": [348.8, 384.99, 455.45, 182.87], "category_id": 1, "id": 13}, {"bbox": [1006.42, 1337.85, 205.88, 102.17], "category_id": 3, "id": 14}], "caption": "Scheme 4. Conversion of Aldehyde 5 to Tri\ufb02ate 4", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 732, 110], "ImageBB": [448, 116, 787, 486]}, "diagram_type": "multiple", "corefs": [[2, 11], [1, 7], [13, 5], [8, 12], [10, 0], [9, 3], [6, 14]]}, {"id": 1084, "width": 1356, "height": 880, "file_name": "op300147f-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [116.0, 796.44, 53.58, 42.74], "category_id": 3, "id": 0}, {"bbox": [521.64, 0.0, 215.04, 278.82], "category_id": 1, "id": 1}, {"bbox": [21.03, 0.0, 218.42, 280.86], "category_id": 1, "id": 2}, {"bbox": [517.57, 502.01, 224.53, 278.82], "category_id": 1, "id": 3}, {"bbox": [1096.87, 499.98, 191.97, 142.46], "category_id": 1, "id": 4}, {"bbox": [613.22, 795.76, 50.87, 40.7], "category_id": 3, "id": 5}, {"bbox": [21.03, 498.62, 324.92, 280.86], "category_id": 1, "id": 6}, {"bbox": [116.0, 274.75, 39.34, 48.17], "category_id": 3, "id": 7}, {"bbox": [643.74, 272.72, 48.84, 50.2], "category_id": 3, "id": 8}], "caption": "Scheme 3. Proposed reaction scheme for the conversion of 1 to 2 in the presence of sulfur and triethyl amine ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 522, 784, 552], "ImageBB": [448, 559, 787, 779]}, "diagram_type": "tree", "corefs": [[2, 7], [1, 8], [6, 0], [3, 5]]}, {"id": 1085, "width": 1356, "height": 472, "file_name": "op3001788-Scheme-c18.png", "license": 0, "bboxes": [{"bbox": [484.33, 228.6, 316.79, 177.72], "category_id": 1, "id": 0}, {"bbox": [1079.24, 2.03, 248.27, 159.41], "category_id": 1, "id": 1}, {"bbox": [569.8, 16.28, 250.31, 160.09], "category_id": 1, "id": 2}, {"bbox": [29.17, 168.23, 312.03, 229.27], "category_id": 1, "id": 3}, {"bbox": [632.21, 379.19, 64.44, 48.84], "category_id": 3, "id": 4}, {"bbox": [166.19, 379.19, 62.41, 48.84], "category_id": 3, "id": 5}, {"bbox": [909.65, 226.56, 303.9, 164.16], "category_id": 1, "id": 6}], "caption": "Scheme 18. Proposed Origin of Chlorinated Byproducts in CPMA (1) ", "pdf": {"Page": 11, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 782, 171], "ImageBB": [448, 178, 787, 296]}, "diagram_type": "tree", "corefs": [[3, 5], [0, 4]]}, {"id": 1086, "width": 2820, "height": 1140, "file_name": "op3001788-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1770.44, 700.95, 481.05, 282.08], "category_id": 1, "id": 0}, {"bbox": [928.24, 4.23, 126.06, 211.56], "category_id": 1, "id": 1}, {"bbox": [1453.03, 445.68, 163.64, 101.54], "category_id": 1, "id": 2}, {"bbox": [1929.84, 349.77, 80.42, 57.83], "category_id": 3, "id": 3}, {"bbox": [1189.22, 52.18, 385.13, 279.26], "category_id": 1, "id": 4}, {"bbox": [1279.51, 339.9, 272.27, 63.47], "category_id": 3, "id": 5}, {"bbox": [1189.22, 700.95, 495.16, 286.31], "category_id": 1, "id": 6}, {"bbox": [1836.74, 71.93, 462.71, 277.84], "category_id": 1, "id": 7}, {"bbox": [553.0, 339.9, 263.8, 66.29], "category_id": 3, "id": 8}, {"bbox": [545.94, 700.95, 292.02, 253.87], "category_id": 1, "id": 9}, {"bbox": [571.34, 1021.11, 221.48, 67.7], "category_id": 3, "id": 10}, {"bbox": [499.39, 60.65, 321.64, 246.81], "category_id": 1, "id": 11}, {"bbox": [1416.35, 1030.98, 749.08, 67.7], "category_id": 3, "id": 12}, {"bbox": [1615.26, 479.53, 40.91, 53.59], "category_id": 3, "id": 13}, {"bbox": [1041.1, 104.37, 50.79, 56.41], "category_id": 3, "id": 14}], "caption": "Scheme 2. Improved Process for the Preparation of Glycopyrrolate 6", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 407, 472, 422], "ImageBB": [82, 116, 787, 401]}, "diagram_type": "tree", "corefs": [[11, 8], [1, 14], [4, 5], [7, 3], [2, 13], [9, 10], [6, 12]]}, {"id": 1087, "width": 3396, "height": 1704, "file_name": "op3001788-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1378.7, 1260.27, 77.2, 61.15], "category_id": 3, "id": 0}, {"bbox": [843.5, 361.78, 119.75, 169.84], "category_id": 1, "id": 1}, {"bbox": [1948.58, 582.58, 266.72, 271.76], "category_id": 1, "id": 2}, {"bbox": [2069.2, 764.32, 40.77, 59.44], "category_id": 3, "id": 3}, {"bbox": [1289.43, 1025.88, 137.6, 254.78], "category_id": 1, "id": 4}, {"bbox": [2069.2, 883.21, 122.32, 90.02], "category_id": 1, "id": 5}, {"bbox": [1948.58, 91.72, 293.9, 273.45], "category_id": 1, "id": 6}, {"bbox": [1617.3, 251.38, 69.66, 61.14], "category_id": 3, "id": 7}, {"bbox": [1664.87, 344.79, 113.83, 166.45], "category_id": 1, "id": 8}, {"bbox": [2453.14, 1017.39, 214.05, 237.79], "category_id": 1, "id": 9}, {"bbox": [779.77, 268.36, 67.96, 57.75], "category_id": 3, "id": 10}, {"bbox": [1617.3, 1110.81, 147.8, 71.33], "category_id": 1, "id": 11}, {"bbox": [2431.05, 529.93, 249.73, 317.61], "category_id": 1, "id": 12}, {"bbox": [744.1, 582.58, 282.01, 276.85], "category_id": 1, "id": 13}, {"bbox": [1487.5, 157.12, 338.76, 94.18], "category_id": 1, "id": 14}, {"bbox": [1349.71, 283.53, 69.15, 53.79], "category_id": 3, "id": 15}, {"bbox": [1580.21, 606.23, 158.79, 230.5], "category_id": 1, "id": 16}, {"bbox": [1126.34, 95.11, 251.43, 263.27], "category_id": 1, "id": 17}, {"bbox": [694.83, 91.72, 338.07, 220.8], "category_id": 1, "id": 18}, {"bbox": [1997.85, 1044.57, 163.09, 254.77], "category_id": 1, "id": 19}, {"bbox": [1168.81, 557.1, 249.73, 275.16], "category_id": 1, "id": 20}, {"bbox": [2425.96, 93.42, 222.55, 283.64], "category_id": 1, "id": 21}, {"bbox": [2065.8, 1295.94, 47.57, 54.35], "category_id": 3, "id": 22}], "caption": "Scheme 3. Synthetic Pathways to Prepare 1-Methyl-pyrrolidin-3-ol 2", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 679, 466, 694], "ImageBB": [10, 701, 859, 1127]}, "diagram_type": "tree", "corefs": [[18, 10], [17, 15], [14, 7], [2, 3], [4, 0], [19, 22]]}, {"id": 1088, "width": 1356, "height": 1272, "file_name": "op3001788-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [994.45, 1011.07, 318.81, 188.64], "category_id": 1, "id": 0}, {"bbox": [930.0, 510.96, 362.24, 260.57], "category_id": 1, "id": 1}, {"bbox": [183.15, 38.68, 62.41, 54.96], "category_id": 3, "id": 2}, {"bbox": [1130.11, 558.46, 75.3, 59.04], "category_id": 3, "id": 3}, {"bbox": [46.81, 935.07, 357.48, 270.75], "category_id": 1, "id": 4}, {"bbox": [972.74, 69.89, 63.08, 61.75], "category_id": 3, "id": 5}, {"bbox": [1046.68, 0.0, 164.83, 161.5], "category_id": 1, "id": 6}, {"bbox": [46.81, 499.43, 303.89, 268.71], "category_id": 1, "id": 7}, {"bbox": [582.02, 570.0, 67.15, 52.93], "category_id": 3, "id": 8}, {"bbox": [1178.28, 1163.75, 69.86, 61.75], "category_id": 3, "id": 9}, {"bbox": [230.64, 16.29, 193.32, 137.07], "category_id": 1, "id": 10}, {"bbox": [263.87, 577.46, 68.52, 59.04], "category_id": 3, "id": 11}, {"bbox": [646.46, 61.75, 164.16, 99.75], "category_id": 1, "id": 12}, {"bbox": [695.98, 1176.64, 75.97, 55.64], "category_id": 3, "id": 13}, {"bbox": [455.84, 613.43, 369.02, 158.78], "category_id": 1, "id": 14}, {"bbox": [534.53, 951.35, 320.86, 264.65], "category_id": 1, "id": 15}, {"bbox": [643.74, 48.86, 68.52, 54.96], "category_id": 3, "id": 16}, {"bbox": [230.64, 1165.1, 73.26, 60.4], "category_id": 3, "id": 17}], "caption": "Scheme 4. Pathways to 1-Benzyl-pyrrolidin-3-on 12, Precursor of Route B ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 742, 125], "ImageBB": [448, 131, 787, 449]}, "diagram_type": "graph", "corefs": [[10, 2], [12, 16], [6, 5], [7, 11], [14, 8], [1, 3], [4, 17], [15, 13], [0, 9]]}, {"id": 1089, "width": 2820, "height": 508, "file_name": "op300181r-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [626.35, 364.16, 114.27, 50.81], "category_id": 3, "id": 0}, {"bbox": [1491.2, 153.85, 61.99, 55.05], "category_id": 3, "id": 1}, {"bbox": [2053.99, 406.5, 117.09, 50.81], "category_id": 3, "id": 2}, {"bbox": [1579.99, 300.64, 172.11, 160.91], "category_id": 1, "id": 3}, {"bbox": [562.87, 211.72, 244.05, 132.68], "category_id": 1, "id": 4}, {"bbox": [1904.45, 76.22, 347.04, 321.81], "category_id": 1, "id": 5}, {"bbox": [1440.33, 4.23, 349.86, 228.66], "category_id": 1, "id": 6}, {"bbox": [1067.9, 203.25, 204.56, 149.62], "category_id": 1, "id": 7}, {"bbox": [1148.31, 379.68, 55.02, 47.99], "category_id": 3, "id": 8}], "caption": "Scheme 6. Proposed Mechanism of the Formation of Impurity 17", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 229, 453, 244], "ImageBB": [82, 251, 787, 378]}, "diagram_type": "single", "corefs": [[4, 0], [7, 8], [6, 1], [5, 2]]}, {"id": 1090, "width": 1268, "height": 772, "file_name": "op300209p-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1108.79, 720.84, 60.89, 49.45], "category_id": 3, "id": 0}, {"bbox": [407.23, 299.87, 40.6, 43.75], "category_id": 3, "id": 1}, {"bbox": [460.51, 344.89, 272.76, 174.98], "category_id": 1, "id": 2}, {"bbox": [111.01, 719.57, 57.08, 52.43], "category_id": 3, "id": 3}, {"bbox": [39.96, 294.8, 41.23, 45.02], "category_id": 3, "id": 4}, {"bbox": [1009.2, 339.18, 258.8, 334.11], "category_id": 1, "id": 5}, {"bbox": [19.66, 388.0, 422.46, 285.29], "category_id": 1, "id": 6}, {"bbox": [521.41, 476.12, 58.36, 46.92], "category_id": 3, "id": 7}, {"bbox": [346.97, 2.54, 271.49, 278.95], "category_id": 1, "id": 8}, {"bbox": [823.34, 722.74, 37.43, 45.02], "category_id": 3, "id": 9}, {"bbox": [733.27, 367.08, 260.07, 306.21], "category_id": 1, "id": 10}, {"bbox": [713.61, 8.24, 281.0, 278.95], "category_id": 1, "id": 11}, {"bbox": [756.11, 303.68, 38.69, 42.48], "category_id": 3, "id": 12}, {"bbox": [0.0, 0.0, 227.09, 281.49], "category_id": 1, "id": 13}], "caption": "Scheme 2. Original Synthesis of N-Aryl Pyrazole 6", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 367, 111], "ImageBB": [92, 116, 409, 309]}, "diagram_type": "multiple", "corefs": [[13, 4], [8, 1], [11, 12], [6, 3], [2, 7], [10, 9], [5, 0]]}, {"id": 1091, "width": 1132, "height": 1496, "file_name": "op300235t-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [943.38, 881.58, 45.64, 47.9], "category_id": 3, "id": 