# Mie–Grüneisen equation of state

The Mie–Grüneisen equation of state is an equation of state that relates the pressure and volume of a solid at a given temperature. It is used to determine the pressure in a shock-compressed solid. The Mie–Grüneisen relation is a special form of the Grüneisen model which describes the effect that changing the volume of a crystal lattice has on its vibrational properties. Several variations of the Mie–Grüneisen equation of state are in use.
The Grüneisen model can be expressed in the form
    $\Gamma =V\left({\frac {dp}{de}}\right)_{V}$
where V is the volume, p is the pressure, e is the internal energy, and Γ is the Grüneisen parameter which represents the thermal pressure from a set of vibrating atoms. If we assume that Γ is independent of p and e, we can integrate Grüneisen's model to get
    $p-p_{0}={\frac {\Gamma }{V}}(e-e_{0})$
where $p_{0}$ and $e_{0}$ are the pressure and internal energy at a reference state usually assumed to be the state at which the temperature is 0K. In that case p$_0$ and e$_0$ are independent of temperature and the values of these quantities can be estimated from the Hugoniot equations. The Mie–Grüneisen equation of state is a special form of the above equation.

## History

Gustav Mie, in 1903, developed an intermolecular potential for deriving high-temperature equations of state of solids. In 1912, Eduard Grüneisen extended Mie's model to temperatures below the Debye temperature at which quantum effects become important. Grüneisen's form of the equations is more convenient and has become the usual starting point for deriving Mie–Grüneisen equations of state.

## Expressions for the Mie–Grüneisen equation of state

A temperature-corrected version that is used in computational mechanics has the form$^{:61}$
    $p={\frac {\rho _{0}C_{0}^{2}\chi \left[1-{\frac {\Gamma _{0}}{2}}\,\chi \right]}{\left(1-s\chi \right)^{2}}}+\Gamma _{0}E;\quad \chi :=1-{\cfrac {\rho _{0}}{\rho }}$
where $C_{0}$ is the bulk speed of sound, $\rho _{0}$ is the initial density, $\rho$ is the current density, $\Gamma _{0}$ is Grüneisen's gamma at the reference state, $s=dU_{s}/dU_{p}$ is a linear Hugoniot slope coefficient, $U_{s}$ is the shock wave velocity, $U_{p}$ is the particle velocity, and $E$ is the internal energy per unit reference volume. An alternative form is
    $p={\frac {\rho _{0}C_{0}^{2}(\eta -1)\left[\eta -{\frac {\Gamma _{0}}{2}}(\eta -1)\right]}{\left[\eta -s(\eta -1)\right]^{2}}}+\Gamma _{0}E;\quad \eta :={\cfrac {\rho }{\rho _{0}}}\,.$
A rough estimate of the internal energy can be computed using
    $E={\frac {1}{V_{0}}}\int C_{v}dT\approx {\frac {C_{v}(T-T_{0})}{V_{0}}}=\rho _{0}c_{v}(T-T_{0})$
where $V_{0}$ is the reference volume at temperature $T=T_{0}$, $C_{v}$ is the heat capacity and $c_{v}$ is the specific heat capacity at constant volume. In many simulations, it is assumed that $C_{p}$ and $C_{v}$ are equal.

### Parameters for various materials

| material | $\rho _{0}$ (kg/m$^3$) | $c_{v}$ (J/kg-K) | $C_{0}$ (m/s) | $s$ | $\Gamma _{0}$ ($T<T_{1}$) | $\Gamma _{0}$ ($T>=T_{1}$) | $T_{1}$ (K) |
| Copper | 8960 | 390 | 3933 | 1.5 | 1.99 | 2.12 | 700 |

