{"categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "images": [{"id": 1186, "width": 2816, "height": 1200, "file_name": "ja1048847-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [737.09, 5.48, 269.58, 212.24], "category_id": 1}, {"id": 1, "bbox": [1452.77, 16.1, 290.82, 184.64], "category_id": 1}, {"id": 2, "bbox": [1784.06, 16.1, 292.95, 184.64], "category_id": 1}, {"id": 4, "bbox": [1450.64, 307.04, 292.95, 212.25], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [6, 7], "products": [2, 3, 5]}], "caption": "Table 3. Synthesis of Indanes: Study of C(sp3)-H Arylation Parameters", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 56, 418, 69], "ImageBB": [58, 78, 762, 378]}, "diagram_type": "single"}, {"id": 1187, "width": 1408, "height": 1760, "file_name": "ja0014685-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [832.04, 258.08, 438.84, 246.94], "category_id": 1}, {"id": 1, "bbox": [155.3, 253.0, 358.05, 246.97], "category_id": 1}, {"id": 2, "bbox": [205.81, 692.4, 289.87, 188.86], "category_id": 1}, {"id": 3, "bbox": [592.16, 727.75, 150.98, 138.36], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [15, 16], "products": [0]}, {"reactants": [0], "conditions": [17, 5], "products": [3, 4]}, {"reactants": [0], "conditions": [18, 6], "products": [11]}, {"reactants": [11], "conditions": [7], "products": [12]}, {"reactants": [11], "conditions": [14], "products": [13]}], "caption": "Figure 1. 1H NMR spectrum (400 MHz) for 2 at -50 \u00b0C in CD2Cl2. The signals marked with +, *, and # corresponds to those for 5, mesitylene, and triphenylmethane, respectively. A signal for the two mesityl ring protons of 2 is overlapped with signals for triphenylmethane. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 476, 775, 533], "ImageBB": [424, 36, 776, 475]}, "diagram_type": "tree"}, {"id": 1188, "width": 1348, "height": 1192, "file_name": "ol8001706-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [221.0, 31.0, 316.0, 187.0], "category_id": 1}, {"id": 1, "bbox": [885.0, 0.0, 253.0, 220.0], "category_id": 1}], "reactions": [{"reactants": [1, 3], "conditions": [], "products": [2]}], "caption": "Table 1. HDA Reaction between Diene 1 and Benzaldehyde Catalyzed by Ti/L4 under Various Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 620, 760, 648], "ImageBB": [439, 658, 776, 956]}, "diagram_type": "single"}, {"id": 1189, "width": 1352, "height": 392, "file_name": "ol1022036-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [452.0, 32.1, 144.1, 62.8], "category_id": 1}, {"id": 2, "bbox": [31.0, 29.0, 289.7, 66.8], "category_id": 1}, {"id": 3, "bbox": [1040.2, 0.0, 286.8, 131.6], "category_id": 1}], "reactions": [{"reactants": [5, 4], "conditions": [2, 3], "products": [6]}], "caption": "Table 1. Microwave-Assisted One-Pot TMS-Deprotection of Compounds 1a-g and Cycloaddition with Azides 2a-c to Give Triazoles 3a-i ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 703, 390, 744], "ImageBB": [58, 753, 396, 851]}, "diagram_type": "single"}, {"id": 1190, "width": 1348, "height": 280, "file_name": "ol501422k-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [38.7, 6.6, 222.0, 125.4], "category_id": 1}, {"id": 4, "bbox": [1035.6, 4.0, 279.2, 127.6], "category_id": 1}, {"id": 5, "bbox": [674.9, 6.0, 338.0, 123.9], "category_id": 1}, {"id": 6, "bbox": [321.7, 11.4, 92.1, 115.5], "category_id": 1}], "reactions": [{"reactants": [5, 8], "conditions": [9, 1], "products": [7, 6]}], "caption": "Table 1. Optimization of the Br\u00f8nsted Acid Promoted Benzylic Nucleophilic Addition of Azaarenesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 383, 125], "ImageBB": [82, 131, 419, 201]}, "diagram_type": "single"}, {"id": 1191, "width": 1352, "height": 392, "file_name": "ol034469l-Figure-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [642.3, 207.3, 412.6, 182.7], "category_id": 1}, {"id": 3, "bbox": [28.2, 223.4, 242.5, 154.4], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4], "products": [1]}], "caption": "Figure 1. Original observation.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 450, 240, 463], "ImageBB": [73, 340, 411, 438]}, "diagram_type": "single"}, {"id": 1192, "width": 1488, "height": 1812, "file_name": "ol016693l-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [458.0, 1681.0, 206.0, 130.0], "category_id": 1}, {"id": 1, "bbox": [610.0, 1291.0, 355.1, 192.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [0], "products": [3]}, {"reactants": [5], "conditions": [2], "products": [1]}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 990, 491, 1003], "ImageBB": [408, 525, 780, 978]}, "diagram_type": "tree"}, {"id": 1193, "width": 3396, "height": 1324, "file_name": "jo4027148-Figure-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2121.0, 971.4, 313.0, 285.8], "category_id": 1}, {"id": 8, "bbox": [412.0, 288.0, 555.0, 439.0], "category_id": 1}, {"id": 9, "bbox": [1435.0, 318.0, 476.0, 375.0], "category_id": 1}, {"id": 10, "bbox": [1504.0, 965.0, 345.0, 277.0], "category_id": 1}, {"id": 11, "bbox": [794.0, 1053.0, 276.0, 118.0], "category_id": 1}, {"id": 12, "bbox": [2405.0, 289.0, 554.0, 440.0], "category_id": 1}, {"id": 13, "bbox": [2726.0, 953.0, 177.0, 285.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [11], "products": [12]}, {"reactants": [17], "conditions": [13], "products": [12]}, {"reactants": [12], "conditions": [0], "products": [14]}, {"reactants": [15], "conditions": [16], "products": [14]}, {"reactants": [14], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [19], "products": [18]}], "caption": "Figure 7. Retrosynthesis of the piperarborenines from methyl coumalate (78).", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 362, 463, 376], "ImageBB": [10, 22, 859, 353]}, "diagram_type": "tree"}, {"id": 1194, "width": 2820, "height": 1636, "file_name": "jo202571h-Figure-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [1935.0, 426.2, 330.3, 283.8], "category_id": 1}, {"id": 4, "bbox": [1554.6, 429.4, 335.4, 278.6], "category_id": 1}, {"id": 7, "bbox": [1540.0, 710.0, 345.0, 345.0], "category_id": 1}, {"id": 11, "bbox": [1186.0, 715.0, 321.0, 349.0], "category_id": 1}, {"id": 14, "bbox": [1928.0, 715.0, 340.0, 335.0], "category_id": 1}, {"id": 15, "bbox": [1983.0, 1196.6, 345.3, 316.4], "category_id": 1}, {"id": 16, "bbox": [1598.2, 1195.8, 307.8, 314.2], "category_id": 1}, {"id": 17, "bbox": [495.0, 430.9, 289.0, 279.1], "category_id": 1}, {"id": 18, "bbox": [1825.5, 7.0, 497.4, 280.6], "category_id": 1}, {"id": 19, "bbox": [1295.8, 4.0, 464.6, 289.1], "category_id": 1}, {"id": 20, "bbox": [468.0, 7.0, 423.5, 281.9], "category_id": 1}, {"id": 21, "bbox": [779.0, 432.0, 258.3, 277.0], "category_id": 1}, {"id": 22, "bbox": [1181.5, 430.0, 329.5, 280.0], "category_id": 1}, {"id": 24, "bbox": [1107.5, 1213.6, 303.3, 327.7], "category_id": 1}, {"id": 25, "bbox": [624.2, 1216.0, 342.8, 323.0], "category_id": 1}], "reactions": [{"reactants": [28], "conditions": [0, 9], "products": [27, 26]}], "caption": "Figure 1. Mutual orientation of the neighboring aromatic rings in S-alkylated thiacalix[4]arenes and the assignment of the stereochemistry of S-alkyl groups. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 535, 784, 563], "ImageBB": [82, 116, 787, 525]}, "diagram_type": "single"}, {"id": 1195, "width": 1476, "height": 2592, "file_name": "ja042849b-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [1101.31, 1589.87, 344.39, 255.56], "category_id": 1}, {"id": 3, "bbox": [768.61, 1618.94, 292.71, 76.29], "category_id": 1}, {"id": 4, "bbox": [922.0, 1932.3, 268.52, 100.48], "category_id": 1}, {"id": 5, "bbox": [203.34, 2098.61, 444.53, 331.47], "category_id": 1}, {"id": 6, "bbox": [775.07, 2239.12, 200.65, 118.28], "category_id": 1}, {"id": 7, "bbox": [1099.7, 2096.99, 350.85, 257.18], "category_id": 1}, {"id": 8, "bbox": [130.66, 1589.87, 184.5, 255.56], "category_id": 1}, {"id": 9, "bbox": [557.04, 1589.87, 186.11, 255.56], "category_id": 1}, {"id": 10, "bbox": [799.72, 905.91, 665.41, 500.0], "category_id": 1}, {"id": 11, "bbox": [139.37, 952.63, 546.72, 369.95], "category_id": 1}], "reactions": [{"reactants": [16], "conditions": [15, 0], "products": [17]}, {"reactants": [17], "conditions": [10, 25, 1], "products": [9]}, {"reactants": [9], "conditions": [11, 2, 3], "products": [14]}, {"reactants": [14], "conditions": [4, 6, 13, 5], "products": [12]}], "caption": "Table 1. Turnover Numbers for the Dismutation of H2O2 Catalyzed by Manganese Salophen Complexes ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 701, 723, 725], "ImageBB": [408, 42, 777, 690]}, "diagram_type": "multiple"}, {"id": 1196, "width": 1348, "height": 676, "file_name": "op900197r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [719.0, 9.0, 483.0, 171.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 1], "products": [3]}], "caption": "Table 1. Cyclization/reduction of 18", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 625, 60], "ImageBB": [425, 74, 762, 243]}, "diagram_type": "single"}, {"id": 1197, "width": 1284, "height": 1228, "file_name": "op8001596-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [969.0, 0.0, 307.1, 229.7], "category_id": 1}, {"id": 3, "bbox": [7.7, 23.4, 309.1, 178.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [1, 4], "products": [0]}], "caption": "Figure 2. Decomposition profile of 2-lithio-3,4-difluoroanisole 6 (0.47 M). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 489, 393, 516], "ImageBB": [66, 179, 387, 486]}, "diagram_type": "single"}, {"id": 1198, "width": 1640, "height": 828, "file_name": "op060249m-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [575.0, 107.0, 336.6, 144.3], "category_id": 1}, {"id": 1, "bbox": [222.0, 580.1, 258.0, 130.9], "category_id": 1}, {"id": 2, "bbox": [1249.7, 509.9, 333.7, 249.7], "category_id": 1}, {"id": 3, "bbox": [1.0, 111.1, 337.2, 140.0], "category_id": 1}, {"id": 7, "bbox": [977.42, 44.51, 138.2, 120.17], "category_id": 1}, {"id": 8, "bbox": [1265.0, 69.0, 330.0, 259.0], "category_id": 1}, {"id": 9, "bbox": [712.0, 461.0, 366.0, 325.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [6], "products": [0]}, {"reactants": [0], "conditions": [8], "products": [9]}, {"reactants": [9], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [1]}], "caption": "Figure 3. Proposed mechanism for the reaction of (S)-propylene oxide with TEPA anions.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 264, 571, 278], "ImageBB": [220, 54, 630, 261]}, "diagram_type": "multiple"}, {"id": 1199, "width": 2808, "height": 2436, "file_name": "op049803n-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1587.0, 1899.0, 258.0, 234.2], "category_id": 1}, {"id": 1, "bbox": [1495.0, 1337.0, 256.0, 229.0], "category_id": 1}, {"id": 2, "bbox": [654.0, 1901.0, 261.0, 242.0], "category_id": 1}, {"id": 3, "bbox": [660.0, 1342.0, 275.0, 224.0], "category_id": 1}], "reactions": [{"reactants": [15, 8], "conditions": [7, 5], "products": [6, 9]}, {"reactants": [10, 11, 12], "conditions": [13], "products": [2, 3, 4]}], "caption": "Table 7. Summary of kernel reaction metrics analysis for sildenafil (Viagra) synthesis determined by algorithm described in text under the assumptions of recoverable reaction solvents and catalysts, solvents used in workup and purification procedures, and each intermediate product committed as a substrate in the next consecutive step in the sequencea ", "pdf": {"Page": 13, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 769, 95], "ImageBB": [74, 98, 776, 707]}, "diagram_type": "multiple"}, {"id": 1200, "width": 1292, "height": 716, "file_name": "op000298d-Table-c1.png", "license": 0, "bboxes": [{"id": 4, "bbox": [598.9, 78.9, 255.1, 248.1], "category_id": 1}, {"id": 5, "bbox": [131.0, 163.2, 296.0, 70.8], "category_id": 1}, {"id": 6, "bbox": [49.0, 428.2, 363.0, 287.8], "category_id": 1}, {"id": 7, "bbox": [803.0, 429.8, 363.0, 286.2], "category_id": 1}], "reactions": [{"reactants": [9, 8], "conditions": [5, 4], "products": [10]}, {"reactants": [10], "conditions": [3, 2], "products": [11]}], "caption": "Table 1. Pilot plant lots of acrylate 5", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 244, 278, 258], "ImageBB": [74, 52, 397, 231]}, "diagram_type": "multiple"}, {"id": 1201, "width": 1344, "height": 672, "file_name": "ol991356m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [152.0, 11.1, 351.0, 107.0], "category_id": 1}, {"id": 1, "bbox": [781.1, 9.9, 419.8, 110.2], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [3], "products": [1]}], "caption": "Table 1. Efficiency of Various Pd Catalysts on the Formation of 4-Nitrobiphenyl in THF-MeOHa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 378, 401, 406], "ImageBB": [74, 410, 410, 578]}, "diagram_type": "single"}, {"id": 1202, "width": 2816, "height": 1788, "file_name": "ol101406k-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [1574.0, 8.0, 233.4, 134.6], "category_id": 1}, {"id": 2, "bbox": [1911.2, 3.2, 161.8, 140.0], "category_id": 1}, {"id": 3, "bbox": [1271.8, 12.8, 215.8, 142.0], "category_id": 1}, {"id": 4, "bbox": [745.8, 16.0, 159.0, 137.2], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2], "products": [4, 1, 3]}], "caption": "Table 1. Uncatalyzed and Enzyme Catalyzed Azidolysis: Substrate Scope", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 439, 88], "ImageBB": [58, 97, 762, 544]}, "diagram_type": "single"}, {"id": 1203, "width": 1352, "height": 1228, "file_name": "op400278d-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [52.9, 43.0, 172.1, 202.0], "category_id": 1}, {"id": 6, "bbox": [110.0, 792.0, 329.0, 217.0], "category_id": 1}, {"id": 7, "bbox": [934.0, 723.0, 316.0, 329.0], "category_id": 1}, {"id": 8, "bbox": [449.0, 564.0, 480.0, 278.0], "category_id": 1}, {"id": 9, "bbox": [43.0, 357.0, 497.0, 188.0], "category_id": 1}, {"id": 10, "bbox": [888.0, 347.0, 464.0, 253.0], "category_id": 1}, {"id": 11, "bbox": [919.0, 78.0, 433.0, 190.0], "category_id": 1}, {"id": 12, "bbox": [305.0, 57.0, 174.0, 199.0], "category_id": 1}], "reactions": [{"reactants": [0, 20], "conditions": [8, 5], "products": [19]}], "caption": "Table 6. Comparative study of Pd-PEPPSI-IPent (1) and Pd- PEPPSI-IPentCl (84) in aryl aminations with electron- de\ufb01cient anilines and electron-rich aryl chlorides ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 141, 417, 186], "ImageBB": [82, 193, 420, 500]}, "diagram_type": "single"}, {"id": 1204, "width": 1344, "height": 1176, "file_name": "op200005e-Table-c1.png", "license": 0, "bboxes": [{"id": 4, "bbox": [628.0, 364.0, 705.0, 328.0], "category_id": 1}, {"id": 5, "bbox": [34.0, 433.0, 205.0, 153.0], "category_id": 1}, {"id": 6, "bbox": [19.0, 69.0, 338.0, 244.0], "category_id": 1}, {"id": 7, "bbox": [732.0, 0.0, 456.0, 246.