OpenLLM-France/wikimedia huggingface dataset:
# Asmic

Anisyl sulfanyl methyl isocyanide (Asmic) is an organic compound with the formula CH$_3$OC$_6$H$_4$SCH$_2$NC. The molecule contains an ortho-methoxy-phenyl sulfide group to which is attached the isocyanide. Asmic is used as a reagent for the synthesis of tri-substituted isocyanides. The compound is a colorless although samples can appear off-white.

## Preparation and reactions

Asmic is prepared by dehydration of the corresponding formamide by POCl$_3$.
Asmic can be deprotonated at the methylene adjacent to the isocyanide. The anionic form of Asmic, which is stable at low temperatures, can be alkylated with a variety of electrophiles. Two sequential deprotonation-alkylation reactions and a subsequent sulfur-lithium exchange reaction allow the synthesis of tri-substituted isocyanides.
The ortho-methoxy-phenyl sulfide group is thought to facilitate deprotonation by chelating to metalated bases allowing for the base to achieve optimal trajectory during the deprotonation.
Asmic can be used to prepare oxazoles by condensation reactions with esters. The ortho-methoxy-phenyl sulfide group can also undergo sulfur-lithium exchange, and likely proceeds via a 10-s-3 sulfuranide.

## Related compounds

* TosMIC
# Tioga Independent School District

Tioga Independent School District is a public school district based in Tioga, Texas (USA). It operates two schools: Tioga Elementary/Middle School and Tioga High School.

## History

The district has one school that, from 1961 until the 2012-2013 school year, served students in grades Pre-Kindergarten through 8th grade. Students in grades nine through twelve attended Gunter High School in the Gunter Independent School District. This arrangement occurred since Tioga High School closed in 1961. At one time the district considered consolidating with another school district. Instead it opted to re-establish its high school.
However, beginning with the 2012-2013 school year, the District began its own high school, starting with the 9th grade and adding one grade each year until all 12 grades were served in the 2015-2016 school year.
In 2014 Tioga ISD had 392 students.
In 2009, the school district was rated "recognized" by the Texas Education Agency.
As of 2016 the district has a single building for all grades. It plans to establish a 62,000-square-foot (5,800 m$^2$) high school building and track. VLK Architects, a company in Fort Worth, Texas, is designing the building. In July 2016 the district voters approved a lease-purchase agreement to buy land for the high school. Groundbreaking occurred in December 2016.
The district changed to a four day school week in fall 2022.

## Academics

The Texas Education Agency gave Tioga ISD the "Early College High School" designation, and it is the only school district in Grayson County to have this. The early college program began in 2015.
# Shakushain's revolt

The revolt of Shakushain (シャクシャインの戦い, Shakushain no tatakai) was an Ainu rebellion against Japanese authority on Hokkaidō between 1669 and 1672 in the Edo period. It was led by Ainu chieftain Shakushain against the Matsumae clan, who represented Japanese trading and governmental interests in the area of Hokkaidō, then controlled by the Japanese (Yamato people).
The war began as a fight for resources between Shakushain's people and a rival Ainu clan in the Shibuchari River (Shizunai River) basin of what is now Shinhidaka, Hokkaidō. The war developed into a last try by the Ainu to keep their political independence and regain control over the terms of their trade relations with the Yamato people.
According to scholar Brett Walker:
   The war of Shakushain stands out as a watershed event in the history of the conquest of Ezo. Shakushain exploded onto the scene as a charismatic leader who proved able to bridge regional differences among Ainu communities, threatening to unite them against the Japanese intrusion from the south. The Tokugawa shogunate reacted by solidifying its own united front of military allies in the northeast, replacing local Matsumae generals with men of its own choosing, thus illustrating its self-appointed role as defender of the realm.
At the end of 1669, Shakushain's forces surrendered to the Matsumae. The two sides exchanged gifts and negotiated a peace settlement; however, while Ainu generals celebrated with "liberal helpings of saké", they were assassinated by Matsumae warriors. Shakushain was among those killed that day.
After the revolt was suppressed, Japan consolidated its control of Hakkaidō. The peace treaty bound the Ainu to swear allegiance to Matsumae. The Ainu tribes remained autonomous, but trade relations between the Ainu and Matsumaeto turned into a trade monopoly, which means the Ainu lost their pricing power in goods and labor transactions with the Yamato. Those unable to support themselves had no choice but to work as forced labor in fish factories in Honshu on a salary about a seventh of the rate paid to the Yamato.
The only other comparable large-scale revolt by Ainu against Japanese rule was the Menashi–Kunashir rebellion of 1789. An earlier rebellion along the same lines was Koshamain's Revolt in 1456.
# Barn theatre

