OpenLLM-France/wikimedia huggingface dataset:
# Dicarbollide

In organometallic chemistry, a dicarbollide is an anion of the formula [C$_2$B$_9$H$_{11}$]$^{2-}$. Various isomers exist, but most common is 1,2-dicarbollide derived from ortho-carborane. These dianions function as ligands, related to the cyclopentadienyl anion. Substituted dicarbollides are also known such as [C$_2$B$_9$H$_{10}$(pyridine)]$^−$ (pyridine bonded to B) and [C$_2$R$_2$B$_9$H$_9$]$^{2-}$ (R groups bonded to carbon).

## Synthesis of dicarbollides

Dicarbollides are obtained by base-degradation of 12-vertex dicarboranes. This degradation of the ortho derivative has been most heavily studied. The conversion is conducted in two-steps, first "deboronation" and second deprotonation:
    C$_2$B$_{10}$H$_{12}$ + NaOEt + 2 EtOH → Na$^+$C$_2$B$_9$H$_{12}$$^−$ + H$_2$ + B(OEt)$_3$
    Na$^+$C$_2$B$_9$H$_{12}$$^−$ + NaH → Na$_2$C$_2$B$_9$H$_{11}$ + H$_2$
The dianion derived from dicarboranes, [C$_2$B$_9$H$_{11}$]$^{2-}$, are nido clusters. Three isomers exist. Most commonly studies is the 7,8-isomer, with two adjacent carbon centers on the rim. 7,9-C$_2$B$_9$H2−11 has non-adjacent carbon centers on the rim. It is derived by degradation of meta-C$_2$B$_{10}$H$_{12}$. 2,9-C$_2$B$_9$H2−11 has only one carbon center on the rim. It is derived by degradation of para-C$_2$B$_{10}$H$_{12}$.

## Coordination compounds

A variety of complexes - a subset of metallaborane - are known with one or two dicarbollide ligands. An example of a 1:1 complex is [Mn(CO)$_3$(η$^5$-7,8-C$_2$B$_9$H$_{11}$)]$^−$.
Most heavily studied are complexes with two dicarbollide ligands, especially sandwich complexes. Thus, these are prepared by salt metathesis reactions, as illustrated by the synthesis of the ferrocene analogue:
    2 Na$_2$C$_2$B$_8$H$_{11}$ + FeCl$_2$ → Na$_2$[Fe(C$_2$B$_8$H$_{11}$)$_2$] + 2 NaCl
These bisdicarbollide dianions are often readily oxidized. Fe(III), Co(III), Ni(III), and Ni(IV) derivatives are known. In some cases, the oxidation induces rearrangement of the C$_2$B$_9$ cage to give complexes where the carbon centers are nonadjacent.

## Precursor to other carboranes

Diprotonation of [C$_2$B$_9$H$_{11}$]$^{2−}$ gives the neutral carborane C$_2$B$_9$H$_{13}$. Pyrolysis of this nido cluster gives closo-C$_2$B$_9$H$_{11}$. Chromate-oxidation of [C$_2$B$_9$H$_{12}$]$^−$ results in deboronation, giving the C$_2$B$_7$H$_{13}$. This carborane features two CH$_2$ vertices.

## Homogeneous catalysis

The clam-shell dicarbollide complex (Cp*)(C$_2$B$_9$H$_{11}$)ZrCH$_3$ catalyzes alkene polymerization.
# Crazy Kutumba

Crazy Kutumba (transl. Crazy family) is a 2010 Kannada comedy film directed by B. Ramamurthy and produced by Ravi Joshi for Luv Kush Productions banner. The story is a remake of Marathi film De Dhakka (2008) which was inspired from the Hollywood film, Little Miss Sunshine (2006).
The film stars Ramesh Aravind and Ananth Nag with Sanathini, Dhanya Rao, Jai Jagadish, Bank Janardhan and other theater artistes from North Karnataka region playing supporting roles.