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [10, 3], "products": [9, 6]}], "caption": "Table 1. Formation of Amide 13 from 8 and Homopiperazine", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 446, 405, 461], "ImageBB": [71, 471, 407, 765]}, "diagram_type": "single"}, {"id": 1205, "width": 996, "height": 1456, "file_name": "jo000585f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [169.6, 1140.0, 340.8, 225.1], "category_id": 1}, {"id": 5, "bbox": [163.0, 79.0, 335.2, 234.0], "category_id": 1}, {"id": 6, "bbox": [158.6, 639.5, 347.5, 222.7], "category_id": 1}, {"id": 7, "bbox": [648.0, 75.0, 345.0, 236.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [], "products": [8]}, {"reactants": [6], "conditions": [5], "products": [7]}, {"reactants": [7], "conditions": [], "products": [0]}], "caption": "  Table 1. Phosphoramidate-Aminophosphonate Rearrangement of (R)-[1-2H1]6c Induced by s-BuLi or               LDA in Et2O or THF ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 440, 761, 478], "ImageBB": [424, 63, 673, 427]}, "diagram_type": "tree"}, {"id": 1206, "width": 1348, "height": 428, "file_name": "acs.orglett.5b02743-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [16.2, 17.3, 302.7, 214.8], "category_id": 1}, {"id": 3, "bbox": [452.3, 153.4, 178.4, 78.3], "category_id": 1}, {"id": 4, "bbox": [919.3, 2.0, 409.5, 229.9], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 7, 5], "products": [6]}], "caption": "Table 1. Exploration of Optimal Conditions for Activation of tert-Butyl Sul\ufb01nyl Groupa ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 631, 784, 662], "ImageBB": [449, 668, 786, 775]}, "diagram_type": "single"}, {"id": 1207, "width": 1356, "height": 720, "file_name": "acs.oprd.6b00180-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [361.0, 72.6, 250.0, 133.4], "category_id": 1}, {"id": 1, "bbox": [1017.0, 1.0, 332.0, 222.0], "category_id": 1}, {"id": 4, "bbox": [3.0, 57.0, 266.0, 159.0], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [2, 3], "products": [1]}], "caption": "Table 6. Temperature E\ufb00ects on the 100 mL Scale Suzuki Reaction of 4-Bromoaniline (2) with PhB(OH)2 in H2O with No Added Liganda ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 553, 777, 599], "ImageBB": [448, 605, 787, 785]}, "diagram_type": "single"}, {"id": 1208, "width": 1344, "height": 544, "file_name": "jo991283k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [251.3, 59.1, 173.6, 137.9], "category_id": 1}, {"id": 1, "bbox": [844.4, 60.0, 179.3, 135.8], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 5], "products": [1]}], "caption": "Table 2. Effect of Bulkiness of the Group Adjacent to    the Carbonyl Moiety on Stereoselectivity in the           Reduction by the APG4 Systema ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [84, 342, 399, 379], "ImageBB": [74, 385, 410, 521]}, "diagram_type": "single"}, {"id": 1209, "width": 1352, "height": 2596, "file_name": "jo2001275-Figure-c2.png", "license": 0, "bboxes": [{"id": 4, "bbox": [348.0, 3.0, 382.0, 388.0], "category_id": 1}, {"id": 5, "bbox": [977.1, 436.0, 374.9, 391.6], "category_id": 1}, {"id": 6, "bbox": [951.0, 10.0, 397.7, 393.2], "category_id": 1}, {"id": 7, "bbox": [398.7, 439.7, 318.3, 375.3], "category_id": 1}, {"id": 8, "bbox": [336.0, 835.7, 855.0, 675.3], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [10, 19], "products": [4]}, {"reactants": [4], "conditions": [11, 17], "products": [6]}, {"reactants": [6], "conditions": [18, 8], "products": [7]}, {"reactants": [7], "conditions": [15, 14], "products": [5]}], "caption": "Figure 2. Biological evaluation of damsin and psilostachyin C.", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 780, 368, 794], "ImageBB": [71, 117, 409, 766]}, "diagram_type": "multiple"}, {"id": 1210, "width": 1356, "height": 2468, "file_name": "jo102193q-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [688.18, 0.0, 367.28, 300.9], "category_id": 1}, {"id": 1, "bbox": [355.0, 0.1, 372.8, 305.3], "category_id": 1}, {"id": 4, "bbox": [274.0, 568.0, 327.0, 263.0], "category_id": 1}, {"id": 5, "bbox": [547.0, 603.0, 601.0, 342.0], "category_id": 1}, {"id": 6, "bbox": [297.0, 1055.0, 510.0, 342.0], "category_id": 1}], "reactions": [{"reactants": [15], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}, {"reactants": [14], "conditions": [5, 9], "products": [6]}, {"reactants": [6], "conditions": [8], "products": [7]}, {"reactants": [11], "conditions": [10], "products": [12]}], "caption": "Figure 2. Anti-proliferative activity of compound 2 against HeLa cells incubated with di\ufb00erent concentrations at di\ufb00erent times (24 96 h). The data are expressed as a percentage of the control MTT reduction (always taken as 100%) and represent the average ( SEM (n = 3). * denotes more signi\ufb01cant value (P < 0.05).13 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 748, 405, 817], "ImageBB": [71, 117, 410, 734]}, "diagram_type": "tree"}, {"id": 1211, "width": 1348, "height": 384, "file_name": "acs.oprd.5b00144-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [119.0, 27.4, 478.0, 187.6], "category_id": 1}, {"id": 2, "bbox": [886.0, 1.0, 350.0, 210.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 2], "products": [3]}], "caption": "Table 1. Reaction Condition Optimization of Friedel\u2212Crafts Alkylation in the Synthesis of Racemic Lorcaserin ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 529, 417, 559], "ImageBB": [82, 566, 419, 662]}, "diagram_type": "single"}, {"id": 1212, "width": 1356, "height": 704, "file_name": "jacs.5b05415-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1045.69, 250.49, 264.53, 168.23], "category_id": 1}, {"id": 1, "bbox": [18.31, 496.66, 277.24, 167.33], "category_id": 1}, {"id": 2, "bbox": [1020.26, 496.66, 311.76, 167.33], "category_id": 1}, {"id": 9, "bbox": [553.35, 271.38, 166.41, 156.43], "category_id": 1}, {"id": 10, "bbox": [17.4, 271.38, 225.46, 126.45], "category_id": 1}, {"id": 11, "bbox": [1056.59, 44.29, 243.63, 168.23], "category_id": 1}], "reactions": [{"reactants": [20], "conditions": [3, 4], "products": [19]}, {"reactants": [19], "conditions": [18, 6], "products": [21]}, {"reactants": [19], "conditions": [5, 7], "products": [0]}, {"reactants": [19], "conditions": [8, 9], "products": [1]}, {"reactants": [19], "conditions": [10, 11], "products": [2]}], "caption": "Figure 1. Gold catalysis and radical reaction relay.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 825, 688, 839], "ImageBB": [448, 640, 787, 816]}, "diagram_type": "tree"}, {"id": 1213, "width": 1012, "height": 680, "file_name": "op700178q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [686.6, 29.8, 324.4, 257.2], "category_id": 1}, {"id": 1, "bbox": [1.5, 36.7, 311.8, 255.4], "category_id": 1}, {"id": 2, "bbox": [412.2, 423.8, 515.4, 256.2], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [8, 9, 10], "products": [2]}, {"reactants": [2], "conditions": [0, 1], "products": [4]}], "caption": "Table 1. Catalyst N-substituent optimisation studya", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 456, 341, 470], "ImageBB": [158, 275, 411, 445]}, "diagram_type": "multiple"}, {"id": 1214, "width": 1348, "height": 472, "file_name": "op0501242-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [130.5, 3.0, 193.4, 188.9], "category_id": 1}, {"id": 3, "bbox": [397.1, 3.0, 217.9, 191.9], "category_id": 1}, {"id": 5, "bbox": [878.3, 5.0, 344.3, 189.8], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [6, 3], "products": [8]}], "caption": "Table 3. Coupling reactions of N-substituted anilines with 2-fluorobenzoic acids in THF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 758, 81], "ImageBB": [439, 85, 776, 203]}, "diagram_type": "single"}, {"id": 1215, "width": 2508, "height": 1716, "file_name": "op000111i-Figure-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [794.5, 612.5, 288.5, 272.8], "category_id": 1}, {"id": 1, "bbox": [290.1, 637.9, 261.6, 245.2], "category_id": 1}, {"id": 2, "bbox": [1176.6, 659.4, 642.2, 723.8], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [5], "products": [0]}], "caption": "Figure 10. Continuous reduction of tetralone, applying polysiloxane-bound oxazaborolidine as catalyst.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 495, 642, 509], "ImageBB": [112, 55, 739, 484]}, "diagram_type": "single"}, {"id": 1216, "width": 1344, "height": 948, "file_name": "op000061h-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [17.1, 43.0, 177.0, 158.0], "category_id": 1}, {"id": 3, "bbox": [258.5, 88.5, 76.6, 62.5], "category_id": 1}, {"id": 4, "bbox": [1079.9, 30.8, 250.5, 167.5], "category_id": 1}, {"id": 5, "bbox": [807.7, 26.3, 282.0, 173.8], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [6, 10], "products": [7, 5]}], "caption": "Table 1. Effect of transition metal salt on aerobic oxidation of 3-methylpyridine (1) by NHPIa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 401, 81], "ImageBB": [74, 88, 410, 326]}, "diagram_type": "single"}, {"id": 1217, "width": 1352, "height": 1056, "file_name": "ol901684h-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [914.9, 72.8, 407.2, 138.0], "category_id": 1}, {"id": 4, "bbox": [278.0, 111.2, 266.0, 63.5], "category_id": 1}, {"id": 5, "bbox": [25.8, 79.0, 208.2, 135.5], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [3, 2], "products": [6]}], "caption": "Table 1. Optimization for Nickel-Catalyzed Direct Alkynylation of Benzoxazole (1) with (Bromoethynyl)benzene (2a)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 195, 390, 222], "ImageBB": [58, 231, 396, 495]}, "diagram_type": "single"}, {"id": 1218, "width": 1344, "height": 1860, "file_name": "ol102738b-Table-c2.png", "license": 0, "bboxes": [{"id": 2, "bbox": [566.0, 21.0, 309.0, 217.0], "category_id": 1}, {"id": 3, "bbox": [655.0, 238.0, 255.0, 116.0], "category_id": 1}, {"id": 4, "bbox": [888.0, 7.5, 316.0, 239.5], "category_id": 1}, {"id": 5, "bbox": [317.0, 12.5, 252.1, 112.6], "category_id": 1}, {"id": 6, "bbox": [139.4, 44.5, 185.6, 153.5], "category_id": 1}, {"id": 9, "bbox": [916.0, 241.0, 272.0, 113.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 1], "products": [3, 5]}], "caption": "Table 2. PBu3-Catalyzed Cascade [3 \u00fe 2] Cyclization-Allylic Alkylation and [2 \u00fe 2 \u00fe 1] Annulation of 1 and 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 397, 117], "ImageBB": [71, 126, 407, 591]}, "diagram_type": "single"}, {"id": 1219, "width": 1344, "height": 700, "file_name": "op200174k-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [932.4, 25.0, 269.4, 185.9], "category_id": 1}, {"id": 1, "bbox": [418.0, 89.0, 202.0, 74.8], "category_id": 1}, {"id": 2, "bbox": [472.1, 482.1, 202.8, 75.8], "category_id": 1}, {"id": 3, "bbox": [922.7, 496.4, 269.7, 135.2], "category_id": 1}, {"id": 4, "bbox": [161.6, 497.5, 149.9, 135.1], "category_id": 1}, {"id": 5, "bbox": [160.3, 23.1, 177.6, 136.8], "category_id": 1}], "reactions": [{"reactants": [9, 4], "conditions": [7], "products": [3]}, {"reactants": [9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [5], "products": [6, 2]}], "caption": "Figure 1. Redox-neutral (borrowing hydrogen, hydrogen autotransfer) aminations. ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 425, 405, 453], "ImageBB": [71, 236, 407, 411]}, "diagram_type": "graph"}, {"id": 1220, "width": 1344, "height": 816, "file_name": "ol051920v-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [76.3, 11.6, 235.2, 189.0], "category_id": 1}, {"id": 3, "bbox": [379.1, 41.8, 198.8, 180.2], "category_id": 1}, {"id": 5, "bbox": [956.0, 1.8, 315.9, 196.1], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [6, 3], "products": [7]}], "caption": "Table 3. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with 3-Benzylpenta-3,4-dien-2-one 2b (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at Room Temperature ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 402, 120], "ImageBB": [74, 125, 410, 329]}, "diagram_type": "single"}, {"id": 1221, "width": 1316, "height": 1164, "file_name": "acs.orglett.5b03590-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [222.2, 2.0, 328.8, 215.0], "category_id": 1}, {"id": 4, "bbox": [66.0, 866.0, 210.5, 205.0], "category_id": 1}, {"id": 5, "bbox": [649.0, 871.0, 344.3, 225.5], "category_id": 1}, {"id": 6, "bbox": [978.0, 863.1, 334.6, 211.5], "category_id": 1}, {"id": 7, "bbox": [1022.1, 561.3, 249.1, 203.2], "category_id": 1}, {"id": 8, "bbox": [721.8, 557.8, 212.5, 205.1], "category_id": 1}, {"id": 9, "bbox": [400.0, 563.0, 206.9, 201.7], "category_id": 1}, {"id": 10, "bbox": [0.0, 539.0, 339.0, 225.6], "category_id": 1}, {"id": 11, "bbox": [686.55, 262.8, 277.85, 203.4], "category_id": 1}, {"id": 12, "bbox": [863.0, 0.0, 228.3, 219.2], "category_id": 1}, {"id": 16, "bbox": [0.0, 261.0, 339.0, 205.0], "category_id": 1}, {"id": 17, "bbox": [319.0, 263.0, 386.0, 207.0], "category_id": 1}, {"id": 18, "bbox": [1010.0, 258.0, 273.0, 205.0], "category_id": 1}, {"id": 19, "bbox": [339.0, 854.0, 334.0, 222.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [29, 15], "products": [12]}], "caption": "Table 2. Cascade Synthesis of Triazinonesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 138, 689, 159], "ImageBB": [453, 165, 782, 456]}, "diagram_type": "single"}, {"id": 1222, "width": 1348, "height": 388, "file_name": "acs.orglett.5b02003-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [385.0, 49.1, 278.1, 165.9], "category_id": 1}, {"id": 4, "bbox": [981.2, 1.0, 347.6, 253.0], "category_id": 1}, {"id": 5, "bbox": [25.3, 29.0, 341.7, 199.0], "category_id": 1}], "reactions": [{"reactants": [8, 5], "conditions": [2, 6], "products": [7]}], "caption": "Table 1. Screening of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 288, 352, 309], "ImageBB": [82, 315, 419, 412]}, "diagram_type": "single"}, {"id": 1223, "width": 1348, "height": 1216, "file_name": "jo9602433-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [804.6, 294.6, 483.1, 516.4], "category_id": 1}, {"id": 1, "bbox": [118.1, 279.0, 480.2, 519.0], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [13, 14, 11], "products": [6, 1, 0]}], "caption": "Table 4. Treatment of (Z)-4 with BTMBr3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [474, 55, 718, 68], "ImageBB": [429, 75, 766, 379]}, "diagram_type": "multiple"}, {"id": 1224, "width": 1356, "height": 956, "file_name": "jo4027148-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [789.0, 0.0, 481.1, 483.2], "category_id": 1}, {"id": 4, "bbox": [81.0, 70.3, 270.7, 329.7], "category_id": 1}, {"id": 5, "bbox": [462.0, 1.0, 199.7, 214.5], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [2, 8, 3], "products": [6]}], "caption": "Table 1. Surprising E\ufb00ects of \u03b1 Substituents on C\u2212H Arylation Chemistry ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 752, 125], "ImageBB": [448, 131, 787, 370]}, "diagram_type": "single"}, {"id": 1225, "width": 1352, "height": 676, "file_name": "ol701624y-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [879.0, 4.0, 368.0, 277.0], "category_id": 1}, {"id": 1, "bbox": [108.0, 47.0, 365.0, 203.