OpenLLM-France/wikimedia huggingface dataset:
# EuFOD

EuFOD is the chemical compound with the formula Eu(OCC(CH$_3$)$_3$CHCOC$_3$F$_7$)$_3$, also called Eu(fod)$_3$. This coordination compound is used primarily as a shift reagent in NMR spectroscopy. It is the premier member of the lanthanide shift reagents and was popular in the 1970s and 1980s.

## Structure and reactivity

Eu(fod)$_3$ consists of three bidentate ligands bound to a Eu(III) center. The metal atom has an electron configuration of f$^6$. The six electrons are unpaired—each in a different singly-occupied f-orbital—which makes the molecule highly paramagnetic. In contrast, Gd(fod)$_3$ with a symmetrical f$^7$ configuration, does not give rise to pseudocontact shifts. The complex is a Lewis acid, being capable of expanding its coordination number of six to eight. The complex displays a particular affinity for "hard" Lewis bases, such as the oxygen atom in ethers and the nitrogen of amines. It is soluble in nonpolar solvents, even more so than related complexes of acetylacetone and hexafluoroacetylacetone.
The fod ligand is the anion of the commercially available 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione. It is a bidentate acetylacetonate ligand prepared from heptafluorobutyric acid (PFBA). It chelates with lanthanides to form Ln(fod)$_3$ for La = Nd, Sm, Eu, Tb, and Lu.

## Uses
### NMR shift reagent

In its original application, Eu(fod)$_3$ was used in NMR spectroscopy to gain additional chemical shift dispersion. As is typical in paramagnetic NMR spectroscopy, the paramagnetic compound induces an additional chemical shift in the protons near those Lewis basic sites that bind to Eu(fod)$_3$. Only small amounts of shift reagents are used, because otherwise the paramagnetism of the reagent shortens the spin-lattice relaxation times of the nuclei, which causes uncertainty broadening and loss of resolution. The availability of higher magnetic field spectrometers has lowered the demand for NMR shift reagents.
The original shift reagent was Eu(DPM)$_3$, also called Eu(thd)$_3$. Its structure is similar to EuFOD, but with tert-butyl groups in place of heptafluoropropyl substituents. That is, DPM$^−$ is the conjugate base derived from dipivaloylmethane, also known as 2,2,6,6-tetramethylheptane-3,5-dione. The ligand fod$^−$ is more lipophilic and by virtue of the perfluoralkyl substituent, its complexes are more Lewis acidic than those derived from DPM$^−$.

### Lewis acid

Eu(fod)$_3$ serves as a Lewis acid catalyst in organic synthesis including stereoselective Diels–Alder and aldol addition reactions. For example, Eu(fod)$_3$ catalyzes the cyclocondensations of substituted dienes with aromatic and aliphatic aldehydes to yield dihydropyrans, with high selectivity for the endo product.
# Suffolk Committees for Scandalous Ministers

The Suffolk Committees for Scandalous Ministers were two committees commissioned by the Earl of Manchester between 24 February and 15 March 1644 in accordance with an ordinance published on 22 January 1644. Manchester had been pressing for authorisation to remove 'scandalous ministers' for some time. This term referred to "any minister who was non-resident, incompetent or idle, scandalous either in life or in doctrine, or in any way ill-affected to Parliament".

## Committeemen
### First Commission

Transcribed by Francis Hill.$^{:25}$
| Name | Location | High Sherriff of Suffolk | Other positions | |
| Sir Edmund Bacon | Redgrave | 1634 | | |
| Sir William Spring | Pakenham | 1641 | Deputy Lieutenant from 1642 | |
| William Soame | Little Thurlow | 1633 | | |
| Maurice Barrow | Barningham | 1643 | | |
| Brampton Gurdon (senior) | Assington | 1629 | | MP for Sudbury 1621–1622 |
| Henry North (senior) | Laxfield | 1620 | | |
| Thomas Tirrell | Gipping | | | |
| Edmund Harvey | Wickham Skeith | | | |
| Brampton Gurdon (junior) | Assington | | | |
| Samuel Moody | Bury St Edmunds | | | |