## Derivation of the equation of state

From Grüneisen's model we have
| $p-p_{0}={\frac {\Gamma }{V}}(e-e_{0})$ | (1) |
where $p_{0}$ and $e_{0}$ are the pressure and internal energy at a reference state. The Hugoniot equations for the conservation of mass, momentum, and energy are
    ${\begin{aligned}\rho _{0}U_{s}&=\rho (U_{s}-U_{p})\,,\\[1ex]p_{H}-p_{H0}&=\rho _{0}U_{s}U_{p}\,,\\[1ex]p_{H}U_{p}&=\rho _{0}U_{s}\left({\frac {U_{p}^{2}}{2}}+E_{H}-E_{H0}\right)\end{aligned}}$
where ρ$_0$ is the reference density, ρ is the density due to shock compression, p$_H$ is the pressure on the Hugoniot, E$_H$ is the internal energy per unit mass on the Hugoniot, U$_s$ is the shock velocity, and U$_p$ is the particle velocity. From the conservation of mass, we have
    ${\frac {U_{p}}{U_{s}}}=1-{\frac {\rho _{0}}{\rho }}=1-{\frac {V}{V_{0}}}=:\chi \,.$
Where we defined $V=1/\rho$, the specific volume (volume per unit mass).
    For many materials U$_s$ and U$_p$ are linearly related, i.e., U$_s$ = C$_0$ + s U$_p$ where C$_0$ and s depend on the material. In that case, we have
    $U_{s}=C_{0}+s\chi U_{s}\quad {\text{or}}\quad U_{s}={\frac {C_{0}}{1-s\chi }}\,.$
The momentum equation can then be written (for the principal Hugoniot where p$_{H0}$ is zero) as
    $p_{H}=\rho _{0}\chi U_{s}^{2}={\frac {\rho _{0}C_{0}^{2}\chi }{(1-s\chi )^{2}}}\,.$
Similarly, from the energy equation we have
    $p_{H}\chi U_{s}={\tfrac {1}{2}}\rho \chi ^{2}U_{s}^{3}+\rho _{0}U_{s}E_{H}={\tfrac {1}{2}}p_{H}\chi U_{s}+\rho _{0}U_{s}E_{H}\,.$
Solving for e$_H$, we have
    $E_{H}={\tfrac {1}{2}}{\frac {p_{H}\chi }{\rho _{0}}}={\tfrac {1}{2}}p_{H}(V_{0}-V)$
With these expressions for p$_H$ and E$_H$, the Grüneisen model on the Hugoniot becomes
    $p_{H}-p_{0}={\frac {\Gamma }{V}}\left({\frac {p_{H}\chi V_{0}}{2}}-e_{0}\right)\quad {\text{or}}\quad {\frac {\rho _{0}C_{0}^{2}\chi }{(1-s\chi )^{2}}}\left(1-{\frac {\chi }{2}}\,{\frac {\Gamma }{V}}\,V_{0}\right)-p_{0}=-{\frac {\Gamma }{V}}e_{0}\,.$
If we assume that Γ/V = Γ$_0$/V$_0$ and note that $p_{0}=-de_{0}/dV$, we get
| ${\frac {\rho C_{0}^{2}\chi }{(1-s\chi )^{2}}}\left(1-{\frac {\Gamma _{0}\chi }{2}}\right)+{\frac {de_{0}}{dV}}+{\frac {\Gamma _{0}}{V_{0}}}e_{0}=0\,.$ | (2) |
The above ordinary differential equation can be solved for e$_0$ with the initial condition e$_0$ = 0 when V = V$_0$ (χ = 0). The exact solution is
    ${\begin{aligned}e_{0}={\frac {\rho C_{0}^{2}V_{0}}{2s^{4}}}{\Biggl&\exp(\Gamma _{0}\chi )\left({\tfrac {\Gamma _{0}}{s}}-3\right)s^{2}-{\frac {\left[{\tfrac {\Gamma _{0}}{s}}-(3-s\chi )\right]s^{2}}{1-s\chi }}+\\&\exp \left[-{\tfrac {\Gamma _{0}}{s}}(1-s\chi )\right]\left(\Gamma _{0}^{2}-4\Gamma _{0}s+2s^{2}\right)\left({\text{Ei}}\left[{\tfrac {\Gamma _{0}}{s}}(1-s\chi )\right]-{\text{Ei}}\left[{\tfrac {\Gamma _{0}}{s}}\right]\right){\Biggr ]}\end{aligned}}$
where Ei[z] is the exponential integral. The expression for p$_0$ is
    ${\begin{aligned}p_{0}=-{\frac {de_{0}}{dV}}={\frac {\rho C_{0}^{2}}{2s^{4}(1-\chi )}}{\Biggl&{\frac {s}{(1-s\chi )^{2}}}{\Bigl-\Gamma _{0}^{2}(1-\chi )(1-s\chi )+\Gamma _{0}[s\{4(\chi -1)\chi s-2\chi +3\}-1]\\&\qquad \qquad \quad -\exp(\Gamma _{0}\chi )[\Gamma _{0}(\chi -1)-1](1-s\chi )^{2}(\Gamma _{0}-3s)+s[3-\chi s\{(\chi -2)s+4\}]{\Bigr )}\\&-\exp \left[-{\tfrac {\Gamma _{0}}{s}}(1-s\chi )\right]\left[\Gamma _{0}(\chi -1)-1\right]\left(\Gamma _{0}^{2}-4\Gamma _{0}s+2s^{2}\right)\left({\text{Ei}}\left[{\tfrac {\Gamma _{0}}{s}}(1-s\chi )\right]-{\text{Ei}}\left[{\tfrac {\Gamma _{0}}{s}}\right]\right){\Biggr ]}\,.\end{aligned}}$
For commonly encountered compression problems, an approximation to the exact solution is a power series solution of the form
    $e_{0}(V)=A+B\chi (V)+C\chi ^{2}(V)+D\chi ^{3}(V)+\cdots$
and
    $p_{0}(V)=-{\frac {de_{0}}{dV}}=-{\frac {de_{0}}{d\chi }}\,{\frac {d\chi }{dV}}={\frac {1}{V_{0}}}\,(B+2C\chi +3D\chi ^{2}+\cdots )\,.$
Substitution into the Grüneisen model gives us the Mie–Grüneisen equation of state
    $p={\frac {1}{V_{0}}}\,(B+2C\chi +3D\chi ^{2}+\cdots )+{\frac {\Gamma _{0}}{V_{0}}}\left[e-(A+B\chi +C\chi ^{2}+D\chi ^{3}+\cdots )\right]\,.$
If we assume that the internal energy e$_0$ = 0 when V = V$_0$ (χ = 0) we have A = 0. Similarly, if we assume p$_0$ = 0 when V = V$_0$ we have B = 0. The Mie–Grüneisen equation of state can then be written as
    $p={\frac {1}{V_{0}}}\left[2C\chi \left(1-{\tfrac {\Gamma _{0}}{2}}\chi \right)+3D\chi ^{2}\left(1-{\tfrac {\Gamma _{0}}{3}}\chi \right)+\cdots \right]+\Gamma _{0}E$
where E is the internal energy per unit reference volume. Several forms of this equation of state are possible.
If we take the first-order term and substitute it into equation (2), we can solve for C to get
    $C={\frac {\rho _{0}C_{0}^{2}V_{0}}{2(1-s\chi )^{2}}}\,.$
Then we get the following expression for p:
    $p={\frac {\rho _{0}C_{0}^{2}\chi }{(1-s\chi )^{2}}}\left(1-{\tfrac {\Gamma _{0}}{2}}\chi \right)+\Gamma _{0}E\,.$
This is the commonly used first-order Mie–Grüneisen equation of state.