OpenLLM-France/wikimedia huggingface dataset:
# Borane dimethylsulfide

Borane dimethylsulfide (BMS) is a chemical compound with the chemical formula BH$_3$·S(CH$_3$)$_2$. It is an adduct between borane molecule (BH$_3$) and dimethyl sulfide molecule (S(CH$_3$)$_2$). It is a complexed borane reagent that is used for hydroborations and reductions. The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran, are its increased stability and higher solubility. BMS is commercially available at much higher concentrations than its tetrahydrofuran counterpart (10 M) and does not require sodium borohydride as a stabilizer, which could result in undesired side reactions. In contrast, BH$_3$·THF requires sodium borohydride to inhibit reduction of THF to tributyl borate (B(OCH$_2$CH$_2$CH$_2$CH$_3$)$_3$). BMS is soluble in most aprotic solvents.

## Preparation and structure

Although usually purchased, BMS can be prepared by absorbing diborane into dimethyl sulfide:
    B$_2$H$_6$ + 2 S(CH$_3$)$_2$ → 2 BH$_3$·S(CH$_3$)$_2$
It can be purified by bulb to bulb vacuum transfer. Although a structure of BMS has not been determined crystallographically, (pentafluorophenyl)-borane dimethylsulfide (C$_6$F$_5$BH$_2$·S(CH$_3$)$_2$), has been examined by X-ray crystallography. The boron atom adopts a tetrahedral molecular geometry.

## Reactions
### Hydroborations

Due to the experimental ease of its use, BMS has become common in hydroboration reactions. In hydroborations with BMS, the dimethylsulfide dissociates in situ, liberating diborane, which rapidly adds to the unsaturated bonds. The resulting organoborane compounds are useful intermediates in organic synthesis. Boranes add to alkenes in an anti-Markovnikov fashion and allow conversion of alkynes to the corresponding cis-alkenes.

### Reductions

BMS has been employed for the reduction of many functional groups. Reductions of aldehydes, ketones, epoxides, esters, and carboxylic acids give the corresponding alcohols. Lactones are reduced to diols, and nitriles are reduced to amines. Acid chlorides are not reduced by BMS.
Borane dimethylsulfide is one of the most common bulk reducing agents used in the Corey–Itsuno reduction. The dimethylsulfide ligand attenuates the reactivity of the borane. Activation by the nitrogen of the chiral oxazaborolidine catalyst of the stoichiometric reducing agent allows for asymmetric control of the reagent. In general BMS does not lead to significantly greater enantiomeric selectivities than borane-THF, however its increased stability in the presence of moisture and oxygen makes it the reagent of choice for the reduction.

## Safety

Borane dimethylsulfide is flammable and reacts readily with water to produce a flammable gas. It also has an unpleasant smell.
# Boris Makojev

Boris Akhsarbekovic Makoev (Russian: Борис Ахсарбекович Макоев; born January 22, 1993, in Ossetia) is a Russian naturalized Slovak freestyle wrestler Ossetian ethnicity who competes at 86 kilograms. In March 2021, he competed at the European Qualification Tournament in Budapest, Hungary and qualified for the 2020 Summer Olympics in Tokyo, Japan.
In 2022, Makojev won one of the bronze medals in his event at the Matteo Pellicone Ranking Series 2022 held in Rome, Italy. He won one of the bronze medals in the men's 86 kg event at the 2022 World Wrestling Championships held in Belgrade, Serbia.
Makojev won the silver medal in the men's 92 kg event at the 2024 European Wrestling Championships held in Bucharest, Romania. He competed at the 2024 European Wrestling Olympic Qualification Tournament in Baku, Azerbaijan hoping to qualify for the 2024 Summer Olympics in Paris, France. He was eliminated in his second match and he did not qualify for the Olympics.
# Kollam MEMU Shed

Kollam MEMU Car Shed is an ISO certified motive power depot facility for maintaining MEMU rakes, situated in the city of Kollam in the Indian state of Kerala. It is one of the four MEMU rake maintenance sheds serving the Southern Railway zone of the Indian Railways. Kollam MEMU Shed is functioning as the control and coordination center of MEMU trains running through Kerala state.

