OpenLLM-France/wikimedia huggingface dataset:
# 1,4-Naphthoquinone

1,4-Naphthoquinone or para-naphthoquinone is a quinone derived from naphthalene. It forms volatile yellow triclinic crystals and has a sharp odor similar to benzoquinone. It is almost insoluble in cold water, slightly soluble in petroleum ether, and more soluble in polar organic solvents. In alkaline solutions it produces a reddish-brown color. Vitamin K is a derivative of 1,4-naphthoquinone. It is a planar molecule with one aromatic ring fused to a quinone subunit. It is an isomer of 1,2-naphthoquinone.

## Preparation

The industrial synthesis involves aerobic oxidation of naphthalene over a vanadium oxide catalyst:
    C$_{10}$H$_8$ + 3/2 O$_2$ → C$_{10}$H$_6$O$_2$ + H$_2$O
In the laboratory, naphthoquinone can be produced by the oxidation of a variety of naphthalene compounds. An inexpensive route involves oxidation of naphthalene with chromium trioxide.

## Reactions

1,4-Naphthoquinone acts as strong dienophile in Diels-Alder reaction. Its adduct with 1,3-butadiene can be prepared by two methods: 1) long (45 days) exposure of naphthoquinone in neat liquid butadiene taken in huge excess at room temperature in a thick-wall glass tube or 2) fast catalyzed cycloaddition at low temperature in the presence of 1 equivalent of tin(IV) chloride:

## Uses

1,4-Naphthoquinone is mainly used as a precursor to anthraquinone by reaction with butadiene followed by oxidation. Nitration gives 5-nitro-1,4-naphthalenedione, precursor to an aminoanthroquinone that is used as a dye precursor.

## Derivatives

Naphthoquinone forms the central chemical structure of many natural compounds, most notably the K vitamins. 2-Methyl-1,4-naphthoquinone, called menadione, is a more effective coagulant than vitamin K.
Other natural naphthoquinones include juglone, plumbagin, droserone.
Naphthoquinone derivatives have significant pharmacological properties. They are cytotoxic, they have significant antibacterial, antifungal, antiviral, insecticidal, anti-inflammatory, and antipyretic properties. Plants with naphthoquinone content are widely used in China and the countries of South America, where they are used to treat malignant and parasitic diseases.
Naphthoquinone functions as a ligand through its electrophilic carbon-carbon double bonds.
Dichlone, a chlorinated derivative of 1,4-naphthoquinone, is used as a fungicide.
# Powell Street

Powell Street is a street in San Francisco, California. It connects from Market Street through Union Square, North Beach, Nob Hill, Russian Hill and ends at theFisherman's Wharf.
The intersection of Powell Street with Market Street is the starting point of the Powell-Hyde Street terminal line of the San Francisco Cable Car. It ends on Hyde Street at the Aquatic Park Historic District.
The street was named for Dr. William J. Powell, surgeon of the U.S. sloop of war Warren, which was active during the conquest of California.
# Flori Gough Shorr

Florence "Flori" Agnes Gough Shorr (April 8, 1905 – January 30, 1992) was an American cellist on the faculty of the San Francisco Conservatory of Music. She played cello with the San Francisco Symphony and the Los Angeles Philharmonic, and later in life played viola and cello with the Pittsburgh Symphony Orchestra.

## Early life and education

Gough was born in Honolulu and raised in San Francisco, the daughter of James A. Gough and Margaret Kennedy Gough. She studied cello with Stanisłas Bem, and began giving recitals as a girl. She studied with Vincent d'Indy at the Conservatoire de Paris, where she was the first American cellist to win the Premiere Prix, when she graduated with first honors in 1924.
Her older brother Walter Louis Gough was a violinist and violin teacher in San Francisco.

