OpenLLM-France/wikimedia huggingface dataset:
# Pinacolone

Pinacolone (3,3-dimethyl-2-butanone) is an important ketone in organic chemistry. It is a colorless liquid with a slight peppermint or camphor odor. It is a precursor to triazolylpinacolone in the synthesis of the fungicide triadimefon and in synthesis of the herbicide metribuzin. The molecule is an unsymmetrical ketone. The α-methyl group can participate in condensation reactions. The carbonyl group can undergo the usual reactions (hydrogenation, reductive amination, etc.). It is a Schedule 3 compound under the Chemical Weapons Convention 1993, due to being related to pinacolyl alcohol, which is used in the production of soman. It is also a controlled export in Australia Group member states.

## Preparation

Most famously, at least in the classroom, pinacolone arises by the pinacol rearrangement, which occurs by protonation of pinacol (2,3-dimethylbutane-2,3-diol).
Industrially pinacolone is made by the hydrolysis of 4,4,5-trimethyl-1,3-dioxane, which is the product of isoprene and formaldehyde via the Prins reaction. It also is generated by ketonization of pivalic acid and acetic acid or acetone over metal oxide catalysts. 3-Methylbutanal is a starting material for 2,3-dimethyl-2-butene, which in turn is converted to pinacolone. Pinacolone can also be produced from 2-methy-2-butanol when reacted with C5 alcohols.

## Uses

Pinacolone is produced in large amounts for use in fungicides, herbicides, and pesticides. Some derivatives include:
* retrosynthetic analysis of vibunazole showed that it was derived from pinacolone.
* It is also used to prepare pinacidil, as well as naminidil.
* Stiripentol
* Tribuzone
* Pivaloylacetonitrile is used in the synthesis of Doramapimod.
* Triadimefon
* Diclobutrazole
* Paclobutrazol
* Valconazole
* Diethylstilbestrol pinacolone [18922-13-9].
* Some kind of Bisphenol A derivative also U.S. patent 4,599,463
* Thiofanox
# Friends in Love

Friends in Love may refer to:
* "Friends in Love", a song by Johnny Mathis and Dionne Warwick
* Friends in Love (Johnny Mathis album), 1982
* Friends in Love (Dionne Warwick album), 1982
# Army Public School

Army Public School may refer to:
* Indian Army Public Schools
* Army Public Schools & Colleges System, Pakistan
# KSLN

KSLN may refer to:
* KSLN-LP, a low-power radio station (95.9 FM) licensed to serve Sullivan, Missouri, United States
* KSLN-TV, a television station (channel 34) formerly licensed to serve Salina, Kansas, United States
* Salina Regional Airport (ICAO code KSLN)
# Robert Membury

Robert Membury was an English politician who was MP for Lyme Regis in 1386, February 1388, 1393, and 1394.
# Anisodontosaurus

Anisodontosaurus is an extinct genus of trilophosaurid allokotosaur known from the Middle Triassic Moenkopi Formation of Arizona. The type species, A. greeri, was named and described by Samuel Paul Welles in 1947.

## Discovery and naming

The holotype, a jaw catalogued as UCMP V3922, was discovered in 1940 and was described seven years later.
Apart from the type specimen, Anisodontosaurus is known from the referred specimen UCMP 37815, a right ilium.

## Classification

Its taxonomic placement was largely unknown (it was placed within the Eosuchia by Welles in 1947) until the holotype was reassessed in 1998, when it was recovered as a lepidosauromorph or a trilophosaurid.
A 2023 redescription of available fossils supported its identification as a trilophosaurid, specifically as the sister taxon to Variodens, from the Late Triassic of the United Kingdom. The clade containing Anisodontosaurus and Variodens is the longest-lasting subset of Trilophosauridae, as Anisodontosaurus is one of the oldest known members of the family while Variodens is among the youngest.
# Rhodospirillales

The Rhodospirillales are an order of Pseudomonadota.

## Notable Families

The Acetobacteraceae comprise the acetic acid bacteria, which are heterotrophic and produce acetic acid during their respiration.
The Rhodospirillaceae include mainly purple nonsulfur bacteria, which produce energy through photosynthesis.