## History

MEMU Car sheds in Kollam and Palakkad were proposed in 2008's Indian Railway Budget. The first announced MEMU shed for Kerala was in Kollam, but the inauguration of this shed was delayed for more than two years due to clearance issues and negligence of Indian Railways. Palakkad MEMU Shed inaugurated on 1 January 2011. The Kollam MEMU Shed was formally commissioned on 1 December 2013, five years after its completion. In the second half of 2019, the Southern Railway started replacing the traditional rakes with High-speed, three-phase MEMU trains running on Kollam routes. As the first step, a three-phase MEMU train with 8 coaches started service on Kollam Junction-Ernakulam Junction-Kollam Junction route from September 2, 2019.

## Operations

The MEMU Car Shed in Kollam currently conducts periodic overhauling activities for two different types of rakes manufactured by ICF, Chennai:
* Generation I rakes
* 3-phase 8 coach rake (Total capacity: 2,402 passengers)
Presently, 9 pairs of MEMU services are operated from/to Kollam Junction. The maintenance works of those rakes are regularly being done in Kollam MEMU shed.
| Train Number | Train Name | Schedule |
| 66301/66302 | Punalur - Kollam MEMU | Daily |
| 66303/66304 | Kollam - Ernakulam Junction MEMU (Via Alappuzha) | All days except Mondays |
| 66305/66306 | Kanyakumari - Kollam MEMU (Via Trivandrum) | All days except Fridays |
| 66307/66308 | Ernakulam Junction - Kollam MEMU (via Kottayam) | All days except Wednesdays |
| 66309/66310 | Kollam - Ernakulam Junction MEMU (Via Alappuzha) | All days except Tuesdays |
| 66311/66312 | Alappuzha - Kollam MEMU | Daily |
| 66315/66316 | Kottayam - Kollam MEMU | Daily |
| 66317/66318 | Punalur - Kollam MEMU | Daily |
| 66321/66322 | Ernakulam Junction - Kollam MEMU (via Kottayam) | Daily |
| 16309/16310 | Ernakulam Junction - Kayamkulam MEMU Express (via Kottayam) | Daily |
# On Another's Sorrow

"On Another's Sorrow" is a poem by the English poet William Blake. The poem discusses human and divine empathy and compassion. It was published as part of the Songs of Innocence and of Experience in 1789 as the last song in the Songs of Innocence section.
Blake argues that human sympathy is a valuable trait. After making this observation about man he then speaks of the sympathy of God, as well. In his commentary on the poem, D. G. Gillham notes that though Blake discusses the nature of God, he attempts to do so in a rational way without referring to the supernatural.
The poem is one of the few entries in Songs of Innocence and of Experience that contains an explicit declaration of innocence. It is also the only poem in the volume that is in Blake's own voice.
# Shu Sasaki

Shu Sasaki (佐佐木 周, Sasaki Shū, born 12 February 1991) is a Japanese professional footballer who currently plays for Hong Kong Premier League club Southern.

## Career

Upon graduating from Kansai University where he played on the varsity team, Sasaki signed his first professional contract with the Blacktown Spartans of the National Premier Leagues in Australia. He played with them from 2014 to 2016, when the club were relegated.
In January 2017, Sasaki signed with Philippines Football League club Global Cebu. He made his debut on 24 January in a 2017 AFC Champions League qualifying play-off match against Sinaporean side Tampines Rovers. He scored his first goal for the club 5 April in a 2017 AFC Cup match against Indonesian side Johor Darul Ta'zim.
On 20 February 2018, Sasaki signed with Hong Kong Premier League club Rangers. He scored his first goal for the club on 4 March in a 2–2 draw against R&F.
Following Rangers' relegation to the Hong Kong First Division, Sasaki joined Pegasus on 2 July 2018.
On 8 April 2020, Sasaki agreed to a mutual termination with Pegasus after the club decided to cut costs due to the 2020 coronavirus pandemic and the subsequent suspension of the 2019–20 season.
On 2 May 2020, Southern announced the signing of Sasaki.

## Honour
### Southern

* Hong Kong Sapling Cup: 2022–23
# Stanhope, Victoria

Stanhope is a town in north central Victoria, Australia. Stanhope is 42 kilometres (26 mi) from Shepparton. It lies 197 kilometres (122 mi) north of the state capital Melbourne and 567 kilometres (352 mi) south west of Canberra the capital city of Australia. At the 2016 census, Stanhope had a population of 828.

## History

The Post Office opened on 21 May 1917 but was known as Lauderdale until 1920.

