OpenLLM-France/wikimedia huggingface dataset:
# Hexafluorothioacetone

Hexafluorothioacetone is an organic perfluoro thione compound with formula CF$_3$CSCF$_3$. At standard conditions it is a blue gas.

## Production

Hexafluorothioacetone was first produced by Middleton in 1961 by boiling bis-(perfluoroisopropyl)mercury with sulfur.

## Properties

Hexafluorothioacetone boils at 8 °C. Below this it is a blue liquid.

### Colour

The blue colour is due to absorption in the visible light range with bands at 800–675 nm and 725–400 nm. These bands are due to T$_1$–S$_0$ and S$_1$–S$_0$ transitions. There is also a strong absorption in ultraviolet around 230-190 nm.

## Reactions

Hexafluorothioacetone acts more like a true thiocarbonyl (C=S) than many other thiocarbonyl compounds, because it is not able to form thioenol compounds (=C-S-H), and the sulfur is not in a negative ionized state (C-S$^−$). Hexafluorothioacetone is not attacked by water or oxygen at standard conditions as are many other thiocarbonyls.
Bases trigger the formation of a dimer 2,2,4,4-tetrakis-(trifluoromethyl)-1,3-dithietane. Bases includes amines.
The dimer can be heated to regenerate the hexafluorothioacetone monomer.
The dimer is also produced in a reaction with hexafluoropropene and sulfur with some potassium fluoride.
Hexafluorothioacetone reacts with bisulfite to form a Bunte salt CH(CF$_3$)$_2$SSO$_2$$^−$.
Thiols reacting with hexafluorothioacetone yield disulfides or a dithiohemiketal:
    R-SH + C(CF$_3$)$_2$S → R-S-S-CH(CF$_3$)$_2$.
    R-SH + C(CF$_3$)$_2$S → RSC(CF$_3$)$_2$SH (for example in methanethiol or ethanethiol).
With mercaptoacetic acid, instead of a thiohemiketal, water elimination yields a ring shaped molecule called a dithiolanone -CH$_2$C(O)SC(CF$_3$)$_2$S- (2,2-di(trifluoromethyl)-1,3-dithiolan-4-one). Aqueous hydrogen chloride results in the formation of a dimeric disulfide CH(CF$_3$)$_2$SSC(CF$_3$)$_2$Cl. Hydrogen bromide with water yields the similar CH(CF$_3$)$_2$SSC(CF$_3$)$_2$Br. Dry hydrogen iodide does something different and reduces the sulfur making CH(CF$_3$)$_2$SH. Wet hydrogen iodide only reduces to a disulfide CH(CF$_3$)$_2$SSC(CF$_3$)$_2$H. Strong organic acids add water to yield a disulfide compound CH(CF$_3$)$_2$SSC(CF$_3$)$_2$OH.
Chlorine and bromine add to hexafluorothioacetone to make CCl(CF$_3$)$_2$SCl and CBr(CF$_3$)$_2$SBr.
With diazomethane hexafluorothioacetone produces 2,2,5,5-tetrakis(trifluoromethyl)-l,3-dithiolane, another substituted dithiolane. Diphenyldiazoniethane reacts to form a three membered ring called a thiirane (di-2,2-trifluoromethyl-di-3,3-phenyl-thiirane)
Trialkylphosphites (P(OR)$_3$) react to make a trialkoxybis(trifluoromethyl)methylenephosphorane (RO)$_3$P=C(CF$_3$)$_2$ and a thiophosphate (RO)$_3$PS.
Hexafluorothioacetone can act as a ligand on nickel.
Hexafluorothioacetone is highly reactive to alkenes and dienes combining via addition reactions. With butadiene it reacts even as low as -78 °C to yield 2,2-bis-(trifluoromethyl)-3,6-dihydro-2H-l-thiapyran.
# Eloji

Eloji or Eloba is a Gram-devta (god of village) folk deity. Statues of Eloji can be found in villages of Rajasthan. He is said to be the lover of Hiranyakashipu's sister Holika. He is shown as a strong man with a mustache exhibiting his long penis in any chowk, or center of a Dhani sitting comfortably with a look of pride on his face. Many songs are sung on holy days by villagers (known as Gair), while playing a folk music instrument similar to a drum, in the praise of his sexual power.

