OpenLLM-France/wikimedia huggingface dataset:
# 1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene

1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene is an organochemical compound from the diene group and a cyclopentadiene derivative. The anion of this compound is used as a sterically demanding ligand, often abbreviated as Cp$^{[BIG]}$, in the organometallic chemistry of sandwich compounds.

## Preparation

1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene can be prepared in a one-step reaction by the palladium-catalyzed reaction of Zirconocene dichloride with 4-n-butylbenzene bromide.

## Reactions

1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene reacts directly with a range of organometallic compounds or in reduced form as a sodium or potassium compound with the salts of main-group and transition metals. The resulting metallocenes, in contrast to the unsubstituted Pentaphenylcyclopentadienyl complexes are in various solvents readily soluble. The perarylated metallocenes, such as samarium, sometimes exhibit unusual stability. This is likely to be explained by hydrogen bonds between the substituents. The reaction of 1,2,3,4,5-pentakis(4-butylphenyl)-1,3-cyclopentadiene with strong basic strontium and barium compounds provides the corresponding coplanar sandwich compounds.
# Ankokuji Village Ruins

The Ankokuji Village Ruins (安国寺集落遺跡, Ankokuji shūraku iseki) is an archaeological site with the traces of a Yayoi period settlement located on the Kunisaki neighborhood of the city of Kunisaki, Ōita Prefecture on the island of Kyushu, Japan. The site was designated a National Historic Site in 1992.

## Overview

The Ankokuji Village Ruins is the remains of a village that was built from the Yayoi period to the early Kofun period, located on a terraced fan of low marshland formed by the Tabuka River, about two kilometers from the present-day coastline. The ruins were discovered in 1920 when pottery shards and large tree roots were discovered during a land reclamation project. Because it is a swampy location, organic artifacts are well preserved, and many wooden agricultural tools, architectural components, postholes, plant seeds, etc. were excavated, along with stone tools and a distinctive type of Yayoi pottery. This earthenware, with a comb pattern on a double-rimmed pot, is named "Ankokuji-style pottery" and is found in other locations in eastern Kyushu, making this the type site for this style. More than 300 post holes, thought to be a group of raised buildings, is thought to be the residential complex. Building materials include lumber with joints, round ladders, square lumber, boards, and logs. The settlement appears to have been surrounded by a large U-shaped ditch, two meters deep and up to 22 meters wide, although if this ditch was for defensive purposes or simply for drainage is unknown. As carbonized rice was also excavated, during the first excavations carried out from 1949 to 1952, the site attracted attention as it supported the theory that rice cultivation was introduced into Japan from eastern Kyushu. It has been dubbed the "Western Toro", and compared to the Toro site in Shizuzoka.
Due to the geography of the Kunisaki Peninsula where this site is located, there was only a small area of cultivated land between the sea and the mountains where weak rice cultivation could be practiced, so it believed that the inhabitants were heavily dependent on hunting, fishing, and gathering of wild plants, as well as maritime trade with the Chugoku and Shikoku regions via the Seto Inland Sea. his is supported by artifacts found in middens near the village site.
Currently, the site is maintained as the Yayoi Village/Ankokuji Village Ruins Park, with reconstructions of ancient buildings and a museum. The site is approximately 25-minutes by car from Oita Airport.
# John Byrne (businessman)

John Byrne (1919 - October 2013) was an Irish property developer and businessperson known for building large offices in central Dublin with his company the Carlisle Trust.

