# Thiostannate

Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,
Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed sulfostannates or sulphostannates.
Different cluster anions are known: [SnS$_4$]$^{4–}$, [SnS$_3$]$^{2–}$, [Sn$_2$S$_5$]$^{2–}$, [Sn$_2$S$_6$]$^{4–}$, [Sn$_2$S$_7$]$^{6–}$, [Sn$_2$S$_8$]$^{2–}$, [Sn$_3$S$_7$]$^{2–}$, [Sn$_4$S$_9$]$^{2–}$, [Sn$_5$S$_{12}$]$^{4–}$, or [Sn$_4$S$_{10}$]$^{4–}$.
The number of sulfur atoms coordinated around the tin atom is most commonly four. However there are also complexes with five or six sulfur atoms surrounding the tin. The behaviour for selenium and tellurium differs as only five selenium or four tellurium atoms can bind to a tin atom. The smaller germanium atom can only accommodate four sulfur atoms. For lead it is hard for it to be in the +4 oxidation state. The SnS$_n$ polyhedrons can be standalone in strongly alkaline conditions, or at higher concentrations or less alkaline can condense together. Polyhedra shapes are tetrahedron for four, trigonal bipyramid for five, and octahedron for six sulfur atoms. The polyhedra can be connected at a vertex (corner), or at an edge. Where connected at an edge, four membered rings of -SnSSnS- with internal angles close to 90°. [Sn$_2$S$_7$]$^{6–}$ is corner bridged. Tetrahedra linked by at the corner by a disulfur bridge are unknown.
Sn$_{10}$O$_4$S$_{20}$$^{8-}$ is a supertetrahedron made from 1, 3 and 6 tin atoms connected by oxygen on the interior and sulfur on the surface.
For anions with formula Sn$_x$S$_y$ the condensation ratio c is given by x⁄y. It can vary from 1⁄4 to just below ⁠1/2⁠.

## Synthesis

The first human production of a thiostannate heated tin oxide with sodium carbonate and sulfur:
2SnO$_2$ + 2Na$_2$CO$_3$ + 9S → 2Na$_2$SnS$_3$ + 2CO$_2$ + 3SO$_2$
Transition metal complexes may be prepared by crystallisation from the ligand solvent.
Copper(II) is normally reduced by sulfide S$^{2-}$ in thiostannates to copper(I).

### Anions

| formula | name | coordination | dimensionality | description |
| [SnS$_4$]$^{4−}$ | | 4 | 0 | tetrahedra |
| [Sn$_2$S$_6$]$^{4−}$ | bis(μ-sulfido)-tetrathiolato-di-tin | 4 | 0 | edge shared |
| [Sn$_3$S$_9$]$^{6−}$ | 1,3,5,2,4,6-trithiatristanninane-2,2,4,4,6,6-hexakis(thiolate) | 4 | 0 | 6 membered ring |
| [Sn$_4$S$_{10}$]$^{4-}$ | | 4 | 0 | tetrameric adamantane-like : tetrahedron of tetrahedra, 6 bridging sulfur, 4 terminal sulfur |

## Reactions

Some hydrates are unstable, where water reacts with the sulfide to make hydrogen sulfide gas.

## List

| formula | system | space group | unit cell Å | volume | density | comment |
| Li$_4$SnS$_4$ | orthorhombic | Pnma | a=13.812 b=7.962 c=6.370 | | | |
| [Li$_8$(H$_2$O)$_{29}$][Sn$_{10}$O$_4$S$_{20}$]·2H$_2$O | triclinic | P1 | a = 11.232, b = 13.097, c = 23.735, α = 102.73°, β = 90.43°, γ = 93.44°, Z = 2 | 3399 | | oxothiostannate |
| (NH$_4$)$_4$Sn$_2$S$_6$·3H$_2$O | orthorhombic | P4$_1$2$_1$2 | a =8.56294 b =8.56294 c= 22.7703 | | | |
| (NH$_4$)$_6$Sn$_3$S$_9$·1.3H$_2$O | monoclinic | C2 | a 16.9872 b 10.54777 c 21.0871 β 108.0389° | 3592.6 | 2.154 | colourless |
| [(CH$_3$)$_3$NH]$_2$Sn$_3$S$_7$ | | | | | | |
| [(CH$_3$)$_4$N]$_2$Sn$_3$S$_7$·H$_2$O | | | | | | |
| [(CH$_3$)$_4$N]$_4$Sn$_4$S$_{10}$ | | | | | | |
| [(CH$_3$CH$_2$)$_4$N]$_2$Sn$_3$S$_7$ | | | | | | |
| [(CH$_3$CH$_2$CH$_2$)$_4$N]$_2$Sn$_4$S$_9$ | | | | | | |
| [(CH$_3$CH$_2$CH$_2$CH$_2$)$_4$N]$_2$Sn$_4$S$_9$ | | | | | | |
| [(CH$_3$CH$_2$CH$_2$)$_4$N][(CH$_3$)$_3$NH]Sn$_4$S$_9$ | | | | | | |
