OpenLLM-France/wikimedia huggingface dataset:
# PMDTA

PMDTA (N,N,N′,N′′,N′′-pentamethyldiethylenetriamine) is an organic compound with the formula [(CH$_3$)$_2$NCH$_2$CH$_2$]$_2$NCH$_3$. PMDTA is a basic, bulky, and flexible, tridentate ligand that is a used in organolithium chemistry. It is a colorless liquid, although impure samples appear yellowish.

## Synthesis

PMDTA is prepared from diethylenetriamine by the Eschweiler-Clarke reaction, involving the use of formaldehyde and formic acid.
    (H$_2$N[CH$_2$]$_2$)$_2$NH + 5 CH$_2$O + 5 HCO$_2$H → (Me$_2$N[CH$_2$]$_2$)$_2$NMe + 5 CO$_2$ + 5 H$_2$O

## Comparison with diethylenetriamine

Unlike diethylenetriamine, all three amines in PMDTA are tertiary. Both PMDTA and diethylenetriamine are tridentate ligands that form two five-membered chelate rings. The σ-donating properties of the amino groups of diethylenetriamine are greater than that of PMDTA in copper(II) complexes. Both ligands can coordinate metal complexes in arrangements where the three nitrogen centers are co-planar or mutually cis.

## Organolithium compounds and PMDTA

PMDTA is used to modify the reactivity of organolithium compounds, which deaggregate in the presence of Lewis bases to enhance their reactivity. Commonly, the ditertiary amine TMEDA is used in these applications; it binds to the lithium center as a bidentate ligand. PMDTA behaves analogously, but since it is tridentate, it binds more strongly to lithium. In contrast to TMEDA, PMDTA forms monomeric complexes with organolithium compounds. Both amines affect the regiochemistry of metalation.
In the PMDTA/n-BuLi adducts, the Li-C bonds are highly polarized, thus increasing the basicity of the butyl group.
The effect of PMDTA on lithium anilide is illustrative of PMDTA's complexing power. The complex, [{PhN(H)Li}$_3$·2PMDTA], is trinuclear, featuring approximately colinear Li$^+$ centers that are three-, four-, and five-coordinate. The central three-coordinate lithium atom is not bonded to PMDTA. One of the terminal Li centers is pseudo-tetrahedral in an N$_4$ coordination sphere. The other terminal lithium atom is five-coordinate and binds to two anilino N centers and the PMDTA.

## Transition metal and aluminium complexes

PMDTA often forms five-coordinate complexes due to steric bulk of the methyl groups. PMDTA stabilize unusual cations. The first cationic derivative of alane, [H$_2$Al(PMDTA)]$^+$[AlH$_4$]$^−$ was prepared by treating H$_3$AlNMe$_3$ with PMDTA.
# Page Miss Glory

Page Miss Glory may refer to:
* Page Miss Glory (play), a 1934 Broadway play written by Joseph Schrank and Philip Dunning
* Page Miss Glory (1935 film), a romantic comedy based on the play
* Page Miss Glory (1936 film), a Merrie Melodies cartoon
# Paha language

Paha or Baha (autonym: [pāhā]) is a Kra language spoken in northern Guangnan County, Wenshan Prefecture, Yunnan. The two villages are located near the border with Longlin County, Guangxi. Paha is often considered to be part of the Buyang dialect cluster and is the most divergent form. Although listed in Ethnologue as Baha Buyang (ISO 639-3: yha), Weera Ostapirat classifies Paha separately from the other Buyang varieties.

## Demographics

Within Guangnan County (广南县), Yunnan, the Paha language is spoken in the two villages of Yangliancun (央连村) (from Zhuang jaaŋ24 lɛŋ31 "lonely Buyang [village]") in Dixu Township (底圩乡) and Anshecun (安舍村) in Bada Township 八达乡. While Yanglian has around 500 Paha speakers, Anshe only has about 100 speakers left. Paha speakers are shifting rapidly to Zhuang and Southwestern Mandarin, particularly in Anshe village. Many Buyang men in Yanglian village are also married to Zhuang women.