## Ritual

Men beg him for sexual powers and females worship him to be gifted with a male child. On the day of Holi when all men sing Holi songs known as Phag which are songs describing their sexual accomplishments, the married women visit Eloji, bow to him, touch his elongated phallus with awe and tell jokes. It is a joyful ritual.
Newlywed couples pay homage to Eloji. The bride gives a hug to Eloji as He has first right over every woman. He is the best man for every bride.
It is also a way of respecting the sexual power that governs the cosmos.

## Holi

Holi is a festival of abandonment and acknowledgement of animal instincts. In Indian society, sex is normally taboo; public expression of love or sexual desire is condemned. Yet, traditions such as Khajuraho and Tantra establish sex as a tool for self-realization in a person's spiritual journey. The love story of Eloji and Holika is famous in traditional folklore.
# Vivienne Cox

Dame Vivienne Cox, DBE (born May 1959) is a British businesswoman, chairman of the supervisory board of Vallourec, the French multinational steel components company.
Cox was born in 1959 and worked for BP for almost three decades before being named as chairperson of the supervisory board of Vallourec, a French multinational steel components company. She is also a non-executive director of Pearson PLC and a commissioner at the UK's Airports Commission.
Since July 2016, Cox has been a non-executive director of GlaxoSmithKline. In July 2018, she became the first Chair of the Rosalind Franklin Institute.

## Honours

Cox was appointed Commander of the Order of the British Empire (CBE) in the 2016 New Year Honours for services to the economy and sustainability and Dame Commander of the Order of the British Empire (DBE) in the 2022 New Year Honours for services to sustainability, and to diversity and inclusion in business.
# Gharmayn

Gharmayn (Tajik: Ғармайн, Russian: Гармен Garmen, Yaghnobi: Ғармен Gharmen) is a village in Sughd Region, northwestern Tajikistan. It is part of the jamoat Anzob in the Ayni District. Its population was 47 in 2017, down slightly from 49 in 2007. It is sometimes divided into a lower part (Domani Gharmen) and an upper part (Sari Gharmen).
The village consisted of several dwellings, that typically of Yaghnobi villages are constructed of dry stone walls and flat roofs. The village is connected by a road and possesses a water mill. The main crops are potatoes which are grown on the steep slope that the village sits on. There is no terracing.

## Toponymy

The village's name is Yaghnobi for "mountain village". The first part of its name "ғар", the Yaghnobi word for mountain, derives from the Sogdian "ꙋr", also meaning mountain.

## Geography

Gharmayn is situated at an altitude of approximately 2,700 metres (8,900 ft) above sea level. The village is located 98 kilometres (61 mi) from the center of the jamoat Anzob, and 133 kilometres (83 mi) from the center of the Ayni District.

## Demographics

Its population was 47 people as of 2017, slightly down from 49 in 2007.
# Thounaojam Kritina Devi

Thounaojam Kritina Devi (born 10 February 2003) is an Indian professional footballer from Manipur, who plays as a defender for the Indian Women's League club Gokulam Kerala. She has also represented India at the youth level.

## Early life

Kritina hails from Haokha Mamang village in Thoubal district, Manipur. Her father, Thounaojam Rajen Singh, is a farmer while her mother is a home maker. Initially, her father was reluctant to send his only daughter to play football but Devi's uncle Deben Singh persuaded him that it would be good for the girl. Deben Singh's son, Kiyam Amarjit Singh (former Under-17 India captain) and another cousin Thounaojam Jeakson Singh, both played for India team in the Under-17 World Cup. All three families stay close by in the same colony.

