OpenLLM-France/wikimedia huggingface dataset:
# Diastereomeric recrystallization

Diastereomeric recrystallisation is a method of chiral resolution of enantiomers from a racemic mixture. It differs from asymmetric synthesis, which aims to produce a single enantiomer from the beginning, in that diastereomeric recrystallisation separates two enantiomers that have already mixed into a single solution. The strategy of diastereomeric recrystallisation involves two steps. The first step is to convert the enantiomers into diastereomers by way of a chemical reaction. A mixture of enantiomers may contain two isomers of a molecule with one chiral center. After adding a second chiral center in a determined location, the two isomers are still different, but they are no longer mirror images of each other; rather, they become diastereomers.
In a prototypical example, a mixture of R and S enantiomers with one chiral center would become a mixture of (R,S) and (S,S) diastereomers. (The R-S notation is explained here.) The conversion of the enantiomeric mixture into a diastereomer pair, depending on the nature of the chemicals, can be via covalent bond formation with the enantiopure resolving agent, or by salt formation, the latter being particularly convenient since acid base chemistry is typically quite operationally simple and high yielding.
The second step, once the diastereomers have formed, is to separate them using recrystallisation. This is possible because enantiomers have shared physical properties such as melting point and boiling point, but diastereomers have different chemical properties, so they can be separated like any two different molecules. It is these, now different, physical properties e.g. Melting point & Enthalpy of fusion which determine the eutectic composition (see Eutectic system) which correlates with the maximum yield of pure diastereomer in the crystallization (R$_{max}$, see example melting point phase diagram of a diastereomeric system across all compositions in Figure 1). Various methods have been developed to screening diastereomeric resolutions by determining the eutectic composition as a means of ranking for yield efficiency.
# Sumner Paine

Sumner Paine (May 13, 1868 – April 18, 1904) was an American shooter. He competed at the 1896 Summer Olympics in Athens.

## Biography

Sumner Paine was born in Boston on May 13, 1868. His father was Charles Jackson Paine, who was a general in the Union Army during the American Civil War, and also was the older brother to John Paine. Sumner briefly attended Harvard University before ending up at the University of Colorado School of Medicine, he earned an M.D. but never practiced, instead he went off to Paris, France, to work.
Paine entered all three of the pistol events in the 1896 Games. He, along with his brother John Paine, was disqualified from the rapid fire pistol because their firearms were not of the appropriate caliber.
The Paine brothers used Colt revolvers in the 25 metre military pistol event, these pistols were superior to the arms used by their opponents, and the brothers had little difficulty winning the top two spots. Sumner finished second with 380 points on 23 hits (of 30 shots) to John's 442 points on 25 hits. The next closest shooter (Nikolaos Morakis from Greece) scored only 205 points.
After winning the military pistol, John withdrew from the 30 metre free pistol event, Sumner easily won this event as well, scoring exactly the same number of points (442) as John had to win the military pistol event, he did this on one fewer hit (24), though, in this case, the second place competitor scored 285 points.
In 1901, Paine went home to find his wife in bed with his daughter's music teacher. To ward him away from the house, he fired four shots at him, missing each time. He was briefly jailed and charged with assault until the police realized who he was and accepted that he must have missed on purpose. He was then released.
Paine died in Boston on April 18, 1904, at age 35, due to pneumonia.
# Coffeeville Lock and Dam

Coffeeville Lock and Dam are located on the Tombigbee River in Choctaw County, Alabama near the town of Coffeeville operated by the US Army Corps of Engineers. Construction on the lock began in 1956 and while the lock was operational in 1960, all works were not completed until 1965. They were originally known as Jackson Lock and Dam.
# Palazzo Puccini, Pistoia

The Palazzo Puccini is a former aristocratic palace located at Via Can Bianco in central Pistoia, Tuscany, Italy. The palace is now used as a boutique guest house/residence.

