OpenLLM-France/wikimedia huggingface dataset:
# Molybdenum hexacarbonyl

Molybdenum hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO)$_6$. This colorless solid, like its chromium, tungsten, and seaborgium analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state.

## Structure and properties

Mo(CO)$_6$ adopts an octahedral geometry consisting of six rod-like CO ligands radiating from the central Mo atom. A recurring minor debate in some chemical circles concerns the definition of an "organometallic" compound. Usually, organometallic indicates the presence of a metal directly bonded via a M–C bond to an organic fragment, which must in turn have a C–H bond.
Like many metal carbonyls, Mo(CO)$_6$ is generally prepared by "reductive carbonylation", which involves reduction of a metal halide with under an atmosphere of carbon monoxide. As described in a 2023 survey of methods "most cost-effective routes for the synthesis of group 6 hexacarbonyls are based on the reduction of the metal chlorides (CrCl$_3$, MoCl$_5$ or WCl$_6$) with magnesium, zinc or aluminium powders... under CO pressures".

## Occurrence

Mo(CO)$_6$ has been detected in landfills and sewage plants, the reducing, anaerobic environment being conducive to formation of Mo(CO)$_6$.

## Inorganic and organometallic research

Molybdenum hexacarbonyl is a popular reagent in academic research.
One or more CO ligands can be displaced by other ligands. Mo(CO)$_6$, [Mo(CO)$_3$(MeCN)$_3$], and related derivatives are employed as catalysts in organic synthesis for example, alkyne metathesis and the Pauson–Khand reaction.
Mo(CO)$_6$ reacts with 2,2′-bipyridine to afford Mo(CO)$_4$(bipy). UV-photolysis of a THF solution of Mo(CO)$_6$ gives Mo(CO)$_5$(THF).

### [Mo(CO)$_4$(piperidine)$_2$]

The thermal reaction of Mo(CO)$_6$ with piperidine affords Mo(CO)$_4$(piperidine)$_2$. The two piperidine ligands in this yellow-colored compound are labile, which allows other ligands to be introduced under mild conditions. For instance, the reaction of [Mo(CO)$_4$(piperidine)$_2$] with triphenyl phosphine in boiling dichloromethane (b.p. ca. 40 °C) gives cis-[Mo(CO)$_4$(PPh$_3$)$_2$]. This cis- complex isomerizes in toluene to trans-[Mo(CO)$_4$(PPh$_3$)$_2$].

### [Mo(CO)$_3$(MeCN)$_3$]

Mo(CO)$_6$ also can be converted to its tris(acetonitrile) derivative. The compound serves as a source of "Mo(CO)$_3$". For instance treatment with allyl chloride gives [MoCl(allyl)(CO)$_2$(MeCN)$_2$], whereas treatment with KTp and sodium cyclopentadienide gives [MoTp(CO)$_3$]$^−$ and [MoCp(CO)$_3$]$^−$ anions, respectively. These anions react with a variety of electrophiles. A related source of Mo(CO)$_3$ is cycloheptatrienemolybdenum tricarbonyl.

### Source of Mo atoms

Molybdenum hexacarbonyl is widely used in electron beam-induced deposition technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms.

## Safety and handling

Like all metal carbonyls, Mo(CO)$_6$ is a dangerous source of volatile metal as well as CO.
# Monkton, Ontario

Monkton is a village in Perth County, Ontario, Canada, located at the intersection of County Roads 55 and 23. The community is west of Milverton and southwest of Listowel.
It is part of the Municipality of North Perth.
The village is home to the Monkton Wildcats, a Senior Hockey Club of the Western Ontario Athletic Association.
The village is situated partly in Logan but largely in Elma.

