# Ukraine at the 2016 Summer Olympics

Ukraine competed at the 2016 Summer Olympics in Rio de Janeiro, Brazil, from 5 to 21 August 2016. This was the nation's sixth consecutive appearance at the Summer Olympics in the post-Soviet era.
Ukraine's medal tally was its lowest since independence, with only two gold and eleven total medals, a far cry from 9 gold and 23 total medals at the 1996 Summer Olympics and less than five gold and 19 medals overall at the 2012 Summer Olympics.

## Medalists

| Medal | Name | Sport | Event | Date |
| Gold | Oleg Verniaiev | Gymnastics | Men's parallel bars | 16 August |
| Gold | Iurii Cheban | Canoeing | Men's C-1 200 m | 18 August |
| Silver | Serhiy Kulish | Shooting | Men's 10 m air rifle | 8 August |
| Silver | Oleg Verniaiev | Gymnastics | Men's artistic individual all-around | 10 August |
| Silver | Olga Kharlan Alina Komashchuk Olena Kravatska Olena Voronina | Fencing | Women's team sabre | 13 August |
| Silver | Zhan Beleniuk | Wrestling | Men's Greco Roman 85 kg | 15 August |
| Silver | Pavlo Tymoshchenko | Modern pentathlon | Men's modern pentathlon | 20 August |
| Bronze | Olga Kharlan | Fencing | Women's sabre | 8 August |
| Bronze | Bohdan Bondarenko | Athletics | Men's high jump | 16 August |
| Bronze | Dmytro Ianchuk Taras Mishchuk | Canoeing | Men's C-2 1000 m | 20 August |
| Bronze | Hanna Rizatdinova | Gymnastics | Women's rhythmic individual all-around | 20 August |
Medals by sport :
| Sport | | | | Total |
| Gymnastics | 1 | 1 | 1 | 3 |
| Canoeing | 1 | 0 | 1 | 2 |
| Fencing | 0 | 1 | 1 | 2 |
| Modern pentathlon | 0 | 1 | 0 | 1 |
| Shooting | 0 | 1 | 0 | 1 |
| Wrestling | 0 | 1 | 0 | 1 |
| Athletics | 0 | 0 | 1 | 1 |
| Total | 2 | 5 | 4 | 11 |
Medals by date :
| Day | Date | | | | Total |
| Day 1 | 6 August | 0 | 0 | 0 | 0 |
| Day 2 | 7 August | 0 | 0 | 0 | 0 |
| Day 3 | 8 August | 0 | 1 | 1 | 2 |
| Day 4 | 9 August | 0 | 0 | 0 | 0 |
| Day 5 | 10 August | 0 | 1 | 0 | 1 |
| Day 6 | 11 August | 0 | 0 | 0 | 0 |
| Day 7 | 12 August | 0 | 0 | 0 | 0 |
| Day 8 | 13 August | 0 | 1 | 0 | 1 |
| Day 9 | 14 August | 0 | 0 | 0 | 0 |
| Day 10 | 15 August | 0 | 1 | 0 | 1 |
| Day 11 | 16 August | 1 | 0 | 1 | 2 |
| Day 12 | 17 August | 0 | 0 | 0 | 0 |
| Day 13 | 18 August | 1 | 0 | 0 | 1 |
| Day 14 | 19 August | 0 | 0 | 0 | 0 |
| Day 15 | 20 August | 0 | 1 | 2 | 3 |
| Day 16 | 21 August | 0 | 0 | 0 | 0 |
| Total | Total | 2 | 5 | 4 | 11 |

## Competitors

| Sport | Men | Women | Total |
| Archery | 1 | 3 | 4 |
| Athletics | 19 | 46 | 65 |
| Badminton | 1 | 1 | 2 |
| Boxing | 4 | 1 | 5 |
| Canoeing | 4 | 5 | 9 |
| Cycling | 3 | 4 | 7 |
| Diving | 3 | 4 | 7 |
| Equestrian | 4 | 1 | 5 |
| Fencing | 5 | 9 | 14 |
| Gymnastics | 5 | 8 | 13 |
| Judo | 4 | 3 | 7 |
| Modern pentathlon | 2 | 1 | 3 |
| Rowing | 4 | 4 | 8 |
| Sailing | 3 | 0 | 3 |
| Shooting | 6 | 2 | 8 |
| Swimming | 5 | 2 | 7 |
| Synchronized swimming | — | 9 | 9 |
| Table tennis | 1 | 1 | 2 |
| Tennis | 2 | 5 | 7 |
| Triathlon | 1 | 1 | 2 |
| Weightlifting | 4 | 4 | 8 |
| Wrestling | 6 | 5 | 11 |
| Total | 87 | 119 | 206 |

## Archery

One Ukrainian archer qualified each for the men's individual recurve by obtaining one of the eight Olympic places available from the 2015 World Archery Championships in Copenhagen, Denmark. Three Ukrainian archers qualified for the women's events by virtue of the nation's podium finish in the team recurve competition at the 2016 Archery World Cup meet in Antalya, Turkey.
| Athlete | Event | Ranking round | Ranking round | Round of 64 | Round of 32 | Round of 16 | Quarterfinals | Semifinals | Final / BM | Final / BM |
| Athlete | Event | Score | Seed | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Rank |
| Viktor Ruban | Men's individual | 663 | 25 | Purnama (INA) W 7–3 | Valladont (FRA) L 0–6 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Veronika Marchenko | Women's individual | 630 | 30 | Nurmsalu (EST) W 6–0 | Ki B-b (KOR) L 2–6 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Anastasia Pavlova | Women's individual | 630 | 29 | Saidiyeva (KAZ) W 6–0 | Tan Y-t (TPE) L 0–6 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Lidiia Sichenikova | Women's individual | 630 | 31 | Narimanidze (GEO) W 7–1 | Chang H-j (KOR) L 2–6 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Veronika Marchenko Anastasia Pavlova Lidiia Sichenikova | Women's team | 1890 | 8 | — | — | Japan (JPN) L 2–6 | did not advance | did not advance | did not advance | did not advance |

## Athletics

Ukrainian athletes achieved qualifying standards in the following athletics events (up to a maximum of 3 athletes in each event):

### Key

* Note–Ranks given for track events are within the athlete's heat only
* Q = Qualified for the next round
* q = Qualified for the next round as a fastest loser or, in field events, by position without achieving the qualifying target
* NR = National record
* N/A = Round not applicable for the event
* Bye = Athlete not required to compete in round