## Phylogeny

The currently accepted taxonomy is based on the List of Prokaryotic names with Standing in Nomenclature (LPSN). The phylogeny is based on whole-genome analysis.
# Dave Konig

Dave Konig is an American comedian and actor. He has made appearances on Marvelous Mrs. Maisel, Crashing (U.S. TV series), The Blacklist, and The Enemy Within. He is also the author of a novel, Good Luck Mr. Gorsky.
He has hosted or co-hosted several TV shows, and appeared in films. He won three New York Emmy Awards as the co-host of the comedy series Subway Q&A and hosted the HBO late-night comedy series Hardcore TV. In 2015, he guest-starred in the second episode of season five of Louie.
As a comedic character actor, Dave Konig has appeared in such films as Final Rinse with Joey Ramone, Home Sweet Hoboken with Ben Gazzara, and Mambo Café with Danny Aiello. On TV he has appeared in season two of HBO’s Boardwalk Empire, and on NBC’s Law & Order: Criminal Intent. He made 11 appearances as the featured guest comedian on the talk/variety show Late Night with Joey Reynolds on NBC Nonstop.
Dave Konig has appeared in comedy clubs and cruise ships throughout his career. In 2010 and 2011, he toured the U.S. in the stand-up comedy revue Pastrami On Rye With Mayo with Tom Cotter, Cory Kahaney, and Ross Bennett. Dave Konig debuted on Broadway as Vince Fontaine in the Tommy Tune revival of Grease. In 2010, he starred Off Broadway in his own solo show Hebrew School Dropout at the Actors Temple Theater in New York City. The New York Times called the show “lightning fast, charming, insightful, and very, very funny”. In 2013, he debuted his second Off Broadway solo show Addicted to Show Business at the St. Luke's Theatre in New York City, which received positive “Reader’s Reviews” in the New York Times Theater section Other theater credits include regional productions of Sugar and The Odd Couple.
# Mir Yusif Mirbabayev

Mir Yusif Mirbabayev (1889, in Erivan, Russian Empire – 1951, in Baku, Azerbaijan SSR, Soviet Union) was an Azerbaijani linguistics scholar, director of the Institute of Linguistics at the Academy of Sciences of the Azerbaijan SSR. He was one of the authors and the scientific editor of the 4-volume Russian-Azerbaijani dictionary, and a recipient of the Stalin Prize in 1948.

## Life

Mir Yusif Mirbabayev was born in 1889 in the city of Irevan. His father, Mirabbas Mirbabayev, was a prominent figure in Irevan and a member of the Irevan City Duma. Mir Yusif received his primary education at the Russian-Tatar and city gymnasiums in Irevan. In 1916, he graduated from the Law Faculty of Moscow University. He served as a clerk at the Azerbaijani People's Republic Embassy in the Republic of Armenia. He was also a member of the Irevan Muslim National Council and authored appeals to both Azerbaijan and Armenia, as well as to the representatives of the Entente powers in the South Caucasus, to cease the massacres against Azerbaijanis in Armenia.
After Armenia fell under Bolshevik influence, he worked at the Military Tribunal of the Armenian Revolutionary Committee and the People's Commissariat of Finance. He held positions as a department head and dean at the Irevan Pedagogical Technical School. He also worked as a research scholar at the History Institute of the Armenian Academy of Sciences and the State Museum. Mir Yusif was a member of the National Minorities Council and the New Turkic Alphabet Committee.
In 1933, he moved to Baku and began working in the field of linguistics. He worked as a scientific secretary at the Azerbaijan branch of the USSR Academy of Sciences and the branch's Dictionary Institute.
In 1944, he defended his doctoral thesis on the influence of the Azerbaijani language on the Armenian language. The research topic was titled "The Influence of the Turkic Language on the Armenian Language." In 1945, he was appointed as the first head of the Institute of Linguistics of the Azerbaijan National Academy of Sciences.
Mir Yusif Mirbabayev played a significant role in the preparation of the Soviet Azerbaijan Encyclopedia. He authored many articles on linguistics, drawing from sources in Arabic, Persian, Russian, English, French, Ottoman Turkish, and Armenian languages.
He was awarded the Stalin Prize in 1948 for his contribution to the preparation of a 4-volume Russian-Azerbaijani dictionary, prepared under the leadership of Academician Heydar Huseynov.
Mir Yusif Mirbabayev passed away in Baku on August 25, 1951.
# Liometopum incognitum

Liometopum incognitum is an extinct species of formicid in the ant subfamily Dolichoderinae known from fossils found in eastern Asia.

