OpenLLM-France/wikimedia huggingface dataset:
# Carbene radical

Carbene radicals are a special class of organometallic carbenes. The carbene radical can be formed by one-electron reduction of Fischer-type carbenes using an external reducing agent, or directly upon carbene formation at an open-shell transition metal complex (in particular low-spin cobalt(II) complexes) using diazo compounds and related carbene precursors. Cobalt(III)-carbene radicals have found catalytic applications in cyclopropanation reactions, as well as in a variety of other catalytic radical-type ring-closing reactions.
Theoretical calculations and EPR studies confirmed their radical-type behaviour and explained the bonding interactions underlying the stability of the carbene radical. Stable carbene radicals of other metals are known, but the catalytically relevant cobalt(III)-carbene radicals have thus far only been synthesized as long-lived reactive intermediates.

## Bonding interactions and radical reactivity

The chemical bond present in carbene radicals is surprising in that it possesses aspects of both Fischer and Schrock type carbenes. As a result, the cobalt carbene radical complexes have discrete radical-character at their carbon atom, thus giving rise to interesting catalytic radical-type reaction pathways.
The mechanism of formation of a carbene radical at cobalt(II) typically involves carbene generation at the metal with simultaneous intramolecular electron transfer from the metal into the metal-carbene π* anti-bonding molecular orbital constructed from the metal d-orbital and the carbene p-orbital. As such, carbene radicals are perhaps best described as 'one-electron reduced Fischer-type carbenes'.
Discrete electron transfer from a sigma-type metal d-orbital (typically the d$_{z2}$ orbital) occurs, leads the typical radical character of the carbene carbon. This behaviour not only explains the carbon-centered radical-type reactivity of these complexes, but also their reduced electrophilicity (suppressing carbene-carbene dimerisation side reactions) as well as their enhanced reactivity to electron-deficient substrates. Furthermore, second coordination sphere hydrogen-bonding interactions give rise to faster reactions because H-bonds are stronger to the reduced carbene as compared to the precursor. Such H-bonding interactions can also facilitate chirality transfer in enantioselective carbene-transfer reactions.
In order for the σ bond to be stabilized (typically with a bond order slightly less than 1), a back-bonding action from the π molecular orbital to the anti-bonding π* molecular orbital is necessary and the porphyrin ring serves as an electron π-symmetry "buffer" to ensure this interaction is obtained.
The back-donation to the π* orbital would result in unfavorable excess electron density on the carbene carbon but the presence of adjacent functional groups (carbonyl or sulfonyl groups have the desired electronegativity) relieve this electron build-up and yield the final radical electron, which occupies a single p atomic orbital state on the carbon.
# John of Canterbury

John of Canterbury (died 1204) was Bishop of Poitiers 1162 to 1181 and subsequently Archbishop of Lyon 1181 to 1193. He became a "cosmopolitan and much-respected churchman".
He began as a clerk to Theobald of Canterbury. He became Treasurer of York in 1152. At the wish of Henry II of England, he was made Bishop of Poitiers, and consecrated at the Council of Tours in 1163. He was a close supporter of Thomas Becket in his quarrel with Henry II.
Though John was elected Archbishop of Narbonne, he did not take up that see since the election was superseded by his being elected to Lyon, which he accepted. At Lyon, he banned preaching by the Waldensians.
John later resigned the see of Lyon to become a monk at the Cistercian Clairvaux Abbey, where he lived out the rest of his life. In his retirement, he received an important papal letter, Cum Marthae circa, dated 29 November 1202.
# 1957 Indian general election in Andhra Pradesh

The 1957 Indian general election polls were held in the Andhra Pradesh state for its 43 seats. The state was formed then recently in 1956 by combining the erstwhile Andhra state and Telugu-speaking areas of Hyderabad State. Indian National Congress has swept the elections by bagging 37 seats.
# Muir Pass