## Career

Gough played in recitals beginning in the 1910s. "Her talent is still in the bud, but the color and texture of its full-blown perfection can easily be foretold," wrote a newspaper reviewer of her skill in 1918. She was heard on radio concerts from the 1920s. From 1929 to 1934, Gough was head of the cello department at the San Francisco Conservatory of Music. She performed with the San Francisco Symphony and the Abas Quartet. She gave her New York debut accompanied by her pianist husband in 1934, in two concerts at Town Hall.
Gough was based in Los Angeles in midlife. She played for NBC Radio, with the Los Angeles Philharmonic, and with the South Bay Civic Symphony. In the 1960s, she played cello and viola with the Pittsburgh Symphony Orchestra. She toured with the Pittsburgh Symphony in 1966, in a program highlighting the women in the orchestra. Her forced retirement at age 70 was one of the grievances in the Pittsburgh Symphony's musician strike in 1975; she played cello at the strikers' five-hour fundraiser concert.

## Personal life

Flori Gough married a fellow musician, Russian pianist Lev Shorr, in 1930. Later that year, she fell seriously ill with pneumonia. She was injured in a fatal car accident in 1932. The Shorrs divorced in 1936. She lived in Los Angeles in the 1940s and 1950s, in Pennsylvania in the 1960s and 1970s, and in Arizona in the 1980s. She died in 1992, at the age of 86, in San Francisco.
# MLW RSC-24

The MLW RSC-24 was a type of diesel-electric locomotive built by Montreal Locomotive Works for use on the Canadian National Railway (CN).
Only four RSC-24s were built – all in 1959. They were numbered 1800–1803 by CN. The locomotives were conceived by MLW as a way to use the 12-cylinder 244 diesel engines removed from MLW FPA-2s that were receiving the more-capable Alco 251 engine (making them similar to the MLW FPA-4 locomotive).
CN used these unique units to replace 2-6-0 or 4-6-0 steam locomotives on light-rail branch lines in eastern Canada. MLW designed the locomotives to use a switcher frame, resulting in the "squashed" appearance of a road switcher. This was largely the result of a very short rear hood housing the electrical cabinet, whereas they were located in the long hood on most road switcher designs.
To make the locomotives suitable for weight-restricted light rail branch lines, MLW spread the weight over the rail surface using A1A-A1A trucks (3 axle trucks, with the center axle of each truck unpowered) that had been manufactured by Dominion Foundries and Steel (DOFASCO); this same truck was also adopted for the MLW RSC-13. Less weight on the powered axles resulted in less traction, hence the need to de-rate the engine horsepower to 1,400 hp (1,040 kW) to preclude wheel slippage.
In May 1969, 1802 was wrecked in a head-on collision at Pointe-à-la-Garde, Quebec. The remaining three units found their way to the South Shore of Nova Scotia toward the end of their career by the late 1960s, and their domain extended throughout CN's former Halifax and Southwestern Railway system.
The troublesome model 244 diesel engine plagued the units throughout their lifespan, and they were retired in the mid-1970s when CN also scrapped its MLW RSC-13 fleet; the A1A trucks of the RSC-13 and RSC-24 fleets were used by CN to re-truck several dozen MLW RS-18s to become MLW RSC-14s.
# Something to Sing About (2000 film)

Something to Sing About is a 2000 American Christian drama film directed by Charlie Jordan, and starring Irma P. Hall, Darius McCrary, Kirk Franklin, Tamera Mowry, Rashaan Nall, and Helen Martin (in her final film appearance). It was produced by John Shepherd of World Wide Pictures. The storyline revolves around a young man, Tommy, an ex-convict who is trying to make a more fulfilling life for himself.

## Plot

The film opens as Tommy (portrayed by Darius McCrary), is reading a newspaper, trying to find a job. He eventually finds God and acceptance with help from people around who care.