| (C$_{12}$H$_{25}$NH$_3$)$_4$Sn$_2$S$_6$ ·2H$_2$O | | | | | | |
| [dabcoH]$_2$Sn$_3$S$_7$ | | | | | | |
| (Et$_4$N)$_2$Sn(S$_4$)$_3$ | | | | | | |
| (Et$_4$N)$_2$Sn(S$_4$)$_2$(S$_6$) | | | | | | |
| ((CH$_3$C(NH$_2$)$_2$)$_8$Sn$_2$S$_6$SnS$_4$ | monoclinic | C 1 2/m 1 | a=23.7739 b=16.0647 c=11.8936 β=99.029 Z=4 | 4486.1 | 1.702 | colourless |
| ((CH$_3$)$_2$NH$_2$)(NH$_4$)SnS$_3$ dimethylammonium ammonium | orthorhombic | P2$_1$2$_1$2$_1$ | a=5.9393 b=12.1816 c=12.4709 Z=4 | 902.26 | 2.054 | colourless |
| (DBNH)$_2$Sn$_3$S$_6$ DBN=1,5-diazabicyclo[4.3.0]non-7-ene | | | | | | Sn(II) and Sn(IV) |
| (1AEP)$_2$Sn$_3$S$_7$ 1AEP = 1-(2-aminoethyl) piperidine | orthorhombic | P2$_1$2$_1$2$_1$ | a=13.2299 b= 22.2673 c=9.0772 Z=4 | 2674.1 | | pale yellow |
| SnS$_2$·en | monoclinic | C2/c | a 15.317 b 10.443 c 12.754, β 93.62° | | | |
| [enH]$_4$[Sn$_2$S$_6$]·en | triclinic | P1 | a 9.8770 b 9.9340 c 15.4230, α 72.630° β 86.220° γ 81.380° | | | |
| Na$_2$SnS$_3$ | | R3m | a=3.834 c=19.876 Z=2 | 253 | 3.43 | |
| Na$_4$SnS$_4$ | tetragonal | P421c | a=7.837 c=6.950 | 427 | 2.64 | |
| Na$_4$Sn$_2$S$_6$ | | | | | | |
| Na$_4$Sn$_2$S$_6$·14H$_2$O | triclinic | P1 | a=10.114 b=7.027 c=9.801 α=108.30 β=92.18 γ=91.11 Z=1 | 663 | 1.95 | |
| Na$_4$SnS$_4$·14H$_2$O | monoclinic | C2/c | a=8.622 b=23.534 c=11.347 β=110.53 Z=4 | 2156 | 1.82 | |
| Na$_4$Sn$_3$S$_8$ | | | | | | |
| Na$_5$[SnS$_4$]Cl·13H$_2$O | monoclinic | P2$_1$/m | a=8.4335 b=11.4958 c=11.5609 β=91.066 Z=2 | 1120.63 | 1.872 | |
| Na$_4$Sn$_2$S$_6$·5H$_2$O | | | | | | |
| Na$_6$Sn$_2$S$_7$ | | C2/c | a=9.395 b=10.719 c=15.671 β=109.97 Z=4 | 1483 | 2.69 | |
| Mg$_2$SnS$_4$ | orthorhombic | Pnma | a=12.93 b=7.52 c=6.16 Z=4 | 599 | 3.28 | |
| Na$_2$MgSnS$_4$ | | R3m | a 3.7496 b 3.7496 c 19.9130 | | | |
| (Ph$_4$P)$_2$Sn(S$_4$)$_3$ | | | | | | |
| K$_2$SnS$_3$ ·2H$_2$O | | | | | | |
| K$_2$SnS$_3$·2H$_2$O | orthorhombic | Pnma | a=6.429 b=15.621 c=10.569 Z=4 | 1061 | 2.06 | |
| K$_2$Sn$_2$S$_5$ | | | | | | |
| K$_2$Sn$_3$S$_7$ ·H$_2$O | | | | | | |
| [K$_4$(H$_2$O)$_4$][SnS$_4$] | | | | | | |
| Ca$_2$SnS$_4$ | orthorhombic | Pnma | a=13.74 b=8.23 c=6.44 Z=4 | 728 | 2.99 | |
| [H$_2$tepa][V$^{III}$(tepa)(μ-Sn$_2$Q$_6$)]$_2$ | orthorhombic | Abm2 | a =7.7486 b =40.410 c =16.745 | | | |
| Mn$_2$SnS$_4$ | tetragonal | I4$_1$/a | a=7.408 c=10.41 Z=8 | 571 | 4.15 | |
| [Mn(en)$_3$]$_2$[Sn$_2$S$_6$] | monoclinic | C2/c | a=15.138 b=10.6533 c=23.586 β=118.42 Z=4 | 3345.2 | 1.787 | colourless |
| [Mn(en)$_3$]$_2$Sn$_2$S$_6$·2H$_2$O | monoclinic | P2$_1$/c | a=10.129, b=15.746, c=11.524, β=102.36° Z=2 | 1795.5 | 1.732 | |
| [Mn(en)$_2$]$_2$(μ-en)[Sn$_2$S$_6$] | triclinic | | a=9.0017 b=9.7735 c=10.8421 α=60.38° β=67.23° γ=70.25° | 752.38 | | |
| [Mn(dien)$_2$]$_2$Sn$_2$S$_6$ | monoclinic | P2$_1$/c | a=12.48 12, b= 9.3760, c=17.7617, β=121.752°, Z=2, | 1767.5 | 1.789 | |
| [Mn(tren)]$_2$Sn$_2$S$_6$ | triclinic | P1 | a 7.653 b 8.088 c 12.200, α 97.27° β 104.06° γ 108.80° Z=1 | 676.0 | 2.044 | yellow |
| [Mn(tren)(H$_2$O)][Mn(baen)]$_3$Mn$_4$Sn$_6$S$_{20}$∙9H$_2$O | orthorhombic | P2$_1$3 | a =21.404 b =21.404 c= 21.404 | | | super tetrahedron |
| {Mn(tepa)}$_2$(μ-Sn$_2$S$_6$) | tetragonal | I4$_1$/a | a=25.977 c=10.041 Z=8 | 6775 | 1.800 | yellow |
| {[Mn(trien)]$_2$[SnS$_4$]} | | | | | | |
| {[Mn(C$_6$H$_{18}$N$_4$)]$_2$SnS$_4$}·4H$_2$O | monoclinic | P2$_1$/c | a 10.8446 b 20.974 c 13.2746 β 113.487° | | | |
| {[Mn(phen)$_2$]$_2$(μ$_2$-Sn$_2$S$_6$)} | monoclinic | P2$_1$/n | a =10.8230 b=9.8940 c=24.811 β=91.356° | | | |
