# 2010 Mutua Madrileña Madrid Open – Women's doubles

Cara Black and Liezel Huber were the defending champions, but they chose not to compete together. Black partnered up with Elena Vesnina, but they lost to Chan Yung-jan and Zheng Jie in the first round. Huber teamed with Anabel Medina Garrigues, but they lost to Chuang Chia-jung and Vania King in the second round. Venus and Serena Williams won in the final 6–2, 7–5 against Gisela Dulko and Flavia Pennetta.

## Seeds

The top four seeds received a bye into the second round.
* Serena Williams / Venus Williams (champions)
* Nuria Llagostera Vives / María José Martínez Sánchez (semifinals)
* Nadia Petrova / Samantha Stosur (second round)
* Liezel Huber / Anabel Medina Garrigues (second round)
* Cara Black / Elena Vesnina (first round)
* Lisa Raymond / Rennae Stubbs (second round)
* Bethanie Mattek-Sands / Yan Zi (second round)
* Gisela Dulko / Flavia Pennetta (final)

## Draw
### Key

* Q = Qualifier
* WC = Wild card
* LL = Lucky loser
* Alt = Alternate
* SE = Special exempt
* PR = Protected ranking
* ITF = ITF entry
* JE = Junior exempt
* w/o = Walkover
* r = Retired
* d = Defaulted
* SR = Special ranking

### Finals

| Semifinals | Semifinals | Semifinals | Semifinals | Final | Final | Final | Final |
| 1 | Serena Williams Venus Williams | 7 | 6 | | | | |
| | Shahar Pe'er Francesca Schiavone | 5 | 2 | | | | |
| | Shahar Pe'er Francesca Schiavone | 5 | 2 | 1 | Serena Williams Venus Williams | 6 | 7 |
| | | | | 8 | Gisela Dulko Flavia Pennetta | 2 | 5 |
| 8 | Gisela Dulko Flavia Pennetta | 6 | 6 | 8 | Gisela Dulko Flavia Pennetta | 2 | 5 |
| 2 | Nuria Llagostera Vives María José Martínez Sánchez | 2 | 4 | | | | |

### Top half

| First round | First round | First round | First round | Second round | Second round | Second round | Second round | Second round | Quarterfinals | Quarterfinals | Quarterfinals | Quarterfinals | Semifinals | Semifinals | Semifinals | Semifinals |
| | | | | 1 | S Williams V Williams | 7 | 6 | | | | | | | | | |
| | S Cîrstea S Peng | 0 | 3 | | A Rosolska Y Shvedova | 6$^4$ | 2 | | | | | | | | | |
| | A Rosolska Y Shvedova | 6 | 6 | | | | | | 1 | S Williams V Williams | 6 | 6 | | | | |
| | V Dushevina E Makarova | 3 | 2 | | | | | | | M Kirilenko A Radwańska | 2 | 4 | | | | |
| | M Kirilenko A Radwańska | 6 | 6 | | M Kirilenko A Radwańska | 7 | 3 | [10] | | | | | | | | |
| | Y-j Chan J Zheng | 6 | 7 | | Y-j Chan J Zheng | 6$^2$ | 6 | [7] | | | | | | | | |
| 5 | C Black E Vesnina | 0 | 6$^6$ | | | | | | | | | | 1 | S Williams V Williams | 7 | 6 |
| | | | | | | | | | | | | | | S Pe'er F Schiavone | 5 | 2 |
| | | | | 4 | L Huber A Medina Garrigues | 2 | 6 | [9] | | | | | | | | |
| | S Errani R Vinci | 0 | 4 | | C-j Chuang V King | 6 | 2 | [11] | | | | | | | | |
| | C-j Chuang V King | 6 | 6 | | | | | | | C-j Chuang V King | 6$^3$ | 3 | | | | |
| | T Garbin R Kops-Jones | 1 | 2 | | | | | | | S Pe'er F Schiavone | 7 | 6 | | | | |
| | S Pe'er F Schiavone | 6 | 6 | | S Pe'er F Schiavone | 6 | 6 | | | | | | | | | |
| WC | L Domínguez Lino A Parra Santonja | 2 | 4 | 6 | L Raymond R Stubbs | 0 | 2 | | | | | | | | | |
| 6 | L Raymond R Stubbs | 6 | 6 | | | | | | | | | | | | | |

### Bottom half

| First round | First round | First round | First round | First round | Second round | Second round | Second round | Second round | Second round | Quarterfinals | Quarterfinals | Quarterfinals | Quarterfinals | Quarterfinals | Semifinals | Semifinals | Semifinals | Semifinals |
| 8 | G Dulko F Pennetta | 6 | 7 | | | | | | | | | | | | | | | |
| | K Peschke K Srebotnik | 3 | 6$^3$ | | 8 | G Dulko F Pennetta | w/o | | | | | | | | | | | |
| WC | D Safina Á Szávay | 2 | 6 | [10] | WC | D Safina Á Szávay | | | | | | | | | | | | |
| | A Amanmuradova S-w Hsieh | 6 | 3 | [8] | | | | | | 8 | G Dulko F Pennetta | 6 | 7 | | | | | |
| | O Govortsova A Kudryavtseva | 6 | 6$^1$ | [5] | | | | | | | A Rodionova P Schnyder | 4 | 5 | | | | | |
| | A Rodionova P Schnyder | 1 | 7 | [10] | | A Rodionova P Schnyder | 4 | 6 | [10] | | | | | | | | | |
| | | | | | 3 | N Petrova S Stosur | 6 | 4 | [6] | | | | | | | | | |
| | | | | | | | | | | | | | | | 8 | G Dulko F Pennetta | 6 | 6 |
| 7 | B Mattek-Sands Z Yan | 6$^6$ | 6 | [10] | | | | | | | | | | | 2 | N Llagostera Vives M J Martínez Sánchez | 2 | 4 |
| | I Benešová B Záhlavová-Strýcová | 7 | 2 | [1] | 7 | B Mattek-Sands Z Yan | 7 | 3 | [8] | | | | | | | | | |
| | V Ruano Pascual M Shaughnessy | 6 | 7 | | | V Ruano Pascual M Shaughnessy | 6$^5$ | 6 | [10] | | | | | | | | | |
| WC | B García Vidagany S Soler Espinosa | 3 | 6$^6$ | | | | | | | | V Ruano Pascual M Shaughnessy | 3 | 7 | [7] | | | | |
| | N Grandin A Spears | 4 | 4 | | | | | | | 2 | N Llagostera Vives M J Martínez Sánchezx` | 6 | 6$^6$ | [10] | | | | |
| | L Dekmeijere A Kleybanova | 6 | 6 | | | L Dekmeijere A Kleybanova | 0 | 2 | | | | | | | | | | |
| | | | | | 2 | N Llagostera Vives M J Martínez Sánchez | 6 | 6 | | | | | | | | | | |