0}, {"bbox": [846.87, 56.13, 248.38, 196.07], "category_id": 1, "id": 1}, {"bbox": [614.96, 458.01, 517.04, 510.39], "category_id": 1, "id": 2}, {"bbox": [451.87, 983.36, 672.56, 505.9], "category_id": 1, "id": 3}, {"bbox": [662.09, 392.9, 33.66, 41.16], "category_id": 3, "id": 4}, {"bbox": [785.53, 1447.36, 45.63, 48.64], "category_id": 3, "id": 5}, {"bbox": [1024.93, 178.11, 38.15, 48.65], "category_id": 3, "id": 6}, {"bbox": [0.0, 0.0, 309.72, 390.65], "category_id": 1, "id": 7}, {"bbox": [0.0, 485.69, 494.51, 460.25], "category_id": 1, "id": 8}, {"bbox": [130.92, 392.15, 36.66, 41.91], "category_id": 3, "id": 9}, {"bbox": [36.66, 1081.4, 300.74, 174.37], "category_id": 1, "id": 10}, {"bbox": [321.69, 900.29, 38.16, 45.65], "category_id": 3, "id": 11}, {"bbox": [76.38, 1087.33, 55.9, 50.13], "category_id": 3, "id": 12}, {"bbox": [469.07, 0.0, 379.3, 386.91], "category_id": 1, "id": 13}], "caption": "Scheme 1. Medicinal chemistry route to the PI3K\u03b4 inhibitor 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [109, 131, 392, 505]}, "diagram_type": "multiple", "corefs": [[7, 9], [13, 4], [1, 6], [8, 11], [2, 0], [10, 12], [3, 5]]}, {"id": 1092, "width": 1356, "height": 940, "file_name": "op3003097-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [144.49, 850.01, 159.41, 46.81], "category_id": 3, "id": 0}, {"bbox": [1025.65, 171.63, 50.87, 49.52], "category_id": 3, "id": 1}, {"bbox": [31.2, 128.89, 217.75, 209.62], "category_id": 1, "id": 2}, {"bbox": [690.55, 404.99, 38.66, 46.13], "category_id": 3, "id": 3}, {"bbox": [16.28, 459.26, 388.01, 371.08], "category_id": 1, "id": 4}, {"bbox": [594.9, 113.97, 261.16, 278.81], "category_id": 1, "id": 5}, {"bbox": [128.88, 400.24, 42.74, 44.78], "category_id": 3, "id": 6}, {"bbox": [690.55, 455.87, 388.69, 374.47], "category_id": 1, "id": 7}, {"bbox": [894.05, 852.05, 29.17, 43.41], "category_id": 3, "id": 8}, {"bbox": [875.74, 8.82, 392.75, 131.6], "category_id": 1, "id": 9}], "caption": "Scheme 4. Process for the preparation of puri\ufb01ed 8", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 741, 110], "ImageBB": [448, 116, 787, 351]}, "diagram_type": "multiple", "corefs": [[2, 6], [5, 3], [9, 1], [4, 0], [7, 8]]}, {"id": 1093, "width": 2820, "height": 932, "file_name": "op300331b-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [349.85, 555.25, 414.75, 245.22], "category_id": 1, "id": 0}, {"bbox": [1904.45, 388.96, 71.95, 56.37], "category_id": 3, "id": 1}, {"bbox": [459.89, 834.29, 64.89, 59.19], "category_id": 3, "id": 2}, {"bbox": [1864.95, 511.57, 602.37, 300.17], "category_id": 1, "id": 3}, {"bbox": [1252.71, 388.96, 70.53, 57.78], "category_id": 3, "id": 4}, {"bbox": [1718.24, 114.15, 338.57, 242.4], "category_id": 1, "id": 5}, {"bbox": [1091.89, 114.15, 335.74, 243.8], "category_id": 1, "id": 6}, {"bbox": [1132.8, 549.62, 517.73, 249.44], "category_id": 1, "id": 7}, {"bbox": [1616.67, 542.57, 259.57, 155.02], "category_id": 1, "id": 8}, {"bbox": [1255.53, 834.29, 71.94, 59.19], "category_id": 3, "id": 9}, {"bbox": [2158.38, 834.29, 56.43, 54.96], "category_id": 3, "id": 10}, {"bbox": [465.53, 390.37, 52.2, 54.96], "category_id": 3, "id": 11}, {"bbox": [348.44, 164.88, 231.36, 212.8], "category_id": 1, "id": 12}, {"bbox": [2073.74, 4.23, 251.1, 250.85], "category_id": 1, "id": 13}], "caption": "Scheme 3. Proposed new synthetic route to NHE-1 inhibitor 1", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 746, 437, 761], "ImageBB": [82, 767, 787, 1000]}, "diagram_type": "multiple", "corefs": [[12, 11], [6, 4], [5, 1], [0, 2], [7, 9], [3, 10]]}, {"id": 1094, "width": 1356, "height": 828, "file_name": "op300343q-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1033.79, 0.0, 322.21, 377.14], "category_id": 1, "id": 0}, {"bbox": [528.43, 0.0, 286.26, 377.14], "category_id": 1, "id": 1}, {"bbox": [385.3, 665.41, 125.49, 71.23], "category_id": 3, "id": 2}, {"bbox": [531.14, 263.86, 47.48, 54.26], "category_id": 3, "id": 3}, {"bbox": [0.0, 6.1, 248.95, 292.35], "category_id": 1, "id": 4}, {"bbox": [982.91, 269.29, 128.89, 56.97], "category_id": 3, "id": 5}, {"bbox": [433.46, 407.66, 323.57, 376.46], "category_id": 1, "id": 6}], "caption": "Scheme 1. Synthetic route to solifenacin (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 472, 700, 487], "ImageBB": [448, 493, 787, 700]}, "diagram_type": "multiple", "corefs": [[1, 3], [0, 5], [6, 2]]}, {"id": 1095, "width": 1352, "height": 1660, "file_name": "op400113a-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [771.22, 372.03, 80.53, 59.79], "category_id": 3, "id": 0}, {"bbox": [298.86, 97.99, 141.96, 219.23], "category_id": 1, "id": 1}, {"bbox": [927.29, 439.29, 424.71, 520.67], "category_id": 1, "id": 2}, {"bbox": [0.0, 511.54, 268.14, 387.8], "category_id": 1, "id": 3}, {"bbox": [354.48, 373.69, 97.96, 61.45], "category_id": 3, "id": 4}, {"bbox": [277.27, 538.94, 330.41, 308.91], "category_id": 1, "id": 5}, {"bbox": [1069.69, 926.37, 34.23, 59.9], "category_id": 3, "id": 6}, {"bbox": [354.48, 1024.73, 432.52, 520.67], "category_id": 1, "id": 7}, {"bbox": [123.6, 376.3, 79.4, 54.1], "category_id": 3, "id": 8}, {"bbox": [406.8, 917.61, 43.98, 52.31], "category_id": 3, "id": 9}, {"bbox": [75.8, 919.27, 71.8, 59.79], "category_id": 3, "id": 10}, {"bbox": [722.24, 3.32, 267.32, 347.12], "category_id": 1, "id": 11}, {"bbox": [78.04, 53.15, 137.8, 283.17], "category_id": 1, "id": 12}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 174, 138, 189], "ImageBB": [82, 196, 420, 611]}, "diagram_type": "multiple", "corefs": [[12, 8], [1, 4], [11, 0], [3, 10], [5, 9], [2, 6]]}, {"id": 1096, "width": 2820, "height": 1308, "file_name": "op400135y-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1560.24, 128.43, 682.78, 429.06], "category_id": 1, "id": 0}, {"bbox": [1049.56, 114.32, 404.88, 141.14], "category_id": 1, "id": 1}, {"bbox": [560.05, 128.43, 584.03, 379.66], "category_id": 1, "id": 2}, {"bbox": [623.53, 601.24, 228.54, 163.72], "category_id": 1, "id": 3}, {"bbox": [1585.63, 825.64, 684.67, 436.11], "category_id": 1, "id": 4}, {"bbox": [560.05, 832.7, 584.03, 388.12], "category_id": 1, "id": 5}], "caption": "Scheme 1. (A) Enzyme-Catalyzed Acylation of Clindamycin Palmitate in Organic Solvent and (B) Current Chemical Synthesis Process of Clindamycin Palmitate ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 784, 125], "ImageBB": [82, 131, 787, 458]}, "diagram_type": "graph", "corefs": []}, {"id": 1097, "width": 2820, "height": 716, "file_name": "op400242j-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [465.53, 5.65, 355.5, 220.36], "category_id": 1, "id": 0}, {"bbox": [1201.92, 4.24, 335.75, 221.77], "category_id": 1, "id": 1}, {"bbox": [1254.12, 387.05, 299.07, 214.71], "category_id": 1, "id": 2}, {"bbox": [1922.79, 0.0, 304.71, 224.6], "category_id": 1, "id": 3}, {"bbox": [701.12, 374.33, 296.25, 224.6], "category_id": 1, "id": 4}, {"bbox": [1811.35, 310.77, 537.47, 363.03], "category_id": 1, "id": 5}], "caption": "Scheme 3. Discovery Chemistry\u2019s preparation of coupled intermediate analogues to 5", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 563, 110], "ImageBB": [82, 116, 787, 295]}, "diagram_type": "multiple", "corefs": []}, {"id": 1098, "width": 2820, "height": 1964, "file_name": "op400242j-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [1184.99, 541.93, 342.8, 222.98], "category_id": 1, "id": 0}, {"bbox": [1390.96, 220.16, 42.32, 50.8], "category_id": 3, "id": 1}, {"bbox": [1412.12, 1875.58, 53.6, 47.98], "category_id": 3, "id": 2}, {"bbox": [1156.78, 1611.67, 420.39, 269.56], "category_id": 1, "id": 3}, {"bbox": [1410.71, 1350.59, 64.89, 50.8], "category_id": 3, "id": 4}, {"bbox": [1227.31, 1119.14, 325.88, 220.16], "category_id": 1, "id": 5}, {"bbox": [541.71, 541.93, 348.45, 225.8], "category_id": 1, "id": 6}, {"bbox": [1917.15, 0.0, 356.91, 273.79], "category_id": 1, "id": 7}, {"bbox": [1951.01, 547.57, 324.46, 225.81], "category_id": 1, "id": 8}, {"bbox": [541.71, 0.0, 345.62, 225.8], "category_id": 1, "id": 9}, {"bbox": [1158.19, 0.0, 375.25, 217.34], "category_id": 1, "id": 10}], "caption": "Scheme 5. Conversion of pyrrolotriazine 2 to PIV-protected pyrrolotriazine 3", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 479, 519, 494], "ImageBB": [82, 501, 787, 992]}, "diagram_type": "graph", "corefs": [[10, 1], [5, 4], [3, 2]]}, {"id": 1099, "width": 1352, "height": 1020, "file_name": "op400269b-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [37.2, 4.06, 128.5, 254.22], "category_id": 1, "id": 0}, {"bbox": [100.77, 932.36, 46.67, 43.95], "category_id": 3, "id": 1}, {"bbox": [1106.49, 294.79, 73.04, 50.03], "category_id": 3, "id": 2}, {"bbox": [359.14, 294.79, 80.48, 50.03], "category_id": 3, "id": 3}, {"bbox": [669.57, 436.77, 349.67, 117.64], "category_id": 1, "id": 4}, {"bbox": [591.12, 2.7, 298.26, 248.81], "category_id": 1, "id": 5}, {"bbox": [710.83, 297.49, 71.02, 46.65], "category_id": 3, "id": 6}, {"bbox": [1065.91, 4.06, 200.2, 250.83], "category_id": 1, "id": 7}, {"bbox": [194.79, 532.78, 60.19, 44.62], "category_id": 3, "id": 8}, {"bbox": [1103.11, 932.36, 56.81, 47.33], "category_id": 3, "id": 9}, {"bbox": [827.84, 530.75, 60.19, 50.03], "category_id": 3, "id": 10}, {"bbox": [343.58, 4.06, 200.2, 250.83], "category_id": 1, "id": 11}, {"bbox": [63.58, 292.08, 58.84, 52.74], "category_id": 3, "id": 12}, {"bbox": [620.2, 931.68, 52.76, 45.98], "category_id": 3, "id": 13}, {"bbox": [544.45, 605.12, 291.5, 312.37], "category_id": 1, "id": 14}, {"bbox": [1065.91, 636.22, 252.95, 277.89], "category_id": 1, "id": 15}, {"bbox": [65.6, 430.01, 332.09, 116.29], "category_id": 1, "id": 16}, {"bbox": [16.23, 607.15, 292.86, 310.34], "category_id": 1, "id": 17}], "caption": "Scheme 4. Discovery Chemistry synthesis of 4 (Z = benzyloxycarbonyl) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 374, 125], "ImageBB": [82, 131, 420, 386]}, "diagram_type": "tree", "corefs": [[0, 12], [11, 3], [5, 