OpenLLM-France/wikimedia huggingface dataset:
# Niobium(V) chloride

Niobium(V) chloride, also known as niobium pentachloride, is a yellow crystalline solid. It hydrolyzes in air, and samples are often contaminated with small amounts of NbOCl$_3$. It is often used as a precursor to other compounds of niobium. NbCl$_5$ may be purified by sublimation.

## Structure and properties

Niobium(V) chloride forms chloro-bridged dimers in the solid state (see figure). Each niobium centre is six-coordinate, but the octahedral coordination is significantly distorted. The equatorial niobium–chlorine bond lengths are 225 pm (terminal) and 256 pm (bridging), whilst the axial niobium-chlorine bonds are 229.2 pm and are deflected inwards to form an angle of 83.7° with the equatorial plane of the molecule. The Nb–Cl–Nb angle at the bridge is 101.3°. The Nb–Nb distance is 398.8 pm, too long for any metal-metal interaction. NbBr$_5$, NbI$_5$, TaCl$_5$ TaBr$_5$ and TaI$_5$ are isostructural with NbCl$_5$.

## Preparation

Industrially, niobium pentachloride is obtained by direct chlorination of niobium metal at 300 to 350 °C:
    2 Nb + 5 Cl$_2$ → 2 NbCl$_5$
In the laboratory, niobium pentachloride is often prepared from Nb$_2$O$_5$, the main challenge being incomplete reaction to give NbOCl$_3$. The conversion can be effected with thionyl chloride: It also can be prepared by chlorination of niobium pentoxide in the presence of carbon at 300 °C.

## Uses

Niobium(V) chloride is the main precursor to the alkoxides of niobium, which find uses in sol-gel processing. It is also the precursor to many other Nb-containing reagents, including most organoniobium compounds.
In organic synthesis, NbCl$_5$ is a very specialized Lewis acid in activating alkenes for the carbonyl-ene reaction and the Diels-Alder reaction. Niobium chloride can also generate N-acyliminium compounds from certain pyrrolidines which are substrates for nucleophiles such as allyltrimethylsilane, indole, or the silyl enol ether of benzophenone.
# Jeffrey Ladd

Jeffrey Ladd (born 1968) is an American photographer and writer on photography. He is a co-founder of Errata Editions.

## Life and work

Ladd gained a Bachelor of Fine Arts degree from the School of Visual Arts in New York City, in 1991.
He is a co-founder of the publisher Errata Editions and its Books on Books series is his concept, publishing affordable facsimile editions of rare and out of print photo books. From 2007 to 2012 he wrote the 5B4 Photography and Books blog, discussing and reviewing photography and art-related books. He was a member of the In-Public street photography collective.
Ladd's street photography was included in 10 – 10 Years of In-Public, published by Nick Turpin in 2010. His book The Awful German Language (2020) contains "lists of interesting German vocabulary words which he juxtaposes next to his black and white photographs". His book, A Field Measure Survey of America Architecture (2021), according to Kyra Ho writing in the Financial Times, contains photographs of houses from the Historic American Buildings Survey's archive of buildings of the 19th- and 20th-century United States, following the Mason–Dixon line, "to create a documentary-style architectural portrait".
Since 2011 he has lived in Cologne, Germany.

## Publications
### Books by Ladd

* The Awful German Language. Leipzig: Spector, 2020. ISBN 978-3959053440.
* A Field Measure Survey of America Architecture. London: Mack, 2021. ISBN 978-1913620417.

### Books with contributions by Ladd

* 10 – 10 Years of In-Public. London: Nick Turpin, 2010. ISBN 978-0-9563322-1-9. Includes an essay by Jonathan Glancey, "Outlandish Harmony"; a foreword by Nick Turpin; and a chapter each by Ladd and various other In-Public members.