Muir Pass is a mountain pass in the Sierra Nevada of California, United States, in Kings Canyon National Park. It is named for John Muir.
The pass is near the midway point of the John Muir Trail and around mile 841 of the Pacific Crest Trail. It crosses the Goddard Divide between Mount Solomons and Mount Warlow, at an elevation of 11,955 feet (3,644 m). The Muir Hut, built by the Sierra Club, is at the summit of the pass. Although the grade is gentle from both directions, snow can persist well into the summer, obscuring the trail for miles.
* View of Mount McGee, Lake McDermand and Wanda Lake, ascending the pass
* The Muir Hut
* Commemorative on the Hut
* Inside the hut
# Kirkburn, Scottish Borders

Kirkburn is a village on the B7062, close to Peebles and the River Tweed, in the Scottish Borders area of Scotland, at the edge of the Cardrona Forest.
Other places in the vicinity are Glen Ho, Glentress, Horsburgh Castle, Innerleithen, Kailzie, Kailzie Gardens, Kirkhope Law, Neidpath Castle and Nether Horsbrugh.
# James Garvey (footballer)

James Patrick Garvey (Q1 1878 – after 1905) was an English professional footballer who played as a goalkeeper.

## Career

Born in Hulme, Garvey began his career with Wigan County in the Lancashire League. He joined Newton Heath in May 1900 as a replacement for Scotland international goalkeeper Frank Barrett, who had moved to New Brighton Tower. He made his Football League debut in the opening game of the 1900–01 season away to Glossop; he conceded just one goal, but Newton Heath were unable to score themselves and they lost 1–0. Garvey kept a clean sheet in Newton Heath's next game, a 4–0 home win over Middlesbrough, but was replaced for the next game by Jimmy Whitehouse, newly signed from Grimsby Town. He only made four more appearances before the end of the season, one of these coming as a result of Whitehouse's selection as an emergency forward against Walsall. He spent most of the rest of the season in the club's reserve team; one notable appearance in December 1900 saw him save a penalty as Newton Heath – whose team consisted of just nine men – held Glossop to a 1–1 draw.
Having failed to establish himself in the Newton Heath first team, he left the club for non-league Middleton in June 1901. After a spell with Stalybridge Rovers, he joined Southport Central ahead of the 1902–03 season. In December 1902, he returned to Newton Heath (now known as Manchester United) with Southport when they were drawn together in the third qualifying round of the 1902–03 FA Cup; although Manchester United won 4–1, Garvey had a good game, saving a penalty from Jack Peddie to keep the score relatively respectable. In March 1904, he was part of the Southport team that reached the final of the Lancashire Senior Cup, where they lost 2–0 to Blackburn Rovers at Deepdale in Preston.
He returned to the Football League with Bradford City in February 1905. He made 22 league appearances for Bradford before suffering a career-ending injury in a game against Stockport County in November 1905.
# James H. Weaver

James H. Weaver may refer to:
* Jim Weaver (Oregon politician) (1927–2020), U.S. congressman from Oregon
* James H. Weaver (Alabama politician), Secretary of State of Alabama, 1856–1860
* James Henry Weaver (1883–1942), American mathematician
# James H. Watson

James H. Watson (c. 1845 – December 29, 1908) was an English-born merchant and political figure in Newfoundland. He represented Trinity Bay in the Newfoundland and Labrador House of Assembly from 1874 to 1882 and from 1893 to 1894.
He was born in Torquay and came to Newfoundland in 1869 where he entered business with his brother Ellis at Hant's Harbour. He was defeated when he ran for reelection in 1882. Watson set up business at L'Anse-au-Loup in 1890. He served as assistant clerk for the assembly from 1892 to 1893. He was elected again in 1893 and unseated by petition in 1894. In 1894, Watson was named a customs inspector at St. John's. He returned to England in 1904 and later died at Torquay in 1908.
# Mike Fraser (rugby union)