## History

Monkton originated with the construction of the Logan gravel road. In 1857 Mr. T. M. Daly, a contractor on the highway, erected the first building in the new settlement, a blacksmith shop located on 47 Maddison st east. Once the gravel road was completed, a stage route was opened from Mitchell to Newry to carry passengers and provide a mail service between the two communities.
Two hotels were built to accommodate travelers, one in Logan, the other in Elma, and a third hotel was built in 1883.
In the same period, Mr. Winstanley obtained a grant of 1,000 acres to aid in the establishment of a sawmill. About 1878 William Machan purchased Edward Winstanley's sawmill in Monkton. Mr. Machan had previously operated a sawmill at Carmunnock. He operated "West Monckton Mills" which was advertised as a "manufacturer and dealer in all kinds of lumber, lath, shingles, and cedar posts." Schade Street was named for the Schade family who owned the farm on which the street was built. James McKenzie opened a post office.
Early settler families included the Machan, Schade, Dobbs, Stewarts, Holmans, Golightlys, Larkins, McKenzies, Merryfields and Reices.
A school was built after the number of families in the village grew. In 1870, a second school was erected and replaced in 1888 by a new building, which served as the local school for many years.
At an early period, Monkton had a match factory, two saw mills, planing mill, shingle mill, tannery and several business houses.

## Religion

In the mid-nineteenth century, pioneer ministers established a Christian church in the village. The local mercantile store, which was operated by Mr. Dunsmore, served as the first church building.
Today there are three churches in Monkton, all within mainline, Protestant denominations: Redeemer Lutheran, Knox Presbyterian and Monkton United Church of Canada.

## Today

Monkton continues to be a thriving village that includes a postal service, community library, recreation centre, several churches and a number of other business establishments.
Monkton is home of the Monkton Wildcats, a club within the Senior AA Hockey League which is part of Western Ontario Athletic Association. Also, Monkton is home to the paralympic hockey player Corbyn Smith. He is known for earning a silver medal in para ice hockey at the 2018 Winter Paralympics.
# Moment in Peking (disambiguation)

Moment in Peking is a 1939 English-language novel written by Lin Yutang.
Moment in Peking may also refer to the following adaptations of the novel:
* Moment in Peking (1988 TV series), a Taiwanese series
* Moment in Peking (2005 TV series), a Chinese series
* Moment in Peking (2014 TV series), a Chinese series
# Moment in the Sun

Moment in the Sun may refer to:
* "Moment in the Sun" (The Living End song), 2008
* Moment in the Sun (EP), an EP by Clem Snide, or the title track
# Money the Mistress

Money the Mistress is a 1726 comedy play by the Irish writer Thomas Southerne. It was his final play.
Staged by John Rich at the Lincoln's Inn Fields Theatre, the cast included James Quin as Warcourt, Lacy Ryan as Mourville, Thomas Walker as Marsan, Richard Diggs as Governor of Tangier, William Milward as Wingrave, Anthony Boheme as Don Manuel, John Hippisley as Davila, Jane Rogers as Harriet and Elizabeth Younger as Mariana.
# Monty Python's Flying Circus (disambiguation)

Monty Python's Flying Circus is a British comedy sketch television series originally broadcast by the BBC between 1969 and 1974.
Monty Python's Flying Circus may also refer to:
* Monty Python's Flying Circus (album), a 1970 comedy album
* Monty Python's Flying Circus: The Computer Game (also known as Monty Python's Flying Circus), a 1990 computer game
# Moonrise (Wolfson book)

Moonrise (full title: Moonrise; One Family, Genetic Identity, And Muscular Dystrophy) is a 2003 book written by Penny Wolfson. The full name refers to her family and her son, Ansel, who struggled throughout life with Duchenne muscular dystrophy. The book was based on an article the author wrote for The Atlantic in 2001, which received a national magazine award.

## Plot

As Ansel progresses in life, he gets weaker, and begins to use a wheelchair, but stays much fitter than most with Duchenne. He later goes to Columbia University. After 23 years of living with this disability, Ansel died at age 38 from congestive heart failure, 20 years longer than predicted at the time of his diagnosis.
# Moonrise (disambiguation)

Moonrise is the first appearance of the Moon over the Earth's eastern horizon.
Moonrise may also refer to:

