OpenLLM-France/wikimedia huggingface dataset:
# Transition metal acyl complexes

Transition metal acyl complexes describes organometallic complexes containing one or more acyl (RCO) ligands. Such compounds occur as transient intermediates in many industrially useful reactions, especially carbonylations. A special case are the transition metal formyl complexes.

## Structure and bonding

Acyl complexes are usually low-spin and spin-paired.
Monometallic acyl complexes adopt one of two related structures, C-bonded and η$^2$-C-O-bonded. These forms sometimes interconvert. For the purpose of electron-counting, C-bonded acyl ligands count as 1-electron ligands, akin to pseudohalides. η$^2$-Acyl ligands count as 3-electron "L-X" ligands.
bridging acyl ligands are also well known, where the carbon bonds to one metal and the oxygen bonds to a second metal. One example is the bis(μ-acetyl) complex [(CO)$_3$Fe(C(O)CH$_3$)$_2$Fe(CO)$_3$]$^{2-}$.

## Synthesis

Metal acyls are often generated by the reaction of low-valent metal centers with acyl chlorides. Illustrative is the oxidative addition of acetyl chloride to Vaska's complex, converting square planar Ir(I) to octahedral Ir(III):
Some acyl complexes can be produced from aldehydes by C-H oxidative addition. This reaction underpins hydroacylation.
In a related reaction, metal carbonyl anions are acylated by acyl chlorides:
    (C$_5$H$_5$)Fe(CO)$_2$Na + CH$_3$C(O)Cl → (C$_5$H$_5$)Fe(CO)$_2$COCH$_3$ + NaCl
Another important route to metal acyls entails insertion of CO into a metal alkyl bond. In this pathway, the alkyl ligand migrates to an adjacent CO ligand. This reaction is a step in the hydroformylation process.
Coordinatively saturated metal carbonyls react with organolithium reagents to give acyls. This reaction proceeds by attack of the alkyl nucleophile on the electrophilic CO ligand.

## Reactions

In practical sense, the most important reaction of metal acyls is their detachment by reductive elimination of aldehydes from acyl metal hydrides:
    L$_n$MC(O)R(H) → L$_n$M + RCHO
This reaction is the final step of hydroformylation.
Another important reaction is decarbonylation. This reaction requires that the acyl complex be coordinatively unsaturated:
    L$_n$MC(O)R → L$_{n-1}$M(CO)R + L
    L$_{n-1}$MC(O)R → L$_{n-1}$M(CO)R
The oxygen center of acyl ligands is basic. This aspect is manifested in O-alkylations, which converts acyl complexes to alkoxycarbene complexes:

## Applications

Metal acyl complexes participate in several commercial processes, including:
* hydroformylation
* acetic acid synthesis
* Eastman acetic anhydride process
* Ethylene-carbon monoxide copolymerization
A reaction involving metal acyl complexes of occasional value in organic synthesis is the Tsuji–Wilkinson decarbonylation reaction of aldehydes.
# Violin Sonatas, KV 26–31 (Mozart)

Wolfgang Amadeus Mozart's set of six sonatas for keyboard and violin, K. 26–31 were composed in early 1766 in The Hague during the Mozart family's grand tour of Europe. They were dedicated to Princess Caroline of Nassau-Weilburg on the occasion of the eighteenth birthday of her brother, William V, Prince of Orange. They were published as Mozart's Opus 4.
These works show an improvement in compositional technique over the sets for Paris (K. 6–9) and London (K. 10–15), although like the previous sets, the keyboard part dominates and the violin may be considered optional.
Mozart composed all three early sets of accompanied sonatas while touring northwest Europe. These types of sonatas were not favored at home in Salzburg. Mozart would not revisit this genre until 1777–78 on a trip to Mannheim and Paris.