## Description

The Renaissance-style facade is simple with stone portals and window frames. The corners also betray rusticated stone elements. While acquired by the ancient Puccini family in the 17th century, however, the palace was refurbished in the 18th century, including frescoes by Luigi Mecherini. The Puccini included a number of prominent art collectors and philanthropists. Puccino di Fortino di Puccino was gonfalonieri of Pistoia in 1339. Fra Puccio Puccino was an Augustinian friar who cared for the townsfolk ill with the plague in 1340. Giuseppe and Tommasso Puccini were professors of Medicine and Anatomy respectively at the University of Pisa. Another Tomasso was a scholar and director of the Uffizi Gallery, and is remembered that during the Napoleonic occupation, for having protected almost all the collection from confiscation. Tomasso's sister Maddalena Puccini was known for her support of the hospitals of the convalescing, while her son, Niccolò, who was the last of the family in the 19th century, endowed all his goods to the local orphanage or the city. Up to his day, the palace had a prominent collection of artworks, subsequently moved to Villa Puccini in Scornio.
# Falsimohnia albozonata

Falsimohnia albozonata is a species of sea snail, a marine gastropod mollusk in the family Buccinidae, the true whelks.
# Sonja Vectomov

Sonja Vectomov (born 21 May 1979) is a Czech-Finnish electronic musician and composer who descends from a family rooted in the classical music world. Vectomov is married to American conductor David Woodard. Her parents are Vladimír Večtomov and Sonja Vectomov.

## Education

In the early 2000s Vectomov studied at Norwich University of the Arts, where she was awarded a Bachelor of Arts with Honours degree in 2005.

## Career

Vectomov's initial music experiments began during the 1980s in Finland and involved musique concrète with home tape recorders, four years of performing and touring with the children's choir Vox Aurea [fi] under the direction of Kari Ala-Pöllänen [fi], and violin and piano studies under a curriculum for precocious children at Keski-Suomen konservatorio, where her father Vladimír Večtomov taught classical guitar. Her grandfather Ivan Večtomov, also a composer, was a cellist with the Czech Philharmonic for 22 years, and her uncle was the cellist Saša Večtomov.
During the mid-1990s, Vectomov moved to Prague to assume a 1st violin chair with the Pražský studentský orchestr under the direction of Mirko Škampa [cs]. Concomitantly she monitored the electronic music scenes in Finland and England.
As a solo artist Vectomov's concerts sometimes involve elements of installation, e.g., the transformation of a stage into a salon. She has stated that Conlon Nancarrow and David Byrne are important influences.

### Lamprophrenia

The title of Vectomov's experimental debut album is her self-coined portmanteau of the Neo-Latin / Greek words lampron (bright) and phrenia (mind). The album features electronic compositions with vocals, and is considered unpredictable and "full of unexpected twists and turns."
The first single "Two in One," for which Mika Johnson directed a music video featuring prima ballerina Jana Andrsová, "recounts a story of death and transfiguration, interspecies karma and plant consciousness—this maiden release from Lamprophrenia pulses with nucleopatriphobic synthesizer rhythms, violin, viola, harmonica, mandolin and the consummate intonements of Vectomov."

## Miscellaneous

Like both of her parents, Vectomov is a pedagogue. She has designed and taught music workshops for at-risk youths and disadvantaged Romani children in Kutná Hora, Czech Republic.
Vectomov makes a cameo appearance in H*art On, Andrea Culková's 2016 documentary film about the virtually unknown early 20th century writer Milada Součková and her husband, Devětsil-era painter Zdeněk Rykr.
# Trinity Church (Thomaston, Connecticut)

Trinity Church is a historic episcopal church at 160 Main Street in Thomaston, Connecticut. Built in two stages, 1871 and 1880, to a design by Richard M. Upjohn, it is a good example of Gothic and Stick Style architecture. The church was listed on the National Register of Historic Places in 1984. It is now part of a merged parish with St. Peter's of Plymouth.

## Description and history

Trinity Church is prominently located in the center of Thomaston, between the opera house and the public library on the north side of Main Street. It is a wood frame Stick style structure, with a complex roof line and a board-and-batten exterior that is a modern aluminum covering for the original, which lies underneath. Its main roof has a front-facing gable, from which cross gables at full height extend, giving a basically cruciform shape to the roof. At the front there is a hip-roofed extension to the left, and a gabled extension to the right that ends in the square tower. A larger hip-roofed cross section extends at the back of the main building. The tower is square for two stories, then begins a steeply-pitched roof section that ends in an open belfry, with a small pyramidal roof at the top. Stick decorations adorn its gables. The interior is modestly decorated, with exposed curved roof trusses, and decorative woodwork in the chancel area.
The church was designed by Richard M. Upjohn, and is in some respects a continuation of his father's promotion of the Gothic Revival, albeit in a more modern sense. The younger Upjohn's best-known work is the Connecticut State Capitol, and he had already designed four similar churches when he created the design for the Thomaston church, which is larger and more elaborate than those earlier designs.
# Christine Hiebert