## Collections

Ladd's work is held in the following permanent collection:
* Brooklyn Museum, Brooklyn, New York: 5 prints (as of May 3, 2023)
# Guirlande de Julie

The Guirlande de Julie (French pronunciation:, Julie's Garland) is a unique French manuscript of sixty-one madrigaux, illustrated with painted flowers, and composed by several poets habitués of the Hôtel de Rambouillet for Julie d'Angennes and given to her on her name day in May 1641. The 1641 manuscript was bought by the Bibliothèque nationale de France in 1989 and is now kept in the Département des Manuscrits of the BnF.

## Context

The salon of Catherine de Vivonne, marquise de Rambouillet (1588–1665), wife of Charles d'Angennes, marquis de Rambouillet (1577–1652), was the first and most brilliant Parisian literary salon of the first half of the 17th century, at its height between 1620 and 1645. The Hôtel de Rambouillet, as it was called, was frequented by renowned précieuses, writers, nobles and "robins".
One of its habitués, Charles de Sainte-Maure, marquis de Montausier (1610–1690), had been in love with the daughter of the marquis and marquise de Rambouillet, Julie d'Angennes (1606–1671), since he first met her in 1631. In the hope of finally wooing her, he decided to give her an extraordinary present.

## Production

Montausier asked the most talented poets of the time, all frequent visitors of the Hôtel de Rambouillet, to write one or several madrigals in which a flower would sing the praises of Julie. The final product was the work of nineteen poets. These madrigaux were composed by writers as famous as Georges de Scudéry, Desmarets de Saint-Sorlin, Valentin Conrart, Jean Chapelain, Racan, Tallemant des Réaux, Robert Arnauld d'Andilly, Simon Arnauld de Pomponne, Isaac Arnauld de Corbeville, Montmor, Germain Habert, Colletet, Claude Malleville, Philippe Habert, Antoine Gombaud, Antoine Godeau, Étienne Martin de Pinchesne [Wikidata], Pierre Corneille for a couple of the madrigals authored by "M. C." (but doubtful, according to Bibliothèque nationale de France) and the marquis de Rambouillet. Montausier himself wrote sixteen of the madrigals.
Then the text was ornamentally written by the calligraphist Nicolas Jarry and the flower quoted in each poem painted by Nicolas Robert, while the binding was done by Le Gascon. The final object turned out to be one of the most extraordinary manuscripts of the century and one of the highlights of the 17th century littérature galante.
Julie found the manuscript by her bed, upon awakening on the morning of her name day, 22 May 1641 (see 1641 in poetry). However, she let Montausier wait another four years, until 1645, before agreeing to marry him, fourteen years after they had first met.

## History of the manuscript

After the death of Montausier in 1690, the manuscript became the possession of the ducal Crussol family, in which his daughter, Marie-Julie de Sainte-Maure (1647-1692), duchesse of Uzès by marriage, had married. The manuscript was first sold in 1699, then several times thereafter. La Guirlande de Julie is now kept at the Département des Manuscrits of the Bibliothèque nationale de France (French National Library). It was published in 1729 (see 1729 in poetry), although several poems had already appeared in various collections.
# Storer v. Brown

Storer v. Brown, 415 U.S. 724 (1974), was a case in which the Supreme Court of the United States upheld a California law that prohibited an individual from running for an elected office as an independent candidate if they were registered with a political party within the 12 months prior to the primary election.
# Jonas Gregaard

Jonas Gregaard Wilsly (born 30 July 1996) is a Danish cyclist, who currently rides for UCI ProTeam Lotto. In October 2020, he was named in the startlist for the 2020 Giro d'Italia.