## Cast

* Ramesh Aravind as Shankar Patil
* Ananth Nag as Mallanna
* Sanathini as Sumathi
* Chindodi Veershankar
* M. S. Umesh
* Rajinikanth
* Jai Jagadish
* Karibasavaiah
* Bank Janardhan
* G. Bharathkumar
* Baby Dhanya Rao as Gowri
* Shanoor Sana

## Plot

A family travels from a village to Bangalore, as one of its members is to participate in a dance contest. En route, the conflicts and travails of the family come to the fore in a humorous manner.

## Soundtrack

The music was composed by Ricky Kej for Junglee music company. One song "Amma Naanu" is composed by Mysore Ananthaswamy. The soundtrack includes popular folk poems written by acclaimed poets such as Kuvempu and K. S. Narasimhaswamy.

## Reception
### Critical response

Shruti Indira Lakshminarayana of Rediff.com scored the film at 3 out of 5 stars and says "As the characters are from Belgaum, they speak Kannada in the North Karnataka style that too very convincingly. Coming to humour, it is the scenes between Anath Nag and Ramesh that mostly invite laughter. The comedian in Rajinikanth (who plays kleptomaniac) impresses only at a few places. Also the film could have done without Sundari's character. A critic from The New Indian Express wrote "Veteran actor Anant Nag shines in the role of a drunkard father. Well-known comedians Umesh and Karibasavayya have played their parts with ease. The newcomers Sanathini, Natana Rajanikanth, who plays a kleptomaniac, Veera Shankar, Vijayakumar and child artist Dhanya really impress and surely can be groomed further for future roles". A critic from Deccan Herald wrote "Ramesh as the sixth-pass genius, husband, disgruntled son and doting father is good. His attempt at learning a different dialect is praiseworthy. Anant Nag, the grizzled, liquor guzzling patriarch caresses each word lovingly. Rajnikant and Vijaykumar provide most of the lighter moments in the film. Baby Nityashree’s innocent look blends in" A critic from Bangalore Mirror wrote "The dialect is from north Karnataka but it has been kept simple enough for comprehension. The comedy, except, for scenes involving Rajinikanth, is subdued. Thankfully Ricky Kej’s music is not loud and the songs blend with the film. Crazy Kutumba is a film parents would want to take their children to".
# Zamboanga Regional Medical Center

The Zamboanga Regional Medical Center (ZRMC), formerly known as the Mindanao Central Sanitarium, is a retained hospital under the Department of Health of the Republic of the Philippines. Established in 1930, it serves a dual function: as a sanitarium catering to Hansen’s Disease patients across Mindanao and as a general hospital serving Region IX.
In 2019, Republic Act No. 11325 was enacted, upgrading the Mindanao Central Sanitarium in Pasobolong, Zamboanga City, into a tertiary-level hospital. This legislation increased its authorized bed capacity for general care services from 50 to 200 beds and mandated the enhancement of its facilities, healthcare services, and human resources.
On January 3, 2025, Republic Act No. 12117 was enacted, officially renaming the Mindanao Central Sanitarium to the Zamboanga Regional Medical Center.
Today, ZRMC continues its commitment to providing comprehensive healthcare services to the people of Region IX and specialized care for Hansen’s Disease patients throughout Mindanao.
# XHHS-FM

XHHS-FM/XEHS-AM is a radio station on 90.9 FM and 540 AM in Los Mochis, Sinaloa, Mexico. It is owned by Radio Sistema del Noroeste and carries the La Mejor Regional Mexican format from MVS Radio.

