OpenLLM-France/wikimedia huggingface dataset:
# Perrhenic acid

Perrhenic acid is the chemical compound with the formula Re$_2$O$_7$(H$_2$O)$_2$. It is obtained by evaporating aqueous solutions of Re$_2$O$_7$. Conventionally, perrhenic acid is considered to have the formula HReO$_4$, and a species of this formula forms when rhenium(VII) oxide sublimes in the presence of water or steam. When a solution of Re$_2$O$_7$ is kept for a period of months, it breaks down and crystals of HReO$_4$·H$_2$O are formed, which contain tetrahedral ReO−4. For most purposes, perrhenic acid and rhenium(VII) oxide are used interchangeably. Rhenium can be dissolved in nitric or concentrated sulfuric acid to produce perrhenic acid.

## Properties

The structure of solid perrhenic acid is [O$_3$Re−O−ReO$_3$(H$_2$O)$_2$]. This species is a rare example of a metal oxide coordinated to water; most often metal–oxo–aquo species are unstable with respect to their corresponding hydroxides:
    M(O)(H$_2$O) → M(OH)$_2$
The two rhenium atoms have different bonding geometries, with one being tetrahedral and the other octahedral, and with the water ligands coordinated to the latter.
Gaseous perrhenic acid is tetrahedral, as suggested by its formula HReO$_4$.

## Reactions

Perrhenic acid or the related anhydrous oxide Re$_2$O$_7$ converts to dirhenium heptasulfide upon treatment with hydrogen sulfide:
    Re$_2$O$_7$ + 7 H$_2$S → Re$_2$S$_7$ + 7 H$_2$O
The heptasulfide catalyzes various reductions.
Perrhenic acid in the presence of hydrochloric acid undergoes reduction in the presence of thioethers and tertiary phosphines to give rhenium(V) complexes with the formula ReOCl$_3$L$_2$.
Perrhenic acid combined with platinum on a support gives rise to a useful hydrogenation and hydrocracking catalyst for the petroleum industry. For example, silica impregnated with a solution of perrhenic acid is reduced with hydrogen at 500 °C. This catalyst is used in the dehydrogenation of alcohols and also promotes the decomposition of ammonia.

### Catalysis

Perrhenic acid is a precursor to a variety of homogeneous catalysts, some of which are promising in niche applications that can justify the high cost of rhenium. In combination with tertiary arsines, perrhenic acid gives a catalyst for the epoxidation of alkenes with hydrogen peroxide. Perrhenic acid catalyses the dehydration of oximes to nitriles.

## Other uses

Perrhenic acid is also used in the manufacture of x-ray targets.
# Shuji Sato (astronomer)

Shuji Sato (佐藤 修二, SATO Shuji, born 9 April 1945, in Fukuoka Prefecture, Japan) is a Japanese astronomer and Professor Emeritus of Nagoya University. His specialty is infrared astronomy.

## Career

1968 graduated from the Department of Physics, Faculty of Science, Kyoto University.
1973 received a PhD degree from the Department of Physics, Graduate School of Science, Kyoto University.
1973 became an assistant professor at the Department of Physics, Graduate School of Science, Kyoto University.
1987 became an associate professor at the Tokyo Astronomical Observatory, University of Tokyo (present National Astronomical Observatory of Japan).
1988 became an associate professor at the National Astronomical Observatory of Japan.
1992 became a professor at the Graduate School of Science, Nagoya University.
2008 retired from Nagoya University and kept the Laboratory as a donated Professor.
His graduate school supervisor was Haruyuki Okuda. One of his students is Motohide Tamura.