### Second Commission

Transcribed by Francis Hill.$^{:25}$
| Name | Location | High Sherriff of Suffolk | Notes |
| Sir John Wentworth | Somerleyton | 1619 | |
| Francis Bacon | Ipswich | | |
| Nathaniel Bacon | Ipswich | | |
| Nathaniel Bacon | Friston | | |
| Francis Brewster | Wrentham | | |
| William Blois | Grundisburgh | 1620 | |
| Robert Brewster | Wrentham | | |
| Robert Duncon | Ipswich | | Brother of Samuel Duncon |
| Peter Fisher | Ipswich | | |
| John Base | Saxmundham | | |
# Buchanan County Courthouse (Virginia)

The Buchanan County Courthouse is a historic courthouse building located at Grundy, Buchanan County, Virginia. It was built in 1905–06. The Renaissance Revival style building is the only building in the downtown with pretensions to architectural sophistication. Designed by architect Frank Pierce Milburn, the design employs local stone, emphasized with a corner clock tower topped with a belvedere. A 1915 fire gutted most of the downtown, including the courthouse, which was rebuilt and expanded by 1917.
It was listed on the National Register of Historic Places in 1982.
# Rash Behari Ghosh

Sir Rash Behari Ghosh CSI CIE (23 December 1845 – 28 February 1921) was an Indian politician, lawyer, social worker and philanthropist.

## Early life

Rashbehari Ghosh was born on 23 December 1845 in Torkona village in Khandaghosh area. His family belonged to the Sadgope caste and resided in Purba Bardhaman district, Bengal Presidency. He attended Burdwan Raj Collegiate School and Presidency College, Kolkata. He obtained a first class in the MA examination in English. In 1871, he passed the Law examination with honours and was awarded the Doctor of Laws degree in 1884.

## Political career

Ghosh became a member of the Indian National Congress and leaned towards the moderate wing. He had deep faith in progress, but was opposed to radicalism in any form. He served as the President of the Congress for two terms. First in the historic 1907 Surat Session, succeeding Dadabhai Naoroji, after which the Congress split into Moderates and Extremists, and then the year after in Madras, 1908.
Ghosh was a member of the Bengal Legislative Council (1891–94, 1906–09) and the Council of India. He was appointed a Companion of the Order of the Indian Empire (CIE) in the 1896 New Year Honours and appointed a Companion of the Order of the Star of India (CSI) in the 1909 Birthday Honours. He was knighted in the 1915 New Year Honours and conferred with his knighthood on 14 July of that year.

## Contributions

Ghosh's contributions earned him a series of honours, such as the Tagore Law Professorship (1875–76) at Calcutta University and an honorary DL degree from Calcutta University (1884).
He made a fortune through his legal practice, but donated much of it by way of charity and endowments. He established Torkona Jagabandhu School (1894). In 1913, he established an endowment for scientific studies at Calcutta University with an initial capital of ten lakh rupees. He also donated 13 lakh rupees to establish a National Council of Education (NCE) at Jadavpur. It later became Jadavpur University. Ghosh was the first president of NCE.
Keeping in line with his ideals, Sir Rashbehari Ghosh Mahavidyalaya was established at Ukhrid in Khandaghosh CD Block in 2010. He also established schools and hospital in his village.
He donated a princely sum (almost 33% of financial expenditure) to Acharya Praffulla Roy for establishing Bengal Chemical and Pharmaceutical Works.

## Street named after Ghosh in Kolkata

Considering the contributions made by Ghosh for the people of India, a street was named after him in Kolkata. Rashbehari Avenue, named after him, starts from Chetla-Sahanagar Bridge (Shaheed Jatin Das Setu) and runs eastwards to Ballygunge and Gariahat.

## Legacy

His house in Burdwan District has been kept intact. His family members still reside there. Few of his descendants have joined the legal profession.
# 1996 PBA All-Filipino Cup

The 1996 Philippine Basketball Association (PBA) All-Filipino Cup was the first conference of the 1996 PBA season. It started on February 18 and ended on May 26, 1996. The tournament is an All-Filipino format, which doesn't require an import or a pure-foreign player for each team.