## History

XEHS-AM 1280 received its concession on November 16, 1957. The 250-watt station was owned by Benito L. Juárez, and in the 1960s, Juárez sold XEHS to Manuel Ceferino Pérez Alvarado. Control was soon after consolidated in a corporation. In the 1990s, XEHS moved to 540 kHz, enabling a daytime power increase to 5,000 watts and a nighttime bump to 2,500 watts. XHHS-FM was approved in 2010, and in 2015, XHHS-FM was authorized to increase power from 4 to 25 kW.
XEHS-AM remains on the air in a continuity obligation, to serve 27,552 people in its coverage area unserved by any other broadcast service.
# Choi Heong Yuen Bakery

Choi Heong Yuen Bakery (咀香園餅家) is the name of two independently-operated bakeries in Macau and Hong Kong. Founded in Macau 1935, the bakery has since become one of the three major bakeries known locally for almond cookies—the other two being Koi Kei and Yeng Kee. A branch opened in Hong Kong in 1961, which later became independent and centred in a trademark dispute with the Macau store.

## History
### History

Choi Heong Yuen Bakery was founded in Macau in 1935 by Wong Kee-sin, who opened its first store on Travessa do Auto Novo in Macau. The bakery initially targeted travellers boarding and disembarking nearby piers. Wong subsequently opened another store on King's Road in Hong Kong in 1961, which was later inherited by his daughter, Wong Siu-ji. Following the Hong Kong store's independent operations, it became known into English as the Chui Heung Yuen Bakery. The bakeries, along with its two rivals in Macau—the Koi Kei and Yeng Kee bakeries—have been reportedly noted for their almond cookies, a type of biscuit now reportedly considered as a popular souvenir in Macau.
Following the passing of the elder Wong, the store was handed over to his nephew, Wong Wing-cheung in the 1960s, before being further passed down in 1993 to the third generation Wong Joek-lai. In 1997, the Macanese bakery began exporting its cookies as a result of poor financial situation of the time, and revamped its stores to consolidate its brand image. In early 2000, the Wong Siu-ji-led Hong Kong bakery followed a similar export strategy, but focusing on the Taiwanese market.

### Mainland China operations

Written in Chinese, the bakery shares the same characters as the unrelated Zhongshan-based Ju Xiang Yuan Bakery that was founded in 1918. To avoid trademark disputes, the Macanese entity of Choi Heong Yuen operates as the 'October Fifth bakery' in the People's Republic of China.

## Trademark disputes between the Hong Kong and Macau bakeries

In August 2007, the Hong Kong bakery's Wong Siu-li filed a trademark complaint with the Hong Kong High Court, alleging that her nephew, who operated Choi Heong Yuen in Macau, violated her Hong Kong trademark rights for “Chui Heung" and “Chui Heung Yuen" when the Macanese bakery participated in the Hong Kong Food Expo (at which the Hong Kong bakery did not participate). A litigation was initiated and the judge issued a temporary injunction order to prevent the nephew from participating in the Food Expo to promote Macau's Choi Heong Yuen.
# Southern Branch Elizabeth River

36°48′34″N 76°17′24″W﻿ / ﻿36.80944°N 76.29000°W﻿ / 36.80944; -76.29000
The Southern Branch Elizabeth River is a 14.5-mile-long (23.3 km), primarily tidal river in the U.S. state of Virginia. It flows from south to north through the city of Chesapeake and forms the boundary between the cities of Portsmouth and Chesapeake for its northernmost 3 miles (5 km). It is a tributary of the Elizabeth River, connecting to the harbor of Hampton Roads to the north. It is part of the Intracoastal Waterway of the Atlantic coast of the United States, connecting by it to the North Landing River, which flows into North Carolina.
# Suryakaanti

Suryakanthi (transl. Sunflower) is a 2010 Indian Kannada language film directed by K.M. Chaitanya and starring Chetan Kumar, Regina Cassandra, Nassar. The music is scored by Illayaraja.

## Premise

The film is a story of an international assassin played by Chetan.

