OpenLLM-France/wikimedia huggingface dataset:
# Thiol-yne reaction

In organic chemistry, the thiol-yne reaction (also known as alkyne hydrothiolation) is an organic reaction between a thiol (−SH) and an alkyne (−C≡CH). The reaction product is an alkenyl sulfide (−CH=CH−S−).
The reaction was first reported in 1949 with thioacetic acid as reagent and rediscovered in 2009. It is used in click chemistry and in polymerization, especially with dendrimers.
* Thiol-yne reaction
* Thiol-yne reaction
This addition reaction is typically facilitated by a radical initiator or UV irradiation and proceeds through a sulfanyl radical species. With monoaddition a mixture of (E/Z)-alkenes form. The mode of addition is anti-Markovnikov. The radical intermediate can engage in secondary reactions such as cyclisation. With diaddition the 1,2-disulfide or the 1,1- dithioacetal forms. Reported catalysts for radical additions are triethylborane, indium(III) bromide and AIBN. The reaction is also reported to be catalysed by cationic rhodium and iridium complexes, by thorium and uranium complexes, by rhodium complexes, by caesium carbonate and by gold.
* Ichinose et al. thiol-yne reaction 1987
* Ichinose et al. thiol-yne reaction 1987
Diphenyl disulfide reacts with alkynes to a 1,2-bis(phenylthio)ethylene. Reported alkynes are ynamides. A photoredox thiol-yne reaction has been reported.

## Polymer chemistry

In polymer chemistry, systems have been described based on addition polymerization with 1,4-benzenedithiol and 1,4-diethynylbenzene, in the synthesis of other addition polymer systems in the synthesis of dendrimers, in star polymers, in graft polymerization, block copolymers, and in polymer networks. Another reported application is the synthesis of macrocycles via dithiol coupling.
# 20 successi di Mina

20 successi di Mina is a compilation album by Italian singer Mina, issued in 1964.
The songs of this album were all taken from the first six albums published between 1960 and 1963, except "Vulcano" that was published in 1963 only on a 45rpm record.

## Track listing
### Side B

* This article on a 1960s compilation album is a stub. You can help Wikipedia by expanding it.
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# Léopold Boisselle

Léopold Boisselle (14 June 1903 – 15 March 1964) was a French racing cyclist. He rode in the 1928 Tour de France.
# Eternity Inc.

Eternity Inc. is an adventure published by Mayfair Games in 1986 for the superhero role-playing game (RPG) DC Heroes.

## Plot summary

Eternity Inc. is an adventure in which the player characters are members of the Los Angeles-based superhero team Infinity, Inc. They are called to the Page Museum when it is invaded by prehistoric animals, and find themselves pitted against Gorilla Grodd and his Neanderthal sorcerers.

## Publication history

Mayfair Games first published the superhero RPG DC Heroes in 1985. The 32-page adventure Eternity Inc. was published the following year, written by Lawrence Schick, with interior art by DC Comics staff, Gideon and Jerry O'Malley, cartography by Jimmy Clouse, and cover art by Ed Hannigan, Denys Cowan, Bob Smith, and Bob LeRose.

## Reception

Pete Tamlyn reviewed Eternity Inc. for White Dwarf #84, and wrote that "the plot is not in any way dependant on the nature of the heroes. It could be run for anyone, which is another useful aspect. Recommended".
# Scott Dickens

Andrew Scott Dickens (born August 4, 1984) is a former competitive swimmer from Canada, who mostly competes in the breaststroke events. He claimed two medals at the 2007 Pan American Games in Rio de Janeiro, Brazil. Dickens won his first national title at the 2004 Canadian Olympic Trials, earning his first trip to the Olympic Games where he finished 19th in the 100-metre breaststroke.
Dickens finished 8th in the semifinal heat and 16th overall in the 100-metre breaststroke at the 2012 Summer Olympics in London. Dickens was feeling sick during his semifinal race, with a running nose the morning of the race. He also finished in 16th in the 200-metre breaststroke, and was part of the Canadian team that finishing in 8th place in the men's 4 x 100 medley relay.
On October 23, 2013, Dickens announced he was retiring from swimming after ten years with the national team.
# ¡Qué fácil es estar en pareja! (18.379 consejos básicos)