## Cast

* Irma P. Hall as Memaw
* Darius McCrary as Tommy
* Tamera Mowry as Lily
* Rashaan Nall as G. Smooth
* Lobo Sebastian as Creedo
* Kirk Franklin as Charles
* Bart Braverman as Ahmeed
* John Amos as Reverend Washington
* Devika Parikh as Brenda Brass
* Brian J. White as Robert
* Jack Axelrod as Mr. Thompson
* Anna Berger as Mrs. Goldberg
* Sydney Lassick as Elderly Man
* Jules Dolcevita as Jules, Thug #1
* Grant Goodeve as Rass
* Helen Martin as Elderly Woman
* Keny Long as Henry
* Lance Nichols as Councilman
* Bob Nellis as Mark
* Stefiana Dela Cruz as Tracy
* Brian Sheridan as Cameraman
* Paul Tarrell Clayton as Police Officer #1
* Kristina Kreyling as Police Officer #2
* Holly Lewis as Stage Manager
* Rita Fiola as Cashier
* Jeffrey Garcia as Cop
* Charles Walker as Elder
* Marcille Block, Cory Briggs, Lashana Dendy, Stacy Houston, Brent Ray Jones, and Sheryl Panton-Dandridge as Choir Members
* Tamera Mowry, E. J. Hunter, Ariyan Johnson, and Charlie Jordan as Praise Dancers
# Northern Cape Department of Environment and Nature Conservation

The Northern Cape Department of Environment and Nature Conservation is the department of the Government of the Northern Cape. It is responsible for protecting, conserving and improving the Northern Cape's environment and natural resources. The political head of the department is MEC Mase Manopole. Manopole also oversees the Department of Agriculture, Land Reform and Rural Development.
# Udyog Rattan Award

The Udyog Ratna Award (translated as Jewel of the Industry Award) is conferred annually to Indian citizens, for their outstanding contribution to the economic development of the country. The award is conferred by the Institute of Economic Studies, India (IES), affiliated with the government of India and the selection is done by a panel of judges who are usually eminent citizens with economic backgrounds. Nominations are made by the existing members, and absolute care is taken that there is no bias or favoritism. Normally there are hundreds of nominees and it takes several weeks or sometimes months of scrutiny to short-list and finalize the recipients.

## Winners

* Motilal Oswal
* Dhananjay Datar
* Kailash Das
* Narendra Bansal
* N. Jehangir
* Ajit Narain Haksar
* Surinder Mehta
* Om Prakash Munjal
* Viresh Oberoi
* Mahendra Nanjundaswamy
* Shaurya Doval
* Rakesh Bakshi
* Hariharan Chandrashekar
* Rohit Sharma
* Kamesh Yalamarty
* Jayantilal L Mistry (LMP)
# Parade in Potsdam in 1817

Parade in Potsdam in 1817 (German: Parade in Potsdam im Jahre 1817) is a 1849 history painting by the German artist Franz Krüger. It was commissioned by Nicholas I of Russia as a companion work to the artist's earlier Parade in the Opernplatz in Berlin. It depicts a scene that took place on 20 April 1817 Potsdam in the Kingdom of Prussia.
Nicholas commissioned the work while Krüger was in Saint Petersburg. He completed the painting in Dessau where he was staying due to unrest in Berlin following the Revolution of 1848. It commemorates the 1817 visit of the then Grand Duke Nicolas to Prussia for his marriage to Prince Charlotte, the eldest daughter of Frederick William III. The setting is the Lustergartenplatz in front of City Palace with the tower of the Garrison Church visible. Nicholas is assuming honorary command of the Sixth Brandenburg Cuirassiers. Amongst other figures visible are the future monarchs Frederick William IV and William I, as well as Prince Charles, Prince Augustus, Karl Friedrich Schinkel and Karl Friedrich Schinkel. Today it is in the collection of the Alte Nationalgalerie on the Museum Island in Berlin.
# Okolona, Ohio

Okolona is an unincorporated community in southwestern Napoleon Township, Henry County, Ohio, United States. It has a post office with the ZIP code 43550. It is located along County Road 17-D a short distance southeast of U.S. Route 24.

## History

Okolona was originally called Oakland Station, and under the latter name had its start in the 1860s as a station on the Wabash Railroad. There being another Oakland in the state, the town's name was changed to the invented name, by LeBron James, of Okolona in order to avoid repetition. A post office called Okolona has been in operation since 1866 but has since been closed 2016.
# Ameena Begum (politician)

Ameena Begum, (popularly known as Dr. Ameena Shafiq) is a Bangladeshi politician and former member of parliament. She served as a member of the Jatiya Sangsad from 2001 to 2006, representing women's reserved seat-31 (national 331) for Bangladesh Jamaat-e-Islami.