### Men

| Athlete | Event | Heat | Heat | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Result | Rank | Result | Rank | Result | Rank |
| Ihor Bodrov | 200 m | 20.86 | 7 | did not advance | did not advance | did not advance | did not advance |
| Serhiy Smelyk | 200 m | 20.66 | 4 | did not advance | did not advance | did not advance | did not advance |
| Vitaliy Butrym | 400 m | 45.92 | 4 | did not advance | did not advance | did not advance | did not advance |
| Ihor Olefirenko | Marathon | — | — | — | — | 2:15:36 | 30 |
| Ihor Russ | Marathon | — | — | — | — | 2:18:19 | 48 |
| Oleksandr Sitkovskyy | Marathon | — | — | — | — | 2:14:24 | 20 |
| Ruslan Dmytrenko | 20 km walk | — | — | — | — | 1:21:40 | 16 |
| Ihor Hlavan | 20 km walk | — | — | — | — | 1:23:32 | 31 |
| Nazar Kovalenko | 20 km walk | — | — | — | — | 1:24:40 | 40 |
| Ivan Banzeruk | 50 km walk | — | — | — | — | 4:11:51 | 39 |
| Serhiy Budza | 50 km walk | — | — | — | — | 3:53:22 | 18 |
| Ihor Hlavan | 50 km walk | — | — | — | — | DNF | DNF |

### Women

| Athlete | Event | Heat | Heat | Quarterfinal | Quarterfinal | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Result | Rank | Result | Rank | Result | Rank | Result | Rank |
| Nataliya Pohrebnyak | 100 m | Bye | Bye | 11.30 | 3 q | 11.32 | 7 | did not advance | did not advance |
| Olesya Povh | 100 m | Bye | Bye | 11.39 | 3 q | 11.29 | 8 | did not advance | did not advance |
| Khrystyna Stuy | 100 m | Bye | Bye | 11.57 | 7 | did not advance | did not advance | did not advance | did not advance |
| Yelyzaveta Bryzhina | 200 m | 23.28 | 5 | — | — | did not advance | did not advance | did not advance | did not advance |
| Nataliya Pohrebnyak | 200 m | 22.64 | 2 Q | — | — | 22.81 | 5 | did not advance | did not advance |
| Nataliya Strohova | 200 m | 23.69 | 7 | — | — | did not advance | did not advance | did not advance | did not advance |
| Olha Bibik | 400 m | 52.33 | 5 | — | — | did not advance | did not advance | did not advance | did not advance |
| Yuliya Olishevska | 400 m | 52.45 | 4 | — | — | did not advance | did not advance | did not advance | did not advance |
| Olha Zemlyak | 400 m | 51.40 | 2 Q | — | — | 50.75 | 3 q | 51.24 | 7 |
| Nataliya Lupu | 800 m | 1:59.91 | 2 Q | — | — | 2:02.10 | 8 | did not advance | did not advance |
| Olha Lyakhova | 800 m | 2:03.02 | 6 | — | — | did not advance | did not advance | did not advance | did not advance |
| Nataliya Pryshchepa | 800 m | 1:59.80 | 3 q | — | — | 1:59.95 | 4 | did not advance | did not advance |
| Hanna Platitsyna | 100 m hurdles | 13.12 | 7 | — | — | did not advance | did not advance | did not advance | did not advance |
| Oksana Shkurat | 100 m hurdles | 13.22 | 7 | — | — | did not advance | did not advance | did not advance | did not advance |
| Olena Yanovska | 100 m hurdles | 13.32 | 7 | — | — | did not advance | did not advance | did not advance | did not advance |
| Olena Kolesnichenko | 400 m hurdles | 56.61 | 3 Q | — | — | 56.77 | 8 | did not advance | did not advance |
| Hanna Titimets | 400 m hurdles | 56.24 | 3 Q | — | — | 55.27 | 4 | did not advance | did not advance |
| Viktoriya Tkachuk | 400 m hurdles | 56.14 | 2 Q | — | — | 56.87 | 8 | did not advance | did not advance |
| Mariya Shatalova | 3000 m steeplechase | 9:30.89 | 16 | — | — | — | — | did not advance | did not advance |
| Yelyzaveta Bryzhina Nataliya Pohrebnyak Olesya Povh Mariya Ryemyen Nataliya Strohova Khrystyna Stuy | 4 × 100 m relay | 42.49 | 3 Q | — | — | — | — | 42.36 | 6 |
| Olha Bibik Alina Lohvynenko Olha Lyakhova Tetyana Melnyk Yuliya Olishevska Olha Zemlyak | 4 × 400 m relay | 3:24.54 | 2 Q | — | — | — | — | 3:26.64 | 5 |
| Olha Kotovska | Marathon | — | — | — | — | — | — | 2:34.57 | 33 |
| Samunnati Lehonkova | Marathon | — | — | — | — | — | — | 2:46.08 | 87 |
| Svitlana Stanko | Marathon | — | — | — | — | — | — | 2:44.26 | 66 |
| Nadiya Borovska | 20 km walk | — | — | — | — | — | — | 1:33:01 | 19 |
| Inna Kashyna | 20 km walk | — | — | — | — | — | — | 1:33:15 | 21 |
| Valentyna Myronchuk | 20 km walk | — | — | — | — | — | — | 1:38:20 | 46 |

### Men

| Athlete | Event | Qualification | Qualification | Final | Final |
| Athlete | Event | Distance | Position | Distance | Position |
| Bohdan Bondarenko | High jump | 2.29 | =1 q | 2.33 | |
| Andriy Protsenko | High jump | 2.29 | =7 q | 2.33 | =4 |
| Dmytro Yakovenko | High jump | 2.26 | 20 | did not advance | did not advance |
| Mykyta Nesterenko | Discus throw | 60.31 | 23 | did not advance | did not advance |
| Oleksiy Semenov | Discus throw | 55.35 | 32 | did not advance | did not advance |
| Dmytro Kosynskyy | Javelin throw | 83.23 | 8 Q | 83.95 | 5 |
| Yevhen Vynohradov | Hammer throw | 73.95 | 11 q | 74.11 | 11 |

### Women

| Athlete | Event | Qualification | Qualification | Final | Final |
| Athlete | Event | Distance | Position | Distance | Position |
| Maryna Bekh | Long jump | 6.55 | 10 q | NM | — |
| Anna Kornuta | Long jump | 6.37 | 19 | did not advance | did not advance |
| Anna Lunyova | Long jump | 6.15 | 31 | did not advance | did not advance |
| Olha Saladuha | Triple jump | 13.97 | 18 | did not advance | did not advance |
| Ruslana Tsykhotska | Triple jump | 13.63 | 26 | did not advance | did not advance |
| Iryna Herashchenko | High jump | 1.94 | 13 Q | 1.93 | =10 |
| Yuliya Levchenko | High jump | 1.92 | 19 | did not advance | did not advance |
| Oksana Okuneva | High jump | 1.89 | 22 | did not advance | did not advance |
| Maryna Kylypko | Pole vault | 4.55 | 14 | did not advance | did not advance |
| Olha Holodna | Shot put | 16.83 | 27 | did not advance | did not advance |
| Halyna Obleshchuk | Shot put | 15.81 | 34 | did not advance | did not advance |
| Natalia Semenova | Discus throw | 58.41 | 15 | did not advance | did not advance |
| Kateryna Derun | Javelin throw | 60.02 | 17 | did not advance | did not advance |
| Hanna Hatsko | Javelin throw | 58.90 | 19 | did not advance | did not advance |
| Iryna Klymets | Hammer throw | 62.75 | 28 | did not advance | did not advance |
| Iryna Novozhylova | Hammer throw | 66.70 | 22 | did not advance | did not advance |
| Nataliya Zolotukhina | Hammer throw | 56.96 | 31 | did not advance | did not advance |

