OpenLLM-France/wikimedia huggingface dataset:
# Spiroketals

In chemistry, Spiroketals are structural motifs composed of two heterocycles sharing one central carbon which makes them a subclass of spiro compound. Their structural specificity lays on the presence of one oxygen atom in each ring, in alpha of the spiro carbon. Although there are no rules about the size of each ring, the most widely encountered spiroketal are composed of five and six membered rings.

## Occurrence in nature

Many natural products of biological interest contain [6,5]- and [6,6]-spiroketal moieties that can adopt various configurations. The first example of a spiroketals in the literature appeared before 1970, such as the triterpenoid saponins and sapogenins. Then several works described the presence of spiroketals in various compounds. Like diarrheic shellfish poisoning (DSP) class of toxins containing in the okadaic acid and ancanthafolicin. The most noticeable occurring spiroketals are the whole range of fruit fly pheromones.

## Pharmacology interest

Due to its non-planar substructure, the spiroketal motif gain interest among the academical and industrial pharmaceutical research fields, both in structure-based drug design (SBDD) and development of screening libraries.
Avermectins have been found in fungus and are antiparasitic drugs. The avermectins appear to paralyze nematodes and arthropods by potentiating the presynaptic release of gamma-aminobutyric acid, thereby blocking post-synaptic transmission of nerve impulses
Tofogliflozin is an inhibitor of human sodium glucose cotransporter 2 (hSGLT2) and was approved in 2014 in Japan for the treatment of Type 2 diabetes

## Chemical synthesis
### Acid catalyzed spiroketalisation

The most employed method to ring close spiroketal consists in the hydrolysis of the dihydroxyketal in acidic conditions, but this method is not granting stereocontrol. Thus, several miscellaneous methods have emerged in order to control the stereoselectivity of the spirocyclisation.
# Vanguard Visionaries (Alison Brown album)

Vanguard Visionaries is a compilation album by American banjoist Alison Brown, released in 2007.

## History

Vanguard Records played a significant role in the 1960s folk revival, releasing music by many influential folk artists, including Doc Watson, Odetta, John Fahey and many others. To commemorate their 60th anniversary, Vanguard released a series of artist samplers titled Vanguard Visionaries.
Professional ratings :
| Review scores ||
| Source | Rating |
| Allmusic | |

## Track listing

All compositions by Alison Brown unless otherwise noted
* "Leaving Cottondale" – 2:32
* "Simple Pleasures" – 2:51
* "Wolf Moon" – 2:52
* "Shoot the Dog" – 3:24
* "Chicken Road" – 4:28
* "View from Above" – 4:54
* "Look Left" – 5:00
* "Cara's Way" – 5:18
* "G Bop (Brown, Burr, Reed, West)" – 3:08
* "Without Anastasia" – 3:13

## Personnel

* Alison Brown – banjo, guitar
* Garry West – bass
* John R. Burr – piano
* Rick Reed – drums, percussion
# Threads (David S. Ware album)

Threads is an album by saxophonist and composer David S. Ware's String Ensemble which was recorded in 2003 and released on the Thirsty Ear label.

## Reception

Professional ratings :
| Review scores ||
| Source | Rating |
| AllMusic | |
| The Guardian | |
| The Penguin Guide to Jazz Recordings | |
In his review for AllMusic, Thom Jurek states "Threads is easily Ware's classic thus far in that it showcases the musician at the height of all of his powers: improvisational, compositional, and as an arranger and bandleader. This is Ware's masterpiece and the first really new compositional statement in jazz in years" The Guardian's John Fordham stated "Some fascinating free-improv, often against startlingly tender and conventionally-harmonised textures, though unlikely to suit a Friday night at Ronnie's".
PopMatters observed "if Threads won’t immediately make Ware as well known as a composer as he is as a player, it definitely serves as a loud call that his skills don’t end with his saxophone". The All About Jazz review said "While some may question this seemingly off-kilter group of selections, it seems that Ware is once again searching for some new musical plane that may be unknown but definitely makes the journey interesting". JazzTimes noted "It's hard not to think of Ware as a guest star on Threads, at least on first listen. However the music's power ends up taking over, making the album likely to become one of the most significant offerings in the saxophonist's career".