## Books

* Moonrise (novel), 2005 novel in the Warriors: The New Prophecy series by Erin Hunter
* Moonrise (Wolfson book), a 2003 nonfiction book by Penny Wolfson about her son, who has muscular dystrophy
* Moonrise, a 1996 Grand Tour novel by Ben Bova
* Moonrise, a Phantom Stallion novel by Terri Farley
* Moonrise, a 2004 Snowfall Trilogy novel by Mitchell Smith
* Moonrise, a 1996 novel by Anne Stuart

## Music

* Moonrise (festival), an annual electronic dance music festival in Baltimore, Maryland, US
* Moonrise (Dadawa album) or the title song, 2013
* Moonrise (Day6 album), 2017
* Moonrise (Loona album), 2008
* "Moonrise", a song by Lynsey de Paul from Taste Me... Don't Waste Me, 1974
* "Moonrise", a song by Paul McCartney from Ocean's Kingdom, 2011
* "Moonrise", a song by Guru Randhawa from Man of the Moon, 2022
* Moonrise (Granger Smith album)

## Other uses

* MoonRise, a proposed NASA robotic mission to the south pole of the Moon
* Moonrise, Hernandez, New Mexico, a 1941 Ansel Adams photograph
* Moonrise (Stanisław Masłowski), an 1884 painting by Stanisław Masłowski
* Moonrise (film), a 1948 film noir crime film adapted from the 1946 novel by Theodore Strauss
# Monsters of Ecatepec

The "Monsters of Ecatepec" is the name given to a serial killing couple Juan Carlos Hernández(1985, Lázaro Cárdenas, Michoacán) and Patricia Martínez (1980, Lázaro Cárdenas, Michoacán). The case also received the names of "The House of Horror" or "The Butchers of Ecatepec". Active in Ecatepec de Morelos, State of Mexico, from 2012 to 2018, the pair are suspected to have committed between 10 and 20 murders, and have also confessed to cannibalizing the bodies of their victims. The pair were apprehended on October 4, 2018, when transporting human remains in a baby stroller.

## Background

They were both born in Lázaro Cárdenas, Michoacán, within a five-year age gap. Juan Carlos' mother was a single mother, who allegedly often dressed him as a girl, brought men to her house and forced her son to watch her sexual encounters. Also, he declared that in his childhood, he suffered sexual abuse by another woman who at the time was his caretaker. When he was 10 years old, he fell from the stairs and suffered a severe traumatic brain injury. Patricia Martínez was born to a poor family, and was manipulative. She was diagnosed with a borderline intelligence disorder linked to intellectual disability. She was a prostitute at the time.
The couple met in 2008, when Patricia worked as waitress at a restaurant, of which Juan Carlos was a regular client. They initiated a relationship and, although he bragged to be an "assassin", she decided to move with him. The couple had four children during their 10-year relationship. They opened a family business where they sold clothing, perfume and cell phones.

## Crimes

Their first victim, according to Patricia's declaration, was a 22-year-old woman who Juan Carlos lured with job promises. In their house, Hernández led her to their bathroom where he raped, beheaded and dismembered her. Martínez kept their children outside the house while the murder occurred. After the murder, Martínez partially cooked the body and ate it with her husband. Their second victim was a teen girl who lived next to them, who suffered an inhalants addiction; they allegedly lured her with promises of wealth. Like the first victim she was also raped, beheaded and dismembered in their bathroom. Patricia cooked the victim's body in oil and salt.
# Monsters from Mars

Monsters from Mars is an underground rock band from California, formed in 2001. Originally an instrumental surf rock trio, the band has since grown in size and influences. Stylistically, the band's current sound incorporates elements of surf rock, garage rock, horror, progressive rock, new wave, experimental electronic music, punk rock, and new trends in underground music. Sonically, the band's sound comes from its heavy use of spring reverb, tremolo-picked guitar leads, tube equipment, Farfisa organ, synthesizers, baritone guitar, theremin, tape delay effects, and occasional saxophone and prog rock drum solo. The band's live show is distinguished by its high energy performances, use of theatrics, fog and colored light ambiance, and proclivity for inducing dancing among audience members.
Monsters from Mars is perhaps best known for its instrumental rendition of the Britney Spears hit, Toxic. Also notable are its connections to the character, Bob Stencil.