## Life and career

John Byrne was born on a small family farm near Lixnaw, County Kerry in 1919. He was the eldest of 12 children, and made money during the Emergency cutting turf and selling it door-to-door. He moved to Britain in 1941 where he earned money building and operating dance halls. Taoiseach Seán Lemass requested that Byrne return to Ireland to build offices for the growing Irish public sector in the early 1960s. He began by building more dance halls across Ireland. Many of his developments were controversial for replacing Georgian and other older buildings in central Dublin with large office buildings such as O'Connell Bridge House and D'Olier House. In the 2000s, Byrne was still leasing offices to the Irish government, and earning more than €5.7 million.
Along with fellow property developers P. V. Doyle and Matt Gallagher, Byrne employed Desmond Fitzgerald as an architect, Des Traynor as his accountant, and Christopher Gore-Grimes as his solicitor. Byrne was a close friend of Matt Gallagher, and following Gallagher's sudden death in 1974 Byrne mentored Gallagher's son, Patrick, when he took over his father's business.
Byrne amassed a site of over 500 acres of green-belt land in Baldoyle during the 1960s and 1970s, including a former Baldoyle racecourse. It was through the development of this land, which had previously been precluded from development, that led to links being drawn between Byrne and Charles Haughey. In May 1970, Haughey attended a meeting between senior officials of Dublin Corporation and Byrne during which the development of this land was discussed including the racecourse. In 1999 Byrne sold the racecourse to Sean Mulryan.
In 1971, Byrne established two trusts with the Guinness Mahon Cayman Trust. During the Moriarty Tribunal, Byrne claimed that he never gave Haughey "a penny in his life, or a pound" when confronted with evidence of more than £300,000 of Byrne's money being transferred to bank accounts controlled by Traynor and used by Haughey. He was also an investor in Celtic Helicopters, a company owned by Haughey's son, Ciarán. Byrne was also implicated in the Ansbacher report, having held trusts in the Cayman Islands in the scheme by Traynor. In 2011, Byrne was successful in having parts of the Ansbacher report which tied him to illegal offshore accounts overturned. He remained a customer of Ansbacher Cayman, being one of the substantial Irish resident customers of the bank.
In 2002, Byrne handed over control of his business to his wife, Ciara. Byrne died at aged 94 in 2013. His son, John Jr, succeeded him in his business the Carlisle Trust. The Carlisle Trust owns a number of Irish companies, such as Smithfield Property Development Ltd, Alstead Securities and Dublin City Estates Ltd.
# William Jesse Goad Land

William Jesse Goad Land (December 7, 1865 – August 1, 1942) was an American botanist, inventor, and professor at the University of Chicago.

## Biography

Land started taking botany classes at the University of Chicago in 1898. He earned his B.S. from the school in 1902, and his Ph.D. in 1904. He started working at the university as an assistant in morphology in 1904 and was promoted to an instructor in botany in 1908. He became assistant professor in 1911, associate professor in 1915, and a full professor in 1928. His teaching focused more heavily on laboratory studies instead of traditional lectures. He retired in 1931, but remained as an emeritus.
Land was a Fellow of the American Association for the Advancement of Science, and a member of many other academic societies. Personally, he was a life member of the National Rifle Association and organized the University of Chicago Rifle Club.
Land was also an accomplished inventor. He created formalin-aceto-alcohol and formalic-acetic-waterfixing agents for his laboratory studies. He also invented a telescopic sight mount for sniper rifles used by the U.S. Army and U.S. Navy.

## Works

* "A Morphological Study of Thuja" (Ph.D. thesis), Botanical Gazette Vol. 36 (1902).
* "Spermatogenesis and Oögenesis in Ephedra trifurca", Botanical Gazette Vol. 38 (1904).
* "Gametophytes and Embryo of Torreya" (with John Merle Coulter), Botanical Gazette Vol. 39 (1905).
* "The origin of air chambers" (with Charles Reid Barnes), Botanical Gazette Vol. 44 (1907).
* "Fertilization and Embryogeny in Ephedra trifurca," Botanical Gazette Vol. 44 (1907).
* "The origin of the cupule of Marchantia" (with Charles Reid Barnes), Botanical Gazette Vol. 46 (1908).
* "An American Lepidostrobus" (with John Merle Coulter), Botanical Gazette Vol. 51 (1911).
* "An Electrical Constant Temperature Apparatus," Botanical Gazette Vol. 52 (1911).
* "A Protocorm of Ophioglossum," Botanical Gazette Vol. 52 (1911).
# Benjamin Hope

Benjamin Hope (born 1976) is a British artist, based in London.

## Life

He grew up in Oxford, the son of the painter Jane Hope and an academic historian (two of his grandparents were also artists).
After studying Mathematics and Physics at the University of Warwick and taking Part III of the Mathematical Tripos at Cambridge University, he was awarded a PhD in theoretical nanoscience at Cambridge. He has been a competitive runner and earned four Cambridge Blues for cross-country.
Hope was invited to join the Oxford Art Society in 1999, and in 2001 his still-life Old Violin won the Oxford Times Critics' Choice at the society's Members' Exhibition. In 2002, for its 400th anniversary, the Bodleian Library commissioned a commemorative still-life.
On leaving academia in 2007, he worked as a risk analyst in the City of London in order to earn enough to start painting professionally. In 2011, he left the City to paint full-time from his studio in Blackheath, South East London.