A barn theatre is a barn refitted to stage plays. There is a long tradition in Europe dating back to at least the 19th century, and barn theatres are still common in England and the United States. They were common in the United States during the 1930s as summer stock theater.
In June 1947 The Billboard wrote that about 200 barn theatres were recorded in the United States for that summer season.
As of the 21st century two barn theaters in Michigan claim to be two of the oldest in the nation: Red Barn in Saugatuck and The Barn Theatre in Augusta.
While commonly summer barn theatres staged popular plays, some of them presented works of new dramatists and new Broadway try-outs.
William Birk, author of a book about the historical Rabbit Run Theatre in Madison, Ohio, wrote that one of the reasons to move to barn theatres in the summers of the 1940s was the lack of air conditioning in big city theatres, including on Broadway.
# Rzezawa

Rzezawa is a village in Bochnia County, Lesser Poland Voivodeship, in southern Poland. It is the seat of the gmina (administrative district) called Gmina Rzezawa. It lies approximately 6 kilometres (4 mi) east of Bochnia and 43 km (27 mi) east of the regional capital Kraków.
# Lipowe, Limanowa County

Lipowe is a village in the administrative district of Gmina Limanowa, within Limanowa County, Lesser Poland Voivodeship, in southern Poland. It lies approximately 3 kilometres (2 mi) west of Limanowa and 51 km (32 mi) south-east of the regional capital Kraków.
# Picnic basket

A picnic basket or picnic hamper is a basket intended to hold food and tableware for a picnic meal. Picnic baskets are standard equipment at many picnics. A traditional picnic hamper is made of woven wicker.
While the basic concept of a picnic basket is quite simple, some picnic baskets sold by gourmet stores are quite large and elaborate, with insulated compartments to hold hot and cold foods, and dishware including wine glasses and porcelain plates which are secured in pockets along with items of cutlery, condiments, corkscrew etc. Many modern picnic baskets also have a special storage section to hold a bottle of wine, the traditional beverage brought along to intimate picnics. Some modern picnic baskets include detachable blankets to sit on.
An innovative picnic hamper advertised for American families in 1953 was designed to clamp over the seat at the back of the family car. The hamper opened with a "built-in midget-size icebox" and slide-out trays "for everyone who wants to eat away from the ants."
Picnic hamper foods usually include pre-prepared sandwiches, pies, fruit, cake, salads and other dishes. A 1917 Australian newspaper article lists items in a picnic hamper for 12 people as: "Ham and mustard sandwiches, tomato and cucumber sandwiches, lettuce and salmon sandwiches, roast fowl, one sponge cake, one currant cake, two dozen scones, one dozen Queen cakes, two dozen lemon cheese tartlets, two dampers, 18 blocks lamington cake, one dozen cream puffs, one dozen custard puffs, 1lb biscuits, 1lb butter, one bottle home-made lemon syrup, one bottle milk, 2lb sugar, 1/4lb tea, four dozen mixed fruit, sweets, one small kettle, six plates, one dozen cups, one jug, one drying cloth, one Billycan, one box matches, four knives, four spoons."