## History and classification

Liometopum incognitum is known from single specimen which is a mostly complete adult queen in dorsal view. The holotype insect was discovered preserved as a compression fossil found in Russia. The specimen preserved in diatomite deposits of the Bol’shaya Svetlovodnaya site. Located in the Pozharsky District, on the Pacific Coast of Russia, the fossil bearing rocks preserve possibly Priabonian plants and animals which lived in a small lake near a volcano. The site has been attributed to either the Maksimovka or Salibez Formations and compared to the Bembridge Marls and Florissant Formation, both of which are Priabonian in age.
At the time of description, the holotype specimen, number PIN 3429/1157 was preserved in the A. A. Borissiak Paleontological Institute collections, part of the Russian Academy of Sciences. The fossil was first described by the trio of paleomyrmecologists Gennady Dlussky, Alexandr Rasnitsyn and Ksenia Perfilieva. In the type description, Dlussky, Rasnitsyn and Perfilieva named the species L. incognitum, with the specific epithet derived from the Latin "incognitum", which means unknown.
L. incognitum is one of a number of species in Liometopum that have been described. There are seven living species found in North America and Eurasian temperate to subtropical areas, while many fossil species are known from North America and Eurasia.

## Description

L. incognitum was described from a lone 14.5 mm (0.57 in) long queen preserved as a partial dorsal impression, missing portions of the legs, wings, antennae, and body. The head is slightly longer than its wide with rounded back corners of the head and the back margin slightly concave. The eyes are placed at the middle point of the head and oval in shape. The cutucle ridges of the face diverge away from each other.
# Pinacosterna marginalis

Pinacosterna marginalis is a species of beetle in the family Cerambycidae. It was described by Stephan von Breuning in 1935.
# Keneally and Cameron

Keneally and Cameron was an Australian television news and commentary program broadcast weekly on Sky News Australia from 2014 to 2015, co-hosted by former NSW Premier Kristina Keneally and former Federal Liberal Minister Ross Cameron. The show was a replacement of axed format The Contrarians, which Keneally and Cameron had co-hosted since mid-2014.
The series focused on mainly political topics, with the co-hosts joined by different newsmakers, politicians and commentators throughout the show, and discussed the issues of the week. The program aired at 4pm on Friday afternoons. The program had news updates from a Sky News presenter every half-hour throughout the show.
The final segment of the show was The Team Australia Awards, named after a phrase coined by Prime Minister Tony Abbott shortly before the program premiered, in which Keneally, Cameron and their guests give awards to prominent Australians or groups. These awards included positive awards such as 'Team Australia MVP' to anyone the hosts thought made a positive contribution during the week, and negative awards including a yellow card and red card given to people who caused controversy or did something wrong during the week.
Tweets were also read out during the show from viewers using the show's hashtag. The program was broadcast from the Sky News centre in the Sydney suburb of Macquarie Park.

## Ending of program

The program last aired on 27 March 2015 with Janine Perrett filling in for Keneally who was on holidays. It was replaced by a two-hour news bulletin on 3 April (which was a public holiday), and again by a new program called The Friday Show hosted by Janine Perrett on 10 April.
It was reported that the show ended due to Keneally being unhappy with the way the program portrayed her. Keneally was named co-host of a new daytime program To The Point, while Cameron remained a contributor to other Sky programs.
# Anilazine

Anilazine (ǎ-nǐl-a-zēn) is an organic compound with the chemical formula C$_9$H$_5$Cl$_3$N$_4$. It is a pesticide used on crops. It comes under the category of triazine fungicides. It is used for controlling fungus diseases which attack lawns and turf, cereals, coffee, and a wide variety of vegetables and other crops. It is also used for the control of potato and tomato leafspots.

## Toxicity

Oral administration to rats and cats, the most common signs of toxicity were diarrhea and vomiting respectively After dermal administration to rabbits mild skin irritation manifested as edema and erythema was observed. Anilazine was more toxic by intraperitoneal injection than by other routes of administration.