## Professional record

1970 constructed Astronomical Infra Red Observatory (AIRO) at Agematsu, Kiso, Nagano, and various infrared photometers and started the infrared observations in Japan.
1980 developed the observations using the instruments overseas, Mauna Kea, Australia, and Mainland, USA and carried out the researches.
1987 arranged the infrastructure to develop the SUBARU Project in Hawaii.
1992 built up TRISPEC (Triple-Range Imager and SPECtrograph with Polarimetry) and carried out the researches at Mauna Kea in 2001~02 and Okayama in 2003.
1998 constructed Infra-Red Survey Facility (IRSF with SIRIUS; Simultaneous InfraRed Imager for Unbiased Survey) at Sutherland, South Africa, and carried out a number of survey works. 2004 constructed the KANATA telescope at Higashi-Hiroshima, with which he carried out the researches using TRISPEC in collaboration with Hiroshima University.
2008 devised a compact and inexpensive instrument, TRIPOL (Triple-Range Imager with Polarimetry) and distributed them in East Asia, with which he is continuing researches.
# 1956 LSU Tigers football team

The 1956 LSU Tigers football team was an American football team that represented Louisiana State University (LSU) as a member of the Southeastern Conference (SEC) during the 1956 college football season. In their second year under head coach Paul Dietzel, the Tigers complied an overall record of 3–7, with a conference record of 1–5, and finished ninth in the SEC.

## Schedule

| Date | Opponent | Site | Result | Attendance |
| September 29 | No. 11 Texas A&M* | Tiger StadiumBaton Rouge, LA (rivalry) | L 6–9 | 61,000 |
| October 6 | at Rice* | Rice StadiumHouston, TX | L 14–23 | 55,000 |
| October 13 | at No. 3 Georgia Tech | Grant FieldAtlanta, GA | L 7–39 | 39,500 |
| October 20 | at Kentucky | McLean StadiumLexington, KY | L 0–14 | |
| October 27 | Florida | Tiger StadiumBaton Rouge, LA (rivalry) | L 6–21 | 35,000 |
| November 3 | Ole Miss | Tiger StadiumBaton Rouge, LA (rivalry) | L 17–46 | 35,000 |
| November 10 | Oklahoma A&M* | Tiger StadiumBaton Rouge, LA | W 13–0 | 22,000 |
| November 17 | Mississippi State | Tiger StadiumBaton Rouge, LA (rivalry) | L 13–32 | 25,000 |
| November 24 | Arkansas* | State Fair StadiumShreveport, LA (rivalry) | W 21–7 | 28,000 |
| December 1 | Tulane | Tiger StadiumBaton Rouge, LA (Battle for the Rag) | W 7–6 | 60,000 |
| *Non-conference gameHomecomingRankings from AP Poll released prior to the game ||||||
# 1962 LSU Tigers football team

The 1962 LSU Tigers football team was an American football team that represented Louisiana State University (LSU) as a member of the Southeastern Conference (SEC) during the 1962 NCAA University Division football season. In their first year under head coach Charles McClendon, the Tigers complied an overall record of 9–1–1, with a conference record of 5–1, and finished third in the SEC.

## Schedule

| Date | Opponent | Rank | Site | TV | Result | Attendance |
| September 22 | Texas A&M* | No. 5 | Tiger StadiumBaton Rouge, LA (rivalry) | | W 21–0 | 68,000 |
| September 29 | Rice* | No. 5 | Tiger StadiumBaton Rouge, LA | | T 6–6 | 67,500 |
| October 6 | at No. 5 Georgia Tech | | Grant FieldAtlanta, GA | NBC | W 10–7 | 49,744 |
| October 13 | Miami (FL)* | No. 6 | Tiger StadiumBaton Rouge, LA | | W 17–3 | 67,500 |
| October 20 | at Kentucky | No. 4 | McLean StadiumLexington, KY | | W 7–0 | 37,000 |
| October 27 | Florida | No. 6 | Tiger StadiumBaton Rouge, LA (rivalry) | | W 23–0 | 67,000 |
| November 3 | No. 6 Ole Miss | No. 4 | Tiger StadiumBaton Rouge, LA (rivalry) | | L 7–15 | 67,500 |
| November 10 | TCU* | No. 9 | Tiger StadiumBaton Rouge, LA | | W 5–0 | 66,500 |
| November 17 | at Mississippi State | No. 10 | Mississippi Veterans Memorial StadiumJackson, MS (rivalry) | | W 28–0 | 40,000 |
| November 24 | at Tulane | No. 8 | Tulane StadiumNew Orleans, LA (Battle for the Rag) | | W 38–3 | 41,000 |
| January 1, 1963 | vs. No. 4 Texas* | No. 7 | Cotton BowlDallas, TX (Cotton Bowl Classic) | CBS | W 13–0 | 75,500 |
| *Non-conference gameHomecomingRankings from AP Poll released prior to the game ||||||||
# Elfi Eder

Elfriede "Elfi" Eder (born 5 January 1970 in Leogang) is a former alpine skier from Austria.
She represented the Caribbean island of Grenada from 1998 to 1999, having previously competed for Austria.
The alpine skier Sylvia Eder is her elder sister.