### Combined events – Men's decathlon

| Athlete | Event | 100 m | LJ | SP | HJ | 400 m | 110H | DT | PV | JT | 1500 m | Final | Rank |
| Oleksiy Kasyanov | Result | 10.78 | 7.54 | 14.50 | 2.01 | 48.56 | 14.34 | NM | DNS | — | — | DNF | DNF |
| Oleksiy Kasyanov | Points | 910 | 945 | 759 | 813 | 882 | 931 | 0 | 0 | — | — | DNF | DNF |

### Combined events – Women's heptathlon

| Athlete | Event | 100H | HJ | SP | 200 m | LJ | JT | 800 m | Final | Rank |
| Alina Fyodorova | Result | 14.10 | 1.80 | 14.38 | 25.44 | 6.00 | 35.44 | DNF | 5038 | 28 |
| Alina Fyodorova | Points | 964 | 978 | 820 | 847 | 850 | 580 | 0 | 5038 | 28 |
| Hanna Kasyanova | Result | 13.66 | 1.77 | 13.25 | 24.60 | 5.88 | 39.10 | 2:16.58 | 5951 | 25 |
| Hanna Kasyanova | Points | 1027 | 941 | 744 | 924 | 813 | 631 | 871 | 5951 | 25 |

## Badminton

Ukraine qualified two badminton players for each of the following events into the Olympic tournament. Artem Pochtarev and Marija Ulitina were selected among the top 34 individual shuttlers each in the men's and women's singles based on the BWF World Rankings as of 5 May 2016.
| Athlete | Event | Group Stage | Group Stage | Group Stage | Elimination | Quarterfinal | Semifinal | Final / BM | Final / BM |
| Athlete | Event | Opposition Score | Opposition Score | Rank | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Rank |
| Artem Pochtarev | Men's singles | Son W-h (KOR) L 9–21, 15–21 | Maliekal (RSA) L 18–21, 19–21 | 3 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Marija Ulitina | Women's singles | Nehwal (IND) W 21–18, 21–19 | Vicente (BRA) W 21–13, 21–13 | 1 Q | Buranaprasertsuk (THA) L 14–21, 16–21 | did not advance | did not advance | did not advance | did not advance |

## Boxing

Ukraine entered five boxers to compete in each of the following weight classes into the Olympic boxing tournament. With the top seed Nicola Adams of Great Britain advancing to the semifinals at the World Championships, Tetyana Kob earned an Olympic spot as a result of her third-place finish at the 2016 European Qualification Tournament in Samsun, Turkey.
On June 16, 2016, Dmytro Mytrofanov received a spare Olympic berth as the next highest-ranked boxer, not yet qualified, in the middleweight division of the AIBA Pro Boxing Rankings, after Turkey's Adem Kılıççı was suspended for failing the re-tested doping sample on steroids from London 2012.
Bantamweight boxer Mykola Butsenko secured an additional Olympic spot with his quarterfinal triumph at the 2016 AIBA World Qualifying Tournament in Baku, Azerbaijan, while Volodymyr Matviichuk and Denys Solonenko rounded out the Ukrainian roster at the 2016 APB and WSB Olympic Qualifier in Vargas, Venezuela.
| Athlete | Event | Round of 32 | Round of 16 | Quarterfinals | Semifinals | Final | Final |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Mykola Butsenko | Men's bantamweight | Hamout (MAR) L 0–3 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Volodymyr Matviichuk | Men's light welterweight | Sotomayor (AZE) L 0–3 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Dmytro Mytrofanov | Men's middleweight | Assomo (FRA) L 0–3 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Denys Solonenko | Men's light heavyweight | Mammadov (AZE) L 0–3 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Tetyana Kob | Women's flyweight | — | Petrova (BUL) W 2–1 | Adams (GBR) L 0–3 | did not advance | did not advance | did not advance |

## Canoeing
### Slalom

Ukraine qualified one canoeist in the women's K-1 class by obtaining a top finish at the 2016 European Canoe Slalom Championships in Liptovský Mikuláš, Slovakia.
| Athlete | Event | Preliminary | Preliminary | Preliminary | Preliminary | Preliminary | Preliminary | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Run 1 | Rank | Run 2 | Rank | Best | Rank | Time | Rank | Time | Rank |
| Viktoriia Us | Women's K-1 | 109.77 | 10 | 109.92 | 13 | 109.77 | 15 Q | 1:51.12 | 12 | did not advance | did not advance |

### Sprint

Ukrainian canoeists qualified a total of three boats in each of the following distances for the Games through the 2015 ICF Canoe Sprint World Championships.
Eight sprint canoeists (four per gender) were selected to the Ukrainian roster for the Games, with Iurii Cheban looking to defend his Olympic title in the men's C-1 200 metres.

#### Men

| Athlete | Event | Heats | Heats | Semifinals | Semifinals | Final | Final |
| Athlete | Event | Time | Rank | Time | Rank | Time | Rank |
| Pavlo Altukhov | C-1 1000 m | 4:19.361 | 4 Q | 3:58.574 | 2 FA | 4:01.587 | 4 |
| Iurii Cheban | C-1 200 m | 41.220 | 3 Q | 40.590 | 3 FA | 39.279 OB | |
| Dmytro Ianchuk Taras Mishchuk | C-2 1000 m | 3:35.284 | 2 Q | 3:38.384 | 1 FA | 3:45.99 | |

#### Women

| Athlete | Event | Heats | Heats | Semifinals | Semifinals | Final | Final |
| Athlete | Event | Time | Rank | Time | Rank | Time | Rank |
| Mariya Povkh | K-1 500 m | 1:54.247 | 3 Q | 2:00.714 | 6 | did not advance | did not advance |
| Inna Hryshchun Anastasiia Todorova | K-2 500 m | 1:43.967 | 3 Q | 1:43.363 | 2 FA | 1:45.868 | 4 |
| Svitlana Akhadova Inna Hryshchun Mariya Povkh Anastasiia Todorova | K-4 500 m | 1:31.727 | 2 Q | 1:35.512 | 2 FA | 1:16.925 | 4 |
Qualification Legend: FA = Qualify to final (medal); FB = Qualify to final B (non-medal)

## Cycling
### Road

Ukrainian riders qualified for the following quota places in the men's and women's Olympic road race by virtue of their top 15 final national ranking in the 2015 UCI Europe Tour (for men) and top 22 in the 2016 UCI World Ranking (for women).
| Athlete | Event | Time | Rank |
| Andriy Hrivko | Men's road race | 6:23:23 | 41 |
| Andriy Hrivko | Men's time trial | 1:16:33.24 | 18 |
| Denys Kostyuk | Men's road race | did not finish | did not finish |
| Andriy Khripta | Men's road race | did not finish | did not finish |
| Hanna Solovey | Women's road race | 4:01:02 | 36 |
| Hanna Solovey | Women's time trial | 48:03.35 | 20 |

### Track

Following the completion of the 2016 UCI Track Cycling World Championships, Ukraine entered one rider to compete only in the Olympics, by virtue of her final individual UCI Olympic ranking in that event.