## Format

The following format will be observed for the duration of the conference:
* Double-round robin eliminations; 14 games per team; Teams are then seeded by basis on win–loss records.
* The top five teams after the eliminations will advance to the semifinals.
* Semifinals will be two round robin affairs with the remaining five teams. Results from the eliminations will be carried over. A playoff incentive for a finals berth will be given to the team that will win at least five of their eight semifinal games.
* The top two teams (or the top team and the winner of the playoff incentive) will face each other in a best-of-seven championship series. The next two teams (or the loser of the playoff incentive and the fourth seeded team) dispute the third-place trophy in a one-game playoff.

## Elimination round
### Team standings

| Pos | Team | W | L | PCT | GB | Qualification |
| 1 | Alaska Milkmen | 10 | 4 | .714 | — | Semifinal round |
| 2 | Formula Shell Zoom Masters | 9 | 5 | .643 | 1 | Semifinal round |
| 3 | Purefoods Tender Juicy Hotdogs | 8 | 6 | .571 | 2 | Semifinal round |
| 4 | San Miguel Beermen | 8 | 6 | .571 | 2 | Semifinal round |
| 5 | Ginebra San Miguel | 7 | 7 | .500 | 3 | Semifinal round |
| 6 | Sta. Lucia Realtors | 6 | 8 | .429 | 4 | |
| 7 | Sunkist Orange Juicers | 4 | 10 | .286 | 6 | |
| 8 | Pepsi Mega Bottlers | 4 | 10 | .286 | 6 | |

## Semifinal round
### Team standings

| Pos | Team | W | L | PCT | GB | Qualification |
| 1 | Purefoods Tender Juicy Hotdogs | 14 | 8 | .636 | — | Advance to the finals |
| 2 | Alaska Milkmen | 13 | 9 | .591 | 1 | Guaranteed finals berth playoff |
| 3 | Ginebra San Miguel | 12 | 10 | .545 | 2 | Qualify to finals berth playoff |
| 4 | San Miguel Beermen | 12 | 10 | .545 | 2 | Proceed to third-place playoff |
| 5 | Formula Shell Zoom Masters | 11 | 11 | .500 | 3 | |
| Pos | Team | W | L | Qualification |
| 1 | Purefoods Tender Juicy Hotdogs | 6 | 2 | |
| 2 | Ginebra San Miguel | 5 | 3 | Qualify to finals berth playoff |
| 3 | San Miguel Beermen | 4 | 4 | |
| 4 | Alaska Milkmen | 3 | 5 | |
| 5 | Formula Shell Zoom Masters | 2 | 6 | |

## Finals berth playoff

* Vintage
* May 14
* recap
* Cuneta Astrodome, Pasay

## Third place playoff

* Vintage
* May 17
* Cuneta Astrodome, Pasay

## Finals

* Vintage
* May 17
* Cuneta Astrodome, Pasay
* Vintage
* May 19
* Cuneta Astrodome, Pasay
* Vintage
* May 21
* Araneta Coliseum, Quezon City
* Vintage
* May 24
* Cuneta Astrodome, Pasay
* Vintage
* May 26
Purefoods TJ Hotdogs 92, Alaska Milkmen 93 (OT) :
* Alaska wins series, 4–1 ||
* Araneta Coliseum, Quezon City
# United Congregational Church of Southern Africa

The United Congregational Church of Southern Africa (UCCSA) is a prominent Christian denomination established in 1967, following the unification of various congregational movements within Southern Africa. Its origins can be traced back to the missionary work of the London Missionary Society in the Cape Colony in 1799. The UCCSA plays a significant role in the religious landscape of Southern Africa, with a membership of approximately 1 000 000. It maintains a notable presence in countries such as South Africa, Mozambique, Botswana, Zimbabwe, and Namibia. The UCCSA is recognized for its contributions to education and social justice in the region.