6], [7, 2], [16, 8], [4, 10], [17, 1], [14, 13], [15, 9]]}, {"id": 1100, "width": 2820, "height": 1732, "file_name": "op400269b-Scheme-c8.png", "license": 0, "bboxes": [{"bbox": [223.0, 587.3, 775.0, 285.62], "category_id": 1, "id": 0}, {"bbox": [853.48, 208.71, 36.68, 46.54], "category_id": 3, "id": 1}, {"bbox": [234.18, 73.33, 125.55, 200.25], "category_id": 1, "id": 2}, {"bbox": [2460.27, 33.84, 135.43, 279.22], "category_id": 1, "id": 3}, {"bbox": [1702.72, 906.76, 38.09, 42.31], "category_id": 3, "id": 4}, {"bbox": [234.18, 1248.03, 766.01, 351.14], "category_id": 1, "id": 5}, {"bbox": [1251.3, 38.08, 433.08, 267.93], "category_id": 1, "id": 6}, {"bbox": [665.85, 29.61, 355.5, 280.63], "category_id": 1, "id": 7}, {"bbox": [1034.05, 1393.28, 220.07, 128.33], "category_id": 1, "id": 8}, {"bbox": [1815.58, 0.0, 325.87, 342.68], "category_id": 1, "id": 9}, {"bbox": [1333.12, 585.23, 780.12, 287.69], "category_id": 1, "id": 10}, {"bbox": [537.3, 437.53, 238.82, 180.79], "category_id": 1, "id": 11}, {"bbox": [988.16, 1428.52, 35.71, 51.34], "category_id": 3, "id": 12}, {"bbox": [1437.51, 208.71, 39.5, 46.54], "category_id": 3, "id": 13}], "caption": "Scheme 8. Overall synthesis of 1\u00b7bis maleate salt (17% overall yield) from cyclohexenone", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 585, 110], "ImageBB": [82, 116, 787, 549]}, "diagram_type": "tree", "corefs": [[7, 1], [6, 13], [10, 4], [8, 12]]}, {"id": 1101, "width": 1356, "height": 1468, "file_name": "op400278d-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [16.16, 1144.14, 321.0, 198.28], "category_id": 1, "id": 0}, {"bbox": [429.71, 847.46, 315.85, 259.23], "category_id": 1, "id": 1}, {"bbox": [33.79, 425.93, 246.81, 160.83], "category_id": 1, "id": 2}, {"bbox": [135.89, 35.25, 224.04, 144.67], "category_id": 1, "id": 3}, {"bbox": [462.76, 1133.86, 344.51, 261.44], "category_id": 1, "id": 4}, {"bbox": [254.15, 534.62, 37.46, 52.14], "category_id": 3, "id": 5}, {"bbox": [860.89, 334.87, 493.61, 316.51], "category_id": 1, "id": 6}, {"bbox": [132.95, 663.87, 246.81, 199.75], "category_id": 1, "id": 7}, {"bbox": [721.32, 975.97, 39.67, 51.41], "category_id": 3, "id": 8}, {"bbox": [732.92, 1288.33, 39.72, 43.51], "category_id": 3, "id": 9}, {"bbox": [1186.94, 516.5, 39.72, 41.62], "category_id": 3, "id": 10}], "caption": "Scheme 3. Proposed NHC\u2212Pd-catalyzed amination pathway for alkyl and aryl amines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 477, 784, 507], "ImageBB": [448, 513, 787, 880]}, "diagram_type": "graph", "corefs": [[2, 5], [6, 10], [1, 8], [4, 9]]}, {"id": 1102, "width": 3396, "height": 1172, "file_name": "op4003467-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [1447.04, 296.6, 61.46, 51.22], "category_id": 3, "id": 0}, {"bbox": [2342.71, 803.62, 62.86, 61.16], "category_id": 3, "id": 1}, {"bbox": [1262.25, 61.16, 280.31, 265.04], "category_id": 1, "id": 2}, {"bbox": [2150.74, 560.66, 332.98, 280.33], "category_id": 1, "id": 3}, {"bbox": [2342.71, 295.62, 64.56, 54.37], "category_id": 3, "id": 4}, {"bbox": [761.08, 416.25, 339.77, 460.42], "category_id": 1, "id": 5}, {"bbox": [1612.21, 56.07, 315.98, 270.13], "category_id": 1, "id": 6}, {"bbox": [1036.3, 844.39, 66.25, 57.77], "category_id": 3, "id": 7}, {"bbox": [1432.13, 847.79, 67.95, 54.37], "category_id": 3, "id": 8}, {"bbox": [1262.25, 567.46, 298.99, 273.53], "category_id": 1, "id": 9}, {"bbox": [1793.98, 293.92, 71.36, 57.77], "category_id": 3, "id": 10}, {"bbox": [2201.71, 56.07, 299.0, 273.53], "category_id": 1, "id": 11}], "caption": "Scheme 5. 7-Bromo-5-chloro-4-methoxy-3,3-dimethyl-2,3-dihydrobenzofuran", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 802, 510, 817], "ImageBB": [10, 834, 859, 1127]}, "diagram_type": "graph", "corefs": [[2, 0], [6, 10], [11, 4], [5, 7], [9, 8], [3, 1]]}, {"id": 1103, "width": 1704, "height": 1192, "file_name": "op5003165-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [302.61, 11.09, 242.94, 301.91], "category_id": 1, "id": 0}, {"bbox": [1136.28, 540.71, 492.71, 303.62], "category_id": 1, "id": 1}, {"bbox": [1310.18, 875.03, 57.96, 46.91], "category_id": 3, "id": 2}, {"bbox": [901.01, 356.5, 37.51, 39.23], "category_id": 3, "id": 3}, {"bbox": [302.61, 534.74, 485.88, 301.92], "category_id": 1, "id": 4}, {"bbox": [826.0, 28.14, 244.65, 303.62], "category_id": 1, "id": 5}, {"bbox": [479.92, 875.89, 50.29, 44.35], "category_id": 3, "id": 6}, {"bbox": [1310.18, 348.82, 53.7, 46.91], "category_id": 3, "id": 7}, {"bbox": [1184.02, 7.68, 343.53, 232.83], "category_id": 1, "id": 8}, {"bbox": [364.84, 353.08, 38.36, 40.09], "category_id": 3, "id": 9}], "caption": "Scheme 5. Formation of core 10", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 797, 266, 812], "ImageBB": [10, 829, 436, 1127]}, "diagram_type": "tree", "corefs": [[0, 9], [5, 3], [8, 7], [4, 6], [1, 2]]}, {"id": 1104, "width": 1352, "height": 936, "file_name": "op700009t-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [812.96, 890.59, 45.31, 43.28], "category_id": 3, "id": 0}, {"bbox": [421.36, 173.11, 39.9, 40.58], "category_id": 3, "id": 1}, {"bbox": [587.74, 526.78, 327.35, 367.19], "category_id": 1, "id": 2}, {"bbox": [1043.59, 175.82, 39.23, 41.25], "category_id": 3, "id": 3}, {"bbox": [986.78, 526.78, 365.22, 367.87], "category_id": 1, "id": 4}, {"bbox": [365.9, 253.58, 311.79, 219.78], "category_id": 1, "id": 5}, {"bbox": [185.99, 181.23, 48.02, 44.63], "category_id": 3, "id": 6}, {"bbox": [83.87, 570.73, 201.54, 198.81], "category_id": 1, "id": 7}, {"bbox": [1140.98, 894.65, 34.5, 40.57], "category_id": 3, "id": 8}, {"bbox": [73.04, 2.7, 241.46, 208.96], "category_id": 1, "id": 9}, {"bbox": [1030.06, 446.99, 34.5, 40.57], "category_id": 3, "id": 10}, {"bbox": [332.76, 29.08, 264.45, 154.85], "category_id": 1, "id": 11}, {"bbox": [926.58, 244.12, 313.15, 218.42], "category_id": 1, "id": 12}, {"bbox": [202.9, 776.31, 45.32, 43.95], "category_id": 3, "id": 13}, {"bbox": [860.3, 10.82, 374.02, 217.07], "category_id": 1, "id": 14}], "caption": "Scheme 1. Original synthetic route for 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 460, 672, 474], "ImageBB": [439, 479, 777, 713]}, "diagram_type": "multiple", "corefs": [[9, 6], [11, 1], [14, 3], [12, 10], [4, 8], [2, 0], [7, 13]]}, {"id": 1105, "width": 1256, "height": 1380, "file_name": "op7000172-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [0.0, 623.38, 285.86, 479.1], "category_id": 1, "id": 0}, {"bbox": [613.83, 8.97, 283.09, 477.03], "category_id": 1, "id": 1}, {"bbox": [390.81, 608.88, 183.66, 214.01], "category_id": 1, "id": 2}, {"bbox": [325.9, 0.0, 214.05, 329.29], "category_id": 1, "id": 3}, {"bbox": [868.61, 1144.59, 77.34, 55.23], "category_id": 3, "id": 4}, {"bbox": [828.57, 552.97, 292.76, 576.43], "category_id": 1, "id": 5}, {"bbox": [667.69, 493.6, 68.35, 52.46], "category_id": 3, "id": 6}, {"bbox": [779.54, 185.01, 309.33, 142.9], "category_id": 1, "id": 7}, {"bbox": [107.71, 479.79, 71.81, 55.92], "category_id": 3, "id": 8}, {"bbox": [85.62, 1103.17, 73.88, 55.23], "category_id": 3, "id": 9}, {"bbox": [15.19, 207.1, 285.86, 222.29], "category_id": 1, "id": 10}], "caption": "Scheme 4. Synthesis of Valsartan precursor 21 using a Suzuki coupling ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 746, 81], "ImageBB": [451, 85, 765, 430]}, "diagram_type": "multiple", "corefs": [[10, 8], [1, 6], [5, 4], [0, 9]]}, {"id": 1106, "width": 2136, "height": 804, "file_name": "op700026n-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [0.0, 4.27, 343.0, 313.99], "category_id": 1, "id": 0}, {"bbox": [767.21, 4.27, 351.55, 311.86], "category_id": 1, "id": 1}, {"bbox": [712.71, 751.87, 47.02, 50.2], "category_id": 3, "id": 2}, {"bbox": [1586.77, 4.27, 353.69, 313.99], "category_id": 1, "id": 3}, {"bbox": [1401.92, 466.71, 734.08, 315.06], "category_id": 1, "id": 4}, {"bbox": [922.15, 402.63, 445.57, 221.08], "category_id": 1, "id": 5}, {"bbox": [1073.88, 578.85, 42.74, 45.93], "category_id": 3, "id": 6}, {"bbox": [424.21, 466.71, 477.63, 315.06], "category_id": 1, "id": 7}, {"bbox": [260.72, 242.44, 48.09, 51.26], "category_id": 3, "id": 8}, {"bbox": [1766.29, 726.24, 231.87, 55.53], "category_id": 3, "id": 9}, {"bbox": [1807.96, 243.5, 56.63, 51.27], "category_id": 3, "id": 10}, {"bbox": [1027.93, 244.57, 47.02, 48.06], "category_id": 3, "id": 11}], "caption": "Scheme 5. Synthesis of amide 1 (MK-0364, taranabant) from bromo alcohol 5", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 510, 67], "ImageBB": [158, 71, 692, 272]}, "diagram_type": "multiple", "corefs": [[0, 8], [1, 11], [3, 10], [7, 2], [5, 6], [4, 9]]}, {"id": 1107, "width": 1356, "height": 732, "file_name": "op7001694-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [740.75, 2.71, 218.42, 107.12], "category_id": 1, "id": 0}, {"bbox": [1159.28, 262.37, 33.24, 43.38], "category_id": 3, "id": 1}, {"bbox": [967.99, 448.12, 388.01, 195.25], "category_id": 1, "id": 2}, {"bbox": [967.99, 2.71, 373.76, 214.91], "category_id": 1, "id": 3}, {"bbox": [1166.07, 680.66, 43.41, 50.17], "category_id": 3, "id": 4}, {"bbox": [104.46, 260.33, 38.67, 43.39], "category_id": 3, "id": 5}, {"bbox": [447.03, 8.81, 271.33, 193.22], "category_id": 1, "id": 6}, {"bbox": [4.07, 47.46, 242.85, 153.21], "category_id": 1, "id": 7}, {"bbox": [549.45, 252.2, 42.06, 46.77], "category_id": 3, "id": 8}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 368, 486, 382], "ImageBB": [424, 387, 763, 570]}, "diagram_type": "tree", "corefs": [[7, 5], [6, 8], [3, 1], [2, 4]]}, {"id": 1108, "width": 1284, "height": 732, "file_name": "op7001694-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [443.2, 63.58, 214.54, 150.94], "category_id": 1, "id": 0}, {"bbox": [226.74, 677.59, 44.32, 52.67], "category_id": 3, "id": 1}, {"bbox": [854.29, 360.31, 405.94, 299.3], "category_id": 1, "id": 2}, {"bbox": [926.23, 50.74, 263.35, 127.17], "category_id": 1, "id": 3}, {"bbox": [1030.93, 682.09, 