## World Cup victories

| Date | Location | Race |
| 18 November 1995 | Vail | Slalom |
| 17 December 1995 | St. Anton | Slalom |
| 30 December 1995 | Semmering | Slalom |
# 1950 Georgia Tech Yellow Jackets football team

The 1950 Georgia Tech Yellow Jackets football team was an American football team that represented Georgia Tech as a member of the Southeastern Conference (SEC) during the 1950 college football season. In their sixth year under head coach Bobby Dodd, the team compiled an overall record of 5–6, with a mark of 4–2 in conference play, placing fifthin the SEC.

## Schedule

| Date | Opponent | Site | Result | Attendance |
| September 23 | at No. 10 SMU* | Cotton BowlDallas, TX | L 13–33 | 54,000 |
| September 30 | South Carolina* | Grant FieldAtlanta, GA | L 0–7 | 25,000 |
| October 7 | Florida | Grant FieldAtlanta, GA | W 16–13 | 21,000 |
| October 14 | at LSU | Tiger StadiumBaton Rouge, LA | W 13–0 | 42,000 |
| October 21 | Auburn | Grant FieldAtlanta, GA (rivalry) | W 20–0 | 22,000 |
| October 28 | No. 4 Kentucky | Grant FieldAtlanta, GA | L 14–28 | 35,000 |
| November 4 | at Duke* | Duke StadiumDurham, NC | L 21–30 | 30,000 |
| November 11 | VMI* | Grant FieldAtlanta, GA | L 13–14 | 22,000 |
| November 18 | Alabama | Grant FieldAtlanta, GA (rivalry) | L 19–54 | 38,000 |
| November 25 | Davidson* | Grant FieldAtlanta, GA | W 46–14 | 20,000 |
| December 2 | at Georgia | Sanford StadiumAthens, Georgia (Clean, Old-Fashioned Hate) | W 7–0 | 50,000 |
| *Non-conference gameHomecomingRankings from AP Poll released prior to the game ||||||
# IRNSS-1D

IRNSS-1D is a satellite in the Indian Regional Navigational Satellite System (IRNSS) constellation. The satellite is the fourth of seven in the constellation, launched after IRNSS-1A, IRNSS-1B and IRNSS-1C. The satellite is the only satellite in the constellation slated to provide navigational services to the region. The satellite will be placed in geosynchronous orbit. It was launched successfully on 28 March 2015 onboard ISRO's PSLV-C27 from Satish Dhawan Space Centre, Sriharikota.

## Satellite

The satellite will help in augmenting the satellite based navigation system of India which is currently under development. The navigational system so developed will be a regional one targeted towards South Asia. The satellite will provide navigation, tracking and mapping services.
IRNSS-1D satellite has two payloads: a navigation payload and CDMA ranging payload in addition with a laser retro-reflector. The payload generates navigation signals at L5 and S-band. The design of the payload makes the IRNSS system inter-operable and compatible with Global Positioning System (GPS) and Galileo. The satellite is powered by two solar arrays, which generate power up to 1,660 watts, and has a life-time of ten years.

### Cost

The total cost of the mission was estimated at ₹14 billion.
# IRNSS-1E

IRNSS-1E is the fifth out of seven in the Indian Regional Navigational Satellite System (IRNSS) series of satellites after IRNSS-1A, IRNSS-1B, IRNSS-1C and IRNSS-1D. It is one among the seven of the IRNSS constellation of satellites launched to provide navigational services to the region. The satellite was placed in geosynchronous orbit. IRNSS-1E has been successfully launched into orbit on 20 January 2016 In 2025, IRNSS-1E was planned to be replaced at its orbital slot of 111.75ºE by NVS-02. However, following the failure of NVS-02, IRNSS-1E will countinue to remain at its slot.