Mike Fraser (born 4 November 1980) is a New Zealand Rugby Union elite referee.
Fraser has been a member of the NZRU referee panel since 2007, and is recognised by World Rugby as an international referee. He made his refereeing debut during the 2013 end-of-year rugby union internationals, where he refereed Georgia vs the United States in Rustavi. He later refereed Wales' clash with Tonga in Cardiff. Before then, he was part of the referee panel for the 2013 IRB Junior World Championship, where he refereed the final between Wales and England, and has refereed in five World Rugby Sevens Series tournaments.
He annually represents the NZRU in the Super Rugby competition and the Wellington Rugby Football Union in the ITM Cup.
He is one of seven designated Assistant referees for the 2015 Rugby World Cup.
# James Victor

Jim or James Victor may refer to:
* James Conway Victor (1792–1864), British Army major general
* James Victor (actor) (1939–2016), Dominican-born American actor
* Jim Victor (1946–2018), American racecar driver (List of driver deaths in motorsport)
* James Victor (cycling) (born 1962), Australian cycling coach
# James Macharia

James Macharia may refer to:
* James Mwangi Macharia (born 1984), Kenyan road running athlete
* James Wainaina Macharia (born 1959), Kenyan accountant and Cabinet Secretary for Health
# James Satloff

James Satloff (born 1962) is an American businessman. He founded Liberty Skis and served as the CEO of C.E. Unterberg, Towbin.

## Education

James Satloff has an MBA from Columbia Business School and a BA from Columbia College, where he majored in computer science and artificial intelligence with a concentration in humanities and French.

## Biography

Satloff is a founder of Liberty Skis, a Colorado-based snow ski manufacturer; the Executive Chairman of InvestorForce, Inc; and a director of Larkspur & Hawk, a New York City-based jewelry manufacturer.
Prior positions include chief executive officer of Inform Technologies LLC from May 24, 2007, to May 2009, and chief executive officer and president of C.E. Unterberg, Towbin. From 1996 through 2004, he served as an executive managing director of Standard & Poor's Investment Services, president of its Compustat division, and president of its broker/dealer, Standard & Poor's Securities, Inc. Additionally, he has held positions at Bankers Trust Company, Salomon Brothers, and Touche Ross & Co.; and he co-founded Fusion Management Consulting with Eric Mendelsohn. Satloff previously served as a vice president of Bankers Trust Company and vice president of Salomon Brothers. He has been the executive chairman of InvestorForce, Inc. since May 2010.
While at C.E. Unterberg, Towbin, Satloff testified before Congress about the impact of the Sarbanes-Oxley Act of 2002 on small businesses, three years after its passage into law. He further commented on new Securities and Exchange Commission rules concerning so-called well-known seasoned issuers, and the rules' effect on small companies seeking access to the public markets.
James Satloff holds a number of US patents for technological innovation, including ones for a simplified computer keyboard, a system for using trading cards interactively, and a portable computer desk with power generator.

## Personal life and family

Satloff is the son of Aaron Satloff, a professor of psychology at the University of Rochester. He is married to Emily Unterberg Satloff, with whom he has two sons, including Dustin Satloff. He resides in New York City. His father-in-law, Thomas I. Unterberg, was the chairman of the investment bank L.F. Rothschild.
# James Wetzel

James Wetzel is Chair of Saint Augustine, Professor of Philosophy, and Director of the Augustinian Institute at Villanova University. He obtained his doctorate from Columbia University.

## Works

* Wetzel, James (1992). Augustine and the Limits of Virtue. Cambridge: Cambridge University Press. ISBN 978-0-521-40541-6.
* Wetzel, James (2010). Augustine: A Guide for the Perplexed. A&C Black. ISBN 978-1-84706-196-6.
* Wetzel, James (2012). Augustine's City of God: A Critical Guide. Cambridge University Press. ISBN 978-1-139-57644-4.
* Wetzel, James (2013). Parting Knowledge: Essays after Augustine. Wipf and Stock Publishers. ISBN 978-1-62189-787-3.
# 2018–19 Saint Kitts and Nevis National Cup

This tournament started on 26 February 2019 with preliminary round.