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [8, 2, 3, 4], "products": [0]}], "caption": "Table 5.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 740, 120, 753], "ImageBB": [73, 756, 411, 925]}, "diagram_type": "single"}, {"id": 1226, "width": 1344, "height": 608, "file_name": "ol701624y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [845.0, 46.0, 400.0, 201.9], "category_id": 1}, {"id": 3, "bbox": [102.3, 37.6, 363.2, 124.3], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "caption": "Table 4.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 362, 120, 375], "ImageBB": [74, 378, 410, 530]}, "diagram_type": "single"}, {"id": 1227, "width": 1348, "height": 328, "file_name": "acs.joc.6b01262-Table-c2.png", "license": 0, "bboxes": [{"id": 2, "bbox": [118.1, 41.4, 317.8, 158.2], "category_id": 1}, {"id": 3, "bbox": [905.0, 6.0, 327.0, 185.7], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 2], "products": [6]}], "caption": "Table 2. E\ufb00ect of Alkyl in the Alkoxy Group in the Benzylimidatesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 372, 125], "ImageBB": [82, 131, 419, 213]}, "diagram_type": "single"}, {"id": 1228, "width": 1348, "height": 380, "file_name": "acs.joc.6b01262-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1025.0, 5.0, 301.0, 189.0], "category_id": 1}, {"id": 1, "bbox": [677.0, 11.0, 323.0, 186.0], "category_id": 1}, {"id": 2, "bbox": [22.0, 30.0, 307.0, 153.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [6, 3], "products": [1, 0]}], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 365, 738, 386], "ImageBB": [449, 392, 786, 487]}, "diagram_type": "single"}, {"id": 1229, "width": 1356, "height": 464, "file_name": "jacs.5b11315-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [79.38, 47.68, 156.99, 143.22], "category_id": 1}, {"id": 1, "bbox": [476.82, 43.44, 292.08, 289.39], "category_id": 1}, {"id": 2, "bbox": [966.06, 55.56, 351.82, 262.64], "category_id": 1}], "reactions": [{"reactants": [1, 9], "conditions": [0, 4], "products": [2]}, {"reactants": [2], "conditions": [5, 6], "products": [3]}, {"reactants": [1, 9], "conditions": [7], "products": [3]}], "caption": "Figure 4. Syntheses of 5 and 6.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 714, 600, 728], "ImageBB": [448, 589, 787, 705]}, "diagram_type": "graph"}, {"id": 1230, "width": 1352, "height": 1008, "file_name": "op800270e-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [0.0, 4.0, 356.0, 317.9], "category_id": 1}, {"id": 4, "bbox": [598.8, 6.0, 355.2, 314.7], "category_id": 1}, {"id": 5, "bbox": [928.0, 3.0, 399.3, 311.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 8], "products": [5, 6]}], "caption": "Table 1. Effect of base and solvent on enolization selectivity of 9 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 388, 73], "ImageBB": [58, 88, 396, 340]}, "diagram_type": "single"}, {"id": 1231, "width": 2808, "height": 1056, "file_name": "ol301556a-Figure-c2.png", "license": 0, "bboxes": [{"id": 2, "bbox": [1035.41, 715.17, 266.39, 214.23], "category_id": 1}, {"id": 3, "bbox": [753.9, 720.1, 258.5, 207.2], "category_id": 1}, {"id": 4, "bbox": [696.6, 319.8, 253.3, 162.1], "category_id": 1}, {"id": 5, "bbox": [423.6, 210.9, 240.9, 189.5], "category_id": 1}, {"id": 6, "bbox": [36.0, 215.1, 214.3, 188.6], "category_id": 1}, {"id": 7, "bbox": [48.7, 718.4, 260.1, 192.9], "category_id": 1}, {"id": 8, "bbox": [447.1, 718.4, 255.1, 209.3], "category_id": 1}, {"id": 9, "bbox": [891.6, 184.8, 420.5, 297.5], "category_id": 1}, {"id": 10, "bbox": [462.9, 493.4, 288.6, 160.7], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [17], "products": [6]}, {"reactants": [6], "conditions": [24, 5], "products": [10]}, {"reactants": [11], "conditions": [12], "products": [5]}, {"reactants": [10], "conditions": [25, 26], "products": [3, 4, 9]}, {"reactants": [9], "conditions": [15], "products": [8]}, {"reactants": [8], "conditions": [14], "products": [2]}], "caption": "Figure 2. Huang\u2019s prior synthesis of palau\u2019imide (10).11", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 970, 364, 986], "ImageBB": [71, 707, 773, 971]}, "diagram_type": "graph"}, {"id": 1232, "width": 1344, "height": 1280, "file_name": "ol1030487-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [361.6, 50.0, 189.5, 54.6], "category_id": 1}, {"id": 4, "bbox": [6.0, 28.43, 271.7, 141.0], "category_id": 1}, {"id": 5, "bbox": [655.0, 2.0, 299.0, 209.0], "category_id": 1}, {"id": 7, "bbox": [1043.0, 2.0, 297.0, 209.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 0, 5, 10], "products": [7, 11]}], "caption": "Table 2. Screening of Catalyst, Solvent, and Reaction Condi- tions for the Synthesis of Pentasubstituted Cyclohexanecar- boxylatesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 396, 128], "ImageBB": [71, 129, 407, 449]}, "diagram_type": "single"}, {"id": 1233, "width": 1352, "height": 480, "file_name": "ol1022036-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [202.9, 167.62, 201.88, 50.98], "category_id": 1}, {"id": 1, "bbox": [27.0, 168.0, 118.1, 49.0], "category_id": 1}, {"id": 3, "bbox": [1070.0, 107.0, 252.0, 115.0], "category_id": 1}], "reactions": [{"reactants": [2, 0, 9, 1, 4], "conditions": [7, 8], "products": [5]}], "caption": "Table 2. One-Pot, Three-Step Synthesis of 1,4-Disubstituted Triazoles 3 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 243, 370, 270], "ImageBB": [58, 279, 396, 399]}, "diagram_type": "tree"}, {"id": 1234, "width": 1344, "height": 416, "file_name": "op100335q-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [52.2, 61.2, 352.8, 291.8], "category_id": 1}, {"id": 1, "bbox": [863.0, 102.2, 176.0, 270.8], "category_id": 1}, {"id": 2, "bbox": [517.0, 103.3, 336.0, 261.7], "category_id": 1}, {"id": 4, "bbox": [1055.0, 81.0, 215.0, 279.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [], "products": [2, 1, 4]}], "caption": "Figure 3. 1H NMR spectra acquired with a \ufb02ow probe for the reaction of 18 with compound 12 to give intermediate 13. A reaction mixture consisting of compound 18, propargylamine (12) and acetonitrile is cycled through the probe. The addition of acetic acid leads to the formation of intermediate 13. This is evident by the disappearance of the N,N-dimethyl peak as intermediate 13 is formed. ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 491, 771, 577], "ImageBB": [437, 578, 773, 682]}, "diagram_type": "single"}, {"id": 1235, "width": 1344, "height": 1172, "file_name": "ol051488h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [329.0, 177.0, 211.4, 163.9], "category_id": 1}, {"id": 1, "bbox": [896.6, 175.3, 386.0, 201.1], "category_id": 1}, {"id": 2, "bbox": [547.0, 0.0, 261.6, 215.1], "category_id": 1}, {"id": 6, "bbox": [60.9, 170.4, 206.1, 193.5], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [2, 10, 4], "products": [1]}], "caption": "Table 2. Asymmetric Conjugate Addition of Aldehydes 3a-g to Vinyl Sulfone 2 Catalyzed by Diamine 4c ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 211, 402, 239], "ImageBB": [74, 244, 410, 537]}, "diagram_type": "single"}, {"id": 1236, "width": 2808, "height": 1412, "file_name": "jo0108865-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2221.9, 433.6, 264.0, 276.4], "category_id": 1}, {"id": 1, "bbox": [926.29, 483.24, 249.81, 231.76], "category_id": 1}, {"id": 2, "bbox": [1538.5, 457.1, 213.8, 228.2], "category_id": 1}, {"id": 3, "bbox": [328.2, 495.7, 274.4, 233.3], "category_id": 1}, {"id": 4, "bbox": [653.2, 1030.0, 208.9, 271.0], "category_id": 1}, {"id": 5, "bbox": [1857.0, 561.0, 248.0, 156.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2], "products": [3]}, {"reactants": [3], "conditions": [10], "products": [4, 6]}, {"reactants": [4], "conditions": [11, 8], "products": [0]}, {"reactants": [0], "conditions": [6], "products": [7]}], "caption": "Table 1. Reduction of 39 and Derivatives with the Catalyst", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [250, 64, 598, 76], "ImageBB": [74, 78, 776, 431]}, "diagram_type": "multiple"}, {"id": 1237, "width": 2820, "height": 2492, "file_name": "acs.oprd.6b00117-Figure-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1816.0, 11.0, 578.0, 242.0], "category_id": 1}, {"id": 1, "bbox": [504.0, 407.0, 297.0, 161.2], "category_id": 1}, {"id": 2, "bbox": [1787.0, 365.0, 525.0, 234.4], "category_id": 1}, {"id": 3, "bbox": [836.0, 31.0, 328.0, 218.6], "category_id": 1}, {"id": 6, "bbox": [895.0, 398.0, 302.0, 189.0], "category_id": 1}, {"id": 8, "bbox": [406.0, 44.0, 334.0, 172.0], "category_id": 1}], "reactions": [{"reactants": [13, 7], "conditions": [5, 0], "products": [1]}, {"reactants": [4, 11], "conditions": [3, 2], "products": [6]}], "caption": "Figure 8. Wavenumbers monitoring and potential intermediate identi\ufb01cation.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 988, 451, 1002], "ImageBB": [82, 355, 787, 978]}, "diagram_type": "multiple"}, {"id": 1238, "width": 1352, "height": 608, "file_name": "acs.oprd.5b00379-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1.0, 461.0, 450.2], "category_id": 1}, {"id": 3, "bbox": [505.1, 142.1, 187.8, 94.8], "category_id": 1}, {"id": 4, "bbox": [722.4, 0.0, 629.6, 484.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 5], "products": [6]}], "caption": "Table 1. Solvent Evaluation for Succinate Amidationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 385, 110], "ImageBB": [82, 116, 420, 268]}, "diagram_type": "single"}, {"id": 1239, "width": 1224, "height": 1332, "file_name": "jo9602433-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [566.0, 203.1, 432.2, 319.9], "category_id": 1}, {"id": 1, "bbox": [646.0, 1000.0, 467.0, 275.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [13], "products": [1]}, {"reactants": [1], "conditions": [], "products": [10]}, {"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [0], "conditions": [3, 4, 11, 12], "products": [2]}], "caption": "Table 1. Treatment of (E)-3 with BTMABr3 or Br2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [451, 372, 743, 385], "ImageBB": [459, 26, 765, 359]}, "diagram_type": "tree"}, {"id": 1240, "width": 1348, "height": 2672, "file_name": "jo302142v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [17.0, 201.0, 359.0, 258.0], "category_id": 1}, {"id": 1, "bbox": [394.0, 183.0, 227.0, 258.0], "category_id": 1}, {"id": 6, "bbox": [735.0, 0.0, 590.0, 283.0], "category_id": 1}, {"id": 7, "bbox": [717.0, 272.0, 626.0, 286.0], "category_id": 1}], "reactions": [{"reactants": [0, 1], "conditions": [], "products": [8, 10]}], "caption": "Table 2. Aldol Reactions of the Ti(IV) \u201cate\u201d Enolate of 1a (R = MOM, Et3Si) with (\u00b1)-5a ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 184, 417, 220], "ImageBB": [82, 224, 419, 892]}, "diagram_type": "tree"}, {"id": 1241, "width": 2820, "height": 3452, "file_name": "acs.joc.5b00301-Figure-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [345.6, 1049.1, 177.4, 133.6], "category_id": 1}, {"id": 1, "bbox": [1811.7, 110.4, 163.5, 127.7], "category_id": 1}, {"id": 2, "bbox": [1966.4, 343.1, 273.3, 272.7], "category_id": 1}, {"id": 3, "bbox": [1240.4, 0.0, 319.8, 183.1], "category_id": 1}, {"id": 4, "bbox": [583.4, 347.0, 268.8, 263.1], "category_id": 1}, {"id": 5, "bbox": [254.42, 1769.15, 247.65, 181.21], "category_id": 1}, {"id": 6, "bbox": [932.96, 1769.15, 235.57, 183.23], "category_id": 1}, {"id": 7, "bbox": [1647.74, 1767.14, 237.59, 185.24], "category_id": 1}, {"id": 8, "bbox": [2328.29, 1767.14, 221.48, 183.22], "category_id": 1}, {"id": 9, "bbox": [579.4, 783.0, 278.5, 272.3], "category_id": 1}, {"id": 10, "bbox": [932.0, 1048.0, 161.9, 133.2], "category_id": 1}, {"id": 11, "bbox": [1969.2, 785.0, 266.5, 269.5], "category_id": 1}, {"id": 12, "bbox": [2320.8, 1054.2, 153.8, 129.8], "category_id": 1}, {"id": 13, "bbox": [1726.4, 1056.0, 174.8, 123.5], "category_id": 1}, {"id": 14, "bbox": [893.22, 1308.92, 331.28, 266.3], "category_id": 1}, {"id": 15, "bbox": [215.0, 1305.5, 335.9, 271.2], "category_id": 1}, {"id": 16, "bbox": [1597.8, 1308.1, 328.0, 267.8], "category_id": 1}, {"id": 17, "bbox": [2274.7, 1310.7, 323.9, 267.5], "category_id": 1}, {"id": 18, "bbox": [847.2, 111.0, 178.5, 129.5], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [], "products": [24]}, {"reactants": [24], "conditions": [], "products": [14]}, {"reactants": [15], "conditions": [], "products": [23]}, {"reactants": [23], "conditions": [], "products": [15]}, {"reactants": [24], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [1], "products": [24]}, {"reactants": [23], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [19], "products": [23]}, {"reactants": [18], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [18]}, {"reactants": [13], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [27], "products": [13]}, {"reactants": [9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [7], "products": [9]}, {"reactants": [8], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [], "products": [8]}, {"reactants": [20], "conditions": [22], "products": [25]}, {"reactants": [25], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [21], "products": [26]}, {"reactants": [26], "conditions": [], "products": [20]}, {"reactants": [25], "conditions": [], "products": [16]}, {"reactants": [16], "conditions": [], "products": [25]}, {"reactants": [26], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [26]}], "caption": "Figure 8. Overlaid benzoin reaction coordinates: pyrrolidinone-based triazolium (I\u2032).", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 988, 487, 1002], "ImageBB": [82, 116, 787, 979]}, "diagram_type": "tree"}, {"id": 1242, "width": 1348, "height": 796, "file_name": "ja511913h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [929.82, 506.46, 314.24, 98.54], "category_id": 1}, {"id": 1, "bbox": [318.7, 534.19, 232.07, 60.54], "category_id": 1}, {"id": 2, "bbox": [95.82, 513.64, 197.15, 97.52], "category_id": 1}, {"id": 3, "bbox": [725.86, 49.82, 370.03, 382.24], "category_id": 1}], "reactions": [{"reactants": [4, 3], "conditions": [6, 5], "products": [2]}], "caption": "Table 1. Optimization of the Decarboxylative Ole\ufb01nationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 773, 111], "ImageBB": [449, 116, 786, 315]}, "diagram_type": "single"}, {"id": 1243, "width": 1348, "height": 396, "file_name": "ja410533y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [411.22, 6.65, 145.75, 135.42], "category_id": 1}, {"id": 3, "bbox": [1001.72, 25.59, 214.62, 136.28], "category_id": 1}, {"id": 5, "bbox": [128.88, 27.31, 162.97, 125.09], "category_id": 1}], "reactions": [{"reactants": [10, 0], "conditions": [8, 9], "products": [5]}], "caption": "Table 