| {[Mn(phen)$_2$]$_2$(μ$_2$-Sn$_2$S$_6$)}·phen | triclinic | P1 | a=10.0642 b=10.6249 c=13.693, α=71.700° β=81.458° γ=84.346° | | | |
| {[Mn(phen)$_2$]$_2$[Sn$_2$S$_6$]}·phen·H$_2$O phen = 1,10-phenanthroline | triclinic | P1 | a=11.3203 b=12.1436 c=12.7586, α=113.200° β=90.908° γ=110.974° | | | |
| [Mn(phen)]$_2$(SnS$_4$)·H$_2$O | monoclinic | C2/m | a=16.146 b=19.262 c=9.938 β=124.970 Z=4 | 2532.6 | 1.928 | red chain |
| {[Mn(phen)$_2$]$_2$[μ-η$^2$-η$^2$-SnS$_4$]$_2$[Mn(phen)]$_2$}·H$_2$O | triclinic | P1 | a=10.8703 b=12.5183 c=14.9644, α=103.381° β=108.390° γ=101.636° | | | |
| {[Mn(2,2′-bipy)$_2$]$_2$[Sn$_2$S$_6$]} | | | | | | |
| (1,4-dabH)$_2$MnSnS$_4$ 1,4-dab = 1,4-diaminobutane | orthorhombic | Fdd2 | a = 22.812, b = 24.789, c = 6.4153, Z = 8 | 3627.8 | | |
| Li$_4$MnSn$_2$Se$_7$ | monoclinic | Cc | a=18.126 b=7.2209 c=10.740 β=93.43 Z=4 | 1403.2 | 4.132 | orange |
| Fe$_2$SnS$_4$ | tetragonal | I4$_1$/a | a=7.308 c=10.338 Z=4 | 552 | 4.32 | |
| {[Fe(tepa)]$_2$[Sn$_2$S$_6$]} | tetragonal | I4$_1$/a | | | | |
| {[Fe(1,2-dach)$_2$][Sn$_2$S$_6$]}·2(1,2-dachH) | | | | | | |
| {[Fe(phen)$_2$]$_2$[Sn$_2$S$_6$]}·phen·H$_2$O | | | | | | |
| [Co(en)$_3$]$_2$[Sn$_2$S$_6$] | orthorhombic | Pbca | a=15.640 b=11.564 c=18.742 Z=4 | 2289.7 | 1.779 | yellow |
| [Co(dien)$_2$]$_2$[Sn$_2$S$_6$] | | | | | | |
| [Co$_2$(cyclam)$_2$Sn$_2$S$_6$]·2H$_2$O | | | | | | |
| [Co(tren)]$_2$Sn$_2$S$_6$ | monoclinic | C2/c | a=12.228 b=9.7528 c=23.285 β=102.90 | 2706.8 | | |
| {[Co(cyclam)]$_2$[Sn$_2$S$_6$]}$_n$·2nH$_2$O cyclam = 1,4,8,11-tetraazacyclotetradecane | | | | | | |
| {[Co(tepa)]$_2$[Sn$_2$S$_6$]} tepa=tetraethylenepentamine | tetragonal | I4$_1$/a | a=25.742 c=9.898 | 6558 | | |
| {[Co(phen)$_2$]$_2$[Sn$_2$S$_6$]}·phen·H$_2$O | | | | | | |
| [Co(2-(aminomethyl)pyridine)$_3$]$_2$Sn$_2$S$_6$·10H$_2$O (2amp) | monoclinic | P2$_1$/c | a=10.1443 b=14.6124 c=18.8842 β=90.601° Z=2 | 2799.1 | 1.633 | yellow |
| [Co(trans-1,2-diaminocyclohexane)$_3$]$_2$Sn$_2$S$_6$·8H$_2$O (dach) | monoclinic | P2$_1$/n | a=12.6521 b=11.7187 c=20.4386 β=91.262° Z=2 | 3029.6 | 1.509 | red |
| Ni$_6$SnS$_2$ Butianite | tetragonal | I4/mmm | a = 3.650, c = 18.141 Z=2 | 241.7 | 7.62 | opaque |
| [Ni(en)$_3$]$_2$[Sn$_2$S$_6$] | | | | | | |
| [Ni(dap)$_3$]$_2$[Sn$_2$S$_6$]·2H$_2$O dap=1,2-diaminopropane | triclinic | P1 | a=9.9046 b=10.527 c=11.319 α =72.13° β =85.19° γ =63.63° | 1004.5 | | |
| [Ni(1,2-dach)$_3$]$_2$[Sn$_2$S$_6$]·4H$_2$O 1,2-dach = 1,2-diaminocyclohexane | | | | | | |
| [Ni(dien)$_2$]$_2$[Sn$_2$S$_6$] | | | | | | |
| {[Ni(cyclen)]$_6$[Sn$_6$S$_{12}$O$_2$(OH)$_6$]}·2(ClO$_4$)·19H$_2$O cyclen = 1,4,7,10-tetraazacyclododecane | | | | | | |
| [Ni(cyclen)(H$_2$O)$_2$]$_4$[Sn$_{10}$S$_{20}$O$_4$]·~13H$_2$O | | | | | | |
| {[Ni(cyclen)]$_6$[Sn$_6$S$_{12}$O$_2$(OH)$_6$]}·2(ClO$_4$)·19H$_2$O | monoclinic | C2/c | a=25.7223 b=15.6522 c=29.070 β=105.879 Z=4 | 11257 | 1.863 | oxothiostannate |
| [Ni(2amp)$_3$]$_2$[Sn$_2$S$_6$]·9.5H$_2$O 2amp = 2-(aminomethyl)pyridine | monoclinic | P2$_1$/n | a=18.7021 b=14.6141 c=20.2591 β=97.696 Z=4 | 5487.2 | 1.655 | purple |
| [Ni(aepa)$_2$]$_2$[Sn$_2$S$_6$] aepa=N-2-aminoethyl-1,3-propandiamine | | | | | | |
| [Ni(tren)]$_2$Sn$_2$S$_6$ | monoclinic | C2/c | a=23.371 b=8.231 c=14.274 β =107.230 Z=4 | 2622.6 | 2.127 | |
| [Ni(tren)$_2$]$_2$[Sn$_2$S$_6$]·8H$_2$O | orthorhombic | P4$_2$/n | a=26.1885 b=26.1885 c=11.1122 | | | |
| [Ni(tren)(2amp)]$_2$[Sn$_2$S$_6$] | triclinic | P1 | a =10.2878 b =11.1100 c =11.4206, α =84.740° β =84.395° γ =79.093° | | | |