## History

The UCCSA has its roots in the early missionary efforts of the London Missionary Society (LMS). The LMS initiated its work in the Cape Colony in 1799, led by missionaries like Dr. Theodorus van der Kemp. The first Congregational church in Cape Town was established by them in 1801. Notable LMS missionaries, including David Livingstone, extended their evangelical efforts among the Tswana and Amandbele peoples.
Post-1820, English and Welsh settlers formed their own congregational congregations. Further expansion occurred with the arrival of missionaries from the American Board of Commissioners for Foreign Missions in 1830 in KwaZulu-Natal. The congregations formed by white settlers eventually led to the creation of the Congregational Union of South Africa. These various missionary and congregational movements culminated in the unification of the three bodies to form the United Congregational Church of Southern Africa in 1967.

## Membership and influence

The UCCSA boasts a significant membership, with over 1 000 000 members across 400 local congregations as of 2024. This denomination is also a member of the World Communion of Reformed Churches.

## Regional influence
### Mozambique

In Mozambique, the UCCSA operates under the Portuguese name Igreja Congregacional Unida do Africa do Sul, with the central office located in Maputo. The Mozambique Synod traces its origins back to the first evangelist, Rev. Edwin Richards, sent in 1880 by the American Board of Commissioners for Foreign Missions. Despite a period of transition where Richards and many members joined the Methodist church, a portion retained their congregational heritage. Currently, the church in Mozambique has 13,400 members in 27 congregations, primarily located in Inhambane, Gaza Province, and Maputo. The official languages used are Portuguese, Xitxe, Tsonga, and Tyopi.

### Botswana

In Botswana, the UCCSA has 51 congregations and over 20,300 members. The denomination is a member of the Botswana Council of Churches.

### Zimbabwe

The UCCSA in Zimbabwe operates several schools and, as of 1995, had 160 congregations..

### Namibia

The Namibia Regional Council of the UCCSA, formed in 1982, consists of 3,000 members across 7 congregations located in Duineveld, Rehoboth, Karlfeld, Windhoek, Luderitz, Walvis Bay, Swakopmund, Grootfrontein. The establishment of these congregations dates back to 1933 when congregational people began moving to Namibia.
# Semifreddi's Bakery

Semifreddi's Bakery is an Alameda-based artisan bakery that serves the entire San Francisco Bay Area. The name Semifreddi means "half-frozen" in Italian.

## Beginnings and early history

In 1984, Eric and Carole Sartenaer, ex-Cheese Board Collective members, opened shop in a 450-square-foot "hole in the wall" bakery in Kensington, California. In January 1987, Barbara Frainier (one of their first employees) took over the business with her husband Michael Rose. In 1988, Tom Frainier (Barbara’s brother) joined the Semifreddi's team. In order to save money, Tom, Barbara, and Michael, lived together in a small flat in Berkeley, California. Tom, who holds an MBA from Berkeley’s Haas School of Business, left an upper management position at Clorox to join his sister and brother in law, both UC Berkeley alumni, in the bread and pastry-making business. When asked about his exit strategy, Frainier replies, "death". After Frainier took the helm as President, CEO, and self-proclaimed, "Chief Boot Licker", Semifreddi's rapidly expanded throughout the San Francisco Bay, while maintaining its emphasis on baking high-quality, European-style artisan bread and pastries.

## Present day

Sold in 2024 Semifreddi's has become one of the largest artisan wholesale bread and pastry bakeries in the Bay Area. It is located in Alameda, California. Semifreddi’s and Acme are the two major players in the San Francisco Bay bread industry. In 2009, Semifreddi’s moved into a 33,000 square foot facility, where the bakery recycles 95 percent of its waste. It operates 24 hours a day, 7 days a week, for all 52 weeks of the year. The bakery utilizes over 25 different recipes and bakes more than 50 different artisan breads and pastries. In a typical week, Semifreddi's bakes and delivers over 200,000 baguettes, rolls, and loaves and 40,000 pastries and cookies a week. Semifreddi's sells to grocery stores, restaurants, and cafés throughout the bay area.