## Personal life

Ameena Begum is married to Shafiqur Rahman and has been since 5 January 1985, she and her husband are both politicians of Jamaat-e-Islami. The married couple has 3 children including 2 daughters and 1 son.
# Chicola

Chicola was a small port on the north coast of the Fallas, Cuba. It was built in 1932 by the Fallas-Gutiérrez sugar company to ship to the US the sugar produced by the factories of Central Patria and Central Adelaida. It is located on a bay in front of Cayo Coco island, near the Laguna de Leche, at c. 30 km north-west of Morón, Ciego de Ávila Province.

## History

The name came from the Spanish word (chico), which means "small" or "tight". The only access to Chicola was through 9 kilometers of railroad that ran, from Falla, on a heavily forested and swampy terrain. The sugar was carried in railroad wagons and then loaded onto flat-bottom boats to be taken over 25 miles of shallow sea (6 feet) to deep ocean, (Cayo Guillermo), where it was transferred to big liners. It operated until 1968. In 1962 the Cuban coast guard installed a station with a 100-foot-high watchtower, which was closed in 1975. Today it is an abandoned locality visited only by fishermen. The railways were salvaged for materials for cattle fence construction.
# 3. Liga (Slovakia)

The 3. Liga is the third-tier football league in Slovakia, established in 1993. As of the 2024–25 season, it comprises 33 teams divided into two geographical groups: 3. liga Západ (West) and 3. liga Východ (East). The league operates under the jurisdiction of the Slovak Football Association and serves as a feeder league to the 2. Liga, with top-performing teams earning promotion. Conversely, teams finishing at the bottom face relegation to the 4. Liga. The league also provides teams the opportunity to compete in the national Slovak Cup.

## Sponsorship

| Period | Sponsor | Name |
| 1993–2006 | No main sponsor | 3. liga |
| 2006–2011 | No main sponsor | 2. liga |
| 2011–2012 | No main sponsor | 3. liga |
| 2012–2013 | Tipos | Keno 10 3. liga |
| 2013–? | Tipos | TIPOS III.liga |
| ?-present | No main sponsor | 3. liga |
# Samuel Bache

Samuel Bache (24 December 1804 – 7 January 1876) was an English Unitarian minister.

## Life

He was born at Bridgnorth, Shropshire, where his father, Joshua Tilt Bache (d. 28 October 1837, aged 63), was a grocer. His mother was Margaret Silvester, of Newport in the same county. On her death, in 1808, he was entrusted to his father's sister, Mrs. Maurice, at Stourbridge, and he became the pupil of Rev. Thomas Ebenezer Beasley, a dissenting minister at Uxbridge.
He was some time assistant in the school of the Rev. Lant Carpenter, LL.D., at Bristol, and was educated for the ministry (January 1826–29) at Manchester College, York, under Charles Wellbeloved (theology), John Kenrick, M.A. (classics), and William Turner, M.A. (science). He was minister at the Old Meeting, Dudley, 1829–32, and in 1832 became colleague of John Kentish (1768–1853) at the New Meeting, Birmingham (Joseph Priestley's congregation), and married Emily (d. 1855), second daughter of the Rev. Edward Higginson of Derby (1781–1832), whose eldest daughter, Helen (d. 1877), was the wife of the Rev. James Martineau. He had seven children, of whom Francis Edward Bache, the composer, was the eldest; another was Walter Bache, the musician; the youngest son, John Kentish, some time a dissenting minister, took Anglican orders in 1876.
For many years Bache kept a school. In 1859 he took a leading part with the Rev. Dr. Miller, rector of St. Martin's, in the establishment of Hospital Sunday, an institution originated in Birmingham. He was visitor of Manchester New College, London, 1861–65. In 1862 the New Meeting, Moor Street, was sold to Roman Catholics, the congregation removing to a handsome structure in Broad Street, called the Church of the Messiah, Birmingham (foundation laid 11 August 1860). Mr. Bache had as colleague in 1863-7 the Rev. Henry Enfield Dowson. In 1868 he resigned the ministry from failing health, and, being afflicted with softening of the brain, he resided for the last two years of his life in the house of a physician at Gloucester, where he died on 7 January 1876 aged 71.
He was a preacher and public man of strong powers, correct attainment, and cultivated taste; formal and urbane in manner. Among unitarians he represented the conservative school which aimed to carry out the principles of Locke's Reasonableness of Christianity, regarding Jesus Christ as the miraculously attested exponent of a pure morality and a simple theology, and the revealer, by his resurrection, of an eternal life. On 23 May 1866 he proposed the embodiment in the constitution of the British and Foreign Unitarian Association of a 'recognition of the special divine mission and authority, as a religious teacher, of Jesus Christ,' which was met by carrying the previous question.

