OpenLLM-France/wikimedia huggingface dataset:
# Nitrosyl bromide

Nitrosyl bromide is the chemical compound with the chemical formula NOBr. It is a red gas with a condensation point just below room temperature. It reacts with water.
Nitrosyl bromide can be formed by the reversible reaction of nitric oxide with bromine. This reaction is of interest as it is one of very few third-order homogeneous gas reactions. NOBr is prone to photodissociation at standard pressure and temperature.
    2 NO + Br$_2$ ⇌ 2 NOBr
Another way to make it is by way of nitrogen dioxide reacting with potassium bromide.
    2NO$_2$ + KBr → BrNO + KNO$_3$

## Dissociation kinetics

The bond breaking of the chemical can be done with photolysis using a light to separate the molecules that are present. Another to separate nitrosyl bromide into NO and Br or Br2 is by having excess of NO which then the experiment will follow first order kinetics. This reverse rate constant was calculated to be kr = 2.29 ± 0.33 x 10-21 cm3 /molecules
With excess Br2 plus NO the reaction follows third order kinetics.
Br2 + 2NO ↔ 2BrNO
Some of the previous experiments that determined reaction rates were also done by Histatsune and Zafonte, Hippler, and Godfrey. Histatsune and Zafonte determined the forward and reverse reaction rate constants. Hippler studied the recombination of Br atoms after photoylsis of less than 0.3 torr of Br2 at room temperate in the range of 1 - 100 atm. He also studied the 2 recombination of Br and NO in the presence of helium. Godfrey examined the kinetics of BrNO formation and destruction using time resolved photolysis techniques. He also included the effects of the loss of Br2 to internal surfaces of the cell in calculations of the reaction rate constants. The reaction rates were determined to be between the range of 1.32 ± 0.14 to 1.68 ± 0.11 x 10-38 cm6 /molecule2 -s for kf and from 2.09 ± 0.55 to 3.71 x 10-21 cm3 /molecule-s for kr.
There was a rate constant found of kf = 1.56 ± 0.20 x 10-38 cm6 /molecule2 - s at 293 ± 1 K
The third order reaction is the best reaction to show the formation of nitrosyl bromide. The third order reaction is rare to see with bond breaking reactions between stable molecules but there have been no experiments to prove that this experiment does not have any intermediate steps, but it is suspected that there is two steps.

## Safety Precautions

Nitrosyl bromide photodissociates to toxic chemicals (bromine and nitric oxide). The chemical or its decomposition products should not get into contact with skin or eyes. Breathing or wafting any of these chemicals towards oneself can endanger health.

## Physical characteristics

Nitrosyl bromide is a red gas at room temperate.
# Red Sulphur Springs, West Virginia

Red Sulphur Springs is an unincorporated community in Monroe County, West Virginia, United States. It once boasted the Red Sulphur Springs Hotel. Red Sulphur Springs is located on West Virginia Route 12, close to Indian Creek.

## History

Red Sulphur Springs was known as a watering place from 1800. The springs were purchased by Dr. William Burke of Richmond in 1830, who built a hotel to accommodate up to 350 guests. Among the notable guests to the springs were Chief Justice of the Supreme Court Roger Taney and Francis Scott Key. The resort was disrupted by the Civil War. Ownership passed to Levi Morton, who had been Vice-President of the United States under Benjamin Harrison. He expanded the hotel, but the resort eventually failed. It was sold during World War I and divided into parcels, and the buildings demolished.

## Notable people

* Cornelia Storrs Adair, educator, first classroom teacher to serve as president of the National Education Association
* Christopher Payne, U.S. consul to St. Thomas
# S/2018 J 3

S/2018 J 3 is a small outer natural satellite of Jupiter discovered by Scott S. Sheppard on 12 May 2018, using the 6.5-meter Magellan-Baade Telescope at Las Campanas Observatory, Chile. It was announced by the Minor Planet Center on 19 January 2023, after observations were collected over a long enough time span to confirm the satellite's orbit.
S/2018 J 3 is part of the Carme group, a tight cluster of retrograde irregular moons of Jupiter that follow similar orbits to Carme at semi-major axes between 22–24 million km (14–15 million mi), orbital eccentricities between 0.2–0.3, and inclinations between 163–166°. It has a diameter of about 1 km (0.62 mi) for an absolute magnitude of 17.3, making it one of Jupiter's smallest known moons.
# Bourbonnais Grey

The Bourbonnais Grey is a rare breed rabbit originally from France. It is a medium, exclusively slate-blue breed reaching around 4–5 kg (11 lb).
# Schoenus pseudoloreus

Schoenus pseudoloreus is a species of sedge endemic to the Western Cape and Northern Cape provinces of South Africa. Its range also reaches the western border of Eastern Cape Province.