| [Ni(tren)(2amp)]$_2$[Sn$_2$S$_6$]·10H$_2$O | monoclinic | P2$_1$/n | a =12.1933 b =13.4025 c =14.8920 β= 103.090° | | | |
| [Ni(tren)(en)]$_2$[Sn$_2$S$_6$]·2H$_2$O | monoclinic | P2$_1$/n | a 12.7041 b 9.8000 c 15.3989, β 108.843° | | | |
| [Ni(tren)(en)]$_2$[Sn$_2$S$_6$]·6H$_2$O | monoclinic | P2$_1$/n | a 12.5580 b 9.7089 c 16.0359, β 91.827° | | | |
| [Ni(tren)(1,2-dach)]$_2$[Sn$_2$S$_6$]·3H$_2$O | triclinic | P1 | a 9.8121 b 10.0080 c 12.422, α 86.38° β 79.65° γ 65.72° | | | |
| [Ni(tren)(1,2-dach)]$_2$[Sn$_2$S$_6$]·4H$_2$O | monoclinic | P2$_1$/n | a 10.7119 b 19.0797 c 11.1005, β 104.803° | | | |
| {[Ni(cyclam)]$_2$[Sn$_2$S$_6$]}·2H$_2$O | | | | | | |
| {[Ni(tepa)]$_2$[Sn$_2$S$_6$]} | monoclinic | P2$_1$/n | | | | |
| {[Ni(phen)$_2$]$_2$[Sn$_2$S$_6$]}·2,2′-bipy | monoclinic | P2$_1$/n | a=10.5715 b=9.9086 c=24.9960 β=92.800 Z=2 | 2615.17 | 1.809 | deep red |
| {[Ni(phen)$_2$]$_2$Sn$_2$S$_6$}·4,4′-bipy·½H$_2$O 4,4′-bipy = 4,4′-bipyridine | monoclinic | C2/c | a=18.3431 b=19.4475 c=15.0835 β=95.556 Z=4 | 5355.4 | 1.789 | dark red-brown |
| {[Ni(phen)$_2$]$_2$[Sn$_2$S$_6$]}·phen·H$_2$O | | | | | | |
| [Ni(L$_1$)][Ni(L$_1$)Sn$_2$S$_6$]$_n$·2H$_2$O L$_1$ = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane | monoclinic | P21/c | | | | |
| [Ni(L$_2$)]$_2$[Sn$_2$S$_6$]·4H$_2$O L$_2$ = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane | triclinic | P1 | | | | |
| [Ni(tren)(ma)(H$_2$O)]$_2$[Sn$_2$S$_6$]·4H$_2$O ma = methylamine | monoclinic | P2$_1$/n | a=11.1715 b=10.5384 c=15.8594 Z=2 | 1827.45 | 1.835 | |
| [Ni(tren)(1,2-dap)]$_2$[Sn$_2$S$_6$]·2H$_2$O | monoclinic | P2$_1$/n | a=12.9264 b=10.1627 c=15.6585 Z=2 | 1889.8 | 1.799 | |
| [Ni(tren)(1,2-dap)]$_2$[Sn$_2$S$_6$]·4H$_2$O | monoclinic | C2/c | a =14.3925 b=15.1550 c=18.9307, β=99.108° | | | |
| [Ni(2amp)$_3$]$_2$[Sn$_2$S$_6$]·9.5H$_2$O 2amp = 2-(aminomethyl)pyridine | monoclinic | P2$_1$/n | a=18.7021 b=14.6141 c=20.2591 Z=4 | 5487.23 | 1.655 | purple |
| Cu$_2$SnS$_3$ Mohite | monoclinic | | a=23.10 b=6.25 c=6.25 β=101.0° | | 4.69 | greenish grey |
| Cu$_3$SnS$_4$ Kuramite | tetragonal | I42m | a = 5.445, c = 10.75, Z = 2 | 318.72 | 4.56 | |
| Cu$_4$SnS$_4$ | orthorhombic | Pnma | a=13.70 b=7.750 c=6.454 Z=4 | 685 | 4.96 | |
| Cu$_4$SnS$_6$ Erazoite | rhombohedral | R3m | a = 3.739, c = 32.941, Z = 2 | | 4.53 | black |
| Cu$_4$Sn$_7$S$_{16}$ | monoclinic | | a=12.75 b=7.34 c=12.71 β=109.5 Z=2 | 1121 | 4.74 | |
| (DBUH)CuSnS$_3$ DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene | monoclinic | P2$_1$/n | a=9.254 b=8.6190 c=18.135, β=92.80° | | | |
| (1,4-dabH$_2$)Cu$_2$SnS$_4$ 1,4-dab = 1,4-diaminobutane | tetragonal | P4$_2$/n | a=14.539 c=11.478 | | | |
| (enH)$_6$Cu$_{40}$Sn$_{15}$S$_{60}$ en=ethylenediamine | cubic | Pn3n | a=25.260 Z=4 | 16119 | 2.727 | black |
| (enH)$_3$Cu$_7$Sn$_4$S$_{12}$ | trigonal | R3c | a=13.532 c=28.933 Z=6 | 4588 | 3.23 | red |
| [H$_2$en]$_2$[Cu$_8$Sn$_3$S$_{12}$] | | | | | | |
| (trenH$_3$)Cu$_7$Sn$_4$S$_{12}$ tren = tris(2-aminoethyl)amine) | trigonal | R3c | a=13.1059 c=29.347 Z=6 | 4365.4 | 3.317 | |
| [dienH$_2$][Cu$_2$Sn$_2$S$_6$] | | | | | | |
| [DBUH][CuSnS$_3$] DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene | | | | | | |
| [1,4-dabH$_2$][Cu$_2$SnS$_4$] | | | | | | |
| {[Cu(cyclam)]$_2$[Sn$_2$S$_6$]}·2H$_2$O cyclam=1,4,8,11-tetraazacyclotetradecane | triclinic | P1 | a=9.0580 b=9.9419 c=10.2352, α=97.068° β=94.314° γ=101.514° | | | |
| (DBNH)$_2$Cu$_6$Sn$_2$S$_8$ DBN=1,5-diazabicyclo[4.3.0]non-7-ene | | | | | | |
