OpenLLM-France/wikimedia huggingface dataset:
# Trimethylsilyl isothiocyanate

Trimethylsilyl isothiocyanate (TMSNCS) is an organosilicon compound that contains an isothiocyanate whose nitrogen atom is covalently bonded to a trimethylsilyl group. The isothiocyanate group is an analog of the isocyanate group, but having a sulfur instead of oxygen.

## Reactions

TMSNCS is useful reagent in organic chemistry. It is an ambident nucleophile, able to react with various alkyl halides, acetals, aldehydes, unsaturated compounds, aziridines, oxiranes, polycyclic aromatic hydrocarbons, and acetylated hexoses to form either thiocyanate or isothiocyanate structures. As an electrophile, it can react with other nucleophiles to form thioamide types of structures, some of which can undergo subsequent reactions to form heterocycles.

### Halide substitutions

As a sulfur nucleophile, TMSNCS substitutes for halides on a range of alkyl substrates, giving alkyl thiocyanates. These substitution reactions involve tetrabutylammonium fluoride used as phase-transfer catalyst and occur under particularly mild conditions.

### Reactions with aldehydes and acetals

As a nitrogen nucleophile, TMSNCS adds across the carbonyl group of aldehydes and substitutes isothiocyanate for one of the ether groups on acetals via acid-catalyzed processes.

### Mercapto-1,2,4-triazoles

A one-step method to prepare mercapto-1,2,4-tiazoles is favored on the industrial scale due to its high efficiency (88% yield) and non-constraining conditions: not requiring anhydrous solvent, inert gas temperature, or chromatographic purification. The method can be summarized as follows: after the equimolar mixture of benzohydrazide and TMSNCS reflux in the presence of EtOH for 5 hours, NaOH is added to the reaction mixture and the solution is refluxed for 4 h. Acetic acid is then used to cool and neutralize, ultimately yielding the pure white solid 3-phenyl-5-mercapto-4H-1,2,4-triazole at 88% yield.

### 2-Amino-1,3,4-oxadiazoles

TMSNCS used for the synthesis of 2-amino-1,3,4-oxadiazoles. The TMSNCS reagent assists in the production of the thiosemicarbazide and the subsequent reaction (cyclodesulfurization of thiosemicarbazides under basic conditions in the presence of I2/KI) results in 2-amino-1,3,4-oxadiazoles in high yields (79–94%). The 2-amino-1,3,4-oxadiazoles resulting from this reaction are: 2-Amino-5-phenyl-1,3,4-oxadiazole, 2-Amino-5-(p-methylphenyl)-1,3,4-oxadiazole, 2-Amino-5-(p-chlorophenyl)-1,3,4-oxadiazole, 2-Amino-5-(p-methoxyphenyl)- 1,3,4-oxadiazole, 2-Amino-5-(p-nitrophenyl) -1,3,4-oxadiazole, 2-Amino-5-(o-methylphenyl)-1,3,4-oxadiazole, 2-Amino-5-(o-chlorophenyl)-1,3,4-oxadiazole, ect.
# Generic Substation Events

Generic Substation Events (GSE) is a control model defined as per IEC 61850 which provides a fast and reliable mechanism of transferring event data over entire electrical substation networks. When implemented, this model ensures the same event message is received by multiple physical devices using multicast or broadcast services. The GSE control model is further subdivided into GOOSE (Generic Object Oriented Substation Events) and GSSE (Generic Substation State Events).

## Generic Object Oriented Substation Events

Generic Object Oriented Substation Events (GOOSE) is a controlled model mechanism in which any format of data (status, value) is grouped into a data set and transmitted within a time period of 4 milliseconds. The following mechanisms are used to ensure specified transmission speed and reliability.
* GOOSE data is directly embedded into Ethernet data packets and works on publisher-subscriber mechanism on multicast or broadcast MAC addresses.
* GOOSE uses VLAN and priority tagging as per IEEE 802.1Q to have separate virtual network within the same physical network and sets appropriate message priority level.
* Enhanced retransmission mechanisms - The same GOOSE message is retransmitted with varying and increasing re-transmission intervals. A new event occurring within any GOOSE dataset element will result in the existing GOOSE retransmission message being stopped. A state number within the GOOSE protocol identifies whether a GOOSE message is a new message or a retransmitted message.
* GOOSE messages are designed to be brand independent. Some vendors offer intelligent electronic devices (IED) that fully support IEC 61850 for a truly interoperable approach within the substation network without requiring vendor specific cables or algorithms.