## Diagnostic characters

The key diagnostic characters of S. pseudoloreus are its narrowly contracted flowering heads with bracts having small ear-like membranaceous extensions that cover the base of each spike. The spikelets of S. pseudoloreus often have firm glumes, as in Schoenus compar and Schoenus arenicola. The leaves of S. pseudoloreus are usually terete (round) and the leaf sheaths are red in colour, except in northern variants that tend to be overall lighter in colour. In addition, the leaf sheaths and part of the flowering stems are often sticky.
Similar to other sedges, plants in this group are very difficult to identify. It appears that part of this problem is caused by the tendency of the southern African Schoenus to form hybrids with each other. Preliminary evidence suggests that there might be hybridization in S. pseudoloreus.
* Base of culms
* Flowering head
* Flowering spikes
* Spikelet
* Nutlets

## Taxonomy

Schoenus pseudoloreus is a species in family Cyperaceae, tribe Schoeneae. Other notable genera in tribe Schoeneae include Lepidosperma, Oreobolus, Costularia, Tetraria and Gahnia. The most closely related species to S. pseudoloreus are other southern African Schoenus species, specifically, species in the Schoenus compar – Schoenus pictus group.
Southern African Schoenus were once classified as Tetraria; however, based on molecular and morphological differences, we now know that the two groups are evolutionary distinct. To ensure that this group of sedges is monophyletic (i.e. the genus only has closely related species), several species of Epischoenus and the southern African Tetraria were transferred into Schoenus. In the field, the southern African Schoenus can be distinguished from Tetraria species by their lack of stem leaves and the absence of reticulate sheaths at the bases of the flowering stems.

## Distribution and ecology

The known distribution of S. pseudoloreus ranges as far north as the Kamiesberg in the Northern Cape Province and near Willowmore in the east. It is a species usually found on dry mountain slopes with varying substrates.

## Images

* Growth form
* Flowering head
* Flowering head
* Flowering head
* Nutlet
# Christina Sawaya

Christina Sawaya (Arabic: كريستينا صوايا; born 16 August 1981) is a Lebanese singer, actress and television host who won the Miss International 2002 pageant.

## Career

She started her career as master of ceremony for big events. She participated in a series of pageants between 1998 and 2002 in which she became the winner of Miss Universities Lebanon in 1998, and was chosen as "Top Model of Lebanon 1999".
In 2001, Sawaya competed against 19 women to become Miss Lebanon 2001 and 2002, where she won and became eligible to compete in the Miss Universe, Miss World and Miss International pageants. She then represented her country in the Miss World 2001 pageant, wherein she was unplaced. But at the Miss Universe 2002 Pageant, Sawaya decided to drop out of the competition due to the raid in Palestine.
She won the Miss International 2002 contest in Tokyo, Japan on September 30, 2002 which had 52 contestants.
She also became the first Miss International winner from Middle Eastern descent. In the same year, Miss World 2002 was Azra Akın from Turkey and the original winner of Miss Earth 2002 was Džejla Glavović from Bosnia and Herzegovina, which are all hailed from dominant Muslim countries.

## Personal life

Sawaya is a conservative Catholic Christian that comes from Lebanon, the only Arab country where the president is Christian by the constitution.
On 15 November 2003, Sawaya married Tony Baroud in Beirut and they had two children. The couple divorced in 2015.
# Oerlikon Balzers

Oerlikon Balzers is part of the OC Oerlikon group, a Swiss technology conglomerate, and a supplier of PVD coatings. The OC Oerlikon group consists of companies in the following divisions: Polymer Processing Solutions and Surface Solutions. The coatings produced by Oerlikon Balzers aim to improve the performance and service life of, for example, metallic precision components by reducing friction and supplying additional hardness.