## Phonology
### Consonants

Paha Buyang has the following consonants.
| | | Labial | Labial | Labial | Coronal | Coronal | Postalveolar | Postalveolar | Velar | Velar | Uvular | Uvular | Glottal |
| | | plain | pal. | bilab. | plain | bilab. | plain | bilab. | plain | bilab. | plain | bilab. | Glottal |
| Nasal | voiceless | m̥ | | | n̥ | | ɲ̊ | | ŋ̊ | | | | |
| Nasal | voiced | m | mʲ | mʷ | n | | ɲ | | ŋ | ŋʷ | | | |
| Plosive | plain voiceless | p | pʲ | pʷ | t | tʷ | tɕ | tɕʷ | k | kʷ | q | qʷ | ʔ |
| Plosive | voiceless aspirated | pʰ | pʲʰ | pʷʰ | tʰ | | tɕʰ | | kʰ | kʷʰ | qʰ | | |
| Plosive | plain voiced | b | bʲ | bʷ | d | | | | ɡ | ɡʷ | | | |
| Plosive | devoiced aspirated | b̥ʱ | b̥ʲʱ | | d̥ʱ | | | | ɡ̊ʱ | | | | |
| Fricative | voiceless | f | | ʍ w | θ | θʷ | ɕ | ɕʷ | | | | | h |
| Fricative | voiced | | | ʍ w | ð | ðʷ | | | ɣ | | ʁ | | |
| Approximant | voiceless | | | ʍ w | | | ȷ̊ | | | | | | |
| Approximant | voiced | | | ʍ w | | | j | ɥ | | | | | |
| Laterals | voiceless | | | | l̥ | | | | | | | | |
| Laterals | voiced | | | | l | | | | | | | | |

### Vowels

Paha Buyang has the following vowels.
| | Front | Central | Back | Back |
| | Front | Central | Unround | Round |
| High | i | | ɯ | u |
| Hi-Mid | e | ə | | o |
| Lo-Mid | ɛ | | | ɔ |
| Low | | a | | |
The three high vowels and the low vowel can be long.

## Grammar

Unlike the Buyang dialects of Langjia, Ecun, and Yalang, Paha negatives (such as pi45) precede the verb, whereas the Buyang dialects always place negatives at the end of a sentence. This phenomenon in Paha is probably due to Chinese influence.
# PS Bangli

PS Bangli is a defunct Indonesian football club based in Bangli, Bali. They used to play in the top division in Indonesian football, the Liga Indonesia. Their home stadium is Kapten i Wayan Dipta Stadium (now home to Bali FC). The club hit financial difficulties in 2005 and has decided to discontinue its run. This led to an opportunity for other clubs from Bali to merge and form a club using Perst Tabanan's license to compete in the Liga Indonesia. Local clubs such as Perseden Denpasar, Persekaba Badung and Persegi Gianyar merged with Persegi Gianyar to form a new club called Bali FC.
# Pagni

Pagni is an Italian surname. Notable people with the surname include:
* Benedetto Pagni (died 1578), Italian Mannerist painter
* Eros Pagni (born 1939), Italian actor
* Ferruccio Pagni (1866–1935), French-Italian painter
* Sergio Pagni (born 1979), Italian archer
# Pain Killer (Turin Brakes song)

"Pain Killer" (also titled "Pain Killer (Summer Rain)") is a song written by Olly Knights and Gale Paridjanian, produced by Tony Hoffer, and recorded by British band Turin Brakes. It was included on Turin Brakes' second album, Ether Song (2003), and was released as the second single from the album in February 2003. The song debuted at its peak of number five on the UK Singles Chart, at which point the single's formats were deleted. Outside the United Kingdom, the song charted in Italy and the Netherlands at numbers 50 and 64, respectively.

## Track listings

UK CD single
* "Pain Killer (Summer Rain)" (radio edit) – 3:41
* "Where's My Army?" (home recording) – 2:32
* "Little Brother" (demo version) – 5:15
* "Pain Killer (Summer Rain)" (video) – 3:41
UK limited-edition 7-inch single
    A. "Pain Killer" (radio edit)
    B. "Little Brother" (demo version)
European limited-edition CD single
* "Pain Killer (Summer Rain)" (radio edit) – 3:41
* "Pain Killer (Summer Rain)" (video) – 3:41