Christine Hiebert (born 1960) is a Swiss-born American artist known for her drawing. Her work is included in the collections of the Whitney Museum of American Art and the Metropolitan Museum of Art. She was raised in Pennsylvania and was educated at the University of the Arts.
# Aldavilla, New South Wales

Aldavilla is a rural locality in the Mid North Coast region of New South Wales, Australia, roughly 10 kilometres west of the town of Kempsey. The locality is bordered on three sides by the Macleay River. Fattorini Creek, a tributary of the Macleay, forms its northern boundary.
Aldavilla has a population of 1,230, close to half of whom are inmates of the Mid North Coast Correctional Centre. The locality is also home to Kempsey's airport, which opened in 1930.
Aldavilla Public School, opened in 1871, is located one kilometre outside of Aldavilla, in the neighbouring locality of Yarravel. The school is notable for using a converted train carriage as one of its classrooms.
# Nico Rosso

Nicolas Rosso (Turin, July 19, 1910 - São Paulo, October 1st, 1981) was an Italian-Brazilian comic artist. Born in Italy, he studied with the masters Giacomo Grosso and Giovanni Reduzzi. He also taught Illustration and Costume History at the Bernard Semeriz School of Graphic Arts. He married Tina Billi in 1937 and had two children: Gianluigi Rosso and Valeria Rosso. He lost almost all of his possessions during World War II, moving to Brazil in 1947 (his family arrived the following year). In São Paulo, he started working in the Arts Department of Editora Brasilgráfica. After that, he became a freelance illustrator, drawing covers and comics for several publishers. Rosso has worked with all comic book genres, but his main works were in the horror genre, including the Coffin Joe comics. He was also a professor at the Escola Panamericana de Artes, which he co-founded. He retired in 1976 for health reasons and died in 1981 after suffering three heart attacks. In 1986, he was awarded posthumously with the Prêmio Angelo Agostini for Master of National Comics, an award that aims to honor artists who have dedicated themselves to Brazilian comics for at least 25 years.
# Coen

Coen may refer to:
* Coen (name), a given name and surname
* Enrico Coen (1957), a British botanist
* Coen brothers, a U.S. filmmaker sibling duo
* Coen River, Cape York Peninsula, Queensland, Australia; named after Jan Pieterszoon Coen in 1623
** Coen, Queensland, Australia; named after the Coen River
*** Coen Airport (IATA airport code: CUQ; ICAO airport code: YCOE), Coen, Cook, Queensland, Australia
*** Coen Carrier Station, Coleman Close, Coen, Shire of Cook, Queensland, Australia; a telegraph station
* Coen River (Costa Rica)
* Coen Tunnel, Amsterdam, Netherlands; named after Jan Pieterszoon Coen
** Second Coen Tunnel, Amsterdam, Netherlands; next to the First Coen Tunnel
* Coen Tunnel (Mingo Junction), Ohio, USA; railway tunnel
* SS Jan Pieterszoon Coen, Dutch passenger ship
* Coen rainbow-skink (Liburnascincus coensis), a lizard
# Nerita sanguinolenta

Nerita sanguinolenta is a species of sea snail, a marine gastropod mollusk in the family Neritidae.
# The Great Actor

The Great Actor (Korean: 대배우; RR: Daebaewoo) is a 2016 South Korean film directed by Seok Min-woo and starring Oh Dal-su. It marked Oh's first starring role in a feature film.

## Plot

Stage actor Jang Sung-pil (Oh Dal-su) has performed in minor roles for 20 years and is currently playing the part of a dog in a children's play, but he dreams of becoming a great actor. As he watches fellow performer Sul Gang-sik (Yoon Je-moon), who used to act with him before making it big, Sung-pil believes that his dream is still possible. His hopes rise when world-famous director Cannes Park holds an audition for the character of a priest in his new film Devil’s Blood. When Sung-pil is accused of being an incompetent father and husband, he claims that he will be performing in the Cannes Park movie with Sul Gang-sik. To turn his lies into truth, Sung-pil embarks on a desperate journey to stardom, using every means possible.

