# Chemical Sciences: A Manual for CSIR-UGC National Eligibility Test for Lectureship and JRF/Space charge

Space charge is a concept in which excess electric charge is treated as a continuum of charge distributed over a region of space (either a volume or an area) rather than distinct point-like charges. This model typically applies when charge carriers have been emitted from some region of a solid—the cloud of emitted carriers can form a space charge region if they are sufficiently spread out, or the charged atoms or molecules left behind in the solid can form a space charge region. Space charge usually only occurs in dielectric media (including vacuum) because in a conductive medium the charge tends to be rapidly neutralized or screened. The sign of the space charge can be either negative or positive. This situation is perhaps most familiar in the area near a metal object when it is heated to incandescence in a vacuum. This effect was first observed by Thomas Edison in light bulb filaments, where it is sometimes called the Edison Effect, but space charge is a significant phenomenon in many vacuum and solid-state electronic devices.

## Cause
### Physical explanation

When a metal object is placed in a vacuum and is heated to incandescence, the energy is sufficient to cause electrons to "boil" away from the surface atoms and surround the metal object in a cloud of free electrons. This is called thermionic emission. The resulting cloud is negatively charged, and can be attracted to any nearby positively charged object, thus producing an electrical current which passes through the vacuum.
Space charge can result from a range of phenomena, but the most important are:
* Combination of the current density and spatially inhomogeneous resistivity
* Ionization of species within the dielectric to form heterocharge
* Charge injection from electrodes and from a stress enhancemement
* Polarization in structures such as water trees
It has been suggested that in AC most of carriers injected at electrodes during a half of cycle are ejected during the next half cycle, so the net balance of charge on a cycle is practically zero. However, a small fraction of the carriers can be trapped at levels deep enough to retain them when the field is inverted. The amount of charge in AC should increase slower than in DC and become observable after longer periods of time.

#### Hetero and Homo Charge

Hetero charge means that the polarity of the space charge is opposite to that of neighboring electrode, and homo charge is the reverse situation. Under high voltage application, a hetero charge near the electrode is expected to reduce the breakdown voltage, whereas a homo charge will increase it. After polarity reversal under ac conditions, the homo charge is converted to hetero space charge.

### Mathematical explanation

If the "vacuum" has a pressure of 10$^{-6}$ mmHg or less, the main vehicle of conduction is electrons. The emission current density (J) from the cathode, as a function of its thermodynamic temperature T, in the absence of space-charge, is given by:
    $J=(1-{\tilde {r}})A_{0}T^{2}\exp \left({\frac {-\phi }{kT}}\right)$
where
    A$_0$ = ${\frac {4\pi emk^{2}}{h^{3}}}\approx$ 1.2 × 10$^6$ A m$^{-2}$K$^{-2}$
    e = elementary positive charge (i.e., magnitude of electron charge),
    m = electron mass,
    k = Boltzmann's constant = 1.38 x 10$^{-23}$J/K,
    h = Planck's constant = 6.55 x 10$^{-34}$ J s,
    φ = work function of the cathode,
    ř = mean electron reflection coefficient.
The reflection coefficient can be as low as 0.105 but is usually near 0.5. For Tungsten, (1 - ř)A$_0$ = 0.6 to 1.0 × 10$^6$ A m$^{-2}$K$^{-2}$, and φ = 4.52 eV. At 2500 °C, the emission is 3000 A/m$^2$.
The emission current as given above is many times greater than that normally collected by the electrodes, except in some pulsed valves such as the cavity magnetron. Most of the electrons emitted by the cathode are driven back to it by the repulsion of the cloud of electrons in its neighborhood. This is called the space charge effect. In the limit of large current densities, J is given by the Child-Langmuir equation below, rather than by the thermionic emission equation above.

## Occurrence

Space charge is an inherent property of all vacuum tubes. This has at times made life harder or easier for electrical engineers who used tubes in their designs. For example, space charge significantly limited the practical application of triode amplifiers which lead to further innovations such as the vacuum tube tetrode.
On the other hand, space charge was useful in some tube applications because it generates a negative EMF within the tube's envelope, which could be used to create a negative bias on the tube's grid. Grid bias could also be achieved by using an applied grid voltage in addition to the control voltage. This could improve the engineer's control and fidelity of amplification.
Space charges can also occur within dielectrics. For example, when gas near a high voltage electrode begins to undergo dielectric breakdown, electrical charges are injected into the region near the electrode, forming space charge regions in the surrounding gas. Space charges can also occur within solid or liquid dielectrics that are stressed by high electric fields. Trapped space charges within solid dielectrics are often a contributing factor leading to dielectric failure within high voltage power cables and capacitors.

## Child's Law

Also known as the Child-Langmuir Law or the Three-Halves Power Law, Child's Law states that the space charge-limited current (SCLC) in a plane-parallel diode varies directly as the three-halves power of the anode voltage ${V_{a}}$ and inversely as the square of the distance $d$ separating the cathode and the anode. That is,
    $I_{a}=JS=2.33\times 10^{-6}{\frac {S\nu {V_{a}}^{3/2}}{d^{2}}}$.
Where $I_{a}$ is the anode current, $J$ the current density, and $S$ the area. This assumes the following:
* The electrodes are planar, parallel, equipotential surfaces of infinite dimensions.
* The electrons have zero velocity at the cathode surface.
* In the interelectrode region, only electrons are present.
* The current is space-charge limited.
* The anode voltage remains constant for a sufficiently long time so that the anode current is steady.

## Mott's steady-state space-charge-limited conduction model

The steady-state space-charge-limited conduction-current density $J$ in a plane-parallel dielectric sample with electrode separation $L$ is proportional to the square of the applied voltage $V$. That is,
    $J={\frac {9{\epsilon }{\mu }{V}^{2}}{8{L}^{3}}}$
This assumes the following:
* There is only one type of charge carrier present.
* The material has no intrinsic conductivity, but charges are injected into it from one electrode and captured by the other.
* The carrier mobility $\mu$ and the dielectric permittivity $\epsilon$ are constant throughout the sample.
* The electric field at the charge-injecting cathode is zero.
As example of application, the steady state space charge limited current across silicon with charge carrier mobility = 1500 cm$^2$/V-s, dielectric constant=11.9 and plate area=10$^{-8}$cm$^2$, space=10$^{-4}$cm can be calculated by on line calcaulator as 1.264$^{-4}$A at voltage 3V.

## Shot noise

Space charge tends to reduce shot noise. Electrons (and positive charge carriers) come with their own built-in negative feedback.

## References

* Telecommunications by A. T. Starr, Second Ed., Sir Isaac Pitman & Sons, Ltd, London, 1958
* Physics of Dielectrics for the Engineer by R. Coelho, Elsevier Scientific Pub. Co., Amsterdam, 1979