## Personnel

Personnel are lifted from the UK CD single liner notes.
* Olly Knights – vocals, writing
* Gale Paridjanian – vocals, writing
* Justin Meldal-Johnsen – bass
* Brian Reitzell – drums
* Dave Palmer – keyboards
* Tony Hoffer – production, mixing
* S. Husky Höskulds – engineering
* Ben Drury – Turin Brakes logo and sleeve artwork
* William Bankhead – sleeve photography
* Kate Nielsen – artwork coordination

## Charts

| Chart (2003) | Peak position |
| Europe (Eurochart Hot 100) | 20 |
| Italy (FIMI) | 50 |
| Netherlands (Single Top 100) | 64 |
| Scotland (OCC) | 4 |
| UK Singles (OCC) | 5 |

## Release history

| Region | Date | Format(s) | Label(s) |
| United Kingdom | 17 February 2003 | 7-inch vinylCD | Source |
| Australia | 31 March 2003 | CD | Source |
| United States | 23 June 2003 | Triple A radio | Astralwerks |
# Pain Killer (Energy Orchard album)

Pain Killer was the fourth album from Northern Ireland-based rock band, Energy Orchard, and was released in 1995.

## Track listing

All tracks composed by Bap Kennedy; except where noted.
* "Wasted" - 4:48
* "She's the One I Adore" (Bap Kennedy, Paul Toner) - 4:06
* "Remember My Name" - 4:41
* "The Past Is Another Country" (Bap Kennedy, Kevin Breslin) - 5:38
* "I Hate to Say Goodbye" (Bap Kennedy, Kevin Breslin) - 6:55
* "Pain Killer" - 4:29
* "D.F. Dogs" - Instrumental) - (Bap Kennedy, Spade McQuade) - 4:21
* "The Shipyard Song" - 3:53
* "Surrender to the City" - 4:50
* "A Sight for Sore Eyes"
# Wicked (1931 film)

Wicked, also known as Condannata in Italy and Malvada in Spain, is a 1931 American pre-Code drama film directed by Allan Dwan and starring Elissa Landi, Victor McLaglen, and Una Merkel. The screenplay concerns a woman who commits murder while trying to save her bandit husband and bears a child in prison. The production dates were between early June and early July 1931.

## Cast

* Elissa Landi as Margot Rande
* Victor McLaglen as Scott Burrows
* Una Merkel as June
* Irene Rich as Mrs. Luther
* Alan Dinehart as Blake
* Theodore von Eltz as Rony Rande
* Oscar Apfel as Judge Luther
* Mae Busch as Arlene
* Ruth Donnelly as Fanny
* Eileen Percy as Stella
* Kathleen Kerrigan as Miss Peck
* Alice Lake as Prisoner
* William Pawley as Cop
* G. Pat Collins as Cop
* Clarence Wilson as Juryman
* Edwin Maxwell as Owner of property
* George Kuwa as Tony's friend
* Lloyd Whitlock as Tony's Friend
# Willi Ankermüller

Willi Ankermüller (18 March 1901, Bad Neustadt an der Saale, Lower Franconia – 7 July 1986 in Grosshesselohe) was a German politician and jurist. He represented the Christian Social Union of Bavaria (CSU), and was a member of the Landtag of Bavaria in the 1950s.

## Education

Ankermüller studied law and political science at the University of Würzburg. There he became an active member of the Catholic Student Association. In 1925, he supported property rights of churches according to the Codex Juris Canonici, and worked as a magistrate and then director of the municipal youth office in Schweinfurt. Two years later he passed the second legal state examination and settled in Schweinfurt as a lawyer. After the Nazis came to power in Germany, he was taken into protective custody in 1933. In 1938, he was recruited into the Wehrmacht and served as a soldier in the Second World War between 1939 and 1945.
He was married to Elisabeth geb. Dielmann.