## Major results
### 2014

    1st Road race, National Junior Road Championships

### 2015

    1st Road race, National Under-23 Road Championships
    1st Stage 2 (TTT) ZLM Tour
    10th Ringerike GP

### 2016

    1st Himmerland Rundt
    1st Mountains classification, Tour de Normandie
    5th Coupe des Carpathes
    6th Ringerike GP
    10th Sundvolden GP

### 2017

    1st Overall Kreiz Breizh Elites
       1st Young rider classification
    3rd Overall Tour of Małopolska
       1st Young rider classification
    6th GP Viborg
    10th Overall Danmark Rundt
    10th Ringerike GP

### 2018

    1st Stage 4 (TTT) Tour de l'Avenir
    3rd Overall Giro della Valle d'Aosta
    4th Overall Tour of Małopolska
       1st Young rider classification

### 2021

    9th Vuelta a Murcia

### 2022

    6th Overall Route d'Occitanie
    7th Overall Tour de Luxembourg

### 2023

    1st Mountains classification, Paris–Nice

### Grand Tour general classification results timeline

| Grand Tour | 2020 | 2021 | 2022 | 2023 |
| Giro d'Italia | 53 | — | — | — |
| Tour de France | — | — | — | 43 |
| Vuelta a España | — | — | — | — |
Legend :
| — | Did not compete |
| DNF | Did not finish |
# FC Delta Tulcea

Fotbal Club Delta Tulcea, commonly known as Delta Tulcea, is a football club from Tulcea, Romania, originally founded in 1973, then refounded in 2005, 2013, and 2021. The club did not enroll in the 2024/25 Liga IV, and last played in the 2023/24 Liga IV, finishing 9th.

## History

The club was founded in 1973 as Fotbal Club Delta Tulcea then reorganized in 2005. The club's first president in the new format was Petre Marinescu since 20 May 2006.
In their first season after the reorganization, the team played in the Romanian third league, where they would win the league's second series by a margin of twenty points from the runner-up, CSM Râmnicu Sărat. The manager behind this success was Constantin Gache.
After having promoted to the second league, with the addition of a few new players, and the same coach, the team would go on to winning the second league in the 2006–07 season after managing an eight-win streak. Even so, the team would not promote to Liga I due to licensing problems.
It is due to this that the team would lose some of its valuable players at the time, and also its coach that went to the rival team Farul Constanța.
After this, they played in the Liga II until their dissolution in the summer of 2013. The club was refounded as Delta Dobrogea Tulcea in the same year.
Delta withdrew from Liga III during the 2018–19 season after a 60 points penalization due to financial problems, but continue to be active at youth level.
On August 27, 2022, Tulcenii announced that the club will not enroll for the 2022–23 season of Liga IV - Tulcea County due to the financial and organizational problems, but they will continue to focus on youth football.

## Honours

Liga II
* Winners (1): 2006–07
Liga III
* Winners (5): 1970–71, 1971–72, 1976–77, 1984–85, 2005–06
* Runners-up (1): 2015–16
Liga IV – Tulcea County
* Winners (3): 1994–95, 2004–05, 2013–14

## Notable players

The footballers enlisted below have had international cap(s) for their respective countries at junior and/or senior level. Players whose name is listed in bold represented their countries at junior and/or senior level on through the time's passing. Additionally, these players have also had a significant number of caps and goals accumulated throughout a certain number of seasons for the club itself as well.

## Former managers

* Vasile Copil (1970–1974)
* Ion Moldovan (1986–1987)
* Constantin Gache (2005–2007)
* Ioan Tătăran (2007–2008)
* Cristea Rusu (2008)
* Constantin Gache (2008–2010)
* Cristian Dulca (2010–2012)
* Gheorghe Mulțescu (2012)
* Erik Lincar (2013)
* Gheorghe Iamandi (2011–2013)
* Cosmin Mărginean (2013–2014)
* Tibor Selymes (2015–2016)
# Daniela Biamonte

Daniela Biamonte (born (1973-12-03)3 December 1973) is a retired Italian volleyball player. She was part of the Italy women's national volleyball team.
She participated in the 1994 FIVB Volleyball Women's World Championship. On club level she played with Brummel Ancona.