## Baked goods

Semifreddi's bakes French and Italian style bread and pastries, which includes baguettes, loaves, batards, and French style pastries. They also bake croutons, cookies, and various seasonal sweets.
# Spellcasting 301: Spring Break

The text adventure game Spellcasting 301: Spring Break is the third and last installment of the Spellcasting series created by Steve Meretzky during his time at Legend Entertainment. All three games in the series tell the story of young Ernie Eaglebeak, a student at the prestigious Sorcerer University, progressing through his studies, learning the arcanes of magic, taking part in student life, occasionally saving the world as he knows it, and having his way with any beautiful women he can get his hands on.

## Technical notes

This is the first, and as it has turned out the only, Spellcasting game to use the 256-colour VGA version of the Legend interactive fiction interface, as well as capable of utilizing the sound card to play both sound effects and music.
Unlike the previous two parts, whose title pages resembled their box covers, the title page of Spellcasting 301 shows only the game's title on plain-blue background, whereas the box cover showed a girl in a bikini reclining on a floating tiger-striped air mattress.

## Reception

Review score :
| Publication | Score |
| Electronic Games | 92% |
Computer Gaming World's Charles Ardai stated that "Spellcasting 301 is vintage Meretzky, up there with his earlier classics ... Everyone else who writes interactive fiction should take a good, hard look at what Meretzky is doing, because he is doing it right". In addition to praising the game's "devious and inimitable wordplay", Ardai approved of the graphics depicting "specimens of female pulchritude ... [some] would do credit to any edition of the Sports Illustrated swimsuit issue". He concluded that "when you are playing this game, you are constantly aware that you are in the hands of a master". In Computer Games Strategy Plus, Gregg Ellsworth highlighted the game's "ingenious puzzles" and "humorous writing", noting that Meretzky "shows the player no mercy in the humor department." He believed that it was a major advancement from Legend's earlier games and praised its audiovisual presentation and interface, ultimately summarizing Spellcasting 301 as "a winner."
In the Chicago Tribune, Dennis Lynch wrote that Spellcasting 301 "is at times sexist and sophomoric, but it's also a clever challenge" Gary Meredith called the game "eminently enjoyable" despite its issues.
# Julia Valadez

Julia Yareli Valadez Alvidrez (born 6 April 2006) is a Mexican professional footballer who plays as a Defensive midfielder for Liga MX Femenil side Pachuca.

## Career

In 2023, she started her career in Pachuca.

## International career

Since 2023, Valadez has been part of the Mexico U-20 team.
# Poitiers (disambiguation)

Poitiers is a city in France.
Poitiers may also refer to:

## Places

* Roman Catholic Archdiocese of Poitiers, France
* Arrondissement of Poitiers, Vienne, Nouvelle-Aquitaine, France
* Canton of Poitiers (disambiguation)
* Grand Poitiers (English: Greater Poitiers), administrative unit in Vienne, Nouvelle-Aquitaine, France
* County of Poitiers, Aquitaine; a county that became the province of Poitou, France

### Facilities and structures

* University of Poitiers, Poitiers, Poitou, France
* Poitiers Campus, Sciences Po
* Poitiers–Biard Airport, Poitou, France
* Poitiers Cathedral, Poitiers, Poitou, France
* Poitiers station, Poitiers, Poitou, France; a train station
* Palace of Poitiers, Poitiers, Poitou, France

## People

* Bishop of Poitiers, a position in the Roman Catholic Church
* Count of Poitiers, a noble title of Aquitaine, France
* House of Poitiers, a noble house of Gaul, Aquitaine, France
* House of Poitiers-Lusignan, a noble house of Aquitaine with kingships in several Crusader kingdoms