## Track listing

All compositions by David S. Ware except as indicated
* "Ananda Rotation" (Matthew Shipp, Ware) - 6:39
* "Sufic Passages" - 9:02
* "Weave Part 1" (Guillermo E. Brown, Ware) - 3:21
* "Threads" - 13:00
* "Carousel of Lightness" - 9:02
* "Weave Part 2" (Brown, Ware) - 3:41

## Personnel

* David S. Ware - tenor saxophone
* Matthew Shipp - piano, Korg Triton
* Daniel Bernard Roumain - violin
* Mat Maneri - viola
* William Parker - bass
* Guillermo E. Brown - drums
# Taro Island

Taro Island is a small island in Solomon Islands with 507 inhabitants. It is the capital of Choiseul Province and is located in Choiseul Bay off the northwest coast.
Taro Island is home to the Choiseul Bay Airport, served by Solomon Airlines with flights to Gizo and other destinations.
In September 2012, groundbreaking for the construction of a police housing project began. The project will be supervised by the Choiseul Province police board, and will strengthen police presence on the island.
The island is vulnerable to sea level rise. In 2016, John A. Church, Colin Woodroffe, and other Australian researchers from CSIRO predicted that Taro Island would become the first provincial capital globally to relocate residents and services due to the threat of sea level rise.
# The Dan Band Live

Professional ratings :
| Review scores ||
| Source | Rating |
| Allmusic | link |
The Dan Band Live is the first album released by The Dan Band. It includes humorous covers of various pop songs.

## Track listing

* "Free Your Mind/I Am Woman"
* "Gloria/Mickey"
* "ABBA Medley"
* "Shoop/Whatta Man/Never Gonna Get It"
* "Genie in a Bottle/No Scrubs/Slave 4 U"
* "Tyrone/No More Drama"
* "Hold On/Luka"
* "Milkshake"
* "Total Eclipse of the Heart"
* "Flashdance/Fame"
* "Whenever Wherever/Hips Don't Lie"
* "You Oughta Know"
* "Que Sera, Sera"
* "I Wanna Rock You Hard This Christmas" (Bonus Track)
* "Total Eclipse of the Heart" (Bonus Track - Studio Version)
# Vincenzo Pacetti

Vincenzo Pacetti (1746–1820) was an Italian sculptor and restorer from Castel Bolognese, particularly active in collecting and freely restoring and completing classical sculptures such as the Barberini Faun (1799 – now in the Glyptothek, Munich)— his most famous work— the Hope Dionysus (now in the Metropolitan Museum of Art) and the Athena of Velletri (1797 – now in the Louvre) and selling them on to rich collectors as finished artefacts. He was the brother of Camillo Pacetti.

## Biography

Vincenzo Pacetti was born in 1746. He studied at the Accademia del Nudo and then trained in the studio of the sculptor-restorer, Pietro Pacili, 1766–72, taking over Pacili's studio at the elder sculptor's death.
As an independent sculptor he was accepted into the Accademia di San Luca, presenting his portrait (illustration) and serving as director, a testament to his reputation. Bartolomeo Cavaceppi, another leading sculptor-restorer esteemed Pacetti enough to make him executor of his will.
From the Barberini, Pacetti was promised the purchase of a cache of Roman sculptures and fragments in 1799, among which prominently figured the Barberini Faun. He removed earlier restorations and sculpted a new right leg in marble, but the members of the Barberini family withdrew their offer of sale, and Pacetti was reimbursed the sum of 2000 zecchini.
As the favoured sculptor-restorer for Prince Marcantonio Borghese, he also produced many reliefs and stucchi on mythological themes for the Sala degli Imperatori (of which "The goat Amanthea" and "Perseus freeing Andromeda" are most notable) and the room housing Bernini's Aeneas and Anchises and Apollo and Daphne, both at the Galleria Borghese. Other works of his are in San Salvatore in Lauro, Santo Spirito in Sassia, Santi Michele e Magno, and the Palazzo Carpegna.
In the latter end of his career his most important patron was Lucien Bonaparte, for whom he supplied plaster casts of famous antique sculptures for his villa at Canino.
He died in Rome. His diary covering the years 1773–1803, and correspondence are important primary resources for the Roman art market of his day.
# Spinasterol

α-Spinasterol is a stigmastane-type phytosterol found in a variety of plant sources such as spinach, from which it gets its name.
The chemical was recently found in Gordonia ceylanica, the first time that this chemical was found in the Gordonia species.
# Three Uneasy Pieces

Three Uneasy Pieces is a collection of three short stories by Australian writer Patrick White, first published by Pascoe Publishing in 1987. It is the final work of fiction he published in his life.

