OpenLLM-France/wikimedia huggingface dataset:
# TCFH

TCFH (N,N,N’,N’-tetramethylchloroformamidinium hexafluorophosphate) is an electrophilic amidine reagent used to activate a number of functional groups for reaction with nucleophilies. TCFH is most commonly used to activate carboxylic acids for reaction with amines in the context of amide bond formation and peptide synthesis.

## Preparation

TCFH is commercially available. It may be prepared from tetramethylurea using a chlorinating agent such as oxalyl chloride, thionyl chloride or phosphorus oxychloride followed by salt exchange.

## Uses

TCFH itself is a common reagent used in the preparation of uronium and guanidinium salts used for amide bond formation and peptide synthesis, such as HATU.
Amide bond formation with TCFH can be performed in a wide range of organic solvents, most commonly acetonitrile, but also water and in the solid state. Reactions typically require an added Brønsted base, and a wide range can be employed including N,N-diisopropylethylamine (DIPEA). In reactions of carboxylic acids with TCFH and a weakly Lewis basic amine like DIPEA, formation of an acid chloride or anhydride as the active acylating agent occurs. Use of N-methylimidazole (NMI) as a base, with both Brønsted and Lewis basic properties, provides some unique advantages. Reactions of carboxylic acids with TCFH and a strongly Lewis basic amine like NMI lead to in situ formation of an N-acyl imidazolium ion (NAI) as the active acylating agent.
These strongly electrophilic NAIs allow for reactions with a wide range of nitrogen nucleophiles, including hindered and electron-deficient amines. An added benefit of the use of NMI as the base, due to its low pK$_a$(H$_2$O) of 7, is that the epimerization of labile stereogenic centers is minimized. The reaction by-products have high water solubility, facilitating reaction workup and isolation.
TCFH can also be used in other reactions involving activation of carboxylic acids from reactions with oxygen-, sulfur- and carbon-nucleophiles for the preparation of esters, thioesters and ketones. Extending beyond reactions with carboxylic acids, TCFH has been shown to be an activator for other oxygen centered nucleophiles, including heterocyclic alcohols, ketooximes, and even alcohols. Reactivity with sulfur centered nucleophiles like thioureas has also been demonstrated.

## Safety

TCFH does not exhibit dermal corrosion or irritation but irritates eyes. The sensitization potential of TCFH was shown to be low compared to other common amide bond forming agents (non-sensitizing at 1% in LLNA testing according to OECD 429). The by-product of the reactions of TCFH is tetramethylurea, which has demonstrated embryotoxic and teratogenic activity in several animal species.
# C18H25N

The molecular formula C$_{18}$H$_{25}$N (molar mass: 255.40 g/mol, exact mass: 255.1987 u) may refer to:
* Dimemorfan, or 3,17-dimethylmorphinan, a cough suppressant of the morphinan family
* Naphthylpropylaminopentane
* Volazocine, an opioid analgesic]] of the benzomorphan class which was never marketed
# Nicholas Szécs

Nicholas from the kindred Szécs (Hungarian: Szécs nembeli Miklós), also known as Nicholas of Komárom (Hungarian: Komáromi Miklós; died 1297) was a Hungarian nobleman, who acted as lord of Komárom (today Komárno, Slovakia) together with his brother Paul since the 1280s.