41.1, 46.24], "category_id": 3, "id": 4}, {"bbox": [1006.52, 277.46, 41.75, 45.6], "category_id": 3, "id": 5}, {"bbox": [23.77, 401.42, 405.94, 202.95], "category_id": 1, "id": 6}, {"bbox": [3.85, 1.93, 290.33, 226.07], "category_id": 1, "id": 7}], "caption": "Scheme 4", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [66, 65, 387, 248]}, "diagram_type": "tree", "corefs": [[6, 1], [3, 5], [2, 4]]}, {"id": 1109, "width": 1320, "height": 780, "file_name": "op7001886-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [464.21, 732.01, 66.7, 47.53], "category_id": 3, "id": 0}, {"bbox": [428.55, 2.64, 306.4, 309.57], "category_id": 1, "id": 1}, {"bbox": [879.56, 700.99, 61.41, 41.58], "category_id": 3, "id": 2}, {"bbox": [510.44, 323.43, 122.16, 51.49], "category_id": 3, "id": 3}, {"bbox": [783.81, 378.88, 307.72, 312.21], "category_id": 1, "id": 4}, {"bbox": [380.35, 410.56, 302.43, 298.35], "category_id": 1, "id": 5}], "caption": "Scheme 9", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [62, 65, 392, 260]}, "diagram_type": "multiple", "corefs": [[1, 3], [5, 0], [4, 2]]}, {"id": 1110, "width": 1320, "height": 596, "file_name": "op800033c-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1115.3, 228.42, 56.13, 43.58], "category_id": 3, "id": 0}, {"bbox": [704.57, 549.94, 60.09, 42.25], "category_id": 3, "id": 1}, {"bbox": [704.57, 228.42, 60.09, 41.6], "category_id": 3, "id": 2}, {"bbox": [640.52, 344.62, 215.93, 175.61], "category_id": 1, "id": 3}, {"bbox": [0.0, 14.52, 224.51, 176.93], "category_id": 1, "id": 4}, {"bbox": [994.46, 26.41, 293.18, 180.23], "category_id": 1, "id": 5}, {"bbox": [640.52, 21.79, 231.08, 181.55], "category_id": 1, "id": 6}, {"bbox": [75.28, 229.75, 35.66, 40.27], "category_id": 3, "id": 7}], "caption": "Scheme 4", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 319, 119, 333], "ImageBB": [62, 338, 392, 487]}, "diagram_type": "tree", "corefs": [[4, 7], [6, 2], [5, 0], [3, 1]]}, {"id": 1111, "width": 1356, "height": 680, "file_name": "op800033c-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [659.35, 240.98, 442.27, 174.45], "category_id": 1, "id": 0}, {"bbox": [177.05, 456.84, 527.74, 171.06], "category_id": 1, "id": 1}, {"bbox": [689.19, 0.0, 400.9, 171.74], "category_id": 1, "id": 2}, {"bbox": [381.23, 77.38, 207.57, 123.55], "category_id": 1, "id": 3}, {"bbox": [552.17, 185.99, 51.55, 40.73], "category_id": 3, "id": 4}, {"bbox": [2.71, 230.8, 433.46, 172.41], "category_id": 1, "id": 5}, {"bbox": [59.02, 2.72, 262.51, 169.02], "category_id": 1, "id": 6}, {"bbox": [404.29, 639.44, 67.16, 38.69], "category_id": 3, "id": 7}, {"bbox": [857.42, 150.7, 47.48, 37.33], "category_id": 3, "id": 8}, {"bbox": [177.05, 187.35, 42.73, 34.62], "category_id": 3, "id": 9}, {"bbox": [209.61, 381.49, 46.12, 35.3], "category_id": 3, "id": 10}, {"bbox": [877.77, 395.07, 43.41, 35.3], "category_id": 3, "id": 11}], "caption": "Scheme 9", "pdf": {"Page": 8, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 486, 60], "ImageBB": [424, 65, 763, 235]}, "diagram_type": "multiple", "corefs": [[6, 9], [3, 4], [2, 8], [5, 10], [0, 11], [1, 7]]}, {"id": 1112, "width": 1048, "height": 656, "file_name": "op900008a-Scheme-c4.png", 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"DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 492, 60], "ImageBB": [460, 69, 727, 453]}, "diagram_type": "tree", "corefs": [[7, 1], [4, 9], [10, 6], [11, 3], [12, 8], [5, 2]]}, {"id": 1114, "width": 1356, "height": 620, "file_name": "op900197r-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [553.52, 577.73, 48.85, 37.33], "category_id": 3, "id": 0}, {"bbox": [976.13, 500.33, 52.91, 40.74], "category_id": 3, "id": 1}, {"bbox": [106.5, 577.73, 45.45, 37.33], "category_id": 3, "id": 2}, {"bbox": [4.75, 350.98, 287.61, 197.55], "category_id": 1, "id": 3}, {"bbox": [71.9, 2.04, 188.58, 232.85], "category_id": 1, "id": 4}, {"bbox": [105.14, 242.36, 39.35, 38.7], "category_id": 3, "id": 5}, {"bbox": [521.64, 12.9, 262.52, 209.09], "category_id": 1, "id": 6}, {"bbox": [452.45, 353.02, 326.96, 195.51], "category_id": 1, "id": 7}, {"bbox": [877.09, 147.32, 327.64, 330.61], "category_id": 1, "id": 8}, {"bbox": [555.56, 239.64, 56.3, 41.42], "category_id": 3, "id": 9}], "caption": "Scheme 9. Alternative Hofmann and amine coupling sequencea ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 719, 73], "ImageBB": [424, 83, 763, 238]}, "diagram_type": "tree", "corefs": [[4, 5], [6, 9], [3, 2], [7, 0], [8, 1]]}, {"id": 1115, "width": 2404, "height": 664, "file_name": "op900242x-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [612.12, 600.4, 42.1, 51.73], "category_id": 3, "id": 0}, {"bbox": [2055.25, 601.6, 48.1, 50.53], "category_id": 3, "id": 1}, {"bbox": [1967.46, 160.03, 381.22, 411.49], "category_id": 1, "id": 2}, {"bbox": [1277.16, 597.99, 46.9, 50.53], "category_id": 3, "id": 3}, {"bbox": [529.14, 121.52, 383.63, 407.89], "category_id": 1, "id": 4}, {"bbox": [1118.42, 131.15, 381.22, 411.49], "category_id": 1, "id": 5}, {"bbox": [0.0, 123.93, 377.62, 409.09], "category_id": 1, "id": 6}, {"bbox": [92.6, 604.01, 44.5, 48.12], "category_id": 3, "id": 7}], "caption": "Scheme 1. Some details of the commercial route for the fluoroaryl-amine mesylate 1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 525, 60], "ImageBB": [109, 65, 710, 231]}, "diagram_type": "single", "corefs": [[6, 7], [4, 0], [5, 3], [2, 1]]}, {"id": 1116, "width": 1704, "height": 364, "file_name": "op9002642-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [0.0, 23.85, 185.83, 264.87], "category_id": 1, "id": 0}, {"bbox": [770.59, 24.7, 192.65, 267.42], "category_id": 1, "id": 1}, {"bbox": [864.36, 314.27, 33.24, 42.58], "category_id": 3, "id": 2}, {"bbox": [110.82, 315.12, 40.06, 41.73], "category_id": 3, "id": 3}, {"bbox": [381.89, 24.7, 193.5, 267.42], "category_id": 1, "id": 4}, {"bbox": [1526.7, 312.56, 146.61, 40.89], "category_id": 3, "id": 5}, {"bbox": [1489.19, 23.0, 194.35, 269.12], "category_id": 1, "id": 6}, {"bbox": [1166.97, 20.44, 191.8, 266.57], "category_id": 1, "id": 7}, {"bbox": [479.06, 314.27, 35.81, 42.58], "category_id": 3, "id": 8}, {"bbox": [1219.82, 310.01, 108.26, 46.84], "category_id": 3, "id": 9}], "caption": "Scheme 2. Proposed Intermediates Detected During Reduction of 2 to 3", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 456, 60], "ImageBB": [197, 65, 623, 156]}, "diagram_type": "single", "corefs": [[0, 3], [4, 8], [1, 2], [7, 9], [6, 5]]}, {"id": 1117, "width": 884, "height": 864, "file_name": "op960008m-Scheme-c14.png", "license": 0, "bboxes": [{"bbox": [642.99, 652.2, 218.46, 211.8], "category_id": 1, "id": 0}, {"bbox": [628.4, 313.05, 255.6, 169.8], "category_id": 1, "id": 1}, {"bbox": [256.05, 321.01, 178.65, 108.78], "category_id": 1, "id": 2}, {"bbox": [256.05, 4.5, 175.12, 96.7], "category_id": 1, "id": 3}, {"bbox": [13.71, 38.03, 209.17, 71.37], "category_id": 1, "id": 4}, {"bbox": [636.9, 0.0, 247.1, 131.7], "category_id": 1, "id": 5}, {"bbox": [0.0, 292.71, 210.5, 149.46], "category_id": 1, "id": 6}, {"bbox": [256.05, 694.64, 154.33, 103.03], "category_id": 1, "id": 7}, {"bbox": [15.04, 704.81, 212.7, 84.9], "category_id": 1, "id": 8}], "caption": "Scheme 14. Selected reactions catalysed by KF/alumina", "pdf": {"Page": 14, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 197, 388, 211], "ImageBB": [131, 216, 352, 432]}, "diagram_type": "multiple", "corefs": []}, {"id": 1118, "width": 1252, "height": 1412, "file_name": "op960008m-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [91.12, 990.31, 201.3, 100.3], "category_id": 1, "id": 0}, {"bbox": [702.09, 1276.38, 237.32, 120.79], "category_id": 1, "id": 1}, {"bbox": [119.37, 206.26, 199.18, 95.35], "category_id": 1, "id": 2}, {"bbox": [692.9, 362.36, 332.68, 199.19], "category_id": 1, "id": 3}, {"bbox": [784.73, 973.35, 226.02, 152.58], "category_id": 1, "id": 4}, {"bbox": [692.9, 0.0, 313.61, 195.66], "category_id": 1, "id": 5}, {"bbox": [696.96, 713.34, 216.54, 143.75], "category_id": 1, "id": 6}, {"bbox": [108.07, 1278.5, 198.47, 101.01], "category_id": 1, "id": 7}], "caption": "Scheme 7. Routes to propylene oxide", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 171, 287, 185], "ImageBB": [85, 190, 398, 543]}, "diagram_type": "multiple", "corefs": []}, {"id": 1119, "width": 1316, "height": 952, "file_name": "op9600419-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [414.09, 846.21, 64.52, 47.42], "category_id": 3, "id": 0}, {"bbox": [1012.51, 289.75, 56.62, 42.15], "category_id": 3, "id": 1}, {"bbox": [369.98, 5.93, 228.44, 295.68], "category_id": 1, "id": 2}, {"bbox": [916.39, 552.51, 347.6, 301.61], "category_id": 1, "id": 3}, {"bbox": [240.29, 558.44, 425.28, 298.97], "category_id": 1, "id": 4}, {"bbox": [791.97, 2.63, 409.48, 294.37], "category_id": 1, "id": 5}, {"bbox": [1075.71, 842.92, 42.79, 46.1], "category_id": 3, "id": 6}, {"bbox": [0.0, 110.63, 272.55, 104.05], "category_id": 1, "id": 7}, {"bbox": [414.09, 298.32, 55.96, 44.12], "category_id": 3, "id": 8}], "caption": "Scheme 6. Pilot scale synthesis of intermediate 3", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 49, 349, 63], "ImageBB": [77, 70, 406, 308]}, "diagram_type": "tree", "corefs": [[2, 8], [5, 1], [4, 0], [3, 6]]}, {"id": 1120, "width": 1312, "height": 1628, "file_name": "op9600419-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [610.95, 461.77, 364.13, 351.82], "category_id": 1, "id": 0}, {"bbox": [180.84, 369.74, 43.99, 48.87], "category_id": 3, "id": 1}, {"bbox": [307.11, 1118.18, 693.22, 365.67], "category_id": 1, "id": 2}, {"bbox": [0.0, 7.33, 461.88, 346.12], "category_id": 1, "id": 3}, {"bbox": [878.96, 0.0, 433.04, 349.38], "category_id": 1, "id": 4}, {"bbox": [688.34, 1494.44, 46.43, 52.93], "category_id": 3, "id": 5}, {"bbox": [746.99, 779.39, 41.55, 50.49], "category_id": 3, "id": 6}, {"bbox": [1017.44, 361.6, 62.73, 48.86], "category_id": 3, "id": 7}], "caption": "Scheme 