## Medical use

In 1955, Bergsmann studied dairin as a tuberculocide.
# Robert Beckham

Robert Beckham may refer to:
* Robert Franklin Beckham (1837–1864), Confederate States Army officer
* Robert C. Beckham (1932–2016), American politician, member of the Georgia House of Representatives
* Bob Beckham (Robert Joseph Beckham, 1927–2013), American country music publisher
# KGNR

KGNR (91.9 FM, "Good News Radio") is a radio station broadcasting a Christian radio format. Licensed to John Day, Oregon, United States, the station is currently owned by CSN International.
# Rhodospirillaceae

The Rhodospirillaceae are a family of Pseudomonadota. The majority are purple nonsulfur bacteria, producing energy through photosynthesis; originally all purple nonsulfur bacteria were included here.
They are often found in anaerobic aquatic environments, such as mud and stagnant water, although they are able to survive in air.
This family also includes Magnetospirillum, which contains tiny chains of magnetite. These let it sense the Earth's magnetic field, which runs downwards as well as north or south, to return to the bottom of a pond (magnetotaxis). Similar magnetite chains found in Martian meteorites have been suggested as evidence of life on Mars.
# Younis Khamis

Younis Khamis Ibrahim (born July 23, 1982 in Dubai) is an Emirati professional basketball player.

## Club career

At the club level, Khamis plays for the AlWasl Club AlShabab Club AlAHli Club in the UAE basketball league. He is also a member of the United Arab Emirates national basketball team.

## International career

Khamis competed for the United Arab Emirates national basketball team at both the FIBA Asia Championship 2007 and GCC Championship 2007 and FIBA Asia Championship 2009 and GCC championship 2010 and FIBA Asia Japan championship 2011 and Arab championship 2011 and Dubai tournaments 2012 and 2013.
# Ministry of Employment and Social Solidarity

The Ministry of Employment and Social Solidarity (in French: Ministère de l'Emploi et de la Solidarité sociale) is a government department in the Canadian province of Quebec. Its primary function is to promote employment and provide financial support for economically disadvantaged people.
The department is overseen by the Minister of Employment and Social Solidarity, who is a member of the Executive Council of Quebec. Ministerial responsibility for employment was separated from social solidarity in 2001, and a different minister assigned to each field. The positions were reunited in 2003. As of the 2022 election, they have been split into the Ministry of Employment and Ministry of Social solidarity. Kateri Champagne Jourdain is the minister of employment while Chantal Rouleau is minister of Social Solidarity.
# Liometopum escheri

Liometopum escheri is an extinct species of Miocene ant in the genus Liometopum. Described by Heer in 1867, fossils of the species were found in Switzerland.
# Pitcairn XO-61

The Pitcairn XO-61 was an American autogyro designed by Pitcairn Aircraft. One of the last autogyros produced, in competition with the Kellett YO-60 and the Sikorsky R-4, it fell victim to cooling problems with its rear-mounted engine and the coming of the helicopter with its ability to hover.
Also known by the company model number PA-44 and the contract designation MX-157, the contract for the XO-61 was taken over by G&A Aircraft upon G&A's acquisition of Pitcairn Aircraft.
# Ken Ohara

Ken Ohara (小原 健, Ohara Ken, born 1942) is a Japanese photographer. Ohara is most noted for his series of photographs titled ONE, in which he presents anonymous faces with standard size and tone.
Ohara moved from Tokyo to New York City in 1962. In 1970 while working as an assistant to HIRO and Richard Avedon, he published ONE, which contained more than 500 tight close-ups of anonymous people's faces he shot on the New York streets. This work was first exhibited at the New York Museum of Modern Art in its 1974 exhibition New Japanese Photography, attracting critical attention. In the last 50 years since then, Ohara has achieved a series of experimental portrait projects in varied formats. They include self-portraits shot every minute for 24 hours (24 Hours), daily photo journals for the duration of one year (Self-Portrait 365 series), and the portraits of 123 local residents near his studio with whom he shots while opening a camera shutter for exactly 60 minutes (with series).
Ohara's work offers an intense examination of space and time in portraiture and provokes a rethinking of the limits of photographic depiction. His work is currently represented by Miyako Yoshinaga Gallery in New York City and in the permanent collection of the Smithsonian American Art Museum, Metropolitan Museum of Art, San Francisco Museum of Modern Art, Museum of Modern Art, New York, Los Angeles County Museum of Art, Folkwang Museum, The Getty Research Institute, The Museum of Fine Arts, Houston, among others.
Ohara resides in Los Angeles, California.
# Anne Green (disambiguation)