| [Co(2-(aminomethyl)pyridine)$_3$]$_2$ Sn$_2$S$_6$·10H$_2$O | monoclinic | P2$_1$/c | a=10.1443 b=14.6124 c=18.8842 β=90.601° Z=2 | 2799.1 | 1.633 | yellow; unstable |
| [Co(trans-1,2-diaminocyclohexane)$_3$]$_2$Sn$_2$S$_6$·8H$_2$O | monoclinic | P2$_1$/n | a=12.6521 b=11.7187 c=20.4386 β=91.262° Z=2 | 3029.6 | 1.509 | red |
| Na$_4$Cu$_{32}$Sn$_{12}$S$_{48}$·4H$_2$O | cubic | Fm3c | a = 17.921 z = 13 | | | black; absorption edge 2.0 eV |
| CuAlSnS$_4$ | cubic | | a=10.28 Z=8 | 1074 | 4.17 | |
| K$_{11}$Cu$_{32}$Sn$_{12}$S$_{48}$·4H$_2$O | cubic | Fm3c | a = 18.0559 z = 14.75 | | | black; absorption edge 1.9 eV |
| Cu$_2$MnSnS$_4$ | tetragonal | | a=5.49 c=10.72 Z=2 | 323 | 4.41 | |
| Cu$_2$FeSnS$_4$ Stannite Ferrokësterite | tetragonal | I42m | a = 5.4432, c = 10.7299 Z=2 | 317.91 | | grey |
| Cu$_2$FeSn$_3$S$_8$ | tetragonal | I4$_1$/a | a=7.29 c=10.31 Z=2 | 548 | 4.82 | |
| Cu$_6$Fe$_2$SnS$_8$ Mawsonite | Tetragonal | P4m2 | a = 7.603, c = 5.358 Z=1 | 309 | 4.65 | brownish orange |
| Cu$_6$FeSn$_2$S$_8$ Chatkalite | Tetragonal | P4m2 | a = 7.61, c = 5.373 Z=1 | 311.1 | 5.00 | |
| Cu$_2$CoSnS$_4$ | Tetragonal | I42m | a=5.402 c=10.805 Z=2 | 315 | 4.56 | |
| Cu$_2$NiSnS$_4$ | | | a=5.425 Z=1 | 160 | 4.49 | |
| Cu$_{13}$VSn$_3$S$_{16}$ Nekrasovite | isometric | | a=10.73 | 1,235 | | brown |
| [Zn(en)$_3$]$_2$[Sn$_2$S$_6$] | orthorhombic | Pbca | a=15.452 b=11.524 c=18.614 Z=4 | 3315.3 | 1.845 | colourless |
| {Zn(tren)}$_2$(μ-Sn$_2$S$_6$) | monoclinic | C2/c | a 12.214 b 9.726 c 23.209 β 102.732° | 2689.3 | 2.107 | light yellow |
| Cu$_2$ZnSnS$_4$ Kësterite | tetragonal | I4 | a = 5.427, c = 10.871 Z=2 | 320.18 | 4.55 | greenish black |
| Cu$_6$$^+$Cu$_2$$^{2+}$(Fe$^{2+}$,Zn)$_3$Sn$_2$S$_{12}$ Stannoidite | orthorhombic | | a = 10.76, b = 5.4, c = 16.09 | 934.9 | 4.68 | brass |
| Cu$_3$(V,Ge,Sn)S$_4$ Ge-Sn-Sulvanite | | | | 361 | | |
| SnGeS$_3$ Stangersite | monoclinic | P2$_1$/b | a = 7.270, b = 10.197, c = 6.846 β = 105.34° Z=4 | 489 | 3.98 | orange |
| Rb$_4$SnS$_4$ | | | | | | |
| Rb$_4$Sn$_2$S$_6$ | | | | | | |
| Rb$_2$Sn$_3$S$_7$·2H$_2$O | | | | | | |
| Rb$_2$Cu$_2$SnS$_4$ | orthorhombic | Ibam | a=5.528 b=11.418 c=13.700 Z=4 | 865 | 4.185 | band gap 2.08 eV |
| Rb$_2$Cu$_2$Sn$_2$S$_6$ | monoclinic | C2/c | a=11.026 b=11.019 c=20.299 β=97.79 Z=8 | 2444 | 3.956 | band gap 1.44 eV |
| Rb$_2$ZnSn$_3$S$_8$ | | | | | | |
| [Rb$_4$(H$_2$O)$_4$][SnS$_4$] | | | | | | |
| Sr$_3$MnSn$_2$S$_8$ | cubic | I43d | a = 14.2287 Z = 8 | 2880.7 | 3.743 | dark green |
| Cu$_2$SrSnS$_4$ | trigonal | P3$_1$ | a = 6.29, c = 15.57 Z=3 | 534 | 4.31 | |
| Sr$_6$Cu$_4$Sn$_4$S$_{16}$ | cubic | I43d | a=13.982 | 2734 | 4.295 | yellow |
| Sr$_6$Cu$_2$FeSn$_4$S$_{16}$ | cubic | I43d | a=14.1349 | | | band gap 1.53 eV |
| SrSnS$_3$ | orthorhombic | Pnma | a=8.264 b=3.867 c=14.116 Z=4 | 451 | 4.45 | |
| [Y$_2$(dien)$_4$(μ-OH)$_2$]Sn$_2$S$_6$ | monoclinic | P2$_1$/n | a=11.854 b=11.449 c=13.803 β=97.978 Z=2 | 1855 | 1.888 | light yellow |
| α-Ag$_8$SnS$_6$ | cubic | | a=21.43 | 9842 | | |
| β-Ag$_8$SnS$_6$ | cubic | | a=10.85 | 1277 | | |
| Ag$_8$SnS$_6$ Canfieldite | orthorhombic | | a = 15.298, b = 7.548, c = 10.699 Z=4 | 1,235.4 | 6.311 | metallic |
| Na$_3$AgSnS$_4$ | monoclinic | P2$_1$/c | a 8.109 b 6.483 c 15.941, α 90° β 103.713 | | | double chain |
| AgCrSnS$_4$ | cubic | | a=10.74 Z=8 | 1239 | 4.92 | |
| Ag$_2$MnSnS$_4$ – Agmantinite | orthorhombic | | a = 6.632, b = 6.922, c = 8.156 Z=2 | | 4.574 | orange |
| Ag$_2$ZnSnS$_4$ Pirquitasite | tetragonal | I4 | a = 5.78, c = 10.82 | 361 | | black |