## Career

* While Kritina was in Class 6, she took part in a grassroots talent hunt in 2014 and she got hooked to the game.
* In 2019 she played a key role in the three-nation tournament with Thailand and Sweden.
* In July 2020, she was named in the probables for the Under-17 World Cup.
* In February 2021, she was one of the six players from Manipur selected for the Indian team for the international friendly matches in Alanya, Turkey.
* In November 2021, she was called for the U-19 National camp in preparation for the SAFF Women's Championship 2021 to be held in Bangladesh.

## Honours

Manipur
* Senior Women's National Football Championship: 2023–24
# Ian Pino

Ian Pino Soler (born 23 January 1996) is a Spanish footballer who plays as a central defender for Albanian club Tirana.

## Club career

Born in Prats de Lluçanès, Barcelona, Catalonia, Pino represented Damm, Espanyol and Almería before moving abroad with Fulham on 5 September 2015. After only playing for the club's under-23 squad, he returned to his home country the following July after agreeing to a contract with Segunda División B side Jumilla.
Pino made his senior debut on 11 September 2016, coming on as a substitute in a 2–0 home win against Real Murcia. On 11 January of the following year, he moved to Málaga and was assigned to the reserves in Tercera División.
Pino scored his first senior goal on 22 January 2017, netting his team's fourth in a 4–3 defeat of Motril. He made his first team debut on 28 November, starting in a 1–1 home draw against Numancia for the season's Copa del Rey.
On 18 February 2022, Soler signed with USL Championship side Louisville City. On 9 March 2023, Soler and Louisville mutually agreed to terminate his contract to allow him to return to Europe.
In March 2023 he signed with Lithuanian Riteriai Club. On 15 March 2023 he made his A Lyga debut against Dainava. On 22 October 2023, he scored against Banga. On 16 November 2023 it was announced he would leave the club.

## Career Statistics

    As of match played 3 November 2024
Appearances and goals by club, season and competition :
| Club | Season | League | League | League | National cup | National cup | Continental | Continental | Other | Other | Total | Total |
| Club | Season | Division | Apps | Goals | Apps | Goals | Apps | Goals | Apps | Goals | Apps | Goals |
| Jumilla | 2016-17 | Segunda División B | 9 | 0 | — | — | — | — | — | — | 9 | 0 |
| Málaga | 2017-18 | La Liga | 0 | 0 | 1 | 0 | — | — | — | — | 1 | 0 |
| Málaga B | 2018-19 | Segunda División B | 23 | 0 | — | — | — | — | — | — | 23 | 0 |
| Zemplín Michalovce | 2019-20 | Slovak 1st League | 14 | 1 | 0 | 0 | — | — | 0 | 0 | 14 | 1 |
| Zemplín Michalovce | 2020-21 | Slovak 1st League | 28 | 1 | 1 | 0 | — | — | — | — | 29 | 1 |
| Zemplín Michalovce | Total | Total | 42 | 2 | 1 | 0 | — | — | 0 | 0 | 43 | 2 |
| Zagłębie Lubin | 2021-22 | Ekstraklasa | 9 | 0 | 1 | 0 | — | — | — | — | 10 | 0 |
| Louisville City | 2022 | USL Championship | 14 | 0 | 3 | 0 | — | — | 0 | 0 | 17 | 0 |
| Riteriai | 2023 | A Lyga | 16 | 1 | 1 | 0 | — | — | — | — | 17 | 1 |
| Alessandria | 2023-24 | Serie C | 15 | 1 | 0 | 0 | — | — | — | — | 15 | 1 |
| Tirana | 2024-25 | Kategoria Superiore | 12 | 0 | 0 | 0 | 2 | 0 | — | — | 14 | 0 |
| Career total | Career total | Career total | 140 | 4 | 7 | 0 | 2 | 0 | 0 | 0 | 149 | 4 |
* ↑ Includes Copa del Rey, Slovak Cup, Polish Cup, U.S. Open Cup, Lithuanian Cup, Coppa Italia, Albanian Cup
* ↑ Appearance(s) in UEFA Europa Conference League
# Atul Butte

Atul Janardhan Butte or Atul J. Butte is an American biomedical informatician, pediatrician, and biotechnology entrepreneur. He is currently the Priscilla Chan and Mark Zuckerberg Distinguished Professor at the University of California, San Francisco. Since April 2015, Butte has serves as inaugural director of UCSF's Bakar Computational Health Sciences Institute.