## Career

Historians György Györffy and Krisztina Tóth identified him with that certain Nicholas, son of Paul, who served as ispán of Győr County just before Paul Szécs. As Nicholas and Paul always appeared in contemporary records together since the 1280s, it is presumable that they were brothers (or at least cousins). According to an undated royal charter by Ladislaus IV, possibly around 1286, the King authorized Lodomer, Archbishop of Esztergom to excommunicate Paul and Nicholas, if they would confiscate two-thirds part of the trade customs in Komárom which were entitled to the Bakonybél Abbey. That data confirmed they jointly owned Komárom Castle since the mid-1280s, possibly as familiares of the powerful Kőszegi family.
After 1296, King Andrew III, who intended to establish an alliance among the local noblemen against the oligarchs – most notably Matthew Csák and the Kőszegis, started negotiations with Nicholas and Paul, among others. As a result, the Szécs brothers left the Kőszegi allegiance and joined Andrew's partisans. Tóth argued Nicholas was appointed ispán of Győr and Komárom Counties after that, thus it is possible he was elder than his brother Paul. He first appeared in sources in this regard since January 1297. Nicholas served as an ad-litem judge during a lawsuit in the case of Óbecse (today Bečej in Serbia) in June 1297, along with Emeric, Bishop of Várad, Master of the treasury Dominic Rátót, Stephen Ákos and Voivode Roland Borsa. As these all persons were members of the alliance which struggled against Matthew Csák, historian Krisztina Tóth argued initially Nicholas would have been that lord with whom King Andrew intends to contract. However Nicholas died shortly afterwards, and his brother Paul became one of the five barons in 1298, who entered into a formal feudal alliance with their King against the oligarchs and the bishops' college.
# Vukël

Vukël (definite form: Vukli) is a settlement in the former Kelmend municipality, Shkodër County, northern Albania. At the 2015 local government reform it became part of the municipality Malësi e Madhe. Vukel is one of the four original villages of Kelmend. Three of these villages, Selca, Nikçi, and Vukli are located in the Kelmend Commune. Boga is located in Shkreli Comune. Inhabitants of Lepusha Village originated from Vukli village.
* View from Brojë into the Vukël valley
* Bar in village center
* Landscape in Vukël
# Steve Harrison (ice hockey)

Steve Harrison (born April 25, 1958) is a Canadian former professional ice hockey defenceman. He last played for the Fort Worth Fire of the Central Hockey League. He is currently the head coach for the Carolina Thunderbirds in the FPHL.

## Career
### Early career

Harrison was drafted from the Toronto Marlboros by the St. Louis Blues, 39th overall, in the 1978 NHL Amateur Draft, but he never played in the NHL and spent the majority of his career with the Salt Lake Golden Eagles. He has also played in the SM-liiga.

### Coaching

Prior to the 1993–94 CHL season, Harrison was named the head coach of the Fort Worth Fire. After the Fire finished with a combined record of 57-63-10 in 2 seasons, failing to qualify for the playoffs in both seasons, he was fired and replaced with Bill McDonald.
Harrison was named the head coach of the Toledo Storm for the 2003–04 ECHL season but was replaced mid-season by Nick Vitucci.
Harrison was named the head coach of the Danville Dashers for the 2014–15 FHL season. The Dashers won the Championship in 2017, but Harrison resigned as their head coach shortly after.
In addition, Harrison coached the New Mexico Renegades during their final season in New Mexico and worked as a scout for the San Jose Sharks.
In summer 2023, Harrison was named head coach of the FPHL Carolina Thunderbirds based in Winston-Salem, North Carolina. He led the Thunderbirds to a second place regular season finish in the FPHL's Continental Division.
# Storyboard (TV series)

Storyboard is a BBC drama anthology series of six 30-minute plays, mostly written by Troy Kennedy Martin, the first series created by the screenwriter. The series was followed by Studio 4.

## Episodes

* "The Gentleman from Paris" (based on a book by John Dickson Carr)
* "The Magic Barrel" (based on a book by Bernard Malamud)
* "The Middle Men"
* "The Long Spoon" (based on a short story by John Wyndham)
* "I'll Be Waiting" (based on a book by Raymond Chandler)
* "Tickets to Trieste" (based on a book by Ken Wlaschin)

## Status

The entirety of the show is missing from the BBC archives.
# Khar Lake (Khovd)

Khar Lake (Mongolian: Хар нуур, ᠬᠠᠷ᠎ᠠᠨᠠᠭᠤᠷ; lit. 'Black Lake') is located in the Khovd aimag (province) in western Mongolia's Great Lakes Depression.