## Satellite

IRNSS-1E will help augmenting the satellite based navigation system of India which is currently under development. The navigational system so developed will be regional, targeted towards South Asia. The satellite will provide navigation, tracking and mapping services.
The satellite will have two payloads: a navigation payload and CDMA ranging payload in addition with a laser retro-reflector. The payload generates navigation signals at L5 and S-band. The design of the payload makes the IRNSS system interoperable and compatible with Global Positioning System (GPS) and Galileo. The satellite is powered by two solar arrays, which generate power up to 1,660 watts, and has a designed life-time of twelve years.

## Launcher

The Polar Satellite Launch Vehicle, in its 33rd flight (PSLV-C31), launched IRNSS-1E from the Second Launch Pad (SLP) of Satish Dhawan Space Centre (SDSC), Sriharikota. As in the previous four launches of IRNSS satellites, PSLV-C31 will use ‘XL’ version of PSLV.
# Frederiksberg RK

Frederiksberg RK is a Danish rugby union club based in Frederiksberg (Copenhagen area). The senior team competes in the DRU Division One. The club also includes a women's team and a vibrant youth section.

## History

The club was founded in 1975 by Erik Andersen, who then served as Chairman of the Danish Rugby Union (1969–1996), to provide the proper sports infrastructure for his children and their friends in the city of Frederiksberg.

## Recent Internationally-Capped Players

* Tomas Mayne
* Rasmus Greve
* Emil Svinth Aagaard
* Michael Attali Strøyberg
* Andrei Ungureanu
* Eugene Hanrahan
* Erwan Caquineau
* Thomas Hobbs
* Rasmus Madum
* Cassius Deschamps
* Otto Kaszner
* Thomas Thimothée
* Geoffroy Gauthier
* Hamish Coventry
* Nikolay Hinov
* Jānis Podiņš
* Unai Arrieta Armendariz

## Honours

* Danish Championship
** 1992, 1993, 2002, 2003, 2004, 2005, 2015, 2018, 2019, 2021*, 2022
* Danish Cup
** 1992, 1994, 1998, 1999, 2001, 2004, 2005, 2006.
The 2020 Danish Championship was not disputed due to the COVID-19 pandemic.
# Hugh Gibbons

Hugh Gibbons (6 July 1916 – 14 November 2007) was an Irish Fianna Fáil politician who sat in Dáil Éireann as a Teachta Dála (TD) for twelve years, from 1965 to 1977.

## Early life

He was born 6 July 1916 in Ballybeg, Strokestown, County Roscommon, the fourth child of Luke Gibbons and his wife Ellen (née Egan). His parents married in 1910 and his father was a publican and merchant. Hugh Gibbons was educated in Carniska national school, Strokestown, and in 1929 won a scholarship to attend secondary school at Summerhill College, Sligo. In 1934 he won a scholarship to University College Galway and passed his final medical exams in December 1940.

## Politics

A medical doctor before entering politics, Gibbons was elected on his first attempt, when he stood as a Fianna Fáil candidate in the Roscommon constituency at the 1965 general election. After constituency changes, he was re-elected at the 1969 general election in the new Roscommon–Leitrim constituency. He was returned to the Dáil again at the 1973 general election, but did not contest the 1977 general election and retired from politics.

## Sports

Gibbons was also holder of three All-Ireland Medals while playing for Roscommon in the All-Ireland Senior Club Football and Junior Club Football Championships. In 1940 he played with the county junior team, which won the All-Ireland junior title that year. He then played for the county team which won the All-Ireland senior titles in 1943 and 1944. He also played for and co founded St Ronan's GAA club in North Roscommon.

## Death and personal life

He married Josephine Lee in 1949, and they had four sons and two daughters. His son, Brian Gibbons was the Labour Party Welsh Assembly Member for Aberavon from 1999 to 2010.
He died on 14 November 2007 at his home in Keadue, aged 91. On his death, he was described by then Taoiseach Bertie Ahern as a "sportsman and a scholar".
# Tarrants, Missouri

Tarrants is a village in central Pike County, Missouri, United States. The population was 22 at the 2010 census.