## Etymology

Hamper comes from ‘hanapier’, meaning a case for goblets. The concept came from France via William the Conqueror in the 11th century. Portable wicker wine carriers became adopted as travellers’ refreshment baskets, as long journeys often meant overnight stays in coaching inns where palatable food was not always available. Travellers would thus carry better food with them in such baskets or hampers.
# Hundred-Mile Wilderness

Download coordinates as:
* KML
* GPX (all coordinates)
* GPX (primary coordinates)
* GPX (secondary coordinates)
The Hundred-Mile Wilderness is the section of the Appalachian Trail in the state of Maine running between Monson and Abol Bridge over the West Branch of the Penobscot River just south of Baxter State Park. It is generally considered the most remote section of the Appalachian Trail, and one of the most challenging to navigate and traverse. This section of the trail is crossed by several logging roads and is maintained by the Maine Appalachian Trail Club. It consists of a small corridor of protected wilderness surrounded by large tracts of public and private land controlled by paper companies. An increasing amount of the adjoining lands are being protected by groups like the Appalachian Mountain Club and the Nature Conservancy.
In 2000, a series of new logging roads and a marked side-trail offered hikers re-supply and lodging opportunities between miles 55 and 65 heading northbound from Monson.
45°36.9′N 69°9.8′W﻿ / ﻿45.6150°N 69.1633°W﻿ / 45.6150; -69.1633﻿ (Hundred-Mile Wilderness)
45°19′18″N 69°30′46″W﻿ / ﻿45.32168°N 69.51286°W﻿ / 45.32168; -69.51286﻿ (Monson, ME) 45°20′28″N 69°31′37″W﻿ / ﻿45.34111°N 69.52685°W﻿ / 45.34111; -69.52685 45°22′46″N 69°28′14″W﻿ / ﻿45.37952°N 69.47046°W﻿ / 45.37952; -69.47046 45°25′01″N 69°25′13″W﻿ / ﻿45.41705°N 69.42029°W﻿ / 45.41705; -69.42029 45°24′56″N 69°22′14″W﻿ / ﻿45.41559°N 69.37042°W﻿ / 45.41559; -69.37042﻿ (Barren Mountain) 45°27′36″N 69°15′21″W﻿ / ﻿45.46013°N 69.25597°W﻿ / 45.46013; -69.25597﻿ (Chairback Mountain) 45°28′26″N 69°17′40″W﻿ / ﻿45.47386°N 69.29442°W﻿ / 45.47386; -69.29442 45°30′59″N 69°19′20″W﻿ / ﻿45.51645°N 69.32219°W﻿ / 45.51645; -69.32219 45°33′17″N 69°14′45″W﻿ / ﻿45.55468°N 69.24592°W﻿ / 45.55468; -69.24592﻿ (White Cap Mountain) 45°34′42″N 69°13′22″W﻿ / ﻿45.57834°N 69.22268°W﻿ / 45.57834; -69.22268 45°36′54″N 69°09′48″W﻿ / ﻿45.61499°N 69.16334°W﻿ / 45.61499; -69.16334 45°36′57″N 69°07′45″W﻿ / ﻿45.61581°N 69.12928°W﻿ / 45.61581; -69.12928 45°39′36″N 68°59′34″W﻿ / ﻿45.65995°N 68.99268°W﻿ / 45.65995; -68.99268 45°43′48″N 69°05′30″W﻿ / ﻿45.73000°N 69.09156°W﻿ / 45.73000; -69.09156 45°49′17″N 69°09′55″W﻿ / ﻿45.82129°N 69.16519°W﻿ / 45.82129; -69.16519 45°48′22″N 69°04′57″W﻿ / ﻿45.80601°N 69.08242°W﻿ / 45.80601; -69.08242 45°50′06″N 68°58′02″W﻿ / ﻿45.83496°N 68.96719°W﻿ / 45.83496; -68.96719﻿ (Abol Bridge)
# Titusville Area School District

The Titusville Area School District is a small, rural public school district located in Titusville, Pennsylvania.
The school district comprises Allegheny Township, Cherrytree Township, Oil Creek Township and Pleasantville Borough located in Venango County; and Centerville Borough, Hydetown Borough, Oil Creek Township, Rome Township and Titusville City located in Crawford County; and Southwest Township located in Warren County. The School District covers about 200 sq mi (520 km$^2$). Per the 2000 federal census data, the district serves a resident population of 14,698. In 2009, the district residents' per capita income was $15,872, while the median family income was $37,271.