## Name

It is also known as Ha-la Hu, Hara Nuur, Har Nuur, Khara Nur, Khar Nuur, and Ozero Kara-Nor
It should be distinguished from the similarly named Khar Lake (Zavkhan), another lake further east in Mongolia.

## Description

It is part of a group of lakes that were once part of a larger prehistoric lake that disappeared 5,000 years ago as the region became drier.
Some sources are using different Khar Lake statistics values:
* Water level: 1,134.08 m
* Surface area: 565.2 km²
* Average depth: 4.14 m
* Volume: 2.34 km$^3$.

### Water Balance

Water balance of Khar Lake (Unit of water balance: mm/year) :
| Surface input | Surface input | Surface output | Surface output | Groundwater inflow- outflow | Retention time, years |
| Precipitation | Inflow | Evaporation | Outflow | Groundwater inflow- outflow | Retention time, years |
| 54.0 | 1,786.9 | 1,117.8 | 1,287.9 | +564.8 | 1.7 |
Khar Lake has a single inflow - Chono Kharaikh Gol river, which creates a river delta.
Khar Lake has a connection to Dörgön Nuur south of it.
# Mill Creek (Susquehanna River tributary, Otego)

Mill Creek is a river in Otsego County, New York. It converges with the Susquehanna River in the town of Otego, southwest of Oneonta.
# Macrostomus mundurucu

Macrostomus mundurucu is a species of dance flies, in the fly family Empididae.
# Rock bunting

The rock bunting (Emberiza cia) is a passerine bird in the bunting family Emberizidae, a group now separated by most modern authors from the finches, Fringillidae.
The genus name Emberiza is from Old German Embritz, a bunting. The specific cia is from a local Italian name for this bird, from zirlare, "to chirp".

## Range

It breeds in northwest Africa, southern Europe east to central Asia, and the Himalayas. It also breeds locally in central Europe. It is partially migratory, with northern populations wintering further south, mainly within the breeding range of the resident southern populations. It is a rare wanderer to western Europe.

## Habitat

The rock bunting breeds in open dry rocky mountainous areas.

## Description

This bird is 16 cm in length. The breeding male has chestnut upperparts, unmarked deep buff underparts, and a pale grey head marked with black striping.
The female rock bunting is a washed-out version of the male, with paler underparts, a grey-brown back and a less contrasted head. The juvenile is similar to the female, but with a streaked head.
There are four races differing mainly in the plumage shades, although the subspecies which breeds in Europe, Africa and western Turkey is the only one to show white wing bars.

## Foraging and breeding

It lays three to five greyish eggs in a lined nest on the ground or occasionally in a low bush. Its natural food consists of insects when feeding young, and otherwise seeds.

## Song

The call is a sharp tseee, and the song is a twittering churrrr-chirrriiii-itt.
# Roseau High School

Roseau High School is a public high school in Roseau, Minnesota, United States serving students from grades 7 through 12. It is part of Roseau Community Schools, Minnesota ISD 682. The school's hockey program has matriculated several NHL and Olympic hockey players.

## Notable people
### Alumni

* Mike Baumgartner (Class of 1967) — NHL player
* Earl Anderson (Class of 1968) — NHL player
* Dale Smedsmo (Class of 1967) — NHL player
* Neal Broten (Class of 1977) — 1980 US Olympic hockey team member, NHL player, greatest Minnesota born hockey player
* Aaron Broten (Class of 1978) — NHL player
* Butsy Erickson (Class of 1978) — NHL player
* Paul Broten (Class of 1984) — NHL player
* Josh Olson (Class of 1999) — NHL player
* Dustin Byfuglien (2001) (transferred out) — NHL player
* Aaron Ness (Class of 2008) — NHL player, New York Islanders

## Faculty

* Dean Blais — 1990–1991 boys' hockey coach
* Dan Fabian — member of the Minnesota House of Representatives, teacher since 1976
* Harold Paulsen — 1940s boys' hockey coach
# Josh McLaurin

Joshua Ivan McLaurin (born January 17, 1988) is a member of the Georgia State Senate in the state of Georgia. McLaurin represents the 14th district in the state Senate, a seat once held by 39th president of the United States Jimmy Carter. Before his election to the state Senate, McLaurin served two terms in the Georgia House of Representatives.