### Persons

* Abra of Poitiers (343–360), Saint Abra
* Saint Agnes of Poitiers (died 586)
* Agnes of Poitou of House Poitiers (1025–1077, also Agnes of Poitiers), Holy Roman Empress
* Aliénor de Poitiers (1444–1509), Burgundian courtier
* Aymar VI de Poitiers (14th century), Count of Valentinois
* Diane de Poitiers (1500–1566), French noblewoman and courtier
* Ebroin of Poitiers (died 850), bishop and administrator of Poitiers
* Gilbert of Poitiers (1085–1154), theologian and logician
* Henry of Poitiers (1217–1217), Bailiff of the Kingdom of Jerusalem
* Hildegar of Poitiers (12th century), physician and mathematician
* Hilary of Poitiers (310–367), Bishop of Poitiers
* Hugh of Poitiers (died 1167), Benedictine monk and chronicler
* Jean de Poitiers (1475–1539), French nobleman
* John of Poitiers (died 1204), Roman Catholic prelate
* John of Poitiers-Lusignan (died 1343), Regent of the Kingdom of Cillicia
* Louis of Poitiers (disambiguation)
* Peter of Poitiers (1130–1215), theologian
* Peter of Poitiers (secretary) (12th century), monk and translator scribe
* Philip of Poitiers (disambiguation)
* Radegund of Poitiers (520–587), Thuringian princess and Frankish queen
* Raymond of Poitiers (1105–1149), Prince of Antioch
* Richard of Poitiers (died 1174), Benedictine monk and author
* William of Poitiers (disambiguation)

## Military

* Battle of Vouillé (507; also called "Battle of Poitiers"), between the Franks and the Visigoths
* Battle of Tours-Poitiers (732; also called "Battle of Poitiers"), in the Umayyad Invasion of Gaul
* Battle of Poitiers (1356), in the Hundred Years War between England and France
* Siege of Poitiers (1569), French Wars of Religion

## Other uses

* First Edict of Poitiers (1573), a treaty that ended the first of the Wars of Religion in France
* Edict of Poitiers (1577), a treaty between France and Huguenot princes
* The Battle of Poitiers (painting), an 1830 painting by Eugène Delacroix
* FC Poitiers, Poitiers, France; a soccer team
# 1944 Republican Party vice presidential candidate selection

This article lists those who were potential candidates for the Republican nomination for Vice President of the United States in the 1944 election. At the start of the 1944 Republican National Convention, New York Governor Thomas Dewey seemed like the likely presidential nominee, but his nomination was not assured due to strong support for Ohio Governor John W. Bricker and former Minnesota Governor Harold Stassen. Though Dewey wanted California Governor Earl Warren as his running mate, Warren was convinced that Franklin D. Roosevelt would win re-election, and refused to be anyone's running mate. Some Republicans wanted to ask Democratic Senator Harry Byrd of Virginia to be the Republican running mate in order to pursue the Southern vote, but this possibility was not seriously pursued. Dewey and his advisers instead worked out a deal in which Bricker's delegates voted for Dewey in the presidential ballot, and Dewey in return chose Bricker as his running mate. The Dewey–Bricker ticket, which balanced the moderate Northeastern and conservative Midwestern wings of the party, was ratified by the Republican convention. The ticket lost the 1944 presidential election to the Roosevelt–Truman ticket.

## Potential running mates
### Finalists

* Governor John W. Bricker from Ohio (1939-1945)
* Governor Earl Warren from California (1943-1953)

### Others

* Representative Everett Dirksen from Illinois (1933-1949)
* Governor Dwight H. Green from Illinois (1941-1949)
* Governor Dwight Griswold from Nebraska (1941-1947)
* Governor Leverett Saltonstall from Massachusetts (1939-1945)
# Peter Wilson (field hockey)

Peter "PJ" Wilson (9 August 1942 – 22 March 2024) was a British hockey player. He competed in the men's tournament at the 1968 Summer Olympics.
Peter Wilson was born in Weston-super-Mare. While studying at St Edmund Hall at the University of Oxford, Wilson played two first-class cricket matches for Oxford University in 1964, against Hampshire and Derbyshire at Oxford. He scored 56 runs in his two matches, with a high score of 30.
Wilson spent most of his career as a teacher at the Dragon School in Oxford, retiring in 2021. He died in March 2024, and a memorial service in his honour was held at the school on 22 September 2024.
# Kulturhaus Lüdenscheid

Kulturhaus Lüdenscheid is a theatre in Ludenscheid, North Rhine-Westphalia, Germany.