## Preliminary round

Played on 26 and 28 February 2019
| Home team | Away team | Result |
| United Old Road Jets | Newton Ground Ballers | 3–0 Awarded |
| Security Forces United FC | Davis Construction Lodge Patriots FC | 3–2 |
| Mantab United | Rivers of Living Water | 3–0 |
| KFC Trinity/Challengers United FC | Caribbean Cable Bath United | 3–0 Awarded |
| Hardtimes United | Molineux FC | 6–0 |

## Round of 16

Played on 19 and 21 March 2019
| Home team | Away team | Result |
| St. Paul's United | Sandy Point FC | 2–1 |
| Conaree FC | Mantab United | 1–0 |
| Cayon Rockets | Security Forces United FC | 3–0 |
| Saddlers United | United Old Road Jets | 4–2 |
| Garden Hotspurs | KFC Trinity/Challengers United FC | 2–1 |
| Newtown United | Hardtimes United | 3–0 |
| Village Superstars | Trafalgar Southstars | 2–0 |
| Dieppe Bay Eagles FC | St. Peters Strikers | 2–7 |

## Quarterfinals

Played on 29, 30 and 31 March 2019
| Home team | Away team | Result |
| Cayon Rockets | St. Peters Strikers | 2–2 (5–4 p) |
| Conaree FC | St. Paul's United | 2–2 (6–5 p) |
| Village Superstars | Saddlers United | 4–1 |
| Newtown United | Garden Hotspurs | 4–0 |

## Top goalscorers

In bold, players that continue active in the competition.
| Rank | Player | Club | Goals |
| 1 | Niquan Phipps | Saddlers United | 3 |
| 2 | Dionis Stephens | St. Peters Strikers | 3 |
| 3 | Denroy Matthew | Saddlers United | 2 |
| 4 | Orlando Mitchum | Newtown United | 2 |
| 5 | Chevaun Walwyn | Hardtimes United | 2 |
| 6 | Vinceroy Nelson | Cayon Rockets | 2 |
| 7 | Sylvester Alexander | Mantab United | 2 |
| 8 | Kareem Harris | St. Peters Strikers | 2 |
| 9 | Joseph Wilkes | Village Superstars | 2 |
| 10 | Errol O'Loughlin | Conaree FC | 2 |
# Miller Peak

Miller Peak may refer to:
* Miller Peak (Arizona), in the Huachuca Mountains, Arizona
* Miller Peak (Explorers Range), in Explorers Range, Antarctica
* Miller Peak (Sentinel Range), in Sentinel Range, Antarctica
* Miller Peak (Montana), mountain in Missoula County, Montana
# Jan Hamřík

Jan Hamřík (born 3 December 1940) is a Czech luger. He competed at the 1964 Winter Olympics and the 1968 Winter Olympics.
# Jamesy P

Jamesy P (born James Morgan, 18 May 1970) is a Vincentian musician (and former barber) who released a soca single in 2002 titled "Nookie". Its 2005 release was a hit, reaching No. 14 on the UK Singles Chart, as well as becoming the biggest song in the Caribbean 2005 to 2006, and hitting Billboards urban charts in the United States and Canada.

## Discography
### Singles

| Title | Year | Chart positions | Chart positions | Chart positions |
| Title | Year | AUS | UK | US R&B/HH |
| "Nookie" (featuring Jabba and M.I.A.) | 2005 | 86 | 14 | 54 |
# James Neil Hollingworth