## Early life

McLaurin was born in Cobb County, Georgia, Georgia. He attended the University of Georgia for college. He then attended Yale Law School, where he briefly lived with author, future U.S. senator, and Vice President JD Vance.

## Political career

After winning the 2018 election for a seat in the Georgia House of Representatives, McLaurin succeeded 17-year incumbent Wendell Willard.
In 2022, following Donald Trump's endorsement of JD Vance for that year's Senate election in Ohio, McLaurin shared private text messages Vance had sent him during the 2016 United States presidential campaign positing that Trump could become "America's Hitler". Vance was later elected and inaugurated as vice president of the United States.
# Mighty Sports Apparel

Mighty Sports Apparel and Accessories, Inc. (MSAA) is a Philippine sportswear manufacturing company headquartered in Guiguinto, Bulacan. The company makes a wide range of customized and ready-to-wear apparel and accessories for numerous types of sports. They are also the official supplier of top colleges and universities in the Philippines such as Xavier School, Ateneo de Manila University, University of the Philippines and De La Salle-College of St. Benilde. It is owned by businessman Caesar Wongchuking.
The sportswear maker also owns the Mighty Sports basketball team that participates in various domestic and international tournaments such as the Pilipinas Commercial Basketball League, William Jones Cup and most recently, Dubai International Basketball Championship that featured former Los Angeles Lakers star Lamar Odom and Ginebra import Justin Brownlee.
In June 2019, Mighty Sports Apparel and Accessories introduced their newly redesigned logo featuring a simplified three-pronged crown representing their core businesses of customized sportswear, ready-to-wear goods, and sports teams.

## Partnerships

The sportswear manufacturer is currently an official merchandise partner of the Ateneo de Manila University and De La Salle-College of St. Benilde. The company was previously the official outfitter of the UP Fighting Maroons Men's Basketball Team. They had a corporate sponsorship with the Bulacan Kuyas (dubbed "Bulacan Kuyas-Mighty Sports") in the Maharlika Pilipinas Basketball League that lasted for only one season.
MSAA is also the apparel and gear manufacturer for Xavier School including varsity team uniforms, PE uniforms and official merchandise. In August 2018, MSAA entered a joint-venture with Xavier School to publish a coffee table book entitled Golden: A Celebration of the Xavier Golden Stallions commemorating the achievements of athletes of Xavier School over the past few decades.
The firm has also sponsored sports organizations and individuals, mostly involving junior, "differently-abled" or any Philippine representative athletes. For example, they sponsored two of Manila's top junior golfers in 2015 and most recently, donated all of Mighty Sports basketball team's Republica Cup 2018 prize money to boost the Paralympic Committee of the Philippines athletes.
In July 2019, Samahang Basketbol ng Pilipinas embarked on a partnership with Mighty Sports Apparel and Accessories to become the official merchandiser and outfitter of the Gilas Pilipinas national basketball team. Under the agreement, Mighty Sports will produce and sell merchandise promoting the Gilas Pilipinas brand.
# Institute of Mental Health and Hospital

The Institute of Mental Health and Hospital Agra, previously known as Agra Lunatic Asylum was established in 1859, in British Raj by State government of Uttar Pradesh. The Institute of Mental Health and Hospital spread over a campus of 172.8 acres in Agra in front of Bilochpura Railway Station near Sikendra. The institute is very famous in India for its treatment, research and training on human mental disorder.