## Sonata in E-flat major, K. 26

* Allegro molto
* Adagio poco andante (in C minor)
* Rondeaux (Allegro)

## Sonata in G major, K. 27

* Adagio poco andante
* Allegro

## Sonata in C major, K. 28

* Allegro maestoso
* Allegro grazioso

## Sonata in D major, K. 29

* Allegro molto
* Menuetto and Trio

## Sonata in F major, K. 30

* Adagio
* Rondeaux (Tempo di Menuetto)

## Sonata in B-flat major, K. 31

* Allegro
* Tempo di Menuetto (Moderato) Theme and six variations
# Abdur Rahman Boyati

Abdur Rahman Boyati (1 January 1939 – 19 August 2013) was a Bangladeshi folk singer. He was also a lyricist, music composer, director and poet. He was awarded Ekushey Padak in 2015 by the Government of Bangladesh. He is most notable for the hits "Mon Amar Deho Ghori Sondhan Kori", "Ei Prithibi Jemon Ache, Temni Pore Robe" and "Din Gele Ar Din Pabi Na".

## Career

Boyati started to sing professionally in 1956. In 1982 he formed a group named Abdur Rahman’s Group.
He was also an actor. He acted in Ashati, directed by Hafiz Uddin, in 1989.

## Honors and awards

Boyati was awarded Ekushey Padak in 2015. He was invited to a cultural show at the dinner party of George Bush Sr. held in the White House in 1990. For his contribution to the music of Bangladesh, Boyati won six national awards in total.
# Viggiano

Viggiano is a comune in the province of Potenza, in the Southern Italian region of Basilicata. It is bounded by the comuni of Calvello, Corleto Perticara, Grumento Nova, Laurenzana, Marsicovetere, and Montemurro.
Viggiano is known for migrant street musicians who have brought their music to Italy and worldwide through the centuries, as well as renowned for the construction of harps. Many Viggianesi had the opportunity to play in many symphonic orchestras in Europe, United States and Australia. The street musicians from Viggiano are cited as an influence on Hector Malot's Sans Famille.
Today Viggiano is known to be home to Europe's largest onshore hydrocarbon field that makes Italy the third-largest oil producer of the continent, behind Norway and United Kingdom.
The comune hosted from 1997 to 2013 the International Flute Competition "Leonardo De Lorenzo", some the jury members over the years included Jean-Pierre Rampal, Julius Baker, Jindřich Feld, Susan Milan, Carol Wincenc, and Ransom Wilson.

## People linked to Viggiano

* Leonardo De Lorenzo - flautist and music educator
* Victor Salvi - harp maker
* Mark Bresciano - football player
* Billie Joe Armstrong - musician
* Francesco Ferramosca - violinist
* Giuseppe Truda - violinist, conductor, composer, teacher

## Demographics

Historical population of Viggiano (Source:) :
| Year | 1861 | 1871 | 1881 | 1901 | 1911 | 1921 | 1931 | 1936 | 1951 | 1961 | 1971 | 1981 | 1991 | 2001 | 2011 |
| Population | 5731 | 6188 | 6030 | 4351 | 4030 | 3777 | 3870 | 4046 | 4152 | 4039 | 3179 | 3088 | 3161 | 3208 | 3122 |
# Chorlton New Mills

Chorlton New Mills is a former large cotton spinning complex in Cambridge Street, Chorlton-on-Medlock, Manchester, England, which has since been converted to apartments.
The complex was initially established in 1814 by members of the Birley family. The original block was an 8-storey building, including two storeys below ground level, of 20 bays and is the oldest surviving fireproof mill in Greater Manchester. It was powered by a 100 hp Boulton and Watt beam engine and illuminated by gas produced in the basement, where it was stored in three gasholders. It stands adjacent to Chorlton Old Mill, rebuilt in 1866 on the site of Robert Owen's 1795 Chorlton Twist Mill.
An extra wing was added to the new mill in 1818, originally powered from the main building but later provided with its own external engine house. In 1829 a 600 loom weaving shed was added, which has since been demolished. In 1845 the two existing spinning blocks were connected by the building of a third 6-bay fireproof block with an internal engine house. The basements of the complex were connected to those of nearby mills by a system of tunnels.
In 1860 the site was taken over by Charles Macintosh and used, together with other nearby mills, for the production of rubberised fabric. It has since been converted to living accommodation.
Together with its metal-bound chimney, built in 1853, it is a Grade II listed building.
# Powerback

Powerback is used by aircraft to move backwards on the ground using the power of their engines in reverse thrust operation. Civil and general aviation aircraft equipped with reverse thrust are technically or theoretically able to use powerbacks as a means of "backing up" but such operation is prohibited or strongly discouraged by aircraft manufacturers as well as airport safety regulations in nations with actual aviation safety regulating agencies.