## History

With the support of Prince Franz Josef II and Swiss industrialist Emil Georg Bührle, Professor Max Auwärter founded Gerätebauanstalt Balzers. The objective was to make the then largely unknown and little-researched vacuum thin film technology usable on an industrial scale. Since no systems and equipment for the production of thin-film coatings were available at the time, the company developed and produced them in-house. The first popular applications were sun protection and anti-reflection coatings for ophthalmic lenses, anti-reflection coatings for camera lenses, optical filters and reflectors and thin films for electronic applications.
In 1976, the company became a member of the Oerlikon Group, then Oerlikon-Bührle Holding AG. In 1983, the first coating center was opened outside of Liechtenstein in Italy. One year later, the step to America was taken, and in 1987, the first center in the Asian region took on its operation in Japan.
In June 2014, the OC Oerlikon Group acquired Sulzer Metco from the Swiss Sulzer AG, which has since then been operating under the name Oerlikon Metco. The thin film business of Oerlikon Metco is integrated into Oerlikon Balzers since 2015. Oerlikon Balzers, Oerlikon Metco and Oerlikon AM form the Surface Solutions division of the Oerlikon Group.
Oerlikon Balzers operates over 110 coating centres in more than 35 countries.
The headquarters of Oerlikon Balzers is located in Balzers, Liechtenstein, where over 530 people are employed.

## Products

The company offers contract coating services in Europe, the Americas, and Asia; PVD and PACVD-based coating; heat treatment; and coating equipment. Its products and services are used in various applications in various industries They also serve the automotive and transportation, aerospace, medical, food and packaging, energy, consumer goods and engineering sectors worldwide.
# Cetaphil

Cetaphil /ˈsiːtəfɪl/ or /ˈsɛtəfɪl/ is a line of skin care products from the Swiss company Galderma, including cleansers, bar soap, cream, lotion, and moisturizers. It was developed in 1947 in Texas and is sold at over seventy grocery stores and pharmacies across the United States, Canada, India, and Nepal. Cetaphil products are also available in pharmacies in Australia, Hong Kong, South Korea, Indonesia, the Philippines, South Africa, Singapore, and some European, Latin American and Caribbean countries.
Prior to a change in formulation, Cetaphil cleanser ingredients were water, cetyl alcohol, propylene glycol, sodium lauryl sulfate, stearyl alcohol, methylparaben, propylparaben, butylparaben. However, in 2021 Cetaphil changed its formula, adding several new ingredients including niacinimide, panthenol, and glycerin.
# Casa Correia de Matos

The Correia de Matos House (Portuguese: Casa Correia de Matos) is a 20th-century house in Guimarães, Portugal.

## Description

Rectangular in plan and uniform in volume, the house features a hipped roof. The facades are two (front) and three (back and sides) stories high, with the lower level clad in granite masonry and the upper levels plastered and painted white, except for the central section of the main facade, which is also clad in granite. The facades are characterized by a base, Tuscan pilaster corners, and a frieze and cornice at the top. The main facade, facing west, is two stories high, divided by a frieze and granite, and topped with a balustraded parapet featuring acroteria inscribed with the initials "CM" for Correia Matos, the family name, and crowned by granite urns.
At the center of the main facade is a round-arched portal with a prominent frame and keystone, protected by double wooden doors with padded panels and a transom window with metal elements painted brown. Above the portal is a balcony window with a straight lintel, topped by a curved pediment supported by three corbels, with a stone basin resting on two corbels, and a wrought iron guardrail. Flanking the portal are two flat-arched windows with granite frames and central keystones; these are topped by two more balcony windows with straight lintels and central keystones, surmounted by a cornice resting on two central corbels and a small wrought iron guardrail.
The side facades are three stories high, divided by a granite frieze, and feature several rectangular windows with differentiated granite frames. The house is surrounded by a small grassy field, apart from the front facade, that faces the Afonso Henriques Avenue.

## History
### Background

The Casa Correia de Matos was constructed on Afonso Henriques Avenue, a road established in the 1890s to connect the city to the train station, which had opened in 1884. When the house's construction started in 1902, the avenue had only one other building, the Vila Flor Palace, making it a prime location for new residential and industrial developments. This lack of surrounding structures allowed architect Marques da Silva to use the house as an experimental project, blending various architectural styles such as Beaux-Arts, Italianate, and Neoclassical.

### Construction and aftermath

The house was built in 1902 on the northern part of Afonso Henriques Avenue. At that time, locals referred to it as Rua Nova (New Street) to distinguish it from the nearby D. João IV Avenue, a name adopted due to its construction just a few years earlier. The house was built by architect Marques da Silva for the Correia de Matos family, and it was his first project in Guimarães, as he later designing other local landmarks such as the Martins Sarmento Society Building, the city market and the Penha Sanctuary.
# Chalkida F.C.