## Geography

Tarrants is located approximately one mile northeast of Bowling Green on Missouri Route AA.
According to the United States Census Bureau, the village has a total area of 0.04 square miles (0.10 km$^2$), all land.

## Demographics
### 2010 census

At the 2010 census there were 22 people, 12 households, and 9 families living in the village. The population density was 550.0 inhabitants per square mile (212.4/km$^2$). There were 13 housing units at an average density of 325.0 per square mile (125.5/km$^2$). The racial makup of the village was 100.0% White. Hispanic or Latino of any race were 4.5%.
Of the 12 households 8.3% had children under the age of 18 living with them, 58.3% were married couples living together, 16.7% had a female householder with no husband present, and 25.0% were non-families. 25.0% of households were one person and 16.6% were one person aged 65 or older. The average household size was 1.83 and the average family size was 2.11.
The median age in the village was 61.5 years. 4.5% of residents were under the age of 18; 9% were between the ages of 18 and 24; 13.5% were from 25 to 44; 36.3% were from 45 to 64; and 36.4% were 65 or older. The gender makeup of the village was 50.0% male and 50.0% female.

### 2000 census

As of the census of 2000, there were 30 people, 15 households, and 10 families living in the village. The population density was 689.3 inhabitants per square mile (266.1/km$^2$). There were 15 housing units at an average density of 344.6 per square mile (133.1/km$^2$). The racial makup of the village was 96.67% White and 3.33% African American.
Of the 15 households 6.7% had children under the age of 18 living with them, 66.7% were married couples living together, and 33.3% were non-families. 20.0% of households were one person and 13.3% were one person aged 65 or older. The average household size was 2.00 and the average family size was 2.30.
The age distribution was 3.3% under the age of 18, 6.7% from 18 to 24, 20.0% from 25 to 44, 40.0% from 45 to 64, and 30.0% 65 or older. The median age was 57 years. For every 100 females, there were 114.3 males. For every 100 females age 18 and over, there were 107.1 males.
The median household income was $20,833 and the median income for a family was $20,833. Males had a median income of $21,250 versus $0 for females. The per capita income for the village was $11,358. None of the population and none of the families were below the poverty line.

## Transportation

While there is no fixed-route transit service in Tarrants, intercity bus service is provided by Burlington Trailways in nearby Bowling Green.
# Murder of Valerie French

Valerie French was an Irish woman who was murdered by her husband, James Kilroy, in June 2019.

## Attack on Valerie French

On 13 June 2019 between 11 pm and midnight, Valerie French (41), was assaulted and killed at her house in Kilbree Lower, outside Castlebar in Co. Mayo. Her husband James Kilroy was arrested and charged with her murder.

## Trials

James Kilroy pleaded not guilty by reason of insanity. Following the collapse of two trials in 2023 a third trial held in July 2024 convicted James Kilroy of murder.
Justice Tony Hunt said that the defence of not guilty by reason of insanity was clearly not applicable as the diagnosis of cannabis-induced psychotic disorder being used clearly came under "intoxicating influence" as mentioned in the relevant legislation.

## Background

French, originally from Leap, County Cork, was a senior occupational therapist working in Castlebar, Co. Mayo, Ireland.
Valerie's mother, Valerie French (née Pyburn) died five months later in November 2019 as a result of a stroke which her family believe was brought on by the enormous stress and uncertainty following the murder of her daughter. Mrs French had said to her family that “my life is ruined” after the loss of her daughter and in concern about the future of her three young grandchildren.
James Kilroy is believed to be originally from Oldcastle, County Meath.
He was employed as a park ranger with the National Parks and Wildlife Service (Ireland) (NPWS) and had been working in Wild Nephin National Park.