## Background

While many aircraft are physically capable of performing powerbacks, many companies impose restrictions on the practice, mainly due to the risk of FOD (foreign object damage) from debris propelled into the air. This problem is magnified even more with planes having wing-mounted engines, as their proximity to the ground can exacerbate debris ingestion if powerbacks are used. Small metal objects are particularly dangerous as they can be propelled into terminal windows, employees on the ground or even the aircraft itself. Applying the brakes when backing up also has the potential to cause a tailstrike.
During the 1980s, many aircraft with aft-mounted engines, such as DC-9s, Boeing 727s, and MD-80s used powerbacks to reduce the number of ground personnel required. For example, Northwest Airlines' fleet of DC-9 aircraft used powerback operations at certain airports, but discontinued the practice in 2005 citing the need to conserve fuel. KLM also avoids using the procedure for the same reasons, noting that powerbacks cause extra wear on the engines.
In addition, in the United States, restrictions on powerbacks are enforced by the FAA, and the local aviation officials. Only certain gates at certain airports are approved for powerbacks, and are usually placarded as such. Many airlines impose stricter safety procedures for powerbacks, which often include disallowing a powerback under certain environmental conditions, such as rain or snow.

## Military use

In several US military aircraft such as the C-130 Hercules, the C-5 Galaxy and the C-17 Globemaster III, powerback operation is technically possible as demonstrated at civil airshows but there are severe limitations on the ability of all reverse-thrust capable aircraft to perform actual "pushback" on their own in actual service.
# Bulgarian National Radio Symphony Orchestra

The Bulgarian National Radio Symphony Orchestra (Bulgarian: Симфоничен оркестър на Българското национално радио) is a Bulgarian radio orchestra based in Sofia, Bulgaria, affiliated with Bulgarian National Radio. It gives concerts in the Bulgaria Concert Hall.

## History

Founded in 1948, the orchestra's first chief conductor was Vassil Stefanov, who remained affiliated with the orchestra from 1948 to 1988. Other conductors affiliated with the orchestra have included Vladimir Simeonov, Alexander Vladigerov, Vassil Kazandjiev, and Milen Nachev. The orchestra's current chief conductor is Emil Tabakov, since 2008. He is scheduled to conclude his chief conductorship of the orchestra in December 2015. In December 2015, the orchestra announced the appointment of Rossen Gergov as its next chief conductor, effective in January 2016.
The orchestra offers a full annual schedule of events, tours internationally and maintains a large discography of recordings. Notable people in building the orchestra over the years include Vassil Stefanov, Vladimir Simeonov, Michail Angelov, Vassil Kazandjiev, Alexander Vladigerov, Milen Nachev and Rossen Milanov.

## Chief conductors

* Vassil Stefanov (1948–1988)
* Alexander Vladigerov (1969–1991)
* Vassil Kazandjiev (1979–1993)
* Milen Nachev (1994–2003)
* Rossen Milanov (2003–2008)
* Emil Tabakov (2008–2015)
* Rossen Gergov (2015–2016)
* Mark Kadin (2016-present)
# Communist Renewal

Communist Renewal (Greek: Κομμουνιστική Ανανέωση, ΚΟΜ.ΑΝ., Kommounistiki Ananeosi, KOMAN) is a communist organization in Greece. The group was formed in February 2000 following a split in late 1999 from the Renewing Communist Ecological Left (AKOA). The founders of Communist Renewal were dissatisfied with the upcoming cooperation between AKOA and Synaspismos. Communist Renewal then aligned with the Communist Party of Greece (KKE) in the 2000 elections. The alliance with KKE was then discontinued, but rekindled for the 2006 Greek local elections.
The organization publishes the magazine Stigma.
# Alliance station

Alliance station is an Amtrak train station in Alliance, Ohio, United States. It is served by the daily Floridian service. The station has a single side platform serving the south track of the Fort Wayne Line, with a brick shelter building.