Athletic Club Chalkis (Greek: Αθλητικός Όμιλος Χαλκίς), also known as A.C. Chalkida, is an association football club based in Chalkida, Greece. The club was founded in 1967 upon the merger of Olympiakos Chalkida and Evrypos Chalkida. Its colours are black and blue and its symbol is the nymph Arethusa.
Their greatest honour was winning the Beta Ethniki in 1968 and playing in the 1968–69 Alpha Ethniki. They currently play in the Group 3 of Gamma Ethniki.

## History
### Before the merger

A.C. Chalkis was founded in 1967 after a merger between the biggest clubs in the city, Olympiakos Chalkida and Evrypos, who were both competing in the Greek Second Division at the time, with Olympiakos finishing 4th and Evrypos 9th.
Due to a law by the regime of the Colonels which ruled Greece since April 1967, athletic clubs that were based in the same city were forced to merge with each other. As a result, Olympiakos Chalkida and Evrypos were merged in summer 1967 and the resulting club was named A.C. Chalkis in order to represent the city of Chalkis as a whole.

### A.C. Chalkis

In the following 1967–68 season and first one after the merger, Chalkida finished 1st in Beta Ethniki's Northern Group and was promoted to the Alpha Ethniki for the first time. However, they were immediately relegated after one season, as they finished 17th in the 1968–69 Alpha Ethniki, second last only to AEL Limassol.
Until 1989 the team competed in the Beta and Gamma Ethniki championships, without repeating the success of their first season, although they won 2 Gamma Ethniki championships in 1977 and 1987. From 1989 to 1996 the team was competing in the lower Gamma and Delta Ethniki championships, and from 1996 to 2003 only in the Delta Ethniki.

### Decline

In 2003 A.C. Chalkis returned to the national championships after seven years, participating in the 2003–04 season of Gamma Ethniki and finishing 11th. Although having finished in a safe mid-table position, the team was in a financial turmoil; the entire squad was released and negotiations with potential investors were unsuccessful. After a planned merger with local club Doxa Prokopiou was not implemented, Chalkida decided to pull out of every championship, remain inactive for a year and re-appear at the local Evia Football Club Association leagues for the 2005–06 season.
A.C. Chalkis finished 1st in the A1 Division of Evia and was promoted to the Delta Ethniki in 2010. The club also won the Evia Amateur Cup six times and finished as runners-up once, with their last victory being in 2012.

## Achievements

* Beta Ethniki
** Winners (1): 1967–68
* Gamma Ethniki
** Winners (1): 1986–87
* Delta Ethniki
** Winners (3): 1991–92, 1993–94, 2002–03
* Evia FCA Championship
** Winners (4): 1976–77, 2009–10, 2014–15, 2021–22
* Evia FCB Championship
** Winners (1): 2007–08
* Evia FCA Cup
** Winners (7): 1994, 1997, 1998, 1999, 2011, 2012, 2018
** Runners-up (1): 2000
# Keith Rayner

Keith Rayner may refer to:
* Keith Rayner (bishop) (1929–2025), Australian Anglican bishop
* Keith Rayner (psychologist) (1943–2015), American cognitive psychologist
# Michael S. Davison Jr.

Michael Shannon Davison Jr. (born 19 November 1941) is a retired United States Army Lieutenant general.

## Early life and education

Davison was born on 19 November 1941 in El Paso, Texas into a military family. His father Michael S. Davison was a United States Army four-star general who served as Commander in Chief, U.S. Army Europe/Commander, Central Army Group from 1971 to 1975. He graduated from the United States Military Academy in 1964.

## Military career

In October 1967 then Captain Davison took command of Company C, 5th Battalion, 7th Cavalry. During the Battle of Huế, from 8–25 February 1968 Davison's company was heavily engaged in combat as they attempted to sever the People's Army of Vietnam (PAVN) supply lines into the city of Huế.$^{:353}$ For his actions during the battle on 12 February, Davison was subsequently awarded the Silver Star.
From June 1994 to July 1997 Major general Davison served as commander of United States Army Security Assistance Command.
Davison retired from the Army in 2000.