| Ag$_2$(Fe$^{2+}$,Zn)SnS$_4$ Hocartite | tetragonal | I42m | a = 5.74, c = 10.96 Z=2 | 361 | 4.77 | brownish grey |
| Ag$^{1+}$(Fe$^{2+}$$_{0.5}$Sn$^{4+}$$_{1.5}$)S$_4$ Toyohaite | tetragonal | | | | | grey |
| [enH][Cu$_2$AgSnS$_4$] | orthorhombic | Pnma | a=19.7256 b=7.8544 c= 6.5083 Z=4 | 1008.3 | 3.577 | red |
| Ag$_2$SrSnS$_4$ | orthorhombic | | a=7.127 b=8.117 c=6.854 Z=2 | 397 | 5.02 | |
| Sr$_6$Ag$_4$Sn$_4$S$_{16}$ | cubic | I43d | a=14.2219 Z=4 | 2876.6 | 4.491 | yellow |
| Sr$_6$Ag$_2$FeSn$_4$S$_{16}$ | cubic | I43d | a=14.2766 | | | band gap 1.87 eV |
| [1,4-dabH$_2$][Ag$_2$SnS$_4$] 1,4-dab = 1,4-diaminobutane | tetragonal | P4$_2$/n | a = 14.7847, c = 11.9087, Z = 8 | 2603.1 | | |
| [H$_2$en][Ag$_2$SnS$_4$] | | | | | | |
| [CH$_3$NH$_3$]$_2$Ag$_4$Sn$^{IV}$$_2$Sn$^{II}$S$_8$ | orthorhombic | Pnma | a =19.378 b =7.390 c =13.683 Z=4 | 1959 | 3.756 | Orange Sn(II) |
| [CH$_3$NH$_3$]$_6$Ag$_{12}$Sn$_6$S$_{21}$ | monoclinic | P2$_1$/c | a =18.8646 b =19.9115 c =14.3125 β 100.117° | | | |
| [(Me)$_2$NH$_2$]$_3$[Ag$_5$Sn$_4$Se$_{12}$] | tetragonal | P42$_1$m | a=13.998 c=8.685 Z=2 | 1701.9 | 4.403 | dark red |
| [enH][Cu$_2$AgSnS$_4$] | | | | | | |
| Cu$_2$CdSnS$_4$ | | I42m | a=5.402 c=10.86 Z=2 | 338 | 4.77 | |
| Ag$_2$CdSnS$_4$ | | Cmc2$_1$ | a=4.111 b=7.038 c=6.685 Z=1 | 193 | 4.95 | |
| Cu$_2$(Cd,Zn,Fe)SnS$_4$ Černýite | tetragonal | I42m | a = 5.48, c = 10.828 Z=4 | 326 | 4.76 | metallic |
| CuInSnS$_4$ | | | a=10.50 Z=8 | 1158 | 4.91 | |
| AgInSnS$_4$ | | | a=10.16 Z=8 | 1048 | 4.59 | |
| (Cu,Fe,Zn,Ag)$_3$(Sn,In)S$_4$ Petrukite | orthorhombic | | a = 7.66, b = 6.43, c = 6.26 | 308 | | brown |
| (Cu,Zn,Fe)$_3$(In,Sn)S$_4$ Sakuraiite | isometric | | a = 5.46 Z=1 | 162 | | greenish grey |
| Sn$_2$S$_3$ | orthorhombic | Pnma | a=8.864 b=3.7471 c=14.020 Z=4 | 466 | 4.76 | |
| Cs$_4$SnS$_4$ | | | | | | 0d |
| Cs$_2$Sn$_3$S$_7$ ·0.5S$_8$ | | | | | | 2d |
| Cs$_4$Sn$_5$S$_{12}$·2H$_2$O | | | | | | 2d |
| [Cs$_4$(H$_2$O)$_3$][SnS$_4$] | | | | | | |
| Cs$_2$Sn(S$_4$)$_2$(S$_6$) | | | | | | |
| Cs$_8$Sn$_{10}$O$_4$S$_{20}$·13H$_2$O | | | | | | |
| [Cs$_{10}$(H$_2$O)$_{18}$][Mn$_4$(μ$_4$-S)(SnS$_4$)$_4$] | | | | | | |
| Cs$_2$ZnSn$_3$S$_8$ | monoclinic | P2$_1$/n | a 7.5366 b 17.6947 c 12.4976, β=94.830° Z=4 | 1660.7 | 3.775 | layered, band gap 3. eV |
| [Ba$_2$(H$_2$O)$_{11}$][SnS$_4$] | | | | | | |
| Li$_2$Ba$_6$MnSn$_4$S$_{16}$ | cubic | I43d | a=14.6080 Z=4 | 3117.3 | 4.007 | light yellow |
| Ag$_2$Ba$_6$MnSn$_4$S$_{16}$ | cubic | I43d | a=14.7064 Z=4 | 3180.7 | 4.349 | yellow |
| Ag$_2$BaSnS$_4$ | orthorhombic | I222 | a =7.127 b =8.117 c =6.854 Z=2 | | | black |
| Ba$_3$Ag$_2$Sn$_2$S$_8$ | | | | | | |
| BaSnS$_2$ | | | | | | Sn(II) |
| BaSn$_2$S$_3$ | | | | | | Sn(II) |
| BaSnS$_3$ | orthorhombic | Pnma | a=8.527 b=3.933 c=14.515 Z=4 | 487 | 4.8 | |
| BaSnS$_3$ | monoclinic | C2/c Cc | a=24.49 b=6.354 c=23.09 β=90.15 Z=28 | 3593 | 4.55 | |
| α-Ba$_2$SnS$_4$ | monoclinic | P2$_1$/c | a=8.481 b=8.526 c=12.280 β=112.97 Z=4 | 818 | 4.24 | |
| β-Ba$_2$SnS$_4$ | orthorhombic | Pnma | a=17.823 b=7.359 c=12.613 | 1654 | 4.18 | |
| Ba$_3$Sn$_2$S$_7$ | monoclinic | P2$_1$/c | a=11.073 b=6.771 c=18.703 β=100.77 Z=4 | 1378 | 4.21 | |
| K$_2$BaSnS$_4$ | | R3c | a 25.419 c 7.497 | | | band gap 3.09 eV; SHG 0.5×AgGaS$_2$ |
| Ba$_6$Cu$_2$FeSn$_4$S$_{16}$ | cubic | I43d | a=14.5260 | | | band gap 1.2 eV |
| Ba$_6$Cu$_2$NiSn$_4$S$_{16}$ | cubic | I43d | a=14.511 | | | band gap 0.82 eV |
| Ba$_6$Li$_2$ZnSn$_4$S$_{16}$ | cubic | I43d | a=14.5924 | | | |