## Post-war career

He began his political career in the spring of 1945, when he was employed by the U.S. military government as a district administrator of the county of Hofheim in Unterfranken. There, he was co-founder of the local CSU in the fall of 1945. The following year, he took over the post of district administrator in the neighboring district of Bad Neustadt an der Saale. His contacts with the Würzburg group of the CSU paved the way for Ankermüller to advance into Bavarian state politics.
In June 1946, he was elected to the Constituent Assembly, which worked out a new Constitution of Bavaria, and served until the end of October 1946. In the popular vote on the constitution on December 1, 1946, and the simultaneous state elections, Ankermüller was elected to the first Bavarian parliament after the end of the war (the Landtag of Bavaria), and six weeks later was appointed Secretary of State in the Ministry of the Interior, led by Josef Seifried. When the Social Democratic Party of Germany (SPD) left the government of Hans Ehard in September 1947, he took over Seifried's office as Minister of the Interior. With the new formation of the CSU / SPD coalition after the regional election in 1950, a new Interior Minister took office: Wilhelm Hoegner who was known as the father of the new Bavarian constitution.
In his parliamentary work, Ankermüller concentrated on legal and security policy issues. He took the chairmanship of the Security Affairs Committee and became deputy chairman of the Committee on Legal and Constitutional Questions. He also served from 1950 to 1962 as a non-professional judge of the Bavarian Constitutional Court.
In October 1957, the four-party coalition led by Wilhelm Hoegner collapsed and Hanns Seidel was elected as the new Prime Minister of Bavaria. Seidel, who also came from Unterfranken, appointed Ankermüller as a Bavarian Minister of Justice in his cabinet. He remained in that office until the state elections in December 1958. He then resumed his activity as an attorney, but until the end of the 5th legislative period in November 1966 he remained a Landtag deputy.

## Awards

* Bavarian Order of Merit, 1959
# PXL

PXL may refer to:
* PXL-2000, camcorder
* Paclitaxel, drug
* PCL 6 Enhanced, printer command language
# Pacific Links International

Pacific Links International (est. in 2012) is an international golf club operator.

## History

Pacific Links International was established in 2012. By 2014, it owned 10 golf clubs in the US and through its network of owned, affiliate and reciprocal clubs controlled more than 100 clubs worldwide.
In 2015, Pacific Links International hired Tiger Woods to redesign Beijing Tian'an Holiday Golf Club.
In 2015 the company established Pacific Links Championship in Tianjin, China. In 2016 and 2017 it was held in Victoria, Canada.
As of 2018, the company controlled 700 golf properties located in 34 countries around the world. It also offered concierge services to its members.
# Palaeonyssia

Palaeonyssia is a genus of moths in the family Geometridae.
# Pakha

Pakha is a village development committee in Kalikot District in the Karnali Zone of north-western Nepal. At the time of the 1991 Nepal census it had a population of 2968 people living in 570 individual households.
# Pacific Heights (disambiguation)

Pacific Heights is a neighborhood of San Francisco.
Pacific Heights may also refer to:
* Pacific Heights, Queensland, a locality in the Shire of Livingstone, Australia
* Pacific Heights, Saskatoon, Saskatchewan
* Pacific Heights (film), a 1990 American psychological thriller directed by John Schlesinger
# Wilhelm Baur

Wilhelm Baur or Wilhelm Baur de Betaz (17 February 1883 in Metz – 26 May 1964 in Lindenfels) was a German Lieutenant General (Generalleutnant) of the Heer during Second World War.

## Biography

Wilhelm Baur was born in Metz (February 17, 1883), in Alsace-Lorraine, which was then part of Germany. He joined the army at twenty years old. He served in the 61st Artillery Regiment, from 1903 until 1914. Baur was detached to the Military Technical Academy in 1909, before being detached to the War-Academy from 1912 to 1914. During the First World War, Baur served as a company-grade officer. He was awarded the Iron Cross.
At the beginning of the Second World War, Wilhelm Baur was appointed Chief of Staff of the Higher Flying-Training-Commander. In March 1940, he took command of the Special-Purpose-Combat-Group in Norway. In September 1940, he was appointed commander of the air district of Greifswald, then commander of the air district of Döberitz. Baur was promoted to the rank of major general (Generalmajor) in July 1941. In May 1942, Baur worked at the headquarters of the armies, with General Walther von Unruh. He was appointed Chief of the Defence Economy Staff, in Norway. Baur was promoted General Lieutenant (Generalleutnant) in August 1943. In September 1944, Wilhelm Baur was eventually placed in Führer-Reserve until the end of the war.