## History

The station site in earlier years served Pennsylvania Railroad, then Penn Central passenger trains northwest to Cleveland, west to Detroit, west to Chicago and east to Philadelphia and New York City. Amtrak service began at the station when the Capitol Limited was rerouted north in fall 1990 from Canton station in Canton. The Pennsylvanian served Alliance from 1998 to 2003.
Amtrak spent $1.5 million to improve the station in 2011. It built a new shelter and installed a 550-foot (170 m) long concrete platform, signage and light poles. Developed by d+A Design+Architecture, LLC of Yardley, Pennsylvania, the shelter is composed primarily of rich red brick and has an enclosed, one-story waiting room with large windows. On the facades facing the street and the tracks, the waiting room is marked by stylized projecting bays faced with coursed ashlar stonework that adds texture to the overall elevation. The design is similar to Connellsville station in Pennsylvania. On November 10, 2024, the Capitol Limited was merged with the Silver Star as the Floridian.
# Morris S. Levy

Morris S. Levy is a film, television, and theatrical producer who was born in Brooklyn, NY and raised in Kings Point, New York. He is the founder and President of M.E.G.A. Films (Morsly Entertainment Group and the Arts), a New York-based production company. He often films in Great Neck as well as all over the New York City area. His films have appeared in the Sundance Film Festival (The Ten-starring Paul Rudd, Winona Ryder, Jessica Alba and Liev Schreiber), the Cannes Film Festival (Seduced and Abandoned-starring Alec Baldwin, Ryan Gosling and Jessica Chastain), and the Tribeca Film Festival (Descent-starring Rosario Dawson) amongst other festivals. His film A Novel Romance won the Audience Award and Best Picture Award at the New York International Film Festival. His TV series, Cop Show (starring Colin Quinn, Jerry Seinfeld, Amy Schumer, Chris Rock and Seth Meyers) won best comedy, among other awards at the 2015 New York City Webfest. His 2020 critically acclaimed film ″Angie: Lost Girls″ won Best Picture at the Moving Parts Film Festival and also won an Award of Excellence from the Accolade Global Film Competition. Mr. Levy is a producer of the Off-Broadway show My Life on a Diet starring Renee Taylor (Emmy Winner and Academy Award Nominee), which received rave reviews from the NY Times, NY Post, LA Times, and was nominated for a 2019 Lucille Lortel Award for Outstanding Solo Show. He is also a producer on the Off Broadway show Mornings at Seven (revival of the Tony Award winning play) starring Tony Roberts, Judith Ivey, and Don Lauria. Before entering the entertainment business, he was a principal in a ladies' clothing company and was also prominent in the New York nightlife business as a promoter/owner.

## Partial filmography

* Descent (2007 film)
* The Ten (2007))
* Seduced and Abandoned (2013)
* Affluenza (2014)
* Cop Show (2015-2016)
* Angie: Lost Girls (2020)
# Robinson Ekspeditionen 1999

Robinson Ekspeditionen: 1999, was the second season of the Danish version of the Swedish show Expedition Robinson and it premiered on 11 September 1999 and aired until 3 December 1999. This season was the first to feature added twist to the game. Dan Martstrand went on to win the season with a 7–2 jury vote over Peer Stakroge becoming the first joker ever to win a season of Expedition Robinson in the world.

## Finishing order

| Contestant | Original Tribes | Episode 2 Tribes | Merged Tribe | Finish |
| Bente Knudsen 47, Them | South Team | | | 1st Voted Out Day 3 |
| Katrine Marboe 19, Frederiksberg | North Team | North Team | | 2nd Voted Out Day 6 |
| Tasja Fouchard 26, Kongens Lyngby | South Team | South Team | | 3rd Voted Out Day 9 |
| Erla Mørch 47, Blokhus | North Team | North Team | | 4th Voted Out Day 12 |
| Kenneth Lynge 35, Hvidovre | South Team | South Team | | 5th Voted Out Day 15 |
| Camilla Wisøfeldt 31, Frederiksberg | North Team | North Team | | 6th Voted Out Day 18 |
| Erik Winther 58, Copenhagen | South Team | South Team | | 7th Voted Out Day 21 |
| Jørgen Kløcker 32, Frederiksberg | North Team | North Team | Robinson | 8th Voted Out 1st Jury Member Day 24 |
| Naeem Sundoo 32, Kongens Lyngby | South Team | South Team | Robinson | 9th Voted Out 2nd Jury Member Day 27 |
| Lone Hattesen 22, Haderslev | South Team | South Team | Robinson | 10th Voted Out 3rd Jury Member Day 30 |
| Morten Josefsen 24, Aarhus | North Team | North Team | Robinson | 11th Voted Out 4th Jury Member Day 33 |
| Henrik Andersen 28, Nykøbing Falster | South Team | South Team | Robinson | 12th Voted Out 5th Jury Member Day 36 |
| Janne Arusi 39, Fredericia | North Team | North Team | Robinson | 13th Voted Out 6th Jury Member Day 39 |
| Lissi Andersen 34, Slagelse | South Team | South Team | Robinson | 14th Voted Out 7th Jury Member Day 42 |
| Martin Vendelboe 26, Vejle | North Team | North Team | Robinson | 15th Voted Out 8th Jury Member Day 46 |
| Peer Stakroge 50, Struer | North Team | North Team | Robinson | Runner-Up Day 47 |
| Dan Marstrand 51, Køge | | South Team | Robinson | Sole Survivor Day 47 |
# Kyrgyzstan national football team results