## Schools

The district operates an early childhood center, which contains a day care center, three elementary schools (grades 1–5), a middle school (grades 6–8), a senior high school (grades 9–12), and one alternative education school. All of the district's facilities have been either constructed or renovated since the 1990s.
* Early Childhood Center is located at 330 Spruce Street in Titsville. Constructed in 1991, the two-story building is home to Day Care, an Early Intervention Program, Pre-K, Pre-1st and Kindergarten Classes for the entire district.
* Main Street Elementary School: opened in 1912 and was renovated in 2002. The school is located at 117 Main Street, Titusville, PA.
* Hydetown Elementary School: opened in 1956 and was renovated in 2001. The school is located at 12294 Gresham Road, Titusville, PA.
* Pleasantville Elementary School: opened in 1942 and was a High School, until the building was merged into the district in 1969. All district Junior High School Students attended at the school until 1977 when the Senior High School was renovated, after that it became solely an elementary school. The school is located at 374 North Main Street, Pleasantville, PA.
* Titusville Area Middle School: opened in 1999, after moving from the High School Complex. The school is located at 415 Water Street, Titusville, PA.
* Titusville Area High School, located at 302 E. Walnut St., Titusville, PA.
# Giacomo Boni (archaeologist)

Giacomo Boni (25 April 1859 – 10 July 1925) was an Italian archaeologist specializing in Roman architecture. He is most famous for his work in the Roman Forum.

## Life

Born in Venice, Boni studied architecture at the Accademia di Belle Arti in his native city and later moved to Rome. During World War I Boni participated as a soldier, and was elected senator in 1923, at which time he embraced fascism.
Boni died in Rome, and he is buried in the Orti Farnesiani on the Palatine Hill.

## Work
### Venice

His early work as an architect involved him in the restoration of the Doge's Palace. During this time he demonstrated his technical skills. In the 1880s, Boni met Horatio Brown, who became his colleague in a shared passion for antiquities.

### Rome

In 1888 Boni went to Rome, where in 1898 the Ministro della Pubblica Istruzione G. Baccelli named him director of excavations in the Forum Romanum. Boni directed this important project from 1898 until his death in 1925. He was interested in the stratigraphy of the Forum, an important advance in the science of Roman archaeology.
His excavations led to many important discoveries, including the Iron Age necropolis near the Temple of Antoninus and Faustina, the Lapis Niger, the Regia, Galleria Cesaree, Horrea Agrippiana, the Temple of Vesta, and other monuments. In 1907 Boni also worked on the slope of the Palatine Hill where he discovered the Mundus (tholos-cistern), a complex of tunnels leading to the Casa dei Grifi, the so-called Aula Isiaca, the so-called Baths of Tiberius and the base of a hut under the peristyle of the Domus Flavia.
The excavations were interrupted by the outbreak of World War I and resumed in 1916.

## Roman religion and fascism

Boni developed a strong interest in the ancient Roman religion and wished to see it revived and some of its rituals restored and adopted by the Italian state. When the National Fascist Party came to power he viewed it as a chance for a pagan revival. He viewed fascism as connected to ancient Rome and agreed with Benito Mussolini's claim that fascism was a sort of continuation of the Roman Empire. Mussolini in turn supported Boni and appointed him as a senator. Boni's role in fascism would however not last long, as he died in 1925 and only lived through a few years of the fascist state. He was buried on the Palatine hill in an extraordinary ceremony organized by the regime. He is considered an early figure in what scholars later would label as "sacred fascism".