| Ba$_6$Ag$_2$ZnSn$_4$S$_{16}$ | cubic | I43d | a=14.6839 | | | |
| BaCdSnS$_4$ | orthorhombic | Fdd2 | a=21.57 b=21.76 c=13.110 Z=32 | 6152 | 4.290 | yellow |
| Ba$_3$CdSn$_2$S$_8$ | cubic | I43d | a=14.723 | | | |
| Ba$_6$CdAg$_2$Sn$_4$S$_{16}$ | cubic | I43d | a=14.725 | | | |
| La$_2$SnS$_5$ | orthorhombic | Pbam | a=11.22 b=7.915 c=3.97 Z=2 | 352 | 5.26 | |
| [La(dien)$_3$]$_2$[Sn$_2$S$_6$]Cl$_2$ | | | | | | band gap 3.25 eV |
| La(peha)(μ–SnS$_4$H) peha=pentaethylenehexamine | triclinic | P1 | a 8.609 b 9.327 c 14.649, α 79.2° β 85.5° γ 63.74° | | | |
| BaCeSn$_2$S$_6$ | orthorhombic | Pmc2$_1$ | a 4.0665 b 19.859 c 11.873 | | | |
| BaPrSn$_2$S$_6$ | orthorhombic | Pmc2$_1$ | a 4.0478 b 19.8914 c 11.9303 | | | |
| BaNdSn$_2$S$_6$ | orthorhombic | Pmc2$_1$ | a 4.0098 b 19.761 c 11.841 | | | |
| [Nd$_2$(en)$_6$(μ$_2$-OH)$_2$]Sn$_2$S$_6$ | monoclinic | P2$_1$/n | a =10.176, b =11.387, c=15.018, β =97.869° | | | |
| Nd(peha)(μ–SnS$_4$H) | triclinic | P1 | a 8.621 b 9.372 c 14.656, α 78.28° β 84.33° γ 63.32° | | | |
| {Nd(tepa)(μ–OH)}$_2$(μ–Sn$_2$S$_6$)]·H$_2$O tepa=tetraethylenepentamine | monoclinic | C2/c | a=21.537 b=12.863 c=17.697 β=124.308° | | | |
| [Nd(dien)$_3$]$_2$[(Sn$_2$S$_6$)Cl$_2$] dien = diethylenetriamine | monoclinic | P2$_1$/n | a = 11.672, b = 15.119, c = 14.157, β = 96.213°, Z = 4 | 2483.6 | | |
| [Nd(dien)$_3$]$_2$[(Sn$_2$S$_6$)(SH)$_2$] | monoclinic | P2$_1$/n | a = 11.719, b = 15.217, c = 14.221, β = 95.775°, Z = 4 | 2523.1 | | |
| (tetaH)$_2$[Eu$_2$(teta)$_2$(tren)$_2$(μ-Sn$_2$S$_6$)]Sn$_2$S$_6$ | triclinic | P1 | a=9.886 b=10.371 c=17.442 α=89.78 β=88.00 γ=85.14 Z=1 | 1780.8 | 1.898 | light yellow |
| [Eu$_2$(tepa)$_2$(μ-OH)$_2$(μ-Sn$_2$S$_6$)](tepa)$_{0.5}$·H$_2$O tepa = tetraethylene-pentamine | monoclinic | C2/c | a=19.803 b=14.998 c=17.800 β=126.57 Z=4 | 4246 | 1.970 | colourless |
| [{Eu(en)$_3$}$_2$(μ-OH)$_2$]Sn$_2$S$_6$ | monoclinic | P2$_1$/n | a = 10.116, b = 11.379, c = 14.949, β = 98.209°, Z=2 | 1703.1 | | |
| [{Eu(en)$_3$}$_2$(μ-OH)$_2$]Sn$_2$Se$_6$ | monoclinic | P2$_1$/n | a = 10.136, b = 11.771, c = 15.423, β = 99.322°, Z = 2 | 1815.8 | | |
| [Eu(dien)$_3$]$_2$[(Sn$_2$S$_6$)(SH)$_2$] | monoclinic | P2$_1$/n | a = 11.656, b = 15.168, c = 14.173, β = 95.682°, Z = 2 | 2493.4 | | |
| (tetaH)$_2$[Sm$_2$(teta)$_2$(tren)$_2$(μ-Sn$_2$S$_6$)]Sn$_2$S$_6$ | triclinic | P1 | a=9.920 b=10.382 c=17.520 α=89.91 β=88.07 γ=85.23 Z=1 | 1797.1 | 1.877 | light yellow |
| {Sm(tepa)(μ–OH)}$_2$(μ–Sn$_2$S$_6$)]·H$_2$O | monoclinic | C2/c | a 21.487 b 12.8199 c 17.716 β 124.675° | | | |
| [Sm$_2$(en)$_6$(μ $_2$-OH)$_2$]Sn$_2$S$_6$ | monoclinic | P2$_1$/n | a 10.129 b 11.377 c 14.962, β 98.128° | | | |
| [Sm(dien)$_3$]$_2$[(Sn$_2$S$_6$)Cl$_2$] | monoclinic | P2$_1$/n | a 11.631 b 15.091 c 14.1420 β 96.202° | | | |
| [Sm(dien)$_3$]$_2$[(Sn$_2$S$_6$)(SH)$_2$] | monoclinic | P2$_1$/n | a 11.698 b 15.212 c 14.219, β 95.654° | | | |
| [Sm(trien)(tren)(Cl)]$_2$Sn$_2$S$_6$ · en | triclinic | P1 | a 10.320 b 10.491 c 13.791, α 100.524° β 91.930° γ 119.083° | | | |
| {Gd(tepa)(μ–OH)}$_2$(μ–Sn$_2$S$_6$)]·H$_2$O | monoclinic | C2/c | a 21.455 b 12.804 c 17.735 β 124.81° | | | |
| [Gd$_2$(en)$_6$(μ$_2$-OH)$_2$]Sn$_2$S$_6$ | monoclinic | P2$_1$/n | a =10.1053 b =11.357 c =14.924, β = 98.346° | | | |
| [Gd(dien)$_3$]$_2$[(Sn$_2$S$_6$)Cl$_2$] dien = diethylenetriamine | monoclinic | P2$_1$/n | a =11.662, b =15.168. c 14.185, β =95.696° | | | |
| {Dy(tepa)(μ–OH)}$_2$(μ–Sn$_2$S$_6$)]·H$_2$O | monoclinic | C2/c | a 21.363 b 12.717 c 17.654 β 124.915° | | | |