## Discography
### Full-Lengths

* Play Some Originals and Some Surf Guitar Classics and Obscurities (Tired Machine, 2002)
* 2004: A Space Odyssey (Tired Machine, 2004)

### Singles

* Surfing Through A Creepy Castle 7" (Tic Tac Totally, 2006)
# Myung Ji-yun

Myung Ji-yun (명지연, born 1975) is a South Korean actress.

## Television

* 2018: The Undateables
* 2018: Misty
* 2014: Everybody Say Kimchi - Im Soo-jin
* 2010: Athena: Goddess of War - Hong Soo-jin
* 2009: Iris - Hong Soo-jin
* 2005: Coma - Kang Soo-jin
* 2003: Scent of Love - Heo Mi-jeong
* 1997: There's a Bluebird - Joon-mi

## Films

* 2010: Iris: The Movie - Hong Soo-jin
* 2005: 틈 (Aperture) - Kang Soo-jin
* 2005: 생일파티 (Birthday Party) - Chul-yeon
* 2003: Too Beautiful to Lie - Hwa-sook
* 2002: 하얀 방 (White Room) - Yoo-sil, In-mi
* 2001: 휴머니스트 (The Humanist) - Sister Rosa
* 2000: 실제상황 (Real Fiction) - flower shop owner
* 1999: 장롱 (Wardrobe) - Chul-yeon
* 1999: 심판 (Judgment) - Chul-yeon
* 1998: 아름다운 시절 (Spring in My Hometown) - Young-sook
* 1997: 바리케이드 (Barricade) - Bhutto
# Olevano sul Tusciano

Olevano sul Tusciano is a town and comune in the province of Salerno in the Campania region of south-western Italy.

## Main sights

* Roman villa of S. Maria a Corte
* Castrum Olibani, a Lombard castle. During the rule of Frederick of Hohenstaufen in southern Italy, it was a seat of Hermann von Salza
* Pope gardens in Salitto
* St. Vincenzo prison
* Convent of Santa Maria di Costantinopoli, a Dominican 16th century building
* Curtis di Santa Maria a Corte
* Church of S. Maria a Corte (1600)
* Church of San Leone Magno (1700)
* Church of Santa Lucia (1700)
* Coven of Santa Regina in Monticello village (1470)
* Chapel of Santa Maria delle Grazie in Monticelli (1746)
* Coven of San Giacomo in Ariano (1400)
* Chapel of San Rocco (remains) near Tusciano river.
* Chapel of Madonna della Neve (1500).
* Coven of Santa Maria del Soccorso in Salitto (1515).
* Chapel of Maria Santissima del Rosario in Salitto (968).
* Chapel of Madonna delle Grazie in Salitto (1500).
* Grotta di Nardantuono: part of St. Michael's cave. Legend has it that the cave was the shelter of Nardantuono bands of brigands led by Antonio di Nardo, the robber Nardantuono century.

## Twin towns

* Wilmington, United States
# Maybe (Carmada song)

"Maybe" is a song recorded by Australian group Carmada and released in October 2014 as the group's debut and lead single from their debut extedend play Realise (2014). Remixes were released in April 2015. The song was certified gold in Australia in 2015.

## Video

The video was released on 28 October 2014. It was filmed along Venice Beach in Los Angeles and shows a young woman on a bike messing everybody's things up.

## Certification

| Region | Certification | Certified units/sales |
| Australia (ARIA) | Gold | 35,000$^^$ |
| $^^$ Shipments figures based on certification alone. |||
# Duvall Farm

The Duvall Farm was a historic farm located in North Laurel, Howard County, Maryland, United States, now the site of Coastal Sunbelt Produce.