1. Selected Optimization Experiments in the Ruthenium-Catalyzed C\u2212C Coupling of Diol 1b and Methyl Acrylate 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 140], "ImageBB": [449, 146, 786, 245]}, "diagram_type": "single"}, {"id": 1244, "width": 1316, "height": 852, "file_name": "ja3058138-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [885.59, 33.27, 423.73, 220.87], "category_id": 1}, {"id": 1, "bbox": [232.18, 99.47, 268.92, 104.49], "category_id": 1}, {"id": 2, "bbox": [6.9, 5.51, 259.31, 252.9], "category_id": 1}], "reactions": [{"reactants": [3, 2], "conditions": [4, 0], "products": [1]}], "caption": "Table 1. Optimization Study for the 2-Alkylation of O-TBS- Tryptophola ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 186, 417, 220], "ImageBB": [86, 226, 415, 439]}, "diagram_type": "single"}, {"id": 1245, "width": 1348, "height": 620, "file_name": "ja053368a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1105.08, 5.53, 228.7, 168.72], "category_id": 1}, {"id": 1, "bbox": [15.29, 47.21, 93.5, 93.5], "category_id": 1}, {"id": 2, "bbox": [148.46, 42.13, 163.64, 97.56], "category_id": 1}], "reactions": [{"reactants": [3, 4], "conditions": [5, 2], "products": [0]}], "caption": "Table 1. DA Reaction of Cyclopentadiene with Methacroleina", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 470, 747, 483], "ImageBB": [439, 488, 776, 643]}, "diagram_type": "single"}, {"id": 1246, "width": 2820, "height": 844, "file_name": "op700060e-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1758.0, 7.0, 341.0, 199.0], "category_id": 1}, {"id": 1, "bbox": [725.0, 24.0, 194.0, 159.0], "category_id": 1}, {"id": 4, "bbox": [1194.6, 9.5, 329.5, 156.3], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 4], "products": [9]}, {"reactants": [9], "conditions": [5, 6], "products": [2]}], "caption": "Table 2. Optimized oxidation/SNAr synthesis of 2-phenylsulfonyl pyridine, 1", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 276, 475, 290], "ImageBB": [58, 304, 763, 515]}, "diagram_type": "single"}, {"id": 1247, "width": 1352, "height": 560, "file_name": "op0340964-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1021.0, 302.0, 325.0, 224.0], "category_id": 1}, {"id": 1, "bbox": [355.0, 302.0, 340.0, 226.0], "category_id": 1}, {"id": 2, "bbox": [6.0, 4.0, 270.0, 224.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 2], "products": [5]}, {"reactants": [5], "conditions": [0, 1], "products": [4]}], "caption": "Figure 3. Acid-catalyzed stereoretentive hydrolysis of (R)-2- chloromandelonitrile into (R)-2-chloromandelic acid. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 751, 409, 779], "ImageBB": [73, 607, 411, 747]}, "diagram_type": "multiple"}, {"id": 1248, "width": 1348, "height": 1760, "file_name": "ol071385u-Table-c2.png", "license": 0, "bboxes": [{"id": 1, "bbox": [925.5, 0.0, 348.0, 283.6], "category_id": 1}, {"id": 3, "bbox": [85.6, 13.0, 368.7, 254.7], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0], "products": [2]}], "caption": "Table 2. Pd-Catalyzed Cyclization of Propargylic Compounds 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 356, 774, 369], "ImageBB": [439, 371, 776, 811]}, "diagram_type": "single"}, {"id": 1249, "width": 2816, "height": 1756, "file_name": "op500224x-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [825.0, 1380.0, 401.0, 260.0], "category_id": 1}, {"id": 2, "bbox": [1504.2, 504.0, 483.3, 304.0], "category_id": 1}, {"id": 3, "bbox": [1001.0, 446.0, 488.5, 340.0], "category_id": 1}, {"id": 7, "bbox": [71.0, 19.0, 275.0, 154.0], "category_id": 1}, {"id": 8, "bbox": [0.0, 118.0, 311.0, 229.0], "category_id": 1}, {"id": 9, "bbox": [696.0, 41.0, 315.0, 331.0], "category_id": 1}, {"id": 10, "bbox": [1406.0, 48.0, 308.0, 314.0], "category_id": 1}, {"id": 11, "bbox": [1970.0, 102.0, 318.0, 263.0], "category_id": 1}, {"id": 12, "bbox": [2497.0, 109.0, 311.0, 253.0], "category_id": 1}, {"id": 13, "bbox": [2397.0, 529.0, 389.0, 244.0], "category_id": 1}, {"id": 14, "bbox": [1990.0, 536.0, 305.0, 237.0], "category_id": 1}, {"id": 15, "bbox": [481.0, 459.0, 514.0, 321.0], "category_id": 1}, {"id": 16, "bbox": [6.0, 462.0, 459.0, 321.0], "category_id": 1}, {"id": 17, "bbox": [3.0, 972.0, 427.0, 228.0], "category_id": 1}, {"id": 18, "bbox": [459.0, 969.0, 449.0, 231.0], "category_id": 1}, {"id": 19, "bbox": [979.0, 972.0, 539.0, 238.0], "category_id": 1}, {"id": 20, "bbox": [1585.0, 969.0, 337.0, 238.0], "category_id": 1}, {"id": 21, "bbox": [1987.0, 959.0, 327.0, 241.0], "category_id": 1}, {"id": 22, "bbox": [2388.0, 969.0, 388.0, 244.0], "category_id": 1}, {"id": 23, "bbox": [13.0, 1383.0, 317.0, 251.0], "category_id": 1}, {"id": 24, "bbox": [436.0, 1367.0, 296.0, 263.0], "category_id": 1}, {"id": 25, "bbox": [1348.0, 1402.0, 452.0, 254.0], "category_id": 1}, {"id": 26, "bbox": [1903.0, 1393.0, 366.0, 231.0], "category_id": 1}, {"id": 27, "bbox": [2378.0, 1380.0, 382.0, 254.0], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [28, 29], "products": [9]}, {"reactants": [9], "conditions": [30, 31], "products": [10]}, {"reactants": [10], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [12]}], "caption": "Table 2. Rh-catalyzed cyclization using silyl alkynes with kinetic protonation and reduction", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 596, 110], "ImageBB": [82, 116, 786, 555]}, "diagram_type": "single"}, {"id": 1250, "width": 1356, "height": 1016, "file_name": "op5001385-Figure-c2.png", "license": 0, "bboxes": [{"id": 3, "bbox": [0.0, 27.0, 218.0, 151.8], "category_id": 1}, {"id": 4, "bbox": [78.1, 325.1, 430.4, 502.8], "category_id": 1}, {"id": 6, "bbox": [878.8, 4.55, 267.9, 210.15], "category_id": 1}, {"id": 7, "bbox": [304.5, 8.0, 241.6, 177.0], "category_id": 1}, {"id": 8, "bbox": [795.6, 325.9, 482.4, 430.1], "category_id": 1}], "reactions": [{"reactants": [6, 12], "conditions": [5, 10], "products": [11, 9]}], "caption": "Figure 2. Through-space NOE interactions in 11a\u2212b.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 564, 712, 578], "ImageBB": [448, 301, 787, 555]}, "diagram_type": "single"}, {"id": 1251, "width": 1352, "height": 1136, "file_name": "op500102h-Table-c2.png", "license": 0, "bboxes": [{"id": 2, "bbox": [873.0, 2.0, 330.0, 211.0], "category_id": 1}, {"id": 3, "bbox": [163.0, 0.0, 319.5, 210.4], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [0, 2], "products": [5]}], "caption": "Table 2. Saponi\ufb01cation of 3,5-bis(\ufb02uoroalkyl)pyrazoles 4", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 403, 110], "ImageBB": [82, 116, 420, 400]}, "diagram_type": "single"}, {"id": 1252, "width": 1356, "height": 668, "file_name": "op200052z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 2.0, 408.0, 219.0], "category_id": 1}, {"id": 1, "bbox": [736.5, 3.1, 485.2, 219.8], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1, 3], "products": [4, 0]}], "caption": "Table 3. Thermal stability study of 6a", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 438, 647, 459], "ImageBB": [436, 469, 775, 636]}, "diagram_type": "single"}, {"id": 1253, "width": 1352, "height": 1272, "file_name": "ol053021c-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [922.6, 167.2, 346.8, 233.0], "category_id": 1}, {"id": 1, "bbox": [81.7, 141.5, 313.6, 237.6], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [2]}], "caption": "Figure 3. Direct comparison of catalysts 1a-d, conversion established by HPLC or GC analysis with benzoic acid and dodecane, respectively, as internal standards (average of 2-3 runs). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 692, 775, 733], "ImageBB": [439, 362, 777, 680]}, "diagram_type": "single"}, {"id": 1254, "width": 1356, "height": 840, "file_name": "ol051920v-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 11.0, 206.0, 157.0], "category_id": 1}, {"id": 1, "bbox": [231.0, 43.0, 215.0, 146.0], "category_id": 1}, {"id": 2, "bbox": [736.0, 1.0, 316.0, 179.0], "category_id": 1}, {"id": 3, "bbox": [1044.0, 3.0, 310.0, 227.0], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [1, 0], "products": [4, 5]}], "caption": "Table 4. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with Ethyl 2-Methylbuta-2,3-dienoate 2c (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at 80 \u00b0C ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 712, 400, 757], "ImageBB": [73, 760, 412, 970]}, "diagram_type": "single"}, {"id": 1255, "width": 1356, "height": 1192, "file_name": "acs.orglett.5b00081-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [989.0, 419.0, 285.0, 267.4], "category_id": 1}, {"id": 1, "bbox": [87.0, 358.0, 212.4, 175.8], "category_id": 1}, {"id": 2, "bbox": [603.0, 39.0, 325.0, 266.9], "category_id": 1}, {"id": 3, "bbox": [985.08, 39.73, 286.12, 263.07], "category_id": 1}, {"id": 4, "bbox": [83.0, 62.0, 124.1, 117.8], "category_id": 1}, {"id": 5, "bbox": [87.98, 181.57, 115.91, 107.27], "category_id": 1}, {"id": 6, "bbox": [299.04, 416.86, 254.32, 257.78], "category_id": 1}, {"id": 7, "bbox": [266.0, 62.0, 290.0, 257.0], "category_id": 1}, {"id": 8, "bbox": [910.0, 129.0, 55.0, 55.0], "category_id": 1}, {"id": 9, "bbox": [632.0, 424.0, 286.0, 258.0], "category_id": 1}, {"id": 10, "bbox": [504.0, 734.0, 280.0, 389.0], "category_id": 1}, {"id": 11, "bbox": [965.0, 742.0, 287.0, 382.0], "category_id": 1}, {"id": 12, "bbox": [113.0, 735.0, 327.0, 383.0], "category_id": 1}], "reactions": [{"reactants": [4, 8], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [9]}, {"reactants": [9, 1], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}], "caption": "Figure 4. Plausible biosynthetic route for duclauxins.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 882, 706, 896], "ImageBB": [448, 575, 787, 873]}, "diagram_type": "tree"}, {"id": 1256, "width": 1348, "height": 324, "file_name": "ol5000692-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [283.4, 5.3, 221.6, 190.7], "category_id": 1}, {"id": 2, "bbox": [794.8, 5.6, 272.2, 173.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 5], "products": [3]}], "caption": "Table 1. Optimization Study for 1-Catalyzed Cyclization of 2a to 3aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 415, 125], "ImageBB": [82, 131, 419, 212]}, "diagram_type": "single"}, {"id": 1257, "width": 1348, "height": 600, "file_name": "ol401042b-Table-c4.png", "license": 0, "bboxes": [{"id": 1, "bbox": [26.3, 56.7, 323.2, 181.3], "category_id": 1}, {"id": 2, "bbox": [472.7, 105.1, 201.8, 114.8], "category_id": 1}, {"id": 3, "bbox": [1000.91, 6.03, 324.09, 240.67], "category_id": 1}], "reactions": [{"reactants": [3, 5], "conditions": [8, 1], "products": [6]}], "caption": "Table 4. Scope of Substrate for Organocatalytic Annulationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 533, 760, 549], "ImageBB": [436, 559, 773, 709]}, "diagram_type": "single"}, {"id": 1258, "width": 1352, "height": 860, "file_name": "ol047761h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.9, 598.2, 220.4, 129.4], "category_id": 1}, {"id": 1, "bbox": [565.0, 241.5, 263.3, 207.5], "category_id": 1}, {"id": 2, "bbox": [41.2, 295.2, 222.5, 126.9], "category_id": 1}, {"id": 3, "bbox": [1048.8, 250.4, 262.0, 203.7], "category_id": 1}, {"id": 4, "bbox": [625.0, 576.0, 253.0, 209.0], "category_id": 1}], "reactions": [{"reactants": [3, 2], "conditions": [], "products": [1]}, {"reactants": [1, 4], "conditions": [], "products": [6]}, {"reactants": [0, 5], "conditions": [], "products": [8]}], "caption": "Figure 1. Two mechanistic pathways for \u03b2-lactone ring opening with nucleophiles. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 278, 409, 305], "ImageBB": [73, 51, 411, 266]}, "diagram_type": "multiple"}, {"id": 1259, "width": 1348, "height": 376, "file_name": "jo501216h-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [805.0, 38.0, 257.0, 132.0], "category_id": 1}, {"id": 3, "bbox": [20.0, 4.0, 262.0, 174.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [2, 1], "products": [5]}], "caption": "Table 3. 1-Iodo-4-nitrobenzene-Catalyzed Synthesis of Benzothiazoles with Oxonea ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 388, 125], "ImageBB": [82, 131, 419, 225]}, "diagram_type": "single"}, {"id": 1260, "width": 1348, "height": 296, "file_name": "jo400501k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [781.0, 5.0, 244.0, 186.8], "category_id": 1}, {"id": 2, "bbox": [334.3, 26.2, 245.7, 166.7], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 5], "products": [0]}], "caption": "Table 1. Optimization of Conditions for the Synthesis of Diaminesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 404, 125], "ImageBB": [82, 131, 419, 205]}, "diagram_type": "single"}, {"id": 1261, "width": 1356, "height": 1320, "file_name": "ol503587n-Figure-c3.png", "license": 0, "bboxes": [{"id": 1, "bbox": [983.3, 1048.3, 265.5, 153.7], "category_id": 1}, {"id": 2, "bbox": [491.1, 1018.8, 391.0, 190.5], "category_id": 1}, {"id": 3, "bbox": [63.8, 1047.2, 391.7, 154.4], "category_id": 1}, {"id": 4, "bbox": [68.8, 744.0, 371.8, 202.9], "category_id": 1}, {"id": 5, "bbox": [493.9, 755.5, 302.6, 182.0], "category_id": 1}, {"id": 6, "bbox": [887.6, 739.5, 405.4, 199.5], "category_id": 1}, {"id": 7, "bbox": [836.8, 474.4, 407.7, 201.6], "category_id": 1}, {"id": 8, "bbox": [517.0, 479.2, 301.7, 181.8], "category_id": 1}, {"id": 9, "bbox": [77.72, 481.2, 303.98, 182.8], "category_id": 1}, {"id": 10, "bbox": [841.4, 130.42, 421.9, 186.98], "category_id": 1}, {"id": 11, "bbox": [490.7, 1.7, 234.7, 210.8], "category_id": 1}, {"id": 12, "bbox": [119.6, 253.7, 249.7, 131.4], "category_id": 1}, {"id": 13, "bbox": [93.8, 33.8, 264.1, 181.3], "category_id": 1}, {"id": 22, "bbox": [879.0, 494.0, 8.0, 3.0], "category_id": 1}], "reactions": [{"reactants": [14, 13], "conditions": [12, 24, 10], "products": [11]}], "caption": "Figure 3. Products formed by coupling of aromatic amines with benzyl alcohols; 7 in toluene, 110 \u00b0C, 48 h, 9\u221216 in xylene, 140 \u00b0C, 24 h. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 470, 784, 499], "ImageBB": [448, 131, 787, 461]}, "diagram_type": "single"}, {"id": 1262, "width": 1928, "height": 1092, "file_name": "op050040t-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1384.6, 793.9, 543.1, 97.2], "category_id": 1, "id": 1}, {"bbox": [1386.5, 40.9, 501.5, 92.1], "category_id": 1, "id": 2}], "caption": "Figure 2. Oxidation of 2-butoxyethanol (2b) to 2-butoxyacetaldehyde (3b) in dichloromethane with 1 M NaOCl (pH 9.5), 5 mol % HOT (1b), and 5.5 mol % NaBr. ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 557, 775, 585], "ImageBB": [184, 280, 666, 553]}}, {"id": 1263, "width": 2820, "height": 1640, "file_name": "acs.oprd.6b00095-Figure-c9.