## Education and career

Butte was born in Philadelphia to Janardhan Butte and Mangala Butte. He attended Brown University, where he studied computer science as an undergraduate student. As a member of the school's Program in Liberal Medical Education he was guaranteed acceptance to Brown's Alpert Medical School, where he obtained his MD in 1995.
Butte completed a residency in pediatrics and a fellowship in pediatric endocrinology, both at Children's Hospital Boston. In 2004, he completed a Ph.D. from the Harvard–MIT Division of Health Sciences and Technology, supervised by Dr. Isaac Kohane.
Butte moved to California and became an assistant professor at Stanford University in 2005. He later became the Chief of the Division of Systems Medicine at Stanford University School of Medicine and Lucile Packard Children's Hospital where he held the position of an associate professor of pediatrics and (by courtesy) computer science and immunology & rheumatology. He moved to the University of California, San Francisco in 2015.
In April 2012, Butte delivered a TEDMED talk describing his lab's development of techniques using massive amount of publicly available biomedical research data to make new discoveries without running a wet-lab and actually outsourcing experiments using assaydepot.com.
Butte has an h-index of over 110 and is recognized by Publons as a highly cited researcher. He has also founded two biotechnology companies (Personalis and NuMedii) and wrote one of the first books on microarray analysis, Microarrays for an Integrative Genomics.

## Personal life

Butte lives with his wife, Gini Deshpande, a cancer biology and biotechnology entrepreneur, and daughter in Menlo Park, CA. As of 2018, Deshpande was the chief executive officer of NuMedii, an artificial intelligence technology company. His brother Manish J. Butte is a pediatrician at University of California, Los Angeles.

## Awards and honors

In 2013, Butte was recognized as an Open Science Champion of Change by the White House. In 2015, he was elected a member of the National Academy of Medicine. In 2021, Butte was elected as a Fellow of the International Society for Computational Biology. In 2022, he became a fellow of the American Association for the Advancement of Science. In 2024, he received the Award for Excellence in Molecular Diagnostics from the Association for Molecular Pathology and the Morris F. Collen Award of Excellence from the American College of Medical Informatics.
# Pic dels Aspres

Pic dels Aspres is a mountain in the northwest of the principality of Andorra, close to the border with Spain. The nearest town is Arinsal, La Massana.

## Geographic features

Some 250 metres below the summit is a round cirque, approximately 100 metres in diameter, which was formed by glacial erosion during the Last Glacial Maximum and which is now a lake, Estany de les Truites (the trout lake).
The valley to the south of the mountain is used as a ski area.

## History

During the Neolithic, sedentary populations inhabited the dels Aspres hills, and built megalithic dolmens in the area.
# 2012 Kazan Kremlin Cup

The 2012 Kazan Kremlin Cup was a professional tennis tournament played on indoor hard courts. It was the third edition of the tournament which was part of the 2012 ATP Challenger Tour. It took place in Kazan, Russia between 30 January and 5 February 2012.

## Singles main-draw entrants
### Seeds

| Country | Player | Rank$^1$ | Seed |
| TUN | Malek Jaziri | 123 | 1 |
| AUT | Andreas Haider-Maurer | 127 | 2 |
| ESP | Arnau Brugués Davi | 138 | 3 |
| ESP | Daniel Muñoz de la Nava | 139 | 4 |
| CZE | Jan Hájek | 140 | 5 |
| RUS | Teymuraz Gabashvili | 141 | 6 |
| RUS | Evgeny Donskoy | 144 | 7 |
| EST | Jürgen Zopp | 148 | 8 |
* Rankings are as of January 24, 2012.