¡Qué fácil es estar en pareja! (18.379 consejos básicos) (It's easy to be a couple! 18,379 basic tips) is a comedy book by Argentine author Luis Pescetti. It was first published in 1995.
# Keith Christian

Dr. Keith Christian is Professor of Zoology at Charles Darwin University where he teaches in the School of Environmental & Life Sciences.
He is a specialist in the physiology of amphibians and reptiles.
# Amblyscirtes reversa

Amblyscirtes reversa, the reversed roadside skipper, is a butterfly of the family Hesperiidae. The species was first described by Frank Morton Jones in 1926. It has a scattered distribution from south-eastern Virginia, south to northern Georgia. It is also found in southern Mississippi and southern Illinois.
The wingspan is 29–35 mm. Adults are on wing from April to August. There are two to three generations per year.
The larvae feed on Arundinaria tecta. Adults feed on flower nectar.
# Franciskovići

Franciskovići (Serbian Cyrillic: Францисковићи) is a neighborhood in Boka Kotorska, Montenegro.
Located east of Krašići on the Luštica peninsula, the village was named after the Serbian family Francisković who built it in the 15th century.
42°24′30″N 18°39′12″E﻿ / ﻿42.40833°N 18.65333°E﻿ / 42.40833; 18.65333
* This Montenegro location article is a stub. You can help Wikipedia by expanding it.
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# Pittsburgh International Airport People Movers

The Pittsburgh International Airport People Mover is a fully automated people mover system at the Pittsburgh International Airport serving Pittsburgh, Pennsylvania.
Designed and installed at a cost of $14 million by AEG-Westinghouse (now Alstom), it runs in two parallel tunnels to connect the Landside Terminal with the Airside Terminal.

## History

The Pittsburgh International Airport People Mover began service upon the opening of the new Midfield Terminal on October 1, 1992, using Westinghouse C-100 vehicles (now known as Alstom Innovia APM 100).
To handle increasing passenger traffic, a $9.5 million improvement project was undertaken by Adtranz in 1999. A total of two cars were added to the people mover system; one was added to each train, turning each two-car train into a three-car train. The stations were then expanded to accommodate the extra cars. The project also included refurbishing of the original cars.
Beginning in 2014 and ending in 2016, the second, $11-million project to the tram system was done by Bombardier (now Alstom) as the system was beginning to age. Components like underframes, floors, climate control, and lighting were updated during this project.
The proposed remodeling project for the airport, unveiled in 2017, planned to take the trams out of service permanently because the proposed Landside Terminal was slated to be connected to the existing Airside Terminal. Construction began in 2021 and is slated to be finished in 2025, which could result in the tram being decommissioned and removed around this time.
# Mahamat Idriss

Mahamat Idriss (ne Koundja Ouya, 17 July 1942 – 3 October 1987) was a Chadian high jumper.
He was born in Fort-Lamy, Chad, French Equatorial Africa.

## Career

Before the Chadian independency on 11 August 1960 he competed for France, winning the French national championships in 1960 and 1961. He also finished twelfth at the 1960 Olympic Games while representing France.
For Chad he finished ninth at the 1964 Olympic Games. It is still Chad's best position ever at the Olympic Games. On the Track and Field News annual world rankings Idriss placed ninth in 1961, tenth in 1964 and eighth in 1966.
His personal best jump was 2.17 metres, achieved in April 1966 in Fort-Lamy. This is still the Chadian record, although it has been equalled by Paul Ngadjadoum and Mathias Ngadjadoum in 1993 and 1996 respectively.
# Shawn Adams

Shawn Adams (born April 4, 1974, in Bridgewater, Nova Scotia) is a Canadian curler from Upper Tantallon, Nova Scotia.