## Clubs

* Brummel Ancona (1994)
# Journal of Specialised Translation

The Journal of Specialised Translation, also known as JoSTrans, is a biannual peer-reviewed open-access academic journal covering research in specialised, non-literary translation. In addition to articles and reviews, the journal contains video material of interviews with translation scholars and professionals from the translation industry. It was established in 2004 with two issues per year. Since 2007, guest-edited thematic issues alternate with non-thematic issues. The founding editor-in-chief was Lucile Desblache (University of Roehampton), who served from 2003 to 2018. She was succeeded in December 2018 by Łucja Biel [pl].

## Abstracting and indexing

The journal is abstracted and indexed in:
* Arts & Humanities Citation Index
* Current Contents/Arts & Humanities
* Current Contents/Social and Behavioral Sciences
* Directory of Open Access Journals
* ERIH PLUS
* International Bibliography of Periodical Literature
* MLA International Bibliography
* Scopus
* Social Sciences Citation Index
According to the Journal Citation Reports, the journal has a 2023 impact factor of 1.2.
# Craig Leon (runner)

Craig Leon (born November 8, 1984) is an American distance runner who represented the United States in the men's marathon at the 2015 Pan American Games.

## Running career
### High school

Leon first participated in competitive running at Van Wert High School. At the 2002 OHSAA Boys' Division II state cross country championships, Leon placed 11th overall in the 5K in 16:31. In his senior year cross country season, his best result in the 5K was 16:03. He graduated from Van Wert in 2003.

### Collegiate

Leon attended Ohio University, where he became a walk-on for Ohio's cross country and track teams. Ohio coach Mitch Bentley had told Leon, "You want to walk on? Sure, go ahead". At the 2007 Hillsdale Relays, Leon ran the men's 10,000 meters in 30:06.54.

### Post-collegiate

After college, Leon took a brief hiatus from high-volume training for a period of two years until he began training for the marathon in 2009. He made his marathon debut at the 2010 Eugene Marathon, where he won in 2:23:15. He then qualified for the 2012 US Olympic Trials after running the marathon at the 2010 USA Marathon Championships in 2:18:29. The following year, he moved to Eugene, Oregon, where he joined Team Run Eugene and signed a professional contract with Mizuno. During the summer of 2015, he earned his first call-up to the United States' distance roster for the 2015 Pan American Games, where he finished in 5th place overall in the men's marathon.
# Bohemia Cycling Track Team

Bohemia Cycling Track Team is a Czech UCI Continental cycling team established in 2015.
# Sébastien Grignard

Sébastien Grignard (born 12 March 1999) is a Belgian professional racing cyclist, who currently rides for UCI ProTeam Lotto. He was promoted from the team's under-23 development squad in 2021.

## Major results
### 2016

    2nd Chrono des Nations
    5th Time trial, National Junior Road Championships

### 2017

    National Junior Road Championships
       1st Road race
       1st Time trial
    1st Chrono des Nations Juniors
    2nd La Philippe Gilbert Juniors [fr]
    3rd Time trial, UEC European Junior Road Championships
    4th Paris–Roubaix Juniors
    4th Nokere Koerse voor Juniores
    5th La Bernaudeau Junior [fr]

### 2019

    3rd Road race, National Under-23 Road Championships

### Grand Tour general classification results timeline

| Grand Tour | 2023 |
| Giro d'Italia | — |
| Tour de France | — |
| Vuelta a España | 118 |
Legend :
| — | Did not compete |
| DNF | Did not finish |
# Roman Catholic Diocese of Auki

The Roman Catholic Diocese of Auki is a suffragan diocese of the Roman Catholic Archdiocese of Honiara in Solomon Islands. It was erected in 1982 from part of the archdiocese.