#### Keirin

| Athlete | Event | 1st Round | Repechage | 2nd Round | Final |
| Athlete | Event | Rank | Rank | Rank | Rank |
| Lyubov Basova | Women's keirin | REL R | 1 Q | 3 Q | 5 |

### Mountain biking

Ukrainian mountain bikers qualified for two women's quota places into the Olympic cross-country race, as a result of the nation's eighth-place finish in the UCI Olympic Ranking List of May 25, 2016.
| Athlete | Event | Time | Rank |
| Yana Belomoyna | Women's cross-country | 1:33:28 | 9 |
| Iryna Popova | Women's cross-country | 1:41:29 | 30 |

## Diving

Ukrainian divers qualified for the following individual spots and synchronized teams at the Olympics through the 2015 FINA World Championships and the 2016 FINA World Cup series.

### Men

| Athlete | Event | Preliminaries | Preliminaries | Semifinals | Semifinals | Final | Final |
| Athlete | Event | Points | Rank | Points | Rank | Points | Rank |
| Illya Kvasha | 3 m springboard | 398.20 | 15 Q | 430.05 | 8 Q | 475.10 | 6 |
| Maksym Dolhov Oleksandr Horshkovozov | 10 m synchronized platform | — | — | — | — | 421.98 | 6 |

### Women

| Athlete | Event | Preliminaries | Preliminaries | Semifinals | Semifinals | Final | Final |
| Athlete | Event | Points | Rank | Points | Rank | Points | Rank |
| Olena Fedorova | 3 m springboard | 318.10 | 10 Q | 321.00 | 8 Q | 304.80 | 11 |
| Anastasiia Nedobiga | 3 m springboard | 309.50 | 12 Q | 290.15 | 18 | did not advance | did not advance |
| Hanna Krasnoshlyk | 10 m platform | 300.80 | 14 Q | 295.45 | 16 | did not advance | did not advance |
| Yulia Prokopchuk | 10 m platform | 297.95 | 15 Q | 300.65 | 14 | did not advance | did not advance |

## Equestrian

Ukraine fielded a squad of four jumping riders into the Olympic equestrian competition by virtue of a top national finish from Central & Eastern Europe at the FEI qualification event in Šamorín, Slovakia. One dressage rider was added to the squad by virtue of a top six finish outside the group selection in the individual FEI Olympic Rankings.

### Dressage

| Athlete | Horse | Event | Grand Prix | Grand Prix | Grand Prix Special | Grand Prix Special | Grand Prix Freestyle | Grand Prix Freestyle | Overall | Overall |
| Athlete | Horse | Event | Score | Rank | Score | Rank | Technical | Artistic | Score | Rank |
| Inna Logutenkova | Don Gregorius | Individual | 68.943 | 41 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |

### Jumping

| Athlete | Horse | Event | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Final | Final | Final | Final | Final | Total | Total |
| Athlete | Horse | Event | Round 1 | Round 1 | Round 2 | Round 2 | Round 2 | Round 3 | Round 3 | Round 3 | Round A | Round A | Round B | Round B | Round B | | | Total | Total |
| Athlete | Horse | Event | Penalties | Rank | Penalties | Total | Rank | Penalties | Total | Rank | Penalties | Rank | Penalties | Total | Rank | Penalties | Rank |
| Ulrich Kirchhoff | Prince de la Mare | Individual | 4 | =27 Q | 4 | 8 | =30 Q | 17 | 25 | 43 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Cassio Rivetti | Fine Fleur du Marais | Individual | 47 # | =68 $^{TO}$ | DSQ | DSQ | DSQ | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Ferenc Szentirmai | Chadino | Individual | 47 | =68 $^{TO}$ | 9 | TO | TO | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| René Tebbel | Zipper | Individual | 0 | =1 Q | 1 | 1 | =12 Q | 2 | 3 | 6 Q | 1 | =14 Q | 5 | 6 | 19 | 6 | 19 |
| Ulrich Kirchhoff Cassio Rivetti Ferenc Szentirmai René Tebbel | See above | Team | 51 | 15 | 14 | — | =13 | did not advance | did not advance | did not advance | — | — | — | — | — | 14 | =13 |
"TO" indicates that the rider only qualified for the team competition. "#" indicates that the score of this rider does not count in the team competition, since only the best three results of a team are counted.

## Fencing

Ukrainian fencers qualified a full squad each in the men's team épée and women's team sabre by virtue of their top 4 national finish in the FIE Olympic Team Rankings, while the women's épée team claimed the spot as the highest ranking team from Europe outside the world's top four. Meanwhile, sabre fencer Andriy Yahodka claimed his Olympic spot by finishing among the top four individuals at the European Zonal Qualifier in Prague, Czech Republic.
The full Ukrainian fencing team, led by London 2012 épée champion Yana Shemyakina and sabre bronze medalist Olha Kharlan, was named on July 5, 2016. Olha Leleiko received a spare berth freed up by Israel to compete in the women's foil as the next highest-ranked fencer, not yet qualified, at the European Zonal Qualifier in Prague, before she was added to the nation's fencing team on July 25, 2016.

### Men

| Athlete | Event | Round of 64 | Round of 32 | Round of 16 | Quarterfinal | Semifinal | Final / BM | Final / BM |
| Athlete | Event | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Rank |
| Anatoliy Herey | Épée | Bye | Kauter (SUI) L 9–15 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Dmytro Karyuchenko | Épée | Rodríguez (COL) L 7–15 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Bohdan Nikishyn | Épée | Bye | Jiao Yl (CHN) W 15–11 | Steffen (SUI) L 14–15 | did not advance | did not advance | did not advance | did not advance |
| Anatoliy Herey Dmytro Karyuchenko Maksym Khvorost Bohdan Nikishyn | Team épée | — | — | Bye | Russia (RUS) W 45–32 | Italy (ITA) L 33–45 | Hungary (HUN) L 37–39 | 4 |
| Andriy Yahodka | Sabre | — | Abedini (IRI) L 9–15 | did not advance | did not advance | did not advance | did not advance | did not advance |

### Women

| Athlete | Event | Round of 64 | Round of 32 | Round of 16 | Quarterfinal | Semifinal | Final / BM | Final / BM |
| Athlete | Event | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Rank |
| Olena Kryvytska | Épée | Bye | Shin A-l (KOR) W 15–14 | Rembi (FRA) L 7–9 | did not advance | did not advance | did not advance | did not advance |
| Kseniya Pantelyeyeva | Épée | Bye | Embrich (EST) L 3–15 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Yana Shemyakina | Épée | Bye | Hurley (USA) W 14–13 | Nakano (JPN) L 8–11 | did not advance | did not advance | did not advance | did not advance |
| Olena Kryvytska Kseniya Pantelyeyeva Anfisa Pochkalova Yana Shemyakina | Team épée | — | — | Brazil (BRA) W 45–32 | China (CHN) L 42–34 | Classification semi-final South Korea (KOR) L 34–45 | 7th place match France (FRA) L 38–45 | 8 |
| Olha Leleiko | Foil | Bye | Guyart (FRA) L 9–15 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Olha Kharlan | Sabre | Bye | González (MEX) W 15–8 | Komashchuk (UKR) W 15–8 | Gulotta (ITA) W 15–4 | Egorian (RUS) L 9–15 | Brunet (FRA) W 15–10 | |
| Alina Komashchuk | Sabre | Bye | Gregorio (ITA) W 15–14 | Kharlan (UKR) L 8–15 | did not advance | did not advance | did not advance | did not advance |
| Olena Kravatska | Sabre | Bye | Muhammad (USA) L 13–15 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Olha Kharlan Alina Komashchuk Olena Kravatska Olena Voronina | Team sabre | — | — | — | South Korea (KOR) W 45-40 | Italy (ITA) W 45-42 | Russia (RUS) L 30-45 | |