## Selected publications

* Boni, Giacomo (1898). The Lagoons of Venice.
* Boni, Giacomo (1898). Studi danteschi in America.
* Aedes Vestae. 1900.
* Boni, Giacomo (1900). "IX.—The Niger Lapis in the Comitium at Rome". Archaeologia. 57 (1): 175–184. doi:10.1017/S0261340900011437.
* "Trajan's Column". Proceedings of the British Academy, 1907–1908. 3: 93–98.
# Rząchowa

Rząchowa is a village in the administrative district of Gmina Szczurowa, within Brzesko County, Lesser Poland Voivodeship, in southern Poland. It lies approximately 4 kilometres (2 mi) north-west of Szczurowa, 19 km (12 mi) north of Brzesko, and 50 km (31 mi) east of the regional capital Kraków.
# Lubień, Lesser Poland Voivodeship

Lubień (Polish pronunciation:) is a village in Myślenice County, Lesser Poland Voivodeship, in southern Poland. It is the seat of the gmina (administrative district) called Gmina Lubień. It lies approximately 12 kilometres (7 mi) south of Myślenice and 37 km (23 mi) south of the regional capital Kraków.
# Pitch World

Pitch World was a home shopping television channel broadcast in the United Kingdom and Ireland on the Freesat and Sky platforms.
Pitch World (which was formerly known as Pitch Plus) acted as a sister channel to Pitch TV. The channel operated 24 hours a day and offered items for sale that could be bought by phone or online. The channel shares its shopping website with Pitch TV.
In August 2009, Pitch World temporarily ceased broadcasting after parent company Pitchwell Group went into liquidation. The sales order line of the channel ceased on August 10, with a statement posted on the channel's website confirming that the company had gone bust on August 24. In the statement, the firm claimed that the situation was due to "unreasonable steps taken from Lloyds bank which ultimately brought the business to a standstill".
Programming from JML continued to broadcast in its place for a time. On 30 September 2009, Pitch TV and Pitch World returned to Sky under the ownership of Pitch World Limited. Pitch World was removed from Freesat channel 804 on 28 August 2009 before being re-added on 1 October 2009.
On 12 April 2013, Pitch World Limited entered administration and the channel was replaced by Discount TV from TV Discount Store Limited on 1 May. Pitch TV was replaced by Armchair Shop from Tristar Media UK Limited on 22 May 2013.
# Steve Israel (American football)

Steven Douglas Israel (born March 16, 1969) is an American former professional football player who was a cornerback in the National Football League (NFL). He played college football for the Pittsburgh Panthers.

## Career

Israel grew up in Lawnside, New Jersey and played high school football at Haddon Heights High School.
He played college football at the University of Pittsburgh and was selected first in the second round of the 1992 NFL draft. He played in the NFL for the Los Angeles Rams, the San Francisco 49ers, the New England Patriots, the New Orleans Saints, and the Carolina Panthers. After ten years in the NFL, Israel is now a college football analyst on ESPNU, Fox Sports and has appeared on some local networks.
Israel founded the EndZone Luncheon Series and created the Gridiron Luncheon Series in Charlotte.

## Personal life

Israel received a BA in economics from the University of Pittsburgh and received business qualifications from the Stanford Graduate School of Business and from Harvard Business School.
In recognition for his contributions to football, Israel was inducted into the Camden County, New Jersey Hall Of Fame and the South Jersey Coaches Hall Of Fame.
Israel is currently married to Lorae Israel and has four children.
# Museum Kunst der Westküste

The Museum Kunst der Westküste (Museum of West Coast Art) is a non-profit foundation, located in Alkersum on the north Frisian island, Föhr. The museum collects, researches, communicates and exhibits art that deals with the themes of sea and coast. The museum began with a collection of paintings donated by the museum's founder, Frederik Paulsen, chairman of Ferring Pharmaceuticals.