## Bishops

* Gerard Francis Loft, S. M. (1983–2004)
* Christopher Michael Cardone, O.P. (2004–2016), appointed Archbishop of Honiara
* Peter Houhou (2018-)

## External links and references

* "Diocese of Auki". Catholic-Hierarchy. Retrieved 2007-01-10.
8°45′57″S 160°41′49″E﻿ / ﻿8.7659°S 160.6970°E﻿ / -8.7659; 160.6970
* This article on a Roman Catholic diocese in Oceania is a stub. You can help Wikipedia by expanding it.
* v
* t
* e
# Northcote Burke

Northcote Richard Burke (fl. 1927–1968) was Dean of New Westminster from 1953 to 1968.
Burke was educated at the Queen's University, Kingston and ordained in 1927. After curacies at Pittsburgh, Ontario, then Kingston, Ontario he was the Rector of St John, Ottawa from 1937 to 1948; and then of Christ Church, Deer Park until his appointment as Dean.
# Paradise Murdered

Paradise Murdered (Korean: 극락도 살인사건; RR: Geukrakdo Sarinsageon; lit. Homicide Case on Paradise) is a 2007 South Korean film starring Park Hae-il and Park Sol-mi, and is the directorial debut of filmmaker Kim Han-min.

## Plot

Off the southern coast of the Korean Peninsula, an island of 17 inhabitants exists. The so-called Paradise Island holds up to its name with its breath-taking mountains and sea coupled with good-natured people. No worries or stress holds for anyone who comes to visit this beautiful oasis. But this peace doesn't last long as every single one of the inhabitants disappear one day without a single trace. Chaos initially breaks out when a blood-drenched corpse is found and everyone becomes a suspect. The furious sea allows them no boat ride to the mainland and their only existing radio communication device has been smashed. Trapped together on the island, everyone is suspicious of each other and even the unseen could be a possible suspect. As hideous secrets get revealed day by day, an island of paradise slowly turns into an island of death.
# Sealion 2000

Sealion 2000 is a vehicular ferry operated by Kangaroo Island SeaLink on the 18 kilometre Cape Jervis to Penneshaw route across Backstairs Passage along with the Spirit of Kangaroo Island. These two ferries provide the main form of transport to Kangaroo Island operating up to 10 trips daily. This vessel is specifically made for passengers and cars and is a larger boat. Unlike the Spirit of Kangaroo Island which is a freight boat, used for transporting trucks as well as passengers.
It was built in 1998 by Tenix, Fremantle. In 2013 it returned to Fremantle for an overhaul that included its engines being replaced.
# Antonella Bragaglia

Antonella Bragaglia (born 4 February 1973) was an Italian female volleyball player. She was part of the Italy women's national volleyball team.
She competed with the national team at the 2000 Summer Olympics in Sydney, Australia, finishing 9th.
# Phony Express

Phony Express is a 1943 short subject directed by Del Lord starring American slapstick comedy team The Three Stooges (Moe Howard, Larry Fine and Curly Howard). It is the 75th entry in the series released by Columbia Pictures starring the comedians, who released 190 shorts for the studio between 1934 and 1959.

## Plot

In the besieged environs of Peaceful Gulch, threatened by a marauding contingent of bandits and brigands, the town's mayor, formulates a stratagem to deter the encroaching menace. This plan entails the dissemination of a fabricated report heralding the imminent arrival of three resolute marshals (the Stooges), their identities appropriated from a wanted poster portraying vagrants, valued at a nominal price. Despite this intricate scheme, the Stooges nearly face expulsion from the township subsequent to a misguided endeavor to administer a purported panacea to the ailing sheriff, afflicted with lumbago, which imperils his well-being.
The Stooges find themselves ensconced within the precincts of a local saloon. Here, they confront the leader of the marauders, Red, who endeavors to assuage them through conviviality and libations, only to have their deception unravelled. In a display of ingenuity, the trio prevails over their adversaries, effectuating their escape from imminent peril.
Subsequently entrusted with the solemn responsibility of safeguarding the town's financial bastion, the Stooges are confronted with a brazen act of bank robbery in their charge's absence. To avert dire consequences, they embark on a quest to apprehend the culprits. Amidst their pursuit, Curly, assuming the guise of a bloodhound, momentarily diverts his attention to a whimsical pursuit of a skunk. Despite this diversion, their tenacity leads them to the discovery of the stolen plunder, just as the malefactors return to their hideaway.
A series of misfortunes culminates in Curly's inadvertent confinement within a stove, unwittingly becoming a receptacle for the ill-gotten gains. However, a fortuitous mishap ensues as a conflagration, ignited accidentally, propels a cascade of bullets, dispersing the outlaws in disarray.