7. Preparation of CI-1011 (1) from acid 2 and sulfamate 3 ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 510, 748, 538], "ImageBB": [443, 545, 771, 952]}, "diagram_type": "tree", "corefs": [[3, 1], [4, 7], [0, 6], [2, 5]]}, {"id": 1121, "width": 1080, "height": 1404, "file_name": "op9800717-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [718.07, 414.39, 331.64, 224.75], "category_id": 1, "id": 0}, {"bbox": [751.1, 1250.89, 318.28, 150.3], "category_id": 1, "id": 1}, {"bbox": [49.18, 410.88, 398.39, 229.66], "category_id": 1, "id": 2}, {"bbox": [411.03, 0.0, 423.68, 222.65], "category_id": 1, "id": 3}, {"bbox": [751.1, 828.07, 294.39, 233.88], "category_id": 1, "id": 4}], "caption": "Scheme 5", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 304, 135, 318], "ImageBB": [107, 323, 377, 674]}, "diagram_type": "tree", "corefs": []}, {"id": 1122, "width": 1116, "height": 1008, "file_name": "ja010342k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [24.53, 35.67, 427.18, 375.12], "category_id": 1, "id": 0}, {"bbox": [65.03, 677.78, 427.18, 312.93], "category_id": 1, "id": 1}, {"bbox": [521.99, 370.49, 24.56, 31.5], "category_id": 3, "id": 2}, {"bbox": [560.17, 964.01, 47.13, 34.97], "category_id": 3, "id": 3}], "caption": "Figure 1. Synthesis of the ligands 5, 6, and 9.", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 352, 304, 365], "ImageBB": [148, 378, 427, 630]}, "corefs": [[0, 2], [1, 3]]}, {"id": 1123, "width": 1348, "height": 588, "file_name": "op960033s-Figure-c8.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [721.0, 1.0, 627.0, 587.0], "category_id": 1, "id": 0}, {"bbox": [0.0, 31.0, 631.0, 529.0], "category_id": 1, "id": 1}], "caption": "Figure 8. Erythromycylamine/acetone adduct.", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 204, 331, 218], "ImageBB": [73, 52, 410, 199]}, "corefs": []}, {"id": 1124, "width": 1352, "height": 380, "file_name": "op900242x-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [41.0, 7.0, 274.0, 236.0], "category_id": 1, "id": 0}, {"bbox": [471.0, 6.0, 354.0, 239.0], "category_id": 1, "id": 1}, {"bbox": [953.0, 7.0, 368.0, 239.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Structures of methyl mesylate, ethyl mesylate, and isopropyl mesylate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 995, 393, 1022], "ImageBB": [58, 896, 396, 991]}, "corefs": []}, {"id": 1125, "width": 2048, "height": 2084, "file_name": "op800189g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [732.0, 328.0, 538.1, 184.0], "category_id": 1, "id": 0}, {"bbox": [174.0, 41.1, 312.1, 92.2], "category_id": 1, "id": 1}, {"bbox": [188.2, 631.5, 543.1, 194.8], "category_id": 1, "id": 2}, {"bbox": [1169.0, 21.0, 535.0, 192.0], "category_id": 1, "id": 3}, {"bbox": [689.0, 3.0, 224.0, 196.0], "category_id": 1, "id": 4}], "caption": "Figure 1. Solubility of enantiomerically pure and racemic calcium pantothenate as a function of temperature and water content in the solvent. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 589, 760, 616], "ImageBB": [154, 65, 666, 586]}, "corefs": []}, {"id": 1126, "width": 1024, "height": 800, "file_name": "op060118l-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [460.0, 290.0, 106.0, 62.0], "category_id": 3, "id": 0}, {"bbox": [75.0, 747.0, 235.0, 53.0], "category_id": 3, "id": 1}, {"bbox": [608.9, 336.6, 415.1, 359.4], "category_id": 1, "id": 2}, {"bbox": [334.2, 53.3, 354.8, 189.1], "category_id": 1, "id": 3}, {"bbox": [3.8, 354.7, 353.1, 345.9], "category_id": 1, "id": 4}, {"bbox": [670.0, 742.0, 226.0, 55.0], "category_id": 3, "id": 5}], "caption": "Figure 1. Structures of (S)-3-(N-methylamino)-1-(2-thienyl)- propan-1-ol (1), duloxetine (2), and fluoxetine (3). ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 441, 775, 469], "ImageBB": [480, 238, 736, 438]}, "corefs": [[3, 0], [4, 1], [2, 5]]}, {"id": 1127, "width": 1264, "height": 972, "file_name": "op020010f-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [4.0, 325.1, 522.5, 265.6], "category_id": 1, "id": 0}, {"bbox": [4.0, 8.0, 561.0, 234.2], "category_id": 1, "id": 1}, {"bbox": [12.0, 713.0, 607.7, 257.0], "category_id": 1, "id": 2}], "caption": "Figure 2. Chemical structures of penicillin G, deacetoxycepha- losporin G (DAOG), and deacetylcephalosporin G (DAG). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 300, 775, 328], "ImageBB": [451, 54, 767, 297]}, "corefs": []}, {"id": 1128, "width": 2816, "height": 1008, "file_name": "ol901760a-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [476.0, 178.0, 377.0, 228.0], "category_id": 1, "id": 0}, {"bbox": [185.0, 410.0, 439.0, 247.0], "category_id": 1, "id": 1}, {"bbox": [884.0, 113.0, 407.0, 223.0], "category_id": 1, "id": 2}, {"bbox": [1296.0, 230.0, 310.0, 225.0], "category_id": 1, "id": 3}, {"bbox": [2142.0, 230.0, 356.0, 208.0], "category_id": 1, "id": 4}, {"bbox": [1510.0, 451.0, 304.0, 122.0], "category_id": 1, "id": 5}, {"bbox": [2295.0, 704.0, 312.0, 176.0], "category_id": 1, "id": 6}, {"bbox": [1102.0, 437.0, 336.0, 188.0], "category_id": 1, "id": 7}, {"bbox": [652.0, 379.0, 407.0, 203.0], "category_id": 1, "id": 8}, {"bbox": [1655.0, 218.0, 540.0, 268.8], "category_id": 1, "id": 9}], "caption": "Figure 4. Free energy profile (kcal/mol, 298 K) for the proposed mechanism for the formation of indolizine derivatives from enynylpiridines E-1a, E-1b, and E-1c. ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 307, 761, 335], "ImageBB": [58, 48, 762, 300]}, "corefs": []}, {"id": 1129, "width": 1344, "height": 724, "file_name": "ol200288w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [584.2, 165.1, 298.4, 533.0], "category_id": 1, "id": 0}, {"bbox": [980.5, 284.0, 337.1, 351.8], "category_id": 1, "id": 1}, {"bbox": [67.3, 252.2, 340.4, 345.6], "category_id": 1, "id": 2}], "caption": "Figure 1. Selected tetramic acid natural products.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 253, 333, 266], "ImageBB": [71, 59, 407, 240]}, "corefs": []}, {"id": 1130, "width": 1344, "height": 484, "file_name": "ol2001864-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1090.7, 447.0, 84.3, 31.0], "category_id": 3, "id": 0}, {"bbox": [100.0, 190.0, 307.0, 248.0], "category_id": 1, "id": 1}, {"bbox": [864.0, 168.0, 379.0, 309.0], "category_id": 1, "id": 2}, {"bbox": [597.0, 443.0, 34.0, 31.0], "category_id": 3, "id": 3}, {"bbox": [426.0, 168.0, 305.1, 273.0], "category_id": 1, "id": 4}], "caption": "Figure 1. X-ray crystal structure of 1 and its fluorescent turn-on function for thiols. All hydrogen atoms are omitted for clarity. The thermal ellipsoids are shown at the 50% probability level. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 485, 405, 526], "ImageBB": [71, 351, 407, 472]}, "corefs": [[4, 3], [2, 0]]}, {"id": 1131, "width": 1416, "height": 1280, "file_name": "op4002164-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [415.0, 1068.0, 98.0, 72.0], "category_id": 3, "id": 0}, {"bbox": [1047.0, 1063.0, 80.0, 85.0], "category_id": 3, "id": 1}, {"bbox": [1.7, 165.2, 263.6, 122.1], "category_id": 1, "id": 2}, {"bbox": [362.3, 146.4, 366.1, 215.7], "category_id": 1, "id": 3}, {"bbox": [918.35, 2.7, 410.15, 373.01], "category_id": 1, "id": 4}, {"bbox": [348.7, 732.7, 340.0, 287.4], "category_id": 1, "id": 5}, {"bbox": [953.6, 737.0, 334.2, 315.1], "category_id": 1, "id": 6}, {"bbox": [339.0, 369.0, 540.3, 237.0], "category_id": 3, "id": 7}, {"bbox": [878.0, 381.0, 538.0, 56.8], "category_id": 3, "id": 8}], "caption": "Table 3. Ru-catalyzed hydrogenation of (E)-7\u00b7HNCy2a", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 437, 756, 459], "ImageBB": [433, 116, 787, 436]}, "corefs": [[3, 7], [4, 8], [5, 0], [6, 1]]}, {"id": 1132, "width": 1356, "height": 400, "file_name": "op400137m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [366.0, 40.0, 621.0, 320.0], "category_id": 1, "id": 0}, {"bbox": [656.0, 359.0, 45.0, 34.0], "category_id": 3, "id": 1}], "caption": "Figure 1. Impurity formed during the alkylation of 11.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 721, 716, 735], "ImageBB": [448, 612, 787, 712]}, "corefs": [[0, 1]]}, {"id": 1133, "width": 1352, "height": 912, "file_name": "op4000219-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [742.9, 366.0, 242.1, 47.0], "category_id": 3, "id": 0}, {"bbox": [60.0, 359.0, 317.0, 53.0], "category_id": 3, "id": 1}, {"bbox": [556.0, 784.0, 796.0, 128.0], "category_id": 3, "id": 2}, {"bbox": [0.0, 35.7, 525.0, 310.3], "category_id": 1, "id": 3}, {"bbox": [105.8, 779.0, 238.2, 52.0], "category_id": 3, "id": 4}, {"bbox": [598.5, 464.2, 572.8, 313.6], "category_id": 1, "id": 5}, {"bbox": [4.0, 468.6, 514.3, 291.4], "category_id": 1, "id": 6}, {"bbox": [620.4, 35.0, 560.6, 321.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Tetracycline antibiotics.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 816, 246, 830], "ImageBB": [82, 578, 420, 806]}, "corefs": [[3, 1], [7, 0], [6, 4], [5, 2]]}, {"id": 1134, "width": 2004, "height": 1116, "file_name": "op1002177-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1430.0, 27.6, 539.5, 319.4], "category_id": 1, "id": 0}, {"bbox": [1420.0, 618.7, 584.0, 329.1], "category_id": 1, "id": 1}, {"bbox": [21.0, 79.0, 616.0, 226.9], "category_id": 1, "id": 2}, {"bbox": [782.1, 0.0, 496.8, 423.8], "category_id": 1, "id": 3}, {"bbox": [612.2, 627.0, 780.8, 328.5], "category_id": 1, "id": 4}, {"bbox": [1637.0, 433.0, 68.0, 65.0], "category_id": 3, "id": 5}, {"bbox": [0.0, 531.0, 463.0, 470.0], "category_id": 1, "id": 6}, {"bbox": [1018.0, 1054.0, 48.0, 60.0], "category_id": 3, "id": 7}, {"bbox": [1721.0, 1061.0, 56.0, 53.0], "category_id": 3, "id": 8}, {"bbox": [354.0, 425.0, 51.0, 57.0], "category_id": 3, "id": 9}, {"bbox": [240.0, 1066.0, 46.0, 50.0], "category_id": 3, "id": 10}, {"bbox": [1062.0, 432.0, 52.0, 63.0], "category_id": 3, "id": 11}], "caption": "Figure 1. Biologically active \u03b2-amino alcohols useful for the treatment of different diseases.