## Gymnastics
### Artistic

Ukraine fielded a full team of six artistic gymnasts (five men and one woman) into the Olympic competition. The men's squad claimed one of the remaining four spots in the team all-around, while Angelina Kysla accepted the Olympic berth as a lone Ukrainian female gymnast in the apparatus and individual all-around events at the Olympic Test Event in Rio de Janeiro.

#### Team

| Athlete | Event | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Final | Final | Final | Final | Final | Final | Final | Final |
| Athlete | Event | Apparatus | Apparatus | Apparatus | Apparatus | Apparatus | Apparatus | Total | Rank | Apparatus | Apparatus | Apparatus | Apparatus | Apparatus | Apparatus | Total | Rank |
| Athlete | Event | F | PH | R | V | PB | HB | Total | Rank | F | PH | R | V | PB | HB | Total | Rank |
| Vladyslav Hryko | Team | 13.666 | 13.766 | 13.700 | — | 14.500 | 13.666 | — | — | 13.166 | 12.666 | 13.866 | 14.241 | 14.666 | 13.700 | — | — |
| Igor Radivilov | Team | 13.666 | — | 15.308 Q | 15.433 Q | — | 13.500 | — | — | 14.600 | — | 15.433 | 15.333 | — | 13.300 | — | — |
| Maksym Semiankiv | Team | 14.200 | 13.700 | 13.666 | 13.633 | 13.300 | 14.566 | 83.065 | 39 | DNS | — | DNS | — | DNS | DNS | | — | — |
| Andriy Sienichkin | Team | — | 14.533 | — | 14.400 | 12.766 | — | — | — | — | 15.333 | — | 14.441 | — | — | | — | — |
| Oleg Verniaiev | Team | 14.833 | 15.566 Q | 15.200 | 15.066 Q | 16.166 Q | 15.133 Q | 91.964 | 1 Q | — | 15.633 | — | — | 15.900 | — | — | — |
| Total | Team | 42.699 | 43.865 | 44.208 | 44.849 | 43.966 | 43.365 | 263.002 | 7 Q | 27.766 | 43.632 | 29.299 | 44.015 | 30.366 | 27.000 | 202.078 | 8 |

#### Individual finals

| Athlete | Event | Apparatus | Apparatus | Apparatus | Apparatus | Apparatus | Apparatus | Total | Rank |
| Athlete | Event | F | PH | R | V | PB | HB | Total | Rank |
| Igor Radivilov | Rings | — | — | 15.466 | — | — | — | 15.466 | 5 |
| Igor Radivilov | Vault | — | — | — | 15.033 | — | — | 15.033 | 8 |
| Oleg Verniaiev | All-around | 15.033 | 15.533 | 15.300 | 15.500 | 16.100 | 14.800 | 92.266 | |
| Oleg Verniaiev | Pommel horse | — | 12.400 | — | — | — | — | 12.400 | 8 |
| Oleg Verniaiev | Vault | — | — | — | 15.316 | — | — | 15.316 | 5 |
| Oleg Verniaiev | Parallel bars | — | — | — | — | 16.041 | — | 16.041 | |
| Oleg Verniaiev | Horizontal bar | — | — | — | — | — | 13.366 | 13.366 | 8 |

#### Women

| Athlete | Event | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Final | Final | Final | Final | Final | Final |
| Athlete | Event | Apparatus | Apparatus | Apparatus | Apparatus | Total | Rank | Apparatus | Apparatus | Apparatus | Apparatus | Total | Rank |
| Athlete | Event | V | UB | BB | F | Total | Rank | V | UB | BB | F | Total | Rank |
| Angelina Kysla | Uneven bars | — | 12.533 | — | — | 12.533 | 68 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Angelina Kysla | Balance beam | — | — | 12.666 | — | 12.666 | 69 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Angelina Kysla | Floor | — | — | — | 13.066 | 13.066 | 56 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |

### Rhythmic

Ukraine qualified a squad of rhythmic gymnasts for the individual and group all-around by finishing in the top 15 (for individual) and top 10 (for group) at the 2015 World Championships in Stuttgart, Germany.
| Athlete | Event | Qualification | Qualification | Qualification | Qualification | Qualification | Qualification | Final | Final | Final | Final | Final | Final |
| Athlete | Event | Hoop | Ball | Clubs | Ribbon | Total | Rank | Hoop | Ball | Clubs | Ribbon | Total | Rank |
| Hanna Rizatdinova | Individual | 18.400 | 18.566 | 18.466 | 18.500 | 73.932 | 3 Q | 18.200 | 18.450 | 18.450 | 18.483 | 73.583 | |
| Athlete | Event | Qualification | Qualification | Qualification | Qualification | Final | Final | Final | Final |
| Athlete | Event | 5 ribbons | 3 clubs 2 hoops | Total | Rank | 5 ribbons | 3 clubs 2 hoops | Total | Rank |
| Olena Dmytrash Yevgeniya Gomon Oleksandra Gridasova Valeriia Gudym Anastasiya Voznyak | Team | 16.950 | 16.866 | 33.816 | 8 Q | 16.866 | 17.416 | 34.282 | 7 |

### Trampoline

Ukraine qualified one gymnast in the women's trampoline by virtue of a top six finish at the 2016 Olympic Test Event in Rio de Janeiro.
| Athlete | Event | Qualification | Qualification | Final | Final |
| Athlete | Event | Score | Rank | Score | Rank |
| Nataliia Moskvina | Women's | 63.300 | 16 | did not advance | did not advance |

## Judo

Ukraine qualified a total of seven judokas for each of the following weight classes at the Games. Six of them (three per gender), highlighted by London 2012 Olympians Georgii Zantaraia and Artem Bloshenko, were ranked among the top 14 eligible judokas for women in the IJF World Ranking List of May 30, 2016, while Quedjau Nhabali at men's middleweight (70 kg) earned a continental quota spot from the European region, as the highest-ranked Ukrainian judoka outside of direct qualifying position. The judo team was named to the Olympic roster on June 1, 2016.