## Personal

In the 2024 United States presidential election, Davison endorsed Kamala Harris.
# Henry Villar

Henry Villar (born May 24, 1987) is a right-handed former Major League Baseball pitcher.
Villar began his professional career in 2006 with the Dominican Summer Astros, going 1-1 with a 2.16 ERA in 13 games (seven starts). He spent 2007 with the DSL Astros as well, going 4-4 with a 2.45 ERA in 13 starts. In 2008, he pitched for the Greeneville Astros, going 3-6 with a 4.41 ERA in 13 starts. With the Lexington Legends in 2009, he was used primarily as a relief pitcher, going 3-4 with a 2.60 ERA in 43 games (three starts).
Villar made his major league debut with the Astros on September 10, 2010. He made eight appearances for the Astros in 2010, all as a relief pitcher.
# Brachyscome ciliaris

Brachyscome ciliaris, commonly known as variable daisy,is a flowering plant in the family Asteraceae it is a small, bushy, perennial herb with white or mauve daisy-like flowers. It grows in the Northern Territory and mainland states of Australia with the exception of South Australia.

## Description

Brachyscome ciliaris is an upright or ascending perennial herb to 45 cm (18 in) high with smooth, occasionally woolly or soft glandular hairs. The leaves may be linear, divided or deeply lobed, narrow at the base and sessile. The white or mauve flower heads 7–15 mm (0.28–0.59 in) in diameter, peduncle thread-like, bracts green, pointed, jagged and lance-shaped. Flowering may occur throughout the year and the fruit is an oblong to egg-shaped, flattened achene 1.5–2.5 mm (0.059–0.098 in) long and brown.

## Taxonomy and naming

This species was first collected by Jacques Labillardière and published in his 1806 Novae Hollandiae Plantarum Specimen under the name Bellis ciliaris. In 1832 Christian Friedrich Lessing transferred it into Brachyscome, and the name has been Brachyscome ciliaris ever since. Because it is such a variable species, specimens have often been referred to new species, and hence this species has many taxonomic synonyms, among them: Brachyscome drummondii Walp., Brachyscome ciliaris var. brachyglossa Gauba, Brachyscome dimorphocarpa G.L.R.Davis, Brachyscome billardierei Benth. and Brachyscome ciliaris var. lanuginosa (Steetz) Benth..The specific epithet (ciliaris) refers to the margins of the fruit.
Three varieties are recognised:
* Brachyscome ciliaris var. ciliaris
* Brachyscome ciliaris var. lanuginosa
* Brachyscome ciliaris var. subintegrifolia

## Distribution and habitat

Geographically speaking, it is very widely distributed, occurring in every Australian state. It is somewhat restricted in terms of habitat, however, favouring red earths and grey sands over limestone or clay, in disturbed areas and on the margins of salt pans.
# Luca Orlando

Luca Orlando (born 26 December 1990) is an Italian football player who plays for Serie D club Manfredonia.

## Club career

He made his Serie B debut for Salernitana in 2010.
# Southwest Regional Medical Center

Southwest Regional Medical Center was located at I-430 and I-30 in Little Rock, Arkansas, It closed on July 15, 2008.
On August 27, 2008, Baptist Health- Arkansas announced that it had acquired the facility. Though financial details were not disclosed, Baptist announced that it planned to relocate support and patient-care services to the Southwest Little Rock facility to accommodate more patients at its main campus.
# Christ the King Cathedral, Aba

The Christ the King Cathedral is a religious building in the Catholic Church that serves as the cathedral of Aba, a city with more than 500,000 inhabitants in Abia State in of Nigeria. The church is the seat of the Bishop of the Diocese of Aba in Nigeria. The first small church of Christ the King in Aba was built by Eugene Groetz in 1929. Before his death in 1948, however, Groetz recognized the need to build a larger church and it sent Akpo Jacob to Italy to study the European Churches.
In 1963 the nave was completed, and in subsequent years various improvements followed. In 1993 a hexagonal baptistery in the nave to the east was added, the sacristy was expanded in 2002, and the exterior was improved with gardens, trees and statues of St. Peter and St. Paul in the west and east of St. Ann. In December 2004, the cathedral was dedicated to Christ the King.
# Marinho Donizete

Mário Donizete Oliveira Ferreira, known as Marinho Donizete, (born July 31, 1980), is a Brazilian defender who currently plays for Sergipe.

## Honours
### Vila Nova

* Campeonato Goiano Série B: 2015
* Campeonato Brasileiro Série C: 2015