## Generic Substation State Events

Generic Substation State Events (GSSE) is an extension of event transfer mechanism in UCA2.0. Only Status data can be exchanged through GSSE and it uses a status list (string of bits) rather than a dataset as is used in GOOSE. GSSE messages are transmitted directly over IEC/ISO 8802-2 and 8802-3 using a similar mechanism to GOOSE messages (refer IEC 61850-7-1 Clause 12.2, IEC 61850-8-1 Clause 6.4). As the GSSE format is simpler than GOOSE it is handled faster in some devices. GSSE is being progressively superseded by the use of GOOSE and support for it may eventually disappear.

## Non-standard event reporting models

Equipment manufacturers have started to offer non-standard protocols to report events over substation networks, citing advantages to these approaches.
* Fixed GOOSE - This is implemented in GE IEDs and makes use of the GSSE data format (list of bits) over the GOOSE protocol. This is said to be faster than GOOSE as it uses (shorter) unstructured data in the transmission string instead of structured data format required used by GOOSE.
# Tax Reform Act of 1976

The Tax Reform Act of 1976 was passed by the United States Congress in September 1976, and signed into law by President Gerald Ford on October 4, 1976, becoming Pub. L.Tooltip Public Law (United States) 94–455.
The act increased the percentage standard deduction to 16% ($2,800 max) and minimum standard deduction to $2,100 (joint returns). The general tax credit (max of $35/capita or 2% of $9,000 income) was temporarily extended, and small business tax rates were temporarily lowered through 1977.
For the first time in US history, the Tax Reform Act of 1976 established tax incentives designed to encourage the preservation of historic structures – "sixty years after architectural obsolescence had first been officially recognized in the US tax code."
The act delayed decreasing in the investment tax credit through 1980. It expanded the individual minimum tax and increased the long-term capital gains holding period from 6 months to 1 year.
A unified rate schedule for estate and gift taxes with a $175,000 exemption was created.
The act also created the 501(h) election procedure, allowing 501(c)(3) non-profit organizations to choose to participate in legislative lobbying limited by the annual financial expenditure on that lobbying, rather than its overall extent.
The act also included a provision preventing states from enacting taxes on electricity companies that discriminated on out of state customers. This was relevant to the ongoing court case of Arizona v. New Mexico and ultimately provided the basis for the ruling in Arizona Public Service Co. v. Snead.

## Capital Gains

The previous major tax legislation (Tax Reform Act of 1969) had established a 10% minimum tax and while it had left long-term capital gains under $50,000 to continue to qualify for the 25 percent alternative capital gains tax rate, it increased the rate on gains over $50,000 to 29.5 percent in 1970, 32.5 percent in 1971, and 35 percent (one-half the 70 percent top tax rate applicable to ordinary income) in 1972 and later years.
This Act increased the minimum tax rate to 15%. The Act also increased the holding period defining long-term capital gains, which receive preferential tax treatment, from six months to one year.
# Sparagovići

Sparagovići is a village in the Ston municipality, Dubrovnik-Neretva County, Croatia. It is connected by the D414 highway.

## Demographics

According to the 2021 census, its population was 104.
# St Mary of the Angels, Liverpool

53°24′58″N 2°58′34″W﻿ / ﻿53.416°N 2.976°W﻿ / 53.416; -2.976
St. Mary of the Angels is a former Roman Catholic church in Everton, Liverpool, built in 1907. It has a magnificent altar of marble, imported to bring Rome to Liverpool. The building of the church was funded by Amy Elizabeth Imrie, a Catholic convert and nun, who became an abbess of the Poor Clare Sisters. She was the heiress to the White Star Line shipping fortune when her uncle, William Imrie, died in 1906.
The church is a Grade II Listed Building; its interiors are also listed. The Roman Catholic Archdiocese of Liverpool shut the church in Fox Street in 2001 and has stated that the church will never be reopened. The Archdiocese was prevented by Liverpool City Council in 2002 from stripping the church's Italian High Renaissance-style interior fixtures and fittings.
The Church was rented out to the Whitechapel Centre (a charity supporting the homeless in Liverpool) until 2005 and since 2006 has become a rehearsal space for the Royal Liverpool Philharmonic orchestra, which rebranded the building as "The Friary". It is not accessible to the public.
# UBASH3A

Ubiquitin-associated and SH3 domain-containing protein A is a protein that in humans is encoded by the UBASH3A gene.
# Netaji Subhash Chandra Bose Memorial PG college

Government Degree College Hamirpur better known as Neta Ji Subash Chandra Bose Memorial PG College is a government college located in Anu Hamirpur, Himachal Pradesh, India. The college is affiliated with Himachal Pradesh University.