## Contents

* The Screaming Potato
* Dancing with Both Feet on the Ground
* The Age of a Wart
# Sri Sridhara Ayyaval Mutt

The Sri Sridhara Ayyaval Mutt is a Hindu mutt in the village of Thiruvisanallur. The mutt was established by a Saivite saint Sridhara Venkatesa Ayyaval who lived and preached here in the late 17th century. The main duties of the mutt are to perpetuate the memory of Sridhara Ayyaval. The mutt also organizes philanthropic activities and holds pujas during major Hindu festivals.
The mutts in Tamil Nadu started for the purpose of developing Hinduism and serving the public. More are less than they are performing the welfare activities in the society. Constructing a temple in Tamil Nadu (by stone) is so expensive. Likewise maintaining the old temple showing the ancient Tamil Nadu culture and style is also expensive. The mutts are partially taking the service.
The following Navagraha temples are situated in the districts of Thanjavur Nagappatinam Thiruvarur and Puducheri territory. But the Kumbakonam town is surrounded by all the Navagrasthalam. So we can take trip from Kumbakonam.
| SL.No | Name of village | Navagraha Temple | Phone Number | Nearby town | Kilometers |
| 1 | Suriyanar koil | Temple of Sun | 0435-2472349 | Kumbakonam | 15 |
| 2 | Thingaloore | Temple of Moon | -- | Thanjavur | 14 |
| 3 | Vaitheeswaran koil | Temple of Mars | 04364-279423 | Mailaduthurai | 13 |
| 4 | Thiruvenkadu | Temple of Mercury | 04364-256424 | Mailaduthurai | 25 |
| 5 | Alangudi | Temple of Jupiter | 04374-269407 | Kumbakonam | 15 |
| 6 | Kanjanur | Temple of Venus | 0435-2473737 | Kumbakonam | 21 |
| 7 | Thirunallar | Temple of Saturn | 04368-236530 | Karaikkal | 05 |
| 8 | Thirunageswaram | Temple of Raghu | 0435-2463354 | Kumbakonam | 17 |
| 9 | Keezha Perumpallam | Temple of Kedhu | 04364-275222 | Mailaduthurai | 33 |
# Tarikh-i Dost Sultan

Tarikh-i Dost Sultan (named for Dost Sultan, son of Bujugha khan, who briefly ruled the Khanate of Khiva in 1557-1558, apparently the patron of the work) is a work of Ötemish Hajji bin Mawlana Muhammad Dosti [ru], an historian of Khwarezm. It is a narrative account of the history of the Ulus of Jochi, including the conversion of Uzbeg Khan, leader of the Golden Horde, to Islam in the early 14th century. The "Tarikh-i Dost Sultan" also served as the foundation for the early historical sections of 'Abdulgaffar Qirimi's Umdet üt-tevärih, a history of the Crimean Tatar people written in 1744.
The work survives only in a single complete manuscript, formerly owned by Turkologist and Bashkir nationalist Zeki Velidi Togan (d. 1970). It has not been edited, and scholarly discussion is limited to Togan's own publications, and publications such scholars as have consulted the manuscript in Togan's library.
# Taste the Salt

Taste the Salt is an album by Daryl Braithwaite released in November 1993. The album reached No. 13 on the Australian ARIA Charts.
Braithwaite undertook the Taste the Salt Tour, nationally from 1 March to 18 April 1994.

## Track listing

* "In the Distance" (Daryl Braithwaite, Ricky Edwards, Simon Hussey)
* "Barren Ground" (Bruce Hornsby, John Hornsby)
* "Breakin' the Rules" (Robbie Robertson)
* "The World as It Is" (Tina Harris, Daniel O'Brien)
* "Wind and Sea" (Ricky Edwards, Daryl Braithwaite)
* "Reflection of Me" (P. Bowman, A. McSweeney)
* "Look What Your Love Has Done to Me" (John Capek, Marc Jordan)
* "Gonna Be Somebody" (John Waite, Jonathan Cain, Anthony Brock)
* "Trust Somebody" (Marc Jordan, Richard Page, Patrick Leonard)
* "Hundreds of Tears" (Sheryl Crow, Robert Marlette)
* "Shout" (Lawrence Maddy, Daryl Braithwaite)

## Personnel

* Daryl Braithwaite – vocals
* Stuart Fraser – guitar, bass
* Scott Griffiths – piano, keyboards, string arrangement
* Simon Hussey – keyboards, drum machine, additional drums, producer
* John Watson – drums, percussion
* John Corniola – additional drums

## Charts

| Chart (1993–94) | Peak position |
| Australian Albums (ARIA) | 13 |

## Singles

| Release date | Single | Peak chart positions |
| Release date | Single | Australia |
| 11 October 1993 | "The World as It Is" | 35 |
| 4 January 1994 | "Barren Ground" | 61 |
| 22 March 1994 | "Breaking the Rules" | — |

## Release history

| Country | Date | Label | Format | Catalog |
| Australia | 8 November 1993 | Columbia/Sony Music Australia | CD | 474864.2 |
# Tauhinu