## Today

Like many towns in this area of Victoria, it relies heavily on its dairy production, and farming. A large dairy processing plant lies in the centre of the town.
Like much of Victoria, Netball and Australian rules football are extremely popular and Stanhope hosts a team which is part of the Kyabram & District Football League.
Services in the town include a general convenience store, a pub, lawn bowls and tennis clubs.
Local landmarks include Lake Cooper and Loch Garry and other towns nearby include Girgarre and Tatura and Echuca.

## Notable people

John McEwen, a.k.a. "Black Jack McEwen", 18th Prime Minister of Australia, was a dairy farmer in Stanhope before entering politics.
* Aerial Picture
# Saginaw Transit Authority Regional Services

Saginaw Transit Authority Regional Services (STARS) is the operator of public transportation in Saginaw, Michigan. Ten local routes service the metropolitan area, and about a million passengers use the agency for transport each year. On July 14, 2023, a new route to Frankenmuth was inaugurated.

## Services
### Fixed routes

* 1. State Street-Kroger-Walmart
* 2. Washington-Outer Drive-Veterans Memorial Parkway
* 3. Michigan-Mackinaw-Court
* 4. Holland-Buena Vista-Janes Street
* 5. 14th-Dixie-Genesee
* 6. Weiss-Bay-Meijer
* 7. Washington-Gallagher
* 8. Jefferson-Hess-Sheridan
* 9. Applebee's-Walmart-SVSU
* 11. Woodbridge-Gratiot Plaza-Michigan
These routes are available Monday–Friday 6:00 am to 9:00 pm, Saturday 8:00 am to 6:00 pm and depart from downtown every 60 minutes.
Fares are $1.00 for general public, $.50 for riders 62 or older with identification, those receiving Medicare with ID, Silver Card (ADA/Disabled) and children under 42". Transfers are free, simply ask the driver when boarding.

### Other services

STARS Lift is a curb to curb service available for disabled riders and seniors over 62 with ID. These rides can be scheduled up to two weeks in advance. Fare is $2.75 each way with a gold card.
STARS Express service is available 24 hours, 7 days a week for riders' round the clock needs such as jobs, medical appointments and groceries. These rides can be scheduled up to 24 hours in advance. These rides are $5.25 each way.
Pigeon Express takes employees to Blue Diamond Steel & Huron Castings three times a day.

## Rosa Parks Transfer Plaza

Rosa Parks Transfer Plaza, located at 615 Johnson Street, serves as the primary transfer point in the STARS system providing an indoor waiting area for passengers. However, STARS has outgrown the facility and has proposed relocating their hub to a new location. Sites under consideration include the Potter Street Station, Riverview Plaza on Genesee Ave., and a site near the Saginaw United High School on Davenport Ave.
# William Petric

William Campbell Petric (born 3 August 2004) is an Australian Olympic swimmer.

## Career

In 2024, Petric qualified for the Summer Olympics in Paris after placing second in the 400 Individual Medley event at the Australian Olympic trials.
In his Olympic debut, Petric finished 12th in the 400 Individual Medley and 10th in the semifinal of the 200 Individual Medley.
Through a scholarship offered by the Sport Australia Hall of Fame, Petric is mentored by two-time AFL Brownlow Medalist, Chris Judd.
# Żołędnica, Greater Poland Voivodeship

Żołędnica is a village in the administrative district of Gmina Rawicz, within Rawicz County, Greater Poland Voivodeship, in west-central Poland. It lies approximately 6 kilometres (4 mi) north-east of Rawicz and 83 km (52 mi) south of the regional capital Poznań.
# Viney Fork Baptist Church

Viney Fork Baptist Church is a historic Baptist church in Speedwell, Kentucky, United States. The church is located at the intersection of Kentucky Route 374 and Kentucky Route 499. It was built in 1802 and added to the National Register of Historic Places in 1989.
The church is a one-and-a-half-story cut sandstone building. Its gable end has a short, squared wooden bell tower. It was deemed "an example of a rural country church notable for its use of windows whose blunted arched shape represent a local interpretation of the Gothic style."