## Work

Working mainly in oil, but also in charcoal, pastel, and pencil, his works include plein air street scenes, detailed still lifes, and impressionistic portraits. The street scenes are mainly of locations in central and south London, while he has also painted landscapes beyond the capital. John Walsh in The Independent called him "a brilliantly accomplished impressionistic painter of street scenes."
His work has been selected for a number of exhibitions, including the Royal Academy Summer Exhibition in 2013. His first solo show, Observations was staged by the JP Art Gallery in London in 2015. A joint exhibition with sculptor Ben Hooper was held at the Gallery Different in Fitzrovia in June 2017.
In 2018 he was elected to The Pastel Society and the New English Art Club.

## Awards and recognition

Hope has won a number of prizes and awards:
* Lynn Painter Stainers Prize, Runner Up (2014)
* Pintar Rapido First Prize (2014)
* Jackson's Prize, United Society of Artists Open Exhibition (2014)
* Jackson's Pastel Portrait Competition, First Prize (2016)
* New English Art Club: Mall Galleries Greetings Card Award (2016)
His work has been selected for exhibition in
* Royal Academy Summer Exhibition, 2013
* New English Art Club
* The Pastel Society
* Royal Institute of Oil Painters
* Royal Society of British Artists
* Royal Society of Portrait Painters.
# Una pequeña parte del mundo

Una pequeña parte del mundo is the second studio album by the Spanish folk rock group Amaral, released in 2000 in Spain.

## Track listing

All tracks composed by Amaral, except Nada de nada, composed by Evangelina Sobredo.
* "Subamos al cielo" (Let's go up to heaven) – 3:18
* "Cabecita loca" (Crazy little head) – 4:47
* "Como hablar" (How to talk) – 4:01
* "Los aviones no pueden volar" (The airplanes can't fly) – 4:13
* "Queda el silencio" (Silence remains) – 4:00
* "Una pequeña parte del mundo" (A small part of the world) – 3:27
* "Botas de terciopelo" (Velvet boots) – 4:05
* "Volverá la suerte" (Luck will come back) – 4:25
* "El día de año nuevo" (New Year's Day) – 3:58
* "El mundo al revés" (The world upside down) – 4:39
* "Siento que te extraño" (I feel that I miss you) – 3:36
* "Nada de nada" (Nothing at all) – 3:41
* "El final" (The end) – 1:50

## Chart performance

In 2005, Una pequeña parte del mundo peaked at #43 in Spain.

## Certifications

| Region | Certification | Certified units/sales |
| Spain (PROMUSICAE) | Gold | 50,000$^^$ |
| $^^$ Shipments figures based on certification alone. |||
# Ian Robb (footballer)

Ian Alexander Robb (born 1 June 1955) is an English former professional footballer who played as a defender in the Football League for York City, in non-League football for Frickley Athletic, Selby Town and Olympia Station, and was on the books of Liverpool without making a league appearance.
# Tianji, Funan County

Tianji (Chinese: 田集; pinyin: Tiánjí) is a town in Funan County, Anhui. As of 2020, it administers three residential neighborhoods: Tianji, Dongyue (东岳), and Sunzhai (孙寨), as well as the following nine villages:
* Zhaowu Village (赵吴村)
* Chengzhai Village (程寨村)
* Zhangji Village (张集村)
* Yangzhai Village (杨寨村)
* Renmiao Village (任庙村)
* Wangda Village (王大村)
* Panglao Village (庞老村)
* Zhaolao Village (赵老村)
* Liulin Village (柳林村)
# Hednota asterias

Hednota asterias is a moth in the family Crambidae. It was described by Edward Meyrick in 1887, after the species was found in Australia.
# Koontz House

Koontz House may refer to:
* Kinter K. Koontz House, Phoenix, Arizona
* Koontz House, Natchez, Mississippi, listed on the NRHP and more commonly known as Green Leaves
* James H. and Cynthia Koontz House, Echo, Oregon, listed on the NRHP and also known as Koontz House
# Ankola railway station

Ankola railway station is a station on Konkan Railway. It is at a distance of 529.001 km (328.7 mi) down from origin. The preceding station on the line is Harwada railway station and the next station is Gokarna Road railway station.
# John Byrne (Irish politician)

John Joseph Byrne (23 September 1878 – 29 July 1942) was an Irish politician. He was first elected to Dáil Éireann as a Cumann na nGaedheal Teachta Dála (TD) for the Dublin North constituency at the June 1927 general election. He was re-elected at the September 1927 and 1932 general elections. He lost his seat at the 1933 general election. He was an unsuccessful candidate at the 1937 general election.
# William Jesson