## Career

Adams rose to curling prominence being runner-up at the 1992 Canadian Junior Curling Championships, and then the next year, won the 1993 Canadian Junior Curling Championships, however he was stripped of the championship because of alcohol violations after the victory.
7 years later Adams came back to the scene winning the Nova Scotia championships for the right to go to the 2000 Labatt Brier, where he finished 3–8. Two years later, at the 2002 Nokia Brier he improved on that record with a 6–5 record. Finally, at the 2005 Tim Hortons Brier, Adams would finish the round-robin with an 8–3 record earning him a berth in the playoffs. In the playoffs, Adams defeated Quebec's Jean-Michel Menard in the 3–4 game, then he defeated Manitoba's Randy Dutiaume in the semi-final before losing to Randy Ferbey and Alberta in the final. Adams won his final Nova Scotia championship in 2011, and went 5–6 at the 2011 Tim Hortons Brier.
In 2011, Adams moved to Newfoundland and Labrador. In 2013, he played in his only provincial championship in the province. He would later move back to Nova Scotia.

## Grand Slam record

Key :
| C | Champion |
| F | Lost in Final |
| SF | Lost in Semifinal |
| QF | Lost in Quarterfinals |
| R16 | Lost in the round of 16 |
| Q | Did not advance to playoffs |
| T2 | Played in Tier 2 event |
| DNP | Did not participate in event |
| N/A | Not a Grand Slam event that season |
| Event | 2005–06 | 2006–07 | 2007–08 | 2008–09 | 2009–10 | 2010–11 | 2011–12 | 2012–13 | 2013–14 | 2014–15 | 2015–16 |
| Masters | SF | Q | Q | Q | DNP | DNP | DNP | DNP | DNP | DNP | Q |
| Canadian Open | DNP | DNP | F | DNP | DNP | DNP | DNP | DNP | DNP | DNP | DNP |
| The National | Q | QF | Q | Q | DNP | DNP | DNP | DNP | DNP | DNP | DNP |
| Players' | DNP | DNP | Q | DNP | DNP | DNP | DNP | DNP | DNP | DNP | DNP |
# Koska et oo täällä enää

"Koska et oo täällä enää" is a song performed by Finnish singer-songwriter Saara Aalto. It was released to digital retailers and streaming platforms on 1 November 2019 by Warner Music Finland. It was released as the second single from her seventh studio album Fairytale – Joulun taikaa.

## Personnel

Credits adapted from Tidal.
* Arto Ruotsala – producer, mixer, programmer
* Saara Aalto – producer, composer, lyricist, vocals
* Meri Sopanen – lyricist
* Pete Eklund – A&R manager

## Charts

| Chart (2019) | Peak position |
| Finland Airplay (Radiosoittolista) | 41 |

## Release history

| Region | Date | Format | Label |
| Various | 1 November 2019 | Digital downloadstreaming | Warner Music Finland |
# Nicholas Orzio

Nicholas Orzio (White Plains, November 12, 1928 - Rockledge, February 5, 2016) was an American photographer. He is known for his World War II photographs. He was inducted into the International Photography Hall of Fame in 1998.
# Marcel Boishardy

Marcel Boishardy (7 February 1945 – 23 September 2011) was a French racing cyclist. He rode in the 1973 Tour de France.
# Gifted Program (Abbott Elementary)

"Gifted Program" is the sixth episode of the American sitcom television series Abbott Elementary. It was written by Jordan Temple, and was directed by Matt Sohn, and the first of which not to be directed by Randall Einhorn. It premiered on the American Broadcasting Company (ABC) in the United States on February 1, 2022.

## Plot

After noticing that a smart new student has transferred to Abbott, Janine (Quinta Brunson) is inspired to start a "gifted program" at their school full of academically excelling students. Janine asks Jacob (Chris Perfetti) to teach. However, many of the other students not in the gifted program start to feel left out. This causes Janine to try to replicate the gifted program's lessons in her own class, only to end up accidentally releasing snakes in the school. With advice from Gregory (Tyler James Williams), Janine dismantles the gifted program in favor of creating a rotational enrichment program for all the students of the school. Meanwhile, Barbara (Sheryl Lee Ralph) encourages a stubborn Melissa (Lisa Ann Walter) into going out with the vending machine owner, Gary, who resupplies snacks in the teacher's breakroom.