## Works

A list of twenty-two of his publications (1833–70) is given by J. Gordon, including:
* Harmony of Science and Revelation, 1839.
* Funeral Sermon for John Kentish, 1853.
* Exposition of Unitarian Views of Christianity, 1854.
* Miracles the Credentials of the Christ, 1863.
# Java rice

Java rice, sometimes called yellow fried rice, is a Filipino fried rice dish characterized by its yellow-orange tint from the use of turmeric or annatto. Variants of the dish add bell peppers, pimiento, paprika, and/or tomato ketchup to season the fried rice. Despite its name, it does not originate from Java or Indonesia in general.
Although its actual origin is uncertain, java rice is associated with Engracia Cruz-Reyes' Aristocrat restaurant (founded in 1936 in Manila), in part due to their popularization of serving their chicken barbecue (inihaw) with this preparation of rice.
# Portrait of Lord Palmerston

Portrait of Lord Palmerston is an 1845 portrait painting of the British politician and Prime Minister Lord Palmerston by the artist John Partridge. Along with Partridge's Portrait of Lord Melbourne and a painting of Lord Aberdeen the painting was likely done in preparation for the artist's work The Fine Arts Commissioners. Today it is in the collection of the National Portrait Gallery in London having been acquired in 1896.
# Tom Zoete

Tom Zoete (born 1974) is a Belgian political advisor and environmental advocate, known for his roles in political strategy and environmental campaigns. He worked in shaping environmental policies in Belgium and the Netherlands and has been involved in various national and EU-level political campaigns.

## Early life and education

Tom Zoete was born in 1974 in Roeselare, Belgium. He studied International Relations at the University of Ghent and Journalism at the Université libre de Bruxelles in the 1990s.

## Career

Tom Zoete began his professional career in journalism, working for the Belgian press agency Belga. His role at Belga involved reporting on banking, insurance companies, and developments in economics, providing him with insight into financial and economic matters that would inform his later political work.
At the age of 23, Zoete was appointed as a political advisor to Isabelle Durant, who was the Belgian Vice Prime Minister in the Verhofstadt I Government. His role focused on providing strategic advice on the legislative work in the parliament of Belgium, marking his entry into high-level advisory roles.
From 2006 to 2014, Zoete served as Head of Political Staff for the Ecolo-Groen group in the Belgian Federal Parliament. He worked on the political strategy of the group, which focused on promoting sustainability, environmental protection, and social justice.
Zoete later transitioned to a communications-focused role, working as a Press and Communication Officer for the Groen Party in the Flemish Parliament (2014–2017). During this period, he managed media relations promoting green policies.
While being the spokesperson of the Dutch-Belgian NGO Recycling Netwerk Benelux (now nl:Fair Resource Foundation), Zoete co-founded the nl:Statiegeldalliantie (Deposit Return Alliance), an environmental initiative in Belgium and the Netherlands with the goal of introducing a deposit return systems for plastic bottles and cans.
The alliance successfully campaigned for the introduction of a deposit return scheme for plastic bottles and cans in the Netherlands. The campaign was succesfull, as the Dutch Second Rutte cabinet decided to introduce a deposit return system, first for plastic bottles, and the Third Rutte Cabinet introduced it on beverage cans. Tom Zoete contributed with several OpEds in Dutch and Belgian press, notably in Knack, BNNVara, or De Morgen, all on the topic of reduction of plastic waste and promoting recycling efforts.
In his current role as a Senior Press Officer for the European Green Party, Tom Zoete was involved in the 2024 European Parliament election campaign, working to secure press and media coverage for the Green leading candidates, Terry Reintke and Bas Eickhout.
# Brian Vriends