This page shows the Kyrgyzstan national football team's results in International Matches, as recognized by FIFA:

## Overview of results

    As of match played 10 September 2024
| Type | Record | Record | Record | Record | Record | Record | Record |
| Type | G | W | D | L | GF | GA | Win % |
| Friendly Matches | 53 | 7 | 15 | 31 | 34 | 96 | 13.21 |
| AFC Asian Cup qualification | 18 | 8 | 2 | 8 | 27 | 29 | 44.44 |
| AFC Asian Cup | 7 | 1 | 2 | 4 | 7 | 11 | 14.29 |
| AFC Challenge Cup qualification | 10 | 5 | 2 | 3 | 12 | 10 | 50 |
| AFC Challenge Cup | 10 | 4 | 0 | 6 | 5 | 11 | 40 |
| FIFA World Cup qualification | 47 | 18 | 7 | 22 | 72 | 72 | 38.3 |
| Other Tournaments | 19 | 6 | 1 | 12 | 21 | 40 | 31.58 |
| Total | 164 | 49 | 29 | 86 | 178 | 270 | 29.88 |

## International Matches
### 1992–1999

| Type | GP | W | D | L | GF | GA |
| Friendly Matches | 4 | 0 | 1 | 3 | 1 | 9 |
| 1996 AFC ACQ | 4 | 1 | 0 | 3 | 3 | 7 |
| 1998 WCQ | 5 | 3 | 0 | 2 | 12 | 11 |
| 2000 AFC ACQ | 3 | 0 | 0 | 3 | 3 | 11 |
| Total | 16 | 4 | 1 | 11 | 19 | 38 |

#### 1999
### 2000–2009

| Type | GP | W | D | L | GF | GA |
| Friendly Matches | 7 | 0 | 1 | 6 | 1 | 13 |
| 2000 West Asian Football Federation Championship | 3 | 0 | 0 | 3 | 0 | 8 |
| 2002 FIFA World Cup qualification | 6 | 1 | 1 | 4 | 3 | 9 |
| 2004 AFC Asian Cup qualification | 2 | 1 | 0 | 1 | 3 | 2 |
| 2006 FIFA World Cup qualification | 8 | 3 | 1 | 4 | 11 | 12 |
| 2006 AFC Challenge Cup | 5 | 3 | 0 | 2 | 4 | 3 |
| Alma TV Cup | 3 | 0 | 0 | 3 | 0 | 9 |
| 2007 Nehru Cup | 4 | 2 | 0 | 2 | 8 | 10 |
| 2010 FIFA World Cup qualification | 2 | 1 | 0 | 1 | 2 | 2 |
| 2008 AFC Challenge Cup qualification | 2 | 1 | 0 | 1 | 2 | 2 |
| 2010 AFC Challenge Cup qualification | 2 | 0 | 2 | 0 | 2 | 2 |
| 2009 Nehru Cup | 4 | 1 | 1 | 2 | 6 | 6 |
| Total | 48 | 13 | 6 | 29 | 42 | 78 |