## History

The congregation of Viney Fork Baptist Church was organized on March 25, 1797, under the guidance of Peter Woods and Christopher Harris from Dreaming Creek and Andrew Tribble and Isaac Newland from Tates Creek. The initial log structure, likely the first church building constructed by white settlers in Kentucky, was replaced by the current sandstone building in 1802.
The church was founded as and remained a Primitive Baptist congregation until 1845, when it transitioned to a Missionary Baptist Church. The upstairs balcony of the church, used as a school during the week and as a place for slaves to worship on Sundays, was removed in 1866. Following the Civil War, the church supported the establishment of Goodloe's Chapel for freed slaves, which remains an active black Baptist church today.
# Pico do Brejo do Cordeiro

Pico do Brejo do Cordeiro is a peak on the island of São Jorge in the Azores.
It is located around the area of Norte Pequeno and is closely related with a peak mountain in the centre of the island. Its elevation is 739 m above sea level and is made up of a pluvial escarpment by the sea. Its geological formations are volcanic and pyroclastic in origin and are very old.
# Stadionul Minerul (Ștei)

Stadionul Minerul is a multi-purpose stadium in Ștei, Romania. It is currently used mostly for football matches, is the home ground of CSO Ștei and holds 800 people. The stadium was opened in 1954, being built by the Soviets during the town construction and was the home ground of Minerul Ștei until 2008, when the club was dissolved.
In 2015 the Town of Ștei started the procedure to get in the administration of the stadium, owned by the Uranium National Company.
# Designer (song)

"Designer" is a Hindi language song and is sung by Guru Randhawa and Yo Yo Honey Singh, Music Video produced by Bhushan Kumar and written by Guru Randhawa and Yo Yo Honey Singh and has received over 100 million views on YouTube.
The single features Divya Khosla Kumar, and the record was released on May 19, 2022. Upon release, the song topped on YouTube trending charts.
# Żurawiniec, Greater Poland Voivodeship

Żurawiniec is a village in the administrative district of Gmina Baranów, within Kępno County, Greater Poland Voivodeship, in west-central Poland.
# Komiaviatrans

Komiaviatrans (Russian: Комиавиатранс) is a regional airline from Russia, which operates mostly domestic regional flights from Komi Republic. Its headquarter located in Syktyvkar.
It is banned from flying in the EU along with all other Russian airlines.

## Destinations

Komivaiatrans operates scheduled flights to the following domestic destinations (As of May 2015):

### Domestic
#### Arkhangelsk Oblast

* Arkhangelsk - Talagi Airport
* Kotlas - Kotlas Airport

#### Belgorod Oblast

* Belgorod - Belgorod International Airport

#### Kaluga Oblast

* Kaluga - Grabtsevo Airport secondary base

#### Komi

* Inta - Inta Airport
* Koslan - Koslan Airport
* Pechora - Pechora Airport
* Syktyvkar - Syktyvkar Airport base
* Troitsko-Pechorsk - Troitsko-Pechorsk Airport
* Ukhta - Ukhta Airport focus city
* Usinsk - Usinsk Airport focus city
* Ust-Tsilma - Ust-Tsilma Airport
* Vorkuta - Vorkuta Airport
* Vuktyl - Vuktyl Airport

#### Krasnodar Krai

* Anapa - Vityazevo Airport seasonal
* Krasnodar - Pashkovsky Airport seasonal
* Sochi - Adler-Sochi International Airport seasonal

#### Moscow / Moscow Oblast

* Moscow Domodedovo Airport

#### Nizhny Novgorod Oblast

* Nizhny Novgorod - Strigino International Airport

#### Perm Krai

* Perm - Bolshoye Savino Airport

#### St Petersburg / Leningrad Oblast

* Pulkovo Airport

#### Samara Oblast

* Samara - Kurumoch International Airport

#### Saratov Oblast

* Saratov - Saratov Tsentralny Airport

#### Stavropol Krai

* Mineralnye Vody - Mineralnye Vody Airport

#### Sverdlovsk Oblast

* Yekaterinburg - Koltsovo Airport

#### Tatarstan

* Nizhnekamsk - Begishevo Airport

### International
#### Azerbaijan

* Baku - Heydar Aliyev International Airport

## Fleet

As of May 2015, the Komiaviatrans fleet consists of the following aircraft:
| Aircraft | In fleet | Orders | Seats | Notes |
| Embraer ERJ 145LR | 5 | | 50 | (as of August 2017) |
| Let L-410 Turbolet | 4 | — | 15 | Stopped operations |
In addition Komiavaiatrans Airlines operates 3 Mi-2 and 29 Mi-8 helicopters.
# Chiang Nai-shin

Chiang Nai-shin (Chinese: 蔣乃辛; pinyin: Jiǎng Nǎixīn; born 24 September 1948) is a Taiwanese politician. He served in the Taipei City Council from 1982 to 2009, when he was elected to the Legislative Yuan.

## Education

After graduating from National Chengchi University with a bachelor's degree in accounting and business, Chiang attended Tatung University, where he earned a master's degree in business administration.