## Legacy

The victim's brother David French has called for a change in the law to strip child guardianship from people convicted of killing partners with whom they share children. The argument for a change in the law was also made in the Irish Times.
Speaking outside the Criminal Courts of Justice, Dublin after the verdict French stated that "Valerie's husband killed her brutally yet he retains all his parental rights to her children. This is an absolutely ridiculous situation. Killing a mother is child abuse. Children have to be protected from abusers. Murderers in the UK have their parental rights suspended under what is called Jade's Law. This loophole needs to be closed to protect the children who are put in this hellish situation every year.".
The verdict and subsequent call for law reform received very significant media coverage.
Holly Cairns TD, Leader of the Social Democrats, started preparing a Bill to suspend parental rights of those convicted of domestic homicide.
The situation has drawn comparisons to the Murder of Jennifer Poole by her ex-partner where her brother Jason also called for law reform.
During a Dail debate on gender based violence brought forward by Ruth Coppinger TD on February 26th, 2025, Justice Minister Jim O'Callaghan announced that a memorandum will go to Government in March seeking an amendment to the Guardianship of Infants Act to implement “Valerie’s Law”, which would remove guardianship rights from people who killed their spouse.
# Countyline, Oklahoma

Countyline, or County Line, is a rural unincorporated community on the Stephens-Carter county line in south central Oklahoma, United States. It is north of State Highway 7. The post office opened June 29, 1928.
# Adrian Beck

Adrian Beck (born 9 June 1997) is a German professional footballer who plays as an attacking midfielder for Bundesliga club 1. FC Heidenheim.

## Career

Born in Crailsheim, Beck spent time with 1899 Hoffenheim, 1899 Hoffenheim II, SSV Ulm and Union Saint-Gilloise, before moving on loan to Scottish club Hamilton Academical in September 2019. The loan ended on 30 January 2020 and the following day, he returned to SSV Ulm.
On 11 May 2022, Beck signed a three-year contract with 1. FC Heidenheim beginning on 1 July 2022.
# Ministry of National Defence and Homeland Veterans (Angola)

The Ministry of National Defence and Homeland Veterans (Portuguese: Ministro da Defesa Nacional e Veteranos da Pátria) is an executive agency of the Government of Angola that controls the Angolan Armed Forces. It is based at Rua 17 de Setembro in Luanda.

## Name changes

* 1975–1995: Ministry of Defence
* 1996–present: Ministry of National Defence

## Structure

* Military Affairs Cabinet ("Casa Militar"), headed by one of the three Ministers of State and answers directly to the Office of the President.

## Minister of National Defence

The Minister of National Defence of Angola is a cabinet level position in the national government. The minister is responsible for the entire defense establishment. The position was established in 1975 with Henrique Teles Carreira as the inaugural minister.

### List

* 1975–1979: Gen. Henrique Teles Carreira
* 1980–1995: Gen. Pedro Pedalé
* 1995–1999: Gen. Pedro Sebastião
* 1999–2010: Gen. Kundi Paihama
* 2010–2014: Gen. Cândido Pereira dos Santos Van-Dúnem
* 2014–2017: Gen. João Manuel Gonçalves Lourenço
* 2017–2020: Gen. Salviano de Jesus Sequeira
* 2020–present: Gen. João Ernesto dos Santos

### Deputies

The commanders of the three major military services each held the title of vice minister of defense.
# Down Twisted

Down Twisted is a 1987 thriller film, directed by Albert Pyun, and starring Carey Lowell, Charles Rocket, Courteney Cox, Norbert Weisser, Linda Kerridge, Trudi Dochtermann and Nicholas Guest.

## Plot

A naïve, good-hearted Los Angeles waitress does not think twice about helping her troubled roommate. Her help lands her in Central America fleeing for her life with a grungy mercenary.

## Cast

* Carey Lowell as Maxine
* Charles Rocket as Reno
* Trudy Dochterman as Michelle (Trudi Dochtermann)
* Thom Mathews as Damalas
* Norbert Weisser as Alsandro Deltoid
* Linda Kerridge as Soames
* Nicholas Guest as Brady
* Galyn Görg as Blake (Galyn Gorg)
* Courteney Cox as Tarah
* Bambi Jordan as Suzie
* Ken Wright as Mr. Wicks
* Alec Markham as Captain
* Eduardo Cassab as Sargento
* Christabel Wigley as Theona
* Joe Holland as Mickey (credited as Tim Holland)

## Release

The film was given a limited theatrical release in March 1987. The home video release was in the United States in 1990 by Media Home Entertainment.