Tauhinu is the Māori name for at least two different species of plants native to New Zealand:
* Ozothamnus leptophyllus, a common colonising native shrub.
* Pomaderris phylicifolia, an endangered colonising plant.
# Paul Mirabaud

Paul Barthélemy Mirabaud (29 June 1848 – 12 May 1908) was a French banker and philatelist from Versailles, Yvelines who was a specialist in the stamps of Switzerland.
In 1921, he was one of the "Fathers of Philately" entered on the Roll of Distinguished Philatelists. Together with Swedish-born Baron Axel de Reuterskiöld he wrote Les Timbres Postes de la Suisse 1843-1860 which was published in 1899. The book is considered well-researched and the first published deep study of Swiss philately. The book is still considered a standard reference and has been the basis for many more modern or more particular enquiries into the field of the Swiss classical issues.
# Taubenkopf

Taubenkopf is the name of the following hills in Germany:
* Taubenkopf (Haardt), a hill in the Haardt mountains of Rhineland-Palatinate
* Taubenkopf (Sickingen Heights), a hill in the northern part of the Sickingen Heights
# St. Andrew's College, Saskatoon

St. Andrew’s College, formerly the Presbyterian Theological College, is a degree-granting, accredited theologically ecumenical seminary of the United Church of Canada. It is located in Saskatoon, Saskatchewan, and was the second affiliated college of the University of Saskatchewan. Along with the College of Emmanuel and St. Chad (Anglican Church of Canada), and the Lutheran Theological Seminary, Saskatoon (Evangelical Lutheran Church in Canada), it makes up the Saskatoon Theological Union (STU).

## History

The Presbyterian Theological College was founded in 1912 and confirmed by an Act of the Saskatchewan Legislature in 1913. That same year, Edmund H. Oliver began his tenure as the first principal of the college, appointed by the Presbyterian General Assembly of Canada. The college was initially founded to meet the needs of students "who had declared their intention of entering the ministry", and in 1920 started training workers among New Canadians.
In 1914, Presbyterian Theological College began the construction of a building on the University of Saskatchewan property but was disrupted by World War I after most of its student body enlisted. The building that St. Andrew's currently occupies was developed in 1922. It had 28 students in 1921-22: ten from Canada, seven from Scotland, five from England, three from Ireland, and one each from France, Hungary, and the United States.
In 1925, Presbyterian Theological College was renamed St. Andrew's College, following the formation of the United Church of Canada.

## Social justice and equity

St. Andrew's invested its first woman graduate in 1922, Lydia Emelie Gruchy, though it would take an additional 13 years for her ordination by the United Church of Canada. The college had a number of conscientious objectors in World War II and the government threatened to close the college in 1942 unless all eligible men would enlist.
The concept of justice and equity were increasingly preoccupations of the college throughout the 1960s, cementing its reputation as a progressive and politically activist theological school. The 1970s saw a shift in student demographics as more women began enrolling and graduating. In 2009, St. Andrew’s began participating in the Affirming Ministries Program of Affirm United, a further shift for inclusivity and equity among diverse sexual orientations and gender identities.

## Programs

St. Andrew’s offers a variety of programs, including Master of Divinity (MDiv), Master of Theological Studies (MTS), and Doctor of Ministry (DMin) degrees. A range of learning certificates are also available, including “Leadership in the Faith Community”, “Leadership in the World”, and “Spiritual Exploration.” St. Andrew's is accredited through the Association of Theological Schools in the United States and Canada.
# Platform 1

Platform 1 is a mental health charity based in Huddersfield, England. It is situated near Huddersfield railway station.

## History

The charity was started in April 2018 by Bob Morse, who has had depression and suicidal thoughts in the past, and Gez Walsh.
In 2020, the charity was announced as one of the winners of the Department for Transport's Transform a Pacer competition. It received a Class 144 unit on 10 July 2021. It plans to convert the former train carriage into a kitchen.

## Work

Platform 1 aims to reduce loneliness by providing a meeting space, support, and community. Activities include bicycle repair.
# Taubensee (Kössen/Unterwössen)

Taubensee (Kössen/Unterwössen) is a lake of Tyrol, Austria.
* This Tyrol location article is a stub. You can help Wikipedia by expanding it.
* v
* t
* e
# The Eye of Judgment: Legends

The Eye of Judgment: Legends is a turn-based card battle video game for the PlayStation Portable. It is a spin-off of the 2007 PlayStation 3 release The Eye of Judgment. Unlike the original game, Legends uses a completely virtual card system rather than having the player own physical cards. With that in mind, it does not use the PSP's camera attachment.
# Scanship

Scanship is a Norwegian company that produces wastewater purification and waste management systems for ferries, cruise ships, disaster relief and merchant shipping.
The company is headquartered in Tønsberg, Norway while the publicly listed holding company which holds all the shares in the company is located in Lysaker.
Scanship has operations in Norway, the United States, Canada, Poland and Italy.
The company started trading on Oslo Axess on April 11, 2014.
# Per Jansen

Per Johan Jansen (14 December 1941 – 8 August 2022) was a Norwegian stage and film actor.