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 330, 560, 344], "ImageBB": [159, 48, 660, 327]}, "corefs": [[2, 9], [3, 11], [0, 5], [6, 10], [4, 7], [1, 8]]}, {"id": 1135, "width": 1104, "height": 668, "file_name": "op100010n-Figure-c8.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1.0, 2.0, 456.0, 581.0], "category_id": 1, "id": 0}, {"bbox": [185.0, 621.0, 51.0, 46.0], "category_id": 3, "id": 1}, {"bbox": [787.0, 621.0, 59.0, 44.0], "category_id": 3, "id": 2}, {"bbox": [546.0, 2.0, 555.0, 586.0], "category_id": 1, "id": 3}], "caption": "Figure 8. Degradation products observed on stability.", "pdf": {"Page": 12, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 217, 355, 231], "ImageBB": [89, 47, 365, 214]}, "corefs": [[0, 1], [3, 2]]}, {"id": 1136, "width": 1352, "height": 1036, "file_name": "ol062257t-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [403.0, 520.0, 34.0, 45.0], "category_id": 3, "id": 0}, {"bbox": [907.0, 926.0, 47.0, 42.0], "category_id": 3, "id": 1}, {"bbox": [735.0, 141.0, 400.0, 356.0], "category_id": 1, "id": 2}, {"bbox": [398.0, 918.0, 42.0, 42.0], "category_id": 3, "id": 3}, {"bbox": [905.0, 520.0, 47.0, 47.0], "category_id": 3, "id": 4}, {"bbox": [701.0, 586.0, 429.0, 348.0], "category_id": 1, "id": 5}, {"bbox": [223.0, 654.0, 324.0, 230.0], "category_id": 1, "id": 6}, {"bbox": [223.0, 167.0, 305.0, 353.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Structural fragments A-D of 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 1001, 662, 1014], "ImageBB": [439, 730, 777, 989]}, "corefs": [[7, 0], [2, 4], [6, 3], [5, 1]]}, {"id": 1137, "width": 1352, "height": 852, "file_name": "ol053021c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [293.0, 458.0, 383.0, 282.0], "category_id": 1, "id": 0}, {"bbox": [772.0, 507.0, 380.0, 229.0], "category_id": 1, "id": 1}, {"bbox": [922.0, 740.4, 69.0, 47.6], "category_id": 3, "id": 2}, {"bbox": [212.3, 144.0, 454.7, 271.0], "category_id": 1, "id": 3}, {"bbox": [756.0, 184.7, 370.9, 228.3], "category_id": 1, "id": 4}, {"bbox": [450.0, 728.4, 61.0, 51.2], "category_id": 3, "id": 5}, {"bbox": [930.0, 410.7, 66.0, 50.3], "category_id": 3, "id": 6}, {"bbox": [454.1, 408.6, 59.9, 57.3], "category_id": 3, "id": 7}], "caption": "Figure 1. Structure of palladium complexes (catalyst precursors) investigated in this study. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 674, 409, 701], "ImageBB": [73, 449, 411, 662]}, "corefs": [[3, 7], [4, 6], [0, 5], [1, 2]]}, {"id": 1138, "width": 1356, "height": 1216, "file_name": "acs.orglett.5b01328-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [100.0, 739.0, 565.0, 387.0], "category_id": 1, "id": 0}, {"bbox": [773.0, 774.0, 469.0, 416.0], "category_id": 1, "id": 1}], "caption": "Figure 3. CD spectra of 1 and 2 in MeOH. Representation of the octant rule for the cyclopentenone moiety of 1. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 842, 784, 870], "ImageBB": [448, 529, 787, 833]}, "corefs": []}, {"id": 1139, "width": 1356, "height": 340, "file_name": "acs.oprd.6b00037-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [563.0, 285.0, 148.0, 49.0], "category_id": 3, "id": 0}, {"bbox": [8.0, 37.0, 1338.0, 237.0], "category_id": 1, "id": 1}], "caption": "Figure 2. Chemical structure of menaquinone-7 (MK-7).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 678, 727, 692], "ImageBB": [448, 584, 787, 669]}, "corefs": [[1, 0]]}, {"id": 1140, "width": 2820, "height": 1296, "file_name": "acs.oprd.5b00370-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2165.0, 505.0, 49.9, 62.5], "category_id": 3, "id": 0}, {"bbox": [1995.8, 154.5, 442.9, 364.2], "category_id": 1, "id": 1}], "caption": "Table 3. E\ufb00ect of Temperature and N2H4\u00b7H2O Stoichiometry in the Continuous Reduction of Thebainea", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 382, 674, 404], "ImageBB": [82, 409, 787, 733]}, "corefs": [[1, 0]]}, {"id": 1141, "width": 1168, "height": 532, "file_name": "acs.oprd.5b00209-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 37.5, 860.9, 242.6], "category_id": 1, "id": 0}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 622, 129, 636], "ImageBB": [128, 513, 420, 646]}, "corefs": []}, {"id": 1142, "width": 1352, "height": 468, "file_name": "ol035711r-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [440.0, 137.5, 472.3, 330.5], "category_id": 1, "id": 0}], "caption": "Figure 7. Ar-Pro Interaction.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 180, 229, 193], "ImageBB": [73, 51, 411, 168]}, "corefs": []}, {"id": 1143, "width": 1352, "height": 2088, "file_name": "ol034700v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1060.9, 1740.2, 279.3, 168.7], "category_id": 1, "id": 0}, {"bbox": [0.0, 1339.0, 959.0, 749.0], "category_id": 1, "id": 1}, {"bbox": [799.01, 1897.59, 552.99, 167.94], "category_id": 1, "id": 2}], "caption": "Figure 1. Diagnostic NOEs observed in 25. Hydrogens on C18 and C19 have been omitted for clarity. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 586, 775, 613], "ImageBB": [439, 52, 777, 573]}, "corefs": []}, {"id": 1144, "width": 1348, "height": 1044, "file_name": "ol026156g-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [453.0, 330.0, 481.0, 149.0], "category_id": 3, "id": 0}, {"bbox": [970.0, 328.0, 371.0, 50.0], "category_id": 3, "id": 1}, {"bbox": [13.0, 330.0, 419.0, 150.0], "category_id": 3, "id": 2}, {"bbox": [288.0, 12.0, 339.0, 300.0], "category_id": 1, "id": 3}, {"bbox": [989.0, 9.0, 277.0, 299.0], "category_id": 1, "id": 4}], "caption": "Table 3. Effects of Substrates on the Catalytic Asymmetric Couplings Mediated by 2ea ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 754, 104], "ImageBB": [439, 114, 776, 375]}, "corefs": [[3, 2], [3, 0], [4, 1]]}, {"id": 1145, "width": 2812, "height": 660, "file_name": "ol020229e-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [362.8, 84.8, 125.4, 98.7], "category_id": 1, "id": 0}, {"bbox": [1118.7, 56.1, 158.8, 120.7], "category_id": 1, "id": 1}, {"bbox": [753.5, 122.0, 129.6, 65.7], "category_id": 1, "id": 2}], "caption": "Table 1. Asymmetric Epoxidation of Olefins Catalyzed by Ketones 2a-ea ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 428, 384, 456], "ImageBB": [74, 455, 777, 620]}, "corefs": []}, {"id": 1146, "width": 1304, "height": 2056, "file_name": "jo9806714-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [684.0, 796.0, 620.0, 641.0], "category_id": 1, "id": 0}, {"bbox": [140.0, 469.0, 292.0, 75.0], "category_id": 1, "id": 1}, {"bbox": [684.0, 399.5, 598.5, 211.5], "category_id": 1, "id": 2}, {"bbox": [2.0, 821.0, 575.0, 601.0], "category_id": 1, "id": 3}, {"bbox": [127.3, 14.0, 314.7, 357.5], "category_id": 1, "id": 4}, {"bbox": [0.0, 1426.0, 579.8, 537.0], "category_id": 1, "id": 5}, {"bbox": [674.0, 1458.0, 624.0, 451.0], "category_id": 1, "id": 6}, {"bbox": [680.0, 0.0, 616.3, 373.0], "category_id": 1, "id": 7}], "caption": "Figure 5. Optimized geometries of unsaturated cyclic com- pounds possessing disulfide units by the HF method with the 6-31G* basis set. ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 592, 409, 631], "ImageBB": [80, 66, 406, 580]}, "corefs": []}, {"id": 1147, "width": 1268, "height": 696, "file_name": "jo980407a-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [3.0, 295.0, 933.0, 401.0], "category_id": 1, "id": 0}, {"bbox": [172.0, 4.0, 1009.0, 365.0], "category_id": 1, "id": 1}], "caption": "Figure 7. Molecular structure of the cationic dimer unit (8)2+\u2022, in which the two octamethylbiphenylenes are related by a crystallographic center of symmetry. For comparison, the bond distances in the neutral donor 8 are listed in parentheses.34 ", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 728, 409, 783], "ImageBB": [84, 545, 401, 719]}, "corefs": []}, {"id": 1148, "width": 1348, "height": 620, "file_name": "jo951899j-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [726.1, 8.0, 450.7, 256.8], "category_id": 1, "id": 0}, {"bbox": [1007.0, 155.0, 142.0, 60.0], "category_id": 3, "id": 1}], "caption": "Table 3. Synthesis of the N-Acetylgalactosamine                Conjugates 7a-d ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [87, 394, 374, 419], "ImageBB": [63, 428, 400, 583]}, "corefs": [[0, 1]]}, {"id": 1149, "width": 1352, "height": 680, "file_name": "jo501216h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [159.0, 578.0, 200.0, 50.0], "category_id": 3, "id": 0}, {"bbox": [737.0, 635.0, 406.0, 42.0], "category_id": 3, "id": 1}, {"bbox": [140.0, 272.0, 158.0, 41.0], "category_id": 3, "id": 2}, {"bbox": [682.0, 346.0, 519.0, 271.0], "category_id": 1, "id": 3}, {"bbox": [703.0, 276.0, 269.0, 36.0], "category_id": 3, "id": 4}, {"bbox": [1.0, 329.0, 666.0, 232.0], "category_id": 1, "id": 5}, {"bbox": [608.5, 63.3, 741.5, 235.2], "category_id": 1, "id": 6}, {"bbox": [61.0, 46.0, 479.5, 196.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Examples of some biologically active substituted benzoxazoles and benzothiazoles. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1014, 417, 1042], "ImageBB": [82, 834, 420, 1004]}, "corefs": [[7, 2], [6, 4], [5, 0], [3, 1]]}, {"id": 1150, "width": 1356, "height": 320, "file_name": "jo400461c-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [414.0, 104.0, 525.0, 213.0], "category_id": 1, "id": 0}], "caption": "Figure 4. Structural components of aryl tert-butyl sulfoxide radical cations. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 1032, 784, 1060], "ImageBB": [448, 932, 787, 1012]}, "corefs": []}, {"id": 1151, "width": 1124, "height": 440, "file_name": "jo060663k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [176.0, 403.0, 25.0, 29.0], "category_id": 3, "id": 0}, {"bbox": [31.0, 143.0, 353.0, 258.0], "category_id": 1, "id": 1}, {"bbox": [520.0, 144.0, 352.0, 258.0], "category_id": 1, "id": 2}, {"bbox": [662.0, 399.0, 24.0, 33.0], "category_id": 3, "id": 3}], "caption": "Figure 1. c Values in THF solution are in", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [571, 580, 774, 593], "ImageBB": [495, 607, 776, 717]}, "corefs": [[1, 0], [2, 3]]}, {"id": 1152, "width": 1856, "height": 2212, "file_name": "acs.oprd.5b00137-Table-c11.