#### 2009
### 2010–2019

| Type | GP | W | D | L | GF | GA |
| Friendly Matches | 25 | 4 | 8 | 13 | 18 | 49 |
| 2010 AFC Challenge Cup | 2 | 0 | 0 | 2 | 0 | 5 |
| 2012 AFC Challenge Cup qualification | 3 | 1 | 0 | 2 | 5 | 6 |
| 2014 AFC Challenge Cup qualification | 3 | 3 | 0 | 0 | 3 | 0 |
| 2014 FIFA World Cup qualification | 2 | 0 | 0 | 2 | 0 | 7 |
| 2014 AFC Challenge Cup | 3 | 1 | 0 | 2 | 1 | 3 |
| 2018 FIFA World Cup qualification | 8 | 4 | 2 | 2 | 10 | 8 |
| 2019 AFC Asian Cup qualification | 6 | 4 | 1 | 1 | 14 | 8 |
| 2019 AFC Asian Cup | 4 | 1 | 0 | 3 | 6 | 7 |
| 2022 FIFA World Cup qualification | 5 | 2 | 1 | 2 | 10 | 5 |
| Total | 61 | 20 | 12 | 29 | 67 | 98 |

#### 2019
### 2020–2029

| Type | GP | W | D | L | GF | GA |
| Friendly Matches | 6 | 2 | 0 | 4 | 8 | 11 |
| 2022 FIFA World Cup qualification | 3 | 1 | 0 | 2 | 9 | 7 |
| 2021 Three Nations Cup | 2 | 2 | 0 | 0 | 5 | 1 |
| 2022 Navruz Cup | 2 | 0 | 0 | 2 | 1 | 4 |
| 2023 AFC Asian Cup qualification | 3 | 2 | 1 | 0 | 4 | 1 |
| 2023 Tri-Nation Series | 2 | 0 | 1 | 1 | 1 | 3 |
| 2023 CAFA Nations Cup | 3 | 1 | 0 | 2 | 4 | 6 |
| Total | 21 | 8 | 2 | 11 | 32 | 33 |
# Asi Domb

Assaf "Asi" Domb (Hebrew: אסי דומב; born 27 February 1974) is a retired Israeli footballer. Currently, he is a manager.

## Early and personal life

Assaf Domb was born in Netanya, Israel, to a Jewish family.
His first wife, out of three, was Israeli television host and model Hilla Nachshon. He has one child from his second marriage.

## Honours

* Israeli Premier League (1):
** 1996–97
* Toto Cup (1):
** 2001–02
* Israel State Cup (1):
** 2006
* Liga Leumit (1):
** 2007–08
# Sid Williams Theatre

The Sid Williams Theatre is a performance theatre in the Comox Valley, Canada. It is in downtown Courtenay, British Columbia. The theatre was first called 'The Gaiety Theatre' in the 1920s. It was then called 'The Bickle Theatre' in the 1930s. It was originally opened as a movie theatre. The stage of the Bickle Theatre was used for plays and musical events before it became an auction house. In 1998, the theatre closed for extensive renovations and earthquake upgrading. The current technical director is Patrick Emery; he has won numerous lighting design awards for his work with the Courtenay Little Theatre. The Sid Williams Theatre created The Blue Circle Series in 2019, a series of online and live concerts spanning from September to early June annually, showcasing professional talent from all over Canada. Blue is the colour of inspiration. The circle celebrates inclusion. It represents the infinite nature of energy. It symbolizes the cycles of time, and the movements of seasons. The circle is sacred to many cultures, and beckons the viewer to be drawn in, like a spotlight on stage.
# 1987–88 Japan Ice Hockey League season

The 1987–88 Japan Ice Hockey League season was the 22nd season of the Japan Ice Hockey League. Six teams participated in the league, and the Oji Seishi Hockey won the championship.

## Regular season

| | Team | GP | W | L | T | GF | GA | Pts |
| 1. | Oji Seishi Hockey | 30 | 21 | 6 | 3 | 135 | 83 | 45 |
| 2. | Kokudo Keikaku | 30 | 20 | 6 | 4 | 134 | 79 | 44 |
| 3. | Sapporo Snow Brand | 30 | 16 | 9 | 5 | 108 | 82 | 37 |
| 4. | Seibu Tetsudo | 30 | 12 | 15 | 3 | 92 | 108 | 27 |
| 5. | Jujo Ice Hockey Club | 30 | 6 | 21 | 3 | 77 | 127 | 15 |
| 6. | Furukawa Ice Hockey Club | 30 | 5 | 23 | 2 | 76 | 143 | 12 |
# Clavocerithium taeniatum

Clavocerithium taeniatum is a species of sea snail, a marine gastropod mollusk in the family Cerithiidae.