## Reception

Upon its initial broadcast on ABC, "Gifted Program" was viewed by 2.77 million viewers, slightly less than the previous episode. This rating earned the episode a 0.58 in the 18-49 rating demographics on the Nielson ratings scale.
The episode airs following its midseason entry in the 2021–22 television season. Filming for the sixth episode took place between August 16, and November 5, 2021, in Los Angeles, California. Like other episodes, interior scenes are filmed at Warner Bros. Studios, Burbank in Burbank, California, with exterior shots of the series being filmed in front of Vermont Elementary School in Los Angeles.
# Tyler Rorke

Tyler Rorke (born May 28, 2003) is a Canadian track cyclist competing in the sprint events. Rorke has won multiple medals in the team sprint event at the Pan American level.

## Career

Rorke made his senior team debut at the 2022 Commonwealth Games. At the 2023 Pan American Games, Rorke won gold in the team sprint event. Rorke has won three medals in the team sprint event at the Pan American Track Cycling Championships, gold in 2023, with silvers in 2022 and 2024.
In June 2024, Rorke was named to Canada's Olympic team. This will mark Rorke's first appearance at the Olympics.
# Paul Moulden

Paul Anthony Joseph Moulden (born 6 September 1967) is an English former footballer who played as a striker for Manchester City, AFC Bournemouth, Oldham Athletic, Molde, Brighton & Hove Albion, Birmingham City, Huddersfield Town and Rochdale. He represented England at youth levels.

## Career

Moulden was born in Farnworth, near Bolton, Lancashire. and attended Thornleigh Salesian School in Bolton As a youth he entered the Guinness Book of Records by scoring 340 goals in a single season for Bolton Lads Club under-15s. He subsequently joined Manchester City, where he was a part of the team which won the 1986 FA Youth Cup. He made his first team debut on 1 January 1986 against Aston Villa aged 18. He made only two further first team appearances that season, both as substitute, but finished the season as top scorer for the reserve team. His first extended run in the first team came in late 1986, and he scored his first goals for the club in a 3–1 win over Aston Villa on 8 November. A broken leg restricted him to three starts in the 1987–88 season. The following season Moulden started the majority of matches, finishing the season as top scorer with 13 goals in 36 league appearances as Manchester City gained promotion to the First Division. However, in the close season he was sold to AFC Bournemouth as a makeweight in the deal which took Ian Bishop to Maine Road.
Moulden spent just seven months on the south coast, scoring 13 goals in 37 starts for the Cherries, before moving to Oldham Athletic on transfer deadline day. At Oldham he struggled with injuries, starting 19 matches in three years. In 1992, Moulden had loan spells at Norwegian club Molde and Brighton & Hove Albion. He then had short spells with a succession of clubs, playing for Birmingham City, Huddersfield and Rochdale before dropping out of League football in 1996.
After retiring from full-time football, he opened a fish and chip shop and played non-league football for Accrington Stanley and Bacup Borough. He went on to coach juniors at his old boys' club and at Manchester City's academy.

## Personal life

His son Louie is also a footballer.
# Jeremiah Hall

Jeremiah Hall (born November 6, 1998) is a former American football fullback. He played college football for the Oklahoma Sooners.

## Early life

Hall grew up in Charlotte, North Carolina and attended Zebulon B. Vance High School. He was named first-team All-State as a senior after gaining 1,005 yards of total offense and scoring 22 touchdowns. Hall was rated a three-star recruit and committed to play college football at Oklahoma over offers from Maryland, Pittsburgh, and Syracuse.