## Background

Government College Anu Hamirpur is located in the district headquarter of Hamirpur. The college was originally named Government Degree College, but in 1995 it changed its name to Neta Ji Subash Chandera Bose Memorial College Hamirpur. The college near traveling sources Airport, Gaggal Airport Dharmashala , Kangra, Railway Station In Una, Una Himachal Railway Station and Bus Stand Hamirpur.
# Sigma Virus

Sigma Virus may refer to:
* Sigmaviruses, a clade of viruses in the family Rhabdoviridae that infect dipterans.
* The Sigma Virus from the Mega Man X video game series, and a major plot point in Marvel vs. Capcom Infinite
# Sweet Sixteen (Abdullahi novel)

Sweet Sixteen, A Coming of Age Story is a 2017 novel by Nigerian politician and writer Bolaji Abdullahi.
The book focuses on Aliya, a young woman who must remind her father that she is no longer a child but a young adult. Sweet Sixteen was featured in the 2019 Joint Admission and Matriculation Board of the Federal Republic of Nigeria as the Novel for Literature in English.

## Synopsis

The events of Sweet Sixteen take place over a weekend and follow Aliya, who has recently turned sixteen. Her father, a retired journalist, has written her a lengthy letter that reflects on her life thus far and gives her advice for the future.

## Development

Abdullahi drew inspiration for the novel from his daughters, who he noted "were growing up very fast". He was concerned with the "kind of values they were growing up with in the midst of so much that was happening all over the country" and wrote his eldest daughter a letter. She shared the note with her friends, some of whom contacted Abdullahi to discuss topics such as sexuality, prompting him to write Sweet Sixteen in order to reach a larger group of people.

## Reception

A reviewer for The Guardian, Akin Oseni, noted that "whether Bolaji Abdullahi has been a success as a politician or otherwise is an exclusive debate for political jurists to negotiate. But with the gift of Sweet Sixteen, there is the possibility that our author may have more to offer humanity in Literature than in politics." The Daily Trust wrote that it was a "compelling tale, loaded with morality and textured with a rich lyrical prose and young adult lingo…story-story, my bestie, OMG among others."
# Treat U Right

Professional ratings :
| Review scores ||
| Source | Rating |
| AllMusic | link |
Treat U Right is the only studio album by American pop group BlackGirl, released on May 10, 1994, by RCA Records. It includes the singles "Krazy", "90's Girl", "Where Did We Go Wrong" and a cover of the Staple Singers' "Let's Do It Again".

## Personnel

* Pam Copeland – vocals, background vocals
* Nycolia "Tye-V" Turman – vocals, background vocals
* Rochelle Stuart – vocals, background vocals
* Teddy Riley, Menton Smith, Antwone Dickey, David Roland Williams, Walter Scott, Chris Smith – remix on track 13

## Charts

Album - Billboard (North America)
| Year | Chart | Position |
| 1997 | Top Heatseekers | 1 |
| 1997 | The Billboard 200 | 46 |
# General Reid

General Reid may refer to:
* Charles Reid (Indian Army officer) (1818–1901), British East India Company general
* Denys Whitehorn Reid (1897–1970), British Indian Army major general
* George Reid (soldier) (1733–1815), New Hampshire Militia brigadier general
* George Croghan Reid (1876–1961), U.S. Marine Corps brigadier general
* John Reid (British Army officer) (1721–1807), British Army general
* William Reid (British Army officer) (1791–1858), Corps of Royal Engineers Board of Ordnance major general
# Tchangmargarya multilabiata

Tchangmargarya multilabiata is a species of large operculate freshwater snail, an aquatic gastropod mollusc in the family Viviparidae, the river snails.

## Distribution

This species appear to be endemic to lakes in Stone Forest, e.g. Lake Changhu, Lake Yuehu and Lake Guangtangzi in Yunnan Province in the China.