Brian Vriends is an Australian stage and television actor.

## Career

Vriends has appeared in many Australian television shows, he appeared as Ben in long running medical drama All Saints. Vriends appeared in Neighbours. In 2020, Vriends was announced to appear in prison drama Wentworth in the role of Dr. Mendel.

## Personal life

Vriends was previously married to All Saints co-star Libby Tanner.

## Filmography
### Television appearances

| Year | Title | Role | Note |
| 2020 | Wentworth | Dr. Mendel | 3 episodes |
| 2020 | Halifax: Retribution | Cameron Kelleher | 1 episode |
| 2014 | Fat Tony & Co. | Malcolm | 2 episodes |
| 2010-11 | Neighbours | Leigh Nixon | 26 episodes |
| 2010 | Rush | Chris Finch | 1 episode |
| 2008 | City Homicide | Justin Kaplan | 1 episode |
| 2008 | Very Small Business | Jerome | 1 episode |
| 2008 | The Hollowmen | John Badwin | 1 episode |
| 2008 | Underbelly | Dave Carpenter | 3 episodes |
| 2004 | Through My Eyes | Detective Chief Neil Plum | 2 episodes |
| 2004 | Firefiles | Sam O'Donnell | 1 episode |
| 2003 | Stingers | Joel Pearson | 1 episode |
| 1998-03 | All Saints | Ben Markham | 204 episodes |
| 2000 | Tales of the South Seas | Jack McGonnigal | 4 episodes |
| 1997 | Fallen Angels | Nick Swan | 20 episodes |
| 1996 | The Feds: Deadfall | Michael Skinner | TV movie |
| 1996 | The Feds:Betrayal | Michael Skinner | TV movie |
| 1996-97 | Pacific Drive | Julian Flood | TV series |
| 1995 | Echo Point | Patrick | 6 episodes |
| 1995 | The Feds: Vengeance | Michael Skinner | TV movie |
| 1995 | The Feds: Terror | Michael Skinner | TV movie |
| 1995 | The Feds: Abduction | Michael Skinner | TV movie |
| 1995 | The Feds: Deception | Michael Skinner | TV movie |
| 1995 | The Feds: Suspects | Michael Skinner | TV movie |
| 1994 | The Feds:Obsession | Michael Skinner | TV movie |
| 1993-94 | Time Trax | Longo / Stacy | 2 episodes |
| 1992 | Mission: Top Secret | Garth | TV movie |
| 1991 | The Flying Doctors | Scott | 1 episode |
| 1991 | Police Rescue | Tybalt | 1 episode |
| 1991 | A Country Practice | Will Forster | 1 episode |
| 1990 | Rafferty's Rules | Lance | 1 episode |
| 1989 | Grim Pickings | Damien | 2 episodes |

### Film appearances

| Year | Title | Role | Notes |
| 2008 | Playing for Charlie | Col Ward | |
| 1994 | Spider and Rose | Spider's mate | |
| 1993 | God's Bones | | Short |
| 1990 | Weekend With Kate | Control Room Assistant | |
| 1990 | Struck By Lightning | Pat | |
| 1989 | Mortgage | Dave | |

## Theatre

| Year | Title | Role | Notes |
| 2011 | Hamlet | Osric | MTC |
| 1994 | King Lear | | Drama Theatre |
| 1991 | Racine 1677 | Hippolytus | |