William Jesson (1580–1651) was an English dyer and politician who was active in local government in Coventry and sat in the House of Commons between 1640 and 1648.
Jesson was the son of Richard Jesson of Coventry and his wife Elizabeth Hill. He became a wealthy dyer of Coventry and was admitted to the council 1628, becoming mayor of Coventry in 1631 and an alderman from 1634. In 1640 Jesson purchased the Warwickshire manor of Nuthurst from Edward Trussell and it remained in the family until around 1754.
In April 1640, Jesson was elected member of parliament for Coventry in the Short Parliament. His uncle and fellow MP Simon Norton was also a dyer and together they helped defeat the aims of a Coventry weaver who petitioned Parliament against cloth from Gloucestershire being brought into the city for dyeing. Jesson was not elected immediately to the Long Parliament in November 1640 but was brought in after the death of Norton in 1641. In 1647 Jesson successfully brought in a vote in parliament to de-garrison Coventry which had been under army and committee domination in the Civil War. He was excluded in 1648 under Pride's Purge.
Jesson married Elizabeth Barker, daughter of Alderman John Barker. Their eldest son William was also MP for Coventry in 1660. Their grandson was Sir William Jesson of Burleigh Hall, Loughborough.
# Bentley's Bandbox

Bentley's Bandbox is an Australian television series which aired in 1960 on ABC. It featured Dick Bentley, John Bluthal, Diana Davidson, and Hazel Phillips, and was a variety show. Six episodes were produced, with ABC following the BBC model of having short seasons for its series.
The archival status of the series is not known, though a 1960 newspaper article confirms that telerecordings were made of the series.

## Reception

Australian Women's Weekly said of the first episode "it was slick, smooth, beautifully done, despite a couple of first-night technical blues" and complained that the series suffered from a bad time-slot.
# Drollinger

Drollinger is a surname. Notable people with the surname include:
* D'Arcy Drollinger (born 1969), American actor, producer, and nightclub owner
* Ralph Drollinger (born 1954), American basketball player and clergyman
# Zupčići

Zupčići is a suburb in the city of Goražde, Bosnia and Herzegovina.

## Demographics

According to the 2013 census, its population was 382.
Ethnicity in 2013 :
| Ethnicity | Number | Percentage |
| Bosniaks | 331 | 86.6% |
| Serbs | 46 | 12.0% |
| Croats | 1 | 0.3% |
| other/undeclared | 4 | 1.0% |
| Total | 382 | 100% |
# UFC 91

UFC 91: Couture vs. Lesnar was a mixed martial arts event held by the Ultimate Fighting Championship (UFC) on November 15, 2008, at the MGM Grand Garden Arena in Las Vegas, Nevada.

## Background

The main event featured the return of UFC Heavyweight Champion Randy Couture versus WWE's Brock Lesnar in a title bout. The decision to grant Lesnar—who was 1–1 in UFC fights at the time, and 2-1 in MMA overall—the title shot was controversial at the time. Some felt it was premature and marketing driven, while others argued the relative lack of depth in the heavyweight division at the time left no clear-cut contenders to the belt.
Matthew Riddle was forced to withdraw from his bout with Ryan Thomas due to an injury. He was replaced by Matt Brown.
Amir Sadollah withdrew from his fight against Nick Catone due to a leg infection. A replacement for Sadollah could not be found, therefore the middleweight bout was pulled from the card. A welterweight match between Dustin Hazelett and Tamdan McCrory, previously scheduled for the preliminary card, was moved to the main card.
Unlike most UFC fight cards, every bout was aired on the PPV broadcast due to the quick endings of the main card bouts.
Also future Lightweight champion Rafael dos Anjos made his UFC debut at this event.

## Results

* ↑ For the UFC Heavyweight Championship.

## Bonus awards

Fighters were awarded $60,000 bonuses.
* Fight of the Night: Aaron Riley vs. Jorge Gurgel
* Knockout of the Night: Jeremy Stephens
* Submission of the Night: Dustin Hazelett

## Purses

The total payroll for the event was $1,118,000.
Brock Lesnar: $450,000 (includes $200,000 win bonus) def. Randy Couture: $250,000
Kenny Florian: $80,000 ($40,000 win bonus) def. Joe Stevenson: $35,000
Dustin Hazelett: $28,000 ($14,000 win bonus) def. Tamdan McCrory: $10,000
Gabriel Gonzaga: $110,000 ($55,000 win bonus) def. Josh Hendricks: $8,000
Demian Maia: $40,000 ($20,000 win bonus) def. Nate Quarry: $25,000
Aaron Riley: $8,000 ($4,000 win bonus) def. Jorge Gurgel: $10,000
Jeremy Stephens: $16,000 ($8,000 win bonus) def. Rafael dos Anjos: $4,000
Mark Bocek: $18,000 ($9,000 win bonus) def. Alvin Robinson: $7,000
Matt Brown $16,000 ($8,000 win bonus) def. Ryan Thomas: $3,000
# Academy of Pharmaceutical Sciences, Pariyaram