## Description

Zhang et al. (2015) provided details about the shell and about the radula.
# Speed calling

Speed calling service allows telephone subscribers to assign one or two digit speed calling codes, by dialing a change speed calling list access code, a feature code, and a new telephone number. Thereafter, the subscribers need only use the assigned speed code to reach the desired party rather than dial the long phone number. This service became commonplace in the 1970s with the spread of Stored Program Control exchanges capable of implementing the required databases. It remains useful in installations of many extensions where programming each telephone set would be arduous. Speed calling subscriptions have largely been replaced by the introduction of telephone handsets which incorporate a local version of speed dial.
Speed Calling allows subscribers to program shortcuts for telephone numbers to dial them quickly with just one or two digits. Both Speed Calling 8 and Speed Calling 30 require a subscription from your local telephone company.
Speed Calling 8 allows subscribers to assign a telephone number to each of the digits 2 through 9, a total of eight numbers. To program the numbers, dial *74, followed by the digit 2 through 9 to assign the number to, followed by the full telephone number as you would normally dial it. Then, to dial the number in the future, dial the digit 2 through 9 followed by #.
Speed Calling 30 allows subscribers to assign a telephone number to each of the numbers 20 through 49, a total of 30 numbers. To program the numbers, dial *75, followed by the number 20 through 49 to assign the number to, followed by the full telephone number as you would normally dial it. Then, to dial the number in the future, dial the number 20 through 49 followed by #.
# St Mary of the Angels, Worthing

The Church of St Mary of the Angels, Worthing, is in Worthing, West Sussex, England. It is a Grade II listed building and the earliest of the four Roman Catholic churches in Worthing. It is an active Roman Catholic parish church in the diocese of Arundel & Brighton and the Worthing deanery.

## History

The Church of St Mary of the Angels was opened by Thomas Grant, Roman Catholic bishop of Southwark, the first local Roman Catholic bishop since the Reformation.
The church was built on land bought by Thomas Gaisford, owner of Offington Hall in Broadwater. Previously Gaisford had allowed the new chapel he had built at Offington Hall to be used by the public from 1859. Gaisford had previously married the Catholic Lady Emily St Lawrence, daughter of Thomas St Lawrence, 3rd Earl of Howth and Lady Emily de Burgh. The church was the first place of Catholic worship in Worthing.
The church was built with the Our Lady of Sion convent adjacent to the church. The convent is run by the Sisters of Sion, who also founded the nearby independent school Our Lady of Sion School. The church lies at the corner of Richmond Road and Crescent Road, close to the triumphal arch of Park Crescent.

## Architecture

Originally designed by Henry Clutton in the style of French Gothic revival with an exterior built of red brick with Portland stone, the church was extended by Frederick Walters in 1897-1907 to include a baptistery and an extension to the porch and sacristy. The church contains a 76-foot-tall (23 m) bell tower with a miniature spire.
# UCR Graduate School of Education

The Graduate School of Education at the University of California, Riverside offers credentials and MA and PhD programs in various fields of teacher education and educational administration. Significant research centers include the California Community College Collaborative, a professional development, leadership training and policy research institute for the community college system, and the Copernicus Project, dedicated to increasing the quality of science educators and education. Also notable is a center dedicated to researching and supporting education for autistic children.
In 2007 the school encountered controversy due to its lack of a diverse faculty.
# Sound of the Republic

Sound of the Republic is the fourth studio album by Swedish hardcore punk band Raised Fist.

## Track listing

* You Ignore Them All – 3:32
* Perfectly Broken – 3:11
* Sunlight – 3:01
* Sound of the Republic – 2:52
* Killing It – 3:27
* Back – 2:35
* Hertz Island Escapades – 2:40
* Some of These Times – 3:36
* Nation of Incomplete – 2:23
* And Then They Run – 3:38
* Bleed Under My Pen – 2:27
* Time Will Let You Go; All Alone, I Break – 3:55

### Previously-Unreleased Version of Time Will Let You Go

A rare, early version of Time Will Let You Go was released on the second disc of Burning Heart's Heartattack Vol. 1 Compilation. In contrast to the hard rock version heard on Sound of the Republic, the Heartattack version is a tekno-metal-hardcore version which is much more listener-friendly than the version found on Sound of the Republic. The Heartattack version also is part of a collection of demo recordings which secured Raised Fist a recording contract. The Heartattack version is listed on the CD packaging and disc art as simply Time Will Let You Go instead of Time Will Let You Go; All Alone, I Break as seen on Sound of the Republic.