## Cast

* Oh Dal-su as Jang Sung-pil
* Yoon Je-moon as Sul Gang-sik
* Lee Geung-young as Cannes Park
* Jin Kyung as Ji-young
* Ko Woo-rim as Kang Won-suk
* Choi Byung-mo as the director
* Kang Shin-il as Dae-ho
* Kim Chul-moo as Kyung-hee
* Park Ji-hwan as Seung-ji
* Ha Ji-eun as Young-suk

## Release & Reception

The film opened on March 30, 2016, topping the box office among domestic films and taking third place overall, just behind American films Zootopia and Batman vs. Superman. The film received mixed reviews, with most critics praising the performances and the story's unexpected depth.
# L. compacta

L. compacta may refer to:
* Leptoxis compacta, the oblong rocksnail, an extinct freshwater snail species endemic to the United States
* Liatris compacta, the Arkansas gayfeather, a herbaceous plant species native to west-central Arkansas in the United States
# Sonja Wiedemann

Sonja Wiedemann (born 8 September 1977) is a German luger who competed from 1999 to 2005. She won two medals in the women's singles at the FIL World Luge Championships with a gold in 1999 and a bronze in 2000.
Wiedemann also won a silver medal in the mixed team event at the 2000 FIL European Luge Championships in Winterberg, Germany.
# The Great Good Place

The Great Good Place may refer to:
* The Great Good Place (book), 1989 book by Ray Oldenburg
* "The Great Good Place" (short story), 1900 short story by Henry James
# Diasporus gularis

Diasporus gularis, also known as the Esmeraldas robber frog, is a species of frog in the family Eleutherodactylidae. It is found in western Colombia (Córdoba Department in the north through Antioquia and Chocó Departments to the Valle del Cauca, Cauca, and Nariño Departments in the southwest) and northwestern and central Ecuador (Esmeraldas, Imbabura, and Chimborazo Provinces).

## Description

Adult males measure 17–22 mm (0.7–0.9 in) and adult females 21–25 mm (0.8–1.0 in) in snout–vent length. The head is as wide as the body and longer than it is wide. The snout is long, and subacuminate in dorsal view, and truncate in lateral view. The tympanum has its upper edge hidden by the low, poorly-defined supra-tympanic fold. The fingers have weak lateral keels and small discs. The toes are basally webbed and have lanceolate discs. Dorsal skin is smooth but may have low tubercles in some specimens. The dorsum is yellowish-tan with yellow flanks. There are some reddish brown dorsal markings: an inter-orbital bar, narrow canthal and broader post-orbital stripes, as well as smaller markings in the scapular region and on the shanks. The iris is golden bronze and has a reddish-brown horizontal streak.
The male advertisement call is a "whistle", consisting of a single tonal note lasting about 0.11 seconds and produced at a rate of 5.2 calls/minute. The call has four harmonics and a peak frequency of 2.7–3.0 kHz.

## Habitat and conservation

Diasporus gularis is a very common frog occurring in both primary forest and disturbed habitats, including deforested areas, at elevations up to 1,770 m (5,810 ft) above sea level but mostly below 400 m (1,300 ft). It is much more common in secondary, degraded vegetation than in primary forests. This adaptable species occurs also in many protected areas and is not facing significant threats.
# Cadi (Surselva)

Cadi, the Sursilvan for "House of God" (Casa Dei), is the historical name of Disentis Abbey and its feudal territories, later part of the Grey League.
The territories in the upper Anterior Rhine valley (Surselva) were given to Disentis Abbey, and thus removed from the direct rule of Raetia Curiensis, by Tello, Bishop of Chur (d. 765). The territory was divided into Sursassiala ("above the gorge", referring to Punt Russein) and Sutsassiala ("below the gorge"). Sursassiala comprised the modern municipalities of Disentis/Mustér, Medel (Lucmagn) and Tujetsch (the latter containing the upper reaches of the Anterior Rhine, with no permanent settlements until the 9th century), Sutsassiala included Sumvitg, Trun and Breil/Brigels. The subjects of Disentis Abbey first used their own seal in 1285. They had their own Landammann (mistral) from 1371. Cadi became an autonomous commune (cumin grond) of the Grey League in 1401. From 1472, the mistral was elected from a ticket of three candidates proposed by the abbot, from the 17th century in free elections. Until 1851, Cadi was divided into four jurisdictions (cuorts) Disentis, Tujetsch, Brigels with Medel, and Trun with Sumvitg.
During 1738–1745, the communes of Cadi purchased their freedom from tithes to the abbey. Cadi as a feudal territory was formally dissolved with the formation of the Canton of Raetia, in 1799, but its organisational structure was preserved until 1851, with two votes in the diet of the Grey League, and from 1803 between two and five representatives in the cantonal legislature of Grisons. The new cantonal constitution of 1851 abandoned the courts, establishing the modern municipalities, forming the Circul da Cadi (Kreis Disentis) within Vorderrhein District (1851–2000), briefly Surselva District (2001–2016), and since 2017 within Surselva Region.
46°42′20″N 8°51′47″E﻿ / ﻿46.705605°N 8.863043°E﻿ / 46.705605; 8.863043
# Coen Boerman

Coen Boerman (born 11 November 1976) is a Dutch former cyclist, who competed as a professional from 2000 to 2002 with Rabobank. He rode in the 2000 Giro d'Italia and the 2001 and 2002 Paris–Roubaix.