### Men

| Athlete | Event | Round of 64 | Round of 32 | Round of 16 | Quarterfinals | Semifinals | Repechage | Final / BM | Final / BM |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Georgii Zantaraia | −66 kg | Bye | Oleinic (POR) L 000–001 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Quedjau Nhabali | −90 kg | Bye | González (CUB) L 000–101 | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Artem Bloshenko | −100 kg | Kurbonov (UZB) W 100–000 | Shah (PAK) W 100–000 | Cho G-h (KOR) W 100–000 | Frey (GER) W 011–000 | Gasimov (AZE) L 000–100 | Bye | Haga (JPN) L 000–100 | 5 |
| Iakiv Khammo | +100 kg | — | Sidibe (BUR) W 100–000 | Krakovetskii (KGZ) L 000–111 | did not advance | did not advance | did not advance | did not advance | did not advance |

### Women

| Athlete | Event | Round of 32 | Round of 16 | Quarterfinals | Semifinals | Repechage | Final / BM | Final / BM |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Maryna Cherniak | −48 kg | Rishony (ISR) W 100–000 | Csernoviczki (HUN) L 000–003 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Viktoriya Turks | −78 kg | Bye | Velenšek (SLO) L 000–001 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Svitlana Iaromka | +78 kg | Bye | Savelkouls (NED) L 000–101 | did not advance | did not advance | did not advance | did not advance | did not advance |

## Modern pentathlon

Ukrainian athletes qualified for the following spots to compete in modern pentathlon. Andriy Fedechko and 2012 Olympian Pavlo Tymoshchenko secured a selection in the men's event by filling in two out of the three Olympic quota places at the 2015 World Championships, while Anastasiya Spas added a spot in the women's event to the roster through the European Championships.
| Athlete | Event | Fencing (épée one touch) | Fencing (épée one touch) | Fencing (épée one touch) | Fencing (épée one touch) | Swimming (200 m freestyle) | Swimming (200 m freestyle) | Swimming (200 m freestyle) | Riding (show jumping) | Riding (show jumping) | Riding (show jumping) | Combined: shooting/running (10 m air pistol)/(3200 m) | Combined: shooting/running (10 m air pistol)/(3200 m) | Combined: shooting/running (10 m air pistol)/(3200 m) | Total points | Final rank |
| Athlete | Event | RR | BR | Rank | MP points | Time | Rank | MP points | Penalties | Rank | MP points | Time | Rank | MP Points | Total points | Final rank |
| Andriy Fedechko | Men's | 16–19 | 2 | 24 | 198 | 2:05.63 | 25 | 324 | 25 | 24 | 275 | 11:47.68 | 26 | 593 | 1390 | 26 |
| Pavlo Tymoshchenko | Men's | 21–14 | 1 | 6 | 227 | 2:05.59 | 24 | 324 | 14 | 16 | 286 | 11:05.74 | 5 | 635 | 1472 | |
| Anastasiya Spas | Women's | 16–19 | 0 | 24 | 196 | 2:14.54 | 11 | 297 | 79 | 30 | 221 | 15:16.82 | 36 | 384 | 1098 | 30 |

## Rowing

Ukraine qualified two boats for each of the following rowing classes into the Olympic regatta. One rowing crew confirmed an Olympic place for their boat in the men's quadruple sculls at the 2015 FISA World Championships in Lac d'Aiguebelette, France, while the rowers competing in the women's quadruple sculls were added to the Ukrainian roster with their top two finish at the 2016 European & Final Qualification Regatta in Lucerne, Switzerland.
Eight rowers (four per gender) were selected to the Ukrainian roster for the Games, with Anastasiya Kozhenkova looking to defend the Olympic title with the women's quadruple sculls crew (Buryak, Nimchenko, & Verkhogliad).
| Athlete | Event | Heats | Heats | Repechage | Repechage | Final | Final |
| Athlete | Event | Time | Rank | Time | Rank | Time | Rank |
| Ivan Dovgodko Dmytro Mikhay Artem Morozov Oleksandr Nadtoka | Men's quadruple sculls | 5:52.90 | 2 FA | Bye | Bye | 6:16.30 | 6 |
| Olena Buryak Anastasiya Kozhenkova Ievgeniia Nimchenko Daryna Verkhohliad | Women's quadruple sculls | 6:35.48 | 1 FA | Bye | Bye | 6:56.09 | 4 |
Qualification Legend: FA=Final A (medal); FB=Final B (non-medal); FC=Final C (non-medal); FD=Final D (non-medal); FE=Final E (non-medal); FF=Final F (non-medal); SA/B=Semifinals A/B; SC/D=Semifinals C/D; SE/F=Semifinals E/F; QF=Quarterfinals; R=Repechage

## Sailing

Ukrainian sailors qualified one boat in each of the following classes through the individual fleet World Championships, and European qualifying regattas.
| Athlete | Event | Race | Race | Race | Race | Race | Race | Race | Race | Race | Race | Race | Race | Race | Net points | Final rank |
| Athlete | Event | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | M* | Net points | Final rank |
| Oleksandr Tugaryev | Men's RS:X | 22 | 31 | 33 | 11 | DNF | 12 | 13 | 16 | 30 | 20 | 30 | 13 | EL | 225 | 23 |
| Pavlo Matsuyev Borys Shvets | Men's 470 | 16 | 13 | 21 | 24 | 25 | 17 | 25 | 24 | 25 | 19 | — | — | EL | 184 | 25 |
M = Medal race; EL = Eliminated – did not advance into the medal race

## Shooting

Ukrainian shooters achieved quota places for the following events by virtue of their best finishes at the 2014 and 2015 ISSF World Championships, the 2015 ISSF World Cup series, and European Championships or Games, as long as they obtained a minimum qualifying score (MQS) by March 31, 2016.

### Men

| Athlete | Event | Qualification | Qualification | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Points | Rank | Points | Rank | Points | Rank |
| Roman Bondaruk | 25 m rapid fire pistol | 579 | 11 | — | — | did not advance | did not advance |
| Pavlo Korostylov | 10 m air pistol | 572 | 35 | — | — | did not advance | did not advance |
| Pavlo Korostylov | 25 m rapid fire pistol | 574 | 16 | — | — | did not advance | did not advance |
| Serhiy Kulish | 10 m air rifle | 327.0 | 4 Q | — | — | 204.6 | |
| Serhiy Kulish | 50 m rifle prone | 620.5 | 32 | — | — | did not advance | did not advance |
| Serhiy Kulish | 50 m rifle 3 positions | 1171 | 14 | — | — | did not advance | did not advance |
| Mykola Milchev | Skeet | 122 | 4 Q | 15 | 3 q | 14 | 4 |
| Oleh Omelchuk | 10 m air pistol | 577 | 14 | — | — | did not advance | did not advance |
| Oleh Omelchuk | 50 m pistol | 550 | 21 | — | — | did not advance | did not advance |
| Oleh Tsarkov | 10 m air rifle | 626.2 | 5 Q | — | — | 79.7 | 8 |
| Oleh Tsarkov | 50 m rifle prone | 623.1 | 12 | — | — | did not advance | did not advance |
| Oleh Tsarkov | 50 m rifle 3 positions | 1172 | 10 | — | — | did not advance | did not advance |