## Cast

* Chetan Kumar as Rohith / Surya
* Regina Cassandra as Kaanti
* Nassar as Malanna Bahdur
* Ganesh Yadav as Stalin
* Ramakrishna as Saheba
* Kishori Ballal
* Sangeetha Gopal (Cameo)

## Soundtrack

All music is composed by Ilaiyaraaja

## Reception
### Critical response

R G Vijayasarathy of Rediff.com scored the film at 2.5 out of 5 stars and says "As mentioned earlier, H C Venu's outdoor images are visually strong. Ilayaraja is very good in creating the background score. His two song compositions Edheya Baagilu Thattadhe and Mouna Neenu have raised above the bar of excellence. Chaithanya's Suryakanthi is worth a watch for Ilayaraja's work and superb outdoor shoot". B S Srivani from Deccan Herald wrote "So are Chetan and Regina. Dialogues sometimes tend to be stilted though... Swaying with gentle twists and turns, "Suryakaanti" allows little time for emotions to register. But this may indeed indicate a future when viewer intelligence finally gets its due. For now, "Suryakaanti" is an entertainer foremost and on that count, is "bhar-poor" 'paisa vasool' film". A critic from Bangalore Mirror wrote "Chetan's acting gets better by the day and Regina too has done a decent job. Ganesh Yadav as Stalin is brilliant in his role. The music is just about okay. The cinematography is commendable. All in all, the direction by K M Chaitanya has worked wonders this time too".
# Grandma pizza

Grandma pizza is a distinct thin, rectangular style of pizza attributed to Long Island, New York. Typically topped with cheese and tomato sauce, it is reminiscent of pizzas baked at home by Italian housewives who lacked a pizza oven. The pizza is similar to Sicilian pizza, but usually with a thinner crust.
A grandma pizza is typically rectangular, with the cheese placed before the tomato sauce, baked in a sheet pan in a home oven, and cut into small squares.

## History

The origins of grandma pizza can be traced back to the early 20th century when immigrants from southern Italy developed a pizza that would be made at home with simple ingredients with standard American cooking equipment (including a standard kitchen oven and sheet pan). The pie's humble roots left it dubbed "grandma pizza", since it was mainly made by first-generation immigrants in their own kitchens.
Despite having existed for generations, the term "grandma pizza" was little known outside of Long Island. Around 1994, Umberto Corteo introduced "Sicilian Grandma pizza" at his Long Island pizzerias; unlike typical thick-crusted Sicilian pizza, his Grandma Sicilian pizza had a thinner crust, though not as thin as Neapolitan. Within a few years, "Grandma pizza" began being advertised by other Long Island restaurants.
By the late 2000s and early 2010s, the name caught on and numerous pizzerias began to offer the pie. Rather than being derogatory, the name indicates both respect for tradition and the simple rustic pizza eaten at home growing up.
# Ron George Round Barn

Ron George Round Barn is a round barn northeast of the U.S. village of Romeoville, Illinois. It was originally constructed for Frank Eaton c. 1912–13 in Bolingbrook, Illinois.

## History

Wilbur J. Fraser, who designed most of the round barns in Illinois, encouraged his brother-in-law Frank Eaton to construct such a barn. Eaton was living in the nearby settlement of Plainfield at the time. The $1,500 building served nine horse stalls and may have served cows as well. It was named after Eaton's young grandson Ron George. Ownership of the barn was later transferred to George, who maintained the property until the 1970s.
George Round Barn was listed on the National Register of Historic Places by the National Park Service in December 1982, four months after four other round barns joined the Register as part of the Multiple Property Submission (MPS), Round Barns in Illinois. In 1998, in an effort to prevent its demolition, the barn was dismantled and moved elsewhere in Bolingbrook. It was finally reconstructed in 2007.

## Architecture

The round barn in 60 feet (18 m) in diameter and sits on a poured concrete foundation. The single-hip roof has wooden shingles. The central silo is elliptical and is accessed from the loft. A wooden cupola is found 60 feet (18 m) above the ground. The main entrance was originally on the northwest side of the barn. The original building materials are still in use. At its original location, the barn abutted two large sheds, one to the east and one from the south. The round design was believed to be more efficient than the typical rectangular barn.
# Eugenio Sena

Eugenio Sena (born 19 December 1991) is an Italian professional football manager.