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1455.0, 0.0, 803.0, 504.5], "category_id": 1, "id": 0}, {"bbox": [562.0, 59.0, 836.0, 324.0], "category_id": 1, "id": 1}], "caption": "Figure 9. Oxidation of glucose in the absence (dotted lines with open symbols) and in the presence of 3.33 g L\u22121 of (a) maltose and (b) cellobiose. Reaction conditions: 4.7 wt % Pt/C, [glucose]0 = 0.25 M, glucose/Pt molar ratio 157, T = 60 \u00b0C, 0.5 L min\u22121 air, pH 9. (\u25a1, \u25a0) gluconate, (\u25cb, red \u25cf) glucarate, (gray \u00d7, green +) NaOH consumption. ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 531, 784, 578], "ImageBB": [82, 116, 787, 526]}}, {"id": 1264, "width": 3396, "height": 1232, "file_name": "acs.oprd.5b00283-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1509.0, 281.0, 309.0, 217.7], "category_id": 1, "id": 4}, {"bbox": [2252.7, 281.0, 290.4, 218.2], "category_id": 1, "id": 5}, {"bbox": [745.0, 725.5, 468.6, 364.8], "category_id": 1, "id": 6}, {"bbox": [792.1, 278.19, 307.58, 221.0], "category_id": 1, "id": 7}, {"bbox": [1319.0, 691.0, 606.3, 434.8], "category_id": 1, "id": 8}, {"bbox": [2016.1, 680.0, 625.0, 451.8], "category_id": 1, "id": 9}, {"bbox": [1119.5, 305.9, 267.5, 161.1], "category_id": 1, "id": 10}, {"bbox": [1838.5, 308.2, 258.7, 158.6], "category_id": 1, "id": 11}], "caption": "Figure 1. (R)-3,5-Bis(tri\ufb02uoromethyl)-\u03b1-methyl-N-methylbenzylamine versions and APIs containing this structural element.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 340, 679, 354], "ImageBB": [10, 22, 859, 330]}}, {"id": 1265, "width": 1344, "height": 496, "file_name": "ol402074u-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1084.2, 175.7, 203.6, 253.7], "category_id": 1, "id": 3}, {"bbox": [56.9, 224.4, 286.4, 155.3], "category_id": 1, "id": 4}, {"bbox": [415.6, 219.9, 176.7, 167.1], "category_id": 1, "id": 5}, {"bbox": [603.0, 164.0, 415.8, 275.9], "category_id": 1, "id": 6}], "caption": "Figure 1. Structures of 7,70 -diamino-2,20 -dindolylmethane (1), peracetylated D-glucuronic acid 2, and chiral anion receptors 3 and 4 investigated in this study. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 666, 405, 711], "ImageBB": [71, 533, 407, 657]}}, {"id": 1266, "width": 2808, "height": 1084, "file_name": "jo200877k-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1953.4, 833.6, 357.2, 136.3], "category_id": 1, "id": 0}, {"bbox": [935.4, 799.4, 273.4, 234.1], "category_id": 1, "id": 1}, {"bbox": [514.2, 759.4, 355.1, 182.5], "category_id": 1, "id": 2}, {"bbox": [1496.4, 699.9, 362.4, 182.1], "category_id": 1, "id": 3}], "caption": "Figure 2. Stationary points on the triplet and singlet surfaces of 1. The calculated energies are in kcal/mol. The energies for (a) 1, 2, 7 and TS-3 were obtained from B3LYP/6-31+G(d) calculations, (b) T1K of 1 (67 kcal/mol), T1A of 1, TS-1, 3, TS-2 and TI of 7 were obtained from UB3LYP/6-31+G(d) calculations, (c) S1K and S1A of 1 were obtained from TD-DFT(B3LYP/6-31+G(d)) calculations on the S0 geometry of 1 as obtained from B3LYP/6-31 +G(d) calculation. (d) T1K (73 kcal/mol) and T2K of 1 were obtained from TD-DFT(UB3LYP/6-31+G(d)) calculations on the S0 geometry of 1 as obtained from B3LYP/6-31+G(d) calculation. ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 341, 770, 410], "ImageBB": [70, 56, 772, 327]}}, {"id": 1267, "width": 1256, "height": 484, "file_name": "ja012253d-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [971.37, 5.65, 284.63, 155.1], "category_id": 1, "id": 0}, {"bbox": [5.7, 14.8, 286.6, 151.6], "category_id": 1, "id": 4}, {"bbox": [987.08, 282.56, 265.15, 149.44], "category_id": 1, "id": 5}, {"bbox": [480.66, 5.65, 306.62, 148.19], "category_id": 1, "id": 6}], "caption": "Scheme 9", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 361, 491, 373], "ImageBB": [451, 372, 765, 493]}, "diagram_type": "tree"}, {"id": 1268, "width": 1344, "height": 732, "file_name": "ol301114z-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [20.84, 14.79, 266.25, 233.31], "category_id": 1, "id": 0}, {"bbox": [406.09, 88.75, 155.31, 111.61], "category_id": 1, "id": 1}, {"bbox": [115.64, 455.85, 424.25, 226.58], "category_id": 1, "id": 2}, {"bbox": [984.97, 39.67, 322.72, 223.22], "category_id": 1, "id": 3}, {"bbox": [896.22, 455.18, 423.58, 226.58], "category_id": 1, "id": 4}, {"bbox": [679.73, 0.0, 151.28, 135.81], "category_id": 1, "id": 5}], "caption": "Scheme 1. Proposed Annulation of 2,3-Disubstituted Indole with MVK Catalyzed by Chiral Primary Amine ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 756, 116], "ImageBB": [437, 127, 773, 310]}, "diagram_type": "graph"}, {"id": 1269, "width": 1352, "height": 1200, "file_name": "op020211j-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [488.99, 591.19, 513.34, 608.77], "category_id": 1, "id": 0}, {"bbox": [0.0, 280.04, 409.86, 215.1], "category_id": 1, "id": 1}, {"bbox": [789.96, 12.85, 545.81, 127.17], "category_id": 1, "id": 2}, {"bbox": [942.82, 292.21, 409.18, 340.24], "category_id": 1, "id": 3}, {"bbox": [0.0, 10.15, 336.14, 125.81], "category_id": 1, "id": 7}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [74, 72, 412, 372]}, "diagram_type": "multiple"}, {"id": 1270, "width": 1000, "height": 528, "file_name": "op025501e-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [663.33, 328.08, 277.64, 128.53], "category_id": 1, "id": 1}, {"bbox": [665.33, 45.51, 331.67, 124.53], "category_id": 1, "id": 4}, {"bbox": [174.09, 331.08, 248.12, 126.53], "category_id": 1, "id": 5}, {"bbox": [6.5, 2.0, 337.67, 223.06], "category_id": 1, "id": 6}], "caption": "Scheme 1. Chemical synthesis of 4", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 240, 639, 254], "ImageBB": [483, 259, 733, 391]}, "diagram_type": "multiple"}, {"id": 1271, "width": 1352, "height": 1828, "file_name": "op060114g-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [64.01, 1355.23, 268.82, 411.5], "category_id": 1, "id": 0}, {"bbox": [1081.69, 0.0, 270.31, 411.51], "category_id": 1, "id": 1}, {"bbox": [641.88, 0.0, 272.48, 416.99], "category_id": 1, "id": 2}, {"bbox": [866.81, 713.28, 272.48, 415.16], "category_id": 1, "id": 6}, {"bbox": [64.01, 42.07, 257.84, 224.95], "category_id": 1, "id": 7}, {"bbox": [64.01, 707.79, 268.82, 413.33], "category_id": 1, "id": 9}, {"bbox": [864.07, 1350.65, 273.39, 414.25], "category_id": 1, "id": 10}], "caption": "Scheme 2", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [439, 71, 777, 528]}, "diagram_type": "tree"}, {"id": 1272, "width": 1152, "height": 1208, "file_name": "op980039c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [631.7, 578.0, 518.3, 462.0], "category_id": 1, "id": 3}, {"bbox": [256.5, 2.1, 641.5, 383.4], "category_id": 1, "id": 4}, {"bbox": [1.0, 616.0, 518.0, 426.0], "category_id": 1, "id": 5}], "caption": "Figure 1. Structure of adenosine A1 receptor antagonists", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 538, 757, 553], "ImageBB": [464, 233, 752, 535]}}, {"id": 1273, "width": 880, "height": 364, "file_name": "op900188v-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [643.8, 1.0, 236.2, 353.4], "category_id": 1, "id": 2}, {"bbox": [84.7, 2.0, 304.8, 345.1], "category_id": 1, "id": 3}], "caption": "Figure 3. Impurities from Ag(I) catalysis are also associated with the Claisen route. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 800, 393, 827], "ImageBB": [117, 706, 337, 797]}}, {"id": 1274, "width": 1332, "height": 340, "file_name": "op800104r-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [720.1, 2.0, 611.9, 267.9], "category_id": 1, "id": 0}, {"bbox": [0.0, 0.0, 615.0, 274.9], "category_id": 1, "id": 1}], "caption": "Figure 1. Structures of gemcitabine and undesired isomer. overall yield was at 5% from compound 2 over eight steps, and the purity of the final product (98%) did not comply with the requirement of USP30 (g99.8%). ", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 292, 760, 358], "ImageBB": [427, 203, 760, 288]}}, {"id": 1275, "width": 1084, "height": 704, "file_name": "op7001886-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [564.0, 295.0, 427.0, 339.0], "category_id": 1, "id": 0}, {"bbox": [0.0, 111.0, 561.0, 516.0], "category_id": 1, "id": 2}], "caption": "Figure 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 411, 476, 425], "ImageBB": [458, 232, 729, 408]}}, {"id": 1276, "width": 884, "height": 1416, "file_name": "op060204l-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [207.0, 950.0, 509.0, 266.0], "category_id": 1, "id": 0}, {"bbox": [2.0, 2.0, 882.0, 739.0], "category_id": 1, "id": 1}], "caption": "Figure 4. Single-crystal X-ray image of (+)-6. (Generated from the PDB file using Jmol Viewer, version 10). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 411, 775, 439], "ImageBB": [498, 54, 719, 408]}}, {"id": 1277, "width": 1252, "height": 848, "file_name": "op060204l-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [795.5, 4.5, 454.5, 255.3], "category_id": 1, "id": 2}, {"bbox": [0.0, 435.7, 555.9, 251.2], "category_id": 1, "id": 3}, {"bbox": [676.9, 458.4, 570.6, 305.2], "category_id": 1, "id": 4}, {"bbox": [27.0, 1.0, 342.0, 252.3], "category_id": 1, "id": 5}], "caption": "Figure 2. Side- and byproducts.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 268, 622, 282], "ImageBB": [452, 53, 765, 265]}}, {"id": 1278, "width": 656, "height": 340, "file_name": "op034198u-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 0.0, 655.0, 304.0], "category_id": 1, "id": 1}], "caption": "Figure 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 142, 495, 156], "ImageBB": [526, 54, 690, 139]}}, {"id": 1279, "width": 420, "height": 988, "file_name": "op034033l-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [79.3, 1.3, 338.2, 159.7], "category_id": 1, "id": 1}], "caption": "Table 1. Initial Additive Screen for Step 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 248, 307, 262], "ImageBB": [306, 172, 411, 419]}}, {"id": 1280, "width": 1268, "height": 600, "file_name": "op0101106-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 18.3, 543.0, 166.8], "category_id": 1, "id": 0}, {"bbox": [658.2, 8.0, 606.8, 225.0], "category_id": 1, "id": 1}, {"bbox": [139.9, 312.3, 954.9, 199.5], "category_id": 1, "id": 2}], "caption": "Figure 1. Undesired products by reduction with 5% Rh-C.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 540, 775, 554], "ImageBB": [450, 386, 767, 536]}}, {"id": 1281, "width": 1280, "height": 956, "file_name": "op010097p-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1.0, 563.0, 318.0, 315.0], "category_id": 1, "id": 0}, {"bbox": [853.0, 562.0, 421.0, 208.0], "category_id": 1, "id": 1}, {"bbox": [280.0, 4.0, 564.0, 377.0], "category_id": 1, "id": 5}, {"bbox": [365.0, 599.0, 451.0, 290.0], "category_id": 1, "id": 6}], "caption": "Figure 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 293, 129, 307], "ImageBB": [82, 54, 402, 293]}}, {"id": 1282, "width": 1352, "height": 644, "file_name": "ol990836a-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [41.59, 430.0, 416.0, 125.92], "category_id": 1, "id": 3}, {"bbox": [430.0, 344.0, 309.0, 258.0], "category_id": 1, "id": 4}, {"bbox": [686.0, 132.0, 622.0, 478.0], "category_id": 1, "id": 5}], "caption": "Figure 1. Building blocks for dendritic catalysts.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 561, 331, 574], "ImageBB": [73, 387, 411, 548]}}, {"id": 1283, "width": 1412, "height": 604, "file_name": "op500120z-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [70.0, 366.0, 274.0, 110.0], "category_id": 1, "id": 0}, {"bbox": [1116.4, 363.3, 295.6, 111.7], "category_id": 1, "id": 1}, {"bbox": [615.2, 353.3, 272.8, 136.2], "category_id": 1, "id": 2}], "caption": "Figure 1. Ionic reaction pathway.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 432, 612, 446], "ImageBB": [433, 272, 786, 423]}}, {"id": 1284, "width": 1356, "height": 300, "file_name": "op300181r-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [502.0, 40.1, 353.0, 192.9], "category_id": 1, "id": 0}], "caption": "Figure 2. Impurity 20 from acetic acid conditions.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 932, 695, 946], "ImageBB": [448, 848, 787, 923]}}, {"id": 1285, "width": 1352, "height": 504, "file_name": "op300055g-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [333.4, 35.0, 531.6, 469.0], "category_id": 1, "id": 0}], "caption": "Figure 3. ADD-NEOP absolute stereochemistry35.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 543, 327, 560], "ImageBB": [82, 410, 420, 536]}}, {"id": 1286, "width": 1416, "height": 1564, "file_name": "ol070527h-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [943.0, 3.0, 269.0, 273.8], "category_id": 1, "id": 0}], "caption": "Table 1. ArN3 Prepared from ArNH2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 274, 90], "ImageBB": [73, 98, 427, 489]}}, {"id": 1287, "width": 1352, "height": 956, "file_name": "ol0701619-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [91.0, 132.0, 1171.0, 824.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Calcium-dependent antibiotics (CDAs) produced by the wild-type S. coelicolor:5 CDA1, R9 ) OPO3H2 and R10 ) H; CDA2, R9 ) OPO3H2 and R10 ) CH3; CDA3, R9 ) OH and R10 ) H; CDA4, R9 ) OH and R10 ) CH3. The a-series contains Z-\u2206Trp (R11 ) \u03c0-bond) and the b-series contains L-Trp (R11 ) H,H) at position 11. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 315, 409, 398], "ImageBB": [73, 51, 411, 290]}}, {"id": 1288, "width": 1352, "height": 600, "file_name": "ol060736m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [261.5, 141.0, 831.5, 393.5], "category_id": 1, "id": 0}], "caption": "Figure 1. Tetrasaccharide components found in the cell wall of Streptomyces sp. MB-8.3g ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 513, 409, 540], "ImageBB": [73, 351, 411, 501]}}, {"id": 1289, "width": 836, "height": 736, "file_name": "jo000081h-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [6.0, 0.0, 828.0, 735.0], "category_id": 1, "id": 0}], "caption": "Figure 3. Mosher ester analysis of bis-acetone ketal 11.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 658, 390, 671], "ImageBB": [138, 461, 347, 645]}}, {"id": 1290, "width": 1356, "height": 1140, "file_name": "acs.orglett.5b01710-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [813.0, 198.0, 443.0, 251.0], "category_id": 1, "id": 0}, {"bbox": [790.7, 618.2, 339.4, 243.5], "category_id": 1, "id": 3}, {"bbox": [104.6, 185.9, 407.4, 236.3], "category_id": 1, "id": 4}, {"bbox": [222.6, 647.0, 335.5, 242.1], "category_id": 1, "id": 5}, {"bbox": [624.4, 890.7, 261.8, 207.3], "category_id": 1, "id": 8}], "caption": "Figure 2. Proposed catalytic cycle of \u03b2-\ufb02uorination.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 528, 700, 546], "ImageBB": [448, 237, 787, 522]}}, {"id": 1291, "width": 1344, "height": 956, "file_name": "ol401571r-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [933.0, 614.0, 313.0, 267.0], "category_id": 1, "id": 1}, {"bbox": [83.0, 168.0, 1181.4, 783.