## History

The first asylum in India is founded by British Government in 1745 in Bombay and second in 1784 in Calcutta. Few more asylums are also founded by British Government in 1857 in big cities of India. In 1859, Agra asylum was also founded by British Government. The Institute of Mental Health and Hospital Agra was established in September 1859, and renamed to Mental Hospital Agra in 1925. Previously it was managed under the provisions of Indian Lunacy Act, 1912. Nowadays it is managed under the provisions of Mental Healthcare Act 2017. In 1994 it was again renamed to Agra Mansik Arogyashala by Honourable Supreme Court of India and made it an autonomous institution which aimed to improve treatment and care of mentally ill persons and provide professional education, training and research on mental health. On 8 February 2001 it again renamed as Institute of Mental Health and Hospital Agra.

## Professional courses

The Institute offers MD Psychiatry, DNB Psychiatry, M.Phil Clinical Psychology, M.Phil Psychiatric Social Work, Post Basic Diploma in Psychiatric Nursing, Short term training programme in Psychiatry.
# Pigs in the City

Pigs in the City is a public art initiative coordinated by Uptown Lexington, Inc., a non-profit organization created to revitalize the downtown (or locally called "uptown") area of Lexington. It includes a near annual event held in the fall in the uptown business district of Lexington, North Carolina, U.S., the self-proclaimed Barbecue Capital of the World. It is part of a larger downtown revitalization effort which has gained significant media attention due its unusual artistic display of full-size ornamental pigs and draws visitors from all over North Carolina. The event is free to the public.

## History

During the 2004 "North Carolina Main Street" 24th Annual Awards Banquet, Pigs in the City won Best Downtown Special Event for their first event in 2003. The event drew over 40,000 visitors from all over the state in its first year. It became an annual event after 2006. The cost to "sponsor" one of the 20 pigs on display was $1,000 during the first exhibition, which paid for the initiative. There was some controversy as the "Root for the Troops" pig was stolen from its perch in front of the Army & Navy Store on Main Street.
The fourth annual "Pigs in the City" event was held from May 23 through October 23, 2008, and was called "Power of the Pig." The pigs were also on display during the 25th Anniversary Lexington Barbecue Festival and during the Official Food Festival of the Piedmont Triad Region of the State of North Carolina, a one-day event that usually draws up to 150,000 visitors from all over the nation to Lexington, a town of about 20,000 residents.
Some of the themes for Pigs in the City 4 include Pigahontas, Tanya "Cabbage Patch" Burcham, This Little Piggy went to Market, Mr. Porkwrench, Huckleberry Pig and Girl Snout.

## Display

A number of artistic pigs are on display throughout the walkway of uptown Lexington, around the entire city square. The pigs are primarily made of fiberglass, and decorated and painted by local artists, each with their own theme. While some pigs are displayed for more than one year, new pigs are created for each year's display.

## Gallery

Some of these are past entries that are now on permanent display throughout Lexington, or at Uptown Lexington, Inc. main office.
* Carpenter pig
* Swine Lake
* Pig Pickin'
* Girl Snout
* Rain or Swine
* Digger the Caterpiggar
* Fire Hog at the Lexington Fire Dept. HQ
* Porknox
* Pigsaw
* Newbee
* Pigasus
# Rocky Branch (Lanes Creek tributary)

Rocky Branch is a 1.40 mi (2.25 km) long 2nd order tributary to Lanes Creek in Anson County, North Carolina.

## Course

Rocky Branch rises about 1.5 miles northeast of Peachland, North Carolina. Rocky Branch then flows southeast to meet Lanes Creek about 2.5 miles north of Peachland.

## Watershed

Rocky Branch drains 1.90 square miles (4.9 km$^2$) of area, receives about 48.0 in/year of precipitation, has a topographic wetness index of 429.73 and is about 38% forested.
# Rundelltown Creek

Rundelltown Creek is a 7.69 mi (12.38 km) long 2nd order tributary to Carr Run in Crawford County, Pennsylvania.

## Course

Rundelltown Creek rises about 0.25 miles south of Norrisville, Pennsylvania, and then flows northeast to join Carr Run about 2 miles northeast of Rundell, Pennsylvania.