| [Hen]$_2$[La(en)$_4$(CuSn$_3$S$_9$)]⋅0.5 en | | | | | | |
| [Hen]$_2$[Ce(en)$_4$(CuSn$_3$S$_9$)]⋅0.5 en | | | | | | |
| [Hen]$_4$[Nd(en)$_4$]$_2$[Cu$_6$Sn$_6$S$_{20}$]⋅3 en | | | | | | |
| [enH]$_4$[Sm(en)$_4$]$_2$[Cu$_6$Sn$_6$S$_{20}$]·3en | monoclinic | C2/m | a 14.257 b 24.242 c 13.119 β 92.223° | | | |
| [Hen]$_4$[Gd(en)$_4$]$_2$[Cu$_6$Sn$_6$S$_{20}$]⋅3 en | | | | | | |
| [enH]$_4$[Ho(en)$_4$]$_2$[Cu$_6$Sn$_6$S$_{20}$]·3en | monoclinic | C2/m | a 14.3859 b 24.361 c 13.175, β 93.526° | | | |
| EuCu$_2$SnS$_4$ | orthorhombic | Ama2 | a=10.4793, b=10.3610, c=6.4015, Z=4 | | | |
| [Hen]$_4$[Er(en)$_4$]$_2$[Cu$_6$Sn$_6$S$_{20}$]⋅3 en | | | | | | |
| [Hen]$_4$[Er(en)$_4$]$_2$[Ag$_6$Sn$_6$S$_{20}$]·3en | monoclinic | C2/m | a 14.557 b 24.397 c 13.412 β 94.42° | | | |
| [Hen]$_4$[Tm(en)$_4$]$_2$[Ag$_6$Sn$_6$S$_{20}$]·3en | monoclinic | C2/m | a 14.517 b 24.380 c 13.422 β 94.46° | | | |
| [Hen]$_4$[Yb(en)$_4$]$_2$[Ag$_6$Sn$_6$S$_{20}$]·3en | monoclinic | C2/m | a 14.536 b 24.397 c 13.397, β 94.63° | | | |
| Cu$_6$SnWS$_8$ Kiddcreekite | isometric | F43m | a = 10.8178 Z=4 | 1265.9 | 4.934 | grey |
| PtSnS Bowlesite | orthorhombic | Pca2$_1$ | a = 6.12 Å, b = 6.12 Å, c = 6.10 Å Z=4 | 228.47 | 10.06 | metallic |
| (Pd,Pt)$_5$(Cu,Fe)$_4$SnTe$_2$S$_2$ Oulankaite | tetragonal | | a = 9.044, c = 4.937 Z=2 | 403.8 | 10.27 | metallic |
| K$_2$Au$_2$SnS$_4$ | triclinic | P1 | a=8.212 b=11.019 c=7.314 α=97.82° β=111.72° γ=72.00° Z=2 | 483.2 | 4.941 | band gap 2.75 eV |
| K$_2$Au$_2$Sn$_2$S$_6$ | tetragonal | P4/mmc | a=7.968 c=19.200 Z=4 | 1219 | 4.914 | band gap 2.30 eV |
| Cs$_2$Au$_2$SnS$_4$ | orthorhombic | Fddd | a = 6.143 b = 14.296 c = 24.578 Z = 4 | 2158.4 | | |
| Ba[Au$_2$SnS$_4$] | orthorhombic | C222$_1$ | a=6.6387 b=11.0605 c=10.9676 Z=1 | 805.32 | 6.418 | red; blue-green luminescent |
| K$_2$Hg$_3$Sn$_2$S$_8$ | | | | | | |
| Cu$_2$HgSnS$_4$ Velikite | tetrahedral | I42m | a = 5.55, c = 10.91 | 336 | 5.450 | dark grey |
| SrHgSnSe$_4$ | | | | | | |
| BaHgSnSe$_4$ | orthorhombic | Fdd2 | a 22.441 b 22.760 c 13.579 | | | |
| EuHgSnS$_4$ | | Ama2 | a=10.3730 b=10.4380 c=6.5680 | | | SHG 1.77×AgGaS$_2$ |
| Tl$_4$SnS$_4$ | | | | | | 0d |
| Tl$_2$SnS$_3$ | | | | | | 1d |
| Tl$_2$Sn$_2$S$_5$ | | | | | | 3d |
| Tl$_4$Sn$_5$S$_{12}$ | | | | | | 3d |
| PbSnS$_2$ Teallite | orthorhombic | Pnma | a = 4.26, b = 11.41, c = 4.09 | 198.8 | 6.36 | metallic |
| PbSnS$_3$ Suredaite | orthorhombic | Pnma | a=8.738 b=3.792 c=14.052 Z=4 | 466 | 6.01 | metallic |
| (Pb,Sn)$_{12.5}$Sn$_5$FeAs$_3$S$_{28}$ Coiraite | monoclinic | | a = 5.84, b = 5.86, c = 17.32 β = 94.14° Z=4 | 591 | 5.92 | dark grey |
| Fe$^{2+}$(Pb,Sn$^{2+}$)$_6$Sn$^{4+}$$_2$Sb$_2$S$_{14}$ Franckeite | triclinic | P1 | a = 46.9, b = 5.82, c = 17.3 α = 90°, β = 94.66°, γ = 90° Z=8 | 4701 | 5.90 | black |
| Pb$_{25.7}$Sn$_{8.3}$Mn$_{3.4}$Sb$_{6.4}$S$_{56.2}$ Ramosite | monoclinic | | a = 5.82, b = 5.92, c = 17.65 β = 99.1° | 600 | | |
| Pb$_3$Sn$_4$FeSb$_2$S$_{14}$ Cylindrite | triclinic | P1 | | | 5.46 | black |
| Pb$_6$Sn$_3$FeSb$_3$S$_{16}$ Potosíite | triclinic | | | | | grey |
| (Pb,Ag)$_4$Sn$_4$FeSb$_2$S$_{15}$ Incaite | monoclinic | | | | | |
| Pb$_2$Fe$_2$Sn$_2$Sb$_2$S$_{11}$ Plumbostannite | | | | | | dark grey |
| Ba$_5$Pb$_2$Sn$_3$S$_{13}$ | orthorhombic | Pnma | | | | |
| Pb$_2$SnInBiS$_7$ Abramovite | triclinic | P1 | a = 23.4, b = 5.77, c = 5.83 α = 89.1°, β = 89.9°, γ = 91.5° | 786.79 | | metallic |
| Pb$_8$Sn$_7$Cu$_3$(Bi,Sb)$_3$S$_{28}$ Lévyclaudite | triclinic | P1 | | | 5.71 | grey |