Anne Green (1891–1979) was an American author and translator.
Ann(e) Green(e) may also refer to:
* Ann Green (died 1518), buried at Church of St Peter, Alstonefield with oldest legible gravestone in England
* Anne Greene (c. 1628–1659), English servant accused of infanticide
* Anne Green (Chief Islander) (born 1952), politician from Tristan da Cunha
* Anne Green (scientist), Australian physician and astronomer
* Anne Green (swimming) (1951–2022), Australian swimming coach
* Anne Catherine Hoof Green (c. 1720–1775), printer and publisher
* Anne Dunkin Greene (c. 1885–1939), American socialite
* Anne Syrett Green (1858–1936), welfare worker and evangelist
* Ann Larsson (athlete) or Ann Larsson Green (born 1955), Swedish sprinter
# Robert Stacy-Judd

Robert Stacy-Judd (1884–1975) was an English architect and author who designed theaters, hotels, and other commercial buildings in the Mayan Revival architecture Style in Great Britain and the United States. Stacy-Judd's synthesis of the style used Maya architecture, Aztec architecture, and Art Deco precedents as his influences.

## Aztec Hotel

Stacy-Judd's most celebrated Mayan Revival designed building is the Aztec Hotel, focusing on the facades, interiors, and furniture. It was built in 1924 on the original U.S. Route 66, and is located in Monrovia, Southern California. Stacy-Judd explained the choice of the name of the hotel.
   When the hotel project was first announced, the word Maya was unknown to the layman. The subject of Maya culture was only of archaeological importance, a, at that, concerned but a few exponents. As a word Aztec was fairly well known, I baptized the hotel with that name, although all the decorative motifs are Maya

## Works

Works include (with attribution as appears in National Register listing):
* Aztec Hotel, 311 W. Foothill Blvd. Monrovia, CA (Stacy-Judd,Robert B.), NRHP-listed
* First Baptist Church of Ventura, 101 S. Laurel St. Ventura, CA (Stacy-Judd, Robert Benjamin), NRHP-listed
* North Hollywood Masonic Temple, 5122 Tujunga Ave., North Hollywood, CA
* Old Armory (Williston, North Dakota), 320 1st Ave., E. Williston, ND (Judd,Robert Stacy), NRHP-listed
* Old Tioga High School-West Section, (Tioga, ND)
* The Philosophical Research Society, 1934, Mayan Revival: 3910 Los Feliz Blvd., Los Angeles, CA
* The "Indian Village" at Soboba Hot Springs, Riverside County, California
* First Baptist Church of Ventura
* North Hollywood Masonic Temple
* Old Armory in Williston, North Dakota
* Philosophical Research Society
* Soboba resort "Indian Village" Riverside County California

## Writing

Stacy-Judd was a friend of the writer T. A. Willard, who published a fanciful account of his travels to Chichen Itza, was extremely influenced by John Lloyd Stephens writings, and perhaps even more so by the illustrations by Frederick Catherwood as presented in their book 'Incidents of Travel in Central America, Chiapas and Yucatán'. a work that introduced many to the wondrous ruins of Central America. Possibly inspired by his friend T.A. Willard, Stacy-Judd published several popular books on Maya culture that blend fact and fiction.
# Angara (surname)

Angara is a surname. Notable people with the surname include:
* Arthur Angara (born 1937), Filipino politician and mayor
* Bella Angara (born 1939), Filipino politician who has served as a governor of Aurora and as a member of the House of Representatives
* Edgardo Angara (1934–2018), Filipino politician who has served as a senator
* Joseph Angara (born 1971), Kenyan cricketer and coach
* Karen G. Angara (born 1973), Filipino politician and mayor
* Michael Angara, Papua New Guinean rugby player
* Rommel N. Angara (born 1980), Filipino poet
* Rommel T. Angara (born 1978), Filipino politician
* Sonny Angara (born 1972), Filipino politician and senator
# Rhodopteriana rhodoptera

Rhodopteriana rhodoptera is a moth in the family Eupterotidae. It was described by Carl Eduard Adolph Gerstaecker in 1871. It is found in Cameroon, the Democratic Republic of the Congo, Ethiopia, Gabon, Kenya, South Africa, Tanzania and Uganda.