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Single-crystal X-ray diffraction analysis for 2a0 . Thermal ellipsoids are shown at the 50% probability level. The single crystal was obtained after methylation of 2a with trimethyl- silyldiazomethane. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 566, 771, 625], "ImageBB": [437, 317, 773, 556]}}, {"id": 1292, "width": 1148, "height": 608, "file_name": "ol050791f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 166.0, 312.5, 260.4], "category_id": 1, "id": 0}, {"bbox": [358.3, 266.8, 90.7, 61.2], "category_id": 1, "id": 1}, {"bbox": [460.2, 141.9, 554.8, 309.7], "category_id": 1, "id": 2}], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 763, 491, 776], "ImageBB": [490, 638, 777, 790]}}, {"id": 1293, "width": 1344, "height": 1828, "file_name": "ol048227c-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [535.0, 0.0, 327.0, 291.0], "category_id": 1, "id": 1}, {"bbox": [582.0, 840.0, 326.0, 118.0], "category_id": 1, "id": 2}, {"bbox": [74.0, 811.0, 325.0, 137.0], "category_id": 1, "id": 5}, {"bbox": [69.0, 0.0, 319.0, 288.0], "category_id": 1, "id": 6}, {"bbox": [63.0, 395.0, 339.0, 309.0], "category_id": 1, "id": 7}, {"bbox": [572.0, 402.0, 336.0, 306.0], "category_id": 1, "id": 9}], "caption": "Table 1. Deoxygenation of Phosphine Oxides Using Ph3Pa as a Sacrificial Reagent ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 409, 409, 438], "ImageBB": [74, 443, 410, 900]}}, {"id": 1294, "width": 1352, "height": 996, "file_name": "ol0348957-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [924.0, 143.0, 302.0, 207.3], "category_id": 1, "id": 0}, {"bbox": [447.34, 141.67, 320.0, 199.0], "category_id": 1, "id": 2}, {"bbox": [1080.0, 473.0, 233.0, 138.3], "category_id": 1, "id": 3}, {"bbox": [283.0, 787.0, 257.0, 138.1], "category_id": 1, "id": 4}, {"bbox": [635.0, 467.0, 362.0, 194.0], "category_id": 1, "id": 5}, {"bbox": [1072.0, 150.0, 3.0, 3.0], "category_id": 1, "id": 6}, {"bbox": [70.0, 148.0, 264.0, 201.0], "category_id": 1, "id": 7}, {"bbox": [718.0, 784.0, 264.0, 143.2], "category_id": 1, "id": 8}, {"bbox": [83.6, 470.0, 314.5, 206.1], "category_id": 1, "id": 9}], "caption": "Figure 1. Fluorinated acetophenones and 19F NMR data (CDCl3).", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 396, 409, 411], "ImageBB": [73, 135, 411, 384]}}, {"id": 1295, "width": 1148, "height": 1344, "file_name": "ol016693l-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [524.0, 200.0, 325.0, 150.0], "category_id": 1, "id": 3}, {"bbox": [96.0, 152.0, 324.0, 285.0], "category_id": 1, "id": 4}, {"bbox": [102.0, 527.0, 290.0, 194.0], "category_id": 1, "id": 5}, {"bbox": [662.0, 524.0, 148.0, 268.0], "category_id": 1, "id": 6}], "caption": "Figure 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 277, 491, 290], "ImageBB": [490, 51, 777, 387]}}, {"id": 1296, "width": 1352, "height": 488, "file_name": "ol0069002-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [159.0, 143.0, 1033.0, 345.0], "category_id": 1, "id": 0}], "caption": "Figure 1. The chitinase inhibitor allosamidin.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 904, 680, 917], "ImageBB": [439, 770, 777, 892]}}, {"id": 1297, "width": 1164, "height": 908, "file_name": "jo9919409-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 115.0, 420.0, 315.0], "category_id": 1, "id": 0}, {"bbox": [0.0, 529.0, 472.0, 321.0], "category_id": 1, "id": 5}, {"bbox": [539.0, 553.0, 418.0, 317.0], "category_id": 1, "id": 6}, {"bbox": [497.0, 137.0, 481.0, 295.0], "category_id": 1, "id": 7}], "caption": "Figure 6. Possible chelation intermediates of base-promoted acetal fission. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 268, 775, 294], "ImageBB": [486, 35, 777, 262]}}, {"id": 1298, "width": 816, "height": 832, "file_name": "jo9919409-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [366.0, 485.0, 324.4, 300.8], "category_id": 1, "id": 0}, {"bbox": [456.0, 0.0, 288.0, 245.0], "category_id": 1, "id": 1}, {"bbox": [23.0, 12.0, 284.0, 163.6], "category_id": 1, "id": 4}, {"bbox": [2.2, 534.3, 317.7, 209.3], "category_id": 1, "id": 5}], "caption": "Figure 3. Conformational energies of mono-sulfoxide 5 and plausible mechanism of diastereoselective oxidation. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 485, 775, 511], "ImageBB": [506, 266, 710, 474]}}, {"id": 1299, "width": 1384, "height": 1548, "file_name": "jo980755c-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [445.0, 88.0, 210.4, 165.0], "category_id": 1, "id": 0}, {"bbox": [698.0, 130.0, 365.0, 67.0], "category_id": 1, "id": 1}], "caption": "Figure 2. UV-vis spectral trace (300-700 nm) for the reaction of styrene (0.1 M) with [RuIV(PPz*)(bpy)O](ClO4)2 (1d) (0.15 mM) in acetonitrile at room temperature under pseudo- first-order conditions. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 761, 409, 814], "ImageBB": [81, 362, 427, 749]}}, {"id": 1300, "width": 2808, "height": 1384, "file_name": "jo980181b-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [903.0, 2.0, 681.0, 395.0], "category_id": 1, "id": 1}], "caption": "Table 1. Proton NMR and Carbon-13 NMR Chemical Shifts and J Values (Hz) for 5 in CDCl3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [153, 64, 695, 77], "ImageBB": [74, 82, 776, 428]}}, {"id": 1301, "width": 1404, "height": 2044, "file_name": "jo962055i-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [81.6, 1476.0, 1301.4, 568.0], "category_id": 1, "id": 0}, {"bbox": [0.0, 3.0, 215.0, 269.0], "category_id": 1, "id": 1}], "caption": "Figure 3.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 751, 496, 764], "ImageBB": [424, 228, 775, 739]}}, {"id": 1302, "width": 1356, "height": 1000, "file_name": "jo502578x-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [554.9, 824.2, 277.3, 112.5], "category_id": 1, "id": 1}, {"bbox": [872.7, 777.0, 232.4, 158.3], "category_id": 1, "id": 2}], "caption": "Figure 2. H/D exchange reactions with the NHC catalysts 1\u22123 and DBU using dimethyl malonate in CDCl3 (0.1 M) with 2 mol % catalyst. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 435, 784, 477], "ImageBB": [448, 176, 787, 426]}}, {"id": 1303, "width": 1356, "height": 388, "file_name": "jo401737t-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [33.7, 44.5, 1284.0, 268.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Structure of C4-Azo-PEG 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 791, 636, 805], "ImageBB": [448, 685, 787, 782]}}, {"id": 1304, "width": 1352, "height": 1448, "file_name": "jo401158d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [247.2, 936.5, 822.8, 511.5], "category_id": 1, "id": 0}, {"bbox": [258.0, 550.0, 632.0, 466.0], "category_id": 1, "id": 1}, {"bbox": [102.0, 66.0, 706.0, 444.0], "category_id": 1, "id": 2}, {"bbox": [626.0, 26.0, 618.0, 479.0], "category_id": 1, "id": 3}], "caption": "Figure 1. Members of the Veratrum family of alkaloids.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 875, 351, 889], "ImageBB": [82, 503, 420, 865]}}, {"id": 1305, "width": 1344, "height": 848, "file_name": "ol7019636-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [708.0, 1.0, 211.0, 241.0], "category_id": 1, "id": 0}, {"bbox": [426.0, 71.0, 144.0, 127.0], "category_id": 1, "id": 1}], "caption": "Table 1. Relevant Reported Chemical and Biological Data for Selected Nitrosamines (from References 9 and 11) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 287, 402, 315], "ImageBB": [74, 318, 410, 530]}}, {"id": 1306, "width": 1352, "height": 604, "file_name": "ol5029223-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [657.1, 66.3, 493.9, 392.8], "category_id": 1, "id": 0}, {"bbox": [198.5, 46.0, 392.4, 412.1], "category_id": 1, "id": 1}], "caption": "Figure 2. HMBC and 1H\u22121H COSY correlations of 1\u22123 and 5.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 290, 396, 306], "ImageBB": [82, 132, 420, 283]}}, {"id": 1307, "width": 1352, "height": 2652, "file_name": "acs.joc.5b02237-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [343.0, 2389.0, 302.0, 236.0], "category_id": 1, "id": 0}, {"bbox": [742.0, 246.0, 334.0, 229.0], "category_id": 1, "id": 1}, {"bbox": [352.0, 285.0, 302.0, 267.0], "category_id": 1, "id": 2}, {"bbox": [738.0, 615.0, 331.0, 250.0], "category_id": 1, "id": 3}, {"bbox": [337.0, 615.0, 317.0, 250.0], "category_id": 1, "id": 4}, {"bbox": [724.0, 889.0, 349.0, 254.0], "category_id": 1, "id": 5}, {"bbox": [334.0, 886.0, 324.0, 274.0], "category_id": 1, "id": 6}, {"bbox": [717.0, 1190.0, 334.0, 271.0], "category_id": 1, "id": 7}, {"bbox": [334.0, 1183.0, 327.0, 292.0], "category_id": 1, "id": 8}, {"bbox": [700.0, 1511.0, 411.0, 249.0], "category_id": 1, "id": 9}, {"bbox": [348.0, 1503.0, 302.0, 271.0], "category_id": 1, "id": 10}, {"bbox": [707.0, 1829.0, 390.0, 236.0], "category_id": 1, "id": 11}, {"bbox": [337.0, 1815.0, 324.0, 274.0], "category_id": 1, "id": 12}, {"bbox": [728.0, 2121.0, 345.0, 239.0], "category_id": 1, "id": 13}, {"bbox": [337.0, 2114.0, 324.0, 249.0], "category_id": 1, "id": 14}, {"bbox": [735.0, 2395.0, 327.0, 227.0], "category_id": 1, "id": 15}], "caption": "Table 1. Structures of Starting Compounds 3, Photoproducts 4, and Their Isolated Yieldsa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 794]}}, {"id": 1308, "width": 1416, "height": 1196, "file_name": "acs.joc.5b00302-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [215.0, 64.0, 398.0, 244.0], "category_id": 1, "id": 0}, {"bbox": [142.0, 542.0, 539.0, 372.0], "category_id": 1, "id": 1}], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 415, 738, 436], "ImageBB": [433, 116, 787, 415]}}, {"id": 1309, "width": 1352, "height": 816, "file_name": "acs.joc.5b00302-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 32.0, 493.0, 373.0], "category_id": 1, "id": 4}, {"bbox": [467.0, 37.0, 449.0, 366.0], "category_id": 1, "id": 5}, {"bbox": [400.0, 466.4, 462.0, 262.6], "category_id": 1, "id": 8}, {"bbox": [957.0, 105.0, 364.0, 236.1], "category_id": 1, "id": 9}, {"bbox": [66.0, 470.4, 329.0, 218.3], "category_id": 1, "id": 10}, {"bbox": [908.0, 470.6, 444.0, 215.4], "category_id": 1, "id": 11}], "caption": "Figure 1. Structures of catalysts screened in this study.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 917, 349, 931], "ImageBB": [82, 704, 420, 908]}}, {"id": 1310, "width": 1352, "height": 944, "file_name": "acs.orglett.5b01872-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [58.17, 625.43, 277.97, 171.07], "category_id": 1, "id": 0}, {"bbox": [26.38, 354.3, 424.74, 220.42], "category_id": 1, "id": 3}, {"bbox": [26.38, 58.15, 259.71, 143.34], "category_id": 1, "id": 4}, {"bbox": [528.63, 295.75, 177.92, 55.53], "category_id": 1, "id": 5}, {"bbox": [779.82, 61.53, 265.8, 143.34], "category_id": 1, "id": 8}, {"bbox": [746.0, 601.77, 445.71, 204.19], "category_id": 1, "id": 9}, {"bbox": [779.82, 323.87, 411.89, 249.5], "category_id": 1, "id": 10}, {"bbox": [334.79, 614.62, 355.75, 175.12], "category_id": 1, "id": 14}], "caption": "Scheme 2. An Attempt to Prepare the Divinyl Intermediate", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 504, 417, 519], "ImageBB": [82, 525, 420, 761]}, "diagram_type": "multiple"}, {"id": 1311, "width": 1352, "height": 676, "file_name": "acs.orglett.5b02680-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [89.28, 36.55, 437.59, 223.36], "category_id": 1, "id": 1}, {"bbox": [858.27, 4.06, 400.4, 257.88], "category_id": 1, "id": 2}, {"bbox": [479.52, 329.62, 405.13, 258.56], "category_id": 1, "id": 3}], "caption": "Scheme 2. Reduction of Isoxazoles 3a\u2212d to Quinolinones 4a\u2212 d Followed by Condensation with Acetone Delivers DBNs 5a\u2212 d ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 493, 417, 538], "ImageBB": [82, 544, 420, 713]}, "diagram_type": "graph"}, {"id": 1312, "width": 1260, "height": 500, "file_name": "ja0171299-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [446.26, 325.85, 289.95, 135.51], "category_id": 1, "id": 0}, {"bbox": [0.0, 0.0, 257.8, 272.28], "category_id": 1, "id": 1}, {"bbox": [429.87, 0.0, 262.85, 269.13], "category_id": 1, "id": 3}, {"bbox": [947.99, 110.3, 308.23, 339.72], "category_id": 1, "id": 5}, {"bbox": [68.07, 325.85, 172.71, 135.51], "category_id": 1, "id": 6}], "caption": "Scheme 6. Formation of Ethyl 3-(S-tert-butylsulfanyl)benzoate 9a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 382, 767, 395], "ImageBB": [451, 395, 766, 520]}, "diagram_type": "tree"}, {"id": 1313, "width": 1356, "height": 1712, "file_name": "ja207331m-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [943.02, 6.25, 267.18, 207.58], "category_id": 1, "id": 0}, {"bbox": [507.32, 583.77, 339.11, 256.9], "category_id": 1, "id": 3}, {"bbox": [253.46, 1258.95, 463.24, 357.99], "category_id": 1, "id": 6}, {"bbox": [125.02, 20.55, 279.14, 177.28], "category_id": 1, "id": 7}, {"bbox": [911.93, 530.13, 276.58, 154.16], "category_id": 1, "id": 8}, {"bbox": [911.93, 1255.52, 443.55, 361.42], "category_id": 1, "id": 10}, {"bbox": [833.16, 861.57, 446.11, 363.98], "category_id": 1, "id": 11}, {"bbox": [355.35, 262.07, 314.26, 228.66], "category_id": 1, "id": 12}, {"bbox": [458.11, 7.71, 233.76, 198.69], "category_id": 1, "id": 13}, {"bbox": [976.15, 250.08, 310.83, 261.21], "category_id": 1, "id": 16}, {"bbox": [77.92, 861.57, 411.87, 362.27], "category_id": 1, "id": 18}], "caption": "Scheme 3. Synthesis of the Right Fragment of Psymberin", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 756, 107], "ImageBB": [436, 117, 775, 545]}, "diagram_type": "multiple"}, {"id": 1314, "width": 2756, "height": 820, "file_name": "ja801487v-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1167.75, 303.01, 187.5, 139.12], "category_id": 1, "id": 0}, {"bbox": [0.0, 309.9, 359.84, 137.74], "category_id": 1, "id": 3}, {"bbox": [1422.81, 318.17, 140.62, 103.3], "category_id": 1, "id": 4}, {"bbox": [552.85, 311.28, 358.46, 137.73], "category_id": 1, "id": 6}], "caption": "Scheme 1. Reaction Scheme for the Photolysis of Dibenzyl Ketones and Recombination Cases in Supramolecular Systems", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 673, 69], "ImageBB": [65, 81, 754, 286]}, "diagram_type": "tree"}, {"id": 1315, "width": 1352, "height": 296, "file_name": "ja905415r-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [156.91, 12.17, 252.95, 227.12], "category_id": 1, "id": 2}, {"bbox": [468.03, 6.08, 259.03, 253.49], "category_id": 1, "id": 3}], "caption": "Scheme 1. Hypothetical Stepwise Mechanism Involving Carbocationic Intermediate II ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 444, 334, 468], "ImageBB": [58, 479, 396, 553]}, "diagram_type": "single"}, {"id": 1316, "width": 1324, "height": 1040, "file_name": "ja992608h-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [0.0, 