James Neil Hollingworth (1933–1996) was a beatnik, hippie, writer, paraplegic, and former manager of the psychedelic folk rock bands Quicksilver Messenger Service and the Ace of Cups. After he suffered disabling injuries in a car crash near Muir Beach, California in 1967, the management of both bands were assumed by Ron Polte.
He wrote under the pseudonym Ambrose Hollingworth Redmoon.
Larry Fink's 2014 book, The Beats, with text by Robert Cordier (1933-2020), contains numerous photos of Hollingworth from 1959.
A well-known aphorism was written by Hollingworth in 1991:
   "I find such expressions as 'peaceful warrior' offensive, trivializing, and insulting. 'Peaceful warrior' is far more than a contradiction in terms. The function of a warrior is to eliminate an exterior enemy presence. Cowardice is a serious vice. Courage is not the absence of fear, but rather the judgment that something else is more important than one's fear. The timid presume it is lack of fear that allows the brave to act when the timid do not. But to take action when one is not afraid is easy. To refrain when afraid is also easy. To take action regardless of fear is brave."
Ambrose was the founder or co-founder of the Six-Day School located high on Mount Shasta, a mountain top in Siskiyou County, California. It was a school that prepared students for survival in the midst of Armageddon through map and compass reading, survival in the wilderness, and occult studies. Students lived in tepees and worked by tending the orchards and gardens. The property was previously called Top of the World Ranch.
# James Valerio

James Valerio (born 1938) is a U.S. artist specializing in photorealist paintings. Valerio was educated at the School of the Art Institute of Chicago, receiving a BfA in 1966 and an MfA in 1968. His work is included in the collection of the Butler Institute of American Art and other museums.
# James S. Warren

James S. Warren was the director of the counter-terrorism branch of the Canadian Security Intelligence Service (CSIS) in 1985 at the time of the Air India bombing. Mel Deschenes is alternatingly referred to as having held the same position at the same time.
On July 16, 1986 he sent a letter defending CSIS from Royal Canadian Mounted Police allegations that they had been un-cooperative and negligent in tracing the suspects prior to the bombing.
He retired from CSIS in 1994, but was called to testify before the Air India Inquiry - where he stated there was "no deliberate attempt to suppress evidence" relating to the recorded audiotapes that were erased by CSIS.
# 2020 Asian-Pacific Judo Championships

The 2020 Asian-Pacific Judo Championships was a Judo event expected to take place in Ulaanbaatar, Mongolia. The championships were originally scheduled to take place from 17 to 19 April, then from 26 to 29 November, but were postponed both times due to the COVID-19 pandemic. The event was eventually cancelled.
# Jan Fredrik Vogt

Jan Fredrik Vogt (born 18 February 1974) is a Norwegian politician for the Progress Party.
He served as a deputy representative to the Norwegian Parliament from Vestfold during the term 2005–2009.
He hails from Sande, Vestfold.
# Milk Day

Milk Day may be a reference to:
* Harvard Milk Day, an unofficial celebration in Harvard, Illinois, USA
* Harvey Milk Day, a celebration of the life of Harvey Milk, a murdered gay rights activist
* World Milk Day, a United Nations organized day to celebrate the importance of milk
* National Milk Day (India), an observance of Verghese Kurien's birthday by the Indian milk industry
# Janardhan

Janardhan is one of the names of Hindu Lord Krishna.
Janardhan may also refer to:
* Bank Janardhan (born 1948), Indian actor
* Boda Janardhan (born 1958), Indian politician
* Janardhan Reddy (disambiguation), several people
* Janardhan Sharma (born 1963), Nepalese politician
* P. Janardhan Reddy (1948–2007), Indian politician
* G. Janardhana Reddy (born 1967–) Indian politician and Industrialist (Former Minister of Tourism Department and Infrastructure Development of Karnataka from 30 May 2008 to 3 August 2011)
# Jan Říha

Jan Říha (11 November 1915 – 15 December 1995) was a Czech football player. He played for Czechoslovakia, for which he played 25 matches and scored 9 goals.
He was a participant in the 1938 FIFA World Cup.
# Mimomyia hybrida