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [162.0, 1032.0, 251.0, 177.6], "category_id": 1, "id": 0}, {"bbox": [170.7, 1648.55, 352.3, 215.35], "category_id": 1, "id": 1}, {"bbox": [181.7, 498.2, 362.4, 118.9], "category_id": 1, "id": 2}, {"bbox": [176.0, 1365.0, 344.2, 185.5], "category_id": 1, "id": 3}, {"bbox": [173.15, 1992.76, 376.55, 121.84], "category_id": 1, "id": 4}], "caption": "Table 11. Catalytic Hydrosilylation of Functionalized Alkenes with Triethoxysilane over SiliaCat Pt(0) under Di\ufb00erent Reaction Conditionsa [Copyright 2013 American Chemical Society] ", "pdf": {"Page": 11, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 392, 784, 422], "ImageBB": [202, 428, 666, 981]}, "corefs": []}, {"id": 1153, "width": 1352, "height": 616, "file_name": "acs.oprd.5b00137-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [73.0, 40.0, 1201.0, 272.0], "category_id": 1, "id": 0}, {"bbox": [31.0, 391.0, 1302.0, 164.0], "category_id": 1, "id": 1}], "caption": "Figure 5. Oleic acid and elaidic acid are 18-carbon fatty acids with a single double bond. However, oleic acid (top) has a cis double bond, which causes a bend in the fatty acid chain, whereas elaidic acid (bottom) has a trans double bond, which straightens the fatty acid chain and profoundly alters its physiological e\ufb00ects. ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 740, 417, 809], "ImageBB": [82, 577, 420, 731]}, "corefs": []}, {"id": 1154, "width": 1356, "height": 940, "file_name": "acs.joc.5b00632-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1014.12, 209.62, 55.62, 46.13], "category_id": 3, "id": 0}, {"bbox": [145.84, 2.71, 415.15, 193.34], "category_id": 1, "id": 1}, {"bbox": [1014.12, 598.33, 52.91, 45.45], "category_id": 3, "id": 2}, {"bbox": [619.32, 686.52, 358.17, 176.38], "category_id": 1, "id": 3}, {"bbox": [277.44, 202.84, 42.74, 46.13], "category_id": 3, "id": 4}, {"bbox": [799.08, 8.82, 410.4, 217.76], "category_id": 1, "id": 5}, {"bbox": [187.9, 415.17, 359.52, 196.05], "category_id": 1, "id": 6}, {"bbox": [805.87, 394.82, 402.25, 196.73], "category_id": 1, "id": 7}], "caption": "Scheme 4. Solvolysis Studies on 2-Oxoclopidogrel", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 731, 110], "ImageBB": [448, 116, 787, 351]}, "diagram_type": "tree", "corefs": [[1, 4], [5, 0], [7, 2]]}, {"id": 1155, "width": 1128, "height": 776, "file_name": "ja017617g-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [328.41, 433.95, 38.37, 40.06], "category_id": 3, "id": 0}, {"bbox": [821.59, 2.26, 297.95, 171.54], "category_id": 1, "id": 1}, {"bbox": [0.0, 55.87, 215.56, 47.96], "category_id": 1, "id": 2}, {"bbox": [230.23, 345.35, 257.87, 82.39], "category_id": 1, "id": 3}, {"bbox": [230.23, 510.13, 413.05, 259.01], "category_id": 1, "id": 4}, {"bbox": [89.72, 155.75, 56.99, 45.7], "category_id": 3, "id": 5}, {"bbox": [550.18, 178.32, 158.56, 50.22], "category_id": 3, "id": 6}, {"bbox": [493.18, 22.01, 256.75, 129.22], "category_id": 1, "id": 7}, {"bbox": [916.96, 178.88, 138.25, 45.71], "category_id": 3, "id": 8}, {"bbox": [716.64, 319.96, 222.89, 121.32], "category_id": 1, "id": 9}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 337, 491, 349], "ImageBB": [467, 349, 749, 543]}, "diagram_type": "graph", "corefs": [[2, 5], [7, 6], [1, 8], [3, 0]]}, {"id": 1156, "width": 1904, "height": 1748, "file_name": "ja029499i-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1026.77, 5.71, 279.07, 233.32], "category_id": 1, "id": 0}, {"bbox": [1045.82, 554.24, 274.31, 120.95], "category_id": 1, "id": 1}, {"bbox": [0.0, 1276.09, 284.79, 286.65], "category_id": 1, "id": 2}, {"bbox": [1621.11, 1289.42, 271.46, 218.08], "category_id": 1, "id": 3}, {"bbox": [454.33, 647.57, 278.12, 281.88], "category_id": 1, "id": 4}, {"bbox": [1621.11, 697.09, 282.89, 235.22], "category_id": 1, "id": 5}, {"bbox": [1045.82, 1501.79, 280.98, 243.79], "category_id": 1, "id": 6}, {"bbox": [456.24, 1122.77, 282.88, 285.69], "category_id": 1, "id": 7}], "caption": "Scheme 1. Proposed Reaction Topology for the Simultaneous Interconnected Unicyclic Rh and Bimetallic Rh-Mn CBER Hydroformylation Reactions ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 764, 88], "ImageBB": [187, 88, 663, 525]}, "diagram_type": "graph", "corefs": []}, {"id": 1157, "width": 1028, "height": 876, "file_name": "jo0014156-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [289.01, 309.04, 32.4, 39.08], "category_id": 3, "id": 0}, {"bbox": [0.0, 6.68, 363.07, 342.98], "category_id": 1, "id": 1}, {"bbox": [5.14, 538.38, 404.21, 270.99], "category_id": 1, "id": 2}, {"bbox": [698.88, 0.0, 305.46, 339.89], "category_id": 1, "id": 3}, {"bbox": [715.85, 534.78, 312.15, 338.87], "category_id": 1, "id": 4}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [209, 331, 272, 345], "ImageBB": [114, 350, 371, 569]}, "diagram_type": "tree", "corefs": [[1, 0]]}, {"id": 1158, "width": 1336, "height": 1816, "file_name": "jo001614p-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [343.28, 1385.39, 69.02, 52.69], "category_id": 3, "id": 0}, {"bbox": [303.32, 335.22, 203.42, 232.56], "category_id": 1, "id": 1}, {"bbox": [743.77, 414.26, 53.58, 51.78], "category_id": 3, "id": 2}, {"bbox": [0.0, 1121.03, 197.98, 248.01], "category_id": 1, "id": 3}, {"bbox": [681.11, 486.02, 228.85, 261.64], "category_id": 1, "id": 4}, {"bbox": [565.77, 1121.03, 194.35, 248.01], "category_id": 1, "id": 5}, {"bbox": [1066.16, 1123.76, 227.95, 256.18], "category_id": 1, "id": 6}, {"bbox": [455.89, 0.0, 238.84, 243.47], "category_id": 1, "id": 7}, {"bbox": [1066.16, 815.79, 229.76, 193.5], "category_id": 1, "id": 8}, {"bbox": [644.78, 1386.3, 80.83, 49.06], "category_id": 3, "id": 9}, {"bbox": [681.11, 223.48, 227.03, 198.04], "category_id": 1, "id": 10}, {"bbox": [743.77, 659.54, 50.86, 57.23], "category_id": 3, "id": 11}, {"bbox": [0.0, 480.57, 172.55, 68.14], "category_id": 1, "id": 12}, {"bbox": [82.64, 1385.39, 76.29, 52.69], "category_id": 3, "id": 13}, {"bbox": [270.63, 1124.67, 236.11, 255.27], "category_id": 1, "id": 14}, {"bbox": [395.95, 565.06, 49.04, 49.96], "category_id": 3, "id": 15}, {"bbox": [1132.46, 1385.39, 71.74, 47.24], "category_id": 3, "id": 16}, {"bbox": [644.78, 1537.1, 227.95, 198.96], "category_id": 1, "id": 17}, {"bbox": [807.34, 1118.31, 194.34, 250.73], "category_id": 1, "id": 18}, {"bbox": [1051.63, 263.45, 180.72, 139.0], "category_id": 1, "id": 19}, {"bbox": [886.35, 1385.39, 89.9, 49.97], "category_id": 3, "id": 20}, {"bbox": [1172.41, 1763.31, 74.47, 49.96], "category_id": 3, "id": 21}, {"bbox": [1091.59, 1503.49, 191.62, 242.56], "category_id": 1, "id": 22}, {"bbox": [1051.63, 565.06, 283.34, 91.75], "category_id": 1, "id": 23}, {"bbox": [272.44, 819.43, 237.03, 194.4], "category_id": 1, "id": 24}, {"bbox": [33.64, 401.2, 119.91, 52.33], "category_id": 1, "id": 25}, {"bbox": [1119.32, 407.74, 56.68, 47.97], "category_id": 3, "id": 26}, {"bbox": [617.9, 178.84, 52.32, 50.14], "category_id": 3, "id": 27}], "caption": "Scheme 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 358, 636, 372], "ImageBB": [442, 378, 776, 832]}, "diagram_type": "tree", "corefs": [[7, 27], [1, 15], [10, 2], [19, 26], [4, 11], [3, 13], [14, 0], [5, 9], [18, 20], [6, 16], [22, 21]]}, {"id": 1159, "width": 1344, "height": 1092, "file_name": "jo201098c-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [747.64, 465.28, 387.94, 50.43], "category_id": 3, "id": 0}, {"bbox": [172.12, 543.28, 481.39, 447.8], "category_id": 1, "id": 1}, {"bbox": [685.11, 548.66, 480.72, 444.44], "category_id": 1, "id": 2}, {"bbox": [907.65, 996.46, 54.46, 46.39], "category_id": 3, "id": 3}, {"bbox": [665.61, 4.03, 508.96, 443.1], "category_id": 1, "id": 4}, {"bbox": [394.66, 998.48, 42.36, 44.37], "category_id": 3, "id": 5}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 417, 127, 432], "ImageBB": [71, 442, 407, 715]}, "diagram_type": "tree", "corefs": [[4, 0], [1, 5], [2, 3]]}, {"id": 1160, "width": 1352, "height": 1256, "file_name": "jo500412w-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [50.05, 0.0, 361.16, 287.52], "category_id": 1, "id": 0}, {"bbox": [526.87, 896.4, 363.87, 254.38], "category_id": 1, "id": 1}, {"bbox": [789.96, 1153.48, 45.99, 52.77], "category_id": 3, "id": 2}, {"bbox": [931.99, 533.78, 360.49, 174.12], "category_id": 1, "id": 3}, {"bbox": [0.0, 483.04, 377.4, 282.79], "category_id": 1, "id": 4}, {"bbox": [1114.79, 752.47, 25.63, 42.22], "category_id": 3, "id": 5}, {"bbox": [1162.63, 973.53, 104.83, 55.47], "category_id": 1, "id": 6}, {"bbox": [261.74, 223.25, 63.58, 49.39], "category_id": 3, "id": 7}, {"bbox": [1113.93, 194.84, 67.63, 56.83], "category_id": 3, "id": 8}, {"bbox": [938.08, 0.0, 359.81, 214.46], "category_id": 1, "id": 9}, {"bbox": [204.93, 748.92, 62.22, 43.97], "category_id": 3, "id": 10}], "caption": "Scheme 5. Proposed Mechanism for the Synthesis of 3a from 1a ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 405, 125], "ImageBB": [82, 131, 420, 445]}, "diagram_type": "graph", "corefs": [[0, 7], [9, 8], [3, 5], [4, 10], [1, 2]]}, {"id": 1161, "width": 1356, "height": 436, "file_name": "jo501006u-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [664.09, 16.27, 153.31, 151.8], "category_id": 1, "id": 0}, {"bbox": [281.51, 270.41, 176.37, 54.89], "category_id": 1, "id": 1}, {"bbox": [664.09, 185.69, 151.95, 61.0], "category_id": 1, "id": 2}, {"bbox": [87.51, 132.15, 191.29, 73.2], "category_id": 1, "id": 3}, {"bbox": [489.76, 305.65, 118.03, 54.22], "category_id": 1, "id": 4}], "caption": "Scheme 1. 