708.74, 517.94, 289.46], "category_id": 1, "id": 1}, {"bbox": [0.0, 347.08, 532.51, 286.81], "category_id": 1, "id": 4}, {"bbox": [647.1, 333.17, 529.86, 284.16], "category_id": 1, "id": 7}, {"bbox": [735.85, 723.31, 514.63, 286.81], "category_id": 1, "id": 8}, {"bbox": [592.12, 2.65, 510.0, 281.51], "category_id": 1, "id": 9}, {"bbox": [15.9, 21.86, 394.08, 207.32], "category_id": 1, "id": 11}], "caption": "Scheme 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 135, 78], "ImageBB": [76, 84, 407, 344]}, "diagram_type": "multiple"}, {"id": 1317, "width": 1016, "height": 1032, "file_name": "jo000585f-Scheme-c19.png", "license": 0, "bboxes": [{"bbox": [13.94, 721.21, 357.34, 232.84], "category_id": 1, "id": 1}, {"bbox": [0.0, 0.0, 289.69, 221.99], "category_id": 1, "id": 2}, {"bbox": [310.35, 361.38, 291.24, 230.25], "category_id": 1, "id": 3}, {"bbox": [690.93, 6.71, 291.24, 230.25], "category_id": 1, "id": 6}], "caption": "Scheme 19", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [570, 524, 641, 538], "ImageBB": [480, 545, 734, 803]}, "diagram_type": "multiple"}, {"id": 1318, "width": 1176, "height": 944, "file_name": "jo0014156-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 0.0, 377.68, 357.69], "category_id": 1, "id": 2}, {"bbox": [0.0, 737.74, 234.73, 181.79], "category_id": 1, "id": 3}, {"bbox": [758.9, 617.72, 413.57, 289.45], "category_id": 1, "id": 5}, {"bbox": [720.66, 0.0, 415.34, 353.57], "category_id": 1, "id": 6}, {"bbox": [157.66, 525.95, 400.04, 212.97], "category_id": 1, "id": 7}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [96, 83, 390, 319]}, "diagram_type": "tree"}, {"id": 1319, "width": 1336, "height": 1200, "file_name": "jo001700p-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [199.16, 812.9, 828.07, 383.05], "category_id": 1, "id": 0}, {"bbox": [0.0, 0.0, 617.54, 266.06], "category_id": 1, "id": 3}, {"bbox": [779.95, 8.69, 493.89, 264.73], "category_id": 1, "id": 4}], "caption": "Scheme 5", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 349, 270, 363], "ImageBB": [75, 369, 409, 669]}, "diagram_type": "tree"}, {"id": 1320, "width": 1356, "height": 944, "file_name": "jo2001534-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [971.38, 53.59, 284.9, 170.26], "category_id": 1, "id": 0}, {"bbox": [147.88, 590.15, 276.08, 139.06], "category_id": 1, "id": 2}, {"bbox": [1082.63, 553.52, 269.3, 175.69], "category_id": 1, "id": 5}, {"bbox": [30.53, 4.07, 242.16, 299.82], "category_id": 1, "id": 6}, {"bbox": [617.29, 592.86, 277.44, 139.06], "category_id": 1, "id": 10}, {"bbox": [466.02, 10.85, 287.61, 221.82], "category_id": 1, "id": 11}], "caption": "Scheme 5. Computational Simulation of the 7-Endo-Trig Cyclization of the Anion 1a- To Give Anion 7a- as a Model Reaction for the Formation of Type 6 Compounds for the Gas Phase and SCRF-CPCM(UAKS) Solution-Phase Simulations (THF) (Relative Energies: SCS-MP2/6-311\u00feG(d,p)// B3LYP/6-31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 310, 771, 431], "ImageBB": [436, 442, 775, 678]}, "diagram_type": "multiple"}, {"id": 1321, "width": 1352, "height": 2008, "file_name": "jo201996w-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [882.48, 611.74, 366.45, 434.95], "category_id": 1, "id": 0}, {"bbox": [12.05, 33.15, 219.87, 202.91], "category_id": 1, "id": 1}, {"bbox": [93.37, 1239.56, 506.0, 551.47], "category_id": 1, "id": 2}, {"bbox": [256.01, 82.37, 247.98, 163.73], "category_id": 1, "id": 9}, {"bbox": [995.93, 358.61, 209.83, 150.67], "category_id": 1, "id": 12}, {"bbox": [326.29, 1073.81, 209.83, 159.72], "category_id": 1, "id": 13}, {"bbox": [93.37, 629.82, 425.68, 385.73], "category_id": 1, "id": 14}, {"bbox": [882.48, 19.09, 397.57, 212.95], "category_id": 1, "id": 15}], "caption": "Scheme 5. Synthesis of Nonsymmetric 2,2\u2034-Disubstitued Tris-ortho-azobenzenes ", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 81, 405, 112], "ImageBB": [69, 119, 407, 621]}, "diagram_type": "tree"}, {"id": 1322, "width": 2820, "height": 1656, "file_name": "jo402763m-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [1516.5, 647.33, 238.42, 207.32], "category_id": 1, "id": 0}, {"bbox": [1238.6, 417.45, 231.35, 214.37], "category_id": 1, "id": 1}, {"bbox": [224.3, 992.86, 334.34, 363.86], "category_id": 1, "id": 2}, {"bbox": [1410.71, 1265.05, 265.21, 220.01], "category_id": 1, "id": 4}, {"bbox": [2039.88, 447.07, 372.43, 276.42], "category_id": 1, "id": 6}, {"bbox": [1728.11, 980.17, 242.65, 204.49], "category_id": 1, "id": 9}, {"bbox": [212.7, 139.62, 286.69, 306.04], "category_id": 1, "id": 11}, {"bbox": [2561.84, 449.89, 258.16, 241.16], "category_id": 1, "id": 15}, {"bbox": [72.26, 595.22, 301.99, 299.86], "category_id": 1, "id": 17}, {"bbox": [622.12, 0.0, 308.95, 242.57], "category_id": 1, "id": 18}, {"bbox": [966.33, 975.94, 320.23, 365.27], "category_id": 1, "id": 19}, {"bbox": [1653.35, 241.16, 286.37, 220.01], "category_id": 1, "id": 21}, {"bbox": [0.0, 937.4, 147.5, 139.9], "category_id": 1, "id": 22}, {"bbox": [1190.64, 104.36, 255.66, 215.78], "category_id": 1, "id": 23}, {"bbox": [977.0, 631.82, 268.65, 236.93], "category_id": 1, "id": 26}], "caption": "Scheme 6. Plausible Catalytic Cycle Reaction Mechanism for the Formation of Chromenes 5 and the Carbonyl Compounds 10a", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 784, 110], "ImageBB": [82, 116, 787, 530]}, "diagram_type": "graph"}, {"id": 1323, "width": 1044, "height": 1260, "file_name": "jo951899j-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [8.2, 216.2, 466.64, 56.1], "category_id": 1, "id": 0}, {"bbox": [376.46, 27.1, 321.61, 53.58], "category_id": 1, "id": 1}, {"bbox": [0.0, 25.21, 305.21, 51.69], "category_id": 1, "id": 2}, {"bbox": [9.46, 758.9, 664.01, 250.86], "category_id": 1, "id": 3}, {"bbox": [285.66, 1099.27, 588.34, 138.04], "category_id": 1, "id": 4}, {"bbox": [11.98, 442.48, 706.9, 253.39], "category_id": 1, "id": 8}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [197, 55, 260, 69], "ImageBB": [101, 75, 362, 390]}, "diagram_type": "multiple"}, {"id": 1324, "width": 1332, "height": 2796, "file_name": "jo961049j-Scheme-c11.png", "license": 0, "bboxes": [{"bbox": [58.75, 1453.25, 254.58, 559.48], "category_id": 1, "id": 0}, {"bbox": [0.0, 323.1, 356.69, 464.37], "category_id": 1, "id": 1}, {"bbox": [959.56, 353.87, 352.49, 444.79], "category_id": 1, "id": 2}, {"bbox": [481.18, 0.0, 311.93, 370.66], "category_id": 1, "id": 4}, {"bbox": [400.05, 1065.81, 96.52, 174.84], "category_id": 1, "id": 6}, {"bbox": [637.84, 865.79, 276.96, 495.14], "category_id": 1, "id": 8}, {"bbox": [517.55, 1619.69, 243.38, 549.69], "category_id": 1, "id": 10}, {"bbox": [990.33, 1553.95, 321.72, 458.78], "category_id": 1, "id": 12}, {"bbox": [637.84, 865.79, 276.96, 495.14], "category_id": 1, "id": 13}], "caption": "Scheme 11", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [203, 49, 274, 63], "ImageBB": [78, 69, 411, 768]}, "diagram_type": "tree"}, {"id": 1325, "width": 1120, "height": 2248, "file_name": "jo9816515-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [559.02, 1583.38, 420.66, 286.77], "category_id": 1, "id": 0}, {"bbox": [913.32, 2105.18, 200.21, 142.82], "category_id": 1, "id": 1}, {"bbox": [701.86, 900.77, 391.43, 330.63], "category_id": 1, "id": 4}, {"bbox": [92.23, 51.73, 383.55, 151.82], "category_id": 1, "id": 5}, {"bbox": [743.48, 3.37, 271.07, 224.92], "category_id": 1, "id": 7}, {"bbox": [0.0, 1583.38, 409.42, 282.27], "category_id": 1, "id": 11}, {"bbox": [916.7, 1966.86, 192.33, 139.45], "category_id": 1, "id": 12}, {"bbox": [95.61, 900.77, 439.78, 330.63], "category_id": 1, "id": 13}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [102, 83, 382, 645]}, "diagram_type": "tree"}, {"id": 1326, "width": 1348, "height": 2096, "file_name": "jo9906328-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [281.1, 1711.19, 578.98, 321.9], "category_id": 1, "id": 1}, {"bbox": [353.47, 868.18, 433.19, 204.46], "category_id": 1, "id": 3}, {"bbox": [0.0, 430.94, 437.38, 204.47], "category_id": 1, "id": 4}, {"bbox": [0.0, 1297.02, 442.63, 197.13], "category_id": 1, "id": 5}, {"bbox": [699.6, 0.0, 167.2, 117.43], "category_id": 1, "id": 6}, {"bbox": [554.8, 1230.97, 217.18, 169.03], "category_id": 1, "id": 7}, {"bbox": [775.12, 436.19, 420.6, 197.12], "category_id": 1, "id": 8}, {"bbox": [217.12, 22.02, 354.52, 195.02], "category_id": 1, "id": 11}, {"bbox": [773.03, 1249.84, 571.64, 282.05], "category_id": 1, "id": 14}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 63, 276, 77], "ImageBB": [74, 84, 411, 608]}, "diagram_type": "graph"}, {"id": 1327, "width": 1352, "height": 1804, "file_name": "ol025887d-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [52.34, 333.0, 497.26, 434.08], "category_id": 1, "id": 0}, {"bbox": [685.87, 365.49, 459.35, 438.59], "category_id": 1, "id": 2}, {"bbox": [383.55, 0.0, 362.79, 248.17], "category_id": 1, "id": 4}, {"bbox": [579.38, 795.96, 723.77, 947.58], "category_id": 1, "id": 5}], "caption": "Scheme 3. 2 + 2 Oligosaccharide Synthesis", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [487, 427, 727, 444], "ImageBB": [439, 449, 777, 900]}, "diagram_type": "multiple"}, {"id": 1328, "width": 1328, "height": 1520, "file_name": "ol048861q-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1027.7, 504.89, 298.73, 262.33], "category_id": 1, "id": 1}, {"bbox": [514.61, 0.0, 309.37, 260.81], "category_id": 1, "id": 4}, {"bbox": [820.94, 1009.78, 507.01, 501.1], "category_id": 1, "id": 5}, {"bbox": [1029.22, 0.0, 296.45, 263.09], "category_id": 1, "id": 9}, {"bbox": [514.61, 478.6, 315.46, 292.43], "category_id": 1, "id": 11}, {"bbox": [0.0, 475.24, 348.9, 296.55], "category_id": 1, "id": 14}, {"bbox": [0.0, 1083.54, 679.56, 336.09], "category_id": 1, "id": 15}, {"bbox": [104.9, 12.17, 189.27, 142.19], "category_id": 1, "id": 16}], "caption": "Scheme 3. Synthesis of Asymmetric Cyclic COA Trimer 24a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 74, 405, 88], "ImageBB": [76, 93, 408, 473]}, "diagram_type": "tree"}, {"id": 1329, "width": 1280, "height": 1232, "file_name": "ol049640n-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [71.08, 79.4, 238.83, 147.28], "category_id": 1, "id": 2}, {"bbox": [978.41, 427.1, 301.59, 237.56], "category_id": 1, "id": 3}, {"bbox": [834.98, 838.19, 435.42, 312.48], "category_id": 1, "id": 4}, {"bbox": [311.84, 837.55, 429.65, 313.12], "category_id": 1, "id": 5}, {"bbox": [980.33, 0.0, 299.67, 230.52], "category_id": 1, "id": 6}, {"bbox": [566.68, 83.24, 223.48, 147.28], "category_id": 1, "id": 7}, {"bbox": [567.96, 423.9, 309.92, 234.36], "category_id": 1, "id": 10}, {"bbox": [0.0, 409.81, 432.22, 316.96], "category_id": 1, "id": 11}], "caption": "Scheme 1. Synthesis of Four New Chiral Nonracemic                   1-Azadienesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [98, 389, 384, 416], "ImageBB": [82, 420, 402, 728]}, "diagram_type": "tree"}, {"id": 1330, "width": 1328, "height": 692, "file_name": "ol0701619-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [95.66, 385.09, 251.12, 210.48], "category_id": 1, "id": 0}, {"bbox": [986.53, 8.63, 337.48, 264.26], "category_id": 1, "id": 1}, {"bbox": [482.31, 455.47, 340.8, 233.05], "category_id": 1, "id": 2}, {"bbox": [1001.15, 422.94, 322.86, 262.26], "category_id": 1, "id": 3}, {"bbox": [2.66, 41.83, 338.14, 229.73], "category_id": 1, "id": 4}, {"bbox": [496.92, 2.66, 335.49, 267.57], "category_id": 1, "id": 5}], "caption": "Scheme 2. Proposed Mechanisms for the Dehydrogenation of                 Amino Acid Residuesa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [77, 365, 406, 392], "ImageBB": [76, 397, 408, 570]}, "diagram_type": "graph"}, {"id": 1331, "width": 1356, "height": 660, "file_name": "ol5000692-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1001.91, 48.83, 227.92, 149.19], "category_id": 1, "id": 0}, {"bbox": [10.18, 165.47, 187.9, 158.0], "category_id": 1, "id": 1}, {"bbox": [419.89, 427.9, 235.39, 149.19], "category_id": 1, "id": 3}, {"bbox": [447.7, 12.88, 315.43, 239.39], "category_id": 1, "id": 4}], "caption": "Scheme 2. Reaction of 1 and 2a; Proposed Formation of 2- Indolylindoline and the Observed Formation of 2,2\u2032- Biindole ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 480, 784, 525], "ImageBB": [448, 532, 787, 697]}, "diagram_type": "tree"}, {"id": 1332, "width": 1352, "height": 756, "file_name": "ol7019636-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [813.63, 186.76, 271.22, 250.37], "category_id": 1, "id": 0}, {"bbox": [276.62, 241.57, 237.4, 149.55], "category_id": 1, "id": 1}], "caption": "Scheme 1. PROLI/NO, a Nitric Oxide Donor", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [484, 811, 730, 824], "ImageBB": [439, 828, 777, 1017]}, "diagram_type": "graph"}, {"id": 1333, "width": 1080, "height": 1036, "file_name": "op010052o-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [341.99, 267.37, 170.73, 241.44], "category_id": 1, "id": 1}, {"bbox": [245.28, 649.79, 440.32, 314.9], "category_id": 1, "id": 2}, {"bbox": [8.64, 286.81, 116.16, 218.22], "category_id": 1, "id": 3}, {"bbox": [522.98, 3.24, 135.92, 304.96], "category_id": 1, "id": 9}, {"bbox": [645.66, 237.6, 429.07, 310.92], "category_id": 1, "id": 11}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [107, 72, 377, 331]}, "diagram_type": "multiple"}, {"id": 1334, "width": 1800, "height": 1912, "file_name": "op0602270-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [495.42, 0.0, 331.88, 325.2], "category_id": 1, "id": 0}, {"bbox": [61.21, 1092.3, 440.91, 322.33], "category_id": 1, "id": 2}, {"bbox": [877.99, 1095.17, 387.35, 324.24], "category_id": 1, "id": 3}, {"bbox": [495.42, 585.36, 340.49, 322.34], "category_id": 1, "id": 5}, {"bbox": [495.42, 1587.75, 393.09, 324.25], "category_id": 1, "id": 6}], "caption": "Scheme 3. Synthetic approach to 4,5-dihydro-3H-dinaphtho[2,1-c;1\u2032,2\u2032-e]phosphepine ligands 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 599, 67], "ImageBB": [200, 71, 650, 549]}, "diagram_type": "graph"}, {"id": 1335, "width": 1908, "height": 1052, "file_name": "op100103v-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [708.22, 0.0, 353.16, 327.37], "category_id": 1, "id": 3}, {"bbox": [711.09, 459.08, 465.78, 295.88], "category_id": 1, "id": 4}, {"bbox": [21.0, 2.86, 281.57, 271.06], "category_id": 1, "id": 5}, {"bbox": [1454.62, 340.73, 453.38, 650.93], "category_id": 1, "id": 6}, {"bbox": [1221.73, 335.96, 177.53, 244.34], "category_id": 1, "id": 9}, {"bbox": [21.0, 416.13, 455.28, 382.73], "category_id": 1, "id": 11}], "caption": "Scheme 5. Initial conditions for stage two for the synthesis of imidazo[5,1-c][1,4]benzoxazine-3-carboxylate 9", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 461, 657, 475], "ImageBB": [171, 480, 648, 743]}, "diagram_type": "multiple"}, {"id": 1336, "width": 2808, "height": 