## Watershed

Rundelltown Creek drains 11.95 square miles (31.0 km$^2$) of area, receives about 45.7 in/year of precipitation, has a wetness index of 509.52, and is about 54% forested.
# Schaaf Creek

Schaaf Creek is a stream in Cooper and Moniteau counties of central Missouri.
The stream headwaters arise just south of Prairie Home in eastern Cooper County at 38°48′23″N 92°35′24″W﻿ / ﻿38.8064178°N 92.5899114°W﻿ / 38.8064178; -92.5899114 and an elevation of approximately 860 feet. The stream flows south passing through the Prairie Home Conservation Area along the Cooper-Moniteau county line to its confluence with Moniteau Creek just east of the county line at 38°44′39″N 92°34′39″W﻿ / ﻿38.7441945°N 92.5774128°W﻿ / 38.7441945; -92.5774128 at an elevation of 594 feet.
# Scrubgrass Run

Scrubgrass Run is a 2.24 mi (3.60 km) long 1st order tributary to Chartiers Creek in Allegheny County, Pennsylvania.

## Course

Scrubgrass Run rises in Mt. Lebanon, Pennsylvania and then flows west-southwest to join Chartiers Creek across from Heidelberg.

## Watershed

Scrubgrass Run drains 1.55 square miles (4.0 km$^2$) of area, receives about 38.5 in/year of precipitation, has a wetness index of 331.29, and is about 15% forested.
# Sheppard Run (East Branch Tunungwant Creek tributary)

Sheppard Run is a 2.92 mi (4.70 km) long first-order tributary to East Branch Tunungwant Creek.

## Variant names

According to the Geographic Names Information System, it has also been known historically as:
* Shepard Run

## Course

Sheppard Run rises about 1 mile (1.6 km) west of Howard, Pennsylvania, and then flows northeast to meet East Branch Tunungwant Creek at Custer City, Pennsylvania.

## Watershed

Sheppard Run drains 2.72 square miles (7.0 km$^2$) of area, receives about 46.3 in/year (118 cm/year) of precipitation, and is about 90.47% forested.
# Yoon Yo-seop

Yoon Yo-seop(Korean: 윤요섭; born March 30, 1982) is a coach for the KT Wiz of the KBO League. He joined SK Wyverns in 2008. After that, he belonged to LG Twins in 2010, and he moved to KT Wiz in 2015. He moved from being a catcher to coach in 2017. He graduated Dankook University.
# USS Charles Ausburn (DD-294)

USS Charles Ausburn (DD-294) was a Clemson-class destroyer built for the United States Navy subsequent to World War I.

## Construction and career

Charles Ausburn, named for Charles Lawrence Ausburne, was launched 18 December 1919 by Bethlehem Shipbuilding Corporation, Squantum, Massachusetts; sponsored by Mrs. D. K. Ausburn; and commissioned 23 March 1920. Assigned to the Atlantic Fleet, Charles Ausburn operated from Charleston, South Carolina, Norfolk, Virginia and Newport, Rhode Island along the Atlantic coast and in the Caribbean through 1924, serving with a reduced complement from October 1920 to May 1922. During those years, as she participated in fleet exercises and training maneuvers, she aided in the development and application of new ideas in naval warfare. In the fall of 1923, Charles Ausburn was equipped to carry a seaplane, with which she performed experiments in the rapidly developing field of naval aviation.
In late summer of 1924, Charles Ausburn cruised to northern latitudes to provide plane guard service in the round-the-world flight of Army aircraft, maintaining stations off Greenland and Newfoundland. On 18 June 1925, she sailed from Boston for a year of duty off Europe and in the Mediterranean, visiting at a large number of ports before her return to New York 11 July 1926. She continued her operations with the fleet, often providing facilities for the training of reservists, until 1 May 1930, when she was decommissioned at Philadelphia. There she was sold 17 January 1931.