### Women

| Athlete | Event | Qualification | Qualification | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Points | Rank | Points | Rank | Points | Rank |
| Natallia Kalnysh | 10 m air rifle | 415.8 | 9 | — | — | did not advance | did not advance |
| Natallia Kalnysh | 50 m rifle 3 positions | 577 | 21 | — | — | did not advance | did not advance |
| Olena Kostevych | 10 m air pistol | 378 | 28 | — | — | did not advance | did not advance |
| Olena Kostevych | 25 m pistol | 575 | 22 | did not advance | did not advance | did not advance | did not advance |
Qualification Legend: Q = Qualify for the next round; q = Qualify for the bronze medal (shotgun)

## Swimming

Ukrainian swimmers achieved qualifying standards in the following events (up to a maximum of 2 swimmers in each event at the Olympic Qualifying Time (OQT), and potentially 1 at the Olympic Selection Time (OST)):

### Men

| Athlete | Event | Heat | Heat | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Time | Rank | Time | Rank | Time | Rank |
| Serhiy Frolov | 1500 m freestyle | 15:04.61 | 17 | — | — | did not advance | did not advance |
| Andriy Hovorov | 50 m freestyle | 21.49 NR | 1 Q | 21.46 NR | 2 Q | 21.74 | 5 |
| Liubomyr Lemeshko | 100 m butterfly | 52.51 | 23 | did not advance | did not advance | did not advance | did not advance |
| Dmytro Oseledets | 200 m breaststroke | 2:15.19 | 37 | did not advance | did not advance | did not advance | did not advance |
| Mykhailo Romanchuk | 1500 m freestyle | 15:01.35 | 15 | — | — | did not advance | did not advance |

### Women

| Athlete | Event | Heat | Heat | Semifinal | Semifinal | Final | Final |
| Athlete | Event | Time | Rank | Time | Rank | Time | Rank |
| Darya Stepanyuk | 50 m freestyle | 25.67 | 42 | did not advance | did not advance | did not advance | did not advance |
| Darya Stepanyuk | 100 m butterfly | 1:00.81 | 33 | did not advance | did not advance | did not advance | did not advance |
| Daryna Zevina | 200 m backstroke | 2:08.88 | 8 Q | 2:09.07 | 9 | did not advance | did not advance |

## Synchronized swimming

For the first time in Olympic history, Ukraine fielded a squad of nine synchronized swimmers to compete in both the women's team and duet routine by virtue of their first-place finish at the FINA Olympic test event in Rio de Janeiro.
| Athlete | Event | Technical routine | Technical routine | Free routine (preliminary) | Free routine (preliminary) | Free routine (preliminary) | Free routine (final) | Free routine (final) | Free routine (final) |
| Athlete | Event | Points | Rank | Points | Total (technical + free) | Rank | Points | Total (technical + free) | Rank |
| Lolita Ananasova Anna Voloshyna | Duet | 93.1358 | 3 | 93.5333 | 186.6691 | 4 Q | 94.0000 | 187.1358 | 4 |
| Lolita Ananasova Olena Grechykhina Oleksandra Sabada Kateryna Sadurska Anastasiya Savchuk Kseniya Sydorenko Anna Voloshyna Daria Iushko Olha Zolotarova | Team | 93.4413 | 4 | — | — | — | 95.1667 | 188.6080 | 4 |

## Table tennis

Ukraine entered three athletes into the table tennis competition at the Games. 2008 Olympian and 2015 European Games bronze medalist Kou Lei secured one of the remaining Olympic spots in the men's singles by winning the repechage play-off match at the European Qualification Tournament in Halmstad, Sweden.
Two-time Olympian Tetyana Bilenko was automatically selected among the top 22 eligible players to confirm her third Olympic appearance in the women's singles. Margaryta Pesotska was originally granted an invitation from ITTF to compete in the same event as one of the next seven highest-ranked eligible players, not yet qualified, on the Olympic Ranking List, but later withdrew from the Games due to injury.
| Athlete | Event | Preliminary | Round 1 | Round 2 | Round 3 | Round of 16 | Quarterfinals | Semifinals | Final / BM | Final / BM |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Kou Lei | Men's singles | Bye | Bye | O Assar (EGY) W 4–3 | Gauzy (FRA) W 4–1 | Freitas (POR) L 0–4 | did not advance | did not advance | did not advance | did not advance |
| Tetyana Bilenko | Women's singles | Bye | Bye | Vacenovská (CZE) W 4–0 | Lee H C (HKG) L 1–4 | did not advance | did not advance | did not advance | did not advance | did not advance |

## Tennis

Ukraine entered seven tennis players (three men and four women) into the Olympic tournament. Rookies Illya Marchenko (world no. 73), Elina Svitolina (world no. 19), and Lesia Tsurenko (world no. 44) qualified directly among the top 56 eligible players in their respective singles events based on the ATP and WTA World Rankings as of June 6, 2016.
Having been directly entered to the singles, Marchenko and Svitolina also opted to play with their partners Denys Molchanov and Olga Savchuk, respectively, in the doubles tournament, while sisters Lyudmyla and Nadiia Kichenok claimed one of eight ITF Olympic women's doubles places, as Ukraine's top-ranked tennis pair outside of direct qualifying position.
Lesia Tsurenko withdrew from the Games before the opening match for health reasons.

### Men

| Athlete | Event | Round of 64 | Round of 32 | Round of 16 | Quarterfinals | Semifinals | Final / BM | Final / BM |
| Athlete | Event | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Rank |
| Illya Marchenko | Singles | Seppi (ITA) L 3–6, 6–3, 6–7$^{(6–8)}$ | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance |
| Illya Marchenko Denys Molchanov | Doubles | — | Fognini / Seppi (ITA) L 4–6, 3–6 | did not advance | did not advance | did not advance | did not advance | did not advance |

### Women

| Athlete | Event | Round of 64 | Round of 32 | Round of 16 | Quarterfinals | Semifinals | Final / BM | Final / BM |
| Athlete | Event | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Opposition Score | Rank |
| Elina Svitolina | Singles | Petkovic (GER) W 2–6, 6–1, 6–3 | Watson (GBR) W 6–3, 1–6, 6–3 | S Williams (USA) W 6–4, 6–3 | Kvitová (CZE) L 2–6, 0–6 | did not advance | did not advance | did not advance |
| Lesia Tsurenko | Singles | Withdrew on 6 August for health reasons | Withdrew on 6 August for health reasons | Withdrew on 6 August for health reasons | Withdrew on 6 August for health reasons | Withdrew on 6 August for health reasons | Withdrew on 6 August for health reasons | Withdrew on 6 August for health reasons |
| Lyudmyla Kichenok Nadiia Kichenok | Doubles | — | Xu Yf / Zheng Ss (CHN) L 0–6, 3–6 | did not advance | did not advance | did not advance | did not advance | did not advance |
| Olga Savchuk Elina Svitolina | Doubles | — | Hlaváčková / Hradecká (CZE) L 6–7$^{(1–7)}$, 6–1, 4–6 | did not advance | did not advance | did not advance | did not advance | did not advance |

## Triathlon

Ukraine entered two triathletes to compete at the Games. Two-time Olympian Yuliya Yelistratova was ranked among the top 40 eligible triathletes in the women's event, while Ivan Ivanov received a spare berth freed up by one of the Germans to compete in the men's event as the next highest-ranked eligible triathlete, not yet qualified, in the ITU Olympic Qualification List as of May 15, 2016.
| Athlete | Event | Swim (1.5 km) | Trans 1 | Bike (40 km) | Trans 2 | Run (10 km) | Total Time | Rank |
| Ivan Ivanov | Men's | 18:58 | 0:51 | 1:00:26 | 0:43 | 35:02 | 1:56.00 | 49 |
| Yuliya Yelistratova | Women's | 20:05 | 0:55 | 1:05:57 | 0:39 | 35:51 | 2:03:27 | 38 |

## Weightlifting

Ukrainian weightlifters qualified four men's and four women's quota places for the Rio Olympics based on their combined team standing by points at the 2014 and 2015 IWF World Championships. The team had to allocate these places to individual athletes by June 20, 2016.
On 2 August 2016, Roman Zaitsev withdrew from the Games due to injury. Instead, Ihor Shymechko took over the vacant spot to compete in the men's super heavyweight division (+105 kg).