### Other entrants

The following players received wildcards into the singles main draw:
* Aydin Akhmetshin
* Anton Manegin
* Stanislav Vovk
* Daniyal Zagidullin
The following players received entry from the qualifying draw:
* Radu Albot
* Thomas Fabbiano
* Evgeny Kirillov
* Mikhail Ledovskikh
The following players received entry as lucky losers:
* Illya Marchenko
* Denis Matsukevich

## Champions
### Singles

Jürgen Zopp def. Marius Copil, 7–6$^{(7–4)}$, 7–6$^{(7–4)}$

### Doubles

Sanchai Ratiwatana / Sonchat Ratiwatana def. Aliaksandr Bury / Mateusz Kowalczyk, 6–3, 6–1
# 1841 Goshen Courthouse

The 1841 Goshen Courthouse is located along Main Street (NY 207) in the center of Goshen, New York, the seat of Orange County, New York, United States. It was designed by popular local architect Thornton M. Niven in a Greek Revival style, meant to be a twin of the one he had already built in Newburgh, which at that time shared seat duties with the larger city. Construction of the building was approved by the county legislature in April 1841 and began shortly thereafter.
During construction of the building, the remains of American Revolutionary War Loyalist guerrilla leader Claudius Smith were rumored to have been found on the site and his skull embedded in the masonry above the front door. A plaque commemorating his hanging in Goshen and the associated tradition was dedicated at the site in 2016.
It was used as a courthouse until 1970, when the recently constructed Orange County Government Center made more space available. It was individually listed on the National Register of Historic Places in 1975. It is also a contributing property to the Church Park Historic District.
As of 2007, an annex to the courthouse houses offices of the Orange County Department of Consumer Affairs and other offices. In 2011, after the Orange County Government Center was damaged by Hurricane Irene, three Supreme Court judges relocated their cases to the courthouse. In 2015, county officials announced a $2.9 million plan to improve insulation and handicap accessibility over the course of approximately a year.
# The Mayor of Zalamea (1954 film)

The Mayor of Zalamea (Spanish:El alcalde de Zalamea) is a 1954 Spanish historical drama film directed by José Gutiérrez Maesso and starring Manuel Luna, Alfredo Mayo and Isabel de Pomés. The film is an adaptation of the Golden Age play The Mayor of Zalamea by Pedro Calderón de la Barca.
This version of the play is remembered for Rey's "solemn" interpretation of Felipe II. According to José Lera, quoting the director himself, "Maesso, as director, had to fight "against the bombast, the flawed acting, the poor quality of the dialogue, the bad setting," although he has managed to give a natural aspect to the drama"

## Plot

A company of soldiers under the command of Captain Álvaro de Ataide (Alfredo Mayo) arrives in the town of Zalamea de la Serena, in Badajoz, because of the war in Portugal. The captain of noble descent is staying in the house of a rich farmer, Pedro Crespo (Manuel Luna), mayor of the town, whose daughter Isabel (Isabel de Pomés) Don Álvaro seduces. Pedro Crespo tries to remedy the situation and for Don Álvaro to marry Isabel, but Don Álvaro rejects her for not being of the nobility. This contempt wounds the honor of Pedro's entire family. Even without having jurisdiction over the soldier, Pedro Crespo orders him to be arrested and has Don Álvaro executed by hanging him. Finally King Don Felipe II (Fernando Rey), reviews the mayor's decision, ratifies it and appoints Pedro Crespo perpetual mayor of Zalamea.