## Early life

Sena was born in 1991 in Ragusa, Sicily, south of Italy. After completing his high school education, he moved to northern Italy to pursue a degree in Sport Science and Exercise at University of Pavia, near Milan. Sena furthered his studies by obtaining a Master’s degree in Football Performance at Università Cattolica del Sacro Cuore Milano.
Sena has held a range of coaching roles with clubs across multiple countries, including: Italy, Hungary, Australia, China, Russia, England, Montenegro, Greece, Saudi Arabia, Georgia, Cyprus and Scotland.

## Academy career

While at university, Sena interned at the Football Club Internazionale Milano center.
In 2014, Sena moved abroad to Hungary, where he joined the Nemzeti Bajnokság I (Premier League) side club Debreceni VSC.There, he worked with youth teams and assisted the club’s scouting department.
In 2015, Sena relocated to Australia and took up coaching roles at Fraser Park FC and Dunbar Rovers FC in Sydney. At Dunbar Rovers, he served as Academy Manager.
He then joined Juventus Football Club where he held roles as a technical coordinator, chief scout, head of football, and lead coach. He worked in countries such as China, Russia, Serbia, Switzerland, and Georgia.
In 2017, Sena returned to Italy and joined Serie A side AC ChievoVerona focusing on youth team development.
In 2018, Sena moved to England to coach Football League Two side Yeovil There, he worked as academy coach and Head of Analysis.

## First team career

The following year, he moved to Montenegro, where he joined FK Obilić as Assistant Manager.
In 2021, Sena’s career took him to Saudi Arabia, where he became Assistant Manager at Saudi First Division League side Al Faisaly, under manager Paolo Tramezzani (former Tottenham Hotspur Football Club and Football Club Internazionale Milano player). During his tenure, Al Faisaly was playing the Saudi Super Cup and AFC Champions League Elite. Sena also briefly served as the club's caretaker manager during this time..
In 2022, Sena took on his first managerial role when he was appointed as the first-team manager of AEP Kozani a club in Greece’s third division.
Sena’s next major move came in 2023 when he joined Scottish Premiership side Livingston. as Assistant Coach and Head of Analysis.
After one season with Livingston, Sena agreed with manager David Martindale to accept an offer as the first-team manager of Podosfairikos Omilos Xylotymbou 2006 in Cyprus' Second League.

## Other work

Beyond coaching, Sena has appeared as a guest interviewer and writer, providing expert commentary on the game. His work has been featured in publications such as La Gazzetta dello Sport. and Tuttosport
# El Cotillo

El Cotillo is a coastal town in the municipality of la Oliva, located in the northern part of the island of Fuerteventura in the Province of Las Palmas, Canary Islands, Spain. It has a population of 1.680 residents (2022).

## History

The history of el Cotillo dates back to the 17th century, when it was known as a fishing settlement based in the disembarkation area called “Puerto del Roque”. The Island Council of Fuerteventura established in that same area the so-called “Casa del Puerto del Tostón”, which became one of the ports of arrival of the trade route between Madeira and Fuerteventura. It wasn't until mid-20th century before it was generally known as “el Cotillo”. The village's port lost its commercial importance over time, and the sparsely populated town relied completely on fishery for their primary income. During the eighties, tourism became an economic alternative to fishery, and the population grew considerably.