## Collection

The Sammlung Kunst der Westküste (Collection of West Coast Art) comprises Danish, German, Dutch and Norwegian art. Executed between 1830 and 1930, the works document life along the continental North Sea coast. Scandinavian and German artists of the 19th and 20th centuries are represented, including Anna Ancher, Michael Ancher, Max Beckmann, Johan Christian Dahl, Peder Severin Krøyer, Christian Krohg, Max Liebermann, Emil Nolde and Edvard Munch.
The collection contains works by Dutch painters such as the Romantic artist, Andreas Schelfhout, and members of The Hague School, Jozef Israëls and Hendrik Willem Mesdag. Johan Barthold Jongkind and Eugène Boudin, who are regarded as precursors of Impressionism and important to the development of European landscape painting in the 19th century, are also represented. Finally, a main focus of the collection is North Frisian painting, represented by the works of de:Otto Heinrich Engel and Hans Peter Feddersen.

## Architecture

The Museum was designed by Sunder-Plassmann Architekten as a multipart museum complex, combining tradition and Modernism. The museum contains six galleries with a total exhibition space of over 900 square metres (9,700 sq ft).
The museum's architecture addresses local building and landscape history in by integrating existing buildings like historical barns, and highlighting the differences between the sandy coastal heathlands and the lower marshland. The complex, built between 2006 and 2009, also includes a museum garden and “Grethjens Gasthof“, built in the style of a Scandinavian manor house from around 1900. Carrying on its traditional function as a meeting place for artists working on Föhr and as a site where natives and guests congregate, this building now houses the museum restaurant Grethjens Gasthof.

## Awards

In 2011 the museum was nominated for the European Museum of the Year Award. The same year Sunder-Plassmann Architekten were awarded the Architekturpreis Schleswig-Holstein and the museum received the Red Dot Design Award for its corporate design.
# Compton Wynyates (parish)

Compton Wynyates or Compton Wyniates is an ancient parish and civil parish in Stratford-on-Avon District, Warwickshire, England. It includes the house and grounds of Compton Wynyates, and extends to the north-east and south-west of the house, with a size of roughly 3.5 by 0.5 miles (6 km × 0.8 km). The parish has an area of 1,038 acres (420 ha). Compton Wynyates was also a village; the earthworks of the village partly survive. It does not have a parish council but has a parish meeting. Population figures for the 2011 census are not available for this parish. Population figures from 1801 to 1961 ranged between 15 and 48, with a figure of 23 in 1961. The civil parish was within Brailes Rural District from 1894 to 1931 and within Shipston-on-Stour Rural District from 1931 to 1974.

## History

The name "Compton" means valley farm/settlement', and the "Wyniates" part means 'windy pass'.
# Anis Nabar

Yohanis Nabar (born 14 September 1992), better known as Anis Nabar, is an Indonesian professional footballer who plays as a winger for Liga 2 club Persipura Jayapura.

## Career
### PSMS Medan

He was signed for PSMS Medan to play in Liga 2 in the 2020 season. This season was suspended on 27 March 2020 due to the COVID-19 pandemic. The season was abandoned and was declared void on 20 January 2021.

## Honours

PSBS Biak
* Liga 2: 2023–24
# Równie

Równie is a village in the administrative district of Gmina Biecz, within Gorlice County, Lesser Poland Voivodeship, in southern Poland. It lies approximately 8 kilometres (5 mi) north-west of Biecz, 14 km (9 mi) north of Gorlice, and 95 km (59 mi) east of the regional capital Kraków.
# Lubomierz, Limanowa County

Lubomierz is a village in the administrative district of Gmina Mszana Dolna, within Limanowa County, Lesser Poland Voivodeship, in southern Poland. It lies approximately 12 kilometres (7 mi) south-east of Mszana Dolna, 20 km (12 mi) south-west of Limanowa, and 54 km (34 mi) south of the regional capital Kraków.
Lubomierz has a municipality called Rzeki, located eastward on the road to Szczawa. The settlement was founded in the 17th century. It used to be the location of the Gorce National Park headquarters, set up at a remote hunting lodge.