### Men

| Athlete | Event | Snatch | Snatch | Clean & Jerk | Clean & Jerk | Total | Rank |
| Athlete | Event | Result | Rank | Result | Rank | Total | Rank |
| Oleksandr Pielieshenko | −85 kg | 175 | 4 | 210 | 5 | 385 | 5 |
| Dmytro Chumak | −94 kg | 174 | 6 | 213 | 6 | 387 | 6 |
| Volodymyr Hoza | −94 kg | 170 | 9 | 205 | 9 | 375 | 9 |
| Ihor Shymechko | +105 kg | 170 | 22 | 195 | 19 | 365 | 19 |

### Women

| Athlete | Event | Snatch | Snatch | Clean & Jerk | Clean & Jerk | Total | Rank |
| Athlete | Event | Result | Rank | Result | Rank | Total | Rank |
| Iulia Paratova | −48 kg | 84 | 4 | 95 | 9 | 179 | 8 |
| Veronika Ivasiuk | −58 kg | 90 | 9 | 103 | 15 | 193 | 13 |
| Iryna Dekha | −75 kg | 114 | 4 | 133 | 8 | 247 | 5 |
| Anastasiya Lysenko | +75 kg | 117 | =9 | 146 | 10 | 263 | 10 |

## Wrestling

Ukraine qualified a total of nine wrestlers for each of the following weight classes into the Olympic competition. Five of them finished among the top six to book Olympic spots in the men's freestyle (97 kg), men's Greco-Roman (85, 98, & 130 kg), and women's freestyle (63 kg) at the 2015 World Championships, while two more Olympic berths were awarded to Ukrainian wrestlers, who progressed to the top two finals at the 2016 European Qualification Tournament.
Three further wrestlers claimed the remaining Olympic slots to round out the Ukrainian roster at the final meet of the World Qualification Tournament in Istanbul.
On May 11, 2016, United World Wrestling (UWW) decided to revoke two Olympic licenses from Ukraine in men's freestyle 66 kg and women's freestyle 58 kg, respectively, due to doping violations at the European Qualification Tournament, but these licenses were redistributed back two months later.
* VT (ranking points: 5–0 or 0–5) – Victory by fall.
* VB (ranking points: 5–0 or 0–5) – Victory by injury (VF for forfeit, VA for withdrawal or disqualification)
* PP (ranking points: 3–1 or 1–3) – Decision by points – the loser with technical points.
* PO (ranking points: 3–0 or 0–3) – Decision by points – the loser without technical points.
* ST (ranking points: 4–0 or 0–4) – Great superiority – the loser without technical points and a margin of victory of at least 8 (Greco-Roman) or 10 (freestyle) points.
* SP (ranking points: 4–1 or 1–4) – Technical superiority – the loser with technical points and a margin of victory of at least 8 (Greco-Roman) or 10 (freestyle) points.

### Men's freestyle

| Athlete | Event | Qualification | Round of 16 | Quarterfinal | Semifinal | Repechage 1 | Repechage 2 | Final / BM | Final / BM |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Andriy Kviatkovskyi | −65 kg | Bye | Asgarov (AZE) L 2–12 $^{SP}$ | did not advance | did not advance | Bye | Molinaro (USA) L 5–8 $^{PP}$ | Did not advance | 13 |
| Valeriy Andriytsev | −97 kg | Bye | Boltukayev (RUS) W 8–5 $^{PP}$ | Musaev (KGZ) W 5–2 $^{PP}$ | Gazyumov (AZE) L 0–11 $^{ST}$ | Bye | Bye | Ibragimov (UZB) L 4–6 $^{PP}$ | 5 |
| Alen Zasyeyev | −125 kg | Makhov (RUS) W 2–2 $^{PP}$ | Petriashvili (GEO) L 6–11 $^{PP}$ | did not advance | did not advance | did not advance | did not advance | did not advance | 10 |

### Men's Greco-Roman

| Athlete | Event | Qualification | Round of 16 | Quarterfinal | Semifinal | Repechage 1 | Repechage 2 | Final / BM | Final / BM |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Zhan Beleniuk | −85 kg | Bye | Othman (EGY) W 9–0 $^{ST}$ | Bayryakov (BUL) W 10–1 $^{SP}$ | Hamzatau (BLR) W 6–0 $^{PO}$ | Bye | Bye | Chakvetadze (RUS) L 2–9 $^{PP}$ | |
| Dimitriy Timchenko | −98 kg | Kiss (HUN) L 0–3 $^{PP}$ | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | 15 |
| Oleksandr Chernetskyi | −130 kg | Mohamed (EGY) W 9–0 $^{ST}$ | Kajaia (GEO) L 1–2 $^{VT}$ | did not advance | did not advance | did not advance | did not advance | did not advance | 9 |

### Women's freestyle

| Athlete | Event | Qualification | Round of 16 | Quarterfinal | Semifinal | Repechage 1 | Repechage 2 | Final / BM | Final / BM |
| Athlete | Event | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Opposition Result | Rank |
| Yuliya Khavaldzhy | −53 kg | Maroulis (USA) L 1–12 $^{SP}$ | did not advance | did not advance | did not advance | Zhong Xc (CHN) L 1–11 $^{SP}$ | did not advance | did not advance | 11 |
| Oksana Herhel | −58 kg | Bye | Ratkevich (AZE) L 5–7 $^{PP}$ | did not advance | did not advance | did not advance | did not advance | did not advance | 13 |
| Yuliya Tkach | −63 kg | Lappage (CAN) W 2–0 $^{VB}$ | Xu R (CHN) L 1–3 $^{PP}$ | did not advance | did not advance | did not advance | did not advance | did not advance | 9 |
| Alina Stadnyk | −69 kg | Dosho (JPN) L 2–10 $^{PP}$ | did not advance | did not advance | did not advance | Tosun (TUR) L 4–7 $^{PP}$ | did not advance | did not advance | 11 |
| Alla Cherkasova | −75 kg | Adar (TUR) L 10–12 $^{PP}$ | did not advance | did not advance | did not advance | did not advance | did not advance | did not advance | 11 |