## Musicians

* Marco Eronen - Guitar
* Daniel Holmberg - Guitar
* Matte Modin - Drums
* Andreas "Josse" Johansson - Bass
* Alexander "Alle" Hagman - Vocals
# Silver Bullet Express

The Silver Bullet Express, also known as the Sunday River Ski Train, was a privately owned and operated ski train that ran from Portland, Maine, to Sunday River Ski Resort near Bethel, Maine. The ski train was owned by Sunday River and sponsored by Coors Light. The train left Portland at 6:45 am, arriving in Bethel at 8:45 am, at which point passengers transferred to buses which would take them to the mountain. The return trip would depart Bethel at 5:15 pm. Amenities included a dining car, parlor car, and a retrofitted boxcar for carrying skis and snowboards. It operated from 1993 until 1996.

## History

In 1993, Les Otten who owned Sunday River envisioned a ski train that would connect the mountain with Auburn, Portland and Boston (through a Portland to Boston passenger rail line that never materialized until 2001 in the form of the Amtrak Downeaster). Otten appointed Carl Spangler to head the ski train effort. That summer a set of seven heritage cars was purchased from Indiana Rail Road, and the St. Lawrence and Atlantic Railroad was hired to operate the train. Buses were also purchased from Chicago Transit Authority to carry skiers from the station in Bethel to the mountain.
# Sweet Sixteen (2016 film)

Sweet Sixteen (Chinese: 夏有乔木，雅望天堂; pinyin: Xià Yǒu Qiáomù Yāwàng Tiāntáng, literally combining the names of the main characters) is a 2016 Chinese romance film directed by Jo Jin-kyu and starring Kris Wu, Han Geng, Joo Won and Lu Shan. It was released in China by Heng Ye Film Distribution on August 5, 2016.

## Plot

Xiao Tian and Shu Yawang are close childhood friends. As a high school student, Yawang is asked by her father to tutor Xia Mu, a boy several years younger than her with a traumatizing past who is taken in by her family. Yawang, Tian and Xia Mu grow up together, and Tian and Yawang fall in love and begin a relationship. Although Yawang comes to see Xia Mu as a younger brother, Xia Mu, who grows into a quiet and brooding teenager, develops feelings for Yawang. Tian enrols in a military academy and Yawang goes to college, and they eventually get engaged.
Yawang graduates and starts working for a landscape development company, but becomes the target of unwanted romantic attention from Qu Weiran, the boss of a company that has connections to Yawang's employer. Xia Mu confesses his feelings for Yawang; she replies that she will always be there for him as his older sister, but her heart belongs to Tian. After a company event, Yawang is drugged and raped by Weiran. When Xia Mu finds out about the assault, he goes to Weiran's office to confront him. Yawang races there to stop him from doing something rash, arriving just as Xia Mu shoots Weiran. She rushes Xia Mu out of the building, and he goes on the run. However, Weiran survives the attack, and Yawang discovers that she is pregnant with Weiran's child. She agrees to marry Weiran if he drops the charges against Xia Mu. Heartbroken, she breaks off all contact with Tian, and her parents urge Tian to move on. When Xia Mu learns about Yawang's pregnancy, he brings her to have an abortion, feeling that he would rather ruin his own life than see Yawang and her child live in misery.
Xia Mu turns himself in and is sentenced to seven years in jail. He is saved from life imprisonment since he willingly confesses his crime. Yawang in turn takes her rape case to court. Weiran is found guilty and receives a ten-year prison sentence. Tian asks Yawang to reconsider ending their relationship as his feelings for her have not changed, but she says that they can't go back to the way things were. On a visit to Xia Mu in prison, Yawang tells him that she will wait for him.

## Cast

* Kris Wu as Xia Mu
* Han Geng as Tang Xiao Tian
* Lu Shan as Shu Yawang
* Bao Bei'er as Zhang Jingyu
* Joo Won as Qu Weiran
* Zhang Yao as Xiao Xue

## Reception

The film grossed CN¥151.9 million at the Chinese box office.
# Moel Gyw

Moel Gyw is a hill in Denbighshire, North Wales and forms part of the Clwydian Range. It is situated just to the south of Moel Famau and Foel Fenlli.