## Staff positions

* Group-Director in the War-Scientific-Department, RLM (1 May 1937-07 Sep 1939)
* Chief of Staff of the Higher Flying-Training-Commander 4 (08 Sep 1939-28 Mar 1940)
* Commander of the Special-Purpose-Combat-Group (Norway) (29 Mar 1940-20 Sep 1940)
* Airport-Area-Commandant, Greifswald (21 Sep 1940-06 Feb 1941)
* Airport-Area-Commandant, Döberitz (07 Feb 1941-4 May 1942)
* Representative of the Luftwaffe in OKW, Special-Staff of General von Unruh (5 May 1942-31 Oct 1942)
* Chief of the Defence Economy Staff Norway (01 Nov 1942-30 Jun 1943)
* Field-Economics-Commander Norway (01 Jul 1943-30 Apr 1944)
* Higher Field-Economics-Officer with the Wehrmacht-Commander Norway (1 May 1944-18 Sep 1944)

## Promotions

* Fähnrich (18 Oct 1903);
* Leutnant (24 Apr 1904);
* Oberleutnant (24 Jul 1912);
* Hauptmann (8 Nov 1914);
* Charakter als Major (8 Apr 1920);
* Oberstleutnant (1 Mar 1935);
* Oberst (1 Aug 1937);
* Generalmajor (1 Jul 1941);
* Generalleutnant (1 Aug 1943)

## Decorations

* Knight's Cross of the Royal Prussian House Order of Hohenzollern with Swords
* Iron Cross (1914), 1st and 2nd classes
* Royal Prussian Plane Spotters badge
* Honour Cross for Combatants
* Wehrmacht Long Service Award, 4th to 2nd class
* Clasp to the Iron Cross
* German Cross in Silver
# Wilhelm von Scherff

Wilhelm von Scherff (6 February 1834 – 1911) was a German general and military writer.
Originally from Frankfurt, he joined the Prussian army in 1852. From 1856 to 1859 he attended the Kriegsschule, and from 1860 to 1866 served as Adjutant in the Prussian army. He took part in the Austro-Prussian War of 1866 and the Franco-Prussian War of 1870–71 as a general staff officer. From 1873 to 1878 he was a teacher of military tactics at the Prussian Military Academy.
In 1879, he was a member of the border adjustment commission in Bulgaria, and after his return he became commander of the 29th infantry regiment. In 1882 he became head of the general staff of the XIth Army Corps, in 1883 Brigade commander, and in 1888 Lieutenant General and commander of the 33rd infantry division in Strasbourg.

## Works

* Studien zur neuen Infanterie-Taktik. A. Bath, 1872–1876
* Die Infanterie auf dem Exercierplatze. Anhaltspunkte und Beispiele für die Ausbildung zum Gefecht. 1873
* Die Lehre von der Truppenverwendung als Vorschule für die Kunst der Truppenführung. A. Bath, 1876–1879
* Einige taktische Grundsätze als Anhalt für die Ausbildung der Infanterie zum Gefecht und Kampfe. A. Bath, 1879
* Reglementarische Studien. 1891-1892
* Praktische Taktik und taktische Theorie; polemische Betrachtungen über reglementarische Fragen. 1893
* Unsere heutige Infanterie-Taktik im Spiegel der Augustkämpfe 1870 um Metz. 1893
* Kriegslehren in kriegsgeschichtlichen Beispielen der Neuzeit. E.S Mittler und Sohn, 1894–1897
* Die Lehre vom Kriege, auf der Grundlage seiner neuzeitlichen Erscheinungsformen. E.S. Mittler und Sohn, 1897
* Der Schlachtenangriff: im Lichte der Schlichtingschen "Taktischen Grundsätze" und der Boguslawskischen "Betrachtungen." 1898
* Vergleichender Rückblick auf die neueste Tagesliteratur über den Infanterieangriff. 1906
# Palani Chettipatti

Palani Chettipatti (P.C. Patti) is a panchayat grama in Theni district in the Indian state of Tamil Nadu. It is located on the road between Theni and Cumbum. The Mullai river flows via this village from Uthamapalayam and goes down the valley pin code is 625531.

## History

It was founded by Palaniappa Chettiar. He and his family members constructed a small dam across the suruliyar river basin in 1840–1845, when John Black Burn was the district collector and magistrate of Madurai-Ramnad Jilla well before the Mullaperiyar Dam was constructed by Colonel John PennyCuick(1895). This dam is used for the irrigation and drinking water supply for several places: Theni - Allinagaram, Palanichettipatti and some near by villages. This dam has the distinction of being the *only* privately owned dam in Tamil Nadu. The founder, Palaniappa Chettiar, was one of the biggest contributors to the construction of the Mullaperiyar Dam.