Mimomyia (Mimomyia) hybrida is a species of zoophilic mosquito belonging to the genus Mimomyia. It is found in Sri Lanka, Malaya, Singapore, Sumatra, Java, Borneo, Philippines, and Thailand.
# Jan Pňovský ze Sovince

Jan Pňovský ze Sovince was the son of Hynek Pňovský ze Sovince and Machna z Lomysnice. Before 1490 he bought the castle of Sovinec. He was a disciple of Mathias Corvinus and since 1487 was the highest Judge of the margraviate of Moravia. In 1508, he was succeeded in his lands by his sons Vok Pňovský ze Sovince and Heralt Pňovský ze Sovince.
# Min barndoms jul (Charlotte Perrelli album)

Min barndoms jul is a Charlotte Perrelli Christmas album, released on 20 November 2013. Perelli's sons Angelo and Alessio contribute to the album along with a choir consisting of 60 children.

## Track listing

* En barndomsjul
* Bjällerklang (Jingle Bells)
* Mössens julafton (Musevisa)
* Nu tändas tusen juleljus
* Hej mitt vinterland (solo by Angelo & Alessio)
* Nu står jul vid snöig port
* Jag såg mamma kyssa tomten (I Saw Mommy Kissing Santa Claus) (solo by Angelo)
* När juldagsmorgon glimmar
* Rudolf med röda mulen (Rudolph the Red-Nosed Reindeer)
* Jul, jul, strålande jul
* När det lider mot jul
* Nu är julen här igen
* Sista dagarna före jul
* Julgransplundring (bonus track)

## Charts

| Chart (2013) | Peak position |
| Sweden (Sverigetopplistan) | 49 |
# Jannuzzi

Jannuzzi is an Italian surname. Notable people with the surname include:
* Lino Jannuzzi (born 1928), Italian journalist and politician
* Luigi Jannuzzi (born 1952), American comedic playwright
* Michele Jannuzzi, co-founder of design studio Jannuzzi Smith
# Mineral Wells, Mississippi

Mineral Wells is an unincorporated community located in central DeSoto County, Mississippi, United States, near the Mississippi/Tennessee border, just south of Memphis and approximately 3 miles (4.8 km) north of Olive Branch on Mississippi Highway 178. Mineral Wells is located on the former St. Louis–San Francisco Railway.
A post office operated under the name Mineral Wells from 1910 to 1994.
# Milton (surname)

Milton is an English surname. Notable people with the surname include:
* Aaron Milton, Canadian football player
* Anne Milton, United Kingdom Member of Parliament
* Arthur Milton, English cricketer and footballer
* Berth Milton Sr., Swedish pornographer
* Berth Milton Jr., Swedish pornographer
* Brian Milton, ultralight aircraft pilot
* CB Milton, pop singer
* Damian Milton, British sociologist and social psychologist
* Eric Milton, Major League Baseball player
* Giles Milton, British journalist and writer
* Joe Milton (born 2000), American football player
* John Milton, English poet
* John Milton (composer), father of the poet John Milton
* John Milton (Florida politician), American politician who was the fifth governor of Florida
* John Milton (Georgia politician), the Secretary of State of Georgia from 1777 to 1799
* John Milton Niles, U.S. editor and political figure from Connecticut
* John Gerald Milton, Democratic United States Senator from New Jersey
* Keenan Milton, a professional skateboarder who died in 2001
* Kendall Milton (born 2002), American football player
* Lance Milton, Canadian football player
* McKenzie Milton (born 1997), American football player
* Michael A. Milton, American theologian
* Michael Milton (cricketer), English cricketer
* Michael Milton (skier), Australian Winter Paralympic skier and cyclist
* Peter Milton, American artist
* Shake Milton, American basketball player
* Tommy Milton, American race car driver
* Trevor Milton (born 1981/1982), American billionaire, CEO and co-founder of Nikola Motor Company
* William Hall Milton, U.S. Senator from Florida
* William Henry Milton, administrator of Mashonaland and South African cricket player