## History

The Duvall Farm was a historic farm worked by descendants of one of Maryland's earliest settlers, Mareen Duvall (1625–1699). The farm was situated on Whiskey Bottom Road, a historic path that once linked Mareen Duvall's Davidsonville plantation to other family plantations formed as settlers moved westward. Simon J. Martenet's 1860 Map of Howard County Maryland shows the farm along the crossroads of Route One, where George Washington once travelled. Robert L. Duvall and his wife Margret owned the property against the B&O tracks giving it the name "Elm Ridge". The site was the low point where barrels of Maryland Rye Whiskey would be delivered from nearby distilleries to load on trains, giving it the name "Whiskey Bottom". In 1914, a freight train struck the barn co-owned by Dr. Warfield and Duvall containing 6,000 pounds (2,700 kg) of tobacco.
In 1991, a Laurel man was charged with killing and setting his girlfriend Cathy May Baier on fire next to the race track, which resulted in a brush fire.
In April 2013 the Duvall Farm was burned from large brush fires that were considered connected to arson on the Laurel Fuel and Oil Company. Fire investigators ordered the house demolished rather than stabilize the historic structure.
The farm was adjacent to historic Laurel Park race track and rezoned for high density "transit-oriented development" under growth policies of Parris Glendening. The agricultural farm was rezoned in anticipation of an unfunded rail stop adjacent to the already existing stop servicing Laurel Park requested by Howard County Executive Kenneth Ulman, whose father was on the Maryland Racing Commission.
In 2014, Ulman provided a "development fast track" to relocate Coastal Sunbelt's facilities from Savage, Maryland. The Transit Oriented Development zoning was rapidly amended to include light industrial uses in January 2014. Since spot zoning for the benefit of a single entity is illegal, the zoning law also included a provision to expedite former planning and zoning director's Joseph Rutter's housing development project around the Rosa Bonheur Memorial Park Cemetery. Ulman was quoted in a newspaper saying "I think this was the fastest rezoning in Howard County history, because this about job creation. We had to get it done". Coastal Sunbelt Produce was offered $1 million in loans and $150,000 in Howard County tax credits to relocate to a 240,000-square-foot (22,000 m$^2$) Preston Scheffenacker Properties facility built on the Duvall Farm with a 99-year lease. The new facility covering the majority of the 33-acre site had a groundbreaking on August 18 with Lieutenant Governor Anthony Brown attending. The 900-employee Coastal Sunbelt operation said it would add 400 new jobs to meet the terms of its state loan.
# 2003 Big Ten Conference football season

The 2003 Big Ten Conference football season was the 108th season for the Big Ten Conference. Michigan won the conference, finishing ahead of Ohio State and Purdue.

## Bowl games

| Date | Bowl Game | Big Ten Team | Opp. Team | Score |
| Dec. 26, 2003 | Motor City Bowl | Northwestern | Bowling Green | 28-24 |
| Dec. 29, 2003 | Alamo Bowl | Michigan State | Nebraska | 17-3 |
| Dec. 31, 2003 | Music City Bowl | Wisconsin | Auburn | 28-14 |
| Dec. 31, 2003 | Sun Bowl | Minnesota | Oregon | 31-30 |
| Jan. 1, 2004 | Outback Bowl | Iowa | Florida | 37-17 |
| Jan. 1, 2004 | Capital One Bowl | Purdue | Georgia | 34-27 (OT) |
| Jan. 1, 2004 | Rose Bowl | Michigan | USC | 28-14 |
| Jan. 2, 2004 | Fiesta Bowl | Ohio State | Kansas State | 35-28 |
# 2003–04 FC Bihor Oradea (1958) season

The 2003–04 season was Bihor Oradea's 45th season in the Romanian football league system, and their 18th season in the Divizia A. At the end of the season the team finished on 16th place and relegated back to Divizia B, after only one season in the top flight of the Romanian football. During this season the club was known as FC Oradea.