## College career

Hall redshirted his true freshman season at Oklahoma. He played in all 14 of Oklahoma's games during his redshirt freshman season and rushed four times for 21 yards and had two receptions for 36 yards. As a redshirt sophomore, Hall caught 16 passes for 169 yards and 3 touchdowns and was named second-team All-Big 12 Conference. He was named first-team All-Big 12 after catching 18 passes for 218 yards and five touchdowns. He repeated as a first-team All-Big 12 selection after finishing his senior season with 32 receptions for 334 yards and four touchdowns.

## Professional career

Hall signed with the New York Giants as an undrafted free agent on May 16, 2022. He was waived on August 16, 2022.
# 2024 Wuhan Open

The 2024 Wuhan Open (also known as Dongfeng Voyah Wuhan Open for sponsorship reasons) is a women's tennis tournament played on outdoor hard courts between October 7–13, 2024. It is the 7th edition of the Wuhan Open, and part of the WTA 1000 tournaments of the 2024 WTA Tour. It is the first edition of the tournament since 2019, with the intervening editions cancelled due to the COVID-19 pandemic. The tournament is held at the Optics Valley International Tennis Center in Wuhan, China.

## Points and prize money
### Point distribution

| Event | W | F | SF | QF | Round of 16 | Round of 32 | Round of 64 | Q | Q2 | Q1 |
| Singles | 1000 | 650 | 390 | 215 | 120 | 65 | 10 | 30 | 20 | 2 |
| Doubles | 1000 | 650 | 390 | 215 | 120 | 10 | — | — | — | — |

### Prize money

| Event | W | F | SF | QF | Round of 16 | Round of 32 | Round of 64 | Q2 | Q1 |
| Singles | $525,115 | $309,280 | $159,439 | $73,193 | $36,568 | $20,714 | $14,846 | $8,828 | $4,624 |
| Doubles | $154,640 | $86,980 | $46,715 | $24,165 | $13,693 | $9,128 | — | — | — |

## Champions
### Singles

* Aryna Sabalenka def. Zheng Qinwen 6–3, 5–7, 6–3

### Doubles

* Anna Danilina / Irina Khromacheva def. Asia Muhammad / Jessica Pegula 6–3, 7–6$^{(8–6)}$

## Doubles main-draw entrants
### Seeds

| Country | Player | Country | Player | Rank$^1$ | Seed |
| CAN | Gabriela Dabrowski | NZL | Erin Routliffe | 6 | 1 |
| USA | Nicole Melichar-Martinez | AUS | Ellen Perez | 21 | 2 |
| USA | Caroline Dolehide | USA | Desirae Krawczyk | 22 | 3 |
| ITA | Sara Errani | ITA | Jasmine Paolini | 28 | 4 |
| BEL | Elise Mertens | CHN | Zhang Shuai | 36 | 5 |
| TPE | Chan Hao-ching | | Veronika Kudermetova | 40 | 6 |
| NED | Demi Schuurs | BRA | Luisa Stefani | 45 | 7 |
| USA | Sofia Kenin | USA | Bethanie Mattek-Sands | 47 | 8 |
* Rankings are as of September 23, 2024

### Other entrants

The following pairs received wildcards into the doubles main draw:
* Jaqueline Cristian / Kamilla Rakhimova
* Tang Qianhui / Wang Xiyu

### Alternates

* Elina Avanesyan / Olivia Gadecki

### Withdrawals

* Harriet Dart / Ashlyn Krueger → replaced by Elina Avanesyan / Olivia Gadecki
# Jean-François Bell

Jean-François Bell (born October 6, 1981) is a retired Cameroonian football (soccer) defender.

## Playing career

During his career, Bell played for Étoile Carouge FC, AC Bellinzona, BSC Young Boys, FC Vaduz, FC Wil 1900, Tonnerre Yaoundé, Urania Genève Sport and FC Plan-les-Ouates.
# Calguia defiguralis

Calguia defiguralis is a species of snout moth in the genus Calguia. It was described by Francis Walker in 1863. It is found in Borneo and Guangdong, China. It has also been recorded from Australia, Sri Lanka and Taiwan.
# Bartholomew Lane