## Life and career

Jansen was born in Bergen on 14 December 1941. He made his stage debut at Det Norske Teatret in 1966. He later had assignments at Oslo Nye Teater, Riksteatret, Hålogaland Teater, Trøndelag Teater, Nationaltheatret and Fjernsynsteatret. He played the title character in the film Ballad of the Masterthief Ole Hoiland from 1970, and the main character in the films A Commuter Kind of Love from 1979 and Hud from 1986. Jansen died on 8 August 2022, at the age of 80.
# Rennau

Rennau is a municipality in the district of Helmstedt, in Lower Saxony, Germany. The Municipality Rennau includes the villages of Ahmstorf, Rennau and Rottorf am Klei.
* Old postcard of Ahmstorf
* The Lutheran church in Rennau
* The Lutheran church in Rottorf am Klei
# Suzanne Chanteau

Suzanne Chanteau (born 27 June 1952) is a French Polynesian medical researcher who directed the Pasteur Institute in New Caledonia from 2008 to 2013. She is notable for developing rapid diagnostic tests for plague, cholera, and bacterial meningitis.
Chanteau was born in Papeete. After studying biology in France, she worked at the Malardé Institute in Tahiti from 1975 to 1993, working on Ciguatera fish poisoningg and Lymphatic filariasis. In 1994 she began working for the Pasteur Institute, initially in Madagascar, where she worked on Tuberculosis and Plague. In Madagascar she developed a rapid diagnostic method for plague and a rapid test for Cholera. In 2002 she was appointed director of the Pasteur Institute's research center in Niger, studying Meningitis. Again, she developed a rapid diagnostic test for the disease. From 2008 to 2013 she was director of the Pasteur Institute in New Caledonia.

## Honours

In 1999 she was made a knight of the Ordre national du Mérite. In 2002 she was made a knight of the National Order of Madagascar. In 2007 she was made a knight of the Legion of Honour.
In September 2019 she was made an officer of the Order of Tahiti Nui.
# Viola Lake

Viola Lake is a small lake in Val Viola, Lombardy, Italy. It is located in the municipality of Valdidentro.
# Three Days (Willie Nelson song)

"Three Days" is a song written by Willie Nelson. It was originally recorded by American country music artist Faron Young on his 1961 album The Young Approach. Young's version was released as a single in January 1962 and peaked at number 7 on the Billboard Hot Country Singles chart.
Nelson recorded his own version of the song on his 1962 debut album, ...And Then I Wrote. He later re-recorded the song for his 1998 album Teatro with backing vocals by Emmylou Harris.
"Three Days" was also recorded by Canadian country music artist k.d. lang on her 1989 album Absolute Torch and Twang. lang's version was released in October 1989 as the album's second single. It peaked at number 9 on the RPM Country Tracks chart in January 1990.
On the 1996 Willie Nelson tribute album, Twisted Willie, the song was performed by L7 with backup vocals by Waylon Jennings.

## Chart performance
### Faron Young

| Chart (1962) | Peak position |
| U.S. Billboard Hot Country Singles | 7 |

### k.d. lang

| Chart (1989–1990) | Peak position |
| Canada Country Tracks (RPM) | 9 |
| US Hot Country Songs (Billboard) | 55 |
# Platyarthridae

Platyarthridae is a family of woodlice, containing the following genera:
* Cephaloniscus Ferrara & Taiti, 1989
* Echinochaetus Ferrara & Schmalfuss, 1983
* Gerufa Budde-Lund, 1909
* Lanceochaetus Schmalfuss & Ferrara, 1978
* Manibia Barnard, 1932
* Niambia Budde-Lund, 1904
* Papuasoniscus Vandel, 1973
* Platyarthrus Brandt, 1833
* Trichorhina Budde-Lund, 1908
They are mostly less than 6 millimetres (0.24 in) long, and cannot roll into a ball (conglobate). They have no lungs on the pleopods, and have very small compound eyes, with fewer than 10 ommatidia. They are similar to members of the family Trachelipodidae, which do have pleopodal lungs, although the lungs can be inconspicuous.