## Political career

Chiang was elected to the Taipei City Council in 1981 and served until 2009. After Diane Lee resigned her legislative seat in January 2009, Chiang won a four-way primary held on 8 February to represent the Kuomintang in the resulting by-election. He subsequently defeated six other candidates in the by-election held on 28 March.
The Democratic Progressive Party nominated retired baseball player George Chao [zh] to run against Chiang in 2012. During his 2016 campaign, Chiang was first opposed by Freddy Lim, a member of the New Power Party, who soon ceded the race to fellow candidate Fan Yun [zh] of the Social Democratic Party. Chiang easily defeated Fan and Minkuotang candidate Wu Hsu-chih.
# 2000 in NASCAR

The following NASCAR national series were held in 2000:
* 2000 NASCAR Winston Cup Series - The top racing series in NASCAR.
* 2000 NASCAR Busch Series - The second-highest racing series in NASCAR.
* 2000 NASCAR Craftsman Truck Series - The third-highest racing series in NASCAR.
| Preceded by1999 in NASCAR | NASCAR seasons 2000 | Succeeded by2001 in NASCAR |
# Nash (tugboat)

Nash is a World War II U.S. Army Large Tug (LT) seagoing tugboat built as hull #298 at Jakobson Shipyard, Oyster Bay, New York as a Design 271 steel-hulled Large Tug delivered in November 1943. Originally named Major Elisha K. Henson (LT-5), in 1946 she was renamed John F. Nash by the U.S. Army Corps of Engineers. Since retirement from the Corps of Engineers, LT-5 has been renamed Major Elisha K. Henson. As of the 1992 date of its listing as a National Historic Landmark, LT-5 was believed to be one of the last functional U.S. Army vessels that participated in Normandy landings.

## Service in World War II

LT-5 sailed to Great Britain in February 1944 in anticipation of Operation Overlord, the planned allied invasion of Europe. On June 6, 1944, LT-5 sailed for Normandy with two barges as part of Operation Mulberry, in support of Overlord. Under fire, the tug ferried supplies to the landing beaches for the next month, in the process shooting down a German fighter aircraft on June 9.
After the war, LT-5 returned to the United States. Assigned to the Buffalo District of the U.S. Army Corps of Engineers in May 1946, LT-5 was renamed John F. Nash after Buffalo District's Senior Engineer and Chief Civilian Assistant for the period 1932 to 1941. From 1946 to 1989, John F. Nash served the lower Great Lakes region by assisting in the maintenance of harbors, and construction projects that included the St. Lawrence Seaway in the 1950s.

## Post-military career

Renamed Major Elisha K. Henson, she has been largely restored to her original configuration by the H. Lee White Marine Museum in Oswego, New York where she is currently on display. Tours are available Mid-May through the end of September. LT-5 was declared a National Historic Landmark in 1992. A sister ship located at Kewaunee, Wisconsin, the Major Wilbur Fr. Browder (LT-4), now the Tug Ludington, is a museum ship which also served the U.S. Army at D-Day and otherwise has a similar history, which was listed on the National Register in 2002.
* LT-5 starboard-side view, 2009.
* LT-5 bow view

## Awards

* American Campaign Medal
* European-African-Middle Eastern Campaign Medal with one campaign star
* World War II Victory Medal
* National Defense Service Medal with star
# Tepeköy, Gökçeada

Tepeköy, also known by its former Greek name Agrídia (Greek: Αγρίδια), is a village on the island of Imbros in northwestern Turkey. It is part of the Gökçeada District of Çanakkale Province. Its population is 177 (2022).

## Geography

It is located 8 km west of the only town of the island, Çınarlı (or in Greek Panagia Balomeni), and 14 km west from the central port of the island. It stands at an altitude of approximately 280m nearby Kastri hill.

## History & Demography

The village had a total population of 177 in 2022, a notable increase since 2007, when it only had 125 inhabitants. It is one of the few predominantly Greek Orthodox settlements in Turkey, with the Greek population ranging at around 75%, and has a Greek mayor, Dimitrios Psaros. A Greek Orthodox Church dedicated to the Annunciation lies within the village. A Greek minority high school and junior high school are operating in the village since 2015.
# Surya Saputra (wrestler)

Surya Saputra (27 December 1967 - 18 June 2024) was an Indonesian wrestler. He competed in the men's freestyle 52 kg at the 1988 Summer Olympics. He died on 18 June 2024 due to complications caused by diabetes.