Bartholomew Lane, in the City of London, runs between the junction of Lothbury and Throgmorton Street in the north to Threadneedle Street in the south. The lane is bordered on its western side by the Bank of England.
The lane is associated with the auctioneer George Robins, whose premises The Auction Mart stood opposite the rotunda of the Bank.
The church of St Bartholomew-by-the-Exchange stood on the eastern side on the corner with Threadneedle Street until it was destroyed in the Great Fire of 1666. It was rebuilt by the office of Sir Christopher Wren and demolished in 1840.
# WAMO

WAMO may refer to:
* WAMO (AM), a radio station (660 AM) licensed to Wilkinsburg, Pennsylvania, United States
* WAOB (AM), a radio station (860 AM) licensed to Millvale, Pennsylvania, which used the call sign WAMO from 1956 until 2009
* WAOB-FM, a radio station (106.7 FM) licensed to Beaver Falls, Pennsylvania, which used the call sign WAMO-FM from 1960 until 2009
* Warner Advanced Media Operations (WAMO), a division of WEA Manufacturing
* The Washington Monument in Washington, D.C.
# Marcel Brunie

Marcel Brunie (29 June 1894 – 12 April 1977) was a French racing cyclist. He rode in the 1922 Tour de France.
# Underground (soundtrack)

Professional ratings :
| Review scores ||
| Source | Rating |
| Allmusic | |
Underground is an album by Goran Bregović, with the music from the film with the same title by Emir Kusturica. Several songs from this album, such as "Mesečina" and "Kalašnjikov", became instant-classic tavern and brass-band hits. The Boban Marković Orchestra is heavily featured in the soundtrack.
Among other pieces, "Mesečina" was performed by Keba, Trans-Siberian March Band and The Lemon Bucket Orkestra. Sezen Aksu covered "Kalašnjikov", "Ausência" and "Mesečina" in Turkish language on her 1997 Bregović-produced album Düğün ve Cenaze, titled "Kalaşnikof", "O Sensin" and "Ayışığı", respectively.

## Track listing

* Kalašnjikov (cf. Kalashnikov)
* Ausência (feat. Cesária Évora)
* Mesečina / Moonlight
* Ya Ya (Ringe Ringe Raja)
* Cajesukarije-Čoček
* Wedding‐Čoček
* War
* Underground‐Čoček
* Underground Tango
* The Belly Button of the World
* Sheva
# Dus Bahane 2.0

"Dus Bahane 2.0" (transl. Ten Excuses 2.0) is a Hindi song from the 2020 film Baaghi 3. The song was a recreation of the original "Dus Bahane" from the film Dus which was sung by Vishal–Shekhar featuring the vocals of KK, Shaan and Tulsi Kumar. The song was recorded, mixed and mastered by Eric Pillai - Future Sound Of Bombay in Mumbai. The song is arranged and programmed by Meghdeep Bose.

## Music video

The makers of Baaghi 3 released its first song "Dus Bahane 2.0" on Wednesday. The track is a rehash of the title track "Dus Bahane" of 2005 film Dus. The music video featured Tiger Shroff and Shraddha Kapoor.

## Release

A teaser of the song was released on 1 February 2020. The official song was released on the T-Series's YouTube channel on 12 February 2020. The song was also made available for Online streaming on Saavn, iTunes and Gaana on the same day. The full music album was released on 5 March 2020 by T-Series.

## Music credits

Credits adapted from T-Series.
* Vishal and Shekhar – composer
* Vishal Dadlani, Shekhar Ravjiani, KK, Shaan, Tulsi Kumar – Singers
* Panchhi Jalonvi – Lyrics
* Meghdeep Bose – Music Producer & Arranger
* Nitin FCP – Song Editor
* Eric Pillai – mixing, mastering [at Future Sound of Bombay]
* Michael Edwin Pillai – assistance mixing, assistance mastering
* Sohrabuddin – recording engineer [at T-Series Studio (Delhi)]
* Meghdeep Bose – recording engineer [at Sound Bakery (Mumbai)]
* Priyanshu Soni – recording assistance
* Prince Gupta – Choreography