## Cast

* Manuel Luna as Pedro Crespo
* Alfredo Mayo as Don Álvaro
* Isabel de Pomés as Isabel
* José Marco Davó as Don Lope de Figueroa
* Alberto Bové as Rebolledo
* Mario Berriatúa as Juan
* Juanita Azores as Chispa
* María Fernanda D'Ocón as Inés
* José Orjas as Don Mendo
* Fernando Rey as El Rey
* Casimiro Hurtado
* José Prada
* Francisco Bernal
* Arturo Marín
* Juan Vázquez
* Manuel Guitián
* Mariano Alcón
* Luis Torrecilla
* Mario Guerrero
# Andrew Goodman

Andrew Goodman may refer to:
* Andrew Goodman (activist) (1943–1964), American social worker and activist
* Andrew Goodman (rugby union) (born 1982), New Zealand rugby union player
* Andrew Goodman (bridge) (born 1946), American bridge player
# The Last One

The Last One may refer to:

## Television

* "The Last One", an episode of Aqua Teen Hunger Force
* "Last Last One Forever and Ever", an episode of Aqua Teen Hunger Force
* "The Last One Forever and Ever (For Real This Time) (We ... Mean It)", an episode of Aqua Teen Hunger Force
* "The Last One" (St. Elsewhere), the 1988 final episode of St. Elsewhere
* "The Last One" (Friends), the final episode of Friends
* The Last One, a documentary by Neal Hutchenson featuring moonshine maker Marvin "Popcorn" Sutton

## Other meanings

* The Last One (software), a computer program from the early 1980s which aimed to allow non-programmers to create application software
* The Last One , a Vertigo mini-series by J. M. DeMatteis
* "The Last One", a song by Cary Brothers from Who You Are, 2007
* "The Last One", a song by Hieroglyphics, from 3rd Eye Vision, 1998
* "The Last One", a song by Maisie Peters from The Good Witch (Deluxe), 2023
# Luba Golovina

Lyubov "Luba" Vladimirovna Golovina (Russian: Любовь Владимировна Головина, Georgian: ლიუბოვ ვლადიმერის ასული გოლოვინა; born 20 April 1990) is a Georgian trampoline gymnast. She has represented Georgia at four Olympic Games (2008, 2012, 2016, 2024). She is the 2019 European Games and 2022 European Championships individual silver medalist. She also won a team bronze medal at the 2023 World Championships and team silver medals at the 2022 and 2024 European Championships.

## Gymnastics career

Golovina began trampoline gymnastics at the age of three, with her parents as her coaches.
Golovina qualified for the trampoline final at the 2008 Summer Olympics, finishing in sixth place. She also qualified for the individual final at the 2010 World Championships but finished last after falling during her third jump. At the 2011 World Championships, she finished 18th in the qualification round.
Golovina finished eighth at the 2012 Olympic Test Event and qualified for the 2012 Summer Olympics. Despite competing with a major back injury, she placed seventh in the final at her second Olympic Games. She did not qualify for the final at the 2013 World Championships, finishing 32nd.
Golovina finished eighth in the individual final at the 2015 World Championships and qualified for the 2016 Summer Olympics. She was injured while competing at the 2016 European Championships. She used money from an International Gymnastics Federation (FIG) scholarship to receive treatment in Turkey and was able to compete at the 2016 Summer Olympics. There, she once again placed seventh in the trampoline final.
Golovina won the individual silver medal at the 2019 European Games held in Minsk, behind Léa Labrousse.
Golovina was not able to train for nine months due to the COVID-19 pandemic. She finished fourth at the 2021 European Championships. She qualified for the final in third place at the 2021 Anadia World Cup, but she made mistakes in the final and only placed seventh.
Golovina helped the Georgian team win the silver medal at the 2022 European Championships. She also won a silver medal in the individual event behind Bryony Page.
Golovina won a bronze medal with the Georgian team at the 2023 World Championships, marking the first time Georgia won a medal at the Trampoline World Championships.
Golovina won a silver medal with the Georgian team at the 2024 European Championships. She qualified for the 2024 Summer Olympics through her results on the 2024 FIG World Cup series. At the age of 34, Golovina represented Georgia at the 2024 Summer Olympics, making her the oldest competitor in the trampoline event, men's or women's. She finished in 11th place in the qualification round, missing out on the final.

## Personal life

Golovina is married to a former football player and gave birth to their son, Alexander, in 2014.