## First team squad

Note: Flags indicate national team as defined under FIFA eligibility rules. Players may hold more than one non-FIFA nationality.
| No. | Pos. | Nation | Player |
| 1 | GK | ROU | Gabriel Rotaru (Vice-Captain) |
| 2 | DF | ROU | Nicolae Stanciu |
| 3 | DF | ROU | Alin Zaha |
| 4 | DF | ROU | Ciprian Dianu (Vice-Captain) |
| 5 | DF | ROU | Aurel Amzucu |
| 6 | MF | ROU | Mihai Lungan |
| 7 | DF | ROU | Dorin Mihuț |
| 8 | MF | ROU | Ion Dumitra (Captain) |
| 9 | FW | ROU | Daniel Lupașcu |
| 9 | FW | ROU | Daniel Stan |
| 10 | MF | ROU | Leonard Naidin (Vice-Captain) |
| 10 | FW | MKD | Jurica Siljanoski |
| 11 | MF | ROU | Ramses Gado |
| 12 | GK | SCG | Dušan Brojcin |
| 12 | GK | ROU | Marius Mârne |
| 13 | MF | ROU | Vasile Georgiu |
| No. | Pos. | Nation | Player |
| 14 | DF | ROU | Cristian Munteanu |
| 15 | MF | ROU | Sebastian Sfârlea |
| 16 | MF | ROU | Radu Mărginean |
| 17 | DF | SCG | Aleksandar Stefanović |
| 18 | MF | ROU | Sándor Fele |
| 19 | DF | ROU | Florin Lazăr |
| 20 | MF | ROU | Alin Coțan |
| 20 | FW | BIH | Aleksandar Obrenović |
| 21 | MF | ROU | Răzvan Frițea |
| 22 | GK | ROU | Cosmin Vâtcă |
| 23 | FW | ROU | Bogdan Vrăjitoarea (Vice-Captain) |
| 24 | FW | ROU | Claudiu Keșerü |
| 25 | FW | ROU | Cristian Cigan |
| 25 | MF | ROU | Mihai Nicolae |
| 25 | FW | ROU | Marius Siminic |

## Competitions
### Divizia A

| Pos | Teamvte | Pld | W | D | L | GF | GA | GD | Pts | Qualification or relegation |
| 12 | Gloria Bistrița | 30 | 9 | 8 | 13 | 36 | 48 | −12 | 35 | Qualification to Intertoto Cup first round |
| 13 | FCM Bacău | 30 | 7 | 10 | 13 | 29 | 43 | −14 | 31 | |
| 14 | Ceahlăul Piatra Neamț (R) | 30 | 7 | 9 | 14 | 34 | 50 | −16 | 30 | Relegation to Divizia B |
| 15 | Petrolul Ploiești (R) | 30 | 6 | 9 | 15 | 38 | 55 | −17 | 27 | Relegation to Divizia B |
| 16 | FC Oradea (R) | 30 | 6 | 6 | 18 | 38 | 50 | −12 | 24 | Relegation to Divizia B |

#### Result round by round

| Round | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 |
| Ground | H | A | H | A | H | A | H | A | A | H | A | H | A | H | A | A | H | A | H | A | H | A | H | H | A | H | A | H | A | H |
| Result | D | L | D | L | L | W | W | L | L | D | L | W | L | W | L | L | L | D | L | L | W | L | L | L | W | D | L | L | L | D |
| Position | 7 | 13 | 15 | 16 | 16 | 14 | 10 | 12 | 14 | 16 | 16 | 15 | 16 | 11 | 14 | 15 | 16 | 16 | 16 | 16 | 15 | 16 | 16 | 16 | 16 | 16 | 16 | 16 | 16 | 16 |
# Pascal Kalemba

Pascal Lukoki Kalemba (26 February 1979 – 27 November 2012) was a Congolese footballer who played as a goalkeeper.

## Career

Born in Kinshasa, Kalemba played club football in the DR Congo and Gabon for TP Mazembe, AS Vita Club, Delta Téléstar, DC Motema Pembe and Missile FC.
He earned 25 caps for the national team between 2001 and 2006, representing them at the African Cup of Nations in 2002 and 2006. He also played in nine FIFA World Cup qualifying matches.

## Later life and death

He died on 27 November 2012.
# 2003 in Belize

Events in the year 2003 in Belize.

## Incumbents

* Monarch: Elizabeth II
* Governor-General: Colville Young
* Prime Minister: Said Musa

## Events

* 2003 Belizean general election
* 2003 Belizean municipal elections
* Speednet formed
* Tour of Belize February
* We the People Reform Movement