652, "file_name": "op2000089-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1331.66, 274.89, 106.76, 99.58], "category_id": 1, "id": 0}, {"bbox": [656.0, 284.71, 276.72, 232.81], "category_id": 1, "id": 1}, {"bbox": [2129.53, 287.51, 243.01, 230.01], "category_id": 1, "id": 2}, {"bbox": [686.9, 64.52, 248.63, 131.83], "category_id": 1, "id": 3}, {"bbox": [2005.91, 14.03, 370.85, 234.21], "category_id": 1, "id": 4}, {"bbox": [434.05, 199.16, 181.21, 123.42], "category_id": 1, "id": 5}, {"bbox": [1349.3, 67.32, 298.42, 129.68], "category_id": 1, "id": 6}, {"bbox": [1372.39, 298.73, 279.54, 234.22], "category_id": 1, "id": 7}], "caption": "Scheme 2. Competitive reactions for the in situ borylation with 1 through a magnesium-halide exchange", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 257, 655, 272], "ImageBB": [71, 282, 773, 445]}, "diagram_type": "multiple"}, {"id": 1337, "width": 1356, "height": 1208, "file_name": "op200312m-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [284.9, 827.23, 208.25, 278.01], "category_id": 1, "id": 2}, {"bbox": [234.71, 371.58, 483.65, 351.91], "category_id": 1, "id": 3}, {"bbox": [776.02, 825.2, 206.89, 276.65], "category_id": 1, "id": 5}, {"bbox": [1008.01, 388.53, 347.99, 292.24], "category_id": 1, "id": 6}, {"bbox": [10.18, 834.69, 238.77, 83.4], "category_id": 1, "id": 7}, {"bbox": [669.52, 0.0, 447.7, 244.1], "category_id": 1, "id": 10}, {"bbox": [8.82, 0.0, 447.02, 244.1], "category_id": 1, "id": 12}, {"bbox": [736.0, 352.59, 198.75, 203.42], "category_id": 1, "id": 13}], "caption": "Scheme 1. Strategy of the new synthesis route", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 431, 710, 446], "ImageBB": [448, 452, 787, 754]}, "diagram_type": "multiple"}, {"id": 1338, "width": 1356, "height": 656, "file_name": "op300058f-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [48.84, 396.07, 248.95, 160.06], "category_id": 1, "id": 0}, {"bbox": [339.17, 36.62, 239.45, 120.05], "category_id": 1, "id": 2}, {"bbox": [801.12, 2.71, 405.65, 191.26], "category_id": 1, "id": 4}, {"bbox": [320.18, 407.6, 240.81, 137.68], "category_id": 1, "id": 6}, {"bbox": [0.0, 31.2, 274.73, 132.93], "category_id": 1, "id": 7}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 505, 110], "ImageBB": [448, 116, 787, 280]}, "diagram_type": "tree"}, {"id": 1339, "width": 2820, "height": 1424, "file_name": "op400242j-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [427.44, 571.44, 404.88, 266.67], "category_id": 1, "id": 0}, {"bbox": [1238.6, 1030.0, 414.75, 321.69], "category_id": 1, "id": 1}, {"bbox": [1990.51, 571.44, 402.05, 262.43], "category_id": 1, "id": 5}, {"bbox": [1232.96, 18.34, 517.73, 262.44], "category_id": 1, "id": 7}, {"bbox": [1238.6, 488.2, 407.2, 345.67], "category_id": 1, "id": 8}], "caption": "Scheme 7. Hypothesized chlorination mechanism to form chloroimidate 18", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 507, 110], "ImageBB": [82, 116, 787, 472]}, "diagram_type": "tree"}, {"id": 1340, "width": 2152, "height": 736, "file_name": "op700026n-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1779.52, 0.0, 346.64, 320.74], "category_id": 1, "id": 0}, {"bbox": [1137.9, 4.31, 345.57, 314.27], "category_id": 1, "id": 2}, {"bbox": [385.4, 424.06, 402.63, 311.94], "category_id": 1, "id": 5}, {"bbox": [0.0, 4.31, 375.71, 309.97], "category_id": 1, "id": 8}, {"bbox": [865.54, 395.0, 447.84, 222.79], "category_id": 1, "id": 11}, {"bbox": [1418.88, 395.0, 733.12, 314.28], "category_id": 1, "id": 12}, {"bbox": [535.04, 3.23, 376.79, 313.2], "category_id": 1, "id": 13}], "caption": "Scheme 1. Synthesis of amide 1 (MK-0364, taranabant) via resolution", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 465, 67], "ImageBB": [156, 71, 694, 255]}, "diagram_type": "multiple"}, {"id": 1341, "width": 1696, "height": 748, "file_name": "op800189g-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [634.62, 391.06, 229.92, 189.17], "category_id": 1, "id": 0}, {"bbox": [1242.09, 638.76, 308.83, 80.59], "category_id": 1, "id": 1}, {"bbox": [1253.12, 392.76, 341.07, 145.05], "category_id": 1, "id": 2}, {"bbox": [0.0, 638.76, 335.98, 82.28], "category_id": 1, "id": 3}, {"bbox": [570.99, 634.52, 310.52, 86.52], "category_id": 1, "id": 4}, {"bbox": [468.33, 11.03, 535.36, 184.92], "category_id": 1, "id": 5}, {"bbox": [82.3, 389.36, 226.53, 187.47], "category_id": 1, "id": 6}], "caption": "Scheme 3. Reversible and irreversible decomposition of PTTCa under various conditions", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 384, 551, 398], "ImageBB": [198, 403, 622, 590]}, "diagram_type": "tree"}, {"id": 1342, "width": 2748, "height": 1800, "file_name": "op970113b-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [1231.72, 0.0, 395.38, 395.98], "category_id": 1, "id": 0}, {"bbox": [1360.94, 1057.31, 549.88, 247.48], "category_id": 1, "id": 1}, {"bbox": [0.0, 455.1, 640.6, 329.98], "category_id": 1, "id": 2}, {"bbox": [2101.9, 59.12, 551.25, 269.48], "category_id": 1, "id": 3}, {"bbox": [1234.47, 661.33, 570.49, 298.67], "category_id": 1, "id": 4}, {"bbox": [2199.5, 874.45, 548.5, 269.48], "category_id": 1, "id": 5}], "caption": "Scheme 3. Reaction pathways which can lead to relocation of the benzoyl moiety", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 49, 521, 63], "ImageBB": [82, 68, 769, 518]}, "diagram_type": "tree"}, {"id": 1343, "width": 1260, "height": 836, "file_name": "op980079g-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [692.72, 10.09, 546.48, 225.76], "category_id": 1, "id": 0}, {"bbox": [359.91, 8.2, 255.28, 104.68], "category_id": 1, "id": 5}, {"bbox": [298.77, 439.55, 361.17, 227.02], "category_id": 1, "id": 6}, {"bbox": [5.67, 9.46, 323.35, 182.25], "category_id": 1, "id": 7}, {"bbox": [763.2, 419.37, 381.45, 89.54], "category_id": 1, "id": 8}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 420, 501, 434], "ImageBB": [450, 439, 765, 648]}, "diagram_type": "multiple"}, {"id": 1344, "width": 1340, "height": 708, "file_name": "op990050s-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [177.64, 291.72, 237.3, 146.87], "category_id": 1, "id": 1}, {"bbox": [546.99, 413.1, 310.37, 171.68], "category_id": 1, "id": 3}, {"bbox": [1023.6, 398.35, 316.4, 244.11], "category_id": 1, "id": 4}, {"bbox": [1008.18, 4.02, 225.24, 324.58], "category_id": 1, "id": 6}, {"bbox": [0.0, 313.85, 127.36, 118.03], "category_id": 1, "id": 8}, {"bbox": [551.69, 30.85, 207.13, 306.47], "category_id": 1, "id": 9}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 299, 501, 313], "ImageBB": [441, 319, 776, 496]}, "diagram_type": "tree"}, {"id": 1345, "width": 1200, "height": 2316, "file_name": "op990067a-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [809.46, 2080.81, 259.4, 120.49], "category_id": 1, "id": 0}, {"bbox": [397.2, 1064.73, 409.95, 285.01], "category_id": 1, "id": 1}, {"bbox": [152.86, 279.22, 257.08, 114.7], "category_id": 1, "id": 2}, {"bbox": [25.48, 543.37, 479.42, 315.14], "category_id": 1, "id": 4}, {"bbox": [680.92, 612.89, 494.48, 278.06], "category_id": 1, "id": 6}, {"bbox": [24.32, 1508.47, 492.16, 395.08], "category_id": 1, "id": 8}, {"bbox": [451.63, 4.63, 391.42, 191.17], "category_id": 1, "id": 9}, {"bbox": [786.3, 1562.92, 411.11, 290.81], "category_id": 1, "id": 10}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [91, 73, 391, 652]}, "diagram_type": "tree"}, {"id": 1346, "width": 732, "height": 484, "file_name": "op800067v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 3.0, 729.0, 411.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of caprolactam 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 349, 634, 363], "ImageBB": [502, 225, 685, 346]}}, {"id": 1347, "width": 1104, "height": 1352, "file_name": "op034033l-Table-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [9.0, 317.0, 348.0, 136.0], "category_id": 1, "id": 0}, {"bbox": [9.0, 505.0, 362.0, 205.0], "category_id": 1, "id": 1}, {"bbox": [541.0, 778.4, 168.8, 130.5], "category_id": 1, "id": 2}, {"bbox": [798.7, 304.7, 175.4, 136.6], "category_id": 1, "id": 3}, {"bbox": [5.48, 765.74, 347.52, 138.36], "category_id": 1, "id": 4}], "caption": "Table 3. Variables for the Model-Robust Process-Screening Design ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 595, 400, 623], "ImageBB": [151, 246, 427, 584]}}, {"id": 1348, "width": 1412, "height": 1604, "file_name": "op025619v-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [856.0, 1274.0, 490.0, 260.0], "category_id": 1, "id": 3}, {"bbox": [842.0, 717.0, 486.0, 259.9], "category_id": 1, "id": 4}, {"bbox": [238.2, 725.0, 486.8, 253.9], "category_id": 1, "id": 5}], "caption": "Table 2. Dependence of 12:13 upon solvent and pKa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 472, 359, 487], "ImageBB": [74, 52, 427, 453]}}, {"id": 1349, "width": 1352, "height": 656, "file_name": "op2003612-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [101.2, 279.4, 223.8, 134.3], "category_id": 1, "id": 0}, {"bbox": [912.7, 278.2, 193.9, 129.4], "category_id": 1, "id": 1}, {"bbox": [886.4, 42.2, 219.0, 128.3], "category_id": 1, "id": 2}, {"bbox": [106.5, 40.3, 213.2, 135.3], "category_id": 1, "id": 3}], "caption": "Figure 1. Biocatalytic resolution of DL-alanine.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 370, 307, 384], "ImageBB": [82, 196, 420, 360]}}, {"id": 1350, "width": 1192, "height": 912, "file_name": "ja040054z-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [683.95, 513.95, 475.85, 329.12], "category_id": 1, "id": 0}, {"bbox": [648.18, 0.0, 516.39, 334.48], "category_id": 1, "id": 1}, {"bbox": [0.0, 0.0, 500.29, 335.68], "category_id": 1, "id": 2}, {"bbox": [32.2, 518.2, 468.09, 327.85], "category_id": 1, "id": 3}], "caption": "Scheme 6", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 125, 76], "ImageBB": [93, 80, 391, 308]}, "diagram_type": "graph"}, {"id": 1351, "width": 1356, "height": 912, "file_name": "jo501785d-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [4.07, 185.77, 232.67, 168.14], "category_id": 1, "id": 0}, {"bbox": [752.96, 18.31, 354.09, 246.78], "category_id": 1, "id": 2}, {"bbox": [330.35, 0.0, 346.63, 284.75], "category_id": 1, "id": 4}, {"bbox": [314.75, 528.15, 347.31, 287.47], "category_id": 1, "id": 5}, {"bbox": [997.16, 346.45, 352.73, 244.75], "category_id": 1, "id": 7}, {"bbox": [150.59, 372.89, 301.86, 134.24], "category_id": 1, "id": 11}, {"bbox": [700.72, 625.78, 347.99, 223.73], "category_id": 1, "id": 12}, {"bbox": [4.07, 521.37, 228.6, 158.65], "category_id": 1, "id": 13}], "caption": "Scheme 1. Possible Reaction Pathways of Rhodium\u2212 Carbene A with \u03b2-Enamino Ester 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 491, 748, 522], "ImageBB": [448, 527, 787, 755]}, "diagram_type": "graph"}, {"id": 1352, "width": 1316, "height": 672, "file_name": "jo9717245-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [545.1, 136.87, 195.52, 152.66], "category_id": 1, "id": 0}, {"bbox": [0.0, 271.1, 311.39, 144.11], "category_id": 1, "id": 1}, {"bbox": [955.89, 0.0, 360.11, 138.84], "category_id": 1, "id": 2}, {"bbox": [450.3, 523.78, 312.05, 144.11], "category_id": 1, "id": 3}, {"bbox": [616.2, 338.88, 97.43, 106.6], "category_id": 1, "id": 4}, {"bbox": [49.37, 0.0, 273.21, 152.0], "category_id": 1, "id": 5}, {"bbox": [955.24, 266.5, 273.2, 147.39], "category_id": 1, "id": 6}, {"bbox": [339.7, 282.95, 183.01, 51.98], "category_id": 1, "id": 7}, {"bbox": [358.13, 21.71, 142.2, 48.04], "category_id": 1, "id": 8}, {"bbox": [748.1, 270.45, 190.02, 65.35], "category_id": 1, "id": 9}, {"bbox": [743.25, 0.0, 188.94, 69.75], "category_id": 1, "id": 10}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [78, 84, 407, 252]}, "diagram_type": "tree"}, {"id": 1353, "width": 1352, "height": 860, "file_name": "ol5020043-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [683.78, 551.84, 273.91, 233.31], "category_id": 1, "id": 2}, {"bbox": [520.1, 0.0, 334.79, 399.0], "category_id": 1, "id": 3}, {"bbox": [812.28, 401.7, 235.37, 183.95], "category_id": 1, "id": 7}, {"bbox": [1003.01, 10.82, 332.76, 373.3], "category_id": 1, "id": 9}, {"bbox": [10.15, 0.0, 356.43, 409.82], "category_id": 1, "id": 10}, {"bbox": [1028.71, 523.43, 205.61, 190.71], "category_id": 1, "id": 11}, {"bbox": [94.01, 445.66, 391.6, 325.29], "category_id": 1, "id": 12}], "caption": "Scheme 2. Retrosynthetic Analysis of 2", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 581, 303, 596], "ImageBB": [82, 602, 420, 817]}, "diagram_type": "multiple"}, {"id": 1354, "width": 1356, "height": 900, "file_name": "op200112g-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [0.0, 206.15, 384.62, 210.23], "category_id": 1, "id": 0}, {"bbox": [412.43, 540.47, 364.95, 314.66], "category_id": 1, "id": 1}, {"bbox": [89.54, 25.09, 267.27, 147.16], "category_id": 1, "id": 2}, {"bbox": [514.86, 0.0, 264.14, 187.9], "category_id": 1, "id": 3}, {"bbox": [982.8, 89.51, 367.09, 342.49], "category_id": 1, "id": 4}, {"bbox": [966.63, 541.83, 371.05, 307.87], "category_id": 1, "id": 5}, {"bbox": [537.55, 193.43, 332.77, 235.54], "category_id": 1, "id": 6}], "caption": "Scheme 6. Mechanism of the isoprenylation reaction utilized to form the \ufb01nal chromene ring system within GLY I ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 123], "ImageBB": [71, 133, 410, 358]}, "diagram_type": "tree"}, {"id": 1355, "width": 956, "height": 1768, "file_name": "op900188v-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [641.03, 1332.85, 286.47, 360.86], "category_id": 1, "id": 0}, {"bbox": [684.35, 33.61, 209.55, 285.67], "category_id": 1, "id": 1}, {"bbox": [651.64, 631.49, 269.67, 359.97], "category_id": 1, "id": 2}, {"bbox": [24.76, 631.49, 293.54, 361.74], "category_id": 1, "id": 5}, {"bbox": [100.8, 23.88, 210.43, 289.21], "category_id": 1, "id": 6}, {"bbox": [24.76, 1332.85, 308.58, 360.86], "category_id": 1, "id": 8}], "caption": "Scheme 3. Preparation of aryl-propargyl ether substratesa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 750, 60], "ImageBB": [474, 70, 713, 512]}, "diagram_type": "tree"}], "annotations": [{"id": 1647, "image_id": 1186, "category_id": 1, "segmentation": [], "area": 57215.6592, "bbox": [737.09, 5.48, 269.58, 212.24], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 1648, "image_id": 1186, "category_id": 1, "segmentation": [], "area": 53697.004799999995, "bbox": [1452.77, 16.1, 290.82, 184.64], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 1649, "image_id": 1186, "category_id": 1, "segmentation": [], "area": 54090.28799999999, "bbox": [1784.06, 16.1, 292.95, 184.64], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 1650, "image_id": 1186, "category_id": 1, "segmentation": [], "area": 62178.6375, "bbox": [1450.64, 307.04, 292.95, 212.25], "iscrowd": 0, "attributes": {"occluded": 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