The Academy of Pharmaceutical Sciences, Pariyaram (APSC Pariyaram) (അക്കാദമി ഓഫ് ഫാർമസ്യൂട്ടിക്കൽ സയൻസസ്, പരിയാരം) is an educational institution in Kannur district, Kerala, India that provides various pharmacy courses such as Bachelor of Pharmacy, Pharm.D and Master of Pharmacy. This institution is approved by the Pharmacy Council of India and the All India Council for Technical Education. This institution was established in 2003 under Pariyaram Medical College.
# Kodena Koppalu

Kodena Koppalu is a small village with rich agricultural lands and human resources in Malavalli taluk in Mandya district, Mysore division in Karnataka, India.in which more than 90% literacy rate. It is located 27 km east of Mandya,39 km From Mysore and 102 km from the state capital Bangalore.

## Colleges

* Bharathi PU College Kirugavalu
* Shanthi College Malavalli
* Govt degree College Maliyuru (Bannur)

## Schools

* Government higher primary school Kodena Koppalu
* GHS Kirugavalu
* Chaitra high school
* Adarsha convent
* Jnana Ganga convent
* Rotary school
* Gokula convent
* This article related to a location in Mandya district, Karnataka, India is a stub. You can help Wikipedia by expanding it.
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# Ang Mestisa

    This is about the novel by Engracio Valmonte. For the painting by Juan Luna, see Una Mestiza.
Ang Mestisa (The Mestiza) is a well-known Tagalog-language novel written by Filipino novelist Engracio L. Valmonte in 1920. Published in two parts, the novel was divided into two books entitled Ang Mestisa Unang Bahagi (The Mestiza Part One) and Ang Mestisa Ikalawang Bahagi (The Mestiza Part Two). The novel was published in Manila, Philippines by the Imprenta Ilagan y Compañia in 1921. It was printed by the Imprenta Nacional during the American period in Philippine history. Later on, the novel was adapted as a zarzuela.

## Description

The setting of the novel was the way of life in the high-levels of Philippine society. The main characters of the story are Elsa (the mestiza), Tirso Silveira (a poet and lawyer), and Teang (the female college student). The main focus of the novel is Elsa, who being a mestiza of Spanish descent, was the representation of arrogance, selfishness, and contemptuousness of the Filipino lower-class. Elsa fell in love with Tirso Silveira but Silveira fell in love with Teang, the representation of coyness or diffidence, kindness, and warmth. Elsa and Teang are opposites of one another. The love triangle, despite Elsa's plans to win Silveira’s heart, resulted in the union of Silveira and Teang. Elsa, as a consequence of her failure, succumbs to insanity.
# Béni Slimane District

Béni Slimane District is a district of Médéa Province, Algeria.
The district is further divided into 3 municipalities:
* Beni Slimane
* Sidi Errabia
* Bouskene
36°13′37″N 3°18′21″E﻿ / ﻿36.22703°N 3.30596°E﻿ / 36.22703; 3.30596
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# You Are My Flower

You Are My Flower is the first children's music album by Elizabeth Mitchell, released in 1998 by Little Bird Records.

## Track listing

* "This Little Light of Mine" — 2:07
* "You Are My Flower" — 2:46
* "John the Rabbit" — 0:57
* "One Day, Two Days, Three Days Old" — 1:56
* "Freight Train" — 2:58
* "Shoo-Fly" — 1:03
* "Little Sack of Sugar" — 1:55
* "Rock & Roll" — 1:20
* "Jingle Bells" — 1:59
* "Lovers Lane" — 2:37
* "Sylvie" — 2:43
* "Pony Boy" — 2:29
* This children's music album-related article is a stub. You can help Wikipedia by expanding it.
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# Gredice (Brčko)

Gredice (Serbian Cyrillic: Гредице) is a village in the municipality of Brčko, Bosnia and Herzegovina.

## Demographics

According to the 2013 census, its population was 1,109.
Ethnicity in 2013 :
| Ethnicity | Number | Percentage |
| Serbs | 1,046 | 94.3% |
| Croats | 55 | 5.0% |
| Bosniaks | 2 | 0.2% |
| other/undeclared | 6 | 0.5% |
| Total | 1,109 | 100% |