## Demographics

As of 2001 India census, Palani Chettipatti had a population of 11,750. Males constitute 51% of the population and females 49%. Palani Chettipatti has an average literacy rate of 75%, higher than the national average of 59.5%: male literacy is 80%, and female literacy is 68%. In Palani Chettipatti, 12% of the population is under 6 years.

## Education
### Schools

A Government Aided School, Palaniappa Memorial Higher Secondary School provides low cost education to thousands of students in the nearby rural areas.
* Benedict Matriculation Higher Secondary School
* Palaniappa Vidyalaya
* Bose Primary
# Palazzo Barbaja, Naples

Palazzo Barbaja is a palace located on via Toledo of the quartiere San Ferdinando of Naples, Italy.
The palace was the home of Domenico Barbaja, a famous theater impresario of 19th century Naples. In the years 1815–1822, Gioacchino Rossini was his guest at times. Rossini had a contract with the Teatro del Fondo to write the music for the libretto of Francesco Berio Salsa to Otello. Berio also lived nearby. Because of his dilatory progress, Rossini was almost imprisoned in his room until he finished the music.
The building dates back to 16th century and was remodeled in the second half of the 18th century in a sober neoclassical style. The ground floor and the mezzanine are covered in ashlar blocks. The first two floors above the ground are marked by giant Ionic pilasters.
40°50′20″N 14°14′55″E﻿ / ﻿40.838889°N 14.248544°E﻿ / 40.838889; 14.248544
# Palazzo Barbarigo della Terrazza

The Palazzo Barbarigo dalla Terrazza is a Renaissance-style palace on the Grand Canal, across the Rio San Polo from the Palazzo Cappello Layard and adjacent to the Palazzo Pisani Moretta in the sestiere of San Polo, in Venice, Italy. In 2015, it housed the Centro Tedesco di Studi Veneziani.

## History

The patrician Daniele Barbarigo commissioned the palace from the architect Bernardin Contin, and construction took place during 1566–1570. The Barbarigo collection that included a number of Titian paintings was sold to czars during the 1850s, and is now displayed in the Hermitage. Some of the renaissance decoration of some rooms is still in place. Known for a large terrace overlooking the Grand Canal
# William Adcock

William Eddrup Adcock (31 December 1846 – 18 May 1931) was an Australian journalist and businessman.
Adcock was born in London to cigar manufacturer George Charles Adcock and Mary, née Goodwin. The family moved to Melbourne, then in the Colony of New South Wales in 1848, where George became a bookseller in Richmond. By 1865, William was a shopkeeper at Gaffney's Creek. On 30 December 1865, he married Emma Sharples, and in 1871, he was appointed editor of the Richmond Free Press. In 1872, he and his family moved to Palmerston (later Darwin) in the Northern Territory, where Adcock ran a general store. In 1874, he stood, unsuccessfully, for election as a councillor for Palmerston, and after his wife's health became an issue in 1878, he returned to Melbourne.
Following his successors' failure, Adcock returned to the territory in partnership with his brother and V. V. Brown. He opened new branches in Palmerston and Derby, and extended his business to include steamship agencies and the local Victoria Hotel, although Adcock himself remained based in Melbourne. In 1885, he returned to the territory to deal with financial difficulties brought on by the failure of the South Australian Town and Country Bank, which led to his being declared insolvent in February 1888. Adcock's appeal, reversed by the Supreme Court of South Australia, but twice reinstated, was ultimately refused in December in a proceeding unique in South Australian legal history. Adcock went to Adelaide on his solicitor's advice and was arrested on 20 December and sent to prison, where he and his counsel, Josiah Symon, continued his dispute with the insolvency court. Adcock spent four years in prison and was ultimately discharged in November 1893, but his assets were liable to be seized if he ever returned to South Australia.
Adcock returned to Victoria and journalism before travelling to Coolgardie, Western Australia, in 1900, where he established mining interests. In 1912, he published a compilation of anonymous articles he had attributed to the Australian Journal on the gold rushes in the 1890s, titled The Gold Rush of the Fifties. He was appointed editor of the journal around 1910, and continued in the position until 1926. He died at his home in Kew in 1926, survived by his second wife, Annie Mary Bowcott, whom he had married on 25 April 1898.