## Major results
### 1996

    1st Rund um Köln Amateurs

### 1997

    1st Stage 9 Olympia's Tour
    3rd Road race, National Under-23 Road Championships

### 1998

    1st Kattekoers
    1st Internatie Reningelst [fr]
    2nd Overall Tour du Loir-et-Cher
    2nd ZLM Tour
    3rd Time trial, National Under-23 Road Championships
    6th Overall Olympia's Tour

### 1999

    1st Stage 1 Circuit des Mines
    1st Stage 4 Volta a Lleida
    3rd Overall Olympia's Tour
    3rd Internationale Wielertrofee Jong Maar Moedig

### 2001

    3rd Ronde van Noord-Holland

### 2002

    1st Stage 1 (ITT) Guldensporentweedaagse
    5th Nokere Koerse
# Buckinbah

Buckinbah Station is located on the edge of the Yeoval, New South Wales township that was the first home to Banjo Paterson.
Yeoval was initially known as Buckinbah in the 1860s until the name was changed in 1882.
It remains today as mixed farming land however the original property has been split up between several owners. The present Buckinbah homestead was built between 1915 and 1917.
# Chrysoteuchia hyalodiscella

Chrysoteuchia hyalodiscella is a moth in the family Crambidae. It was described by Aristide Caradja in 1927. It is found in Sichuan, China.
# L'ARP

La Société civile des Auteurs Réalisateurs et Producteurs, acronym L'ARP is France's "Guild of Authors, Directors and Producers." It is a Copyright collective that ensures Collective rights management.
L'ARP co-sponsors City of Lights, City of Angels festival in Los Angeles as well as the VCU French Film Festival in Richmond, Virginia.
# Blas C. Silva Boucher

Blas C. Silva Boucher (2 February 1869 - 27 January 1949) was a twentieth-century Puerto Rican engineer from Ponce, Puerto Rico. He is credited with the creation of the Ponce Creole architectural style, even though he was trained as an engineer, not a designer.

## Early years

Blas Cornelio Silva Boucher was born in Hormigueros, Puerto Rico on 2 February 1869.

## Schooling

Silva received his high school diploma from the Liceo de Mayaguez (Mayaguez Liceum) and then studied engineering in Spain through a scholarship from the Sociedad Protectora de la Inteligencia (Intelligence Protection Society). In Madrid, Silva did freelance school work in road, drainage, and ports engineering. He then entered the prestigious Spanish National Engineering School where he studied for eight years. He did his practicums in Aragon, Catalonia and Valencia, Spain.

## Professional life

He returned to the Island where he took an engineering position in the Puerto Rico Public Works Bureau. Three years later, he resigned to establish his own private engineering practice. When the post of City Engineer became vacant in the city of Ponce, Silva was unanimously selected, from among various applicants, as the candidate to fill the position.

## Death and legacy

Silva died in San Juan on 27 January 1949. Among Silva's most distinguished works are the Font-Ubides House (1913) and the Subira Residence (1910), both listed in the National Register of Historic Places. He also designed and built the Salazar-Candal House (1919).

## Honors

He is honored at Ponce's Park of the Illustrious Ponce Citizens. Ponce's best-known bridge, Puente de los Leones, located over Río Portugués on PR-1/Bulevar Miguel Pou at Calle Lolita Tizol, was named "Puente Blas Silva" before it was renamed Puente de Los Leones.

## Contemporary recognition

The Puerto Rico Historical Preservation Office recently said of him, "Blas Silva was probably the most established of the 'wedding-cake architects' and was thus sought after mostly by the 'nouveau riche' of the period. Silva's houses are among the richest in Ponce, among which the [Font-Ubides] stands out for its circular porches." It added that "Silva, as had other foreign-trained architects, succeeded in integrating classical education with the traditional elements of the Spanish Caribbean."
# Culicoides annettae

Culicoides annettae is a species of Culicoides. It is found in Central America.