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Proposed Catalytic Cycle for the Indole Synthesis", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 187, 784, 202], "ImageBB": [448, 208, 787, 422]}, "diagram_type": "graph", "corefs": [[8, 10], [2, 5], [4, 3], [11, 0], [9, 12]]}, {"id": 1174, "width": 1008, "height": 636, "file_name": "op010073i-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [137.16, 204.24, 35.8, 42.86], "category_id": 3, "id": 0}, {"bbox": [777.56, 592.03, 32.77, 39.84], "category_id": 3, "id": 1}, {"bbox": [631.83, 232.48, 40.34, 42.36], "category_id": 3, "id": 2}, {"bbox": [0.0, 2.02, 304.57, 167.92], "category_id": 1, "id": 3}, {"bbox": [618.21, 327.28, 313.65, 232.98], "category_id": 1, "id": 4}, {"bbox": [196.66, 546.65, 34.79, 40.34], "category_id": 3, "id": 5}, {"bbox": [62.53, 400.91, 327.26, 89.26], "category_id": 1, "id": 6}, {"bbox": [518.37, 4.54, 324.74, 221.38], "category_id": 1, "id": 7}], "caption": "Scheme 2. Synthetic plan", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 224, 67], "ImageBB": [116, 72, 368, 231]}, "diagram_type": "multiple", "corefs": [[3, 0], [7, 2], [4, 1], [6, 5]]}, {"id": 1175, "width": 1216, "height": 664, "file_name": "op0102013-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [0.0, 2.43, 438.59, 313.84], "category_id": 1, "id": 0}, {"bbox": [0.0, 331.47, 491.51, 316.27], "category_id": 1, "id": 1}, {"bbox": [675.83, 620.98, 43.79, 32.85], "category_id": 3, "id": 2}, {"bbox": [130.18, 291.33, 44.4, 36.5], "category_id": 3, "id": 3}, {"bbox": [675.83, 297.42, 52.31, 35.88], "category_id": 3, "id": 4}, {"bbox": [538.35, 330.87, 489.08, 313.23], "category_id": 1, "id": 5}, {"bbox": [129.57, 623.42, 54.75, 34.06], "category_id": 3, "id": 6}, {"bbox": [548.08, 7.91, 490.3, 313.83], "category_id": 1, "id": 7}], "caption": "Scheme 7. Process for 16r-Me epoxide (3b)", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 689, 67], "ImageBB": [456, 72, 760, 238]}, "diagram_type": "multiple", "corefs": [[0, 3], [7, 4], [1, 6], [5, 2]]}, {"id": 1176, "width": 1248, "height": 1400, "file_name": "op0300488-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [695.61, 49.72, 526.08, 314.46], "category_id": 1, "id": 0}, {"bbox": [63.75, 586.19, 198.24, 84.05], "category_id": 1, "id": 1}, {"bbox": [179.33, 301.15, 45.53, 46.92], "category_id": 3, "id": 2}, {"bbox": [941.49, 1354.48, 56.74, 45.52], "category_id": 3, "id": 3}, {"bbox": [727.13, 1071.54, 481.25, 284.34], "category_id": 1, "id": 4}, {"bbox": [305.42, 552.58, 562.51, 310.95], "category_id": 1, "id": 5}, {"bbox": [0.0, 11.21, 442.02, 233.21], "category_id": 1, "id": 6}, {"bbox": [32.22, 1055.43, 535.9, 233.21], "category_id": 1, "id": 7}, {"bbox": [253.59, 1310.36, 65.14, 47.62], "category_id": 3, "id": 8}], "caption": "Scheme 1. Allylation of \u03b2-D-glucose pentaacetate 2 using ZnCl2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 284, 392, 313], "ImageBB": [86, 316, 398, 666]}, "diagram_type": "multiple", "corefs": [[6, 2], [7, 8], [4, 3]]}, {"id": 1177, "width": 2120, "height": 2380, "file_name": "op049953y-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [228.57, 2171.43, 42.86, 51.43], "category_id": 3, "id": 0}, {"bbox": [133.39, 771.51, 55.97, 57.14], "category_id": 3, "id": 1}, {"bbox": [665.75, 1640.64, 599.07, 464.33], "category_id": 1, "id": 2}, {"bbox": [781.28, 494.1, 483.54, 315.5], "category_id": 1, "id": 3}, {"bbox": [1579.23, 503.62, 478.77, 236.93], "category_id": 1, "id": 4}, {"bbox": [914.67, 2204.98, 115.52, 57.15], "category_id": 3, "id": 5}, {"bbox": [0.0, 0.0, 457.33, 178.59], "category_id": 1, "id": 6}, {"bbox": [915.86, 771.51, 58.36, 57.14], "category_id": 3, "id": 7}, {"bbox": [1751.21, 2207.86, 131.01, 46.43], "category_id": 3, "id": 8}, {"bbox": [136.96, 1402.52, 52.4, 54.77], "category_id": 3, "id": 9}, {"bbox": [889.66, 1403.71, 267.97, 101.2], "category_id": 3, "id": 10}, {"bbox": [1748.35, 1544.2, 59.55, 51.2], "category_id": 3, "id": 11}, {"bbox": [1751.92, 2329.99, 114.34, 50.01], "category_id": 3, "id": 12}, {"bbox": [219.14, 1970.44, 59.55, 61.91], "category_id": 3, "id": 13}, {"bbox": [1457.75, 1640.64, 605.02, 457.19], "category_id": 1, "id": 14}, {"bbox": [778.9, 0.0, 478.77, 178.59], "category_id": 1, "id": 15}, {"bbox": [1575.66, 1092.97, 488.3, 277.41], "category_id": 1, "id": 16}, {"bbox": [0.0, 492.91, 482.34, 323.84], "category_id": 1, "id": 17}, {"bbox": [781.28, 1106.06, 409.69, 272.65], "category_id": 1, "id": 18}, {"bbox": [0.0, 1109.63, 482.34, 292.89], "category_id": 1, "id": 19}, {"bbox": [0.0, 1637.07, 544.28, 305.98], "category_id": 1, "id": 20}, {"bbox": [1748.35, 771.51, 59.55, 57.14], "category_id": 3, "id": 21}, {"bbox": [1579.23, 0.0, 485.92, 234.55], "category_id": 1, "id": 22}, {"bbox": [1748.35, 1413.24, 71.46, 55.95], "category_id": 3, "id": 23}], "caption": "Scheme 1. 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Degradation of GLY I (1) and its dehydrated producta", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 435, 108], "ImageBB": [127, 117, 717, 506]}, "diagram_type": "tree", "corefs": [[1, 7]]}, {"id": 1179, "width": 1352, "height": 716, "file_name": "op3000042-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [108.21, 42.61, 168.69, 62.89], "category_id": 1, "id": 0}, {"bbox": [971.22, 158.93, 38.55, 45.98], "category_id": 3, "id": 1}, {"bbox": [980.69, 621.5, 38.55, 46.66], "category_id": 3, "id": 2}, {"bbox": [894.8, 0.0, 344.93, 165.69], "category_id": 1, "id": 3}, {"bbox": [837.31, 370.6, 390.92, 231.29], "category_id": 1, "id": 4}, {"bbox": [351.7, 451.08, 308.41, 172.45], "category_id": 1, "id": 5}, {"bbox": [178.55, 158.25, 41.94, 47.34], "category_id": 3, "id": 6}, {"bbox": [363.19, 0.0, 242.81, 163.66], "category_id": 1, "id": 7}, {"bbox": [487.64, 158.93, 43.29, 45.98], "category_id": 3, "id": 8}, {"bbox": [403.1, 623.53, 39.23, 45.99], "category_id": 3, "id": 9}], "caption": "Scheme 1. Ritter\u2019s originally proposed mechanism", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 365, 110], "ImageBB": [82, 116, 420, 295]}, "diagram_type": "tree", "corefs": [[0, 6], [7, 8], [3, 1], [4, 2], [5, 9]]}, {"id": 1180, "width": 1352, "height": 1984, "file_name": "op300031r-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [90.35, 397.99, 660.29, 296.76], "category_id": 1, "id": 0}, {"bbox": [962.42, 1889.48, 171.3, 51.13], "category_id": 3, "id": 1}, {"bbox": [962.0, 1835.13, 242.4, 47.77], "category_id": 3, "id": 2}, {"bbox": [555.03, 1199.93, 224.4, 110.17], "category_id": 3, "id": 3}, {"bbox": [913.4, 398.98, 356.53, 299.74], "category_id": 1, "id": 4}, {"bbox": [142.98, 1694.19, 218.44, 102.23], "category_id": 3, "id": 5}, {"bbox": [1055.46, 683.83, 66.52, 49.62], "category_id": 3, "id": 6}, {"bbox": [707.94, 291.79, 65.53, 51.61], "category_id": 3, "id": 7}, {"bbox": [381.28, 684.82, 59.57, 44.66], "category_id": 3, "id": 8}, {"bbox": [552.06, 14.89, 389.22, 286.83], "category_id": 1, "id": 9}, {"bbox": [735.74, 1327.96, 554.05, 519.08], "category_id": 1, "id": 10}, {"bbox": [57.59, 1411.33, 390.21, 290.8], "category_id": 1, "id": 11}, {"bbox": [478.58, 934.93, 387.23, 286.83], "category_id": 1, "id": 12}], "caption": "Scheme 6. Conversion of Acid 27 to Akt Inhibitor 1", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 378, 110], "ImageBB": [82, 116, 420, 612]}, "diagram_type": "multiple", "corefs": [[9, 7], [4, 6], [0, 8], [12, 3], [11, 5], [10, 2], [10, 1]]}, {"id": 1181, "width": 1352, "height": 1248, "file_name": "op300170q-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1193.74, 630.58, 65.6, 56.16], "category_id": 3, "id": 0}, {"bbox": [1113.93, 418.81, 203.58, 192.83], "category_id": 1, "id": 1}, {"bbox": [528.9, 77.13, 139.32, 172.53], "category_id": 1, "id": 2}, {"bbox": [973.25, 391.75, 67.63, 54.12], "category_id": 3, "id": 3}, {"bbox": [185.32, 1083.22, 42.61, 56.16], "category_id": 3, "id": 4}, {"bbox": [835.95, 713.8, 378.08, 462.12], "category_id": 1, "id": 5}, {"bbox": [121.74, 382.95, 72.37, 59.54], "category_id": 3, "id": 6}, {"bbox": [986.78, 1107.58, 64.25, 59.54], "category_id": 3, "id": 7}, {"bbox": [47.34, 77.13, 267.16, 329.5], "category_id": 1, "id": 8}, {"bbox": [33.14, 748.99, 365.9, 338.97], "category_id": 1, "id": 9}, {"bbox": [808.22, 0.0, 372.67, 442.49], "category_id": 1, "id": 10}], "caption": "Scheme 2. 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Chlorination of Pyrrolotriazine 12", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 705, 110], "ImageBB": [448, 116, 787, 375]}, "diagram_type": "graph", "corefs": [[3, 7], [6, 9], [1, 0], [2, 8], [5, 10]]}, {"id": 1183, "width": 3396, "height": 1028, "file_name": "op300331b-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [1600.32, 668.54, 69.65, 59.38], "category_id": 3, "id": 0}, {"bbox": [2313.83, 27.15, 239.54, 152.71], "category_id": 1, "id": 1}, {"bbox": [1306.42, 352.93, 703.32, 407.23], "category_id": 1, "id": 2}, {"bbox": [910.58, 45.81, 254.83, 154.41], "category_id": 1, "id": 3}], "caption": "Scheme 10. Formation of unwanted diacylation side product 23", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 838, 442, 853], "ImageBB": [10, 870, 859, 1127]}, "diagram_type": "tree", "corefs": [[2, 0]]}, {"id": 1184, "width": 1356, "height": 1124, "file_name": "op4003467-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [346.63, 274.71, 68.51, 57.66], "category_id": 3, "id": 0}, {"bbox": [986.98, 274.71, 63.09, 55.62], "category_id": 3, "id": 1}, {"bbox": [798.41, 16.28, 318.81, 284.88], "category_id": 1, "id": 2}, {"bbox": [944.93, 699.33, 68.51, 51.55], "category_id": 3, "id": 3}, {"bbox": [219.1, 71.22, 316.11, 170.93], "category_id": 1, "id": 4}, {"bbox": [799.08, 390.7, 324.25, 316.09], "category_id": 1, "id": 5}, {"bbox": [564.38, 651.17, 67.83, 54.26], "category_id": 3, "id": 6}, {"bbox": [374.44, 392.74, 306.61, 272.67], "category_id": 1, "id": 7}, {"bbox": [558.95, 189.25, 172.3, 93.6], "category_id": 1, "id": 8}], "caption": "Scheme 3. 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