## Places of interest

El Cotillo is surrounded by some of Europe's best beaches, including a range of bays with crystal clear waters and fine sand beaches, known as “la Concha” and “los Lagos”. In 2016, local newspaper La Provincia - Diario de Las Palmas reported that el Cotillo's beaches ranked among the ten best ones in Europe, as voted for by users of the online travel site TripAdvisor.
Torre del Tostón is the village's most prominent monument. It was built in 1700 to defend the coast against pirates who operated from France, England and North Africa (Barbary pirates). Torre del Tostón was recognized as “Bien de Interés Cultural” in 1949.
# Spirit Mound Creek

Spirit Mound Creek is a tributary of the Vermillion River, located in southeastern Clay County, South Dakota. It passes through the Spirit Mound Historic Prairie.
# Grodna (Blake)

In the mythological writings of William Blake, Grodna is the third son of Urizen.
In Chapter VIII of The Book of Urizen his birth is described:
    Grodna rent the deep earth, howling
    Amaz'd; his heavens immense cracks
    Like the ground parched with heat,[...]
His identification is with the classical element Earth, in the alignment of Urizen's four sons.
# Iwai Rebellion

The Iwai Rebellion (磐井の乱, Iwai no Ran) was a rebellion against the Yamato court that took place in Tsukushi Province, Japan (now nearby Ogōri city in Fukuoka Prefecture) in 527 AD. The rebellion was named after its leader, Iwai, who is believed by historians to have been a powerful governor of Tsukushi. The rebellion was quelled by the Yamato court, and played an important part in the consolidation of early Japan. The main record of the rebellion can be found in the Nihon Shoki, although it is also mentioned in Kojiki and other historical sources.

## Background

The Yamato Kingdom was formed in the central areas of Honshu in the late 3rd or early 4th century, and by 350 this state had extended its rule to the western part of Honshu and the northern part of Kyushu. In 366, Yamato invaded the Korean peninsula, which at the time was divided into three kingdoms: Goguryeo, Paekje, and Silla. On several occasions (391 and 404), Japanese troops as allies of the Paekje kingdom invaded Korea and fought against the Silla and Goguryeo kingdoms.

## Rebellion

At the beginning of the 6th century, the rising Silla kingdom began to threaten Japan's allies in Korea. At the same time, the kingdom of Baekje, a Japanese ally, was attacked from two sides by the kingdoms of Silla and Goguryeo, and sent 513 Confucian scholars to Yamato with a request for help. Before Yamato could send aid to Mimana and Baekje, Iwai, the governor of the Tsukushi region (semi-autonomous Kumaso region in northern Kyushu), made a treacherous alliance with the Silla kingdom, thus blocking the Yamato kingdom's attempts to send aid to Korea. This was the first recorded rebellion against the ruling imperial dynasty. Mononobe no Arakabi, the leader of a warrior clan, was sent to quell the rebellion. In 528, Iwai was overthrown and executed, and the previous autonomy of his area ended with the establishment of Daizaifu Fortress, a government military stronghold on the island of Kyushu.

## Consequences

Power in northern Kyushu passed into the hands of the Otomo clan, but Gaya fell to the Silla kingdom in 562.
# Dub Lémna ingen Tighearnáin

Dub Lemna ingen Tighearnáin, Queen of Ireland, died 943.

## Background

Dub Lemna was a daughter of Tighearnáin mac Seallachan, King of Breifne (died c. 888). Her brother, Ruarc mac Tighearnáin (fl. c. 893), was the eponym and ancestor of the clan Ó Ruairc, Kings of Breifne.

## Marriage and children

Dub Lemna married Donnchad Donn of the Clann Cholmáin, who was King of Mide and High King of Ireland from 919 till his death in 944. She was his third wife. Her children by Donnchad are uncertain but they do not include Oengus mac Donnchada, who appears to have been a son of Cainnech ingen Canannán of Ailech, who died in 929.
This leaves sons Conn (died 944) and Domnall Donn (died 952), daughters Flann ingen Donnchad Donn (died 940) and Óebfhinn ingen Donnchad Donn.

## Annalistic reference

The Chronicon Scotorum, sub anno 943, state that "Dub Léna daughter of Tigernán, king of Bréifne, wife of the king of Temair, i.e. Donnchad son of Flann, dies.."