## Production notes

Phony Express was filmed on March 27–31, 1943. The film title is a parody of the "Pony Express," a fast mail service that crossed the North American continent from Saint Joseph, Missouri to Sacramento, California from April 1860 to October 1861. Some of the plot and minimal stock footage would be recycled in Merry Mavericks.
This was the last Three Stooges short co-written by Monte Collins, who died on June 1, 1951.

## Cast

* Moe Howard as Moe
* Larry Fine as Larry
* Curly Howard as Curly
* Shirley Patterson as Lola
* Bud Jamison as Red Morgan
* Ernie Adams as the Banker
* Sally Cleaves as Dancing Partner
* Chester Conklin as Mr. Higgins
* Thomas Judge "Tex" Cooper as Barfly
* Joel Friedkin as Dr. Abdul
* Joe Garcio as a Henchman
* George Gray as a Messenger
* Herman Hack as a Dancer
* Ray Jones as Red's Henchman
* John Merton as Red's Henchman
* George Morrell as a Townsman
* Snub Pollard as Sheriff Hogwaller
# United States v. Freed

United States v. Freed, 401 U.S. 601 (1971), was a United States Supreme Court case in which the Court held the National Firearms Act's registration requirements do not violate the Fifth Amendment to the United States Constitution. Additionally, the Court held that the Act's restrictions against a person's "receiv[ing] or possess[ing] a firearm which is not registered to him," did not require the recipient to have the specific intent to possess an unregistered firearm. Consequently, the Court ruled that the buyer of unregistered hand grenades was subject to criminal liability, despite a lack of a requirement that the defendant have had a "specific intent or knowledge that the hand grenades were unregistered."

## Decision of the Court

The Court concluded, "This is a regulatory measure in the interest of the public safety, which may well be premised on the theory that one would hardly be surprised to learn that possession of hand grenades is not an innocent act."
# United States v. Reidel

United States v. Reidel, 402 U.S. 351 (1971), was a United States Supreme Court case in which the Court held that a postal regulation that banned the sale of adult materials was constitutionally permissible.

## Background

At the time of this case, § 1461 of Title 18 prohibited the mailing of any "obscene, lewd, lascivious, indecent, filthy or vile article, matter, thing, device, or substance..." § 1461 provided for fines and/or up to five years imprisonment for first offenders, and up to ten years for later offenses.
Two years earlier, in Stanley v. Georgia (1969), the Court had found a constitutional right to possess pornographic materials.
In 1970, Norman Reidel advertised, sold, and mailed copies of his $1 booklet, The True Facts about Imported Pornography, to adult-identified customers. Reidel was prosecuted under three counts of violating § 1461. The United States District Court for the Central District of California dismissed the case, whereupon the U.S. appealed directly to the Supreme Court.
The Court heard and decided this case along with United States v. Thirty-seven Photographs.

## Opinion of the Court

Associate Justice Byron White penned the Court's opinion reversing the district court and finding the postal regulation Constitutional. While individuals still retain a right to possess pornography, as the Court had found in Stanley v. Georgia, the government still had the power to regulate the distribution and sale of obscene materials, as it had found in Roth v. United States (1957).
Justice Hugo Black, joined by Justice William O. Douglas, dissented in both this case and in Thirty-seven Photographs case, arguing that § 1461 was unconstitutional, that the First Amendment to the United States Constitution "denies Congress the power to act as censor".